nustar pipeline operating partnership l.p. product...

Version 1 – 2017 01 01

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NuStar Pipeline Operating Partnership L.P.

Product Specifications

North Pipeline

Version 1 – 2017 01 01

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SPECIFICATIONS FOR A GRADE GASOLINE

NORTH PIPELINE

(Conventional Gasoline - This product does not meet the requirements for reformulated gasoline and may not be used in any

reformulated gasoline covered area.)

Origin Shipments

Specification Points

ASTM

Test

Methods

Minimum

Maximum

Deliveries

(At Terminals)

Gravity, Degrees API D287 Report Only

Color Undyed

Volatility 1/

Benzene, vol % D3606 4.9

Mercaptan Sulfur,wt %

2/

D3227 0.003

Hydrogen Sulfide D3227 None

Copper Corrosion D130 1

Silver Corrosion D7667,D7671 1

Gum, Existent,

mg/lOOml

D381 4 5

Oxidation Stability, min. D525 240 180

Phosphorous, g/gal D3231 0.003 0.005

Lead, g/gal D3237 0.010 0.05

Research Octane {R} D2699 Report

Report Motor Octane {M} D2700

(R+M)/2 D4814 91.0

Sulfur, ppm D2622 80

Oxygenates, vol % D4815,D5599 0.05

Haze rating 3/ D4176 2 3

NACE Corrosion TM0172,

D7548

B+

Odor 4/ Nonoffensive

1/ Refer to Seasonal Gasoline Volatility Schedule. 2/ Mercaptan Sulfur determination is waived if the result of the Doctor Test

ASTM D4952 is negative. 3/ Compliance with ASTM D4176 will be determined using Procedure 2 at the following temperatures, adjusted

seasonally: February 16 - September 30 55 F max October 1 - February 15 45 F max

4/ Any gasoline exhibiting an offensive odor and/or containing more than 0.30wt%dicyclopentadiene will not be accepted

for shipment.

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SPECIFICATIONS FOR SUB OCTANE GRADE GASOLINE

NORTH PIPELINE

(Conventional Gasoline - This product does not meet the requirements for reformulated gasoline and may not be used in any

reformulated gasoline covered area.)

Origin Shipments


ASTM

Test

Methods

Minimum

Maximum

Deliveries

(At Terminals)

Gravity, Degrees API D287

D1298

D4052

Report Only

Color Undyed

Volatility 1/ D5191

Vapor to Liquid Ratio 1/ D5188

Drivability Index JV D4814

Mercaptan Sulfur, wt % 2/ D3227 0.004

Hydrogen Sulfide D3227 None

Copper Corrosion D130 1

Silver Corrosion D7667, D7671 1

Gum, Existent, mg/100ml D381 4 5

Oxidation Stability, min. D525 240

Phosphorous, g/gal D3231 0.003 0.005

Lead, g/gal D3237 0.010 0.05

Research Octane {R} D2699 3/

Motor Octane {M} D2700 3/

(R+M)/2 D4814 3/

Sulfur, ppm D2622 80

Benzene, vol % D3606 4.9

Oxygenates, vol % D4815, D5599 0.05

Haze rating 4/ D4176 2 3

NACE Corrosion TM0172, D7548 B+

Odor 5/ Nonoffensive

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SPECIFICATIONS FOR SUB OCTANE GRADE GASOLINE (cont’d)

NORTH PIPELINE

1/ Refer to Seasonal Gasoline Volatility Schedule.

2/ Mercaptan Sulfur determination is waived if the result of the Doctor Test ASTM D4952 is

negative.

3/ Shipper has certified this product to meet 87 Octane when blended with 10% ethanol.

The following parameters apply before blending with 10% denatured fuel ethanol.

Physical property Test method Origin limits

Distillation, D86 10% Evap (T10),F Report

20% Evap (T20),F Report

50% Evap (T50),F 170

RVP 6/ D5191 Report

Vapor to Liquid Ratio Class 1 Class 2 Class 3 Class 4 Class 5

D5188, min1/7 129 122 116 107 102

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SPECIFICATIONS FOR SUB OCTANE GRADE GASOLINE (cont’d)

NORTH PIPELINE

4/ Compliance with ASTM D4176 will be determined using Procedure 2 at the following

temperatures, adjusted seasonally:

February 16 - September 30 55 F max

October 1 - February 15 45 F max

5/ Any gasoline exhibiting an offensive odor and/or containing more than 0.30 wt %

dicyclopentadiene will not be accepted for shipment.

6/ RVP limits on ethanol blended gasoline are controlled by various federal and state

regulations and waivers, which are generally greater than the limits for base gasoline.

7/ D5188 is the referee method. The alternate equation in D4814 may also be used.

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SPECIFICATION FOR FUNGIBLE ULTRA LOW SULFUR FUEL DIESEL

GRADE 37

NORTH PIPELINE

Shipments (At Origin)


ASTM

Test

Methods

Minimum

Maximum

Deliveries

(At Terminals)

May Be

Gravity, Degrees A.P.I. D287 30

Color D1500 2.5 3.0

Color visual Undyed

Distillation, D86

50% Recovered, F Report

90% Recovered, F 540 640

OR

Simulated distillation D2887

50% Recovered, F Report

90% Recovered, F 572 673

Corrosion, Copper Strip @122 F D130

Cetane

(1) Cetane Number D613 40

Or (2) Cetane Index, Procedure A D4737 40

Flash, F D93 130 125

Thermal Stability,

(1) Thermal, % reflectance D6468 (W)

D6468(Y)

75

82

Aging Period (minutes) D6468 90

OR (2) Oxidation, mg/100ml D2274 2.5

Carbon Residue on 10% Bottoms

(Ramsbottom) - Percent D524 0.35

Cloud Point, F D2500, D577

D5772, D5773 1

1/

Pour Point, F D97, D5949

D5950, D5985

1/

Viscosity, cSt @ 104 F D445 1.9 4.1

Haze Rating 2/ D4176 2 3

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SPECIFICATION FOR FUNGIBLE ULTRA LOW SULFUR FUEL DIESEL

GRADE 37 (cont’d)

NORTH PIPELINE



ASTM

Test

Methods

Minimum

Maximum

Deliveries

(At Terminals)

May Be

Ash,wt% D482 0.01

Sulfur, ppm 3/ D2622 *12 15

NACE Corrosion TM0172,

D7548 B+

Aromatics (Volume %) D975 35

Or Aromatics by Cetane Index D976 40

BS&W, vol.% D2709 <0.05

Conductivity, pS/m @ 70 F D2624 250

1/ Due to fungible specifications, the cloud/pour point for diesel products must comply with

the ASTM specifications for the region in which the diesel is produced. It should be

noted that diesel products distributed into colder climates may require lower cloud and/or

pour points or suppressors, i.e., winterization.

2/ The finished product shall be visually free of undissolved water, sediment, and suspended

matter in proffered tankage and at the point of delivery. Compliance with this

workmanship clause will be determined by ASTM D4176, Procedure 2 at 77 F or at

actual conditions present at the point and time of sampling, whichever is lower.

3/ Origin laboratory certifying sulfur content must qualify the test method used per EPA

Performance Based Testing Criteria (see CFR 80.584). The referee method will be

ASTM D5453. * Sulfur limit, 12 ppm for interconnecting pipelines.

Additional Requirements:

Biodiesel: The use of any biodiesel fuel as a blending component is prohibited.

Dyes: ULSD grade shipments may not be dyed

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SPECIFICATION FOR Y GRADE No. 1 FUEL OIL DISTILLATE

GRADE 58

NORTH PIPELINE



ASTM

Test

Methods

Minimum

Maximum

Deliveries

(At Terminals)

May Be

Gravity, Degrees A.P.I. D287 35.0

Distillation, D86

10% Recovered, F 419


OR

Simulated Distillation D2887



Corrosion, Copper Strip @122F D130 1

Cetane

(1) Cetane Number D613 40

(2) Cetane Index, procedure A D4737 40

Centane Index 1/ D976 40

Flash, F D93 125 160 115

Carbon Residue on 10% Bottoms

(Ramsbottom) – Precent D524 0.15

Pour Point, F D97 -25

Haze Rating 2/ D4176 2 3

Sulfur – ppm 3/ D2622 12 15

Mercaptan Sulfur, wt % 4/ D3227 0.004

Viscosity at 104 F, cSt D445 1.3 2.4

Ash, wt % D482 0.01

NACE Corrosion

TM0172

D7548 B+

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SPECIFICATION FOR Y GRADE No. 1 FUEL OIL DISTILLATE

GRADE 58 (Cont’d)

NORTH PIPELINE

1/ ASTM D976 data is required for low sulfur fuel oils to demonstrate aromatics compliance per the

EPA.

2/ The finished product shall be visually free of undissolved water, sediment, and suspended matter in proffered tankage and at the point of delivery. Compliance with this workmanship clause will be determined by ASTM D4176, Procedure 2 at 77 F or at actual conditions present at the point and time of sampling, whichever is lower.

3/ ASTM D7039 and D5453 may be used as an alternate method providing adequate correlation to

ASTM D2622 is provided. *Sulfur limit, 12 ppm for interconnecting pipelines.

4/ Mercaptan Sulfur determination is waived if the result of the Doctor Test ASTM D4952 is negative.

Dyes: Y-Grade petroleum fuel oil distillate shipments shall not be dyed.

Biodiesel: The use of any biodiesel as a blending component is prohibited.

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SPECIFICATION FOR B GRADE BIO-DIESEL FUEL

NORTH PIPELINE

Shipment (At Origin)


ASTM

*Test

Methods

Minimum

Maximum

Deliveries 1/

(At Terminals)

May Be

Density, Kg/L D4052 Report

Distillation, D1160

Atmospheric equivalent

temperature

90% Recovered, F or

680

Simulated Distillation

(Modified)

D2887 680

Corrosion, Copper Strip

@122F

D130 1

Cetane Number D613 47

Flash, P.M.,F D93 200

Alcohol control (Must meet one of the following)

Methanol content, %

mass

EN14110 0.2

Flash, P.M., F D93 266

Oxidation Stability EN14112 6 hrs 3 hrs

Carbon Residue on 100%

sample, %

D4530 0.050

Cloud Point, F D2500 36

Viscosity, cSt @104 F D445 1.9 6.0

Sulfated Ash, %mass D874 0.020

Haze Rating @ 60 F D4176 No. 2

Sulfur, ppm 2/ D5453 15

NACE Corrosion TM0172 B+

Free Glycerin, % mass D6584 0.020

Monoglyceride, % mass D6584 0.450

Total Glycerin, % mass D6584 0.240

Acid Number, mgKOH/g D664 0.40

Phosphruse content wt % D4951 0.001

Water & Sediment vol % D2709 0.050

Calcium & Magnesium,

combined, ppm

EN14538 5.0

Sodium & Potassium,

combined, ppm

EN14538 5.0

Minimum Delivery

Temperate 3/

MMP

Workmanship 4/ MMP

Filtration, Seconds

(modified), max

D7501 125

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SPECIFICATION FOR B GRADE BIO-DIESEL FUEL (cont’d)

NORTH PIPELINE

Biodiesel Supplier must be BQ9000 certified. No Methyl Esters derived from yellow grease.

1/ Delivered products meet all applicable requirements at time and place of delivery.

2/ All results provided must use an EPA qualified instrument.

3/ Minimum delivery temperature of+50 F for acceptance for delivery.

4/ Workmanship: At the time of acceptance, the finished fuel shall be visually free from

undissolved water, sediment, or suspended matter and shall be clear and bright.

Additives: BioExtend 30

Eastman – Tenox 21

Kemin BF 320

Nalco EC5609A

* Alternative methods found in association the D6751 the ASTM specification for biodiesel are accepted.

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SPECIFICATION FOR E GRADE ETHANOL

NORTH PIPELINE


Test

Methods

Shipments

Deliveries

Apparent proof, 60 F Hydrometer Report

Or Density, 60F D4052 Report

Water, Vol %, mas E3203 or E1064 1.0

Ethanol, Volume %, min D5501 93.5 93.0

Methanol, Volume %, max D5501 0.5

Sulfur, ppm (wt/wt), max D5453 10

Solvent Washed Gum

Mg/100ml, max Air jet

method

D381

5

Potential Sulfate, mass ppm, D7319

Max 4

Chloride, mg/L,

Max

D7319

5

Copper, mg/L,

Max

D1688

Procedure A

Modified per 4806

0.08

Acidity (as Acetic Acid), D1613

Mass %,max 0.007

pHe D6423

Minimum 6.5

Maximum 9.0

Appearance @ 60 F Visual examination Visibly free of suspended or precipitated

contaminants. Must be clear and bright

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SPECIFICATION FOR E GRADE ETHANOL (cont’d)

NORTH PIPELINE

Denaturant Content and Type Only approved denaturants and amounts listed in D4806

Corrosion Inhibitor Additive, Minimum treat rate Vendor Additive

One of the following is required 6 lbs./1000 bbls. Innospec DCI-11 Plus

20 lbs./1000 bbls. G.E.Betz Endcor GCC9711

20 lbs./1000 bbls. Octel DCI-11

20 lbs./1000 bbls. Petrolite Tolad 3222

20 lbs./1000 bbls. Nalco 5403

20 lbs./1000 bbls. Betz ACN 13

20 lbs./1000 bbls. Midcontinental MCC5011E

13 lbs./1000 bbls. Midcontinental MCC5011PHE

13 lbs./1000 bbls. Petrolite Tolad 3224

13 lbs./1000 bbls. US Water Services Corrpro 654

13 lbs./1000 bbls. US Water Services Corrpro 656

6 lbs./1000 bbls. Ashland Anergy ECI-6

3 lbs./1000 bbls. G.E. Power & Water 8Q123ULS

5 lbs./1000 bbls. Nalco EC5624A Plus

6 lbs./1000 bbls. US Water Services Corrpro Pro NT

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SPECIFICATION FOR Q GRADE COMMERICAL JET FUEL

NORTH PIPELINE



ASTM

Test

Methods

Minimum

Maximum

Deliveries

(At Terminals)

May Be*

Gravity, API D287 37.5 50.5 37.0 – 51.0

Acidity, Total, Mg KOH/g D3242 0.1

Freezing Point, F D2386 -40

Existent Gum, mg/100ml D381 5 7

Sulfur, Total, ppm D2622 +3000

Mercaptan Sulfur, ppm 1/ D3227 30

Color Saybolt D156 +16 +14

Corrosion, Copper D130 1

Water Separation Index D7224 85 75

Aromatics, vol. % D1319 25

Net Heat of Combustion,

BTU/lb 2/

D4809 18,400

Flash Point, F D56,D93 102 100

Viscosity @ -4 F, cSt D445 8

Electrical Conductivity, pSm D2624 Report

Thermal Stability;

Filter pressure drop, mm Hg.

Heater tube rating 5/

D3241 3/

25

<3

4/

Distillation, F @ 760 mm Hg

10% Recovered, F

50% Recovered, F

90% Recovered, F

Final Boiling Point, F

Residue, Vol. %

Loss, Vol. %

D86

396

Report

Report

562

1.5

1.5

400

572

OR

Simulated Distillation

10% Recovered, F

50% Recovered, F

90% Recovered, F

Final Boiling Point, F

D2887

365

Report

Report

644

Combustion

(1) Smoke Point, mm

D1322 25

OR

(2) Smoke Pain, mm D1322 18

AND Napthalenes vol. % D1840 3.0

Particulate Matter D5452 Report

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SPECIFICATION FOR Q GRADE COMMERICAL JET FUEL (cont’d)

NORTH PIPELINE

1/ The Mercaptan Sulfur determination may be waived if the result of a Doctor Test by

ASTM D4952 is negative.

2/ Equation 2 in D3338 may be used as an alternate method.

3/ ASTM D3241 Thermal Stability test must be conducted at 262 C for 2.5 hours at origin.

Peacock or abnormal color deposits result in a failure and are not accepted.

4/ ASTM D3241 Thermal Stability test results for deliveries will be generated at a minimum

test temperature of 260 C.

5/ 85 nm maximum by referee metrological methods Annex A3 ETTR or Annex 2 ITR.

Additives:

Antioxidants: Shipments may, but are not required to, contain a maximum of 8.4 pounds

per 1,000 barrels (not including weight of solvent) of the following anti-oxidants:

(1) N, N-diisopropylparaphenylene diamine.

(2) 75% (min) of 2, 6-ditertiary-butyl phenol plus 25% (max) of tertiary and tritertiary

butyl phenols.

(3) 72% (min) 2, 4-dimethyl-6-tertiary-butyl phenol plus 28% (max) of monomethyl

and dimethyl tertiary-butyl phenols.

(4) 55% (min) 2, 4-dimethyl-6-tertiary-butyl phenol plus 45% (max) of mixed tertiary

and ditertiary butyl phenols

Metal Deactivators: Shipments may, but are not required to, contain the following metal

deactivators at a maximum of 2.0 lbs per 1,000 barrels (not including weight of solvent):

(1) n, N-disalicylidene-1, 2-propane diamine.

No other additives are permitted.

The carrier shall not be responsible for the concentration of additives in jet fuel deliveries at

terminals.

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SEASONAL GASOLINE VOLATILITY

SHIPMENTS FROM ORIGIN

V-GRADE

NORTH PIPELINE

Jan Jan Feb Feb Mar Apr May Jun Jul Aug Sep Sep Oct Nov Dec 1-15 16-31 1-15 16-28 1-31 1-30 1-31 1-30 1-31 1-31 1-15 16-30 1-31 1-30 1-31

MN 15.00 15.00 13.50

13.50

10.00 8.50 9.00 9.00 9.00 9.00 9.00 11.50 13.50 15.00 15.00

E-5 E-5 D-5 D-5 B-45 A-4 A-4 A-3 A-3 A-2 A-2 C-3 D-4 E-5 E-5


ND 15.00 15.00 13.50

13.50

10.00 8.50 9.00 9.00 9.00 9.00 9.00 11.50 13.50 15.00 15.00


Abbreviations: MN= Minnesota

ND= North Dakota

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SEASONAL GASOLINE VOLATILITY

SHIPMENTS FROM ORIGIN

A GRADE PREMIUM GASOLINE

NORTH PIPELINE


MN 15.00 15.00 13.50

13.50

10.00 8.50 9.00 9.00 9.00 9.00 9.00 11.50 13.50 15.00 15.00



ND 15.00 15.00 13.50

13.50

10.00 8.50 9.00 9.00 9.00 9.00 9.00 11.50 13.50 15.00 15.00


Abbreviations: MN= Minnesota

ND= North Dakota

Version 1 – 2017 01 01

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Revision Table

Version No. Date Action(s)

1 1/1/17 Initial Issue

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