snow characterization workshop 2008 3d (lecture 2) martin schneebeli
TRANSCRIPT
3D microstructural analysis
two methods for 3D microstructural analysis:
– polycut = serial sectioning– microCT = micro computer
tomography
polycut
microCT
3D image: tomography-BET
QuickTime™ and aTIFF (Uncompressed) decompressor
are needed to see this picture.
Principle of the new method
snow
snow
phthalate
raw CTimages
segmented images
image processing
image inversion
"digital replica"
new method
Sample preparation: casting
• casting technique is identical as for polycut• replace the air in the pores by diethyl phthalate• diethyl phthalate: melting point -3°C, but
solidification temperature is much lower (c. -30°C)
• freeze with dry ice
Sample preparation: trimming
• at -20°C to prevent melting of the phthalate
• cut and trim samples to cylinders of 18 mm diameter
Experimental setup: vacuum
• store samples in vacuum desiccator
• high vacuum pump: final pressure ~5×10-2 mbar
• optional: put drying agent in desiccator
Experimental setup: microCT
• when sublimation terminated: microCT measurement
• same measurement protocol as for snow
Image processing
• raw CT-images: Gaussian filtered (3D)
• image segmentation: local minimum of the histogram as threshold
-2000 0 2000 4000 6000 8000 10000 12000 140000
20000
40000
60000
80000
100000
120000
140000
160000
180000
Min.4203
icecounts
grey level
air
threshold
-2000 0 2000 4000 6000 8000 10000 12000 140000
20000
40000
60000
80000
100000
120000
140000
160000
180000
Min.3691
phthalate
counts
grey level
air
threshold
air
ice air
phthahlate
Sublimation process
9
10
11
12
13
14
15
16
0 12 24 36 48 60 72 84 96 108 120
time (h)
sample weight (g)
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1
0 12 24 36 48 60 72 84 96 108 120
time (h)
normalized weight (g)
Weight loss
• vacuum pressure is a good indicator of the progress
• drying agent significantly accelerates the sublimation process
0
20
40
60
80
100
0 12 24 36 48 60 72 84 96 108 120
time (h)
pressure (a.u.)
vacu
um
pre
ssu
ren
orm
aliz
ed
weig
ht
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1
0 12 24 36 48 60 72 84 96 108 120
time (h)
normalized weight (g)
with drying agent
Validation: samples
• special sample holder for validation measurements
• CT-measurement of snow before casting
• casting and vacuum sublimation in the CT sample holder
• measurement of the phthalate after sublimation digital replica
• comparison between digital replica and orginal snow structure
Validation: structural parameters
0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.500
5
10
15
20
25
30
35
40
45
50
55
60
65
70
frequency (%)
thickness (mm)
(a)
0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.500
5
10
15
20
25
30
35
40
45
50
55
60
65
70
frequency (%)
spacing (mm)
(b)
structural parameters: density, SSA, trabecular thickness, trabecular spacing, etc.
relative errors are very small (a few percent)
trabecular thickness trabecular spacing