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Bibliography on Mossbauer spectroscopy (including selected books and papers which have

been cited above)

The following books are devoted to Mossbauer spectroscopy and its applications. Most contain

an introductory section on the technique and the interpretation of the interactions. Although

many are not recent , the principles of Mossbauer spectroscopy have not changed!

G.M. Bancroft. 1973. Mossbauer Spectroscop y. An Introduction for Inorganic Chemists and

Geochemists. McGraw-Hill, New York, 252 pp.

G.N. Belozerski . 1993. Mossbauer Studies of Surface Layers. Studies in Physical and

Theoretical Chemistry, No. 81. Elsevier, Amsterdam, 457 pp.

R.L. Cohen. 1976. Applications of Mossbauer Spectroscopy, vol. I. Academic Press, New

York, 349 pp.

R.L. Cohen. 1980. Applications of Mossbauer Spectroscopy, vol. 2. Academic Press, New

York, 439 pp.

T.E . Cranshaw, B.W. Dale, G.O. Longworth and C.E. Johnson. 1985. Mossbauer Spectroscopy

and its Applications. Cambridge University Press, Cambridge, 119 pp.

J. Danon. 1968. Lectures on the Mossbauer Effect. Gordon and Breach , New York, ISO pp.

D.P.E . Dickson and F.E. Berry (eds.). 1986. Mossbauer Spectroscopy. Cambridge University

Press, Cambridge, 274 pp.

H. Frauenfelder. 1962. The Mossbauer Effect: a Review with a Collection of Reprints .

Benjamin, New York, 336 pp.

T.C. Gibb . 1976. Principles of Mossbauer Spectroscopy. Chapman and Hall , London, 254 pp.

V.I. Goldanskii and R.H. Herber (eds .). 1968. Chemical Applications of Mossbauer

Spectroscopy. Academic, New York, 701 pp.

U. Gonser (cd.). 1975. Mossbauer Spectroscop y. Topics in Applied Physics, vol. 5. Springer,

Berlin, 241 pp.

U. Gonser (ed.). 1981. Mossbauer Spectroscopy /l - The Exotic Side of the Method . Springer,

Berlin, 196 pp.

N.N. Greenwood and T.C . Gibb . 1971. Mossbauer Spectroscopy. Chapman and Hall , London,

659 pp.

l.J. Gruverman (cd.). 1965. Mossbauer Effect Methodology, vol. 1. Plenum, New York, 200 pp.

l.J. Gruverman (ed.). 1966. Mossbauer Effect Methodology, vol. 2. Plenum, New York, 191 pp.

l.J. Gruverman (ed.). 1967. Mossbauer Effect Methodology, vol. 3. Plenum, New York, 250 pp.

l.J. Gruverman (ed.). 1968. Mossbauer Effect Methodology, vol. 4. Plenum, New York, 270 pp.

l.J. Gruverman (ed.). 1970. Mossbauer Effect Methodolog y, vol. 5. Plenum, New York, 278 pp.

l.J. Gruverman (cd.). 1971. Mossbauer Effect Methodology , vol. 6. Plenum, New York, 237 pp.

l.J. Gruverman (cd.). 1971. Mossbauer Effect Methodology, vol. 7. Plenum, New York, 308 pp.

l.J. Gruverman and C.W . Seidel (cds. ). 1973. Mossbauer Effect Methodolog y, vol. 8. Plenum,

New York, 281 pp.

406 References

1.1. Gruverman, C.W . Seidel and D.K. Dieterley (eds .). 1974. Mossbauer Effect Methodology ,

vol. 9. Plenum, New York. 344 pp.

1.1. Gruverman and C.W . Seidel (eds.). 1974. Mossbauer Effect Methodology. vol. 10. Plenum.

New York , 354 pp.

P. Gutlich, R. Link and A. Trautwein (eds.) . 1978. Mossbauer Spectroscopy and Transition

Metal Chemistry. Inorganic Chemistry Concepts, vol. 3. Springer, Berlin. 280 pp.

P. Gtitlich and G.M . Kalvius (eds .). 1983. Trends in Mossbauer Spectroscopy. Proceedings of

the Second Seeheim Workshop on Mossbauer Spectroscopy, May 1983. Mainz,

University of Mainz, 315 pp.

P. Gtitlich and H. Spiering. 1988. Third Seeheim Workshop on Mossbauer Spectroscopy.

Hyperfine Interactions 47-48. 644 pp.

P. Gutlich, W. Meisel and H. Spiering. 1995. Fourth Seeheim Workshop on Mossbauer

Spectroscopy . Hyperfine Interactions 95, 358 pp.

R.H . Herber. 1984. Chemical Mossbauer Spectroscopy . Plenum, New York , 378 pp.

C. Janot. 1972. L 'Effet Mossbauer et ses Applications ala Physique Solide et ala Metallurgic

Physique. Masson. Paris . 234 pp.

B. Kolk . 1984. Study of dynamical properties of solids with the Mossbauer effect. In

Dynamical Properties ofSolids, G.K. Horton and A.A. Maradudin, eds . North Holland.

Amsterdam, 1-328.

GJ. Long (ed .). 1984. Mossbauer Spectroscopy Applied to Inorganic Chemistry, vol. I.

Plenum, New York, 667 pp.

GJ. Long (ed.) . 1987. Mossbauer Spectroscopy Applied to Inorganic Chemistry, vol. 2.

Plenum, New York, 626 pp.

GJ. Long and F. Grandjean (eds .). 1989. Mossbauer Spectroscopy Applied to Inorganic

Chemistry, vol. 3. Plenum. New York, 644 pp.

GJ. Long and F. Grandjean (eds .). 1993. Mossbauer Spectroscopy Applied to Magnetism and

Materials Science. vol. I. Plenum. New York , 479 pp.

GJ. Long and F. Grandjean (cds .). 1996. Mossbauer Spectroscopy Applied to Magnetism and

Materials Science, vol. 2. Plenum, New York. 361 pp.

GJ. Long and lG. Stevens (eds.), 1986. Industrial Applications of the Mossbauer Effect.

Plenum, New York, 796 pp. [ISIAME 1984].

A.G. Maddock. 1997. Mossbauer Spectroscopy : Principles and Applications. Chichester,

Horwood, 261 pp.

L. May . 1971. An Introduction to Mossbauer Spectroscopy. Adam Hilger. London. 203 pp.

M. Miglierini and D. Petridis (eds .). 1999. Mossbauer Spectroscopy in Materials Science.

Kluwer, Dordrecht. 432 pp.

S. Merup, 1981. Paramagnetic and Superparamagnetic Relaxation Phenomena Studied by

Mossbauer Spectroscopy . Polyteknisk Forlag, Lyngby, Denmark, 260 pp.

GJ. Perlow (ed .). 1977. Workshop on New Directions in Mossbauer Spectroscopy . American

Institute of Physics , New York. 152 pp.

Mossbauer Spectroscopy of Environmental Materials 407

G.K. Shenoy and F.E. Wagner (eds .), 1978. Mossbauer Isomer Shifts. North-Holland,

Amsterdam, 956 pp.

J.G . Stevens and G.K. Shenoy (eds .). 1981. Mossbauer Spectroscopy and its Chemical

Applications . Advances in Chemistry Series, No. 194. American Chemical Society,

Washington, D.C., 642 pp.

B.V. Thosar, P.K. Iyengar, 1.K. Srivastava and S.c. Bhargava. 1983. Advances in Mossbauer

Spectroscopy . Elsevier, New York, 924 pp.

A. Vertes, L. Korecz and K. Burger. 1979. Mossbauer Spectroscopy . Akaderniai Kiad6,

Budapest, and Elsevier, Amsterdam, 432 pp.

A. Vertes and Z. Homonnay (eds .). 1997. Mossbauer Spectroscopy of Sophisticated Oxides.

Akaderniai Kiad6, Budapest, 340 pp.

A. Vertes and D.L. Nagy (eds .). 1990. Mossbauer Spectroscopy of Frozen Solutions.

Akaderniai Kiad6, Budapest, 302 pp.

H. Wegener. 1966. Der Mossbauer-Effekt und seine Anwendung in Physik und Chemie.

Bibliographisches Institut, Mannheim, 226 pp.

G.K. Wertheim. 1964. Mossbauer Effect: Principles and Applications. Academic Press, New

York , 116 pp.

Reviews and major works on the applications of Mlissbauer spectroscopy to geology and

mineralogy

G.M . Bancroft. 1979. Mossbauer spectroscopic studies of the chemical state of iron in silicate

minerals . Jounal de Physique 40, Colloque C2, 40, 464-471.

F.J. Berry . 1990. Mossbauer spectroscopy. In: Instrumental Surface Analysis of Geologic

Materials, D.L. Perry, ed. VCH , Weinheim, Germany, 157-190.

A.J .F. Boyle and H.E. Hall. 1962. The Mossbauer Effect. In: Reports on Progress in Physics,

vol. 25, 441-524.

1.M.D. Coey. 1984. Mossbauer spectroscopy of silicate minerals. In: Miissbauer Spectroscopy

Applied to Inorganic Chemistry, vol. 1, G.J. Long , ed. Plenum, New York, 443-509.

J.D . Fabris and J.M .D. Coey . 2000. Espectroscopia Mossbauer do 57Fe e medidas magneticas

na analise de geomateriales. In: Topicos em cienco do solo / publicaciio da Sociedade

Brasileira de Ciencia do Solo, vol. I. Vicosa , Brazil, 48-102 .

B.A. Goodman. 1980. Mossbauer spectroscopy. In: Advanced Chemical Methods for Soil and

Clay Minerals Research, J.W . Stucki and W.L. Banwart, eds . D. Reidel, Dordrecht, 1­

92.

B.A. Goodman. 1982. Mossbauer spectroscopy. In: Advanced Techniques for Clay Minerals

Analysis, 1.1. Fripiat, ed . Elsevier, Amsterdam, 113-137 .

B.A. Goodman. 1994. Mossbauer spectroscopy. In Clay Mineralogy: Spectroscopic and

Chemical Determinative Methods, M.J. Wilson, ed. Chapman and Hall, London, 68­

119.

408 References

F.C. Hawthorne. 1988. Mossbauer spectroscopy. In: Spectroscopic Methods in Mineralogy and

Geology. Reviews in Mineralogy, vol. 18. Mineralogical Society of America,

Washington, D.C., 255-340.

E. Kuzmann, S. Nagy, A. Vertes, T.G. Weizburg and V.K. Garg. 1998. Geological and

mineralogical applications of Mossbauer spectroscopy. In: Nuclear Methods in

Mineralogy and Geology: Techniques and Applications, A. Vertes, S. Nagy and K.

Suvegh, eds. Plenum, New York, 285-376.

E. Kuzmann, S. Nagy and A. Vertes. 2003. Critical review of analytical applications of

Mossbauer spectroscopy illustrated by mineralogicaland geological examples. Pure and

Applied Chemistry 75, 801-858.

C. McCammon. 1995. Mossbauer spectroscopy of minerals. In: Mineral Physics and

Crystallography: a Handbook of Physical Constants, TJ. Ahrens, ed. American

Geophysical Union, Washington, D.C., 332-347.

S. Mitra. 1992. Applied Mossbauer Spectroscopy: Theory and Practice for Geochemists and

Archaeologists. Pergamon, Oxford, 381 pp.

E. Murad and J.H. Johnston. 1987. Iron oxides. In: Mossbauer Spectroscopy Applied to

Inorganic Chemistry , vol. 2, GJ. Long, ed. Plenum, New York, 507-582.

D.G. Rancourt. 1998. Mossbauer spectroscopy in clay science. Hyperfine Interactions 117, 3­38.

lG. Stevens (ed.). 1981. Mossbauer spectroscopy. In: Handbook of Spectroscopy, vol. 3. CRC

Press, Boca Baton, USE, 403-528.

lG. Stevens, A. Khasanov, J.L. Miller, H. Pollak and Z.Li. 1998. Documentation and

evaluation of Mossbauer data for minerals. Hyperfine Interactions 117, 71-8I.

lG. Stevens, A.M. Khasanov, lW. Miller, H. Pollak and Z. Li. 1998. Mossbauer Mineral

Handbook. Mossbauer Effect Data Center, Asheville N.C., 527 pp. Also available in

computer form.

T. Tominaga and Y. Minai. 1984. Applications of Mossbauer spectroscopy to environmental

and geochemical studies. Nuclear Science Applications 1, 749-79I.

Recent Conference Proceedings

For earlier conferences see, for example, the Mossbauer Effect Data Center data base (nextsection) or Kolk (1984).

International Conference on the Applications of the Mossbauer Effect (ICAME) series:

ICAME'87 Proceedings of the International Conference on the Applications of the

Mossbauer Effect (ICAME'S7) . 1988. SJ. Campbell, J.D. Cashion, P.E. Clark and

RJ. Pollard, eds. Hyperfine Interactions 40-42, 1297 pp.

Mossbauer Spectroscopy of Environmental Materials 409

ICAME'89 Proceedings of the International Conference on the Applications of the

Mossbauer Effect (ICAME'89) . 1990. D.L. Nagy, K. Lazar and Zs. Kajcsos, eds.

Hyperfine Interactions 53·8, 2787 pp.

ICAME'91 Proceedings of the International Conference on the Applications of the

Mossbauer Effect (ICAME'9/) . 1992. Y.F. Hsia, Q.J. Yan, F.S. Li, G.L. Zhang,

X.L. Ni, eds. Hyperfine Interactions 68-71.

ICAME'93 Proceedings of the International Conference on the Applications of the

Mossbauer Effect (ICAME'93) . 1994. G.J. Long and F. Grandjean, eds. Hyperfine

Interactions 90-94, 2422 pp.

ICAME'95 International Conference on the Applications of the Mossbauer Effect, ICAME­

95, Part I. 1996. I. Ortalli, ed. Italian Physical Society, Bologna, 388 pp.

International Conference on the Applications ofthe Mossbauer Effect. ICAME-95

Part II • Conference Proceedings. vol. 50. 1996. I. Ortalli, ed. Italian Physical

Society, Bologna, 1006 pp.

ICAME'97 Proceedings of the International Conference on the Applications of the

Mossbauer Effect (ICAME'97) . 1998. E. Baggio-Saitovich. H. Rechenberg and

R.B. Scorzelli, eds. Hyperfine Interactions 113, 523 pp.

ICAME'99 Applications of the Mossbauer Effect (ICAME'99) . 2000. F.G. Parak and AX

Trautwein , eds. Hyperfine Interactions 126, 452 pp.

ICAME2001 Proceedings of the International Conference on the Applications of the

Mossbauer Effect (ICAME200/). 2002. M.F. Thomas, T.e. Gibb and J.M.

Williams, eds. Hyperfine Interactions 141-142, 661 pp; Hyperfine Interactions

(C), 5, 250 pp.

International Symposia on the Industrial Applications of the Mossbauer Effect (lSIAME) series:

ISIAME88 Proceedings of the International Symposium on the Industrial Applications of the

Mossbauer Effect. 1989. M. Carbucicchio and G. Principi, eds. Hyperfine

Interactions 45-6, 769 pp.

ISIAME92 Proceedings of the Third International Symposium on the Industrial Applications

of the Mossbauer Effect. 1993. Y. Nakamura, T. Shinjo and S. Nasu, eds. Nuclear

Instruments and Methods in Physics Research B 76, 448 pp.

ISIAME96 Industrial Applications of the Mossbauer Effect (ISIAME'96). Parts I and II.

1998. H. Pollak and U. Karfunkel, eds. Hyperfine Interactions 111, 372 pp; 112,

282 pp.

ISIAME2000 International Symposium on the Industrial Applications of the Mossbauer Effect

(lSIAME2000). 2002. D.C. Cook and G.R. Hoy, eds. Hyperfine Interactions 139­

140,723 pp.

Mossbauer Spectroscopy in Clay Science. 1998. D.G. Rancourt, ed. Hyperfine Interactions 117,

435 pp.

410 References

Nuclear Resonant Scattering of Synchrotron Radiation. 2000 . E. Gerdau and H. de Waard,

eds .• Part A. Hyperfine Interactions 123·4. 879 pp. Part B. Hyperfine Interactions 125.

212 pp.

Data bases

The most comprehensive collection of Mossbauer data is kept by the Mossbauer Effect Data

Center (MEDC). situated at the University of North Carolina at Asheville. N.C.. United States.

Their data base is accessible on the web and they also produce specialized literature searches

(Mossbauer Micros) on different topics. including minerals. in paper and soft copy form . A

search of their data base will produce a larger set of valid references than a conventional

literature search because of the high proportion (- 30 %) of Mossbauer papers which are

presented at specialized conferences. not all of which are published in regular journals. and also

papers which contain Mossbauer data but do not have it in the title or keywords. They claim

to have over 99 .9 % of all papers ever published which have Mossbauer data as any part of the

article and can supply copies of any of these papers from their files.

Subsets of the data base are available as "Micros" and some of the 28 current topics

which may interest readers include: Minerals Parts I and II (also ava ilable in book form).

Relaxation. Microcrystals and Nanocrystals, Corrosion. Instrumentation. CEMS and Reviews.

See also Stevens et al. (1998) for further information.

The MEDC also produces a monthly journal. the Mossbauer Effect Reference and Data

Journal. which contains citations and data from all the latest papers and occasional feature

articles. Another useful publication is a list of recommendations for the reporting of Mossbauer

data, which has been approved by the International Board for the Applications of the

Mossbauer Effect and by IUPAC.

F. Berry, H. de Waard and 1. Stevens. 2001. Revised recommendations on nomenclature and

conventions for reporting Mossbauer data . Mossbauer Effect Reference and Data Journal

24(10) .

The MEDC can be contacted at their web site : http ://www.unca.edu/medc/ or via email

to MEDC@unca.edu.

Another useful source of information is the Mossbauer Information eXchange (MIX)

run from the Central Research Institute for Physics (KFKI) of the Hungarian Academy of

Sciences . This provides a web-site of information and an electronic newsletter to which

participants can send news items and requests. It can be contacted at its web site :

hltp ://www.kfki .hu/-mixhp or for instructions on subscribing to the MIX -Bulletin. send an

email to mix-request@sunserv.kfki.hu with INFO in the title line .

Data fitting programs

Many groups have developed their own data fitting programs. some of which have been

published and are available from the authors .

Mossbauer Spectroscopy of Environmental Materials 411

There are also several programs available commercially, for example:

RECOIL - Mossbauer Research Group . Physics Department. University of Ottawa. Ottawa.

Canada. httpv/www.physics.uouawa.ca, email : recoil @physics.uottawa.ca

WMOSS - WEB Research Co. Minneapol is MN. U.S.A.• http://www.webres.com. email:

tkent @webres.com

MOSSWINN - Department of Nuclear Chemistry, Eotvos Lorand University. Budapest.

Hungary , http ://www .chem.elte.hulnuclear/mosswinn.htm.

email : SUSU77@LUDENS .ELTE.HU

Mossbauer Spectroscopy ofEnvironmental Materials

Index

a-Fe, 16, 22, 28, 32, 55, 65, 85, 261, 271,

276,286,289,316,322

P-S~ 28~288

y-Fe, 271, 276, 289

Acid, 61,90,148,226,228,233,

235-238,250,262,276,284,302,332

- ammonium oxalate , 163, 186, 194,

206,213,236-237- mine drainage, 232-236, 242, 250,

269

Acidithiobacillus, 61, 233, 341

Activated carbon, 58,334,339,343-347

Akaganeite, 161-163,200-201 ,208-209,

211,232,237-239,307,333

Aluminium substitution, 137,170,177,

181-182,210-211 ,277-278

Ankerite , 259,268,273

Apatite , 332

Archaeology, 306-307

Arsenopyrite, 234, 335-342

Ash, 203, 256-258, 260-261, 273-281,

290

Au(CN)2, 339,343-345,347,348

AuCI, 344-345

AuCN, 343-344,347-348

Aurostibite, 337

Austenite , 53,315-317

Bacterial oxidation, 269,340

Bauxite, 283,332

Basalt, 229-230, 232

Bentonite, 148, 218, 221, 302, 317

Bemalite, 161-163

Biotite, 121 ,131 ,134,191 ,196,226-229,

268

Black coal, 256-257,261-262,268-269,

271-273,276,282,285-286

Bornite , 332-333Brown coal, 39,256,262-265,275-277,

280,285-286,289

Brucite sheet , 128, 243

Calaverite, 337

Calc ium aluminoferrite, 277-281

Carboni zation , 271, 275-276

Carburi zation , 318

Catalyst, 183, 185, 187,283-285,288

Cassiterite (see also SnOz), 315

Celadonite, 144, 147,229

Cementite, 276,285,317-318

Ceramics, 15, 135-136,291-293 ,298,

306,308,313

Chlorite, 117,129,193-199,228-229,

259,273 ,309,311,342

cis, 121 , 123, 129-130, 136, 142, 144,

147,149-150,152,154,221,228

Clay, 121 ,127-130,132-133,135-138,

140-142,148-149,152,157,159-160,

163-164, 189, 192, 198-199,207-212,

214-216,218-223,229,232,260,273,

277,291-292,298,301-302,306-313,

-firing, 135,159,165,291-313

-mineral , 18,120,126-127,129,204,

207,261 ,268-270,273,277,291-293,

308,311

- -size, 127-130,133,135,138,

141-142,152,157,160,189,291 ,302

Coal, 39, 91,204,232,250,252,255-290,

315,317

Colour, 42, 127, 142, 159-160, 165, 168,

172,178,190,193,196,199,211,222,

217,230,237,242,245,250,291,301,

307

Coke, 260, 272, 290, 317

Coquimbite, 259

Corrosion, 75,89,241-242,281 ,317,333

Crandallite, 332

Criddleite, 337

Crystallinity, 55-56, III, 125-126, 137,162-164,167,176,179-180,182-183,

185,1 88,190,192,198,211 ,223,234-235,237,283,342

Ferrimagnet,

Ferrite,

Ferritin,

Ferromagnet ,

FeSnz,

Firing,

414

Curie temperature, 13,33 ,166-167,177

Cyanide, 340-341, 343-347

Debye temperature, 4-6,23 ,287

Dithionite , 147,154- 156,163,190,

196-197,201 ,208, 211,214,21 7,

219,222-223,228,302,31 I

Electric field gradient (EFG), 25-27,

30-31,41-42,45-46,49, 83, 91,

96,165,167,267,281 ,335

Electron delocalization, 174

Electrum, 337

f-va1ue, 3-7,23,43,51-53,58,65,91 ,93,

104-107,109,123,125,257,323

Fayalite, 274

Feroxyhite, 161-163

Ferrihydrite , 119, 146, 150, 160-165,

182-188,192-201,203,206,209,211 ,

213-214 ,219,221 ,233-235,237,242,

280, 283-284, 339

14,16,30,32,174

15-16,273-274, 279,281 ,

315-317

159,183,186,209

13-14,16,30,32-33

285,289

127,135,142,150,159,165,

275, 291-296, 298-313

Fischesserite, 337,346

Frustration , 13, 18, 154,331

Gamet, 15, 27, 191

Glass, 52-53,58,61 , Ill , 114, 136,

154,217,230,260,271,273-275,277,

281,291,300,310,321 ,323,329,331

Glauconite, 144,147,150

Goethite, 12,34,41,152,155 ,160-163,

165,168-170,176-182,186,188,

190-193,196-197,199-201 ,203-205,

208-213 ,216-21 7,219,221-222,226,

229-230 ,232-237,244-245,247,250,

259,267,269-270,273,275,284,286,

307-308,310,317,329-330,333,339,

343

Index

Gold, 12,53,58,334-349

- , hidden, 347

Goldanskii-Karyagin , 43,50-51 , 133,344

Gossan, 216

Granite, 228

Green rust, 61, 241-245

Gypsum, 275

Halloysite, 136

Hematite, 12,16,28,31,69,143,

160-163,165-172,177-178,181 ,183,

188, 190-194, 196, 199-205, 208-212 ,

216-218,221,223,229-230,232,

250-251, 259-260 , 268, 271-276, 278,

281,296-297,300-303,305,307-311,

317-318,329,333,340

Hercynite, 274, 308

Humate, 264-265, 275, 285-286

Hydroliquefaction , 256,267-268, 273,

276,281-286,288-289

Illite, 128,134-135,141-147,149-150,

154,195,199,219,221 ,247,259-260,

270-271 , 273, 275, 298-302, 308-309,

311

Ilmenite, 215-216, 230, 329-331

Infrared (IR), 137,217

- spectroscop y, 10,37,64,132,137,

152, 183,209,292,295,319

Ionic radius, 59,129,137,169,216

Iron ore, 189,317-329

Iron oxide, 34,62,94,107,127,135-138,

144,148-150,152,154,157,159-188,

190, 192-193, 196-197,200-204,

208-214,216-219,221-223,226,

228-230 ,232,242,256,259,276,

283-284,290-291,294,307-308,

319,329,339

[ron substitution, 181,210,216

Isomer shift, 19-22,24,27-28,31,42,46,

54-55,58-60,62,65,71,96,107, Ill ,

113-117,138,140,165,173-174,177,

198,238,257,265,274,282,295-297,

300,310, 312,320-322 ,324-329,

334-339 ,344-345 ,348

Mossbauer Spectroscopy ofEnvironm ental Materials 415

Oxalate,

Nontronite,

Olivine,Ores,

Millisite,Montbrayite,Montmorillonite,

332

337

39,135,147-151,221 ,

259,301-304

Morin temperature, 166, 170

- transition, 31, 162, 165-170, 192, 20 I,

216,334

Mullite, 293-297,309

Nagyagite, 337Neel temperature, 15, 154, 168, 176,

178-179, 181,239,277,329

NMR, 12,19,32,37,53,64,136,294,

319

129,135,152-156,230,

304-306

Octahedral, 6, 15,27,42,55, 128-131,

138,141 ,144,147,149,159,175,178,

221,226,229-230,242,286,297,321-321

- coordination, 130,137,138,141 ,152,

172, 177, 184,219,263,275-276,

285-286,289,293-294,319,321-323,

325,338-339

- sheet, 128, 136, 138, 147

-site, 129,140,142,146-147,150,152,

154,156,165,178,201,230,245-247,

294,299,312,321,330-331

217,226,230

58,61, 182, 197,232,255,31~329,332,334-336,340-341,346,

348-349

Organic, 9,42,93 ,163,116-177,183,

193,196,208-209,241,247,255,272,273,275,282,286,289

163,186,194,197,201,206,

213-214,236-237

Oxidation, 61, 75, 129-130, 138, 147,

151 ,154,157,160,163,176,182,

192-194,196-197,199,216,225-237,

239,241-245 ,247-248,250,259,263,

269-271,275,282,291 ,298-299,323,329,340-342,347

Jarosite, 203,232-234,237-239,259-260,

268-269,275,342-343

Kaolin, 129,136,142,218,221-222,

295-296, 333

Kaolinite, 39,132,128-129,134-140,

142,144,148-149,199,214,216,

293-299, 308-311Komelite, 259

Kostovite, 337

Krennerite, 337

Laterite, 182,208,217-216,218

Layercharge, 128,141,147,152

Lepidocrocite, 160-163,200,214,235

Lignite, 4,255-256,268,275-277,281,

286

Loess, 190-I92

Lorentzian, 1-2,43-45 ,57,63, 72, 95-96,

98-99,102-104,107-109,111-115,117,

120,122,130,132,184,209,319

Lowtemperatureashing (LTA), 261, 268,

270,275

Maghemite, 12, 15, 159, 161-163, 165,

172, 176-178, 194, 20I, 210, 230-232,

268,305

Magnesioferrite, 15,58,260,273 ,278

Magnetite, 6,12,15,41,42,159-165,

172-176,189-191,194,196,199,201 ,

204-205,210,214,217,228-232,241 ,

245-247,259-260,268,271-273,275,

278,285,317-318,329-330,340

Maldonite, 337

Manganese, 85,169,189,197-198,201 ,

206,214,216

- nodules, 198-20I, 206

Marine, 144,190,198-199,203-204,214

Mars, 84-85,217,233

Melanterite, 235,250,252,259,342

Metakaolin, 293-297,309

Meteorite, 230-231

Mica, 87,91,134-135,137,141-142

Mine, 61,232-234,236, 239, 242, 250,

269,290,340-343,347

416

Paramagnetic, 12,29,38-39,57,106,

129,137,139,142,151 ,155 ,157,

164,166-167,173,179,183,190-191 ,

194,197,203, 205, 208, 211-212,214,

216-217,219, 221-223,230,232,

234-235,239, 250-251, 260, 274,

297-298, 300-302, 305, 307, 310, 312

- relaxation, 29,37-39,62,125 ,

132-133,139,146,150-151 ,157,

221-223,265-267,297,302-303,332

Particle size , 31,40,55,58,118,125-127,

152,160,164,167-168,170-172,

176-177,181-182,184-185,187,189,

194,200,204,207,209-210,212,

216-218,230,234,236,241,256,269,

277,283-285,290,292

Peat , 4,93,255

Petzite, 337

Pharmacosiderite, 343

Phyllosilicate, 123,127-157,1 60,164,

189,194,198-199,215,212,221 ,236,

247,291-293,302,307,310-312

Polyurethane foam, 58,345,347

Porphyrin, 262, 267

Pseudobrookite, 329,331

Pseudorutile, 329-331

Pyrite , 12,91 ,106,142,146,198-199,

204-205,232,250, 255-260,262,

267-273,275-276,278,282-285,290,

315-316,335-336,338-340,342,348

Pyrolysis, 256, 270-271, 276

Pyrrhotite, 260, 268, 271-273, 276,

282-286,289,340

Quadrupole splitting, 27-28,30-31 ,38,

46,49,53-55,58-61,91 ,109, Ill ,

113-117,119-120,129,138,140,144,

149-150,154,156,165-167,171 ,174,

177,179,183-186,194,196-197,

200-201,203-204,208-209,214,216,

218-219,228-229,238-239, 242-243,

245,264-265,274,276,294-297, 300,

302-306,308-310,312,320-322,

324-329 ,331 ,334-335 ,338-339,348

Index

Rapid Mossbauer, 316

Reco illess fraction , 3,7,43-44,51,83,

104, 107, 255, 257-258, 282, 288,

323, 332, 334-345

Redox, 147-148, 190,196,199,205,216

Reduction, 14,22,24,53,61 ,83,

147-149,154-157,170,181 ,193,

216-217,245,270,282,285,291 ,

297,317,323,343

Relaxation, 3,29,35-42,57,62,68,80,

82,86,95-96,99, 117-118, 122, 125,

132-133,139,146,150-151 ,179,

181-182,184-185,206,221-223,

265-267,284,288,297,302-303,332

Roemerite, 259

Rozenite, 250,252,259

Rutile, 329,331

Schwertmannite, 163,233-234,236-238

Scorodite, 342-343

Sediment, 142, 144, 147, 159-160, 172,

189-207,225,241 ,247-249,251-252

-, terrestrial, 190-192

- , freshwater , 190, 192-198, 203

- , marine , 190, 198-203

Serpentine, 128,135,140-141

Shale, 141, 232, 268

Siderite, 50,194,197-198,259,261-262,

268-270, 272-273

Slag , 58, 111 ,256,271 ,290,316-329,349Slime, 345-346

Smectite, 128,135,142,147-150,152,

154,199,201 ,214,216-217,219,221,

229,308-309

Sn, 10,285,287-289

SnCI2, 284, 286

SnO, 287-288

Sn02, 151 ,284-285, 287-289, 315

SnS , 285,287-289

~SO~ 2M

Soil, 61,136-138,141 ,147,159-160,

163-164,172,176-178,181-182,189,

196,204,207-218,221-223,228-229,

231-232,242,245,307

Miissbauer Spectroscopy ofEnvironmental Materials 417

Spinel, 6,15-16,58-59,126,159,161 ,

172, 176-177,200,274,278,293-296,

300,302,329

Structure, 14-16,27,36,39-40,61 ,66,

121 ,127,132,136,140,144,161 ,

165-167,169,172,174,176-178,

182-183,214,229,237-239,245,267,

271,277-278,284,293-294,296,305,

319,323,329,331,333-334,336,340,

344-345

Sulfate, 150, 190,233-234,237-239,243,

250,257,259-260,262,269-270,

272-273,276,280-281 ,285,341 ,343

Sulfide, 232-237,239,250,259,284,336,

340-341Superparamagnetic relaxation, 40, 179,

181-182,184,206

Superparamagnetism, 23,29,36,39,41 ,

99,117-118,124,179,267,273,277

Sylvanite, 338

Synchrotron, 3,9, 84-85, 87, 245

Szomolnokite, 235,250,259,282,285

TBP, 345

Tetrahedral, 6,55 ,129-131 ,141 ,144,

147,152-156,175,183,229-230,

297,319,321-322

- coordination, 129,146,159,172, 174,

177,183-184,294,321 ,325

- sheet, 128

- site, 15,129,142,152,154,172,230,

247,294,331

Texture, 43,49-52,59,91 ,94, 106, 109,

114, 133-134,344Titanium, Ti, 10, 43, 53, 159, 168, 176,

320, 329-331

W+, 42-43, 126, 176,329-331

Titanomagnetite, 176, 199,217,230,

329-330

trans, 121 , 123, 129-130, 142, 144, 147,

15~ 152,221 ,228,306

Troilite, 230,260,268,271-272,283 ,

285,286

Olvospinel, 176, 329

Vermiculite, 226,228-230,339

Verwey transition, 6,28, 162, 172

Vivianite, 42,193,197,268

Voigtian, 112,115,117,120

Volcanics, 196

Water, 4,87-88, 136, 148, 167-168, 170,

179, 182, 186, 189, 195,207,225,233,

255,262,265,267,272,275,280,287,

293,299

Weathering, 127,136,144,147,157,159,

172, 178, 189, 192, 196,207-208,

216-218, 225-239, 255-256, 268-269,

329,343

X-ray diffraction, 50,55,58-59,128,133,

135,137-138,148,163-164,177,180,

182, 188, 192-195, 197, 200-20 I, 205,

208-209,211 ,214,216,219,221-222,

226,228,232,234-239,241,245,257,

274,282,285 ,291-297,299-300,306,

308,311

About the Authors

John John Cashion (left) is Associate Professor in the School of Physics andMaterials Engineering at Monash University in Melbourne , Australia. He wasborn in Launceston , Tasmania in 1942 and completed a B.Sc. and an M.Sc. inphysics at the University of Melbourne. In 1969 he completed a D.Phil. atOxford University. His first appointment was in the Department of Physics atMonash University, where he has remained ever since. He has held visitingappointments at the Technical University of Munich, Germany, the Los AlamosNational Laboratory, the Argonne National Laboratory (both in the USA) andthe CSIRO Division of Mineral Processing in Melbourne , Australia.

Enver Murad (right) heads the external section of the Geological Survey ofBavaria in Marktredwitz, Germany. He was born on the 9 June 1941 in Berlin,Germany. In 1966 he graduated in mineralogy from the Technische HochschuleDarmstadt , and received a PhD in mineralogy in 1970 from the University ofFrankfurt. Following graduation he was employed on research positions at theUniversities of Tubingen and Munich, Germany, where he completed a Dr. rer.nat. habil. in 1986, and the North Carolina State University in Raleigh, NC.

Both John Cashion and Enver Murad have cooperated over many years in thestudy of minerals, soils and clays using Mossbauer spectroscopy.