requirements for synthesisgas-supply to a chemical verbund
TRANSCRIPT
Requirements for Synthesisgas-Supply to a Chemical Verbund
6th International Freiberg Conference
Martin Gall, Dr. Heinrich Laib, Dr. Peter SalingBASF SE, Ludwigshafen, Germany
Requirements for Synthesisgas-Supply to a Chemical Verbund
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Contents
BASF - The Chemical Company
General Supply Aspects
Sustainability Evaluation
Renewable Feedstock
BASF – The Chemical Company
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Sales 2013: € 73,973 million
EBIT 2013: € 7,273 million
Employees: 112,200(as of December 31, 2013):
6 Verbund sites and 376 other production sites
Our chemistry is used in almost all industries
We combine economic success, social responsibility and environmental protection
We create chemistry for a sustainable future
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production vs. emissions
4
+100%
-48%
-74%
Development since 1990 Index 1990 = 100%, BASF Group excl. oil and gas business
volume of sales product
absolute greenhousegas emissions
specific green housegas emissions0
50
100
150
200
250
1990 1994 1998 2002 2006 2010
100
2013
BASF – The Chemical Company
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BASF Ludwigshafen Verbund – Aerial view
Requirements for Synthesisgas-Supply
Synthesisgases:• Hydrogen• Carbonmonoxide• Mixtures of Hydrogen and Carbonmonoxide
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Demand quantities Plant capacities
Requirements for Synthesisgas-Supply
Mega Plants(Methanol, XtL, ….)
“Typical” Chemical Plant (Formic Acid, BDO,Iso-Cyanates, ….)
Dedicated plants @ max. designor multi-train set-up, integrated
Additionally supply to “typical” chemical plants possible
Plant capacities
SMR Coal-POx ATR
typical demand significantly smallerthan world-scale plant capacity
Verbund sites with cummulated demandcan gain “economy of scale”
Verbund
Demand quantities
50 kNm3/h 500 kNm3/h250 kNm3/h
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CO H2
Hydrogen concentration (vol %)
0 50 100
Adjustment of H2 / CO – Ratio (simplified)
SMRNG-PoxATR
CoalPOx
OilPOx
Demand – Operational window
Increase H2 portion via shift reaction
Increase CO portion via CO2 recycle, import
CO + H2O CO2 + H2
Clients demand
TechnologiesFeedstock
Requirements for Synthesisgas-Supply
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Syngas Verbund Ludwigshafen – Overview
ASU
Ammonia plants
Synthesisgas plant1 + 2 + 3
Steamcrackers
Chlorine plantsHydrogenco-producers
H2 clients
CO clients
Oxo clients
∑ 90 clients
… Cyclohexane plant Aromatics plant Butanediol plant SteamCracker Hydramin plant Neopentylglycol Budimate plant Special Amines Pentyl plant Ultramid plant Phthalodinitril Amidoacid plant Methanol plant Butyl plant Hydroxylamine Chloridazone Poly-THF plant Lysmeral plant …
Requirements for Synthesisgas-Supply
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Relevance within the Verbund
Syngas - Downstreams (Ludwigshafen – extract)
Production
Oxogas
Carbonmon-oxide
HydrogenOxo-gas
H2
Polyamide 6
Valeraldehyde
Higher Oxalc.
Hydroxylaminsulfate
Butanoles
Cyclohexane
Propionaldehyde
Formic AcidCO
HA free baseHA free base
BDO/HDO PTHFPTHF
Caprolactam
THF
GBL
PlasticizersPlasticizers
NVP/PVPNVP/PVP
Propionaldehyde
Valeraldehyde
Butanoles
Cyclohexane
n-Butanol
n-Nonanol Hexamoll DINCH
Polyamides
Dispersions
Palatinol 10P
Diethylketon
Carbonyl Iron Power
Methacrylic Acid
Propylheptanol
Palatinol N
Anon/Anol
Butylacrylates
Butylacrylates
Isophorondiamines
Feed Acidifiers
Trilone
Dispersions
Catamold
Resins
Vitamine E
Iron Carbonyl
Propionic Acid
MeFOFormamide
Hydrogen Cyanide
1 € 40 €
Requirements for Synthesisgas-Supply
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Relevance within the Verbund
Syngas - Downstreams (Ludwigshafen – extract)
Production
Oxogas
Carbonmon-oxide
HydrogenOxo-gas
H2
Polyamide 6
Valeraldehyde
Higher Oxalc.
Hydroxylaminsulfate
Butanoles
Cyclohexane
Propionaldehyde
Formic AcidCO
HA free baseHA free base
BDO/HDO PTHFPTHF
Caprolactam
THF
GBL
PlasticizersPlasticizers
NVP/PVPNVP/PVP
Propionaldehyde
Valeraldehyde
Butanoles
Cyclohexane
n-Butanol
n-Nonanol Hexamoll DINCH
Polyamides
Dispersions
Palatinol 10P
Diethylketon
Carbonyl Iron Power
Methacrylic Acid
Propylheptanol
Palatinol N
Anon/Anol
Butylacrylates
Butylacrylates
Isophorondiamines
Feed Acidifiers
Trilone
Dispersions
Catamold
Resins
Vitamine E
Iron Carbonyl
Propionic Acid
MeFOFormamide
Hydrogen Cyanide
Reliability and Flexibilityare key requirements for
Synthesisgas-Supply
Down-streamclients
1 € 40 €
Requirements for Synthesisgas-Supply
Balancing all three dimensions
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International Trade
International Communities
Training
Global Warming
Land use changeSustainability
Evaluation
Meet theexpectationsof society
Society
Ensurethe profitabilityof business
Economy
Care for theenvironment
Ecology
Sustainability Evaluation
Sustainability Evaluation
Tools
Eco-Efficiency Analysis Includes environmental impacts and
life cycle costs
Already over 600 analysis since 1996
Validated method by and
Life Cycle Assessment (LCA) Evaluates of environmental impacts
Life Cycle Inventory Quantifies inputs and outputs
SEEBALANCE® Includes social aspects
ISO
140
40 &
140
44IS
O 1
4045
Overview of information and effort requirements
Effort
Sust
aina
bilit
y -I
nfor
mat
ion
low high
economic viewearly stagecalculation tools Total Cost of Ownership
Eco-EfficiencyAnalysis
SEEBALANCE ®
+ environmental impact
+ social impact
Sustainability Evaluation
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Environmental Burden
low
high
Resource Consumption
Energy Consumption
Emissions
Toxicity Potential
Risk Potential
Land Use
Water use (in future)
Effect Category Ecological Fingerprint
Calculation of relative product position
0,00
0,50
1,00
Energy Consumption
Emissions
Toxicitypotential
Risk potential
ResourceConsumption
Land Use
process 1 process 2 process 3
Calculation Normalization Weightingand aggregation
Aggregation and weighting
of impact categories
Sustainability Evaluation
Environmental Assessment
3
2
1
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Eco-Efficiency Analysis – result presentation
Production ofProduct X
0.4
1.0
1.60.41.01.6
Costs (normalized)
Envi
ronm
enta
l bur
den
(nor
mal
ized
)
process 3
process 2
process 1
Sustainability Evaluation
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SEEBALANCE – result presentation
1,6
1,0
0,4
1,0
0,4
1,6
1,0
0,4
Sustainability Evaluation
highest socio-ecoefficiency
lowest socio-ecoefficiency
intermediate
transparent accepted methodology and weighting high aggregation of results possible
Chemicals based on renewable feedstock
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concepts
Integrated production
Certified allocation concept(massbalance approach)
ConventionalMarkets
dedicated consumers
Fossil fuelsRaw materials Production Market
BASFVerbund
ProductsFossil
feedstock
Bio-feed-stock
dedicatedproducts
dedicatedproduction
Bio-feed-stock
Fossil fuelsRaw materials Production Market
BASFVerbund
Products
Fossilfeed-stock
Dedicated plants
ConventionalMarkets
dedicated consumers
Chemicals based on renewable feedstock
1919
Integrated production – massbalance approach
Bio-feed-stock
Fossil fuelsRaw materials
Fossilfeed-stock
Production
BASFVerbund
Products
ConventionalMarkets
Market
Our integrated and highly efficient production is an available option for the use of renewable feedstock A publicly accepted certification system provides the method to allocate renewable feedstock to certain
products / a portion of certain products
concept rapidly available to help our clients to achieve their sustainability goals
dedicated consumers
Chemicals based on renewable feedstock
2020
Flexibility and reliability are key requirements
Single plant demand typically below world scale plant capacities
Demand portfolio is site specific, very big variation (quantity, composition)
Demand for products based on renewables will increase
Sustainability evaluation results will become a quality criteria( expertise to apply established tools necessary )
Key statements – typical chemical site
Requirements for Synthesisgas-Supply
Site-specific supply concepts which balances requirements to all aspects
technological economical ecological social