temperature and heat - university of hawaiiplam/ph170_summer_2011/l17/17_lecture...specific heat and...
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PowerPoint® Lectures for University Physics, Twelfth Edition – Hugh D. Young and Roger A. Freedman
Lectures by James Pazun
Chapter 17
Temperature and Heat
Modified by P. Lam 8_4_2010
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Topics for Chapter 17
• Condition for thermal equilibrium.
• temperature scales
• thermal expansion thermal stress
• heat, phase changes, and calorimetry
• heat flows with convection, conduction, and radiation (qualitative)
Copyright © 2008 Pearson Education Inc., publishing as Pearson Addison-Wesley
Condition for thermal equilibrium
cold hot A B A B
Non-equilibrium
T A > T B
Net energy flows from A to B
Equilibrium
T A = T B
No net energy flow
TA =temperature of system A TB=temperature of system B
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The zeroth law of thermodynamics • If A is in thermal equilibrium with C and B is in thermal equilibrium
with C, then A is also in thermal equilibrium with B
• Simply stated: If TA=TC and TB=TC, then TA=TB
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Application of the “zeroth” law
• When the doctor takes your temperature, the doctor implicitly invokes the “zeroth” law because the doctor assumes the thermometer has reached thermal equilibrium with your body and reading the temperature of the thermometer is the same as reading your temperature.
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Relating the three popular temperature scales • Values on the temperatures scales (Fahrenheit, Centigrade/Celsius,
and Kelvin) may be readily interconverted. See Figure below.
oC + 273 ! K &
180
100
oC( ) + 32 = o
F
Absolute zero = absolute lowest temperature.
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Calibration of Thermometers • There are many physical properties which
vary with temperature and hence can be used as a thermometer. Here are two examples:
• (1) Expansion and contraction of a liquid such as mercury or alcohol as the temperature increases or decreases, respectively.
• (2) Pressure of a gas inside a constant volume container increases as temperature rises.
• Thermometers are calibrate with some reproducible temperatures such as
(i) Melting point of ice at 1 atmospheric pressure
(ii) Boiling point of water at 1 atmospheric pressure
!
Pressure " T (in Kelvin)
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Thermal expansion—linear and volume expansion
• A change in length accompanies a change in temperature. The amount of the change depends on the material.
!
"L
Lo
#$"T
$ = linear expansion coefficient ofthe material
unit of $ = 1/Kelvin
Similarly for volume expansion :
"V
Vo
# %"T; for "small" "T, % & 3$
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Coefficients of expansion
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Thermal stress • Thermal expansion joints allow
roads to expand and contract freely without causing stress to the materials.
• “Thermal stress” - Stress (force/area) develops in a material if it is not allowed to expand or contract as temperature changes.
!
F
A=Y
"L
Lo
=Y# "T ; Y = Young's modulus of the material
The textbook use a negative sign to remind us the direction of the force
F
A= $Y#"T
I think that it is not necessary and may be even confusing
(one more convention to remember!)
You can figure out which direction is the force using common sense.
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Thermal stress • Example 17.5: An aluminum
cylinder (10 cm long with cross-sectional area =20cm2) is used at a spacer between two rigid walls. At T=17.2oC it just fit between the two walls. When it warms up to 22.3oC, what is the stress (force/area) in the cylinder and the total force it exerts on each wall? Given the Young’s modulus for aluminum is 7x1010 N/m2 and is linear expansion coefficient is 2.4 x10-5/K
!
F
A=Y
"L
Lo
=Y# "T
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Specific heat and heat capacity
• The specific heat of a substance reveals how much temperature will change when a given amount of heat is added or removed from the substance.
• Water is a “benchmark” as one gram of water will absorb 1 cal of heat to raise its temperature by 1oC.
!
Q = mc"T
m = mass; mc = heat capacity
!
c =1cal
g•Co
= 4190J
kg•K
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Specific heat values
Note:Specific heat varies with temperature and pressure. These values are valid for a limited range of temperature and pressure only.
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Phase changes and temperature behavior
Example: Start with 1 kg of ice at -20oC and add heat.
T
Heat input (kJ) 0oC
-20oC
100oC
solid
Liquid
gas
Not drawn to scale!
Heat of fusion
Heat of vaporization
Pressure=1 atm.
42kJ (42+334)=376KJ (376+419)=795kJ (795+2256)kJ
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Heats of Fusion and Heats of Vaporization
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Calorimetry
Example 17.8: (a) A 0.5 kg aluminum cup is initially at T=150oC. 0.3kg hot water (T=70oC) is poured into the cup. Assume no heat exchange with the surrounding, find the final temperature of the cup and the water.
!
"Qtotal = 0 = mAlcAl (Tf #TiAl) + mwcw (Tf #Ti
w)
0 = (0.5)(910)(Tf #150) + (0.3)(4190)(Tf # 70)
$ Tf = 91.3oC
(b) What happens if the initial temperature of the aluminum cup were 200 oC?
!
"Qtotal = 0 = mAlcAl (Tf #TiAl
) + mwcw (Tf #Tiw)
0 = (0.5)(910)(Tf # 200) + (0.3)(4190)(Tf # 70)
$ Tf =104.6oC!!
What does it mean?
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Calorimetry
Example 17.9 (change in temperature and phase): 0.25 kg of water in a cup is initially at T=25oC. An amount ice (initially at T=-20oC) is poured into the cup. How much ice is needed so that the final temperature will be OoC and no ice left. Assume no heat exchange with the surrounding and the cup has negligible heat capacity.
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Methods of heat transfer (qualitative)
• Heat conduction through a solid.
• Heat current is
• (1) proportional to the temperature difference
• (2) proportional to the cross-sectional area (A)
• (3) inversely proportional to the length of the solid
!
Heat current (Joule
s=Watt) "
dQ
dt= kA
TH #TCL
k = thermal conductivity of the solid W
m •K
$
% & '
( )
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Convection of heat (qualitative)
• Heat transfer in a fluid (gas or liquid).
• Heat energy is carried by the movement of the hot fluid particles (if movement is restricted than there is no convection)
• Hot fluid (less dense) rises while cold fluid (more dense) decends.
• Gravity is necessary for convection.
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Radiation of heat (qualitative)
• A hot object can lose energy by emitting electromagnetic radiations.
• On the right, an infrared photograph shows the infrared radiation given off by a person.
hot
cold
!
Radiation heat current (Watt) = Ae"T4
T = temperature of the hot object in Kelvin!
A = cross - sectional area
e = emissivity (depends on the nature of the object)
(0 < e < 1)
" = a fundamental constant # 5.67x10-8 W
m2K
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