Nissin Chemical Industry Co.,Ltd.

VINYBLANVinyl Chloride Emulsion

Vinyl chloride emulsion

This is a world-�rst, ground-breaking emulsion that has been developed using the company’sunique polymerization technology. The product is extensively used and highly rated because it leverages the features of vinyl chloride to provide excellent dispersion of colorant etc., chromogenic properties and �ame resistance.

Features of Vinyblan

Vinyblan is a copolymerized resin consisting of vinyl chloride with acrylic acid ester and vinyl acetate, it has the following features: 1) Water-based emulsion for excellent safety. 2) Chemical stability enables excellent miscibility with all kinds of emulsions, inorganic colorants, plasticizers. 3) Coats of paint are �ame-resistant thanks to self-extinguishing properties. 4) Coats of paint have excellent resistance to plasticizer, alcohol, acid, and alkal. 5) Strong polarity from vinyl chloride resin, and excellent chromogenic properties when printing.

Paintingmaterial/ink applications

All kinds of painting materials/ink binders

Media absorbing layer applicationsInkjet printing absorbing layer/

heat sublimating printing absorbing layer

Textile treatment applicationsFlameproo�ng for

non-woven fabrics and textiles, etc.

1

150 63 58 12

Grade Solid Content%

Viscosity(mPa•s) PH

Averageparticle size

(nm)

Tg(˚C)

MFT(˚C)

Acid Value(KOHmg/g)

Vinyl chloride/acrylic acid ester group emulsion products(Vinyl chloride/acrylic acid ester copolymer)

271

8.5

8.5

7.5

278

690

902

900

43

43

54

50

40

200

200

300

200

230

180

500

330

200

-3

33

46

60

70

0

46

60

80

Min. 80ºC

14

5

6

9

6

B-type viscometer/23˚C X 6rpm

Vinyl chloride/vinyl acetate group emulsion products(Vinyl chloride/vinyl acetate copolymer)

500 7.5

8.5

Vinyl chloride emulsion products(Vinyl chloride copolymer)

7.5700

30

30

50

50

30

30

73

70

46

57

7.5

Vinyl chloride /Polyurethane aqueous solution(Vinyl chloride copolymer)

Min. 80ºC

701

603 50 300 6.0

985 37 300 6.0 70 80 5Min. 80ºC

VINYBLAN grades

Min. 80ºC

2

715S 25 10 7.5 90 25 80ºC

7.5745

30

30

100

50

140

70

55

57

31

50

7.5

Vinyl chloride / Acrylic aqueous solution products(Vinyl chloride copolymer)

Min. 80ºC

737 47ºC

30 300 7.5 100 42 450ºC

747 30 50 7.5 6650 58ºC 35

735

Highly �ame-resistant. Endows all kinds of emulsionswith �ame resistance.

Textile Treatment

The main ingredient of Vinyblan is vinyl chloride, providing excellent �ameresistance. It can be used as a �ame-resistant binder in �ame resistance �nishingof textiles/non-woven fabrics. It can be applied in various methods, including spray, gravure, foaming and dipping.

FeaturesFeatures

900Hard Type, Satisfactory heat resistance (no discoloration)

25.5 70

N

902

690

985

Semi-hard type

Oxygen index number measurement methodTest pieces: Vinyblan 278/690/900/985

Test piece production: Each Vinyblan is poured onto the mold of mold release paper, and items of the right size that have been dried with a desiccator (80˚C - 120˚C) are cut and taken as test pieces. (Test piece size: length 10cm x width thickness 1mm).Combustion test: LOI Standard (conforming to JIS K7201).

Flame resistance (MVSS) measurement methodBacking: 100% polyester woven fabric.Coating volume: 50g or 100g/m2 (dry)Treatment: DippingDrying: 130˚C X 5 minutesFlame resistance: MVSS-302 standard

N

N

N16025.0

6027.5

31.0 N

High solid content. Satisfactory heat resistance (no discoloration)

271

Application GradeOxygen

index number(LOI value)/

TextileNon-woven fabricFireproo�ng

278 Soft type

Noncombustibility(MVSS standard)Coating volume 100g[mm/min]

Features

Non combustibility(MVSS standard)Coating volume

50g[mm/min]

24.5 140 N

Fiber �ameresistance

4

Painting material Painting materials can be endowed with �ame resistance.

Paint/Ink binder applications

Vinyblan can be used as a binder in water-based paint, coating, and ink formulations. It is highly regarded for its adhesion to vinyl chloride substrates, its colorant dispersion due to the strong polarity of vinyl chloride, and its mechanical stability. The 700 series has excellent adhesion to all kinds of substrates due to the polymerization of acrylic aqueous solution as protective colloid.

Media applications

By using Vinyblan surfaces can be endowed with excellent chromogenic properties.

278603701900985

Products within this group have:Very good chromogenic propertiesThermochromic resistance

278

700701

715S735737745747

Gravure inkInkjet inkPaper coating

Small particle sizeProduces a very transparent �lmSuperior water and/or alcohol resistance Excellent colorant dispersionCan be used with varrious alcohols and solvents

Application Grade Features

Screen Printing

603

Suppress the increase in viscosity after mixing the silica, printing surface can be endowed with outstanding chromogenic properties.

Application Grade

Industrial IJ printingabsorbing layer

Heat sublimating printing absorbinglayer

278Transparent �lm formation possible.(100 - 120ºCX10 seconds, thickness 5 microns).

Features

High level of chromogenic properties, Superior water resistance after �lm formation.

701

3

700 278

Features

700 series schematic diagram

1. Excellent water resistance since it does not use emulsi�er.2. Normal temperature deposition is possible by using alcohol as a solvent.3. Minute particle size enables production of �lms that have glossy transparency.4. Excellent dispersion and satisfactory miscibility with organic pigment and all other kinds of addition agents.

Common emulsion 700 series

Emulsi�er molecule

Polymer moleculePolymer molecule

With minus charge With minus charge

Hydrophilic groupLipophilic group

Hydrophilic group

5

700

701

715S

30

30

23

50

50

50

7.5

7.5

7.5

30

30

90

70

73

25 0

57

46

8

B-type viscometer/23°C×6 rpm

Min. 80°C

Min. 80°C

Solid content(%)

Viscosity (mPa•s)

Average particle size (nm)

Acid value (KOHmg/g)Grade PH Tg（℃） MFT（℃）

VINYBLAN 700 series.

The VINYBLAN 700 series is a polymerized vinyl chloride emulsion that hasbeen developed without using any emulsi�er, based on the company's unique technology as a protective colloid for acrylic aqueous solutions, etc.

Acrylic aqueous solution 700 701 715S

×

×

○

○

○

○

○

○

271/278 ７００ ７０１ 715S

All kinds of solvent resistance tests.

Colorant dispersion

Test piece: Glass plate painted with Bar Coater No.6100 °C ×5 minutes drying.Testing: Drip pure water/alcohol/plasticizer on �lm and observe state after 24 hours.

Testing method

No change No change No change No change

Whitening No change No change No change

Swelling No change No change No change

Pure water

Alcohol (methyl alcohol)

Plasticizer (DOP)

Miscibility

Dispersion

E.g., Drip methyl 　　 alcohol

Blank After 24 hours

Test piece: Adjusted with carbon black MA100 (manufactured by Mitsubishi Paper Mills, Ltd.) 20g, each Vinyblan 67g, and pure water 13g.Miscibility: We determined whether or not the adjusted test piece and colorant would mix.Stirring conditions: Stirred with dispar at 2000 rotations×30 minutes.　　○: Mixed without thickening.　　△: Mixed but thickened.　　×: Did not mix, and aggregate was produced. Dispersion: Successive precipitation was determined by the following criteria.　　○: No precipitation.　　△: Precipitated, but with repeated stirring possible.

6

Acrylic aqueous solution

Acrylic aqueous solution

715S 715S

Acrylic aqueous solution

３２～３２～３１２～３２～３２２１２２～３２２１２

Methanol / Isopropanol

Diethylene glycol / Triethylene glycol

Diethylene glycol mono n-butyl ether（IPA併用）2-pyrrolidone / N-methyl pyrrolidone

Triethylene glycol mono-n-butyl ether

1,5 Pentane diol

MEK

MIBK

3

3

2～ 1（3）3

3

3

3

2

3

3

2～ 1（3）3

3

3

2

1

3

3

2～ 1（3）3

3

3

2

1

７００

３３３２３３３２２～３３３３２２３

７０１

３３３２～３３３３２～３３３３３２～３２～３３

７１5S

３３３３３３３３３３３３３３３

700 701 715S

3：Mixture possible　2：Viscosity increasing　1：Gelation

3：No change　2：Partially peeling or Slightly Whitening　1：Peeling or Whitening

Adhesion to the various substrates

Testing method

Solvent miscibility.

Gluing properties

Abrasion resistance

Water resistant friction property

Alcohol resistance

Water resistance

Gluing properties

Abrasion resistance

Water resistant friction property

Alcohol resistance

Water resistance

Gluing properties

Abrasion resistance

Water resistant friction property

Alcohol resistance

Water resistance

Solvent

Mixture: Sample: VINYBLAN: IPA: Diethylene glycol n Butyl ether : Water=20:15:15:50　Paint: Painted with Bar Coater No.6 on each substrate 　Dried: 60°C ×１min

Gluing properties: Tape peeling test Abrasion resistance: Rubbing test was carried out using gauze (load 200g, repeated 30 times).Water resistant friction property: Rubbing test was carried out using gauze dipped in water (load 200g, repeated

30 times).Alcohol resistance: Rubbing test was carried out using gauze dipped in IPA (load 200g, repeated 30 times).Water resistance: The painted substrate is immersed in water at normal temperatures and allowed to soak for

one hour, then conditions are observed.

PET

PVC

Aluminum

Mixing ratio:VINYBLAN,water and solvent in the propotion 7:5:2.

7

VINYBLAN 700 series.

２７１２７８６０３６９０９００９０２９８５

3

3

3

3

3

3

2

2

1

1

2

1

3

3

3

3

3

3

2

2

1

TPG/PG TPM CS-12 DPNB/TPNB DPNB:TPM=1:1

700:DPNB=1:1※

150001400013000120001100010000

900080007000600050004000300020001000

00 10 20 30 40 50 60 70

271

278

603

690

900

700

701

902

715S

690（TPM）278（TPM）690（CS-12）278（CS-12）

MFT （℃）

0 5 10 15

70

60

50

40

30

20

10

0

-10

Tripylene glycol/Propylene glycol 2,2,4-Trimethyl-1,3-pentanediol monoisobutyrate (TEXANOL)

Tripropylene glycol methyl ether Dipropylene glycol n- butyl ether Tripropylene glycol n- butyl ether

Water-soluble high-boiling solvent can be mixed.Even high-boiling solvent that is not water-soluble can be mixed if it is mixed in advance with water-soluble high-boiling solvent or Vinyblan 700.

Miscibility with the high-boiling solvent and VINYBLAN.

Testing method

3： Mixture possible　2： Mixture possible by strong stirring　1： Gelation

All kinds of phthalate plasticizers

Thickening curve for each grade.

Additional example

Amount of UH-450VF added［g/1000gEm］

Visc

osity

(m

P a ・

s)

Ratio of deposition agent mixture (%)

Change to MFT by means of ratio of deposition agent mixture

Example of VINYBLAN adjustment.

1. Adjustment of viscosity.

2. Example of adjustment of MFT (Minimum Film Temperature).

Thickener: Adekanol UH-450VF (manufactured by ADEKA, Inc.)Gluing properties: All kinds of emulsions are added, and

measurements are taken at 23°C/6rpm (BM-type viscometer).

8

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Nissin Chemical Industry Co., Ltd.+81.3.3295.3931www.nissin-chemical.co.jp

CautionPlease retain the information on the product safety data sheet and technicalinformation.Please limit the use of this product toindustrial uses.Data from this catalog are notspecification values. To determine ifthis matches your purpose of use,please carry out your own companytesting in advance.Furthermore, introduction of useapplications contained herein is not aguarantee against patent infringement.Changes in descriptions in this catalog,improvements in performance, andchanges in specifications may occurwithout proir notification.Prior to reproducing any of this material please contact us.

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Nissin Chemical Industry CO., Ltd.

Jan. 2018