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SECURITY rl AýSIFtcATInNI r' TrWO DAr'.r Form Approved DOCU M ENTATION PAG0E OM No. 0704-0188 ~. D -A 955 450 b. RESTRICTIVE MARKINGSn".V~ AD-A955 450 .... 3. DISTRIBUTION/AVAILABILITY OF REPORT Approved for public release ; 2b. DECLASSIFICATION/DOWNGRADING SCHEDULE diA tri -e"t f " o "2 ro latted 4. PERFORMING ORGANIZATION REPORT NUMBER(S) 5. MONITORING ORGANIZATION REPORT NUMBER(S) _ __ PO - TR - 8 9 - U 4i'- 9 6a. NAME OF PERFORMING ORGANIZATION 6b. OFFICE SYMBOL 7a. NAME OF MONITORING ORGANIZATION Gordon Research Conferences (If applicable) AFOSR Pastore Chemical Laboratories, I 6c. ADDRESS (City, State, and ZIP Code) 7b. ADDRESS (City, State, and ZIP Code) Univ f Rhode Island BLDG 410 Kingston, Rhode Island 02881 BAFB DC 20332--448 Ba. NAME OF FUNDING/SPONSORING 8b. OFFICE SYMBOL 9. PROCUREMENT INSTRUMENT IDENTIFICATION NUMBER ORGANIZATION (If applicable) AFOSR AFOSR-78-3553 8c. ADDRESS (City, State, and ZIP Code) 10. SOURCE OF FUNDING NUMBERS PROGRAM PROJECT TASK WORK UNIT BLDG 410 ELEMENT NO. NO. NO. ACCESSION NO. BAFB DC 20332-6448 61102F 2303 BI 11. TITLE (Include Security Classification) e GORDON RESEARCH CONFERENCE ON ORGANOMETALLIC CHEMISTRY 12. PERSONAL AUTHOR(S) P.M. Treichel 13a. TYPE OF REPORT 13b. TIME COVERED 14. DATE OF REPORT (YV-ar, Month, Day) 115. PAGE COUNT Final = FROM 2/1/78 TO 11/30 Nov 16, 1978 17 16. SUPPLEMENTARY NOTATION 17. COSATI CODES 18. SUBJECT TERMS (Continue on reverse if necessary and identify by block number) FIELD GROUP SUB-GROUP 19. ABSTRACT (Continue on reverse if necessary and identify by block number) DTIC SELECTE APR27 19891 Best Available Copy 20. DISTRIBUTION/AVAILABILITY OF ABSTRACT 21. ABSTRACT SECURITY CLASSIFICATION Q UNCLASSIFIED/UNLIMITED 0 SAME AS RPT CI DTIC USERS unclassified 22a. NAME OF RESPONSIBLE INDIVIDUAL i2b. TELEPHONE (Include Area Code) 22c. OFFICE SYMBOL Dr. Ionald Ball - 767-4960 , NC DD Form 1473, JUN 86 Previous editions are obsolete. SECURITY CLASSIFICATION OF THIS PAGE 89 4 25 019

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Page 1: SECURITY rl Form Approved DOCU M ENTATION PAG0E OM …'New Applications of Organomercury,-palladcium, and -rhodium Compounds in Organic Synthesis R. Larock Palladium Catalyzed Allylia

SECURITY rl AýSIFtcATInNI r' TrWO DAr'.r

Form ApprovedDOCU M ENTATION PAG0E OM No. 0704-0188

~. D -A 955 450 b. RESTRICTIVE MARKINGSn".V~AD-A955 450 ....3. DISTRIBUTION/AVAILABILITY OF REPORT

Approved for public release ;2b. DECLASSIFICATION/DOWNGRADING SCHEDULE diA tri -e"t f " o "2 ro latted

4. PERFORMING ORGANIZATION REPORT NUMBER(S) 5. MONITORING ORGANIZATION REPORT NUMBER(S)

_ __ PO -TR - 8 9 - U 4i'- 96a. NAME OF PERFORMING ORGANIZATION 6b. OFFICE SYMBOL 7a. NAME OF MONITORING ORGANIZATIONGordon Research Conferences (If applicable) AFOSRPastore Chemical Laboratories, I

6c. ADDRESS (City, State, and ZIP Code) 7b. ADDRESS (City, State, and ZIP Code)

Univ f Rhode Island BLDG 410Kingston, Rhode Island 02881 BAFB DC 20332--448

Ba. NAME OF FUNDING/SPONSORING 8b. OFFICE SYMBOL 9. PROCUREMENT INSTRUMENT IDENTIFICATION NUMBERORGANIZATION (If applicable)

AFOSR AFOSR-78-3553

8c. ADDRESS (City, State, and ZIP Code) 10. SOURCE OF FUNDING NUMBERSPROGRAM PROJECT TASK WORK UNIT

BLDG 410 ELEMENT NO. NO. NO. ACCESSION NO.

BAFB DC 20332-6448 61102F 2303 BI

11. TITLE (Include Security Classification) eGORDON RESEARCH CONFERENCE ON ORGANOMETALLIC CHEMISTRY

12. PERSONAL AUTHOR(S)

P.M. Treichel13a. TYPE OF REPORT 13b. TIME COVERED 14. DATE OF REPORT (YV-ar, Month, Day) 115. PAGE COUNT

Final = FROM 2/1/78 TO 11/30 Nov 16, 1978 17

16. SUPPLEMENTARY NOTATION

17. COSATI CODES 18. SUBJECT TERMS (Continue on reverse if necessary and identify by block number)

FIELD GROUP SUB-GROUP

19. ABSTRACT (Continue on reverse if necessary and identify by block number)

DTICSELECTEAPR27 19891

Best Available Copy

20. DISTRIBUTION/AVAILABILITY OF ABSTRACT 21. ABSTRACT SECURITY CLASSIFICATION

Q UNCLASSIFIED/UNLIMITED 0 SAME AS RPT CI DTIC USERS unclassified22a. NAME OF RESPONSIBLE INDIVIDUAL i2b. TELEPHONE (Include Area Code) 22c. OFFICE SYMBOL

Dr. Ionald Ball - 767-4960 , NCDD Form 1473, JUN 86 Previous editions are obsolete. SECURITY CLASSIFICATION OF THIS PAGE

89 4 25 019

Page 2: SECURITY rl Form Approved DOCU M ENTATION PAG0E OM …'New Applications of Organomercury,-palladcium, and -rhodium Compounds in Organic Synthesis R. Larock Palladium Catalyzed Allylia

FINAL REPORT

AFOSR GRANT NO: 78-3553 APKIa-K- s 9- 4 9 9

GRANT TITLE: Gordon Researcrt Conference on Organometallic Chemistry

GRANTEE: Gordon Research ConferencesPastore Chemical LaboratoriesUniversity of Rhode IslandKingston, Rhode Island 02881

FRINC!PAL INVESTIGATOR: P. M. Treichel(Conference Chairman)Department of ChemistryUniversity of WisconsinMadison, WI 53706

The Gordon Research Conference on Organometallic Chemistry was held at

Andover Academy, New Hampton, N.H., August 13-19, 1978. In attendance were

149 persons, whose names appear on the attached Registration List. This is

rather a large number of attendees for Gordon Conference; the previous

* conferences on Organometallic Chemistry had 117 attendees which is a more

typical number for most conferences. The large interest in this specific

conference is, we feel, a response to the strong program. While the presence

of a large number of participants could have detracted from the informality

of the conference this did not happen because the conference succeeded in

involving a very large number of people in the program.

As is customary at Gordon Research Conferences, the major portion of

the program contained a series of primary speakers (Program attached).

Thirteen such sessions spanned three general areas: 1) Carbon Ligands Including

Reactions of Coordinated CO (Schrock, MIT; Bercaw, Cal. Tech; Pruett, Union

Carbide), 2) Main Group Chemistry (Reich, U. of Wisconsin; Nonmant, U. of Paris,

France; Ashby, Georgia Tech; Eisch, SUNY-Binghamton, and Halasa, Firestone) and

3) Inorganic and Organic Chemistry of Complexes of the Platinum Group Metals

(Stone, Bristol, England; Stille, Colirado State U.; Maitlis, Sheffield, England;

Heck, U. of Delaware; and Green, Bristol, England). In constructing this program

effort was made to draw the most active people from the U.S. and abroad to

participate in this conference. In addition, we were pleased to be Lble to

integrate industrial speakers into the program. This had been our intention

since a substantial fraction of the conference attendees are from industrial

laboratories. Of course this grant from the AFOSR was instrumental in allowing

,s to get the foreign speakers who participated and greatly strengthened the

program.

4 . • '- ':" .. . ... . .. .

Page 3: SECURITY rl Form Approved DOCU M ENTATION PAG0E OM …'New Applications of Organomercury,-palladcium, and -rhodium Compounds in Organic Synthesis R. Larock Palladium Catalyzed Allylia

Final Report, Page 2

There were ten short research papers interspersed in the program. Thepersons enlisted in this part of the program may be identified as some of themore outstanding young organometallic chemists. In addition we solicited andreceived twenty-eight papers for two poster sessions which were held in thelate afternoons during the week. These sessions generated a lot of interestas they generally were on recent unpublished work, and often were on topics

outside of the topics chosen for the major addresses.

In all over 70 persons participated as speakers, as discussion leaders,or as contributors in the Poster Sessions. This means a high fraction ofattendees were active participants in the program, which contributed to thefavorable overall atmosphere of the conference.

SignaturePrincipal Investigator

November 16, 1978

o," •Aoue~ston For

EOI, i NTIS GRA&T

I: D' OT IC V ,[ f7J0

J Ul..............

I Diltrlbutioa/

flAvai'ibtY CodesAvail and/or

10ist Special

Page 4: SECURITY rl Form Approved DOCU M ENTATION PAG0E OM …'New Applications of Organomercury,-palladcium, and -rhodium Compounds in Organic Synthesis R. Larock Palladium Catalyzed Allylia

PROGRXl

GORDO RESEARCH CONIFEREACES

ORGMOMETALLIC CUI.,1ISTRY

August 14-18, 1978

Prcctor Academy, Andover, New Hampshire

P. .i1. Treichel, Chairman

.I. . aesz, Vice Chairman

E'onday, August 14

J. Labinger, Disc'ssion Lea4UVivqraity QfNotro Dame

fiono and 3is Alkylidene Complexesof Niobium and Tantalum, andReactions Involving Olefins R. R. Schrock

24.I.T.

..G. Doyle, Discussion Leader* .Exxon ResearchHomogeneous Activation ofCarbon ilonoxide J. E. Bercavi

California Inst. of Technol

J 3. Gldysz, Discussion LeadU.C.L.A.

Catalysis of Carbon Monoxide-Hydrogen Reactions .R. Pruett

Union Carbide Corporation

Short Papers H. Alper, Session'ChaLzmanU. of Ottawa

Reactions of the CationicCarbene Complex $!i (CO) 2 Fe-CIS') .+with Alkenes and Alkynes 4. Brookhart

U. of North Carolina

Uolybdenum PerfluorocarbaneComplexes D. Reger

U. of South Carolina

Reduction of Coordinated CO byTrialkylborohydvidco; Synthosisof Transition kletal Formyls,

rHytinlnyalkyls, and Aniona J, Gladyss

Page 5: SECURITY rl Form Approved DOCU M ENTATION PAG0E OM …'New Applications of Organomercury,-palladcium, and -rhodium Compounds in Organic Synthesis R. Larock Palladium Catalyzed Allylia

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Tuesdav, August 15

R. Larock, Discussion LeaderIowa State University

Selenium and Silicon in OrganicSynthesis H. J. Reich

U. of WJisconsin - Hadison

G. Posner, Discussioh'LeaderJohns Hopkins University

Recent Developments in theCatalytic or Stoichiometric Useof Copper ialts in OrganicSynthesis J. F. Normant

University of Paris

.D. Bergbreiter, Discussion ITexas A & U

Concerning the Question ofDistinguishing Polar from SingleElectron Transfer Reactions inMain Group Lietal Chemistry E. C. Ashby

Georgia Tech.

Short Paper J, Ncrton, Session ChairmanPrinieton University

A Short, Simple, StereocontrolledSteroid Total Synthesis UsingOrejanocopper Reagents G. Posner

Johns Hopkins: University

Wednebday, August 16

R. P. Hughes, Discussion LeDartmouth College

Organometallic [letallocycles inBonding and l-ichanistic Studies J. J. Cisch

SUNY - Binghamton

H. Richey, Discussion LeadiPenn State University

Organolithium Catalysis of Olefinand Diene Polymerization: Akruitful Area for Research A. Halasa

Firestone, Akron Ohio

Short Papers ..R. Keiter, Session chairmm

Ulycroijan Transfar in DncnaIr•0n tris-VaL.u,,ait-j Cuiajplexus 'S. Ittel

go. l'duPý)nt dellemours & Cc

Page 6: SECURITY rl Form Approved DOCU M ENTATION PAG0E OM …'New Applications of Organomercury,-palladcium, and -rhodium Compounds in Organic Synthesis R. Larock Palladium Catalyzed Allylia

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Yet Another Unexpected Radical'Pathway-in an OrganometallicReaction J. Labinger

U. of Notre Dame

K. Barnett, Discussion LeaderU. of -laissouri, St. Louis

Synthesis via Ligand FreePlatinum Complexes F. G. A. Stone

;,The University, .Bristol, Engl:.

Thursday, August 17

T. tlhitesides , Discussion Le.Eastman Kodak Co.

Transition Zletal Catalyzed OrganicSyntheses J. K. Stille

"Colorado State University

D. Reger, Discussion LeaderU. of South Carolina

New Types of Homogeneous Catalystsand the Hydrogenation of Aromatics P. MI. Nlaitlis

The University, Sheffield

Short Papers D. Singleton, Session Chairmai"Shell Development Company

'New Applications of Organomercury,-palladcium, and -rhodium Compoundsin Organic Synthesis R. Larock

Palladium Catalyzed Allylia Alkylationof Olefins L. Hegedus

Colorado State University

An Improved Catalyst for 1lethyleneLactone Synthesis as a Result ofMechanittic Study J. Norton

Princeýin University

Calorimetric Studies of Reactionsof 14%odium or Iridium Complexes D. Blake

U. of Texas, Arlington

Friday. AusulS

Lo. egedus, Discussion LeaderColorado State University

PalladiuM Catalyzed Reactions ofVinylic 1halides with Amines

I I • A • I I I 9 I I __ I___IIII

Page 7: SECURITY rl Form Approved DOCU M ENTATION PAG0E OM …'New Applications of Organomercury,-palladcium, and -rhodium Compounds in Organic Synthesis R. Larock Palladium Catalyzed Allylia

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S. Ittel, Discussion Leader

Reactions of Co-ordinatedAlkenes and Acetylenes 1-1. Green

The University, BristolEngland

Page 8: SECURITY rl Form Approved DOCU M ENTATION PAG0E OM …'New Applications of Organomercury,-palladcium, and -rhodium Compounds in Organic Synthesis R. Larock Palladium Catalyzed Allylia

1974 GORDONI RESEARCH CONFERENCE O ORGANOIETAL7 XC CLIEVIIISTRYSchedule for Poster Displays

(Authors of poster displays are requested to be available inthe vicinity of -their display to answer questions from 5:15to 5:45 p.m. on the days that their display is scheduled.)

lcnday and Tuesday, August 14,15 (Papers do. 1 throucgh 13)

1. R.A. Laine, D.W. Thonas, L.W. Cary and S.E. 3uttrill, SRIInternational "Applications of the Water-Gas Shift Reaction.Catalytic Act ivakions- f..;akt1iay-. kmn•nei" Drlng 't~adlysi1 oE theWater-Gas Shift Reaction."

2. J.0I. Suggs, Bell Labs"Catalytic Hydroacylation."

3. P.R. Jones and J.G. Shelnut, University of New Hampshire"Uara-Products from reta-Arylcadmium Reagents: A cine-Substitution

4. A.J. Schultz*, J.1I. Williams*, G.D. Stucky"+, S.D. Ittel'and R.R. Schrock#,*Argonne National Laboratory, +University of Illinois,&E.I. dnPont,#iIassachusetts Institute of Technology"Structural liodels for C-H aond Scission. N~eutron DiffractionStudies of an Aliphatic C-H° 0Fe Interaction and an UnusualTa-Alkylidene Complex."

5 V.L. Coedken, P. DeHaven and L. U1arren, Florida State Universit"Linuclear Rhodium(II) Complexel of the Tetramethyltetraazadibenzo-C14jann.-iene Ligand, C2 2 112 2 N4 ': Crystal Structure and ChemicalReactivity."

6. K.1-. Barnett*, D.J. Blumert, T.L. 3rown&, *University of nissouSt. Louis, &University of Iliinois-Urbana"Trimethylamine N-Oxide Promoted Substitution in fletal Carbonyls."

7. L°H. Pignolat and D. Dcughty, University of minnesota"Catalytic Decarbonylation of Aldehydes Using Rh(I) Complexes ofChelating Diphosphine Ligands."

8. V.P. K-irkov and R.Go Wall, Chevron Research Company"CatalYt- -Rearrangement oZ Vinyloxiranes to 2,5-Dihydrofuranes°"

9. P. McArdle and T. Higgins, University College Galway (Ireland)"Selective Imerization of 4-Vinylcyclohexene by Iron CarbonylComplexes."

10. R.H. Crabtree', D.F. Chodosh, H. Felkin& and G.E. Llorris&,*Yale U-nivri-ty, &ICSN, CNRS (Gif-sur-Yvette, France)"uA Trinuclear Iridium Cluster Complex Containing a TricoordinateHydrogen Atom."

11. R.J. ýW£inney and D.A. Pensak, Central Research and DevelopmentDU Pont"Application of holecular Orbital Theovy to Transition Ietal Comple)CAlculation of the Change in Enthalpy for Some Dissociative Processc

Page 9: SECURITY rl Form Approved DOCU M ENTATION PAG0E OM …'New Applications of Organomercury,-palladcium, and -rhodium Compounds in Organic Synthesis R. Larock Palladium Catalyzed Allylia

Poster Displays 1978 G.R.C. Organometallic Chemistry p. 2

12. R.F. Lockwood, U'D. -Hodes,, andT K.U.-"icholas,-Ioston.Co1l~ge"Cobalt-Complexed Propargyl Cations as Interxeiates in OrganicSynthesis."

13. A. Eisenstadt, Tel-Aviv University"A Novel C-Assisted -iOrganotransition Netal Cation: The Protonatiof l-subsituted-2,2,7,7-tetramethyl-3,5-cycloheptadiene Irontricar-bonyl Complexes."1

Wednesday and Thursday, August. 16,17• (Papers Nos. 14 through

14. R.D. Kerber and T. Chiang, State University of New York atStony Brook""q- (Triphenylcyclopropenyl) tricarbonylcobIlt."

15. P.D. Frisch and G.P. Khare, University of M0laine at Orono"Oxidative Addition Reactions of RhCl(CO)(PR3 ) 3 and the CyclopropenIons C3 R3 +, R=Ph, Cl."

16. I. Arai, G.D. Daves, Jr,, Oregon Graduate Center"Palladiuma-Catalyzed Arylation of Enol Ethers and Esters."

17. J.A.K. Howard, J.11. Dassgtt, G.K. Barker, F.G.A. Stone, andiW. Green, University of Bristol."Structural Aspects of Some New fletal Isocyanide Complexes."

18. L.J. Farrugia, J.L. Spencer and F.G.A. Stone, University of nD"S yntheses of Reactive 1iixed-i-ietal Clusters."

19. T.A. George, G.E. Dossard, D.C. Busby, S.D.A. Iske, Jr., andC. Winters, University of Nebraska-Lincoln"Chemlical and Physical Properties of Alkyldiazenido and Alkylhydra-Derivatives of Liolybdenum."

20. D.F. barten, University of Oklahoma"Approaches to Unsaturated Lactone Netal Complexes: Propargyl andAllenyl Alcohols."

21. D. Touchard, H. Le Bozec, A. Gorgues and P. Dixneuf, Universildo Rennes"Activation Towards Electrophiles of Carbon Disulfide and Ileteroal:by Coordination."

22. WI.L. Waltz, 0. Hackelberg, L.A. Dorfman and A. Wojcicki, OhioState University"uPulse Radiolysis Studies of Manganese Carbonyls."

23. P.1.I. Treichel and W.K. Wong, University of Wisconsin"Reactions 6f Coordinatod Phosphiness Synthesis of ChelatingPhosphines."

24. Ch.Elschenbroich, J. Heck, R. Z4bckel and U. Zenneck, Philipps1Jni %Z-siit Za~iirburg"dovel Dis (T-Arene)Chromium Complexes of Condensed Arenes, Dipheny]ant] C.2]Jparacyclophane."

Page 10: SECURITY rl Form Approved DOCU M ENTATION PAG0E OM …'New Applications of Organomercury,-palladcium, and -rhodium Compounds in Organic Synthesis R. Larock Palladium Catalyzed Allylia

Poster Displays- 1976, G.R.C. Organometallic Chemistry p. 3

25. J.S. Bradley, G.". Anse.l and E.tJ. Hill, Exxon Research andEngineering Co."Recent "cork in Ruthenium Carbide Cluster Chemistry."

2G. GCS. LewanCdos, Central idchicjan University"Silver(I) Catalyzed Deuterium Exchancje of Terridinal Acetylenes."

27. N.D. A(aesz and G.D. Jarvinen, University of California, LosAnje les"iRate Study of the Cyclormetalation of cis-licthyl(tribenzylphosi;hine)-(tetracarbonyl) manganese."

28. F. liares, S.E. Jacobson, and R. Tang# Corporate Research,Allied Chemical"Oxidation of cyclic ketones by Hydrocen Peroxide Catalyzed byGroup VI Lietal Peroxo Complexes."

0

Page 11: SECURITY rl Form Approved DOCU M ENTATION PAG0E OM …'New Applications of Organomercury,-palladcium, and -rhodium Compounds in Organic Synthesis R. Larock Palladium Catalyzed Allylia

GORDOil 17ZLS~Z!dC,' COt JFM I'ACES

ORGANO,:-IETALLI C CHEAISTRY

Aucgust 14-19, 197¶3P~roctor Acas-eiay

Andover, Jew !ýaiu.?shire

iR.egistration List

Ci. ' Carriacje FAaAl - Farr.t !iLSq A- iary LowJell StoneCAR-it - -Carr I - Infirr-ary £10 - iortonG - G u' i c IVES - Ives T -Thoreau

MJEW - New Dorm GA - Gannett SUl - Sumr-irfielCdLIA - iiaci~enzie D - Davis

Alper, 'kiowarC! ilon-res iiellanly, F.D. GA 32Univarsity of Ottawa. UniversityDept. Of Cheittistry 3, R~ue AlfreO. ýJlerner()ttaw'a, Ontario, Canac-a K1_1 9..4 G0093 Luihouse Cedex France

Lncjelici, Rubert Sum 2 Bell, Robect i-iLS, 2 1Iow.a State University General Ejectric *:'-,.t:J)lvDep)t. of Ciier'Istry N4i.Iooiai 5L,10, PO ~3oxAmes, Iotia 50311 Schenectady, 1J1Y 12301

`-rnett, John llon-ras belr:iont, Janes GA 3"Doti Cileiical USA Stanford University

aeiEnnj-lam: La.Loratory Chemi. De,)t.!;ox 400) StanforC, CA 9)4305

bercaw, John N~ew 2 4;.rnold, i~ary j.A 3 California Inst. of Tecanulo~jyiAi4co Cilei.'ica1 Co. 1201 E. Calif., Dedt. of Cheiiistry503 South -iddc~e~yay ive. Pasadena, CiA 91125Glanulc:en, k~ 1)03C

Jerybreiter, David New 24ikrnott, Robert GA 5 Texas A6.1 University.1illikun "es.aorch Corporation Dept. of Cher.izLryIron Ore zual College Station, T4X 77ý1*433,'artanb.urc,, SC 293U4

3lake, Daniel Su-i 21Ashiby, Zuiene Swa 3 University of Texas at 1ArlincjtonCeorgia Tecii Ce.ityDpri:nPtlanta, G,,, 3A332 Cheulintry, DaT;: 76nt(6chool of Cli~emistry) A~njoT E1

Zoue'jouk, Philip iLXS 21Jarnatt, iXunnath Suzi 1 11orth Dakota State UniversityUniv. of I.issouri - L~t. Louis Dept. of Chexistry, ;XJD;UDept. of Che, tistry FrjoDý 50102bt. Loouis, ,:0 63121 Fr~o

Lower, Zarton iiLS' 22.:,ah % v1 av~i GA 1 Hercules, Inc.-Gulf flwsonrch r. INVon~nm&ut: c'r. rl~search Center / C5C

i10Orwo 15J30 a'ib.Atntjton#- 041. 19399i'O DraerS230

"Dradloey John G4~ 2Exxon Research & En~jinatirint, Co.PO L~ox 45Linden, 0 701r,

Page 12: SECURITY rl Form Approved DOCU M ENTATION PAG0E OM …'New Applications of Organomercury,-palladcium, and -rhodium Compounds in Organic Synthesis R. Larock Palladium Catalyzed Allylia

-2-

Registration List, Organom1etallic Charaistry

Braunstein, P. CA 2 Clark, Robin CA 4

Universite Louis Pasteur University College London

Institute de Chimie 20 Gordon St.Rue Blaise Pascal F-67003 Strasbourg London WC1 H OAJ U.K.

FranceCohen, yryman(and Niarie) Carr 4

Briody, Robert IlLS 22 zastn=I? Kodak Co.

PPG Industries :iesearch Labs 310.g P2

PO LOX 4026 Rochester, 1Y 14650

Corpus Christi, TX 7G408 Connolly, John ;,ILS 24

Brookhart, iUaurice Sum 21 Uiiversity of Missouri - Kansas Ci

Univ. of North Carolina Dept. Of ChemistryDept. of Chemistry Kansas City, isO 64110Chai~el lull, N4C 27514

Crabtree, Robert I.LS 24

Broussard, Jerry D 4 Yale UniversityCelanese Chemical Co. 225 Prospect St (Dent. of Chernistr

PO BoX 9077 New Haven, CT 06511

Corpus Christi, TX 7340ODanidlS, Willilm NjO 35

Budnik, Richard GA 3Union Carbide CorporationTarrytowt, NY 10591 Daves, Doyle L4LS 26

Oragon Graduate Center

Carrol, Earmon VLS 23 19600 IAj Halter road

Univ. of Arkansas Beaverton, Oregon 97005

Dept. of Chem.Fayetteville, Arkansas 72701 Davis, 1iilliam GA 20

M&T ChemicalS Inc.Corefice, Steven GA 13 PO Box 1104Amoco Chemitcals Corp. RabhaY, NJ 07065

Box 400, .Jarronville Roadiaperville, I11. 50540 Dean, Walter IlLS 26

Emory UniversityCharbonneau, Larry(and Kathryn) Dept. of Chemistry

Carr 3 Atlanta, GA 30322

Celanese Research Company86 Morris AVG Dessau, Ralph Non-res

Summit, NJ 07901 Mobil Res. & DeV. Corp.Box 1025

Chiang, Chin-Shu VULS 37 Princeton, NJ 08540

Oxirane InternationalTechnical Center 201 College Rd E. Devon, Thomas(and Arlene) Carr 5

Princeton, NJ 03540 Texas Eastman Co.Po Box 7444 Resar-h Division

Christianson, Robert CA 19 Longview, TX 75602

Sterling tlinthrop Res. InatituleColtumbia Turnpike Dilworth, Jon CA 4

Ronesolaer, My 12144 Unit of Nitrogen FixationUniversity of Sussex, aighton,

Clark,, George MS 23 DLN1 9Q0Cordova Chemicfal Co.

P0 aox 134001 Bldg 0525 D1iauf, Pierre Henri G 22

nerjmmnto, CA 94813 University of Waterlooc/o Prof. A.J. CARTY

Dept. of CharidstryWaterloo Ontario N2L 3GI Canadr

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-3-Registration List, .Organometallic Chemistry

Dolling, Ulf i4on-res Fentcn, Donald G 23£Ierck Sharp & Dohne Res. Lab. Union Oil Company of CaliforniaPO Box 2000, R 801 202 PO bo; 76 Research DepartmentRahway, NJ 07065 Brea, aA 92621

Douglas, Walter 1.1LS 27 Forgi(;ne, Peter GA 24COP, Inc 10 UoP Plaza American Cyanamid Co.Algonquin and 1;t. Prospect Rds. 1937 W. Main St.Des Plaines, Ill. 60016 Stamford, CT 06905

Doyle, Gerald D 23 Frankel, Edwin GA 25Exxon Research & Engineering Co. Northern Re~onal Res. CenterCorporate Res. Labs. P0 Box 45 FR, SEA, USDALinden, J 07036 M15 worth University

e Peoria, Ill. 61604Dubeck, Lhlichael GA 21Ethyl Corp. Frisch, Douglas G 231600 17 8 •Lle Rd University of FaineFerndale, alI Dept. of Chemistry11 Orono, NE 04473Ersch, John Sum 22S, Y at ninghamiton George, Adrian MA 21Dept. of Chemistry University of NebraskaBinghamton, NY 13901 Chemistry Dept.

Lincoln, NE 68588Eisenstadt, Amihai Farm 3Abic Pharm. & Chem. Ltd. Gibson, Thomas(and Chris) Ives 34Ramat-Gan Israel Prccter & Gamble Co.

Mliami Valley LabsEhmann, 11illiam aILS 38 Cincinnati, OH 45247SCM OrganicsPO Box 309 Gladysz, John Sam 24Jacksonville, FL 32201 UCLA Chemistry Dept.

405 Hilgard AveEllis, John D 21 Los Angeles, CA 90024Univ. of kiinnesotaDept. of Chem, Kolthoff & Smith Goedken, Virgil 1A 21

Halls Florida State U.1Iinneapolis, 12N 55455 Dept. of Chemistry

Elschenbroith',, Christoph(and Ellen) Tallahassee, FL 32306

Farm 2 Graham, W.A.G. (and Sydna) Ives 2=achbereich Chemie, Univ. of .arburg University of AlbertaLahnburge Dept. of ChemistryD-355 Niarburg U-Gormany Edmonton, Alberta, Canada TGG2G2Engebrecht, Ronald GA 22 Green, AiLchael Ives 32Eastman Kodak Co. The UniversityResoarch Laboratories Dept. of Inorganic Chemistry1660 Lake Ave Bristol DS8 ITS, U.K,Rochester, NY 14650

Halasa, Adel Farm 1Erickson, Robert GA 23 Firestone Central ResearchG.D. Searle & Co.Box 5110chtrnajo, Ill. 60016

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-4-Registration List, Organometallic Chemistry

Heck, Richard Sum 23 Jones, Paul 14A 23University of Delaware University of New HampshireDept. of Chemistry Dept. of Chemistryi4ewark, DE 19711 Durham, NH 03824

1

Hegedus, Louis Sum 24 Huang, J.N.. GA 29Colorado State University Firestone Tire & RubberDept. of Chemistry Central Research Lab.Fort Collins, Colorado 80521 1200 Firestone Parkway

Akron, OH 44317Henry, Ilalcolm Non-resUS "*iry o1atick Pps. & Day. Command Kaesz, Herbert Farm 4Kansas Street Dept. of Chemistry UCLAWatick, MA 01760 405 Hlilgard Ave

Los Angeles, CA 90024Hewertson, ilarren(and Charles Cove11)

Ives 31 Kaplan, Barbara MA 5Imperial Chemical Industries Ltd., Union Carbide Corp. R / DCorporate Lab. P0 Box 3361PO Box 11, The Heath, Runcorn South Charleston, W. Va 25303Cheshire, England

Kaus, MIalcom T 22Hillman, Manny GA 27 Stauffer Chemical Co.Brookhaven National Laboratory Eastern Research CenterBldg 801 Dcbbs Ferry, RY 10522Upton, NY 11973

Keiter, Richard New 4Hoffman, Norris MLS 38 Eastern Illinois UniversityJ.T. Baker Chemical Company Dept. of Chemistry222 Red School Lane/ Research Charleston, Ill. 61920Phillipsburg, UJ 08365

Kerber, Robert T 24Howard, Judith MA 4 SrMY at Stony BrookUniversity of Bristol Dept. of ChemistryCantoucs Close, Bristol Stony Brook, NY 11794BS81TS England

Kisch, Hlorst D 4Hughes, Russell Farm 1 Institut fur Strahlen :hemie iDartmouth College Nax-Planck - Inst. F. Kohlen ForscChemistry Department 1 * Stiftstr 34-36Hanover, MH 03755 D-4330 Mulheim, W-Germany

Husk, Ronald M.A 23 Knifton, John T 31U.S. Army Research Office Texaco Inc.PO Box 12211 PO Box 4128Research Triangle Park, NC 27709 Austin, TX 78765

Ittel, Steven Now 1 Kurkov, Victor GA 30ELI. duPont de Nemours & Co. Chevron Research Co.Central Research 576 Standard AveExperimentAl ftiQ,Pn E32n/.6 CRAM Richmond, CA 94802Wilmington, DE 19098

Labinger, Jay Sum 4Johnson, Jack GA 28 University of Notre DameExxon Research and Engineering Dept. of ChemistryCorporate flea. Lab. P0 Box 45 Notre Dame, Ind. 46556Linden, NJ 07036

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-5-Registration List, Organometallic Chemistry

Laine, Richard T 31 ilares, Frank G 22SRI International Allied Chemical Corporation333 Ravenswood Ave / Chemistry Corporate Research CenterMenlo Park, CA 94025 PO Box 1021 R

Morristown, NJ 07960Larock, Richard Sum 4Iowa State University 1.Iasler, t*illiam NLS 31Dept. of Chemistry DoF. Goodrich R&D CenterAmes, Iowa 50011 9921 Brecksville Rd.

Brecksville, OH 44141Lawrence, John(and Christine) I 3Goodyear Tire & Rubber Co. Mat: szko, Anthony HILS 27-142 Goodyear Blvd Air Force Office of Scientific ResAkron, OH 44316 Bolling AFB Bldg 410

Washington, DC 20332Legzdin, Peter MLS 25The University of 3ritish Columbia 1-.lauldin, Charles G 32Department of Chamistry Exxon Research & Development LabsVancouver, B.C. Canada V6T 11-5 PO Box 2226

Baton Rouge, Louisiana 70C21Lewan~os, Glenn T 32

Central ilichigan Univ. Z-cArdle, Patrick NO 25Dept. of Chemistry University CollegeMt. Pleasant, 11I 48059 Chemistry Department

Galwa. IrelandLyons, James(and lHarlyne) Carr 6Suntech, Inc. -McCoy, John Won-resApplied nn, Chemicals Division ARCO Chemical Co. / Res. & Eng.PO iox 1135' 500 South Ridgew'ay AveDiarcus, Hook, PA 19061 Glenolden, PA 19036

Ila, King 120 35 NcGinnis, James 1hA 22Celanese Research CompanyNiorris Court

hiador, Irving(and Shirley) Cart C summit, NJ 07901Allied Chemicali3ox 1021 R M.cKinney, Ronald Wiew 1

m4orristown, NJ 07960 E.I. duPont de Nemours & Co.Central Research

Maitlis, P.M. D 2 Experimental Station E328/327 CR&The University Wilmington, DE 19098Department of ChemistryShiffield, England Mocella, iitichael Carr 9

Air Products and Chemicals, Inc.kianchand, Percy T 32 Corporate Research & DevelopmenntlVpffmann - La Roche Inc. PO Box 538k,1,M9,darh f.ivision Allentown, PA 10105Nutley, IJJ 07110

i4orrell, Dennis Carr 7.larianelli, Robert DILS-37 Union Carbida CorporationDepartment of Energy P0 Box 8361Division of Chemical Sciences; .. Charleston, WV 25314office of 3a.ic Enorgy SieneoiiWashington, DC 20545

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l6-Pegistration List, Orcjanometallic Chemistry

Murib, Jawad(and Jeanne)- T I Posner, Gary D 1U.S. Industrial Chem. Co. (USI) The Johns Hopkins University1275 Section Rd. Dept. of ChemistryCincinnati, OH 45237 Baltimore, MD 21218

Nicholas, Kenneth 11LS 31 Pruett, Roy New 4Boston College Union Carbide CorporationChemistry Dept. Chem. and plasticsChestnut 11ill, NA 02167 PO Box 83G1

South Charleston, WV 25303INormant D 3University of Paris Raksis, Joseph(and Elaine) 110 3tour 44 - 4 Place Jussieu 75230. Paris ;I.R. Grace & Co., Research DivisitCedex 05 France 7379 Route 32

Columbia, ID 21044Norton, Jack D 22Princeton University Ramsden, Hugh MIO 21Chemistry Dept. Rhodia, IncPrinceton,iNJ 00540 297 Jersey Ave Bldg 28

New Brunswick, NJ 00903Orchin, £iilton(and Ruth) M-1O 2University Cincinnati Rankel, Lillian I 2Dept. of Chemistry liobil Research & Development Corp.Cincimnati, OH 45221 PO Box 1025,

Princeton, N;J 03540Palacas, James G 32

Rawls, Rebecca MA 2Chemical & Engineering News

Partenheimer, UJ. 110 31 1155 16th St. N.W.Amoco Chemical Corporation Washington, DC 20036PO Box 400Naperville, Ill 60540 Reger, Daniel New 3

U. of South CarolinaPaxson, Timm Z.10 31 Dept. of Chemisti.yShell Development Co. Columbia, SC 29208Box 1380Houston, TX 77001 Reich, Hans New 2

University of WisconsinPearce, Ronald CA 2 Dept. of ChemistryImperial Chemical Industries M4adison, VI 53706Petrochemicals DivisionPO Box 90 Wilton M~iddlesbrough Reu-ers, Hans 140 32Cleveland TS6 OJE England Univ. of Alberta

Dept. of ChemistryPiccolini, Richard MA 24 Edmonton, Alta., CanadaRohm and Haas Co.Norristown and McKean RdS. Richey, Herman New 21Spring House, PA 19477 Penn State University

Dept. of Chemistry, 152 DaveyPignol.t, Louis D 21 University Park, PA 16C02University of ,innoestzaDept. of Chcpmiutry Roundhill, D.M. XS 32Mi'nna.&,o's. M4 55455 Washington State Univ.

Chemistry DepartmzntPullmau, WA 99164

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-7-Registration List, Organometallic Chemistry

Scheben, J.A. Sargents Lake Shore Spencer, John(and Herete) ko 24Cottages University of Bristol

School of ChemistryU.S. Industrial-Chemicals - Co. Cantocks Close1275 Section Rd. Bristol, England DS8 ITSCincinnati, OH 45237

Stille, John New 23Schrock, Richard New 21 Colorado State UniversityI-LIT Dept. of ChemistryDept. of Chemistry 6-331 Fort Collins, CO 60523Cambridge, iAA 02139

Stone, F.G.A. D 24Schultz, Arthur 1,10 33 Bristol UniversityArgonne tiational Laboratory Bristol B8 U.K.9700 S. Cass Ave.Chemistry Division Suggs, J. !Willian GA 30Argonne, IL 60439 Bell Labs

600 flountain AveScott, Allen 140 33 Hurray Hill, NJ 07974The Upjohn Company7265-91-1 Sweigart, Dwight GA 4Kalamazoo, iLI 49001 Swarthmore College

Dept. of ChemistrySeres, Josef(and Thomas) "MO 34 Swarthmore, PA 190'uSandoz, Inc.Bldg. 407 Research & Development Traichpl, Paul Sun 1E. Hanover, NJ 07936 University of Wisconsin

Dept. of ChemistryShcherbakov, V.I. MO 22 M~adison, WI 5370514ITDept. of Chemistry Wagner, Klaus M.LS 34Cambridge, IoA 02139 Hercules Incorporated

Hercules Research CenterSheats, John~and Mlargaret) T 25 wilmington, DE 19899Rider CollegeLawrenceville, NJ 08648 Wagner, Frank GA 36

St, m Chemicals Inc.Shubkin, Ronald MD 26 7 Mlulliken Way -PO Box 108Ethyl Corp. Dexter Industrial Park1600 W. Eight H1ile Rd. Newburyport, 1A 01950Ferndale, IT 40220 ..

Whitesides, Thomas G 24Singleton, David New 22 Eastman Kodak Co.Shell Davelopment Company Lake AvePO Box 1300 Rochester, NJ 14607Houston, TX 77001

WoJcicki, Andrew D 1Smith, James(and Helen) Ives 22 The Ohio State UnivorsityUniversity of Waterloo Dept. of ChemistryDapt. of Chemistry rnlummnn, Of 43210

Sorrell, Thomas GA 31 Yoo, Jin ILS 35Atlantic Richfield Company

Univ. of North Carolina Harvey Research CenterDept. of Chemistry 400 E. Sibley Blvd.Chno Hi*11, NC 27514 Harvey, Ii f0426

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-8-

i•3gistration List, Organometallic Chemistry

Yoshida, Takao Non-resInternational Flavors & FragrancesResearch and Developmekit Center1515 State HighwayUnion Beach, iWJ 07735

Zampini, Anthony GA 38v.ons anto, Co800 N. Lindberch Blvd.St. Louis, 1iO 63166

eI