wax additives - munzing.com · 2–3 industrial fluids - waxes content general overview 4 – 7...
TRANSCRIPT
WAX ADDITIVESFOR LUBRICANTS
FORM
ING & PROTECTION
2–3 INDUSTRIAL FLUIDS - WAXES
CONTENT GENERAL OVERVIEW 4 – 7
TEMPORARY CORROSSION PROTECTION 8 – 9
PTFE-PRODUCTS 10 – 11
CERETAN 12 – 13
MECHANISMOFWAXINFORMINGFLUIDS 14
The sphere makes the difference.
For more than 180 years, MÜNZING has been helping its
customers perfect their products by creating specialty
additives that are precisely right for them. As a highly
regarded, privately owned company headquartered in
Abstatt, Germany, MÜNZING has a presence in more
than 40 countries and is a technology-driven organiza-
tion with an extensive network of highly skilled R&D
and technical service professionals. Our manufactur-
ing plants in America, Europe and Asia have broad syn-
CERETAN – Spherical micronized waxesCERETAN spherical micronized waxes are produced us-
ing our highly advanced spraying technology. Not only
is their particle shape unique but also the way they en-
hance your formulation. The spherical shape offers a
very even surface, improves the dispersing properties
and redu ces the amount of wax usage due to its high
LUBA-print – Wax dispersionsOur high quality wax dispersions are a necessity for all
custo mers, who prefer working with a ready-made dis-
persion in contrast to a dry wax. The ease of incorporation
is one of the major advantages of the liquid products.
Being an expert for wax additives our technical service
Air milled waxes Spray micronized waxes
The sphere makes the difference.
efficiency. Thegenerationofdustduring the incorpo-
ration process is redu ced, because of the narrowly de-
finedparticlesizedistributionofourspraymicronized
waxes. We guarantee a D99 value, which reduces the
probability of oversized particles being contained in
your formulation.
team will help you improve your surface properties of
your products. In close cooperation with you, our
modern laboratory and staff are at your disposal to
develop and formulate wax disper sions to meet your
specificneedsandprovidethedesiredeffects.
thesis and formulation capabilities in order to best
serve our global customer base.
Our additives have achieved worldwide recognition for
their performance, quality and technical innovation.
This first-class product line includes defoamers,
dispersants, rheology modifiers, emulsifiers,
wetting and leveling agents, micronized and
coated waxes, and wax dispersions and emul-
sions.
4–5 INDUSTRIAL FLUIDS - WAXES
General overview
Product Chemistry of additive
Carrier system
Base fluid Additive
Ant
i-gr
affiti
Bik
e ch
ain
lubr
ican
t
Care
pro
duct
s
(car
)
Care
pro
duct
s
(floo
r)
Cutt
ing
past
e
Die
cas
ting
(A
lum
iniu
m, …
)
EP-A
ddit
ive
Hot
for
ging
(r
elea
se a
gent
)
NSF
-H1
lubr
ican
ts
Oil
base
d lu
bric
ant
(d
eep
draw
ing)
Pol
ymer
sea
ling
Scre
w c
oati
ngs
Sint
er m
etal
(d
ry w
ax lu
bric
ant)
Tem
pora
rry
corr
osio
n pr
otec
tion
Tran
spor
t pr
otec
tion
(a
nti-
scra
tch)
Tube
for
min
g
Wat
er b
ased
dr
y lu
bric
ant
(d
eep
draw
ing)
Wet
wir
e dr
awin
g
CERETAN M 82 * Montanester f ●● ●●CERETAN MA 7008 CERETAN MA 7020 CERETAN MA 7019
EBS mp ●● ● ●● ● ●● ●●CERETAN MA 7050 CERETAN MA 7080 EBS mp ●● ●●CERETAN MC 6015 Carnauba mp ●● ●● ●CERETAN MF 5108 PTFE mp ●● ● ●● ● ● ●●CERETAN MM 8015 Ester mp ●● ●● ●
GENERAL OVERVIEW – MICRONIZED WAXES
GENERAL OVERVIEW – WAX DISPERSIONS
e = esterep/aw = extreme pressure additive
( phoshporic acid ester combination)f = flakes
mp = miconized powdero = oils = solventw = water
LUBA-print & LUBARIT Chemistry of additive
Carrier system
Base fluid Additive
Ant
i-gr
affiti
Bik
e ch
ain
lubr
ican
t
Care
pro
duct
s
(car
)
Care
pro
duct
s
(floo
r)
Cutt
ing
past
e
Die
cas
ting
(A
lum
iniu
m, …
)
EP-A
ddit
ive
Hot
for
ging
(r
elea
se a
gent
)
NSF
-H1
lubr
ican
ts
Oil
base
d lu
bric
ant
(d
eep
draw
ing)
Pol
ymer
sea
ling
Scre
w c
oati
ngs
Sint
er m
etal
(d
ry w
ax lu
bric
ant)
Tem
pora
rry
corr
osio
n pr
otec
tion
Tran
spor
t pr
otec
tion
(a
nti-
scra
tch)
Tube
for
min
g
Wat
er b
ased
dr
y lu
bric
ant
(d
eep
draw
ing)
Wet
wir
e dr
awin
g
138/E PTFE w ●● ● ● ●164/G Amide w ●● ● ●● ●●164/R Amide w ●● ● ● ● ●● ●●204/F * Co-polymer w ●● ● ●● ●● ●● ●● ●204/P * Co-Polymer w ●● ● ●● ●● ●● ●● ●204/W * Co-Polymer w ●● ●● ● ●● ●267/A * PTFE e ●● ● ●267/B * PTFE o ●● ● ● ●●280 AG * Paraffin Blend w ●● ● ●●280/F Paraffin Blend w ●● ● ● ●
Gen
eral
ove
rvie
w
Product Chemistry of additive
Carrier system
Base fluid Additive
Ant
i-gr
affiti
Bik
e ch
ain
lubr
ican
t
Care
pro
duct
s
(car
)
Care
pro
duct
s
(floo
r)
Cutt
ing
past
e
Die
cas
ting
(A
lum
iniu
m, …
)
EP-A
ddit
ive
Hot
for
ging
(r
elea
se a
gent
)
NSF
-H1
lubr
ican
ts
Oil
base
d lu
bric
ant
(d
eep
draw
ing)
Pol
ymer
sea
ling
Scre
w c
oati
ngs
Sint
er m
etal
(d
ry w
ax lu
bric
ant)
Tem
pora
rry
corr
osio
n pr
otec
tion
Tran
spor
t pr
otec
tion
(a
nti-
scra
tch)
Tube
for
min
g
Wat
er b
ased
dr
y lu
bric
ant
(d
eep
draw
ing)
Wet
wir
e dr
awin
g
CERETAN M 82 * Montanester f ●● ●●CERETAN MA 7008 CERETAN MA 7020 CERETAN MA 7019
EBS mp ●● ● ●● ● ●● ●●CERETAN MA 7050 CERETAN MA 7080 EBS mp ●● ●●CERETAN MC 6015 Carnauba mp ●● ●● ●CERETAN MF 5108 PTFE mp ●● ● ●● ● ● ●●CERETAN MM 8015 Ester mp ●● ●● ●
GENERAL OVERVIEW – MICRONIZED WAXES
GENERAL OVERVIEW – WAX DISPERSIONS
furtherWaxDispersionsonPage6–7
* Experimental product availability on request
Recommended Highly recommended
LUBA-print & LUBARIT Chemistry of additive
Carrier system
Base fluid Additive
Ant
i-gr
affiti
Bik
e ch
ain
lubr
ican
t
Care
pro
duct
s
(car
)
Care
pro
duct
s
(floo
r)
Cutt
ing
past
e
Die
cas
ting
(A
lum
iniu
m, …
)
EP-A
ddit
ive
Hot
for
ging
(r
elea
se a
gent
)
NSF
-H1
lubr
ican
ts
Oil
base
d lu
bric
ant
(d
eep
draw
ing)
Pol
ymer
sea
ling
Scre
w c
oati
ngs
Sint
er m
etal
(d
ry w
ax lu
bric
ant)
Tem
pora
rry
corr
osio
n pr
otec
tion
Tran
spor
t pr
otec
tion
(a
nti-
scra
tch)
Tube
for
min
g
Wat
er b
ased
dr
y lu
bric
ant
(d
eep
draw
ing)
Wet
wir
e dr
awin
g
138/E PTFE w ●● ● ● ●164/G Amide w ●● ● ●● ●●164/R Amide w ●● ● ● ● ●● ●●204/F * Co-polymer w ●● ● ●● ●● ●● ●● ●204/P * Co-Polymer w ●● ● ●● ●● ●● ●● ●204/W * Co-Polymer w ●● ●● ● ●● ●267/A * PTFE e ●● ● ●267/B * PTFE o ●● ● ● ●●280 AG * Paraffin Blend w ●● ● ●●280/F Paraffin Blend w ●● ● ● ●
Gen
eral
ove
rvie
w
6–7 INDUSTRIAL FLUIDS - WAXES
General overview
GENERAL OVERVIEW – WAX DISPERSIONS
LUBA-print & LUBARIT Chemistry of additive
Carrier system
Base fluid Additive
Ant
i-gr
affiti
Bik
e ch
ain
lubr
ican
t
Care
pro
duct
s
(car
)
Care
pro
duct
s
(floo
r)
Cutt
ing
past
e
Die
cas
ting
(A
lum
iniu
m, …
)
EP-A
ddit
ive
Hot
for
ging
(r
elea
se a
gent
)
NSF
-H1
lubr
ican
ts
Oil
base
d lu
bric
ant
(d
eep
draw
ing)
Pol
ymer
sea
ling
Scre
w c
oati
ngs
Sint
er m
etal
(d
ry w
ax lu
bric
ant)
Tem
pora
rry
corr
osio
n pr
otec
tion
Tran
spor
t pr
otec
tion
(a
nti-
scra
tch)
Tube
for
min
g
Wat
er b
ased
dr
y lu
bric
ant
(d
eep
draw
ing)
Wet
wir
e dr
awin
g
280/W Paraffin Blend w ●● ● ● ● ●288/B Wax Blend w ●● ●● ● ●320 PE o ● ● ●●434/F Carnauba w ●● ●● ●● ●● ● ●● ●466/F PP w ●● ●● ●● ●● ●499 PE w ●● ● ●● ● ● ●● ●●506 * Ester w ●● ●● ●● ●●551/2 PE w ●● ● ● ● ● ●●645/A Polyamid w ●● ●650/C Wax Blend s ●● ●●680/F PE w ●● ● ●● ●● ● ●901/A Wax Blend e ●● ●● ●●904/B Additivated mineral oil o/e ●● ●●934/W (ND) PTFE s ●● ●●942 PE w ●● ●● ● ● ●● ● ● ●965/A Carnauba w ●● ●● ●● ●● ● ●967/A Wax Blend w ●● ●●3000/B-1 P-Ester
Fatty acid ester ep/aw ●● ●● ●● ● ● ●● ●3520 PE w ● ● ● ● ●● ● ●● ●5500 PE w ●● ● ●● ● ● ●● ●EXP 6150/1 * P-Ester neutralized ep/aw ●● ●● ●● ● ● ●● ●KL 30 Ester w ●● ●● ● ●●T-152/D30 T-152/D30-T T-152/D40 * T-152/D60
Wax Blend s ●● ● ●● ● ●● ●●
e = esterep/aw = extreme pressure additive
( phoshporic acid ester combination)mp = miconized powder
o = oils = solventw = water
Gen
eral
ove
rvie
w
GENERAL OVERVIEW – WAX DISPERSIONS
* experimental product availability on request
Recommended Highly recommended
LUBA-print & LUBARIT Chemistry of additive
Carrier system
Base fluid Additive
Ant
i-gr
affiti
Bik
e ch
ain
lubr
ican
t
Care
pro
duct
s
(car
)
Care
pro
duct
s
(floo
r)
Cutt
ing
past
e
Die
cas
ting
(A
lum
iniu
m, …
)
EP-A
ddit
ive
Hot
for
ging
(r
elea
se a
gent
)
NSF
-H1
lubr
ican
ts
Oil
base
d lu
bric
ant
(d
eep
draw
ing)
Pol
ymer
sea
ling
Scre
w c
oati
ngs
Sint
er m
etal
(d
ry w
ax lu
bric
ant)
Tem
pora
rry
corr
osio
n pr
otec
tion
Tran
spor
t pr
otec
tion
(a
nti-
scra
tch)
Tube
for
min
g
Wat
er b
ased
dr
y lu
bric
ant
(d
eep
draw
ing)
Wet
wir
e dr
awin
g
280/W Paraffin Blend w ●● ● ● ● ●288/B Wax Blend w ●● ●● ● ●320 PE o ● ● ●●434/F Carnauba w ●● ●● ●● ●● ● ●● ●466/F PP w ●● ●● ●● ●● ●499 PE w ●● ● ●● ● ● ●● ●●506 * Ester w ●● ●● ●● ●●551/2 PE w ●● ● ● ● ● ●●645/A Polyamid w ●● ●650/C Wax Blend s ●● ●●680/F PE w ●● ● ●● ●● ● ●901/A Wax Blend e ●● ●● ●●904/B Additivated mineral oil o/e ●● ●●934/W (ND) PTFE s ●● ●●942 PE w ●● ●● ● ● ●● ● ● ●965/A Carnauba w ●● ●● ●● ●● ● ●967/A Wax Blend w ●● ●●3000/B-1 P-Ester
Fatty acid ester ep/aw ●● ●● ●● ● ● ●● ●3520 PE w ● ● ● ● ●● ● ●● ●5500 PE w ●● ● ●● ● ● ●● ●EXP 6150/1 * P-Ester neutralized ep/aw ●● ●● ●● ● ● ●● ●KL 30 Ester w ●● ●● ● ●●T-152/D30 T-152/D30-T T-152/D40 * T-152/D60
Wax Blend s ●● ● ●● ● ●● ●●
Gen
eral
ove
rvie
w
8–9 INDUSTRIAL FLUIDS - WAXES
Temporary Corrosion Protection
Tem
pora
ry C
orro
sion
Pro
tect
ion LUBA-print & LUBARIT Chemistry of additive Carrier
systemBase fluid Additive Active
substance based on
Dilution with deion water
(yes / no)
Saltspray test time
(15µm dry film)
Saltspray test time
(30µm dry film)
Hydrophobicity improvement
as additiv
Film hardness improvemnt for
T-152/…
Dewatering fluid
(protection fluid)
Special features
204/F * Co-Polymer w ●● ● cp y 12 h 50 h Repellent effect
204/P * Co-Polymer w ●● ● cp y 22 h 70h Repellent effect
204/W * Co-Polymer w ●● cp+ci n 30 h 78h
280/F Paraffin w ●● pa y ●●
280/W Paraffin w ●● pa y ●●
501/S-100 PE s ●● pe n ● ●●
904/B Additivated mineral oil o/s ●● ci n ●●
3000/B-1 P-Ester Fatty acid ester ep/aw ●● ep y ●
T-152/D30 T-152/D30-T T-152/D40 * T-152/D60
Wax Blend s ●● ● pa n 30 h 480 h ** ●● ●available with several flash points (D30/D40/D60)
TEMPORARY CORROSION PROTECTION
ci = corrosion inhibitorcp = co-polymere = esterep/aw = extreme pressure additive
( phoshporic acid ester combination)
* experimental product availability on request** can be improved by a combination with resin and corrosion inhibitor up to > 1000 h
h = houro = oilpa = paraffin-blend
pe = Polyethylens = solventw = water
Removal with hot alkaline water / cleaner
Tem
pora
ry C
orro
sion
Pro
tect
ionLUBA-print & LUBARIT Chemistry of additive Carrier
systemBase fluid Additive Active
substance based on
Dilution with deion water
(yes / no)
Saltspray test time
(15µm dry film)
Saltspray test time
(30µm dry film)
Hydrophobicity improvement
as additiv
Film hardness improvemnt for
T-152/…
Dewatering fluid
(protection fluid)
Special features
204/F * Co-Polymer w ●● ● cp y 12 h 50 h Repellent effect
204/P * Co-Polymer w ●● ● cp y 22 h 70h Repellent effect
204/W * Co-Polymer w ●● cp+ci n 30 h 78h
280/F Paraffin w ●● pa y ●●
280/W Paraffin w ●● pa y ●●
501/S-100 PE s ●● pe n ● ●●
904/B Additivated mineral oil o/s ●● ci n ●●
3000/B-1 P-Ester Fatty acid ester ep/aw ●● ep y ●
T-152/D30 T-152/D30-T T-152/D40 * T-152/D60
Wax Blend s ●● ● pa n 30 h 480 h ** ●● ●available with several flash points (D30/D40/D60)
TEMPORARY CORROSION PROTECTION
Recommended Highly recommended
10–11 INDUSTRIAL FLUIDS - WAXES
PTFE-Products
PTF
E-Pr
oduc
ts
Product Chemistry of additive Carrier system Basefluid Additive Active substance Fineness Bio degradable (yes / no)
CERETAN MF 5108 PTFE mp ●● 100 % D50 = 3,0 µm D99 = 8,0 µm n
CERETAN VP 1029 * PTFE mp ●● 100 % D50 = 4,5 µmD99=7,0µm
n
LUBA-print 138/E PTFE w ●● 60% approx. 220 nm n
LUBA-print 934/W (ND) PTFE s ●● 32 % approx. 2 µm n
LUBARIT 267/A * PTFE e ●● ● 20 % very fine to transparent; not measurable y **
LUBARIT 267/B * PTFE o ●● 20 % D90 = 1,0 µm n
PTFE-PRODUCTS
e = estermp = miconized powdero = oil
* experimental product availability on request ** specificestersystemistapprox.75%bio-degradable
s = solventw = water
PTF
E-Pr
oduc
ts
Product Chemistry of additive Carrier system Basefluid Additive Active substance Fineness Bio degradable (yes / no)
CERETAN MF 5108 PTFE mp ●● 100 % D50 = 3,0 µm D99 = 8,0 µm n
CERETAN VP 1029 * PTFE mp ●● 100 % D50 = 4,5 µmD99=7,0µm
n
LUBA-print 138/E PTFE w ●● 60% approx. 220 nm n
LUBA-print 934/W (ND) PTFE s ●● 32 % approx. 2 µm n
LUBARIT 267/A * PTFE e ●● ● 20 % very fine to transparent; not measurable y **
LUBARIT 267/B * PTFE o ●● 20 % D90 = 1,0 µm n
PTFE-PRODUCTS
Recommended Highly recommended
12–13 INDUSTRIAL FLUIDS - WAXES
CERETAN
CER
ETA
N
Product Wax type Care products Cutting paste Dry lubricants (water based)
Lubricants (water based)
Sinter metal Thickening effect Wet wire drawing Wire rope lubricants
CERETAN MA 7008 CERETAN MA 7019 CERETAN MA 7020 CERETAN MA 7025 CERETAN MA 7050 CERETAN MA 7080
Amide Wax (Ethylene bis(stearamide)) ●● ●● ●● ●● ●● ●●
CERETAN A 71 Amide Wax (Erucamid) ● ● ●CERETAN MC 6015 Carnauba Wax ●●CERETAN MT 9120 CERETAN T 91 Fischer-Tropsch ●● ●●CERETAN P 21 Polypropylene ●●CERETAN MF 5108 PTFE(Polytetraflourethylene) ● ● ●● ●● ●CERETAN VP 1029 ** PTFE(Polytetraflourethylene) ● ● ●CERETAN M 82 * RefinedMontanester,
partiallysaponified ●●CERETAN MM 8015 RefinedMontanester,
partiallysaponified ●● ●●
CERETAN
* non-standard product ** experimental product - availability on request
CER
ETA
N
Product Wax type Care products Cutting paste Dry lubricants (water based)
Lubricants (water based)
Sinter metal Thickening effect Wet wire drawing Wire rope lubricants
CERETAN MA 7008 CERETAN MA 7019 CERETAN MA 7020 CERETAN MA 7025 CERETAN MA 7050 CERETAN MA 7080
Amide Wax (Ethylene bis(stearamide)) ●● ●● ●● ●● ●● ●●
CERETAN A 71 Amide Wax (Erucamid) ● ● ●CERETAN MC 6015 Carnauba Wax ●●CERETAN MT 9120 CERETAN T 91 Fischer-Tropsch ●● ●●CERETAN P 21 Polypropylene ●●CERETAN MF 5108 PTFE(Polytetraflourethylene) ● ● ●● ●● ●CERETAN VP 1029 ** PTFE(Polytetraflourethylene) ● ● ●CERETAN M 82 * RefinedMontanester,
partiallysaponified ●●CERETAN MM 8015 RefinedMontanester,
partiallysaponified ●● ●●
CERETAN
Recommended Highly recommended
14–15 INDUSTRIAL FLUIDS - WAXES
Mechanism of wax in forming fluids
Wax particles (yellow) preventing metal to metal by ball bearing spacer effect
Wax particles preventing metal to metal contact
Wax melts, viscous liquid facing metal on both sides
Wax melts, yellow viscous liquid facing metal on both sides
Metal plates moving against each other - motion
Metal plates moving against each other - motion
Metal
Metal
Metal
Metal
Metal
Metal
Metal
Metal
Wax film (blue) provides additional protection
Wax is still solid [ T < Tm ]
Wax is still solid [ T < Tm ]
Wax melts [ T > Tm ]
Wax melts [ T > Tm ]
Wax as dry film
Wax inside oil
Notes
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UE_2018_018-EN-V02_02|18
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Contact
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MÜNZING Shanghai Co.Ltd.Rm1701B-1703ANo. 20, Lane 1228, ZRT TowerJiangchang Rd.Shanghai200072P.R. CHINAPhone+862161491561Fax +862161491563E-Mail [email protected]
MÜNZING CHEMIE Iberia S.A.U.Carrer Temple, 15 1° derechaES08911 Badalona (Barcelona) SPAINPhone+34935722075Fax +34935722683E-Mail [email protected]
MÜNZING Micro Technologies GmbHDr.-Bergius-Strasse16–2406729Elsteraue GERMANYPhone +49 3441 829 10-22Fax +49 3441 829 10-20E-Mail [email protected]
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