programme of study - ensc-lille.fr · michel fontanille, yves gnanou dunod, 2002 isbn 2100039822 -...

2014-2015

École Na! onale Supérieure de Chimie de LilleAvenue Mendeleïv - BP 90108 - Bât. C7

Cité Scien� fi que

59652 Villeneuve d’Ascq cedex

FRANCE

Contact : interna� [email protected]

www.ensc-lille.fr

Programme of studyNa! onal Graduate School of Engineering Chemistry of Lille

(France)

Année 2012-2013

3rd academic year (semesters 5 and 6)

MODULE : ORGANIC AND MOLECULAR CHEMISTRY

SUBJECT:

STRUCTURE AND REACTIVITY OF ORGANIC MOLECULES

Chim

Coordinator:

Professor Philippe Cotelle

[email protected]

+33 (3) 20 43 48 58

Building C1-Office 101

Compulsory

Code: CH1503

Semester: 5

Lecture: 17 Hours

Directed studies: 11 Hours

Language: French

Coefficient: 3

ECTS: 1.5

Instructor(s):

Philippe Cotelle

Learning outcomes:

Give the same basis for every student from all particular formations

The students will be able to:

Have an idea of the structural 3D representation of an organic compound

Anticipate the reactivity from the structure and the electronic properties of a molecule

Propose reasonable short synthetic route(s) for the synthesis of organic compounds

Prerequisite:

Basic competences acquired during previous formations (CPGE, CPI, DEUG, DUT, BTS, ATS).

Paul Arnaud : Cours de chimie organique, Dunod 15ème édition, 1990, ISBN 2-0401-9716-8. Nicolas

Rabasso : Chimie organique, de Boeck, 2006, ISBN 2-8041-5210-3

Contents:

Chemical bond (theory of the covalent bond, hybridization concept, molecular orbital theory…)

3D structures of small organic molecules

Reactivity in relation with the structure and the electronic properties

Additions to multiple bonds

Aliphatic Substitutions on sp3 carbon

Eliminations

Substitutions on aromatic carbons (electrophilic and nucleophilic)

Pericyclic reactions (including Diels-Alder reactions)

Aldehydes and ketones : tautomeric equilibrium (keto/enol), condensations, transpositions.

Addition on the carbonyl function, Michael addition, Robinson annulation

Additional information:

Media: powerpoint presentation

Bibliographical references: Vollhardt, Schore : Traité de chimie organique, 5ème édition,2009, ISBN 2-

8041-5884-5

Clayden, Greeves, Warren, Wothers : Organic chemistry, 1ère édition, 2001, ISBN 978-0-19-850346-0

Assessment: two written exams (the first one in november, 1 hour, the second one in january, 2 hours)

Remarks:

CI 1Y

mailto:[email protected]


SUBJECT:

APPLIED MOLECULAR SPECTROSCOPIES

Chim

Coordinator:

Philippe Cotelle

[email protected]

03 20 43 48 58


Compulsory

Code : CH1502

Semester : 5

Lecture: 15 Hours

Directed studies:

Language : French

Coefficient : 4

ECTS : 2

Instructor(s) :

Prénom(s) /Nom(s)

Learning outcomes :

(Description en termes de compétences générales ou spécifiques.)

Prerequisite:

(Exigences préalables. Indication des connaissances préalables présumées acquises au début de l'unité de cours; indication des cours requis au préalable.) Contents :

Other :

Contents :

(Présentation concise de chaque unité.)


Media :

Bibliographical references:

Assessment: (nature, durée, chronologie, fréquence)

Remarks:

CI 1Y

Instructor(s):

Eric BUISINE

[email protected]

Phone: 03 20 33 77 48

ENSCL - C7B

Learning outcomes:

The aim of this course is to develop fundamental knowledge necessary for a good understanding of the

main molecular spectroscopy techniques used in analytical chemistry. The course describes Micro-

Wave rotational spectroscopy, Infra-Red vibrational spectroscopy and UV/Vis electronic spectroscopy.

Prerequisite:

None

Contents:

Chapter I - Introduction: electromagnetic wave ; electromagnetic spectrum ; absorption and emission of radiation ; molecular energy states ; population of molecular states and transitions ; transition dipole moment ; transition probability ; selection rules ; measurement of the absorption mode intensities ; spectral linewidth ; spectrum sensitivity and resolution. Chapter II - MW rotational spectroscopy: moments of inertia ; molecular rotators - Diatomic and linear

polyatomic molecules: frequencies and intensities of rotational transitions ; selection rules ; centrifugal

distortion effect ; rotation-vibration coupling - Non-linear molecules.

Chapter III - IR vibrational spectroscopy - Diatomic molecule: harmonic oscillator approximation ; fundamental vibration frequency ; effect of bond strength ; effect of atomic masses ; selection rules and intensities of vibrational transitions ; rovibration spectrum ; selection rules and intensities of rovibrational transitions - Polyatomic molecules: vibrational degrees of freedom and normal modes of vibration ; bond deformation vibrations ; angular deformation vibrations ; selection rules and activity of normal modes ; intensity of vibrational transitions ; harmonic and combination spectral lines. Chapter IV - UV/Vis electronic spectroscopy - Molecular electronic states ; electron configuration and molecular spin states (doublet, triplet…) ; electronic transitions in organic molecules ; Franck-Condon principle ; selection rules and intensity of vibronic transitions ; chromophores and solvatochromism ; desexcitation mechanisms ; fluorescence and phosphorescence. Additional information:

Media : copy of PowerPoint presentations are accessible from the intranet

Bibliographical references: None

Assessment: written 2 hour exam without documents (semester 6)

Remarks:

Related directed studies are given in the course unit CH1602 (semester 6)

The exam is unique for the two course units CH1502 and CH1602



http://www.sciencedirect.com/science/article/pii/0009261477806209

http://www.sciencedirect.com/science/article/pii/0009261477806209


SUBJECT:

APPLIED MOLECULAR SPECTROSCOPIES

Chim

Coordinator:

Philippe Cotelle

[email protected]

+33 (3) 20 43 48 58


Compulsory

Code: CH1602

Semester: 6

Lecture: 13 Hours


Language: French

Coefficient: 4

ECTS: 2

Instructor(s):

Eric BUISINE

[email protected]

Phone: 03 20 33 77 48

ENSCL - C7B

Alain MOISSETTE

(IR and UV/Vis: directed

studies)

[email protected]

Phone: 03 20 43 69 62

LASIR - C8)

Learning outcomes:

Acquiring fundamental knowledge necessary for a good understanding of the one-dimensional Nuclear

Magnetic Resonance (NMR) molecular spectroscopy applied to 1H and 13C nuclei ; determining the

potential structures of small organic molecules from their 1H and 13C 1D-NMR spectra but also from

their IR vibrational and UV/Vis electronic spectra.

Prerequisite:

Contents: course unit CH1502 (semester 5) Contents:

Chapter I - Introduction: NMR active nuclei ; energy and magnetic/spin states of nuclei in organic molecules ; spin transition and magnetic resonance frequency ; macroscopic magnetization ; basic pulsed NMR principles; the signal in pulsed NMR (FID); relaxation mechanisms ; Fourier Transform of the NMR signal ; intensity of NMR signals and quantitative analysis ; introduction to 13C NMR spectroscopy (NOE effects, 1H decoupling technique). Chapter II - Chemical Shift: definition ; shielding constant ; shielding and deshielding effects ; magnetic

anisotropy of molecules ; chemical shifts of typical 1H and 13C nuclei in organic molecules ; influence of

conformational and chemical exchanges.

Chapter III - Scalar spin-spin coupling: polarization mechanisms ; scalar coupling energy ; coupling and

chemical structure ; typical 1H-1H homonuclear coupling constants (geminal, vicinal, long-range) ;

coupling of 1H nuclei bound to heteroatoms ; chemical equivalence ; magnetic equivalence ; first- and

second-order scalar coupling systems.


Media: copy of PowerPoint presentations are accessible from the intranet

Bibliographical references: none

Assessment: written 2 hour exam without documents (semester 6)

Remarks:

The exam is unique for the two course units CH1502 and CH1602

With regard to directed studies, 6 hours are dedicated to interpretation of IR vibrational and UV/Vis

electronic spectra and 8 hours to interpretation of 1D-NMR 1H and 13C spectra.

CI 1Y




SUBJECT:

ADVANCED ORGANIC CHEMISTRY

Coordinator:

Philippe Cotelle

[email protected]

+33 (3)20 43 48 58

Building C1- Office 101

Compulsory

Code: CH1603

Semester: 6

Lecture: 20 Hours


Language: French

Coefficient: 3

ECTS: 1.5

Instructor(s):

Gaëlle Fontaine

[email protected]

03 20 43 46 83

Bureau 2

Learning outcomes:

Synthesis and reactivity of multifunctional organic compound and heterocycles

Prerequisite:

Contents:

Carboxylic compounds and derivatives Amines Heterocycles Phosphorus, Sulfur, Selenium, Boron and Silicon based compounds



Vollhardt, chimie organique, De Boeck, 1990.

Rabasso, N.: Chimie organique; généralités, études des grandes fonctions et méthodes

spectroscopiques; De Boeck, 2006.

Remarks:

CI 1Y




SUBJECT:

INTRODUCTION TO POLYMER CHEMISTRY

Chim

Coordinator:

Philippe Cotelle

[email protected]

+33 (3) 20 43 48 58

Building C1 - Office 101

Compulsory

Code: CH1604

Semester: 6

Lecture: 8 Hours


Language: French

Coefficient: 1

ECTS: 1

Instructor(s):

Patrice WOISEL

Frédéric CAZAUX

Learning outcomes:

The purpose of this course is to introduce the basic concepts of polymer synthesis and to describe

leading features of polymers.

At the end of the module, students will be able to:

- understand what polymers are made up of, their properties, and basic polymer nomenclature

- identify the key parameters of the free radical homopolymerization

- understand the principle industrial polymerization processes work

Prerequisite:

CH1503

Contents:

- Introduction to polymer chemistry: historical and economic backgrounds

- Kinetics and thermodynamics of free redical polymerizations

- Industrial polymerization processes


Media: Duplicated lecture note + documents given during the courses


- La polymérisation : Principes et applications

George ODIAN Polytechnica, 1994 ISBN 2840540282

- Chimie et physico-chimie des polymères

Michel FONTANILLE, Yves GNANOU Dunod, 2002 ISBN 2100039822

- Exercices et problèmes de chimie macromoléculaire

Thierry HAMAIDE, Michel BARTHOLIN Editions TEC & DOC, 1999 ISBN 2743003537

Assessment: 1 written exam (1H30)

Remarks:

CI 1Y


MODULE : INORGANIC CHEMISTRY

SUBJECT:

INTRODUCTION TO SOLID STATE CHEMISTRY

Coordinator:

Rose-Noelle Vannier

rose-noelle.vannier@ensc-

lille.fr

+33 (0)3 20 43 65 83 / office

208

Compulsory

Code: CH1506

Semester: 5

Lecture: 16 Hours


Language: French

Coefficient: 2

ECTS: 1

Instructor(s):

Murielle Rivenet

[email protected]

03 20 33 64 35 / room 228

Learning outcomes:

To know the main structure types. To quote the structure types of solids with an example. To calculate

compactness of a solid. To determine the coordination number and coordination polyhedron of an

atom or an ion in the solid. To be able to establish the relations between the lattice parameters, the

interatomic or interionic distances and the density within a solid. To describe the intermolecular forces

responsible for the solids cohesion. To analyze the nature and strength of the cohesion forces existing

in a solid. To calculate the lattice energy. To predict the structure of a solid according to Pauling’s rules

and to the calculation of the crystal field stabilization energies (Jahn-Teller effect). To explain the

electrical properties starting from the band theory. To know some physical properties of solids as for

examples: luminescence, lasers, conductivity of graphite and of graphite intercalation compounds,

lithium batteries, applications of semi-conductors. To be able to explain the relation between the

properties of materials and their solid structure.

Prerequisite:

Electronic structure of atoms according to the quantum theory – Periodic table of the elements -

Properties of the elements and their trend along the periodic table - Lewis’s chemical bonding theory –

Basis on the quantum theory of chemical bonding – Prediction of the molecular geometry according to

the Valence Shell Electron Pairs Repulsion (VSEPR).

Contents:

The first part of the lecture aims to describe the crystal structures of various materials according to

their bond types: metals, ionic structures, covalent network structures and molecular structures. The d

electron effects on transition metal compounds are considered on the basis of the crystal field theory

and on the Jahn-Teller effects. A section is devoted to the calculation of the lattice energy of ionic

crystals using either the sum of the electrostatic forces or the Born-Haber cycle and thermochemical

calculations.

The second part introduces the band model for bonding. Then, some of the physical properties of solids

are seen: electronic conductivity and optical properties. This section aims to relate the physical

properties of solids to their electronic and crystal structures. Many applications of solids are considered

in order to illustrate the factors that influence the selection of a material for a particular application.


Media: slides

Bibliographical references: Chimie des solides, Jean-Francis Marucco, Ed. EDP Sciences - Introduction à

la chimie du solide, Lesley Smart, Elaine Moore, Ed. Masson - Solid State Chemistry and its applications,

Anthony R. West, Ed. Wiley - Introduction à la cristallographie et à la chimie structurale, Maurice Van

Meerssche, Janine Feneau-Dupont, Ed. Peeters - Chimie inorganique, André Casalot, André Durupthy,

Ed. Hachette Supérieur

Assessment: a first written exam on prerequisite in november (1 hour of examination) and a final

written exam in January (2 hours of examination)

Remarks:

CI 1Y

mailto:[email protected]/


SUBJECT:

CRISTALLOGRAPHY

Coordinator:

Rose-Noëlle VANNIER


lille.fr

+33 (0)3 20 43 65 83

C7 A, Office 208

Compulsory

Code: CH1507

Semester: 5

Lecture: 24 Hours

Directed studies:

Language:

French/English

Coefficient: 3

ECTS: 2

Instructor(s):


Learning outcomes:

The aim of this lecture is to give the basics in crystallography to approach the field of materials science,

on one hand, and the analysis of crystalline structures of either mineral or organic compounds, on the

other hand.

Crystallographers have their own rules and language. At the end of this lecture, students should be able

to understand the description of crystalline structure (bibliography) and discuss with specialists in the

field.

They will possesses the necessary bases to approach the characterization of materials by X-ray

diffraction, a technique which is widely used for the analysis of minerals and metals, for instance in the

field of cement or materials recycling.

Prerequisite:

No prerequisite Contents :

In a first part, the lattice and symmetry in crystals are explained. Then, the international tables of

crystallography are introduced. In a second part, X-ray diffraction on single crystal and powder is

described with an emphasis on the evidence of element of symmetry in the crystalline structure.


Media: A copy of the necessary media to follow the lecture will be given to the student. The main part

of the lecture is available on the intranet network of the school.

References:

Eléments de radiocristallographie, R. Ouahes, Ed. Publisud,

Analyse structurale et chimique des matériaux, J.P. Eberhart, Dunod,

Les rayons X, A. Guinier, Collection "Que sais-je ?", Presses universitaires de France,

International Tables for Crystallography, Volume A, edited by Theo Hahn, by Kluwer Academic

Publishers, Dordrecht/Boston/London (1989).

Assessment:

A written exam, 2h.

Remarks:

This subject requires a personal work to master the crystallographic tools. Corrected exercises and

previous exams with their correction are available on the intranet network of the school so that the

student can train themselves.

This lecture is opened to the foreign students within the framework of the international exchanges of

the school and, if needed, it can be given in English

CI 1Y




SUBJECT :

INORGANIC AND INDUSTRIAL CHEMISTRY

Coordinator:



lille.fr

03 20 43 65 83

C7 A, Office 208

Compulsory

Code: CH1606

Semester: 6

Lecture: 20 Hours

Directed studies:

Language: French

Coefficient: 2

ECTS: 1

Instructor(s):


Learning outcomes:

The objective of this lecture is to get a general knowledge on the basic mineral products (halogen,

hydrogen, ammonia, nitric acid, oxygen, nitrogen) from their preparation to their use. Main points are:

electrolysis of Moissan, preparation of chlorine, methane reforming, hydrogen storage, Ni-MH battery,

fuel cells, Li-ion battery, oxygen and the nitrogen separation from air.

Prerequisite:

No prerequisite Contents:

The lecture is divided into 6 chapters: I. Halogens (preparation of fluorine (uranium enrichment), of chlorine, of bromine and iodine)

II. Hydrogen, vector of energy for future, from its production to its storage

III. Hydrides (Ni-MH battery, synthesis of ammonia, nitric acid)

IV. Fuels cells (different kind of FC: PEM, DMFC, MCFC, SOFC, defect in solids, solid state reaction, sol-

gel, shaping techniques)

V. From alkaline cells to Li-ion battery

VI. Oxygen and nitrogen from air (distillation from liquid air, PSA, VSA process)





Techniques de l'Ingénieur,

Actualité chimique,

Cours de chimie minérale, Maurice Bernard, Ed. Dunod,

Chimie industrielle, Robert Perrin, Jean-Pierre Scharff, ed. Masson

Chimie Inorganique, R.B. Heslop, P.L. Robinson, Ed. Flammarion Médecine Sciences

Descriptive Chemistry, Mc Quarries, Rock, Ed. freeman and co, New-York

Assessment: A written exam, 2h.

Remarks:

Corrected exercises and previous exams with their correction are available on the intranet network of

the school...

CI 1Y



MODULE : GENERAL CHEMISTRY

SUBJECT:

THERMODYNAMICS

Coordinator:

Prof. Sergey GORYACHEV

serguei.goriatchev@ensc-

lille.fr

Tel: +33 (0)3 20 33 64 96

Building P5 -Office 221

Compulsory

Code: CH1508

Semester: 5

Lecture: 28 Hours


Language: French

Coefficient: 4

ECTS: 2

Instructor(s) :


Prof. Charaffeddine JAMA

Learning outcomes:

Can to use the main thermodynamic functions and relations in Chemical Engineering and Material

Sciences.

Know the behavior, the equations of state and the thermodynamic diagrams of real gases, fluids and

solids.

Be able to deal with the phase transformations.

Know how to calculate a chemical equilibrium state of thermodynamic system.

Prerequisite:

Fluid mechanics. Statistical physics. General thermodynamics.

Contents:

Courses

Statistical thermodynamics. Thermodynamics quantities. Thermodynamics data. Thermodynamics

transformations. Real gases. Phase equilibrium. Solutions. Chemical reactions.

Directed studies

Thermodynamics principles. Functions of state. Chemical potential. Reaction quantities. Evolution

and equilibrium of a system. Variance. Displacement of chemical equilibrium. Binary solid-liquid and

liquid-vapor equilibrium.



1. Landau L., Lifchitz E. - Physique statistique, Ellips, Paris, 1998.

2. Durupthy A. et al. - Thermodynamique chimique, 2de année PC-PC*, Cours avec exercices corrigés,

Hachette, 1996.

3. Brénon-Audat F. et al. - Thermodynamique chimique, 2de année PC-PC*, Exercices et problèmes

corrigés, Hachette, 2003.

4. I. Prigogine, D. Kondepudi - Thermodynamique : des moteurs thermiques aux structures dissipatives,

Edition Odile Jacob, Paris, 1999.

Remarks:

CI 1Y




SUBJECT:

ELECTROCHEMISTRY IN SOLUTION

Coordinator:

caroline.pirovano@ensc-

lille.fr

+33 (0)3 20 43 49 73

Building C7a - Office 224

Compulsory

Code: CH1501

Semester: 5

Lecture: 9 Hours


Language: French

Coefficient: 2

ECTS: 1

Instructor(s):

Caroline PIROVANO

Christophe VOLKRINGER

Learning outcomes:

The acquisition of the electrochemistry fundamentals in solution

Prerequisite:

● Basic knowledge acquired in preparatory years

● Complementary knowledge learnt in Practical studies of Analytical Chemistry (TP1501) Contents:

Brief plan of the course:

● Chemical Equilibrium in solution

Thermodynamics, Acid-base equilibrium, Complexation, Solubility and precipitation

● Redox Reactions

The redox potential, The electrochemical potential, Nernst equation, Diagrams of Latimer, Formal

Potential, Diagrams of Pourbaix

● Electrodes

The electrochemical chain, Redox indicator electrodes, Reference electrodes, Ion selective electrodes

● Electrochemical processes - Fundamentals notions

Principle of the production of electrochemical reactions, Faraday's law, Faradaic versus non-faradaic

processes, The electrochemical cells, Galvanic cells, Electrolytic cells, the electrochemical cell for

electroanalytical measurement: the three electrodes cell


Media: lecture manual and materials for tutorial classes. Additional documents are available on the

intranet (annals of the examination with corrections)


● Électrochimie analytique et réactions en solution, B. Trémillon, tome 1 & 2, Éd. Masson (1993)

● Électrochimie, des concepts aux applications, F. Miomandre, S. Sadki, P. Audebert, R. Méallet-

Renault, Sciences Sup, Dunod (2005)

● Electrochemical Methods: Fundamentals and Applications, Allen J. Bard, Larry R. Faulkner, 2nd

edition, Éd. Wiley (2001)

Assessment: An intermediate written examination (1h30 by the end of October or beginning of

November). A final written examination (2h in January).

Remarks:

CI 1Y




SUBJECT:

APPLIED THERMODYNAMICS

Coordinator :

Compulsory

Code: CH1608

Semester: 6

Lecture: 8 Hours

Directed studies:

Language: French

Coefficient: 1

ECTS: 1

Instructor(s) :

Charlotte.becquart@ensc-

lille.fr

Bâtiment C6, Office 17,

+33 (0)3 20 43 49 44

Learning outcomes:

Use of Ellingham diagramm

A good understanding of phase diagrams

Knowledge of how a blast furnace operates

Knowledge of the processing of Al

Prerequisite:

Thermodynamics (S5)

Contents:

I Processing methods of metals and alloys

II Which method should one use? ; II-1 Reminders in Thermodynamics; II-2 Ellingham Diagramms ; II-3

Oxyde reduction by hydrogen and C oxyde

III Steel processing ; III-1 small historical introduction ; III-2 Fe oxydes ; III-3 The blast furnace ; III-4

Phenomena involved in the process ; III-4 From cast iron to steel ; III-5 Electrical processing of steels ;

III-6 Casting III-7 Rolling

IV Al processing; IV-1 A bit of history IV-2 from the ore to the oxyde: beauxite to Al2O3 ; IV-3 from the

oxyde to liquid Al ; IV-4 processing of the melt ; IV-5 Al Recycling

V Thermodynamical bases for the interpretation of equilibrium diagrams


Bibliographical references: 1/ « précis de métallurgie », Jean Barralis et Gérard Maeder, Edition Nathan,

2005.

2/ « Métallurgie : du minerai au matériau », Jean Philibert, Alain Vignes, Yves Bréchet et Pierre

Combrade, Edition Dunod, 2002

3/ « Phase transformations in metals and alloys », David A. Porter and K.E. Easterling, Van Nostrand

Reinhold (UK) Co. Ltd 1981

4/ « Thermodynamique des matériaux, de l’élaboration des matériaux à la genèse des

microstructures », Gérard Lesoult, Traité des matériaux, Presses polytechniques et universitaires

Romandes, 2010.

Assessment: 1 hour written exam at the end of the course

Remarks:

CI 1Y




SUBJECT:

KINETICS

Coordinator:

anne-sophie.mamede@ensc-

lille.fr

+33 (0)3 20 33 70 90

Building C3 - Office 106

Compulsory

Code: CH1609

Semester: 6

Lecture: 16 Hours


Language: French

Coefficient: 3

ECTS: 1

Instructor(s):

Anne-Sophie MAMEDE

Learning outcomes:

The course is designed so that engineering students can acquire and use the concepts of chemical

kinetics: understanding patterns and reaction mechanisms, establishing rate laws and identifying the

factors influencing the rate of the chemical reaction (temperature, pressure, ionic strength in solution,

catalysts ...)

Prerequisite:

Mathematical notions including the integration of differential equations

Basic knowledge in Physical Chemistry gained in preparatory classes (CPGE, CPI, L2, DUT, BTS, ATS…)

Contents:

The first chapter contains general information on chemical transformations and their kinetic evolution

to determine the order of the reaction and its rate constant. The second chapter presents the basic

processes and concepts of rate theories (elementary theory of collisions and activated complex theory).

The third chapter is dedicated to the kinetics of chemical processes in homogeneous phase

(nucleophile substitutions and consecutive, parallel, opposed, chain reactions, etc. ...). The fourth

chapter focuses on the kinetic aspects of reactions in liquid phase with the study of the influence of

diffusion, of the dielectric permittivity of the solvent or of the ionic strength. Catalytic phenomena in

solution, including acid-base and enzymatic catalysis are also discussed. Fifth chapter deals with the

kinetics of heterogeneous catalysis with introduction to the concepts of molecular adsorption and

desorption, of Langmuir isotherm and of BET isotherm characterizing physisorption phenomenon.

Finally some mechanisms of heterogeneous catalysis are presented including the models of Langmuir-

Hinshelwood and of Eley-Rideal.


Media: Class and practical exercises manuals


Introduction à la cinétique chimique, S. Logan, Dunod, 1998

Cinétique et catalyse, G. Scacchi, M. Bouchy, J.-F. Foucaut, O. Zahraa, R. Fournet, Editions Tec&Doc,

Lavoisiser, 2011

Cinétique et catalyse hétérogène, B. Gilot, R. Guiraud, Technosup, Ellipses, 2004

Assessment: Written evaluation of 2 hours with class manual

Remarks:

CI 1Y




SUBJECT:

ELECTROCHEMICAL METHODS

Coordinator:


lille.fr

+33 (0)3 20 43 49 73

Building C7a- Office 224

Compulsory

Code: CH1601

Semester: 6

Lecture: 11 Hours


Language: French

Coefficient: 3

ECTS: 2

Instructor(s):

Caroline PIROVANO


Learning outcomes:

In the continuity of the course of electrochemistry in solution (CH1501), this teaching allows to deepen

the general theoretical characteristics of the electrochemical processes and to approach the main

electroanalytical methods.

Prerequisite:

● Electrochemistry in solution (CH1501) Contents:

● Mass transfert

Nernst-Planck equation, convection, migration, diffusion and Fick's laws, the Nernst diffusion layer and

steady-state conditions, the Cottrell equation

● Electrodes kinetics

Standard electrochemical rate constants, Butler-Volmer kinetics, the Tafel law, mass transfer versus

charge transfer

● Current-potential curves: examples and applications

Current-potential curves applications, sensors and biosensors, organic electrochmistry, inorganic

electrosynthesis, corrosion, etc.

● Potentiometry and amperometry

Potentiometric method (at i = 0 and i 0), amperometric method

● Voltammetry

General principle and experimental consideration, polarography and mercury electrodes, cyclic voltammetry, pulse voltammetry, (staircase voltammetry, NPV, DPV, SWV, stripping voltammetry) Additional information:

Media: lecture manual and materials for tutorial classes. Additional documents are available on the

intranet (annals of the examination with correcVolmertions)


● Électrochimie analytique et réactions en solution, B. Trémillon, tome 1 & 2, Éd. Masson (1993)

● Électrochimie, des concepts aux applications, F. Miomandre, S. Sadki, P. Audebert, R. Méallet-

Renault, Sciences Sup, Dunod (2005)

● Electrochemical Methods: Fundamentals and Applications, Allen J. Bard, Larry R. Faulkner, 2nd

edition, Éd. Wiley (2001)

Assessment: written examination (2h in January)

Remarks:

CI 1Y



MODULE : CHEMICAL ENGINEERING

SUBJECT:

FLUID MECHANICS AND HYDRODYNAMICS

Coordinator:

[email protected]

+33 (3)20335436

Ecole Centrale de Lille

Compulsory

Code : CH1509

Semester : 5

Lecture: 12 Hours


Language : French

Coefficient : 2

ECTS : 1

Instructor(s):

Nouria/Fatah

Learning outcomes:

Fluid mechanics : Fluid statics, Ideal and real fluid dynamics. Basic relations. Viscosity, pressure drop

(on line and miscellaneous). Piping design and specifications. Fluid pumping, centrifugal pump

specification.

Prerequisite:

Unit operations: Elementary knowledge gained in preparatory classes (CPGE, CPI, DEUG, DUT, BTS, ATS, Licence) Contents:

Introduction-Basic definitions-Symbols and Unit-Definition of the pressure and physical flow-Properties of the liquid- Fluids Statics- Energy conservation system- fluids dynamics - pressure and fluid measurement, pumps. Additional information:

Media:

Copy of slides presentation


-Coulson J.M., Richardson J.F. , ‘Chemical Engineering’, Pergamon Press 1990

-R.Byron Bird, Warren Stewart, et E.N. Lightfoot : “Transport phenomena”, John Wiley & Sons 2001

-Cours de Mr Acloque (site intranet de l'ENSCL)

Assessment:

Lectures: 5 sessions of course, 1h20 duration and 2 sessions of class work, 1h 20 duration.

Written exam 2h, without documents

Remarks:

CI 1Y

mailto:[email protected]+33%20(3)20335436Ecole%20Centrale%20de%20Lille




SUBJECT:

HEAT AND EXCHANGE TRANSFER

Coordinator:

[email protected]

+33 (3)20335436


/Building C

Compulsory

Code : CH1610

Semester : 6

Lecture: 10 Hours


Language : French

Coefficient : 2

ECTS : 1

Instructor(s):

Nouria/Fatah

Learning outcomes:

General. Heat transmission by radiation, conduction. Different types of heat exchangers. General

relations for heat transfer coefficients. Design of shell and tube exchangers. Special study of

evaporators, reaction vessels - steady and unsteady operation.

The goal of this class : Analysis of heat transfer problems : méthodology

Prerequisite:

Fluid mechanics and applied thermodynamics

Contents:

-Units and dimensions -Physics origins and rate equations (conduction, convection and radiation)-conservation of Energysrequirement-Heat Exchangers (Heat exchangers types, heat exchangers analysis, heat exchangers design and performance calculations) Additional information:

Media : copy of slides presentation


-Coulson J.M., Richardson J.F. , ‘Chemical Engineering’, Pergamon Press 1990


-Course : A. Acloque (site intranet de l'ENSCL)

Assessment: Lectures: 6 sessions of course, 1h20 duration and 2 sessions of class work, 2h duration.

Written exam 2h, without documents,

Remarks:

CI 1Y





SUBJECT:

MASS TRANSFER AND ABSORBERS

Coordinator :

Nouria Fatah

[email protected]

+33 (0)3.20.33.54.36


Building C.

Compulsory

Code: CH1611

Semester: 6

Lecture: 11 Hours


Language: French

Coefficient: 2

ECTS: 1

Instructor(s) :

Marek Czernicki

Learning outcomes:

Main objective of this course is to give basic concepts of the absorption process. This lecture covers the

methods used to calculate the absorbers. Diffusive and convective mass transfer is presented. Different

methods to calculate mass transfer coefficients are shown

The goal of this class is that students will develop a conceptual understanding of mass transfer

processes

Prerequisite:

Topics to be covered include: Principles of mass transfer, diffusion in gas and liquid, Fick's laws of diffusion. Differential equations of mass transfer, determination of mass transfer coefficient, calculation of counter-current and co-current packed bed columns. Contents:

Topics to be covered include: Principles of mass transfer, diffusion in gas and liquid, Fick's laws of diffusion. Differential equations of mass transfer, determination of mass transfer coefficient, calculation of counter-current and co-current packed bed columns.


Media: copy of presentation


Coulson J.M., Richardson J.F. , ‘Chemical Engineering’, Pergamon Press 1990


-Lefrançois B., ‘Chimie Industrielle’, Technique et Documentation Lavoisier, Paris 1995

-Techniques de l’Ingénieur, Transfert de matière J1077, Distillation absorption colonnes garnies J2626,

Cinétique de transfert de matière entre 2 phases J1075.

- Lieto J., ‘Le Génie Chimique à l’Usage de Chimiste’, Techniques et Documentation, Lavoisier, Paris

1998

-J.L. Humphrey, G.E. Keller, ‘Procédés de séparation’, Dunod, Paris 2001

Assessment: Lectures: 8 sessions of course, 1h20 duration and 2 sessions of class work, 2h, duration.


Remarks:

Student will be able to do typical basic calculations involving mass transfer. This includes calculations of

packed bed absorption columns and mass transfer coefficients

CI 1Y

MODULE : COMPUTER SCIENCE AND APPLIED STATISTICS

SUBJECT:

APPLIED STATISTICS

Coordinator:

serguei.goriatchev@ensc-

lille.fr

+33 (0)3 20 33 64 96

Office 221

Building P5

Compulsory

Code: CH1510

Semester: 5

Lecture: 15 Hours

Directed studies:

Language: French

Coefficient: 2

ECTS: 2

Instructor(s):


Learning outcomes:

Every measure involves inevitable errors, and above all in an industrial context, it matters to be able to

evaluate their importance. In that course, practical indications are given on methods of errors

estimation.

Prerequisite:

Mathematics (Probabilities)

Contents:

Probabilities and statistics.

Sampling.

Estimation of statistical parameters.

Statistical tests.

Comparison of frequencies, means, variances and distribution functions.

Correlation.

Linear regression.



F. Dress, Probabilités et Statistique (Rapppels de cours ), Dunod, Paris (1997).

F. Couty, J. Debord et D. Fredon, Probabilités et Statistiques (Résumés de cours et 157 exercices),

Dunod, Paris (1999).

R. Veysseyre, Statistique et probabilités pour l’ingénieur, Dunod, Paris (2004).

W. W. Hines, Probabilités et Statistique pour ingénieurs, Chenelère Education, Montréal (2005).

Remarks:

CI 1Y



MODULE : COMPUTER SCIENCE AND APPLIED STATISTICS

SUBJECT :

DATA SYSTEMS AND TREATMENT

Coordinator :

[email protected]

+33 (0)3 20 33 62 25

Office 232

Building C6

Compulsory

Code: CH1511

Semester: 5

Lecture:


Language: French

Coefficient:

ECTS :

Instructor(s) :

Ludovic Thuinet

Serguei Goriatchev

Learning outcomes:

To know how to use some chosen software and numerical tools in order to deal with data.

● Optimal use of Excel to program formulas and to calculate them, to plot graphs from calculated data

in Excel or from other source files. Organization of the calculation sheet to solve a complex scientific

problem

● To know how to use a programming software, i.e. to master the syntactic rules, to know the different

types of variables. To be able to write short numerical algorithms with loops and conditional operators

Prerequisite:

None Contents:

General presentation of Excel: cell format, formulas insertion, absolute/relative references…

How to plot graphs with Excel and how to analyze the data (bars of uncertainty, linear regression…)

Use of specific tools in Excel, like Solver

General presentation of the programming language Scilab: syntactic rules, main types of variables

How to use or create input/output data with Scilab

Use of loops "for" and "while" and conditional operators (if-then-else-end)


Media: 2 short documents summarizing the main features of Excel and Scilab. Students are also given

User manuals for Word and Powerpoint and a document entitled "how to write a report: guide to

authors", but these are not the topic of any exercises in this module.

Bibliographical references: A complete documentation on Scilab is at the disposal of the students on

the ENSCL Intranet. Various examples of scientific problems solved with Scilab can be found on the

ENPC website: http://cermics.enpc.fr/scilab_new/site/

Assessment: Students are assessed on the knowledge taught in this module through the module

physical chemistry-practical studies (TP1502), in which they have to use these numerical tools.

Remarks:

CI 1Y


MODULE :ANALYTICAL CHEMISTRY (Practical studies)

SUBJECT:

ANALYTICAL CHEMISTRY

Chim

Coordinator:


lille.fr

+33 (0)3 20 43 49 73

Office 224

Building C7a

Compulsory

Code: TP1501

Semester: 5

Practical studies: 36 Hours

Project:

Language: French

Coefficient: 7

ECTS: 4.5

Instructor(s):

Teachers:

Anne-Sophie MAMEDE

Caroline PIROVANO

Fabienne SAMYN


Technical staff:

Catherine CANDELIER

Maxence VANDEWALLE

Learning outcomes:

The objectives of this cycle of Practical class of Analytical Chemistry are:

● The acquisition of the basic notions in analytical chemistry in aqueous solution

● The acquisition of Good Laboratory Practice (GPL) through the development of care, initiative, rigour.

respect for the conditions of hygiene and safety in laboratory, writing a laboratory notebook…

● The control of all the operations to be performed during any manipulations: the preparation

(conceptions of experimental protocols), the realization and the interpretation of the results.

Prerequisite:

● Classical methods learnt in preparatory classes

● Notions of safety in laboratory (FE1501-3)

Contents:

The practical class of Analytical Chemistry begins with an initiation to the classical laboratory

techniques (Tutorial classes and preparatory practical classes). Once this preparatory cycle

accomplished in small groups, the students work then individually at fixed post, every student having

his own material, he prepares his solutions, titrates and calibrates them.

The studied titrations are:

● acid-base titration

● gravimetric titration

● complexometric titration

● redox titration


Media: manual of practical class of Analytical Chemistry


● Vogel's Quantitative Chemical Analysis, 6th Ed., 2000, Pearson Education Limited

● Fundamentals of analytical chemistry, D.A. Skoog, D.M. West, F.J. Holler, eighth edition, Thomson-

Brooks/Cole, 2004

Assessment: students are evaluated on their results and the quality of manipulation, the reports. Oral

interrogations to test the preparation as well as short written examinations are possible during the

practical session.

Remarks:

CI 1Y



MODULE : PHYSICAL CHEMISTRY (Practical studies)

SUBJECT:

PHYSICAL CHEMISTRY

Chim

Coordinator:


lille.fr

+33 (0)3 20 43 49 73

Office 224

Building C7a

Compulsory

Code: TP1502

Semester: 5

Practical studies: 40.5 Hours

Project:

Language: French

Coefficient: 7

ECTS: 4.5

Instructor(s):

Teachers:

Charlotte BECQUART

Serguei GORIATCHEV

Anne-Sophie MAMEDE

Caroline PIROVANO

Fabienne SAMYN

Ludovic THUINET

Technical staff:

Catherine CANDELIER

Learning outcomes:

This cycle of practical works led the students to discover new experimental techniques and to check

concretely the fundamental laws, the theoretical principles and the specific methods of physical

chemistry.

The use of computing tools allows the students to acquire the control of these tools (through the

exploitation of their results, programming, modelling and the writing of reports).

Prerequisite:

● Basic knowledge acquired in preparatory years and in practical classes of Analytical Chemistry

(TP1501)

● Knowledge learnt in the courses of general chemistry: electrochemistry (CH1501), thermodynamic

(CH1508), spectroscopy (CH1502), chemical kinetics (CH1609)

● Knowledge acquired in the data systems and treatments module (CH1511)

● Notions of safety in laboratory (FE1501-3)

Contents:

In this cycle of manipulations are thus approached:

● Electrochemical methods ( potentiometry, conductimetry, polarography...)

● Chemical kinetics

● Spectroscopic methods (spectroscopy U.V. and atomic spectroscopy)

● Thermal analyses

● Modelling


Media: a manual of practical class of Physical Chemistry given to the students and additional

documentations are available in the laboratory during the sessions.


● Analyse Chimique. Méthodes et techniques instrumentales modernes; F. Rouessac, A. Rouessac,

Dunod

● Fundamentals of analytical chemistry, D.A. Skoog, D.M. West, F.J. Holler, eighth edition, Thomson-

Brooks/Cole, 2004

Assessment: Reports, oral preparation test, written theorical examination possible at the end of the

practical classes

Remarks:

CI 1Y



MODULE : CHEMICAL CHEMISTRY (Practical studies)

SUBJECT:

CHEMICAL ENGINEERING

Chim

Coordinator:

[email protected]

+33 (0)3.20.33.54.36


Building C

Compulsory

Code : TP1503

Semester : 5


Project:

Language : French

Coefficient : 3

ECTS : 2

Instructor(s):

R. BECHARA, M. CZERNICKI, F.

DHAINAUT et N. FATAH

Learning outcomes:

Practical works of Chemical engineering program: theory, practice and calculations. The experimental training try to carry out a harmonization between the basic disciplines of the chemistry and those of Chemical engineering. The unit operations of Chemical engineering (praticals): -Hydrodynamics in a packed column, -Heat exchanger -Fluid mechanics

Prerequisite:

Elementary knowledge gained in preparatory classes (CPGE, CPI, DUT, BTS, ATS) Notions of fluid flow, mass transfer and heat transfer.

Contents:

Practical work of Chemical engineering gathers theory, practical program and numerical modelling. They try to carry out an harmonization accentuated between the basic disciplines of chemistry and those of Chemical engineering and target three objectives: - to supplement the course of the teaching of Chemical engineering. - to confront the students with semi-industrial scale pilots during a sufficient working time in order to obtain results of good quality and into practice to put the theoretical teaching exempted at the time of the courses and directed work -Numerical Modeling : The purpose of this study is to introduce the modelisation possibilities offered by Comsol. In the first part, the design of an heat exchanger allows to review the fundamental of technical drawing in 3D. Then, flows across a cylinder are modelled, in laminar state according to the Navier-Stokes equations, but also in turbulent state with the k- model. In the last part, a multiphysics phenomena, between 2 equation systems is accomplished by considering the convection and conduction phenomena in order to take into account the heat transfer. Manipulations are the following: Hydrodynamics in a packed column, Heat exchanger Fluid mechanics


Media: Teachers documents

Bibliographical references: Courses of chemical engineering P. Wuithier : Raffinage et Génie Chimique, ed. Technip Perry : Chemical Engineers Handbook, Mc Graw Hill Mc Cabe & Smith: Unit Operations of Chemical Engineering, Mc Graw Hill

Assessment: Written report

Remarks:

CI 1Y


MODULE : INORGANIC CHEMISTRY (Practical studies)

SUBJECT:

INORGANIC CHEMISTRY

Chim

Coordinator:

Catherine Renard

[email protected]

+33 (0)320434434

Building C7A, office 226

Compulsory

Code: TP1603

Semester: 6


Project:

Language: French

Coefficient: 7

ECTS : 4.5

Instructor(s):

Teachers :

Marie Colmont

Murielle Rivenet

Catherine Renard

Nathalie Tancret

Christophe Volkringer

Technical staff :

Catherine Candelier

Learning outcomes:

- Carry through a synthesis from a detailed protocol and master the methods of analysis,

- Know how to write the chemical equations and to exploit the results,

- Know the safety rules and how to manage waste.

Prerequisite:

Contents: Know the glassware and its use

Have acquired the basics of analytical chemistry and physical chemistry

Contents:

The purpose of this lab is to introduce engineering students to the multiplicity of preparation

techniques of inorganic chemistry - by ceramic method, in solution, by co-precipitation - and synthesis

of commodity chemicals (sodium carbonate by the Solvay process, soda and chlorine by electrolysis)....

The products obtained after each synthesis must be characterized, this brings the engineering students

to apply their knowledge in analytical and physical chemistry. It is also an opportunity to introduce

engineering students to physicochemical techniques of analysis such as X-ray diffraction, thermal

analyzes


Media:


Assessment:

Reporting of practical work,

Practical assessment : preparation, understanding of the practical work, general behavior,

Final written examination (1h)

Remarks:

CI 1Y


MODULE : ORGANIC CHEMISTRY (Practical studies)

SUBJECT:

ORGANIC CHEMISTRY

Chim

Coordinator:

Vangelis.agouridas@ensc-

lille.fr

03.20.43.44.40

Building C3, office 210

Compulsory

Code: TP1604

Semester: 6


Project:

Language: French

Coefficient: 7

ECTS: 4.5

Instructor(s):

Vangelis Agouridas

Learning outcomes:

Organic Synthesis, Purification and characterization of organic compounds by FTIR, NMR

Prerequisite:

Basic Organic Chemistry (Sem 4)

Contents:

9*4h session:

1. Distillation (evaluation of purity by Gas Chromatography)

2. Liquid-liquid extraction

3. Purification of a solid by recristallization

4. Friedel-Craft acylation of toluene (GC, FTIR)

5. Functional group protection (FTIR)

6. Grignard addition (FTIR, NMR)

7. Wittig Olefination under microwave + column chromatography (FTIR, NMR)

8. Green synthesis of heterocycles + introduction to green metrics (FTIR, NMR)

9. Camphor: oxidation et stereoselective reduction (GC, FTIR, NMR)


Media:

Handout


Purification of laboratory chemicals fifth edition, 2003, W. L. F. Armarego and C. L. L. Chai, Butterworth

Heinemann (imprint of elsevier science), ISBN 0-7506-7571-3

Assessment:

Continual assessment + 1*2h written exam

Remarks:

CI 1Y



MODULE : SUSTAINABLE DEVELOPMENT

SUBJECT:

FUNDAMENTALS OF SUSTAINABLE DEVELOPMENT

Coordinator:

Jean Claude Van Duysen

Compulsory

Code: FE1501-1

Semester: 5

Lecture: 8 Hours

Directed studies:

Language: French

Coefficient: 5

ECTS: 1

Instructor(s):

Jean Claude Van Duysen

Learning outcomes:

The course has for objectives 1) to explain the concept of sustainable development, 2) to show how

this concept became influential and 3) to describe the way it is used in current society (companies,

cities, etc.).

The student will acquire all the cultural bases needed to apply sustainable development principles in his

professional career, and more globally in the society.

Prerequisite:

There is no prerequisite to follow the course.

Contents:

The course will explain:

the sustainable development principles,

the origins of the environmental consciousness and notion of sustainability,

the current issues of the planet (environment, energy, social, etc.),

the national and international regulatory context supporting a sustainable development,

the implementation of sustainable development principles in current society,

three examples of application of these principles in industry: reduction of CO2 emissions, green

growth and energy efficiency.

Each lecture will partially rely on a discussion between the Professor and the students, in particular on

themes regarding current society.


Support:

Regular reading of a daily newspaper or a societal magazine.

Bibliographical references :

J. C. van Duysen et Stéphanie Jumel, le Développement Durable, éditions l’Hamarttan, 2008.

Site Internet de Jean-Marc Jancovici : http://www.manicore.com/inc_menu/plan_fr.html

Stratégie Européenne en faveur du développement durable :

http://europa.eu/legislation_summaries/environment/sustainable_development/l28117_fr.ht

m

Site Internet du Ministère du Développement Durable :

http://www.developpement-durable.gouv.fr/

André Jean Guérin et Thierry Libaert, Le développement durable, Dunod. Topos. 2008.

Assessment :

no exam.

the knowledge acquired by the students during the course is assessed through the interest they

manifest during the lectures, the level of their involvement in a dialogue with the professor,

and their participation in the « Ingenieur 21 » cell which is in charge of managing sustainable

development activities within the School.

Remarks:

CI 1Y

http://www.manicore.com/inc_menu/plan_fr.html

http://europa.eu/legislation_summaries/environment/sustainable_development/l28117_fr.htm

http://europa.eu/legislation_summaries/environment/sustainable_development/l28117_fr.htm

http://www.developpement-durable.gouv.fr/


SUBJECT:

INDICATORS OF SUSTAINABILITY

Coordinator:

Jean Claude van Duysen

Compulsory

Code: FE1501-2

Semester: 5

Lecture: 4 Hours

Directed studies:

Language: French

Coefficient: 5

ECTS : 1

Instructor(s):


Learning outcomes:

The course has for objectives to train the student 1) to use the main indicators of sustainability and 2)

to contribute to the writing of a “sustainable development report”.

At the end of the training, the student:

will have understand the principles on which rely the indicators taken into account,

will have identify the strengths and weaknesses of these indicators,

will be able to calculate them,

will be able to interpret the results and define an action plan to improve them,

will know the main rubrics required in a “sustainable development report”.

Prerequisite:

The only prerequisite is to have assimilated the notions presented in the course on “the foundation of

sustainable development”.

Contents:

The course focuses on three indicators of sustainability:

ecological footprint,

carbon accounting,

external costs.

For each of these indicators, the course will detail:

the principles on which relies the indicator,

the calculation method,

the strengths and weaknesses.

The course includes also a description of the main rubrics required in “sustainable development report”,

as well as an analysis of some “sustainable development reports” from large French companies.



WWF Living Planet Report : http://awsassets.panda.org/downloads/lpr2010.pdf

Calcul de l’empreinte écologique du Grand Lyon :

http://www.grandlyon.com/fileadmin/user_upload/Pdf/developpement_durable/referentiel_envir

onnement/2004118_gl_referentiel_environnement_empreinteecolo.pdf

Qunatification des coûts externes liées à la pollution atmosphériques :

http://web.me.com/arirabl/Site/Publications_files/Re%CC%81sultatsExternE-PollAtmos.pdf

Bilan de Carbone – ADEME :


Assessment:

no exam.

the knowledge acquired by the students during the course is assessed through the interest they

manifest during the lectures, the level of their involvement in a dialogue with the professor,

and their participation in the « Ingenieur 21 » cell which is in charge of managing sustainable

development activities within the School.

Remarks:

CI 1Y

http://awsassets.panda.org/downloads/lpr2010.pdf

http://www.grandlyon.com/fileadmin/user_upload/Pdf/developpement_durable/referentiel_environnement/2004118_gl_referentiel_environnement_empreinteecolo.pdf

http://www.grandlyon.com/fileadmin/user_upload/Pdf/developpement_durable/referentiel_environnement/2004118_gl_referentiel_environnement_empreinteecolo.pdf




SUBJECT:

SECURITY AND RISKS

Coordinator :

[email protected]

+33 (0)3.20.43.48.8

Building C7 - office 8

Compulsory

Code: FE1501-3

Semester: 5

Lecture: 8 Hours

Directed studies:

Language: French

Coefficient: 5

ECTS: 1

Instructor(s) :

Serge BOURBIGOT

Learning outcomes:

To learn the basics of lab safety and of methods of risk analysis

Prerequisite:

Basics in chemistry Contents :

Lab safety: the basic rules for the chemist, labelling, what to do if…?, protect yourself, signboard, the experiments, risk estimation Risk analysis: general approach for risk analysis, preliminary analysis of risk, fault tree analysis, Hazop method, Mosar method


Media: Powerpoint

Bibliographical references: La sécurité en laboratoire de chimie et de biochimie par

André Picot - La Gestion Des Risques, Manuel De Mise en Œuvre par Pierre Périlhon

Assessment:

Remarks:

CI 1Y


http://www.amazon.fr/s/ref=ntt_athr_dp_sr_1/278-7286527-2282862?_encoding=UTF8&search-alias=books-fr&field-author=Andr%C3%A9%20Picot

http://www.priceminister.com/s/pierre+p%e9rilhon


SUBJECT:

LIFE CYCLE ANALYSIS

Coordinator :

[email protected]

+33 (0)3.20.43.48.8

Building C7 - office 8

Compulsory

Code: FE1501-4

Semester: 5

Lecture: 8 Hours

Directed studies:

Language: French

Coefficient: 5

ECTS: 1

Instructor(s) :

Serge Bourbigot

Learning outcomes:

To learn the basics of life cycle analysis

Prerequisite:

No specific knowledge is required Contents :

Climat and energy LCA definition How to make LCA? LCA in context LCA and reduction of environmental impacts Examples SimaPro software


Media:


Assessment: ACV project with report and defense

Remarks:

CI 1Y


MODULE : ENGLISH

SUBJECT:

ENGLISH

Chim

Coordinator:

Anne GUEGAND

Abdelamar BENAÏSSA

Office 965

Tel:+33 (3)20336060

Compulsory

Code: LV1501

Semester(s): 5+6

Lecture:


Language: English

Coefficient: 9

ECTS: 5

Instructor(s):

Anne GUEGAND

Abdelamar BENAÏSSA

Learning outcomes:

Language tuition at the ENSCL has a double objective:

-To help all students develop the communication skills they will need in professional situations through

interactive practice activities.

- To encourage prospective graduates to develop an international opening onto foreign companies and

universities to facilitate cross-cultural adaptability and adaptation.

Contents:

-TOEFL

-Ist year topics (for example: Travelling, Work, Education…)


Media: Various (newspaper articles, publications, video documents, case studies…)

Assessment: Continuous language assessment is carried out through two written tests, an interview

and a presentation in English.

Remarks:

No English course for beginners

CI 1Y

Tel:+33

MODULE : GERMAN

SUBJECT:

GERMAN

Chim

Coordinator:

Beate WINKLER

[email protected]

Tel. +33 (0)320336061

Office 951

Compulsory

Code: LV1502

Semester(s): 5+6

Lecture:


Language: German

Coefficient: 9

ECTS: 5

Instructor(s):

Beate WINKLER

Monika BERTOUT

Nathalie CHAPTAL

Caroline SIPPL

Learning outcomes:

Prerequisites:

All levels.

Pupils who have never studied German can enroll in a course for "beginners".

Objectives and skills referred:

Progress in the four language skills, but especially in the two that cause the greatest problem (listening

comprehension and oral expression) to validate at least the level B1 or B2 (A2 for the beginners) of the

CEFR.

Ability to integrate in a professional environment (with regard to courses and internships at University

or in foreign companies) and to communicate in situations of everyday life; acquisition of basic

knowledge of scientific and technical German in the field of chemistry

Contents:

Non-exhaustive list - all aspects are not always treated and sometimes deferred or deepened in the

second year:

school career: learn how to describe personal curricula and talk about own motivation, differences

between the educational systems; the student life.

Work: basic business vocabulary, internships; writing a CV, letter of motivation, e-mails. Reflection on

the way how to submit and first simulations of telephone interviews with the intention to the search

for internships; active search for internships…

Housing: housing search (internship), administrative approaches, living in collocation, "casting" with

future roommates …

Means of communication: specific vocabulary of the telephone, the computer; discovery of the main

websites of German information…

Food, food security, health: vocabulary of everyday life, an aspect of the chemistry in the area of food.

Travel and work in German speaking countries: (focusing on the internship), administrative procedures,

geography, tourism, intercultural aspects …

working in chemical laboratories: basic vocabulary, describe basic experiments


Media:

Various authentic media (print media, audio, video, movies, business documents, the internet).

The method "Studio D" for beginners.


Books, movies in original version and journals are available on loan in a small German library.

Assessment:

Continuous language assessment is carried out through at least two written tests (two hours each) and

an oral test divided into two parts (a presentation and an interactive part)

Remarks:

Students are strongly encouraged to confirm their level by a certification in cooperation with the

Goethe-Institute:

"Zertifikat Start 2" (level A2 of the CEFR) for beginners.

"Zertifikat Deutsch" (Level B1 /B2 /C1 of the CEFR) for the more advanced students.

CI 1Y


MODULE : SPANISH

SUBJECT:

SPANISH

Chim

Coordinator:

Compulsory

Code: LV1506

Semester(s): 5+6

Lecture:


Language: Spanish

Coefficient: 9

ECTS: 5

Instructor(s):

Hakima Larabi

Learning outcomes:

Strengthening B1 level of the Frame Common reference European for Languages, preparation for B2

level. (At the end of the 1st year, the student must be able to talk about basic scientific subjects).

Helping all students develop the communication skills they will need in professional situations (through

interactive practice activities).

Contents:

Linguistic, scientific and cultural aspects: - Oral comprehension: multimedia language laboratory or video sequence. - Oral expression: simulations and role play activities. - Written understanding: scientific or cultural texts. - Written grammatical Competences - Written expression (writing a CV, a letter, an email…) Additional information:

Media: Various (newspaper articles, audio and video documents…)

Bibliographical references: Actividades para el Marco Común B2 (ELE).


and a presentation in spanish

Remarks:

No Spanish course for beginners.

CI 1Y

MODULE : FRENCH AS A FOREIN LANGUAGE

SUBJECT :

FRENCH AS A FOREIN LANGUAGE

Chim

Coordinator :

Catherine FORTUNATO

Polytec 'Lille

Compulsory

Code : LV1505

Semester(s) : 5+6

Lecture:


Language :

Coefficient : 9

ECTS : 5

Instructor(s) :

Catherine FORTUNATO

Polytec 'Lille

Learning outcomes :

Good knowledge of language in particular at a professional level: understanding the main part of a

text, take current notes, express one's opinion in a brief but clear way on a general or professional

subject.

Contents :

3 hours/week of Fench as a Foreign language


Media :


Assessment:

Remarks:

CI 1Y

MODULE : JAPANESE (OPTIONAL)

SUBJECT:

JAPANESE (OPTIONAL)

Chim

Coordinator:

Jean-Luc RIGAL

[email protected]

Office 951

Compulsory

Code: LV1504

Semester(s): 5+6

Lecture:


Language: Japanese

Coefficient:

ECTS:

Instructor(s):

Geoffrey DUCATILLON 1 2

Hitomi KIMURA 3

Aki KIUCHI 1

Nozomu MIZUKAMI 2

Shoko MORITA 4 5

Jean-Luc RIGAL 1 2 3

Maki TAMAOKI 1

Sachie WATANABE 2

Learning outcomes:

The main object of this course is to give basic communication tools to the students who intend to do their first, second or/and third year industrial placements in Japan, but also to complete the curriculum of future managers of a branch of industry which has many relations with Japan.

Contents:

One third of the course is devoted to civilization and two thirds to language. Because of the very particular writing system of Japanese, in which two syllabaries and at least 2000 ideograms are combined, reading and writing are given the same importance as oral work. In addition to the learning and systematic use of the two syllabaries, strong emphasis is put on the logic of ideograms, the objective being, through the study of a few hundreds of them, to facilitate the subsequent assimilation of those - much more numerous - which are necessary to everyday life.

Level 1: In particular, Nihongo shoho 1-6, Hiragana nyûmon, Kanban no kanji, Survival Japanese,

JDSR 1-5 .


Media:

Minna no nihongo, Nihongo shoho (1, 2, 3), Nihongo chûkyû, Kana nyûmon (hiragana 1) (katakana 2),

Nelson Kan’ei jiten (2, 3), Kanji for everybody (2, 3)


Nihon etoki jiten 1-16 (JTB), Nihongo notes 1-5 (The Japan Times), Situational Japanese 1-5 (The Japan

Times)

Assessment:

Oral and written exams, continuous assessment

Remarks:

The course is divided into 5 levels, and not according to the three years of the curriculum. As a matter of fact, if Level I is mainly attended by first year students, Level II by second year students and Level III by third year students, some students start the study of Japanese in their second/third year, whereas other students - especially those who come from the "CPI" - may have been studying Japanese for two years or more when they start their engineering studies.

Prerequisites:

None, other than the desire to learn Japanese (WRITTEN INCLUDED)

CI 1Y

Année 2012-2013

4th academic year (semesters 7 and 8)


SUBJECT:

SYNTHESIS STRATEGY IN ORGANIC CHEMISTRY

Coordinator:


[email protected]

+33 (3) 20 43 48 58

Office 101 Building C1

Compulsory

Code: CI2703

Semester: 7

Lecture: 15 Hours


Language: French

Coefficient: 3

ECTS: 1.5

Instructor(s):

Philippe Cotelle

Learning outcomes:

Being able of proposing a multi-step synthesis of a molecule of moderate complexity

Prerequisite:

Organic chemistry of monofunctional molecules, semester S5 module CH1503 and semester S6 module

CH1603

Contents :

Introduction: Analysis and synthesis approach Linear and convergent multi-step synthesis

Protection/deprotection: the protective groups

Selectivity

Chemio, regio, stereoselectivity

Enantiospecificity and asymmetric induction

Enantiomer resolution

Use of natural starting material

Use of chiral auxiliary

Enantioselective catalysis

Retrosynthesis: the disconnection approach

The course will be based itself on simple examples of total synthesis


Media:

Bibliographical references: F. A. Carey, R. J. Sundberg, Advanced organic chemistry, volume 2, 3rd Ed,

De Boeck, 1997, ISBN-10 2-8041-5233-2.

S. Warren, P Wyatt, Organic chemistry : the disconnection approach, 2nd Ed, Wiley, 2008, ISBN-978-0-

470-71237-5

Assessment: Written exam (2 hours) at the end of the semester (january)

Remarks:

CI 2Y



SUBJECT:

ORGANOMETALLIC CHEMISTRY

Coordinator :

Pr Philippe Cotelle

[email protected]

+33 (3) 20 43 48 58


Compulsory

Code: CI2705

Semester: 7

Lecture: 8 Hours

Directed studies:

Language: French

Coefficient :

ECTS: 1

Instructor(s) :

Pr PELINSKI Lydie

[email protected]

+33 (0) 3 20 43 65 01

ENSCL, Bureau 106

Learning outcomes:

The objective of this course is to get the student the importance of organometallic chemistry as a tool

in organic synthesis and bring her knowledge in this field.

Prerequisite:

Bases acquired in organic chemistry in 1st year.

Contents :

Introduction to organometallic chemistry, general properties of organometallic complexes and their

preparation.

Particular bound metal-ligand, backdonation

Organometallics: electronic effects, protecting and stabilising groups

Reaction of cyclisation: Pauson-Khand reaction, metallacyles with titanium, trimerisation of alkynes


Media :

Chimie organométallique, Didier Astruc, Ed EDP Sciences.

Chimie organique : Hétéroéléments, stratégies de synthèse et chimie organométallique, Nicolas

Rabasso, Ed. De Boeck.


Assessment: no evaluation

Remarks:

CI 2Y




SUBJECT:

APPLIED SPECTROSCOPY

Coordinator:

Pr Philippe Cotelle

[email protected]

+33 (3) 20 43 48 58


Compulsory

Code: CI2702

Semester: 7

Lecture: 17 Hours


Language: French

Coefficient: 3

ECTS: 1.5

Instructor(s):

Eric BUISINE

(NMR course)

Caroline TOKARSKI

(mass spectrometry and

chromatography: course and

directed studies)

caroline.tokarski@univ-

lille1.fr

Phone: +33 (0)3 20 33 64 33

MSAP - C4

Learning outcomes:

Mass spectrometry and chromatography (12-hour course and 6-hour directed studies): develop strong

theoretical knowledge; interpret mass spectra allowing chemical molecule identification (low molecular

weight organic molecules, macromolecules, polymers, etc.); identify the most suitable instruments for

specific applications (target molecule and specific question) and describe the extent and limitations of

the data obtained.

NMR (5-hour course): initiate to 2D-NMR spectroscopy; have a good understanding of homo-nuclear

1H-1H and hetero-nuclear 1H-13C 2D correlation experiments; after NMR practicals (TP2701, semester

7), being able to determine the structures of small organic molecules from their related sets of 1D- and

2D-NMR spectra; completing the course of first year (CH1602, semester 6) with respect to 13C NMR

spectroscopy.

Prerequisite:

Contents: course unit CH1602 (semester 6) Contents:

Mass spectrometry: main ionization techniques (electron impact, chemical ionization, desorption-

ionization, desolvatation-ionization) and analyzer geometries (quadripolar filters, ion trap, orbitrap,

time of flight, magnetic sectors, Fourier transform ion cyclotron resonance) including most recent

hybrid devices.

Chromatography: theoretical and instrumental basis for technique application including recent

developments ; main fundamental values characteristic of a separation ; liquid, gas and supercritical

chromatographies ; optimization of analytical conditions (resolution, analysis length and charge loss) ;

different recent chromatographic systems (nanoflow systems and coupling to mass spectrometry).

NMR: 1H decoupling technique; NOE effects ; 1D-13C APT experiment; 1D-13C DEPT135 experiment;

principle of the 2D-NMR experiment ; the signal in 2D-NMR and its Fourier Transform; principal 2D-

homonuclear (COSY, TOCSY, NOESY) and heteronuclear (HMQC/HSQC, HMBC) correlation experiments


Media: copy of PowerPoint NMR presentations are accessible from the intranet

Bibliographical references: Mass Spectrometry: Principles and Applications. Edmond de Hoffmann and

Vincent Stroobant. Publisher: Wiley-Interscience

Assessment: written 2 hour exam without documents

Remarks:

CI 2Y


http://www.amazon.com/Edmond-de-Hoffmann/e/B001IXO6EE/ref=ntt_athr_dp_pel_1

http://www.amazon.com/s/ref=ntt_athr_dp_sr_2?_encoding=UTF8&sort=relevancerank&search-alias=books&field-author=Vincent%20Stroobant

http://www.amazon.com/s/ref=ntt_athr_dp_sr_2?_encoding=UTF8&sort=relevancerank&search-alias=books&field-author=Vincent%20Stroobant


SUBJECT:

POLYMERS CHEMISTRY

Coordinator:

Pr Philippe Cotelle

[email protected]

+33 (3) 20 43 48 58


Compulsory

Code: CI2704

Semester: 7

Lecture: 15 Hours


Language: French

Coefficient: 3

ECTS: 1.5

Instructor(s):

Patrice WOISEL

Frédéric CAZAUX

Learning outcomes:

The course aims at giving an extensive knwoledge of the molecular design fo synthetic

macromolecules. Aftre the course, the student should be able to :

- draw up a synthetic pathway for the synthetis of different functionalized polymers

- predict the structure, the architecture and the composition of synthetic polymers

Prerequisite:

CH1604

Contents:

-Polyadditions: free radical, anionic and cationic polymerizations-mechanisms, kinetics,

thermodynamics, stereoregularity, average molecular weights and distribution. Living polymerization.

-Free radical copolymerization: kinetics, reactivity ratios, Q-e scheme.

-Step-growth polymerization: linear polycondensation, gels.


Media:

Duplicated lecture note + documents given during the courses









Remarks:

CI 2Y



SUBJECT:

PHYSICO CHEMISTRY OF POLYMERS

Coordinator:

Pr Philippe Cotelle

[email protected]

+33 (3) 20 43 48 58


Compulsory

Code : CI2804

Semester : 8

Lecture: 14 Hours

Directed studies:

Language : French

Coefficient : 2

ECTS : 1

Instructor(s):

Patrice WOISEL

[email protected]

+33 (0)320434954

Build. C6 - office 123

Learning outcomes:

After the course, the student should obtain a broad theoretical knowledge about structure and

properties of polymers and about the methods and techniques that are used to characterize polymers

Prerequisite:

CI2704

Contents:

- Introduction to the physico-chemistry of polymers

- Thermodynamics of polymer solutions and blends : Flory-Huggins theory, predicting polymer solubility

- Determination of molecular weights: osmometry, mass spectrometry, NMR

- Light scattering: principle, experimental method, Zimm plot, MW determination and radius of giration


Media:

Duplicated lecture note + documents given during the courses


Polymers : Chemistry & Physics of Modern Materials, 2nd edition J. M. G. COWIE, Blackie Academic & Professional, Chapman & Hall, 1997, ISBN 075140134X

Initiation à la chimie et à la physico-chimie macromoléculaires Vol.12 : Chimie de l’élaboration du matériau polymère, Collectif, Groupe Français des Polymères, 2001

Introduction to Polymer Science, F. W. BILLMEYER, Wiley, 1984, ISBN 0471031968


Remarks:

CI 2Y


mailto:[email protected]%20+33%20(0)320434954Build.



MODULE : MATERIALS SCIENCE

SUBJECT :

MAIN CLASSES OF MATERIALS

Coordinator :

Jean-Bernard VOGT

Jean-bernard.vogt@ensc-

lille.fr

+33 (0)3 20 43 40 35

Building C6 -office 223

Compulsory

Code : CI2706

Semester : 7

Lecture: 20 Hours

Directed studies:

Language : French

Coefficient :

ECTS : 1

Instructor(s) :

Nathalie TANCRET

Jean-Bernard VOGT

Patrice WOISEL

Industrial lecturer

Learning outcomes :

Knowledge of main classes of materials – metals, polymers, ceramics, composites- , of their

microstructure, of their physico –chemical characteristics and range of applications

Prerequisite:

Physics and chemistry basis, thermodynamics, bachelor level

Contents :

I- INTRODUCTION

Main properties of materials: thermal, electrical, mechanical, corrosion resistance

Functional materials/ structural materials

II – POLYMERIC MATERIALS

General introduction of polymeric materials, basic polymers, advanced polymers

III – METALLIC ALLOYS

Solidification, crystallography, cast irons and steels, copper and copper alloys, aluminium and Al alloys:

IV – GLASSES AND CERAMICS

From the divided solid to the melted solid, cement, zeolite, ceramic, glass, methods of synthesis,

relation between techniques and energy savings


Media : copies of slides or copies of slide figures


Materials Science and Engineering: an introduction, W.D. Callister, 2000, John Wiley & Sons

Assessment: no exam

Remarks:

CI 2Y


SUBJECT :

MECANICAL ANALYSIS OF MATERIALS

Coordinator :

Jean-Bernard VOGT


lille.fr

+33 (0)3 20 43 40 35


Compulsory

Code : CI2707

Semester : 7

Lecture: 11 Hours

Directed studies:

Language :

French/English

Coefficient :

ECTS : 1

Instructor(s) :

Jean-Bernard VOGT

Learning outcomes :

- The course aims at extending the knowledge towards mechanical aspect of materials. Modern

analytical techniques and testing methods used when assessing materials behaviour such as plasticity

and failure are presented.

After completion of this course, the student should be able to:

I) describe the most important methods and techniques used in materials testing and characterization

II) choose the most appropriate one according to the material and the integrity to emphasize

III) describe the basic aspects of failure feature related to mechanical loading

Prerequisite:

General knowledge in physics, bachelor level

Contents :

I – INTRODUCTION

Stress, strain, types of solicitation

II- MECHANICAL TEST for PLASTICITY CHARACTERIZATION

Tensile test, compression, hardness, creep

III - MECHANICAL TEST for FRACTURE CHARACTERIZATION

Notch effect, impact test, toughness, fatigue


Media: photocopies of slide figures


Des matériaux, J.-P. Baïlon et J.-M. Dorlot Presses Internationales Polytechnique -

Science et génie des matériaux, W.D. Callister Jr, Dunod

Assessment: no exam

Remarks:

Slides are in English

CI 2Y




SUBJECT :

ANALYSIS OF SOLIDS

Coordinator :

Jean-Bernard VOGT


lille.fr

+33 (0)3 20 43 40 35


C7A -office 208

Compulsory

Code: CI2708

Semester: 7

Lecture: 15 Hours

Directed studies:

Language: French

Coefficient: 2

ECTS: 1

Instructor(s) :

Marie COLMONT



lille.fr

+33(0)3 20 43 65 83

Learning outcomes:

A general knowledge of the main techniques of characterization of solids. In order to be able to face a

given problem.

Prerequisite:

Basics in crystallography abd X-ray diffraction (Lectures CH-1507, CI 1A ) Contents: space groups, Bragg law, diffraction

Contents:

This lecture is an overview of the main techniques used for the characterization of solids: X-ray fluorescence, X-ray diffraction (quantitative analysis, size of crystallite, micro-strain, residual strain, texture), SEM, TEM, XPS, SIMS (XPS and SIMS will be detailed in S9 in the frame of the materials specialty). Large facilities (synchrotron radiation, neutron reactors) will be introduced with a focus on absorption techniques (EXAFS and XANES)… Additional information:




Techniques de l'Ingénieur,

Analyse structurale et chimique des matériaux, J.P. Eberhart, Dunod,

Analyses chimiques, Francis Rouessac et Annick Rouessac, Dunod,

Assessment:

Written exam, 2h

Remarks:

These lectures are completed by case studies, initiation into the treatment of X-ray patterns by the

Rietveld method, a demonstration in X-ray fluorescence X and the visit of the technical platforms in the

CIMAS module.

CI 2Y

MODULE : FORMULATION CHEMISTRY

SUBJECT:

FORMULATION PHYSICAL CHEMISTRY

Coordinator:

Jean-marie.aubry@univ-

lille1.fr

Tél. +33 (0)3 20 33 63 64

Compulsory

Code: CI2709

Semester: 7

Lecture: 15 Hours

Directed studies:

Language: French

Coefficient: 2

ECTS: 1

Instructor(s) :

Jean-Marie Aubry

Learning outcomes:

● Be aware of the nature, the diversity and the specificities of formulation industries

● Discover "performance chemicals" defined by their functional properties but neither by their

chemical structure nor their purity.

● Understand the logic of formulation design complying with predefined specifications.

● Acquire the fundamentals of physical chemistry of surfaces and interfaces.

Prerequisite:

● Basics of organic chemistry, macromolecular chemistry and physical chemistry acquired in first year

● Thermodynamics of ideal solutions

Contents:

INTRODUCTION TO FORMULATION CHEMISTRY: ● Description and specificities of formulation industries: detergent, cosmetics, paint, pharmaceutical… ● Performance chemicals and their functional properties: surfactants, pigments, fragrances, binders ... ● Specifications and usage properties of formulated products. ● Strategy to design formulated products illustrated on the example of a detergent PHYSICAL CHEMISTRY OF SURFACES AND INTERFACES: ● Surface and interfacial tensions: definition and measurement methods. ● Influence of interfacial curvature: capillary pressure and Young-Laplace equation. ● Solvents (risks, selection criteria, Hansen parameters), application du surface degreasing. ● Contact angle, wetting and dewetting of ideal and real surfaces, Zisman method. Additional information:

Media: Duplicated lecture notes with exercises


AUBRY, SCHORSCH, La Formulation : Présentation Générale, Techn. Ingén. (1999) J 2110, 1-20

NARDELLO-RATAJ, HO TAN TAÏ, Les lessives en poudre, Actualité Chim. (mars 2003), 3-10

Assessment: One written exam 1h

Remarks:

CI 2Y




SUBJECT :

EXPERIMENTAL DESIGNS

Coordinator :

Jean-Marie Aubry

Jean-Marie.Aubry@univ-

lille1.fr

C6 Building, room 21 or 11

Build. C6 room 21 ou 11

Tél. +33 (0)3 20 33 63 64

Compulsory

Code: CI2813

Semester: 8

Lecture: 16 Hours


Language: French

Coefficient: 2

ECTS: 1

Instructor(s) :

Christel Pierlot

[email protected]

Jean-Marie Aubry

Learning outcomes :

After the teaching, the student should be able to

-select the strategy (Screening , Interaction, Optimization, ...) to solve a problem.

-determine the experimental area (factors, levels, number of levels)

-interpret the mathematical model obtained (importance of the coefficients or isoréponses curves)

Prerequisite:

Statistics (mean, standard deviation, normal distribution, Student's coefficients) Matrix algebra (transposed matrix, multiplication) Discussion on the coefficients of mathematical models of degree 1 Contents :

Course, application works, use of experiments design software (Nemrod) Plan of the course :

Study of the influence of many independent factors

Screening matrix

Study of the factors with interactions

Factorial matrix at 2 levels

Factorial fractional matrix

Optimization by the Simplex method

Isoresponses curves

Composite matrix

Doehlert design


Media : Issue paper for course and application exercises

Bibliographical references: Pharmaceutical experimental design, Gareth A. Lewis, Didier Mathieu, Roger

Tan Luu Phan. Marcel Dekker Inc, 1999, New York, Basel

Assessment: Written examination, 2 hours, without documents

Remarks:

CI 2Y


http://www.google.fr/search?hl=fr&tbo=p&tbm=bks&q=inauthor:%22Gareth+A.+Lewis%22

http://www.google.fr/search?hl=fr&tbo=p&tbm=bks&q=inauthor:%22Didier+Mathieu%22

http://www.google.fr/search?hl=fr&tbo=p&tbm=bks&q=inauthor:%22Roger+Tan+Luu+Phan%22

http://www.google.fr/search?hl=fr&tbo=p&tbm=bks&q=inauthor:%22Roger+Tan+Luu+Phan%22


SUBJECT:

POLYMER FORMULATION

Coordinator:


lille1.fr

C6 Building, room 21 or 11

Build. C6 room 21 ou 11

Tél. +33 (0)3 20 33 63 64

Compulsory

Code: CI2710

Semester: 7

Lecture: 9 Hours

Directed studies:

Language: French

Coefficient:

ECTS: 1

Instructor(s):

[email protected]

/ +33 (0)3.20.43.48.88/

Office N°8

Learning outcomes:

To discover the formulation for polymeric materials and to understand why it is necessary

Prerequisite:

Physics, chemistry and polymer chemistry at the undergraduate level

Contents:

Polymer structure Processing of polymeric materials: thermoplastics, thermosets Fillers and additives: nanocomposite, flame retardants, stabilizers Composites


Media: Powerpoint

Bibliographical references: -

Assessment: -

Remarks:

CI 2Y





SUBJECT:

SEPARATION PROCESS

Coordinator:

[email protected]

+33 (0)320335436

ECLille Building C

Compulsory

Code: CI2715

Semester: 8

Lecture: 8 Hours


Language: French

Coefficient: 2

ECTS: 1

Instructor(s):

Nouria/Fatah

Learning outcomes:

UNIT OPERATIONS: Separation technology an drying

-Separations "liquid-solid" : particle size, shape and size distribution-Filtration process equipment and

calculations- Filter media- membrane filtration- membrane technology- centrifugation- sedimentation.

-separation "gas-solid" : Cyclone technology, design and calculations

-Drying solids: spray drying and fluidization-design, calculations and industrial applications

-Special care is taken to point out industrial applications and economic impact.

Prerequisite:

Fluids mechanics, heat transfer and thermodynamics Contents:

-Introduction -Filtration Fondamentals - Particle size, shape and size distribution -Fluid Flow through porous media -Membrane filtration -Membrane technology

-Inverse osmosis

-Electrodyalisis

-Sedimentation

-Centrifugation

-Gas cleaning: separation "gas-solid" : Cyclone technology

- Drying solids : spray drying and fluidization


Media: copy of slides presentation


-Procédés de séparation, Techniques, sélection, dimensionnement, J. L.Humphrey et G. E. Keller, Dunod

-Génie Industriel alimentaire tome II, Techniques Séparatives, P. Mafart et E. Béliard, Lavoisier

-Aide mémoire, Génie Chimique, E. Koller, Dunod

Assessment: Lectures: 6 sessions of course, 1h20 duration and 3 sessions of class work, 2h duration.

Written exam 2h, without documents,

Remarks:

CI 2Y

mailto:[email protected]+33%20(0)320335436ECLille




SUBJECT:

BINARY AND MULTICOMPONENT DISTILLATION

Coordinator:

[email protected]

+33 (0)320335436

ECLille Building C

Compulsory

Code: CI2711

Semester: 7

Lecture: 7 Hours

Directed studies:

Language: French

Coefficient: 2

ECTS: 1

Instructor(s):

Marek Czernicki

Fabien Dhainaut

Learning outcomes:

Main objective of this course is to give basic concepts of the binary and multicomponent distillation.

This lecture covers the methods used to calculate the distillation column.

In the second part of this unit, liquid-liquid extraction focus on how to selectively remove a compound

from a liquid phase with a solvent

Prerequisite:

Mass transfer and its application to the unit operations, heat transfer and heat exchangers, applied

thermodynamics.

Mixture rule

Contents:

Topics to be covered include: Principles of distillation, McCabe-Thiele method for binary distillation,

tray efficiency. Vapour Liquid equilibrium relations for non-ideal multicomponent solutions. MESH

equations for rigorous distillation, short-cut methods, distillation column network, extractive and

reactive distillation

Introduction to ternary diagrams, agitated vessels. Combination of agitated vessels and extraction

columns. Multiple alimentation columns. Continuous countercurrent extraction with reflux


Media:


● H.Z. Kister, « Distillation Design », McGraw-Hill, 1992

● H.Z. Kister, « Distillation Operation », McGraw-Hill, 1989

● J.G. Stichlmair, J.R. Fair, « Distillation Principles and Practices », WILEY-VCH, 1998

● Techniques de l’Ingénieur, Génie des Procédés, J1070, J1072, J2623

● Equilibrium-Stage Separation Operations in Chemical Engineering, E.J. HENLEY et J.D. SEADER

(WILEY), 1981

R.E. Treybal, "Mass Transfer Operations", McGraw-Hill, 1981

Assessment:


Remarks:

Student will be able to calculate distillate columns

CI 2Y





SUBJECT:

REACTORS

Coordinator:

[email protected]

+33 (0)320335436

ECLille Building C

Compulsory

Code: CI2816

Semester: 8

Lecture: 7 Hours


Language: French

Coefficient : 2

ECTS: 1

Instructor(s):

Rafeh BECHARA

[email protected]

03.20.33.54.44

Learning outcomes :

At the end of this course, students are capable to choose the type of reactors and to identify their

operating conditions.

Prerequisite:

1st year chemical kinetics basic knowledge, and thermodynamics basic knowledge Contents :

Reactors are equipment in which the chemical transformations are performed. The way they work is

very important for all the equipment placed upstream and downstream in an industrial process. The

objectives of the present course are to give the students basic knowledge of different kinds of reactors.

In order to make the reactor design calculation clearer, only homogeneous reactive mixtures are

considered.

After a description of the fundamental aspects needed for reactor calculations, such as mass and heat

transfers, several kinds of reactors are examined in more detail. They are respectively the well-mixed

batch reactor, the continuous stirred tank reactor, the continuous tubular plug flow reactor and the

cascade of tank reactors.

A selection of problems with numerical calculations is proposed to illustrate the importance of the

choice of the reactor for given chemical transformation(s).



J. Villermaux, Génie de la Réaction Chimique, 2nd Ed., Lavoisier Tec&Doc, 1993.

O. Levenspiel, Chemical Reaction Engineering, John Wiley & Sons, 1962.

D. Schweich, Génie de la Réaction Chimique, Lavoisier Tec&Doc, 2001.

J.M. Coulson, J.F. Richardson, Chemical Engineering, Pergamon Press, 1990.

P. Trambouze, Réacteurs chimiques, Techniques de l’Ingénieur, J 4020.

Assessment: Written Examen

Remarks:

CI 2Y

mailto:[email protected]%0d+33%20(0)320335436%0dECLille





SUBJECT:

ASPEN

Coordinator:

[email protected]

+33 (0)320335436

ECLille Building C

Compulsory

Code: CI2714

Semester: 7

Lecture:


Language: French

Coefficient: 1

ECTS: 1

Instructor(s):

Marek Czernicki

Learning outcomes:

Student will be able to do typical basic numerical simulation of industrial Unit.

Prerequisite:

Mass transfer and its application to the unit operations, heat transfer and heat exchangers, applied thermodynamics

Contents:

Topics to be covered include basic knowledge of steady-state simulation of distillation column, heat exchangers; use the thermodynamics bank of data


Media:


Documentation of Aspen Plus, www.aspentech.com

Assessment:

Students are evaluated during Laboratory classes of Chemical engineering.)

Remarks:

CI 2Y




MODULE 1 : MATERIALS SCIENCE

SUBJECT:

CORROSION

Coordinator:

Jean-Bernard VOGT


lille.fr

+33 (0)3 20 43 40 35


Semi-optional

Code: OP2801-1

Semester: 8

Lecture: 16 Hours

Directed studies:

Language: French

Coefficient: 2

ECTS: 1

Instructor(s):

Ingrid PRORIOL-SERRE,

[email protected]

+ Industrial lecturer

Learning outcomes:

The objective of the course is to present the origin and mechanism of corrosion degradation.

After completion of this course, the student should be able to: i) identify the type of corrosion

degradation - ii) propose an experimental procedure for corrosion resistance characterization

iii) select a material resistant against corrosion or a method for corrosion protection

Prerequisite:

Electochemistry, metallurgy, materials science knowledge : bachelor and first year master Contents:

Introduction: definition of corrosion – impacts of corrosion in industry

● Electrochemical aspects and types of corrosion : electrochemical reactions, Ellingham diagram, dry

corrosion, aqueous corrosion (Nernst law, Pourbaix diagram, electrochemical kinetic, Bulter-Volmer

equation, Tafel extrapolation method, corrosion potential, potential / current density curves), factors

influencing corrosion phenomena, types of corrosion

● General corrosion: atmospheric corrosion, uniform aqueous corrosion, passive materials

● Localized corrosion: galvanic corrosion, pitting corrosion, crevice corrosion, intergranular corrosion,

erosion corrosion and cavitation corrosion

● Corrosion at elevated temperature

● Corrosion prevention: materials selection, structures design, layer protection (coatings, paints,

surface treatments), use of corrosion inhibitors, electrochemical protection (sacrificial anode,

impressed current protection), service corrosion tests



Bibliographical references: Corrosion et chimie de surface des métaux, D. Landolt, Traité des Matériaux,

Volume 12, Presses polytechniques et universitaires Romandes

Corrosion des matériaux à haute température, G. Béranger, JC. Colson, F. Dabosi, Editions de Physique

Corrosion et anticorrosion, G. Béranger, H. Mazille, Mécanique et Ingénerie des matériaux, Hermes,

Précis de corrosion, J-J. Lanoureux, Sciences des matériaux, MASSON

Corrosion Engineering Handbook, Edited by Philip A. Schweitzer, P. E., Marcel Dekker, Inc.

Principles and prevention of corrosion, Denny A. Jones, printed by Quinn-Woodbine, 1991

Assessment: single written test

Remarks:

CI 2Y



SUBJECT:

CATALYTIC MATERIALS

Coordinator:

Jean-Bernard VOGT


lille.fr

+33 (0)3 20 43 40 35


Semi-optional

Code: OP2801-2

Semester: 8

Lecture: 15 Hours

Directed studies:

Language: French

Coefficient: 2

ECTS: 1

Instructor(s):

Anne-Sophie MAMEDE

anne-sophie.mamede@ensc-

lille.fr

+33 (0)3 20 33 70 90

Bureau 106

Bâtiment C3

Learning outcomes:

The course is designed so that engineering students can acquire and use the concepts of

heterogeneous catalysis. This course aims to define the phenomena that occur at the surface of a solid

and that regulate the catalytic act. It also presents the main characterization tools to determine the

textural and physico-chemical properties of catalytic materials. Finally, industrial applications of the

three classes of catalysts (metal, oxide, and acid-base) are presented.

Prerequisite:

Knowledge acquired in the kinetics module in CI 1Y - CH1609

Basic knowledge gained in CI 1Y and in preparatory classes (CPGE, CPI, L2, DUT, BTS, ATS…)

Contents:

The course is divided into six chapters:

- Introduction and Overview: Definitions, Chemical equilibrium, Action mode of a catalyst

- Adsorption - Application to the measurement of the solid surface: Physisorption, Adsorption

isotherms (Langmuir, BET method), Chemisorption, Chemisorption isotherms (Langmuir, Temkin,

Freundlich), Application to surface characterization of metal catalysts

- Textural characterization of catalysts: Surface Area, Distribution of pore size, Porosimetry,

Characterization of the active phase by temperature programmed measurements

- Physical Kinetics - Transfers of heat and mass: Overview, Diffusion of reactants and products, Extra-

and intra granular diffusions

- Metal Catalysts: Preparation and design, Industrial applications (Fischer-Tropsch reaction, automotive

depollution, desulfurization ...)

- Acid-Base Catalysts: Acid solids, Zeolites


Media: Class manual including exercises


Cinétique et catalyse, G. Scacchi, M. Bouchy, J.-F. Foucaut, O. Zahraa, R. Fournet, Editions Tec&Doc,

Lavoisiser, 2011

Cinétique et catalyse hétérogène, B. Gilot, R. Guiraud, Technosup, Ellipses, 2004

Chimie des surfaces et catalyse, G.A. Somorjai, M.-P. Delplancke, Ediscience International, 1995

Assessment: Written evaluation of 1h30

Remarks:

CI 2Y






SUBJECT:

METALLURGY

Coordinator:

Jean-Bernard VOGT


lille.fr

+33 (0)3 20 43 40 35


Semi-optional

Code: OP2801-3

Semester: 8

Lecture: 15 Hours

Directed studies:

Language: French /English

Coefficient: 2

ECTS: 1

Instructor(s):

Charlotte Becquart


lille.fr, Bât C6. Bureau 217

Tel 03 20 43 49 44

Learning outcomes:

A good understanding of phase diagrams, specially the steel and cast iron phase diagrams. Good

knowledge of the different kinds of defects in metallic materials. Good knowledge of solidifications and

solid state phase transitions.

Prerequisite:

Applied Thermodynamics S5

Cristal structure S5

Contents:

Solidification;I Experimental study of solidification : determination et interpretation of the phase

diagrams

Defects; I Point defects: vacancies, self-interstitials, substitutional atoms, hetero-interstitials. ; II 1D :

dislocations ; III 2D : twins, grain boundaries ; IV 3D : precipitates

The FeC diagram;I Steels; II Norms; III Steels heat treatments; IV Cast Irons

Phase transformations;I Thermodynamics behind solidification diagrams; II Kinetics of phase

transformation in metals and metallic alloys in the solid state. ; III Precipitation in metal solid solutions;

IV The martensitic transformation V The bainitic transformation

Solidification in real conditions


Media: copy of the slides.

Bibliographical references: 1/ « Précis de métallurgie », Jean Barralis et Gérard Maeder, Edition Nathan,

2005. 2/ « Des matériaux », Jean-Paul Baïlon et Jean-Marie Dorlot, Presses internationales

polytechnique, Ecole polytechnique de Montréal, 2000. 3/« Métallurgie : du minerai au matériau »,

Jean Philibert, Alain Vignes, Yves Bréchet et Pierre Combrade, Edition Dunod, 2002 4/ « Aide mémoire

de l’ingénieur, métallurgie. Alliages. Propriétés», Guy Murry, Dunod, Paris 2004 5/« Phase

transformations in metals and alloys », David A. Porter and K.E. Easterling, Van No strand Reinhold (UK)

Co. Ltd 1981 6/« Binary alloy phase diagrams » T.B. Massalski, ASTM publishers, 1990

Assessment: 2 h written exam

Remarks:

CI 2Y






SUBJECT:

PHYSICS OF POLYMERIC MATERIALS

Coordinator:

Jean-Bernard VOGT


lille.fr

+33 (0)3 20 43 40 35


Semi-optional

Code: OP2801-5

Semester: 8

Lecture: 12 Hours

Directed studies:

Language: French/ English

Coefficient: 2

ECTS: 1

Instructor(s) :

Serge Bourbigot

[email protected]

03.20.43.48.88

Bureau N°8

Learning outcomes:

To learn the basics of the physics of polymeric materials

Prerequisite:

Physics, chemistry and polymer chemistry at the undergraduate level

Contents:

Part 1: structure and dynamics Polymer structure Molecular dynamic Semi-crystalline polymer Part 2: Mechanics of polymeric materials Thermomechanical analysis Creep, recovery and relaxation Time/temperature scanning: transitions in polymer Time/temperature scanning: thermosets Frequency scanning


Media: Powerpoint

Bibliographical references: De la macromolécule au matériau polymère by JL Halary et F Lauprêtre

Assessment: written exam

Remarks:

CI 2Y



mailto:Serge%20Bourbigot%[email protected]

mailto:Serge%20Bourbigot%[email protected]


SUBJECT:

PLASTICITY RUPTURE

Coordinator:

Jean-Bernard VOGT


lille.fr

+33 (0)3 20 43 40 35


Semi-optional

Code: OP2801-6

Semester: 8

Lecture: 16 Hours

Directed studies:

Language: French/English

Coefficient: 2

ECTS: 1

Instructor(s):

Jean-Bernard VOGT

Learning outcomes:

The course deals with the mechanisms of plastic deformation of metals and metallic alloys and are

explained with the dislocation theory. The applications of plasticity are described through numerous

examples related to forming technology and to fracture mechanisms

Prerequisite:

Mechanical properties of materials - crystallography, bachelor level

Contents:

I ELASTICITY

Stress-strain relations, physical origin

II PLASTICITY (cf.dislocations)

Physical origin - concept of dislocations - Schmid Boas law - plastic behaviour - twinning

III HARDENING

Solid solution, cold working, grain refinement, precipitation

IV RUPTURE

Brittle fracture, ductile fracture, fatigue failure

V. FORMING

Processes, drawing, lubrication




Engineering materials, an introduction to their properties and applications, M.A. Ashby and D.R.H.

Jones, materials Science and technology, Vol.34, Pergamon press (1982) -

Mechanical behaviour of materials, T.H. Courtney, Mc Graw Hill Publishing Company (1990)

Assessment: single written exam, 1h

Remarks:

Slides are in English and the teacher is ready to switch to English language if necessary

CI 2Y




SUBJECT:

GLASSES CERAMICS

Coordinator:

Jean-Bernard VOGT


lille.fr

+33 (0)3 20 43 40 35


Semi-optional

Code: OP2801-7

Semester: 8

Lecture: 19 Hours

Directed studies:

Language: French

Coefficient: 2

ECTS: 2

Instructor(s):

Nathalie TANCRET

Learning outcomes:

Know the different families of ceramics (traditional, technical, cement) and glasses chemically and

structurally (crystallized, amorphous) and the related physical properties (magnetism,

superconductivity, ...)

Know the methods of manufacture in the laboratory and in industry, and know how to choose the best

method of manufacture according to specifications: energy saving, desired purity of the material, form

and use of the final material ...

Prerequisite:

Basics of inorganic chemistry

S7 course "introduction to materials," glasses and ceramics part

Notions of crystallography

Contents:

The aim of this course is to deepen the concepts covered in the course "Introduction to Materials" (S7)

of the great families of ceramics and glass. In particular, we will consider the following materials:

traditional and technical ceramics, cements, glasses and zeolites. Part will be devoted to various

methods of manufacturing that directly affect the nature of the material and, therefore, on its

properties. We will see manufacturing methods most commonly used in industry and we will discuss

the importance of techniques for energy savings.

Finally, special attention will be given to applications of these materials on an industrial scale and in the

daily lives of us all.

Although not all aspects can be considered in this course, the most important points will be developed

to give students good basics in solid state matter. This knowledge can be further explored in the third

year in the option "optimization and reliability of materials" or further studies (Master).


Media: lecture notes given by instructor

Bibliographical references: Solid State Chemistry : An Introduction, second edition, Lesley SMART and

Eliane MOORE, published by Chapman et Hall (UK - 1995).

Chimie Industrielle, Robert PERRIN et Jean-Pierre SCHARFF, 2ème édition, Masson (Paris - 1997).

Matériaux 2 : Microstructure et Mise en Œuvre, Michael ASHBY et David Rayner Hunkin JONES,

translated from English by Yves BRECHET, Joël COURBON et Michel DUPREUX, Editions Dunod (Paris -

1991).

Assessment: one written test, 1.5 h, at the end of the semester, with documents.

The aim is to transpose this knowledge seen during the course to real cases studies.

Remarks:

CI 2Y



MODULE 2 : MOLECULES

SUBJECT:

NATURAL MOLECULES

Coordinator :

Professeur Philippe Cotelle

[email protected]

+33 (0)3 20 43 48 58


Semi-optional

Code: OP2802-6

Semester: 8

Lecture: 12 Hours

Directed studies:


Coefficient: 2

ECTS: 1

Instructor(s):

Philippe Cotelle

Learning outcomes:

Have a vision of set on the chemistry of natural substances, their biosynthesis (steroids and terpenes),

of their total synthesis (some examples) and their biological, physiological properties

Prerequisite:

Basis in organic chemistry, semesters S5 & S6, CH1503 and CH1603 and semester S7, CH2703

Contents:

General introduction on secondary metabolites

Steroids (Cholesterol, vitamin D3, Sexual and adrenocortical hormones, Diosgenin (an important raw

material from plants)

Terpenoids (Sesquiterpenes, Monoterpenes, Sesquerterpenes, Diterpenes, Carotenes and A, E and K

vitamins)

Lipids and eicosanoids (true lipids (esters of fatty acids and alcohols (glycerol, fatty alcohols, sterols),

glycerolipids, waxes), complex lipids (Glycerophospholipids), eicosanoids (Prostaglandins, Leucotrienes)

Alkaloids (papaverine, morphine, quinine, lysergic acid, colchicine)

Polyphenols (Phenylpropanoids, catecholamines and derivatives, lignans, flavanoids, tannins)

Natural dyes and pigments


Media: powerpoint

Bibliographical references: S .V. Bhat, B.A. Nagasampagi, M. Sivakumar, Chemistry of natural products,

Springer, 2005, ISBN 3-540-40669-7

K. C. Nicolaou, T. Montagnon, Molecules that changed the world, Wiley-VCH, 2008, ISBN 978-3-527-

30983-2

Assessment: Written exam (1 hour)

Remarks:

CI 2Y



SUBJECT:

FORMULATION OF SURFRACTANTS AND DISPERSED SYSTEMS

Coordinator:


[email protected]

+33 (0)3 20 43 48 58


Semi-optional

Code: OP2802-4

Semester: 8

Lecture: 15 Hours

Directed studies:

Language: French

Coefficient: 2

ECTS: 1

Instructor(s):

Prof. Jean-Marie Aubry


lille1.fr

Tél. +33 (0)3 20 33 63 64

Learning outcomes:

Know the major classes of surfactants and their main physicochemical and functional properties

Know the traditional and modern scales for the classification of surfactants based on their

amphiphilicity.

Discover the principles of formulation of emulsions and microemulsions

Prerequisite:

Basics of organic chemistry, macromolecular chemistry and physical chemistry acquired in first year

Concepts acquired in the introductory course in the formulation chemistry course of the second year

Contents:

Surfactants: Définition, main classes and synthesis Physical chemistry of aqueous solutions of surfactant (CMC, Gibbs' equation, liquid crystals, packing parameter, cloud point, Krafft temperature) Functional properties (wetting, dispersing, emulsifying, foaming, detergency, antistatic, antifoaming). Introduction to the formulation of emulsions and microemulsions. Additional information:

Media: Duplicated lecture notes with exercises


Assessment: One written exam 1:30h

Remarks:

CI 2Y





SUBJECT:

FUNCTIONAL POLYMERS

Coordinator:


[email protected]

+33 (0)3 20 43 48 58


Semi-optional

Code: OP2802-1

Semester: 8

Lecture: 20 Hours

Directed studies:


Coefficient: 2

ECTS: 1

Instructor(s):

Patrice WOISEL

[email protected]

0320434954

Bât. C6 p. 123

Learning outcomes:

This course will overview various synthetic methods for making well-defined polymers. This course also

discusses about the applications of well-defined polymer systems as smart drug delivery materials.

After attending this course, students should be able to:

- distinguish between principle radical polymerization techniques allowing the elaboration of well-

defined polymer molecules and describe the characteristic features of each..

- unterstand the role of polymer structure and intermolecular interactions in determining the

properties of assemblies.

- distinguish the different stimuli capable of altering polymer properties

Prerequisite:

Modules CH1604/CI2704/CH1503

Other:

Contents:

- The general concepts about the preparation of well-defined polymers - Different Controlled Radical Polymerization( CRP) techniques - Elaboration and self-assembly of amphiphilic diblock copolymers - Main types of stimuli for stimulus-responsive polymers/ Applications of stimuli responsive polymers


Media: Duplicated lecture note of practical class + Publications given during the courses


- Controlled/Living Radical Polymerization : Progress in ATRP

Krysztof MAtyjaszewski ACS Division of Polymer Chemsitry ISBN 9780841269958

Assessment:

One written exam (2H)

Remarks:

CI 2Y


mailto:[email protected]ât




SUBJECT:

HOMOGENEOUS CATALYSIS

Coordinator:


[email protected]

+33 (0)3 20 43 48 58


Semi-optional

Code: OP2802-3

Semester: 8

Lecture: 15 Hours

Directed studies:


Coefficient: 2

ECTS: 1

Instructor(s):

Francine Agbossou-

Niedercorn

francine.agbossou@ensc-

lille.fr

03 20 43 49 27

Bureau 108

Learning outcomes:

Catalysis is the central issue of many chemical processes which can be examined on an academic level,

but which also take place in living systems or in large scale industrial rectors. This teaching aims (1) at

providing students the understanding of the science lying behind the important industrial applications

of homogeneous catalysis, especially for the manufacture of both commodity and fine chemicals (2)

give the future chemists a global vision of the elementary steps of organometallic chemistry and of the

catalytic cycles (3) provide kinetic and selectivity data as well as plant schemes. The most important

industrial applications of homogeneous catalysis will be covered i.e. carbonylations, hydroformylations,

polymerizations, oligomerizations, metathesis, hydrocyanation, oxidations, fine chemistry (C-C

coupling, hydrogenation, isomerization).

Prerequisite:

A good knowledge of organic chemistry, some training in organometallic chemistry will be welcome.

Contents:

Chap. 1: Sustainable chemistry, introduction to catalysis - Chap. 2: Introduction to homogeneous

catalysis, rôle of the catalyst and of the catalytic cycle - Chap. 3: Introduction to the transition metal

chemistry, reactivity of the complexes and to the elementary steps of organometallic chemistry - Chap.

4: Carbonylation: acetic acid and acetic anhydride synthesis, alkynes carbonylation, other

carbonylations - Chap. 5: Hydroformylation: OXO synthesis, biphasic hydroformylation, other

hydroformylation processes - Chap. 6: Oxidation: Wacker process, other industrial oxidation processes

- Chap. 7: Oligomerization: SHOP process, Dimersol, Difasol, other oligomérization processes - Chap. 8 :

Metathesis - Chap. 9: Polymerization: Ziegler Natta catalysis, homogeneous polymerization processes-

Chap. 10: Fine chemistry: isomerization, C-C coupling - Chap. 11: butadiene Hydrocyanation,

adiponitrile synthesis - Chap. 12: Hydrosilylation - Chap. 13: Hydrogenation and asymmetric

hydrogenation.


Media: handouts containing the slides of the course

Bibliographical references: a) Applied Homogeneous Catalysis with Organometallic Compounds B.

Cornils, W. A. Herrmann, Second Ed. Wiley-VCH, 2002 - b) Catalysis : concepts and green applications,

G. Rothenberg, Wiley-VCH, 2008 - c) Homogeneous catalysis, understanding the art, P.W.N.M. van

Leeuwen, Kluwer Academic Publishers, 2004

Assessment: 1h30, end of the course, annual

The final assessment relies on the content of the course without document neither calculator. The

students should have a very good knowledge of the basics of organometallic chemistry, the catalytic

cycles, and the important industrial applications of homogeneous catalytic processes. Specific trends of

the industrial processes have to be known. The general level of understanding of the kinetic and

selectivity of the processes will be evaluated through comparison of the processes, the catalytic

cycles…

Remarks:

CI 2Y


mailto:[email protected]%20%20%2003




SUBJECT:

MOLECULAR CHEMISTRY AND FORMULATION

Coordinator:


[email protected]

+33 (0)3 20 43 48 58


Semi-optional

Code: OP2802-7

Semester: 8


Project:

Language: French

Coefficient: 3

ECTS: 2

Instructor(s):

Christel PIERLOT

[email protected]

Valérie MOLINIER

[email protected]

Patrick DAUBIAS, Ingénieur

Maxence VANDEWALLE,

Technicien

Doctorants moniteurs

Learning outcomes:

Illustration of the notions of colloidal chemistry presented during the lessons (superficial tension,

surface agents, rheological agents)

Implementation of conductimetric measurements to determine the critical micellar concentration of

surfactants and the phase inversion temperature of an emulsion

Synthesis of functional compounds (dyeing agents, cosmetic oil). Implementation of an enzymatic

catalysis illustrating the principles of green chemistry

Setting up of an experimental design to optimize the dyeing of fibers

Prerequisite:

Physico-chemistry of formulation (S7), experimental design (S8), formulation of surfactants and

dispersed systems (S8)

Organic and macromolecular chemistry (S5, S6, S7)

Contents:

TP1: Synthesis of dyeing agents for textile

TP2: Enzymatic synthesis of a cosmetic oil: Isopropylmyristate

TP3: Determination of surfactants' CMC by conductivity and UV spectrophotometry

TP4: Superficial tension and rheological agents


Media: practical booklet

Bibliographical references: -

Assessment: notation of the reports written for each practical

Remarks:

CI 2Y





SUBJECT:

ORGANOMETALLIC CHEMISTRY

Coordinator:


[email protected]

+33 (0)3 20 43 48 58


Semi-optional

Code: OP2802-5

Semester: 8

Lecture: 12 Hours

Directed studies:

Language: French

Coefficient: 2

ECTS: 1

Instructor(s):

Pr PELINSKI Lydie

[email protected]

+33 (0) 3 20 43 65 01

ENSCL, Bureau 106

Learning outcomes:

The objective of this course is to get the student the development of organometallic chemistry as a tool

in organic synthesis, especially in drug synthesis. Examples of industrial development should make it

possible to the students to better understand the importance of metals during synthesis steps

Prerequisite:

Bases acquired in organic chemistry in 1st year.

Contents:

Organometallic synthesis and applications in fine chemistry: organometallics as electrophiles and as

nucleophiles.

Synthetic applications of transition metal carbene complexes: introduction, Fischer and Schrock

carbène complexes, Dötz reaction.

Palladium catalysed reactions in organic synthesis: introduction, Heck, Sonogashira, Stille, Suzuki

réactions, …

Chemistry of lanthanides, gold and Zirconium in organic synthesis

Bioorganometallic chemistry: metalloenzymes, bioanalysis, organometallics and therapy.


Media:

Chimie organométallique, Didier Astruc, Ed EDP Sciences.

Chimie organique : Hétéroéléments, stratégies de synthèse et chimie organométallique, Nicolas

Rabasso, Ed. De Boeck.

Les complexes de palladium en synthèse organique, Jean-Marc Campagne et Damien Prim, CNRS

Editions.


Assessment: written tests, 1h30.

Remarks:

CI 2Y




SUBJECT:

STRUCTURE AND FUNCTIONALITY OF BIOMOLECULES

Coordinator:


[email protected]

+33 (0)3 20 43 48 58


Semi-optional

Code: OP2802-2

Semester: 8

Lecture: 20 Hours

Directed studies:


Coefficient: 2

ECTS: 1

Instructor(s):

Vangelis Agouridas

Learning outcomes:

Aminoacids, Protein Structure, Knowledge of tools related to enzymatic catalysis as well as industrial

applications

Prerequisite:

Advanced Organic Chemistry (Sem. 7), Kinetics and Thermodynamics (notions)

Contents:

0. General introduction 1. From aminoacids to functional proteins: enzymes (aminoacids, protein structure, enzymes and coenzymes) 2. Theory of enzymatic activity (Enzymatic catalysis through history, a molecular approach to enzymatic catalysis) 3. Kinetics, Influence of physicochemical effectors (Henri-Michaelis-Menten, influence of pH, T°, ionic strenght) 4. Enzymatic catalysis: different types of transformations (study of hydrolytic reactions, oxidoreductases and application for fine chemicals and industrial processes) Additional information:

Media:

Lecture notes


The organic chemistry of drug design and drug action, R. B. Silverman, 1992, Academic Press, Inc, ISBN

0-12-643730-0

Biocatalysis, A.S. Bommarius & B. R. Riebel, 2004, Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim ISBN

3-527-30344-8

Biotransformations in Organic Chemistry 6th edition, K. Faber, 2011, Springer-Verlag Berlin Heidelberg,

ISBN 978-3-642-17392-9

Assessment:

1h written exam

Remarks:

CI 2Y


MODULE : DESIGN AND SYNTHESIS OF MATERIALS AND COMPOUNDS WITH DEFINED PROPERTIES

SUBJECT:

DESIGN AND SYNTHESIS OF MATERIALS AND COMPOUNDS WITH DEFINED PROPERTIES

Coordinator :

Catherine Renard

[email protected]

+33 (0)3 20 43 44 34

BLDG C7A, office 226

Compulsory

Code: TP2703

Semester: 7


Project: 20 Hours

Language: French

Coefficient: 10

ECTS: 8

Instructor(s) :

Vangelis Agouridas

Marie Colmont

Gaëlle Fontaine

Valérie Molinier

Catherine Renard

Murielle Rivenet

Nathalie Tancret

Personnel technique :

Catherine Candelier

Patrick Daubias

Maxence Vandewalle

Learning outcomes:

Manage a project from planning to implementation :

- Conduct a bibliographic survey on a given subject,

- Select, prepare, organize and conduct experiments,

- Prepare a written report including a bibliographic review and a report of the experiments conducted,

- Present their work as an oral presentation.

Prerequisite:

Contents: Introduction to bibliographic research and writing a report - theoretical and practical

knowledge of conventional chemical characterization techniques.

Contents:

The projects are designed as mini-research projects. The goal is to lead students to gain more

autonomy in the preparation, selection, organization and carrying out manipulations. If the subject

lends itself to it, students are encouraged to contact industrial or academic experts in the field.

Projects start with a bibliographic review, after which students must develop their own project. This

first step allows a thorough introduction to bibliographic research methods. Students then determine

the most appropriate synthesis routes and analysis for the subject. They are encouraged to use the

division of instrumentation available at ENSCL and expand their investigation to characterization

techniques available in the research laboratories of the USTL. After this period, the students have 56

hours, blocked for a week and a half, to implement their project.

Topics are updated every year and have an industrial and / or fundamental interest.


Assessment:

Report (bibliographic and practical) - oral presentation - investment in the project.

Remarks:

CI 2Y


MODULE : INDUSTRIAL CHEMISTRY/ANALYSIS METHODS AND SECURITY

SUBJECT:

INDUSTRIAL CHEMISTRY:ANALYSIS METHODS AND SECURITY (CIMAS)

Coordinator:

Eric BUISINE

[email protected]

/ +33 (0)3 20 33 77 48 / ENSCL

- C7B

Compulsory

Code : TP2701

Semester : 7


Project:

Language : French

Coefficient : 6

ECTS : 3

Instructor(s):

Serge BOURBIGOT


Patrice WOISEL

Jérémie BOUQUEREL

Ludovic THUINET

Eric BUISINE

Assistant-engineer:

Patrick DAUBIAS

Learning outcomes:

Acquiring practical knowledge of analytical techniques frequently used in industry: NMR , X-ray

diffraction, X-ray fluorescence, chromatography gas and liquid (HPLC) , gas chromatography–mass

spectrometry (GC-MS), scanning electron spectroscopy (SED). Quantitative, qualitative aspects and

limits of each technique are underlined. With these practicals, students have also the opportunity to be

sensitized to safety problems and the means deployed in industry (thermal control of chemical

reactions, resistance to fire and to heat of materials).

Prerequisite:

Program: course units CH1502 (semester 5), CH1602 (semester 6), CI2702 and CI2708 (semester 7)

Contents:

Analysis techniques:

- 1D and 2D dimensional Nuclear Magnetic Resonance (NMR) spectroscopy ; X-ray fluorescence ; X-ray

diffraction ; chromatography gas and liquid (HPLC) ; gas chromatography–mass spectrometry (GC-MS) ;

mechanical characterization of materials: hardness test, monotonic tensile test ; scanning electron

spectroscopy (SED)

Safety:

Evaluation of the fire-resistance for an intumescent coating ; calorimetry for safety evaluation of

chemical reactions


Media: paper documentation

Bibliographical references: given in the documentation

Assessment: participation during the practicals ; level of knowledge ; no result report

Remarks:

Working by group of four students

CI 2Y



MODULE : POLYMER CHEMISTRY

SUBJECT:

POLYMER CHEMISTRY

Coordinator:

[email protected]

+33 (0)3 20 43 43 40

Build. C6 -office 120

Compulsory

Code: TP2806

Semester: 8


Project:

Language: French

Coefficient: 6

ECTS: 3

Instructor(s):

Frédéric CAZAUX

Fabienne Samyn

Learning outcomes:

To put into practice knowledge acquired in courses and directed studies upon various synthesis

methods, as molecular weights determination and kinetics parameters during a polymerization

reaction.

Prerequisite:

Modules CH1604 et CI2704 Contents:

5 practicals by student:

- Synthesis of a styrene / methyl methacrylate copolymer

- Production of a plate of poly(methyl methacrylate) by a thermal or a photochemical process

- Synthesis of a polyamide-6,6, a polyurethane, and a phenolic thermoset

- Curing of a stratified composite material

- Suspension and emulsion polymerization of styrene - Mass distribution characterization by Gel

Permeation Chromatography analysis (GPC)

- Kinetics of free radical bulk polymerization of styrene by dilatometry

- Kinetics of polycondensation of amino-11 undecanoic acid


Media: Duplicated lecture note of practical class + documents given during the sessions








Assessment:

A report by practical, among which 3 with an oral evaluation on a part.

Remarks:

CI 2Y

mailto:[email protected]%20+33%20(0)3%2020%2043%2043%2040%20Build.%20C6



MODULE : CHEMICAL ENGINEERING (Practical studies)

SUBJECT:

CHEMICAL ENGINEERING

Coordinator:

[email protected]

+33(0)320335436

Build.

Obligatoire

Code: TP2805

Semester: 8


Project:

Language: French

Coefficient: 3

ECTS: 2

Instructor(s):

R. BECHARA, M. CZERNICKI, F.

DHAINAUT and N. FATAH

Learning outcomes:

Practical work of Chemical engineering gathers theory, practical program and simulation. They try to carry out a harmonization accentuated between the basic disciplines of chemistry and those of Chemical engineering and target three objectives: - to supplement the course of the teaching of Chemical engineering. - to confront the students with pilots of semi-industrial scale during a sufficient working time in order to obtain results of good quality and into practice to put the theoretical teaching exempted at the time of the courses and directed work. The unit operations of Chemical engineering implemented are: - Distillation and simulation by software ASPEN, - Absorption on columns, - Evaporator - Reactors

Prerequisite:

Notions of heat transfer, Thermodynamics of equilibrium between phases, Notions of elements of chemical reaction engineering.

Contents:

Manipulations are the following :

Absorption in a packed column

Distillation in a packed column and simulation (Aspen)

Evaporator “type Kestner,

Reactors: comparison between batch reactor, mixed flow reactor and plug flow reactor


Media:

Teachers documents

Bibliographical references: Courses of chemical engineering P. Wuithier : Raffinage et Génie Chimique, ed. Technip Perry : Chemical Engineers Handbook, Mc Graw Hill Mc Cabe & Smith : Unit Operations of Chemical Engineering, Mc Graw Hill

Assessment:

Written report

Remarks:

CI 2Y

mailto:[email protected]+33(0)320335436Build.



MODULE : THE COMPANY

SUBJECT:

MANAGEMENT

Coordinator:

Robert VAZILLE

Compulsory

Code: FE2808

Semester: 8

Lecture: 16 Hours

Directed studies:

Language: French

Coefficient: 2

ECTS: 1

Instructor(s):

Robert VAZILLE

[email protected]

06 8498 3505)

Learning outcomes:

The objective is to facilitate the integration of the students and to enhance their success within the

organisation at the beginning of their professional carreer.

Prerequisite:

No prerequisite.

Contents:

SESSION 1:

Overall survey of the different styles of management through different case studies.

SESSION 2:

Quality – ISO 9001 – Processus – EFQM

SESSION 3:

Knowledge Management – Transformer of information – Key concepts – Explicit and tacit knowledge –

KM for individual application – KM within a team

SESSION 4:

Crisis Management, - conflicts - acquisition



Peter Senge - la Vème discipline /Michael Porter - Competitive Advantage - Competitive Edge of

Nations/Patrick Lagadec - Le Management des Crises/Elihayu Goldratt - La théorie des contraintes - Le

but/Daniel Goleman - L'intelligence émotionnelle/Covey Stephen - The 7 habits of highly effective

people/ Gordon - Cadres efficaces/ Jack Welch - Jack/Carlos Ghosn - Turn round/Byham William -

Zapp/Michel Hammer - le re-engineering/Tom Peter - Liberation Management/Michael Tracy -

L'exigence du choix/Ouakin Mark Alain - Lire aux éclats/Walter Isaacson - Steve Jobs.

Assessment:

This is done through a short report made by the students at the end of each session, They have the task

to show their understanding of the key concepts.

Remarks:

CI 2Y


MODULE : THE COMPANY

SUBJECT :

LAW

Coordinator :

Philippe BRELIVET Avocat

Compulsory

Code : FE2809

Semester : 8

Lecture: 12 Hours

Directed studies:

Language : French

Coefficient : 2

ECTS : 1

Instructor(s) :

Philippe BRELIVET Avocat

Learning outcomes :

This law lecture aims to help students to know and to understand the international and national legal

system. As a result of this lecture, students will be able to understand fundamental legal system in a

great number of fields as for instance : International Law, European Union Law, Civil Law, Business Law,

Intellectual and Industrial Property Law, Criminal Law.

Prerequisite:

No prerequisite is asked to attend this law lecture.

Contents :

I – Public Law

1° International Law

United Nations Organisation: General Assembly, Security Council, setting up and function.

World Trade Organisation: General Assembly, Settlement Dispute Organisation, international

regulation of trade.

2° European Union (EU) Law

EU Treaty, EU commission, EU council, EU parliament, EU court of justice. EU Law (directives,

regulations, decisions).

3° The 4th october 1958 French fifth Republic Constitution

The President of the Republic, the Government, the Parliament, election, setting up, function,

executive branch power, government branch power, legislative branch power.

II – Private Law

1° Property law

Different goods and rights classification

2° Estate interest rights

Property system, intellectual and industrial property law, patents, brands, drawings and patterns

copyrightable designs, action for infrigement.

3° Contract law

Typology of various contracts, commercial sale contract, regulation of the e-business.

4° Competition and consumption law

Illicit and unfair competition law, consumption law, sale regulation for consumers and professionals.

5° Criminal law and business criminal law

9Penal offenses, different steps of a criminal trial, corporate asset abuse.


Media :


Assessment:

Remarks:

CI 2Y

MODULE : ENTREPRISE

Unité de cours :

PROPRIETE INDUSTRIELLE

Chim

Coordonnateur :

INPI

Obligatoire

Code : FE2706

Semestre : 7

Cours : 10 Heures

TD :

Langue : Français

Coefficient :

Crédits ECTS : 1

Intervenants :

Objectifs et compétences visées :

- Appréhender les concepts de base et les finalités des différents outils de la propriété industrielle ;

- Savoir mobiliser la propriété industrielle comme source d’information dans le cadre d’un processus

d’innovation ou d’une recherche documentaire ;

- Maîtriser les méthodes et outils de recherches dans les bases de données de propriété industrielle.

Pré-requis :

Aucun

Programme :

Séance 1 – Enjeux et outils de la propriété intellectuelle / industrielle

- La propriété intellectuelle et industrielle : Définitions des concepts, Les enjeux de la propriété

industrielle, instrument de stratégie économique, Intérêt comme support de l’innovation dans

l’entreprise.

- Les précautions et bons réflexes avant tout lancement de projet : La conception (le brevet d’invention,

le brevet de perfectionnement), Comment protéger la valeur ajoutée par l’esthétique (le droit d’auteur

et les dessins et modèles), L’aspect commercial (les signes distinctifs, la marque, pour différencier ses

produits et services de ceux de la concurrence), Le développement à l’international.

- Les acteurs de la propriété industrielle : En France, A l’étranger.

Séance 2 – La propriété industrielle, source d’information pour la veille

- Le brevet, les marques, dessins et modèles : outils d’information incontournables de la créativité

industrielle.

- Veille et propriété industrielle : Le rôle de la veille dans la stratégie d’entreprise, Les différents types

de veille (technologique, économique, stratégique, concurrentielle…), brevets, marques, dessins et

modèles, outils d’informations stratégiques et concurrentielles.

- La place de la propriété industrielle dans le système d’information de l’entreprise : Organiser la

diffusion de l’information vers les utilisateurs clés, pour en faire un outil de connaissance et de

décision.

Séance 3 – Utiliser les bases de données de propriété industrielle

- Présentation des bases de données de propriété industrielle (payantes et gratuites)

- Les recherches dans les bases de données : Les différentes méthodologies de recherches dans les

bases de données de propriété industrielle ; remise d’un mémo.

Séance 4 – Cas pratiques de recherches dans les bases de données

- Mise en pratique : exercices de recherches dans les bases de données de brevets.

- Recherches bibliographiques dans les brevets du domaine de la chimie (en lien avec les projets

étudiants).

Informations supplémentaires :

Références bibliographiques :

Aucune

Modes d’évaluation et objectifs :

Aucune

Remarques Particulières :

CI 2A

MODULE : PRODUCTION TOOLS

SUBJECT :

INDUSTRIAL CATALYSIS AND PRODUCTION

Coordinator:

Edmond PAYEN

[email protected]

Office: +33(0)320337737

Mobile: 0680539988

Compulsory

Code : FE2703

Semester : 7

Lecture: 11 Hours

Directed studies:

Language : French

Coefficient : 3

ECTS : 1

Instructor(s):

Edmond PAYEN

Learning outcomes :

The objective is to show students the passage of fundamental knowledge in heterogeneous catalysis to

existing real systems, ie the production units The course is divided into two parts, i) the first one

covering the fundamental aspects of the catalysis for different processes will be taught by academics

and ii) the second one which aims students to understand the industrial aspects. It will be presented

by industrials will consist on the detailed presentation of industrial complexes.

This course focuses on the large chemical processes based on the fossil energy ressources, those

dealing with the biomasse ones are described in the S9

Prerequisite:

Fundamental knowledges required for this course are the theoretical basis of heterogeneous catalysis

namely, physical adsorption, ii) the mechanisms of catalysis of contact, the adsorption isotherms, the

chemical kinetics of simple and complex heterogeneous reactions.

Contents :

Part 1: Fundamental aspects of heterogeneous catalysis (12 h)

Chap. I: Introduction: Importance of heterogeneous catalysis: Economic data, Catalysis and Sustainable

Development, Petrorefining versus Petrochemistry

Chapter II: Hydrotreating/hydroconversion of petroleum fractions (HDS- kinetic and thermodynamic

aspect-reactors and micropilot), Hydrotreating (HDT), Aromatic hydrogenation (kinetic and

thermodynamic Aspect)

Chapter III: Cracking/Reforming/isomerization of petroleum fractions (catalyst/reactor) Chapter

IV: Diagram of a refinery and Valorisation of refinery gas (Syngas, FT synthesis)

Chapter V: Development of naphtha: production of large chemical intermediates

Oxidation of alkanes and olefins (ODH, mild oxidation): kinetic (Mars van Krevelen) and thermodynamic

aspects, reactor (type of reactor, explosive range), BTX.

Chapter VI: The DeNOx Catalysis: Fundamental aspects

Part 2: Industrial Units (12h): (Given by industrials)

Chapter I: Catalytic materials for automotive pollution control and industrial units (Dr V Harlé, Solvay-

Rhodia) – 2h40

Chapter II: Refining and Petrochemicals: on site course (3h) followed by a visit of the site)

Chapter III: Main chemical intermediates (Arkema) (2h40)

-Acrylic acid, maleic anhydride, formaldehyde, ... : Appearance and Reactor thermodynamic

- Basic rules for innovation in Catalysis and Processes and economics to value better catalyst

Chapter IV: Future of petroleum industry (IFPEN) (1h40)

Chap. V: dimerizations/co-dimerizations of olefins: Processes and New Technologies (IFPEN 2h)

Special Note: the bibliography will be given for each course


Media : Xerox copy of the Power Point Draw will be distributed

Bibliographical references: Techniques of the Engineer, D. horn - Kinetics and Catalysis, G. Scacchi, M.

Bouchy, J.F. Fouvaut, O. Zahraa Ed Lavoisier Technique and Documentation, 1996 ISBN: 2-7430-0144-5

- Chemical Kinetics and Catalysis, Richard I. Masel, A Wiley Interscience Wiley and Sons, INC.

PUBLICATION, 2001 ISBN 0-471-24197-0 - Principles and practice of heterogeneous catalysis, JM

Thomas, WJ Thomas, ISBN 3-527-29288-8 WCH 1996

Assessment: The writing examination will focus on real situation in which the students will have to

propose or justify the process selected or chosen for the implementation of a reaction in an industrial

environment taking into account the problems related to hygiene and safety.

Remarks:

CI 2Y


MODULE : PRODUCTION TOOLS

SUBJECT :

NUMERICAL MODELLISATION

Coordinator :

[email protected]

+33 (0)3 20 33 62 25

Office 232

Building C6

Compulsory

Code: FE2807

Semester: 8

Lecture:


Language: French

Coefficient: 2

ECTS : 1

Instructor(s) :

Ludovic Thuinet

Andrée De Backer

Learning outcomes:

At the end of the course, the student must be able to use a rigorous method to model a specific

phenomenon in chemistry, which means :

To understand the underlying theory of the problem, to formulate the equations by specifying all the

assumptions made;

To solve the equations: generally, complex equations cannot be solved directly and require the use of a

specific numerical algorithm;

To write the programme in a specific language;

To analyze the numerical results and to compare them to experimental data.

At the end of this work, the student must understand how a scientific software is built.

Prerequisite:

Basic knowledge of a programming language, especially Scilab. Contents:

Subject CH1511: data systems

Subject TP1502: physical chemistry (practical studies)

Contents :

3 subjects will be chosen among the other courses taught at the ENSCL. The student will have to use

the following methodology:

To study a problem and to translate it mathematically

To choose an algorithm to solve the equations

To write the programme in Scilab

To plot and analyse the results with Scilab


Media: 1 short document summarizing the main features of Scilab.

Bibliographical references: a complete documentation on Scilab is at the disposal of the students on

the ENSCL Intranet. Various examples of scientific problems solved with Scilab can be found on the

ENPC website: http://cermics.enpc.fr/scilab_new/site/

Assessment: final exam of 2h on computers

Remarks:

CI 2Y


MODULE : ENGLISH

SUBJECT:

ENGLISH

Chim

Coordinator:

Anne GUEGAND

Abdelamar BENAÏSSA

Office 965

Tel:+33 (0)320336060

Compulsory

Code: LV2702

Semester(s): 7+8

Lecture:


Language: English

Coefficient : 9

ECTS: 5

Instructor(s):

Anne GUEGAND

Abdelamar BENAÏSSA

Learning outcomes:

Language tuition at the ENSCL has a double objective :





Contents:

-TOEIC -2nd year topics (for example: Money and Commerce, Health and Safety, Recruitment…)




and a presentation in English.

Remarks:


CI 2Y

Tel:+33

MODULE : GERMAN

SUBJECT:

GERMAN

Chim

Coordinator:

Beate WINKLER

[email protected]

Tel. +33 (0)320336061

Office 951

Compulsory

Code : LV2701

Semester (s): 7+8

Lecture:


Language: German

Coefficient: 9

ECTS : 5

Instructor(s):

Beate WINKLER

Monika BERTOUT

Nathalie CHAPTAL

Caroline SIPPL

Learning outcomes:

Prerequisites:

All levels.

Pupils who have never studied German can enroll in a course for "beginners".


Progress in the four language skills, but especially in the two that cause the greatest problem (listening

comprehension and oral expression) to validate at least the level B1 or B2 (A2 for the beginners) of the

CEFR.


or in foreign companies) and to communicate in situations of everyday life; acquisition of basic

knowledge of scientific and technical German in the field of chemistry.

Contents:

Internship report: learning how to describe and present the content of the students' internships. Describing a chemical process. The company: basic business German; overview of companies in the various areas of chemistry. Body, health, hygiene: visit to a doctor, security at work; cosmetic and pharmaceutical industry …

Environment and sustainable development: "green" chemistry, examples of businesses and their

activities in the German-speaking countries, current news on chemical incidents.

Dialects and characteristics of different regions in Germany and Austria - an introduction.


Media:


The method "Studio D" for beginners.



Assessment:

Continuous language assessment is carried out through at least two written tests (two hours each) and

an oral test divided into two parts (a presentation and an interactive part).

Remarks:

Students are strongly encouraged to confirm their level by a certification in cooperation with the

Goethe-Institute:

"Zertifikat Start 2" (level A2 of the CEFR) for beginners.

"Zertifikat Deutsch" (Level B1 /B2 /C1 of the CEFR) for the more advanced students.

CI 2Y


MODULE : SPANISH

SUBJECT:

SPANISH

Chim

Coordinator:

Compulsory

Code: LV2706

Semester(s): 7+8

Lecture:


Language: Spanish

Coefficient: 9

ECTS: 5

Instructor(s):

Hakima Larabii

Learning outcomes:

Strengthening B2 level of the Frame Common reference European for Languages, preparation at C1

level. At the end of the second year, the student must have attained the level of the autonomous

speaker.

Helping all students develop the condition skills they will need in professional situations (through


Contents:

Linguistic, scientific and cultural aspects:

- Oral comprehension: multimedia language laboratory or video sequence.

- Oral expression: simulations and role play activities.

- Written comprehension: scientific or cultural texts.

- Written grammatical competences.

- Written expression (writing an informal or definite letter, a dialogue…)

- Preparation for the B2 DELE (Diploma de Español como Lengua Extranjera = B2 Spanish Certificate).


Media: Various (Newspaper articles, audio and video documents…).

Bibliographical references: Marco Común Europeo C1.

Assessment: Continuous language assesment is carried out through two written tests, an interview and

a presentation in Spanish.

Remarks:


CI 2Y

MODULE : FRANÇAIS LANGUE ETRANGERE

Unité de cours :

FRANÇAIS LANGUE ETRANGERE

Chim

Coordonnateur :

CUEEP

Obligatoire

Code : LV2705

Semestre(s) : 7+8

Cours :

TD : 50 Heures

Langue :

Coefficient : 9

Crédits ECTS : 5

Intervenants :


Maîtrise efficace de la langue en particulier sur un plan professionnel : comprendre l’essentiel d’un

texte, prendre des notes en cours, donner son avis de façon brève mais claire sur un sujet général ou

professionnel.

Programme :

50H de FLE sur l'année en présentiel complétées, en fonction des acquis antérieurs et des besoins, par

un suivi individualisé avec auto-formation dirigée


Supports :

Références bibliographiques :

Modes d’évaluation et objectifs :

Examen écrit et oral


CI 2A

MODULE : JAPANESE (OPTIONAL)

SUBJECT:

JAPANESE (OPTIONAL)

Chim

Coordinator:

Jean-Luc RIGAL

[email protected]

Office 951

Compulsory

Code: LV2704

Semester(s): 7+8

Lecture:


Language: Japanese

Coefficient:

ECTS:

Instructor(s):


Hitomi KIMURA 3

Aki KIUCHI 1

Nozomu MIZUKAMI 2

Shoko MORITA 4 5


Maki TAMAOKI 1

Sachie WATANABE 2

Learning outcomes:

The main object of this course is to give basic communication tools to the students who intend to do their first, second or/and third year industrial placements in Japan, but also to complete the curriculum of future managers of a branch of industry which has many relations with Japan.

Contents:

One third of the course is devoted to civilization and two thirds to language. Because of the very particular writing system of Japanese, in which two syllabaries and at least 2000 ideograms are combined, reading and writing are given the same importance as oral work. In addition to the learning and systematic use of the two syllabaries, strong emphasis is put on the logic of ideograms, the objective being, through the study of a few hundreds of them, to facilitate the subsequent assimilation of those - much more numerous - which are necessary to everyday life. Level 2: In particular, Nihongo shoho 7-13, JDSR 6-14, Katana nyûmon, Bushu 1-100 (101-214 in level 3).


Media:

Minna no nihongo, Nihongo shoho (1, 2, 3), Nihongo chûkyû, Kana nyûmon (hiragana 1) (katakana 2),

Nelson Kan’ei jiten (2, 3)


Nihon etoki jiten 1-16 (JTB), Nihongo notes 1-5 (The Japan Times), Situational Japanese 1-5 (The Japan

Times)

Assessment:

Oral and written exams, continuous assessment

Remarks:

The course is divided into 5 levels, and not according to the three years of the curriculum. As a matter of fact, if Level I is mainly attended by first year students, Level II by second year students and Level III by third year students, some students start the study of Japanese in their second/third year, whereas other students - especially those who come from the "CPI" - may have been studying Japanese for two years or more when they start their engineering studies.

Prerequisites:

None, other than the desire to learn Japanese (WRITTEN INCLUDED)

CI 2Y


SUBJECT :

THE CHEMISTRY OF CARBOHYDRATES

Coordinator:


[email protected]

03 20 43 48 58

Door 101 Building C1

Obligatoire

Code : OP2802-8

Semester : 8

Lecture : 10 Hours

Directed Studies :

Language : French

Coefficient : 1.5

ECTS :

Instructor(s):


Learning Outcomes:

Have a vision of set on the carbohydrate structure (mono, di et polysaccharides) and their use as agro

sourced building blocks in the synthesis of biological active molecules

Be able to apply the protection/deprotection strategy to the carbohydrate chemistry and design

synthesis of mono and disaccharides of biological interest (ex : 18-fluoroglucose for positron emission

tomography, Tamiflu, AZT)

Prerequisite:

Basis in organic chemistry, semesters S5 & S6, CH1503 and CH1603 and semester S7, CH2703

Contents:

• Introduction: cycle of carbon, fonctions, métabolism

• Structure: Classification, fonctions (aldose, cétose, reductor, non-réducteur), isomerism,

anomerism, equilibrium (furanose, pyranose, acyclic form)

Monosaccharides, Disaccharides, Polysaccharides, Cyclic saccharides

• protection, reactivity, synthesis

• Introduction

• Reduction

• Oxidation

• Reactions at the carbonyl fonction

• Protection of the hydroxyl groups

• Synthesis of some compounds of biological interest

• Additional information:

Media : powerpoint

Bibliographical references : S .V. Bhat, B.A. Nagasampagi, M. Sivakumar, Chemistry of natural products,

Springer, 2005, ISBN 3-540-40669-7

Assessment : Written exam (1 hour)

Remarks:

CI 2Y


Année 2012-2013

5th academic year (semesters 9 and 10)Final year of study Master level

MODULE : BIOMASS

SUBJECT:

MOLECULAR AND ENZYMATIC CONVERSION OF BIOMASS INTO CHEMICALS

Coordinator:

[email protected]

Office :+33 (0)320434949

Mobile : 0680539988

Semi-optional

Code: OP3901-11

Semester: 9

Lecture: 20 Hours

Directed studies:

Language: French

Coefficient: 4

ECTS: 2

Instructor(s):

Valérie MOLINIER

[email protected]

+33 (0)320 33 63 66

Office 19, building C6

Learning outcomes:

Knowing the main biomass feedstock and their conversion into chemicals in a context of sustainable

development

Have an overview of the nature and use of the platform molecules easily accessible at an industrial

scale from chemical and enzymatic conversion of biomass, with an emphasis on the starch derivatives

Get familiar with the “Green Chemistry” principles

Knowing the solvents and surfactants obtained from biomass: their preparation, their properties, their

use and how they can substitute the petrochemical homologues

Prerequisite:

Contents:

Organic chemistry lessons of semesters S5, S6 and S7 ; Formulation physico-chemistry S7

Contents:

Context

Why using biomass as raw material for chemicals

Definitions: biomass / valorisation / green chemistry / synthon

Resources / biomass feedstock

Chemicals from starch

The starch-rich cultures

Starch extraction

From starch to glucose / main applications

From glucose to sorbitol / main applications

Some other synthons accessibles from starch via Oxydation / Fermentation / Dehydratation /

Hydrogenation

Solvents from biomass (see separate description)

Surfactants from biomass (see separate description)


Media: lesson documents


Selected scientific articles corresponding to the keywords: biomass, biorefineries, agro-synthons,

chemicals from biomass, biosolvents, biosurfactants

« La chimie verte » Paul Colonna

Assessment:

Written exam (2h) at the end

Remarks:

CI 3Y



MODULE : CHEMISTRY OF BIOMASS

SUBJECT:

CATALYSIS FOR PRODUCING KEY CHEMICAL INTERMEDIATES

Coordinator:

[email protected]

+33 (0)320434949

0680539988

Building C3

Obligatoire

Code: OP3901-12

Semester: 9

Lecture: 20 Hours

Directed studies: -

Language: French

Coefficient: 4

ECTS: 2

Instructor(s):

Franck Dumeignil

franck.dumeignil@univ-

lille1.fr

+33(0)3.20.43.49.38

Bureau 101/Bât C3

Learning outcomes:

The student who will have validated this module will have acquired a broad, complete and up-to-date

view of the main types of catalytic transformations to be implemented in the latest concepts of

biorefineries. His(her) knowledge will place him(her) at the forefront of the state of art in a booming

emerging sector with a strong societal demand, where many - both academic and industrial - career

opportunities already open.

Prerequisite:

Students wishing to take this training must have a good background in catalysis and must be aware of

the most usual reactions (and of the main moieties of interest) in organic chemistry, together with

having a broad basic knowledge of the main current techniques used in spectrochemistry. The

multidisciplinary nature of the topic addressed in the lectures also requires a good general culture and

a spirit of curiosity that is not limited to chemistry but also touches on all scientific disciplines.

Contents:

The development and implementation of biorefinery processes is of the upmost importance to meet

the vision towards a sustainable economy based on bio-resources. In this context, catalysis, either

enzymatic, heterogeneous or homogeneous is playing a major role like this is already the case in a

‘conventional’ refinery based on the treatment and the conversion of petro-resources. Nevertheless,

contrary to petro-resources of which the nature and composition variations are ‘relatively’ limited,

under the term ‘bio-resource’ or ‘biomass’ are gathered compounds of very different natures, namely

cellulose, hemicellulose, oils, lignin and so on… Thus, a complete set of specific catalytic processes must

be developed, which will constitute core technologies that will be implemented in the so-called

‘biorefineries’.

The major catalytic technologies developed for – especially – elaborating the new generation of

biorefineries expected for 2015-2020 will be thus reviewed within the frame of these lectures (e.g.,

project 'EuroBioRef' leaded by the coordinator of this teaching unit:

http://www.dr18.cnrs.fr/assets/files/weblettre210/EuroBioRef_H_Res.pdf).


Media: Lecture presented under the form of Powerpoint presentations, with movies, and written

documents.

Bibliographical references: http://eurobioref.org/Summer_School/

‘Biorefinery: From Biomass to Chemicals and Fuels’ (Eds Michele Aresta, Angela Dibenedetto, Franck

Dumeignil) Degruyter editions. ISBN: 978-3-11-026028-1.

Assessment: Final control under the form of a multiple-choice questionnaire.

Remarks:

CI 3Y


http://www.dr18.cnrs.fr/assets/files/weblettre210/EuroBioRef_H_Res.pdf

http://eurobioref.org/Summer_School/

MODULE : CHEMISTRY OF THE BIOMASS

SUBJECT:

CHEMISTRY OF NATURAL AND BIOSOURCED MACROMOLECULES

Coordinator:

[email protected]

0320434949

0680539988Tel / Bureau

Obligatoire

Code: OP3901-13

Semester: 9

Lecture: 20 Hours

Directed studies: -

Language: French

Coefficient: 4

ECTS: 2

Instructor(s):

Patrice Woisel

Patrice.woisel@ensc-

lille.fr/0320434954/Bât. C6 p.

123

Learning outcomes:

The main objective of this course is to present an overview of the different chemical transformations

that can be used to elaborate interesting polymeric materials from biosourced (macro)molecules.

Prerequisite:

CH1604/CI2704/CH1503

Contents:

Chapter 1: Introduction

1) Different classes of biosourced polymeric materials

2) Agricultural sectors involved

3) Industrial sectors involved

4) Assets and constraints

Chapter 2: Agro-materials

1) Main classes of vegetal based biopolymers

2) Biosynthesis and properties

3) Chemical transformations and applications

Chapter 3 : Bio-polymers

1) Main synthons

2) Polymerisation of synthons


Media: Duplicated lecture note + documents given during the courses


1) Renewable Polymers: Synthesis, Processing, and Technology Vikas Mittal (Editor), Wiley, ISBN: 0470938773, 978-0470938775

2) Monomers, Polymers And Composites From Renewable Resources Elsevier, 2008 ISBN: 0080453163, 9780080453163

Assessment: 1 written exam

Remarks:

CI 3Y


mailto:[email protected]/0320434954/Bât

mailto:[email protected]/0320434954/Bât

http://www.amazon.com/s/ref=ntt_athr_dp_sr_1/187-0149602-9811838/187-0149602-9811838?_encoding=UTF8&sort=relevancerank&search-alias=books&ie=UTF8&field-author=Vikas%20Mittal

MODULE : CHEMISTRY OF THE BIOMASS

SUBJECT:

BIOENERGIES

Coordinator:

[email protected]

+33 320434949

Building C3 – ground floor

Phone +33 (0)680539988

Semi-optional

Code: OP3901-14

Semester: 9

Lecture: 20 Hours

Directed studies:

Language: French

Coefficient:

ECTS: 2

Instructor(s):

Edmond PAYEN

Learning outcomes:

After the S6 and S7 during which the students had learned industrial heterogeneous catalysis and seen the major industrial processes especially for energy production, the student who has validated this module will have acquired a broad vision, integrity and timeliness, of the major types of transformations, catalytic or not, implemented or considered for the production of energy from biomass. Knowledge of the chemistry of these processes and reactors to implement will place them at the top of the state of the art in an emerging sector booming industrial level (bioTfuel project site on Total Dunkerque site, Sasol-Katar).

Prerequisite: Students wishing to follow this training would have a good grounding in i) heterogeneous catalysis, ca. physical and chemical adsorption, formal kinetics, catalyst preparation (ca. should have followed the course XXXX -A.S Mamede S6- and the XXXX-A S Mamede S8 ) and ii) Industrial Catalysis and production (course XXXX-E. Payen S7) Contents Chap. 1: (1 h): Introduction: The energy sources of the XIX to XXI century ; Chap. 2 (3 h): biogas (CH4, CO2, ...): Production process, purification; Downstream applications (oxidation of methane, etc ...). Chap. 3 (1 h): 1st generation of biobased fuels: @ Diester, process AXENS Chap. 4 (4 h): Bioconversion of cellulose and hemicellulose: Processes of hydrolysis and fermentation primarily for alcohols;

Valuation of alcohols (Bio fuel and fuel additives; steam reforming (hydrogen production and co-products

Chap. 5 (5 h): Biosyngas (CO/H2) of lignin and biomass waste Production process: gasification of waste biomass Processing / Applications: (FT synthesis for obtaining alkanes, diesel additives);

Synthesis Syngas for the production of alcohols and other compounds (MeSH, ethylene, hydrogen).

Chap. 6 (5 h): bio-oils and their transformations Methods for obtaining (Flash Pyrolysis, .... of lignin and biomass residues; Purification and processing of bio-oils (HDO, decarboxylation, FCC ...) Applications of bio-oils (diesel fuels by gasification and FT) Conclusion: Schematic global energy production from biomass 1 conference given by an industrial in the energy sector (1h) Additional informations Media: Power Point available on the intranet, Printout distributed (with inset for free student comments)) Bibliographical references: Les biocarburants, D Ballerini, Editions Technip, 2006, France

Bibliographic references given during the course Assessment: Final writing examination (2h) will be performed that will be divided into 2 parts, the 1

st one dealing

with fondamental aspects of a process and the second one which will consist in an analysis of a scientific publication on a process Remarks:

CI 3Y


MODULE : CLEAN PROCESSES

SUBJECT:

BIOPROCESSES

Coordinator:

[email protected]

+33 320434949


Phone +33 (0)680539988

Philippe Jacques

Tel+33 (0)328767440

Philippe.Jacques@polytech-

lille.fr

Semi-optional

Code: OP3901-21

Semester: 9

Lecture: 20 Hours

Directed studies:

Language: French

Coefficient: 4

ECTS: 2

Instructor(s):

Marlène Chollet

François Krier

Alice Rochex

François Coutte

Learning outcomes:

To understand basic microbiology at qualitative and quantitative point of view (the different types of

micro-organisms, their conditions and kinetic of growth, their metabolism)

To be able to set up and develop a microbial product (strain screening, growth optimization, production

in bioreactors, formulation)

Prerequisite:

General biochemistry, mass transfer, heat transfer, mixing

Contents:

The course is organized with combined lectures and exercises.

Chapters : History, Microbial culture and mass balance, Growth kinetics, Growth control and

sterilization, cellular structure and microscopy, taxonomy, metabolism, genetic engineering, production

in bioreactors, downstream processing, Bioprocess optimization, Examples of production : yeast,

antibiotics, enzymes, biopesticides, biosurfactants, soil bioremediation.


Media: syllabus

Bibliographical references: Microbiology, Prescott ; Microbiologie Industrielle, Leveaux ; Techniques de

l’ingénieur

Assessment: written examination with general questions and exercises

Remarks:

CI 3Y


MODULE : PROCEDES PROPRES

Unité de cours :

GENIE DES REACTEURS – REACTEURS DU FUTUR/TECHNOLOGIES PROPRES

Chim

Coordonnateur :

[email protected]

Semi-optionnel

Code : OP3901-23

Semestre : 9

Cours : 15 Heures

TD :

Langue : Français

Coefficient :

Crédits ECTS :

Intervenants :

Pascal Fongarland


The objective of this learning unit is to give some skills for the experimental design and scale-up of

industrial or laboratory reactors for clean processes. The coupling between chemical reaction (catalytic

or not) and the mass/heat transfer will be studied using the chemical engineering tools. The first part

will allow to identify the limitations of the traditional reactor technologies in order to introduce the

different ways of improvements for the new reactors as process intensification (microreactors,

structured reactors ...) or the integration of other unit operations (reactive extraction ...).

Pré-requis :

The knowledge required for this course are the bases in mass/heat transfer and in dimensional analysis.

Bases in ideal reactors (perfectly mixed reactor, plug flow reactor) are also required. The knowledge in

heterogeneous catalysis will be brought with the course provided in the second year and will allow to

give a background in the problematic of the heterogeneous reactors .

Programme :

Part 1: Heterogeneous reactors (course/TD 15 h) Chap. I. Introduction Industrial reactors, the reactor in the process. Chap. II. Chemical production rate Measurement of a kinetic rate, apparent and intrinsic rate, chemical and physical phenomena coupling. Chap. III. Reaction/diffusion competition. External and internal mass transfer, the case of gas-liquid system. Chap. IV. Heterogeneous reactors Fixed and fluidized bed, agitated reactors, scaling and simulation of heterogeneous reactors. Part 2: New reactors and clean technologies (course/TD 10 h) Chap. I. What are the needs to design new reactors ? Limitations of actual technologies, process intensification: a "new-old" concept, the different approaches. Chap. II. Mass/heat Transfer intensification Micro and structured reactors, characteristic parameters, process security, drawbacks of the micro technology, "numbering-up" vs "scaling-up", energy saving, examples. Chap. III: From batch to continuous reactor. Chap. IV: Shift of the equilibrated reactions Shift equilibrium, reactive distillation, membrane technology. Chap. V: Conclusion et perspectives Intensification et clean process, integrated process


Supports : Power Point with paper copy

Bilibiography: Génie de la réaction catalytique, D. Schweich, Ed. Tech&Doc; Techniques de l'ingénieur;

Elements of Chemical Reaction Engineering, H. Scott Foggler, Pearson Int. ed.

Course evaluation : Writing exam (2h).


CI 3A

MODULE : CLEAN PROCESSES

SUBJECT:

RECYLING AND GREEN PLASTIC MANUFACTURING PROCESS

Coordinator:

[email protected]

+33 320434949


Phone +33 (0)680539988

Semi-optional

Code: OP3901-24

Semester: 9

Lecture: 15 Hours

Directed studies:

Language: French

Coefficient: 2.5

ECTS: 1

Instructor(s):

Sophie DUQUESNE,

+33(0)320337236, Office 112

Learning outcomes:

The aim of this lecture is to present the engineering processes of polymers and composite materials

that meet the criteria of sustainable development as well as the recycling processes.

Prerequisite:

Contents: Polymer Material sciences (S7-S8) ; Life Cycle Assessment (S5) ; Polymer characterisation and

formulation (S7-S8) ; Polymer from Renewable Resources (S9)

Contents:

Green Engineering Process of Polymer and Composites

- The use of natural substances (starch…)

- Bacterial polymers production

- Innovative Processes (reactive extrusion, use of supercritical fluid…)

- Clean Production of Composites

Polymer Recycling

- Sorting of polymers

- Chemical recylcing

- Mechanical recycling

- Recycling of polymer composites


Media:


Caroline Baillie; Green Composites: Polymer Composites and the Environment, CRC Press

Assessment: written exam, 60min

Remarks:

CI 3Y


MODULE : ENVIRONMENT

SUBJECT:

GASEOUS EFFLUENT TREATMENT

Coordinator:

[email protected]

+33 320434949


Phone +33 (0)680539988

Semi-optional

Code: OP3901-31

Semester: 9

Lecture: 20 Hours

Directed studies:

Language: French

Coefficient: 4

ECTS: 2

Instructor(s):

Jean-François / Lamonier

Anne / Ponchel

Learning outcomes:

Control the industrial emissions into the atmosphere to improve the air quality is a major

environmental and economic challenge for the industrial world. Since the reduction targets of

industrial pollutants in the air are increasingly difficult to reach, it has become essential to treat the

gaseous emissions before their release into the atmosphere. This course unit aims to present the most

suitable remediation methods but also recent developments which can be implemented for the

treatment of air containing pollutants. A student who has validated this course unit will have acquired

skills in current concepts and practices of treatment processes of the air (like regenerative or

destructive) but also will possess a thorough knowledge of the latest technological developments for

the treatment of industrial gaseous effluents

Prerequisite:

Basic notions of thermodynamics and kinetics (solubility, reactivity, catalysis ...)

Contents:

* Sources and impacts of major pollutants at local, regional and global scale

* Means implemented in the fight against air pollution

* Presentation of the different processes leading to the destruction or the recovery of the pollutants

* Application to the treatment of NOx, N2O, SOx, VOC and dust (current technology, emerging or

innovative / research)

* Capture, Storage and Recovery of CO2


Media:

Courses in the form of "powerpoint" presentation + handouts


1. Traitement des pollutions industrielles – Emilian Koller - Dunod/L'Usine Nouvelle (2009)

2. Les COV dans l’environnement – Pierre Le Cloirec - Tec & Doc, Lavoisier, Paris (1998)

3. Traitement des fumées - Pierre Le Cloirec – Techniques de l’Ingénieur (2006)

4. Analyse et traitement physicochimique des rejets atmosphériques industriels – M. Popescou et Coll -

Tec & Doc, Lavoisier, Paris (1998)

5. La réduction des émissions de composés organiques volatils dans l’industrie - Guide et Cahier

Techniques, Ademe, Angers (1998) …

Assessment:

1 Final exam: questions from lesson + study of documents

Remarks:

CI 3Y



SUBJECT:

WATER TREATMENT

Coordinator:

[email protected]

0320

0680539988Tel / Bureau

Semi-optional

Code: OP3901-32

Semester: 9

Lecture: 20 Hours

Directed studies:

Language: French

Coefficient: 4

ECTS: 2

Instructor(s):

Alain HURE

[email protected]

+ 33 3 44 38 39 40

+ 33 6 62 00 75 24

Learning outcomes:

Cover the main problem of water treatment

Make the useful knowledge on pollution

Understanding the issues in its various aspects, prevention, conditioning and treatment

Prerequisite:

No special knowledge if its to have a good knowledge in chemistry

Contents:

1: raw water

2: industrial water

3: drinking water

4: treatment of urban and industrial waste water

5: waste management of sludge


Media: powerpoint presentation


Memento technique de l’eau – Degremont ; Corosion des métaux et alliages – Beranger et Mazille ;

Heat echanger fouling – Muller Steinhagen ; L’épuration biologique des eaux – Edeline; Bactéries et

environnement - Pelmont

Assessment:

Remarks:

CI 3Y




SUBJECT:

CONTAMINATED SOILS TREATMENT

Coordinator:

[email protected]

+33 320434949


Phone +33 (0)680539988

Obligatoire

Code: OP3901-33

Semester: 9

Lecture: 8 Hours

Directed studies:

Language: French

Coefficient: 1.5

ECTS: 1

Instructor(s):

Nicolas PROIX

[email protected]

Laboratoire d’analyses des

sols,

273 rue de Cambrai

62000 Arras

Learning outcomes:

To acquire fundamental knowledge on soils, to know the methods of treatments of polluted soils and

the analytical tools.

Prerequisite:

General chemistry

Contents:

- Presentation of soils (2 hours): Notion of pedology, quality of the French soils

- Various pollutants (2 hours): Pollutants of mineral origin, organic pollutants

- Treatments (3 hours): The various methods of remediation, the stabilization, the management of

polluted sites

- Legislation and examples of case studies (1 hour)


Media: lecture manual.


Guide des analyses en analyse pédologique, Denis Baize, ed Quae, 2000

Les éléments traces métalliques, approche fonctionnelle et spatiale, Denis Baize, ed Quae, 2002

Stratégie de remediation des sols pollués, jean Louis Morel,

Assessment:

A written examination

Remarks:

CI 3Y




SUBJECT:

RECYCLABILITY AND RECOVERY OF INDUSTRIAL WASTES

YCLABILITE ET VALORISATION DES DECHETS INDUSTRIELS

Coordinator:

[email protected]

+33 320434949


Phone +33 (0)680539988

Semi-optional

Code: OP3901-34

Semester: 9

Lecture: 12 Hours

Directed studies:

Language: French

Coefficient: 2

ECTS: 1

Instructor(s):

Caroline PIROVANO

Murielle RIVENET

Learning outcomes:

In the global context of the management of waste and in the respect for the criteria of sustainable

development, the objectives of this lecture are to present, from an economic, legislative and

technologic point of view, the principles of recycling and valorization of industrial wastes.

Prerequisite:

General chemistry

Contents:

- The global context of wastes: classifications of wastes, legislation…

- Wastes regulation and recovery: The actors and their problematic

- Thermal treatments methods and associated valorisations

- Recycling of metals (ferrous and non ferrous), the management of the steel-making by-products

- Recycling of oils and solvents

- Recycling of nuclear fuel cycle


Media:

Lecture manual.


- Techniques de l'Ingénieur (http://www.techniques-ingenieur.fr/)

- Environmental Chemistry, 9th ed., Stanley E. Manahan, CRC Press, 2010

- ADEME publications, various documentations…

Assessment:

A written examination

Remarks:

CI 3Y


http://www.techniques-ingenieur.fr/

MODULE : FORMULATION PHYSICAL CHEMISTRY

SUBJECT:

FORMULATION PHYSICAL-CHEMISTRY

Coordinator:

Prof. Jean-Marie AUBRY

Jean-marie.aubry@ensc-

lille.fr

Tel + 3 (0)320 33 63 64

Office: C6 Ground floor

Obligatoire

Code: OP3902-11

Semester: 9

Lecture: 60 Hours

Directed studies:

Language: French

Coefficient: 12

ECTS: 4

Instructor(s):

Prof Jean-Marie AUBRY

Prof Jean-Louis SALAGER

(University of Merida)

Learning outcomes:

Learning fundamental concepts and basic techniques of colloidal chemistry

Understanding the physical origin of optical effects (opacity, dullness, color, pearlescent) utilized in

formulated products.

Master the tools for designing micro-and macro-emulsions with given characteristics (morphology,

particle size, stability, viscosity).

Prerequisite:

Light-matter interactions (scattering, refraction, diffraction)

Binary and ternary phase diagrams.

Superficial, interfacial and self-aggregative properties of surfactants

Contents:

A) Molecular solubilization

● HSE properties of conventional and eco-friendly solvents

● Hansen solubility parameters and novel solubilization theories

B) Colloids and dispersed systems Solid / Liquid:

● Physico-chemical and functional properties of surfactants

● DLVO theory, steric and electrostatic stabilization of dispersed systems

● Interaction of light with dispersed systems (particle size, opacity)

C) Phase diagram of binary and ternary systems Surfactant / Water / Oil

● Solubilization in water of hydrophobic compounds (application to perfumes and degreasing)

● Microemulsions, the HLD and the “optimal formulation” concepts

D) Emulsions

● Maps formulation-composition (correlation between micro- and macro- emulsions)

● Principles of emulsion formulation and characterization methods


Media: Handout of JL Salager’s slides

Bibliographical references: All articles of the section “Formulation” of the encyclopedia “Techinques de

l’Ingénieur”

Assessment: Written examination of 2 hours

Remarks:

CI 3Y



MODULE : EXPERIMENTAL DESIGN AND DATA ANALYSIS

SUBJECT:

EXPERIMENTAL DESIGN FOR MIXTURES

Coordinator:


lille.fr

Tél +33(0)3 20 33 63 64

Building C6

Semi-optional

Code: OP3902-21

Semester: 9

Lecture: 10 Hours

Directed studies:

Language: French

Coefficient: 2

ECTS: 1

Instructor(s):

Christel Pierlot

[email protected]

Tél : 03-20-33-63-65

Bât C6, RdC, salle 21

Learning outcomes:

Provide basic notions for designing and analyzing experimental design mixtures

Prerequisite:

Contents:

Classical experimental design (screening matrix ,factorial and fractional factorial

matrix, Simplex, Surfaces responses)

Contents:

1. Introduction

2. Details of the approach

3. Scheffé Simplex Networks

4. Scheffé Simplex Networks (centroids)

5. Axial matrices

6. Mixtures with constraints


Media:

Distributed lecture notes, course on power point


Techniques de l'ingénieur : Planification d’expériences en formulation, Didier MATHIEU, Roger PHAN-

TAN-LUU, J2241, (2001).

Assessment:

Submission of a report (15 pages) and oral presentation (15 min) on a project to

optimize recipes (chocolate mousses, marshmallows,nougat, ...) by the method of experimental

designs (classic or mixtures)

Remarks:

CI 3Y




MODULE : EXPERIMENTAL DESIGN AND DATA ANALYSIS

SUBJECT:

ADVANCED EXPERIMENTAL DESIGN AND PRINCIPAL COMPONENT ANALYSIS

Coordinator:


lille.fr

Tél +33(0)3 20 33 63 64

Building C6

Semi-optional

Code: OP3902-22

Semester: 9

Lecture: 5 Hours


Language: French

Coefficient:

ECTS: 1

Instructor(s):

Christel Pierlot

[email protected]

Tél : +33(0)3 20 33 63 65


Learning outcomes:

Provide basic notions necessary to design and analyze

- advanced experiments designs (custom matrix, exchanges algorithm construction )

- A classical method of statistical analysis: the principal component analysis (PCA).

Prerequisite:

Contents: classical experimental design (screening matrix ,factorial and fractional factorial

matrix, Simplex, Surfaces responses)

Conventional statistics courses (mean, variance, standard deviation,normal distribution, ...)

Contents:

Course (5 hours):

1) Advanced Design of Experiments

1.1) matrix with factors at more than 3 levels

1.2) Custom Matrix, with constraints, algorithm exchanges construction

2) Principal Component Analysis

Directed studies (5h):

1) In classroom

Completion of design of experiments with constraints (optimization of a cocktail by sensorial analysis)

2) On the computer

Use of softwares (design of experiments and ACP)

-treatment data from the optimization of a cocktail, and a variety of situations encountered

in formulation area.


Media:



Techniques de l'Ingénieur : Analyse des données ou statistique exploratoire multidimensionnelle,

Philippe BESSE, Alain BACCINI, AF620 (2011).

Assessment: Test in computer room (1 hour) using two sofwares (design of experiments and ACP)

Remarks:

CI 3Y




MODULE : FUNCTIONAL INGREDIENTS AND FORMULATIONS

SUBJECT:

COLOR, DYES AND PIGMENTS

Coordinator:


lille.fr

Tél +33(0)3 20 33 63 64

Building C6

Semi-optional

Code: OP3902-31

Semester: 9

Lecture: 6 Hours

Directed studies:

Language: French

Coefficient: 5

ECTS: 1

Instructor(s):

Christel Pierlot

[email protected]

Tél : +33 (0)3-20-33-63-65


Learning outcomes:

Provide basic notions necessary to to understand the mechanisms ofcolor perception.To understand

the principles of color measurement. To know the main pigments and dyes used in industry.

Prerequisite:

Contents: classical organic, inorganic and general chemistry courses

Contents:

Mechanisms of color perception.

How do you measure a color (apparatus)?

Main dyes and pigments

Review of formulated products


Media:



Techniques de l'Ingénieur-Colorants et pigments-Alain Bondoux, AM3234, (2003).

Assessment:

Test without documents, 45 min

Remarks:

CI 3Y




MODULE : FUNCTIONAL INGREDIENTS AND FORMULATIONS

SUBJECT:

RHEOLOGICAL AGENTS

Coordinator:


lille.fr

Tél +33(0)3 20 33 63 64

Building C6

Semi-optional

Code: OP3902-32

Semester: 9

Lecture: 6 Hours

Directed studies:

Language: French

Coefficient: 5

ECTS: 1

Instructor(s):

Christel Pierlot

[email protected]

Tél : +33 (0)3-20-33-63-65


Learning outcomes:

Descriptions of the various organic and mineral rheological agents used in formulation

Prerequisite:

Contents: classical organic and polymer chemistry courses

Contents:

-Rheology: Reminder

-Emulsions

-Polymers (Thickening, reversible and irreversible Gelling)

- Minerals

- Surfactants

- Review of formulated products (cosmetic creams, shampoos, ...)


Media: Distributed lecture notes, course on power point

Bibliographical references: Techniques de l'Ingénieur :

Formulation des polymères synthétiques en cosmétique, Bernard LE NEINDRE, Patrick CANCOUËT, J 2

190 (2011).

Carraghénanes : agents gélifiants,épaississants et stabilisants+ Carraghénanes : agents gélifiants,

épaississants et stabilisants, Jaime ZAMORANO, F 5 080 (2006).

Mesure de la viscosité, Viscosimètres et rhéomètres, Dominique DUPUIS, R 2 351 (2008).

Assessment: Test without documents, 45 min

Remarks:

CI 3Y




MODULE: FUNCTIONNAL INGREDIENTS AND FORMULATIONS

SUBJECT:

BIO-BASED SUFRACTANTS AND SOLVENTS

Coordinator:


lille.fr

Tél +3 3 20 33 63 64

Office: Building C6

Ground flour

Semi-optional

Code: OP3902-34

Semester: 9

Lecture: 10 Hours

Directed studies:

Language: French

Coefficient: 2

ECTS: 1

Instructor(s):

Valérie MOLINIER

[email protected]

+33 3 20 33 63 66

Office 19, Building C6

Ground flour

Learning outcomes:

Knowing the solvents and surfactants obtained from biomass: their preparation, their properties, their

use and how they can substitute the petrochemical homologues

Prerequisite:

Contents:

Organic chemistry lessons of semesters S5, S6 and S7; Formulation physico-chemistry S7

Contents:

Solvents from biomass

- Definitions (solvents, biosolvents, solvents from biomass) - Families of “green” solvents on the market: preparation, volumes, industrial actors - Evolution of the solvents market / environmental regulations - Application fields for biosolvents: solvents (pharmacy, agrochemistry), lubrificants, plasticizers (paints, coatings) - Substitution of dangerous solvents / physico-chemical and predictive tools - Physico-chemical characteristics of “green” solvents; formulation of green solvents Surfactants from biomass

- Families of “green” surfactants on the market: volumes, industrial actors - Evolution of the surfactants market / environmental regulations - Sources of the lipophilic part: fatty esters / acids / alcohols: preparation, nomenclature - Surfactants from glycerol, sorbitol, glucose, sucrose:

Application fields Industrial and alternative (green chemistry) preparation Physico-chemical properties compared to petrochemical derivatives Bionotox properties

- Surfactants produced by micro-organisms: biosurfactants Additional information:

Media:

lesson documents


Selected scientific articles corresponding to the keywords: biosolvents, biosurfactants

Nonionic surfactants (Surfactant science series)

Handbook of applied surface and colloid chemistry

Assessment:

Written exam (1h) at the end

Remarks:

/

CI 3Y




MODULE : PROCESS OF THE FORMULATION ENGINEERING

SUBJECT:

RHEOLOGY OF FLUIDS

Coordinator:


lille.fr

Tél : +33 3 20 33 63 64

Office : bât. C6 -RdC

Obligatoire

Code: OP3902-41

Semester: 9

Lecture: 10 Hours

Directed studies:

Language: French

Coefficient: 4

ECTS: 1

Instructor(s):

Guillaume Delaplace

Learning outcomes:

Students will be able:

- To distinguish different types of rheological behavior of liquid (Newtonian or not): purely viscous

fluids (shear thinning, yield stress, shear thickening), time-dependent fluid (thixotropic), with elastic

properties (viscoelastic),

- To implement adequate rheological tests to identify the rheological behaviour of unknown products.

- To take into account the rheological properties to model transfers (flow, heat and mass) in

continuous and discontinuous processes

Prerequisite:

Licence chemistry or physical

Contents:

1 Definition - fluid/solid - Newtonian and Non Newtonian - main problems related to non-newtonian

behaviour in chemical industry - rheology goal: a science to better identify the flow of the complex

fluid and associated transfer

2. Terminology standard for simple shear tests used in rheology - laminar shear movement - velocity

gradient, shear rate, shear stress, apparent viscosity - units, order of magnitude, dependent and the

pressure - viscosity, specific, intrinsic, dynamic...

3 Classification of rheological behaviour with pure shear tests: purely viscous fluids (shear thinning,

yield stress, shear thickening), time-dependent fluid (thixotropic), with elastic properties (viscoelastic),

4. Models typically used to describe the rheological behaviour of fluids

5. Devices for measuring the rheological properties - rheometer in steady mode- rheometer in transient

mode - oscillating tests

6. Interaction rheology - Processes - Velocity profile (friction in ducts and in vessel) , Residence time

distribution, heat transfer performances

7 Methods of modelling of transfers in real systems (batch and continuous) - Determination and use of

dimensionless numbers associated to rheological properties - concept of Metzner and Reed - concept

of Metzner and Otto


Media: Poly / slide show

Bibliographical references:Poly de Mécanique des fluides non-newtoniens – Initiation à la rhéologie,

Guy Couarraze et Jean-Louis Grossiord, 3ième Editions, Editions TEC&DOC, 2000 Mécanique des fluides

appliquée, Régis JOULIE, Edition ellipses, 1998 –Mécanique et rhéologie des fluides en Génie chimique,

N. MIDOUX, Editions TEC&DOC -Lavoisier, 1993 - Delaplace G , Guerin R (2006) Mélange des produits

pâteux – Caractéristiques d’un système agité (eds) les Techniques de l’Ingénieur [F 3 350], Traité

Opérations unitaires - Génie de la réaction chimiques, 1-20

Publications of Delaplace et al. on rheology aspects in various chemical engineering journal

Assessment: test 1 Hour with documents and Calculator on applied problem

Remarks:

CI 3Y



MODULE : PROCESS OF THE FORMULATION ENGINEERING

SUBJECT:

MIXING: CHEMICAL ENGINEERING

Coordinator:


lille.fr

Tél 03 20 33 63 64

Office: bât. C6 R de C

Obligatoire

Code: OP3902-42

Semester: 9

Lecture: 10 Hours

Directed studies:

Language: French

Coefficient: 4

ECTS: 1

Instructor(s):

Delaplace Guillaume

Learning outcomes:

Students will be able: - to understand the major importance of the mixing operation in industry and the

aims of this operation to accelerate transport phenomena - to design adequate mixing equipments for

various media (solid/liquid, liquid, liquid/liquid, gas/liquid, solid/solid) - to understand how determining

predictive process relationship for controlling batch output - to understand scale up problem and rules

Prerequisite:

Introduction to rheology

Contents:

1. Introduction: the difficulties to design accurately a mixing operation

2. Reminder: Classification of fluid according to their rheological behavior.

3. Main goals of mixing operations in relation with physical properties of media

4. Technical aspects – various flows induced by impellers and design of a mixing equipment.

5. Analysis of transport phenomena in agitated tank: theory of similarity and dimensional analysis

6 Example: determination of process relationships for various mixing systems: power consumption,

mixing time, heat and mass transfer with Newtonian liquid

7. Tools to characterize mixing operation: CFD and velocimeter (LDA, PIV…).

8. scale up

9. Impact of rheological behavior on the mixing process.

10.Process relationships in agitated tank for dispersed systems (S/L, L/L, G/L)


Media: Poly & slideshow


Thesis Henri Poincaré university Nancy I 1998 - Guillaume Delaplace - Agitation de fluides fortement

visqueux, Newtoniens ou non, par des agitateurs de proximité types ancre et rubans hélicoïdaux.

Delaplace G , Guerin R (2006) Mélange des produits pâteux – Caractéristiques d’un système agité (eds)

les Techniques de l’Ingénieur [F 3 350], Traité Opérations unitaires - Génie de la réaction chimiques, 1-

20 Delaplace G, Guerin R, (2006) Mélange des produits pâteux – Performances des agitateurs (eds) les

Techniques de l’Ingénieur [F 3 352], Traité Opérations unitaires - Génie de la réaction chimiques , 1-10

Jeantet Romain, Brulé Gérard, Delaplace Guillaume 2011 Génie Des Procédés Appliques A l'Industrie

Laitiere Editeur : Tec & Doc, 196 pages ISBN : 978-2-7430-1359-1

Publications of Delaplace et al. on mixing topic in various chemical engineering journal

Assessment: Test 1 H with documents and Calculator: assessment of expertise

Remarks:

CI 3Y



MODULE : EXPERIMENTAL PRACTICES

SUBJECT:

FORMULATION CHEMISTRY

Coordinator:


lille.fr

Tél +33(0)3 20 33 63 64

Building C6

Semi-optional

Code: OP3902-51

Semester: 9

Lecture:


Language: French

Coefficient: 4

ECTS: 1

Instructor(s):

Christel Pierlot

[email protected]

Tél : +33(0) 320 33 63 65

Building C6, Ground floor-

Office 21

Learning outcomes:

To give practical notions necessary to design, prepare and characterize complex mixtures encountered

in formulation and specialties industries.

Prerequisite:

Contents: classical formulation courses

Contents:

Aqueous micellar solutions

Emulsion Formulation

Emulsion and phase inversion temperature (PIT)

Formulation of a white acrylic paint

Formulation of an colored acrylic paint

Colored cement

Microemulsion and theory of HLD (Hypophilic Lipophilic Deviation)

Color measurement and design of experiments

Formulation of lipsticks

Rheology, texturing agents xanthan and caroub gum


Media: Distributed practical works fascicules

Bibliographical references: Techniques de l'ingénieur : Formulation - Présentation générale, Jean-Marie

AUBRY, Gilbert SCHORSCH, J2110 ( 1999).

Assessment: Distributed practical works fascicules to be completed

Remarks:

CI 3Y




MODULE : PRACTICAL STUDIES

SUBJECT:

PHYSICO-CHEMISTRY OFOLYMERS

Coordinator:


lille.fr

Tél +33(0)3 20 33 63 64

Building C6

Semi-optional

Code: OP3902-52

Semester: 9

Lecture: 9 Hours

Directed studies:

Language: French

Coefficient: 4

ECTS: 1

Instructor(s):

Frédéric CAZAUX

Frederic.cazaux@ensc-

lille.fr/+33(0)3 20 43 43

40/Building C6 -office 120

Learning outcomes:

To learn to manipulate tools allowing to characterize covers with paint: thickness, adhesion, shine,

color, covering power, stripe.

To know how to determine a Minimal Film Formation Temperature (MFFT) using a specific equipment.

To approach the rheology of paints.

To characterize paints by ThermoGravimetric Analysis.

Prerequisite:

Courts on the "formulation of paints and varnish" of 3rd year

Contents:

2 practicals by student:

- Rheologic characterization of a paint

- Determination of the Minimal Film Formation Temperature (MFFT) of a latex

- Characterization of covers with paint: thickness, adhesion, shine, color, covering power, stripe, …

- Characterization of a paint by ThermoGravimetric Analysis


Media: Duplicated lecture note of practical class


Assessment: A report by practical

Remarks:

CI 3Y



mailto:[email protected]/+33(0)3%2020%2043%2043%2040/Building%20C6



MODULE : EXPERIMENTAL PRACTICES

SUBJECT:

COLLOIDAL PHYSICAL AND MICROFLUIDIC CHEMISTRY

Coordinator:


lille.fr

Tél +33(0)3 20 33 63 64

Building C6

Semi-optional

Code: OP3902-53

Semester: 9

Lecture:


Language: French

Coefficient: 4

ECTS: 1

Instructor(s):

Valérie Molinier

[email protected]

Tél : +33(0)3-20-33-63-66

Christel Pierlot

[email protected]

Tél : +33(0)3-20-33-63-65

Building C6, ground floor

Learning outcomes:

Knowing how to use different devices in the formulation industry: tensiometer, laser particle size

analyzer, zetameter, device for stability of emulsions and suspensions measurements.

Analysis of the measured physicochemical data with these devices (critical micellar concentration,

particle size, stability ...).

Understand the complementarity of these analyzes and the link with the formulated

product (appearance, viscosity ...)

Prerequisite:

Contents:

Practical works of:

Molecular chemistry and formulation (ENSCL-S8)

Formulation chemistry (ENSCL-S9)

Contents:

The following operations will be performed:

Measurement of surface tension or interfacial using tensiometers (drop profile, ring,

plate, rotating drop and in dynamic mode).

Measurement of contact angle (advancing and receding)

Measure of the stability of an emulsion by transmission or scattering of light

Size measurement by laser granulometry, dynamic light scattering (DLS)

Zeta potential measurement

An important part will be devoted to analyzing the results


Media: Practical works fascicle


Assessment: Submission of a report (or / and) Oral presentation

Remarks:

CI 3Y





MODULE : BEHAVIOUR OF MATERIALS

SUBJECT:

RELIABILITY AND DAMAGE OF MATERIALS

Coordinator:

Jean-Bernard VOGT


lille.fr

+33 (0)3 20 43 40 35


Semi-optional

Code: OP3903-11

Semester: 9

Lecture: 20 Hours

Directed studies:


Coefficient: 6

ECTS:

Instructor(s):

Jean-Bernard VOGT

Learning outcomes:

The objective of the lecture is to identify and to understand damage mechanisms of structural

materials (especially those employed in the chemical industry) that result from mechanical

solicitations and from environmental effect.

From this knowledge, the students will be able to run industrial plants with safety conditions or

will be able to conduct fracture and corrosion analysis.

Prerequisite:

Metallurgy, mechanical properties, corrosion, analytical chemistry

Contents:

influence of temperature and stress on the different kind of fracture (monotonic loading): cleavage, ductile rupture, creep type rupture, ruptures maps

fatigue fracture: initiation and propagation; stress response to strain cycling, fatigue resistance diagrams , dislocations structures,

extrusions-intrusions and microcrack initiation, classification and behaviour of short

cracks , long crack propagation, Crack growth rate regimes, crack tip plasticity , fatigue

crack closure

Environmentally-assisted fracture mechanisms: liquid metal embrittlement, hydrogen

embrittlement, stress corrosion cracking, corrosion – fatigue

Wear: erosion, abrasion, adhesion Non destructive evaluation




Mechanical behaviour of materials, Thomas H. Courtney, McGraw-Hill Publishing Company (1990)

Stress-Corrosion cracking : materials performance and evaluation, Russel H. Jones, ASM International (1992)

Solution to Hydrogen Attack in Steels, P.F. Timmins, ASM International (1997) Fatigue of Materials, S. Suresh, Cambridge University Press (1991)

Assessment:

Joint written exam with metallic alloys, all documents permitted, 2h

Remarks:

CI 3Y



MODULE : BEHAVIOUR OF MATERIALS

SUBJECT:

METALLIC ALLOYS

Coordinator:

Jean-Bernard VOGT


lille.fr

+33 (0)3 20 43 40 35


Semi-optional

Code: OP3903-21

Semester: 9

Lecture: 20 Hours

Directed studies:


Coefficient: 6

ECTS:

Instructor(s):

Jean-Bernard VOGT

Learning outcomes:

The objective of the lecture is to identify the main families of metallic alloys, monolithic or assembled, which exhibit a high resistance to mechanical loading and to corrosion. The student will be able to optimize the choice of a material regarding the application in the field of chemical industry, energy industry, transportation, bio medical …. This unit is in good interaction with the subject “Reliability and damage mechanisms of engineering

materials”

Prerequisite:

Contents: Metallurgy, mechanical properties, corrosion, analytical chemistry

Contents:

The lecture comprises two parts.

The first part is devoted the main families of metallic alloys resistant to corrosion and stresses:

Stainless steels Nickel alloys Zirconium alloys Shape memory alloys Aluminium alloys

The second part deals with the concept of multimaterials which consists in assembling materials

at different scales:

Multiphased steels

Composites materials

Welding

Metallic foam

Cladding



Bibliographical references: Les aciers inoxydables, P. Lacombe, B. Baroux, G. Béranger, Les éditions de physique (1990)

Le zirconium, G. Béranger, P. Lacombe, R. Tricot, Les éditions de physique (1990)

Matériaux industriels-matériaux métalliques, M. Colombié et coll., Dunod (2000)

Assessment:

Joint written exam with reliability and damage mechanism of structural alloys, all documents

permitted, 2h

Remarks:

CI 3Y



MODULE : MATERIALS SOLUTIONS

SUBJECT:

POWDER TECHNOLOGY AND SHAPING

Coordinator:

Jean-Bernard VOGT


lille.fr

+33 (0)3 20 43 40 35


Obligatoire

Code: OP3903-22

Semester: 9

Lecture: 20 Hours

Directed studies:


Coefficient: 6

ECTS: 2

Instructor(s):

Nouria Fatah

Learning outcomes:

The lectures on powder technology and coating within the “Ecole Nationale Supérieure de Chimie de Lille” covers the study of the physical properties: theory and the measurement techniques on sampling, porosity, real and apparent densities, particle size analysis (technique of diffraction and diffusion, image processing, sieving), definition of size and average diameters of particles, specific surface area, the shape factor, the phenomenon of agglomeration and flow behaviour in the system and their impact on the conception and the calculation of coating properties.

This course treats cohesive and non cohesive powders by showing the importance of interaction forces (Van Der Waals, electrostatic and capillary forces), the influence of the phenomenon of agglomeration, distribution of the strain within a powder and the different tests measurements of the powders flows properties such as the shearing cell, the tapping, the angle of slope, the angle of repose, the floodability and the consolidation.

This course presents the techniques and development of coating technology according to four systems: agitation, dispersion, consolidation and thermal system. The processes like the mixing granulator, spray-drying, prilling, sintering, mécanosynthèse and mécanofusion will be studied.

The teaching of the powders must be accompanied by selection of problems with numerical

calculations is proposed to illustrate the importance of the choice of the coating process and powder

technology.

Prerequisite:

heat transfer, mass transfer, fluids mechanics, solids physicals

Contents:

- Introduction: Particle technology - Particle Characterization and measurement - Fondamental properties of particle - Coating technology: objectives and products forms - Process and equipment - Applications


Media: copy of slides presentation


M. RHODES, « PRINCIPLES OF POWDER TECHNOLOGY », John Wiley and Sons, 1990

Assessment: written exam

Remarks:

CI 3Y



MODULE : SOLUTIONS MATERIALS

SUBJECT:

SURFACE TREATMENT

Coordinator:

Jean-Bernard VOGT


lille.fr

+33 (0)3 20 43 40 35


Semi-optional

Code: OP3903-23

Semester: 9

Lecture: 15 Hours

Directed studies:


Coefficient: 5

ECTS: 2

Instructor(s):

Charlotte Becquart


lille.fr, Building C6. Office 217

Tel +33(0)3 20 43 49 44

Learning outcomes:

At the end of the module, the students should have a good knowledge of the physical basis as well the technologies used in the different surface treatments that exist. Prerequisite:

2nd

year lectures in material science, in particular, the corrosion lecture

Contents: The purpose of this course is introducing the students to the various methods, physical,

mechanical, or electrochemical, which can be used to modify a materials’ surface. Most of the time,

these treatments aim at protecting the material from an external attack, however they can have other

purposes : increase wear, erosion or friction resistance, electrical properties modifications, optical

properties modifications...In a first part, the course presents what is a surface, which processes can be

responsible for its degradation, which methods can be used to improve the surface properties, what

are pre-treatments, what are the methods which can be used to characterize the surface.

In a second part, some of the most commonly used processes are studied in more details : Physical

Vapour Deposition (PVD) and Chemical Vapour Deposition (CVD), thermochemical treatments,

galvanization, ion Implantation, mechanical treatments ... This second part is done in the form of oral

reports prepared by the students from lecture material given by the instructor.


Media: copy of the slides

Bibliographical references: 1/ -Y. Adda, J.M. Dupouy, J. Philibert et Y. Quéré, Eléments de Métallurgie

Physique, Vol.6, INSTN, CEA, collection enseignement 2/ -S. Audisio, M. Cailler, A. Galerie et H. Mazille,

Traitements de Surface et Protection contre la Corrosion, Ecole d'été, Aussois 1987, les éditions de

physique. 3/ -Manuel des traitements de surface à l'usage des bureaux d'études, Club des traitements

de surface, CETIM. 4/ -J. Barralis et G. Maeder, Métallurgie, Tome 2: alliages ferreux, ENSAM (1983),

Editions communications actives, ISBN 2 85932 004. 5 / -Groupe de recherches sur l'usure des

matériaux industriels, Organisation de Coopération et de Développements Economiques, Glossaire des

termes et définitions dans le domaine du frottement, de l'usure et de la lubrification (tribologie). 6/ Le

livre de l'acier, éditeurs Gérard Béranger, Guy Henry, Germain Sanz (1994) 7/ -Principes de base du

traitement thermique, Pyc édition, Publications Yves Colombot. 8/ -Advances of surface treatments,

Proceedings of the AST World Conference Advances in Surface Treatments and Surface finishing (Paris

1986), A. Niku-Lari director, volume 5, Pergamon Press 9/ Surface Treatments for Improved

Performance and Properties, Edited by J.J. Burje and V. Weiss, Plenum Press, New York and London

(1982) 10/ -Friction and Wear, A.D. Sarkar, Academic Press, a Subsidiary of Harcourt Brace Jovanovitch,

Publishers, London . New York . Toronto . Sydney . San Fransisco (1980) 11/ -Tribology: Principles and

Design Applications, R. D. Arnell, P.B. Davies, J. Halling and T.L. Whomes, Published by Macmillan

Education Ltd (1991) 12/ -Surface Engineering, Edited by S.A. Meguid, Elsevier Applied Science, London

and New York (1990) 13/ -Théorie et pratique industrielle du frottement, J.J. Caubet, Technip Paris,

Dunod Paris (1964) 14/ -Matériaux : propriétés et applications, M.F. Ashby et D.R. Jones, Dunod Paris

1996 15/ -Articles divers dans "Traitement Thermique", "Galvano-Organo-Traitement de Surface",

"News on Coatings and Corrosion", "Annual Review of Material Science", "Journal of Metals", "MRS

Bulletin". 16/ -Les Aciers, Ben Simon, Pyc-édition, cours professé au C.E.S.T.O 17/ -Principles of the

surface treatments of steels, C.R. Brooks, Technomic publishing Co. Inc. Lancaster Basel

Assessment: The students will prepare a one hour lecture on one of the surface treatments by groups

of 2 and with documents provided by the instructorer

Remarks:

CI 3Y





MODULE : SOLUTIONS MATERIALS

SUBJECT:

GLASSES

Coordinator:

Jean Bernard Vogt

jean-bernard.vogt@ensc-

lille.fr

Phone : (+33) 03 20 43 40 35

Building C6 – room 223

Semi-optional

Code: OP3903-24

Semester: 9

Lecture: 10 Hours

Directed studies:

Language: French

Coefficient:

ECTS:

Instructor(s):

Nathalie TANCRET

[email protected]

Phone : (+33) 03 20 33 64 35

Learning outcomes:

Know the glassy state, the chemical compounds capable of forming a glass and the rules governing the formation.

Know the role of modifier ions, in particular, the “mixed-alkali effect” and its impact on the glass properties: viscosity, thermal expansion coefficient, conductivity.

Know to look for information on a topic related to the glass industry, synthesize and report to a non-specialist audience.

Prerequisite:

Basics of Inorganic Chemistry, S7 course "Introduction to Materials", Part glass and ceramics, S8 course

"ceramics and glass" part on glasses, Notions of physical properties, Know how to conduct a

bibliographic research.

Contents:

The aim of this course is to deepen the notions viewed in the course "ceramics and glass" (S8), only the

part related to glasses. This teaching is divided into two parts:

1. a first in authoritarian pedagogy, provided by the teacher, which outlines the glassy state, formation,

why and how, the role of modifying oxides and their influence on the physical properties of the

manufactured glass.

2. a second part, participatory pedagogy, conducted by the students themselves in the form of

presentations, 1/2 hour group on a subject of their choice among the various concrete problems

related to the field of glass: the special role boron and its future replacement by other ions (REACH),

bubble problem in the manufacturing process, reducing emissions of pollutants out of glass factory

chimneys, forming, cutting of flat glass, ...



Le verre, science et technologie, James Barton et Claude Guillemet, EDP Sciences (Les Ulis, 2005)

Introduction to glass science and technology, 2nd edition, James E. Shelby, The Royal Society of Chemistry (RSC) (Cambridge, 2009)

Assessment: Oral presentation in groups of 3 students, based on a summary of real cases

Remarks:

CI 3Y




MODULE : METHODS OF ANALYSIS

SUBJECT:

NUMERICAL TOOL FOR MATERIAL SELECTION

Coordinator:

Jean-Bernard VOGT


lille.fr

+33 (0)3 20 43 40 35


Semi-optional

Code: OP3903-31

Semester: 9

Lecture: 4 Hours



Coefficient: 3

ECTS:

Instructor(s):

Charlotte Becquart


lille.fr, Building C6. Office 217

Tel +33(0)3 20 43 49 44

Learning outcomes:

At the end of the class, the student should know how to write specifications as well as how to use CES

to chose the appropriate material for a given use.

Prerequisite:

Materials science, mechanical properties, reliability of materials, corrosion

Contents: the purpose of this lecture is to show the students how the software CES can be used to assist them in selecting a material for a given application.

-Introduction: designing a component implies 3 problems which are not independent: (i) selecting the materials, (ii) selecting the shape, and (iii) selecting the process to make the component. Writing the specifications is difficult as some criteria are hard to quantify (aesthetics …) and as there exists an hyper choice of materials and processes. - Materials: the four families

- Properties

- Shaping processes - Material indices.

What is a material index ? How do we determine a material index? case studies (CES selector)


Media: copy of the slides


“Materials selection in Mechanical Design”, M.F. Ashby, Butterworth et Heinemann

“Matériaux : propriétés et applications”, M.F. Ashby et D.R. Jones, Dunod Paris 1996

Assessment: written report

Remarks:

CI 3Y






SUBJECT:

PRACTICAL USE OF THE METHOD OF FINITE ELEMENTS METHODS

Coordinator:

Jean-Bernard VOGT


lille.fr

+33 (0)3 20 43 40 35


Semi-optional

Code: OP3903-32

Semester: 9

Lecture: 10 Hours



Coefficient: 4

ECTS: 1

Instructor(s):

Jérémie BOUQUEREL

Maître de Conférences

[email protected]

+33(0)3.20.43.42.29

Learning outcomes:

The objective of the course is to describe the use of the Finite Element Method (FEM) when predicting the behaviour of a component. The student will learn how to solve a problem with the FEM technique and make use of a FEM based

software

Prerequisite:

General knowledge in physics and in materials science

Contents:

1- Introduction

Positioning the FEM method when simulating the components behaviour

Introducing to the main numerical tools used in the industry

2- Application example : solving a problem with the FEM technique (selecting the

correct laws, discretization, boundary conditions, nodal approximation, finite

element concept, numerical solving, post-processing)

3- Training - applications :

Use of a FEM based software (RDM6 / Abaqus®)

Determining the behaviour of a material submitted to thermo-mechanical

constraints


Media:


Introduction to Computational Plasticity, F. Dunne, N. Petrinic, Oxford University Press (2005)

Assessment:

Remarks:

No specific exam

CI 3Y





SUBJECT:

TECHNIQUES OF CONVENTIONAL ANALYSES

Coordinator:

Jean-Bernard VOGT


lille.fr

+33 (0)3 20 43 40 35


Semi-optional

Code: OP3903-32

Semester: 9

Lecture: 10 Hours


Language: French

Coefficient: 4

ECTS: 1

Instructor(s):

Jérémie BOUQUEREL

(contact), assistant

professor

Séverine BELLAYER,

research engineer

Anne-Sophie MAMEDE,

assistant professor

Learning outcomes:

• The objective of the course is to describe the modern investigation techniques of materials

microstructure.

• The student will be able to assign the most suitable tool to be used to solve a problem of

material identification

Prerequisite:

General knowledge in physics, in analytical chemistry, in crystallography and in materials

Contents:

At first, physical phenomenons which are on the basis of the techniques are explained as well as a

description of their experimental procedure.

Then, technical sessions are organized in front of each equipment where the student can appreciate

the technique with an expert. The following techniques are considered:

Scanning electron microscopy (SEM),

Energy Dispersive X-ray Spectroscopy (EDX)

Electron Back Scattered diffraction (EBSD)

Transmission Electron Microscopy (TEM)

Atomic force Microscopy (AFM)

X-Ray Photoelectron Spectroscopy (XPS).

The technical sessions take place in laboratories of ENSCL, UCCS and UMET, for which the expertise is

largely recognized.

UCCS : Unité de Catalyse et Chimie du Solide

UMET : Unité Matériaux Et Transformations


Media:


Méthodes usuelles de caractérisation des surfaces, D. David, R. Caplain, Eyrolles (1988)

Microcaractérisation des solides, M. Ammou, CRAM-LPSES-CNRS (1989) Assessment:

Remarks:

No specific exam

CI 3Y



MODULE : QUALITY, HEALTH, SAFETY

SUBJECT:

SUSTAINABLE DEVELOPMENT

Coordinator:


Jean-claude.van-

[email protected]

Tel : 06 82 80 89 33

Compulsory

Code: FE3901-1

Semester: 9

Lecture: 10 Hours

Directed studies:

Language: French

Coefficient: 1

ECTS:

Instructor(s):


Learning outcomes:

The course has for objectives 1) to explain how the principles of sustainable development can be implemented in the industrial world and 2) to show the benefits of this implementation. At the end of the course, students will understand that sustainable development can be a mainspring

of growth for the industry, and will be able to define the outlines of a sustainable development policy

at the enterprise level.

Prerequisite:

The only prerequisite is to have mastered the concepts presented in the first year course on the fundamentals and indicators of sustainable development.

Contents:

The course is made of four parts

Reminder on sustainable development principles,

Sustainable development: a mainspring of growth for the industry,

Examples of application of sustainable development principles in industry,

Two ambitious concepts "zero CO2" factory and "ecofriendly" factory.


Support :

Regular reading of a daily newspaper or a societal magazine..

Bibliographical references :

J. C. van Duysen et Stéphanie Jumel, le Développement Durable, éditions l’Hamarttan, 2008. PME et développement durable :

http://ressources-rse.org/assets/files/1_RSE/1_1OUVRAGES/guide_pme_DD%20CCI.pdf

Guide du Développement Durable : http://publications.medef.com/guide/Entreprises-et-DD.pdf

Assessment method : assessment is based on mini-projects conducted in groups of two or three

students on a theme related to sustainable development. Each group gives a 4 to 5 page report which is

graded.

Remarks:

CI 3Y

http://ressources-rse.org/assets/files/1_RSE/1_1OUVRAGES/guide_pme_DD%20CCI.pdf

http://publications.medef.com/guide/Entreprises-et-DD.pdf

MODULE : QUALITY, HEALTH, SAFETY

SUBJECT:

INDUSTRIAL SECURITY

Coordinator:

[email protected]

/ +33(0)3.20.43.48.88/ office

N°8

Compulsory

Code: FE3901-2

Semester: 9

Lecture: 20 Hours

Directed studies:

Language: French

Coefficient:

ECTS:

Instructor(s):

[email protected]

/ +33(0)3.20.43.48.88/

officeN°8

+ External speakers who are

experts in different fields of

safety of the industry - As an

example, IRSN - Auchan -

Univ. Haute Alsace - CREPIM -

Gendarmerie have given talks

in 2011/2012

Learning outcomes:

To learn safety applied to the industry and to learn how to quantify hazards

Prerequisite:

Chemical engineering at the undergraduate level Contents:

Survey of safety in the industry

Hazard process

Proportioning of safety valve

Atmospheric dispersion

Combustions – explosions

Dust explosions

Safety Controls for Chemical Reaction Hazards

Domino effect


Media: Powerpoint

Bibliographical references: Sécurité des procédés chimiques : Connaissances de base et méthode

d'analyse de risques by A. Laurent

Assessment: Project

Remarks:

CI 3Y



MODULE : ENGLISH

SUBJECT:

ENGLISH

Coordinator:

Anne GUEGAND

Abdelamar BENAÏSSA

office 965

Tel:+33(0)320336060

Compulsory

Code: LV3901

Semester: 9

Lecture:


Language: English

Coefficient: 6

ECTS:

Instructor(s):

Anne GUEGAND

Abdelamar BENAÏSSA

Learning outcomes:

Language tuition at the ENSCL has a double objective:





Contents:

Professional Presentation Skills (presenting one's company, presenting a project, presenting one's research…)



Assessment: Continuous language assessment is carried out through one written test and a

presentation in English.

Remarks:


CI 3Y

MODULE : GERMAN

SUBJECT:

GERMAN

Coordinator:

Beate WINKLER

[email protected]

Tel. +33(0)320336061

office 951

Compulsory

Code: LV3902

Semester: 9

Lecture:


Language: German

Coefficient: 6

ECTS:

Instructor(s):

Beate WINKLER

Monika BERTOUT

Learning outcomes:

Prerequisites:

All levels.


Progress in the four language skills, but especially in oral expression.


or in foreign companies) and to communicate in situations of everyday life.

Consolidation of knowledge of scientific and technical German in the field of chemistry

Contents:

Non-exhaustive list - all aspects are not always treated and some contents of CI 2Y may be continued. The company (continuation): business German; overview of companies in the various areas of chemistry.

Current news in the fields of chemistry, economy and politics - (mainly oral expression: presentations

and debates)


Media:




Assessment:

Continuous language assessment is carried out through one written test (two hours) and at least one

oral test divided into two parts (a presentation and an interactive part).

Remarks:

Students who started learning German in the first year of CI 1Y are strongly encouraged to confirm

their level by a certification in cooperation with the Goethe-Institute:

"Zertifikat Start 2" (level A2 of the CEFR).

CI 3Y


MODULE : SPANISH

SUBJECT:

SPANISH

Coordinator:

Larabi Hakima

Compulsory

Code: LV3906

Semester: 9

Lecture:


Language: Spanish

Coefficient: 6

ECTS:

Instructor(s):

Larabi Hakima

Learning outcomes:

Strengthening B2 level of the Frame Common reference European for Languages, preparation at C1

level. At the end of the third year, the student must have strung the level of the autonomous speaker.

Helping all students develop the condition skills they will need in professional situations (through


Contents:

Linguistic, scientific and cultural aspects:

- Oral comprehension: multimedia language laboratory or video sequence.

- Oral expression: simulations and role play activities, to assess a situation, writing report, professional

project; managing a team; job and apparitional interviews.

- L’entretien d’embauche (les métiers de la chimie…)

- Written comprehension: scientific or cultural texts.

- Written grammatical competences.

- Written expression (writing an informal or definite letter, a dialogue…)

- Approfondir les connaissances: organiser une campagne de sensibilisation sécurité/environnement…).


Media: Various (Newspaper articles, audio and video documents…).

Bibliographical references: Marco Común Europeo C1.

Assessment: Continuous language assesment is carried out through a written test, an interview and a

presentation in spanish.

Remarks:


CI 3Y

MODULE : JAPANESE

SUBJECT:

JAPANESE

Coordinator:

Jean-Luc RIGAL

[email protected]

Office 951

Optional

Code: LV3904

Semester: 9

Lecture:


Language: Japanese

Coefficient:

ECTS:

Instructor(s):


Hitomi KIMURA 3

Aki KIUCHI 1

Nozomu MIZUKAMI 2

Shoko MORITA 4 5


Maki TAMAOKI 1

Sachie WATANABE 2

Learning outcomes:

The main object of this course is to give basic communication tools to the students who intend to do

their first, second or/and third year industrial placements in Japan, but also to complete the curriculum

of future managers of a branch of industry which has many relations with Japan.

Contents:

One third of the course is devoted to civilization and two thirds to language. Because of the very

particular writing system of Japanese, in which two syllabaries and at least 2000 ideograms are

combined, reading and writing are given the same importance as oral work. In addition to the learning

and systematic use of the two syllabaries, strong emphasis is put on the logic of ideograms, the

objective being, through the study of a few hundreds of them, to facilitate the subsequent assimilation

of those - much more numerous - which are necessary to everyday life.

Level 3: In particular, Nihongo shoho 14-21, Bushu 101-214 , and a tale from the Meisaku anime

ehon series.


Media: Minna no nihongo, Nihongo shoho (1, 2, 3), Nihongo chûkyû, Kana nyûmon (hiragana 1)

(katakana 2), Nelson Kan’ei jiten (2, 3)

Bibliographical references: Nihon etoki jiten 1-16 (JTB), Nihongo notes 1-5 (The Japan Times),

Situational Japanese 1-5 (The Japan Times)

Assessment: oral and written exams, continuous assessment

Remarks:

The course is divided into 5 levels, and not according to the three years of the curriculum. As a matter

of fact, if Level I is mainly attended by first year students, Level II by second year students and Level III

by third year students, some students start the study of Japanese in their second/third year, whereas

other students - especially those who come from the "CPI" - may have been studying Japanese for two

years or more when they start their engineering studies.

Prerequisites: None, other than the desire to learn Japanese (WRITTEN INCLUDED)

CI 3Y

programme of study - ensc-lille.fr · michel fontanille, yves gnanou dunod, 2002 isbn 2100039822 -...

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