sections 3.3 & 3.4covalent bonding and lewis structures learning goals: writing valid lewis...
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Sections 3.3 & 3.4 Covalent Bonding and Lewis Structures
Learning goals:
Writing valid Lewis structures for molecular substances
Predicting molecular geometry from Lewis structures (VSEPR theory)
Understanding electronegativity and how this concept allows the distinction between polar bonds and non-polar bonds
Using Lewis structures to determine whether a molecule has a dipole moment or not
Using the octet rule to compute formal charges on atoms and multiple bonding between atoms
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Sections 3.3 & 3.4 Covalent Bonding and Lewis Structures
(1)Lewis “dot” (electron) structures of valence electrons for atoms
(2)Use of Periodic Table to determine the number of “dots”
(3)Use of Lewis structures to describe the electronic structures of atoms and molecules
(4)Works best for covalent bonds and for elements in the first full row of the Periodic Table: H, He, Li, Be, B, C, N, O, F, Ne
(5)Works with restrictions for second full row of the Periodic Table and beyond: Na, Mg, Al, Si, P, S, Cl, Ar
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Some issues about Lewis Structures to be discussed:
(1) Drawing “valid” Lewis structures which follow the “octet” rule (holds almost without exception for first full row)
(2) Drawing structures with single, double and triple bonds
(3) Dealing with isomers (same composition, different constitution)
(4) Dealing with resonance structures (same constitution, different bonding between atoms)
(5) Dealing with “formal” charges on atoms in Lewis structures
(6) Dealing with violations of the octet rule:
Molecules which possess an odd number of electrons
Molecules which are electron deficient
Molecules which are capable of making more than four covalent bonds
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Lewis “dot-line” representations of atoms and molecules
(1) Electrons of an atom are of two types: core electrons and valence electrons. Only the valence electrons are shown in Lewis dot-line structures.
(2) The number of valence electrons is equal to the group number of the element for the representative elements.
(3) For atoms the first four dots are displayed around the four “sides” of the symbol for the atom.
(4) If there are more than four electrons, the dots are paired with those already present until an octet is achieved.
(5) Ionic compounds are produced by complete transfer of an electron from one atom to another.
(6) Covalent compounds are produced by sharing of one or more pairs of electrons by two atoms.
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The valence capacity of an atom is the atom’s ability to form bonds with other atoms. The more bonds the higher the valence.
The valence of an atom is not fixed, but some atoms have typical valences which are most common:
Carbon: valence of 4Nitrogen: valence of 3 (neutral molecules) or 4 (cations)Oxygen: valence of 2 (neutral molecules) or 3 (cations)Fluorine: valence of 1(neutral molecules) or 2 (cations)
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Covalent bonding and Lewis structures
(1)Covalent bonds are formed from sharing of electrons by two atoms.
(2)Molecules possess only covalent bonds.
(3)The bedrock rule for writing Lewis structures for the first full row of the periodic table is the octet rule for C, N, O and F: C, N, O and F atoms are always surrounded by eight valence electrons.
(4) For hydrogen atoms, the doublet rule is applied: H atoms are surrounded by two valence electrons.
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3.4Covalent Bonds
and LewisStructures
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• In 1916 G. N. Lewis proposed that atomscombine in order to achieve a more stableelectron configuration.
• Maximum stability results when an atomis isoelectronic with a noble gas.
• An electron pair that is shared between two atoms constitutes a covalent bond.
The Lewis Model of Chemical Bonding
The Lewis Model of Chemical Bonding
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Covalent Bonding in H2
Covalent Bonding in H2
HH .. HH..
Two hydrogen atoms, each with 1 electron,Two hydrogen atoms, each with 1 electron,
can share those electrons in a covalent bond.can share those electrons in a covalent bond.
HH :: HH
• Sharing the electron pair gives each hydrogen an electron configuration analogous to helium.
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Covalent Bonding in F2
Covalent Bonding in F2
Two fluorine atoms, each with 7 valence electrons,Two fluorine atoms, each with 7 valence electrons,
can share those electrons in a covalent bond.can share those electrons in a covalent bond.
• Sharing the electron pair gives each fluorine an electron configuration analogous to neon.
....
....FF.. FF..:: ::
....
....
FF :: FF:: ::........
....
....
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The Octet RuleThe Octet Rule
• The octet rule is the most useful in cases involving covalent bonds to C, N, O, and F.
FF :: FF:: ::........
....
....
In forming compounds, atoms gain, lose, or In forming compounds, atoms gain, lose, or share electrons to give a stable electron share electrons to give a stable electron configuration characterized by 8 valence configuration characterized by 8 valence electrons.electrons.
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ExampleExampleExampleExample
CC ........
FF::..........
Combine carbon (4 valence electrons) andCombine carbon (4 valence electrons) andfour fluorines (7 valence electrons each)four fluorines (7 valence electrons each)
to write a Lewis structure for CFto write a Lewis structure for CF44..
:: FF::........CC
:: FF::........
:: FF::........:: FF::
....
....
The octet rule is satisfied for carbon and The octet rule is satisfied for carbon and each fluorine.each fluorine.
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ExampleExampleExampleExample
It is common practice to represent a covalentIt is common practice to represent a covalentbond by a line. We can rewritebond by a line. We can rewrite
:: FF::........CC
:: FF::........
:: FF::........:: FF::
....
....
....
CCFF
FF
FF
FF
....
............:: ::
:: ::
:: ::
....
asas
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3.4Double Bonds and
Triple Bonds
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Inorganic examplesInorganic examplesInorganic examplesInorganic examples
CC:: :: ::OO....::OO
....:: :: CC ::OO
....OO....::
:: :: ::NN::CC::HH ::NNCCHH
Carbon dioxideCarbon dioxide
Hydrogen cyanideHydrogen cyanide
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Organic examplesOrganic examplesOrganic examplesOrganic examples
EthyleneEthylene
AcetyleneAcetylene:: :: ::CC::CC::HH HH CCCCHH HH
CC:: ::CC....
HH :: ::....
HHHHHH
CC CC
HH HH
HHHH
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3.4Formal Charges
• Formal charge is the charge calculated for an atom in a Lewis structure on the basis of an equal sharing of bonded electron pairs.
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Nitric acidNitric acid
.... ::
....HH OO
OO
OO
NN
::
::....
....
• We will calculate the formal charge for each atom in this Lewis structure.
Formal charge of HFormal charge of H
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Nitric acidNitric acid
.... ::
....HH OO
OO
OO
NN
::
::....
....
• Hydrogen shares 2 electrons with oxygen.• Assign 1 electron to H and 1 to O.• A neutral hydrogen atom has 1 electron.• Therefore, the formal charge of H in nitric acid is
0.
Formal charge of HFormal charge of H
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Nitric acidNitric acid
.... ::
....HH OO
OO
OO
NN
::
::....
....
• Oxygen has 4 electrons in covalent bonds.• Assign 2 of these 4 electrons to O.• Oxygen has 2 unshared pairs. Assign all 4 of these
electrons to O.• Therefore, the total number of electrons assigned to
O is 2 + 4 = 6.
Formal charge of OFormal charge of O
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Nitric acidNitric acid
.... ::
....HH OO
OO
OO
NN
::
::....
....
• Electron count of O is 6.
• A neutral oxygen has 6 electrons.
• Therefore, the formal charge of O is 0.
Formal charge of OFormal charge of O
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Nitric acidNitric acid
.... ::
....HH OO
OO
OO
NN
::
::....
....
• Electron count of O is 6 (4 electrons from unshared pairs + half of 4 bonded electrons).
• A neutral oxygen has 6 electrons.• Therefore, the formal charge of O is 0.
Formal charge of OFormal charge of O
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Nitric acidNitric acid
.... ::
....HH OO
OO
OO
NN
::
::....
....
• Electron count of O is 7 (6 electrons from unshared pairs + half of 2 bonded electrons).
• A neutral oxygen has 6 electrons.• Therefore, the formal charge of O is -1.
Formal charge of OFormal charge of O
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Nitric acidNitric acid
.... ::
....HH OO
OO
OO
NN
::
::....
....
• Electron count of N is 4 (half of 8 electrons in covalent bonds).
• A neutral nitrogen has 5 electrons.
• Therefore, the formal charge of N is +1.
Formal charge of NFormal charge of N
––
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Nitric acidNitric acid
.... ::
....HH OO
OO
OO
NN
::
::....
....
• A Lewis structure is not complete unless formal charges (if any) are shown.
Formal chargesFormal charges
––
++
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Formal ChargeFormal ChargeFormal ChargeFormal Charge
Formal charge = Formal charge =
group numbergroup numberin periodic tablein periodic table
number ofnumber ofbondsbonds
number ofnumber ofunshared electronsunshared electrons
–– ––
An arithmetic formula for calculating formal charge.An arithmetic formula for calculating formal charge.
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"Electron counts""Electron counts" and formal and formal charges in NHcharges in NH44
+ + and BFand BF44--
11
44
NN
HH
HH HH
HH
++77
44
....
BBFF
FF
FF
FF
....
............:: ::
:: ::
:: ::
....
––
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3.5Drawing Lewis Structures
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Constitution
• The order in which the atoms of a molecule are connected is called its constitution or connectivity.
• The constitution of a molecule must be determined in order to write a Lewis structure.
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• Step 1: The molecular formula and the connectivity are determined by experiment.
Table 1.4 How to Write Lewis Structures
Table 1.4 How to Write Lewis Structures
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• Step 1: The molecular formula and the connectivity are determined by experiment.
• Example:Methyl nitrite has the molecular formula CH3NO2. All hydrogens are bonded to carbon, and the order of atomic connections is CONO.
Table 1.4 How to Write Lewis Structures
Table 1.4 How to Write Lewis Structures
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• Step 2: Count the number of valence electrons. For a neutral molecule this is equal to the number of valence electrons of the constituent atoms.
Table 1.4 How to Write Lewis Structures
Table 1.4 How to Write Lewis Structures
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• Step 2: Count the number of valence electrons. For a neutral molecule this is equal to the number of valence electrons of the constituent atoms.
• Example (CH3NO2):
Each hydrogen contributes 1 valence electron. Each carbon contributes 4, nitrogen 5, and each oxygen 6 for a total of 24.
Table 1.4 How to Write Lewis Structures
Table 1.4 How to Write Lewis Structures
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• Step 3: Connect the atoms by a covalent bond represented by a dash.
Table 1.4 How to Write Lewis Structures
Table 1.4 How to Write Lewis Structures
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• Step 3: Connect the atoms by a covalent bond represented by a dash.
• Example:Methyl nitrite has the partial structure:
Table 1.4 How to Write Lewis Structures
Table 1.4 How to Write Lewis Structures
CC OO NN OOHH
HH
HH
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• Step 4: Subtract the number of electrons in bonds from the total number of valence electrons.
Table 1.4 How to Write Lewis Structures
Table 1.4 How to Write Lewis Structures
CC OO NN OOHH
HH
HH
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• Step 4: Subtract the number of electrons in bonds from the total number of valence electrons.
• Example:24 valence electrons – 12 electrons in bonds. Therefore, 12 more electrons to assign.
Table 1.4 How to Write Lewis Structures
Table 1.4 How to Write Lewis Structures
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• Step 5: Add electrons in pairs so that as many atoms as possible have 8 electrons. Start with the most electronegative atom.
Table 1.4 How to Write Lewis Structures
Table 1.4 How to Write Lewis Structures
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• Step 5:
Add electrons in pairs so that as many atoms as
possible have 8 electrons. Start with the most
electronegative atom.
• Example:
The remaining 12 electrons in methyl nitrite are
added as 6 pairs.
Table 1.4 How to Write Lewis Structures
Table 1.4 How to Write Lewis Structures
....CC OO NN OOHH
HH
HH
........ ::
.... ....
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• Step 6:
If an atom lacks an octet, use electron pairs on an
adjacent atom to form a double or triple bond.
• Example:
Nitrogen has only 6 electrons in the structure shown.
Table 1.4 How to Write Lewis Structures
Table 1.4 How to Write Lewis Structures
....CC OO NN OOHH
HH
HH
........ ::
.... ....
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• Step 6:
If an atom lacks an octet, use electron pairs on an
adjacent atom to form a double or triple bond.
• Example:
All the atoms have octets in this Lewis structure.
Table 1.4 How to Write Lewis Structures
Table 1.4 How to Write Lewis Structures
........
CC OO NN OOHH
HH
HH
....::....
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• Step 7:
Calculate formal charges.
• Example:
None of the atoms possess a formal charge in this
Lewis structure.
Table 1.4 How to Write Lewis Structures
Table 1.4 How to Write Lewis Structures
........
CC OO NN OOHH
HH
HH
....::....
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• Step 7:
Calculate formal charges.
• Example:
This structure has formal charges; is less stable
Lewis structure.
Table 1.4 How to Write Lewis Structures
Table 1.4 How to Write Lewis Structures
........
CC OO NN OOHH
HH
HH
.... ::....++ ––
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Condensed structural formulas
• Lewis structures in which many (or all) covalent bonds and electron pairs are omitted.
HH
OO
CC CC CC
HH HH HH
HH
HHHH :: ::
HH
can be condensed to:can be condensed to:
CHCH33CHCHCHCH33
OHOH
(CH(CH33))22CHOHCHOHoror
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Bond-line formulas
• Omit atom symbols. Represent structure by showing bonds between carbons and atoms other than hydrogen.
• Atoms other than carbon and hydrogen are called heteroatoms.
CHCH33CHCH22CHCH22CHCH3 3 is shown asis shown as
CHCH33CHCH22CHCH22CHCH22OHOH is shown asis shown as
OHOH
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Bond-line formulas
• Omit atom symbols. Represent structure by showing bonds between carbons and atoms other than hydrogen.
• Atoms other than carbon and hydrogen are called heteroatoms.
HH ClClCC
CC
HH22CC
HH22CC
CHCH22
CHCH22
HHHH
is shown asis shown as
ClCl
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3.5Constitutional Isomers
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Constitutional isomers
• Isomers are different compounds that have the same molecular formula.
• Constitutional isomers are isomers that differ in the order in which the atoms are connected.
• An older term for constitutional isomers is “structural isomers.”
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A Historical Note
• In 1823 Friedrich Wöhler discovered that when ammonium cyanate was dissolved in hot water, it was converted to urea.
• Ammonium cyanate and urea are constitutional isomers of CH4N2O.
• Ammonium cyanate is “inorganic.” Urea is “organic.” Wöhler is credited with an important early contribution that helped overturn the theory of “vitalism.”
NHNH44OCNOCNAmmonium cyanateAmmonium cyanate
HH22NCNHNCNH22
OO
UreaUrea
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NitromethaneNitromethane Methyl nitriteMethyl nitrite
.... ::
HH CC
OO
OO
NN
::
::....
––
++
HH
HH
Examples of constitutional isomers
• Both have the molecular formula CH3NO2 but the atoms are connected in a different order.
....CC OO NN OOHH
HH
HH
....::.... ....
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3.5Resonance
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two or more acceptable octet Lewis structures
may be written for certain compounds (or ions)
Resonance
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• Step 6:
If an atom lacks an octet, use electron pairs on an
adjacent atom to form a double or triple bond.
• Example:
Nitrogen has only 6 electrons in the structure shown.
Table 1.4 How to Write Lewis Structures
Table 1.4 How to Write Lewis Structures
....CC OO NN OOHH
HH
HH
........ ::
.... ....
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• Step 6:
If an atom lacks an octet, use electron pairs on an
adjacent atom to form a double or triple bond.
• Example:
All the atoms have octets in this Lewis structure.
Table 1.4 How to Write Lewis Structures
Table 1.4 How to Write Lewis Structures
........
CC OO NN OOHH
HH
HH
....::....
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• Step 7:
Calculate formal charges.
• Example:
None of the atoms possess a formal charge in this
Lewis structure.
Table 1.4 How to Write Lewis Structures
Table 1.4 How to Write Lewis Structures
........
CC OO NN OOHH
HH
HH
....::....
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• Step 7:
Calculate formal charges.
• Example:
This structure has formal charges; is less stable
Lewis structure.
Table 1.4 How to Write Lewis Structures
Table 1.4 How to Write Lewis Structures
........
CC OO NN OOHH
HH
HH
.... ::....++ ––
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•same atomic positions
•differ in electron positions
more stable more stable Lewis Lewis
structurestructure
less stable less stable Lewis Lewis
structurestructure
........
CC OO NN OOHH
HH
HH
.... ::....++ ––
........
CC OO NN OOHH
HH
HH
....::....
Resonance Structures of Methyl Nitrite
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•same atomic positions
•differ in electron positions
more stable more stable Lewis Lewis
structurestructure
less stable less stable Lewis Lewis
structurestructure
........
CC OO NN OOHH
HH
HH
.... ::....++ ––
........
CC OO NN OOHH
HH
HH
....::....
Resonance Structures of Methyl Nitrite
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• Electrons in molecules are often delocalized
between two or more atoms.
• Electrons in a single Lewis structure are
assigned to specific atoms-a single Lewis structure
is insufficient to show electron delocalization.
• Composite of resonance forms more accurately
depicts electron distribution.
Why Write Resonance Structures?
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•Ozone (O3)
–Lewis structure of ozone shows one double bond and one single bond
Expect: one short bond and one Expect: one short bond and one long bondlong bond
Reality: bonds are of equal length Reality: bonds are of equal length (128 pm)(128 pm)
Example
OO OO••••
OO••••
••••••••••••••••––++
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•Ozone (O3)
–Lewis structure of ozone shows one double bond and one single bond
Resonance:Resonance:
Example
OO OO••••
OO••••
••••••••••••••••––++
OO OO••••
OO••••
••••••••••••••••––++
OO OOOO••••
••••••••••••••••
–– ++
••••
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3.7The Shapes of Some Simple
Molecules
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•tetrahedral geometry•H—C—H angle = 109.5°
Methane
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• tetrahedral geometry•each H—C—H angle = 109.5°
Methane
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• The most stable arrangement of groups attached to a central atom is the one that has the maximum separation of electron pairs(bonded or nonbonded).
Valence Shell Electron Pair Repulsions
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•bent geometry•H—O—H angle = 105°
but notice the tetrahedral arrangement but notice the tetrahedral arrangement of electron pairsof electron pairs
OOHH
....
HH
::
Water
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•trigonal pyramidal geometry•H—N—H angle = 107°
but notice the tetrahedral arrangement but notice the tetrahedral arrangement of electron pairsof electron pairs
NNHH
HH
HH
::
Ammonia
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•F—B—F angle = 120°• trigonal planar geometry
allows for maximum separationof three electron pairs
Boron Trifluoride
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• Four-electron double bonds and six-electron triple bonds are considered to be similar to a two-electron single bond in terms of their spatialrequirements.
Multiple Bonds
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•H—C—H and H—C—Oangles are close to 120°
•trigonal planar geometry
CC OOHH
HH
Formaldehyde: CH2=O
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•O—C—O angle = 180°•linear geometry
OO CC OO
Figure 1.12: Carbon Dioxide
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3.7:Polar Covalent Bonds and Electronegativity
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ElectronegativityElectronegativityElectronegativityElectronegativity
•An electronegative element attracts electrons.•An electropositive element releases electrons.
Electronegativity is a measure of an element to attract electrons toward itself when bonded to another element.
Electronegativity is a measure of an element to attract electrons toward itself when bonded to another element.
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Pauling Electronegativity ScalePauling Electronegativity ScalePauling Electronegativity ScalePauling Electronegativity Scale
1.0
Na
0.9
Li Be B C N O F
1.5
Mg
1.2
2.0
Al
1.5
2.5
Si
1.8
3.0
P
2.1
3.5
S
2.5
4.0
Cl
3.0
•Electronegativity increases from left to rightin the periodic table.
•Electronegativity decreases going down a group.
•Electronegativity increases from left to rightin the periodic table.
•Electronegativity decreases going down a group.
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• The greater the difference in electronegativitybetween two bonded atoms; the more polar the bond.
GeneralizationGeneralization
nonpolar bonds connect atoms ofnonpolar bonds connect atoms ofthe same electronegativitythe same electronegativity
H—HH—H ::NN NN::FF::........FF::
....
....
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• The greater the difference in electronegativitybetween two bonded atoms; the more polar the bond.
GeneralizationGeneralization
polar bonds connect atoms ofpolar bonds connect atoms ofdifferent electronegativitydifferent electronegativity
::OO CC
FF::........HH
OO........HH
HH
OO::.... ....
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3.7Molecular Dipole Moments
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++——
not polarnot polar
• A substance possesses a dipole moment if its centers of positive and negative charge
do not coincide. = e x d
• (expressed in Debye units)
Dipole Moment
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——++
polarpolar
• A substance possesses a dipole moment if its centers of positive and negative charge
do not coincide. = e x d
• (expressed in Debye units)
Dipole Moment
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•molecule must have polar bonds
–necessary, but not sufficient
•need to know molecular shape
–because individual bond dipoles can cancel
OO CC OO++-- --
Molecular Dipole Moments
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OO CC OO
Carbon dioxide has no dipole moment; Carbon dioxide has no dipole moment; = 0 D = 0 D
Molecular Dipole Moments
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= 1.62 D= 1.62 D = 0 D= 0 D
Carbon tetrachlorideCarbon tetrachloride DichloromethaneDichloromethane
Comparison of Dipole Moments
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Resultant of theseResultant of thesetwo bond dipoles istwo bond dipoles is
= 0 D= 0 D
Carbon tetrachloride has no dipoleCarbon tetrachloride has no dipolemoment because all of the individualmoment because all of the individualbond dipoles cancel.bond dipoles cancel.
Resultant of theseResultant of thesetwo bond dipoles istwo bond dipoles is
Carbon tetrachloride
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Resultant of theseResultant of thesetwo bond dipoles istwo bond dipoles is
= 1.62 D= 1.62 D
Resultant of theseResultant of thesetwo bond dipoles istwo bond dipoles is
The individual bond dipoles do notThe individual bond dipoles do notcancel in dichloromethane; it hascancel in dichloromethane; it hasa dipole moment.a dipole moment.
Dichloromethane