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Nanoengineereed Assemblies and Advanced Micro/Nanosystems www.cambridge.org © in this web service Cambridge University Press Cambridge University Press 978-1-107-40915-6 - Nanoengineered Assemblies and Advanced Micro/Nanosystems: Materials Research Society Symposium Proceedings: Volume 820 Editors: David P. Taylor, Jun Liu, David Mcllroy, Lhadi Merhari, J. B. Pendry, Jeffrey T. Borenstein, Piotr Grodzinski, Luke P. Lee and Zhong Lin Wang Frontmatter More information

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Nanoengineereed Assemblies andAdvanced Micro/Nanosystems

www.cambridge.org© in this web service Cambridge University Press

Cambridge University Press978-1-107-40915-6 - Nanoengineered Assemblies and Advanced Micro/Nanosystems:Materials Research Society Symposium Proceedings: Volume 820Editors: David P. Taylor, Jun Liu, David Mcllroy, Lhadi Merhari, J. B. Pendry, Jeffrey T. Borenstein, Piotr Grodzinski, Luke P. Lee and Zhong Lin WangFrontmatterMore information

www.cambridge.org© in this web service Cambridge University Press

Cambridge University Press978-1-107-40915-6 - Nanoengineered Assemblies and Advanced Micro/Nanosystems:Materials Research Society Symposium Proceedings: Volume 820Editors: David P. Taylor, Jun Liu, David Mcllroy, Lhadi Merhari, J. B. Pendry, Jeffrey T. Borenstein, Piotr Grodzinski, Luke P. Lee and Zhong Lin WangFrontmatterMore information

MATERIALS RESEARCH SOCIETY

SYMPOSIUM PROCEEDINGS VOLUME 820

Nanoengineered Assemblies andAdvanced Micro/Nanosystems

Symposia held April 13-16,2004, San Francisco, California, U.S.A.

EDITORS:

David P. TaylorThe Aerospace Corporation

El Segundo, California, U.S.A.

Jun LiuSandia National Laboratories

Albuquerque, New Mexico, U.S.A.

David McllroyUniversity of Idaho

Moscow, Idaho, U.S.A.

Lhadi MerhariCeramec

Limoges, France

J.B. PendryImperial College LondonLondon, United Kingdom

Jeffrey T. BorensteinCharles Stark Draper Laboratory

Cambridge, Massachusetts, U.S.A.

Piotr GrodzinskiLos Alamos National Laboratory

Los Alamos, New Mexico, U.S.A.

Luke P. LeeUniversity of California-Berkeley

Berkeley, California, U.S.A.

Zhong Lin WangGeorgia Institute of Technology

Atlanta, Georgia, U.S.A.

IMIRISIMaterials Research Society

Warrendale, Pennsylvania

www.cambridge.org© in this web service Cambridge University Press

Cambridge University Press978-1-107-40915-6 - Nanoengineered Assemblies and Advanced Micro/Nanosystems:Materials Research Society Symposium Proceedings: Volume 820Editors: David P. Taylor, Jun Liu, David Mcllroy, Lhadi Merhari, J. B. Pendry, Jeffrey T. Borenstein, Piotr Grodzinski, Luke P. Lee and Zhong Lin WangFrontmatterMore information

cambridge university press Cambridge, New York, Melbourne, Madrid, Cape Town, Singapore, São Paulo, Delhi, Mexico City

Cambridge University Press32 Avenue of the Americas, New York ny 10013-2473, USA

Published in the United States of America by Cambridge University Press, New York

www.cambridge.orgInformation on this title: www.cambridge.org/9781107409156

Materials Research Society506 Keystone Drive, Warrendale, pa 15086http://www.mrs.org

© Materials Research Society 2004

This publication is in copyright. Subject to statutory exceptionand to the provisions of relevant collective licensing agreements, no reproduction of any part may take place without the written permission of Cambridge University Press.

This publication has been registered with Copyright Clearance Center, Inc.For further information please contact the Copyright Clearance Center,Salem, Massachusetts.

First published 2004 First paperback edition 2012

Single article reprints from this publication are available throughUniversity Microfilms Inc., 300 North Zeeb Road, Ann Arbor, mi 48106

CODEN: MRSPDH

isbn 978-1-107-40915-6 Paperback

Cambridge University Press has no responsibility for the persistence oraccuracy of URLs for external or third-party internet websites referred to inthis publication, and does not guarantee that any content on such websites is,or will remain, accurate or appropriate.

Effort sponsored by the Air Force Office of Scientific Research, Air Force Material Command, USAF,under F49550-04-1-0259. The U.S. Government is authorized to reproduce and distribute reprints forGovernmental purposes notwithstanding any copyright notation thereon. The views and conclusionsherein are those of the authors and should not be interpreted as necessarily representing the officialpolicies or endorsements, either expressed or implied, of the Air Force Office of Scientific Research orthe U.S. Government.

This material is based upon work supported by the National Science Foundation under Grant NumberDMR-0342173. Any opinions, findings, and conclusions or recommendations expressed in thismaterial are those of the author(s) and do not necessarily reflect the views of the National ScienceFoundation.

www.cambridge.org© in this web service Cambridge University Press

Cambridge University Press978-1-107-40915-6 - Nanoengineered Assemblies and Advanced Micro/Nanosystems:Materials Research Society Symposium Proceedings: Volume 820Editors: David P. Taylor, Jun Liu, David Mcllroy, Lhadi Merhari, J. B. Pendry, Jeffrey T. Borenstein, Piotr Grodzinski, Luke P. Lee and Zhong Lin WangFrontmatterMore information

CONTENTS

Preface: Symposium O xiii

Preface: Symposium R: xv

Materials Research Society Symposium Proceedings xvii

SYMPOSIUM O

SELF-ASSEMBLED MATERIALS

* The Fabrication of Self-Assembling Peptides IntoNanofiber Scaffolds Through Molecular Self-Assembly 3

Xiaojun Zhao, Jessica Dai, and Shuguang Zhang

INTERFACIAL SCIENCES AND NOVELMICROSYSTEMS/MICRODEVICES

* Magnetic and Electric Manipulation of a Single Cell in Fluid 17Hakho Lee, Tom P. Hunt, and Robert M. Westervelt

* Actin Nanotracks for Hybrid Nanodevices Based onLinear Protein Molecular Motors 25

G.S. Watson, C. Cahill, J. Blach, S. Myhra, Y. Alexeeva,E.P. Ivanova, and D.V. Nicolau

Covalent Immobilization of DNA and Hybridization onMicrochips by Microsecond Electric Field Pulses 37

F. Fixe, H.M. Branz, D.M.F. Prazeres, V. Chu, and J.P. Conde

Optoelectronic Detection of DNA Molecules Using anAmorphous Silicon Photodetector 43

F. Fixe, D.M.F. Prazeres, V. Chu, and J.P. Conde

* Invited Paper

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Cambridge University Press978-1-107-40915-6 - Nanoengineered Assemblies and Advanced Micro/Nanosystems:Materials Research Society Symposium Proceedings: Volume 820Editors: David P. Taylor, Jun Liu, David Mcllroy, Lhadi Merhari, J. B. Pendry, Jeffrey T. Borenstein, Piotr Grodzinski, Luke P. Lee and Zhong Lin WangFrontmatterMore information

NANOPARTICLE SYNTHESISAND APPLICA TIONS

Characterization of Alumina and Silica Sol-Gel EncapsulatedFe/Co/Ru Nanocatalysts in MicroChannel Reactors for F-TSynthesis of Higher Alkanes 51

D. Kuila, V.S. Nagineni, S. Zhao, H. Indukuri, Y. Liang,A. Potluri, U. Siriwardane, N. Seetala, and J. Fang

Reaction and Diffusion Dynamics in a Microfluidic Format 57Dietrich Kohlheyer, Rob G.H. Lammertink,Stefan Schlautmann, Geert A.J. Besselink, Paul Vulto,and Richard B.M. Schasfoort

Targeting Magnetic Nanoparticles in High Magnetic Fieldsfor Drug Delivery Purposes 63

Ramazan Asmatulu, Richard O. Claus, Judy S. Riffle,and Michael Zalich

Photophysical Properties of CdS Nanoparticles in Thin Filmsfor Opto-Chemical Sensing 69

Elena A. Guliants, Barbara A. Haruff, James R. Gord,and Christopher E. Bunker

Decoration of Carbon Nanotubes With Gold Nanoparticlesfor Catalytic Applications 75

Wei Lii, Xicheng Ma, Ning Lun, and Shulin Wen

NANOMATERIALS AND NANOFABRICATIONS INMICROSYSTEMS AND MICRODEVICESI

Carbon Nanotube-Based Permeable Membranes 83Jason K. Holt, Hyung Gyu Park, Olgica Bakajin,Aleksandr Noy, Thomas Huser, and David Eaglesham

* Experimental Study of Filling Carbon Nanotubes WithNucleic Acids 89

Daxiang Cui, Cengiz S. Ozkan, Yong Kong, andHuajian Gao

Control of Doping and Electronic Transport in Nanowires 101Jianxin Zhong and G. Malcolm Stocks

* Invited Paper

VI

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Cambridge University Press978-1-107-40915-6 - Nanoengineered Assemblies and Advanced Micro/Nanosystems:Materials Research Society Symposium Proceedings: Volume 820Editors: David P. Taylor, Jun Liu, David Mcllroy, Lhadi Merhari, J. B. Pendry, Jeffrey T. Borenstein, Piotr Grodzinski, Luke P. Lee and Zhong Lin WangFrontmatterMore information

Integrating Carbon Nanotubes for Atomic Force MicroscopyImaging Applications 107

Qi Ye, Alan M. Cassell, Hongbing Liu, Jie Han, andMeyya Meyyappan

TISSUE ENGINEERING

Use of Soft Lithography for Multi-Layer MicroMolding(MMM) of 3D PCL Scaffolds for Tissue Engineering 115

Yang Sun, Nicholas Ferrell, and Derek J. Hansford

Design and Fabrication of a Constant Shear MicrofluidicNetwork for Tissue Engineering 121

E.J. Weinberg, J.T. Borenstein, M.R. Kaazempur-Mofrad,B. Orrick, and J.P. Vacanti

* NanoLiterBioReactor: Monitoring of Long-Term MammalianCell Physiology at Nanofabricated Scale 127

Ales Prokop, Zdenka Prokop, David Schaffer, Eugene Kozlov,John Wikswo, David Cliffel, and Franz Baudenbacher

Development of Self-Assembled Muscle-Powered Microdevices 139Jianzhong Xi, Jacob J. Schmidt, and Carlo D. Montemagno

NANOMA TERIALS AND NANOFABRIC A TIONS INMICROSYSTEMS AND MICRODEVICES II

Novel Chemical Approach to Achieve Advanced SoftLithography by Developing New Stiffer, PhotocurablePDMS Stamp Materials 147

Kyung M. Choi and John A. Rogers

Liquid Phase Deposition of Poly(ethylene terephthalate) Films 155Robert M. Bryce, Hue T. Nguyen, Rik R. Tykwinski,Ray G. DeCorby, Mark R. Freeman, and Ying Y. Tsui

INTEGRA TED MICRO ANAL YSIS

Ion Channel Sensor on a Silicon Support 163Michael Goryll, Seth Wilk, Gerard M. Laws,Stephen M. Goodnick, Trevor J. Thornton, Marco Saraniti,John M. Tang, and Robert S. Eisenberg

* Invited Paper

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Cambridge University Press978-1-107-40915-6 - Nanoengineered Assemblies and Advanced Micro/Nanosystems:Materials Research Society Symposium Proceedings: Volume 820Editors: David P. Taylor, Jun Liu, David Mcllroy, Lhadi Merhari, J. B. Pendry, Jeffrey T. Borenstein, Piotr Grodzinski, Luke P. Lee and Zhong Lin WangFrontmatterMore information

POSTER SESSION

Rapid Prototyping of Glass Microfluidic Devices UsingFemtosecond Laser Pulses 171

Myung-Il Park, Jun Rye Choi, Mira Park, Dae Sik Choi,Sae Chae Jeoung, and Chong-Ook Park

Optimization of Mechanical Properties of Thin Free-Standing Metal Films for RF-MEMS 177

Jaap M.J. den Toonder and Auke R. van Dijken

Microstructural Design and Evaluation of Porcelain/Mullite/Alumina Layered Structure for Dental Application 183

Hyung-Jun Jang, Dong-Ho Park, Yeon-Gil Jung, andHee-soo Lee

Low Coherence Interferometric Metrology for Ultra-ThinMEMs Structures 189

Wojciech Walecki, Frank Wei, Phuc Van, Kevin Lai,Tim Lee, Vitali Souchkov, S.H. Lau, and Ann Koo

Tuning the Mechanical Properties of Poly-Silicon Film bySurface Modification Using Plasma Treatment 195

Wang-Shen Su, Weileun Fang, and Ming-Shih Tsai

Fabrication and Characterization of Platinum-IridiumElectrodes With Micro-Structured Surfaces for NeuralStimulation Applications 201

Sachin S. Thanawala, Daniel G. Georgiev, Afzal Khan,Ronald J. Baird, and Gregory Auner

Electroactive Polymer Deformable Micromirrors (EAPDM)for Biomedical Optics 207

Cheng Huang, Bo Bai, Baojun Chu, Jim Ding, andQ.M. Zhang

A Multi-Layer Technology for Biocompatible PolymerMicrosystems With Integrated Fluid and ElectricalFunctionality 215

Eileen D. Moss, Arum Han, and A. Bruno Frazier

Synthesis and Characterization of Ag Nanoparticle,Ag-TiO2 Nanoparticle and Ag-Ti02-Chitosan Complexand Their Application to Antibiosis and Deodorization 221

Young Hwan Kim and Young Soo Kang

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Cambridge University Press978-1-107-40915-6 - Nanoengineered Assemblies and Advanced Micro/Nanosystems:Materials Research Society Symposium Proceedings: Volume 820Editors: David P. Taylor, Jun Liu, David Mcllroy, Lhadi Merhari, J. B. Pendry, Jeffrey T. Borenstein, Piotr Grodzinski, Luke P. Lee and Zhong Lin WangFrontmatterMore information

A Study of the Growth Curves of C. xerosis and E. coliBacteria in Mediums Containing Cobalt FerriteNanoparticles 227

Marjorie Flores, Nanell Colon, Omayra Rivera,Nicole Villalba, Yahira Baez, David Quispitupa,Javier Avalos, and Oscar Perales

NANO AND BIO MICROSYSTEMSAND DEVICES

Integrating Biomaterials Into Microsystems: Formationand Characterization of Nanostructured Titania 235

Zuruzi Abu Samah, Blaine C. Butler, Emily R. Parker,Ayesha Ahmed, Heather M. Evans, Cyrus R. Safinya,and Noel C. MacDonald

Impedance-Based Biosensors 241X. Huang, D.W. Greve, I. Nausieda, D. Nguyen, andM.M. Domach

* From an Integrated Biochip Detection System to aDefensive Weapon Against the SARS-CoV Virus:OBMorph 249

Chih-Kung Lee, Chi-Wan Lin, Shiming Lin,Adam Shih-Yuan Lee, Jiun-Yan Wu, Shu-Sheng Lee,Wen-Hsin Hsiao, Shih-Jui Chen, and An-Bang Wang

SYMPOSIUM R

PHOTONIC STRUCTURES

* Polariton-Enhanced Near Field Lithography and ImagingWith Infrared Light 265

Gennady Shvets and Yaroslav A. Urzhumov

* Fabrication of 2D and 3D Photonic Bandgap StructuresUsing Laser-Assisted Imprinting of Self-Assembled Particles 277

Y.F. Lu, L.P. Li, K.K. Mendu, J. Shi, D.W. Doerr, andD.R. Alexander

Synthesis and Self-Assembly of Metal-Coated Nanoparticles 289W. Park and T. Borsa

* Invited Paper

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Cambridge University Press978-1-107-40915-6 - Nanoengineered Assemblies and Advanced Micro/Nanosystems:Materials Research Society Symposium Proceedings: Volume 820Editors: David P. Taylor, Jun Liu, David Mcllroy, Lhadi Merhari, J. B. Pendry, Jeffrey T. Borenstein, Piotr Grodzinski, Luke P. Lee and Zhong Lin WangFrontmatterMore information

Fabrication of Two-Dimensional Photonic Structure ofTitanium Dioxide With Sub-Micrometer Resolution byDeep X-ray Lithography 295

Koichi Awazu, Makoto Fujimaki, Xiaomin Wang,Akihide Sai, and Yoshimichi Ohki

Fabricate Photonic Crystals Based on ZnS/Opal System viaSolvothermal Method 301

Jieming Cao, Xin Chang, Lijia Pan, Hongmei Ji, Jinsong Liu,Jie Feng, Fang Zhang, Haiyan Wang, Jie Tao, and Guoyue Xu

PHOTON, ELECTRON AND ION BEAMAPPROACHES TONANOFABRICATION

* Implanted 3D Micro/Nano-Structure Fabrication: NewProcessing Techniques for the Creation of Nanoscale Opto-Mechanical Machines in Silicon Dioxide on a Silicon Wafer 309

Meg Abraham

Ion Beam Lithographic Fabrication of Ordered VO2

Nanoparticle Arrays 319R. Lopez, J.Y. Suh, L.C. Feldman, and R.F. Haglund Jr.

Patterning and Reactive Ion Etching of Diamond Films UsingLight Coupling Masks 325

Patrick W. Leech, Geoff K. Reeves, and Anthony S. Holland

SELF-ASSEMBLY: FABRICATIONAND CHARACTERIZATION

Morphologically Weil-Defined Gold NanoparticlesEmbedded in Thermo-Responsive Hydrogel Matrices 333

Chun Wang, Nolan T. Flynn, and Robert Langer

Fabrication of Ordered Sub-Micron Topographies onLarge-Area Poly(Urethane Urea) by Two-StageReplication Molding 339

Keith R. Milner, Mallory Balmer, Henry J. Donahue,Alan J. Snyder, and Christopher A. Siedlecki

* Invited Paper

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Cambridge University Press978-1-107-40915-6 - Nanoengineered Assemblies and Advanced Micro/Nanosystems:Materials Research Society Symposium Proceedings: Volume 820Editors: David P. Taylor, Jun Liu, David Mcllroy, Lhadi Merhari, J. B. Pendry, Jeffrey T. Borenstein, Piotr Grodzinski, Luke P. Lee and Zhong Lin WangFrontmatterMore information

Investigation of the Layer-by-Layer Assembly of ColloidCrystals on a Templated Substrate 345

Sonia Grego, Thomas Jarvis, Brian Stoner, and Jay Lewis

Influence of H2 Preconditioning on the Nucleation and Growthof Self-Assembled Germanium Islands on Silicon (001) 351

Gabriela D.M. Dilliway, Nicholas E.B. Cowern, Lu Xu,Patrick J. McNally, Chris Jeynes, Ernest Mendoza,Peter Ashburn, and Darren M. Bagnall

Formation of Three-Dimensional Ni Nanostructures forLarge Area Catalysts 357

J.D. Carey, SJ. Henley, E. Mendoza, C.E. Giusca,A.A.D.T. Adikaari, and S.R.P. Silva

Anatase Inverse Opal: Preparation and ElectrochemicalProperties 363

Marketa Zukalova, Martin Kalbac, and Ladislav Kavan

DESIGN, APPLICATION,CHARACTERIZATION AND SIMULATIONS

OF NANOSTRUCTURED MATERIALS

* Atomic Force Microscopy Applications to Neuroscience 371Helen A. McNally

* Microfluidics and Beyond—Devices for Applications inBiotechnology 381

Martina Daub, Rolf M. Kaack, Oliver Gutmann,Chris P. Steinert, Remigius Niekrawietz, Peter Koltay,Bas de Heij, and Roland Zengerle

* Three-Dimensional Representation of Curved Nanostructures 393Z. Huang, D.A. Dikin, W. Ding, Y. Qiao, Y. Fridman,and R.S. Ruoff

Ab Initio Structural Properties and Stress-DeformationAnalysis by Rheological Modeling of Diamonds-ContainingNanocarbon Nanotubes 401

Maksim V. Kireitseu and Liya Bochkaryova

*Invited Paper

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Cambridge University Press978-1-107-40915-6 - Nanoengineered Assemblies and Advanced Micro/Nanosystems:Materials Research Society Symposium Proceedings: Volume 820Editors: David P. Taylor, Jun Liu, David Mcllroy, Lhadi Merhari, J. B. Pendry, Jeffrey T. Borenstein, Piotr Grodzinski, Luke P. Lee and Zhong Lin WangFrontmatterMore information

Controlling the Sensing Volume of Metal NanosphereMolecular Sensors 407

Molly M. Miller and Anne A. Lazarides

Author Index 415

Subject Index 419

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Cambridge University Press978-1-107-40915-6 - Nanoengineered Assemblies and Advanced Micro/Nanosystems:Materials Research Society Symposium Proceedings: Volume 820Editors: David P. Taylor, Jun Liu, David Mcllroy, Lhadi Merhari, J. B. Pendry, Jeffrey T. Borenstein, Piotr Grodzinski, Luke P. Lee and Zhong Lin WangFrontmatterMore information

PREFACE

SYMPOSIUM O

Nanotechnology holds the promise of an entirely new class of materials and a new generation ofmicrodevices with superior properties and performance. Governments world-wide are now investingan estimated $2.0 billion dollars a year to explore this new area of science and technology. Thesuccessful integration of nanotechnology and microtechnology is expected to have enormoustechnological and economic benefits. Microsystems, including microelectromechanical systems(MEMs), bioMEMs, nanoelectromechanical systems (NEMs), optical, electronic, and electrochemicalmicrosystems, have great potential for many applications ranging from advanced computing, chemicaland biological analysis/detection, drug delivery/discovery, tissue engineering, chemical and materialssynthesis, to energy conversion and storage. New advanced microsystems with integrated nanometerscale structures and functions present a multidisciplinary challenge. The performance of suchmicrosystems also depends on the understanding of the properties on both the nano- and micro- scales.Therefore, advanced microsystems provide an ideal platform to bridge the "top-down" approach thathas been widely used in industry for microdevices, and the "bottom-up" approach that has been widelyinvestigated for new materials and devices. Recently, the Review Committee of the NationalNanotechnology Initiatives recommended: "Revolutionary change will come from integratingmolecular and nanoscale components into high order structures.... To achieve improvements overtoday's systems, chemical and biologically assembled machines must combine the best features of thetop-down and bottom-up approaches."

Many symposia had been organized on synthesis and characterization of nanomaterials, and onmicrofluidic and microelectronic systems. Symposium O, "Advanced Microsystems—Integrationwith Nanotechnology and Biology," held April 13-16 at the 2004 MRS Spring Meeting inSan Francisco, California, was unique because it provided an international forum to focus onintegration of advanced microsystems with biomaterials, and also provided the latest developments innanomaterials and nanotechnology. This symposium addressed scientific and technology challengesin materials science for advanced nano- and microsystems, novel concept, design, devices orsystems/architectures with functions and structures spanning many length scales, integration anddevelopment of multiscale fabrication tools and methodologies, integration of biological and syntheticmaterials and control of the interface between biological and non-biological components, control ofoptical and electronic energy transfer coupled across multiple length scales, coupling of mechanicalforces across nano-, micro- and larger scales, including the control of fluidic transport, andunderstanding and predicting fundamental behavior and reliabilities of materials and systems. Expertsin materials sciences, chemistry, biology, and microtechnology participated in this symposium. Thefirst half of this proceedings contains most of the exciting results presented at Symposium O, whichwe hope will become valuable references to scientists and engineers who work in these areas.

Jun LiuJeffrey T. BorensteinPiotr GrodzinskiLuke P. LeeZhong Lin Wang

June 2004

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www.cambridge.org© in this web service Cambridge University Press

Cambridge University Press978-1-107-40915-6 - Nanoengineered Assemblies and Advanced Micro/Nanosystems:Materials Research Society Symposium Proceedings: Volume 820Editors: David P. Taylor, Jun Liu, David Mcllroy, Lhadi Merhari, J. B. Pendry, Jeffrey T. Borenstein, Piotr Grodzinski, Luke P. Lee and Zhong Lin WangFrontmatterMore information

www.cambridge.org© in this web service Cambridge University Press

Cambridge University Press978-1-107-40915-6 - Nanoengineered Assemblies and Advanced Micro/Nanosystems:Materials Research Society Symposium Proceedings: Volume 820Editors: David P. Taylor, Jun Liu, David Mcllroy, Lhadi Merhari, J. B. Pendry, Jeffrey T. Borenstein, Piotr Grodzinski, Luke P. Lee and Zhong Lin WangFrontmatterMore information

PREFACE

SYMPOSIUM R

Both of the three-dimensional nanoengineered assemblies symposia that have been held by theMaterials Research Society were intended to bring together researchers from a wide range of fields.The conference topic is not focused on a particular area of research, but on a goal that is beingpursued by many groups approaching from diverse directions. There were only a handful of papersthat presented true "3D nanoengineered assemblies" at the first meeting in the Fall of 2002. It wasanticipated that most of the papers would be either "not quite truly 3D" or "3D but not quite on thenanoscale." The first symposium was directed at both the fabrication methods for creating thesestructures in materials as well as understanding the phenomena that make possible uniqueapplications for these materials. By the time of the second symposium, Symposium R, "Three-Dimensional Nanoengineered Assemblies II," held April 12-16 at the 2004 MRS Spring Meetingin San Francisco, California, there had been significant progress in realizing these materials andmany of the most interesting phenomena have become the focus of very active areas of research.

There are many approaches with the ability to fabricate or assemble three-dimensionalstructures with nanoscale precision. These approaches to making 3D structures range fromlithography, through beam based direct write methods, through "soft lithography" contact printing,through various pick and place methods to self-assembly. Self-assembly includes biological andbiomimetic based methods which generated significant interest in "3D Nano I" and this thread hascontinued through the "3D Nano II" symposium. If biological processes can be understood andcontrolled or mimicked, then there is potential to build structures starting on the nanoscale. Thedirected self-assembly and the bottom-up approach to processing implicitly offers some 3D controlfrom the nanoscale all the way to large structures. A "3D Nano II" session (with Morley Stone,Mark Hildebrand, and Ken Sandhage) explored chemical conversion of biologically createdcalcium carbonate structures, which may be a particularly direct path to producing useful materials.

One of the most interesting aspects of nanotechnology is the ability to access physicalphenomena that occur on the nanoscale. Many of these phenomena have become prototypicalexamples of the promise of new technology, from catalysis and fluidics to energy storage. Photonicsystems are also an important and well-known class of 3D nanoengineered systems.

A focus topic of the first "Three-Dimensional Nanoengineered Assemblies" symposium wasthe emerging field that has been called "plasmonics." Rufus Ritchie coined the term "plasmons" in1957 to describe the particle-like behavior of plasma oscillations in materials. There has been anongoing interest in these surface or bulk plasmons that run as longitudinal charge density wavesinside materials or at interfaces. John Pendry has been one of the main proponents of the view thatphotonics and plasmonics are related on a fundamental level and that it is possible to modelphotonic crystals and other systems in terms of their plasmon resonances. Plasmon-relatedphenomena include light funnels, perfect lenses, magnetic properties from non-magnetic materials,and left-handed index materials. It may have been Harry Atwater that coined the term"plasmonics" to make the analogy between plasmon applications and electronics. The light funnel(transmission through subwavelength apertures) session with Francisco Garcia-Vidal, Tineke Thio,and Han Woerdman was one of the most active MRS sessions in our memory. The "perfect lens"talk of Gennady Shvets and the "left-handed materials" talk of David R. Smith exemplified therapid development of this exciting area that seems very rich with applications. Many of the invitedspeakers were in this area of photonics and plasmonics, including a particularly inspiring talk byEli Yablonovitch. It also seems clear from recent work in this area (particularly from the work ofJohn Pendry and Eli Yablonovitch) that many of the future applications in the area of plasmonicswill involve 3D nanoengineered assemblies.

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Cambridge University Press978-1-107-40915-6 - Nanoengineered Assemblies and Advanced Micro/Nanosystems:Materials Research Society Symposium Proceedings: Volume 820Editors: David P. Taylor, Jun Liu, David Mcllroy, Lhadi Merhari, J. B. Pendry, Jeffrey T. Borenstein, Piotr Grodzinski, Luke P. Lee and Zhong Lin WangFrontmatterMore information

The above commentary does not span very many of the areas presented in the symposium.In the area of microfluidics, Juan Santiago and Stephen Turner presented the tutorial session.Martina Daub presented an approach to building accurate dispensing arrays for biologicalapplications. Meg Abraham, Richard Haglund, Hans Loeschner, Albert Polman, Z.F. Ren, andPrakash Koonath all presented beam based fabrication methods. Y.F. Lu, Paul Alivisatos' group,and Chun Wang presented papers on nanoparticle assemblies. In addition to those alreadymentioned, Harry Atwater, Axel Scherer's group, Chris Berven, Naomi Halas, Vlademir Shalaev,and Anand Gopinath presented plasmonics/photonics talks. A number of approaches werepresented for using contact fabrication methods, including John Rogers' lead off talk on softlithography. Armand Rosenberg and Robert Rudd presented the results of their simulations. Pickand place assembly schemes ranged from Helen McNally's AFM manipulation of biologicalspecies to Rodney Ruoff s nanorobots.

A large number of excellent talks presented interesting work in this symposium. Part of thesuccess of this symposium is that it touches on a presently topical aspect of research. However, thereal strength of this meeting was the multidisciplinary character of the entire symposium. Thissymposium succeeded in presenting a snapshot of the current work in this topic to researchers, inkeeping with the best traditions of the Materials Research Society Meetings. Finally, the success ofthe symposium is a direct result of the generous support we received from the Air Force Office ofScientific Research and the National Science Foundation. The co-organizers thank the manyparticipants who contributed by giving talks and by their presence and we look to the future to seewhat advances evolve from the cross-disciplinary exchange provided by this excellent symposiumon three-dimensional nanoengineered assemblies.

David P. TaylorDavid McllroyLhadi MerhariJ.B. Pendry

July 2004

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Cambridge University Press978-1-107-40915-6 - Nanoengineered Assemblies and Advanced Micro/Nanosystems:Materials Research Society Symposium Proceedings: Volume 820Editors: David P. Taylor, Jun Liu, David Mcllroy, Lhadi Merhari, J. B. Pendry, Jeffrey T. Borenstein, Piotr Grodzinski, Luke P. Lee and Zhong Lin WangFrontmatterMore information

MATERIALS RESEARCH SOCIETY SYMPOSIUM PROCEEDINGS

Volume 782— Micro- and Nanosystems, D. LaVan, M. McNie, A. Ayon, M. Madou, S. Prasad, 2004,ISBN: 1-55899-720-2

Volume 783— Materials, Integration and Packaging Issues for High-Frequency Devices, P. Muralt, Y.S. Cho,J-P. Maria, M. Klee, C. Hoffmann, C.A. Randall, 2004, ISBN: 1-55899-721-0

Volume 784— Ferroelectric Thin Films XII, S. Hoffmann-Eifert, H. Funakubo, A.I. Kingon, I.P. Koutsaroff,V. Joshi, 2004, ISBN: 1-55899-722-9

Volume 785— Materials and Devices for Smart Systems, Y. Furuya, E. Quandt, Q. Zhang, K. Inoue,M. Shahinpoor, 2004, ISBN: 1-55899-723-7

Volume 786— Fundamentals of Novel Oxide/Semiconductor Interfaces, C.R. Abemathy, E. Gusev,D.G. Schlom, S. Stemmer, 2004, ISBN: 1-55899-724-5

Volume 787— Molecularly Imprinted Materials—2003, P. Kofinas, MJ. Roberts, B. Sellergren, 2004,ISBN: 1-55899-725-3

Volume 788— Continuous Nanophase and Nanostructured Materials, S. Komarneni, J.C. Parker, J. Watkins,2004, ISBN: 1-55899-726-1

Volume 789— Quantum Dots, Nanoparticles and Nanowires, P. Guyot-Sionnest, NJ. Halas, H. Mattoussi,Z.L. Wang, U. Woggon, 2004, ISBN: 1-55899-727-X

Volume 790— Dynamics in Small Confining Systems—2003, J.T. Fourkas, P. Levitz, M. Urbakh, KJ. Wahl,2004, ISBN: 1-55899-728-8

Volume 791— Mechanical Properties of Nanostructured Materials and Nanocomposites, R. Krishnamoorti,E. Lavernia, L Ovid'ko, C.S. Pande, G. Skandan, 2004, ISBN: 1-55899-729-6

Volume 792— Radiation Effects and Ion-Beam Processing of Materials, L. Wang, R. Fromknecht, L.L. Snead,D.F. Downey, H. Takahashi, 2004, ISBN: 1-55899-730-X

Volume 793— Thermoelectric Materials 2003—Research and Applications, G.S. Nolas, J. Yang, T.P. Hogan,D.C. Johnson, 2004, ISBN: 1-55899-731-8

Volume 794— Self-Organized Processes in Semiconductor Heteroepitaxy, R.S. Goldman, R. Noetzel,A.G. Norman, G.B. Stringfellow, 2004, ISBN: 1-55899-732-6

Volume 795— Thin Films—Stresses and Mechanical Properties X, S.G. Corcoran, Y-C. Joo, N.R. Moody,Z. Suo, 2004, ISBN: 1-55899-733-4

Volume 796— Critical Interfacial Issues in Thin-Film Optoelectronic and Energy Conversion Devices,D.S. Ginley, S.A. Carter, M. Gratzel, R.W. Birkmire, 2004, ISBN: 1-55899-734-2

Volume 797— Engineered Porosity for Microphotonics and Plasmonics, R. Wehrspohn, F. Garcial-Vidal,M. Notomi, A. Scherer, 2004, ISBN: 1-55899-735-0

Volume 798— GaN and Related Alloys—2003, H.M. Ng, M. Wraback, K. Hiramatsu, N. Grandjean, 2004,ISBN: 1-55899-736-9

Volume 799— Progress in Compound Semiconductor Materials III—Electronic and OptoelectronicApplications, D. Friedman, M.O. Manasreh, I. Buyanova, F.D. Auret, A. Munkholm, 2004,ISBN: 1-55899-737-7

Volume 800— Synthesis, Characterization and Properties of Energetic/Reactive Nanomaterials,R.W. Armstrong, N.N. Thadhani, W.H. Wilson, JJ. Gilman, Z. Munir, R.L. Simpson, 2004,ISBN: 1-55899-738-5

Volume 801— Hydrogen Storage Materials, M. Nazri, G-A. Nazri, R.C. Young, C. Ping, 2004,ISBN: 1-55899-739-3

Volume 802— Actinides—Basic Science, Applications and Technology, L. Soderholm, J. Joyce, M.F. Nicol,D. Shuh, J.G. Tobin, 2004, ISBN: 1-55899-740-7

Volume 803— Advanced Data Storage Materials and Characterization Techniques, J. Ahner, L. Hesselink,J. Levy, 2004, ISBN: 1-55899-741-5

Volume 804— Combinatorial and Artificial Intelligence Methods in Materials Science II, R.A. Potyrailo,A. Karim, Q. Wang, T. Chikyow, 2004, ISBN: 1-55899-742-3

Volume 805— Quasicrystals 2003—Preparation, Properties and Applications, E. Belin-Ferre, M. Feuerbacher,Y. Ishii, D. Sordelet, 2004, ISBN: 1-55899-743-1

Volume 806— Amorphous and Nanocrystalline Metals, R. Busch, T. Hufhagel, J. Eckert, A. Inoue,W. Johnson, A.R. Yavari, 2004, ISBN: 1-55899-744-X

www.cambridge.org© in this web service Cambridge University Press

Cambridge University Press978-1-107-40915-6 - Nanoengineered Assemblies and Advanced Micro/Nanosystems:Materials Research Society Symposium Proceedings: Volume 820Editors: David P. Taylor, Jun Liu, David Mcllroy, Lhadi Merhari, J. B. Pendry, Jeffrey T. Borenstein, Piotr Grodzinski, Luke P. Lee and Zhong Lin WangFrontmatterMore information

MATERIALS RESEARCH SOCIETY SYMPOSIUM PROCEEDINGS

Volume 807— Scientific Basis for Nuclear Waste Management XXVII, V.M. Oversby, L.O. Werme, 2004,ISBN: 1-55899-752-0

Volume 808— Amorphous and Nanocrystalline Silicon Science and Technology—2004, R. Biswas,G. Ganguly, E. Schiff, R. Carius, M. Kondo, 2004, ISBN: 1-55899-758-X

Volume 809— High-Mobility Group-IV Materials and Devices, M. Caymax, E. Kasper, S. Zaima, K. Rim,P.F.P. Fichtner, 2004, ISBN: 1-55899-759-8

Volume 810— Silicon Front-End Junction Formation—Physics and Technology, P. Pichler, A. Claverie,R. Lindsay, M. Orlowski, W. Windl, 2004, ISBN: 1-55899-760-1

Volume 811— Integration of Advanced Micro- and Nanoelectronic Devices—Critical Issues and Solutions,J. Morais, D. Kumar, M. Houssa, R.K. Singh, D. Landheer, R. Ramesh, R. Wallace, S. Guha,H. Koinuma, 2004, ISBN: 1-55899-761-X

Volume 812— Materials, Technology and Reliability for Advanced Interconnects and Low-k Dielectrics—2004,R. Carter, C. Hau-Riege, G. Kloster, T-M. Lu, S. Schulz, 2004, ISBN: 1-55899-762-8

Volume 813— Hydrogen in Semiconductors, N.H. Nickel, M.D. McCluskey, S. Zhang, 2004,ISBN: 1-55899-763-6

Volume 814— Flexible Electronics 2004—Materials and Device Technology, B.R. Chalamala, B.E. Gnade,N. Fruehauf, J. Jang, 2004, ISBN: 1-55899-764-4

Volume 815— Silicon Carbide 2004—Materials, Processing and Devices, M. Dudley, P. Gouma, P.G. Neudeck,T. Kimoto, S.E. Saddow, 2004, ISBN: 1-55899-765-2

Volume 816— Advances in Chemical-Mechanical Polishing, D. Boning, J.W. Bartha, G. Shinn, I. Vos,A. Philipossian, 2004, ISBN: 1-55899-766-0

Volume 817— New Materials for Microphotonics, J.H. Shin, M. Brongersma, F. Priolo, C. Buchal, 2004,ISBN: 1-55899-767-9

Volume 818— Nanoparticles and Nanowire Building Blocks—Synthesis, Processing, Characterization andTheory, O. Glembocki, C. Hunt, C. Murray, G. Galli, 2004, ISBN: 1-55899-768-7

Volume 819— Interfacial Engineering for Optimized Properties III, C.A. Schuh, M. Kumar, V. Randle,C.B. Carter, 2004, ISBN: 1-55899-769-5

Volume 820— Nanoengineered Assemblies and Advanced Micro/Nanosystems, J.T. Borenstein,P. Grodzinski, L.P. Lee, J. Liu, Z. Wang, D. Mcllroy, L. Merhari, J.B. Pendry, D.P. Taylor,2004, ISBN: 1-55899-770-9

Volume 821— Nanoscale Materials and Modeling—Relations Among Processing, Microstructure andMechanical Properties, P.M. Anderson, T. Foecke, A. Misra, R.E. Rudd, 2004,ISBN: 1-55899-771-7

Volume 822— Nanostructured Materials in Alternative Energy Devices, E.R. Leite, J-M. Tarascon,Y-M. Chiang, E.M. Kelder, 2004, ISBN: 1-55899-772-5

Volume 823— Biological and Bioinspired Materials and Devices, J. Aizenberg, C. Orme, W.J. Landis,R. Wang, 2004, ISBN: 1-55899-773-3

Volume 824— Scientific Basis for Nuclear Waste Management XXVIII, J.M. Hanchar, S. Stroes-Gascoyne,L. Browning, 2004, ISBN: 1-55899-774-1

Volume 825E—Semiconductor Spintronics, B. Beschoten, S. Datta, J. Kikkawa, J. Nitta, T. Schapers, 2004,ISBN: 1-55899-753-9

Volume 826E—Proteins as Materials, V.P. Conticello, A. Chilkoti, E. Atkins, D.G. Lynn, 2004,ISBN: 1-55899-754-7

Volume 827E—Educating Tomorrow's Materials Scientists and Engineers, K.C. Chen, M.L. Falk,T.R. Finlayson, W.E. Jones Jr., LJ. Martinez-Miranda, 2004, ISBN: 1-55899-755-5

Prior Materials Research Society Symposium Proceedings available by contacting Materials Research Society

www.cambridge.org© in this web service Cambridge University Press

Cambridge University Press978-1-107-40915-6 - Nanoengineered Assemblies and Advanced Micro/Nanosystems:Materials Research Society Symposium Proceedings: Volume 820Editors: David P. Taylor, Jun Liu, David Mcllroy, Lhadi Merhari, J. B. Pendry, Jeffrey T. Borenstein, Piotr Grodzinski, Luke P. Lee and Zhong Lin WangFrontmatterMore information

SYMPOSIUM O

www.cambridge.org© in this web service Cambridge University Press

Cambridge University Press978-1-107-40915-6 - Nanoengineered Assemblies and Advanced Micro/Nanosystems:Materials Research Society Symposium Proceedings: Volume 820Editors: David P. Taylor, Jun Liu, David Mcllroy, Lhadi Merhari, J. B. Pendry, Jeffrey T. Borenstein, Piotr Grodzinski, Luke P. Lee and Zhong Lin WangFrontmatterMore information