sludge-to-cement conversion
TRANSCRIPT
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A REVIEW OF RELATED LITERATURE AND STUDIES
Overview
This research study investigates on the utilization of alum sludge from
wastewater treatment as a clay substitute in Portland cement production. This chapter
presents a summary of the relevant studies carried out in the area of conversion
wastewater sludge into construction material. Moreover, this chapter highlights the
effect of sludge-cement ratio to the mechanical properties of the Portland cement.
The Review
3.1 Sludge used as c!s"ruc"i! #a"erial
3.1.1 Sludge as ce#e!"$li%e #a"erial&
The potential of utilizing dewatered sludge to produce cementitious materials is one
aspect of using sludge as new material resource. Tay and Show (!!" concluded that
digested and dewatered sludge could be used to produce cement li#e material. $n
preparing cement specimens, the sludge was dried and mi%ed with limestone powder.
The resulted mi%ture was ground and incinerated. The sludge cement was found to
have high water demand and &uic# setting compared with ordinary cement. 'valuation
of mortar cube strength showed that it was possible to produce masonry binder made of
cement sludge that would satisfy the strength re&uirements of the STM standard for
masonry cement. )urther studies were needed to evaluate long term properties such as
durability prior to acceptance as a suitable masonry binder. Sewage sludge pellets
(SSP" is used as substituting material in raw mi% formulation in manufacturing process
of Portland cement. Monzo (!!*" replaced ++ of cement clin#er dry weight by (SSP"
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without any problem or larger differences comparing to cement made with normal
clin#er contents. oh et al. +/0 used pulverized sludge ash blended with cement in
concrete mi%. The sewage sludge treated at 11! !2 to remove organic materials for
using as filler in concrete. The presented ash was collected and pulverized to finer than
+1!3m, then incorporated into the cement. The results indicated that concrete
wor#ability was improved as sludge ash content 2hapter 4 sludge as construction
materials 4-1 increased. The /-day compressive strength of concrete cubes with +!
sludge ash in cement was about the same of ordinary concrete, but when sludge ash
increase up to *!, the strength drops by 1! +/0. Sewage sludge ash (SS" was
used as replacement of cement at +1 and 4! by weight in mortar. ccording to
Monzo, the mortar containing +1 of (SS" as replacement of cement has a
compressive strength similar to reference mortar. 5hen (SS" content increased up to
4!, a significant decrease was observed. oncalves (!!*" tried to use sewage
sludge treated at different temperature as replacement material of cement in mortar
preparation. dry sludge at +!1 !2 was used as replacement of cement by ! of dry
weight. The result showed that there was no setting occurred. nother trial was done
but by using treated sludge at *1!!2, 6!!!2, /1!!2 as replacement of 1 and +! of
cement weight. The results indicated that the presence of any #ind of previous treated
sludge caused decreasing in mortar compressive strength.
3.'.( Sludge i! c!cre"e #i)"ures
The possibility of using dry sludge as additive materials to concrete has been
investigated by 7alls (!!1". The sewage sludge was passed through a drying process
to reduce its humidity to a certain limit and #illing microorganisms8 this allowed adding
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dry sludge to concrete mi% without large change in mi%. 9ry sludge was added to
concrete mi% as fine sand at percent various from !-+!. The use of sludge in concrete
was beneficial in that when sludge reacts with cement and comes to form of binding
matri%, the sludge components were stabilized and &uantity of laechable heavy ions
was reduced compared to free dry sludge. The results obtained by 7alls showed that
the compressive strength of concrete decreased as the sludge content increased.
Sludge content of +! or more cannot be used because the setting time was delayed
and the concrete mechanical properties were reduced significantly. durability test was
carried out on samples with sludge as additive to concrete to evaluate long term
performance. sample was sub:ected to accelerated attac#. These attac#s involved a
combined wet-dry cycles using fresh and sea water, accelerated aging in an autoclave
and accelerated carbonation. The results indicated by 7alls and ;a&ue (!!1" showed
that sludge concrete has durability similar to reference concrete. 2hapter 4 sludge as
construction materials 4-< Sewage sludge was also used in manufacturing of concrete
for pavement but as replacement of sand. replacement of
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3.'.* Sludge i! cera#ic a!d glass +rduc"i!
2eramic industry is a high consumer of silicate which consider as the basic raw material
of ceramic. The main components of sludge ash are silicate (Si> ", this ma#e sludge
ash applicable to use as raw material in ceramic production. Suzu#i (!!6" produce
ceramic samples by adding limestone to sewage sludge incinerated ash. The sludge
ash is presented as fine dust, so it can be directly mi%ed with other ceramic paste
components. 2eramic samples containing 1! sludge ash showed strength, acid
resistance, and absorption coefficient within the normal range for ceramic. ccording to
)erriera (!!4", the leaching test results of ceramic containing sludge ash showed
minimum diffusion values of heavy metals. $n other application, sludge ash is converted
into glassli#e material. melting of sludge ash components converted ash into glass.
The melting process is #nown by verification process has a temperature above +4!! o2.