sludge-to-cement conversion

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    A REVIEW OF RELATED LITERATURE AND STUDIES

    Overview

    This research study investigates on the utilization of alum sludge from

    wastewater treatment as a clay substitute in Portland cement production. This chapter

    presents a summary of the relevant studies carried out in the area of conversion

    wastewater sludge into construction material. Moreover, this chapter highlights the

    effect of sludge-cement ratio to the mechanical properties of the Portland cement.

    The Review

    3.1 Sludge used as c!s"ruc"i! #a"erial

    3.1.1 Sludge as ce#e!"$li%e #a"erial&

    The potential of utilizing dewatered sludge to produce cementitious materials is one

    aspect of using sludge as new material resource. Tay and Show (!!" concluded that

    digested and dewatered sludge could be used to produce cement li#e material. $n

    preparing cement specimens, the sludge was dried and mi%ed with limestone powder.

    The resulted mi%ture was ground and incinerated. The sludge cement was found to

    have high water demand and &uic# setting compared with ordinary cement. 'valuation

    of mortar cube strength showed that it was possible to produce masonry binder made of

    cement sludge that would satisfy the strength re&uirements of the STM standard for

    masonry cement. )urther studies were needed to evaluate long term properties such as

    durability prior to acceptance as a suitable masonry binder. Sewage sludge pellets

    (SSP" is used as substituting material in raw mi% formulation in manufacturing process

    of Portland cement. Monzo (!!*" replaced ++ of cement clin#er dry weight by (SSP"

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    without any problem or larger differences comparing to cement made with normal

    clin#er contents. oh et al. +/0 used pulverized sludge ash blended with cement in

    concrete mi%. The sewage sludge treated at 11! !2 to remove organic materials for

    using as filler in concrete. The presented ash was collected and pulverized to finer than

    +1!3m, then incorporated into the cement. The results indicated that concrete

    wor#ability was improved as sludge ash content 2hapter 4 sludge as construction

    materials 4-1 increased. The /-day compressive strength of concrete cubes with +!

    sludge ash in cement was about the same of ordinary concrete, but when sludge ash

    increase up to *!, the strength drops by 1! +/0. Sewage sludge ash (SS" was

    used as replacement of cement at +1 and 4! by weight in mortar. ccording to

    Monzo, the mortar containing +1 of (SS" as replacement of cement has a

    compressive strength similar to reference mortar. 5hen (SS" content increased up to

    4!, a significant decrease was observed. oncalves (!!*" tried to use sewage

    sludge treated at different temperature as replacement material of cement in mortar

    preparation. dry sludge at +!1 !2 was used as replacement of cement by ! of dry

    weight. The result showed that there was no setting occurred. nother trial was done

    but by using treated sludge at *1!!2, 6!!!2, /1!!2 as replacement of 1 and +! of

    cement weight. The results indicated that the presence of any #ind of previous treated

    sludge caused decreasing in mortar compressive strength.

    3.'.( Sludge i! c!cre"e #i)"ures

    The possibility of using dry sludge as additive materials to concrete has been

    investigated by 7alls (!!1". The sewage sludge was passed through a drying process

    to reduce its humidity to a certain limit and #illing microorganisms8 this allowed adding

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    dry sludge to concrete mi% without large change in mi%. 9ry sludge was added to

    concrete mi% as fine sand at percent various from !-+!. The use of sludge in concrete

    was beneficial in that when sludge reacts with cement and comes to form of binding

    matri%, the sludge components were stabilized and &uantity of laechable heavy ions

    was reduced compared to free dry sludge. The results obtained by 7alls showed that

    the compressive strength of concrete decreased as the sludge content increased.

    Sludge content of +! or more cannot be used because the setting time was delayed

    and the concrete mechanical properties were reduced significantly. durability test was

    carried out on samples with sludge as additive to concrete to evaluate long term

    performance. sample was sub:ected to accelerated attac#. These attac#s involved a

    combined wet-dry cycles using fresh and sea water, accelerated aging in an autoclave

    and accelerated carbonation. The results indicated by 7alls and ;a&ue (!!1" showed

    that sludge concrete has durability similar to reference concrete. 2hapter 4 sludge as

    construction materials 4-< Sewage sludge was also used in manufacturing of concrete

    for pavement but as replacement of sand. replacement of

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    3.'.* Sludge i! cera#ic a!d glass +rduc"i!

    2eramic industry is a high consumer of silicate which consider as the basic raw material

    of ceramic. The main components of sludge ash are silicate (Si> ", this ma#e sludge

    ash applicable to use as raw material in ceramic production. Suzu#i (!!6" produce

    ceramic samples by adding limestone to sewage sludge incinerated ash. The sludge

    ash is presented as fine dust, so it can be directly mi%ed with other ceramic paste

    components. 2eramic samples containing 1! sludge ash showed strength, acid

    resistance, and absorption coefficient within the normal range for ceramic. ccording to

    )erriera (!!4", the leaching test results of ceramic containing sludge ash showed

    minimum diffusion values of heavy metals. $n other application, sludge ash is converted

    into glassli#e material. melting of sludge ash components converted ash into glass.

    The melting process is #nown by verification process has a temperature above +4!! o2.