proceedings of october 4-6,2000 u.s.a. … · proceedings of october 4-6,2000 orlando, florida,...

PROCEEDINGS OF

October 4-6,2000Orlando, Florida, U.S.A.

SPONSORED BY

Editor: Keith J. KocibaThe Lubrizol Corporation

Assistant Editor: Tara Kirchner-JeanThe Lubrizol Corporation

UB/TIB Hannover 89121 866 912

TWENTY-EIGHTH CONFERENCEOF THE

NORTH AMERICAN THERMAL ANALYSISSOCIETY

OCTOBER 4 - 6,2000Sheraton World Resort, Orlando, Florida

WEDNESDAY MORNINGOct. 4,2000

OPENING SESSION

ARCTIC; David Jones, Presiding

8:00 Opening Remarks; Alan Riga

8:10 Mettler Award 2000, Jon Foreman presenting to

Professor Michael ReadingLoughborough University

1. Mettler Award 2000 lecture: Sample Determined andModulated Temperature Control, Micro-Thermal Methods:Some Observations on the Past and Proposals for the Future;p. 25

PLENARY LECTURE

2. 8:50 The Role of Thermal Methods in the Characterisation ofPyrotechnic Systems; Professor E.L. Charsley, University ofHuddersfield; p. 26

9:30 Break

CHARACTERIZATION OF POLYMERS BY THERMAL ANALYSISAND RHEOLOGY

CORAL A; Larry Judovits, Presiding

3. 10:00 High Performance DSC-High Scanning Rate DSC:Applications to Polymers; (Invited Lecturer) ProfessorVincent B.F. Mathot, DSM Research; p. 32

4. 10:40 Generalized and Localized Heating in Micro-ThermalAnalysis; Reading M., D. Price, T. Lever; p. 38

5. 11:00 Surface Finish of Injection Molded Materials by Micro-Thermal Analysis; Provotas, M.S.; p. 39

6. 11:20 Analysis of Glass-Filled Polypropylene Using Micro-TA;Xie, W., B. Sisk, Z. Gao, W-P Pan; p. 45

7. 11:40 Problem Solving with Micro-Thermal Analysis; Lever, T.D. Price, M. Reading; p. 52

DAVID DOLLIMORE SYMPOSIUM ON PHARMACEUTICALAPPLICATIONS OF THERMAL ANALYSIS

CORAL B; Poonam Aggarwal, Presiding

8. 10:00 Recent Advances in Pharmaceutical Thermal Analysis;(Invited Lecturer) Professor Duncan Craig, The Queen'sUniversity of Belfast; p. 53

9. 10:40 A Comparative Method for Developing Vapor PressureCurves Based on Evaporation Data Obtained from aSimultaneous TG-DTA Unit; Phang, P., D. Dollimore, S.Evans; p. 54

10. 11:00 Utilization of Differential Scanning Calorimetry forPharmaceutical Crystal Form Quantitation ; Vitez, I . ; p.60

11. 11:20 The Use of Benzoic Acid as a Calibration Material inThermal Analysis; Wright, S., P. Phang, D. Dollimore, K.Alexander; p. 61

12. 11:40 TG/TG/MS: Applications to Determination of ResidualMoisture in Pertussis Vaccine and other Freeze-DriedBiological Products; May, J., Alfred Del Grosso, Nora Etz,Roscoe Wheeler, Louis Rey; p. 67

SIMULTANEOUS AND COMBINED TECHNIQUES FOR MATERIALCHARACTERIZATION

CARRIBEAN C; Suk-Fai Lau, Presiding

13. 10:00 Thermal Characterization of Ni-Based Super-Alloy;Suwardie, J., R. Artiaga, J. Mier; p. 75

14. 10:20 Investigation of the Thermal Decomposition of TwoAdvanced Materials by TG-DTA-MS Coupling Technique;Lu C-W., Y-f. Zhang, T-G. Xi, Y-X. Chen, X-L. Zhou, L-M.Lu, M. Schubnell; p. 80

15. 10:40 Characterization of Polymer Coatings on Silicon Wafers byUsing TG/FTIR/MS; Chen, D. ; p. 87

16. 11:00 Characterization of the Ceramic Coating of Iron with TiNand TiN by Temperature ModulatedThermomagnetometry, Dilatometry and DTA; Myslinski,P., A. Wasik, P. Kamasa, M. Pyda, B. Wunderlich; p. 88

17. 11:20 Investigation of Thermal Expansion Characteristics of theComposite Material BNf-SiO2 by PRD and XRD; Lu C-W.,Y-X Chen, X-L. Zhou, M-D. Chen, T-G. Xi; p. 94

18. 11:40 The Use of Simultaneous and Combined Techniques for thePreparation and Characterization of Multi Metal OxideCeramics; Mullens, J., D. Mondelaers, R. Nouwen, M.VanBael, G. Vanhoyland, K. VanWerde, L. Van Poucke; p. 95

THERMAL ANALYSIS OF EXPLOSIVES, PROPELLANTS ANDPYROTECHNICS

CARRIBEAN B; Jim Pickard, Presiding

19. 10:00 Critical Ignition Temperature; Pickard, J . ; p. 103

20. 10:20 Isoconversional Kinetic Analysis of the ThermalDecomposition of the High Explosive NTO; Long, G., B.Brems, C. Wight; p. 109

21. 10:40 Thermal Characterization of Passivated AluminiumNanopowder; Jones, D., P. Brousseau, R. Fouchard, A.M.Turcotte, Q. Kwok, P. Lightfoot; p. 115

22. 11:00 Thermal Decomposition of Composite HMX/HTPBPropellant; Peterson, J., C. Wight; p. 121

23. 11:20 Characterization of a Microencapsulated Marking Agentfor Explosives by TGA; Mintz, K.; p. 127

24. 11:40 A Competition Between Vaporization and Liquid StateDecomposition for the High Explosive RDX; Long, G., S.Vyazovkin, G. Brems, C. Wight; p. 133

12:00 Lunch

WEDNESDAY AFTERNOONOct. 4,2000

25. 1:30 Mettler Award 1999, ARCTIC, Jon Foreman presenting to

Professor Stephen Z.D. ChengThe University of Akron

The Role of Metastable States in Polymers: Concepts, Principles andExperimental Observations; no abstract available

CHARACTERIZATION OF POLYMERS BY THERMAL ANALYSISANDRHEOLOGY


26. 2:10 Phase Transformations in Nano-Confined Environments;Cheng, S., L. Zhu, Q. Ge, R. Quirk, E. Thomas, B. Hisao, F.Yeh, B. Lotz; p. 139

27. 2:30 High Quality Heat Capacity Measurements at DifferentFrequencies of Temperature Modulation; Wunderlich, B. ;p. 140

28. 2:50 Dynamics of Reversible Melting Revealed from FrequencyDependent Heat Capacity; Schick, C , A. Wurm, S.Adamovsky, Marand, H.; p. 146

29. 3:10 Verification of Crystallization and Crystal PerfectionProcesses Seen in PET by MDSC®; Thomas, L., S.Aubuchon; p. 152

30. 3:30 Enhanced Characterization of Polymeric Materials usingStep Scan DSC; Sichina, W., Cassel, R.; p. 158

31. 3:50 Ionic Aggregation Effect on the Crystallization Behavior ofIonomeric Systems; Gao, Y., N. Choudhury, N. Dutta, J.Matisons; p. 167

4:10 Break

32. 4:30 Characterization of Polymer Blends by MDSC®; Thomas,L., S. Aubuchon; p. 173

33. 4:50 Determination of Bound Rubber and Filler Distriubtion inElastomer Blends by Thermogravimetric Analysis;Woolard, C , McFadzean, B.; p. 179

34. 5:10 Thermal Transitions in the PVDF Observed by DRS, DSC,DMA and TSDC Techniques; Korzhenko, A., F. Beaume, B.Ernst; p. 185

35. 5:30 Structure-Property Relationships in High-Strain P (VDF-TrFE) Electrostrictors as Revealed by Thermal Analysis;Ramotowski, T., A. Amin, G. Kavarnos, R. Ting; p. 192

DAVD3 DOLLIMORE SYMPOSIUM ON PHARMACEUTICALAPPLICATIONS OF THERMAL ANALYSIS


36. 2:10 Freeze Drying Modelled by MDSC®; Aubuchon, S., L.Thomas; p. 198

37. 2:30 Characterization of Spray Dried and MicronisedSalbutamol Sulphate by Modulated Temperature DSC;Murphy, J., D. Craig, A. Coutts; p. 204

38. 2:50 Studies of Cimetidine Preformulated and Tablets for TGand DSC Coupled to the Photovisual System; Macedo, R.O., F. dos Santos Souza, Aragao, G, Veras, J.; p. 210

39. 3:10 Volatization, Evaporation and Vapor Pressure StudiesUsing a Thermobalance; Price, D. ; p. 216

40. 3:30 Thermal Analysis of the Evaporation of Compounds usedin Aromatherapy; Hazra, A., D. Dollimore, K. Alexander; p.222

3:50 Break

41. 4:10 Characterization of Pharmaceutical Materials usingThermal Analysis; Sichina, W.; p. 223

42. 4:30 Thermal Characterization of the Quercetin and RutinFlavonoids; da Costa, E., Filho, J., do Nascimento, T.,Macedo, R.O.; p. 231

43. 4:50 A TG- DTA Study of Sublimation of Nicotinic Acid;Menon, D., D. Dollimore, K. Alexander; p. 237

44. 5:10 New Enhancements in the Area of High ResolutionDifferential Scanning Calorimetry (DSC), Ferrara, J., V.Reddy, R. Byrne, N. Nakamura, R. Kinoshita; p. 240

POLYMER DEGRADATION BY THERMAL ANALYSIS

CARRIBEAN C; Bob Howell, Presiding

45. 2:10 Impact of the Incorporation of Functionalized AcrylateMonomers on the Thermal Stability of Vinylidene ChloridePolymers; Howell, B.A.; p. 241

46. 2:30 Use of a CCD Camera for Simultaneous DSC -Chemiluminescence and Multiple Sample PolymerDegradation Studies; Woo, L., C. Sandford, H. Blom, M.ling, S. Ding; p. 246

47. 2:50 The Utility of Kinetic Analysis hi the Determination ofReaction Mechanism; Howell, B.A.; p. 252

48. 3:10 Stabilizing Effect of Oxygen on Thermal Degradation ofPoly(methyl-methacrylate); Peterson, J., S. Vyazovkin, C.Wight; p. 256

49. 3:30 Kinetic Parameters of Polymer Degradation by SAPO-37;Femandes, V.J., A.S. Aranjo, G.J.T. Fernandes, J.R. Matos, M.Ionashiro; p. 262

50. 3:50 Thermal Decomposition of Cycloadducts ofVinylnaphthalenes with Electron-Deficient Dienophiles;Howell, B.A., J.J. Powers, D.B. Priddy; p. 263

4:10 Break

51. 4:30 Impact of Initiator Characteristics on the Thermal Stabilityof Vinylidene Chloride Copolymers; Howell, B.A.,DJE.Plaver, L.J. Hahnfield, S.M. Kling, M.L. Mounts; p. 269

52. 4:50 Interpretation of Isothermal TGA for Catalyst DopedPMMA films; Rdissi, A., S. Simon; p. 273

53. 5:10 Thermal Decomposition Characteristics of StructurallyDiverse Polystyrenes; Howell, B. A., Y. Cui, D.B. Priddy; p.279

54. 5:30 Thermal Stability of Vinylidene Chloride PolymersProduced by Suspension and Emulsion Techniques;Howell, B.A., D.E. Beyer,, D.E. Plaver, LJ. Hahnfield, S.M.Kling, M.L. Mounts; p. 283

THERMAL ANALYSIS OF EXPLOSIVES, PROPELLANTS ANDPYROTECHNICS

CARRIBEAN B; Jim Pickard, Presiding

55. 2:10 Thermal Decomposition of High Nitrogen EnergeticCompounds - Tetrazines; Oxley, J., J. Smith, J. Zhang, H.Chen; p. 287

56. 2:30 Kinetic Analysis of TA Data: Getting the Error Bars Right;Wight, C, S. Vyazovkin; p. 295

57. 2:50 Thermal Analysis of High Explosives Aged in the Stockpile;Stinecipher-Campbell, M., Garcia, D.; p. 301

58. 3:10 Thermal Properties of KDNBF, A Primer for Explosives;Jones, D., R. Fouchard, A.M. Turcotte, P. Lightfoot, Q. Kwok;p. 308

3:30 Break

HAZARD EVALUATION BY THERMOANALYTICAL METHODS

CARRIBEAN B; Ed Donoghue, Presiding

59. 3:50 Phenomenon of Autocatalysis in Decomposition ofEnergetic Chemicals; Chervin, S., G. Bodman; p. 314

60. 4:10 Thermal Analysis of Polymer Flammability; Lyon,R, R.Walters; p. 321

61. 4:30 DSC Hazard Evaluation of Thermally Unstable Materials;Blaine, R., G. Dallas, T. Kelly; p. 328

62. 4:50 Thermal Hazard Assessment of Emulsion Explosives;Jones, D., P. lightfoot, R. Fouchard, G. Chalmers, I. Alilovic;p. 334

63. 5:10 Introduction of the New DRC Differential ReactionCalorimeter; Le Parlouer, P., C. Mathonat, J.L. Daudon, X.Le Tacon; p. 340

64. 5:30 Understanding the Large Scale Chemistry of EthylDiazoacetate Via Reaction Calorimetry; Clark, J., A. Shah,J. Peterson; p. 346

WEDNESDAY EVENINGOct. 4,2000

POSTER SESSION, 6:00-7:30

ATLANTIC; David Jones, Presiding

PI Multi Frequency TMDSC Studies of Polymers - Benefits andLimitations, Merzlyakov, M., C. Schick; p. 352

P2 Thermal Decomposition Properties of Polymer Fibers, Lee, J., C.Hsu, K Cheng; p. 353

P3 A Study on the Thermal Behaviors of Uncaldnedand CaCO3 Mixture, Lee, J., C. Hsu, K. Cheng; p. 360

P4 Thermal Properties and Firing Characteristics of theZr/KCI04/Viton A Priming Compositions, Lee, J., C. Hsu, C-L.Chang; p. 367

P5 A Study on Devitrification and Nucleation of Calcium PhosphateGlass with SisN4 Additive, Lee, J., C. Hsu, K. Cheng; p. 375

P6 Thermal Properties and Self Life of HMX-HTPB Based Plastic-Bonded Explosives, Lee, J., C. Hsu; p. 383

P7 Use of Several Thermal Analysis Techniques to Study the Crackingof an NBR Insulator on the Booster Separation Motor (BSM) of theSpace Shuttle; Wingard, C ; p. 389

P8 Center for Thermal Analysis, Vyazovkin, S., Wight, C ; p. 396

P9 Applications of DSC and RADEX on Thermal Hazard Analysis -Examples on Cumene Hydroperoxide, Peng, D.J., Y.J. Yang, P.J.Wen, P.Y. Yeh, H.Y Hou and CM Shu; p. 397

P10 Emergency Relief System Design for A Reactor Contining PhthalicAnhydride, Shu, CM., K.H.Hu, P.J. Wen, P.Y Yeh, Y.J.Yang, H.Y.Hou, D.J. Peng; p. 398

P l l Thermal Decomposition of Cumene Hydroperoxide by IsothermalMicrocalorimeter, Hou, H.Y., CM. Shu, Y.S Duh, D.J. Peng, YJ.Yang; p. 399

P12 A New Instrument for Photo-Thermal Analysis, Foreman, J., M.Zemo; p. 400

P13 Thermal Analysis of Tobacco Using TG/DTG and DTA, Longanezi.T., M. Campos, C Mothe; p. 401

P14 Thermal Analysis of Granite and Marble Industry Residue toCeramic Material, Filho, H., H. Polivanov, Emilio Barroso, V.Almeida, C. Mothe; p. 406

P15 Thermal Properties of DMNB, A Detection Agent for Explosives,Jones, D., R. Fouchard, Q. Kwok, P. Lightfoot; p. 412

P16 Kinetic Study of Cashew Gum and Pine Gum by DSC, Araujo, C ,H. Mothe, C. Mothe; p. 418

P17 Using an Adiabatic Calorimeter to Separate Catalytic and Self-Decomposition Reactions for Hydrogen Peroxide in the Presence ofHydrochloric Acid; Y-J. Yang, W-J Ger, J-R Wang, W-H Lin, C MShu; p. 424

P18 A Study of the Evaporation of a Fragrance Component Using aSimultaneous TG-DTA Unit, Sorokina, T., K. Alexander, D.Dollimore; p. 425

P19 Thermal Characterization of Eutectic Explosives Containing HNIWYeh,T-F,H-PLiu; p. 431

P20 The Kinetics of Decomposition of Magnesium Carbonate HydroxideHydrate; N. Khan, D. Dollimore, K. Alexander; p. 432

P21 Thermal Penetration Times as a Nondestructive Measure ofOrientation, C. Chandler, N.E. Mathis, R.J. Samuel; p. 433

P22 Three Dimensional Homogeneity Characterization in CompositeMaterials, Nancy Mathis presented by Craig Dixon; p. 434

P23 Orientation and Position Dependant Thermal Conductivity, NancyMathis and Christina Chandler; p. 435

P24 Study of Protein Stability and Denaturation Kinetics by DifferentialScanning Calorimetry, Young, P., P. Phang, D. Dollimore, C. Schall;p. 436

P25 Power Modulated vs. Temperature Modulated TGA and DSC,Keith J. Kociba; p. 437

P26 THERMAL: A Global Interactive Forum for Thermal Analysis,Michael J. Rich; p. 438

P27 A Critical Examination of the Sugar Substitue Xylitol, Phang, P., P.Young, D. Dollimore; p. 439

™ l ^ t ^ ' ^ 1 ^ D S C Study of P h a s e Transformations inNickd-Titenmm Orthodontic Wires, Brantley, William A., M. Iijima,T.H. Grentzer, p. 440

P29 Influence of the Dying With Disper D he Thermal

P30 Isothermal Crystallization of Starch-Water Systems: ModulatedDifferential Scanning Calorimetry Study, De Meuter, P., H. Rahier,B. Van Mele; p. 447

P31 Frequency Dependent Heat Capacity in the Cure of Epoxy Resins,Van Assche, G., B. Van Mele, Y. Saruyama; p. 448

P32 Applications of Micro-TA to Composite Materials, Van Assche, G.,B. Van Mele; p. 449

P33 Phase Separation in Miscible PEO/PES Blends as Detected byModulated Temperature DSC, Swier, S., B. Van Mele, G. Dreezen,G. Groeninckx; p. 450

P34 Modulated Temperature DSC Study of the Kinetics of PhaseSeparation in Miscible PEO/PES Blends: Effect of MolecularWeight of PEO, Swier, S., R. Pieters, B. Van Mele; p. 451

P35 Type HI Demixing Behavior in PVME-Water as Studied byMTDSC, Swier, S., K. Van Durme, B. Van Mele; p. 452

P36 Thermal Techniques for the Characterisation of FerroelectricMaterials Prepared by Sol-Gel Synthesis, Mullens, J., M.K. VanBael, R. Nouwen, G. Vanhoyland, K. Van Werde, D. Mondelaers, D.Nelis, L.C. Van Poucke; p. 453

P37 Quantitative Method for Evolved Gas Analysis Using TG-MS,Takai, Y., K. Ishikiriyama, M. Todoki; p. 454

P38 A Stability Study of Drug Excipients and Their Effect on the DrugSalsalate Using Different Physical Methods; Shulga, O., D.Dollimore, D. Alexander, p. 455

P39 Thermal Properties of Liquid Crystalline Epoxies Cured WithAmines for Composite Applications; Huang, Hong-Wen, Wei-Fang Suand Wei-Ping Pan; p. 456

P40 Synthesis and Thermal Properties of Poly (Methyl Methacrylate)-Clay Hybrids; Hu, Jyh Ming, Wei-Ping Pan, George J Jiang; p. 457

P41 Thermal Properties of A High Refractive Index Epoxy ResinSystem; Fu, Ya-Ching, Wei-Fang Su and Wei-Ping Pan; p. 458

P42 Thermal Properties of Phthalic Anhydride and Phenolic ResinCured Rigid Rod Epoxy Resin; Lee, David Yin-Chung, Wei-Fang Suand Wei-Ping Pan; p. 459

A Thermal Analysis Study of the Dehydration of Epsom Salt; Khan,F., D. Dollimore, K.; p. 460

Comparison of Dolomite Decomposition Kinetics with RelatedCarbonates and the Effect of Procedural Variables on its KineticParameters; Samtani, M., D. Dollimore, K. Alexander, p. 465

Thermal Stability of Folic Acid and Associated Excipients; Vora, A.M. Samtani, D. Dollimore, K. Alexander; p. 470

A Study on the Thermal Decomposition Behaviors of PETN, RDX,HNS and HMX; Lee, J-S., Hsu, C-K., Chang, C-L.; p. 471

THURSDAY MORNING

Oct. 5, 2000

PLENARY LECTURE

ARCTIC; Don Burlett, Presiding

65. 8:00 Temperature-Modulated DSC: Applications andInterpretation; S.L. Simon, G. B. McKenna, Texas TechUniversity; p. 476

8:40 Break

CHARACTERIZATION OF POLYMERS BY THERMAL ANALYSIS

AND RHEOLOGY


66. 9:00 Analytic Rheology of Polymer Melts; (Invited Lecturer)Professor Ron Larson, University of Michigan; no abstractavailable

67. 9:40 Thermal Laser-Interferometric Creep Rate Spectroscopy:High Resolution Analysis of Relaxations in PolymericMaterials and Brittle Solids; Bershtein, V., N. PeschanskayaP. Yakushev; p. 482

10:00 OPEN

68. 10:20 Measuring the Fiber Shrinkage Using DMT A; Suwardie,J.;p. 488

10:40 Break

69. 11:00 Theory and Applications of Modulated TemperatureProgramming to Thermomechanical Techniques; Price, D.;p. 489

70. 11:20 Thermophysical Properties of a Thermal InterfaceMaterial; He, Y.; p. 495

71. 11:40 Use of Several Thermal Analysis Techniques on a HypalonPaint Coating for the Solid Rocket Booster (SRB) of theSpace Shuttle; Wingard, C; p. 501

DAVID DOLLIMORE SYMPOSIUM ON PHARMACEUTICALAPPLICATIONS OF THERMAL ANALYSIS


72. 9:00 Calculation of Vapor Pressure Curves for Hydroxy BenzoicAcid Compounds Using Thermogravimetry; Chatterjee, K.,D. Dollimore, K. Alexander; p. 509

73. 9:20 Quality and Disintegration Properties of Drugs andExcipients by Thermal Analytical Techniques; Riga, A., H.Griffith, Z. Gao, W-P. Pan, R. Collins; p. 510

74. 9:40 Quality Control of the Thiabendazole Pre-Formulated andTablets for TG and DSC Coupled to the PhotovisualSystem; Macedo, R.O., T. C. G. do Nascimento; p. 511

10:00 OPEN

10:20 Break


CORAL B; Suk-Fai Lau, Presiding

75. 10:40 The Study of Decomposition Mechanism of OrganicModified Clay by Thermex™ Inlet and GC/TOFMStechnique; Gao, Z., D. Zou, W. Xie, W. Pan; p. 517

76. 11:00 Thermal Characterization of Materials Using Evolved GasAnalysis; Xie, W., W. Pan; p. 523

77. 11:20 Surface and Solution Properties of OrganophosphorusChemicals and Performance Relationships in Wear Tests;Riga, A., W. Pistillo; p. 530

11:40 OPEN

CURE AND PROPERTHES OF THERMOSETTING MATERIALS

CARRIBEAN C; Brace Prime, Presiding

78. 10:00 Characterization of Cure and Properties of ThermosettingSystems by Modulated Temperature DSC; (InvitedLecturer) Professor Bruno van Mele, Vrije UniversiteitBrussel, H. Rahier, G.Van Assche, S. Swier; p. 534

79. 10:40 Development and Characterization of a ThermosettingResin for Universal Composite Processing; Hayes, B.,E.P.M. Williams, J. Seferis; p. 542

80. 11:00 Evolution of Viscoelastic Properties and Residual StressesDuring Thermoset Cure; Prasatya, P., G. McKenna, S.Simon; p. 548

81. 11:20 New TMA Method for the Measurement of Polymerizationinduced Shrinkage hi Photopolymers; Bair, H., M.Schilling, V. Colvin, A. Hale, N. Levinos; p. 554

82. 11:40 Thermal Analysis of Thermosetting Adhesives for Wood;Riedl, B., B. Park, Y. Bedard; p. 560

14

APPLICATIONS OF THERMAL CONDUCTIVITY TECHNIQUES

CARRIBEAN B; Nancy Mathis, Presiding

83. 9:00 Nondestructive study of temperature - propertycorrelations during the curing of rubberized fabric;Chandler, C , N. Mathis, Lin Li; p. 567

84. 9:20 Relationship of Dielectric Cure State to ThermalConductivity of Epoxy Resin; Shepard, D.D., S.E. Smith; p.573

85. 9:40 Thermal Conductivity of PTFE and PTFE Composites,Price, D.M., M. Jarratt; p. 579

10:00 Break

86. 10:20 Thermal Conductivity Imaging Using the Atomic ForceMicroscope; Price, D.M., M. Reading, A. Hammiche, H.M.Pillock; p. 585

87. 10:40 Thermal Effusivity as a Void or DelaminationMeasurement; Chandler, C, N. Mathis; p. 591

88. 11:00 Laser Flash Measurements of Adhesive Bondline EffectiveThermal Conductivity and Contact Resistance UsingMultilayer Methods; Campbell, R.C., S,E. Smith; p. 597

89. 11:20 Parameter Optimization for Measuring ThermalProperties of Electronic Materials Using the TransientPlane Source Technique; Dixon, C , M. Strong, M. Zhang;p. 598

12:00 BUSINESS MEETING

12:45 Lunch

THURSDAY AFTERNOONOct. 5,2000

CHARACTERIZATION OF POLYMERS BY THERMAL ANALYSISAND RHEOLOGY

CORAL A; Manika Varma-Nair, Presiding

90. 2:00 The Anomalies of Segmental Dynamics in ComplexPolymer Systems as Studied via Combined CRS/DSCApproach; Bershtein, V., N. Peschanskaya, P. YakushevV.A.Bershtein, V.M. Egorov, L.M. Egorova, P.N. Yakushev, A.M.Fainleib, P. Pissis, P. Sysel; p. 604

91. 2:20 Torque and Normal Force Measurements to Characterizethe Rheological Response of Concentrated PolymerSolutions; McKenna, G, V. Soulivong, X. Shi, O'Connell, P.;p. 611

92. 2:40 Advances in Polymer On-Line Capillary Rheology; Nelson,B.; p. 617

93. 3:00 Method for Analysis of Dynamic Mechanical ThermalAnalysis Data Using the Havriliak-Negami Model; Szabo,J., I Keough; p. 623

3:20 Break

THERMAL CHARACTERIZATION OF OILS

CORAL A; Vijay Reddy, Presiding

94. 3:40 Rheological and Dielectric Thermal Analysis of FailedEngine Oils; Riga, A.; p. 629

95. 4:00 Thermal Decomposition of Base Oils by Conventional,Isothermal and Modulated TGA.; Gamlin, C , N.Choudhury, N. Dutta, J. Matisons; p. 630

96. 4:20 The TGA Noack Test for the Assessment of Engine OilVolatility; Sichina, W.; p. 637

97. 4:40 TGA Noack Method for Lubricating Oils; Reddy, V.,R.Byrne, O. Sakamoto; p. 642

16

DAVD3 DOLLIMORE SYMPOSIUM ON PHARMACEUTICALAPPLICATIONS OF THERMAL ANALYSIS


98. 2:00 Thermal Studies of Albizia inopinnata Crude Extract in thePresence of Cyclodextrin and Aerosil by TG and DSCCoupled to the Photovisual System; Dantas de Medeiros,A.C., I. Almeida de Medeiros, R.O. Macedo; p. 647

99. 2:20 A Calorimetric Study of Modified Soy Proteins via EnzymeCatalyzed Reactions. Effect of Protease Specificity;Briones-Martinez, R., C. Fernandez, M.I. Cortes-Vazquez; p.652

100. 2:40 The Effect of Annealing on the Glass Transition Region ofSucrose Solutions; Kett, V., D. Craig, D. Deutsch; p. 653

101. 3:00 Spiking: A Novel Approach for Characterizing Polymorphsby DSC; Drayton, R.; p. 659

CURE AND PROPERTDZS OF THERMOSETTING MATERIALS

CARRIBEAN C; Bruce Prime, Presiding

102. 2:00 A Scaleable Methodology for Thermal Analysis fromMacro- to Micro- TA Using Thermoset Composites;(Invited Lecturer) Professor James Seferis, University ofWashington; p. 667

103. 2:40 Evaluation of Interphase Thermal Properties on GlassFiber Composites Using Scanning Thermal Microscopy;Tillman, M., B. Hayes, J. Seferis; p. 668

104. 3:00 Evaluation of Adhesives for Pressure Sensor Development;

Adhihetty, I., D. White, A. McNeil; p. 674

3:20 Break

105. 3:40 Characterization of a Dielectric Thin Film for Flip ChipPackaging; He, Y.; p. 675

106. 4:00 Property Characterization Of A Novel Water ReducibleChemical Agent Resistant Coating; Eng, Anthony, MalayPatel, Forrest Pilgrim; p. 681

107. 4:20 Evaluation of High Performance Fibrous Systems inHoneycomb Applications; Wu, Y., J. Seferis; p. 687

108. 4:40 Thermal Behavior and Stability of UV Curable Adhesivesfor Microelectronics Assembly; Tsang, C-F, Hui, H-K; p.693


CARRIBEAN C; Suk-Fai Lau, Presiding

109. 2:00 Simultaneous Thermal Analysis of HexahydrophthalicAnhydride; Suwardie, J., R. Artiaga, F. Barbadillo; p. 699

110. 2:20 Localized Evolved Gas Analysis Using a Scanning ThermalMicroscope; Price, D., M. Reading; p. 705

111. 2:40 DSC By TGA/SDTA 851E Considering Mass Changes;Riesen, R., M. Schubnell, J. Foreman; p. 710

112. 3:00 Automated Thermogravimetry - Mass spectrometry;Foreman, J., M. Zemo; p. 716

113. 3:20 Polymer Characterization Using Simultaneous TG/MS andTG/GC/MS Techniques; Potts, I., S. Froelicher, D. Chen, G.Koncar; p. 719

3:40 Break

114. 4:00 Evolved Gas Collection from a ThermogravimetricAnalyser and Identification by Gas Chromatography -Mass Spectrometry; Lever, T., D. Price; p. 720

115. 4:20 Characterization of Thermal Stability Behavior by meansof TGA/FITR-Coupling in Quality Assurance; Hoffmann,F., R. Riesen, J. Foreman; p. 726

116. 4:40 A New Principle for Creation Sensitive TA & Calve-DeviceBased on Combination of Methods of Thermal Analysisand Electromoving Forces (EMF) with Solid Electrolyte;Mudretsova, S., A. Maiorova; p. 732

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117. 5:00 Perkin-Elmer Outstanding Student Award 2000Presentation and Lecture

ARCTIC, Wei-Ping Pan, Presiding

Dr. Karin EzbianskyFormerly of the University of Pennsylvania, now of GE Plastics

THERMAL STUDffiS OF P-ACETOXYETHYLSILSESQUIOXANESCHLORIDE-FREE PRECURSORS FOR SIO2 FILMS; p. 739

5:20 End of technical program for Thursday, Oct. 5,2000

7:00 AWARDS BANQUET

FRIDAY MORNING

Oct. 6,2000

PLENARY LECTURE

ARCTIC; David Jones, Presiding

118. 8:00 Decomposition of Solids Accompanied by Melting-Bawn -Kinetics; Prof. M. Brown, University of Witwatersrand, Prof.B.D. Glass; p. 748

8:40 Break

CHARACTERIZATION OF POLYMERS BY THERMAL ANALYSIS

ANDRHEOLOGY

CORAL A; Manika Varma-Nair, Presiding

119. 9:00 Melting and Crystallization of Low Molecular WeightPolyethylene by Calorimetry; Pak, J., B. Wunderlich; p. 764

120. 9:20 The Thermodynamic and Structural Properties ofMetallocene-Type Random Ethylene Copolymers;Simanke, A., R. Alamo; p. 770

121. 9:40 Crystallization, Melting and Morphology at Ambient andHigh Pressures of Homogeneous Ethylene Copolymers withHigh Comonomer Contents; Eynde, S., V. Mathot, G.Hohne, H. Reynaers; p. 777

122. 10:00 Kinetic and Morphological Studies of a Series of NarrowPropylene-Ethylene Copolymers; Chatterjee, J., A. Little,R.G. Alamo; p. 784

10:20 Break

123. 10:40 Reversible and Irreversible Heat Capacities ofPoly{Cardonyl(Ethylene-Co-Propylene)} by Temperature-Modulated Differential Scanning Calorimetry, TMDSC;Pyda, M., B. Wunderlich; p. 791

124. 11:00 Structure and Properties of Polypropylene Polymers in aSpunbonding Process; Bhat, G., R. Nanjundappa, R. Kotra;p. 797

20

125. 11:20 Determination of the Processing History of PP Fibers byThermal Analyses; Bhat, G, A. Saraf; p. 803

11:40 OPEN

THERMAL ANALYSIS IN ENVffiONMENTAL APPLICATIONS

CARRIBEAN B; Shaheer Mikhail, Presiding

126. 9:00 Utility of MDSC® in Monitoring Solvent-Based CoatingCure; Thomas, L., S. Aubuchon; p. 804

127. 9:20 Analysis of Crystallinity hi Polyolefin UndergroundStorage Tanks by MDSC®; Aubuchon, S., L. Thomas; p.809

128. 9:40 Thermal Reduction of Steel-Making Secondary Materialsn. Electric-Arc-Furnace Dust; Mikhail, S., A.M. Turcotte;p. 815

129. 10:00 Kinetic Parameters of Regeneration of Coked Alumina byTG; Fernandes, V.J., A.S.Araujo, GJ.T. Fernandes; p. 816

10:20 Break

MODERN APPLICATIONS OF SOLUTION CALORIMETRY

CARRIBEAN C; Bob Flowers, Presiding

130. 10:40 Thermal Characterization of Second Tier ConfigurationalExcitations hi Glassforming Liquids; (Invited Lecturer)Professor Austen Angell, V. Velikov, Arizona State University;p. 817

131. 11:20 Cycloalkanes Solubility Determination through DifferentialScanning Calorimetry; Young, P., D. Dollimore, C Schall;p. 818

132. 11:40 Single Seed Calorimetry Analysis of Corn Flour; Aggarwal,P.; p. 824

21

GENERAL SESSION

CORAL B: Alan Riga, Presiding

133. 9:00 Characterization of Thermal and Mechanical Behavior ofPolyimide Films - A Product Performance Evaluation;C.F. Tsang, H.K. Hui; p. 827

134. 9:20 Thermogravimetric Evaluation of Flame Retardancy ofPolyester/Sisal Composite; Fernandes, V.J., D.R. Silva, V.M.Fonseca; p. 833

135. 9:40 Tg and Cp Measurements on Perfluoropolyethers; R.

Siemens, T.E.. Karis; p. 834

10:00 Break

136. 10:20 Lead-Tin Solder Characterization by Differential ScanningCalorimetry; Fleszar, M.; p. 840

137. 10:40 Characterizing Solid-Solid Interactions in Binary Mixturesof Alkylcyclohexanes using Differential ScanningCalorimetry; Young, P., D. Dollimore, C. Schall; p. 846

138. 11:00 An "ASTM-Uke" Standard Test Method for theComposition and Wear of Cellulose-Based AutomaticTransmission Plates by Thermogravimetric Analysis andX-Ray Diffraction Analysis; Riga, A.; p. 852

139. 11:20 Concept of Variable Activation Energy: Why it just can'tstay put?; Vyazovkin, S.; p. 853

140. 11:40 High Scanning Rate DSC: A New Standard?; Pijpers.T.,E. van der Vegte, V. Mathot, B. Cassel; p. 860

12:00 Lunch

22

FRIDAY AFTERNOONOct. 6,2000

HAZARD EVALUATION BY THERMOANALYTICAL METHODS

CARRIBEAN B; Ed Donoghue, Presiding

141. 1:30 Advanced Reactive System Screening Tool; Burelbach, J.;p. 861

142. 1:50 Safe Process Development from Reaction Hazards TestingLeggett, D.; p. 862

143. 2:10 The Interpretation of Thermal Analytical Data in theDetermination of a Safe Operating Envelope for the PilotPlant Scale-Up of Chemical Processes; Tuma, L.; p. 869

144. 2:30 The Versatile VSP2: A Tool for Adiabatic ThermalAnalysis and Vent Sizing Applications; Askonas, C , J.Burelbach, J. Leung; p. 879

MODERN APPLICATIONS OF SOLUTION CALORIMETRY

CARRIBEAN C; Bob Flowers, Presiding

145. 1:30 Recent Advances in Calorimetry for Intra- and Inter-Molecular Analysis of Biomolecules; Chellani, M.; p. 880

146. 2:10 Calorimetric Studies of Molecular Recognition; Flowers,R.; p. 881

GENERAL SESSION

CORAL B; Alan Riga, Presiding

147. 1.-30 Recent Developments in DSC Software: DeterminingKinetics and Thermodynamic Parameters of RecycledPolyethylene Terephthalate; Cassel, R., L. Li; p. 882

148. 1:50 Micro Thermal Analysis Calibration and Repeatability;Blaine, R., D. Slough, D. Price; p. 883

23

149. 2:10 Multi Frequency Heat Capacity Measurement by DifferentTypes of Temperature Modulation; Kamasa, P., M. Pyda,M. Merzlyakov, C. Schick, B. Wunderlich; p. 889

150. 2:30 Portable Thermal Analyser: A New Calorimetric Concept;Le Parlouer, P., L. Benoist, I. Chan; p. 895

151. 2:50 Advances to Dynamic Mechanical Analysis; Foreman, J.; p.901

152. 3:10 Understanding and Getting the Most from DSC Data inPolymorphic Study; Drayton, R.; p. 906

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proceedings of october 4-6,2000 u.s.a. … · proceedings of october 4-6,2000 orlando, florida,...

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