Self consistent ion trajectories in electron

shading damage

T.G. Madziwa, F.F. Chen & D. Arnush UCLA Electrical Engineering

ltptlNovember 2002

Abstract

In electron-shading damage, the photoresist is charged negatively, preventing electrons from entering the trench, while ions are accelerated toward the bottom of the trench. We have numerically calculated the effect of these fields on the ion trajectories. The ions are injected at acoustic speed from a sheath edge far from the substrate, and the electrons have a Maxwell-Boltzmann distribution. The photoresist and trench walls are assumed to be insulators, and the trench bottom a conductor at various potentials relative to the sheath edge. The potentials on all surfaces are given initial values, and a Poisson solver is used to compute the electric field everywhere. The ions’ trajectories in this field are then computed. Setting the flux of ions to each dielectric surface equal to the Maxwellian electron flux yields a new value of the surface charge. The E-fields and trajectories are then recomputed, and the process iterated until the values converge. It is found that the E-field is concentrated near the entrance to the trench, the only place where the charges matter. The ions receive a kick there and then coast the rest of the way. Thus the trajectories are very sensitive to the exact shape of the photoresist and will change as the etch progresses.

Motivation

Hashimoto et al. JJAP 1994

sheath

1. Verification of the physical picture of electron shading damage mechanism.

New result: ion orbits are ballistic inside the trench and are determined by fields at the entrance

There are no significant numbers of ions that hit the sidewalls.

Methodology 1

•Define space with dielectric and trench, and metal collector.

•Define sheath edge.

•Assume ions are emitted from sheath edge with directed velocity cs.

•Assume electrons are Maxwellian everywhere.

• Assume j = 0 on dielectric surfaces. This causes the plane surface to charge to –15.5 V, according to the plane floating potential formula.

•On the trench walls, potential will self-adjust so that the ion and electron fluxes are equal.

Methodology 2

•Ion flux depends on the E-field in trench, which depends on wall potential.

•We use a 2D Poisson solver to get E-fields for given boundary potentials and then calculate the ion orbits in this E-field.

•We then iterate until the potential distribution and ion orbits converge to a stable solution.

•Initially, the walls are assumed to be a potential that gradually changes from the one on the dielectric to the one on the collector.

• To avoid a singularity when no ions are collected in a cell, we approximate that to be 0.1 ion received. This makes an empty bin much more negative (~-40V) than bin with one ion.

diagram is upside down

Setup II

•The purple region is the region of interest and it lies in the plasma sheath

•Ions (Nions) are emitted from the plasma-sheath boundary with the Bohm velocity

•We count the ions that fall in the vertical and horizontal bins

L

S

HS

W

x1

y1

x3 x4

collector

Dielectric material

Vacuum region x1

y2

y3

y4

Current densities

y

eJ Jy iy Wi

exp( ( ))e

J en v V Ve e r x sk TB e

The ion current densities per bin:

The electron current density:

where Vx is the potential in bin x and is the random velocity of the electrons.

r

The condition for surface voltage calculation is that:

J Je i

Scale Invariance I•Our simulations were done in mm dimensions.

•We want to show that by going down to more realistic dimensions, the results remain valid.

•We look at the invariance of the Poisson solution, scaling of the time of flight of ions and the equation of motion.

•We look at the case where all lengths are scaled by a uniform factor

HS

W

Scale Invariance II2

0

( )e i

eV n n

Start with Poison’s equation:

Then:

2 2 20/ , / , /e D e e s eeV KT KT n e c KT M Define:

2 2 20

21 ( / )D

ei e

e

KTn n

n e

Let s be the scale length of the gradient , and define , so that

/ sr r

2 2 2s

2

2

21 i

eD

ns

n

Now we have:

For, s << D we can solve Laplace’s equation:2 0

( ) atb b b r r r

subject to the boundary conditions:

Sidewall ions AR=7, -40V bias

0 5 10 4 0.001 0.0015 0.0020

0.002

0.004

0.006

0.008

0.01

0.012

0.01415par

0

Y final

2.5par0 X final

zoom

Ion trajectories: AR=7, -26V bias

0 1 10 4 2 10 4 3 10 4 4 10 4 5 10 4 6 10 40

0.001

0.002

0.003

0.004

0.005

0.006

0.007

0.008

0.009

0.01

0.011

0.012

0.013

0.0

ynb

1.2W0 xnb

ions bend at the entrance to the trench

A few ions can hit the sidewall here

Inside the trench, the ions go in straight paths

zoom

Sidewall ions AR=5, -26V bias

0.001 0.0020.005

0.006

0.007

0.008

0.009

0.01

0.011

trace 1

0.012

5par

Y final

2.5par0.25W X final

Sidewall ions AR=5, -26V bias

Ion orbits appear to be straight inside the trench

Sidewall ions AR=5, -26V bias

Scale: 80 to 1

With increased magnification, ion orbits also cross

Aspect ratio: 5 to 1Bias: -26 Volts

2.510 4 3.12510 4 3.7510 4 4.37510 4 5 10 40.006

0.0065

0.007

0.0075

0.008

0.0085

0.009HS

6par

ynb

1W0.5W xnb

The ions bend a lot more with AR=3 and so more ions fall on the sidewalls.

Trajectories AR=3, -22V

Sidewall ions -26V bias

0 5 10 4 0.001 0.0015 0.0020

0.002

0.004

0.006

0.008

0.01

0.012

0.01415par

0

Y final

2.5par0 X final0 5 10 4 0.001 0.0015 0.002

0

0.002

0.004

0.006

0.008

0.01

12par

0

Y final

2.5par0 X final

0 5 10 4 0.001 0.0015 0.0020.005

0.006

0.007

0.008

0.009

10par

5par

Y final

2.5par4.292 10

4

X final

AR=7:1 AR=3:1AR=5:1

Why more sidewall ions at lower AR?

zoom

zoom

Answer lies in distribution of equipotential lines.

AR=7 -26V

No sidewall ions

AR=3 -22V

Sidewall ions

Collector Ions: AR = 3 All aspect ratios follow the same trend.As |V| increases, so

does the ions on collector… (and sidewall ions decrease)

760

800

840

880

-70 -60 -50 -40 -30 -20 -10 0

Bias voltage/V

colle

ctor

ions

Limit cycles: isolated periodic solutions

A typical simulation will come to one of these types of solutions (and some more types not shown here):

Monotonic increase/decrease

Damping oscillations 3 limit cycle

2 limit cycle

Chaos

a limit cycle when the trajectory repeats itself

0 5 10 4 0.001 0.0015 0.002

0

0.002

0.004

0.006

0.008

0.01

12par

0

Y final

2.5par0 X final0 5 10 4 0.001 0.0015 0.002

0

0.002

0.004

0.006

0.008

0.01

12par

0

Y final

2.5par0 X final0 5 10 4 0.001 0.0015 0.002

0

0.002

0.004

0.006

0.008

0.01

12par

0

Y final

2.5par0 X final

0

2

4

6

8

10

12

14

16

1 2 3 4 5 6 7 8 9 10 11 12 13 14

Bin #

Ions c

ollec

ted

Sidewall ions at AR=5 -18V bias:

0

2

4

6

8

10

12

14

16

1 2 3 4 5 6 7 8 9 10 11 12 13 14

Bin #Ion

s coll

ected

0

2

4

6

8

10

12

14

16

1 2 3 4 5 6 7 8 9 10 11 12 13 14

Bin #

Ions c

ollec

ted3 limit cycle: 62 ions, 56 ions, 34 ions

0

10

20

30

40

50

60

70

80

0 5 10 15 20 25

Iteration #

Side

wal

l Ion

s

Dependence on overall structure

Case 1: straight edges Case 2: arc at entrance

Not much change in the number of ions deposited on sidewalls.

With the rounded edges, there are significantly more ions on the collector than with the sharp corners.

What about a minor change in structure like a kink on surface?

KnL02, case c: kink close to trench opening

Case a: no kink

KnL01, case b: kink not too close to trench opening

Kinks on surface with a bias of –18V

13.5%15.3%17.5%

10%9.6%11%

1.8%0.15%0.29%

Case

13.5%15.3%17.5%arc

10%9.6%11%Collector

1.8%0.15%0.29%Sidewalls

cbaCase

A tiny kink on surface gives rise to ion distribution changes

A small kink on the surface changes the sidewall profiles much more than a complete change in structure. (compare with the case of an arc versus straight edges)

A kink close to the opening of the trench increases sidewall ions from a max of 0.29% to 1.8%

AR=5, -60V bias, 2 bins in metal

Sheath region

Inside the trench

Inside the metal trench,

0 5 10 5 1 10 4 1.510 4 2 10 4 2.510 4 3 10 4 3.510 4 4 10 4 4.510 40

9.6153810 4

0.00192

0.00288

0.00385

0.00481

0.00577

0.00673

0.00769

0.00865

0.00962

0.01058

0.01154

0.0125d

0.000

ynb

1W0 xnb

Effect of neighboring trenches

•More sidewall ions when there are adjacent trenches

•Ions collected are symmetrical (just like the geometry)

•More ions are collected on the inner walls

Double trench, AR=5, -22V bias

0.006 0.004 0.002 0 0.002 0.004 0.0060.004

0.0051

0.0063

0.0074

0.0086

0.0097

0.0109

0.01212par

4par

Yfinal

0.0060.006 Xfinal

Ion shadowing effect

Conclusions•insignificant number of ions hit the wall with single trenches.

•Ions drift freely inside trench once their orbits are set by the fields at the entrance.

•Fewer ions hit the wall at high potentials because of the large acceleration.

•Fewer ions hit the sidewall at large aspect ratio because the field lines are straighter.

•Fewer sidewall ions with large collectors because the field lines are straighter.

There are still too few ions hitting the sides to change the etching profile.