november 2015 blair wisdom co-digestion – the path to success
TRANSCRIPT
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BLAIR WISDOM
CO-DIGESTION – THE PATH TO SUCCESS
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AGENDA CO-DIGESTION OVERVIEW FEASIBILITY ENSURE SUCCESS OF RECEIVING STATIONS
AND PRETREATMENT SAFEGUARD FOR STABLE DIGESTER
PERFORMANCE
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CO-DIGESTION OVERVIEW
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• It takes shape in many forms. Essentially, it is the addition of high strength waste (HSW) to anaerobic digesters
• Commonly practiced with the brown grease (BG) portion of fats, oils, and grease (FOG)
• Increasing focus on industrial and pre-consumer wastes• Dairy whey• Fruit/vegetable wastes• Institutional food wastes• Corn silage
WHAT IS CO-DIGESTION?
Black & Veatch | November 2015
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• Excess capacity in digesters may afford opportunity for revenue from tip fees.
• Regional haulers (FOG and others) may need an outlet (encourage them to keep it out of collection system.• Control where HSW are injected in plant –
turn from waste that consumes energy to an enhancement
• Increased load can make energy recovery more attractive
WHY WOULD YOU CO-DIGEST?
Black & Veatch | November 2015
Energy
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ORGANIC RESOURCES-TO-ENERGYCO-LOCATION/(CO)-DIGESTION AND GAS UTILIZATION
GAS UPGRADING
RNG
FLEET
PIPELINE
Sludge
WWTP
EXISTING DIGESTERS
CO-GEN GRID
COMMERCIAL ORGANICS
SOURCE SEPARATEDORGANICS/
ORGANIG FRACTION OF MSW
FOG
DEDICATEDDIGESTERS
Black & Veatch | November 2015
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• Reliable systems provide valuable service to industries
• Increased revenue
• On-site power production provides greater reliability
• Flexibility for multiple energy uses
CO-DIGESTION CAN ENHANCE OVERALL SUSTAINABILITY
Black & Veatch | November 2015
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PROS/CONS OF CO-DIGESTION
Black & Veatch | 2 September 2015
Source: Braun, Wellinger (2003); Grasmug, Braun (2003); Schmelz (2007); STOWA, (2006) adapted
ADVANTAGES Synergistic effects (location, infrastructure) Qualified & experienced personnel on site Improves digester performance thanks to
symbiotic behaviors Increase in revenues through tipping fees Self-sufficient generation of renewable energy on-site achievable Biosolids contain less contaminants, more
nutrients, and are more suitable for agricultural use than conventional biosolids
Increased in gas production and quality Improved economics, benefitting rate payers for
publically owned treatment works
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PROS/CONS OF CO-DIGESTION
Black & Veatch | 2 September 2015
Source: Braun, Wellinger (2003); Grasmug, Braun (2003); Schmelz (2007); STOWA, (2006) adapted
DISADVANTAGES Capital costs; feedstock receiving station and
conditioning/removal of contaminants before feeding digester and increased mixing may be required
Increased chemical oxygen demand (COD)/nutrient load of digestate’s filtrate
Foam formation and scum layers in digester Odors Dewaterability: increased amount of biosolids Hygienization may be required Deposition of material (pipe & valve blockage;
reduced digester volume) Mixing Challenges
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FEASIBILITY
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PROCESS CAPACITY
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• Drivers: • Combat rising energy costs• Institute sustainable practices• Fully utilize equipment capacities
• Capacity evaluation:• Average 32 day SRT• 100 ppd of VS/kcf
ROCK RIVER WATER RECLAMATION DISTRICT
Black & Veatch | November 2015
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ROCK RIVER EXISTING STABILIZATION AND GAS HANDLING
Excess Digester Capacity Excess Gas Treatment Capacity
Excess Engine Generator Capacity
Limited Gas Handling Capacity
Black & Veatch | November 2015
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AVAILABILITY OF HSW
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SIGNIFICANT BIOGAS POTENTIAL IN HIGH STRENGTH WASTES
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Black & Veatch | November 2015
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ORGANIC FEEDSTOCKS & PROPERTIES FOR AD
MANURE, SEWAGE SLUDGE; FOOD PROCESSING WASTE
INDUSTRIAL SLUDGE (e.g. Thin Stillage from EtOH Production); BG (FOG)
SLAUGHTER HOUSE WASTES
COMMERCIAL FOOD WASTES(Restaurants; Cafeterias)
COMMERCIAL FOOD WASTES (Groceries; Packaged Waste)
RESIDENTIAL SOURCE SEPARATED ORGANIC WASTE; ORGANIC FRACTION OF MSW
Increase in total solids (TS) content
Decrease in homogeneity
Increase in contamination(non-digestible)
Black & Veatch | November 2015
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AREA SPECIFIC HSW
• Survey industries in service area• Evaluate characteristics & value of available wastes
• pH• Total and Volatile Solids (TS and VS)• Total and Soluble COD• Total Ammonia Nitrogen (TAN) • Total Kjeldahl Nitrogen (TKN)• Volatile Fatty Acids (VFA) • Long Chain Fatty Acids (LCFA)• Alkalinity• Gas Production and Composition• Capillary Suction Time (CST) and Sludge Dewatering• Biosolids Odors
• Determine loading and any adverse effects
Black & Veatch | November 2015
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• Increased interest in yellow grease for biodiesel• Gasoline price fluctuations• Carbon footprint/offsets
• Increased use of yellow grease in • Animal feed• Cosmetics
• Increased consideration as substrate for industrial anaerobic Digestion
• Grant/offset benefits• Renewable energy generation
• Reduced restaurant generation from recession
INCREASED COMPETITION FOR FOG – LONG TERM OUTLOOK?
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Black & Veatch | November 2015
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OBJECTIVES & MEASURES: Increase of Waste Diversion
towards Zero Waste Goal (meet local, state and federal landfill diversion and/or organics ban requirements)
Closing Carbon and Nutrient Loop
Cheap and plentiful feedstock for energy production
Educate food establishments,food processors, retailers, andresidents of organics collection
COMMERCIAL AND RESIDENTIAL SOURCE SEPARATED ORGANICS - CO-DIGESTION
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Black & Veatch | November 2015
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AVAILABILITY OF HSW
Contacted 50 companies in surrounding area
Conclusions of HSW Survey• Abundant supply of Non-FOG high strength wastes
• Thin stillage, dairy wastes, distillers syrups• 4,000 to 5,000 gallons per day of FOG waste generated within
the district’s service area• Another 20,000 gallons per day of FOG waste generated
Around the district’s service area
Adequate Supply for 20,000 GPD HSW Facility
Black & Veatch | November 2015
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ASSESS THE BENEFITS
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Operational Costs• Some added maintenance• Added loads to the plant• Potentially added biosolids
disposal costs
B&V - 22
WHAT ARE THE OPERATIONAL COSTS AND BENEFITS?
Operational Benefits• Increased biogas• Increased waste heat from
engine generators• Tipping fees• Service to customers
Black & Veatch | November 2015
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ENSURE SUCCESS OF RECEIVING STATIONS AND PRETREATMENT
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HAULING CONSIDERATIONS
• What type of wastes are being processed?• Processed source separated
food wastes?• “Liquid” high strength wastes?
• Efficient truck unloading• Hauling schedules?• Multiple trucks at a time?
• Cleaning stations• Weigh scales• Hauled load management
and billing
Black & Veatch | November 2015
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PRE-TREATMENT AND MATERIALS HANDLING ISSUES
Pretreatment: Rock traps, screens, grinding, depackaging (industrial wastes) Remove non-biodegradable
materials Protect downstream equipment Reduce particle size to optimize
digestion Storage tanks
Mixing Site specific heating Heat tracing, HEX, mixing with
warm sludge
Black & Veatch | November 2015
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DEBRIS IN HAULED WASTES
Black & Veatch | November 2015
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FOG/BG CO-DIGESTION EXAMPLE: WATSONVILLE WWTP
Source: Kester, G. (2008)
PLANT DESIGN CAPACITY: 12 MGDFOG CO-DIGESTION: 3,000 – 10,000 GAL/DAY
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Black & Veatch | November 2015
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EXAMPLE – DES MOINES WRA - 170,000 GALLON RECEIVING TANK
Black & Veatch November 2015
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DES MOINES WRA - RECEIVING/STORAGE TANK
• Mixed via recirculation pumps and nozzles
• Lined for corrosion control
Black & Veatch | November 2015
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SUMMARY OF RECEIVING CONCEPTS
BASIC OR SOPHISTICATED SYSTEMS – NO TWO ARE THE SAME!
• Simple systems with rock-boxes - traps grit/debris before larger tank
• Mechanical systems for removing debris• Some have storage while others go straight to
digesters• Heating? Is it needed?
Black & Veatch | November 2015
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SAFEGUARD FOR STABLE DIGESTER PERFORMANCE
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OPEQUON WRF – FREDERICK WINCHESTER SERVICE AUTHORITY (FWSA)
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Black & Veatch | November 2015
• Current Solids Treatment:• Lime-Stabilized biosolids – landfill
disposal• Frame and Plate Filter Presses
• Design Solids Process:• Two mesophilic primary digesters
and one secondary digester
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SOLIDS PROCESS Black & Veatch | November 2015
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SOLIDS DESIGN SUMMARY
• Substrates for co-digestion:• Wastewater sludge• Kraft Foods waste• Dairy whey waste• GTW and DAF Float• Food waste
Solids retention time, daysMaximum Month
Annual Average
1520
VS Loading Rate, ppd/kcfMaximum Month
Annual Average
154132
Expected Volatile Solids Reduction, %Maximum Month
Average Annual
4545
Black & Veatch | November 2015
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PILOT TESTING - DIGESTER SET UP AND OPERATION
• 4 digesters with working volume of 9.75L, 15 day SRT
• Mesophilic temperature (370C)• Seeded with 8 Liters of digester
effluent from Christiansburg WWTP
Schematic Diagram showing
Digester setup
Black & Veatch | November 2015
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PARAMETERS ANALYZED
• pH• Total and Volatile Solids (TS and VS)• Total and Soluble COD• Total Ammonia Nitrogen (TAN) • Total Kjeldahl Nitrogen (TKN)• Volatile Fatty Acids (VFA) • Long Chain Fatty Acids (LCFA)• Alkalinity• Gas Production and Composition• Capillary Suction Time (CST) and Sludge Dewatering• Biosolids Odors
Black & Veatch | November 2015
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Waste Characteristics (Part II)
High Strength Waste Total COD(mg/L)
TS(mg/L)
VS(mg/L)
GTW 50,000 40,000 37,000
Whey 87,000 78,000 56,000
DAF 600,000 300,000 285,000
Juice waste 76,000 44,000 43,000
Sludge Mix ~35,000 ~30,000 ~23,000
Part I: Feed contained Juice Waste and Whey Waste only. Digester performance was assessed and the roles of alkalinity and VFA concentrations were evaluated
Part II: Carried out in three phases with increasing concentrations of all the food wastes listed in the table above.
Black & Veatch | November 2015
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• Total Time of Operation: 310 Days• The above mentioned compositions were attained on Day 180• Juice processing waste underwent a sudden, drastic change on Day 240• New waste much “stronger”• Digester 4 which was receiving the highest HSW load by volume
exhibited failure
Black & Veatch | November 2015
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• Wastes being added were acidic in nature, especially the juice processing waste
• The sudden change in the nature of the waste seems to have inflicted a “shock load” on the digester that exhibited failure
“Old” Juice
waste“New” Juice
Waste
pH 4.10 3.10
Total Solids (mg/L)
32,000 72,000
Volatile Solids (mg/L)
31,000 68,000
Total COD (mg/L)
66,000 208,000
Failure Caused by Shock Load to Digester
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Acidic wastes can reduce buffering capacity of anaerobic systems.
The nature of the wastes to be added as co-substrates to anaerobic digesters is therefore something that must be thoroughly studied
Similar Juice mix with supplemental ammonia did not show failure
Variability in the nature of the HSW must be monitored as sudden changes in the HSW feed might push digesters to failure
Black & Veatch | November 2015
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Black & Veatch | November 2015
0 2 4 6 8 10 120
10
20
30
40
50
60
70
80
Control 8% DAF 12% DAF 16% DAF20% DAF 25% DAF 5% GTW 9% GTW12% GTW 16% GTW 22% GTW 16% GTW (Diluted)22% GTW (Diluted)
Time in days
Cum
ulati
ve B
ioga
s Pro
ducti
on (m
L)Biomethane Potential Analysis
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