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Contract No. 68-01 -6669 v>EPA U.S. ENVIRONMENTAL PROTECTION AGENCY TECHNICAL ASSISTANCE TEAM ROY F. WESTON, INC. Spill Prevention & Emergency Response Division In Association with Jacobs Engineering Group Inc. Tetra Tech Inc. and ICF Incorporated DESIGNERS ^ CONSULTANTS 599882 SEMS DocID

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Page 1: U.S. ENVIRONMENTAL PROTECTION AGENCY · 01-F-00799 (5139) Suite 202, 111 South Bedford Street, Burlington, MA 01803 • (617) 229-6430 TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RES!

Contract No. 68-01 -6669

v>EPAU.S. ENVIRONMENTAL PROTECTION AGENCY

TECHNICAL

ASSISTANCE

TEAM

ROY F. WESTON, INC.Spill Prevention & Emergency Response Division

In Association with Jacobs Engineering Group Inc. Tetra Tech Inc.and ICF Incorporated

DESIGNERS ^ CONSULTANTS

599882SEMS DocID

Page 2: U.S. ENVIRONMENTAL PROTECTION AGENCY · 01-F-00799 (5139) Suite 202, 111 South Bedford Street, Burlington, MA 01803 • (617) 229-6430 TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RES!

O W |n

TABLE OF CONTENTS

Cover Letter

Technical Direction Document

:orpose

Cr.ronogical Log

Safety Plan

Appendices

Grid Layout Soil Sampling Site DrawingBH-l Survey Sampling Grid

Page 3: U.S. ENVIRONMENTAL PROTECTION AGENCY · 01-F-00799 (5139) Suite 202, 111 South Bedford Street, Burlington, MA 01803 • (617) 229-6430 TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RES!

I COVER LETTER

Page 4: U.S. ENVIRONMENTAL PROTECTION AGENCY · 01-F-00799 (5139) Suite 202, 111 South Bedford Street, Burlington, MA 01803 • (617) 229-6430 TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RES!

01-F-00799 (5139)

Suite 202, 111 South Bedford Street, Burlington, MA 01803 • (617) 229-6430

TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RES! >»NSE REMOVAL AND PREVENTION EI’A CON TRACT 68-01-6669

Mr. Steven R. NovickDeputy Project OfficerU.S. Environmental Protection Ager.cy60 Westview StreetLexington, MA 02173

Dear Mr. Novick:

The accompanying report, Soil Sampling Operations - Burns Hill Road - Hudson, New Hampshire, is submitted to document that the requirements of Technical Direction Document No. 01-8603-17 have been met. The major element of the TDD was the preparation of a sampling grid from which the TAT could accurately obtain soil samples. A grid map of the sampled area is included in the appendix of this report. Using that layout, the TATs collected 39 soil samples from the site. The samples were submitted to NERL for analysis.

If there are any questions, I can be reached at (617) 229-A O A ' '

April 28, 1986

6430.

Sincerely,

ROY F. WESTON, INC.

Larry J. Dziuk, Ph. D. Technical Assistance Team Leader

cc: David Ferenz

LJD/jsp

Roy F. Weston, Inc.Spill Prevention & Emergency Response Division

In Association with Jacobs Engineering Group Inc., Tetra lech, Inc., and ICF Incorporated

Page 5: U.S. ENVIRONMENTAL PROTECTION AGENCY · 01-F-00799 (5139) Suite 202, 111 South Bedford Street, Burlington, MA 01803 • (617) 229-6430 TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RES!

21. TECHNICAL DIRECTION DOCUMENT

Page 6: U.S. ENVIRONMENTAL PROTECTION AGENCY · 01-F-00799 (5139) Suite 202, 111 South Bedford Street, Burlington, MA 01803 • (617) 229-6430 TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RES!

1. COSTCENTER: i{

01

TECHNICAL DIRECTION DOCUMENT (TDD)tiCElVE J0JHM emergency response and

SPILL PREVENTION PROGRAM

ROY F. WESTON, INC.

-S" I ^

2. NO.:< 'Siozn

2A TYPE:, ->..'r

3. PRIORITY:

HIGH (1)□' MEDIUM (2)

□ LOW (3)

'AOTs&fc'& $f FUNDS. [ 5. EPA SITE ID/ (IF APPLICABLE):

P^'cercla (i) L.LrA''t.a7/' fy

□ 311 (?)□ OTHER (3)_

5A. EPA SITE NAME 0 (IF APPLICABLE):Of-* .• 11.’LL 1 .0

. i <■ i ^. rx

6. COMPLETION DATE:5/> /V C.

7. OVERTIME APPROVED: YES □ NO

8. REFERENCE

i’-FO:

□ >tS p(NO

□ ATTACHED□ P.'CK UP

9- GENERAL TASK DESCRIPTION: /p£pS'A'A77<:'\//

r.-c,n ■- s.y,,<rLl/^T .

//i 7 5/)

/ / T ^ -T ^ // / <

ZlDLuJL-

9A. SPECIAL PROJECT - ESTIMATED COST: H^TOESTIMATED HOURS:

10. SPECIFIC ELEMENTS. Oj ? O ,/^C z. / '? ' ^/ C/T /?--i/C a

>. ,4 J? <- z' 'V c ^ 1.,^ ^ __

-1 v 7b^ y 4 •> . ^ i • /-7 o v L - <> S •> /~/f / >/

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I ■ F *,A/Cv s /r s /) y.-i fi \ PR/v Oa h t ( <'l-\ 7,/ •'I / ■ < / J

--------1------------------/

11. INTERIM DEADLINES:6' . "// 2-/?v /

r/y/’i\ ■

OWL

/.yFc ,

n.^’Zc.^c

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12. DESIRED REPORT FORM: FORMAL REPORT □ LETTER REPORT □ FORMAL BRIEFING □

^OTHER (SPECIFY): ^ oQ A P ^ LXl,^y ,VC \ , ^>1 /, ^ ^ S A /?^ Xj

13. COMMENTS- DSC, • T).

416. RECEIVED BY: ^ACCEPTED CLACCEPTED WITH EXCEPTIONS □ REJECTED

-*?-*/ / (TATLsSKSNATURE)

17. DATE:

I ;«. descriptor lai/miail/lTMilql^lfllt^l^lsIsIftlRlPl/jTJiutel I I WAA-A-Mth ITT7RI«i 1 Whii« - TATL Copy

i 2 Gf**n - OPO Copy (Signed by TATL R*pUC«« Ong.n«4|

3 C«n«iy - NPMO Copy

Sn««i 4 P.ofc - Pfofeef OHic«« Copy

Shf • | i Blue — C AA AMi... ........................... n <- ,

Page 7: U.S. ENVIRONMENTAL PROTECTION AGENCY · 01-F-00799 (5139) Suite 202, 111 South Bedford Street, Burlington, MA 01803 • (617) 229-6430 TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RES!

01-F-00800 (5139)

III. Purpose

The purpose of the soil sampling phase of cleanup operations at the Burns Hill Road Hazardous Waste Site is to establish the presence, if any, of contaminated soils at the site. This information is essential to determine appropriate emergency actions for soil removal, if necessary.

IV. Chronological Log

April 14, 1986

Robert Donati, Anthony Andronico, and Denis Young (V.'eston TAT) arrived at the Burns Hill Road Drum site in Hudson, Nev Hampshire to begin the site survey and sampling grid layout. They located five survey control points in order to establish grid point 0, and the grid was tied into Woods Road and Burns Hill ?oad.

April 15, 1986

Robert Donati, Anthony Andronico, and Denis Young (Keston TAT) arrived at the Burns Hill Road site to continue the sampling grid layout. Beginning at point 0, they located an approximate north- south, east-west grid pattern at 25 foot intervals, using wood stakes. A total of 74 grid points were established.

April 16 1986

Robert Donati, Denis Young, and Mark Hall (Weston TAT) arrived at the Burns Hill Road site to complete the grid layout and soil sampling operation. There were 9 more grid points located for a total of 83 grid points and 12 east-west grid lines.

R. Donati, D. Young, and M. Hall completed the soil sampling operation as described in Appendix B of this report. A total of 39 soil samples were collected and transferred to the EPA New England Regional Laboratory, in Lexington, Massachusetts, for analysis.

Robert Donati April 28, 1986

Page 8: U.S. ENVIRONMENTAL PROTECTION AGENCY · 01-F-00799 (5139) Suite 202, 111 South Bedford Street, Burlington, MA 01803 • (617) 229-6430 TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RES!

V. SAFETY PLAN

Page 9: U.S. ENVIRONMENTAL PROTECTION AGENCY · 01-F-00799 (5139) Suite 202, 111 South Bedford Street, Burlington, MA 01803 • (617) 229-6430 TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RES!

SITE SAFETY PLAN BURNS HILL ROAD SIT

HUDSON, NEW HAMPSHIP

Page 10: U.S. ENVIRONMENTAL PROTECTION AGENCY · 01-F-00799 (5139) Suite 202, 111 South Bedford Street, Burlington, MA 01803 • (617) 229-6430 TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RES!

TABLE OF CONTENTS

01 -r-00757 (5121 )

A. Emergency : hone Numbers 1

B. Directions to Hospital (Written & Map) 2

C. Known Cont minants 3-13

D. Introduction & Site Background 14

E. Purpose 15

. F. Applicability 15

G. Responsibi; ties 15

H.

I.

1. On-See:' Coordinator (OSC) 162. Safety .fficer 163. Respons Manager 16

Safety Procedures and Levels of Protection 17

1. Respiratory Protection Program 172. Trainin' and Medical Monitoring Progr^n 173. General Safety Rules & Equipment 17-184. Morning Safety Meetings 185. Site Control 186. Designation of Work Zones at the Site 18-197. Personnel Protection 19

a. Protective Equipment - Level A 20b. Protective Equipment - Level B 21-22c. Protective Equipment - Level C 22-23d. Protective Equipment - Level D 23

8. Alternate Levels of Protection 24

Decontamination Protocol 24

1. Complete Procedures 24-252. Equipment 253. Personnel Decontamination Flow Chart 26

Air Monitoring 27

Cold Exposure 27-28

1. Treatment 28

Page 11: U.S. ENVIRONMENTAL PROTECTION AGENCY · 01-F-00799 (5139) Suite 202, 111 South Bedford Street, Burlington, MA 01803 • (617) 229-6430 TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RES!

TABLE OF CONTENTS (CONT'D)

L. Map of ite

M. Approval Page

N. Signature Page

29

30

31

Page 12: U.S. ENVIRONMENTAL PROTECTION AGENCY · 01-F-00799 (5139) Suite 202, 111 South Bedford Street, Burlington, MA 01803 • (617) 229-6430 TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RES!

A. EMERGENCY PHONE NUMBERS

In the event of a medical emergency, the OSC or his designee will notify the appropriate authority. The following list of phone numbers will be distributed to all supervisory and security personnel.

1. FIRE - i: ;ison: 883-7707

2. AMBULANCE - Hudson: 883-7707

3. HOSPITALS — Memorial — Nashua: 883—6681 (directions on map)

- St. Joseph's - Nashua: 889-6681

4. POLICE - Hudson: 883-5508

5. FEDERAL GOVERNMENT - USEPA (24 hour hotline): 617/2:3-7265

USEPA (office): 617/861-6700

6. STATE GOVERNMENT - State Police (Concord, NH) : 800->52-3411

- New Hampshire Office of Waste Management: 603/271-4664

- New Hampshire Water Supply Pollution Control Commission 603/271-3503

7. EPA ENVIRONMENTAL RESPONSE TEAM: 201/321-6660

POISON INFORMATION: 603/646-5000 (Hanover, NH)800/562-8236 (NH - Dartmouth Hitchcock

Medical Center)

9. 0. H. MATERIALS CO.: 800/536-9540

10. CENTER FOR DISEASE CONTROL: 404/329-3311 (day)

404/329-3644 (night)

11. ROY F. WESTON, INC.: 617/229-6430

Routes to local hospitals will be distributed to all supervisory and security personnel. Any person injured in Exclusion Area will be decontaminated prior to transport to the hospital, dependent upon the severity of the injury.

1

Page 13: U.S. ENVIRONMENTAL PROTECTION AGENCY · 01-F-00799 (5139) Suite 202, 111 South Bedford Street, Burlington, MA 01803 • (617) 229-6430 TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RES!

B• DIRECTIONS TO MEMORIAL HOSPITAL

From the Burns Hill Road Site en Hill Road. Follow tor approxima le:t onto Pelham Road arid follow f 3a (Lowell Road). Turn right <: approximately 2 miles to Route 1. li its, turn left onto Ferry Sti • Bridge. At the next fork in the : (East Hollis Street). Follow E. to the third traffic light. : Me;:«irial Hospital will be on the I on Main Street.

trance, turn right onto Bur: tely 1 mile to the end. Tu ;r a few hundred feet to Rou- ::to Lowell Road and follow f

■ (Ferry Street). At traff et and travel over the Huds oad, bear left onto Route 11 Hollis Street for about 1 mi] urn left onto Main Street •?ft at the next traffic ligr

2

Page 14: U.S. ENVIRONMENTAL PROTECTION AGENCY · 01-F-00799 (5139) Suite 202, 111 South Bedford Street, Burlington, MA 01803 • (617) 229-6430 TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RES!
Page 15: U.S. ENVIRONMENTAL PROTECTION AGENCY · 01-F-00799 (5139) Suite 202, 111 South Bedford Street, Burlington, MA 01803 • (617) 229-6430 TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RES!
Page 16: U.S. ENVIRONMENTAL PROTECTION AGENCY · 01-F-00799 (5139) Suite 202, 111 South Bedford Street, Burlington, MA 01803 • (617) 229-6430 TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RES!

C. KNOWN CONTAMI NANTS LIST

Drum sample Hampshire Div; Waste, indie, compunds in Site. The fo: of these cont : Guidelines fo: Dangerous Proi Sax.

analysis results r sion of Public Healt.■ed a total of fe 'he drums at the Bu lowing information o minants as available Chemical Hazards, 1' ertiesof Industrial

ported by the State <;■ Services; Bureau of Ha;- teen (14) volatile ; iS Hill Road Hazardous •lines pertinent data fc in (1) Occupational Heal

by NIOSH/OSHA and (2 Materials, 1979 by Irvi.-.

NewrdousganicWasteeach

N.

First Aid Ins:'actions

Unless otherwi be followed s

; noted, the follow. ;ig first-aid procedures

^sequent to an expos re to any of these comp.hall nds.

Dermal ex; sures - wash the ;kin with a mild soa or

f ff?ent. If clothing has be .wne contaminated, renev the If irritation is pr- : ent, seek medical after. - ion

immediatel-.

2. Inhalation - remove the vict artificial respiration or CPR . attention j mediately.

to fresh air and pe:form

necessary. Seek ne Meal

Ingestion seek medical attention immediately. Ur;less otherwise .ited, do not indue- vomiting. if vomitinc* is

warranted, nave victim touch • finger to the back of' his throat or administer syrup of ip- cac. Never induce vomiting

in an unconscious person. ^

4. Eye Contact Wash the eye (s) immediately with warm wai holding the eyelid open. Get medical attention for victim immediately.

;er , the

COMPOUNDS

Carbon Tetrachloride CC1 --------- ----- 4

A colorless liquid with an ether-like odor, used primarily for metal degreasing, chlorinating organic compounds, and as *.rrefr^frant ' solvent, and agricultural fumigant. It has a TLV of 5 ppm and and IDLH of 300 PPm, and is also a knwn

carcinogen.

Health Hazards

Carbon Tetrachloride is toxic by ingestion, inhallation, and skin absorbtion. it is also a narcotic and a known

carcinogen .

3

Page 17: U.S. ENVIRONMENTAL PROTECTION AGENCY · 01-F-00799 (5139) Suite 202, 111 South Bedford Street, Burlington, MA 01803 • (617) 229-6430 TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RES!

Effects of Overexposure

Short term exposure: Carbon tetrachloride m=v causedrowsiness, dizziness, incoordination ' andunconsciousness. Delayed effects from over-exposure include damage to heart, liver and kidneys. Eye contactto liquid carbon tetrachloride causes burning and intense ir r1tation.

Long-term exposure: Prolonged exposure to carbonIfcH?l0ri^ cause liver and kidney damage, as well as siun irritation.

Procedures: For exposure of carbontetrachloride on skin and e.-es, areas should t*-> washed with water. If it has been “ ~-■allowed, induce vorr ting.

Warning Properties

a. Odor threshold: Carbon tetrachloride hasthreshold of 50 ppm. at odor

b. Eye irrigation level: Carbon tetrachloride is irritatingto the eyes, but no information is available r. varding the concentration at which irritation occurs.

C‘ e°f warnin9 properties: since the odorthreshold of carbon tetrachloride is well above the permissable exposure, it is condidered a substance with poor warning properties.

2 • Chloroform CHCl-j

ine?ndfleSS liJui? with a Peasant, sweet odor, whose uses inciude manufacturing of flourocarbons and refrigerant p opellants, use as an extractant solvent in manufacturing, has cJe^cal intermediate in dyes and pesticides. ItcJrofnoiL ?1PPm fnd-an IDLH of 1000 PPm' and is a known

* Al®° toxic gasses and vapors may be released when chloroform decomposes.

Health Hazards

Chloroform inhalation affect the

is most commonly hazardous as a result and eye and skin contact, although it can

body if it is swallowed.

ofalso

4

Page 18: U.S. ENVIRONMENTAL PROTECTION AGENCY · 01-F-00799 (5139) Suite 202, 111 South Bedford Street, Burlington, MA 01803 • (617) 229-6430 TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RES!

Effects of Overexposure

Short-term exposure: Chloroform may cause headache,drowsiness, dizziness, vomiting, unconsciousness, irregular heart beat, and death. Liver and kidney damage may also result from exposure to chloroform va; ,r. When splashed in the eye, chloroform causes ain and ir:itation. Swallowing chloroform is followedimmediately by severe burning of the mouth ar, : throat,pain in the chest and abdomen, and vomiting.

b. Lot.g-term exposure: Prolonged exposure to chloroform maycause liver and kidney damage, as well as produce skin ir•itation.

c. First-Aid procedures: For eye and skin expc ure, thecontaminated ai ■ a should be promptly washed v th large amounts of water. If a person breathes large o,ounts of chloroform, mov- the exposed person th fresh air andperrorm artificial respiration, if necessary. when chloroform has '.-aen swallowed, induce vomiting provided the person is o nscious.

Warning Properties

Odo: threshold: It has been reported that the odorthreshold for chloroform is 50 ppm.

Eye irritation level: Eye exposure of highconcentrations of chloroform in conscious individuals causes a moderate sensation of stinging, automatically inducing protective closure of the lids.

Evaluation of warning properties: Since fatigue occursduring exposure to chloroform, this material is considered to have poor warning properties.

3. Dichloroethane C^H^C12

A colorless liquid with a chloroform-like odor. It has a TLV of 200 ppm and an IDLH of 4000 ppm.

Health Hazards

Dichloroethane can affect the body if it is inhaled or if it comes in contact with the eyes or skin. It can also affect the body if it is swallowed.

Effects of Overexposure

a. Short-term Exposure: Breathing dichloroethane vapor maycause drowsiness and unconsciousness. It might also cause damage to the liver, kidneys, and lungs. Splashing the liquid in the eyes may cause irritation.

5

Page 19: U.S. ENVIRONMENTAL PROTECTION AGENCY · 01-F-00799 (5139) Suite 202, 111 South Bedford Street, Burlington, MA 01803 • (617) 229-6430 TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RES!

b. Long term Exposure: Prolonged, confined, or repeatedskin contact with dichloroethane can produce a sliahthum ^

Warning Properties

The A: ;a Hygienic Guide reports t! it dichloroethane ha a distinctive, easily recognizable od<r at the TLV.

Dichloroethane is not known to be an eye irritant.

NOTE: If this substance is swallowed, vomiting should beinducec „

4. Dichlor ethylene C1CH:CHC1

A colo. less liquid with an ether-li ..a, slightly acrid oc used pr. manly as a solvent for organic materials. It ha TLV of 100 ppm and an IDLH Of 4000 p: ~.

Health Hazards

Dichlorcethylene can affect the bo iy if it is inhal* d, ingested, or if it comes in contact with the eyes and sk n' Over expo cure may cause dizziness, drowsiness, ,-nd

unconsci usness.

For fint-aid when contacted with eyes or skin, wash water. if swallowed, induce vomitinc.

wi th

Warning Properties

Dichloroethylene has an odor threshold of 0.085 ppm and is considered to be a material with adequate warning properties.

5* Ethyl Benzene C-2-Z-G-Z

Ethyl Benzene is a colorless liquid with an aromatic odor. It has a TLV of 100 ppm and an IDLH of 2000 ppm. it has an odor threshold of 140 ppm. it is used primarily as a solvent.

Health Hazards

Ethyl Benzene can affect the body if it is inhaled, swallowed, or comes in contact with the eyes of skin.

Effects of Overexposure

Short-term Exposure: Ethyl Benzenethe eyes, nose, throat, and skin, concentrations, irritating effects and a person may begin to feel weak, become unconscious.

causes irritation of With exposure to high are more pronounced, dizzy, drowsy, and

6

Page 20: U.S. ENVIRONMENTAL PROTECTION AGENCY · 01-F-00799 (5139) Suite 202, 111 South Bedford Street, Burlington, MA 01803 • (617) 229-6430 TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RES!

6 .

b. Long-term Exposure: Prolonged or repeated Ethyl Benzene

exposure on the skin may cause skin rash.

Methyl-Isobutyl Keytone ( CH^ ) tCHC^COC^

A colorless stable liquid with a pleasant odor, used as a solvent for paints, varnishes, nitrocellulose and lacquers. It is soluble in water and miscible with nost organic solvents. It has a TLV of 100 ppm and an IDLH Of 3000 ppm.

Health Hazards

Methyl-isobutyl Keytone is hazardous primarily through ingestion and inhalation but may be absorbed through the skin. It is also flammable, therefore a dangerous fire risk and will cause a violent reaction with potassium tertbutoxide .

ben zene They are suspected

7• Polychlorinated Biphenyl (PCB) - 1248

One of several aromatic compunds containing two nuclei with two or more substituent chlorine atoms, colorless liquids that are highly toxic and are carcinogens. It's PEL is 1 mg/m3 and it's IDLH is 10 mg/m3’

Health Hazards

PCB's have two distinct actions on the body, namely, a skin effect and a—toxic—action on the liver. The lesion produced in the liver is an acute yellow atrophy. This toxic action is increased if there is exposure to carbon tetrachloride at the same time. In persons who have suffered systematic intoxication, the usual signs and symptoms are nausea, vomiting, loss of weight, jaundice, edema and abdominal pain. Where the liver damage has been severe the patient may pass into a coma and die.

8. Styrene C6H5CH=CH2

A colorless liquid with a sweet aromatic odor at low concentrations and a sharp, penetrating, and disagreeable odor at high concentrations. Among its numerous uses, it can

serve as a packaging material, as well as an automotive radiator leak stopper. It has a TLV of 50 ppm and an IDLH Of 5000 ppm.

Health Hazards

Styrene is hazardous through ingestion, inhallation, and skin and eye contact. Symptoms of exposure include eye, nose, throat, and skin irritation, and to become sleepy or unconscious. Chronic skin exposure nay produce a skin rash. Personnel who show symptoms of styrene exposure should be removed from exposure and the symptoms will disappear.

7

Page 21: U.S. ENVIRONMENTAL PROTECTION AGENCY · 01-F-00799 (5139) Suite 202, 111 South Bedford Street, Burlington, MA 01803 • (617) 229-6430 TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RES!

Warning Properties

a. O'ior threshold: The odor threshold of styrene is 0 08

ppm.

b. Eye irritation level: Styrene vapor has been found tohave transient irritant effects on the eyes atconcentrations of 200 to 400 ppm.

c. Evaluation of warning properties: Since the odorthreshold of styrene is below the permissible exposure l^mit, it is treated as a material with adequate warnina properties. ^

9 . Tetracnloroethylene C2d 4

A colorless liquid with ar. odor like chloroform or ether. Ithas a 7LV of 100 ppm and an IDLH of 500 ppm.

Health Hazards

Tetracnloroethylene can affect the body if it is inhaled or it it comes in contact with the eyes or skir.. It can also affect the body if it is swallowed.

Effects of Overexposure

a. Short-term Exposure: Tetrachloroethylene my causeheadache, nausea, drowsiness, dizziness, incoordination, and unconsciousness. it my also cause irritation of the?YeS'^°S®' and.throft and flushing of the face and neck. In addition, it might cause liver damage with such findings as yellow jaundice and dark urine. The liverdamage my become evident several weeks after the

exposure.

b. Long-term Exposure: Prolonged or repeated overexposure

to liquid tetrachloroethylene my cause irritation of the skin. It might also cause damage to the liver and kidneys.

Warning Properties

a. Odor Threshold: Several sources state that 50 ppm is theodor threshold for tetrachloroethylene.

b. Eye Irritation Level: Eye exposure to high

concentrations of (tetrachloroethylene) vapor my cause mild sensation or irritation to the eyes, but serious injury is not likely.

Concentrations as low as 106 ppm have been reported to produce eye irritations

8

Page 22: U.S. ENVIRONMENTAL PROTECTION AGENCY · 01-F-00799 (5139) Suite 202, 111 South Bedford Street, Burlington, MA 01803 • (617) 229-6430 TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RES!

c. Other Information: Exposure to 513 to 690 ppm for tenminutes may produce nose and throat irritation.

«i. Evaluation of Warning Properties: Since the odorthreshold of te trachloroethyl: ne is below the permissible exposure iimit, and since eye irritation occurs at a concentration only twice the permissible exposure limit, its warnin: properties are considered to be adequate.

NOTE: If this substance is swallowed, vomiting should beinduced.

10. 1,1,1 Trichloi ethane CH^ccij

*,1,1 trichlc: oethane is a colo: less liquid with sweetuhloroform-lik odor, used as a:, industrial solvent, netal

-egreaser, an pesticide, it's is 350 ppm and it's IDLHs 1000 ppm.

ealth Hazards

*»1,1 trichlcroethane is hazardous if it is i-haled, -ngested, or crones in contact with the eyes or skin.

-.ifects of Ove: xposure

Short-term -..xposure: Exposure to 1,1,1 trichloroethane

vapor may cause headache, dizziness, drowsiness, unconsciousness, irregular heart beat, and death. It can also cause irritation if contacted with the eyes or skin in liquid form.

b. Long-term exposure: Studies of animals have shown somereproductive abnormalities when exposed to high concentrations of 1,1,1 trichloroethane.

c. First-aid procedures: For exposure of 1,1,1trichloroethane on skin and eyes, areas should be washed with water. If it has been swallowed, induce vomiting.

Warning Properties

a. Odor threshold: The odor threshold of 1,1,1trichloroethane ranges from 20 to 100 ppm.

b. Eye irritation level: In controlled human exposures ofup to 500 ppm, no effects other than slight eye irritation was noted, however, at 1000 ppm and above, mild eye irritation was experienced.

c. Evaluation of warning properties: 1,1,1 trichloroethaneis considered a material with adequate warning properties.

9

Page 23: U.S. ENVIRONMENTAL PROTECTION AGENCY · 01-F-00799 (5139) Suite 202, 111 South Bedford Street, Burlington, MA 01803 • (617) 229-6430 TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RES!

1,1/2, Trichlo roe thane CHCI^ch^

1,1,2, trich loroethane is a colorless liquid c.'. loro form-1 iki? odor. It has a TLv of 10 ppm and its s 0 ppm. It is suspected carcino-. n.

wi th: dlh

ais

H a1th Hazards

1.^,2 Trichloi ethane can affect t. e body if it is i-haled

it comes in contact with the eyes or skin, or if it is s-allowed. It may be absorbed through the skin.

E: lects of Ovei cposure

a. Short-term irritation incoordinat also cause

exposure: 1,1,2 T;ichloroethane may causeof the eyes ..nd nose, drow- . ness, :n, unconsciousness, and death. I: might ver and kidney dam-.^e.

b.

NCbe

Long term Exposure: Repeated or prolonged exposure to1,1,2 Tnch. uroethane might caus e liver or kidney c mage.

: If a pez son swallows this suostance, vomiting shouldnduced.

Try chloroethvle:. CHC1CC12

A colorless liquid with a chloroform,-like odor, used cleaning solvent, degreaser, or as and dry-cleaning sole It has a TLV or 100 ppm and a IDLH of 1000 ppm, and suspected carcinogen.

as acion. is a

Health Hazards

13.

Trichloroethylene is hazardous through the major routes of

exposure: Inhalation, ingestion, dermal and eye contactbranes?h2^?XpCTre in<^Ude headache and drowsiness followed y anesthesia and narcosis and is potentially fatal. Chronic

exposures may result in damage to the liver and other organs.

Toluene_C6H5CH3

Toluene is a colorless liquid to Benzene. It has a TLV of and an odor threshold of 10-15

with an aromatic odor 100 ppm and a IDLH of

ppm.

si mu lar 2000 ppm

Health Hazards

Toluene

contactcan affect the body if it with the eyes or skin, or

isif

inhaled, if it comes in it is swallowed.

10

Page 24: U.S. ENVIRONMENTAL PROTECTION AGENCY · 01-F-00799 (5139) Suite 202, 111 South Bedford Street, Burlington, MA 01803 • (617) 229-6430 TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RES!

Effects of Overexposure

Short-term Exposure eyes, respiratory- fat icue, weakness, drowsiness. Pecul: as "pins and nee: cone ntrations may liquid splashed i temporary damage. in seeing in bright

: Toluene ray caus- irritation of thetract, and skin. It may also cause confusion, heada'ie, dizziness, and

ar skin sensation r.-y be produced such :es feeling" or num'-ness. Very high cause unconsciousness and death. The

the eye may cause irritation and Inhalation may als 3 cause difficulty light.

b. Lone term Exposure: Repeated or pro! nged exposure to

liqu . : toluene may cause drying and era king of the skin.

14. Xylene C ; 1(CH3)2

A color.- ss liquid wi •. h aromatic odors wh ;e uses include rZcfna°n gasoline, protective coatings, jlvent for alkydresins, lacquers, enamels, and synth- ;is of orqanicpOmpounds . It has a PEL Of 100 ppm and IDLH of 10,000

Health H -. ards

Xylene can affect the b; dy if it is inhaled, if it comes in

contact with the eyes or skin, or if it i <= ,enter the body through the skin. ' allowed. it may

Effects o: Overexposure

a.

c.

Short-term exposure: Xylene vapor may cause irritation

° , e eyes' nose' and throat. At high concentrations,

vapor may cause severe breathing difficulties which may be delayed in onset. it mly also cause

lzziness, staggering, drowsiness, and unconsciousness,

kidneys. 3S cause irreversible damage to the liver and

Long-term exposure: Prolonged exposure may cause a skin

rash and irreversible eye damage.

First-Aid procedures: If xylene contacts the eyes orskin, wash with water. if swallowed, do not induce vomiting.

Warning Properties

a. Odor threshold: The initial odor of 200has an intensity of approximately 3 and valve of 1.

ppm for xylene an irritation

11

Page 25: U.S. ENVIRONMENTAL PROTECTION AGENCY · 01-F-00799 (5139) Suite 202, 111 South Bedford Street, Burlington, MA 01803 • (617) 229-6430 TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RES!

b. Eye irritation level: Xylene vapor will cause eye irritation. Lesions

vacuoles in the cornea of cats expc have een observed.

exposures of 200 ppm in the form of fin-3 ed to xylene vapors

Evaluation of >-.,rning properties: to be a material with good warning

Xylene is consider- :

operties.

12

Page 26: U.S. ENVIRONMENTAL PROTECTION AGENCY · 01-F-00799 (5139) Suite 202, 111 South Bedford Street, Burlington, MA 01803 • (617) 229-6430 TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RES!

TLV'S AND IDLH VALUES FOR KNOWN CONTAMINANTS

TLV (TWA)

Carbon Tetrachloride

Chloroform

Dichloroethane

Dichloroethylene

Ethyl Benzene

Methyl Isobutyl Keytone (MIBK)

Polychlorinated Biphenyl (PCB) - 1248

Styrene

Tetr achloroethylene

1/1/1 Trichloroethane

1/1,2 Trichloroethane

Trichloroethylene

Toluene

Xylene

5 ppm

10 ppm 1

200 pp m 4

200 ppm 4

100 ppm 2

100 ppm 3

1 mg.. 'x?

50 ppm 5

100 ppm

350 ppm 1

10 pp.m

100 ppm 1

100 ppm 2

100 ppm 10,

IDLH

300 ppm

.,000 ppm

,000 ppm

,000 ppm

,000 ppm

,000 ppm

10 mg/m"^

,000 ppm

500 ppm

,000 ppm

500 ppm

,000 ppm

,000 ppm

,000 ppm

13

Page 27: U.S. ENVIRONMENTAL PROTECTION AGENCY · 01-F-00799 (5139) Suite 202, 111 South Bedford Street, Burlington, MA 01803 • (617) 229-6430 TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RES!

D. INTRODUCTION & SITE BACKGROUND

On September II, 1985, Roberta Pirie and Jan Patterson, from the State of New Hampshire Bureau of Hazardous Waste compliance and Enforcement; Division of Public Health Services (NHDPHS) investigated a complaint, by Bob and Denise Mathews, regarding the discovery of several 55-gallon drums located on private property at 52 Burns Hill Road in Hudson, NH.

The property has been owned by Denise Mathew's father, Mr Roqer Guerette, since 1949. From 1950-1956. Mr. Guerette mowed the field each year for hay. After 1956, several junkyard dealers used the site as a disposal area for various forms of industrial and solid wastes, including several 55-gallon drums. Because these oisposal practices went relatively unmanaged, verv little information is avaiiable regarding the generator(s) of the drums, although it is suspected that Mr. R. Pelanger, who owns an autorepair and junkyard business, rented this property for several years.

On August 7, 1985, Bob Mathews who lives adjacent to the site, contracted a bulldozer to clear the site and transfer the tires to the landfill. During this clean-up operation, the equipment operator noticed several 55-gallon dru.ms among the tires and other miscellaneous debris. As he began to move these drums, S^VSna^ began leaking an unknown liquid material with a "strong odor". At that point, Mr. Mathews stopped all site activity and contacted the NHDPHS. This complaint prompted the state to conduct an initial site investigation on September 11, 1985.

2?t0b6r i1, }985' Pa™ Sprague and Kevin Hopkins, from the NHDPHS, conducted a technical hazardous waste site assessment at the Burns Hill Road Site, which was a follow-up to the initial complaint inspection of September 11, 1985.

The site is approximately 2 acres and is classified nostly as rural and wooded. The site is bordered by Bob Mathew's property o the northwest, the old Hudson Dunp to the east, and Burns Hill

Road to the southwest. During the NHDPHS investigation, it was learned that in addition to the tires and other debris, the site also contained 14 - 55 gallon drums and 22 partially full drums of hazardous waste solvents. Several of the drums wer- also analyzed for pesticide and PCB contamination, and showed either low or undetectable levels.

Following this investigation, the NHDPHS classified the site as

a top priority for drum removal and further remedial investigation".

14

Page 28: U.S. ENVIRONMENTAL PROTECTION AGENCY · 01-F-00799 (5139) Suite 202, 111 South Bedford Street, Burlington, MA 01803 • (617) 229-6430 TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RES!

E. PURPQS

The pu r contra ■ estab] . mandat chemic

zones . provide this ir the Nat

pose of thir

•or person ■■ >h person y safety

1 hazards : contamina:

for contir -leaiate remo ional Contin

> plan is to assig >1 relative to •1 safety and erating procedur ncountered on th -on, establish de gencies which may val action, in a>: -ency Plan (NCP).

responsibilities t safety and site rotection standarc

•s relative to phys • site, distinguish ontamination proceci arise during the c: cordance with 40 CF.-

EPA and acu r i ty , , site cal and various

:res, and arse of

; 300.38,

applic; tlity

This follow, action, enteric: set fo: that a • OSHA or In the regulat: protoco. used i,\ Standard

atoco 1 ado. by any and and any po. the site s

th herein w. tivity is t dtate and 1 event of

; n , the mo : is in ac- the Office

Operating g

esses the safe- all personnel in sons that may vis ill read and sigr. 11 remain in effe­minated. it de­al regulations,

conflict betv stringent of th-

rdance with, an. of Emergency anc fety Guides

procedures that Ived in this CERCL- t the site. All ;. this safety plan, t until the OSC , s not supercede any but is in addition en this protocol two will be enfor refers to the ter

Remedial Response

-'i 11 be removal rsonnel rotocol rtifies Federal o them, and a ed. The inology !OERR).

G. RESPONS:HILITIES

1. On-Scene Coordinator (OSC)

The National Oil and Hazardous Substance PollutionContingency Plan (NCP) authorizes the OSC to coordinate and l ect federally financed response or cleanup activities at

the site. The NCP also makes the OSC responsible for

40 crRS3S?.3*branff^fnn?erns at the response scene <see

At this the OSC

hazardous waste site, the primary responsibilities of relative to safety include the following:

a. io ensure that all personnel allowed to enter th- sited.e., EPA, TAT, contractors, State, visitors) ar- aware o- the Potential hazards associated with substances known or suspected to be on site;

To ensure that said personnel are aware of the provisionsP-5hiS.plf" an? ere instructed in the safety practices

ch.-tined in the plan, including its emergency procedures;

To ensure available site;

that the appropriate safety and properily utilized by all

equipmentpersonnel

ison

15

Page 29: U.S. ENVIRONMENTAL PROTECTION AGENCY · 01-F-00799 (5139) Suite 202, 111 South Bedford Street, Burlington, MA 01803 • (617) 229-6430 TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RES!

d. To direct the safety monitoring efforts of the si*e

Safety Officer; and

e. To correct any work practices or onditions under h ■-> control that may result in ex >sure to hazard/ ..I substances or i. jury to personnel.

The On-Scene Coordinator for this site is David Ferenz. T OSC may alter this health and Safety Pi..n as site conditior ; indicate prudent and safe.

2. Safety Officer

_n accordance with EPA’s Occupational Health and Safer .- Manual as ordered by the Executive Order 12196: "The Safer -fficer is responsible for implementir the safety plan . ; he site. "

t the Burns Hill R. 5d Hazardous Waste r.te, the Site Safer fficer shall:

Monitor compliar.-e of workers relati e to pre-establishe : personnel protr. tion levels ( i.e. . use of necessar clothing and equipment to ensure the safety c: personnel) ;

. Notify the OSC of discrepancies c: violations of th- safety plan; and,

c. Evaluate weather and contamination hazard information, and recommend to the OSC any necessary modifications tc work plans and personnel protection levels to maintain personnel safety.

The Safety Officer for this site shall be Robert Donati.

3. Response Manager

The Response Manager will direct the action of all contract personnel in accordance with the Site Safety Plan, and will ensure compliance of all safety procedures.

The Response Manager for this site will be David Meeker ofO.H. Materials Co. Any accidents or injuries, no matter how- minor, will be reported to the Response Manager who will report to the OSC. All accidents will be recorded on Accident Report forms, and a copy given to the OSC.

3 6

Page 30: U.S. ENVIRONMENTAL PROTECTION AGENCY · 01-F-00799 (5139) Suite 202, 111 South Bedford Street, Burlington, MA 01803 • (617) 229-6430 TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RES!

H. SAFETY PROCEDURES AND LEVELS OF PROTECTION

1. Respiratory Protection Program

A ] 1 contractor a:. : government personnel involved n on site activities shall have a writte:. respiratory protection program. All personnel wearing self-contained breathing apparatus (SCBA) and air-pur ifyino respirators c site are i equired to be fit tested, physically qualified to wear a SCBA/respirator, and properly trained and experienced in their use. All respiratory protection equipment is to be properly decontaminated at the end -f each workday.

r--rsons who have beards or other ;acial hair tha* will not allow proper fit of respiratory protection will not be p.-rmitted to enter areas requiring . ich protection.

2 . T: aininq and Medic a 1 Monitoring Pro r ram

Personnel will h .ve either formal training or n-the-job tr aining for thor 2 tasks they are assigned to ; ■ rform on site. All unf. cniliar activit.es will be rehearsedb-. orehand.

All contractor a: i Federal personnel who are hazardous substances shall be enrolled in me r.itoring program.

(•-•posed to a medical

3. General Safety Rules And Equipment

a. Do not wark alone when performing tasks in areas that require protective clothing unless the work will be of short duration and another person has been informed of your location, or while performing any task that could be potentially incapacitating.

b. There will be no eating, drinking, or smoking in either the Exclusion Zone or the Contamination Reduction Zone.

c. All personnel must pass through the Contamination Reduction Zone to enter the Exclusion Zone.

d. An emergency deluge shower/spray can is to be located on the Decontamination truck.

e. Where practical, all too Is/equip .rent will be spark proof, explosion resistant and/or bonded and grounded.

f. Fire extinguishers will be on site.

17

Page 31: U.S. ENVIRONMENTAL PROTECTION AGENCY · 01-F-00799 (5139) Suite 202, 111 South Bedford Street, Burlington, MA 01803 • (617) 229-6430 TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RES!

g. Since site evacuation may be necessary if an explosion,fire, or the like occurs on site, an individual shall be assigned to sound a horn. The evacuation signal will betwo long blasts every iO seconds until all -ersonnel are evaluated and account 'd for. This proced re will be reviewed at each mornin.’s safety meeting (i scribed in H 4 , . elow) .

h. A :irst-aid kit will ,\e on scene at all times during operational hours.

i. The location of all emergency equipment on rite will be within the Decontaminat: n truck.

j. No parking of non-esse: r ial vehicles inside of the work are will be permitt . since safety la _s may be obs* acted.

k. No -ork will be perfor red in the Exclusion one during hour- of darkness.

4. Morning afety Meetings

A morni g safety meeting wi .1 be conducted each ray for all site personnel. Daily atte; lance sheets will be maintained. The sarety procedures, vacuation procedur s, escape procedures, and the day's planned operation. will be discussed during these meetings.

5. Site Control

Site access must be controlled to eliminate risk of.spreading contaminants and to protect the public. The perimeter of the site will be cordoned off with barrier tape and appropriate warning signs will be posted. Uniformed security service will be provided during all non-work hours. Except in an emergency, all personnel shall enter and exit through the Contamination Reduction Zone.

6. Designation of Work Zones at the Site

The entire site will be divided into three zones:

a. The Exclusion Zone (EZ) which is known to be or have a potential for becoming contaminated;

b. The Contamination Reduction Zone (CRZ) where decontamination of personnel and equipment exiting the Exclusion Zone will be performed.

18

Page 32: U.S. ENVIRONMENTAL PROTECTION AGENCY · 01-F-00799 (5139) Suite 202, 111 South Bedford Street, Burlington, MA 01803 • (617) 229-6430 TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RES!

The Clean Zone (CZ) which is not contaminated;c.

As work progresses on site, the OSC may determine that an area previously designated an EZ is no longer so classified. Such a change, however, is not intended to change the desingation of the CRZ since this may involve movement of the decontamination facilities, andconsequently, increase costs.

d. Specific layout of these zones:

1. The Exclusion Zone (EZ) is that portion of the site where drums are present or excavation of drums is occurring which includes the drum staging area.

2. The Contamination Reduction Zone (CRZ) will bestratigically located just before the actual removal action begins. It's location shall take into consideration site characteristics such as wind direction, points of access from rroin roads, access agreements by local residents and site spaceconstraints.

j. The Clean Zone (CZ) will include all those areas outside the Contamination Reduction Zone and the Exclusion Zone until such time during the removal action as these 2 zones are declared clean by the OSC.

4. The location of these zones are illustrated on the site map (see Figure 1 - Section L).

7. Personnel Protection

Personnel protective equipment and safety requirements must be appropriate to protect against the known or worst potential hazards on the site. Protective equipment should be selected based on the concentrations and possible routes of personnel exposure to known or potential worst case substances.

The appropriate level of protection shall be determined prior to the initial entry on site based on the best available information. Subsequent information may result in changing the original level selected.

Level C protection has been selected as the entry level of protection into the EZ as dictated by routine air monitoring. Level B protection shall be worn when organic contaminants exceed 5 ppm above background. Level B protection shall be worn at all times when work operations involve the handling of drums; excavation, staging, sampling, and overpacking.

19

Page 33: U.S. ENVIRONMENTAL PROTECTION AGENCY · 01-F-00799 (5139) Suite 202, 111 South Bedford Street, Burlington, MA 01803 • (617) 229-6430 TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RES!

*. Personal Protection Equipment - Level A

Positive Pressure SCBA (MSHA/NIOSH approved) operated in the positive pressure mode.

Totally Encapsulating Suit (bo-‘:s & gloves att ;hed)

Gloves - 1: ;er (tight fitting chemical resis.ant)

Boots - Gaemical-protective, steel toe auu shank, depending on suit boot construction; worn over suit boot

Gloves - Outer, chemical-resistant. Dependiag on suit constructic n worn over suit gloves. May be replaced with tight-fitt; eg, chemical-resistant gloves worn :aside suit gloves.

Underwear - Cotton, "long-john" type

Hard Hat (under suit)

Disposable protective suit, c'.oves, and boo? - . (Worn under or ov- r encapsulating sui•)

Coveralls ( .under' su it)

2-Way Radio Communications

Criteria for Use

When the type(s) and concentration(s) of toxic substances are known require the highest level of combined protection to the respiratory tract, skin, and eyes. These conditions would be:

i. Atmospheres which are "immediately dangerous to life and health" (IDLH)

A. IDLH 1 s can be found in the NIOSH/OSHA's "Pocket Guide to Chemical Hazards" and/or otherreferences.

b. Known atmospheres or potential situations that would effect the skin or eyes, or could be absorbed into the body through these surfaces in toxic quantities**

i• Potential situations are those where vapors may be

generated or splashing may occur through siteactivities.

Standard reference books should be obtain concentrations hazardous to mucous membranes.

consu lted skin , eyes,

to

or

20

Page 34: U.S. ENVIRONMENTAL PROTECTION AGENCY · 01-F-00799 (5139) Suite 202, 111 South Bedford Street, Burlington, MA 01803 • (617) 229-6430 TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RES!

c. Oxygen deficient atmospheres with above conditions

At si toxic

tes where the type(s) and/or substances are unknown.

potential concentrations of

a. Unless circumstances st: site should be presum- respiratory system, ski would provide the highe initiai entry team.

ingly indicate otherwise, the i to prevent hazards to the 1 and eyes. Level A protection -t level of protection for the

i. Such circumstances mi oht be:

A. Environmental measurements contiguous to the site

B. Reliable, accurate historical data

C. Open, unconfined oeas

D. Minimal probability of vapor's presence or splashing with cutaneous effecting substances.

ii. Enclosed areas such as building, railroad cars, ships

HOi */ 6tc *

Total vapor reading indicate over 1: i ppm on

instruments such as the photoionizer or or :anic vaporanA.V7pr "

b. Personnel Protective Equip tie n t Level B

o Positive pressure SCBA, MSHA and NIOSH approved

o Chemical resistant clothing (hood and booties to be taped to the main body portion; as a whole, to be

Tyvek PE)1™^ gloves and outer boots ie. Saranex of

o Gloves - Outer, chemical resistant

o Gloves - Inner, chemical resistant (two or more layers)

o Boots - Outer, chemical resistant

o Boots - Inner, chemical resistant, with steel toes and shank

Hard hat (attached face shield optional)

font l Fadio communications - intrinsically safe

21

Page 35: U.S. ENVIRONMENTAL PROTECTION AGENCY · 01-F-00799 (5139) Suite 202, 111 South Bedford Street, Burlington, MA 01803 • (617) 229-6430 TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RES!

Criteria for use: conditions

meet i ng any of the fo 1 lowi ng

o Atmospher s exist, or have that are immediately dange ( IDLH) ( .- ference NIOSH/OSHA Chemical azards

: iie potential to ex.it, as to life and he.C.th Pocket Guide to

o Atmospher s exist, or have the potential to ex tthat contain less than 19.5% < xygen '

o Total atmospheric concentrations of unidentified?nnb°rne contaminants exist n a range from 5ppm to 100 ppm ccordmg to reading obtained on a Cen- ry OVA, HNU : notoionizer, or the >quivilent

o Atmospher.: contaminants, . li,:id splashes, or ot ;r direct '' ntact with small areas of skin ] ;t unprotect. : in using this lev. 1 of protection, w ;i not produ.- an adverse affect

o None of tf. criteria for using level A are met

c * Personnel Prot ctive Equipment - I ve1 C

o Full-face air-purifying respiator, MSHA and Nlr :h approved, -ith GMC-s cartridge or Type N canniste:

o Chemical esistant clothing (•aod and booties to e taped to t:.a main body; as a -hole, to be taped -.o inner glov. s and outer boots ie. Saranex or Tyvek pc)

o Gloves - Outer, chemical resistant

o Gloves - Inner, chemical resistant (two or morelayers)

o Boots - Outer, chemical resistant

° Bu0tf Inner' chemical resistant, with steel toes and

o Hard hat (attached face shield optional)

o 2 way radio communications - intrinsically (optional)

o Escape mask (optional)

Criteria for Use:

o Measured air concentrations of identified substances will be reduced by the respirator to the substance's

exposure limit or less, and will be within tho service limit of the canister.

22

Page 36: U.S. ENVIRONMENTAL PROTECTION AGENCY · 01-F-00799 (5139) Suite 202, 111 South Bedford Street, Burlington, MA 01803 • (617) 229-6430 TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RES!

o Atmospheric contaminants, liquid splashes, or other direct contact with small areas of skin left unprotected by using this level of protection, will not produce an adverse affect

o Air will be monitored periodically (hourly)

o None of the criteria for using level of protection A or B is met

<*• Personnel Protective Equipment - Level D

Alternatively, Level D may be choosen when the site Safety Officer deems this level appropriate. Level D is the basic work uniform and should be worn for all site operations where no greater level of protection is required. Level D protection should be selected whensite operations will definitely not expose personnel to toxic materials. The following equipment shall be utilized in Level P.

Personnel Protective Equipment

o Coveralls

o Gloves (optional)

o Boots - Inner/outer, chemical resistant, with steel toes and shank

o Boots - Outer, chemical resistant (optional)

o Hard Hat (optional)

o Safety glasses or goggles (optional)

o 2 way radio communications (optional)

o Escape mask (optional)

Criteria for Use

o No indication of airborne health hazards present

o Work functions preclude splashes, immersion, or unexpected inhalation of any hazardous substance

o None of the criteria for using level of protection A, B, or C is met

23

Page 37: U.S. ENVIRONMENTAL PROTECTION AGENCY · 01-F-00799 (5139) Suite 202, 111 South Bedford Street, Burlington, MA 01803 • (617) 229-6430 TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RES!

Alternative Levels of Protection3 .

The site Safety Officer may determine if alternate levels of protection are necessitated under adverse site conditions. Should this occur, the protocol will follow procedures outlined in Standard Operating Safety Guides.

I. DECONTAMINATION PROTOCOL

Decontamination Protocol will involve the thorough decontamination of all equipment and personnel leaving the EZ and

CRZ areas. The following decontamination procedures will be followed at the Burns Hill Road Site. Changes in tnese procedures may be made by the OSC to accommodate changing site operations.

Personnel are responsible for decontamination (and routine maintenance) of their individual face masks. They will be decontaminated at the end of each day, using the following procedure, at a minimum.

Wash in a detergent solution, such as lysol in water. Rinse with water and hang to dry.

1. Complete Procedure

The Decontamination Protocol will ba a six (6) stage process, which will be strictly adhered to by all personnel entering the EZ, or areas of the site deemed by the OSC or Safety Officer to contain hazardous vapor concentrations.

a. Reduction Area Number One (1)

Deposit equipment used on site on plastic drop cloths or in different containers with plastic liners.

b- Reduction Area Number Two (2)

Scrub outer boots in a detergent solution (such as water and lysol) then step into a second container to rinse boots.

c. Reduction Area Number Three (3)

Wash outer gloves in a detergent solution (such as water and lysol) then rinse in a second container of water. If gloves can not be adequately cleaned, dispose of them in the container at the next station.

24

Page 38: U.S. ENVIRONMENTAL PROTECTION AGENCY · 01-F-00799 (5139) Suite 202, 111 South Bedford Street, Burlington, MA 01803 • (617) 229-6430 TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RES!

Reduction Area Number Four (4)

is removed from outer gloves and boots and deposited lined container for disposal. Boots are removed

down. Outer gloves , or placed or the rack,

Tape

in a ----- LUL uisposai. Boots are removed andplace: on the rack, ups;de down. Outer gloves are then remov-d and disposed of, or placed o: the rack, finger

e. Reduction Area Number Five ( 5)

Remove SCBA/air purifying respirator, hang to dry.

f. Reduc;Ion Area Number Six (6)

Wash and rinse and

Remov., tape joining the ain body of chemical resistant cloth, * to inner gloves, oooties, and hood. Remove the

then main body, t, en booties, tnen inner gloves in all items in 1 .ned container.

hood, Dispose

2. Equipment

Jta9ia" area just ins:de th« exclusion U- established to d- contaminate the vehicles. The

cleaned300 Ca^^fn'^h ‘"eSe vehioleE “ill be steam cleaned Care will be take;, to ensure the- the runoff i<?contained to the site and property disposed.

25

Page 39: U.S. ENVIRONMENTAL PROTECTION AGENCY · 01-F-00799 (5139) Suite 202, 111 South Bedford Street, Burlington, MA 01803 • (617) 229-6430 TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RES!

3. PERSONNEL DECONTAMINATION FLOW CHART

DEPOSIT EQUIPMENT USED ON PLASTIC DROPC:OTHS

BOOT SCRUB/RINSE i

I

■ -'TER GLOVE WASH/RIN-E

. Z_T.7“ .T APE/OUTER GLOVE/BOO!'

REMOVAL

SCBA/AIR PURIFYING RESPIRATOR

REMOVAL/WASH/RINSE

INNER GLOVES/BOOTIES/HOOD

REMOVAL

26

Page 40: U.S. ENVIRONMENTAL PROTECTION AGENCY · 01-F-00799 (5139) Suite 202, 111 South Bedford Street, Burlington, MA 01803 • (617) 229-6430 TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RES!

J. AIR MONITORING

For this site the EZ will be monitored prior to bginninng of each day, periodically (hourly) th and at anytime site conditions warrant additiona Measurements are to be taker; with a Century OVA the HNU Pr.otoionizer, and the Cumbustible gas/o.,

entering at the oughout the day,

investigation. n the GC mode or indicator.

Levels of protection will be as follows:

Level of Protection

Lev^i A Levvl B Levo 1 C Levr-1 D

LEVEL

OXYGEN 19.5- - 25.0%

Less than 19.5%

Grear.er than 25.0%

COMBUSTIBLEGAS Less than 10% of LEL

10% - 25% of LEL

Greater than 25% of LEL

Total Air Concentrations Above Background (for Minimum of

5 Continuous Minutes)_________

>99 ppm 5-99 ppm 0-5 ppm

0 ppm

ACTION

Continue

SCBA required, combustible gas meters not reliable.

Exit

Continue

Procede with CAUTION

EXIT

K- EFFECTS OF COLD EXPOSURE

Persons working outdoors in temperatures at or below freezing may e rostbitten. Extreme cold for a short time may cause severe

injury to exppsed body surfaces, or result in profound generalized cooling, causing death. Areas of the body which have high surface area-to-volume ratio such as fingers, toes, and ears, are the most susceptible.

Two factors influence the development of a cold injury: ambienttemperature and the velocity of the wind. wind chill is used to escribe the chilling effect of moving air in combination with low temperature. For instance, 10 degrees Fahrenheit with a wind ot 10 miles per hour (nph) is equivalent in chilling effect to still air at -18 degrees Fahrenheit.

27

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As a general rule, the greatest incremental increase in wind chill occurs wtien a wind of 5 nph increases to 10 nph. Additionally, water conducts heat 240 times faster than air. Th ;s, the body -ools suddenly when rhemical -protect ive 'guioment is removed if th- clothing undernea* is perspiration sr -dced".

Lo'al injury re siting from cold is. included in the gen ric term fi .stbite. The. e are several degrees of damage. Frostbite of th. extremities < an be categorized ir.to:

Frost nip or incipient frostbite: Characterized by suddenlyblanching or whitening of skin.

Superficial :rostbite; Skin has a waxy or white a: oearance and is firm • ' the touch, but ti sue beneath is resident.

Deep frostbit •>: Tissues are col-:, pale, and solid; • >;tremelyserious in jur . .

Systemic hypother:-.ia is caused by exposure to freezing or rapidly dropping temperature. Its symptoms -re usually exhibited in five sta.es: 1) shiv ring, 2) apathy, ostlessness, sleepirss, and(sc-etimes) rapi-; cooling of the body to less than 95 degrees Fahrenheit, 3) unconsciousness, glassy stare, slow pul;e, and slew respiratory rate, 4) freezinc of the extremiti- s, and fir, illy, 5) death .

1. Treatment

a.

b ,

c.

Give artificial respiration, if necessary.

Bring the victim into a warm room as quickly as p ssible

Remove wet or frozen clothing and anything -.hat is constricting.

Rewarm the victim rapidly by wrapping him in warm blankets, or by placing him in a tub of water that is warm but not hot to the hand or forearm.

If the victim is conscious, give him hot liquids by mouth ( not alcohol) .

Dry the victim thoroughly if water was used to rewarm him.

Carry out appropriate procedures as describe : forfrostbite.

28

Page 42: U.S. ENVIRONMENTAL PROTECTION AGENCY · 01-F-00799 (5139) Suite 202, 111 South Bedford Street, Burlington, MA 01803 • (617) 229-6430 TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RES!

L. HURNS HILL ROAD SITE MAP

/

/ I/ /

//

FIGURE 1

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M. I approve Hudson,New safety of operations

this Safety Hampshire.

persons who

Plan for the Burns Hill Road site in It adequately provides for the health and

will or may be effected by on si*o

/V V--. -A-//

David W. Tordoff, Safety Office? Oil & Hazardous Materials Section Region I

5" /\

Date

Page 44: U.S. ENVIRONMENTAL PROTECTION AGENCY · 01-F-00799 (5139) Suite 202, 111 South Bedford Street, Burlington, MA 01803 • (617) 229-6430 TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RES!

N. SIGNATURE PAGE

name organization date

1.

2.3.

4.

5.

6. _

7

8

9

11 •_

12

13 •_

14 •_

15

i6 ._

17._

18

19-_.

20.

31

Page 45: U.S. ENVIRONMENTAL PROTECTION AGENCY · 01-F-00799 (5139) Suite 202, 111 South Bedford Street, Burlington, MA 01803 • (617) 229-6430 TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RES!

VI. APPENDICES

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APPENDIX A

GRID LAYOUT

Prior to soil sampling, a sampling grid was established to assure proper sample location identification. Using Burns Hill Road as survey control, an approximate north-south, east-west grid pattern was laid out across the site covering areas where drums, tires, and other debris were found. The line extending from point 0 to point N2+41 was used as the grid baseline. Along this baseline, 12 sampling stations were set at 25 fort intervals. At each of these stations, east-west grid lines v -re established with grid points also at 25 foot intervals (See attached Weston Drawing BH-1).

Page 47: U.S. ENVIRONMENTAL PROTECTION AGENCY · 01-F-00799 (5139) Suite 202, 111 South Bedford Street, Burlington, MA 01803 • (617) 229-6430 TECHNICAL ASSISTANCE TEAM FOR EMERGENCY RES!

APPENDIX B

SOIL SAMPLING

Composite soil samples were collect.ed from each grid point at the Burns Hill Read site accroding to the following procedure:

o Using a post-hole digger, a 12 inch hole was dug -at each sampling point.

o The hole was then tested for possible soil gas releases utilizing the HNU Model PI 101 Photo Ionizer. If abnormally high readings were observed, then tr.e hole was dug to 24 inches.

o With a metal sampling spoon, soil from the hole was placed in a plastic bucket from each point along a sincie east-west grid line in order to obtain a total of 100 ounces of soil to be composited.

o From the soil collected, three composite soil samples were obtained: two 120 ml VOA viles and one 32 ouncesample jar.

o Any soil remaining in the bucket was placed back into the coring holes.

o Composite soil samples were collected at all 12 east- west grid lines for a total of 36 samples.

o In order to assure that no cross contamination occurred between sampling stations, all sampling equipment was thoroughly decontaminated with soap and water.

In addition to the grid stations, a red 55-gallon drum discovered near the site entrance was also sampled. The drum contained dark soil and other miscellaneous solid waste debris. As requested by the EPA On-Scene Coordinator, two 120 ml VOA viles and one 32 ounce sample jar was collected from the drum.

All 39 soil samples from the Burns Hill Road site were collected and prepared in accordance with EPA sampling protocol and transferred to the EPA New England Regional Laboratory (NERL) for

analysis.

1 No HNU readings were observed above background, except at point

N1+50E100.Backgrould: less than 1 ppm at 0.5 span settingN1+50E100: 5 ppm at 0.5 span setting.