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    TheThe

    NucleusNucleus

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    Nuclear stability and radioactive decay Kinetics of radioactive decay

    Nuclear transformations Detection and uses of radioactivity

    Nuclear fission and fusion

    Effects of radiation

    The NucleusThe Nucleus

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    Nuclear chemistry is theNuclear chemistry is the

    study of the nucleusstudy of the nucleus

    Electron cloud

    Nucleus

    Electrons are

    very small and

    have a negativecharge. They

    are light and

    far apart

    The nucleus

    contains protons(+)and neutrons (0).

    They are very heavy

    and close together.

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    How do nuclei stickHow do nuclei stick

    together?together?

    Protons are allpositive and repel

    each other. This is the

    electronic force.

    All nucleons (p, n)

    have a new force, thestrong nuclear force

    that holds them

    together anyway.

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    Nuclear NotationNuclear Notation

    To keep track of what nucleons an atom has

    chemists write their symbols with two

    numbers

    In any reaction (nuclear or chemical) these

    numbers must also balance.

    C

    12

    6

    atomic mass = protons + neutrons

    atomic number = protons

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    Nuclear notation: GenericNuclear notation: Generic

    SymbolsSymbols

    XA

    Z

    equired, distinguishes one

    sotope from another

    Optional, redundant info

    With the element symbol

    Element symbol

    A nuclide can also be written: element-A

    carbon 14, is 14 C

    uranium 238 is238

    U

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    Find your Beaker! AndFind your Beaker! And

    respond to the following.respond to the following.Write the following atoms in nuclear notationPro/Neu Symbol Atom

    4/3 Be Be

    12/14 Mg Mg

    20/22 Ca Ca

    20/24 Ca Ca

    43/50 Tc Tc

    74

    26

    12

    42

    20

    44

    20

    93

    43

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    Types of RadioactiveTypes of Radioactive

    DecayDecayTo balance nuclear reactions we need to include particles with

    special names

    particle = helium nucleus He

    particle = electron e-

    positron e+

    Neutron n

    Proton = hydrogen nucleus H

    Gamma Ray

    4

    2

    0

    -1

    10

    1

    +1

    0+1

    00

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    Nuclear StabilityNuclear Stability Approx 1,500 different nuclei are known;

    about 264 are stable

    Elements with N/P ratio = 1:1 are stable

    Above atomic number 20, stable nucleihave a higher N/P ratio up to about 1.53:1

    Stable nuclei fall within a region called

    "band of stability"; if they fall outside area,

    they undergo spontaneous radioactive

    decay

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    Band ofBand of

    StabilityStability All nuclei with 84

    or more protonsare unstable

    Heavy nuclei withtoo many neutronsor too many

    protons areunstable

    Alpha Decay

    Positron emission and/orelectron capture

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    Nuclear StabilityNuclear Stability

    Nuclei below the zone of stability are likely toundergo:

    Positron production, + (too many protons and

    not enough neutrons so a proton is converted toa neutron and a positron is emitted)

    Electron capture, - (too many protons and not

    enough neutrons so a proton is changed into aneutron and an electron is captured in the

    process.)

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    Nuclear StabilityNuclear Stability

    Alpha particle production (an alphaparticle is released dropping the atomicnumber by 2 and the atomic mass by 4)

    Nuclei above the zone of stability are likelyto undergo:

    Beta particle production, - (too manyneutrons and not enough protons so anelectron is released as a neutron is

    converted to a proton)

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    Alpha Particle ProductionAlpha Particle Production

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    Nuclear StabilityNuclear Stability

    Gamma rays or rays are producedusually during a decay process that

    has emitted an alpha or beta particle.

    The gamma ray is a high energyphoton. They almost always

    accompany electron captureprocesses to release excess energy.

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    Decay of Uranium - 238Decay of Uranium - 238

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    Writing Nuclear EquationsWriting Nuclear Equations

    Write the nuclear

    equation representing thedecay of Potassium 40

    as it emits a positron.

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    Writing Nuclear EquationsWriting Nuclear Equations

    AnswerAnswer

    Fi dFi d R di tiR di ti

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    Find yourFind your RadioactivemanRadioactivemanand try these HOTand try these HOT

    Problems!!Problems!! 11 C produces a positron

    214 Bi produces a - particle

    237Np produces an particle

    Potassium - 40 captures an electron

    Potassium - 40 emits a - particle

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    More Practice!More Practice!Balance the following nuclear reactions:

    Gallium 73 transmutes to germanium-73Platinum -192 transmutes to osmium-188Bombarding alpha particles to anunknown element produces berkelium-243 and a neutronFusion of uranium-238 and carbon-12produces 6 neutrons and what otherelement?

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    Alpha Beta Gamma!Alpha Beta Gamma!

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    Geiger-Muller CounterGeiger-Muller Counter

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    elative Energieselative Energies particles are heavy,

    slow, and low energy.They cant penetrate

    paper.

    particles are small,

    fast, and medium

    energy. They cant

    penetrate foil

    rays are photons,have no mass, are fast,

    and high energy.

    Some may be stopped

    by lead.

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    Nuclear FissionNuclear Fission

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    Nuclear Power PlantNuclear Power Plant

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    Nuclear FusionNuclear Fusion

    St ll F ti f C bSt ll F ti f C b

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    Stellar Formation of Carbon -Stellar Formation of Carbon -

    1212

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    Effects of a nuclear bomb

    1) Explosive Blast

    - a lot of pressure makes houses fall down2) Direct Radiation

    - radioactive nuclei ejected from the bomb

    3) Thermal Radiation

    - heat and light that will burn you

    4) Radioactive Fallout

    - dust and debris are made radioactive, enter the

    atmosphere and spread long distances

    http://www.pbs.org/wgbh/amex/bomb/sfeature/effects.html

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    Plasma Ball of Early AtomicPlasma Ball of Early Atomic

    Bomb TestBomb Test

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    Plasma Ball of Early Atomic BombPlasma Ball of Early Atomic Bomb

    TestTest

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    How long doesHow long does

    radioactivity stay around?radioactivity stay around?

    Every radioactive nucleus has a half life.

    This is the amount of time before half of it is gone.

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    Half LifeHalf Life

    The amount of time it takes for half of the nuclide todecay.Time N

    0 100

    1 50

    2 25

    3 12.54 6.25

    5 3.125