THE ADHESION SOCIETY

PROCEEDINGS

of the

Eighteenth Annual Meeting

Xas,1995

HILTON HEAD, SC19-22 FEBRUARY, 1995

J. W. HOLUBKA, EDITOR

LIBRARY OF CONGRESS NUMBER- 95,75757UNIVERSITAT^;

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THE ADHESION SOCIETY

PROGRAM OF THE 18TH ANNUAL MEETING

SUNDAY EVENING

4:00 • 6:00 REGISTRATION

6:00 • 7:00 PRESIDENT'S RECEPTION

7:00 - 7:45 BUSINESS MEETING

MONDAY MORNING

8:00 - 8:15 * MEETING OPENING REMARKSJames P. Bell - President erf Adhesion SocietyJoseph W. Holubka -1995 Program Chairman

MONDAY MORNING - SESSION 1

The Adhesion Society Award for Excellence in Adhesion Science SessionSponsored by the 3M Company. Awardee: Professor Jacques Schultz

Session Chair: James P. Bell, University of Connecticut

8:15 - 8:30 3M Award Presentation to Dr. Jacques SchultzAlPocius,3M

8:30 - 9:00 "THE RELATIONSHIP BETWEEN SURFACEENERGETICS AND ADHESION SRTENGTH", ProfessorJacques Schultz, University of Haute Alsace, Centre National de laRecherche Scientifique, France, p . l

9:00 - 9:30 "THE ROLE OF ADHESION PROMOTERS ON THESTRUCTURE OF THE INTERPHASE", M. Grunze.T.Strunskus and C. Woll, Angewandte Physikalische Chemie derUniversitat Heidelberg, Germany, p. 5

9:30 • 10:00 Break

10:00 - 10:30 "VISCOELASTICITY AND KINETICS OF WETTING ONRUBBERY MATERIALS ", Alain Carre and Martin E R.Shanahan, Centre de Recherche Corning Europe and Centre National dela Recherche Scientifique, France, p .8

10:30... 11:00 "SURFACE AND INTERFACIAL STUDIES OF PLASMA-MODIFIED COMPOSITES". Joannie W. Chin and James P.Wightman, Department of Chemistry. Virginia Tech.. USA. p . 11

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11:00 - 11:30 "ANALYSIS OF THIN CYANLRATE PREPOLYMERFILMS ON SOLIDS AS A MODEL OF THE ADHESIVEINTERPHASE". W. Possart. S. Dieckhoff. D. Fanter. T. Gesang.A. Hartwig, R. Hoper. V. Schlett. and O.-D. Hennemann. FraunhoferInstitute of Applied Materials Research. Germany, p. 15

11:30 - 12:00 "THE DIRECT MEASUREMENT OF SURFACE FORCESBETWEEN SOLID POLYMER FILMS AND ITSRELATIONSHIP TO POLYMER SURFACE ANDADHESION SCIENCE", Alphonsus V. Pocius. 3M AdhesiveTechnologies Center: and V. S. Mangipudi and M. Tirrell. Departmentof Materials Science and Chemical Engineering. University ofMinnesota, USA. p. 18

12:00 - 1:30 LUNCH

MONDAY AFTERNOON - SESSION 2A

NEW MATERIALS FOR ADHESIVES AND COATINGS #1

Session Chair: Terry St Clair, NASA, USA

1:30 - 1:40 Opening CommentsTerry St. Clair, NASA, USA

1:40 - 2:10 "ADHESIVE PROPERTIES OF CUREDPHENYLETHYNYL TERMINATED IM1DE OLIGOMERS",B. J. Jensen, R. G. Bryant, J. G. Smith, and P. M. Hergenrother,NASA Langley Research Center, USA.

2:10 - 2:40 "ACRYLIC ADHESION TO POLYOLEFIN*. Jeffrey T. Fields.Andrew Garton, and James P. Bell, University of Connecticut. USA.p. 21

2:40 - 3:10 "VINYLPHOSPHONIC ACID ANODIZING ALUMINUMFOR STRUCTURAL ADHESIVE BONDING", G. A.Nitowski. Aluminum company of America and K. Wefer and J. G.Dillard, Virginia Tech, USA. p. 24

3:10 - 3:30 BREAK

3:30 - 4:00 "USING POLYMERIC BINDERS IN SUSPENSIONPREPREGGING AND TAILORING FIBER/MATRIXADHESION FOR CARBON-REINFORCEDCOMPOSITES", S. Gardner. A. Gonzalez. R. M. Davis. S. Case. J.J. Lesko, and K. L. Reifsnider, Department of Chemical Engineering,Virginia Tech, USA. p.27

4:00 - 4:30 "FUNCTIONALIZED BLOCK COPOLYMERS ASADHESION PROMOTERS", Michael S Kent, and RandallSaunders. Sandia National Labs. USA. p. 29

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4:30 - 5:00 "SYNTHESIS AND PROPERTIES OF THEPHENYLETHYNYL-TERMINATED POLYIMIDE LARC-PETI-5". Roberto J. Cano and Brian J. Jensen. NASA LangleyResearch Center. USA. p. 32

MONDAY AFTERNOON - SESSION 2B

MODELLING OF ADHESION PROCESSES

Session Chair: Anna Balazs, University of Pittsborg

1:30 - 1:40 Opening CommentsAnna Balazs, University of Pittsburg.

1:40 - 2:10 "ADHESION AT METAL-CERAMIC INTERFACES: ANELECTROSTATICS - BASED MODEL", J. W. Mintmire and F.H. Streitz, Naval Research Laboratory, USA. p. 35

2:10 - 2:40 "A COMPUTER MODEL FOR WETTING HYSTERESIS",S. P. Wesson and A. Mahale, TRI Princeton, USA. p. 38

2:40 - 3:10 "METALLIZATION OF POLYIMIDE SURFACES: STILLNO CONSISTENT MODEL", M. Grunze, T. Strunskus, and Ch.Woll, Angewandte Physikalische Chemie, and Technische Fakultat derChristian-Albrechts-Universitatzu Kiel, Germany, p. 41

3:10 • 3:30 BREAK

3:30 - 4:00 "SPECIAL ADHESIVE FINITE ELEMENTS FORMODELLING ADHESIVELY BONDED JOINTS ANDCRACK-PATCH REPAIRS IN TWO- AND THREE-DIMENSIONS", M. W. Taylor, Raul Andruet, and D. A. Dillard,Department of Engineering Science and Mechanics, Virginia Tech.,USA. p. 45

4:00 - 4:30 "ATOMIC SCALE ADHESION, FRICTION, AND WEARIN HYDROCARBON SYSTEMS", J. A. Harrison, and M. D.Perry, Chemistry Department, United States Naval Academy; R. J.Colton and C. T. White, Naval Research Laboratory; and D. W.Brenner, Department of Material Science and Engineering, NorthCarolina State University, USA. p. 47

4:30 - 5:00 "ADHESION MECHANICS DURING LOW SPEEDNORMAL IMPACT OF SPHERICAL "ROCKS" INTOMULTILAYERED PAINTED STEEL SUBSTRATES". A. C.Ramamurthy and Joseph W. Kolubka, Ford Motor Company; andDennis Mihora, FM Analysts, USA. p.52

IX

MONDAY AFTERNOON - SESSION 2C

SMALL PARTICLE ADHESION #1

Session Chair: Don Rimai, Eastman Kodak Company

1:30 - 1:40 Opening CommentsDon Rimai, Eastman Kodak Company

1:40 - 2:10 "TIME DEPENDENT ADHESION INDUCEDPHENOMENA: VISCOELASTIC CREEP OF APOLYMERIC SUBSTRATE OVER RIGID PARTICLES", D.S. Rimai, L. P. DeMejo, J. H. Chen, R. C. Bowen and T. H. Mourey.Eastman Kodak Company. USA. p.56

2:10 - 2:40 "PARTICLE GENERATION IN CORROSIVE GASDELIVERY SYSTEMS", S. Krishman. S. Grube. A. Tudhope andO. Laparra. Ultra Clean Technology, and VLSI Technology, Inc. USA.p.59

2:40 - 3:10 "ENHANCED REMOVAL OF RADIOACTIVE PARTICLESFROM CIRCUIT BOARDS BY FLUORINATEDSURFACTANT SOLUTIONS", R. Kaiser, C. S. Yam and O. K.Harling, Entropic Systems Inc, and Department of NuclearEngineering, MIT, USA. p. 62

3:10 - 3:30 BREAK

3:30 - 4:00 "EFFECT OF SURFACE MOISTURE ON THEPOLARIZATION OF INDIVIDUAL GLASS PARTICLES",T. N. Tombs and T. B. Jones, Eastman Kodak Company and theDepartment of Electrical Engineering, University of Rochester, USA.p. 66

4:00 - 4:30 "PARTICLE BOUNCE OR CAPTURE: THE ROLE OFADHESION FORCES", Bart Dahneke, Eastman Kodak Company,USA.

4:30 - 5:00 "MEASUREMENT OF ADHESION BETWEENPOLYMERS: INFLUENCE OF INTERFACIALCHAINS", M. Deruelle, V. S. Mangipudi, M. Tirrell. Department of

Chemical Engineering and Materials Science. University of Minnesota,and L. Leger, Laboratoire de Physique de la Matiere Condensee,

College de France. URA CNRS, France, p. 69

5:00 - 5:30 "HYDROPHOBIC COAGULATION AND FLOATATIONOF ULTRA FINE COAL", Zhiwei Jiang. Yingjia Kang. andYouzhu Li, China University of Mining and Technology, China, p. 72

MONDAY EVENING - POSTER SESSION - 8:00 -10:00

Session Chair: John Dillard, Virginia Tech

1. "A STUDY OF THE EFFECTS OF LOW POWER PLASMATREATMENT ON CARBON BLACK, GRAPHITE AND HIGHLYORIENTATED PYROLYTIC GRAPHITE (HOPG) STRUCTURES", S.O'Kell amd C Jones, Department of Materials, Science and Engineering, Universityof Liverpool, England, p. 75

2. "A STUDY OF THE INTERPHASE REGION IN CARBON FIBREEPOXY COMPOSITES USING DYNAMIC MECHANICALTHERMAL ANALYSIS", K. Atkinson and C. Jones, Department of Materials,Science and Engineering, University of Liverpool, England, p. 77

3. "PLASMA-POLYMERIZED FILMS: ADHESIVE BONDINGAPPLICATIONS", L. Deshayes, M. Charbonnier, F. Gaillard, J. Baborowski,and M. Romand, CNRS, France, p. 79

4. "PLASMA-PRETREATMENT OF POLYMERS: APPLICATION TOTHEIR METALLIZATION BY AN ELECTODELESS PROCESS", M.Alami, M. Charbonnier, and M. Romand, CNRS, France, p. 83

5. "USE OF EVANESCENT WAVES FT-IR SPECTROSCOPY FOR IN-SITU STUDY OF THE DEGRADATION OF POLYMER-SUBSTRATESYSTEMS", I. Linossier, F. Gaillard and M. Romand, CNRS, France, p. 86

6. "INFLUENCE OF CHEMICAL ELECTROCHEMICAL ANDPHYSICAL SURFACE TREATMENTS OF AISI 304L ON ITSREACTIVITY - CONSEQUENCES ON ADHESION TO EPOXYRESINS ", F. G. Gaillard, E Peiilex and M. Romand, CNRS, France, p. 89

7. "ADHESION OF RUBBER TO STEEL: THE USE OF PLASMAPOLYMERIZED PRIMER FILMS", Y. M. Tsai, F. J. Boerio, and W. J. vanOoij, Department of Materials Science and Engineering, University of Cincinnati;and Dong K. Kim, Goodyear Tire and Rubber Company, USA. p. 92

8. "PLASMA POLYMERIZED SILICON CONTAINING PRIMERS FORALUMINUM", C. E. Taylor, I Segall and F. J. Boerio, Department of MaterialsScience and Engineering, University of Cinsinnati; and D. J. Ondms. R. A. Dickieand S. Ward, Ford Motor Company, USA. p.95

9. "CARBON FIBER - POLYMER MATRIX ADHESION IN HIGHPERFORMANCE COMPOSITES", H. Zhuang and J. P. Wightman.Department of Chemistry. Virginia Polytechnic Institute and State University. USA.p. 98

10. "TIME AND TEMPERATURE DEPENDENT FRACTURE OFSTEEL/EPOXY JOINTS", K. L. Urban, M. D. Rakestraw, T. Chang, N. E.Shephard, D. A. Dillard, J. G. Dillard. and T. C. Ward, Department of EngineeringScience and Mechanics, Virginia Tech, USA. p . 100

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11. "CONTROL OF TOUGHENED POLYCYANLRATE MORPHOLOGYUTILIZING GRADIENT TEMPERATURE CURING". D. S. Porter. C.A. Williams. S. A. Srinivasan. J. E. McGrath and T. C. Ward. Department ofChemistry. Virginia Tech. USA. p. 102

12. "INTERFACIAL CHARACTERIZATION OF CTRE AND CTFEBLENDS WHEN USED AS HOT MELT ADHESIVES AND THEIMPLECATIONS ON ADHESION AND FUNCTIONALCHARACTERIZATION", J. L. Longhenry and B. J. Love, Department ofMaterials Science and Engineering, Virginia Tech. USA. p. 104

13. "ASPECTS OF DENATURING IN ADHESIVE BONDING TODENTIN", R. R. Hamandi and B. J. Love. Department of Materials Science andEngineering, Virginia Tech, USA. p. 106

14. "ACCELERATED DEBONDING TEST TO EVALUATE DURABILITYOF METAL/ADHESIVE BONDS". T. Chang, Y. H. Lai, N. E Shephard, EA. Sproat and D. A. Dillard, Virginia Tech. USA. p. 108

15. "NEW INVESTIGATIONS INTO FLUORINATED CELLULOSEFIBERS ", Ulli Becker and Wolfgang Glassser, Wood Science and Forest ProductsResearch, Virginia Tech, USA. p. 110

16. "SPLICING OF SAPPHIRE AND SILICA FIBER", A. Barnes. S.Gollapudi, R. May, and R. Clais, Bradley Department of Electrical Engineering,Virginia Tech, USA. p. 112

17. "DURABILITY OF ADHESIVELY BONDED TITANIUM", S. A. Risch,B. L. Holmes, G. S. Frick, J. P. Wightman, and J. G. Dillard, Department ofChemistry, Virginia Tech, USA. p. 114

18. "AN EXTENSION OF THE JKR TECHNIQUE TO DESCRIBEADHESION HYSTERESIS IN MODIFIED PDMS", Susanne Perutz,Pascal Silbersan, F. I. Kramer and C. Cohen, Cornell University, USA. p. 116

19. "MODEL EXPERIMENTS ON ELASTOMER-SOLID ADHESION", Y.Marciano, M. Deruelle, M Tirrell, H. Hervet, and L. Leger, CNRS, France; andDepartment of Chemical Engineering and Materials Science, University ofMinnesota, USA. p. 119

20. "INTERACTION OF FUNCTIONAL GROUPS IN POLYMERS WITHSTEEL SURFACES", I. Sutherland, P. Carpenter. R. J. Heath and B. Pearson.Department of Chemistry, Loughborough University, England, p. 121

21. "ADSORPTION OF POLYCYANURATE FILMES ON SILICONWAFERS AND ALUMINUM SUBSTRATES STUDIED BY XPS", S.Dieckhoff, V. Schlett, W. Possart, and 0. D. Hennemann. Fraunhofer-Institut furAngewandte Materialforschung, Germany, p. 123

22. "A COMPARISON OF SCANNING FORCE MICROSCOPY ANDELLIPSOMETRY FOR THICKNESS DETERMINATION OFULTRATHIN POLYMER FILMS". T. Gesang. D. Fanter. R. Hofer. W.Possart, O. D. Hennemann, Fraunhofer institut fur Angewandte Materialforschung,Germany, p. 126

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23. " ADHESIVE SELECTION PROTOCOL ". Gregory L. Anderson. ThiokolCorporation, USA. p. 129

24. "CHEMISTRY AND REACTIVITY OF CARBOXYLIC ACIDCONTAINING SURFACES", C A. Fleischer. G. Apai. W. P. McKenna.Eastman Kodak Co., USA. p. 132

25. "EFFECT OF PLASTICIZER CONTENT AND PHOTOAGING ONPVB/GLASS ADHESION", R. J. May and B. J. Love, Department of MaterialsScience and Engineering, USA. p. 135

26. "EXPERIMENTAL STUDY OF KGR-1 ADHESIVE SHEARSPECIMENS ", M. Y. Tsai, and J. Morton, Department of Engineering Scienceand Mechanics, Virginia Tech and R. B. Krieger, Cytec Engineered Materials Inc.USA.

27. "PHOTOELASTIC STUDY- OF PROPAGATING CRACKS INADHESIVE JOINTS ", Y. Y. Wang and F. P. Chiang, Departmetn of MechanicalEngineering, State University of New York at Stony Brook, USA. p. 137

28. "THE DIFFUSION OF ISODODECYL PELARGONATE WITHIN ANEPOXY ADHESIVE" K. Kwan and T. C. Ward, Virginia Tech, USA. p. 139

29. "FRACTURE TOUGHNESS TESTING OF ADHESIVELY BONDEDSHEET STEEL", I. Ashcroft, P Basu, and G. Spinks, Department of MaterialsEngineering, Uninverity of Wollongong, Australia, p. 141

30. "ADHESION OF PAINT COATINGS TO ALLOY COATEDSUBSTRATES", Youlai Zhang, I Ashcroft, M Binns and G. M. Spinks,Department of Materials Engineering, Uninverity of Wollongong, Australia, p. 143

31. "MEASURING THE POWER LAW DEPENDENCE OF THE VANDER WAALS INTERACTION USING ATOMIC FORCEMICROSCOPE TECHNIQUES", Ron Reifcnberger. B. Gady, and D.Schleef, Department of Physics, Purdue University, USA. p. 145

32. "AEROSIZER PARTICLE SIZE DISTRIBUTION MEASUREMENTSOF FREE-FLOWING AND COHESIVE DRY POWDERS", Bart Dahneke,Eastman Kodak Company, USA.

33. "EQUILIBRIUM INTERMOLECULAR DISTANCE AT THE FIBRE-MATRIX INTERFACE IN MODEL COMPOSITES", M. Nardin and J.Schultz, CNRS, France, p. 147

34. "LOW ENERGY ION IMPLANTATION/DEPOSITION AS A FILMSYNTHESIS AND BONDING TOOL "/Andre Anders, Sirnone Anders, IanBrown and Igor Ivanov, Lawrence Berkeley Laboratory, University of Calefornia.USA. p. 149

35. "SURFACE ANALYSIS, PEEL STRENGTH AND SEALANTADHESION TO AGED OXYGEN PLASMA MODIFIEDUNPLASTICIZED PVC FILMS". Mojgan Babaj-Cline and J. P. Wightman.Derjartrnent of Chemistry, Virginia Tech, USA. p. 151

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36. "HUMIDITY AND TEMPERATURE DOUBLY SHIFTED FRACTUREENERGY MASTER CURVES FOR THE PREDICTION OF SEALANTADHESION". N. E. Shephardand J. P. Wightman. Department of Chemistry,Virginia Tech. USA. p. 155

37. "ALTERING THE FIBER MATRIX INTERPHASE INSEMICRYSTALLINE POLYMER MATRIX COMPOSITES". R. L. Clarkand R. G. Kander, Department of Materials Science and Engineering, Virginia Tech.USA. p. 157

38. "HIGH SPEED INFRA RED IMAGING OF FRACTURE INTHERMOPLASTIC OLEFINS", Y. Wang, S. Telenkov. Z. L. Wu. T. Ahmed,X. Wang, L. D. Favro, P. K. Kuo and R. L. Thomas, Wayne State University; A.C Ramamurthy, Ford Motor Company; W. Brostow. N. D'Sousa and H. Galina,University of North Texas, USA. p. 159

39. "FILM FORMATION OF LATEX COATINGS", C. A. Fleischer. H. R.Grashof, D. Schwark, K. Schlafer. and J. F. El man,-Eastman Kodak Comany,USA. p. 162

40. "THE WETTABILITY OF ROUGH SUBSTRATES BY VISCOUSPOLYMER MELTS". S. A. Tschetter, N. Shephard and J. P. Wightman.Department of Chemistry, Virginia Tech, USA. p. 165

41 . "EFFECT OF ADHEREND TYPE UPON THE ADHESIVE MODE-IFRACTURE ENERGY OF DCB JOINTS", A. J. Bell, AJ. Kinloch and Y.Wang, Department of Mechanical Engineering, Imperial College of Science,Technology and Medicine, England, p. 167

42. "POLYMERIC COUPLING AGENTS FOR ENHANCING THEADHESION OF EPOXY TO STEEL", Karthik Vaideeswaran and James P.Bell, University of Connecticut, USA. p. 171

43. "PHASE DIAGRAMS OF ACRYLIC PRESSURE SENSITIVEADHESIVE", Hyun-Joong Kim and Hiroshi Mizumachi, University of Tokyo,Japan, p. 173

44. "THE DESIGN OF COMPOSITE TO METAL TUBULAR LAP JOINTSFOR TORSIONAL LOADING", M. D. Roseman, and A. J. Kinlcch,Department of Mechanical Engineering, Imperial College of Science, Technologyand Medicine, England, p. 176

45. "HEAT CYCLES LEAD TO IMPROVEMENTS FOR CHLORINATEDPOLYOLEFIN ENHANCED PAINT TO PLASTIC ADHESION",William L. Dechent and James O. Staffer, University of Missouri-Roila. USA.p. 182

XIV

TUESDAY MORNING - SESSION 3A

NEW MATERIALS FOR ADHESIVES AND COATINGS - #2

Session Chair: Terry St Clair, NASA, USA

8:00 • 8:10 OPENING COMMENTSTerry L. SL Clair

8:10 - 8:40 "RELATIONSHIP BETWEEN THE SILICA CONTENT OFSYNTHETIC VULCANIZED STYRENE-BUTADIENERUBBER AND ITS ADHESION PROPERTIES", A. Torro-Palau, J. M. Martin-Martinez, J. C. Femandez-Garcia, and A. C.Orgiles-Barcelo, INESCOP and Adhesion and Adhesives Laboratory,University of Alicante, Spain, (paper dedicated to honoringProfessor Schultz). p. 185

8:40 - 9:10 "DESIGN AND CHARACTERIZATION OF HIGHPERFORMANCE POLYIMIDE ADHESIVE", G. W. Meyer, B.Tan, J. Heidbrink, and J. E. McGrath, Department of Chemistry,Virginia Tech, USA. p. 189

9:10 - 9:40 "THE FRACTURE EFFICIENCY OF TESTS FORADHESIVE BONDS", Yeh-hung Lai and D. A. Dillard, VirginiaTech, USA. p. 192

9:40 • 10:00 BREAK

10:00 - 10:30 "SURFACE-MODIFICATION OF STYRENE -BUTADIENE COPOLYMERS AND THEIR ADHESION TOCOPPER AND TO GOLD", Paul D. Mumbauer, and Gregory S.Ferguson, Department of Chemistry, Lehigh University, p. 195

10:30 - 11:00 "A THERMOPLASTIC POLYETHERIM1DE ADHESIVE",Terry L. St. Clair and Donald J. Pogar, NASA Langley ResearchCenter, USA. p. 198

11:00 - 11:30 "NEW COUPLING AGENTS FOR BONDING POLYMERSTO ALUMINUM", Stephanie L Nesbitt, J. P. Bell, and D. E.Nikles, Department of Chemical Engineering, University ofConnecticut, and Center for Materials for Information Technology, andthe University of Alabama, USA. p. 199

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TUESDAY MORNING - SESSION 3B

CHEMICAL/PHYSICAL CHARACTERIZATION OF ADHESIVEINTERACTIONS #1

Session Chair: Marek Urban, North Dakota State University

8:00 - 8:10 Opening CommentsMarek Urban, North Dakota State University, USA

8:10 - 8:40 "INFRARED AND RAMAN SPECTROSCOPY OFPOLYMER/METAL INTERPHASES: APPLICATION TOADHESION", F. J. Boerio. 1. Segall, C. E. Taylor, Y. M. Tsai, J.T. Young, and W. W. Zhao, Department of Materials Science andEngineering, University of Cincinnati. USA. p. 202

8:40 - 9:10 "RHEO-PHOTOACOUSTIC FT-IR SPECTROSCOPY ANDINTERLAYER ADHESION OF POLYMERS", Brian D.Pennington and Marek W. Urban, North Dakota State University,USA. p. 206

9:10 - 9:40 "THE DETERMINATION OF ADSORPTION ISOTHERMSBY XPS AND TOF-SIMS", J. F. Watts, J. E. Castle, M. M.Chehimi, and M-L Abel, Department of Materials Science andEngineering, University of Surrey, England; and Institut deTopologieet de Dynamique des Systemes, University of Paris, France, p. 209

9:40 - 10:00 BREAK

10:00 - 10:30 "THE QUANTITATIVE EVALUATION OF ACID-BASEPROPERTIES BY XPS", S. R. Leadley, J. F. Watts and G.Beamson, Department of Materials Science and Engineering, Universityof Surrey, England, p. 212

10:30 - 11:00 "DYNAMICS OF ADHESION PROMOTERS AND THEPHYSICAL PROPERTIES OF COMPOSITES",Timothy W.H. Wang and Frank Blum, Department of Chemistry and MaterialsResearch Center, University of Missouri-Rolla, USA. p. 215

11:00 - 11:30 "DETECTION OF SUBADHESIVE HYDRATION OFALUMINUM ADHERENDS BY ELECTROCHEMICALIMPEDANCE SPECTROSCOPY", G. D. Davis and P. L.Whisnant, Martin Marietta Laboratories, and J. D. Venables, Venablesand Associates, USA. p. 218

11:30 -12:00 "THE ADSORPTION OF SILANE MOLECULES ONYTTRIUM TREATED STEEL SUBSTRATES: A ROUTETO IMPROVED BOND PERFORMANCE", S. J. Davis and JF. Watts, Department of Materials Science and Engineering. Universityof Surrey, England, p. 221

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12:00 - 12:30 "PENETRATION OF SILVER INTO SELF-ASSEMBLEDORGANIC MONOLAYERS", G. C. Herdt and A. W. Czanderna.Measurements and Characterization Branch. National RenewableEnergy Laboratory, USA. p. 224

TUESDAY MORNING - SESSION 3C

SMALL PARTICLE ADHESION #2

Session Chain Don Rimai, Eastman Kodak Company

8:00 - 8:10 Opening CommentsDon Rimai, Eastman Chemical Company

8:10 - 8:40 "THE ADHESION OF GLASS PARTICLES TO SILICONSUBSTRATES", R. C. Bowen, D. S. Rimai, and L. P. DeMajo,Eastman Kodak Co., USA. p. 227

8:40 - 9:10 "PARTICLE REMOVAL FROM SMOOTH AND ROUGHSURFACES UNDER SUBSTRATE ACCELERATION",Mehdi Sokani, and Goodarz Ahmadi, Department of Mechanical andAeronautical Engineering, Clarkson University, USA. p. 230

9:10 - 9:40 "A SIMPLE MODEL FOR THE EFFECTS OF TIME ONTHE ADHESION OF SUBMICROMETER PARTICLES TOSUBSTRATES", F. Zhang and A. A. Busnaina, ClarksonUniversity; and D. S. Rimai, Eastman Kodak Co., USA. p. 233

9:40 - 10:00 BREAK

10:00 - 10:30 "PARTICLE ADHESION: A MOLECULAR DYNAMICSAPPROACH", D. Quesnei, D. S. Rimai and L. P. DeMajo,Department of Mechanical Engineering, University of Rochester, USA.

10:30 - 11:00 "TONER ADHESION: THE EFFECT OF NON-UNIFORMSURFACE CHARGE DISTRIBUTION", D. Hays, E Eklund,W. H. Wayman and L. J. Brillson, Xerox, USA. p. 237

11:00 - 11:30 "RELATIONSHIPS BETWEEN PARTICLE ROUGHNESS,PARTICLE-SURFACE ADHESION AND PARTICLECHARGING", H. A. Mizes, M. L. Ott, E A. Eklund and Dan Hays,Xerox Corporation, USA. p. 240

11:30 - 12:00 "HUMIDITY SENSITIVITY OF THE ADHESION OFTONER PARTICLES TREATED WITH SURFACE-MODIFIED SURFACE ADDITIVES", Mary L. Ott and Scott M.Silence, Xerox Corporation, USA. p. 243

TUESDAY AFTERNOON FREE

XVII

TUESDAY EVENING - SESSION 4A

DURABILITY: ENVIRONMENTALLY INDUCED ADHESIONREDUCTION

Session Chair: Rose Ryntz, Ford Motor Company

7:00 - 7:10 Opening CommentsRose Ryntz, Ford Motor Company

7:10 - 7:40 "MEASUREMENT OF WET ADHESION COATINGSYSTEM ON STEEL: An EQUIVALENT CIRCUITMODEL", Peter J.Moreland.Zeneca Resins, England, p. 246

7:40 - 8:10 "A STUDY OF THE EFFECTS OF MOISTUREDIFFUSION ON THE STRENGTH AND FATIGUERESISTANCE OF EPOXY BONDED ADHESIVE JOINTS".J. A. Harris Materials and P. A. Fay, Material Engineering ResearchLaboratory Ltd. and Ford Motor Company, England, p. 249

8:10 • 8:40 "RELATIONSHIP BETWEEN ADHESION LOSS ANDWATER AT THE POLYMER / SUBSTRATE INTERFACE",Tinh Nguyen, David Alsheh, Dale Bentz and Eric Byrd, NationalInstitute of Standards and Technology, USA. p. 252

8:40 - 9:10 "EFFECT OF PRECURE MOISTURE EXPOSURE ON ASTRUCTURAL EPOXY ADHESIVE", S. M. Ward, M. A.DeBolt, G. L. Westerbeek, and R. A. Dickie, Ford ResearchLaboratory, USA. p. 255

9:10 - 9:40 "ADHESIVE BONDING OF COATED STEELS", I. A.Ashcroft, P. Basu, and G. Spinks, Department of Engineering,University of Wollongong, Australia, p. 258

9:40 - 10:10 "SILANE COUPLING AGENTS AS ADHESIONPROMOTERS FOR BONDING THERMOPLASTICPOLYMERS TO ALUMINUM", Steven H. McKnight and JohnW. Gillespie, Center for Composite Materials, University of Delaware.USA. p. 261

TUESDAY EVENING - SESSION 4B

CHEMICAL/PHYSICAL CHARACTERIZATION OF ADHESIVEINTERACTIONS #2

Session Chair: Marek Urban

7:00 - 7:10 Opening CommentsMarek Urban. North Dakota State University, USA

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7:10 - 7:40 "CHARACTERIZATION OF INTERPHASES IN POLYMER- POLYMER JOINTS". M. F. Vallat, C. Spitteri. J. Schultz. A.Belgrine, G. Evrard. and A. Coupard. Centre de Rescherches sur laPhysico-Chemie des Surfaces Solides and Laboratoire de Recherches etde Controle des Caoutchous et des Plastiques, France, p. 264

7:40 - 8:10 "THE INFLUENCE OF SURFACE MORPHOLOGY ONTHE ADHESION OF COATINGS TO THERMOPLASTICPOLYOLEFINS UNDER STRESS", Rose A. Ryntz, FordMotor Company, USA. p. 267

8:10 - 8:40 "IN SITU FTIR STUDY OF THE REACTION OFORGANOSILANES AT THE FLAT SILICA SURFACE", M.J. Azzopardi and H. Arribart, Laboratoire CNRS/Saint Gobain, France.p. 275

8:40 - 9:10 "ADHESION BETWEEN SEMICRYSTALINEPOLYMERS", E Boucher, J. P. Folkers, H. Hervet and L. Leger,Laboratoire de la Matiere Condensee - URA CNRS, France, p. 278

9:10 - 9:40 "CHARACTERIZATION OF INTERFACES BETWEENVACUUM DEPOSITED SILICONE DIOXIDE FILMS ANDPOLYMETHYL METHACRYLATE SUBSTRATES", W. H.Tsai, J. T. Young, Y. M. lian and S. L. l iao, Polymer Analysis andCharacterization Department, Union Chemical Laboratories, Taiwan.p. 281

9:40 • 10:10 "ADHESION MECHANISMS OF POLYURETHANES TOGLASS SURFACES", R. K. Agrawal and L. T. Drzal, MichiganState University, USA. p. 285

TUESDAY EVENING - SESSION 4CPRESSURE SENSITIVE ADHESIVES

Session Chair: Louis Sharpe, Consultant, USA

7:00 - 7:10 Opening CommentsLouis Sharpe, Consultant, USA

7:10 - 7:40 "SURFACE AND INTERFACIAL STRUCTURE OFRELEASE COATINGS FOR PRESSURE SENSITIVEADHESIVES", David J. Kinning, 3M Adhesive TechnologiesCenter, USA. p. 288

7:40 - 8:10 "STRUCTURE-PROPERTY-PERFORMANCERELATIONSHIPS IN EMULSION PRESSURESENSITIVE ADHESIVES: EFFECT OF MATERIAL ANDFORMULATING PARAMETERS", Krishan C. Sehgal and DavidR. Bassett, USCAR Emulsion Systems, Union Carbide Corporation,USA. p. 292

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8:10 - 8:40 "IMAGING THE BONDING AND DEBONDING OFPRESSURE SENSITIVE ADHESIVES". Robert K. Galkiewicz.3M Adhesive Technologies Center, USA. p. 296

8 : 4 0 - 9:10 "RATE - TEMPERATURE DEPENDENCE OF THEAUTOHESION OF CARBON BLACK-FILLED STYRENE-BUTADIENE RUBBER", G. R. Hamed and P. S. Wu, PolymerScience Department, University of Akron. USA . p. 300

9:10 - 9:40 "VISCOELASTIC PROPERTIES OF PRESSURESENSITIVE ADHESIVES", E. P. Chang, Avery Research Center,USA. p. 303

9:40 - 10:00 "SILICONE PRESSURE SENSITIVE ADHESIVES WITHENHANCED SURFACE WETTABILITY", Dr. Shaow B. Lin,Specialty Coatings Technology, GE Silicones, USA. p. 307

10:00 - 10:20 "MAXIMUM PEEL STRENGTHS OF PRESSURESENSITIVE STYRENE BUTADIENE LATEX POLYMERSOVER WIDE TEMPERATURE AND PEEL RATERANGES", J. J. Spitzer, J. Antonucci, A. E. Karabela, and K. P.Lok, BASF, USA. p. 310

10:20 - 10:40 "WATER WICKING RATE OF AN ABSORBANT PAPERLAMINATED BY PRESSURE SENSITIVE ADHESIVE", T.Yang, and R. J. Nelson, Abbott Laboratories, USA. p. 313

WEDNESDAY MORNING - SESSION 5A

MECHANICAL CHARACTERIZATION OF COATING/ADHESIVE-SUBSTRATE INTERPHASE

Session Chair: Christopher Brown, Worcester Polytechnic Institute

8:00 - 8:10 Opening CommentsChristopher Brown, Worcester Polytechnic Institute

8:10 - 8:40 "HERTZIAN INDENTATION TEST FOR MONITORINGTHE FRACTURE ENERGY OF POLYMER/GLASSINTERFACES IN SANDWICH GEOMETRIES", J. E. Ritter,T. J. Lardner, G. Bao, and P. Juntawongso, Department of MechanicalEngineering, University of Mass. USA. p. 316

8:40 - 9:10 "INTERFACIAL CRACK GROWTH IN POLYMER/GLASSSANDWICH SPECIMENS", J. E Ritter, T. J. Lardner. G. C.Prakesh, and A. J. Stewart, Department of Mechanical Engineering,University of Mass. USA. p. 319

9:10 - 9:40 "RATE DEPENDENT INTERFACIAL AND COHESIVEFRACTURES IN CONVENTIONAL DOUBLECANTILEVER BEAM SPECIMENS". M. D. Rakestraw, M. W.

Taylor. Y. H. Lai. T. Chang and D. A. Dillard. Department ofEngineering Science and Mechanics. Virginia Tech. p.322

9:40 • 10:00 BREAK

10:00 - 10:30 "STUDY OF EFFECT OF THICKNESS ON MECHANICALPROPERTIES OF ADHESIVE MATERIALS BY SIEM", Y.Y. Wang, Qing Wang and Fu-pen Chiang, Department of MechanicalEngineering, State University of New York at Stony Brook, USA. p.325

10:30 - 11:00 "TOPOGRAPHY AND CAPILLARY BONDING OF WETPOLYETHYLENE SURFACES", S. C. Colbeck, CRREL and J.B. Rossacci, E M. Shipulski and C. A. Brown, MechanicalEngineering Department, Worcester Polytechnic Institute, USA. p.328

11:00 - 11:30 "FRACTURE OF AN ADHESIVE SUBSTRATEINTERFACE IN SANDWICH SPECIMENS", J. G. Swadenerand K. M. Uechti, Engineering Mechanics Research Laboratory,University of Texas, USA. p. 331

11:30 - 12:00 "ELASTOPLASTIC, THREE DIMENSIONAL STRESSANALYSIS OF THE PENINSULA BLISTER TEST", A.

Shirani and K.M. Liechti, Engineering Mechanics Research LaboratoryUniversity of Texas, USA p. 334

WEDNESDAY MORNING - SESSION 5B

APPLICATIONS OF ADHESION SCIENCE

Session Chair: Kimberly Chaffin, Ford Motor Company

8:00 - 8:10 Opening commentsKimberly Chaffin, Ford Motor Company

8:10 - 8:40 "RF CURING IMPLEMENTATION IN AUTOMOTIVEPRODUCTION", Kimberly A. Chaffin, Chi Li, and R. A. DickieFord Research Laboratory, Ford Motor Company, USA. p. 337

8:40 - 9:10 "GUIDED WAVES FOR METAL TO COMPOSITEADHESION BOND INSPECTION", Joseph L. Rose and KrishnaRajana, and Semyen Pelts, Department of Engineering, Science andMechanics, Pennsylvania State University, USA. p. 340

9:10 - 9:40 "THE BOEING WEDGE TEST: FACT OR FICTION", R. D.Adams, University of Bristol, England.

9:40... 10:00 BREAK

10:00 - 10:30 "INCREASED ADHESION AT THE FIBER INTERFACEFOR POLYETHYLENE FIBER PAPERS FOLLOWING

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OXYFLUORATION TREATMENT". B. Riedl and H. Chtourou.Centre for Research on Science and Engineering of Macromolecules.Laval University. Canada, p. 343

10:30 - 11:00 "PERFORMANCE TESTING OF COATED ALUMINUMFOOD AND BEVERAGE PRODUCTS". R. A. Haaksma.Corporate Research and Development, Reynolds Metals Company,USA p. 346

WEDNESDAY MORNING - SESSION 5C

GENERAL PAPERS

Session Chair - Greg Anderson, Thiokol

8:00 - 8:10 Opening CommentsGreg Anderson, Thiokol

8:10 - 8:40 "BOND STENGTH OF THE FRP-WOOD INTERFACE", J.F. Davalos and E. J. Barbero, Constructed Facilities Center, USA. p .349

8:40 - 9:10 "FAILURE ANALYSIS AND CHARACTERIZATION OF APHENOLIC ADHESIVE USED TO SEPARATE BRONZEFROM A SULFUR CURED RUBBER", George Dallas, EugeneSlagowski, Wayne Cheatle and Linda Shalkowski, Research andDevelopment, Beloit Manhattan, USA. p. 352

9:10 - 9:40 "EFFECT OF CONTAMINATION AND ROUGHNESS OFSTAINLESS STEEL ON THE ADHESIVE BONDINGWITH A SILICONE ELASTOMER", M. Mantel, N. Shephard,and J. P. Wightman, Virginia Tech and Ugine Research Center,France, p. 355

9:40 - 10:00 BREAK

10:00 - 10:30 "EFFECT OF ELECTRODEPOSITION OF POLYAMICACID ON THE SURFACE PROPERTIES OF CARBONFIBERS", W. Yuan and J. O. Iroh, Department of Materials Scienceand Engineering, University of Cincinnati, USA. p. 359

10:30 - 11:00 "BOND CHARACTERISTICS AT POLYMER-PIGMENTINTERFACES", J. Lara, Shu-De Rong. and H. P. Schreiber,Department of Chemical Engineering, Ecole Poly technique, Canada, p .362

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