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    Lecture Presentations on

    Environmental Engineering

    Course EENV101

    Part 2b Wk 7-8Solid-Waste Management

    Chapter Ten of Textbook

    By Engr. Jessica. M. Castillo

    3rd Term 2015-2016

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    COURSE OBJECTIVES

    1. Explain important ecology concepts relevant to environmentalengineering such as biodiversity, pollution effects,bioaccumulation, Climate Change, waste management,among others. (CO1)

    2. Articulate the different environmental scenario in terms of

    hazards and risks in the air, water and soil environment.(CO2)

    3. Discuss the different environmental control technologies andprinciples for Green Engineering. (CO3)

    4. State the existing international agreements, local laws, rules

    and regulations of the government on environmental issues.(CO4)

    5. Recommend environmental solutions and appropriate designtreatment schemes to reduce environmental risks such aspollution control and proper waste disposal. (CO5)

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    Week 7-8 : Learning ObjectivesDescribe the key components of a solid-waste management system. (CO1)

    Identify the objectives of solid-waste management

    Distinguish between municipal solid wastes and other solid wastes. (CO1, CO2,CO4)

    Explain the process of conducting the Waste Accumulation and CharacteristicsStudy (WACS). (CO1, CO2)

    Explain the issues associated with design and operation of successful solidwaste subsystems (collection, transfer stations, material recovery facilities,composting facilities, waste to energy facilities, and landfills). (CO3)

    Solve mixing problems to determine an appropriate C/N ratio for composting. .(CO2)

    Integrate principles of the pollution prevention hierarchy into a Solid WasteManagement System. (CO1)

    Explain the concerns with landfill gas and leachate and how they areaddressed.

    Discuss important provisions of the Ecological Solid Waste Management Act ofthe Philippines (R.A. 9003) and its IRR. (CO3)

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    Environmental Issues:

    • Climate Change

    • Ozone Depletion

    • Green House Effect

    • Water Pollution

    •  Air Pollution• Noise Pollution

    • Solid Wastes• Denuded forests

    • Landslides• Fish kill

    • Oil spill

    • etc

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    WASTE GENERATION

    Kinds of Solid Wastes and its sources

    STORAGE

    Material Recovery Facility

    COLLECTIONSolid waste Reduction

    TRANSPORT

    PROCESSINGManagement Technologies

    DISPOSAL

    SOLID WASTE MANAGEMENT

    AND ENGINEERING

    In all of these stages wastes have to be reduced.

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    Sources of Solid Wastes

    Residential (e.g. Detached homes, apartments) Commercial (stores, restaurants, malls etc.

    Institutional (schools, hospitals etc.)

    Construction and Demolition (road construction)

    Municipal services (markets, slaughter houses etc.)

    Treatment Plant sites (MRFs, dumpsites etc.)

    Industrial (food processing plants, power plants)

     Agricultural (cropping farms, dairies, orchards) Mining (coal mining, oil/gas exploration)

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    Kinds of Solid Wastes

    Definition of Solid WASTE- a generic term used to describe the things

    we throw away: garbage, refuse, trash

    -discarded item that can be reused, recycled,or reclaimed.

    - sludge

    - toxic and

    hazardous wastes

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    Characteristics OR TYPES of Solid Waste

    zeroresource.com

    Nature of the material

    Organic

    Inorganic

    Putrescible (biodegradable)

    Non-putrescible (non-biodegradable) Combustible

    Non-combustible (ceramics, metals)

    Non- Biodegradable (plastics, metals)

    Toxic and Hazardous household chemicals

    medical wastes

    harmful chemicals

    Industrial wastes

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    CHARACTERIZING SOLID WASTES

    Origin /Source

    Municipal (MSW) : homes, commercial,

    institutional)

    Non-municipal: agricultural, industry, mining

    etc.

    Disposal

    Reuse- Recycle

    Energy transformation

    Nature

    Non-combustible (ceramics, metals)

    Non- Biodegradable (plastics, metals)

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    Amount of Municipal Solid Waste

    (MSW)The density of solid waste is the mass of

    solid waste per unit volume. The density of

    collected solid waste is 180 to 450 kg/m3

    bioenergypro.com

    The amount of MSW generated is simply

    the amount generated per capita

    multiplied by the

    number of population.

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    Municipal/ City Solid Wastes of

    NAGA (WACS) http://naga.gov.ph/go/ecological-profile/page/2/

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    Factors affecting solid wastes accumulation

    Rapid Urbanization

    Changing Lifestyles

    Public Indifference

    Consumption Patterns

    Public awareness

    Government initiatives

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    Problems with Municipal Solid

    Wastes

     Accumulation

    Pollution

    Collection

    Dump sites Material Recovery Facility

    Recycling

    Market for recyclables

    Health Impacts

    etc

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     A municipality with a population of 250,000 generatesMSW of 0.3 kg/capita daily.

    a) How much MSW is generated by the town/wk?

    b) If the garbage is collected twice a week, with 2 truckloads

    per day, one in the morning and one in the afternoon,

    how many truckloads per week would that be.

    Note that the capacity of the is truck 5 metric tons,

    but only 75% is the actual load.

    c) How much is the cost of garbage collection per week,

    if the rental of the truck is P3,000 per load.d) If the MSW is reduced by half, how much savings

    would that be per annum?

    Sample Problem : Collection and Transport :

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    Waste Management vs.

    Waste reduction

    Sanitary Landfill

    Incineration

    Energy Conversion

    Green Engineering DesignsRecycling, reuse of products

    Composting

    Redesign Sources of Waste

    Process Modification

    Education and Legislation

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    Solid Waste Collection

    The Local Government elected officials decides:

    How is the collection to be done?

    How often would the collection be? What wastes should be collected

    note: usually hazardous wastes are not included.

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    CONVENTIONAL DISPOSAL

    METHODS

    - Open Dumps

    - Sanitary Landfills

    - Burning or Incineration

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    ENVIRONMENTAL IMPACTS

    - Ozone depletion

    - Soil and ground water contamination

    - Rivers and Lakes pollution

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    REPUBLIC ACT NO. 9003

    ECOLOGICAL SOLID WASTE MANAGEMENT

    ACT OF 2000

    AN ACT PROVIDING FOR AN ECOLOGICAL SOLID WASTEMANAGEMENT PROGRAM, CREATING THE NECESSARY

    INSTITUTIONAL MECHANISMS AND INCENTIVES, DECLARING CERTAINACTS PROHIBITED AND PROVIDING PENALTIES, APPROPRIATING

    FUNDS THEREFOR, AND FOR OTHER PURPOSES

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    DENR Administrative Order 49 1998

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    The principles of Ecological Waste Management

    (EWM) have been adopted by the

    (DENR) and the Presidential Task Force on Waste

    Management (PTFWM) as themain strategy to address the growing problems of

    solid waste management.

    These principles centre of the so-called 3Rs of

    effective solid waste management:• reduction of waste (waste minimization);

    • recovery of waste for recycling; and

    • re-use of materials, primarily for energy

    generation.

    Sect. 1.4 Technical Guidelines for 

    MUNICIPAL SOLID WASTE DISPOSAL

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    RECYCLING AND

    MATERIAL RECOVERY

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    Solution:

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    Reuse and Recycle

    Give examples

    Refer to : http://www.thisland.illinois.edu/57ways/57ways_27.html 

    http://www.thisland.illinois.edu/57ways/57ways_27.htmlhttp://www.thisland.illinois.edu/57ways/57ways_27.html

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    Waste to Energy Incineration

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    COMPOSTING

    http://extension.missouri.edu/p/G6956

    Carbonaceous

    +

    Nitrogenous

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    What is a compost?

    “Compost is partially decomposed organic matter. It is dark and easilycrumbled and has an earthy aroma. It is created by biological processes in

    which soil-inhabiting organisms break down plant tissue.

    When decomposition is complete, compost has turned to a dark-

    brown powdery material called humus. The processes occurring in a compost

    pile are similar to those that break down organic matter in soil. However,decomposition occurs much more rapidly in the compost pile because the

    environment can be made ideal for the microbes to do their work .”

    Compost therefore is a better alternative to chemical fertilizer,because it does not only contain (N-P-K) but also other minerals and

    microorganisms needed by the plants. However, the process should be

    controlled in such a way that non beneficial components are excluded.

    http://extension.missouri.edu/p/G6956

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    COMPOSTING PROBLEM

    REFER to page 547 of textbook

    Replace oat straw with rice straw

    and determine the proper ingredient

    for composting.

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    Composting Process

    The length of time necessary for

    the composting process depends on

    several conditions:

    Carbon-to-nitrogen ratio Surface area of particles

     Aeration

    Moisture Temperature

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    http://www.ilaxstudio.com/blog/wp-content/uploads/2011/03/110309LandFillCan1.jpg

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    Eco-industrial Revolution

    - Goal is to make industrial manufacturing

    processes cleaner and more sustainable

    by redesigning them to mimic how

    nature deals with wastes.

    - Nature: waste outputs becomes nutrient

    inputs

    - Resource exchange webs: wastes ofone manufacturer becomes raw

    materials for another

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    Phytoremediation is the direct use of trees,

    green plants and their associated

    microorganisms to stabilize or reducecontamination in soils, persistent metals,

    sludge, sediments, surface water, or ground

    water.

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    Selling Services instead of

    thingsExample:

    Outsourcing:

    Instead of simply selling airconditioning units, they provide air

    conditioning systems to manufacturing

    plants. The service company provides the

    maintenance and repairs, improvements etc.

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    WASTE GENERATIONKinds of Solid Wastes and its sources

    STORAGE

    Material Recovery Facility

    COLLECTION

    Solid waste Reduction TRANSPORT

    PROCESSING

    Management Technologies

    DISPOSAL

    SOLID WASTE MANAGEMENT

    AND ENGINEERING

    In all of these stages wastes have to be reduced.

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    Sanitary Landfill* sites where waste

    is isolated from the environment until it is safe.

    http://worldfromeyes.blogspot.com/2011/04/sanitary-landfill-waste-management.html

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    Minimum Requirements: Full or partial hydrogeological isolation: if a site cannot be located on

    land which naturally contains leachate security, additional lining

    materials should be brought to the site to reduce leakage from the baseof the site (leachate) and help reduce contamination of groundwater and

    surrounding soil. If a liner - soil or synthetic - is provided without a

    system of leachate collection, all leachate will eventually reach the

    surrounding environment. Leachate collection and treatment must be

    stressed as a basic requirement.

    Formal engineering preparations: designs should be developed from

    local geological and hydrogeological investigations. A waste disposal

    plan and a final restoration plan should also be developed.

    Permanent control: trained staff should be based at the landfill to

    supervise site preparation and construction, the depositing of waste and

    the regular operation and maintenance.

    Planned waste emplacement and covering: waste should be spread in

    layers and compacted. A small working area which is covered daily

    helps make the waste less accessible to pests and vermin.

    http://web.mit.edu/urbanupgrading/urbanenvironment/sectors/solid-waste-landfills.html

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    HAZARDOUS WASTES

    Refers to any solid waste or combination ofsolid wastes which is toxic, ignitable, corrosive or

    reactive enough that may

    (1) cause harm, or significantly contribute to an

    increase in mortality or an increase in seriousirreversible, or incapacitating reversible, illness; or

    (2) pose a substantial present or potential

    hazard to human health or the environment when

    improperly treated, stored, transported, or disposedof, or otherwise managed;

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    Hazardous Wastes include:

    Infectious waste from hospitals: equipment,

    instruments, utensils, and fomites of a disposable naturefrom patients who are suspected to have or have been

    diagnosed as having communicable diseases and must

    therefore be isolated as required by public health agencies,

    laboratory wastes such as pathological specimens .(i.e. alltissues, specimens of blood elements, excreta, and

    secretions obtained from patients or laboratory animals).

    Nuclear wastes made radioactive by exposure to

    the radiation incidental to the production or utilization of

    nuclear fuels but does not include nuclear fuel, or

    radioisotopes which have reached the final stage of

    fabrication so as to be usable for any scientific, medical,

    agricultural, commercial, or industrial purpose.

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    Hazardous Wastes also include:

    Toxic Metals or Substances coming from domestic

    tools an appliances (including children toys), laboratories,

    industrial wastes etc.

    Lead is one of the toxic metals that can harm the

    nervous system (neurotoxin), resulting to but not limitedto lowered IQ, shortened attention span, hearing damage,

     Another is Mercury, which is released into the

    environment mostly by burning coal and incinerating wastesand can build to high levels in some types of fish consumed

    by humans. This could also harm the nervous system esp

    in developing fetus. Lately some cosmetics are also found

    to have high mercury content.

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    DENR Administrative Order -

    Environment Management Board

     Administrative Order No. 2007-23 : Additional Requirements for the Issuance ofthe Priority Chemical L is t (PCL) of 2005. It is a list of existing and new chemicals

    that DENR-EMB has determined to a potentially pose unreasonable risk to public

    health, workplace, and the environment. ...

    Persistence refers to the property of a substance whose half-life in water,

    sediment, soil, or air exceeds duration of fifty (50) days. Sludge may be used

    as a surrogate for sediment. Metals are considered to be persistent in all

    media.

    Toxicity refers to the quality of a substance which meets any of the following

    criteria:

     Acute lethality

    Chronic or sub-lethal toxicityTeratogenicity

    Carcinogenicity

    Bioaccumulation potential is the measure of a substance’s ability to

    increase its concentration down the food chain.

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    What Harmful Chemicals Are

    in Your Home?Cleaning : Disinfectants, cleaning materials

    Painting : Latex and Oil based paint containing

    lead, VarnishGardening : Pesticides, Weed killers(herbicides)

     Automotive : Gasoline, Antifreeze, Battery acid,

    Brake and transmission fluid,

    rust remover 

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    Basel Convention, is an international treaty that was designed

    to reduce the movements of hazardous waste between

    nations, and specifically to prevent transfer of hazardous waste

    from developed to less developed countries (LDCs).

    It does not, however, address the movement of radioactivewaste.

    The Convention is also intended

    a). to minimize the amount and toxicity of wastes generated,

    b). to ensure their environmentally sound management asclosely as possible to the source of generation, and

    c). to assist LDCs in environmentally sound management of the

    hazardous and other wastes they generate.

    The Convention was opened for signature on 22 March 1989,

    and entered into force on 5 May 1992.

    Basel Convention on the Control of Transboundary

    Movements of Hazardous Wastes and Their

    Disposal.

    http://en.wikipedia.org/wiki/Developed_countrieshttp://en.wikipedia.org/wiki/Less_Developed_Countrieshttp://en.wikipedia.org/wiki/Less_Developed_Countrieshttp://en.wikipedia.org/wiki/Developed_countries

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    Pyrolysis is formally defined as chemical decomposition induced in organic materials by

    heat in the absence of oxygen.

    In practice, it is not possible to achieve a completely oxygen-free atmosphere; actual

    pyrolytic systems are operated with less than stoichiometric quantities of oxygen.

    Because some oxygen will be present in any pyrolytic system, nominal oxidation will

    occur. If volatile or semivolatile materials are present in the waste, thermal desorption

    will also occur.

    Pyrolysis transforms hazardous organic materials into gaseous components, small

    quantities of liquid, and a solid residue (coke) containing fixed carbon and ash.

    Pyrolysis of organic materials produces combustible gases, including carbon monoxide,

    hydrogen and methane, and other hydrocarbons. If the off-gases are cooled, liquids

    condense producing an oil/tar residue and contaminated water.

    Pyrolysis typically occurs under pressure and at operating temperatures above 430 °C

    (800 °F). The pyrolysis gases require further treatment. The off-gases may be treated in

    a secondary combustion chamber, flared, and partially condensed. Particulate removal

    equipment such as fabric filters or wet scrubbers are also required.

    Treatment : Pyrolysis

    Source c: http://www.frtr.gov/matrix2/section4/4-25.html

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    CAS Registry No. Chemical Name

    108-90-7 1,4-CHLOROBENZENE

    106-93-4 1,2-DIBROMOETHANE

    95-50-1 0-DICHLOROBENZENE

    106-46-7 1,4-DICHLOROBENZENE

    107-06-2 1,2-DICHLOROETHANE

    122-66-7 1,2 DIPHENYLHYDRAZINE108-46-3 3-HYDROXYPHENOL

    7647-18-9 ANTIMONY PENTACHLORIDE

    7440-38-2 ARSENIC COMPOUNDS

    1332-21-4 ASBESTOS*

    71-43-2 BENZENE

    7440-41-7 BERYLLIUM COMPOUNDS7440-43-9 CADMIUM COMPOUNDS

    56-23-5 CARBON TETRACHLORIDE*

    CHLORINATED ETHERS

    CHLOROFLUORO CARBONS*

    67-66-3 CHLOROFORM

    76-06-2 CHLOROPICRIN

    18540-29-9 CHROMIUM COMPOUNDS

    57-12-5 CYANIDE COMPOUNDS*

    64-67-5 DIETHYL SULFATE

    106-93-4 ETHYLENE DIBROMIDE75-21-8 ETHYLENE OXIDE

    111-30-8 GLUTARALDEHYDE

    50-00-0 FORMALDEHYDE

    9002-83-9 HALONS*

    118-74-1 HEXACHLOROBENZENE

    67-72-1 HEXACHLOROETHANE302-01-2 HYDRAZINE

    7439-92-1 LEAD COMPOUNDS

    149-30-4 MBT

    594-42-3 MERCAFTAN

    PERCHLOROMETHYL

    Priority Chemicals List

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    7439-97-6 MERCURY COMPOUNDS

    74-87-3 METHYL CHLORIDE

    75-09-2 METHYLENECHLORIDE2385-85-5 MIREX

    87-86-5 PENTACHLOROPHENOL

    127-18-4 PERCHLROETHYLENE

    108-95-2 PHENIC ACID

    75-44-5 PHOSGENE

    85-44-9 PHTHALIC ANHYDRIDE59536-65- 1 POLYBROMINATED

    BIPHENYLS

    1336-36-3 POLYCHLORINATED

    BIPHENYLS

    1,1,1 -TRICHLOROETHANE**

    79-01-6 TRICHLOROETHYLENETRIBUTYLTIN

    7782-49-2 SELENIUM

    75-01-4 VINYL CHLORIDE

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    "O l ft th l t

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    " Only after the las t

    tree has been cu t

    down, Only after thelas t r iver has been

    po isoned, Only after

    the las t f ish has been

    caugh t, Only then w i ll

    you f ind That moneycanno t be eaten ."  –Cree Indian Prophecy