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National Energy Technology Laboratory
Kristin Gerdes
Office of Program Performance and Benefits
January 9, 2014
EPRI / NETL Energy Analysis Exchange Webinar
NETL Studies on the Economic Feasibility of CO2 Capture Retrofits for the U.S. Power Plant Fleet
• NETL – John Wimer
– Michael Matuszewski
– Charles Zelek
– Jose Benitez
– Robert Stevens
– James Black
• Booz-Allen – Vincent Chou
• Worley-Parsons
• OnLocation
Acknowledgments
2
NETL Carbon Capture Retrofit Analyses
3
Energy Velocity: Unit-Specific
Data
NETL CCRD
Carbon Capture Retrofit Database
PC, NGCC, Industrial
New SOA Post-Combustion
Capture System Quotes Systems Analysis of
Capture Retrofits for Reference Plants:
PC, NGCC, Industrial
Analysis of Cost Metrics for
Existing Fleet
FE/NETL CO2 CTUS
NEMS
2nd Generation Post-Combustion Capture System
Cost/Perf
QGESS: Retrofit Cost Estimating Methodology
NETL Carbon Capture Retrofit Analyses
4
Ventyx Energy Velocity
Database: Unit-Specific Data
NETL CCRD
Carbon Capture Retrofit Database
PC, NGCC, Industrial
New SOA Post-Combustion
Capture System Quotes Systems Analysis of
Capture Retrofits for Reference Plants:
PC, NGCC, Industrial
Cost of Capture Curves for
Existing Fleet
FE/NETL CO2 CTUS
NEMS
2nd Generation Post-Combustion Capture System
Cost/Perf
QGESS: Retrofit Cost Estimating Methodology
• For greenfield plant, COE impact is minor while cost of capture is slightly higher for new quote due to its higher efficiency
Baseline Retrofit Capture Technology Update
PC Plants Technology/Quote Vintage
Metric 2005 Amine 2012 Amine
Net Energy Penalty [kWhnet/lb CO2 Captured]
0.181 (+26%)
0.144
Reference Capital Cost [$/tpd CO2 Capt. @ full load]
$55,400 (-17%)
$66,400
Incremental Fixed O&M [$/tpd CO2 Capt. @ full load]
$1,828 (-5%)
$1,926
Incremental Variable O&M [$/tpd CO2 Capt. @ full load]
$2.59 (-50%)
$5.13
CO2 Capture Basis [tpd] 11,216 11,216
5
6
0.0000
0.0500
0.1000
0.1500
0.2000
0.2500
NGCC-2012 PC-2012 NGCC-2005 PC-2005
Ene
rgy
pe
na
lty
[kW
h/l
b c
aptu
red
CO
2]
Electrical Derate
Steam Turbine Derate
Net Derate Contributions
2005
69% 64% 61% 57%
PC: ~30% reduction in regeneration energy penalty
NGCC: ~15% reduction in regeneration energy penalty
NETL Carbon Capture Retrofit Analyses
7
Energy Velocity: Unit-Specific
Data
NETL CCRD
Carbon Capture Retrofit Database
PC, NGCC, Industrial
New SOA Post-Combustion
Capture System Quotes Systems Analysis of
Capture Retrofits for Reference Plants:
PC, NGCC, Industrial
Analysis of Cost Metrics for
Existing Fleet
FE/NETL CO2 CTUS
NEMS
2nd Generation Post-Combustion Capture System
Cost/Perf
QGESS: Retrofit Cost Estimating Methodology
Reference Capture Plants: Cost of Electricity
DRAFT Results 8
57
90
46
80 81
146
45
124
0
20
40
60
80
100
120
140
160
No
n-C
aptu
re
90
% C
aptu
re
Exis
tin
g
90
% C
aptu
re
No
n-C
aptu
re
90
% C
aptu
re
Exis
tin
g
90
% C
aptu
re
Greenfield Retrofit Greenfield Retrofit
NGCC with NG @ $6.13/MMBtu PC
CO
E, 2
01
1$
/MW
h
T&S
Fuel
Var O&M
Fix O&M
Capital
• Cost Retrofitting with CCS economically incentivized via sale of CO2 if:
• When normalized by CO2 captured, the above becomes: – Cost of capture
– Minimum CO2 plant gate price for which CCS retrofits are incentivized
Cost of Capture for CCS Retrofits
Annual Revenues from Sale of
Captured CO2
Annualized Capital and Incremental O&M
Costs for Retrofit
Annual Revenues Foregone Due to Lost Generation (Derate)
≤ +
Reference Capture Plants: Cost of Capture
NG Price = $6.13/MMBtu Market Power Price = $60/MWh
10
80
89
61
72
0
10
20
30
40
50
60
70
80
90
100
Greenfield Retrofit Greenfield Retrofit
NGCC PC
Co
st o
f C
aptu
re, 2
01
1$
/to
nn
e C
O2
Energy PenaltyLost ProfitEnergy Penalty
O&M
Capital
DRAFT Results
NETL Carbon Capture Retrofit Analyses
11
Energy Velocity: Unit-Specific
Data
NETL CCRD
Carbon Capture Retrofit Database
PC, NGCC, Industrial
New SOA Post-Combustion
Capture System Quotes Systems Analysis of
Reference Capture Plants:
PC, NGCC, Industrial
Analysis of Cost Metrics for
Existing Fleet
FE/NETL CO2 CTUS
NEMS
2nd Generation Post-Combustion Capture System
Cost/Perf
QGESS: Retrofit Cost Estimating Methodology
• Carbon Capture Retrofit Database (CCRD)
– Existing pulverized coal fleet
– Existing NGCC fleet
– Industrial sources
• Ammonia
• Cement
• Ethanol
• Refinery hydrogen
• Natural gas processing
NETL CCRD
12
• Data on 1,355 individual PC units (324 GW) and 601 (216 GW) NGCC units – Key information: Unit ID, Nameplate Capacity, Heatrate,
CO2 Emissions, Capacity Factor, Base Plant O&M Costs
• Cost and performance parameters – Retrofit capital costs, incremental O&M costs and scaling
approach
– Derate (in kWh/lb CO2 captured)
– Can be modified to reflect impact of R&D
• Calculation of cost of capture, incremental COE, etc.
• Sensitivities to economic life, capacity factor, etc.
• Filter by plant size, age, etc.
NETL CCRD PC and NGCC
13
14
0%
5%
10%
15%
20%
25%
30%
35%
40%
7,000 8,000 9,000 10,000 11,000 12,000 13,000
Po
we
r P
en
alty
[% o
f ori
gin
al o
utp
ut]
Pre-Retrofit Heat Rate [BTU/kWh HHV]
Net Output Penalties of CCS Retrofits
PC-2005 Amine
PC-2012 Amine
PC-Sorbent Based
PC-Membrane Based
Ideal Power Penalty
Net Derate Projections*
*As evaluated on baseline existing plant. Does not include balance of plant improvements
Includes: •Regeneration Energy •Capture Electrical •Compression Electrical •Off-design ST Operation
Thermodynamic Advancements
0.181 kWh/lb
0.144 kWh/lb
0.143 kWh/lb
0.113 kWh/lb
0.048 kWh/lb
• Retrofitting with CCS economically incentivized via sale of CO2 if:
– When normalized by CO2 captured, the above becomes the cost of capture or the
minimum CO2 plant gate price for which CCS retrofits are incentivized
• NETL Carbon Capture Retrofits Database (CCRD) provides retrofit assessments for entire fleet
Incentivizing CCS Retrofits with EOR Revenues
Annual Revenues
from Sale of Captured CO2
Annualized Capital and Incremental O&M
Costs for Retrofit
Annual Revenues Foregone Due to Lost Generation (Derate)
≤ +
Ventyx Energy Velocity: Unit-specific data
NETL CCRD PC, NGCC,
Industrial Sources
Scales retrofit costs and calculates
derates and lost revenues for units in
entire fleet
NETL Retrofit Studies: Incremental cost and
derate of retrofits for example plants
$ per Mwh
kWh lost per lb CO2
$ per lb CO2
Output, CO2 emissions,
heat rate, etc.
AEO/NEMS: Projected electricity price
(to estimate lost revenues)
CO2 Supply Curves:
Minimum CO2 plant gate price for which
CCS retrofits are incentivized for each
unit in the fleet
0
50
100
150
200
250
300
50 55 60 65 70 75 80 85 90 95 100
Cu
mu
lati
ve R
etro
fits
In
cen
tivi
zed
(G
W p
re-r
etro
fit)
Minimum Plant Gate CO2 EOR Revenue Required to Incentivize CCS ($/tonne)
15
NETL Carbon Capture Retrofit Analyses
16
Energy Velocity: Unit-Specific
Data
NETL CCRD
Carbon Capture Retrofit Database
PC, NGCC, Industrial
New SOA Post-Combustion
Capture System Quotes Systems Analysis of
Capture Retrofits for Reference Plants:
PC, NGCC, Industrial
Analysis of Cost Metrics for
Existing Fleet
FE/NETL CO2 CTUS
NEMS
2nd Generation Post-Combustion Capture System
Cost/Perf
QGESS: Retrofit Cost Estimating Methodology
1. Estimate cost and performance for state-of-the-art retrofit for baseline existing plant
2. Identify system that meets 2nd Generation goal of $40/tonne for baseline greenfield plant – Conceptual, 550MW greenfield installation
– Includes benefits of A-USC Steam cycle
3. Apply same 2nd Generation capture technology to baseline existing plant – Retain existing limitations such as fixed steam
cycle, non-capture heat rate, etc. and exclude advanced technologies that could improve the base plant (e.g., AUSC materials)
4. Extrapolate SOA and 2nd Gen performance and cost to existing power plant fleet
5. Assess market competitiveness for entire fleet – incentivizing CCS with CO2 sales
Analysis of CCS Retrofits of Existing PC Fleet
New CCS
Existing CCS
17
18
2030 Oil Prices May Support EOR CO2 Prices that are Equal to or Above CO2 Capture Costs
0
10
20
30
40
50
60
70
80
20 40 60 80 100 120 140 160 180
CO
2 E
OR
Pri
ce a
t P
ow
er
Pla
nt
Gat
e ($
/to
nn
e)
WTI ($/bbl) From 2008 to mid-2011, the average annual new contract price for CO2 ($/MSCF) at the Denver City, Texas “hub”, varied between 1.8% and 2.5% of the average annual WTI Crude oil price ($/bbl) in the corresponding years. Expressed in $/tonne, this is 34% to 47% (at standard conditions of 60 ⁰F and 14.7 psia). (The non-averaged contract prices ($/MSCF) varied between 1.4 and 3.3% of the oil price between 2008 and mid-2011.) Source: Chaparral Energy “US CO2 & CO2 EOR Developments” Panel Discussion at CO2 Carbon Management Workshop December 06, 2011. Estimated 100 km pipeline transport cost of $3.65/tonne is subtracted to convert the historical “hub” price to an estimated power plant gate price.
Probable CO2 Prices
Unlikely CO2 Prices
$138/bbl*
$61
$42
*NEMS Projection
-50
0
50
100
150
200
250
300
350
0 10 20 30 40 50 60 70 80 90
Cu
mu
lati
ve
Retr
ofi
ts I
nc
en
tiviz
ed
(G
W p
re-r
etr
ofi
t)
Minimum Plant Gate CO2 EOR Revenue Required to Incentivize CCS ($/tonne)
State-of-the-Art
UnlikelyCO2 Prices
abovehistorical range
PossibleCO2 Prices
withinhistorical range
ProbableCO2 Prices
belowhistorical range-50
0
50
100
150
200
250
300
350
0 10 20 30 40 50 60 70 80 90
Cu
mu
lati
ve
Retr
ofi
ts I
nc
en
tiviz
ed
(G
W p
re-r
etr
ofi
t)
Minimum Plant Gate CO2 EOR Revenue Required to Incentivize CCS ($/tonne)
State-of-the-Art
2nd Generation
UnlikelyCO2 Prices
abovehistorical range
PossibleCO2 Prices
withinhistorical range
ProbableCO2 Prices
belowhistorical range
Minimum Plant Gate CO2 EOR Revenue to Incentivize CCS – Year 2030
*NEMS Projections. Capital costs reflect ~15% premium due to increase in oil prices.
• Same CF pre- and post-retrofit
• 30-yr economic life
• $75/MWh* power price
• $138/bbl oil*
2nd Generation technology provides ~24% decrease in top decile CO2 price
32.4GW (top decile)
19
0
50
100
150
200
250
300
350
-60 -40 -20 0 20 40 60 80 100
Cu
mu
lati
ve
Re
tro
fits
(G
W p
re-r
etr
ofi
t)
Marginal Costs w/CO2 Revenue [$/MWh]
Pre-Retrofit
Post-Retrofit - no EOR Revenue
Post Retrofit w/CO2 Revenue ($10/tonne)
Post Retrofit w/CO2 Revenue ($30/tonne)
0
50
100
150
200
250
300
350
-60 -40 -20 0 20 40 60 80 100
Cu
mu
lati
ve
Re
tro
fits
(G
W p
re-r
etr
ofi
t)
Marginal Costs w/CO2 Revenue [$/MWh]
Pre-Retrofit
Post-Retrofit - no EOR Revenue
Post Retrofit w/CO2 Revenue ($10/tonne)
Post Retrofit w/CO2 Revenue ($30/tonne)
0
50
100
150
200
250
300
350
-60 -40 -20 0 20 40 60 80 100
Cu
mu
lati
ve
Re
tro
fits
(G
W p
re-r
etr
ofi
t)
Marginal Costs w/CO2 Revenue [$/MWh]
Pre-Retrofit
Post-Retrofit - no EOR Revenue
Post Retrofit w/CO2 Revenue ($10/tonne)
Post Retrofit w/CO2 Revenue ($30/tonne)
0
50
100
150
200
250
300
350
-60 -40 -20 0 20 40 60 80 100
Cu
mu
lati
ve
Re
tro
fits
(G
W p
re-r
etr
ofi
t)
Marginal Costs w/CO2 Revenue [$/MWh]
Pre-Retrofit
Post-Retrofit - no EOR Revenue
Post Retrofit w/CO2 Revenue ($10/tonne)
Post Retrofit w/CO2 Revenue ($30/tonne)
$10/tonne CO2
Incremental Marginal Cost Trends Retrofitting SOA CO2 Capture
Retrofit: Increased O&M, lost power revenue
$30/tonne CO2
Reasonable CO2 revenue supports higher dispatch
But to what level?
20
-50
0
50
100
150
200
250
300
350
0 10 20 30 40 50 60 70 80 90
Cu
mu
lati
ve
Re
tro
fits
In
ce
nti
viz
ed
(G
W p
re-r
etr
ofi
t)
Minimum Plant Gate CO2 EOR Revenue Required to Incentivize CCS ($/tonne)
Existing CF
Increase to 75% CF
Increase to 85% CF
UnlikelyCO2 Prices
above
historical range
PossibleCO2 Prices
within
historical range
ProbableCO2 Prices
below
historical range-50
0
50
100
150
200
250
300
350
0 10 20 30 40 50 60 70 80 90
Cu
mu
lati
ve
Re
tro
fits
In
ce
nti
viz
ed
(G
W p
re-r
etr
ofi
t)
Minimum Plant Gate CO2 EOR Revenue Required to Incentivize CCS ($/tonne)
Existing CF
Increase to 75% CF
Increase to 85% CF
UnlikelyCO2 Prices
above
historical range
PossibleCO2 Prices
within
historical range
ProbableCO2 Prices
below
historical range
Effect of Dispatch - 2030 Capacity Factor Parameter Sensitivity
*NEMS Projections. Capital costs reflect ~15% premium due to increase in oil prices.
State of the Art
• 30-yr life • $75/MWh*
power price • $138/bbl oil* State
of the Art
2nd
Gen
~24% decrease in top decile CO2 price
2nd Generation
-50
0
50
100
150
200
250
300
350
0 10 20 30 40 50 60 70 80 90
Cu
mu
lati
ve
Re
tro
fits
In
ce
nti
viz
ed
(G
W p
re-r
etr
ofi
t)
Minimum Plant Gate CO2 EOR Revenue Required to Incentivize CCS ($/tonne)
Existing CF
Increase to 75% CF
Increase to 85% CF
UnlikelyCO2 Prices
above
historical range
PossibleCO2 Prices
within
historical range
ProbableCO2 Prices
below
historical range
Note shift from EOR revenues @ $100/bbl
32.4GW (top decile)
21
-50
0
50
100
150
200
250
300
350
0 10 20 30 40 50 60 70 80 90
Cu
mu
lati
ve
Re
tro
fits
In
ce
nti
viz
ed
(G
W p
re-r
etr
ofi
t)
Minimum Plant Gate CO2 EOR Revenue Required to Incentivize CCS ($/tonne)
30yr
20yr
10yr
UnlikelyCO2 Prices
above
historical range
PossibleCO2 Prices
within
historical range
ProbableCO2 Prices
below
historical range-50
0
50
100
150
200
250
300
350
0 10 20 30 40 50 60 70 80 90
Cu
mu
lati
ve
Re
tro
fits
In
ce
nti
viz
ed
(G
W p
re-r
etr
ofi
t)
Minimum Plant Gate CO2 EOR Revenue Required to Incentivize CCS ($/tonne)
30yr
20yr
10yr
UnlikelyCO2 Prices
above
historical range
PossibleCO2 Prices
within
historical range
ProbableCO2 Prices
below
historical range
Effect of Economic Life - 2030
State of the Art
• 85% CF • $75/MWh
power price • $138/bbl oil
State of the Art
~27% decrease in top decile CO2 price
2nd Generation
2nd Gen
32.4GW (top decile)
Short-term (10yr) investment viewpoints reduce viability by ~90%!
22
• Even with EOR revenues, SOA technology unlikely to promote significant retrofits
• 2nd gen improvements reduce cost of capture by ~25% and significantly increase potential of deployment
– CO2 contract price relationship to price of WTI crude
• EOR market while limited in size, is an excellent transition step for proving out carbon capture and reducing risk for future installations
• Still need help for “slam dunk” EOR scenario
– Need CO2 capture R&D success!
– Dispatch is essential – and likely achievable
– Regulatory drivers encouraging CO2 capture should also support a long-term (30yr) investment viewpoint
Conclusions
Compared cost of CO2 retrofits to minimum CO2 price in EOR market
23
24
Limitations and Next Steps
• Limitations of analysis
– Uncertainty in crude oil and CO2 price projections
– Plant locations relative to EOR opportunities
– Capability of EOR sites to take entire stream
• Next Steps
– FE/NETL CTUS model integrates with NEMS
– Links CO2 sources and sinks
– Detailed transport and storage/EOR cost models
– Evaluate combinations of CO2 emissions price and CO2 revenues
NETL Carbon Capture Retrofit Analyses
25
Energy Velocity: Unit-Specific
Data
NETL CCRD
Carbon Capture Retrofit Database
PC, NGCC, Industrial
New SOA Post-Combustion
Capture System Quotes Systems Analysis of
Capture Retrofits for Reference Plants:
PC, NGCC, Industrial
Analysis of Cost Metrics for
Existing Fleet
FE/NETL CO2 CTUS
NEMS
2nd Generation Post-Combustion Capture System
Cost/Perf
QGESS: Retrofit Cost Estimating Methodology
NETL Post Combustion Capture Retrofit Cost
Update
Reference Plant Cost Metrics
Ventyx Energy Velocity Database
Plant listPlant design & operating data
CCS Retrofit Cost Metrics
Cost Scaling Factors
NGCC Cost
Model
Financial Factors
NETL CCRD PC and NGCC
26
Capture
Cost
Model
NETL CCRD Industrial Sources
27
NETL Industrial Source CCS Cost
Study
Reference Plant Cost Metrics
EPA GHG Database
Plant listAnnual CO2 emissions
CCS Retrofit Cost Metrics
Cost Scaling Factors
Industrial Sector Cost
Model
Financial Factors
NETL Carbon Capture Retrofit Analyses
28
Energy Velocity: Unit-Specific
Data
NETL CCRD
Carbon Capture Retrofit Database
PC, NGCC, Industrial
New SOA Post-Combustion
Capture System Quotes Systems Analysis of
Capture Retrofits for Reference Plants:
PC, NGCC, Industrial
Analysis of Cost Metrics for
Existing Fleet
NETL CTUS NEMS
2nd Generation Post-Combustion Capture System
Cost/Perf
QGESS: Retrofit Cost Estimating Methodology
• Capture equipment costs scaled from greenfield study costs • Add equipment specific to retrofit:
– Eg. Steam turbine modifications and letdown turbine
• Add retrofit difficulty factors to capital cost equipment subaccounts – Equipment and material scope adjustments
• Accounts for minor differences in equipment specifications, layout, duct routing, and items where additional complexity is likely to be encountered
• Range from 1.00 to 1.25 within each subaccount
– Labor productivity adjustments • Productivity losses associated with working on an existing operating
plant site in potentially highly congested areas, and with modifications and tie in to existing equipment and/or systems
• Range from 1.00 to 1.30 within each subaccount
– Typical impact of retrofit difficulty factor on total plant cost is +10%
Posted on NETL QGESS page: http://www.netl.doe.gov/energy-analyses/quality_guidelines.html
QGESS: Retrofit Cost Estimating Methodology
29