the salt industry center of japan - shiojigyo.com · "á 4 2005 11 ¬29 ã9Ô + ã9Õ 13 (30...

20052005 1111 292913:3013:30 16:3016:30 12:3012:30

33

The Salt Industry Center of JapanThe Salt Industry Center of Japan

2005 11 29 13 30

13:30 16:30

1.

( ) 1

2.

( ) 16

3.

( ) 25

4.

( ) 35

1.

9 4

1 2) 3)

2.

( ) ( )

( -1)

( -1)

( )

( ) ( )

( )

( )

- 1 -

-1

3.

3.1

( ) (

) ( ) ( )

( -1) ( )

( ) -2 1 4

( )

-3

20%

- 2 -

-1

-3

0

2

4

6

0.0 0.5 1.0 1.5(mm)

(sec

)

0.6

0.8

1.0

1.2

1.4

1.6

(g/c

m3 )

max min Ave.

-2 ( )) 1.5mm

3.2

(Cl) (Ca)

(Mg) (K) (SO4) (Na)

( )

( )

- 3 -

( ) K

( CaSO4)

( )

3) 1

3.2.1

-4

-4 ( )

1)

3 10%

0.5%

- 4 -

( -5)

05

1015202530354045

0.5

0.5

1

13

35

510

1015

1520

2) (Mg)

Mg ( )

(

) Mg 3 %

Mg (0.01

0.02 %) Mg

( K

) Mg

mg/kg

( -6)

(%)

-5

3) NaCl

NaCl 92 96%

99.5%

99.92%

70%

Mg %

-6 Mg

NaCl

NaCl

( -7) -7 NaCl

4)

- 5 -

0

20

40

60

80

100

0.01

0.01

0.02

0.02

0.05

0.05

0.1

0.1

0.2

0.2

0.5

0.5

1 1<

0.01%

( )

(

) 0.02%

( -8)

-8

5)

(Ca) (SO4)

SO4

SO4 0.2 %

SO4

1 % Ca SO4 ( CaSO4)

(K) 0.2%

(K 0.01 0.02%)

1 %

K (NaCl ) ( )

2 KCl 20%

- 6 -

3.2.2

( )

1) (As)

g/kg(ppb)

(0.02mg/kg

) ( )

As As

As

( -9)

0

20

40

60

80

100

0.02

0.02

0.05

0.05

0.1

0.1

0.2

0.2

0.3

0.3

0.5

0.5

1.0 1<

As (mg/kg)

-9

2) (Cd)

( ng/kg)

g/kg

g/kg 1 ( )

3) (Pb)

( ng/kg)

Pb

4) (Cu)

( ng/kg)

μg/kg μg/kg Cu 1mg/kg

- 7 -

Cu

5) (Hg)

(1ng/kg )

6)

(Cr) 3mg/kg

(Ni) (Fe)

Cr

Cr

Fe (Mn) (Al)

( )

3.3

(N) (Si) (P)

( )

( )

( -1 -10) -1 ( ) (%)

( ) 5.44 5.47

IM 0.12 0.02 Cl 56.23 56.41 Ca 0.26 0.20 Mg 0.42 0.41 SO4 1.36 1.19

K 0.13 0.14 NaCl 91.41 91.70

( )

( )

4)

- 8 -

0.1

1

10

100

1000

10000

100000

Cd Co Cu Fe Mn Mo Ni Pb Ti V Zn

(μg/

kg)

(0.01%)

-10

pH (10 )

3.4

( )

(

)

4.

- 9 -

( 2)

1) , , , , , “ ”,

,32,pp133-144,(1999)

2) , , , , “ ( )”

,36,pp305-320,(2003)

3) ( ) ,“ ”,(2004)

4) , , , , “ ”,

16 ,(2004)

- 10 -

1

169 ( ) (%) (mg/kg)

Ca Mg NaCl As Cu Pb Cr Fe Mn

5.02 0.005 0.13 0.17 93.21 ND ND ND ND ND ND 3.74 0.002 0.056 0.62 89.85 ND ND ND ND ND 0.033

4.15 0.00 0.11 0.37 93.61 ND 0.24 ND ND 7.0 ND 3.48 0.00 0.09 0.15 95.37 ND 0.30 ND ND ND ND

4.07 0.006 0.10 0.35 93.93 ND ND ND ND 7.7 ND 7.01 0.00 0.20 0.34 85.37 ND ND ND ND ND ND

( ) 3.40 0.00 0.16 0.21 95.01 ND ND ND ND 0.92 ND 3.69 0.00 0.068 0.29 94.68 ND ND ND ND ND ND

3.53 0.00 0.076 0.28 94.78 ND ND ND ND ND ND 4.07 0.00 0.13 0.38 93.49 ND 0.30 ND ND 2.5 0.1

1.29 0.00 0.049 0.066 98.00 ND ND ND ND ND ND 6.37 0.002 0.030 0.52 90.76 ND ND ND ND ND ND

4.38 0.002 0.057 0.64 91.51 ND 0.22 ND ND ND ND SUNSALT 1.36 0.006 0.20 0.012 97.33 ND ND ND ND 3.7 1.9

1.20 0.22 0.00 0.18 97.80 ND ND ND ND 0.56 0.063 1.37 0.16 0.001 0.15 97.90 ND ND ND ND ND 0.064

2.79 0.025 0.39 0.12 94.73 ND ND ND ND 29 0.69 2.41 0.00 0.089 0.14 96.64 ND ND ND ND ND ND

6.11 0.002 0.18 0.15 92.51 ND ND ND ND ND ND 7.27 0.006 0.28 0.42 89.54 ND ND ND ND ND ND 7.56 0.01 0.29 0.29 90.05 ND ND ND ND 7.9 1.1

9.72 0.03 0.24 0.70 85.85 ND ND ND ND 24 1.3 1.05 0.032 0.16 0.22 97.21 ND ND ND ND 0.95 0.14

7.95 0.012 0.29 0.47 88.82 0.022 ND ND 0.12 1.3 0.20 5.59 0.010 0.23 0.45 91.29 ND 0.57 ND ND ND 0.14

7.24 0.030 0.22 0.71 88.25 ND ND ND ND ND ND

11.32 0.016 0.21 1.34 81.25 ND 0.23 ND ND 0.93 0.54 9.39 0.026 0.57 0.62 85.27 ND ND ND ND 2.4 ND

(PURE BONIN SALT)

10.11 0.058 0.53 0.87 83.48 ND ND ND ND 0.74 0.099

6.00 0.00 0.14 0.27 91.96 ND 1.1 ND ND 0.18 ND 7.73 0.012 0.21 0.60 88.52 ND 0.43 ND ND 2.1 0.16 10.82 0.048 0.92 0.54 83.19 0.065 ND ND ND ND 0.074 9.59 0.004 0.026 0.018 90.10 ND ND ND ND 1.6 0.22

8.75 0.00 0.074 0.19 89.86 ND ND ND ND 1.3 0.18 5.17 0.00 0.039 0.060 94.27 ND 0.25 ND ND ND ND

8.96 0.00 0.050 0.41 88.89 ND ND ND ND 9.4 ND 5.32 0.002 0.028 0.20 93.58 ND ND ND ND 1.1 0.15

7.00 0.00 0.14 0.28 90.99 ND 0.96 ND ND 0.43 ND 8.84 0.00 0.02 0.02 90.93 ND ND ND ND 1.1 0.2

( ) 17.85 0.12 0.50 1.63 72.08 ND ND ND ND 4.1 0.098 9.01 0.00 0.40 0.35 87.60 ND ND ND ND 0.95 0.086

3.86 0.00 0.10 0.16 94.65 ND 0.27 ND 0.16 0.78 ND 5.35 0.001 0.28 0.18 92.65 ND 0.54 ND ND ND ND

5.27 0.001 0.31 0.28 92.02 ND ND ND ND ND ND 10.64 0.010 0.12 0.90 84.38 ND ND ND ND ND 0.056

8.35 0.004 0.39 0.52 87.57 ND 0.35 ND ND 0.70 ND 3.09 0.010 0.32 0.55 92.86 1.3 ND ND 0.40 2.8 2.9 9.04 0.010 0.28 1.08 83.93 ND ND ND 0.22 1.7 ND

8.59 0.098 1.15 0.63 84.02 0.025 ND ND 0.28 12 0.34

- 11 -

10.15 0.009 0.28 0.81 84.82 ND ND ND ND ND ND 7.47 0.026 0.14 0.54 89.25 ND 0.21 ND ND 2.7 0.25

4.98 0.00 0.088 0.14 94.09 ND ND ND ND ND ND 5.55 0.00 0.036 0.38 92.37 ND ND ND ND ND ND 7.79 0.014 0.040 0.24 91.02 ND ND ND ND 2.3 0.41

4.69 0.014 0.005 0.002 95.25 0.023 ND ND ND 2.4 0.26 3.80 0.006 0.036 0.030 95.74 ND ND ND ND 2.0 0.19

6.66 0.008 0.13 0.094 92.41 ND ND ND ND ND 0.23 ( ) 5.43 0.002 0.11 0.080 93.64 ND ND ND ND ND 0.13

7.92 0.00 0.018 0.018 91.82 ND ND ND ND 0.85 0.11 4.28 0.00 0.039 0.17 94.70 ND ND ND ND ND 0.056 7.53 0.008 0.10 0.39 90.02 ND ND ND ND 5.7 0.49 2.85 0.00 0.072 0.068 96.48 ND ND ND ND 0.67 0.15 6.22 0.00 0.12 0.15 92.52 ND ND ND ND ND 0.17

6.33 0.00 0.029 0.046 93.23 ND ND ND ND ND 0.072 0.15 0.00 0.021 0.017 99.67 ND ND ND ND ND ND

0.20 0.03 0.01 0.06 99.24 ND ND ND ND 0.4 ND 0.51 0.020 0.046 0.054 98.76 ND ND ND ND ND ND

0.36 0.01 0.08 0.08 98.81 ND ND ND ND 1.0 0.3 0.58 0.00 0.12 0.08 98.54 ND ND ND ND 0.4 ND

fleur de sel 0.82 0.00 0.038 0.024 98.82 ND ND ND ND ND 0.070 5.12 0.035 0.94 0.43 89.18 ND ND ND 0.18 1.8 ND

8.31 0.074 1.10 0.68 84.34 0.20 0.34 ND 0.18 1.1 0.062 1.48 0.040 0.34 0.32 95.62 ND ND ND ND ND ND

10.94 0.028 0.30 0.34 86.30 ND ND ND 0.62 15 0.48 5.04 0.004 0.22 0.33 92.59 ND ND ND ND ND ND

3.04 0.018 0.18 0.83 92.15 ND ND ND 0.13 1.4 ND 4.52 0.003 0.22 0.55 91.76 ND ND ND ND ND ND 9.61 0.13 0.56 3.19 71.94 ND 1.7 ND 3.0 15 0.57

8.07 0.18 0.41 3.16 73.72 ND 0.37 ND 3.1 14 4.4 5.84 0.68 0.53 3.63 72.44 ND ND ND ND 1.2 0.17

2.95 0.00 0.046 0.002 96.84 ND ND ND ND 0.61 0.089 3.90 0.002 0.021 0.34 94.54 ND ND ND ND ND 0.46

6.75 0.00 0.011 0.52 91.04 ND ND ND ND ND 0.26 2.45 0.00 0.014 0.003 97.40 ND ND ND ND ND ND

3.41 0.002 0.15 0.21 95.31 ND ND ND ND 0.60 0.22 3.75 0.00 0.074 0.26 94.73 ND ND ND ND 1.4 0.20

3.65 0.00 0.09 0.30 94.63 ND 0.3 ND ND 4.0 0.2 1.62 0.001 0.023 0.27 97.01 ND ND ND ND 3.2 0.25

3.71 0.001 0.020 0.37 94.63 ND ND ND ND ND 0.23 6.36 0.038 1.08 0.84 85.06 0.044 ND ND 0.49 3.3 0.083

( ) 7.52 0.026 0.46 0.67 87.02 ND ND ND 0.22 3.5 0.10 3.76 0.012 0.40 0.27 93.52 ND ND ND ND 1.0 0.060


12.56 0.14 0.24 2.85 72.44 ND ND ND 4.6 19 2.0 3.96 0.00 0.12 0.35 93.88 ND 0.2 ND ND 1.8 0.2

0.20 0.002 0.049 0.004 99.58 ND ND ND ND ND 0.066 0.14 0.00 0.030 0.003 99.65 ND ND ND ND ND 0.10

0.13 0.00 0.036 0.004 99.62 ND ND ND ND ND 0.088 0.16 0.002 0.028 0.006 99.54 ND ND ND ND ND 0.11



4.87 0.004 0.022 1.03 67.97 ND ND ND ND 3.2 2.6

- 12 -

( ) 0.14 0.002 0.030 0.005 99.55 ND ND ND ND 1.5 1.9

0.60 0.018 0.12 0.071 98.64 ND 1.8 ND ND 5.1 1.9 0.19 0.002 0.056 0.010 99.55 ND ND ND ND 1.1 2.0

0.14 0.00 0.038 0.001 97.89 ND 1.4 ND ND 0.61 ND 0.15 0.00 0.023 0.002 98.98 ND 0.22 ND ND 0.58 0.13

0.17 0.004 0.094 0.013 99.37 ND 0.38 ND ND 1.2 0.65 7.94 0.020 0.29 0.27 89.74 ND ND ND ND 14 2.9

4.46 0.068 0.14 0.54 92.42 ND ND ND 0.25 12 3.6 10.33 0.010 0.18 0.15 88.17 ND ND ND ND 5.3 0.48

7.43 0.029 0.011 0.68 89.18 ND ND ND 0.11 0.69 0.22 6.44 0.006 0.067 0.064 92.85 ND ND ND ND 0.50 0.33

4.90 0.021 0.13 0.31 93.09 ND ND ND ND 3.2 3.6 WHITE MINERAL 4.47 0.022 0.17 0.22 93.66 ND ND ND ND 5.3 1.2


2.77 0.031 0.14 0.23 95.44 ND ND ND ND 5.6 2.2 ARWEN 1.28 0.040 0.076 0.10 97.79 ND ND ND ND 8.0 3.8

MOTHIA ( )

1.42 0.016 0.11 0.18 97.12 ND ND ND ND 8.3 0.75

Natural Salt 2.03 0.040 0.14 0.39 95.57 ND ND ND 0.12 9.1 0.75 1.79 0.24 0.37 0.24 95.35 ND ND ND ND 47 5.4

4.85 0.24 0.10 0.48 92.20 0.052 ND ND ND 66 3.1 7.10 0.020 0.24 0.80 87.90 ND ND ND ND 3.0 0.41

3.88 0.33 0.15 0.57 92.51 0.070 ND ND 0.78 78 9.0

2.70 0.68 0.29 0.45 93.70 0.12 ND ND 1.1 143 7.7

Fin ( ) 2.90 0.31 0.18 0.45 94.08 0.073 ND ND 0.78 65 5.2 3.53 0.070 0.13 0.22 94.75 ND ND ND ND 4.9 4.3

3.91 0.012 0.046 0.064 95.57 ND ND ND ND 4.3 3.5 3.31 0.23 0.062 0.61 93.26 ND 0.29 ND 5.7 39 3.2 1.02 0.50 0.29 0.052 96.81 0.98 ND ND ND 5.5 0.83

2.03 0.24 0.38 0.014 96.32 0.32 ND 1.3 ND 22 1.2 1.32 0.039 0.064 0.08 98.22 ND ND ND ND 9.4 11

1.37 0.030 0.02 0.04 98.35 ND ND ND ND 5.2 4.2 1.02 0.020 0.36 0.093 97.16 0.53 ND ND ND 5.2 1.7


MOTHIA ( )

4.93 0.078 0.31 0.19 93.07 ND ND ND 0.27 8.9 1.2

4.44 0.027 0.13 0.31 93.53 ND ND ND ND 2.5 2.6 5.68 0.34 0.15 0.51 91.07 0.058 ND ND ND 59 5.2

4.02 0.36 0.14 0.55 92.55 0.047 ND ND 0.20 54 5.0

11.43 0.60 0.28 0.44 85.03 0.11 ND ND 0.21 126 7.5

7.74 0.069 0.12 0.68 88.46 ND ND ND 0.26 16 7.4

19.69 0.024 0.32 0.45 76.90 ND ND ND ND 4.9 4.9 17.14 0.060 0.18 1.35 75.67 ND ND ND ND 10 5.1

0.16 0.022 0.032 0.007 99.50 ND ND ND ND 6.0 0.30 0.35 0.004 0.15 0.02 98.86 ND ND ND ND 0.97 ND

( ) Antica Salina

0.50 0.15 0.19 0.051 98.39 ND ND ND 0.17 14 1.6

( ) Antica Sakina

0.57 0.001 0.074 0.064 98.89 ND ND ND ND 1.6 1.0

- 13 -

0.10 0.004 0.037 0.008 99.64 ND ND ND ND 1.2 3.0

0.33 0.80 0.025 0.069 98.53 ND ND ND ND 12 1.7 ( ) 0.28 0.017 0.16 0.016 98.91 ND ND ND ND 13 0.34


ROCK SALT 0.14 0.026 0.22 0.033 98.56 ND ND ND ND 1.0 ND SALE di ROCCIA 0.03 0.001 0.022 0.001 99.87 ND ND ND ND 0.95 0.80

0.22 0.16 0.20 0.02 98.72 0.03 ND ND ND 40 0.54 0.05 0.006 0.031 0.000 99.68 ND ND ND ND 1.5 1.2

0.07 0.016 0.21 0.016 98.97 ND ND ND ND 0.85 ND 0.25 0.075 0.12 0.064 98.50 ND ND ND ND 30 0.44

0.12 0.008 0.066 0.010 99.10 ND ND ND 0.16 2.4 0.061 Sale di roccia (Tre Pini) 0.02 0.004 0.00 0.004 99.92 ND ND ND ND ND 0.69

0.84 0.058 0.76 0.006 96.52 ND ND ND ND 11 0.57 Mineral Harvest SALT 0.72 0.004 0.072 0.016 99.01 ND ND ND 0.30 1.7 0.16 Sale di roccia (Fino) 0.02 0.011 0.043 0.000 99.80 ND ND ND ND 3.5 1.1

0.25 0.002 0.00 0.006 99.47 ND ND ND ND 0.62 1.0 0.02 0.2 1.0 0.1 0.5 0.1

ND( )

- 14 -

2

- 15 -

1.

2.

42

11 53 -1

-1

18 65 2,000

2003 9 10

1,128 56.4

3.

3.1

-1 -2

- 16 -

-1 -2

3/4

2

-3

-4

-3 -4

- 17 -

-3

-4

6

36.2 28.6 3

3.2

-5 -6

-5 -6

19.8

9.5

56.9

3

3.3

-7

-8 -9

- 18 -

-7

-8 -9

-7 -8 9

2 1/3

2

- 19 -

-10

-10

1,128 668 6

55.8

3

6 10

- 20 -

3.4

-11

-11

4

4

-12

- 21 -

-12

4 2

1

-13

- 22 -

-13

- 23 -

4.

1/3

4

- 24 -

1

2001 100 ( -1)

2002 100 ( )

1997 ( 9 ) 5 2002

2

1

( ) (

)

5

800 1000m

- 25 -

- 26 -

1000m 2400m

1500m 3 1000m

( )

3.5 % 3.0 % 3.0 % 3.5 % 3.3 %

3.0 % 3.4 % 3.2 % 3.0 % 2.8 %

3.5 % 3.0 % 3.0 % 3.0 % 3.3 % 3.2 %

3.5 % 3.4 % 3.5 %

2

1997

21

6

- 27 -

3

3

3 3.5 % 97 %

( )

-1 3

-1

- 28 -

-2

-3

( ) -4

-4

( )

(

) -5 7

-5

- 29 -

-6

-7

(

) -8 10

-8

-10-9

- 30 -

(

) -11,12

-11

-12

( )

( )

-13

-13

7

( )

- 31 -

4

21

5

6

- 32 -

86.36 % 0.71 % 0.39 %

0.25 %

72.86 g 3.15 g 1.06 g 0.93 g

97.12 g

0.85 g 1.04 g 0.23 g

7

1

10 g

2.3 g

2.3 g

2.3 2.5421 5.8 g

2 1

38.22 g 100 g

38.21 2.5421

97.12 g

8

- 33 -

3

10km 200 m

- 34 -

- 35 -

1.

( )

2.

120 130 -1

24 50

2 50

0.6%

2002

890

(2002 )

690

120

760

-1

- 36 -

14%

-1

99%

1%

3.

3% 97%

( )

( )

6 7

( )

3.1

8

1970 (9 )

-2 -3

US Geological Survey 2003

63)36

1

US Geological Survey 2003

63)36

-1

1

( )

- 37 -

250 300t/ha120 4,300ha

( 0.4 940 )

-2

1950

-4

3.2

-4

60t/ha120 20,000ha

( 1.8 4,350 )

-3

100t/ha120 1,2000ha

( 2,600 )

1949

( ) 1952

1

2

1955

1960

-5

-6

-5

( )

-6

( ) ( )

- 38 -

( ) 78%

75%

-6

-7

( )

-8

1972

-8

-7

+ -+ -

- 39 -

- 40 -

-9 1

300ha

65

1965 100

1985

640

4.

1905

( )

1996 7 *)

4.1

-8

-9

*)

- 41 -

(

) ( )

( )

1) ( )

( -10)

1 2 2

1 3,000 4,000m3

1 7m

430 570m2 5m 5m 17

23 2

-10 ( )

- 42 -

-6

0.3 0.7mm

0.5 0.7mm 1mm

1 1

-11

6 7

430 570m2 1/6 1/7

( ) 2 1/2 1/5 1

2) ( )

30

-11 ( )

- 43 -

30

5

-12 -13

(

)

3) ( )

-6

30 90%

10%

( )

-12 -13

- 44 -

-14

( )

(

*) )

( )

-2

( )

4.5% 30%

( )

-15

-14

*) ( )

-2 ( , 42, p.32 (1988))

[%]

15.51 0.37 1.07 0.60 11.90 2.60 9.00 5.60

4.50 5.20 16.20 8.60

4)

5)

( )

- 45 -

4.2

BSE

( )

( )

1)

( ) ( )

- 46 -

- 47 -

-15

( )

1

-15 ( )

2)

( )

CODEX ( ) 5 (

) 2005 4

2005 10

(1)

(2)

15 16 18

370

(3)

11

370

(4)

11

370

(5)

- 48 -

- 49 -

-3

(

)

( , 112, p.262 (2003))

-3

PCB

1,3-

1,2-

1,1-

-1,2-

1,1,1-

1,1,2-

2003

2006 4

-3 3

800

3

- 50 -

- 51 -

4.3

ppm ppb ppm

1ppm 1000kg 1g

1ppb 1/1000

-16

1 181 H 2 He

2 13 14 15 16 173 Li 4 Be 5 B 6 C 7 N 8 O 9 F 10 Ne

11 Na 12 Mg 13 Al 14 Si 15 P 16 S 17 Cl 18 Ar3 4 5 6 7 8 9 10 11 12

19 K 20 Ca 21 Sc 22 Ti 23 V 24 Cr 25 Mn 26 Fe 27 Co 28 Ni 29 Cu 30 Zn 31 Ga 32 Ge 33 As 34 Se 35 Br 36 Kr

37 Rb 38 Sr 39 Y 40 Zr 41 Nb 42 Mo 43 Tc 44 Ru 45 Rh 46 Pd 47 Ag 48 Cd 49 In 50 Sn 51 Sb 52 Te 53 I 54 Xe

55 Cs 56 Ba 57 71 72 Hf 73 Ta 74 W 75 Re 76 Os 77 Ir 78 Pt 79 Au 80 Hg 81 Tl 82 Pb 83 Bi 84 Po 85 At 86 Rn

87 Fr 88 Ra 89 103

57 La 58 Ce 59 Pr 60 Nd 61 Pm 62 Sm 63 Eu 64 Gd 65 Tb 66 Dy 67 Ho 68 Er 69 Tm 70 Yb 71 Lu

89 Ac 90 Th 91 Pa 92 U 93 Np 94 Pu 95 Am 96 Cm 97 Bk 98 Cf 99 Es 100 Fm 101 Md 102 No 103 Lr

ISO/IEC17025

-16 ( )

- 52 -

5.

2 ( -17 -18) -17

(Harvester)

-18 (mining)

-17 ( ) -18 ( )

the salt industry center of japan - shiojigyo.com · "á 4 2005 11 ¬29 ã9Ô + ã9Õ 13 (30...

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