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    WATERENVIRONMENT

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    The ExtraordinaryThe Extraordinary

    Properties of WaterProperties of Water

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    WaterWater

    A water molecule (H2O), ismade up of threethree atoms one oxy!en and two hydro!en"

    H

    HO

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    What areWhat arethethe

    PropertiesPropertiesof Water#of Water#

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    Properties of WaterProperties of Water

    At sea le$el, pure waterAt sea le$el, pure water %oils at%oils at&'' &'' andandfree*es at ' free*es at ' ""

    TheThe%oilin! temperature of water%oilin! temperature of waterdecreases at hi!her ele$ationsdecreases at hi!her ele$ations(lower atmospheric pressure)"(lower atmospheric pressure)"

    +or this reason, an+or this reason, an e!!e!!will taewill taelon!er to %oillon!er to %oil at hi!her altitudesat hi!her altitudes

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    Water is -ess .ense as aWater is -ess .ense as a

    /olid/olid 0ce is less dense0ce is less denseas a solid than as

    a li1uid (ice floats)

    -i1uid water has hydro!en %ondshydro!en %ondsthat are constantly %ein! %roenconstantly %ein! %roen

    and reformed"and reformed"

    +ro*en water+ro*en waterforms a crystalliecrystallie

    latticelatticewhere%y molecules are set

    at fixed distances"

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    Water is -ess .ense as aWater is -ess .ense as a/olid/olid

    Which is ice and which is water#Which is ice and which is water#

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    Acids, 2ases and pHAcids, 2ases and pH

    One water moleculeOne water molecule in 33' millionin 33' millionnaturallynaturally dissociatesdissociatesinto a Hydro!eninto a Hydro!en0on0on (H4)(H4) and a Hydroxide 0onand a Hydroxide 0on (OH)(OH)

    Hydro!en 0on Hydroxide 0onHydro!en 0on Hydroxide 0on

    AcidAcid sese

    H2O H+ + OH

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    The pH /caleThe pH /cale

    0ndicates the concentration of Hconcentration of H44ionsions5an!es from ' 6 &7' 6 &7pH of 8 is neutral8 is neutral

    pH ' up to 8 is acid' up to 8 is acid 9 H4pH a%o$e 8 6 &7a%o$e 8 6 &7is %is %asic9 OHEach pH unit represents a factor of

    &':&':chan!e in concentrationpH ; is &' x &' x &' (&''') stron!erpH ; is &' x &' x &' (&''') stron!erthan a pH of

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    AcidsAcids

    /tron!/tron!AcidsAcids

    ha$e a pHha$e a pHofof &;&;ProduceProduce

    lots oflots ofH H44 ionsions

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    2ases2ases

    /tron!/tron!asesases ha$ea pH of &&&&to &7to &7

    ontain lotslotsof OHof OHionsionsand fewerH4 ions

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    2uffers2uffers

    Wea acids or %ases that react withWea acids or %ases that react withstron! acids or %ases to pre$entstron! acids or %ases to pre$entsharp, sudden chan!es in pHsharp, sudden chan!es in pH(neutrali*ation)"(neutrali*ation)"

    Produced naturally %y the %odyProduced naturally %y the %ody totomaintain homeostasismaintain homeostasis

    Weak AcidWeak Acid Weak BaseWeak Base

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    Water: The Facts

    Water is possibly the most important

    compound in living organisms.

    Water consists of 1 atom of oxygen

    combined with 2 atoms of hydrogen.

    Water makes up 70 to 9 percent of most

    organisms.

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    What are the characteristics of

    water?

    1. Water is polar.

    2. Water molecules attract other water

    molecules. !his property is cohesion.

    ". Water displays adhesion.

    #. Water expands when it free$es.

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    Water is Polar

    % polar molecule hasan une&ualdistribution ofcharge'eachmolecule has a

    positive end and anegative end.

    %ll polar substancesare attracted to other

    polar substances.

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    Why is this polarity important?

    (olar water molecules attract other

    water molecules as well as ions and other

    polar molecules.)ecause of this attraction* water can

    dissolve many ionic compounds* such as

    salt and polar molecules like sugar.

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    How do water molecules

    attract?Water molecules form hydrogen bondshydrogen bonds.

    +ydrogen bonds are weak bonds that

    form between the positively chargedhydrogen atoms of one water moleculeand the negatively charged oxygen atomsof another water molecule.

    !his ability of water molecules to sticktogether is called cohesioncohesion.

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    Also due to its polarity

    Water displays the property of adhesionadhesion

    which is the ability of one substance to

    cling to another.,xamples of adhesion include water-s

    ability to creep up thin tubes. (lants

    show this property when they send waterfrom the soil up through their tissues.

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    And finallywater expands when it

    freezes.

    )ecause of this

    property* ice is less

    dense than li&uidwater.

    !his property can be

    seen when ice forms

    and floats on thesurface of a pond.

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    Auatic !iomesMarine

    cean

    ,stuary

    Fresh Water

    /ivers and treams otic3akes and (onds entic3

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    "ceans

    alinity averages " ppt full strength sea water3.4ue to high concentrations of sodium and chloride

    cean is more than salt and water* but most ocean waters

    are very poor in nutrients

    (hosphate* nitrate* ammonium* iron ceans cover 5716 of ,arth* but only account for 06 of

    the ,arth-s primary production.

    )iological deserts not limited by water* but by nutrients

    nlike terrestrial biomes* production is not higher at e&uator and

    lower at the tropics 8respond to nutrient concentrations like

    upwellings.

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    "ceansoastal regions are much more productive

    than non'coastal areas.

    /ich nutrient input from coastal rivers

    :ost of the worlds great fisheries come from

    the continental shelf

    !oo many nutrients can lead to algal blooms*

    which may deoxygenate the watereutrophication3

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    #ome Fish $ife History

    Anadromous8 fish that spend their adult

    life in salt water but spawn in freshwater

    almon* striped bass* %merican shad

    Catadromous8 fish that spend their adult

    life in freshwater but spawn in saltwater%merican eel

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    %stuariesWhere the river meets the seaometimes classified freshwater* sometimes

    classified marine

    :ost productive biome on ,arthupport a diverse fauna including a variety

    of worms* oysters* crabs* and waterfowl.

    erve as nursery habitat for manyorganisms.

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    &arsh Types

    ;resh water marshsalinity < 1.0 ppt.(lants are not salt tolerant and include maidencane* bulltongue*

    alligatorweed* cattails* and spikerush

    =ntermediate marshsalinity averages "." ppt.

    (lants are slightly salt tolerant and include spikerush* three'corner

    grass* arrowhead* cordgrass* wiregrass* roseau cane* and deer pea

    )rackish marshsalinity averages about > ppt.

    typically dominated by cordgrass or wiregrass

    alt marshsalinity averages about 1? ppt.

    oyster grass is common* but few other plant species can survive

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    Freshwater Marsh

    Brackish MarshIntermediate Marsh

    Salt Marsh

    http://stahl.ce.washington.edu/projects/marsh.jpg
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    'i(ers and #treams

    @enerally represent the excess of precipitation on landareas over evaporation from them.

    (recipitation that falls is either evaporated* transpirated*

    enters the ground water supply* or flows down rivers

    ;low is down'hill and varies seasonally/elated to rainfall and iceAsnow melt

    )eginning of a river B thesourceand the end of a river B

    the mouth

    4ischarge' volume of water passing a given point duringa period of time

    hannel Width C 4epth C Delocity

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    'i(ers and #treams;low velocity is important in determining abiotic

    and biotic components.;low related to slope and precipitation

    ediment type* current strength

    nly certain organisms can withstand strong flow

    !he faster the flow* the more material can betransported in the water

    :aterials are transported by running water in

    three principal states4issolved matter

    uspended solids

    )ed load

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    &a)or 'i(ers of The World

    NameDischarge103m3/sec

    Length103km

    Drainage Area106km2

    Ama!n" S!#th America 212$%0 6$%% &$'(

    )!ng!" A*rica 3+$6& %$'0 %$01

    ,anges-Brahma.#tra" India 3($&0 2$+0 1$62angte" )hina 21$(1 &$+( 1$+%

    enisei" SS 1'$3+ &$&% 2$&+

    Mississi..i N!rth" America 1'$30 6$02 3$22

    Mek!ng" Asia 11$0% %$00 0$(0

    Nile" A*rica 3$10 6$6& 3$3&

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    Water Pollution * +leanup

    11 June 2010 Water-Pollution.ppt 31

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    Water pollution

    lasses of pollution* pollutants(athogens* parasites

    xygen'demanding wastes

    =norganic chemicals=norganic plant nutrients

    rganic chemicals

    ediments

    /adioactive material

    +eat thermal pollution3

    11 June 2010 Water-Pollution.ppt 32

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    Water pollution

    (athogens* parasites

    sually from sewage* feedlots* slaughterhouses

    Diruses)acteria cholera* ...3

    oliform bacteria usually notpathogenic*

    sed as indicators of pollution

    (roto$oan parasites @iardia*

    ryptosporidium3

    11 June 2010 Water-Pollution.ppt 33

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    Water pollution

    xygen'demanding wastes

    rganic materials from sewage*

    slaughterhouses* etc.

    4ecomposed by bacteria

    )acteria re&uire* consume dissolved oxygen

    E)iological xygen 4emandF )43

    :easure of water &ualityow in pristine water

    11 June 2010 Water-Pollution.ppt 34

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    Water pollution

    =norganic chemicals:ostly from industry

    +eavy metals

    ead* arsenic* mercury* copper ions* etc.

    %mmonia

    %cidsulfuric acid* nitric acid from acid deposition

    %lso from industry

    )ases caustic alkalines3

    11 June 2010 Water-Pollution.ppt 35

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    Water pollution

    =norganic plant nutrients fertili$ers3

    ;rom agriculture* lawns G gardens

    eaching into groundwater

    /un'off into surface waters

    timulate growth of algae algal blooms3*

    eutrophication

    %lgae die* sink* become oxygen'demandingwaste

    11 June 2010 Water-Pollution.ppt 3

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    Water pollution

    =norganic plant

    nutrients fertili$ers3

    ;rom agriculture*lawns G gardens

    ,utrophication

    Hatural process

    %ccelerated by excess

    nutrient input

    %lgae die* sink*

    become oxygen'

    demanding waste

    11 June 2010 Water-Pollution.ppt 3!

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    Water pollution

    rganic chemicalsfrom industry* restaurants* cars* households*

    farms

    @asoline* oil,ngine coolant ethylene glycol3

    olvents

    4etergents

    (esticides insecticides* herbicides* fungicides

    (olychlorinated )iphenyls ()s3

    11 June 2010 Water-Pollution.ppt 3"

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    Water pollution

    ediments,rosion from construction sites* streets G

    roads* farms* sewage

    4ense sediments sink* accumulate edimentation in reservoirs

    ess dense sediments may stay in water

    /educe clarity increase turbidity3

    /educe light penetration G photosynthesis

    11 June 2010 Water-Pollution.ppt 3#

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    Water pollution /adioactive material

    ;rom spills* waste from atomic weapons production

    +anford* Washington

    avannah /iver (lant* outh arolina

    ;rom nuclear power plants minor3 losely regulated

    +eat Ethermal pollutionF3

    +eated water from cooling of electrical generating

    e&uipment

    %lters ecosystem of river* lake

    11 June 2010 Water-Pollution.ppt 40

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    Water pollution Hon'point and (oint sources

    11 June 2010 Water-Pollution.ppt 41

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    ,round water pollution (ollution of a&uifers Hon'point and (oint sources

    (ollutants slow to break down in cold G dark

    11 June 2010 Water-Pollution.ppt 42

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    Water pollution

    =n lakes* reservoirs

    ow flow rate* long

    residence time

    4eep* stratification

    (ollutants can

    accumulate*

    concentrate

    11 June 2010 Water-Pollution.ppt 43

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    Water pollution

    =n streams* rivers +igher flow rate*

    dilution effect

    !urbulent Well mixed

    Well oxygenated

    ong riverbanks*

    contact with land ubIect to non'point

    source pollutants

    ften flow near cities

    11 June 2010 Water-Pollution.ppt 44

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    Water pollution

    (revention)etter to H! pollute than to clean up laterlean up is expensive

    lean up is never complete

    11 June 2010 Water-Pollution.ppt 45

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    #ewa-e Treatment

    (rimarycreens and settling tanks remove grit G

    suspended organic matter.

    econdaryewage aeratedJ aerobic bacteria consume

    organic mattereave dissolved inorganics* H"* (#* etc.

    !ertiary;ilters most dissolved inorganics and remaining

    dissolved organic compounds

    11 June 2010 Water-Pollution.ppt 4

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    #ewa-e Treatment

    (rimarycreens and settling tanks remove grit G

    suspended organic matter.

    11 June 2010 Water-Pollution.ppt 4!

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    #ewa-e Treatmentecondaryewage aeratedJ aerobic bacteria consume organic matter

    eave dissolved inorganics* H"* (#* etc.

    11 June 2010 Water-Pollution.ppt 4"

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    #ewa-e Treatment

    !ertiary;ilters most dissolved

    inorganics andremaining dissolved

    organic compoundsan be done

    biologically in wetlandsHatural

    %rtificial

    11 June 2010 Water-Pollution.ppt 4#

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    Types and #ources of Water Pollution

    Point sources

    Nonpoint sources

    Biologicaloxygendemand

    Water $ualitWater $ualit

    WaterWater

    QualityQuality

    GoodGood 8-98-9

    Do (ppm) at 20CDo (ppm) at 20C

    SlightlySlightly

    pollutedpolluted

    oderatelyoderately

    pollutedpolluted

    !ea"ily!ea"ily

    pollutedpolluted

    Gra"elyGra"ely

    pollutedpolluted

    #$%-8#$%-8

    &$'-#$%&$'-#$%

    elo &$'elo &$'

    elo &elo & g$ &3&

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    Point and onpoint #ources

    NNIN4 S)5S

    ran streets

    S##rande7el!.ment

    8astewatertreatment.lant

    #ral h!mes

    )r!.land

    Fact!r9

    Animal *eedl!t

    IN4S)5S

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    Water pollution

    )acteria* Diruses* (roto$oa* (arasitic worms

    xygen demanding substances

    =norganic plant nutrientsrganic chemicals

    ediment or suspended matter

    !hermal pollution@enetic pollution

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    :!!.lankt!n0$123..m

    h9t!.lankt!n0$002& ..m

    8ater0$000002 ..m

    ;erring g#ll12% ..m

    Lake tr!#t%$(3 ..m

    ;erring g#ll eggs12% ..m

    iologi*al

    ag+i,i*atio+

    iologi*al

    ag+i,i*atio+

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    Pollution of #treams

    O&%'en (a' )ur*eO&%'en (a' )ur*e

    Fig$ 20-&

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    Pollution of $a/es

    EutrophicationDischarge !* #ntreated

    m#nici.al sewage

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    Fi-. 01230

    Auifer

    Water well

    Migratingvapor phase

    Contaminant plume moveswith the groundwater

    Free gasolinedissolves ingroundwater(dissolvedphase)

    roundwater!low

    Waterta"le

    asolineleakage plume(li#uid phase)

    $eakingtank

    Bedrock

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    ,roundwater Pollution: +auses

    )!al stri.mine r#n!**

    #m.ingwell

    8aste lag!!n

    Accidentals.ills

    ,r!#ndwater*l!w

    )!n*ined a@#i*er

    Discharge

    Leakage *r!m *a#lt9casing

    ;aard!#s waste inecti!n wellesticides

    ,as!linestati!n

    B#ried gas!lineand s!l7ent tank

    Sewer

    )ess.!!lse.tic tank

    De-icingr!ad salt

    0nc!

    n*ine

    d*res

    hwate

    ra@#

    i*er

    )!n*ine

    d*res

    hwate

    ra@#

    i*er

    8ater .#m.ingwell

    Land*ill

    Fig$ 20-11

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    ,roundwater Pollution Pre(ention

    Monitoring a#ui!ers

    %trictl& regulating

    ha'ardous waste disposal

    %toring ha'ardous materials

    a"ove ground

    Construction sites

    .r"an sprawlBacteria and viruses!rom

    Cities-oic metalsand oil !rom

    0ndustr&1itrogen oides!rom autos and

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    Fi-. 032314 p. 515

    Health& 'oneClear o&gen*richwaters promote growth

    o! plankton and sea grassesand support !ish+

    O&gen*depleted 'one%edimentation and algaeovergrowth reduce sunlight

    kill "ene!icial sea grasses useup o&gen and degrade ha"itat+

    ,ed tidesEcess nitrogen causeseplosive growth o!toicmicroscopic algaepoisoning !ish andmarine mammals+

    Farms

    ,uno!! o! pesticides manure and!ertili'ers adds toins and ecessnitrogen and phosphorus+

    -oic sediments

    Chemicals and toicmetals contaminateshell!ish "eds killspawning !ish andaccumulate in the tissueso! "ottom !eeders+

    %ediments are washed intowaterwa&s choking !ish andplants clouding waters and"locking sunlight+

    !romsewers and septictanks contaminateshell!ish "eds

    O&gen*depleted'one

    Closed

    "each

    and oil !romstreets andparking lotspollute waters/

    !rom autos andsmokestackstoic chemicalsand heav& metals ine!!luents !low into"a&s and estuaries+

    Closedshell!ish "eds

    Fi + 23*45

    'educin- Water Pollution throu-h

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    'educin- Water Pollution throu-h

    #ewa-e Treatment

    (rimary and econdary sewage treatment.

    Fi ure 01236Fi ure 01236

    Technolo-ical Approach: 7sin- Wetlands

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    Technolo-ical Approach: 7sin- Wetlands

    to Treat #ewa-e88

    ((

    %& centimeter

    la9er !* limest!negra7el c!ated with

    dec!m.!sing acteriaFirst c!ncrete .!!l Sec!nd c!ncrete .!!l

    SeageSeage

    Wetla+d typeWetla+d type

    pla+tpla+tWetla+d typeWetla+d type

    pla+tpla+t

    .reated.reated

    aterater

    ,l 9 l " tl / #t P ll ti i l i

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    ,lo9al "utloo/: #tream Pollution in e(elopin-

    +ountries

    Water in many

    of central

    hinaKs riversare greenish

    black from

    uncontrolled

    pollution by

    thousands of

    factories.

    Fi ure 012;Fi ure 012;

    What Can 6ou 7o8

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    Water 9ollution

    : Fertili'e garden and &ard plants with manure or compost

    instead o! commercial inorganic !ertili'er+

    : Minimi'e &our use o! pesticides+

    : 7o not appl& !ertili'er or pesticides near a "od& o! water+

    : row or "u& organic !oods+

    : 7o not drink "ottled water unless tests show that &our tap

    water is contaminated+ Merel& re!ill and reuse plastic "ottles

    with tap water+

    : Compost &our !ood wastes+

    : 7o not use water !resheners in toilets+

    : 7o not !lush unwanted medicines down the toilet+

    : 7o not pour pesticides paints solvents oil anti!ree'e or other

    products containing harm!ul chemicals down the drain or onto