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2017-10-04_rwL / 1 SOLPOL-4/5: NEUARTIGE KOLLEKTORSYSTEME AUS KUNSTSTOFF MOTIVATION, ZIELSETZUNGEN UND HIGHLIGHTS Reinhold W. LANG, Gernot M. WALLNER und Jörg FISCHER Institute of Polymeric Materials and Testing Johannes Kepler University Linz, Austria Tagung: IEA SHC Task 54 Kosteneffiziente solarthermische Systeme Johannes Kepler Universität Linz 04. Oktober, 2017 A science-driven Austrian research initiative by JKU-IPMT for innovations in solar technologies with polymeric materials

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  • 2017-10-04_rwL / 1

    SOLPOL-4/5: NEUARTIGE KOLLEKTORSYSTEME AUS KUNSTSTOFF

    MOTIVATION, ZIELSETZUNGEN UND HIGHLIGHTS

    Reinhold W. LANG,

    Gernot M. WALLNER und Jrg FISCHER

    Institute of Polymeric Materials and Testing

    Johannes Kepler University Linz, Austria

    Tagung: IEA SHC Task 54Kosteneffiziente solarthermische SystemeJohannes Kepler Universitt Linz

    04. Oktober, 2017

    A science-driven Austrian research initiative by JKU-IPMT

    for innovations in solar technologies with polymeric materials

  • 2017-10-04_rwL / 2

    Development of Plastics & Steel(annual production in terms of volume)

    0

    50

    100

    150

    200

    250

    300

    350

    1950 1960 1970 1980 1990 2000 2010 2020

    mill. m3

    Based on data fromPlastics Europe andInternational Iron &Steel Institute (IISI)

    Plastics

    Steel

    Polymer production (worldwide 2014)

    - ca. 311 mio. t/year

    - ca. 5-6 % AAGR (since 1960)

    7 key success factors of plastics

    Plastics and polymer composites/hybrids still exhibit an exceptional

    innovation, growth & growth rate potential, unmatched by other materials.

    ?

    Properties wide range and tailorable

    property profiles

    Design high design flexibility;

    large potential for multi-

    functional integration

    Processing excellent processability

    Economy cost efficient products

    Ecology energy efficient

    products/applications

    Innovation still outstanding &

    extraordinary potential

    Growth essentially no resource

    Potential limitation

    PLASTICS MATERIALS OF THE 21. CENTURY

  • 2017-10-04_rwL / 3

    Kunststoffe sind vielfltig einsetzbar und durchdringen alle Lebensbereiche

    Medizintechnik

    Verpackung (1)

    (inkl. Gtertransport/Logistik)

    Feinwerk-

    technik

    LinsenhalterDVD-Player

    3 mm

    Infrastruktur-

    & Bautechnik (2)

    Information, Telekommunikation

    Mobilitt (3)

    Sport/Freizeit

    BMW i3

    Boeing 787

    Simplon

    PLASTICS MATERIALS OF THE 21. CENTURY !?

  • 2017-10-04_rwL / 4

    Development of new plastics

    based on new monomersDevelopment of new plastics based

    on existing monomers

    Innovations by accident(but by diligent work)

    Innovations by science(by diligent & systematic work)

    Source:

    R. Mlhaupt

    (UoF, 1994)

    From novel materials to needs! From needs to novel materials!

    Where are we heading?

    From welfare relevant product/energy NEEDS of a global population

    to novel, multi-functional MATERIALS

    based on an overall SYSTEMS perspective.

    PLASTICS WHERE ARE WE HEADING?A HISTORY BASED ATTEMPT FOR AN OUTLOOK

  • 2017-10-04_rwL / 5

    Ca. 25-30 % of the

    global end energy demand

    is low temperature heat

    T < 100 C

    SOLARTHERMAL

    collector additions

    (worldwide 2016)

    21 GWth ~ 15 mio. m2

    ~ 0.3 mio. tons of material

    SOLARTHERMAL ENERGY TECHNOLOGIESA (FAST) GROWING MARKET ?

    SOLARTHERMAL Total Global Capacity

    (2006 2016)

    Source: RENEWABLES GLOBAL STATUS REPORT (06/2017)

    CAGR (2006 2016)

    14 % p.a.

  • 2017-10-04_rwL / 6

    Features of conventional ST collectors

    Mostly vacuum glass pipe & flat plate collectors

    Multitude of materials with little contribution of polymers

    Cost intensive processing and production, assembly

    and installation

    Vacuum tube

    (glass pipe) collectorFlat plate

    collector

    Novel (nearly)

    all-polymeric ST collectors

    Sunlumo Technology GmbH

    One World Collector

    MAGEN eco-Energy

    Polymer Collector

    GREENoneTEC (concept)

    Thermosiphon Polymer

    Collector

    DIE VISION (2009) NEUE IMPULSE FR SOLARTECHNOLOGIEN

    KUNSTSTOFFE ALS INNOVATIONSTREIBER & MOTOR

  • 2017-10-04_rwL / 7

    DIE VISION (2009) NEUE IMPULSE FR SOLARTECHNOLOGIEN

    KUNSTSTOFFE ALS INNOVATIONSTREIBER & MOTOR

    bergeordnete Motivation & Zielsetzung von SolPol:

    Steigerung der Innovationskraft & Wettbewerbsfhigkeit

    sterreichischer Unternehmen im Solartechnologiesektor

    durch mittel- und lngerfristige Forschungskooperationen von

    Wissenschaft & Wirtschaft und durch

    Einbeziehung von Akteuren der gesamten Wertschpfungskette.

    2 Hauptbegrndungen fr Polymerwerkstoffe als Innovationstreiber:

    Maschneiderbare Eigenschaften und Verarbeitung (Performance)

    Kostenreduktion und Wachstumsfhigkeit

  • 2017-10-04_rwL / 8

    A RESEARCH CONSORTIUM COVERING THE ENTIRE VALUE CREATION CHAIN

    MaterialSemi-

    finished Product

    Component System Market

    10 Scientific Partners

    19 Company Partners

    SOLPOL project platform

    Total budget: ~14 mio. EURO

    Duration: 2010-2018 (8 years)

    OVERALL RESEARCH FIELDS & GOALS:

    All-polymeric solar-thermal collector systems

    Novel encapsulation materials for PV modules

    THE RESEARCH INITIATIVE SOLPOL

    FACTS & FIGURES

  • 2017-10-04_rwL / 9

    AGRU Kunststofftechnik GmbH

    ALANOD GmbH & Co. KG

    APC Advanced Polymer Compounds

    Borealis AG

    Calus GmbH

    Easol e.U.

    Engel Austria GmbH

    Gabriel-Chemie Gesellschaft m.b.H.

    GREENoneTEC Solarindustrie GmbH

    Greiner Technology & Innovation GmbH

    KE KELIT Kunststoffwerk Gesellschaft m.b.H.

    KIOTO Photovoltaics GmbH

    Lenzing Plastics GmbH & Co KG

    PerkinElmer Vertriebs GmbH

    Schfer GmbH

    SENOPLAST KLEPSCH & Co GmbH

    Sunlumo Technology GmbH

    Sun Master Energiesysteme GmbH

    Sunplugged GmbH

    COMPANY PARTNERS OF SOLPOL

  • 2017-10-04_rwL / 10

    The SolPol-4/5 Solar-thermal Performance Pyramid (3 Levels)

    MAIN CHALLENGES AND KEY QUESTIONS

  • 2017-10-04_rwL / 11

    The SolPol-4/5 Solar-thermal Performance Pyramid (3 Levels)

    MAIN CHALLENGES AND KEY QUESTIONS

  • 2017-10-04_rwL / 12

    SOLPOL-4/5 RESEARCH PROGRAMTOWARDS ALL-POLYMERIC COLLECTOR DESIGNS & SYSTEMS

    Work Package

    (WP) structure

    &

    interaction with

    other projects

    WP-02:High-Quality

    Non-Pumped Systems

    So

    lPo

    l-1

    /2

    SolPol-4/5

    IEA-SHC Task39 / IEA-SHC Task54

    WP-01:Low-Cost

    Pumped Systems SC

    OO

    P

    WP-Leader: Sunlumo,

    JKU-IPMT

    WP-Leader: AEE INTEC,

    GoT/GTI

    WP-03:Novel Materials and Test Methods

    WP-Leader: JKU-IPMT

  • 2017-10-04_rwL / 13

    Development of new plastics

    based on new monomersDevelopment of new plastics based

    on existing monomers

    Innovations by accident(but by diligent work)

    Innovations by science(by diligent & systematic work)

    Source:

    R. Mlhaupt

    (UoF, 1994)

    From novel materials to needs! From needs to novel materials!

    Where are we heading?

    From welfare relevant product/energy NEEDS of a global population

    to novel, multi-functional MATERIALS

    based on an overall SYSTEMS perspective.

    PLASTICS WHERE ARE WE HEADING?A HISTORY BASED ATTEMPT FOR AN OUTLOOK

  • 2017-10-04_rwL / 14

    THE SOLPOL RESEARCH INITIATIVE OF JKU-IPMT (19/10 COMPANY/SCIENTIFIC PARTNERS)

    A Comprehensive Systems & Science Based Approach since 2010

    From the planetary/world systems perspective

    to the engineering systems/components perspective

    to the polymeric materials perspective

    with tailored polymeric materials & products

    to market penetration & growth?

    SOLARTHERMAL ENERGY TECHNOLOGIESTOWARDS ALL-POLYMERIC COLLECTOR DESIGNS & SYSTEMS

  • 2017-10-04_rwL / 15

    (1) The planetary/world systems perspective

    selection of 5 representative climate regions (Meteonorm)

    Lufttemperatur - Standortvergleich

    -20

    -10

    0

    10

    20

    30

    40

    50

    Athe

    n

    Forta

    leza

    Gra

    z

    Pret

    oria

    Pekin

    g

    Tem

    pera

    tur

    Ta [

    C]

    Air temperatures

    Kumulierte Globalstrahlung geneigt - Standortvergleich

    0

    500

    1000

    1500

    2000

    2500

    1.1 31.1 2.3 1.4 1.5 31.5 30.6 30.7 29.8 28.9 28.10 27.11 27.12

    Zeit

    Glo

    bals

    trah

    lun

    g g

    en

    eig

    t

    ku

    mu

    liert

    Q [

    kW

    h/m

    ]

    Athen gen. Fortaleza gen. Graz gen. Pretoria gen. Peking gen.

    Global irradiation(cumulated p.a.)

    Relative humidity(cumulated p.a.)

    0,00

    0,10

    0,20

    0,30

    0,40

    0,50

    0,60

    0,70

    0,80

    0,000 0,020 0,040 0,060 0,080 0,100 0,120

    eta

    dT/G Km/W

    Kollektorkennlinien ber DT / G Einfachplatte ExellD-112 3mm

    Doppelstegplatte LT2UV10/2RS17-112 10 mm

    Dreifachstegplatte LT2UV10/3RS19-112 10 mm

    Solpol2 AP02a Vergleich Abdeckungen von Sabic

    Hufigkeiten absolute Feuchte - Standortvergleich

    0

    500

    1000

    1500

    2000

    0-1

    2-3

    4-5

    6-7

    8-9

    10

    -11

    12

    -13

    14

    -15

    16

    -17

    18

    -19

    20

    -21

    22

    -23

    24

    -25

    26

    -27

    Klassen [g/kgTrL]

    Stu

    nd

    en

    [h

    /a]

    Athen Fortaleza Graz Pretoria Peking

    (2) The engineering systems/components perspective

    definition of collector type and system (modeling/simulation)

    (3) The component specific materials perspective

    Quantitative material property

    & performance requirements

    SOLARTHERMAL ENERGY TECHNOLOGIESTOWARDS ALL-POLYMERIC COLLECTOR DESIGNS & SYSTEMS

  • 2017-10-04_rwL / 1616

    Temperature and pressure profile of a plastics absorber

    Temperature frequency of collector (mean temperature)

    Minimum and maximum pressure of absorber

    Source:

    Ch. Fink, A. Kaiser, R. Hausner

    (AEE-INTEC, Gleisdorf, A)

    Performance Requirements for All-polymeric ST Collector Systems

    SOLARTHERMAL ENERGY TECHNOLOGIESTOWARDS ALL-POLYMERIC COLLECTOR DESIGNS & SYSTEMS

    More in

    presentation by

    Th. Ramschak

  • 2017-10-04_rwL / 17

    Example 1: PO absorber material Example 2: PO liner for buried,

    large-volume hot-water stores

    Service requirement service life: 30+ years

    System type & service

    requirements pressurized OHC system

    service life: 20+ years

    region: Graz (Austria)

    SOLARTHERMAL ENERGY TECHNOLOGIESTOWARDS ALL-POLYMERIC COLLECTOR DESIGNS & SYSTEMS

    NOVEL POLYOLEFIN-COMPOUNDS FOR SOLARTHERMAL SYSTEMS (BOREALIS, AGRU)

    Research goal: Polyolefins (PE, PP) with

    15+ C enhanced long-term temperature resistance

    (incl. science-based lifetime assessment)

  • 2017-10-04_rwL / 18

    SOLARTHERMAL ENERGY TECHNOLOGIESTOWARDS ALL-POLYMERIC COLLECTOR DESIGNS & SYSTEMS

    Performance/Price Pyramid of Plastics

    Plastics used commercially

    for absorbers of

    glazed flat plate collectors Performance/Price Requirements

    With OH-control:

    polyolefins (PE, PP)

    thermal stability plus ~15 K

    Without OH-control:

    high-performance plastics

    price reduction to < 6 /kg

    Primary overall aims

  • 2017-10-04_rwL / 19

    SOLARTHERMAL ENERGY TECHNOLOGIESTOWARDS ALL-POLYMERIC COLLECTOR DESIGNS & SYSTEMS

    Planing tool for production of

    micro-sized specimens Automated production of

    micro-sized specimens with

    reproducible geometrical dimensions

    and material properties achieved!

    Cylinder-head

    screw M5x12Stanley RB108

    Blade

    Body

    Clamping

    Plate

    Aging acceleration via micro-sized specimens(Dissertations: K. Grabmayer, M. Povacz, M. Grabmann )

    CNC machining process

    Number of micro-sized specimens

    produced so far (as of 2011):

    > 30,000 for material screening(aging and testing for many in progress)

    ~ 2,000 for method development

    More in

    presentation

    by M. Grabmann

  • 2017-10-04_rwL / 20

    SOLARTHERMAL ENERGY TECHNOLOGIESTOWARDS ALL-POLYMERIC COLLECTOR DESIGNS & SYSTEMS

    -20 0 20 40 60 80 10010

    0

    101

    102

    103

    104

    105

    Graz

    Athens

    Pretoria

    Fortaleza

    Beijing

    fr

    eq

    uen

    cie

    s, h

    /a

    absorber temperature, C

    Overheating protected

    collector system for DHW

    (domestic hot water)

    OHC collector: Lifetime assessment for extruded PP absorbers

    Temperature loading profile

    2,4 2,6 2,8 3,0 3,21

    10

    100

    1000

    10000

    100000

    experimental data PP-B2

    Gugumus (1999) data 0.1% AO-1

    Gugumus (1999) data 0.05% AO-1

    predicted data PP-B2

    tim

    e-t

    o-e

    mb

    rittle

    me

    nt, d

    103 (1/T), K

    -1

    PP-B2

    ongoing

    Endurance time extrapolation

    Lifetime, years Graz, AT Athens, GR Pretoria, RSA Fortaleza, BR Beijing, CHN

    PP-B1 21 15 14 8 23

    PP-B2 (Borealis) 32 25 24 15 34

    Lifetime modelling:

    Extrapolation by Gugumus approach

    Cumulative damage model (Miners

    rule) failure time (tf)

    1 =

    =1

    =

    / , Quelle: T. Ramschak(AEE INTEC, 2014)

    Source: Dissertation M. Povacz (JKU IPMT, 2014)

    More in

    presentation

    by M. Grabmann

  • 2017-10-04_rwL / 21

    One-World-Solar-Collector

    SOLARTHERMAL ENERGY TECHNOLOGIESTOWARDS ALL-POLYMERIC COLLECTOR DESIGNS & SYSTEMS

    THE ONE-WORLD-SOLAR-SYSTEM BY SUNLUMO TECHNOLOGY GMBH

    Polymer-made

    solar pumping group

    with

    push-fit connectors

    and piping

    One-World-Solar-Systemwith polymer-made hot water storage

    More in presentation

    by R. Buchinger

  • 2017-10-04_rwL / 22

    2.5 3 3.5 4 4.5 5 5.5 61E-06

    1E-05

    1E-04

    1E-03

    chlorinated water (5 ppm)

    chlorinated water (1 ppm)

    deionized water

    CT, R = 0.1, f = 10 Hz, 80C PAGF30-C

    da/d

    N (

    mm

    /cycle

    )

    DK (MPa.m0.5)

    Specimen

    TestsetupTap water

    Drinking water

    5 ppm Cl

    Integrated Storage Collector (ISC)conventional materialswith PA-GF endcaps

    working principle

    Fatigue crackgrowth kinetics

    More in

    presentation by

    P. BradlerMore in

    presentation by

    G. Ziegler

    SOLARTHERMAL ENERGY TECHNOLOGIESTOWARDS ALL-POLYMERIC COLLECTOR DESIGNS & SYSTEMS

    ALL-POLYMERIC ISC BY GREENONETEC SOLARINDUSTRIE GMBH

  • 2017-10-04_rwL / 23

    Ecological Assessment: From function units at the materials level to material indices

    at the component/systems level

    The Ecological Performance PyramidEcological life cycle assessment (ELCA) for

    various product and performance levels

    Generic

    aspects:product- and

    application

    independent

    R.W.Lang, M.Svoboda, H.Kicker

    Univ. of Cambridge (UK; 04/2013)

    SOLARTHERMAL ENERGY TECHNOLOGIESTOWARDS ALL-POLYMERIC COLLECTOR DESIGNS & SYSTEMS

    One-World-Solar-System

    with polymer-made hot water storage Sunlumo Technology GmbH

    Source:

    H. Kicker et al.(JKU-IPMT, 2015)

  • 2017-10-04_rwL / 24

    Ecological Assessment: From function units at the materials level to material indices

    at the component/systems level

    The Ecological Performance PyramidEcological life cycle assessment (ELCA) for

    various product and performance levels

    Generic

    aspects:product- and

    application

    independent

    R.W.Lang, M.Svoboda, H.Kicker

    Univ. of Cambridge (UK; 04/2013)

    SOLARTHERMAL ENERGY TECHNOLOGIESTOWARDS ALL-POLYMERIC COLLECTOR DESIGNS & SYSTEMS

    One-World-Solar-System

    with polymer-made hot water storage Sunlumo Technology GmbH

    Source: H. Kicker et al. (JKU-IPMT, 2015)

  • 2017-10-04_rwL / 25

    All-polymeric solar-thermal

    collector systems

    Sunlumo Technology GmbH

    One World Collector In total, some 50+ academic theses

    14+ PhD Dissertations

    17+ Masters Thesis

    16+ Bachelors Thesis

    Some 40+ refereed publications(so far, many more to come!)

    More than 100 presentations/talksat nat./internat. conferences & symposia

    SolPol directed by:

    R. W. Lang & G. M. Wallner

    Novel encapsulation polymers

    for Photovoltaics

    SCIENTIFIC-ACADEMIC

    OUTPUT:

    Mediainfo:22. Mai 2017

    Award Ceremony:28. Mrz 2017

    THE JKU SOLPOL RESEARCH INITIATIVESUMMARY AND OUTCOME SO FAR

  • 2017-10-04_rwL / 26

    Features of conventional ST collectors

    Mostly vacuum glass pipe & flat plate collectors

    Multitude of materials with little contribution of polymers

    Cost intensive processing and production, assembly

    and installation

    Vacuum tube

    (glass pipe) collectorFlat plate

    collector

    Novel (nearly)

    all-polymeric ST collectors

    Sunlumo Technology GmbH

    One World Collector

    MAGEN eco-Energy

    Polymer Collector

    GREENoneTEC (concept)

    Thermosiphon Polymer

    Collector

    DIE VISION (2009) NEUE IMPULSE FR SOLARTECHNOLOGIEN

    KUNSTSTOFFE ALS INNOVATIONSTREIBER & MOTOR