suzuki—miyaura cross-coupling of benzylic phosphates with arylboronic acids

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2006 Polyphenylalkane derivatives Q 0720 Suzuki—Miyaura Cross-Coupling of Benzylic Phosphates with Arylboronic Ac- ids. — The title reaction tolerates a number of functional groups but is not applicable to secondary phosphate substrates: in the case of (VI) styrene is the only product ob- served. — (MCLAUGHLIN, M.; Org. Lett. 7 (2005) 22, 4875-4878; Dep. Process Res., Merck Res. Lab., Merck&Co., Inc., Rahway, NJ 07065, USA; Eng.) — R. Steudel 09- 094

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Page 1: Suzuki—Miyaura Cross-Coupling of Benzylic Phosphates with Arylboronic Acids

2006

Polyphenylalkane derivativesQ 0720 Suzuki—Miyaura Cross-Coupling of Benzylic Phosphates with Arylboronic Ac-

ids. — The title reaction tolerates a number of functional groups but is not applicable to secondary phosphate substrates: in the case of (VI) styrene is the only product ob-served. — (MCLAUGHLIN, M.; Org. Lett. 7 (2005) 22, 4875-4878; Dep. Process Res., Merck Res. Lab., Merck&Co., Inc., Rahway, NJ 07065, USA; Eng.) — R. Steudel

09- 094

The Suzuki–Miyaura Cross‐Coupling as the Key Step in the

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