m/s cytech coatings pvt. ltd.-ii 1environmentclearance.nic.in/writereaddata/online/ec/... · 2015....

M/s Cytech Coatings Pvt. Ltd.-II 1


ANNEXURE-I: POINT WISE TABULAR COMPLIANCE OF AWARDED TOR

The project authorities gave a detailed presentation on the salient features of the project and proposed

environmental protection measures to be undertaken along with the draft Term of References for the

preparation of EIA/EMP report. All Synthetic Organic Chemicals Industry located inside the notified industrial

area/estate are listed at S.N. 5(f) under category ‘B’. However, applicability of general condition due to project

location within interstate boundary, proposal is treated as category ‘A’ and appraised by Expert Appraisal

Committee (I).

M/s Cytech Coatings Pvt. Ltd.-II have proposed for setting up of Synthetic Resin Manufacturing Unit at Plot No.-

C1-2807, Chemical Zone, GIDC Notified Area, Sarigam, Taluka - Umargam, District Valsad, Gujarat. Total plot

area is 1180 m2. Total cost of the project is Rs. 4.40 Crore. Damanganga River is flowing at a distance of 6 Km.

D&NH wildlife sanctuary is located at a distance of 17 Km. Forest patches are located at a distance of 2 Km.

Following are the particulars of Awarded TOR Points &point wise compliance status with compliance note:

ToR

No. ToR description Compliance status & Remark

1. Executive summary of the project

Complied Executive Summary is submitted with EIA report as separate document.

2. Justification of the project Complied The justification of the project has been explained in EIA Report under Chapter 2, Section-2.12. , Page no 13.

3. Promoters and their back ground.

Complied The detail of promoters of the company has been given in EIA Report under Chapter 1, Section-1.1.2, Page no 1.

4. Regulatory framework.

Complied The Regulatory Framework applicable to the project has been explained in EIA Report under Chapter 1, Section-1.2.4, Page no.2.

5. A map indicating location of the project and distance from severely polluted area.

Complied The map has been presented in EIA Report under Chapter 2, Figure 2.1, Page no. 15.

6. Project location and plant layout.

Complied The project location map & layout have been presented in EIA Report Annexure- VII (A&B).

7. Infrastructure facilities including power sources.

Complied The infrastructure facilities required for the project have been explained in EIA Report under Chapter 2, Section 2.2.1 to 2.2.6., Page no. 17 to 21.

8. Total cost of the project along with total capital cost and recurring cost/annum for environmental pollution control measures.

Complied The total cost & break up including capital & recurring cost for environmental pollution control measures has been presented in EIA Report under Chapter 2, Section 2.2.6, Page no. 21.

9. Project site location along with site map of 10 km area and site details providing various industries, surface water bodies, forests etc.

Complied The project site location & map of 10 km area with necessary features has been presented in EIA


ToR


Report under Chapter 3, Figure 3.1(a), Page no. 38.

10. Present land use based on satellite imagery for the study area of 10 km radius. Details of land availability for the project along with supporting document.

Complied The present land use based on Quick Bird Image-2009 satellite image has been presented in EIA Report under Chapter 3, Section 3.5 &Details of land documents have been presented in EIA Report Annexure- VI.

11. Location of National Park/Wild life sanctuary/Reserve forest within 10 km radius of the project.

Complied There is no National Park/WLS falling within 10 km radius of project site. Details are given in EIA Report under Chapter 3, Section 3.2 & Table 3.1., Page no. 36.

12. Permission from the State Forest Department regarding the impact of the proposed plant on the surrounding reserve forests.

Not Applicable Since there is no reserve forest falling within the Study Area. Hence permission from State Forest Department is not required.

13. Details of the total land and break-up of the land use for green belt and other uses.

Complied The breakup of plot area/land of the proposed project has been presented in EIA Report under Chapter 2, Section 2.2.1, Page no. 17.

14. List of products along with the production capacities.

Complied The list of proposed project has been tabulated in EIA Report under Chapter 2, Section 2.1.1 , Page no. 13.

15. Detailed list of raw material required and source, mode of storage.

Complied The details of raw materials have been explained in EIA Report under Chapter 2, Figure 2.3.1, Page no 21, and Hazardous Raw material source, mode of storage have been explained in RA report , Table 2.2 page no. 7.

16. Manufacturing process details along with the chemical reactions and process flow chart.

Complied The details have been explained in EIA Report under Chapter 2, Figure 2.3.2, and Page no. 22.

17. Action plan for the transportation of raw material and products.

Complied The action plan for transportation of raw materials has been shown in RA report, Section, 2.11, Page no.22.

18. Site-specific micro-meteorological data using temperature, relative humidity, hourly wind speed and direction and rainfall is necessary.

Complied The site specific micro-meteorological data has been presented in EIA Report under Chapter 3, Section 3.2.3, Page no.55.

19. Ambient air quality monitoring at 6 locations within

the study area of 5 km., aerial coverage from project

site as per NAAQES notified on 16th September,

2009. Location of one AAQMS in downwind

direction.

Complied The details of ambient air quality monitoring at 6 locations has been explained in EIA Report under Chapter 3, Section 3.2.4, Page no. 57.

20. One season site-specific micro-meteorological data using temperature, relative humidity, hourly wind speed and direction and rainfall and AAQ data (except monsoon) for PM10, SO2, NOx, CO, NH3

Complied One season data of site specific micrometeorology has been presented in EIA Report under Chapter 3, Section 3.2.3, Page no. 55.


ToR


including VOCs shall be collected. The monitoring stations shall take into account the pre-dominant wind direction, population zone and sensitive receptors including reserved forests. Data for water and noise monitoring shall also be included.

One season data of ambient air quality monitoring for PM10, SO2, NOx , CO,NH3 including VOCs has been presented in EIA Report under Chapter 3, Section 3.2.4, Page no. 57.

21. Details of water and air pollution and its mitigation plan

Complied Details of Air and Water Pollution & Control Measures proposed for the project have been described in EIA Report under Chapter 2, Section 2.4.1 & 2.4.2, Page no.28 & 29, And Its Mitigation plan have been described in EIA Report under Chapter 8, Section 8.3.1.& 8.3.2, Page no. 132 & 133.

22. Air pollution control measures proposed for the effective control of gaseous/ process emissions within permissible limits.

Complied The details of Air pollution control measures proposed for the effective control of gaseous/ process emissions has been described in EIA Report under Chapter 4, Section 4.3.3, Page no. 94.

23. An action plan prepared by SPCB to control and monitor secondary fugitive emissions from all the sources.

No considerable fugitive emission is anticipated except negligible emission of organic vapour/ fumes.

24. Determination of atmospheric inversion level at the project site and assessment of ground level concentration of pollutants from the stack emission based on site specific meteorological features. Air quality modelling for proposed plant.

Complied The details regarding Modeling for Emission &Ambient Air Quality has been described in EIA Report under Chapter 4, Section 4.3.3.1, Page no.94.

25. Name of all the solvents to be used in the process and details of solvent recovery system.

Complied All solvents are utilized in reactions for manufacturing of proposed products. Hence issue of solvent recovery is not anticipated.

26. Design details of ETP, incinerator, if any along with boiler, scrubbers/bag filters etc.

The detail of ETP is given in EIA Report under Chapter 8, Section 8.3.2., Page no 134.

27. Action plan to control ambient air quality as per NAAQS Standards notified by the Ministry on 16th

September, 2009.

Complied Action plan to control ambient air quality as per NAAQES Standards notified by the Ministry on 16thSeptember, 2009has been described in EIA Report under Chapter 5 as Environmental Monitoring Plan and as EMP in Chapter 8, Section 8.3.1.

28. Permission from Competent Authority for the drawl of 30.5 m3/day water. Water balance chart including quantity of effluent generated recycled and reused and effluent discharge.

Complied Acknowledged Copy of water requirement letter To GIDC water Supply Department are enclosed as Annexure VII (D). Detail of Water balance chart including quantity of effluent generated recycled and reused and effluent discharge have been describer in EIA Report , Chapter-2, Section 2.4.2,Page no. 29


ToR


29. Complete scheme of effluent treatment. Characteristics of untreated and treated effluent to meet the standard.

Complied The detail of ETP is given in EIA Report under Chapter 8, Section 8.3.2., Page no 134.

30. Zero discharge effluent concepts to be adopted.

The unit will have industrial effluent generation from process, washings and boiler& cooling blow down. The industrial effluent will be treated in full-fledged in-house ETP equipped with all required Primary, Secondary & Tertiary Treatment units. The treated wastewater will be disposed off through the underground disposal pipeline of GIDC Sarigam which is going to Arabian sea. Details are presented in EIA Report under Chapter 2, section 2.4.2., pg-29 and Chapter 8, section 8.3.2., pg-137.

31. Ground water quality monitoring minimum at 6 locations shall be carried out. Geological features and Geo-hydrological status of the study area and ecological status (Terrestrial and Aquatic).

Complied Detail of Ground water quality monitoring minimum at 6 locations have been described in EIA report, Chapter-3, Section-3.2.2.2., Page no. 52. Detail of Geological features and Geo-hydrological status of the study area and ecological status (Terrestrial and Aquatic) have been described in EIA report, Chapter-3, Section-3.2.1.1 & 3.2.2.1., Page no. 42 & 51.

32. The details of solid and hazardous wastes generation, storage, utilization and disposal particularly related to the hazardous waste calorific value of hazardous waste and detailed characteristic of the hazardous waste. Action plan for the disposal of fly ash generated from boiler shall be included.

Complied The details of hazardous wastes have been described in EIA Report under Chapter 2, Section 2.4.3., Page no 30. There is no Fly ash generation from existing & proposed project. Boiler will be operated using Natural Gas as fuel.

33. Material Safety Data Sheet for all the Chemicals are being used/will be used.

Complied The details of Material Safety Data Sheet for all the Chemicals will be used are given as Annexure- VIII.

34. Authorization/Membership for the disposal of solid/hazardous waste in TSDF.

We have taken Membership Sarigam Waste & Effluent Management Company Ltd. for the disposal of solid/hazardous waste in TSDF. The copy of membership letter is enclosed in EIA report under Annexure-VII

35. Risk assessment for storage for chemicals/solvents. Action plan for handling & safety system.

Complied The Risk Assessment Report has been enclosed in EIA Report under Annexure IV.

36. An action plan to develop green belt in 33 % area. Layout plan for green belt shall be provided.

Complied The details of greenbelt development have been described in EIA Report under Chapter 2, Section 2.4.5, Page no. 30 &Chapter 8, Section 8.4.1., Page no. 144.


ToR


37. Action plan for rainwater harvesting measures at plant site shall be included to harvest rainwater from the roof tops and storm water drains to recharge the ground water.

Roof Rainwater harvesting at plant site wiil not be feasible Since the unit is located in GIDC, Chemical zone.

38. Details of occupational health programme. i) To which chemicals, workers are exposed directly or indirectly. ii) Whether these chemicals are within Threshold Limit Values (TLV)/ Permissible Exposure Levels as per ACGIH recommendation. iii) What measures company have taken to keep these chemicals within PEL/TLV. iv) How the workers are evaluated concerning their exposure to chemicals during pre-placement and periodical medical monitoring. v) What are onsite and offsite emergency plan during chemical disaster. vi) Liver function tests (LFT) during pre-placement and periodical examination. vii) Details of occupational health surveillance programme.

Complied Some employees working in the storage and production area are suspected to be exposed to some toxic/hazardous chemicals. Considering the probability of the exposure to the hazardous chemicals a separate document of “Chemical Safety Plan” is prepared as a part of RA report which is enclosed in the present EIA report as Annexure-IV. The details of Occupational Health and Safety are also mentioned in EIA Report under Chapter 8, Section 8.3.6, pg. 145.

39. Socio-economic development activities shall be in place.

Complied The details of socioeconomic development activities have been described in EIA Report under Chapter 8, Section 8.4.2.,Page no 145.

40. Note on compliance to the recommendations mentioned in the CREP guidelines.

CREP Guidelines are not applicable to the proposed project as CPCB has not issued any CREP Guidelines.

41. Detailed Environment management Plan (EMP) with specific reference to details of air pollution control system, water & wastewater management, monitoring frequency, responsibility and time bound implementation plan for mitigation measure shall be provided.

Complied EMP for proposed project has been prepared covering all necessary measures & action plans. The prepared EMP focusing on all mitigation measures & action plan required for control & prevention of probable impacts of the proposed project has been described in EIA Report under Chapter 8., Section 8.3., Page no.131

42. EMP shall include the concept of waste-minimization, recycle / reuse / recover techniques, Energy conservation, and natural resource conservation.

Complied The detailed EMP have been described in EIA Report under Chapter 8.The details of energy conservation, waste minimization &reuse/recyle, resource recovery & reuse/recycling etc. have


ToR


been described as Cleaner Production Measures in EIA Report under Chapter 8, Section 8.3.

43. Total capital cost and recurring cost/annum for environmental pollution control measures.

Complied The detailed Total capital cost and recurring cost/annum for environmental pollution control measures have been described in EIA report, Chepter-5, Table-5.3, Page no 121.

44. Corporate Environmental Responsibility (a) Does the company have a well laid down Environment Policy approved by its Board of Directors? If so, it may be detailed in the EIA report. (b) Does the Environmental Policy prescribe for standard operating process/ procedures to bring into focus any infringement / deviation/violation of the environmental or forest norms / conditions? If so, it may be detailed in the EIA report. (c )What is the hierarchical system or Administrative order of the company to deal with the environmental issues and for ensuring compliance with the EC conditions. Details of this system may be given. (d)Does the company have a system of reporting of non-compliance / violations of environmental norms to the Board of Directors of the company and / or shareholders or stakeholders at large? This reporting mechanism should be detailed in the EIA report.

At present company has not laid down any “Environmental Policy”. However, the company will laid down “Environmental Policy” approved by Board Of Director after commissioning of proposed unit. The company will prepare Environmental Policy for standard operating process/ procedures to bring into focus any infringement / deviation / violation of the environmental or forest norms / conditions. Some basic details of same is described in EIA report, Chapter 8, section 8.2. Company has planned for formulation of Environmental Management Cell as described in in EIA report, Chapter 8, sectfor ion 8.2. EMP prepared for the proposed project contains a brief procedure and system for reporting of non-compliance / violations of environmental norms to the Board of Directors of the company and / or shareholders or stakeholders at large. Such details are described in EIA report, Chapter 8, sectfor ion 8.2

45. Any litigation pending against the project and/or any direction/order passed by any Court of Law against the project, if so, details thereof.

Since this is a proposed new unit, which will establish after obtaining EC and necessary permissions, this condition is not applicable to us.

46. Public hearing issues raised and commitments made by the project proponent on the same should be included separately in EIA/EMP Report in the form of tabular chart with financial budget for complying with the commitments made.

As the proposed new project is located within the GIDC notified industrial area, which is notified before 2006 on 05/05/1997. And further as per the recent OM No. J-11013/36/2014-IA-I Dated. 10/12/2014 our project is exempted from Public Hearing. The Plot allotment/ transfer letter and the letter showing the unit is within the Notified Area is enclosed in EIA report as Annexure- VI

47. A tabular chart with index for point wise compliance of above TORs.

Complied


ToR


* The following general points shall be noted: i. All documents shall be properly indexed, page numbered. ii. Period/date of data collection shall be clearly indicated. iii. Authenticated English translation of all material provided in Regional languages. iv. The letter/application for EC shall quote the MOEF file No. and also attach a copy of the letter. v. The copy of the letter received from the Ministry shall be also attached as an annexure to the final EIA-EMP Report. vi. The final EIA-EMP report submitted to the Ministry must incorporate the issues in this letter. The index of the final EIA-EMP report must indicate the specific chapter and page no. of the EIA-EMP Report. vii. Certificate of Accreditation issued by the QCI to the environmental consultant shall be included.

Complied

PM10 - Dispersion Modeling Results

Page 1

X Y Concentration Elevation Hill Heights Flagpole Aver. Period Source Group Rank Net ID Date [ug/m3] (ZELEV) (ZHILL) (ZFLAG) (AVE) (GRP)

266110 2237023 0.01793 3 3 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 267110 2237023 0.01772 3 3 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 268110 2237023 0.03087 4 4 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 269110 2237023 0.02433 7.2 7.2 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 270110 2237023 0.03027 12.7 12.7 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 271110 2237023 0.03266 8.6 8.6 0 24-HR ALL 1ST UCART1 10/11/2013 24 hr 272110 2237023 0.03683 20.5 20.5 0 24-HR ALL 1ST UCART1 12/25/2013 24 hr 273110 2237023 0.05546 12.2 12.2 0 24-HR ALL 1ST UCART1 12/25/2013 24 hr 274110 2237023 0.0364 23.1 23.1 0 24-HR ALL 1ST UCART1 12/19/2013 24 hr 275110 2237023 0.0401 22.9 22.9 0 24-HR ALL 1ST UCART1 12/28/2013 24 hr 276110 2237023 0.02476 30.3 30.3 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 277110 2237023 0.01792 38.1 38.1 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 278110 2237023 0.0187 45.4 45.4 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 279110 2237023 0.0189 57.7 57.7 0 24-HR ALL 1ST UCART1 10/25/2013 24 hr 280110 2237023 0.02139 39.1 39.1 0 24-HR ALL 1ST UCART1 12/8/2013 24 hr 281110 2237023 0.01889 34.3 34.3 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 282110 2237023 0.02704 28.4 28.4 0 24-HR ALL 1ST UCART1 12/17/2013 24 hr 283110 2237023 0.02672 31.2 31.2 0 24-HR ALL 1ST UCART1 12/17/2013 24 hr 284110 2237023 0.01456 31.6 31.6 0 24-HR ALL 1ST UCART1 12/17/2013 24 hr 285110 2237023 0.01453 30.9 30.9 0 24-HR ALL 1ST UCART1 12/7/2013 24 hr 286110 2237023 0.0115 53.6 53.6 0 24-HR ALL 1ST UCART1 12/7/2013 24 hr 266110 2238023 0.02105 4.5 4.5 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 267110 2238023 0.02099 4.7 4.7 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 268110 2238023 0.02131 4.5 4.5 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 269110 2238023 0.03489 8.8 8.8 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 270110 2238023 0.0205 13.9 13.9 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 271110 2238023 0.04095 20.7 20.7 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 272110 2238023 0.03463 18.2 18.2 0 24-HR ALL 1ST UCART1 10/11/2013 24 hr 273110 2238023 0.06709 24.4 24.4 0 24-HR ALL 1ST UCART1 12/25/2013 24 hr 274110 2238023 0.04217 18.4 18.4 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 275110 2238023 0.04491 19.1 19.1 0 24-HR ALL 1ST UCART1 12/28/2013 24 hr 276110 2238023 0.02804 26.9 26.9 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 277110 2238023 0.02016 41.1 41.1 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 278110 2238023 0.02165 45.7 45.7 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 279110 2238023 0.01842 43.7 43.7 0 24-HR ALL 1ST UCART1 11/6/2013 24 hr 280110 2238023 0.01863 72.2 72.2 0 24-HR ALL 1ST UCART1 12/8/2013 24 hr 281110 2238023 0.02757 38.4 38.4 0 24-HR ALL 1ST UCART1 12/17/2013 24 hr 282110 2238023 0.033 31 31 0 24-HR ALL 1ST UCART1 12/17/2013 24 hr 283110 2238023 0.02019 29.8 29.8 0 24-HR ALL 1ST UCART1 12/17/2013 24 hr 284110 2238023 0.01627 26.5 26.5 0 24-HR ALL 1ST UCART1 12/7/2013 24 hr 285110 2238023 0.01238 34 34 0 24-HR ALL 1ST UCART1 12/7/2013 24 hr 286110 2238023 0.0063 50.8 50.8 0 24-HR ALL 1ST UCART1 10/6/2013 24 hr 266110 2239023 0.01383 10.6 10.6 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 267110 2239023 0.024 4.4 4.4 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 268110 2239023 0.02556 11.3 11.3 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 269110 2239023 0.02596 10 10 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 270110 2239023 0.03716 9.5 9.5 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 271110 2239023 0.03602 18.8 18.8 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 272110 2239023 0.04558 28.2 28.2 0 24-HR ALL 1ST UCART1 10/11/2013 24 hr 273110 2239023 0.0635 30.7 30.7 0 24-HR ALL 1ST UCART1 12/25/2013 24 hr 274110 2239023 0.05425 19.7 19.7 0 24-HR ALL 1ST UCART1 12/25/2013 24 hr

Discrete Receptor ID


Page 2



275110 2239023 0.05242 24.9 24.9 0 24-HR ALL 1ST UCART1 12/28/2013 24 hr 276110 2239023 0.03215 24.2 24.2 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 277110 2239023 0.02046 30.7 30.7 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 278110 2239023 0.02384 41.8 70 0 24-HR ALL 1ST UCART1 10/25/2013 24 hr 279110 2239023 0.0288 42.5 42.5 0 24-HR ALL 1ST UCART1 12/8/2013 24 hr 280110 2239023 0.02961 51.5 51.5 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 281110 2239023 0.03958 35.6 35.6 0 24-HR ALL 1ST UCART1 12/17/2013 24 hr 282110 2239023 0.02839 30.9 87 0 24-HR ALL 1ST UCART1 12/17/2013 24 hr 283110 2239023 0.01954 30 30 0 24-HR ALL 1ST UCART1 12/7/2013 24 hr 284110 2239023 0.01414 30.1 30.1 0 24-HR ALL 1ST UCART1 12/7/2013 24 hr 285110 2239023 0.00767 36.6 36.6 0 24-HR ALL 1ST UCART1 10/6/2013 24 hr 286110 2239023 0.01149 38 38 0 24-HR ALL 1ST UCART1 11/8/2013 24 hr 266110 2240023 0.01566 18.4 18.4 0 24-HR ALL 1ST UCART1 12/8/2013 24 hr 267110 2240023 0.01386 12.8 12.8 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 268110 2240023 0.0292 17.1 17.1 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 269110 2240023 0.03196 18.4 18.4 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 270110 2240023 0.03164 10.8 10.8 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 271110 2240023 0.0375 20.3 20.3 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 272110 2240023 0.05745 29.4 38 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 273110 2240023 0.04649 28.4 28.4 0 24-HR ALL 1ST UCART1 11/6/2013 24 hr 274110 2240023 0.086 31.8 45 0 24-HR ALL 1ST UCART1 12/25/2013 24 hr 275110 2240023 0.05735 23 23 0 24-HR ALL 1ST UCART1 12/28/2013 24 hr 276110 2240023 0.03864 26.8 26.8 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 277110 2240023 0.02356 38.3 38.3 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 278110 2240023 0.02721 44.4 72 0 24-HR ALL 1ST UCART1 10/25/2013 24 hr 279110 2240023 0.03562 45.6 45.6 0 24-HR ALL 1ST UCART1 12/8/2013 24 hr 280110 2240023 0.06145 68.8 93 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 281110 2240023 0.04128 35.6 35.6 0 24-HR ALL 1ST UCART1 12/17/2013 24 hr 282110 2240023 0.02284 30.1 30.1 0 24-HR ALL 1ST UCART1 12/7/2013 24 hr 283110 2240023 0.01732 33.3 33.3 0 24-HR ALL 1ST UCART1 12/7/2013 24 hr 284110 2240023 0.00931 31 31 0 24-HR ALL 1ST UCART1 10/6/2013 24 hr 285110 2240023 0.0143 31.6 31.6 0 24-HR ALL 1ST UCART1 11/8/2013 24 hr 286110 2240023 0.01145 35.7 35.7 0 24-HR ALL 1ST UCART1 11/8/2013 24 hr 266110 2241023 0.01475 15.6 15.6 0 24-HR ALL 1ST UCART1 11/8/2013 24 hr 267110 2241023 0.0191 18.4 18.4 0 24-HR ALL 1ST UCART1 12/8/2013 24 hr 268110 2241023 0.01672 24.3 62 0 24-HR ALL 1ST UCART1 10/19/2013 24 hr 269110 2241023 0.03508 26.5 93 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 270110 2241023 0.03962 18.6 18.6 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 271110 2241023 0.03937 15.5 15.5 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 272110 2241023 0.0418 41.9 41.9 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 273110 2241023 0.06864 37.8 37.8 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 274110 2241023 0.1062 24.8 24.8 0 24-HR ALL 1ST UCART1 12/25/2013 24 hr 275110 2241023 0.06036 21.5 21.5 0 24-HR ALL 1ST UCART1 12/28/2013 24 hr 276110 2241023 0.04535 23.8 23.8 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 277110 2241023 0.02738 31.3 31.3 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 278110 2241023 0.02903 37.9 37.9 0 24-HR ALL 1ST UCART1 12/8/2013 24 hr 279110 2241023 0.04164 50.5 50.5 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 280110 2241023 0.05796 39.4 39.4 0 24-HR ALL 1ST UCART1 12/17/2013 24 hr 281110 2241023 0.0277 33.5 33.5 0 24-HR ALL 1ST UCART1 12/7/2013 24 hr 282110 2241023 0.02016 30.1 30.1 0 24-HR ALL 1ST UCART1 12/7/2013 24 hr 283110 2241023 0.01209 33 33 0 24-HR ALL 1ST UCART1 10/6/2013 24 hr


Page 3



284110 2241023 0.01764 33.3 33.3 0 24-HR ALL 1ST UCART1 11/8/2013 24 hr 285110 2241023 0.01177 38.1 38.1 0 24-HR ALL 1ST UCART1 10/6/2013 24 hr 286110 2241023 0.00848 36.3 36.3 0 24-HR ALL 1ST UCART1 10/6/2013 24 hr 266110 2242023 0.02026 4.9 4.9 0 24-HR ALL 1ST UCART1 12/28/2013 24 hr 267110 2242023 0.018 10.5 10.5 0 24-HR ALL 1ST UCART1 10/24/2013 24 hr 268110 2242023 0.01949 17.3 17.3 0 24-HR ALL 1ST UCART1 12/8/2013 24 hr 269110 2242023 0.02718 40.2 93 0 24-HR ALL 1ST UCART1 12/8/2013 24 hr 270110 2242023 0.03979 24.9 24.9 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 271110 2242023 0.05167 21.7 21.7 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 272110 2242023 0.05294 31.2 31.2 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 273110 2242023 0.25762 67.8 87 0 24-HR ALL 1ST UCART1 12/25/2013 24 hr 274110 2242023 0.09086 28.1 28.1 0 24-HR ALL 1ST UCART1 12/25/2013 24 hr 275110 2242023 0.08806 23.1 23.1 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 276110 2242023 0.05693 26.9 26.9 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 277110 2242023 0.03843 30.8 30.8 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 278110 2242023 0.05055 33.3 33.3 0 24-HR ALL 1ST UCART1 12/8/2013 24 hr 279110 2242023 0.0715 46.3 46.3 0 24-HR ALL 1ST UCART1 12/17/2013 24 hr 280110 2242023 0.04213 37.3 37.3 0 24-HR ALL 1ST UCART1 12/17/2013 24 hr 281110 2242023 0.02348 26.7 26.7 0 24-HR ALL 1ST UCART1 12/7/2013 24 hr 282110 2242023 0.01869 34.5 34.5 0 24-HR ALL 1ST UCART1 11/8/2013 24 hr 283110 2242023 0.01994 34.6 34.6 0 24-HR ALL 1ST UCART1 11/8/2013 24 hr 284110 2242023 0.01252 36.2 36.2 0 24-HR ALL 1ST UCART1 10/6/2013 24 hr 285110 2242023 0.0082 40.8 40.8 0 24-HR ALL 1ST UCART1 10/6/2013 24 hr 286110 2242023 0.0054 37.3 37.3 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 266110 2243023 0.01903 15.7 15.7 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 267110 2243023 0.02097 10.7 10.7 0 24-HR ALL 1ST UCART1 11/6/2013 24 hr 268110 2243023 0.02513 12.5 12.5 0 24-HR ALL 1ST UCART1 11/6/2013 24 hr 269110 2243023 0.02544 20.3 20.3 0 24-HR ALL 1ST UCART1 10/24/2013 24 hr 270110 2243023 0.03321 24.3 24.3 0 24-HR ALL 1ST UCART1 12/8/2013 24 hr 271110 2243023 0.04777 36.9 80 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 272110 2243023 0.07904 49.8 160 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 273110 2243023 0.06703 33.1 33.1 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 274110 2243023 0.08885 26.7 26.7 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 275110 2243023 0.12954 28.5 28.5 0 24-HR ALL 1ST UCART1 12/25/2013 24 hr 276110 2243023 0.07575 31.3 31.3 0 24-HR ALL 1ST UCART1 12/28/2013 24 hr 277110 2243023 0.04754 31.8 31.8 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 278110 2243023 0.05635 38.9 38.9 0 24-HR ALL 1ST UCART1 12/17/2013 24 hr 279110 2243023 0.06623 33 33 0 24-HR ALL 1ST UCART1 12/17/2013 24 hr 280110 2243023 0.03265 35.5 35.5 0 24-HR ALL 1ST UCART1 12/7/2013 24 hr 281110 2243023 0.02748 25.9 25.9 0 24-HR ALL 1ST UCART1 11/8/2013 24 hr 282110 2243023 0.01809 27.5 27.5 0 24-HR ALL 1ST UCART1 11/8/2013 24 hr 283110 2243023 0.01211 32.5 32.5 0 24-HR ALL 1ST UCART1 10/6/2013 24 hr 284110 2243023 0.00781 37.8 37.8 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 285110 2243023 0.00946 38.9 38.9 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 286110 2243023 0.01272 42.7 42.7 0 24-HR ALL 1ST UCART1 11/10/2013 24 hr 266110 2244023 0.01288 12.6 12.6 0 24-HR ALL 1ST UCART1 10/21/2013 24 hr 267110 2244023 0.0144 14.8 14.8 0 24-HR ALL 1ST UCART1 11/6/2013 24 hr 268110 2244023 0.02345 13.8 13.8 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 269110 2244023 0.02948 15.3 15.3 0 24-HR ALL 1ST UCART1 11/6/2013 24 hr 270110 2244023 0.0397 26.2 26.2 0 24-HR ALL 1ST UCART1 11/6/2013 24 hr 271110 2244023 0.03835 35.5 160 0 24-HR ALL 1ST UCART1 10/24/2013 24 hr


Page 4



272110 2244023 0.00975 128.3 160 0 24-HR ALL 1ST UCART1 10/23/2013 24 hr 273110 2244023 0.11423 39 160 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 274110 2244023 0.09731 33.1 33.1 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 275110 2244023 0.21746 21.1 21.1 0 24-HR ALL 1ST UCART1 12/25/2013 24 hr 276110 2244023 0.09951 25.5 25.5 0 24-HR ALL 1ST UCART1 12/28/2013 24 hr 277110 2244023 0.07493 35.2 35.2 0 24-HR ALL 1ST UCART1 12/8/2013 24 hr 278110 2244023 0.13545 54.9 145 0 24-HR ALL 1ST UCART1 12/17/2013 24 hr 279110 2244023 0.03965 35.1 145 0 24-HR ALL 1ST UCART1 12/7/2013 24 hr 280110 2244023 0.03978 25.5 25.5 0 24-HR ALL 1ST UCART1 11/8/2013 24 hr 281110 2244023 0.018 25.3 25.3 0 24-HR ALL 1ST UCART1 10/6/2013 24 hr 282110 2244023 0.01065 26.6 26.6 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 283110 2244023 0.01503 28.6 28.6 0 24-HR ALL 1ST UCART1 11/10/2013 24 hr 284110 2244023 0.02175 36.8 36.8 0 24-HR ALL 1ST UCART1 11/10/2013 24 hr 285110 2244023 0.02319 34.3 34.3 0 24-HR ALL 1ST UCART1 11/10/2013 24 hr 286110 2244023 0.02262 34.5 34.5 0 24-HR ALL 1ST UCART1 11/10/2013 24 hr 266110 2245023 0.01782 12.5 12.5 0 24-HR ALL 1ST UCART1 10/21/2013 24 hr 267110 2245023 0.02028 12.1 12.1 0 24-HR ALL 1ST UCART1 10/21/2013 24 hr 268110 2245023 0.02236 10.6 10.6 0 24-HR ALL 1ST UCART1 10/21/2013 24 hr 269110 2245023 0.02397 12.9 12.9 0 24-HR ALL 1ST UCART1 10/21/2013 24 hr 270110 2245023 0.02788 25.5 133 0 24-HR ALL 1ST UCART1 11/6/2013 24 hr 271110 2245023 0.01945 107.3 133 0 24-HR ALL 1ST UCART1 10/10/2013 24 hr 272110 2245023 0.07425 40.3 160 0 24-HR ALL 1ST UCART1 11/6/2013 24 hr 273110 2245023 0.09045 47.4 47.4 0 24-HR ALL 1ST UCART1 12/8/2013 24 hr 274110 2245023 0.17822 34 34 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 275110 2245023 0.17928 27.7 27.7 0 24-HR ALL 1ST UCART1 11/6/2013 24 hr 276110 2245023 0.14869 28.3 28.3 0 24-HR ALL 1ST UCART1 12/28/2013 24 hr 277110 2245023 0.11414 38 38 0 24-HR ALL 1ST UCART1 12/20/2013 24 hr 278110 2245023 0.04923 39 145 0 24-HR ALL 1ST UCART1 12/7/2013 24 hr 279110 2245023 0.04708 31.5 145 0 24-HR ALL 1ST UCART1 11/8/2013 24 hr 280110 2245023 0.0161 18.1 18.1 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 281110 2245023 0.02546 23.8 23.8 0 24-HR ALL 1ST UCART1 11/10/2013 24 hr 282110 2245023 0.0306 24.6 24.6 0 24-HR ALL 1ST UCART1 11/10/2013 24 hr 283110 2245023 0.03164 30.9 30.9 0 24-HR ALL 1ST UCART1 11/10/2013 24 hr 284110 2245023 0.02594 28.5 28.5 0 24-HR ALL 1ST UCART1 11/10/2013 24 hr 285110 2245023 0.02046 28.5 28.5 0 24-HR ALL 1ST UCART1 11/10/2013 24 hr 286110 2245023 0.01651 34.6 34.6 0 24-HR ALL 1ST UCART1 11/10/2013 24 hr 266110 2246023 0.01965 2.7 17 0 24-HR ALL 1ST UCART1 11/19/2013 24 hr 267110 2246023 0.02334 10.6 10.6 0 24-HR ALL 1ST UCART1 11/19/2013 24 hr 268110 2246023 0.02519 4.1 4.1 0 24-HR ALL 1ST UCART1 11/19/2013 24 hr 269110 2246023 0.02802 11.5 11.5 0 24-HR ALL 1ST UCART1 11/19/2013 24 hr 270110 2246023 0.03533 20.2 20.2 0 24-HR ALL 1ST UCART1 10/21/2013 24 hr 271110 2246023 0.04933 23.6 23.6 0 24-HR ALL 1ST UCART1 10/21/2013 24 hr 272110 2246023 0.06876 34.9 34.9 0 24-HR ALL 1ST UCART1 10/21/2013 24 hr 273110 2246023 0.10035 73.4 73.4 0 24-HR ALL 1ST UCART1 12/18/2013 24 hr 274110 2246023 0.16872 40.6 40.6 0 24-HR ALL 1ST UCART1 11/6/2013 24 hr 275110 2246023 0.3672 36.7 36.7 0 24-HR ALL 1ST UCART1 11/2/2013 24 hr 276110 2246023 0.2892 33 33 0 24-HR ALL 1ST UCART1 12/28/2013 24 hr 277110 2246023 0.10077 40.4 40.4 0 24-HR ALL 1ST UCART1 11/30/2013 24 hr 278110 2246023 0.02666 31.6 31.6 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 279110 2246023 0.04472 27.4 27.4 0 24-HR ALL 1ST UCART1 11/10/2013 24 hr 280110 2246023 0.04017 22.9 22.9 0 24-HR ALL 1ST UCART1 11/10/2013 24 hr


Page 5



281110 2246023 0.03115 27.7 27.7 0 24-HR ALL 1ST UCART1 11/10/2013 24 hr 282110 2246023 0.02225 24.6 24.6 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 283110 2246023 0.01821 28.2 28.2 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 284110 2246023 0.01479 30.1 30.1 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 285110 2246023 0.01234 33.5 33.5 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 286110 2246023 0.01017 33.9 33.9 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 266110 2247023 0.01059 0 0 0 24-HR ALL 1ST UCART1 11/11/2013 24 hr 267110 2247023 0.01202 0 0 0 24-HR ALL 1ST UCART1 11/11/2013 24 hr 268110 2247023 0.01419 6.1 6.1 0 24-HR ALL 1ST UCART1 11/11/2013 24 hr 269110 2247023 0.01708 11.2 11.2 0 24-HR ALL 1ST UCART1 11/11/2013 24 hr 270110 2247023 0.02097 15.5 15.5 0 24-HR ALL 1ST UCART1 11/11/2013 24 hr 271110 2247023 0.02752 24.9 24.9 0 24-HR ALL 1ST UCART1 11/11/2013 24 hr 272110 2247023 0.0389 37.8 37.8 0 24-HR ALL 1ST UCART1 11/11/2013 24 hr 273110 2247023 0.0655 45.3 88 0 24-HR ALL 1ST UCART1 11/11/2013 24 hr 274110 2247023 0.10372 44.8 132 0 24-HR ALL 1ST UCART1 11/11/2013 24 hr 275110 2247023 0.20181 42.7 42.7 0 24-HR ALL 1ST UCART1 11/11/2013 24 hr 276110 2247023 1.00E-05 37.3 37.3 0 24-HR ALL 1ST UCART1 10/25/2013 24 hr 277110 2247023 0.21689 53.7 84 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 278110 2247023 0.09698 32.2 32.2 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 279110 2247023 0.06165 24.9 24.9 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 280110 2247023 0.04507 28.2 28.2 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 281110 2247023 0.03338 26.8 26.8 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 282110 2247023 0.02694 32.8 32.8 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 283110 2247023 0.02126 29.8 29.8 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 284110 2247023 0.01749 28.9 28.9 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 285110 2247023 0.01474 27.8 27.8 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 286110 2247023 0.01276 30.7 30.7 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 266110 2248023 0.01162 0 0 0 24-HR ALL 1ST UCART1 10/25/2013 24 hr 267110 2248023 0.01465 0 0 0 24-HR ALL 1ST UCART1 10/25/2013 24 hr 268110 2248023 0.01915 10 10 0 24-HR ALL 1ST UCART1 10/25/2013 24 hr 269110 2248023 0.02352 13.8 13.8 0 24-HR ALL 1ST UCART1 10/25/2013 24 hr 270110 2248023 0.02694 17.4 17.4 0 24-HR ALL 1ST UCART1 10/25/2013 24 hr 271110 2248023 0.02758 23 23 0 24-HR ALL 1ST UCART1 11/4/2013 24 hr 272110 2248023 0.06086 62.2 64 0 24-HR ALL 1ST UCART1 11/4/2013 24 hr 273110 2248023 0.10684 27.1 132 0 24-HR ALL 1ST UCART1 11/4/2013 24 hr 274110 2248023 0.13868 46.6 219 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 275110 2248023 0.24865 57.1 219 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 276110 2248023 0.08795 36.2 219 0 24-HR ALL 1ST UCART1 10/1/2013 24 hr 277110 2248023 0.14501 35.1 71 0 24-HR ALL 1ST UCART1 10/16/2013 24 hr 278110 2248023 0.15544 26.9 26.9 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 279110 2248023 0.03435 17.8 17.8 0 24-HR ALL 1ST UCART1 12/20/2013 24 hr 280110 2248023 0.01051 25.7 25.7 0 24-HR ALL 1ST UCART1 12/20/2013 24 hr 281110 2248023 0.00664 29.8 29.8 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 282110 2248023 0.00792 31.7 31.7 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 283110 2248023 0.00862 32.1 32.1 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 284110 2248023 0.0087 27.1 27.1 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 285110 2248023 0.00868 25.8 30 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 286110 2248023 0.00851 28.1 28.1 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 266110 2249023 0.0091 0 0 0 24-HR ALL 1ST UCART1 10/25/2013 24 hr 267110 2249023 0.01297 0 0 0 24-HR ALL 1ST UCART1 11/4/2013 24 hr 268110 2249023 0.02375 11 11 0 24-HR ALL 1ST UCART1 11/4/2013 24 hr


Page 6



269110 2249023 0.03689 15.3 15.3 0 24-HR ALL 1ST UCART1 11/4/2013 24 hr 270110 2249023 0.0433 15.8 15.8 0 24-HR ALL 1ST UCART1 11/4/2013 24 hr 271110 2249023 0.0322 18 18 0 24-HR ALL 1ST UCART1 11/4/2013 24 hr 272110 2249023 0.05741 22.8 22.8 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 273110 2249023 0.07049 22.7 22.7 0 24-HR ALL 1ST UCART1 10/22/2013 24 hr 274110 2249023 0.1332 30.2 219 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 275110 2249023 0.03618 82.5 219 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 276110 2249023 0.02695 83.2 219 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 277110 2249023 0.07089 25.8 219 0 24-HR ALL 1ST UCART1 10/10/2013 24 hr 278110 2249023 0.063 19.6 19.6 0 24-HR ALL 1ST UCART1 10/16/2013 24 hr 279110 2249023 0.08647 21.8 21.8 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 280110 2249023 0.05964 27.7 27.7 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 281110 2249023 0.02497 24.3 24.3 0 24-HR ALL 1ST UCART1 12/20/2013 24 hr 282110 2249023 0.01118 27.1 27.1 0 24-HR ALL 1ST UCART1 12/20/2013 24 hr 283110 2249023 0.00502 20.8 20.8 0 24-HR ALL 1ST UCART1 12/20/2013 24 hr 284110 2249023 0.00284 28.6 28.6 0 24-HR ALL 1ST UCART1 12/20/2013 24 hr 285110 2249023 0.00225 32.5 32.5 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 286110 2249023 0.00229 30.2 30.2 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 266110 2250023 0.02246 0 0 0 24-HR ALL 1ST UCART1 11/4/2013 24 hr 267110 2250023 0.02384 0 0 0 24-HR ALL 1ST UCART1 11/4/2013 24 hr 268110 2250023 0.02034 9.3 9.3 0 24-HR ALL 1ST UCART1 11/4/2013 24 hr 269110 2250023 0.02349 19.2 19.2 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 270110 2250023 0.03498 18.7 18.7 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 271110 2250023 0.0383 17.3 17.3 0 24-HR ALL 1ST UCART1 11/7/2013 24 hr 272110 2250023 0.05107 17 17 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 273110 2250023 0.07157 15.6 15.6 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 274110 2250023 0.07981 26.1 219 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 275110 2250023 0.04515 33.3 219 0 24-HR ALL 1ST UCART1 10/4/2013 24 hr 276110 2250023 0.20107 74.2 219 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 277110 2250023 0.05681 24.6 214 0 24-HR ALL 1ST UCART1 12/30/2013 24 hr 278110 2250023 0.04567 18.6 18.6 0 24-HR ALL 1ST UCART1 10/17/2013 24 hr 279110 2250023 0.04362 29 29 0 24-HR ALL 1ST UCART1 10/16/2013 24 hr 280110 2250023 0.03789 11.8 11.8 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 281110 2250023 0.04835 16.5 16.5 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 282110 2250023 0.0322 16.1 16.1 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 283110 2250023 0.01752 25.1 25.1 0 24-HR ALL 1ST UCART1 12/20/2013 24 hr 284110 2250023 0.01049 32.3 32.3 0 24-HR ALL 1ST UCART1 12/20/2013 24 hr 285110 2250023 0.0055 33.7 33.7 0 24-HR ALL 1ST UCART1 12/20/2013 24 hr 286110 2250023 0.00304 36.8 36.8 0 24-HR ALL 1ST UCART1 12/20/2013 24 hr 266110 2251023 0.01121 0 0 0 24-HR ALL 1ST UCART1 10/9/2013 24 hr 267110 2251023 0.01712 0 0 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 268110 2251023 0.0223 0 0 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 269110 2251023 0.02561 10 10 0 24-HR ALL 1ST UCART1 11/7/2013 24 hr 270110 2251023 0.02639 9.6 9.6 0 24-HR ALL 1ST UCART1 10/22/2013 24 hr 271110 2251023 0.03763 9.1 9.1 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 272110 2251023 0.0482 12.2 12.2 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 273110 2251023 0.05907 12 12 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 274110 2251023 0.05205 17.1 17.1 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 275110 2251023 0.00887 27.7 27.7 0 24-HR ALL 1ST UCART1 10/4/2013 24 hr 276110 2251023 0.00875 27 197 0 24-HR ALL 1ST UCART1 10/1/2013 24 hr 277110 2251023 0.0333 39.6 79 0 24-HR ALL 1ST UCART1 12/30/2013 24 hr


Page 7



278110 2251023 0.0247 20.7 20.7 0 24-HR ALL 1ST UCART1 10/10/2013 24 hr 279110 2251023 0.03233 7.1 24 0 24-HR ALL 1ST UCART1 10/17/2013 24 hr 280110 2251023 0.03403 23 23 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 281110 2251023 0.01914 14.2 14.2 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 282110 2251023 0.0328 23.4 23.4 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 283110 2251023 0.03152 26.4 26.4 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 284110 2251023 0.02195 30.3 30.3 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 285110 2251023 0.01297 27.3 27.3 0 24-HR ALL 1ST UCART1 12/20/2013 24 hr 286110 2251023 0.00899 29.9 29.9 0 24-HR ALL 1ST UCART1 12/20/2013 24 hr 266110 2252023 0.0169 0 0 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 267110 2252023 0.01741 0 0 0 24-HR ALL 1ST UCART1 11/7/2013 24 hr 268110 2252023 0.01713 0 0 0 24-HR ALL 1ST UCART1 11/7/2013 24 hr 269110 2252023 0.02347 0 0 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 270110 2252023 0.02726 0 0 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 271110 2252023 0.03369 2.4 2.4 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 272110 2252023 0.05009 5.4 5.4 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 273110 2252023 0.03548 10.5 10.5 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 274110 2252023 0.0318 16.4 16.4 0 24-HR ALL 1ST UCART1 10/4/2013 24 hr 275110 2252023 0.00429 33 33 0 24-HR ALL 1ST UCART1 12/30/2013 24 hr 276110 2252023 0.00656 21.6 21.6 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 277110 2252023 0.01521 17.5 17.5 0 24-HR ALL 1ST UCART1 10/1/2013 24 hr 278110 2252023 0.02456 21 21 0 24-HR ALL 1ST UCART1 12/30/2013 24 hr 279110 2252023 0.02331 8.4 21 0 24-HR ALL 1ST UCART1 10/10/2013 24 hr 280110 2252023 0.02142 17.2 17.2 0 24-HR ALL 1ST UCART1 10/17/2013 24 hr 281110 2252023 0.02785 18.3 18.3 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 282110 2252023 0.01891 25.9 25.9 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 283110 2252023 0.0212 26.4 26.4 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 284110 2252023 0.02497 32.7 32.7 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 285110 2252023 0.02178 28.8 28.8 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 286110 2252023 0.01563 29.3 29.3 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 266110 2253023 0.01478 0 0 0 24-HR ALL 1ST UCART1 11/7/2013 24 hr 267110 2253023 0.01452 0 0 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 268110 2253023 0.01917 0 0 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 269110 2253023 0.02056 0 0 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 270110 2253023 0.02579 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 271110 2253023 0.0414 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 272110 2253023 0.02172 1.2 1.2 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 273110 2253023 0.03148 12.8 12.8 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 274110 2253023 0.01497 17.8 17.8 0 24-HR ALL 1ST UCART1 10/4/2013 24 hr 275110 2253023 0.0106 56 99 0 24-HR ALL 1ST UCART1 10/19/2013 24 hr 276110 2253023 0.00526 21.1 95 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 277110 2253023 0.01442 13.8 13.8 0 24-HR ALL 1ST UCART1 10/1/2013 24 hr 278110 2253023 0.02399 22.7 22.7 0 24-HR ALL 1ST UCART1 12/30/2013 24 hr 279110 2253023 0.01246 8 8 0 24-HR ALL 1ST UCART1 10/3/2013 24 hr 280110 2253023 0.02458 18.9 18.9 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 281110 2253023 0.01823 21.8 21.8 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 282110 2253023 0.02486 23.5 23.5 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 283110 2253023 0.01857 30.2 30.2 0 24-HR ALL 1ST UCART1 10/4/2013 24 hr 284110 2253023 0.01359 26.2 26.2 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 285110 2253023 0.01829 27.6 27.6 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 286110 2253023 0.01857 31 31 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr


Page 8



266110 2254023 0.0148 0 0 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 267110 2254023 0.01704 0 0 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 268110 2254023 0.01561 0 0 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 269110 2254023 0.02067 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 270110 2254023 0.03455 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 271110 2254023 0.01966 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 272110 2254023 0.02387 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 273110 2254023 0.0223 17.5 17.5 0 24-HR ALL 1ST UCART1 10/4/2013 24 hr 274110 2254023 0.00518 13.4 13.4 0 24-HR ALL 1ST UCART1 10/4/2013 24 hr 275110 2254023 0.0029 16.6 16.6 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 276110 2254023 0.00434 9.4 9.4 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 277110 2254023 0.01289 20 20 0 24-HR ALL 1ST UCART1 10/1/2013 24 hr 278110 2254023 0.01698 17.5 17.5 0 24-HR ALL 1ST UCART1 12/30/2013 24 hr 279110 2254023 0.01165 10 10 0 24-HR ALL 1ST UCART1 12/30/2013 24 hr 280110 2254023 0.01978 16.9 16.9 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 281110 2254023 0.0221 25.8 25.8 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 282110 2254023 0.01767 26.4 26.4 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 283110 2254023 0.02198 26.3 26.3 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 284110 2254023 0.01683 27.1 27.1 0 24-HR ALL 1ST UCART1 10/4/2013 24 hr 285110 2254023 0.01245 25.9 25.9 0 24-HR ALL 1ST UCART1 10/4/2013 24 hr 286110 2254023 0.01335 29.9 29.9 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 266110 2255023 0.01515 0 0 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 267110 2255023 0.01224 0 0 0 24-HR ALL 1ST UCART1 10/29/2013 24 hr 268110 2255023 0.01701 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 269110 2255023 0.0288 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 270110 2255023 0.02003 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 271110 2255023 0.01448 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 272110 2255023 0.02067 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 273110 2255023 0.01557 16.3 16.3 0 24-HR ALL 1ST UCART1 10/4/2013 24 hr 274110 2255023 0.00385 14 14 0 24-HR ALL 1ST UCART1 10/19/2013 24 hr 275110 2255023 0.00267 17.4 17.4 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 276110 2255023 0.00476 16.8 16.8 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 277110 2255023 0.00993 0 0 0 24-HR ALL 1ST UCART1 10/1/2013 24 hr 278110 2255023 0.01105 16.8 16.8 0 24-HR ALL 1ST UCART1 12/30/2013 24 hr 279110 2255023 0.01482 21.7 21.7 0 24-HR ALL 1ST UCART1 12/30/2013 24 hr 280110 2255023 0.01025 20.6 20.6 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 281110 2255023 0.02467 27.3 27.3 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 282110 2255023 0.01676 23.6 23.6 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 283110 2255023 0.01586 25.1 25.1 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 284110 2255023 0.0197 30 30 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 285110 2255023 0.01572 28.2 28.2 0 24-HR ALL 1ST UCART1 10/4/2013 24 hr 286110 2255023 0.01228 22.2 22.2 0 24-HR ALL 1ST UCART1 10/4/2013 24 hr 266110 2256023 0.01032 0 0 0 24-HR ALL 1ST UCART1 11/6/2013 24 hr 267110 2256023 0.0143 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 268110 2256023 0.02416 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 269110 2256023 0.0199 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 270110 2256023 0.01044 0 0 0 24-HR ALL 1ST UCART1 10/31/2013 24 hr 271110 2256023 0.01842 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 272110 2256023 0.01442 0 0 0 24-HR ALL 1ST UCART1 10/4/2013 24 hr 273110 2256023 0.00761 0 0 0 24-HR ALL 1ST UCART1 10/19/2013 24 hr 274110 2256023 0.00338 13.8 13.8 0 24-HR ALL 1ST UCART1 10/19/2013 24 hr


Page 9



275110 2256023 0.00245 13.4 13.4 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 276110 2256023 0.00592 17.7 17.7 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 277110 2256023 0.0081 0.5 0.5 0 24-HR ALL 1ST UCART1 10/1/2013 24 hr 278110 2256023 0.00722 13 13 0 24-HR ALL 1ST UCART1 12/30/2013 24 hr 279110 2256023 0.01384 19.9 19.9 0 24-HR ALL 1ST UCART1 12/30/2013 24 hr 280110 2256023 0.00674 18.7 18.7 0 24-HR ALL 1ST UCART1 12/30/2013 24 hr 281110 2256023 0.01596 20.9 20.9 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 282110 2256023 0.02315 27.4 27.4 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 283110 2256023 0.01219 23.3 23.3 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 284110 2256023 0.01435 25.2 25.2 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 285110 2256023 0.01688 28.3 28.3 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 286110 2256023 0.01373 24.8 24.8 0 24-HR ALL 1ST UCART1 10/4/2013 24 hr 266110 2257023 0.01221 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 267110 2257023 0.02046 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 268110 2257023 0.01902 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 269110 2257023 0.0107 0 0 0 24-HR ALL 1ST UCART1 10/31/2013 24 hr 270110 2257023 0.01217 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 271110 2257023 0.01562 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 272110 2257023 0.01265 0 0 0 24-HR ALL 1ST UCART1 10/4/2013 24 hr 273110 2257023 0.00882 0 0 0 24-HR ALL 1ST UCART1 10/19/2013 24 hr 274110 2257023 0.00272 10.7 10.7 0 24-HR ALL 1ST UCART1 10/19/2013 24 hr 275110 2257023 0.00265 14.7 14.7 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 276110 2257023 0.00709 11.1 11.1 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 277110 2257023 0.00669 8.8 8.8 0 24-HR ALL 1ST UCART1 10/1/2013 24 hr 278110 2257023 0.00558 17.8 17.8 0 24-HR ALL 1ST UCART1 10/1/2013 24 hr 279110 2257023 0.01093 15 15 0 24-HR ALL 1ST UCART1 12/30/2013 24 hr 280110 2257023 0.00901 18.3 18.3 0 24-HR ALL 1ST UCART1 12/30/2013 24 hr 281110 2257023 0.00841 23.1 23.1 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 282110 2257023 0.01889 20.6 20.6 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 283110 2257023 0.01876 23.9 23.9 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 284110 2257023 0.00906 26.2 26.2 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 285110 2257023 0.01268 22.6 22.6 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 286110 2257023 0.01408 21.9 21.9 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr AQ (CCPL) 276110.68 2247023.87 7.00E-05 37.31 37.31 0 24-HR ALL 1ST 10/25/2013 24 hrAQ (PALI) 274508.67 2251567.12 0.02773 20.52 20.52 0 24-HR ALL 1ST 10/4/2013 24 hr AQ (PUNAT) 277635.66 2249303.76 0.06285 22.68 197 0 24-HR ALL 1ST 10/17/2013 24 hrAQ (BHILAD) 279930.11 2244698.09 0.02223 21.28 21.28 0 24-HR ALL 1ST 10/6/2013 24 hr AQ (DAHELI) 276916.75 2242422.63 0.04043 31.12 31.12 0 24-HR ALL 1ST 12/4/2013 24 hr AQ (SARAI) 271773.3 2244824.09 0.06649 43.46 160 0 24-HR ALL 1ST 11/6/2013 24 hr DW (PDISCR) 275927.82 2246557.21 0.67583 36.57 36.57 0 24-HR ALL 1ST 10/31/2013 24 hrDW (PDISCR) 275748.63 2246090.42 0.50571 33.96 33.96 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 275569.45 2245623.63 0.46195 37.74 37.74 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 275390.26 2245156.84 0.30981 29.07 29.07 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 275211.08 2244690.05 0.25515 29.47 29.47 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 275031.9 2244223.26 0.19452 22.26 22.26 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 274852.71 2243756.47 0.17507 27.82 27.82 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 274673.53 2243289.68 0.15612 31.78 31.78 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 274494.34 2242822.89 0.12881 26.97 26.97 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 274315.16 2242356.1 0.11428 28.27 28.27 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 274135.98 2241889.31 0.10056 27.48 27.48 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 273956.79 2241422.52 0.09176 30.31 30.31 0 24-HR ALL 1ST 12/25/2013 24 hr


Page 10



DW (PDISCR) 273777.61 2240955.73 0.08126 27.67 27.67 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 273598.42 2240488.94 0.07314 25.97 25.97 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 273419.24 2240022.15 0.06723 26.3 26.3 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 273240.06 2239555.36 0.06285 28.53 28.53 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 273060.87 2239088.57 0.05935 31.96 43 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 272881.69 2238621.78 0.05821 38.07 38.07 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 272702.5 2238154.99 0.051 26.9 26.9 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 272523.32 2237688.2 0.04774 24.45 24.45 0 24-HR ALL 1ST 12/25/2013 24 hr

SOx - Dispersion Modeling Results

Page 1


266110 2237023 0.01632 3 3 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 267110 2237023 0.01639 3 3 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 268110 2237023 0.02845 4 4 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 269110 2237023 0.02236 7.2 7.2 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 270110 2237023 0.02762 12.7 12.7 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 271110 2237023 0.0301 8.6 8.6 0 24-HR ALL 1ST UCART1 10/11/2013 24 hr 272110 2237023 0.0337 20.5 20.5 0 24-HR ALL 1ST UCART1 12/25/2013 24 hr 273110 2237023 0.05063 12.2 12.2 0 24-HR ALL 1ST UCART1 12/25/2013 24 hr 274110 2237023 0.0336 23.1 23.1 0 24-HR ALL 1ST UCART1 12/25/2013 24 hr 275110 2237023 0.0365 22.9 22.9 0 24-HR ALL 1ST UCART1 12/28/2013 24 hr 276110 2237023 0.02254 30.3 30.3 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 277110 2237023 0.01634 38.1 38.1 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 278110 2237023 0.01703 45.4 45.4 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 279110 2237023 0.01731 57.7 57.7 0 24-HR ALL 1ST UCART1 10/25/2013 24 hr 280110 2237023 0.01944 39.1 39.1 0 24-HR ALL 1ST UCART1 12/8/2013 24 hr 281110 2237023 0.01728 34.3 34.3 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 282110 2237023 0.02467 28.4 28.4 0 24-HR ALL 1ST UCART1 12/17/2013 24 hr 283110 2237023 0.02437 31.2 31.2 0 24-HR ALL 1ST UCART1 12/17/2013 24 hr 284110 2237023 0.01329 31.6 31.6 0 24-HR ALL 1ST UCART1 12/17/2013 24 hr 285110 2237023 0.01325 30.9 30.9 0 24-HR ALL 1ST UCART1 12/7/2013 24 hr 286110 2237023 0.01052 53.6 53.6 0 24-HR ALL 1ST UCART1 12/7/2013 24 hr 266110 2238023 0.01916 4.5 4.5 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 267110 2238023 0.01911 4.7 4.7 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 268110 2238023 0.0197 4.5 4.5 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 269110 2238023 0.03211 8.8 8.8 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 270110 2238023 0.01873 13.9 13.9 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 271110 2238023 0.03742 20.7 20.7 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 272110 2238023 0.03195 18.2 18.2 0 24-HR ALL 1ST UCART1 10/11/2013 24 hr 273110 2238023 0.06118 24.4 24.4 0 24-HR ALL 1ST UCART1 12/25/2013 24 hr 274110 2238023 0.03836 18.4 18.4 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 275110 2238023 0.0409 19.1 19.1 0 24-HR ALL 1ST UCART1 12/28/2013 24 hr 276110 2238023 0.02554 26.9 26.9 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 277110 2238023 0.01842 41.1 41.1 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 278110 2238023 0.01972 45.7 45.7 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 279110 2238023 0.01677 43.7 43.7 0 24-HR ALL 1ST UCART1 11/6/2013 24 hr 280110 2238023 0.01698 72.2 72.2 0 24-HR ALL 1ST UCART1 12/8/2013 24 hr 281110 2238023 0.02518 38.4 38.4 0 24-HR ALL 1ST UCART1 12/17/2013 24 hr 282110 2238023 0.03012 31 31 0 24-HR ALL 1ST UCART1 12/17/2013 24 hr 283110 2238023 0.01844 29.8 29.8 0 24-HR ALL 1ST UCART1 12/17/2013 24 hr 284110 2238023 0.01486 26.5 26.5 0 24-HR ALL 1ST UCART1 12/7/2013 24 hr 285110 2238023 0.0113 34 34 0 24-HR ALL 1ST UCART1 12/7/2013 24 hr 286110 2238023 0.00575 50.8 50.8 0 24-HR ALL 1ST UCART1 10/6/2013 24 hr 266110 2239023 0.0126 10.6 10.6 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 267110 2239023 0.02185 4.4 4.4 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 268110 2239023 0.02327 11.3 11.3 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 269110 2239023 0.02398 10 10 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 270110 2239023 0.03415 9.5 9.5 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 271110 2239023 0.03292 18.8 18.8 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 272110 2239023 0.04206 28.2 28.2 0 24-HR ALL 1ST UCART1 10/11/2013 24 hr 273110 2239023 0.05792 30.7 30.7 0 24-HR ALL 1ST UCART1 12/25/2013 24 hr 274110 2239023 0.04968 19.7 19.7 0 24-HR ALL 1ST UCART1 12/25/2013 24 hr 275110 2239023 0.04777 24.9 24.9 0 24-HR ALL 1ST UCART1 12/28/2013 24 hr



Page 2



276110 2239023 0.02931 24.2 24.2 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 277110 2239023 0.0187 30.7 30.7 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 278110 2239023 0.02187 41.8 70 0 24-HR ALL 1ST UCART1 10/25/2013 24 hr 279110 2239023 0.02623 42.5 42.5 0 24-HR ALL 1ST UCART1 12/8/2013 24 hr 280110 2239023 0.02711 51.5 51.5 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 281110 2239023 0.03616 35.6 35.6 0 24-HR ALL 1ST UCART1 12/17/2013 24 hr 282110 2239023 0.02594 30.9 87 0 24-HR ALL 1ST UCART1 12/17/2013 24 hr 283110 2239023 0.01786 30 30 0 24-HR ALL 1ST UCART1 12/7/2013 24 hr 284110 2239023 0.01292 30.1 30.1 0 24-HR ALL 1ST UCART1 12/7/2013 24 hr 285110 2239023 0.00699 36.6 36.6 0 24-HR ALL 1ST UCART1 10/6/2013 24 hr 286110 2239023 0.01044 38 38 0 24-HR ALL 1ST UCART1 11/8/2013 24 hr 266110 2240023 0.01423 18.4 18.4 0 24-HR ALL 1ST UCART1 12/8/2013 24 hr 267110 2240023 0.01264 12.8 12.8 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 268110 2240023 0.02659 17.1 17.1 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 269110 2240023 0.0291 18.4 18.4 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 270110 2240023 0.02917 10.8 10.8 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 271110 2240023 0.0344 20.3 20.3 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 272110 2240023 0.05257 29.4 38 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 273110 2240023 0.04231 28.4 28.4 0 24-HR ALL 1ST UCART1 11/6/2013 24 hr 274110 2240023 0.07846 31.8 45 0 24-HR ALL 1ST UCART1 12/25/2013 24 hr 275110 2240023 0.05231 23 23 0 24-HR ALL 1ST UCART1 12/28/2013 24 hr 276110 2240023 0.03525 26.8 26.8 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 277110 2240023 0.02154 38.3 38.3 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 278110 2240023 0.02501 44.4 72 0 24-HR ALL 1ST UCART1 10/25/2013 24 hr 279110 2240023 0.03249 45.6 45.6 0 24-HR ALL 1ST UCART1 12/8/2013 24 hr 280110 2240023 0.05632 68.8 93 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 281110 2240023 0.03774 35.6 35.6 0 24-HR ALL 1ST UCART1 12/17/2013 24 hr 282110 2240023 0.02091 30.1 30.1 0 24-HR ALL 1ST UCART1 12/7/2013 24 hr 283110 2240023 0.01584 33.3 33.3 0 24-HR ALL 1ST UCART1 12/7/2013 24 hr 284110 2240023 0.0085 31 31 0 24-HR ALL 1ST UCART1 10/6/2013 24 hr 285110 2240023 0.013 31.6 31.6 0 24-HR ALL 1ST UCART1 11/8/2013 24 hr 286110 2240023 0.01041 35.7 35.7 0 24-HR ALL 1ST UCART1 11/8/2013 24 hr 266110 2241023 0.01372 15.6 15.6 0 24-HR ALL 1ST UCART1 11/8/2013 24 hr 267110 2241023 0.01737 18.4 18.4 0 24-HR ALL 1ST UCART1 12/8/2013 24 hr 268110 2241023 0.01521 24.3 62 0 24-HR ALL 1ST UCART1 10/19/2013 24 hr 269110 2241023 0.03195 26.5 93 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 270110 2241023 0.03611 18.6 18.6 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 271110 2241023 0.03621 15.5 15.5 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 272110 2241023 0.03826 41.9 41.9 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 273110 2241023 0.06304 37.8 37.8 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 274110 2241023 0.09693 24.8 24.8 0 24-HR ALL 1ST UCART1 12/25/2013 24 hr 275110 2241023 0.05513 21.5 21.5 0 24-HR ALL 1ST UCART1 12/28/2013 24 hr 276110 2241023 0.0414 23.8 23.8 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 277110 2241023 0.02495 31.3 31.3 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 278110 2241023 0.02646 37.9 37.9 0 24-HR ALL 1ST UCART1 12/8/2013 24 hr 279110 2241023 0.03815 50.5 50.5 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 280110 2241023 0.05307 39.4 39.4 0 24-HR ALL 1ST UCART1 12/17/2013 24 hr 281110 2241023 0.02539 33.5 33.5 0 24-HR ALL 1ST UCART1 12/7/2013 24 hr 282110 2241023 0.01847 30.1 30.1 0 24-HR ALL 1ST UCART1 12/7/2013 24 hr 283110 2241023 0.01104 33 33 0 24-HR ALL 1ST UCART1 10/6/2013 24 hr 284110 2241023 0.01603 33.3 33.3 0 24-HR ALL 1ST UCART1 11/8/2013 24 hr 285110 2241023 0.01073 38.1 38.1 0 24-HR ALL 1ST UCART1 10/6/2013 24 hr


Page 3



286110 2241023 0.00773 36.3 36.3 0 24-HR ALL 1ST UCART1 10/6/2013 24 hr 266110 2242023 0.01882 4.9 4.9 0 24-HR ALL 1ST UCART1 12/28/2013 24 hr 267110 2242023 0.01663 10.5 10.5 0 24-HR ALL 1ST UCART1 12/28/2013 24 hr 268110 2242023 0.01774 17.3 17.3 0 24-HR ALL 1ST UCART1 12/8/2013 24 hr 269110 2242023 0.02473 40.2 93 0 24-HR ALL 1ST UCART1 12/8/2013 24 hr 270110 2242023 0.03628 24.9 24.9 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 271110 2242023 0.04714 21.7 21.7 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 272110 2242023 0.04852 31.2 31.2 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 273110 2242023 0.2379 67.8 87 0 24-HR ALL 1ST UCART1 12/25/2013 24 hr 274110 2242023 0.08308 28.1 28.1 0 24-HR ALL 1ST UCART1 12/25/2013 24 hr 275110 2242023 0.08031 23.1 23.1 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 276110 2242023 0.05202 26.9 26.9 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 277110 2242023 0.03503 30.8 30.8 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 278110 2242023 0.04611 33.3 33.3 0 24-HR ALL 1ST UCART1 12/8/2013 24 hr 279110 2242023 0.06557 46.3 46.3 0 24-HR ALL 1ST UCART1 12/17/2013 24 hr 280110 2242023 0.03864 37.3 37.3 0 24-HR ALL 1ST UCART1 12/17/2013 24 hr 281110 2242023 0.02155 26.7 26.7 0 24-HR ALL 1ST UCART1 12/7/2013 24 hr 282110 2242023 0.01702 34.5 34.5 0 24-HR ALL 1ST UCART1 11/8/2013 24 hr 283110 2242023 0.01814 34.6 34.6 0 24-HR ALL 1ST UCART1 11/8/2013 24 hr 284110 2242023 0.01143 36.2 36.2 0 24-HR ALL 1ST UCART1 10/6/2013 24 hr 285110 2242023 0.00749 40.8 40.8 0 24-HR ALL 1ST UCART1 10/6/2013 24 hr 286110 2242023 0.00495 37.3 37.3 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 266110 2243023 0.01733 15.7 15.7 0 24-HR ALL 1ST UCART1 12/18/2013 24 hr 267110 2243023 0.01927 10.7 10.7 0 24-HR ALL 1ST UCART1 12/28/2013 24 hr 268110 2243023 0.02289 12.5 12.5 0 24-HR ALL 1ST UCART1 11/6/2013 24 hr 269110 2243023 0.02316 20.3 20.3 0 24-HR ALL 1ST UCART1 10/24/2013 24 hr 270110 2243023 0.03025 24.3 24.3 0 24-HR ALL 1ST UCART1 12/8/2013 24 hr 271110 2243023 0.04359 36.9 80 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 272110 2243023 0.07231 49.8 160 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 273110 2243023 0.06131 33.1 33.1 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 274110 2243023 0.0818 26.7 26.7 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 275110 2243023 0.1187 28.5 28.5 0 24-HR ALL 1ST UCART1 12/25/2013 24 hr 276110 2243023 0.06946 31.3 31.3 0 24-HR ALL 1ST UCART1 12/28/2013 24 hr 277110 2243023 0.0434 31.8 31.8 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 278110 2243023 0.05179 38.9 38.9 0 24-HR ALL 1ST UCART1 12/17/2013 24 hr 279110 2243023 0.06079 33 33 0 24-HR ALL 1ST UCART1 12/17/2013 24 hr 280110 2243023 0.03006 35.5 35.5 0 24-HR ALL 1ST UCART1 12/7/2013 24 hr 281110 2243023 0.02506 25.9 25.9 0 24-HR ALL 1ST UCART1 11/8/2013 24 hr 282110 2243023 0.0165 27.5 27.5 0 24-HR ALL 1ST UCART1 11/8/2013 24 hr 283110 2243023 0.01107 32.5 32.5 0 24-HR ALL 1ST UCART1 10/6/2013 24 hr 284110 2243023 0.00716 37.8 37.8 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 285110 2243023 0.00865 38.9 38.9 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 286110 2243023 0.01164 42.7 42.7 0 24-HR ALL 1ST UCART1 11/10/2013 24 hr 266110 2244023 0.01172 12.6 12.6 0 24-HR ALL 1ST UCART1 10/21/2013 24 hr 267110 2244023 0.01311 14.8 14.8 0 24-HR ALL 1ST UCART1 11/6/2013 24 hr 268110 2244023 0.02136 13.8 13.8 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 269110 2244023 0.02689 15.3 15.3 0 24-HR ALL 1ST UCART1 11/6/2013 24 hr 270110 2244023 0.03619 26.2 26.2 0 24-HR ALL 1ST UCART1 11/6/2013 24 hr 271110 2244023 0.03495 35.5 160 0 24-HR ALL 1ST UCART1 10/24/2013 24 hr 272110 2244023 0.00891 128.3 160 0 24-HR ALL 1ST UCART1 10/23/2013 24 hr 273110 2244023 0.10446 39 160 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 274110 2244023 0.08939 33.1 33.1 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr


Page 4



275110 2244023 0.19949 21.1 21.1 0 24-HR ALL 1ST UCART1 12/25/2013 24 hr 276110 2244023 0.09143 25.5 25.5 0 24-HR ALL 1ST UCART1 12/28/2013 24 hr 277110 2244023 0.06867 35.2 35.2 0 24-HR ALL 1ST UCART1 12/8/2013 24 hr 278110 2244023 0.12436 54.9 145 0 24-HR ALL 1ST UCART1 12/17/2013 24 hr 279110 2244023 0.03666 35.1 145 0 24-HR ALL 1ST UCART1 12/7/2013 24 hr 280110 2244023 0.03634 25.5 25.5 0 24-HR ALL 1ST UCART1 11/8/2013 24 hr 281110 2244023 0.01651 25.3 25.3 0 24-HR ALL 1ST UCART1 10/6/2013 24 hr 282110 2244023 0.00978 26.6 26.6 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 283110 2244023 0.01381 28.6 28.6 0 24-HR ALL 1ST UCART1 11/10/2013 24 hr 284110 2244023 0.01992 36.8 36.8 0 24-HR ALL 1ST UCART1 11/10/2013 24 hr 285110 2244023 0.02122 34.3 34.3 0 24-HR ALL 1ST UCART1 11/10/2013 24 hr 286110 2244023 0.02069 34.5 34.5 0 24-HR ALL 1ST UCART1 11/10/2013 24 hr 266110 2245023 0.01623 12.5 12.5 0 24-HR ALL 1ST UCART1 10/21/2013 24 hr 267110 2245023 0.01847 12.1 12.1 0 24-HR ALL 1ST UCART1 10/21/2013 24 hr 268110 2245023 0.02037 10.6 10.6 0 24-HR ALL 1ST UCART1 10/21/2013 24 hr 269110 2245023 0.02183 12.9 12.9 0 24-HR ALL 1ST UCART1 10/21/2013 24 hr 270110 2245023 0.0254 25.5 133 0 24-HR ALL 1ST UCART1 11/6/2013 24 hr 271110 2245023 0.01773 107.3 133 0 24-HR ALL 1ST UCART1 10/10/2013 24 hr 272110 2245023 0.06786 40.3 160 0 24-HR ALL 1ST UCART1 11/6/2013 24 hr 273110 2245023 0.08299 47.4 47.4 0 24-HR ALL 1ST UCART1 12/8/2013 24 hr 274110 2245023 0.16364 34 34 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 275110 2245023 0.16455 27.7 27.7 0 24-HR ALL 1ST UCART1 11/6/2013 24 hr 276110 2245023 0.13675 28.3 28.3 0 24-HR ALL 1ST UCART1 12/28/2013 24 hr 277110 2245023 0.10398 38 38 0 24-HR ALL 1ST UCART1 12/20/2013 24 hr 278110 2245023 0.04564 39 145 0 24-HR ALL 1ST UCART1 12/7/2013 24 hr 279110 2245023 0.04314 31.5 145 0 24-HR ALL 1ST UCART1 11/8/2013 24 hr 280110 2245023 0.01482 18.1 18.1 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 281110 2245023 0.02349 23.8 23.8 0 24-HR ALL 1ST UCART1 11/10/2013 24 hr 282110 2245023 0.02816 24.6 24.6 0 24-HR ALL 1ST UCART1 11/10/2013 24 hr 283110 2245023 0.02907 30.9 30.9 0 24-HR ALL 1ST UCART1 11/10/2013 24 hr 284110 2245023 0.02379 28.5 28.5 0 24-HR ALL 1ST UCART1 11/10/2013 24 hr 285110 2245023 0.01875 28.5 28.5 0 24-HR ALL 1ST UCART1 11/10/2013 24 hr 286110 2245023 0.01511 34.6 34.6 0 24-HR ALL 1ST UCART1 11/10/2013 24 hr 266110 2246023 0.01788 2.7 17 0 24-HR ALL 1ST UCART1 11/19/2013 24 hr 267110 2246023 0.02124 10.6 10.6 0 24-HR ALL 1ST UCART1 11/19/2013 24 hr 268110 2246023 0.02293 4.1 4.1 0 24-HR ALL 1ST UCART1 11/19/2013 24 hr 269110 2246023 0.02554 11.5 11.5 0 24-HR ALL 1ST UCART1 11/19/2013 24 hr 270110 2246023 0.03222 20.2 20.2 0 24-HR ALL 1ST UCART1 10/21/2013 24 hr 271110 2246023 0.045 23.6 23.6 0 24-HR ALL 1ST UCART1 10/21/2013 24 hr 272110 2246023 0.06272 34.9 34.9 0 24-HR ALL 1ST UCART1 10/21/2013 24 hr 273110 2246023 0.09104 73.4 73.4 0 24-HR ALL 1ST UCART1 12/18/2013 24 hr 274110 2246023 0.15517 40.6 40.6 0 24-HR ALL 1ST UCART1 11/6/2013 24 hr 275110 2246023 0.33703 36.7 36.7 0 24-HR ALL 1ST UCART1 11/2/2013 24 hr 276110 2246023 0.26755 33 33 0 24-HR ALL 1ST UCART1 12/28/2013 24 hr 277110 2246023 0.0924 40.4 40.4 0 24-HR ALL 1ST UCART1 11/30/2013 24 hr 278110 2246023 0.02473 31.6 31.6 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 279110 2246023 0.04149 27.4 27.4 0 24-HR ALL 1ST UCART1 11/10/2013 24 hr 280110 2246023 0.03718 22.9 22.9 0 24-HR ALL 1ST UCART1 11/10/2013 24 hr 281110 2246023 0.02876 27.7 27.7 0 24-HR ALL 1ST UCART1 11/10/2013 24 hr 282110 2246023 0.02041 24.6 24.6 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 283110 2246023 0.01668 28.2 28.2 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 284110 2246023 0.01354 30.1 30.1 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr


Page 5



285110 2246023 0.01129 33.5 33.5 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 286110 2246023 0.00931 33.9 33.9 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 266110 2247023 0.00964 0 0 0 24-HR ALL 1ST UCART1 11/11/2013 24 hr 267110 2247023 0.01095 0 0 0 24-HR ALL 1ST UCART1 11/11/2013 24 hr 268110 2247023 0.01292 6.1 6.1 0 24-HR ALL 1ST UCART1 11/11/2013 24 hr 269110 2247023 0.01555 11.2 11.2 0 24-HR ALL 1ST UCART1 11/11/2013 24 hr 270110 2247023 0.01909 15.5 15.5 0 24-HR ALL 1ST UCART1 11/11/2013 24 hr 271110 2247023 0.02506 24.9 24.9 0 24-HR ALL 1ST UCART1 11/11/2013 24 hr 272110 2247023 0.0354 37.8 37.8 0 24-HR ALL 1ST UCART1 11/11/2013 24 hr 273110 2247023 0.0599 45.3 88 0 24-HR ALL 1ST UCART1 11/11/2013 24 hr 274110 2247023 0.09515 44.8 132 0 24-HR ALL 1ST UCART1 11/11/2013 24 hr 275110 2247023 0.18641 42.7 42.7 0 24-HR ALL 1ST UCART1 11/11/2013 24 hr 276110 2247023 1.00E-05 37.3 37.3 0 24-HR ALL 1ST UCART1 10/25/2013 24 hr 277110 2247023 0.1999 53.7 84 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 278110 2247023 0.08895 32.2 32.2 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 279110 2247023 0.0565 24.9 24.9 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 280110 2247023 0.04122 28.2 28.2 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 281110 2247023 0.03048 26.8 26.8 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 282110 2247023 0.02457 32.8 32.8 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 283110 2247023 0.01938 29.8 29.8 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 284110 2247023 0.01594 28.9 28.9 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 285110 2247023 0.01344 27.8 27.8 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 286110 2247023 0.01163 30.7 30.7 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 266110 2248023 0.01058 0 0 0 24-HR ALL 1ST UCART1 10/25/2013 24 hr 267110 2248023 0.01335 0 0 0 24-HR ALL 1ST UCART1 10/25/2013 24 hr 268110 2248023 0.01745 10 10 0 24-HR ALL 1ST UCART1 10/25/2013 24 hr 269110 2248023 0.02144 13.8 13.8 0 24-HR ALL 1ST UCART1 10/25/2013 24 hr 270110 2248023 0.02459 17.4 17.4 0 24-HR ALL 1ST UCART1 10/25/2013 24 hr 271110 2248023 0.02522 23 23 0 24-HR ALL 1ST UCART1 11/4/2013 24 hr 272110 2248023 0.05565 62.2 64 0 24-HR ALL 1ST UCART1 11/4/2013 24 hr 273110 2248023 0.09776 27.1 132 0 24-HR ALL 1ST UCART1 11/4/2013 24 hr 274110 2248023 0.12771 46.6 219 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 275110 2248023 0.22884 57.1 219 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 276110 2248023 0.08143 36.2 219 0 24-HR ALL 1ST UCART1 10/1/2013 24 hr 277110 2248023 0.1343 35.1 71 0 24-HR ALL 1ST UCART1 10/16/2013 24 hr 278110 2248023 0.14187 26.9 26.9 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 279110 2248023 0.03133 17.8 17.8 0 24-HR ALL 1ST UCART1 12/20/2013 24 hr 280110 2248023 0.00958 25.7 25.7 0 24-HR ALL 1ST UCART1 12/20/2013 24 hr 281110 2248023 0.00611 29.8 29.8 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 282110 2248023 0.00727 31.7 31.7 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 283110 2248023 0.00789 32.1 32.1 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 284110 2248023 0.00795 27.1 27.1 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 285110 2248023 0.00793 25.8 30 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 286110 2248023 0.00776 28.1 28.1 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 266110 2249023 0.0083 0 0 0 24-HR ALL 1ST UCART1 10/25/2013 24 hr 267110 2249023 0.01183 0 0 0 24-HR ALL 1ST UCART1 11/4/2013 24 hr 268110 2249023 0.02164 11 11 0 24-HR ALL 1ST UCART1 11/4/2013 24 hr 269110 2249023 0.0336 15.3 15.3 0 24-HR ALL 1ST UCART1 11/4/2013 24 hr 270110 2249023 0.03946 15.8 15.8 0 24-HR ALL 1ST UCART1 11/4/2013 24 hr 271110 2249023 0.02941 18 18 0 24-HR ALL 1ST UCART1 11/4/2013 24 hr 272110 2249023 0.05249 22.8 22.8 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 273110 2249023 0.06429 22.7 22.7 0 24-HR ALL 1ST UCART1 10/22/2013 24 hr


Page 6



274110 2249023 0.12238 30.2 219 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 275110 2249023 0.03266 82.5 219 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 276110 2249023 0.01988 83.2 219 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 277110 2249023 0.06478 25.8 219 0 24-HR ALL 1ST UCART1 10/10/2013 24 hr 278110 2249023 0.05774 19.6 19.6 0 24-HR ALL 1ST UCART1 10/16/2013 24 hr 279110 2249023 0.07876 21.8 21.8 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 280110 2249023 0.05427 27.7 27.7 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 281110 2249023 0.02271 24.3 24.3 0 24-HR ALL 1ST UCART1 12/20/2013 24 hr 282110 2249023 0.01018 27.1 27.1 0 24-HR ALL 1ST UCART1 12/20/2013 24 hr 283110 2249023 0.00458 20.8 20.8 0 24-HR ALL 1ST UCART1 12/20/2013 24 hr 284110 2249023 0.00258 28.6 28.6 0 24-HR ALL 1ST UCART1 12/20/2013 24 hr 285110 2249023 0.00208 32.5 32.5 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 286110 2249023 0.00211 30.2 30.2 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 266110 2250023 0.02042 0 0 0 24-HR ALL 1ST UCART1 11/4/2013 24 hr 267110 2250023 0.02169 0 0 0 24-HR ALL 1ST UCART1 11/4/2013 24 hr 268110 2250023 0.01854 9.3 9.3 0 24-HR ALL 1ST UCART1 11/4/2013 24 hr 269110 2250023 0.02142 19.2 19.2 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 270110 2250023 0.0319 18.7 18.7 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 271110 2250023 0.03496 17.3 17.3 0 24-HR ALL 1ST UCART1 11/7/2013 24 hr 272110 2250023 0.04667 17 17 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 273110 2250023 0.06552 15.6 15.6 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 274110 2250023 0.07325 26.1 219 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 275110 2250023 0.04142 33.3 219 0 24-HR ALL 1ST UCART1 10/4/2013 24 hr 276110 2250023 0.18106 74.2 219 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 277110 2250023 0.05185 24.6 214 0 24-HR ALL 1ST UCART1 12/30/2013 24 hr 278110 2250023 0.04183 18.6 18.6 0 24-HR ALL 1ST UCART1 10/17/2013 24 hr 279110 2250023 0.03984 29 29 0 24-HR ALL 1ST UCART1 10/16/2013 24 hr 280110 2250023 0.0345 11.8 11.8 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 281110 2250023 0.04398 16.5 16.5 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 282110 2250023 0.02929 16.1 16.1 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 283110 2250023 0.01591 25.1 25.1 0 24-HR ALL 1ST UCART1 12/20/2013 24 hr 284110 2250023 0.00954 32.3 32.3 0 24-HR ALL 1ST UCART1 12/20/2013 24 hr 285110 2250023 0.005 33.7 33.7 0 24-HR ALL 1ST UCART1 12/20/2013 24 hr 286110 2250023 0.00277 36.8 36.8 0 24-HR ALL 1ST UCART1 12/20/2013 24 hr 266110 2251023 0.01021 0 0 0 24-HR ALL 1ST UCART1 10/9/2013 24 hr 267110 2251023 0.01559 0 0 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 268110 2251023 0.0203 0 0 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 269110 2251023 0.02333 10 10 0 24-HR ALL 1ST UCART1 11/7/2013 24 hr 270110 2251023 0.02402 9.6 9.6 0 24-HR ALL 1ST UCART1 10/22/2013 24 hr 271110 2251023 0.03433 9.1 9.1 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 272110 2251023 0.04404 12.2 12.2 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 273110 2251023 0.05401 12 12 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 274110 2251023 0.04762 17.1 17.1 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 275110 2251023 0.00813 27.7 27.7 0 24-HR ALL 1ST UCART1 10/4/2013 24 hr 276110 2251023 0.00802 27 197 0 24-HR ALL 1ST UCART1 10/1/2013 24 hr 277110 2251023 0.03036 39.6 79 0 24-HR ALL 1ST UCART1 12/30/2013 24 hr 278110 2251023 0.02251 20.7 20.7 0 24-HR ALL 1ST UCART1 10/10/2013 24 hr 279110 2251023 0.02952 7.1 24 0 24-HR ALL 1ST UCART1 10/17/2013 24 hr 280110 2251023 0.03139 23 23 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 281110 2251023 0.01743 14.2 14.2 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 282110 2251023 0.02981 23.4 23.4 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 283110 2251023 0.02864 26.4 26.4 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr


Page 7



284110 2251023 0.01994 30.3 30.3 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 285110 2251023 0.01178 27.3 27.3 0 24-HR ALL 1ST UCART1 12/20/2013 24 hr 286110 2251023 0.00817 29.9 29.9 0 24-HR ALL 1ST UCART1 12/20/2013 24 hr 266110 2252023 0.01537 0 0 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 267110 2252023 0.01584 0 0 0 24-HR ALL 1ST UCART1 11/7/2013 24 hr 268110 2252023 0.0156 0 0 0 24-HR ALL 1ST UCART1 11/7/2013 24 hr 269110 2252023 0.02139 0 0 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 270110 2252023 0.02483 0 0 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 271110 2252023 0.03074 2.4 2.4 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 272110 2252023 0.0457 5.4 5.4 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 273110 2252023 0.03243 10.5 10.5 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 274110 2252023 0.02905 16.4 16.4 0 24-HR ALL 1ST UCART1 10/4/2013 24 hr 275110 2252023 0.00389 33 33 0 24-HR ALL 1ST UCART1 12/30/2013 24 hr 276110 2252023 0.00599 21.6 21.6 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 277110 2252023 0.01387 17.5 17.5 0 24-HR ALL 1ST UCART1 10/1/2013 24 hr 278110 2252023 0.02237 21 21 0 24-HR ALL 1ST UCART1 12/30/2013 24 hr 279110 2252023 0.02121 8.4 21 0 24-HR ALL 1ST UCART1 10/10/2013 24 hr 280110 2252023 0.01955 17.2 17.2 0 24-HR ALL 1ST UCART1 10/17/2013 24 hr 281110 2252023 0.0256 18.3 18.3 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 282110 2252023 0.01738 25.9 25.9 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 283110 2252023 0.01927 26.4 26.4 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 284110 2252023 0.02268 32.7 32.7 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 285110 2252023 0.01978 28.8 28.8 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 286110 2252023 0.0142 29.3 29.3 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 266110 2253023 0.01344 0 0 0 24-HR ALL 1ST UCART1 11/7/2013 24 hr 267110 2253023 0.01324 0 0 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 268110 2253023 0.01746 0 0 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 269110 2253023 0.01872 0 0 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 270110 2253023 0.02351 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 271110 2253023 0.03772 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 272110 2253023 0.01986 1.2 1.2 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 273110 2253023 0.02872 12.8 12.8 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 274110 2253023 0.01368 17.8 17.8 0 24-HR ALL 1ST UCART1 10/4/2013 24 hr 275110 2253023 0.00985 56 99 0 24-HR ALL 1ST UCART1 10/19/2013 24 hr 276110 2253023 0.0048 21.1 95 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 277110 2253023 0.01313 13.8 13.8 0 24-HR ALL 1ST UCART1 10/1/2013 24 hr 278110 2253023 0.02183 22.7 22.7 0 24-HR ALL 1ST UCART1 12/30/2013 24 hr 279110 2253023 0.01135 8 8 0 24-HR ALL 1ST UCART1 10/3/2013 24 hr 280110 2253023 0.0229 18.9 18.9 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 281110 2253023 0.01675 21.8 21.8 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 282110 2253023 0.0228 23.5 23.5 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 283110 2253023 0.0173 30.2 30.2 0 24-HR ALL 1ST UCART1 10/4/2013 24 hr 284110 2253023 0.01235 26.2 26.2 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 285110 2253023 0.01662 27.6 27.6 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 286110 2253023 0.01687 31 31 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 266110 2254023 0.01347 0 0 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 267110 2254023 0.01551 0 0 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 268110 2254023 0.01422 0 0 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 269110 2254023 0.01884 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 270110 2254023 0.03146 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 271110 2254023 0.01795 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 272110 2254023 0.02176 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr


Page 8



273110 2254023 0.02033 17.5 17.5 0 24-HR ALL 1ST UCART1 10/4/2013 24 hr 274110 2254023 0.00474 13.4 13.4 0 24-HR ALL 1ST UCART1 10/4/2013 24 hr 275110 2254023 0.00266 16.6 16.6 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 276110 2254023 0.00397 9.4 9.4 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 277110 2254023 0.01172 20 20 0 24-HR ALL 1ST UCART1 10/1/2013 24 hr 278110 2254023 0.01545 17.5 17.5 0 24-HR ALL 1ST UCART1 12/30/2013 24 hr 279110 2254023 0.0106 10 10 0 24-HR ALL 1ST UCART1 12/30/2013 24 hr 280110 2254023 0.01842 16.9 16.9 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 281110 2254023 0.02058 25.8 25.8 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 282110 2254023 0.0162 26.4 26.4 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 283110 2254023 0.02013 26.3 26.3 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 284110 2254023 0.01567 27.1 27.1 0 24-HR ALL 1ST UCART1 10/4/2013 24 hr 285110 2254023 0.01159 25.9 25.9 0 24-HR ALL 1ST UCART1 10/4/2013 24 hr 286110 2254023 0.01212 29.9 29.9 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 266110 2255023 0.01378 0 0 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 267110 2255023 0.01114 0 0 0 24-HR ALL 1ST UCART1 10/29/2013 24 hr 268110 2255023 0.0155 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 269110 2255023 0.02622 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 270110 2255023 0.01826 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 271110 2255023 0.01322 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 272110 2255023 0.01882 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 273110 2255023 0.0142 16.3 16.3 0 24-HR ALL 1ST UCART1 10/4/2013 24 hr 274110 2255023 0.00358 14 14 0 24-HR ALL 1ST UCART1 10/19/2013 24 hr 275110 2255023 0.00245 17.4 17.4 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 276110 2255023 0.00442 16.8 16.8 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 277110 2255023 0.00903 0 0 0 24-HR ALL 1ST UCART1 10/1/2013 24 hr 278110 2255023 0.01007 16.8 16.8 0 24-HR ALL 1ST UCART1 12/30/2013 24 hr 279110 2255023 0.01347 21.7 21.7 0 24-HR ALL 1ST UCART1 12/30/2013 24 hr 280110 2255023 0.00954 20.6 20.6 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 281110 2255023 0.02298 27.3 27.3 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 282110 2255023 0.0156 23.6 23.6 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 283110 2255023 0.01452 25.1 25.1 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 284110 2255023 0.01801 30 30 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 285110 2255023 0.01463 28.2 28.2 0 24-HR ALL 1ST UCART1 10/4/2013 24 hr 286110 2255023 0.01143 22.2 22.2 0 24-HR ALL 1ST UCART1 10/4/2013 24 hr 266110 2256023 0.00962 0 0 0 24-HR ALL 1ST UCART1 11/6/2013 24 hr 267110 2256023 0.01302 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 268110 2256023 0.02199 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 269110 2256023 0.01812 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 270110 2256023 0.0095 0 0 0 24-HR ALL 1ST UCART1 10/31/2013 24 hr 271110 2256023 0.01677 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 272110 2256023 0.01313 0 0 0 24-HR ALL 1ST UCART1 10/4/2013 24 hr 273110 2256023 0.00709 0 0 0 24-HR ALL 1ST UCART1 10/19/2013 24 hr 274110 2256023 0.00315 13.8 13.8 0 24-HR ALL 1ST UCART1 10/19/2013 24 hr 275110 2256023 0.00225 13.4 13.4 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 276110 2256023 0.0055 17.7 17.7 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 277110 2256023 0.00737 0.5 0.5 0 24-HR ALL 1ST UCART1 10/1/2013 24 hr 278110 2256023 0.00658 13 13 0 24-HR ALL 1ST UCART1 12/30/2013 24 hr 279110 2256023 0.01257 19.9 19.9 0 24-HR ALL 1ST UCART1 12/30/2013 24 hr 280110 2256023 0.00613 18.7 18.7 0 24-HR ALL 1ST UCART1 12/30/2013 24 hr 281110 2256023 0.01486 20.9 20.9 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 282110 2256023 0.02154 27.4 27.4 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr


Page 9



283110 2256023 0.01134 23.3 23.3 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 284110 2256023 0.01312 25.2 25.2 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 285110 2256023 0.01541 28.3 28.3 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 286110 2256023 0.01277 24.8 24.8 0 24-HR ALL 1ST UCART1 10/4/2013 24 hr 266110 2257023 0.01112 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 267110 2257023 0.01861 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 268110 2257023 0.01731 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 269110 2257023 0.00973 0 0 0 24-HR ALL 1ST UCART1 10/31/2013 24 hr 270110 2257023 0.01109 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 271110 2257023 0.01421 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 272110 2257023 0.01152 0 0 0 24-HR ALL 1ST UCART1 10/4/2013 24 hr 273110 2257023 0.00822 0 0 0 24-HR ALL 1ST UCART1 10/19/2013 24 hr 274110 2257023 0.00253 10.7 10.7 0 24-HR ALL 1ST UCART1 10/19/2013 24 hr 275110 2257023 0.00246 14.7 14.7 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 276110 2257023 0.00659 11.1 11.1 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 277110 2257023 0.00608 8.8 8.8 0 24-HR ALL 1ST UCART1 10/1/2013 24 hr 278110 2257023 0.00508 17.8 17.8 0 24-HR ALL 1ST UCART1 10/1/2013 24 hr 279110 2257023 0.00993 15 15 0 24-HR ALL 1ST UCART1 12/30/2013 24 hr 280110 2257023 0.00819 18.3 18.3 0 24-HR ALL 1ST UCART1 12/30/2013 24 hr 281110 2257023 0.00782 23.1 23.1 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 282110 2257023 0.01757 20.6 20.6 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 283110 2257023 0.01744 23.9 23.9 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 284110 2257023 0.00843 26.2 26.2 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 285110 2257023 0.01158 22.6 22.6 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 286110 2257023 0.01285 21.9 21.9 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr AQ (CCPL) 276110.68 2247023.87 6.00E-05 37.31 37.31 0 24-HR ALL 1ST 10/25/2013 24 hrAQ (PALI) 274508.67 2251567.12 0.02536 20.52 20.52 0 24-HR ALL 1ST 10/4/2013 24 hr AQ (PUNAT) 277635.66 2249303.76 0.0577 22.68 197 0 24-HR ALL 1ST 10/17/2013 24 hrAQ (BHILAD) 279930.11 2244698.09 0.02046 21.28 21.28 0 24-HR ALL 1ST 10/6/2013 24 hr AQ (DAHELI) 276916.75 2242422.63 0.03688 31.12 31.12 0 24-HR ALL 1ST 12/4/2013 24 hr AQ (SARAI) 271773.3 2244824.09 0.06079 43.46 160 0 24-HR ALL 1ST 11/6/2013 24 hr DW (PDISCR) 275927.82 2246557.21 0.62629 36.57 36.57 0 24-HR ALL 1ST 10/31/2013 24 hrDW (PDISCR) 275748.63 2246090.42 0.47096 33.96 33.96 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 275569.45 2245623.63 0.42861 37.74 37.74 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 275390.26 2245156.84 0.28624 29.07 29.07 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 275211.08 2244690.05 0.23486 29.47 29.47 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 275031.9 2244223.26 0.17862 22.26 22.26 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 274852.71 2243756.47 0.16056 27.82 27.82 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 274673.53 2243289.68 0.14295 31.78 31.78 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 274494.34 2242822.89 0.11789 26.97 26.97 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 274315.16 2242356.1 0.1045 28.27 28.27 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 274135.98 2241889.31 0.0919 27.48 27.48 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 273956.79 2241422.52 0.08379 30.31 30.31 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 273777.61 2240955.73 0.0742 27.67 27.67 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 273598.42 2240488.94 0.06678 25.97 25.97 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 273419.24 2240022.15 0.06137 26.3 26.3 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 273240.06 2239555.36 0.05736 28.53 28.53 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 273060.87 2239088.57 0.05415 31.96 43 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 272881.69 2238621.78 0.05313 38.07 38.07 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 272702.5 2238154.99 0.04656 26.9 26.9 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 272523.32 2237688.2 0.04361 24.45 24.45 0 24-HR ALL 1ST 12/25/2013 24 hr

NOx - Dispersion Modeling Results

Page 1

X Y Concentration Elevation Hill Heights Flagpole Aver. Period Source Group Rank Net ID Date

[ug/m3] (ZELEV) (ZHILL) (ZFLAG) (AVE) (GRP) 266110.68 2237023.87 0.25024 3 3 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 267110.68 2237023.87 0.24899 3 3 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 268110.68 2237023.87 0.43309 4 4 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 269110.68 2237023.87 0.3409 7.2 7.2 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 270110.68 2237023.87 0.42291 12.7 12.7 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 271110.68 2237023.87 0.45818 8.6 8.6 0 24-HR ALL 1ST UCART1 10/11/2013 24 hr 272110.68 2237023.87 0.51543 20.5 20.5 0 24-HR ALL 1ST UCART1 12/25/2013 24 hr 273110.68 2237023.87 0.77494 12.2 12.2 0 24-HR ALL 1ST UCART1 12/25/2013 24 hr 274110.68 2237023.87 0.51034 23.1 23.1 0 24-HR ALL 1ST UCART1 12/25/2013 24 hr 275110.68 2237023.87 0.55964 22.9 22.9 0 24-HR ALL 1ST UCART1 12/28/2013 24 hr 276110.68 2237023.87 0.34555 30.3 30.3 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 277110.68 2237023.87 0.2502 38.1 38.1 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 278110.68 2237023.87 0.26106 45.4 45.4 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 279110.68 2237023.87 0.26434 57.6 57.6 0 24-HR ALL 1ST UCART1 10/25/2013 24 hr 280110.68 2237023.87 0.29836 39.1 39.1 0 24-HR ALL 1ST UCART1 12/8/2013 24 hr 281110.68 2237023.87 0.26407 34.2 34.2 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 282110.68 2237023.87 0.37788 28.4 28.4 0 24-HR ALL 1ST UCART1 12/17/2013 24 hr 283110.68 2237023.87 0.37307 31.2 31.2 0 24-HR ALL 1ST UCART1 12/17/2013 24 hr 284110.68 2237023.87 0.20306 31.5 31.5 0 24-HR ALL 1ST UCART1 12/17/2013 24 hr 285110.68 2237023.87 0.20291 30.9 30.9 0 24-HR ALL 1ST UCART1 12/7/2013 24 hr 286110.68 2237023.87 0.16068 53.6 53.6 0 24-HR ALL 1ST UCART1 12/7/2013 24 hr 266110.68 2238023.87 0.29378 4.5 4.5 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 267110.68 2238023.87 0.293 4.7 4.7 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 268110.68 2238023.87 0.29934 4.5 4.5 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 269110.68 2238023.87 0.48917 8.8 8.8 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 270110.68 2238023.87 0.28645 13.8 13.8 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 271110.68 2238023.87 0.57246 20.7 20.7 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 272110.68 2238023.87 0.48604 18.2 18.2 0 24-HR ALL 1ST UCART1 10/11/2013 24 hr 273110.68 2238023.87 0.9372 24.4 24.4 0 24-HR ALL 1ST UCART1 12/25/2013 24 hr 274110.68 2238023.87 0.58846 18.4 18.4 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 275110.68 2238023.87 0.6267 19 19 0 24-HR ALL 1ST UCART1 12/28/2013 24 hr 276110.68 2238023.87 0.3915 26.9 26.9 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 277110.68 2238023.87 0.28173 41.1 41.1 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 278110.68 2238023.87 0.30224 45.7 45.7 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 279110.68 2238023.87 0.25725 43.7 43.7 0 24-HR ALL 1ST UCART1 11/6/2013 24 hr 280110.68 2238023.87 0.25953 72.2 72.2 0 24-HR ALL 1ST UCART1 12/8/2013 24 hr 281110.68 2238023.87 0.38566 38.4 38.4 0 24-HR ALL 1ST UCART1 12/17/2013 24 hr 282110.68 2238023.87 0.46106 31 31 0 24-HR ALL 1ST UCART1 12/17/2013 24 hr 283110.68 2238023.87 0.28188 29.8 29.8 0 24-HR ALL 1ST UCART1 12/17/2013 24 hr 284110.68 2238023.87 0.22741 26.5 26.5 0 24-HR ALL 1ST UCART1 12/7/2013 24 hr 285110.68 2238023.87 0.17288 34 34 0 24-HR ALL 1ST UCART1 12/7/2013 24 hr 286110.68 2238023.87 0.08812 50.8 50.8 0 24-HR ALL 1ST UCART1 10/6/2013 24 hr 266110.68 2239023.87 0.19318 10.7 10.7 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 267110.68 2239023.87 0.33494 4.4 4.4 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 268110.68 2239023.87 0.35682 11.3 11.3 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 269110.68 2239023.87 0.36454 10 10 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 270110.68 2239023.87 0.52073 9.5 9.5 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 271110.68 2239023.87 0.50366 18.8 18.8 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 272110.68 2239023.87 0.63988 28.2 28.2 0 24-HR ALL 1ST UCART1 10/11/2013 24 hr 273110.68 2239023.87 0.88743 30.7 30.7 0 24-HR ALL 1ST UCART1 12/25/2013 24 hr



Page 2


[ug/m3] (ZELEV) (ZHILL) (ZFLAG) (AVE) (GRP)Discrete

Receptor ID 274110.68 2239023.87 0.75842 19.6 19.6 0 24-HR ALL 1ST UCART1 12/25/2013 24 hr 275110.68 2239023.87 0.73215 24.9 24.9 0 24-HR ALL 1ST UCART1 12/28/2013 24 hr 276110.68 2239023.87 0.44901 24.2 24.2 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 277110.68 2239023.87 0.28564 30.6 30.6 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 278110.68 2239023.87 0.33407 41.9 70 0 24-HR ALL 1ST UCART1 10/25/2013 24 hr 279110.68 2239023.87 0.40296 42.6 42.6 0 24-HR ALL 1ST UCART1 12/8/2013 24 hr 280110.68 2239023.87 0.41438 51.5 51.5 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 281110.68 2239023.87 0.55339 35.6 35.6 0 24-HR ALL 1ST UCART1 12/17/2013 24 hr 282110.68 2239023.87 0.39654 30.9 87 0 24-HR ALL 1ST UCART1 12/17/2013 24 hr 283110.68 2239023.87 0.27318 30 30 0 24-HR ALL 1ST UCART1 12/7/2013 24 hr 284110.68 2239023.87 0.19746 30.1 30.1 0 24-HR ALL 1ST UCART1 12/7/2013 24 hr 285110.68 2239023.87 0.10719 36.6 36.6 0 24-HR ALL 1ST UCART1 10/6/2013 24 hr 286110.68 2239023.87 0.16034 38 38 0 24-HR ALL 1ST UCART1 11/8/2013 24 hr 266110.68 2240023.87 0.21844 18.4 18.4 0 24-HR ALL 1ST UCART1 12/8/2013 24 hr 267110.68 2240023.87 0.19351 12.8 12.8 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 268110.68 2240023.87 0.40757 17.1 17.1 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 269110.68 2240023.87 0.44615 18.4 18.4 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 270110.68 2240023.87 0.44395 10.8 10.8 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 271110.68 2240023.87 0.52512 20.3 20.3 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 272110.68 2240023.87 0.80368 29.4 38 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 273110.68 2240023.87 0.64884 28.4 28.4 0 24-HR ALL 1ST UCART1 11/6/2013 24 hr 274110.68 2240023.87 1.20191 31.9 45 0 24-HR ALL 1ST UCART1 12/25/2013 24 hr 275110.68 2240023.87 0.80092 22.9 22.9 0 24-HR ALL 1ST UCART1 12/28/2013 24 hr 276110.68 2240023.87 0.53979 26.8 26.8 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 277110.68 2240023.87 0.32925 38.3 38.3 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 278110.68 2240023.87 0.38127 44.4 72 0 24-HR ALL 1ST UCART1 10/25/2013 24 hr 279110.68 2240023.87 0.49708 45.6 45.6 0 24-HR ALL 1ST UCART1 12/8/2013 24 hr 280110.68 2240023.87 0.86097 68.8 93 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 281110.68 2240023.87 0.57636 35.5 35.5 0 24-HR ALL 1ST UCART1 12/17/2013 24 hr 282110.68 2240023.87 0.31959 30.1 30.1 0 24-HR ALL 1ST UCART1 12/7/2013 24 hr 283110.68 2240023.87 0.24221 33.4 33.4 0 24-HR ALL 1ST UCART1 12/7/2013 24 hr 284110.68 2240023.87 0.13022 31 31 0 24-HR ALL 1ST UCART1 10/6/2013 24 hr 285110.68 2240023.87 0.19951 31.5 31.5 0 24-HR ALL 1ST UCART1 11/8/2013 24 hr 286110.68 2240023.87 0.15951 35.7 35.7 0 24-HR ALL 1ST UCART1 11/8/2013 24 hr 266110.68 2241023.87 0.20775 15.6 15.6 0 24-HR ALL 1ST UCART1 11/8/2013 24 hr 267110.68 2241023.87 0.26648 18.4 18.4 0 24-HR ALL 1ST UCART1 12/8/2013 24 hr 268110.68 2241023.87 0.23337 24.3 62 0 24-HR ALL 1ST UCART1 10/19/2013 24 hr 269110.68 2241023.87 0.48974 26.5 93 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 270110.68 2241023.87 0.55337 18.6 18.6 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 271110.68 2241023.87 0.55189 15.5 15.5 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 272110.68 2241023.87 0.58492 41.9 41.9 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 273110.68 2241023.87 0.96173 37.9 37.9 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 274110.68 2241023.87 1.48424 24.8 24.8 0 24-HR ALL 1ST UCART1 12/25/2013 24 hr 275110.68 2241023.87 0.84418 21.5 21.5 0 24-HR ALL 1ST UCART1 12/28/2013 24 hr 276110.68 2241023.87 0.63372 23.8 23.8 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 277110.68 2241023.87 0.38259 31.3 31.3 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 278110.68 2241023.87 0.40611 37.9 37.9 0 24-HR ALL 1ST UCART1 12/8/2013 24 hr 279110.68 2241023.87 0.58241 50.4 50.4 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 280110.68 2241023.87 0.81078 39.4 39.4 0 24-HR ALL 1ST UCART1 12/17/2013 24 hr 281110.68 2241023.87 0.38781 33.5 33.5 0 24-HR ALL 1ST UCART1 12/7/2013 24 hr


Page 3



Receptor ID 282110.68 2241023.87 0.28184 30.1 30.1 0 24-HR ALL 1ST UCART1 12/7/2013 24 hr 283110.68 2241023.87 0.16894 32.9 32.9 0 24-HR ALL 1ST UCART1 10/6/2013 24 hr 284110.68 2241023.87 0.24603 33.3 33.3 0 24-HR ALL 1ST UCART1 11/8/2013 24 hr 285110.68 2241023.87 0.16391 38 38 0 24-HR ALL 1ST UCART1 10/6/2013 24 hr 286110.68 2241023.87 0.11831 36.2 36.2 0 24-HR ALL 1ST UCART1 10/6/2013 24 hr 266110.68 2242023.87 0.28521 4.9 4.9 0 24-HR ALL 1ST UCART1 12/28/2013 24 hr 267110.68 2242023.87 0.25197 10.5 10.5 0 24-HR ALL 1ST UCART1 12/28/2013 24 hr 268110.68 2242023.87 0.27195 17.3 17.3 0 24-HR ALL 1ST UCART1 12/8/2013 24 hr 269110.68 2242023.87 0.37878 40.1 93 0 24-HR ALL 1ST UCART1 12/8/2013 24 hr 270110.68 2242023.87 0.55566 24.9 24.9 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 271110.68 2242023.87 0.72201 21.7 21.7 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 272110.68 2242023.87 0.74104 31.2 31.2 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 273110.68 2242023.87 3.62149 67.7 87 0 24-HR ALL 1ST UCART1 12/25/2013 24 hr 274110.68 2242023.87 1.27157 28.1 28.1 0 24-HR ALL 1ST UCART1 12/25/2013 24 hr 275110.68 2242023.87 1.22986 23.1 23.1 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 276110.68 2242023.87 0.7952 26.8 26.8 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 277110.68 2242023.87 0.53716 30.9 30.9 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 278110.68 2242023.87 0.70624 33.3 33.3 0 24-HR ALL 1ST UCART1 12/8/2013 24 hr 279110.68 2242023.87 1.00185 46.3 46.3 0 24-HR ALL 1ST UCART1 12/17/2013 24 hr 280110.68 2242023.87 0.58841 37.2 37.2 0 24-HR ALL 1ST UCART1 12/17/2013 24 hr 281110.68 2242023.87 0.32854 26.7 26.7 0 24-HR ALL 1ST UCART1 12/7/2013 24 hr 282110.68 2242023.87 0.26125 34.5 34.5 0 24-HR ALL 1ST UCART1 11/8/2013 24 hr 283110.68 2242023.87 0.27797 34.6 34.6 0 24-HR ALL 1ST UCART1 11/8/2013 24 hr 284110.68 2242023.87 0.17479 36.2 36.2 0 24-HR ALL 1ST UCART1 10/6/2013 24 hr 285110.68 2242023.87 0.11456 40.8 40.8 0 24-HR ALL 1ST UCART1 10/6/2013 24 hr 286110.68 2242023.87 0.07564 37.3 37.3 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 266110.68 2243023.87 0.26546 15.7 15.7 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 267110.68 2243023.87 0.29268 10.7 10.7 0 24-HR ALL 1ST UCART1 11/6/2013 24 hr 268110.68 2243023.87 0.35075 12.4 12.4 0 24-HR ALL 1ST UCART1 11/6/2013 24 hr 269110.68 2243023.87 0.35519 20.3 20.3 0 24-HR ALL 1ST UCART1 10/24/2013 24 hr 270110.68 2243023.87 0.46365 24.3 24.3 0 24-HR ALL 1ST UCART1 12/8/2013 24 hr 271110.68 2243023.87 0.6673 36.9 80 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 272110.68 2243023.87 1.10586 49.8 160 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 273110.68 2243023.87 0.93751 33.1 33.1 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 274110.68 2243023.87 1.24587 26.7 26.7 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 275110.68 2243023.87 1.80975 28.4 28.4 0 24-HR ALL 1ST UCART1 12/25/2013 24 hr 276110.68 2243023.87 1.05914 31.3 31.3 0 24-HR ALL 1ST UCART1 12/28/2013 24 hr 277110.68 2243023.87 0.66387 31.8 31.8 0 24-HR ALL 1ST UCART1 12/4/2013 24 hr 278110.68 2243023.87 0.79122 38.9 38.9 0 24-HR ALL 1ST UCART1 12/17/2013 24 hr 279110.68 2243023.87 0.92661 33 33 0 24-HR ALL 1ST UCART1 12/17/2013 24 hr 280110.68 2243023.87 0.45742 35.5 35.5 0 24-HR ALL 1ST UCART1 12/7/2013 24 hr 281110.68 2243023.87 0.38388 25.8 25.8 0 24-HR ALL 1ST UCART1 11/8/2013 24 hr 282110.68 2243023.87 0.25214 27.5 27.5 0 24-HR ALL 1ST UCART1 11/8/2013 24 hr 283110.68 2243023.87 0.16917 32.5 32.5 0 24-HR ALL 1ST UCART1 10/6/2013 24 hr 284110.68 2243023.87 0.10941 37.8 37.8 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 285110.68 2243023.87 0.13222 39 39 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 286110.68 2243023.87 0.17798 42.8 42.8 0 24-HR ALL 1ST UCART1 11/10/2013 24 hr 266110.68 2244023.87 0.17975 12.6 12.6 0 24-HR ALL 1ST UCART1 10/21/2013 24 hr 267110.68 2244023.87 0.20096 14.8 14.8 0 24-HR ALL 1ST UCART1 11/6/2013 24 hr 268110.68 2244023.87 0.32726 13.8 13.8 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr


Page 4



Receptor ID 269110.68 2244023.87 0.41178 15.3 15.3 0 24-HR ALL 1ST UCART1 11/6/2013 24 hr 270110.68 2244023.87 0.5546 26.2 26.2 0 24-HR ALL 1ST UCART1 11/6/2013 24 hr 271110.68 2244023.87 0.53584 35.5 160 0 24-HR ALL 1ST UCART1 10/24/2013 24 hr 272110.68 2244023.87 0.13585 128.5 160 0 24-HR ALL 1ST UCART1 10/23/2013 24 hr 273110.68 2244023.87 1.59797 39 160 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 274110.68 2244023.87 1.36393 33.1 33.1 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 275110.68 2244023.87 3.04318 21 21 0 24-HR ALL 1ST UCART1 12/25/2013 24 hr 276110.68 2244023.87 1.39332 25.6 25.6 0 24-HR ALL 1ST UCART1 12/28/2013 24 hr 277110.68 2244023.87 1.05133 35.2 35.2 0 24-HR ALL 1ST UCART1 12/8/2013 24 hr 278110.68 2244023.87 1.89966 55 145 0 24-HR ALL 1ST UCART1 12/17/2013 24 hr 279110.68 2244023.87 0.55493 35 145 0 24-HR ALL 1ST UCART1 12/7/2013 24 hr 280110.68 2244023.87 0.55588 25.5 25.5 0 24-HR ALL 1ST UCART1 11/8/2013 24 hr 281110.68 2244023.87 0.25182 25.3 25.3 0 24-HR ALL 1ST UCART1 10/6/2013 24 hr 282110.68 2244023.87 0.14935 26.6 26.6 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 283110.68 2244023.87 0.21089 28.6 28.6 0 24-HR ALL 1ST UCART1 11/10/2013 24 hr 284110.68 2244023.87 0.30454 36.8 36.8 0 24-HR ALL 1ST UCART1 11/10/2013 24 hr 285110.68 2244023.87 0.32448 34.3 34.3 0 24-HR ALL 1ST UCART1 11/10/2013 24 hr 286110.68 2244023.87 0.31636 34.5 34.5 0 24-HR ALL 1ST UCART1 11/10/2013 24 hr 266110.68 2245023.87 0.24878 12.5 12.5 0 24-HR ALL 1ST UCART1 10/21/2013 24 hr 267110.68 2245023.87 0.28316 12.1 12.1 0 24-HR ALL 1ST UCART1 10/21/2013 24 hr 268110.68 2245023.87 0.31231 10.6 10.6 0 24-HR ALL 1ST UCART1 10/21/2013 24 hr 269110.68 2245023.87 0.33478 12.9 12.9 0 24-HR ALL 1ST UCART1 10/21/2013 24 hr 270110.68 2245023.87 0.38909 25.5 133 0 24-HR ALL 1ST UCART1 11/6/2013 24 hr 271110.68 2245023.87 0.27333 107 133 0 24-HR ALL 1ST UCART1 10/10/2013 24 hr 272110.68 2245023.87 1.03866 40.3 160 0 24-HR ALL 1ST UCART1 11/6/2013 24 hr 273110.68 2245023.87 1.26668 47.3 47.3 0 24-HR ALL 1ST UCART1 12/8/2013 24 hr 274110.68 2245023.87 2.49445 33.9 33.9 0 24-HR ALL 1ST UCART1 10/8/2013 24 hr 275110.68 2245023.87 2.51311 27.7 27.7 0 24-HR ALL 1ST UCART1 11/6/2013 24 hr 276110.68 2245023.87 2.07966 28.3 28.3 0 24-HR ALL 1ST UCART1 12/28/2013 24 hr 277110.68 2245023.87 1.59353 38 38 0 24-HR ALL 1ST UCART1 12/20/2013 24 hr 278110.68 2245023.87 0.6915 39 145 0 24-HR ALL 1ST UCART1 12/7/2013 24 hr 279110.68 2245023.87 0.65715 31.5 145 0 24-HR ALL 1ST UCART1 11/8/2013 24 hr 280110.68 2245023.87 0.22618 18.2 18.2 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 281110.68 2245023.87 0.35777 23.8 23.8 0 24-HR ALL 1ST UCART1 11/10/2013 24 hr 282110.68 2245023.87 0.42921 24.6 24.6 0 24-HR ALL 1ST UCART1 11/10/2013 24 hr 283110.68 2245023.87 0.44325 30.9 30.9 0 24-HR ALL 1ST UCART1 11/10/2013 24 hr 284110.68 2245023.87 0.36295 28.5 28.5 0 24-HR ALL 1ST UCART1 11/10/2013 24 hr 285110.68 2245023.87 0.28616 28.5 28.5 0 24-HR ALL 1ST UCART1 11/10/2013 24 hr 286110.68 2245023.87 0.23072 34.6 34.6 0 24-HR ALL 1ST UCART1 11/10/2013 24 hr 266110.68 2246023.87 0.27422 2.7 17 0 24-HR ALL 1ST UCART1 11/19/2013 24 hr 267110.68 2246023.87 0.32574 10.6 10.6 0 24-HR ALL 1ST UCART1 11/19/2013 24 hr 268110.68 2246023.87 0.35171 4.1 4.1 0 24-HR ALL 1ST UCART1 11/19/2013 24 hr 269110.68 2246023.87 0.39188 11.6 11.6 0 24-HR ALL 1ST UCART1 11/19/2013 24 hr 270110.68 2246023.87 0.49301 20.1 20.1 0 24-HR ALL 1ST UCART1 10/21/2013 24 hr 271110.68 2246023.87 0.68912 23.6 23.6 0 24-HR ALL 1ST UCART1 10/21/2013 24 hr 272110.68 2246023.87 0.96046 34.8 34.8 0 24-HR ALL 1ST UCART1 10/21/2013 24 hr 273110.68 2246023.87 1.39636 73.4 73.4 0 24-HR ALL 1ST UCART1 12/18/2013 24 hr 274110.68 2246023.87 2.36754 40.6 40.6 0 24-HR ALL 1ST UCART1 11/6/2013 24 hr 275110.68 2246023.87 5.14728 36.7 36.7 0 24-HR ALL 1ST UCART1 11/2/2013 24 hr 276110.68 2246023.87 4.05077 33 33 0 24-HR ALL 1ST UCART1 12/28/2013 24 hr


Page 5



Receptor ID 277110.68 2246023.87 1.40962 40.4 40.4 0 24-HR ALL 1ST UCART1 11/30/2013 24 hr 278110.68 2246023.87 0.37594 31.6 31.6 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 279110.68 2246023.87 0.6296 27.4 27.4 0 24-HR ALL 1ST UCART1 11/10/2013 24 hr 280110.68 2246023.87 0.56425 22.9 22.9 0 24-HR ALL 1ST UCART1 11/10/2013 24 hr 281110.68 2246023.87 0.4368 27.7 27.7 0 24-HR ALL 1ST UCART1 11/10/2013 24 hr 282110.68 2246023.87 0.31139 24.6 24.6 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 283110.68 2246023.87 0.25468 28.2 28.2 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 284110.68 2246023.87 0.20678 30.1 30.1 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 285110.68 2246023.87 0.17255 33.5 33.5 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 286110.68 2246023.87 0.14222 33.9 33.9 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 266110.68 2247023.87 0.14781 0 0 0 24-HR ALL 1ST UCART1 11/11/2013 24 hr 267110.68 2247023.87 0.16785 0 0 0 24-HR ALL 1ST UCART1 11/11/2013 24 hr 268110.68 2247023.87 0.19814 6.1 6.1 0 24-HR ALL 1ST UCART1 11/11/2013 24 hr 269110.68 2247023.87 0.23851 11.2 11.2 0 24-HR ALL 1ST UCART1 11/11/2013 24 hr 270110.68 2247023.87 0.2928 15.5 15.5 0 24-HR ALL 1ST UCART1 11/11/2013 24 hr 271110.68 2247023.87 0.38434 24.9 24.9 0 24-HR ALL 1ST UCART1 11/11/2013 24 hr 272110.68 2247023.87 0.54323 37.8 37.8 0 24-HR ALL 1ST UCART1 11/11/2013 24 hr 273110.68 2247023.87 0.91693 45.3 88 0 24-HR ALL 1ST UCART1 11/11/2013 24 hr 274110.68 2247023.87 1.45438 44.8 132 0 24-HR ALL 1ST UCART1 11/11/2013 24 hr 275110.68 2247023.87 2.84189 42.6 42.6 0 24-HR ALL 1ST UCART1 11/11/2013 24 hrAQ (CCPL) 276110.68 2247023.87 0.00093 37.3 37.3 0 24-HR ALL 1ST UCART1 10/25/2013 24 hr 277110.68 2247023.87 3.04805 53.7 84 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 278110.68 2247023.87 1.35656 32.1 32.1 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 279110.68 2247023.87 0.86221 24.8 24.8 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 280110.68 2247023.87 0.63022 28.2 28.2 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 281110.68 2247023.87 0.46649 26.8 26.8 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 282110.68 2247023.87 0.37624 32.8 32.8 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 283110.68 2247023.87 0.29689 29.8 29.8 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 284110.68 2247023.87 0.24424 28.9 28.9 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 285110.68 2247023.87 0.20588 27.8 27.8 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 286110.68 2247023.87 0.17818 30.7 30.7 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 266110.68 2248023.87 0.16233 0 0 0 24-HR ALL 1ST UCART1 10/25/2013 24 hr 267110.68 2248023.87 0.20473 0 0 0 24-HR ALL 1ST UCART1 10/25/2013 24 hr 268110.68 2248023.87 0.26757 10 10 0 24-HR ALL 1ST UCART1 10/25/2013 24 hr 269110.68 2248023.87 0.32843 13.8 13.8 0 24-HR ALL 1ST UCART1 10/25/2013 24 hr 270110.68 2248023.87 0.37618 17.4 17.4 0 24-HR ALL 1ST UCART1 10/25/2013 24 hr 271110.68 2248023.87 0.38689 23 23 0 24-HR ALL 1ST UCART1 11/4/2013 24 hr 272110.68 2248023.87 0.85214 62.4 64 0 24-HR ALL 1ST UCART1 11/4/2013 24 hr 273110.68 2248023.87 1.49304 27.1 132 0 24-HR ALL 1ST UCART1 11/4/2013 24 hr 274110.68 2248023.87 1.94379 46.5 219 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 275110.68 2248023.87 3.51323 57.1 219 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 276110.68 2248023.87 1.2413 36.2 219 0 24-HR ALL 1ST UCART1 10/1/2013 24 hr 277110.68 2248023.87 2.03787 35.1 71 0 24-HR ALL 1ST UCART1 10/16/2013 24 hr 278110.68 2248023.87 2.17242 26.9 26.9 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 279110.68 2248023.87 0.48013 17.7 17.7 0 24-HR ALL 1ST UCART1 12/20/2013 24 hr 280110.68 2248023.87 0.1469 25.7 25.7 0 24-HR ALL 1ST UCART1 12/20/2013 24 hr 281110.68 2248023.87 0.09292 29.8 29.8 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 282110.68 2248023.87 0.11079 31.8 31.8 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 283110.68 2248023.87 0.1204 32.1 32.1 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 284110.68 2248023.87 0.12139 27 27 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr


Page 6



Receptor ID 285110.68 2248023.87 0.12123 26 30 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 286110.68 2248023.87 0.11871 28.1 28.1 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 266110.68 2249023.87 0.12696 0 0 0 24-HR ALL 1ST UCART1 10/25/2013 24 hr 267110.68 2249023.87 0.18152 0 0 0 24-HR ALL 1ST UCART1 11/4/2013 24 hr 268110.68 2249023.87 0.33211 11 11 0 24-HR ALL 1ST UCART1 11/4/2013 24 hr 269110.68 2249023.87 0.51526 15.3 15.3 0 24-HR ALL 1ST UCART1 11/4/2013 24 hr 270110.68 2249023.87 0.60454 15.9 15.9 0 24-HR ALL 1ST UCART1 11/4/2013 24 hr 271110.68 2249023.87 0.44895 18 18 0 24-HR ALL 1ST UCART1 11/4/2013 24 hr 272110.68 2249023.87 0.80239 22.8 22.8 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 273110.68 2249023.87 0.98609 22.7 22.7 0 24-HR ALL 1ST UCART1 10/22/2013 24 hr 274110.68 2249023.87 1.87154 30.2 219 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 275110.68 2249023.87 0.49024 82.7 219 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 276110.68 2249023.87 0.32952 83.3 219 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 277110.68 2249023.87 0.99077 25.8 219 0 24-HR ALL 1ST UCART1 10/10/2013 24 hr 278110.68 2249023.87 0.88229 19.7 19.7 0 24-HR ALL 1ST UCART1 10/16/2013 24 hr 279110.68 2249023.87 1.20616 21.8 21.8 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 280110.68 2249023.87 0.83275 27.8 27.8 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 281110.68 2249023.87 0.34853 24.3 24.3 0 24-HR ALL 1ST UCART1 12/20/2013 24 hr 282110.68 2249023.87 0.15622 27.2 27.2 0 24-HR ALL 1ST UCART1 12/20/2013 24 hr 283110.68 2249023.87 0.07018 20.8 20.8 0 24-HR ALL 1ST UCART1 12/20/2013 24 hr 284110.68 2249023.87 0.03959 28.6 28.6 0 24-HR ALL 1ST UCART1 12/20/2013 24 hr 285110.68 2249023.87 0.03159 32.5 32.5 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 286110.68 2249023.87 0.03205 30.2 30.2 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 266110.68 2250023.87 0.31337 0 0 0 24-HR ALL 1ST UCART1 11/4/2013 24 hr 267110.68 2250023.87 0.33249 0 0 0 24-HR ALL 1ST UCART1 11/4/2013 24 hr 268110.68 2250023.87 0.28371 9.4 9.4 0 24-HR ALL 1ST UCART1 11/4/2013 24 hr 269110.68 2250023.87 0.32852 19.2 19.2 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 270110.68 2250023.87 0.48844 18.7 18.7 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 271110.68 2250023.87 0.53477 17.3 17.3 0 24-HR ALL 1ST UCART1 11/7/2013 24 hr 272110.68 2250023.87 0.71433 17 17 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 273110.68 2250023.87 1.00347 15.6 15.6 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 274110.68 2250023.87 1.11665 26.1 219 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 275110.68 2250023.87 0.6301 33.3 219 0 24-HR ALL 1ST UCART1 10/4/2013 24 hr 276110.68 2250023.87 2.87309 74 219 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 277110.68 2250023.87 0.79348 24.6 214 0 24-HR ALL 1ST UCART1 12/30/2013 24 hr 278110.68 2250023.87 0.63892 18.6 18.6 0 24-HR ALL 1ST UCART1 10/17/2013 24 hr 279110.68 2250023.87 0.60947 29 29 0 24-HR ALL 1ST UCART1 10/16/2013 24 hr 280110.68 2250023.87 0.52823 11.7 11.7 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 281110.68 2250023.87 0.67439 16.5 16.5 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 282110.68 2250023.87 0.44931 16.1 16.1 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 283110.68 2250023.87 0.24428 25.1 25.1 0 24-HR ALL 1ST UCART1 12/20/2013 24 hr 284110.68 2250023.87 0.14636 32.3 32.3 0 24-HR ALL 1ST UCART1 12/20/2013 24 hr 285110.68 2250023.87 0.07675 33.7 33.7 0 24-HR ALL 1ST UCART1 12/20/2013 24 hr 286110.68 2250023.87 0.0425 36.8 36.8 0 24-HR ALL 1ST UCART1 12/20/2013 24 hr 266110.68 2251023.87 0.15657 0 0 0 24-HR ALL 1ST UCART1 10/9/2013 24 hr 267110.68 2251023.87 0.23918 0 0 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 268110.68 2251023.87 0.31116 0 0 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 269110.68 2251023.87 0.35753 10 10 0 24-HR ALL 1ST UCART1 11/7/2013 24 hr 270110.68 2251023.87 0.36864 9.6 9.6 0 24-HR ALL 1ST UCART1 10/22/2013 24 hr 271110.68 2251023.87 0.52562 9.1 9.1 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr


Page 7



Receptor ID 272110.68 2251023.87 0.67508 12.2 12.2 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 273110.68 2251023.87 0.82466 12 12 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 274110.68 2251023.87 0.72766 17.2 17.2 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 275110.68 2251023.87 0.12361 27.7 27.7 0 24-HR ALL 1ST UCART1 10/4/2013 24 hr 276110.68 2251023.87 0.12274 27 197 0 24-HR ALL 1ST UCART1 10/1/2013 24 hr 277110.68 2251023.87 0.46507 39.5 79 0 24-HR ALL 1ST UCART1 12/30/2013 24 hr 278110.68 2251023.87 0.34483 20.7 20.7 0 24-HR ALL 1ST UCART1 10/10/2013 24 hr 279110.68 2251023.87 0.45162 7.1 17 0 24-HR ALL 1ST UCART1 10/17/2013 24 hr 280110.68 2251023.87 0.47749 23 23 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 281110.68 2251023.87 0.267 14.2 14.2 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 282110.68 2251023.87 0.45713 23.3 23.3 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 283110.68 2251023.87 0.43952 26.4 26.4 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 284110.68 2251023.87 0.30615 30.3 30.3 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 285110.68 2251023.87 0.18084 27.3 27.3 0 24-HR ALL 1ST UCART1 12/20/2013 24 hr 286110.68 2251023.87 0.12541 29.9 29.9 0 24-HR ALL 1ST UCART1 12/20/2013 24 hr 266110.68 2252023.87 0.23567 0 0 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 267110.68 2252023.87 0.24303 0 0 0 24-HR ALL 1ST UCART1 11/7/2013 24 hr 268110.68 2252023.87 0.23883 0 0 0 24-HR ALL 1ST UCART1 11/7/2013 24 hr 269110.68 2252023.87 0.32784 0 0 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 270110.68 2252023.87 0.38036 0 0 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 271110.68 2252023.87 0.47149 2.4 2.4 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 272110.68 2252023.87 0.69861 5.3 5.3 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 273110.68 2252023.87 0.49635 10.5 10.5 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 274110.68 2252023.87 0.44412 16.4 16.4 0 24-HR ALL 1ST UCART1 10/4/2013 24 hr 275110.68 2252023.87 0.05977 33 33 0 24-HR ALL 1ST UCART1 12/30/2013 24 hr 276110.68 2252023.87 0.09173 21.6 21.6 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 277110.68 2252023.87 0.21218 17.5 17.5 0 24-HR ALL 1ST UCART1 10/1/2013 24 hr 278110.68 2252023.87 0.34249 20.9 20.9 0 24-HR ALL 1ST UCART1 12/30/2013 24 hr 279110.68 2252023.87 0.32512 8.4 21 0 24-HR ALL 1ST UCART1 10/10/2013 24 hr 280110.68 2252023.87 0.29899 17.1 17.1 0 24-HR ALL 1ST UCART1 10/17/2013 24 hr 281110.68 2252023.87 0.39025 18.3 18.3 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 282110.68 2252023.87 0.26498 25.9 25.9 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 283110.68 2252023.87 0.29559 26.4 26.4 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 284110.68 2252023.87 0.34808 32.7 32.7 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 285110.68 2252023.87 0.30366 28.8 28.8 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 286110.68 2252023.87 0.21802 29.3 29.3 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 266110.68 2253023.87 0.20609 0 0 0 24-HR ALL 1ST UCART1 11/7/2013 24 hr 267110.68 2253023.87 0.203 0 0 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 268110.68 2253023.87 0.26748 0 0 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 269110.68 2253023.87 0.2867 0 0 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 270110.68 2253023.87 0.36068 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 271110.68 2253023.87 0.57773 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 272110.68 2253023.87 0.30357 1.2 1.2 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 273110.68 2253023.87 0.43931 12.8 12.8 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 274110.68 2253023.87 0.20873 17.8 17.8 0 24-HR ALL 1ST UCART1 10/4/2013 24 hr 275110.68 2253023.87 0.15134 56.1 99 0 24-HR ALL 1ST UCART1 10/19/2013 24 hr 276110.68 2253023.87 0.07349 21.1 95 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 277110.68 2253023.87 0.20114 13.8 13.8 0 24-HR ALL 1ST UCART1 10/1/2013 24 hr 278110.68 2253023.87 0.33452 22.6 22.6 0 24-HR ALL 1ST UCART1 12/30/2013 24 hr 279110.68 2253023.87 0.17401 8.1 8.1 0 24-HR ALL 1ST UCART1 10/3/2013 24 hr


Page 8



Receptor ID 280110.68 2253023.87 0.34644 18.9 18.9 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 281110.68 2253023.87 0.25532 21.8 21.8 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 282110.68 2253023.87 0.34834 23.6 23.6 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 283110.68 2253023.87 0.26173 30.2 30.2 0 24-HR ALL 1ST UCART1 10/4/2013 24 hr 284110.68 2253023.87 0.18943 26.2 26.2 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 285110.68 2253023.87 0.25502 27.7 27.7 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 286110.68 2253023.87 0.2589 31.1 31.1 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 266110.68 2254023.87 0.20667 0 0 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 267110.68 2254023.87 0.23786 0 0 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 268110.68 2254023.87 0.21768 0 0 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 269110.68 2254023.87 0.28902 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 270110.68 2254023.87 0.48213 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 271110.68 2254023.87 0.27439 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 272110.68 2254023.87 0.33352 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 273110.68 2254023.87 0.31143 17.5 17.5 0 24-HR ALL 1ST UCART1 10/4/2013 24 hr 274110.68 2254023.87 0.07221 13.4 13.4 0 24-HR ALL 1ST UCART1 10/4/2013 24 hr 275110.68 2254023.87 0.04061 16.6 16.6 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 276110.68 2254023.87 0.06066 9.4 9.4 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 277110.68 2254023.87 0.17973 20 20 0 24-HR ALL 1ST UCART1 10/1/2013 24 hr 278110.68 2254023.87 0.23698 17.5 17.5 0 24-HR ALL 1ST UCART1 12/30/2013 24 hr 279110.68 2254023.87 0.16247 10 10 0 24-HR ALL 1ST UCART1 12/30/2013 24 hr 280110.68 2254023.87 0.27874 16.9 16.9 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 281110.68 2254023.87 0.31138 25.8 25.8 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 282110.68 2254023.87 0.2473 26.4 26.4 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 283110.68 2254023.87 0.30754 26.3 26.3 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 284110.68 2254023.87 0.23711 27.1 27.1 0 24-HR ALL 1ST UCART1 10/4/2013 24 hr 285110.68 2254023.87 0.1754 25.9 25.9 0 24-HR ALL 1ST UCART1 10/4/2013 24 hr 286110.68 2254023.87 0.18611 29.9 29.9 0 24-HR ALL 1ST UCART1 12/21/2013 24 hr 266110.68 2255023.87 0.21135 0 0 0 24-HR ALL 1ST UCART1 11/5/2013 24 hr 267110.68 2255023.87 0.17073 0 0 0 24-HR ALL 1ST UCART1 10/29/2013 24 hr 268110.68 2255023.87 0.23782 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 269110.68 2255023.87 0.40198 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 270110.68 2255023.87 0.27935 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 271110.68 2255023.87 0.20253 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 272110.68 2255023.87 0.28824 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 273110.68 2255023.87 0.21722 16.3 16.3 0 24-HR ALL 1ST UCART1 10/4/2013 24 hr 274110.68 2255023.87 0.05412 14 14 0 24-HR ALL 1ST UCART1 10/19/2013 24 hr 275110.68 2255023.87 0.03737 17.4 17.4 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 276110.68 2255023.87 0.06705 16.8 16.8 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 277110.68 2255023.87 0.13852 0 0 0 24-HR ALL 1ST UCART1 10/1/2013 24 hr 278110.68 2255023.87 0.15437 16.9 16.9 0 24-HR ALL 1ST UCART1 12/30/2013 24 hr 279110.68 2255023.87 0.2065 21.6 21.6 0 24-HR ALL 1ST UCART1 12/30/2013 24 hr 280110.68 2255023.87 0.1445 20.7 20.7 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 281110.68 2255023.87 0.34766 27.3 27.3 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 282110.68 2255023.87 0.23615 23.6 23.6 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 283110.68 2255023.87 0.22167 25 25 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 284110.68 2255023.87 0.27541 30 30 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 285110.68 2255023.87 0.22113 28.1 28.1 0 24-HR ALL 1ST UCART1 10/4/2013 24 hr 286110.68 2255023.87 0.17288 22.1 22.1 0 24-HR ALL 1ST UCART1 10/4/2013 24 hr 266110.68 2256023.87 0.14542 0 0 0 24-HR ALL 1ST UCART1 11/6/2013 24 hr


Page 9



Receptor ID 267110.68 2256023.87 0.19979 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 268110.68 2256023.87 0.33723 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 269110.68 2256023.87 0.27748 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 270110.68 2256023.87 0.14551 0 0 0 24-HR ALL 1ST UCART1 10/31/2013 24 hr 271110.68 2256023.87 0.25719 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 272110.68 2256023.87 0.20139 0 0 0 24-HR ALL 1ST UCART1 10/4/2013 24 hr 273110.68 2256023.87 0.10735 0 0 0 24-HR ALL 1ST UCART1 10/19/2013 24 hr 274110.68 2256023.87 0.0476 13.9 13.9 0 24-HR ALL 1ST UCART1 10/19/2013 24 hr 275110.68 2256023.87 0.03431 13.5 13.5 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 276110.68 2256023.87 0.08335 17.7 17.7 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 277110.68 2256023.87 0.11303 0.5 0.5 0 24-HR ALL 1ST UCART1 10/1/2013 24 hr 278110.68 2256023.87 0.10089 13 13 0 24-HR ALL 1ST UCART1 12/30/2013 24 hr 279110.68 2256023.87 0.19293 19.9 19.9 0 24-HR ALL 1ST UCART1 12/30/2013 24 hr 280110.68 2256023.87 0.09396 18.8 18.8 0 24-HR ALL 1ST UCART1 12/30/2013 24 hr 281110.68 2256023.87 0.22491 20.9 20.9 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 282110.68 2256023.87 0.32609 27.4 27.4 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 283110.68 2256023.87 0.17167 23.3 23.3 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 284110.68 2256023.87 0.20064 25.2 25.2 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 285110.68 2256023.87 0.23582 28.3 28.3 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 286110.68 2256023.87 0.19332 24.8 24.8 0 24-HR ALL 1ST UCART1 10/4/2013 24 hr 266110.68 2257023.87 0.17066 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 267110.68 2257023.87 0.28546 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 268110.68 2257023.87 0.26524 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 269110.68 2257023.87 0.14919 0 0 0 24-HR ALL 1ST UCART1 10/31/2013 24 hr 270110.68 2257023.87 0.17009 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 271110.68 2257023.87 0.21778 0 0 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 272110.68 2257023.87 0.17644 0 0 0 24-HR ALL 1ST UCART1 10/4/2013 24 hr 273110.68 2257023.87 0.12434 0 0 0 24-HR ALL 1ST UCART1 10/19/2013 24 hr 274110.68 2257023.87 0.03831 10.7 10.7 0 24-HR ALL 1ST UCART1 10/19/2013 24 hr 275110.68 2257023.87 0.03731 14.6 14.6 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 276110.68 2257023.87 0.09983 11.1 11.1 0 24-HR ALL 1ST UCART1 10/13/2013 24 hr 277110.68 2257023.87 0.09333 8.8 8.8 0 24-HR ALL 1ST UCART1 10/1/2013 24 hr 278110.68 2257023.87 0.07781 17.8 17.8 0 24-HR ALL 1ST UCART1 10/1/2013 24 hr 279110.68 2257023.87 0.15244 15 15 0 24-HR ALL 1ST UCART1 12/30/2013 24 hr 280110.68 2257023.87 0.12559 18.2 18.2 0 24-HR ALL 1ST UCART1 12/30/2013 24 hr 281110.68 2257023.87 0.11846 23.1 23.1 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 282110.68 2257023.87 0.26607 20.6 20.6 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 283110.68 2257023.87 0.26438 24 24 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 284110.68 2257023.87 0.12763 26.2 26.2 0 24-HR ALL 1ST UCART1 10/18/2013 24 hr 285110.68 2257023.87 0.17716 22.6 22.6 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr 286110.68 2257023.87 0.19682 22 22 0 24-HR ALL 1ST UCART1 12/5/2013 24 hr AQ (CCPL) 276110.68 2247023.87 0.00093 37.31 37.31 0 24-HR ALL 1ST 10/25/2013 24 hrAQ (PALI) 274508.67 2251567.12 0.38779 20.52 20.52 0 24-HR ALL 1ST 10/4/2013 24 hr AQ (PUNAT) 277635.66 2249303.76 0.88027 22.68 197 0 24-HR ALL 1ST 10/17/2013 24 hrAQ (BHILAD) 279930.11 2244698.09 0.31163 21.28 21.28 0 24-HR ALL 1ST 10/6/2013 24 hr AQ (DAHELI) 276916.75 2242422.63 0.56473 31.12 31.12 0 24-HR ALL 1ST 12/4/2013 24 hr AQ (SARAI) 271773.3 2244824.09 0.92964 43.46 160 0 24-HR ALL 1ST 11/6/2013 24 hr DW (PDISCR) 275927.82 2246557.21 9.50371 36.57 36.57 0 24-HR ALL 1ST 10/31/2013 24 hrDW (PDISCR) 275748.63 2246090.42 7.12645 33.96 33.96 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 275569.45 2245623.63 6.49927 37.74 37.74 0 24-HR ALL 1ST 12/25/2013 24 hr


Page 10



Receptor IDDW (PDISCR) 275390.26 2245156.84 4.35089 29.07 29.07 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 275211.08 2244690.05 3.57763 29.47 29.47 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 275031.9 2244223.26 2.72472 22.26 22.26 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 274852.71 2243756.47 2.451 27.82 27.82 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 274673.53 2243289.68 2.18413 31.78 31.78 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 274494.34 2242822.89 1.80176 26.97 26.97 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 274315.16 2242356.1 1.59789 28.27 28.27 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 274135.98 2241889.31 1.40575 27.48 27.48 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 273956.79 2241422.52 1.28234 30.31 30.31 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 273777.61 2240955.73 1.13555 27.67 27.67 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 273598.42 2240488.94 1.02207 25.97 25.97 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 273419.24 2240022.15 0.93942 26.3 26.3 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 273240.06 2239555.36 0.87809 28.53 28.53 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 273060.87 2239088.57 0.82902 31.96 43 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 272881.69 2238621.78 0.8133 38.07 38.07 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 272702.5 2238154.99 0.71265 26.9 26.9 0 24-HR ALL 1ST 12/25/2013 24 hrDW (PDISCR) 272523.32 2237688.2 0.66729 24.45 24.45 0 24-HR ALL 1ST 12/25/2013 24 hr

Micrometeorological Data

TEMPERATURE (◦C)

Month Maximum Minimum

October- 2013 38.00 20.60

November - 2013 38.10 24.00

December - 2013 37.50 22.80

RELATIVE HUMIDITY (%)


October- 2013 99.00 31.90

November - 2013 91.00 23.00

December - 2013 91.00 23.20

WIND SPEED (m/s)


October- 2013 6.00 0.00

November - 2013 5.70 0.00

December - 2013 5.70 0.00

URBAN MIXING HEIGHT (m)


October- 2013 2599.00 14.10

November - 2013 4000.00 8.80

December - 2013 2972.00 13.80

Micrometeorological Data

FREQUENCY COUNT

Date 1/10/2013 31/12/2013 Time 0.00 23.00

Organization M/s. Unistar Environment and Research Labs Pvt. Ltd.

Location G.I.D.C. Vapi.

Calm 0.68% Total Samples 2208

Directions 0.1 - 2.1

2.1 - 3.6

3.6 - 5.7

5.7 - 8.8 8.8 - 11.1

>= 11.1 Total

NNE 169 247 266 1 0 0 683

ENE 208 268 177 0 0 0 653

ESE 62 94 37 0 0 0 193

SSE 53 55 33 2 0 0 143

SSW 41 25 13 0 0 0 79

WSW 52 25 17 0 0 0 94

WNW 51 42 17 0 0 0 110

NNW 46 100 92 0 0 0 238

FREQUENCY DISTRIBUTION

Date 1/10/2013 31/12/2013 Time 0.00 23.00

Organization M/s. Unistar Environment and Research Labs Pvt. Ltd.

Location G.I.D.C. Vapi.

Calm 0.68% Total Samples 2208

Directions 0.1 - 2.1 2.1 - 3.6 3.6 - 5.7 5.7 - 8.8 8.8 - 11.1 >= 11.1 Total

NNE 0.07654 0.11187 0.12047 0.00045 0 0 0.30933

ENE 0.0942 0.12138 0.08016 0 0 0 0.29574

ESE 0.02808 0.04257 0.01676 0 0 0 0.08741

SSE 0.024 0.02491 0.01495 0.00091 0 0 0.06476

SSW 0.01857 0.01132 0.00589 0 0 0 0.03578

WSW 0.02355 0.01132 0.0077 0 0 0 0.04257

WNW 0.0231 0.01902 0.0077 0 0 0 0.04982

NNW 0.02083 0.04529 0.04167 0 0 0 0.10779

ENVIRONMENTAL TESTING METHOD

Sr. No.

Parameters

Test Method / Standard against which tests are performed

Range of testing/ Limits

of detection

Uncertainty of Measurement

(±) As per NABL As per MoEF

• Ambient Air Quality Monitoring

1. Particulate Matter PM 10

Gravimetric Method. IS-5182 Part-23:2006

Gravimetric Method. IS-5182 Part-23:2006

10 - 1000 µg/m3 42 .0 ± 5.1

2. Particulate Matter PM2.5

Gravimetric Method. CPCB Manual Volume – 1, May 2011

Gravimetric Method. CPCB Manual Volume – 1, May 2011

4 - 100 µg/m3 12.0 ± 7.0

3. Sulphur Dioxide IS-5182(Part-2):2001 Reaffirmed 2006

IS-5182(Part-2):2001 Reaffirmed 2006

4 – 1050 µg/m3 33.4 ± 8.0

4. Oxides of Nitrogen

Jacob & Hochheiser IS-5182 Part-6:2006

Jacob & Hochheiser IS-5182 Part-6:2006

6 - 420 µg/m3

21.6 ± 5.0

5. Carbon Monoxide (Co)

-- By Using Gas Analyzer -- --

6. Voc --

Adopted from OSHA & NIOSH (By GLC)

-- --

7. Noise Level -- SLM-100 (Instrument) -- --

• Stack Emission Monitoring

8. Particulate Matter

IS 11255( Part 1):1985, Reaffirmed 2003

IS 11255( Part 1):1985, Reaffirmed 2003

10 - 500 mg/Nm3

50.0 ± 10.8

9. Sulphur Dioxide IS 11255(Part 2): 1985, Reaffirmed 2003

IS 11255(Part 2): 1985, Reaffirmed 2003

4 - 1000 mg/Nm3

16.8 ± 0.70

10. Oxides of Nitrogen

IS 11255(Part 7):2005 IS 11255(Part 7):2005 5 - 400 mg/Nm3 6.4 ± 2.2

Sr. No.

Parameters

Test Method / Standard against which tests are performed

Range of testing/ Limits

of detection

Uncertainty of Measurement

(±) As per NABL As per MoEF

• Potable and domestic water, Ground water , Surface water ( Rivers, lakes ) Specification: IS 10500:2012

1. Colour (Pt-Co Scale)

IS 3025(Part 4): 1983, Reaff. 2006 Visible Comparison Method

IS 3025(Part 4): 1983, Reaff. 2006 Visible Comparison Method

1 – 50 Hazen 10 + 2

2. Odour IS 3025 (Part 5): 1983, Reaff. 2006 Qualitative Method

IS 3025 (Part 5): 1983, Reaff. 2006 Qualitative Method

Agreeable/ Not Agreeable

N.A.

3. Turbidity IS 3025 ( Part10):1984, Reaffirmed 2006 Nephelometer Method

IS 3025 ( Part10):1984, Reaffirmed 2006 Nephelometer Method

1.0-100 NTU 99.60 ± 0.67

4. pH APHA,22nd Ed., 2012, 4500-H+ B,4-92 IS 3025(Part 11):1983, Reaff. 2006 By pH Meter

APHA,22nd Ed., 2012, 4500-H+ B,4-92 IS 3025(Part 11):1983, Reaff. 2006 By pH Meter

5 - 12

4.01 ± 0.06

5. Temperature __ IS 3025(Part 9) 1984 -- -- 6. Total Hardness as

CaCO3 APHA, 22nd Ed., 2012, 3500 - B, 3-67 EDTA Titrimetric Method

APHA, 22nd Ed., 2012, 3500 - B, 3-67 EDTA Titrimetric Method

1 - 500 mg/L

20.80 ± 2.31

7. Total Dissolved Solid

APHA, 22nd Ed., 2012, 2540 C, 2-65

Gravimetric Method

APHA, 22nd Ed., 2012, 2540 C, 2-65 Gravimetric Method

5 - 1000mg/L 150.80 ± 3.30

8. Calcium as Ca __ APHA, 22nd Ed.,2012, 3500 Ca.B

-- --

9. Magnesium as Mg

APHA, 22nd Ed.,2012, 3500-Mg, B,3-84 By calculation

APHA, 22nd Ed.,2012, 3500 Mg, B,3-84 By calculation

5 - 500 mg/L

N.A.

10. Total Alkalinity IS 3025(Part 23): 1986, Reaff. 2009, Amds.2 Titration Method

IS 3025(Part 23): 1986, Reaff. 2009, Amds.2 Titration Method

0.5 -500 mg /L

51.50 ± 5.40

11. Chloride as Cl- APHA, 22nd Ed.,2012,, 4500-Cl, B,4-72 IS 3025(Part 32):1988,

APHA, 22nd Ed.,2012,, 4500-Cl, B,4-72 IS 3025(Part 32):1988,

0.15 - 250 mg/L

9.65 ± 0.82

Reaff. 2009 Argentometric Method

Reaff. 2009 Argentometric Method

12. Sulphate as SO4-2 IS 3025(Part 24): 1986,

Reaff. 2009 IS 3025(Part 24): 1986, Reaff. 2009

1 - 40 mg/L

19.66 ± 0.33

13. Nitrate as NO3 APHA, 22nd Ed.,2012 4500 NO3 -B, 4- 122 UV Spectrophotometric Screening Method.

APHA, 22nd Ed.,2012 4500 NO3 -B, 4- 122 UV Spectrophotometric Screening Method.

0.01– 10 mg/L

2.01 + 0.59

14. Fluoride as F APHA, 22nd Ed., 2012, 4500-F , D, 4 – 87 (SPADNS Spectrometer Method)

APHA, 22nd Ed., 2012, 4500-F , D, 4 – 87 (SPADNS Spectrometer Method)

0.15 – 1.4 mg/L 0.75 + 0.27

15. Sodium APHA,22nd Ed.,2012, 3500-Na, B, 3-97 Flame Photometric In emission mode Method

APHA,22nd Ed.,2012, 3500-Na, B, 3-97 Flame Photometric In emission mode Method

1.0 - 100 mg/L

30.04 ± 0.36

16. Potassium __ APHA 22n

Ed.,2012,3500 K,B -- --

17. Total Nitrogen __ APHA 22nd Ed.,2012, 4500 NH3 - B

-- --

18. Total Phosphorous

__ APHA 22nd Ed.,2012, 4500 – P , D

-- --

19. Dissolved Oxygen

__ IS 3025(Part 38)1989, (APHA 22nd Ed.,2012,4500 – O, B)

-- --

20. Bio-Chemical Oxygen

__ IS 3025(Part 44)1993 Amd .01

-- --

21. Chemical Oxygen Demand

__ IS 3025(Part 58)2006, (APHA 22nd Ed.,2012,5220 –B)

-- --

22. Phenolic Compound

__ APHA 22nd Ed.,2012, 5530 - C

0.001 --

23. Lead as Pb __ IS 3025(Part 47)1994 Amd.02, (APHA 22nd

0.01 --

Ed.,2012 3111 –B) 24. Arsenic __ APHA 22nd Ed.,2012,

3114 - C 0.01 --

25. Cadmium __ IS 3025(Part41)1992, (APHA 22nd Ed.,2012,3111 –B)

0.003 --

26. Total Coliform __ APHA 22nd Ed.,2012,9222 - B

Absent --

27. E. Coli __ IS : 15185 : 2002 Absent --

Sr. No.

Parameters Unit Test Method / Standard against which tests are performed

• Soil Quality Testing

1. Bulk Density gm/ml

Soil Analysis BY M.I Jackson Method

2. Salinity ppt

3. Porosity %

4.

Texture Class

Silt %

Clay %

Sand %

5. Ph( 5% Solution) --

6. Electrical Conductivity µs

7. Cation Exchange Capacity meq/100gm Clay

8. Sodium mg/kg

9. Potassium mg/kg

10. Nitrogen mg/kg

11. Magnesium mg/100 gm

12. Phosphorous mg/100 gm

13. SAR --

14. Water Holding Capacity ml/100 gm

15. Iron as Fe mg/lit.

16. Copper as Cu mg/lit.

17. Zinc as Zn mg/lit.

18. Manganese as Mn mg/lit.

19. Nickel as Ni mg/lit.

Annexure- VII (E)

Gujarat Industrial Development Corporation (GIDC) notified area of Vapi & Sarigam.

In study Area two GIDC Area is covered, Vapi GIDC & Sarigam GIDC. There is a cluster of

numerous large-scale, medium-scale and small-scale industries, engaged in manufacture of

variety of products, for example pharmaceuticals, dyes and chemicals, paper mills, paints,

plastics, packaging, textiles, specialilty chemicals and others in the Gujarat Industrial

Development Corporation (GIDC) notified area of Vapi & Sarigam.

The "Vapi Industrial Estate" was started by GIDC in 1967, and has spread to 11.4 km² and

houses over 1400 industries, the majority of which are small-scale units (SSIs). Today, about

70% of the total industries in the township are chemical plants, mainly for

chemical distillation and the production of pesticides, dyes, dye intermediaries and paints.

Other industries in the GIDC include paper, packaging, pharmaceuticals, plastics, rubber,

textiles, wood, computer hardware & software, engineering workshops, glass and food

products. Another striking feature of Vapi is the Common Effluent Treatment Plant (or

CETP). This is the largest of its kind in Asia, treating the pollutants from these industries. The

CETP is run by Vapi Waste & Effluent Management Company, promoted by the Vapi

Industries Association, CETP is one of the India's biggest plant in term of capacity. In study

area there is some part of the Vapi GIDC was covered

The "Sarigam Industrial Estate" was started by GIDC in 1993, and has spread to about 5.19

km².There are over 200 industries in the estate and the majority of these industries are

small-scale units (SSIs) falling in category of chemical industries. The Sarigam Industrial

estate has also develop the most important infrastructures like Common Effluent Treatment

Plant (or CETP), water supply system, internal roads, Natural gas supply and common waste

disposal facilities/TSDF.

List of Some Industries Covered in 10 Km radius of Study area.

Sr. No. Name of Industries Location

1. Pidilite Industries Limited GIDC, Vapi

2. United Phosporus Limited GIDC, Vapi

3. Arti Industries Lmited. GIDC, Vapi

4. Phthalo Colours & Chemicals (I) Ltd. GIDC, Vapi

5. Micro Inks Ltd. GIDC, Vapi

6. Bilag Indstries Pvt. Ltd. GIDC, Vapi

7. India Gelatin & Chemicals Ltd. GIDC, Vapi

8. Shah Pulp & Papers Pvt. Ltd. GIDC, Vapi

9. Amoli Organices Ltd. GIDC, Vapi

10. Richter Themis medicare India Pvt. Ltd. GIDC, Vapi

11. Sarna Chemicals GIDC, Vapi

12. Garnet Papaer Mills GIDC, Vapi

13. N. R. Papaer Mills Pvt Ltd. GIDC, Vapi

14. Zandu Parmacutecals Works Pvt. Ltd. GIDC, Vapi

15. Vapi Care Pharma Pvt Ltd. GIDC, Vapi

16. A. H. Traders Vapi

17. Asian Aerosol Pvt. Ltd. Vapi

18. Abdul Gaffar Siddick Khatri Vapi

19. Aarkay Paints Pvt. Ltd. GIDC, Vapi

20. Anjana Industries GIDC, Vapi

21. Ajanta Paints GIDC, Vapi

22. Apurva Chemicals GIDC, Vapi

23. Accra Pac (India) Pvt. Ltd. GIDC, Vapi

24. Artek Home Care Pvt. Ltd. GIDC, Vapi


25. Amee Rubber Ind. P. L. GIDC, Vapi

26. Amrit Chemical Industries Vapi

27. Balaji Engineering GIDC, Vapi

28. Bhavini Products GIDC Vapi

29. Coated Sales Co. Pvt. Ltd. Vapi

30. Crystal Polymers Vapi

31. CS Specialty Chemicals P. L. GIDC, Vapi

32. Divyalok Pharma Pvt. Ltd. GIDC, Vapi

33. D. R. Cosmetics Pvt. Ltd. GIDC, Vapi

34. Daman Ganga Paper Mills Pvt. Ltd. – 258 (Oil Division) GIDC, Vapi

35. Daman Ganga Paper Mills Pvt. Ltd. – 1 GIDC, Vapi

36. Daman Ganga Paper Mills Pvt. Ltd. – 2 GIDC, Vapi

37. D. M. Steel Suppliers GIDC, Vapi

38. Chemie Synth (Vapi) Ltd. GIDC, Vapi

39. GHCL Ltd. GIDC, Vapi

40. GHCL Ltd. II GIDC, Vapi

41. GSPC Gas Company Limited Vapi

42. Gujarat Industrial Chemicals GIDC, Vapi

43. J. B. Industries GIDC, Vapi

44. Hindustan Metal Industries GIDC, Vapi

45. Vapi Oxide Color Pvt. Ltd. GIDC, Vapi

46. Vapi Pigments 796/1 GIDC, VAPI

47. Vapi Pigments 795/2 GIDC, VAPI

48. Uniform Paints GIDC, Vapi

49. Sarvaiya Chemicals Industries Pvt. Ltd. GIDC, Vapi


50. Rachana Trading Corporation (Old) GIDC, Vapi

51. Rachana Trading Corporation (New) GIDC, Vapi

52. Rishita Fashions GIDC, Vapi

53. RVN Paper & Boards Pvt. Ltd. GIDC, Vapi

54. Resin & Allied Chemicals Industries Pvt. Ltd. GIDC, Vapi

55. Orvin Industries GIDC, Vapi

56. Padmavati Décor Pvt. Ltd. GIDC, Vapi

57. Pharma Chem Industries (Guj.) Pvt. Ltd. Vapi

58. Patil Dyestuff Industries Vapi

59. K. K. Poonja & Sons Vapi

60. L. S. Chemicals& Pharmaceuticals GIDC, Vapi

61. Jaidev Enterprises GIDC, Vapi

62. Kruti Chemicals GIDC, Vapi

63. Kataria Automóbiles Ltd. GIDC, Vapi

64. Kissan Agro Fertilizers Vapi

65. Kenson Metal Tubes Vapi

66. Khemka Glass Products Pvt. Ltd. GIDC, Vapi

67. Krishna Finechem Industries (C1-73 Herb. D.) Vapi

68. Krishna Finechem Industries (C1-74) Vapi

69. K. D. Industries GIDC, Vapi

70. Indian Scientific Glass Industries Vapi

71. Innova Industries GIDC, Vapi

72. Imperial Paint GIDC, Vapi

73. Ink-O-Coats GIDC, Vapi

74. Intech Orchem P Ltd. GIDC, Vapi


75. Sabereo Organics Gujarat. Ltd. GIDC, Sarigam

76. Swadeshi Textiles Pvt. Ltd. GIDC, Sarigam

77. Metloied Pharmaceuticals Pvt. Ltd. GIDC, Sarigam

78. Damodar Yarns Pvt. Ltd. GIDC, Sarigam

79. JBF Industries Limited. GIDC, Sarigam

80. Aarti Drugs Ltd. GIDC, Sarigam

81. Phemicar Limited. GIDC, Sarigam

82. Sutlej Textiles Industries Ltd. (Unit : DAMAN GANGA HOME TEXTILES)

GIDC, Sarigam

83. Sutlej Textiles Industries Ltd. (Unit : DAMAN GANGA GARMENTS)

GIDC, Sarigam

84. Sutlej Textiles Industries Ltd. (Unit : DAMAN GANGA FARBIC) GIDC, Sarigam

85. Sutlej Textiles Industries Ltd. (Unit: Damanganga Processors Ltd.)

GIDC, Sarigam

86. Sutlej Textiles Industries Ltd. (Power Plant)

GIDC, Sarigam

87. Arihant Rubber Industries GIDC, Sarigam

88. Artee Graphite P. L. GIDC, Sarigam

89. Ace Chemie (India) GIDC, Sarigam

90. Advance Rubber Industries GIDC, Sarigam

91. Aditya Chemicals Sarigam

92. Apar Industries Limited Khatalwada

93. A. K. Rubber Fansa, Umbergaon

94. Bhanu Metal Industries Daheli

95. Baijul Pharma Pvt. Ltd. GIDC, Sarigam

96. Balaji Industries GIDC, Sarigam

97. Citizen Umbrella Manufactures Ltd. (43/1/3) Umbergaon, Sanjan

98. Chandan Synthetics & Polymers GIDC, Sarigam

99. Costwold Architectural Products (India) Pvt. Ltd. GIDC, Sarigam


100. Dashmesh Rubber GIDC, Sarigam

101. Esjay International Pvt. Ltd. GIDC, Sarigam

102. Famy Care Ltd. GIDC, Sarigam

103. Fine Industries GIDC, Sarigam

104. Good Earth Agrochem Pvt. Ltd. GIDC, Sarigam

105. GHCL LTD. (Textile Div.) Bhilad

106. Girnar Synthetic & Polymers GIDC, Sarigam

107. Gel Poly Pack GIDC, Sarigam

108. Hindustan Chemical Corporation Sarigam

109. Hena Chem GIDC, Sarigam

110. Hi-Tech Rubber Industries GIDC, Sarigam

111. H. J. Industries GIDC, Sarigam

112. Jaksons Limited Kalsar

113. Jeet Petroleum Pvt. Ltd. Nandigam

114. J. J. Stone Quarry Sarigam

115. Jeevan Chemicals Pvt. Ltd. GIDC, Sarigam

116. Jeevan Chemicals Pvt. Ltd. GIDC, Sarigam

117. Jaiswal Scrap Traders GIDC, Sarigam

118. Juggernaut Auto Industries GIDC, Sarigam

119. Jetking Rubber Industries (Unit – I) GIDC, Sarigam

120. Jetking Rubber Industries (Unit – II) GIDC, Sarigam

121. JR Fibreglass Industries Pvt. Ltd. GIDC, Sarigam

122. J. B. Chem Industries GIDC, Sarigam

123. J. K. Rolling Mills GIDC, Sarigam

124. Konark Naturals & Phytochemicals GIDC, Sarigam


125. Keaum Organics Pvt. Ltd. GIDC, Sarigam

126. Khushi Chemicals GIDC, Sarigam

127. Kishan Industries GIDC, Sarigam

128. Khyati Industries GIDC, Sarigam

129. L. S. Chemicals & Pharmaceuticals (1018) GIDC, Sarigam

130. Lamifab Industries – 1 GIDC, Sarigam

131. L S Auxi Chem Pvt. Ltd. GIDC, Sarigam

132. Mittal Industries Sarigam

133. Madura Industrial Textiles Ltd. Sarigam By Pass Road

134. Natraj Industries Sarigam

135. Nano Inks And Coatings P. L. GIDC, Sarigam

136. Nice Pack Industries Pvt. Ltd. Valwada

137. Polysol Industries GIDC, Sarigam

138. Polysol Industries (New) GIDC Sarigam

139. Pooja Phospho Chem GIDC , Sarigam

140. Polyfil Rubber Products GIDC, Sarigam

141. Platina Oil Field Pvt. Ltd. GIDC, Sarigam

142. Pharma Chemicals Industries (Unit – I) GIDC, Sarigam

143. Pharma Chemicals Industries (Unit – II) GIDC, Sarigam

144. Pravina Pharma Chem Products GIDC, Sarigam

145. Ronak Chemicals GIDC, Sarigam

146. Ronak Chemicals (Unit – II) (Ronak Pharma) GIDC, Sarigam

147. Rushikesh Industries GIDC , Sarigam

148. Raj & Co. Daheli

149. Reliance Rubber Industries GIDC, Sarigam


150. Rishi Plast GIDC Sarigam

151. Shivam Extrusion Pvt. Ltd GIDC Sarigam

152. Shubh Synthetics GIDC, Srigam

153. Sarvaiya Chemicals Industries Pvt. Ltd. Zaroli

154. Shree Krishna Stone Quarry (Sarigam) Sarigam

155. Shreeji Paperpack Industries Sarigam

156. Shreeji Paperpack Industries Sarigam

157. Shree Ganeshwara Dye Chem GIDC, Sarigam

158. Sarigam Oxytrade P. L. GIDC, Sarigam

159. Sandhya Dyes & Chemicals GIDC, Sarigam

160. Sandhya Industrial Chemicals GIDC, Sarigam

161. Sandhya Industrial Chemicals GIDC, Sarigam

162. Sandhya Plasticizers & Chemicals GIDC, Sarigam

163. Shivam Textiles & Proofing Industries GIDC, Sarigam

164. Systematic Steel Industries Ltd. (1229-1230) GIDC, Sarigam

165. Systematic Steel Ltd. GIDC, Sarigam

166. Shah Packwell Industries Daheli

167. Shree Trikur Industries GIDC, Sarigam

168. Shri Sai Rubber Products GIDC, Sarigam

169. Shree Sai Rubber Products GIDC, Sarigam

170. Sudarshan Silicate Pvt. Ltd. GIDC, Sarigam

171. Somatic Pharma Salts GIDC, Sarigam

172. Shiv Chemical Industries GIDC, Sarigam

173. Satya Aromatic Industries GIDC, Sarigam

174. Sulfavet (I) P. L. GIDC, Sarigam


175. Sugam Health Care GIDC, Sarigam

176. Sunways Laboratories P. L. GIDC, Sarigam

177. Shivam Chemicals GIDC, Sarigam

178. Sarigam Industrial Products GIDC, Sarigam

179. Sarigam Industrial Products (Unit – II) GIDC, Sarigam

180. Shree Varah Enterprises GIDC, Sarigam

181. Shree Bhagyoday Industries GIDC, Sarigam

182. Talreja Infotech Pvt. Ltd. GIDC, Sarigam

183. Tulsi Chem industries GIDC, Sarigam

184. Unique Enterprises GIDC, Sarigam

185. Viraj Engineering GIDC Sarigam

186. Veritas Industries Pvt. Ltd. Near Sarigam

187. Western Refrigeration P. L. GIDC, Sarigam

188. Zain Tube Industries GIDC, Sarigam

ETHYLENE GLYCOL EGL

CAUTIONARY RESPONSE INFORMATION

Common Synonyms Thick liquid Colorless Odorless

Sinks and mixes with water.

1,2-Dihydroxyethane1,2-EthanediolEthylene dihydrateGlycolMonoethylene glycol

Call fire department.Notify local health and pollution control agencies.Protect water intakes.

Fire Combustible.Extinguish with dry chemical, alcohol foam, or carbon dioxide.Water may be ineffective on fire.Cool exposed containers with water.

Exposure CALL FOR MEDICAL AID.

LIQUIDIrritating to skin and eyes.If swallowed, will cause loss of consciousness.Remove contaminated clothing and shoes.Flush affected areas with plenty of water.IF IN EYES, hold eyelids open and flush with plenty of water.IF SWALLOWED and victim is CONSCIOUS, have victim drink wateror milk and have victim induce vomiting.IF SWALLOWED and victim is UNCONSCIOUS OR HAVING CON-VULSIONS, do nothing except keep victim warm.

WaterPollution

Effect of low concentrations on aquatic life is unknown.May be dangerous if it enters water intakes.Notify local health and wildlife officials.Notify operators of nearby water intakes.

1. CORRECTIVE RESPONSE ACTIONSDilute and disperseStop discharge

2. CHEMICAL DESIGNATIONS

2.1 CG Compatibility Group: 20; Alcohol,glycol

2.2 Formula: HOCH2CH2OH2.3 IMO/UN Designation: Not listed

2.4 DOT ID No.: Not listed2.5 CAS Registry No.: 107-21-12.6 NAERG Guide No.: Not listed2.7 Standard Industrial Trade Classification:

51221

3. HEALTH HAZARDS

3.1 Personal Protective Equipment: Goggles; shower and eye bath.

3.2 Symptoms Following Exposure: Inhalation of vapor is not hazardous. Ingestion causes stupor orcoma, sometimes leading to fatal kidney injury.

3.3 Treatment of Exposure: INGESTION: induce vomiting and call a physician. SKIN AND EYES: flushwith water.

3.4 TLV-TWA: Not listed.

3.5 TLV-STEL: Not listed.

3.6 TLV-Ceiling: 100 mg/m3

3.7 Toxicity by Ingestion: Grade 1; LD50 = 5 to 15 g/kg (rat, guinea pig, mouse)

3.8 Toxicity by Inhalation: Currently not available.

3.9 Chronic Toxicity: Fatal kidney injury may result if ingested.

3.10 Vapor (Gas) Irritant Characteristics: Vapors are nonirritating to the eyes and throat.

3.11 Liquid or Solid Characteristics: No appreciable hazard. Practically harmless to the skin.

3.12 Odor Threshold: Odorless

3.13 IDLH Value: Not listed.

3.14 OSHA PEL-TWA: Not listed.

3.15 OSHA PEL-STEL: Not listed.

3.16 OSHA PEL-Ceiling: Not listed.

3.17 EPA AEGL: Not listed

4. FIRE HAZARDS

4.1 Flash Point: 240°F O.C. 232°F C.C.

4.2 Flammable Limits in Air: LEL = 3.2%;UEL not listed

4.3 Fire Extinguishing Agents: Water fog,alcohol foam, carbon dioxide, or drychemical

4.4 Fire Extinguishing Agents Not to BeUsed: Water or foam may causefrothing.

4.5 Special Hazards of CombustionProducts: Not pertinent

4.6 Behavior in Fire: Not pertinent

4.7 Auto Ignition Temperature: 775°F

4.8 Electrical Hazards: Not pertinent

4.9 Burning Rate: 1.0 mm/min.

4.10 Adiabatic Flame Temperature: Currentlynot available

4.11 Stoichometric Air to Fuel Ratio: 11.9(calc.)

4.12 Flame Temperature: Currently notavailable

4.13 Combustion Molar Ratio (Reactant toProduct): 5.0 (calc.)

4.14 Minimum Oxygen Concentration forCombustion (MOCC): Not listed

5. CHEMICAL REACTIVITY

5.1 Reactivity with Water: No reaction

5.2 Reactivity with Common Materials: Noreaction

5.3 Stability During Transport: Stable

5.4 Neutralizing Agents for Acids andCaustics: Not pertinent

5.5 Polymerization: Not pertinent

5.6 Inhibitor of Polymerization: Not pertinent

6. WATER POLLUTION

6.1 Aquatic Toxicity:>100 ppm/48 hr/shrimp/LC50/salt water

6.2 Waterfowl Toxicity: Currently notavailable

6.3 Biological Oxygen Demand (BOD):12.5% (theor.), 5 days; 78% (theor.). 20days

6.4 Food Chain Concentration Potential:None

6.5 GESAMP Hazard Profile:Bioaccumulation: 0Damage to living resources: 0Human Oral hazard: 2Human Contact hazard: II

Reduction of amenities: XX

7. SHIPPING INFORMATION

7.1 Grades of Purity: Industrial grade; low-conductivity grade

7.2 Storage Temperature: Ambient

7.3 Inert Atmosphere: No requirement

7.4 Venting: Open (flame arrester)

7.5 IMO Pollution Category: D

7.6 Ship Type: Data not avaialable

7.7 Barge Hull Type: Currently not available

8. HAZARD CLASSIFICATIONS

8.1 49 CFR Category: Not listed

8.2 49 CFR Class: Not pertinent

8.3 49 CFR Package Group: Not listed.

8.4 Marine Pollutant: No

8.5 NFPA Hazard Classification:

Category ClassificationHealth Hazard (Blue).......... 1

Flammability (Red)............. 1

Instability (Yellow)............. 0

8.6 EPA Reportable Quantity: 5000 pounds

8.7 EPA Pollution Category: D

8.8 RCRA Waste Number: Not listed

8.9 EPA FWPCA List: Not listed

9. PHYSICAL & CHEMICAL

PROPERTIES

9.1 Physical State at 15° C and 1 atm: Liquid

9.2 Molecular Weight: 62.07

9.3 Boiling Point at 1 atm: 387.°F = 197.6°C =470.8°K

9.4 Freezing Point: 8.6°F = 13°C = 260°K

9.5 Critical Temperature: Not pertinent

9.6 Critical Pressure: Not pertinent

9.7 Specific Gravity: 1.115 at 20°C (liquid)

9.8 Liquid Surface Tension: Not pertinent

9.9 Liquid Water Interfacial Tension: Notpertinent

9.10 Vapor (Gas) Specific Gravity: Not pertinent

9.11 Ratio of Specific Heats of Vapor (Gas):1.095

9.12 Latent Heat of Vaporization: 344 Btu/lb =191 cal/g = 8.00 X 105 J/kg

9.13 Heat of Combustion: –7259 Btu/lb = –4033cal/g = –168.9 X 105 J/kg

9.14 Heat of Decomposition: Not pertinent

9.15 Heat of Solution: (est.) –20 Btu/lb = –12cal/g = –0.5 X 105 J/kg

9.16 Heat of Polymerization: Not pertinent

9.17 Heat of Fusion: 43.26 cal/g

9.18 Limiting Value: Currently not available

9.19 Reid Vapor Pressure: 0.008 psia

NOTES

JUNE 1999

ETHYLENE GLYCOL EGL

9.20SATURATED LIQUID DENSITY

Temperature(degrees F)

Pounds per cubic foot

405060708090

100110120130140150160170180190200210

70.12969.91069.69069.45969.20968.95968.69068.41968.12967.83067.52067.20066.87066.53066.17965.82065.44065.059

9.21LIQUID HEAT CAPACITY


British thermal unit perpound-F

20406080

100120140160180200220240260280300

0.5360.5490.5630.5760.5890.6030.6160.6290.6430.6560.6690.6830.6960.7090.723

9.22LIQUID THERMAL CONDUCTIVITY


British thermal unit inchper hour-square foot-F

7580859095

100105110115120125130135140145150155160165170175180185

1.7001.6971.6941.6911.6881.6851.6831.6801.6771.6741.6711.6681.6651.6621.6591.6561.6531.6501.6471.6441.6411.6381.635

9.23LIQUID VISCOSITY


Centipoise

NOT

PERTINENT

9.24SOLUBILITY IN WATER


Pounds per 100 poundsof water

MISCIBLE

9.25SATURATED VAPOR PRESSURE


Pounds per square inch

60708090

100110120130140150160170180190200210220230240250260270280290300

0.0010.0010.0020.0030.0050.0080.0120.0170.0260.0370.0530.0750.1060.1460.2010.2730.3690.4930.6530.8591.1201.4511.8672.3863.029

9.26SATURATED VAPOR DENSITY



60708090

100110120130140150160170180190200210220230240250260270280290300

0.000010.000010.000020.000030.000050.000080.000120.000170.000250.000350.000500.000690.000950.001300.001760.002360.003140.004130.005400.007000.009000.011500.014600.018400.02305

9.27IDEAL GAS HEAT CAPACITY



0255075

100125150175200225250275300325350375400425450475500525550575600

0.3440.3540.3640.3730.3820.3910.4000.4090.4170.4250.4330.4400.4480.4550.4620.4680.4750.4810.4870.4930.4980.5040.5090.5140.518

JUNE 1999

Chemical Name : Ethylene glycol

Synonyms: 1,2-Ethanediol, Ethane-1,2-diol, Glycol, Monoethylene glycol, Ethylene dihydrate, Zerex

Formula : C2H6O2

Toxic

1. CHEMICAL IDENTITY

Chemical Classification: Trade Name :

CAS No: 107-21-1 UN No: 3082Regulated Identification Shipping Name :Codes / Label : Hazardous Waste ID No :

Hazchem Code :Hazardous substance, liquidClass 9, Toxic 5

3Z

HAZARDOUS INGREDIENTS C.A.S. No. HAZARDOUS INGREDIENTS C.A.S. No.12

34

Ethylene glycol 107-21-1

2. PHYSICAL / CHEMICAL DATA197.3 Liquid Clear, colorless,

syrupy, liquid. -13 0.092 mm Hg @

25 degOdourless.

2.14 Miscible

1.1135 g/cu cm @ 20 deg C

Miscible with lower aliphatic alcohols, glycerol, acetic acid.

Boiling Pt. °C:

Physical State:

Vapour Pressure @ 35°C mmHg:

Appearance:

Odour:

Vapour Density(Air =1):

Solubility inwater at 30°C g/100ml:

Others:

Specific Gravity (Water =1 ): pH :

Melting Pt °C:

3. FIRE / EXPLOSION HAZARD DATAFlammability : 3.2 111

21.6TDG Flammability:LEL:UEL:

Flash Point °C in OC:Flash Point °C in CC:

Autoignition Temperature °C : 400Explosion sensitivity to impact:Explosion sensitivity to static Electricity:Hazardous Combustion Products :Hazardous Polymerization :Combustible Liquid:Flammable Material:Pyrophoric Material:

Explosive Material:Oxidiser :Organic Peroxide :

Corrosive MaterialOthers:

MATERIAL SAFETY DATA SHEETSEthylene glycol267

Stable at room temperature in closed containers under normal storage and handling conditions.Chlorosulfonic acid, dimethyl terephthalate, oleum, phosphorus pentasulfide, silvered-copper wire, sodium hydroxide, sulfuric acid, titanium butoxide. Causes ignition at room temperature with chromium trioxide, potassium permanganate, and sodium peroxide.

Chemical Stability

Incompatibility with other material

4. REACTIVITY DATA:

:

Page 1 of 3Ethylene glycol

Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.ReactivityHazardous Reaction Products5. HEALTH HAZARD DATA

Inhalation, Ingestion, Skin and Eyes

Inhalation : � May cause respiratory tract irritation. Heated or misted substance may cause headache, irregular eye movements, and possible coma.�Ingestion : �May cause nausea and vomiting. Toxicity follows 3-stage progression. (1) involves central nervous system effects including paralysis of eye muscles, convulsions, and coma. Metabolic acidosis and cerebral swelling may also occur. (2) involves cardiopulmonary system with symptoms of hypertension, rapid heart beat, and possible cardiac failure. (3) involves severe kidney abnormalities including possible renal failure.�Skin : �May cause skin irritation. Low hazard for usual industrial handling.�Eye : �May cause moderate eye irritation.�

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.

Routes of entry:Effects of Exposure / Symptoms:

Emergency Treatment :

1 1 0

LD50 (oral-rat) mg/kg:

Permissible Exposure Limit:

TLV (ACGIH) :

STEL:Odour Threshold:

Health Flammability Reactivity SpecialNFPA HazardSignals

Inhalation:

Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.

Skin:

First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital

Eyes:

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.

Ingestion:

LC50 (rat) mg/kg:

6. PREVENTIVE MEASURESWear appropriate eye protection and protective clothing to prevent skin and eye contact.Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Ground and bond containers when transferring material. Avoid contact with skin and eyes. Avoid ingestion and inhalation.

Personal ProtectiveEquipmentHandling

:

:

Precautions :

Keep away from sources of ignition. Store in a cool, dry, well-ventilated area away from incompatible substances.

Storage :

7. EMERGENCY / FIRST AID MEASURES

Fire Extinguishing MediaSpecial ProcedureUnusual Hazards

FIRE::::

::


Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Remove all sources of ignition. Provide ventilation.

First Aid Measures:

Antidotes / Dosages:

Steps To Be Taken

Waste Disposal Method:

EXPOSURE:

SPILLS :

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.

Inhalation:

Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.

Skin:

First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital

Eyes:


Ingestion:

8. ADDITIONAL INFORMATION / REFERENCES

9. MANUFACTURERS / SUPPLIERS DATA

Information contained in this material data sheet is believed to be reliable but no representation, guarantee or warranties of any kind are made as to its accuracy, suitability for a particular application or results to be obtained from them. It is up to the manufacturer/ seller to ensure that the information contained in the material safety data sheet is relevant to the product manufactured / handled or sold by him as the case may be. The Government makes no warranties expressed or implied in the respect of the adequacy of this document for any particular purpose.

NAME OF FIRM :MAILING ADDRESS :TELEPHONE / TELEX NOS :TELEGRAPHIC ADDRESS :

Contact personin Emergency :Local Bodies involved :Standard Packing :Trem Card Details / Ref :

10. DISCLAIMER

End of documentTotal No. of Pages: 3

:

OTHERS :


p. 1

2 3 0

He a lt h

Fire

Re a c t iv it y

Pe rs o n a lPro t e c t io n

2

2

0

J

Material Safety Data SheetParaformaldehyde MSDS

Section 1: Chemical Product and Company Identification

Product Name: Paraformaldehyde

Catalog Codes: SLP1627

CAS#: 30525-89-4

RTECS: RV0540000

TSCA: TSCA 8(b) inventory: Paraformaldehyde

CI#: Not available.

Synonym: Aldacide, Flo-Mor, Formagene, Paraform;Polyoxymethylene; Triformol; Trioxymethylene

Chemical Name: Paraformaldehyde

Chemical Formula: (C-H2-O)n polymer

Contact Information:

Sciencelab.com, Inc.14025 Smith Rd.Houston, Texas 77396

US Sales: 1-800-901-7247International Sales: 1-281-441-4400

Order Online: ScienceLab.com

CHEMTREC (24HR Emergency Telephone), call:1-800-424-9300

International CHEMTREC, call: 1-703-527-3887

For non-emergency assistance, call: 1-281-441-4400

Section 2: Composition and Information on Ingredients

Composition:

Name CAS # % by Weight

Paraformaldehyde 30525-89-4 100

Toxicological Data on Ingredients: Paraformaldehyde: ORAL (LD50): Acute: 800 mg/kg [Rat]. DUST (LC50): Acute: 1070mg/m 4 hours [Rat].

Section 3: Hazards Identification

Potential Acute Health Effects:Very hazardous in case of skin contact (irritant), of eye contact (irritant). Hazardous in case of skin contact (sensitizer), ofingestion, of inhalation. Slightly hazardous in case of skin contact (corrosive), of eye contact (corrosive). The amount of tissuedamage depends on length of contact. Eye contact can result in corneal damage or blindness. Skin contact can produceinflammation and blistering. Inhalation of dust will produce irritation to gastro-intestinal or respiratory tract, characterized byburning, sneezing and coughing. Severe over-exposure can produce lung damage, choking, unconsciousness or death.Inflammation of the eye is characterized by redness, watering, and itching. Skin inflammation is characterized by itching,scaling, reddening, or, occasionally, blistering.

Potential Chronic Health Effects:Slightly hazardous in case of skin contact (sensitizer). CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS:Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance

http://www.sciencelab.com/

p. 2

is toxic to mucous membranes. Repeated or prolonged exposure to the substance can produce target organs damage.Repeated exposure of the eyes to a low level of dust can produce eye irritation. Repeated skin exposure can produce localskin destruction, or dermatitis. Repeated inhalation of dust can produce varying degree of respiratory irritation or lung damage.Repeated exposure to a highly toxic material may produce general deterioration of health by an accumulation in one or manyhuman organs.

Section 4: First Aid Measures

Eye Contact:Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15minutes. Cold water may be used. Get medical attention immediately.

Skin Contact:In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothingand shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before reuse. Thoroughly cleanshoes before reuse. Get medical attention immediately.

Serious Skin Contact:Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medicalattention.

Inhalation:If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medicalattention immediately.

Serious Inhalation:Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. Ifbreathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It maybe hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious orcorrosive. Seek immediate medical attention.

Ingestion:Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconsciousperson. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar,tie, belt or waistband.

Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Flammable.

Auto-Ignition Temperature: 300°C (572°F)

Flash Points: CLOSED CUP: 70°C (158°F).

Flammable Limits: LOWER: 7% UPPER: 73%

Products of Combustion: These products are carbon oxides (CO, CO2).

Fire Hazards in Presence of Various Substances:Slightly flammable to flammable in presence of open flames and sparks, of heat. Non-flammable in presence of shocks.

Explosion Hazards in Presence of Various Substances:Risks of explosion of the product in presence of mechanical impact: Not available. Slightly explosive in presence of openflames and sparks, of heat.

Fire Fighting Media and Instructions:Flammable solid. SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray or fog. Cool containing vesselswith water jet in order to prevent pressure build-up, autoignition or explosion.

Special Remarks on Fire Hazards:

p. 3

May re-ignite after fire is extinguished. Decomposition into flammable formaldehyde gas on heating.

Special Remarks on Explosion Hazards: May explode or burn with explosive violence

Section 6: Accidental Release Measures

Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.

Large Spill:Flammable solid. Corrosive solid. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Usewater spray curtain to divert vapor drift. Use water spray to reduce vapors. Prevent entry into sewers, basements or confinedareas; dike if needed. Eliminate all ignition sources. Call for assistance on disposal.

Section 7: Handling and Storage

Precautions:Keep locked up.. Keep container dry. Keep away from heat. Keep away from sources of ignition. Ground all equipmentcontaining material. Do not ingest. Do not breathe dust. Never add water to this product. In case of insufficient ventilation,wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoidcontact with skin and eyes. Keep away from incompatibles such as oxidizing agents, reducing agents, metals, acids.

Storage:Keep container in a cool, well-ventilated area. Keep container tightly closed and sealed until ready for use. Avoid all possiblesources of ignition (spark or flame).

Section 8: Exposure Controls/Personal Protection

Engineering Controls:Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommendedexposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminantsbelow the exposure limit.

Personal Protection:Splash goggles. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or equivalent.Gloves.

Personal Protection in Case of a Large Spill:Splash goggles. Full suit. Vapor and dust respirator. Boots. Gloves. A self contained breathing apparatus should be used toavoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handlingthis product.

Exposure Limits: Not available.

Section 9: Physical and Chemical Properties

Physical state and appearance: Solid. (Amorphous solid powder .)

Odor: Formaldehyde. Pungent. (Slight.)

Taste: Not available.

Molecular Weight: (30.03)n g/mole

Color: White.

pH (1% soln/water): 6.7 [Neutral.]

Boiling Point: Not available.

p. 4

Melting Point:120 - 170 deg. C Decomposition temperature: 164°C (327.2°F)

Critical Temperature: Not available.

Specific Gravity: Density: 1.46 (Water = 1)

Vapor Pressure: Not applicable.

Vapor Density: 1.03 (Air = 1)

Volatility: 9% (w/w).

Odor Threshold: Not available.

Water/Oil Dist. Coeff.: Not available.

Ionicity (in Water): Not available.

Dispersion Properties: See solubility in water.

Solubility:Partially soluble in cold water. Insoluble in diethyl ether. Soluble in fixed alkali hydroxide solution. Insoluble in alcohol.Insoluble in most organic solvents. The higher polymers are insoluble in water. The rate at which paraformaldehyde dissolves(hydrolyzes) in water is at a minimum at pH 3-5; it increases rapidly at lower or higher pHs Solubility in water: 500 mg/l ofwater @18 deg. C

Section 10: Stability and Reactivity Data

Stability: The product is stable.

Instability Temperature: Not available.

Conditions of Instability: Heat, ignition sources (sparks, flames, friction), incompatible materials

Incompatibility with various substances: Reactive with oxidizing agents, reducing agents, metals, acids.

Corrosivity: Non-corrosive in presence of glass.

Special Remarks on Reactivity:Incompatible with liquid oxygen, isocyanates, anhydrides, metals (bronze, brass, copper, copper alloys, steel) Moisturesensitive

Special Remarks on Corrosivity: Not available.

Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Absorbed through skin. Eye contact. Inhalation. Ingestion.

Toxicity to Animals:WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oraltoxicity (LD50): 800 mg/kg [Rat]. Acute toxicity of the dust (LC50): 1070 mg/m 4 hours [Rat]. 3

Chronic Effects on Humans: Causes damage to the following organs: mucous membranes.

Other Toxic Effects on Humans:Very hazardous in case of skin contact (irritant). Hazardous in case of skin contact (sensitizer), of ingestion, of inhalation (lungcorrosive). Slightly hazardous in case of skin contact (corrosive), of eye contact (corrosive).

Special Remarks on Toxicity to Animals:Lowest Published Lethal Dose: LDL [Rabbit] - Route: skin; Dose: 10000 mg/kg.

Special Remarks on Chronic Effects on Humans:

p. 5

May affect genetic material (mutagenic). While Paraformaldehyde has not been identified as a carcinogen, it should behandled with caution since Formaldehyde (the monomer from which it is made) is a carcinogen.

Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: Causes severe skin irritation and possible burns. Eyes: Causes severe eye irritationand burns. May result in corneal injury. Inhalation: May be harmful if inhaled. May affect respiration (dyspnea), cause severeirritation of the upper respiratory tract with pain, burns, and inflammation of the lining of the nose and throat and lungs. Maycause loss of smell, and may cause pulmonary edema, bronchopneumonia. Ingestion: May be harmful if swallowed. Maycause severe digestive tract irritation with inflammation of the mouth, throat and stomach, abdominal pain, nausea, vomiting,and diarrhea. Chronic Potential Health Effects: Skin: Repeated or prolonged skin contact may cause sensitization dermatitis.Eyes: Repeated or prolonged eye contact may cause conjunctivitis. Inhalation: Repeated or prolonged inhalation may causechronic bronchitis or asthma. Ingestion: Repeated or prolonged ingestion may affect the kidneys

Section 12: Ecological Information

Ecotoxicity: Not available.

BOD5 and COD: Not available.

Products of Biodegradation:Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.

Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.

Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

DOT Classification: CLASS 4.1: Flammable solid.

Identification: : Paraformaldehyde UNNA: 2213 PG: III

Special Provisions for Transport: Not available.

Section 15: Other Regulatory Information

Federal and State Regulations:Connecticut hazardous material survey.: Paraformaldehyde Illinois toxic substances disclosure to employee act:Paraformaldehyde Illinois chemical safety act: Paraformaldehyde New York release reporting list: ParaformaldehydeRhode Island RTK hazardous substances: Paraformaldehyde Pennsylvania RTK: Paraformaldehyde MassachusettsRTK: Paraformaldehyde Massachusetts spill list: Paraformaldehyde New Jersey: Paraformaldehyde New Jersey spilllist: Paraformaldehyde Louisiana spill reporting: Paraformaldehyde California Director's list of Hazardous substances:Paraformaldehyde TSCA 8(b) inventory: Paraformaldehyde CERCLA: Hazardous substances.: Paraformaldehyde: 1000 lbs.(453.6 kg)

Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).

Other Classifications:

WHMIS (Canada):CLASS B-4: Flammable solid. CLASS D-2B: Material causing other toxic effects (TOXIC).

DSCL (EEC):

p. 6

HMIS (U.S.A.):

Health Hazard: 2

Fire Hazard: 2

Reactivity: 0

Personal Protection: j

National Fire Protection Association (U.S.A.):

Health: 3

Flammability: 2

Reactivity: 0

Specific hazard:

Protective Equipment:Gloves. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or equivalent. Wearappropriate respirator when ventilation is inadequate. Splash goggles.

Section 16: Other Information

References: Not available.

Other Special Considerations: Not available.

Created: 10/10/2005 08:44 PM

Last Updated: 06/09/2012 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, wemake no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assumeno liability resulting from its use. Users should make their own investigations to determine the suitability of the information fortheir particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or forlost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.comhas been advised of the possibility of such damages.

Material Safety Data Sheet

1. PRODUCT AND COMPANY IDENTIFICATION

Product Name Paraformaldehyde

Cat No. O4042500; T353500

Synonyms Formaldehyde polymer; Polyoxymethylene; Polyformaldehyde

Recommended Use Laboratory chemicals

2. HAZARDS IDENTIFICATION

Target Organs Eyes, Skin, Respiratory system

Potential Health Effects

Acute EffectsPrinciple Routes of Exposure

Eyes Severely irritating to eyes.

Skin Irritating to skin. May be harmful in contact with skin. May cause sensitization by skin contact.

Inhalation Harmful by inhalation. Irritating to respiratory system. May cause pulmonary edema.

Ingestion Harmful if swallowed. Ingestion may cause gastrointestinal irritation, nausea, vomiting anddiarrhea.

Chronic Effects Limited evidence of a carcinogenic effect.. Mutagenic effects have occurred in experimentalanimals..

See Section 11 for additional Toxicological information.

Aggravated Medical Conditions No information available.

_____________________________________________________________________________________________

Page 1 / 8

Revision Number 2

Flammable solid. Harmful by inhalation and if swallowed. Irritating to eyes, respiratory system and skin. Possible cancerhazard. May cause cancer based on animal data. May cause pulmonary edema. May cause sensitization by skin contact.

Creation Date 11-Oct-2010 Revision Date 01-Apr-2013

CompanyFisher ScientificOne Reagent LaneFair Lawn, NJ 07410Tel: (201) 796-7100

DANGER!

Emergency Telephone NumberCHEMTREC®, Inside the USA: 800-424-9300CHEMTREC®, Outside the USA: 001-703-527-3887

Emergency Overview

Odor pungentAppearance White Physical State Solid

_____________________________________________________________________________________________

3. COMPOSITION/INFORMATION ON INGREDIENTS

Haz/Non-haz

Component CAS-No Weight %

Paraformaldehyde 30525-89-4 >90

4. FIRST AID MEASURES

Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.Immediate medical attention is required.

Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Obtain medical attention.

Inhalation Move to fresh air. If breathing is difficult, give oxygen. Do not use mouth-to-mouth resuscitationif victim ingested or inhaled the substance; induce artificial respiration with a respiratorymedical device. Immediate medical attention is required.

Ingestion Do not induce vomiting. Call a physician or Poison Control Center immediately.

Notes to Physician Treat symptomatically.

5. FIRE-FIGHTING MEASURES

Flash Point 71°C / 159.8°F

Method - No information available.

Autoignition Temperature 300°C / 572°F

Explosion LimitsUpper 73%

Lower 7.0%

Suitable Extinguishing Media Use water spray, alcohol-resistant foam, dry chemical or carbondioxide. Cool closed containers exposed to fire with water spray.

Unsuitable Extinguishing Media No information available.

Hazardous Combustion Products No information available.

Sensitivity to mechanical impact No information available.

Sensitivity to static discharge No information available.

Specific Hazards Arising from the ChemicalFlammable. Containers may explode when heated.

Protective Equipment and Precautions for FirefightersAs in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protectivegear. Thermal decomposition can lead to release of irritating gases and vapors.

6. ACCIDENTAL RELEASE MEASURES

Personal Precautions Use personal protective equipment. Ensure adequate ventilation. Remove all sources ofignition. Avoid dust formation. Take precautionary measures against static discharges.

_____________________________________________________________________________________________

Page 2 / 8

Thermo Fisher Scientific - Paraformaldehyde

Flammability 3 Instability 0

Revision Date 01-Apr-2013

Physical hazards N/ANFPA Health 2

_____________________________________________________________________________________________

Environmental Precautions Should not be released into the environment.

Methods for Containment and CleanUp

Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Takeprecautionary measures against static discharges. Sweep up or vacuum up spillage and collectin suitable container for disposal. Avoid dust formation. Keep in suitable, closed containers fordisposal..

7. HANDLING AND STORAGE

Handling Use only under a chemical fume hood. Wear personal protective equipment. Keep away fromopen flames, hot surfaces and sources of ignition. Take precautionary measures against staticdischarges. Avoid dust formation. Do not get in eyes, on skin, or on clothing. Avoid ingestionand inhalation. Use spark-proof tools and explosion-proof equipment..

Storage Keep containers tightly closed in a dry, cool and well-ventilated place. Flammables area. Keepaway from heat and sources of ignition.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Measures Use only under a chemical fume hood. Ensure that eyewash stations and safety showers areclose to the workstation location. Use explosion-proof electrical/ventilating/lighting/equipment.

Exposure Guidelines This product does not contain any hazardous materials with occupational exposure limitsestablished by the region specific regulatory bodies.

NIOSH IDLH: Immediately Dangerous to Life or Health

Personal Protective EquipmentEye/face Protection Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's

eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.

Skin and body protection Wear appropriate protective gloves and clothing to prevent skin exposure.

Respiratory Protection Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limitsare exceeded or if irritation or other symptoms are experienced.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State Solid

Appearance White

Odor pungent

Odor Threshold No information available.

pH 3.5-5.0 10% susp.

Vapor Pressure 1.2 mmHg @ 25 °C

Vapor Density 1.03 (Air = 1.0)

Viscosity No information available.

Boiling Point/Range No information available.

Melting Point/Range 120 - 170°C / 248 - 338°F

Decomposition temperature No information available.

Flash Point 71°C / 159.8°F

Evaporation Rate No information available.

Specific Gravity 1.46

Solubility No information available.

log Pow No data available

Molecular Weight 30.03

10. STABILITY AND REACTIVITY

_____________________________________________________________________________________________

Page 3 / 8

Thermo Fisher Scientific - Paraformaldehyde Revision Date 01-Apr-2013

_____________________________________________________________________________________________

10. STABILITY AND REACTIVITYStability Stable under normal conditions.

Conditions to Avoid Incompatible products. Excess heat. Keep away from open flames,hot surfaces and sources of ignition. Avoid dust formation.

Incompatible Materials Strong oxidizing agents

Hazardous Decomposition Products Carbon monoxide (CO), Carbon dioxide (CO2)

Hazardous Polymerization Hazardous polymerization does not occur.

Hazardous Reactions None under normal processing..

11. TOXICOLOGICAL INFORMATION

Acute Toxicity

Component InformationComponent LD50 Oral LD50 Dermal LC50 Inhalation

Paraformaldehyde 800 mg/kg ( Rat ) Not listed 1070 mg/m3 ( Rat ) 4 h

Irritation Irritating to eyes, respiratory system and skin

Toxicologically SynergisticProducts

No information available.

Chronic Toxicity

Carcinogenicity There are no known carcinogenic chemicals in this product

Sensitization May cause sensitization by skin contact

Mutagenic Effects Mutagenic effects have occurred in experimental animals.

Reproductive Effects No information available.

Developmental Effects No information available.

Teratogenicity No information available.

Other Adverse Effects Carcinogenic effects have been reported in experimental animals. The toxicological propertieshave not been fully investigated.. See actual entry in RTECS for complete information.

Endocrine Disruptor Information No information available

12. ECOLOGICAL INFORMATION

Ecotoxicity

Do not empty into drains.

Persistence and Degradability Expected to be biodegradable.

Bioaccumulation/ Accumulation No information available

_____________________________________________________________________________________________

Page 4 / 8

Revision Date 01-Apr-2013Thermo Fisher Scientific - Paraformaldehyde

_____________________________________________________________________________________________

Mobility No information available

13. DISPOSAL CONSIDERATIONS

Waste Disposal Methods Chemical waste generators must determine whether a discarded chemical is classified as ahazardous waste. Chemical waste generators must also consult local, regional, and nationalhazardous waste regulations to ensure complete and accurate classification.

14. TRANSPORT INFORMATION

DOT

UN-No UN2213

Proper Shipping Name PARAFORMALDEHYDE

Hazard Class 4.1

Packing Group III

TDG

UN-No UN2213


Hazard Class 4.1

Packing Group III

IATA

UN-No 2213


Hazard Class 4.1

Packing Group III

IMDG/IMO

UN-No 2213


Hazard Class 4.1

Packing Group III

15. REGULATORY INFORMATION

International Inventories

Component TSCA DSL NDSL EINECS ELINCS NLP PICCS ENCS AICS CHINA KECL

Paraformaldehyde XU X - - - X X X X X

Legend:X - ListedE - Indicates a substance that is the subject of a Section 5(e) Consent order under TSCA.F - Indicates a substance that is the subject of a Section 5(f) Rule under TSCA.N - Indicates a polymeric substance containing no free-radical initiator in its inventory name but is considered to cover the designatedpolymer made with any free-radical initiator regardless of the amount used.P - Indicates a commenced PMN substanceR - Indicates a substance that is the subject of a Section 6 risk management rule under TSCA.

_____________________________________________________________________________________________

Page 5 / 8


_____________________________________________________________________________________________

S - Indicates a substance that is identified in a proposed or final Significant New Use RuleT - Indicates a substance that is the subject of a Section 4 test rule under TSCA.XU - Indicates a substance exempt from reporting under the Inventory Update Rule, i.e. Partial Updating of the TSCA Inventory Data BaseProduction and Site Reports (40 CFR 710(B).Y1 - Indicates an exempt polymer that has a number-average molecular weight of 1,000 or greater.Y2 - Indicates an exempt polymer that is a polyester and is made only from reactants included in a specified list of low concern reactants thatcomprises one of the eligibility criteria for the exemption rule.

U.S. Federal Regulations

TSCA 12(b) Not applicable

SARA 313Not applicable

SARA 311/312 Hazardous CategorizationAcute Health Hazard Yes

Chronic Health Hazard No

Fire Hazard Yes

Sudden Release of Pressure Hazard No

Reactive Hazard No

Clean Water Act

Component CWA - HazardousSubstances

CWA - ReportableQuantities

CWA - Toxic Pollutants CWA - Priority Pollutants

Paraformaldehyde X 1000 lb - -

Clean Air ActNot applicable

OSHANot applicable

CERCLAThis material, as supplied, contains one or more substances regulated as a hazardous substance under the ComprehensiveEnvironmental Response Compensation and Liability Act (CERCLA) (40 CFR 302)

Component Hazardous Substances RQs CERCLA EHS RQs

Paraformaldehyde 1000 lb -

California Proposition 65This product does not contain any Proposition 65 chemicals.

State Right-to-Know

Component Massachusetts New Jersey Pennsylvania Illinois Rhode Island

Paraformaldehyde X X X - X

U.S. Department of TransportationReportable Quantity (RQ): NDOT Marine Pollutant NDOT Severe Marine Pollutant N

U.S. Department of Homeland SecurityThis product does not contain any DHS chemicals.

Other International Regulations

_____________________________________________________________________________________________

Page 6 / 8


_____________________________________________________________________________________________

Mexico - Grade No information available

Canada

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and theMSDS contains all the information required by the CPR.

WHMIS Hazard ClassB4 Flammable solidD1B Toxic materialsD2A Very toxic materialsD2B Toxic materials

16. OTHER INFORMATION

Prepared By Regulatory AffairsThermo Fisher ScientificEmail: [email protected]

Creation Date 11-Oct-2010

Print Date 01-Apr-2013

Revision Summary "***", and red text indicates revision

DisclaimerThe information provided on this Safety Data Sheet is correct to the best of our knowledge, information and belief at the dateof its publication. The information given is designed only as a guide for safe handling, use, processing, storage,transportation, disposal and release and is not to be considered as a warranty or quality specification. The informationrelates only to the specific material designated and may not be valid for such material used in combination with any othermaterial or in any process, unless specified in the text.

End of MSDS

_____________________________________________________________________________________________

Page 7 / 8


_____________________________________________________________________________________________

_____________________________________________________________________________________________

Page 8 / 8


p. 1

1 3 2

He a lt h

Fire

Re a c t iv it y

Pe rs o n a lPro t e c t io n

3

1

2

H

Material Safety Data SheetTolylene-2,4-diisocyanate MSDS

Section 1: Chemical Product and Company Identification

Product Name: Tolylene-2,4-diisocyanate

Catalog Codes: SLT1264

CAS#: 584-84-9

RTECS: CZ6300000

TSCA: TSCA 8(b) inventory: Tolylene-2,4-diisocyanate

CI#: Not available.

Synonym: Toluene-2,4-diisocyanate

Chemical Formula: C9H6N2O2

Contact Information:

Sciencelab.com, Inc.14025 Smith Rd.Houston, Texas 77396

US Sales: 1-800-901-7247International Sales: 1-281-441-4400

Order Online: ScienceLab.com

CHEMTREC (24HR Emergency Telephone), call:1-800-424-9300

International CHEMTREC, call: 1-703-527-3887

For non-emergency assistance, call: 1-281-441-4400

Section 2: Composition and Information on Ingredients

Composition:

Name CAS # % byWeight

Tolylene-2,4-diisocyanate 584-84-9 100

Toxicological Data on Ingredients: Tolylene-2,4-diisocyanate: ORAL (LD50): Acute: 5800 mg/kg [Rat]. VAPOR (LC50):Acute: 14 ppm 4 hour(s) [Rat]. 10 ppm 4 hour(s) [Mouse].

Section 3: Hazards Identification

Potential Acute Health Effects:Extremely hazardous in case of ingestion. Very hazardous in case of skin contact (irritant), of eye contact (irritant), ofinhalation. Hazardous in case of skin contact (permeator). Slightly hazardous in case of skin contact (corrosive). Severe over-exposure can result in death. Inflammation of the eye is characterized by redness, watering, and itching. Skin inflammation ischaracterized by itching, scaling, reddening, or, occasionally, blistering.

Potential Chronic Health Effects:CARCINOGENIC EFFECTS: Classified 2 (Reasonably anticipated.) by NTP. MUTAGENIC EFFECTS: Not available.TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance is toxic to lungs, thenervous system, liver, mucous membranes. Repeated or prolonged exposure to the substance can produce target organsdamage. Repeated exposure to an highly toxic material may produce general deterioration of health by an accumulation in oneor many human organs.

http://www.sciencelab.com/

p. 2

Section 4: First Aid Measures

Eye Contact: Check for and remove any contact lenses. Do not use an eye ointment. Seek medical attention.

Skin Contact:After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin with runningwater and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Cover the irritated skin with anemollient. If irritation persists, seek medical attention. Wash contaminated clothing before reusing.

Serious Skin Contact:Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medicalattention.

Inhalation: Allow the victim to rest in a well ventilated area. Seek immediate medical attention.

Serious Inhalation:Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. Ifbreathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It maybe hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious orcorrosive. Seek immediate medical attention.

Ingestion:Do not induce vomiting. Examine the lips and mouth to ascertain whether the tissues are damaged, a possible indication thatthe toxic material was ingested; the absence of such signs, however, is not conclusive. Loosen tight clothing such as a collar,tie, belt or waistband. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention.

Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: May be combustible at high temperature.

Auto-Ignition Temperature: 620°C (1148°F)

Flash Points: CLOSED CUP: 127°C (260.6°F). OPEN CUP: 135°C (275°F).

Flammable Limits: LOWER: 0.9% UPPER: 9.5%

Products of Combustion: These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...).

Fire Hazards in Presence of Various Substances: Slightly flammable to flammable in presence of oxidizing materials.

Explosion Hazards in Presence of Various Substances:Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product inpresence of static discharge: Not available. Slightly explosive to explosive in presence of oxidizing materials.

Fire Fighting Media and Instructions:SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet.

Special Remarks on Fire Hazards: Not available.

Special Remarks on Explosion Hazards: Not available.

Section 6: Accidental Release Measures

Small Spill: Absorb with an inert material and put the spilled material in an appropriate waste disposal.

Large Spill:If the product is in its solid form: Use a shovel to put the material into a convenient waste disposal container. If the product isin its liquid form: Absorb with an inert material and put the spilled material in an appropriate waste disposal. Be careful that theproduct is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities.

p. 3

Section 7: Handling and Storage

Precautions:Keep locked up Keep container dry. Keep away from heat. Keep away from sources of ignition. Empty containers pose a firerisk, evaporate the residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not breathe gas/fumes/ vapour/spray. Never add water to this product In case of insufficient ventilation, wear suitable respiratory equipment Ifingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes Keep awayfrom incompatibles such as moisture.

Storage:Keep container dry. Keep in a cool place. Ground all equipment containing material. Keep container tightly closed. Keep in acool, well-ventilated place. Highly toxic or infectious materials should be stored in a separate locked safety storage cabinet orroom.

Section 8: Exposure Controls/Personal Protection

Engineering Controls:Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respectivethreshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location.

Personal Protection:Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.

Personal Protection in Case of a Large Spill:Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoidinhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling thisproduct.

Exposure Limits:TWA: 0.02 (ppm) TWA: 0.14 (mg/m3) Consult local authorities for acceptable exposure limits.

Section 9: Physical and Chemical Properties

Physical state and appearance: Liquid.

Odor: Not available.

Taste: Not available.

Molecular Weight: 174.16 g/mole

Color: Colorless to light yellow.

pH (1% soln/water): Not applicable.

Boiling Point: 251°C (483.8°F)

Melting Point: 19.4°C (66.9°F)

Critical Temperature: Not available.

Specific Gravity: 1.2244 (Water = 1)

Vapor Pressure: 0.01 mm of Hg (@ 20°C)

Vapor Density: 6 (Air = 1)

Volatility: Not available.

Odor Threshold: 0.449 ppm

Water/Oil Dist. Coeff.: Not available.

Ionicity (in Water): Not available.

p. 4

Dispersion Properties: Not available.

Solubility: Insoluble in cold water.

Section 10: Stability and Reactivity Data

Stability: The product is stable.

Instability Temperature: Not available.

Conditions of Instability: Not available.

Incompatibility with various substances: Highly reactive with moisture.

Corrosivity: Non-corrosive in presence of glass.

Special Remarks on Reactivity: Not available.

Special Remarks on Corrosivity: Not available.

Polymerization: Yes.

Section 11: Toxicological Information

Routes of Entry: Dermal contact. Eye contact. Inhalation. Ingestion.

Toxicity to Animals:WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oraltoxicity (LD50): 5800 mg/kg [Rat]. Acute toxicity of the vapor (LC50): 10 ppm 4 hour(s) [Mouse].

Chronic Effects on Humans:CARCINOGENIC EFFECTS: Classified 2 (Reasonably anticipated.) by NTP. The substance is toxic to lungs, the nervoussystem, liver, mucous membranes.

Other Toxic Effects on Humans:Extremely hazardous in case of ingestion. Very hazardous in case of skin contact (irritant), of inhalation. Hazardous in case ofskin contact (permeator). Slightly hazardous in case of skin contact (corrosive).

Special Remarks on Toxicity to Animals: Not available.

Special Remarks on Chronic Effects on Humans: Not available.

Special Remarks on other Toxic Effects on Humans: Not available.

Section 12: Ecological Information

Ecotoxicity: Not available.

BOD5 and COD: Not available.

Products of Biodegradation:Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.

Toxicity of the Products of Biodegradation: The products of degradation are more toxic.

Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:

p. 5

Section 14: Transport Information

DOT Classification: CLASS 6.1: Poisonous material.

Identification: : Toluene diisocyanate : UN2078 PG: II

Special Provisions for Transport: Not available.

Section 15: Other Regulatory Information

Federal and State Regulations:California prop. 65: This product contains the following ingredients for which the State of California has found to causecancer, birth defects or other reproductive harm, which would require a warning under the statute: Tolylene-2,4-diisocyanateCalifornia prop. 65: This product contains the following ingredients for which the State of California has found to cause cancerwhich would require a warning under the statute: Tolylene-2,4-diisocyanate Pennsylvania RTK: Tolylene-2,4-diisocyanateMassachusetts RTK: Tolylene-2,4-diisocyanate TSCA 8(b) inventory: Tolylene-2,4-diisocyanate SARA 302/304/311/312extremely hazardous substances: Tolylene-2,4-diisocyanate SARA 313 toxic chemical notification and release reporting:Tolylene-2,4-diisocyanate CERCLA: Hazardous substances.: Tolylene-2,4-diisocyanate

Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).

Other Classifications:

WHMIS (Canada):CLASS D-1A: Material causing immediate and serious toxic effects (VERY TOXIC). CLASS D-2A: Material causing other toxiceffects (VERY TOXIC).

DSCL (EEC):R26- Very toxic by inhalation. R38- Irritating to skin. R41- Risk of serious damage to eyes. R45- May cause cancer.

HMIS (U.S.A.):

Health Hazard: 3

Fire Hazard: 1

Reactivity: 2

Personal Protection: h

National Fire Protection Association (U.S.A.):

Health: 3

Flammability: 1

Reactivity: 2

Specific hazard:

Protective Equipment:Gloves. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respiratorwhen ventilation is inadequate. Splash goggles.

Section 16: Other Information

References: Not available.

Other Special Considerations: Not available.

Created: 10/10/2005 12:06 AM

Last Updated: 06/09/2012 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, wemake no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume

p. 6

no liability resulting from its use. Users should make their own investigations to determine the suitability of the information fortheir particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or forlost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.comhas been advised of the possibility of such damages.

of 7

MATERIAL SAFETY DATA SHEETParaformaldehyde

Section 01 - Chemical And Product And Company Information

Product Identifier …………………….... Paraformaldehyde

Product Use …………………………...... Fungicides, bactericides, disinfectant, adhesives, hardener, waterproofing agent for gelatins.

Supplier Name……………………….….. ClearTech Industries Inc.2302 Hanselman AvenueSaskatoon, SK. Canada S7L 5Z3

Prepared By................……………..…... ClearTech Industries Inc. Technical Department Phone: (306)664-2522

Preparation Date.........…………….….... May 19, 2010

24-Hour Emergency Phone………….... 306-664-2522

Section 02 - Composition / Information on Ingredients

Hazardous Ingredients....…………..... ParaformaldehydeFormaldehyde

<= 100%off-gas(paraformaldehyde will off-gas formaldehyde)

CAS Number...................…….……......ParaformaldehydeFormaldehyde

30525-89-450-00-0

Synonym (s)...................……………....Granuform, paraformaldehyde n-powder, paraformaldehyde n-granules, polyoxymethylene, polyoxymethylene glycols, paraform polyoxymethylene

of 7

Section 03 - Hazard Identification

Inhalation...................………….…..... May cause irritation to nose, throat, lungs and airways. May cause an allergic reaction involving narrowing of air passages of the lungs in some sensitive individuals. May also cause lung edema (fluid buildup in lungs). Onset of symptoms may be delayed.

Skin Contact / Absorption…….….... May cause severe skin irritation including redness, burning, drying of skin and cracking of skin. Passage into body through the skin is possible but unlikely that any harmful effects would occur during safe handling and use.

Eye Contact................………….…..... Causes severe eye irritation and/or damage including stinging, tearing, redness and swelling.

Ingestion.....................……………….. Causes severe irritation and inflammation of the gastrointestinal tract.Severe stomach pains follow with possible loss of consciousness.

Exposure Limits…………………….... This material decomposes readily to form formaldehyde. Formaldehydehas the following guidelines:

ACGIH/TLV: 0.3ppmOSHA/PEL: 0.75ppm TWA, 2ppm STEL

Section 04 - First Aid Measures

Inhalation....................………………... Remove victim to fresh air. Give artificial respiration only if breathing has stopped. If breathing is difficult, give oxygen. Seek immediate medical attention.

Skin Contact / Absorption…………... Remove contaminated clothing. Wash affected area with water. Seek medical attention if irritation occurs or persists.

Eye Contact..................……………..... Flush immediately with water for at least 20 minutes. Forcibly hold eyelids apart to ensure complete irrigation of eye tissue. Seek immediate medical attention.

Ingestion......................……………….. If individual is drowsy or unconscious, do not give anything by mouth. Place individual on their left side with head down. Only induce vomitting after consultation with a physician, medical facility or poison control center. Seek immediate medical attention.

Additional Information.....………….... Note to physician: observe for latent pulmonary edema.

Section 05 - Fire Fighting

Conditions of Flammability………..... Flammable solid.

of 7

Means of Extinction........…………...... Dry chemical, foam carbon dioxide

Flash Point....…………………………... 70°C (Tag closed cup)

Auto-ignition Temperature………….. 300°C

Upper Flammable Limit ……………... 73%

Lower Flammable Limit...……….….... 7%

Hazardous Combustible Products.... May form formaldehyde, carbon monoxide, carbon monoxide, hydrocarbons.

Special Fire Fighting Procedures...... Wear NIOSH-approved self-contained breathing apparatus and protective clothing.

Explosion Hazards…………………..... May form explosive organic dust clouds.

Section 06 - Accidental Release Measures

Leak / Spill................….…………….... Wear appropriate personal protective equipment. Ventilate area. Eliminate all ignition sources. Stop spill at source and prevent material from entering drains, sewers, stream and other bodies of water. Scoop spilled material into clean containers for recovery. Contaminated material should be transferred into a container for future disposal.

Deactivating Materials...……….….... Spills can be neutralized with ammonium hydroxide or sodium sulphite.

Section 07 - Handling and Storage

Handling Procedures.......………….... Use proper equipment for lifting and transporting all containers. Use sensible industrial hygiene and housekeeping practices. Wash thoroughly after handling. Avoid all situations that could lead to harmful exposure. Use protective equipment when opening containers as product will decompose to formaldehyde.

Storage Requirements......……...…... Store in a cool, dry, well-ventilated place and away from sources ofignition and imcompatible materials. Avoid storage in direct sunlight. Material decomposes to formaldehyde depending on time and temperature.

of 7

Section 08 - Personal Protection and Exposure Controls

Protective EquipmentEyes.………………………….……….... Chemical goggles, full-face shield, or a full-face respirator is to be worn at

all times when product is handled. Contact lenses should not be worn; they may contribute to severe eye injury.

Respiratory…………………………...... Use full-face NIOSH approved formaldehyde or acid gas cartridge or canister respirator with particulate filter within the limitations of these devices. Use self-contained breathing apparatus in all other situations.

Gloves………………………………...... Impervious gloves of chemically resistant material (neoprene or rubber) should be worn at all times. Wash contaminated clothing and dry thoroughly before reuse.

Clothing………………………..……..... Body suits, aprons, and/or coveralls of chemical resistant material should be worn at all times. Wash contaminated clothing and dry thoroughly before reuse.

Footwear……………………………...... Impervious boots of chemically resistant material should be worn.

Engineering Controls

Ventilation Requirements………....... Mechanical ventilation (local exhaust) is preferred to control exposure and process conditions. Supply sufficient replacement air to make up for air removed by exhaust systems.

Other…………………………………..... Emergency shower and eyewash should be in close proximity.

Section 09 - Physical and Chemical Properties

Physical State.......……....…………..... Solid

Odor and Appearance…..…………..... White, free flowing prill with a pungent odour.

Odor Threshold....……………............. Not available

Specific Gravity (Water=1)…………... Not available

Vapor Pressure (mm Hg, 20oC)….…. Not available

Vapor Density (Air=1)..……………...... 1.03 (formaldehyde)

Evaporation Rate........……..…….…... Not available

Boiling Point...............………….…...... Releases formaldehyde gas when heated.

of 7

Freeze/Melting Point....……………..... Not available

pH............................……………….…... 5.0 (+/- 1.51)

Water/Oil Distribution Coefficient..... Not available

Bulk Density..............…………….….... Not available

% Volatiles by Volume………..…….... Not available

Solubility in Water...………………...... Dispersible in water

Molecular Formula......………….…..... Not available

Molecular Weight........……………...... Not available

Section 10 - Stability and Reactivity

Stability.................…………....…………….. Stable under normal conditions. This product decomposes on contactwith water or moist air to formaldehyde.

Incompatibility..............…………..………... Alkali metals, alkalis, amines, isocyanates, nitorgen oxides, strong mineral acids, oxidizers. Product decomposes upon contact with water.

Hazardous Products of Decomposition... Decomposition products can include formaldehyde, carbonmonoxide, hydrocarbons and hydrogen.

Polymerization...........…………….…….….. Will not occur.

Section 11 - Toxicological Information

Irritancy.................……..………….….. Highly irritating

Sensitization........…….......…………... Repeated exposure can cause sensitization on skin and respiratory tract.

Chronic/Acute Effects……...………... Prolonged exposure to skin may cause skin burns, blistering, scaling and dryness. Medical conditions which may be aggravated by exposure to this product include conjunctivitis of the eye, dermatitis of the skin, asthma andrespiratory diseases.

Synergistic Materials...……....…….... Not available

of 7

Animal Toxicity Data......…..……….... Paraformaldehyde:

LD50(oral,rat): 800mg/kgLD50(dermal,rabbit): 10,000mg/kgLC50(rat, 4 hour): 1070mg/m3

Formaldehyde:

LD50(oral,rat): 100mg/kgLD50(dermal,rabbit): 270mg/kg88LC50(rat, 2 hour): 203mg/m3

Carcinogenicity......……......……….... Formaldehyde is listed as a carcinogen by NTP, IARC and OSHA.

Reproductive Toxicity..…...……….... No data available for assessing any hazards to fetus from maternal exposure to material.

Teratogenicity..........….....………….... Not available

Mutagenicity...........…….....………….. Not available

Section 12 - Ecological Information

Fish Toxicity..................…………….... Product is toxic to fish and wildlife.

Biodegradability.............……….…..... Paraformaldehyde breaks down in water to form formaldehyde.

Environmental Effects……………….. Not available

Section 13 - Disposal Consideration

Waste Disposal...........…...…………... Dispose in accordance with all federal, provincial, and/or local regulations including the Canadian Environmental Protection Act.

Section 14 - Transportation Information

TDG Classification

Class……………..………………..…..... 4.1

Group...............…………….......…….... III

PIN Number.................……..………..... UN 2213

of 7

Other…………………………………...... Secure containers (full and/or empty) with suitable hold down devises during shipment.

Section 15 - Regulatory Information

WHMIS Classification.......…………....B, D1, D2

NOTE: THE PRODUCT LISTED ON THIS MSDS HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF THE CANADIAN CONTROLLED PRODUCTS REGULATIONS. THIS MSDS CONTAINS ALL INFORMATION REQUIRED BY THOSE REGULATIONS.

Section 16 - Other Information

Note: The responsibility to provide a safe workplace remains with the user. The user should consider the health hazards and safety information contained herein as a guide and should take those precautions required in an individual operation to instruct employees and develop work practice procedures for a safe work environment. The information contained herein is, to the best of our knowledge and belief, accurate. However, since the conditions of handling and use are beyond our control, we make no guarantee of results, and assume no liability for damages incurred by the use of this material. It is the responsibility of the user to comply with all applicable laws and regulations.

Attention: Receiver of the chemical goods / MSDS coordinator

As part of our commitment to the Canadian Association of Chemical Distributors (CACD) Responsible Distribution®

initiative, ClearTech Industries Inc. and its associated companies require, as a condition of sale, that you forward the attached Material Safety Data Sheet(s) to all affected employees, customers, and end-users. ClearTech will send any available supplementary handling, health, and safety information to you at your request.

If you have any questions or concerns please call our customer service or technical service department.

ClearTech Industries Inc. - Locations

Corporate Head Office: 2302 Hanselman Avenue, Saskatoon, SK, S7L 5Z3Phone: 306-664-2522

Fax: 306-665-6216

www.ClearTech.ca

Location Address Postal Code Phone Number Fax NumberRichmond, B.C. 12431 Horseshoe Way V7A 4X6 604-272-4000 604-272-4596

Calgary, AB. 5516E - 40th St. S.E. T2C 2A1 403-279-1096 403-236-0989Edmonton, AB. 11750 - 180th Street T5S 1N7 780-452-6000 780-452-4600Saskatoon, SK. 2302 Hanselman Avenue S7L 5Z3 306-933-0177 306-933-3282

Regina, SK. 555 Henderson Drive S42 5X2 306-721-7737 306-721-8611Winnipeg, MB. 340 Saulteaux Crescent R3J 3T2 204-987-9777 204-987-9770

Mississauga, ON. 7480 Bath Road L4T 1L2 905-612-0566 905-612-0575

24 Hour Emergency Number - All Locations - 306-664-2522

http://www.ClearTech.ca/

PARAFORMALDEHYDE PFA


Common Synonyms Solid powder White Irritating odor


Formaldehyde polymerPolyformaldehydePolyoxymethylenePolyoxymethylene glycol

Keep people away.Avoid contact with solid, dust and vapor.Call fire department.Notify local health and pollution control agencies.Protect water intakes.

Fire Combustible.Wear goggles and self-contained breathing apparatus.Extinguish with water, foam, dry chemical or carbon dioxide.

Exposure CALL FOR MEDICAL AID.DUSTIrritating to eyes, nose and throat.Harmful if inhaled.Move to fresh air.If breathing has stopped, give artificial respiration.If breathing is difficult, give oxygen.

SOLIDIrritating to skin and eyes.If swallowed, will cause nausea, vomiting or loss of consciousness.Remove contaminated clothing and shoes.Flush affected areas with plenty of water.IF IN EYES, hold eyelids open and flush with plenty of water.IF SWALLOWED and victim is CONSCIOUS, have victim drink wateror milk.

WaterPollution

HARMFUL TO AQUATIC LIFE IN VERY LOW CONCENTRATIONS.May be dangerous if it enters water intakes.Notify local health and wildlife officials.Notify operators of nearby water intakes.

1. CORRECTIVE RESPONSE ACTIONSDilute and disperseStop dischargeCollection Systems: Dredge


2.1 CG Compatibility Group: Not listed.

2.2 Formula: HO(CH2O)nH2.3 IMO/UN Designation: 9.0/22132.4 DOT ID No.: 22132.5 CAS Registry No.: 30525-89-42.6 NAERG Guide No.: 133

2.7 Standard Industrial Trade Classification:51622

3. HEALTH HAZARDS

3.1 Personal Protective Equipment: Goggles or face shield; protective clothing.

3.2 Symptoms Following Exposure: Vapor or dust irritates eyes, mucous membranes, and skin; maycause dermatitis. Ingestion of solid or of a solution in water irritates mouth, throat, and stomachand may cause death.

3.3 Treatment of Exposure: INGESTION: give milk or white of egg beaten with water; call a doctor.SKIN OR EYES: rinse with copious amounts of water.



3.6 TLV-Ceiling: Not listed.

3.7 Toxicity by Ingestion: Grade 3; LD50 = 50 to 500 mg/kg


3.9 Chronic Toxicity: Currently not available

3.10 Vapor (Gas) Irritant Characteristics: Vapor is moderately irritating such that personnel will not usuallytolerate moderate or high vapor concentrations.

3.11 Liquid or Solid Characteristics: Minimum hazard. If spilled on clothing and allowed to remain, maycause smarting and reddening of the skin.

3.12 Odor Threshold: Currently not available






4. FIRE HAZARDS

4.1 Flash Point: 199°F (approx.) O.C.; 160°F (approx.)

C.C.

4.2 Flammable Limits in Air: (formaldehydegas) 7.0%-73.0%

4.3 Fire Extinguishing Agents: Water, foam,dry chemical, or carbon dioxide

4.4 Fire Extinguishing Agents Not to BeUsed: Currently not available


4.6 Behavior in Fire: Changes toformaldehyde gas, which is highlyflammable.

4.7 Auto Ignition Temperature: 572°F(approx.)


4.9 Burning Rate: Not pertinent


4.11 Stoichometric Air to Fuel Ratio: Notpertinent.


4.13 Combustion Molar Ratio (Reactant toProduct): Not pertinent.



5.1 Reactivity with Water: Forms watersolution of formaldehyde.


5.3 Stability During Transport: Slowlydecomposes to formaldehyde gas.




6. WATER POLLUTION

6.1 Aquatic Toxicity:32 ppm/24 hr/catfish/TLm/fresh water100-300 ppm/48 hr/flounder/TLm/salt

water


6.3 Biological Oxygen Demand (BOD): 37%,5 days; (theor.) 47%, 5 days


6.5 GESAMP Hazard Profile: Not listed


7.1 Grades of Purity: 91-99%, powder and flake




7.5 IMO Pollution Category: Currently not available

7.6 Ship Type: Currently not available



8.1 49 CFR Category: Flammable solid

8.2 49 CFR Class: 4.1

8.3 49 CFR Package Group: III






8.6 EPA Reportable Quantity: 1,000 pounds.

8.7 EPA Pollution Category: C


8.9 EPA FWPCA List: Yes


PROPERTIES

9.1 Physical State at 15° C and 1 atm: Solid

9.2 Molecular Weight: 600 (approx.)

9.3 Boiling Point at 1 atm: Decomposes

9.4 Freezing Point: 311–342°F = 155–172°C =428–445°K



9.7 Specific Gravity: 1.46 at 15°C (solid)




9.11 Ratio of Specific Heats of Vapor (Gas):Not pertinent

9.12 Latent Heat of Vaporization: Not pertinent



9.15 Heat of Solution: –150 Btu/lb = –83.5 cal/g= –3.50 X 105 J/kg


9.17 Heat of Fusion: Currently not available


9.19 Reid Vapor Pressure: Currently notavailable

NOTES

JUNE 1999





NOT

PERTINENT




NOT

PERTINENT




NOT

PERTINENT



Centipoise

NOT

PERTINENT




INSOLUBLE

UNLESS

HOT




NOT

PERTINENT




NOT

PERTINENT




NOT

PERTINENT

JUNE 1999



Common Synonyms Solid powder White Irritating odor


Formaldehyde polymerPolyformaldehydePolyoxymethylenePolyoxymethylene glycol

Keep people away.Avoid contact with solid, dust and vapor.Call fire department.Notify local health and pollution control agencies.Protect water intakes.

Fire Combustible.Wear goggles and self-contained breathing apparatus.Extinguish with water, foam, dry chemical or carbon dioxide.

Exposure CALL FOR MEDICAL AID.DUSTIrritating to eyes, nose and throat.Harmful if inhaled.Move to fresh air.If breathing has stopped, give artificial respiration.If breathing is difficult, give oxygen.

SOLIDIrritating to skin and eyes.If swallowed, will cause nausea, vomiting or loss of consciousness.Remove contaminated clothing and shoes.Flush affected areas with plenty of water.IF IN EYES, hold eyelids open and flush with plenty of water.IF SWALLOWED and victim is CONSCIOUS, have victim drink wateror milk.

WaterPollution




2.1 CG Compatibility Group: Not listed.

2.2 Formula: HO(CH2O)nH2.3 IMO/UN Designation: 9.0/22132.4 DOT ID No.: 22132.5 CAS Registry No.: 30525-89-42.6 NAERG Guide No.: 133

2.7 Standard Industrial Trade Classification:51622

3. HEALTH HAZARDS

3.1 Personal Protective Equipment: Goggles or face shield; protective clothing.

3.2 Symptoms Following Exposure: Vapor or dust irritates eyes, mucous membranes, and skin; maycause dermatitis. Ingestion of solid or of a solution in water irritates mouth, throat, and stomachand may cause death.

3.3 Treatment of Exposure: INGESTION: give milk or white of egg beaten with water; call a doctor.SKIN OR EYES: rinse with copious amounts of water.




3.7 Toxicity by Ingestion: Grade 3; LD50 = 50 to 500 mg/kg




3.11 Liquid or Solid Characteristics: Minimum hazard. If spilled on clothing and allowed to remain, maycause smarting and reddening of the skin.







4. FIRE HAZARDS

4.1 Flash Point: 199°F (approx.) O.C.; 160°F (approx.)

C.C.

4.2 Flammable Limits in Air: (formaldehydegas) 7.0%-73.0%

4.3 Fire Extinguishing Agents: Water, foam,dry chemical, or carbon dioxide

4.4 Fire Extinguishing Agents Not to BeUsed: Currently not available


4.6 Behavior in Fire: Changes toformaldehyde gas, which is highlyflammable.

4.7 Auto Ignition Temperature: 572°F(approx.)


4.9 Burning Rate: Not pertinent







5.1 Reactivity with Water: Forms watersolution of formaldehyde.


5.3 Stability During Transport: Slowlydecomposes to formaldehyde gas.




6. WATER POLLUTION

6.1 Aquatic Toxicity:32 ppm/24 hr/catfish/TLm/fresh water100-300 ppm/48 hr/flounder/TLm/salt

water


6.3 Biological Oxygen Demand (BOD): 37%,5 days; (theor.) 47%, 5 days


6.5 GESAMP Hazard Profile: Not listed


7.1 Grades of Purity: 91-99%, powder and flake








8.1 49 CFR Category: Flammable solid

8.2 49 CFR Class: 4.1







8.6 EPA Reportable Quantity: 1,000 pounds.





PROPERTIES



9.3 Boiling Point at 1 atm: Decomposes

9.4 Freezing Point: 311–342°F = 155–172°C =428–445°K
















NOTES

JUNE 1999





NOT

PERTINENT




NOT

PERTINENT




NOT

PERTINENT



Centipoise

NOT

PERTINENT




INSOLUBLE

UNLESS

HOT




NOT

PERTINENT




NOT

PERTINENT




NOT

PERTINENT

JUNE 1999

Chemical Name : Phenol

Synonyms: Carbolic acid, Monohydroxy benzene, Phenic acid, Phenyl hydroxideFormula : C6H6O

Toxic




Hazchem Code :PhenolClass 6.1, Toxic 13

2X


34

Phenol 108-95-2

2. PHYSICAL / CHEMICAL DATA181.75 Solid Colorless if pure

40.91 0.35 mm Hg @ 25 deg C

Sweet - tarry odour.

3.24 8.28X10+4 mg/l @ 25 deg C

1.071 g/cm3

Soluble in alcohol, chloroform, ether, glycerol, carbon disulfide, volatile and fixed oils, and aqueous alkali hydroxides.6 (aq. soln.)

Boiling Pt. °C:

Physical State:


Appearance:

Odour:



Others:


Melting Pt °C:

3. FIRE / EXPLOSION HAZARD DATAYesFlammability : 1.3 85

9.5 79TDG Flammability:LEL:UEL:


Autoignition Temperature °C : 715Explosion sensitivity to impact: StableExplosion sensitivity to static Electricity: May be ignited by electrostatic discharge.Hazardous Combustion Products : Emits toxic fumes. Unburned vapor is toxic yields

flammable vapors when heated, which will form explosive mixtures with air.

Hazardous Polymerization : Will not occur.YesYesNo

NoNoNo

NoCombustible Liquid:Flammable Material:Pyrophoric Material:



MATERIAL SAFETY DATA SHEETSPhenol481

Stable under normal temperatures and pressures.Chemical Stability 4. REACTIVITY DATA

:Page 1 of 3Phenol

Strong oxidisers, butyl-chloral hydrate, camphor, chloral hydrate, diuretin, lead acetate, menthol and naphthalene.Violent reaction with aluminium chloride + nitrobenzene (120°C), sodium nitrate + trifluoro acetic acid, butadiene. Can react with oxidising materials.

Incompatibility with other materialReactivity

Hazardous Reaction Products5. HEALTH HAZARD DATA

Eyes, Skin, Inhalation, Ingestion

Inhalation: Causes severe irritation of upper respiratory tract with coughing, burns, breathing difficulty, and possible coma. May be fatal if exposed to high concentrations. Skin: Harmful if absorbed through the skin. Direct skin contact results in white, wrinkled discoloration, followed by severe burns. Phenol solutions may be absorbed through the skin rapidly to cause systemic poisoning and possible death. Eye: Contact with liquid or vapor causes severe burns and possible irreversible eye damage. May cause chemical conjunctivitis and corneal damage. Ingestion: Harmful if swallowed. May cause severe and permanent damage to the digestive tract. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea.

If the victim shows any ill effects, move him to fresh air area, keep him quiet and warm. If breathing stops, give artificial respiration.



530 mg/kg 10 ppm(38 mg/m3)

5 ppm (19 mg/m3), skin

0.048 ppm

5 ppm (19 mg/m3), skin

4 2 0



TLV (ACGIH) :



Inhalation:

Remove the contaminated clothing under water shower. Wash the affected area with plenty of flowing water and soap for 15 mins.

Skin:

Immediately flush with plenty of water. Seek medical aid.Eyes:Do not induce vomiting. Give milk, egg white or large amounts of water.Ingestion:

LC50 (rat) mg/kg:

6. PREVENTIVE MEASURESDo not eat or drink at work place. Provide fresh air mask for confined areas, rubber gloves, protective overclothing, rubber shoes and full face shield.Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Minimize dust generation and accumulation. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Do not ingest or inhale. Store protected from light. Discard contaminated shoes. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.

Personal ProtectiveEquipment

Handling

:

:

Avoid contact with the material.Precautions :

Store in a well ventilated area, away from heat and flame. Outdoor storage is preferred.

Storage :


:

:

:

Page 2 of 3Phenol

Sweep up spilled substance, carefully collect remainder. Wash the surface with soap and water. Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container.Seal all waste in vapour tight plastic bags for eventual disposal.

First Aid Measures:


Steps To Be Taken


EXPOSURE:

SPILLS :

Alcohol foam, CO2, dry chemical powder and water spray.Keep the containers cool by spraying water if exposed to heat or flame. Do not extinguish fire unless flow can be stopped.Vapours form explosive mixture with air.

Fire Extinguishing MediaSpecial Procedure

Unusual Hazards

FIRE:::

:

If the victim shows any ill effects, move him to fresh air area, keep him quiet and warm. If breathing stops, give artificial respiration.

Inhalation:

Remove the contaminated clothing under water shower. Wash the affected area with plenty of flowing water and soap for 15 mins.

Skin:

Immediately flush with plenty of water. Seek medical aid.Eyes:Do not induce vomiting. Give milk, egg white or large amounts of water.Ingestion:

8. ADDITIONAL INFORMATION / REFERENCESPhysical description: White crystalline mass of hygroscopic, translucent needle-shaped crystals; pink or red when impurities are present; darkens on exposure to light.Absorption of phenolic solution through the skin may be very rapid, can cause death in a few minutes to several hours by exposure of as little as 64 square inches of skin. Lesser exposure may cause damage to kidneys, liver, pancreas, spleen, lungs. Causes corrosion of lips, mouth, throat. Ingestion of 15 gms. may be fatal. Potentially explosive reaction with aluminium chloride + nitromethane (110 deg C / 110 Bar), formaldehyde, peroxydisulfuric acid.9. MANUFACTURERS / SUPPLIERS DATA




10. DISCLAIMER


:

OTHERS :

Page 3 of 3Phenol

CARBOLIC OIL (MIXTURE) CBO


Common Synonyms Liquid Colorless - darkens onexposure to light

Sweet tar odor


Carbolic acidLiquefied phenolMiddle oil

Evacuate.Keep people away. AVOID CONTACT WITH LIQUID.Wear chemical protective suit with self-contained breathing apparatus.Call fire department.Notify local health and pollution control agencies.Protect water intakes.

Fire Combustible.POISONOUS GASES ARE PRODUCED WHEN HEATED.Wear chemical protective suit with self-contained breathing apparatus.Extinguish with water, dry chemical, foam or carbon dioxide.


LIQUIDPOISONOUS IF SWALLOWED OR IF SKIN IS EXPOSED.Remove contaminated clothing and shoes.Flush affected area with plenty of water.IF IN EYES, hold eyelids open and flush with plenty of water.IF SWALLOWED and victim is CONSCIOUS, have victim drink wateror milk.DO NOT INDUCE VOMITING.

WaterPollution


1. CORRECTIVE RESPONSE ACTIONSDilute and disperseStop dischargeCollection Systems: PumpDo not burn


2.1 CG Compatibility Group: 21; Phenols,cresols

2.2 Formula: C6H5OH

2.3 IMO/UN Designation: 9.0/28212.4 DOT ID No.: 28212.5 CAS Registry No.: 108-95-22.6 NAERG Guide No.: 1532.7 Standard Industrial Trade Classification:

51241

3. HEALTH HAZARDS

3.1 Personal Protective Equipment: Fresh air mask for confined areas; rubber gloves; protectiveclothing; full face shield

3.2 Symptoms Following Exposure: Will burn eyes and skin. The analgesic action may cause loss ofpain sensation. Readily absorbed through skin, causing increased heart rate, convulsions, anddeath.

3.3 Treatment of Exposure: INHALATION: remove victim to fresh air, keep quiet and warm. If breathingstops, start artificial respiration. INGESTION: do NOT induce vomiting. Give milk, egg whites, orlarge amounts of water. Get medical assistance. No known antidote. EYES AND SKIN: removecontaminated clothing. Flush eyes with water for 15 minutes or until physician arrives. Wash skinwith soap and water.

3.4 TLV-TWA: 5 ppm



3.7 Toxicity by Ingestion: Grade 2; LD50 = 0.5 to 5 g/kg (rat)


3.9 Chronic Toxicity: Causes cancer in experimental animals.

3.10 Vapor (Gas) Irritant Characteristics: Vapors cause moderate irritation such that personnel will findhigh concentrations unpleasant. The effect is temporary.

3.11 Liquid or Solid Characteristics: Fairly severe skin irritant. May cause pain and second-degreeburns after a few minutes contact.

3.12 Odor Threshold: 0.05 ppm

3.13 IDLH Value: 250 ppm

3.14 OSHA PEL-TWA: 5 ppm




4. FIRE HAZARDS


4.2 Flammable Limits in Air: 1.7%-8.6%

4.3 Fire Extinguishing Agents: Water, drychemical, foam, or carbon dioxide

4.4 Fire Extinguishing Agents Not to BeUsed: Not pertinent

4.5 Special Hazards of CombustionProducts: Unburned vapor is toxic

4.6 Behavior in Fire: Yields flammable vaporswhen heated, which will form explosivemixtures with air
















6. WATER POLLUTION

6.1 Aquatic Toxicity:

11.5-28.5mg/1/96 hr/bluegill/TLm/freshwater

1.5 ppm/48 hr/rainbow trout/TLm/freshwater


6.3 Biological Oxygen Demand (BOD):200%, 5 days


6.5 GESAMP Hazard Profile:Bioaccumulation: TDamage to living resources: 3Human Oral hazard: 2

Human Contact hazard: IIReduction of amenities: XX


7.1 Grades of Purity: 90-92% phenol; 80-82%phenol (Remainder consists of cresols andwater)



7.4 Venting: Pressure-vacuum

7.5 IMO Pollution Category: A

7.6 Ship Type: 2

7.7 Barge Hull Type: 1


8.1 49 CFR Category: Poison

8.2 49 CFR Class: 6.1

8.3 49 CFR Package Group: II






8.6 EPA Reportable Quantity: Not listed.

8.7 EPA Pollution Category: Not listed.




PROPERTIES



9.3 Boiling Point at 1 atm: 359.2°F = 181.8°C =455.0°K

9.4 Freezing Point: <105.6°F = <40.9°C =<314.1°K

9.5 Critical Temperature: 790.0°F = 421.1°C =694.3°K

9.6 Critical Pressure: 889 psia = 60.5 atm = 6.13MN/m2


9.8 Liquid Surface Tension: 41 dynes/cm =0.041 N/m at 20°C




9.12 Latent Heat of Vaporization: 129.6 Btu/lb =72.0 cal/g = 3.014 X 105 J/kg

9.13 Heat of Combustion: –13,401 Btu/lb =–7445 cal/g = –311.707 X 105 J/kg


9.15 Heat of Solution: Not pertinent





NOTES

JUNE 1999

CARBOLIC OIL (MIXTURE) CBO




110115120125130135140145150155160165170175180185190195200205210

65.03064.90064.75964.62964.50064.37064.25064.12063.99063.86063.74063.61063.49063.36063.24063.12063.00062.87062.75062.63062.510




CURRENTLY

NOT

AVAILABLE




122 1.113



Centipoise

110115120125130135140145150155160165170175

4.3023.9293.5943.2923.0212.7752.5542.3532.1712.0051.8551.7181.5931.479




68 8.400




708090

100110120130140150160170180190200210220230240250260270280290300310320

0.0120.0170.0240.0340.0480.0660.0910.1230.1650.2200.2890.3780.4900.6290.8021.0161.2781.5961.9822.4463.0023.6634.4465.3706.4537.718




708090

100110120130140150160170180190200210220230240250260270280290300310320

0.000190.000270.000390.000540.000740.001000.001350.001800.002380.003110.004030.005180.006610.008360.010500.013110.016240.020000.024490.029800.036070.043420.052000.061970.073500.08679




0255075

100125150175200225250275300325350375400425450475500525550575600

0.2240.2370.2500.2620.2740.2860.2970.3090.3190.3300.3410.3510.3600.3700.3790.3880.3970.4050.4140.4220.4290.4360.4440.4500.457

JUNE 1999

POLYMETHYLENE POLYPHENYL ISOCYANATE PPI


Common Synonyms Liquid Dark brown Weak odor

Sinks in water.

PAPI

KEEP PEOPLE AWAY. AVOID CONTACT WITH LIQUID AND VAPOR.Call fire department.Notify local health and pollution control agencies.Protect water intakes.

Fire Combustible.Containers may explode in fire.Extinguish with dry chemicals or carbon dioxide.Cool exposed containers with water.


LIQUIDPOISONOUS IF SWALLOWED.Irritating to skin and eyes.Remove contaminated clothing and shoes.Flush affected areas with plenty of water.IF IN EYES, hold eyelids open and flush with plenty of water.IF SWALLOWED and victim is CONSCIOUS, have victim drink wateror milk and have victim induce vomiting.IF SWALLOWED and victim is UNCONSCIOUS OR HAVING CON-VULSIONS, do nothing except keep victim warm.

WaterPollution


1. CORRECTIVE RESPONSE ACTIONSStop dischargeCollection Systems: PumpClean shore line


2.1 CG Compatibility Group: 12; Isocyanate2.2 Formula: C6H4(NCO)CH2C6H4(NCO)-and

polymer2.3 IMO/UN Designation: Not listed

2.4 DOT ID No.: Not listed2.5 CAS Registry No.: Currently not available2.6 NAERG Guide No.: Not listed2.7 Standard Industrial Trade Classification:

51489

3. HEALTH HAZARDS

3.1 Personal Protective Equipment: Air-line or organic canister mask; goggles or face shield; rubbergloves and other protective clothing to prevent contact with skin.

3.2 Symptoms Following Exposure: Inhalation causes breathlessness, chest discomfort, and reducedpulmonary function; wheezing, cough, and sputum may also occur. Contact with liquid irritateseyes and skin. Ingestion causes irritation of mouth and stomach.

3.3 Treatment of Exposure: Get medical attention at once following all exposures to this compound.INHALATION: remove victim to fresh air; give artificial respiration if breathing has stopped; oxygencan be given by qualified personnel. EYES: immediately wash with large amounts of water for atleast 15 min. SKIN: flush immediately with water, wipe off, treat with 30% isopropyl alcohol(rubbing alcohol), and wash with soap and water. INGESTION: induce vomiting at least 3 times bygiving warm salt water (one tablespoon of salt per cup); follow with a quart of milk and a mildcarthartic such as milk of magnesia.




3.7 Toxicity by Ingestion: Grade 1; LD50 = 5 to 15 g/kg



3.10 Vapor (Gas) Irritant Characteristics: Vapors are moderately irritating such that personnel will notusually tolerate moderate or high concentrations.

3.11 Liquid or Solid Characteristics: Causes smarting of the skin and first-degree burns on shortexposure; may cause second-degree burns on long exposure.







4. FIRE HAZARDS

4.1 Flash Point: 425°F O.C.

4.2 Flammable Limits in Air: Not pertinent

4.3 Fire Extinguishing Agents: Dry chemicalor carbon dioxide



4.6 Behavior in Fire: Containers mayexplode.

4.7 Auto Ignition Temperature: Currently notavailable


4.9 Burning Rate: Currently not available







5.1 Reactivity with Water: Reacts slowly,forming heavy scum and liberatingcarbon dioxide gas. Dangerous pressurecan build up if container is sealed.

5.2 Reactivity with Common Materials: Nohazardous reaction unless confined andwet.

5.3 Stability During Transport: Stable if keptsealed and dry




6. WATER POLLUTION


Currently not available


6.3 Biological Oxygen Demand (BOD):Currently not available


6.5 GESAMP Hazard Profile:Bioaccumulation: 0

Damage to living resources: 0Human Oral hazard: 0Human Contact hazard: IIReduction of amenities: XX


7.1 Grades of Purity: 50% methylenebis-phenylisocyanate plus 50% polymer

7.2 Storage Temperature: 35–125°F

7.3 Inert Atmosphere: Low-pressure dry nitrogen

7.4 Venting: Safety relief


7.6 Ship Type: 2







8.5 NFPA Hazard Classification: Not listed





9. PHYSICAL & CHEMICAL PROPERTIES



9.3 Boiling Point at 1 atm: 392°F = 200°C =473°K

9.4 Freezing Point: Not pertinent




9.8 Liquid Surface Tension: Currently notavailable





9.13 Heat of Combustion: (est.) –13,000 Btu/lb= –7,200 cal/g = –300 X 105 J/kg






9.19 Reid Vapor Pressure: Very low

NOTES

JUNE 1999

POLYMETHYLENE POLYPHENYL ISOCYANATE PPI




3436384042444648505254565860626466687072747678808284

76.08976.02075.95075.87975.80975.74075.66975.59975.53075.45975.38975.32075.25075.17975.11075.04974.98074.91074.83974.77074.70074.62974.55974.49074.41974.349




5152535455565758596061626364656667686970717273747576

0.4000.4000.4000.4000.4000.4000.4000.4000.4000.4000.4000.4000.4000.4000.4000.4000.4000.4000.4000.4000.4000.4000.4000.4000.4000.400




525456586062646668707274767880828486

1.0481.0481.0481.0481.0481.0481.0481.0481.0481.0481.0481.0481.0481.0481.0481.0481.0481.048



Centipoise

3334353637383940414243444546474849505152535455565758

4348.0003918.0003531.0003184.0002872.0002592.0002340.0002113.0001909.0001726.0001560.0001412.0001277.0001157.0001047.000

949.000860.199780.000707.500642.000582.799529.299480.799437.000397.299361.299




INSOLUBLE

REACTS




60708090

100110120130140150160170180190200210

0.0000.0000.0000.0000.0000.0000.0000.0000.0000.0000.0000.0000.0000.0000.0000.000




60708090

100110120130140150160170180190200210

0.000000.000000.000000.000000.000000.000000.000000.000000.000000.000000.000000.000000.000000.000000.000000.00000




NOT

PERTINENT

JUNE 1999

SODIUM HYDROXIDE SHD


Common Synonyms Solid flakes or pellets White Odorless


Caustic sodaLye

Keep people away. Avoid contact with solid and dust.Wear rubber overclothing (including gloves).Notify local health and pollution control agencies.Protect water intakes.

Fire Not flammable.May cause fire on contact with combustibles.Flammable gas may be produced on contact with metals.Wear rubber overclothing (including gloves).Flood discharge area with water.Cool exposed containers with water.

Exposure CALL FOR MEDICAL AID.DUSTIrritating to eyes, nose and throat.Move to fresh air.If breathing has stopped, give artificial respiration.If breathing is difficult, give oxygen.IF IN EYES, hold eyelids open and flush with plenty of water.

SOLIDWill burn skin and eyes.Harmful if swallowed.Remove contaminated clothing and shoes.Flush affected areas with plenty of water.IF IN EYES, hold eyelids open and flush with plenty of water.IF SWALLOWED and victim is CONSCIOUS, have victim drink wateror milk.DO NOT INDUCE VOMITING.

WaterPollution

Dangerous to aquatic life in high concentrations.May be dangerous if it enters water intakes.Notify local health and wildlife officials.Notify operators of nearby water intakes.



2.1 CG Compatibility Group: 5; Caustics2.2 Formula: NaOH


52262

3. HEALTH HAZARDS

3.1 Personal Protective Equipment: Chemical safety goggles; face shield; filter or dust-type respirator;rubber boots; rubber gloves.

3.2 Symptoms Following Exposure: Strong corrosive action on contacted tissues. INHALATION: dustmay cause damage to upper respiratory tract and lung itself, producing from mild nose irritation topneumonitis. INGESTION: severe damage to mucous membranes; severe scar formation orperforation may occur. EYE CONTACT: produces severe damage.

3.3 Treatment of Exposure: INHALATION: remove from exposure; support respiration; call physician.INGESTION: give water or milk followed by dilute vinegar or fruit juice; do NOT induce vomiting.SKIN: wash immediately with large quantities of water under emergency safety shower whileremoving clothing; continue washing until medical help arrives; call physician. EYES: irrigateimmediately with copious amounts of water for at least 15 min.; call physician.



3.6 TLV-Ceiling: 2 mg/m3

3.7 Toxicity by Ingestion: (10% solution) oral rabbit LDLo = 500 mg/kg


3.9 Chronic Toxicity: None

3.10 Vapor (Gas) Irritant Characteristics: Non-volatile

3.11 Liquid or Solid Characteristics: Severe skin irritant. Causes second-and third-degree burns on shortcontact and is very injurious to the eyes.


3.13 IDLH Value: 10 mg/m3

3.14 OSHA PEL-TWA: 2 mg/m3




4. FIRE HAZARDS

4.1 Flash Point: Not flammable

4.2 Flammable Limits in Air: Not flammable

4.3 Fire Extinguishing Agents: Not pertinent




4.7 Auto Ignition Temperature: Notflammable


4.9 Burning Rate: Not flammable







5.1 Reactivity with Water: Dissolves withliberation of much heat; may steam andsplatter

5.2 Reactivity with Common Materials:When wet, attacks metals such asaluminum, tin, lead, and zinc to produceflammable hydrogen gas.


5.4 Neutralizing Agents for Acids andCaustics: Flush with water, rinse withdilute acetic acid



6. WATER POLLUTION

6.1 Aquatic Toxicity:125 ppm/96 hr/mosquito fish/TLm/fresh

180 ppm/23 hr/oysters/lethal/saltwater


6.3 Biological Oxygen Demand (BOD): None



Damage to living resources: 1Human Oral hazard: 1Human Contact hazard: IIReduction of amenities: X


7.1 Grades of Purity: Technical flakes; USP pellets



7.4 Venting: Open





8.1 49 CFR Category: Corrosive material

8.2 49 CFR Class: 8

8.3 49 CFR Package Group: II











PROPERTIES



9.3 Boiling Point at 1 atm: Very high

9.4 Freezing Point: 604°F = 318°C = 591°K









9.13 Heat of Combustion: Not pertinent







NOTES

JUNE 1999

SODIUM HYDROXIDE SHD




NOT

PERTINENT




NOT

PERTINENT




NOT

PERTINENT



Centipoise

NOT

PERTINENT




3436384042444648505254565860626466687072747678808284

44.81047.66050.50053.35056.19059.04061.88064.71967.57070.41073.25976.09978.95081.79084.63987.48090.32093.16996.00998.860

101.700104.500107.400110.200113.099115.900




NOT

PERTINENT




NOT

PERTINENT




NOT

PERTINENT

JUNE 1999

Chemical Name : Sodium hydroxide

Synonyms: Caustic soda, Soda lye, Lye, Sodium hydrateFormula : NaOH

Explosive, Reactive, Oxidizing, Corrosive



CAS No: 1310-73-2 UN No: 1823 / 1824Regulated Identification Shipping Name :Codes / Label : Hazardous Waste ID No :

Hazchem Code :Sodium hydroxide, Solid / SolutionClass 8, Explosive, Reactive, Oxidizing, Corrosive

162W / 2R


34

Sodium hydroxide 1310-73-2

2. PHYSICAL / CHEMICAL DATA1388 Solid Colourless to white,

solid (flakes, beads, granular form)

323 1 mm Hg at 739 °C

Odourless

1.1 kg/L

2.13 at 25 °C

Soluble in alcohol, methanol and glycerol

13-14 (soln.)

Boiling Pt. °C:

Physical State:


Appearance:

Odour:



Others:


Melting Pt °C:

3. FIRE / EXPLOSION HAZARD DATANoFlammability :

TDG Flammability:LEL:UEL:


Autoignition Temperature °C :Explosion sensitivity to impact: StableExplosion sensitivity to static Electricity: StableHazardous Combustion Products : Emits toxic fumes of Na2OHazardous Polymerization : Will not occur.

NoNoNo

NoNoNo

YesCombustible Liquid:Flammable Material:Pyrophoric Material:



MATERIAL SAFETY DATA SHEETSSodium hydroxide571

StableWater, acids, flammable liquids, organic halides, metals, Al, Sn, Zn, nitromethane and nitro compounds

Chemical Stability Incompatibility with other material

4. REACTIVITY DATA::

Page 1 of 3Sodium hydroxide

Vigorous reaction with organic halides, metals, nitro compounds.ReactivityHazardous Reaction Products5. HEALTH HAZARD DATA

Inhalation, Ingestion., Skin & Eyes

Inhalation: Causes small burns to upper respiratory tract and lungs, mild nose irritation. Ingestion: Causes severe damage to mucous membrane. Severe scaring or perforation may occur. Eyes: Severe damage. Skin: Causes severe burns.

Remove the victim from exposure. Support respiration, give oxygen, if necessary.



2 mg/m3 2 mg/m3

3 0 0



TLV (ACGIH) :



Inhalation:Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Discard contaminated clothing in a manner which limits further exposure.

Skin:

Get medical aid. Do not allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes).

Eyes:

Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately.

Ingestion:

LC50 (rat) mg/kg:

6. PREVENTIVE MEASURESAvoid contact with solid or liquid. Provide side covered safety goggles, face shield, dust-type respirator, rubber shoes and rubber hand gloves. Wash thoroughly after handling. Do not allow water to get into the container because of violent reaction. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation. Discard contaminated shoes.


:

:

Precautions :

Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area. Store protected from moisture.

Storage :

First Aid Measures:EXPOSURE:


Keep the containers cool by spraying water if exposed to heat or flame.Toxic gases are produced.


Unusual Hazards

FIRE:::

:

Remove the victim from exposure. Support respiration, give oxygen, if necessary.Inhalation:Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Discard contaminated clothing in a manner which limits further exposure.

Skin:

::


Sweep and collect without making dust. Wash the surface with plenty of water and soap.Seal all waste in vapour-tight plastic bags for eventual disposal.


Steps To Be Taken


SPILLS :

Get medical aid. Do not allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes).

Eyes:

Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately.

Ingestion:

8. ADDITIONAL INFORMATION / REFERENCESVigorous reaction with 1,2,4,5 - Tetrachlorobenzene has caused many industrial explosions and forms extremely toxic 2,3,7,8 - Tetrachlorodibenzodioxin. Under proper conditions of temperature, pressure and state of division, it can react or ignite violently with acetic acid, acetaldehyde, acetic anhydride, acrolein, acrylonitrile, allyl alcohol, allyl chloride.9. MANUFACTURERS / SUPPLIERS DATA




10. DISCLAIMER


:

OTHERS :


Chemical Name : Phthalic anhydride

Synonyms: Phthalic acid anhydride, PAN, 1,2-Benzenedwarboxylic acid anhydrideFormula : C8H4O3

Toxic




Hazchem Code :Phthalic anhydrideClass 8, Toxic 5

2X


34

Phthalic anhydride 85-44-9

2. PHYSICAL / CHEMICAL DATA295 (sublimes)

Solid White lustrous needles or powder

130.8 5.17X10-4 mm Hg at 25 deg C

Characteristic, acrid odor

5.7 6,200 mg/L at 25 deg C

1.53 at 20° /4 °C

Soluble in alcohol, slightly soluble in etherAcidic

Boiling Pt. °C:

Physical State:


Appearance:

Odour:



Others:


Melting Pt °C:

3. FIRE / EXPLOSION HAZARD DATANoFlammability : 1.7 165

10.5 151.8TDG Flammability:LEL:UEL:


Autoignition Temperature °C : 227Explosion sensitivity to impact: StableExplosion sensitivity to static Electricity:Hazardous Combustion Products : Fire will produce irritating, corrosive and/or toxic gases.Hazardous Polymerization : Will not occur.

NoNoNo

NoNoNo




MATERIAL SAFETY DATA SHEETSPhthalic anhydride508

StableStrong oxidisers

Violent reaction with nitric acid + sulphuric acid above 80°C. In water, solid has very slow reaction. Liquid spatters when in contact with water.

Chemical Stability Incompatibility with other materialReactivity


:

Page 1 of 3Phthalic anhydride

Mixtures with copper oxide or sodium nitrite explode when heated.Hazardous Reaction Products5. HEALTH HAZARD DATA

Inhalation, Ingestion, Eyes & Skin

Solid irritates skin and eyes, causing coughing and sneezing. Liquid causes severe thermal burns. Inhalation of the substance may cause lung oedema.

Gargle with water and use a sedative cough mixture. Ingestion: Induce vomiting and give water, milk or vegetable oil.



4020

12 mg/m3 (2 ppm)

0.08-0.19 ppm (0.32 - 0.72 mg/m3)1 ppm 6 mg/m3

3 1 0



TLV (ACGIH) :



Inhalation:

Flush with water for at least 15 mins. If burnt by molten material remove as much solid as possible, soak off the remainder in cold water, and then treat the burns. Seek medical aid.

Skin:


Eyes:

Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.

Ingestion:

LC50 (rat) mg/kg:

6. PREVENTIVE MEASURESAvoid contact with liquid or vapours. Provide rubber apron, rubber shoes, face shield, approved vapour respirator, leather or rubber hand gloves and shoes. Wash thoroughly after handling. Use only in a well ventilated area. Use with adequate ventilation. Ground and bond containers when transferring material. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Do not ingest or inhale. Do not allow contact with water. Discard contaminated shoes. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.


Handling

:

:

Precautions :

Store in a cool, dry, well ventilated area away from heat and oxidising materials.

Storage :


CO2, dry chemical powderKeep the containers cool by spraying water if exposed to heat or flame.


Unusual Hazards

FIRE:::

:

:


Sweep and collect without making dust. Wash the surface with plenty of water and soap.Seal all waste in vapour tight bags for eventual disposal.

First Aid Measures:


Steps To Be Taken


EXPOSURE:

SPILLS :

Gargle with water and use a sedative cough mixture. Ingestion: Induce vomiting and give water, milk or vegetable oil.

Inhalation:


Skin:


Eyes:


Ingestion:

8. ADDITIONAL INFORMATION / REFERENCESCombustible when exposed to heat or flame. The production of this material has caused many industiral explosions. Mixture with copper oxide or sodium nitrite explodes when heated. Used in plasticizers, polyester resins, dyes and drugs.9. MANUFACTURERS / SUPPLIERS DATA




10. DISCLAIMER


:

OTHERS :


Food and Agriculture Organization of the United Nations

WHO/HSE/FOS/11.1

Background Paper on

Acute and Repeated-Dose Toxicity of Bisphenol A

FAO/WHO Expert Meeting on Bisphenol A (BPA) Ottawa, Canada, 2–5 November 2010

Prepared by

Michelle Twaroski Center for Food Safety and Nutrition, United States Food and Drug

Administration, College Park, Maryland, USA

Note to readers:

The first draft of this paper was prepared by the named author, and the paper was then revised following discussions at the November 2010 meeting.

1

© World Health Organization 2011

All rights reserved. Publications of the World Health Organization are available on the WHO web site (www.who.int) or can be purchased from WHO Press, World Health Organization, 20 Avenue Appia, 1211 Geneva 27, Switzerland (tel.: +41 22 791 3264; fax: +41 22 791 4857; e-mail: [email protected]). Requests for permission to reproduce or translate WHO publications – whether for sale or for noncommercial distribution – should be addressed to WHO Press through the WHO web site (http://www.who.int/about/licensing/copyright_form/en/index.html).

The designations employed and the presentation of the material in this publication do not imply the expression of any opinion whatsoever on the part of the World Health Organization concerning the legal status of any country, territory, city or area or of its authorities, or concerning the delimitation of its frontiers or boundaries. Dotted lines on maps represent approximate border lines for which there may not yet be full agreement. The mention of specific companies or of certain manufacturers’ products does not imply that they are endorsed or recommended by the World Health Organization in preference to others of a similar nature that are not mentioned. Errors and omissions excepted, the names of proprietary products are distinguished by initial capital letters. All reasonable precautions have been taken by the World Health Organization to verify the information contained in this publication. However, the published material is being distributed without warranty of any kind, either expressed or implied. The responsibility for the interpretation and use of the material lies with the reader. In no event shall the World Health Organization be liable for damages arising from its use.

Toxicological and Health Aspects of Bisphenol A

2

CONTENTS 1. Acute toxicity ............................................................................................................................................. 2

2. Repeated-dose toxicity ............................................................................................................................... 2

2.1 Mice ..................................................................................................................................................... 2

2.2 Rats ...................................................................................................................................................... 3

2.3 Dogs..................................................................................................................................................... 9

3. Summary and conclusion............................................................................................................................ 9

Bisphenol A (BPA) is of low acute toxicity. Repeated-dose studies in rats and mice have shown effects

on the liver, kidney and body weight, with a lowest no-observed-adverse-effect level of 5 mg/kg body

weight per day. There are no specific long-term toxicity studies with BPA other than those conducted

to examine its carcinogenicity.

1. ACUTE TOXICITY

In a United States National Toxicology Program study (NTP, 1982), bisphenol A

(BPA) was administered via gavage to F344 rats and B6C3F1 mice in 1.5% acacia oil.

The median lethal dose (LD50) values were calculated to be 4.1 g/kg body weight (bw)

for male rats, 3.3 g/kg bw for female rats, 5.2 g/kg bw for male mice and 4.1 g/kg bw

for female mice. The Center for the Evaluation of Risks to Human Reproduction

(CERHR) panel on BPA (Chapin et al., 2008) summarized additional data on acute

toxicity; the lowest reported oral LD50s for rat, mouse, guinea-pig and rabbit are 3250,

2400, 4000 and 2230 mg/kg bw, respectively. An intraperitoneal study referenced in

Chapin et al. (2008) gave an LD50 of 150 mg/kg bw in the mouse.

2. REPEATED-DOSE TOXICITY

2.1 Mice

In an NTP (1982) study, B6C3F1 mice (five of each sex per dose) were administered

BPA at concentrations of 0, 500, 1000, 2500, 5000 or 10 000 mg/kg in feed (Purina

chow) for 14 days. Dietary concentrations corresponded to doses of approximately 0,

120, 240, 600, 1200 and 2400 mg/kg bw per day. No differences were noted regarding

body weight or mortality compared with controls.

In another NTP (1982) study, B6C3F1 mice (10 of each sex per dose; 5 weeks old at

start, purchased from National Cancer Institute [NCI]) were fed BPA in a dietary

admix at concentrations of 0, 5000, 10 000, 15 000, 20 000 or 25 000 mg/kg for 13

weeks. Doses were estimated by the European Union (2003) to be 0, 600, 1200, 1800,

2400 and 3000 mg/kg bw per day in male mice and 0, 650, 1300, 1950, 2600 and

3250 mg/kg bw per day in female mice. Animals were group housed (five per cage) in

polycarbonate cages, with ad libitum food and water, standard temperature and

humidity, and a 12-hour light/dark cycle. Animals were observed twice daily,

weighed weekly and sacrificed at 91 days for necropsy and histopathology. Non-dose-

related findings were reported with regard to mortality (2/10 in females at 5000

mg/kg) and body weight decreases in all females. Body weight was also decreased in

males at and above 15 000 mg/kg. Multinucleated giant hepatocytes were observed in

Acute and Repeated-Dose Toxicity of BPA

3

all male mice in a dose-related manner with regard to incidence and severity. This

finding was not observed in females.

In a study compliant with Organisation for Economic Co-operation and Development

(OECD) guideline 416, Tyl et al. (2008) administered BPA via feed to nine groups of

6-week-old mice (Crl:CD-1 (ICR)BR, Charles River) at doses of 0 (two groups),

0.018, 0.18, 1.8, 30, 300 or 3500 mg/kg (equivalent to intakes of 0, 0.003, 0.03, 0.3, 5,

50 and 600 mg/kg bw per day, respectively). 17β-Estradiol was used as a reference

compound and was administered at 0.5 mg/kg (intake of 0.08 mg/kg bw per day) to a

separate group. F0 animals were exposed for 8 weeks prior to mating, during the

mating period, through gestation and during the 3-week lactation period. F1 offspring

(28 of each sex per group) were exposed through premating, mating, gestation and

lactation. F0 dams were necropsied after weaning occurred, and F1 dams and F2

offspring were necropsied at the time of weaning of F2 offspring. F0 and F1 males

were necropsied at the end of the gestation of their respective F1 and F2 litters. In

addition, one F1 male per litter was randomly selected at weaning for retention and

treatment for 3 months. These animals were evaluated for andrology, necropsy and

histopathology concurrent with F1 parental males. (This resulted in an additional 21–

27 mice in the BPA treatment groups and 50 in controls.) Animals were fed Purina

5002, assayed for phytoestrogen content, ad libitum, and standard housing practices

were employed. Systemic treatment-related effects at 3500 mg/kg included increased

liver weights (absolute and relative), increased incidence of minimal to mild

centrilobular hepatocyte hypertrophy, increased kidney weights (absolute and

relative), increased minimal to mild nephropathy (F0 and F1 adults and retained F1

adult males), and reduced absolute and relative spleen weights (F1 and F2 male and

female weanlings; not observed in adult animals). Results at 300 mg/kg included

increased incidence of minimal to mild centrilobular hepatocyte hypertrophy (adult F0

males, retained F1 males and F1 females). The systemic no-observed-adverse-effect

level (NOAEL) for the study was 5 mg/kg bw per day.

2.2 Rats

In an NTP (1982) study, F344 rats (five of each sex per dose) were administered BPA

at concentrations of 0, 500, 1000, 2500, 5000 or 10 000 mg/kg in feed (Purina chow)

for 14 days. Dietary concentrations correspond to doses of approximately 0, 50, 100,

250, 500 and 1000 mg/kg bw per day.1 Body weight gain (mean) was decreased in

male animals receiving 2500 mg/kg and above and in females receiving 5000 mg/kg

and above; no effects on mortality were noted.

Yamasaki et al. (2002a,b) investigated the toxicity of BPA in an enhanced OECD

guideline 407 subacute (28-day) toxicity study. Briefly, Crj:CD (SD) rats (7 weeks

old, 10 of each sex per group) were administered BPA orally via gavage at 0 (olive oil

vehicle), 40, 200 or 1000 mg/kg bw per day in a volume of 5 ml/kg bw. A companion

study was included that treated animals with ethinyl estradiol. As a result of toxicity,

the high dose was reduced to 600 mg/kg bw per day on day 8. Animals were

individually housed in stainless steel wire-mesh cages with standard laboratory

conditions and were provided commercial diet (MF, Oriental Yeast Company, Japan)

and water ad libitum. Examinations included general clinical observations (daily), a

1 Doses are as cited in European Union (2003) using the default calculations of Gold et al. (1984).


4

functional observational battery (week 4), detailed clinical observations (weekly),

body weight (twice per week), feed consumption (weekly), haematology, clinical

chemistry, hormone analysis (triiodothyronine, thyroxine, thyroid-stimulating

hormone, prolactin, testosterone, estradiol, follicle stimulating hormone, luteinizing

hormone), spermatology, estrous cycling, organ weights and histopathology.

Statistical analysis included Bartlett’s test for homogeneity of variance followed by

analysis of variance and Dunnett’s (homogeneous) or Kruskal-Wallis

(heterogeneous). Treatment-related mortality occurred at the high dose (one female

and three males) in the first 2 weeks. Clinical signs included soft stool in animals

treated with BPA at doses of 200 mg/kg bw per day and above. Feed consumption

was decreased at and above 200 mg/kg bw per day in both sexes during week 1 of

administration, whereas body weight was decreased in males at 600 mg/kg bw per day

and females at and above 200 mg/kg bw per day. At the high dose, haematological

factors that were reportedly affected (data not shown) included increased prothrombin

time (males) and reduced haematocrit and haemoglobin concentration (females). The

authors reported an increase in glutamic–oxaloacetic transaminase activity in males

treated with BPA at and above 200 mg/kg bw per day and decreased triglycerides “or”

increased alkaline phosphatase activity, γ-glutamyl transpeptidase activity or chloride

in males treated with 600 mg/kg bw per day (data not shown). In females, decreased

cholinesterase, albumin and albumin to globulin ratio were observed at the high dose;

decreased cholinesterase activity was also observed at the intermediate dose and

increased glutamic–oxaloacetic transaminase activity at the high dose (data not

shown).

In the companion publication of the study (Yamasaki et al., 2002b), combined results

are tabulated, indicating increases in prothrombin time, total cholesterol, chloride and

activities of glutamic–pyruvic transaminase, γ-glutamyl transpeptidase and alkaline

phosphatase at the high dose, whereas glutamic–pyruvic transaminase activity was

also increased at the intermediate dose (assumed combined sexes). α2u-Globulin was

decreased at the middle and high doses. No changes were noted with regard to

hormones or sperm parameters (data not shown); however, diestrus was prolonged in

high-dose females. In animals that died early at the high dose, findings included

enlarged kidneys, mucosal elevation in the forestomach and atrophy of the spleen and

thymus. In terminally sacrificed animals, enlarged caecum was observed at and above

200 mg/kg bw per day (both sexes); mucosal elevation of the forestomach was also

seen in high-dose females. High-dose males had decreased relative ventral prostate

weight and increased relative testis and relative adrenal weights. Females had

decreased relative heart weight at and above 200 mg/kg bw per day and increased

relative liver and relative thyroid weights at the high dose. Histopathological

examination of animals that died early indicated findings in the intestines, spleen,

thymus and renal glands. In terminal sacrificed animals treated with BPA at and

above 200 mg/kg bw per day, findings were observed in the intestine, forestomach,

renal tubules (degeneration and necrosis) and adrenals (cortical vacuolization).

Females also had sinus dilatation of the mesenteric lymph node and prominent

nucleoli of hepatocytes.

In a study by Takahashi & Oishi (2001), male F344/DuCrj rats (eight of each dose, 4

weeks of age) were fed a dietary admix of 0%, 0.25%, 0.5% or 1% BPA (stated as

equivalent to 0, 235, 466 and 950 mg/kg bw per day) for 44 days (mean body weight

of 200 g for control animals). Diet (CE-2), which consisted of 45% soya bean cake,


5

was provided ad libitum and stated to have daidzin, glycitin, genistin, daidzen,

glycitein and genistein at 125, 26.7, 146, 3.95, 25.4 and 3.87 µg/g, respectively.

Animals were housed four to a cage in stainless steel cages with standard laboratory

conditions and water provided ad libitum. Body weights and feed consumption were

recorded 5 days per week, and clinical observations were made daily. At sacrifice,

blood samples were taken to determine testosterone levels, and weights were taken of

testes, preputial gland, epididymides, prostate (ventral, lateral and dorsal), seminal

vesicles with coagulation gland, kidneys and liver. Testis was fixed in formaldehyde

and stained with haematoxylin and eosin for histopathological examination. A

statistically significant decrease in body weight gain was observed at and above 466

mg/kg bw per day at the end of the dosing period. Statistically significant and dose-

related decreases in absolute (>22%) and relative liver weights (>10%) were observed

at and above 466 mg/kg bw per day, compared with controls. Relative kidney weights

were significantly increased (>8%) at and above 235 mg/kg bw per day, but no

change in absolute kidney weight was observed. Other statistically significant effects

included a decrease in both absolute and relative weights of preputial gland at and

above 235 mg/kg bw per day (≥26% and ≥22%, respectively); a decrease in absolute

(45%) and relative (32%) dorsal and lateral prostate gland weights at 950 mg/kg bw

per day; and a decrease in absolute (but not relative) seminal vesicle gland weight at

950 mg/kg bw per day (47%). No effects were observed on the weights (absolute or

relative) of the testes, epididymides or ventral prostate glands following BPA

treatment. No effect was seen on testosterone levels. At necropsy, a decrease in the

diameter of seminiferous tubules, arrest of spermatogenesis and a decrease in

elongated spermatids were observed at and above 235 mg/kg bw per day. Treatment

with BPA also led to disorganization of late spermatids in stages I–VI at and above

235 mg/kg bw per day, non-significant occasional sloughing at and above 466 mg/kg

bw per day and nuclear pyknosis of late spermatids at 950 mg/kg bw per day.

Disappearance of step 19 spermatids in stages VII and VIII and the disorganization of

late spermatids in stages I–VI were observed at and above 235 mg/kg bw per day.

BPA-treated animals (all doses) had significantly decreased seminiferous tubules in

stages I–VI and significantly increased seminiferous tubules in stages IV–XI and XII–

XIV, whereas no change was noted in stages VII–VIII.

In a study by Til, Roverts & Beems (1978), Wistar rats (15 of each sex per group)

were fed BPA in a dietary admix at concentrations of 0, 100, 500 or 2500 mg/kg for

90 days. Mean BPA dose levels were calculated by the authors as 0, 7, 37 and 182

mg/kg bw per day in males and 0, 7, 37 and 185 mg/kg bw per day in females,

respectively. Male rats were sacrificed on days 91–92, and females on days 92 and 95.

Routine haematology and biochemical investigations were performed at sacrifice.

Urinalysis was performed on urine collected from 10 rats of each sex per group during

the 16 hours prior to sacrifice. At necropsy, animals in the control and high-dose

groups were subject to a complete and thorough gross and histopathological

examination (which included reproductive organs). Statistically significant findings

included decreased mean body weight gain in males (17%) and females (9%) at 2500

mg/kg and at and above 500 mg/kg, respectively; decreased fasting blood glucose

levels in males (8%) and females (12%) at 2500 mg/kg and at and above 500 mg/kg,

respectively; decreased creatinine levels in males at and above 500 mg/kg (15–16%);

and increased total white blood cell counts in females at 2500 mg/kg (31%). No other

treatment-related haematological, urinalysis or biochemical effects were observed. At

2500 mg/kg, a statistically significant increase in the relative weights of the following


6

organs was observed compared with control: brain in males (15%) and females

(11%); kidneys (8%) in females; and testes (13%) in males. At necropsy, the only

effects observed were enlarged caeca in two males at 500 mg/kg and seven males and

nine females at 2500 mg/kg and alopecia in one female at 100 mg/kg, three females at

500 mg/kg and six females and one male at 2500 mg/kg. The changes in the caecum

and skin were not accompanied by any microscopic changes.

In an NTP (1982) study, F344 rats (10 of each sex per dose; 5 weeks old at start,

purchased from NCI) were fed BPA in a dietary admix at concentrations of 0, 250,

500, 1000, 2000 or 4000 mg/kg for 13 weeks. Corresponding doses were estimated by

the European Union (2003) to be 0, 25, 50, 100, 200 and 400 mg/kg bw per day.

Animals were group housed (five per cage) in polycarbonate cages, food and water

were supplied ad libitum, and standard temperature and humidity and a 12-hour

light/dark cycle were maintained. Animals were observed twice daily, weighed

weekly and sacrificed at 91 days for necropsy and histopathology. Deaths were

observed in male rats dosed at 1000 mg/kg (2/10). Feed consumption was not affected

by BPA at any dose, whereas body weight was reduced in all animals dosed at and

above 1000 mg/kg. Hyaline masses of the bladder lumen were reported in all males

treated with BPA (5/10, 3/10, 3/10, 6/10, 4/10), whereas caecal enlargement was

observed in all animals with the exception of those receiving the low dose.

In a study by Ema et al. (2001), developmental and reproductive toxicity of BPA was

examined in an OECD guideline 416 standard two-generation study in Crj:CD(SD)

IGS rats (Charles River, Japan). Animals (25 of each sex per dose) were gavaged

daily with BPA at doses of 0, 0.2, 2, 20 or 200 µg/kg bw per day throughout

premating, mating, gestation and lactation. F0 males were 5 weeks old and F0 females

were 10 weeks old when placed on study 10 or 2 weeks prior to mating, respectively.

F1 rats were gavaged starting on postnatal day (PND) 23 and treated for 10 weeks

prior to mating. F2 males and females were gavaged starting on PND 22 for 4 and 11

weeks, respectively, prior to necropsy. Stainless steel cages were used for housing.

Bedding and diet (CFR-1, Oriental Yeast Company, Japan) and drinking-water were

analysed for BPA, with limits of detection of less than 0.003 µg/g and 0.03 µg/l,

respectively. In adult animals, statistically significant systemic effects included

decreased absolute lung weight at 0.2 and 200 µg/kg bw per day (F1 males, no change

in relative lung weight), decreased absolute kidney weight at 200 µg/kg bw per day

(F1 males, not significant with regard to relative kidney weight) and decreased

absolute but not relative testes weight at 20 µg/kg bw per day (F1 males).

Significantly decreased serum luteinizing hormone and triiodothyronine levels were

observed in 0.2, 2 and 20 µg/kg bw per day F0 females and in 200 µg/kg bw per day

F0 females, respectively, but not in F0 males or F1 adults (data not shown). Changes

were concluded to be sporadic, inconsistent or non–dose dependent; accordingly,

findings were considered not to be treatment related.

In an expanded OECD guideline 416 study by Tyl et al. (2002), BPA was

administered via feed (Purina 5002) to Crl:CD[SD]BR (Charles River, NC) virgin rats

(30 of each sex per dose) at doses of 0, 0.015, 0.3, 4.5, 75, 750 or 7500 mg/kg

(equivalent to mean intakes of 0, 0.001, 0.02, 0.3, 5, 50 and 500 mg/kg bw per day,

respectively). F0 animals were exposed for 10 weeks prior to mating, during the

mating period, through gestation and during the lactation period until weaning (PND

21). F1 litters were culled to 10 pups (equal sex ratio) at PND 4. F1 and F2 offspring


7

(30 of each sex per group) were exposed through premating (13–15 weeks), mating,

gestation and lactation. F0 males were sacrificed and necropsied after F1 delivery. F3

weanlings were sacrificed after approximately 10 weeks of continued dietary

exposure. Systemic effects at 7500 mg/kg included reduced body weight and body

weight gain (F0, F1, F2 and F3); reduced body weight during gestation and lactation

(F0, F1 and F2 females); decreased terminal body weights (all); increased slight to mild

renal tubular degeneration and chronic hepatic inflammation (F1 and F2 females); and

chronic hepatic inflammation (F0 males). At 750 mg/kg, effects observed included

reduced body weights during lactation (F1 females), reduced body weights during

gestation and lactation (F0 and F2 females) and decreased terminal body weights (F1

[all] and F2 [males]). Parental absolute organ weights reportedly reduced at 7500

mg/kg included liver, kidneys, adrenal glands, spleen, pituitary and brain; however,

relative weights were either unaffected or increased, and the authors suggested that

this observation was a result of reduced terminal body weights. Other organ changes

at lower doses were not considered treatment related owing to lack of consistency

across generations or lack of a dose–response relationship. These same observations

were provided for F1, F2 and F3 weanlings sacrificed on PND 21 (high dose decreased

absolute organ weights, increased relative organ weights due to body weight changes

and sporadic organ weight changes at lower doses). The systemic NOAEL for the

study was 5 mg/kg bw per day.

Stump et al. (2010) examined the effects of oral BPA exposure in Sprague-Dawley

Crl:CD (Charles River, NC) rats with regard to developmental neurotoxicity in a

study compliant with OECD guideline 426 and United States Environmental

Protection Agency guideline 870.6300. Briefly, six groups of pregnant rats (24 of

each sex per dose) were fed a dietary admix from gestation day (GD) 0 to PND 21 at

BPA levels of 0, 0.15, 1.5, 75, 750 or 2250 mg/kg. The corresponding intakes were

calculated to be 0, 0.01, 0.12, 5.85, 56.4 and 164 mg/kg bw per day during gestation

and 0, 0.03, 0.25, 13.1, 129 and 410 mg/kg bw per day during lactation, respectively.

Animals were housed individually in stainless steel wire-mesh cages during the study

except from GD 18 to PND 21, when dams and pups were housed in

polyphenylsulfone RaTEMP thermoplastic rat cages with ground corncob. Feed (PMI

5002) and reverse osmosis–purified drinking-water were provided ad libitum. Diet

and water were analysed for contaminants. Diet was also measured for phytoestrogen

content. Statistical methods were defined (Holson, 2008), and litter was used as the

experimental unit. Non-reproductive end-points examined in the F0 dams included

body weight, feed consumption, detailed clinical observations, survival, gross

necropsy, absolute and relative organ weights (kidney and liver) and microscopic

examination of the kidney, liver, stomach, thymus, ureter and diaphragm. For the F1

pups, general pathology and neuropathology, body weights, feed consumption, and

absolute and relative organ weights were also measured. No treatment-related effects

were noted with respect to mortality, morbidity, clinical observations, organ weights

(absolute and relative), or macroscopic and microscopic examinations in F0 dams or

F1 pups. Statistically significant reductions in mean body weights and/or body weight

gains were observed in F0 females treated with BPA at 750 and 2250 mg/kg in the diet

during gestation and lactation. Similar reductions in body weights and body weight

gains were also observed in 750 and 2250 mg/kg F1 offspring during lactation. In

addition, significant reduction in mean feed consumption was observed in treated F0

females in 750 and 2250 mg/kg groups during gestation. The systemic NOAEL was


8

75 mg/kg (5.85 and 13.1 mg/kg bw per day during gestation and lactation,

respectively).

Systemic toxicity of BPA has also been examined in rats using non-oral routes of

exposure. In a rat inhalation study by Dow Chemical Co. (Nitschke et al., 1988), BPA

was administered to F344 rats (Charles River, NY) at 0, 10, 50 or 150 mg/m3 via

whole-body inhalation for 6 hours per day, 5 days per week, for 13 weeks. Animals

(30 of each sex per group), which were approximately 7 weeks of age at the start of

the study, were provided feed (Purina 5002) ad libitum throughout the study and

housed in stainless steel wire cages. Animals were sacrificed (10 of each sex per

group) at 1 day after exposure and after 4 or 12 weeks of recovery. End-points

examined included clinical observations, ophthalmic (pre-study) observations, body

weight and feed consumption (weekly), clinical chemistry and haematology (at

terminal sacrifice), gross pathology, organ weights (brain, liver, kidney, lung and

testes) and histopathology (complete for control and high dose at 13 weeks, select for

recovery terminal sacrifice and other doses). Statistical analysis included Bartlett’s

test, analysis of variance, Dunnett and Wilcoxon Rank-Sum with Bonferroni

correction for multiple comparisons. During treatment, a reddish material was

observed around the nose of males and females exposed to 50 or 150 mg/m3. Perineal

soiling was observed in females at and above 10 mg/m3 and in males at and above 50

mg/m3. One animal died at 10 mg/m

3 from “traumatic” causes. Decreased body

weight was observed in all males at exposures of 10 mg/m3 and higher and in females

at and above 50 mg/m3; no changes were noted in feed intake. Haemoglobin was

increased in males at 10 mg/m3. Clinical chemistry changes after 13 weeks of high-

dose treatment in males included decreased serum glutamic–pyruvic transaminase and

serum glutamic–oxaloacetic transaminase activities and glucose, whereas females had

increased alkaline phosphatase activity and decreased total protein and albumin levels.

Absolute liver weights were decreased in low- and high-dose males, whereas in

females, terminal body weight and kidney and liver weights were decreased and

relative brain and lung weights were increased at the high dose. Mid-dose findings in

females included increased relative brain weight. At exposures of 50 and 150 mg/m3,

enlarged caecum, haemolysed blood present in stomach, perineal and facial soiling,

and very slight goblet cell hyperplasia in the respiratory epithelium and nasal

turbinates were observed. Various effects were also seen in 4-week recovery animals,

including lower body weights in both sexes (>50 mg/m3); decreased white blood cells

(10 and 150 mg/m3), increased alkaline phosphatase and decreased serum glutamic–

pyruvic transaminase activities (150 mg/m3) in females; and increased relative brain

weight in males (150 mg/m3). Findings with regard to caecum and nasal

histopathology were reduced compared with continual treatment animals. Findings

observed at the 12-week recovery in high-dose animals included decreased body

weight (males) and total protein and globulin levels (females) and decreased kidney

weights (absolute and relative, both sexes). Decreased white blood cell counts (not

differential) were also found in males at low and high doses. No histopathological

alterations were reported. The study authors did not consider the changes in

haematology or clinical chemistry to be biologically significant and considered the

changes in organ weights to be related to changes in body weight and, as they were

unaccompanied by microscopic changes, non-concerning. The study authors

concluded that BPA did not result in any effects on the lower respiratory tract at any

of the concentrations tested.


9

2.3 Dogs

In a 14-day dose range–finding feeding study, male and female adult Beagle dogs

(two of each sex) were administered BPA at dietary concentrations of 2000, 4000,

8000 or 12 000 mg/kg (estimated to be equivalent to 49, 88, 281 or 293 mg/kg bw per

day in males and 50, 137, 262 or 278 mg/kg bw per day in females) (General Electric,

1976). As noted in the European Union (2003) review, no differences were noted with

regard to body weight, feed consumption or clinical signs. Standard gross and

microscopic examinations were conducted in which histopathology indicated slight

focal congestion and haemorrhages in the gastrointestinal tract of some of these

animals.

In a 90-day study in dogs that was not compliant with good laboratory practice

(General Electric, 1976), 32 Beagle dogs (four of each sex per dose group) were

administered BPA at 0, 1000, 3000 or 9000 mg/kg in the diet (Purina dog chow) for

90 days. Animals were individually housed with standard humidity and temperature

controls and weighed 6.5–13.4 kg at the start of the study. The European Union

(2003) estimated BPA intake to be 0, 28, 74 and 261 mg/kg bw per day in males and

0, 31, 87 and 286 mg/kg bw per day in females. Observations were made daily, a

general examination was conducted monthly, and body weight and feed consumption

were measured weekly. Standard haematology and clinical chemistry were conducted

monthly; ocular exams, urinalysis, selected organ weights, gross pathology and

histopathology (control and high-dose animals only) were also conducted. No effects

were noted with regard to mortality, appearance, behaviour, ophthalmology, body

weight, feed consumption, haematology, clinical chemistry, urinalysis, gross

pathology or histopathology. An increase in relative liver weight was observed in both

male (14%) and female (35%) dogs at the highest dose. Based on the findings for liver

at the high dose, the NOAEL is 3000 mg/kg (74 and 87 mg/kg bw per day in males

and females, respectively).

3. SUMMARY AND CONCLUSION

BPA has been tested in a variety of species, using multiple standard protocols, to

ascertain the potential acute, short-term and subchronic toxicity that may occur

following exposure. The available data suggest that BPA is of low acute toxicity.

With regard to repeated exposures, Tyl et al. (2002, 2008) conducted two large

multigenerational studies in rats and mice using dietary administration of BPA over a

wide range of doses (1 or 3 µg/kg bw up to 500 or 600 mg/kg bw), allowing for dose–

response assessment. These studies demonstrated effects on the liver, kidney and body

weight at doses of 50 mg/kg bw and higher. A more recent study by Stump et al.

(2010), which also used an expanded dose range and the same animal model as that

used by Tyl et al. (2002), demonstrated similar findings (on common end-points

examined), with a lowest NOAEL of 5 mg/kg bw. The liver also appeared to be a

target organ in a non-rodent model (dog), with a NOAEL of 74 mg/kg bw following

oral exposure.

There are no long-term toxicity studies with BPA other than the carcinogenicity

studies discussed in the background paper on carcinogenicity.


10

In conclusion, BPA is of low acute toxicity, and the lowest NOAEL for subchronic

exposure currently available is approximately 5 mg/kg bw per day, as identified in

several studies. No research needs were identified in this area.

REFERENCES

Chapin RE et al. (2008). NTP-CERHR expert panel report on the reproductive and developmental

toxicity of bisphenol A. Birth Defects Research. Part B, Developmental and Reproductive

Toxicology, 83:157–395.

Ema M et al. (2001). Rat two-generation reproductive toxicity study of bisphenol A. Reproductive

Toxicology, 15(5):505–523.

European Union (2003). European Union risk assessment report: 4,4′-isopropylidenediphenol

(bisphenol-A) risk assessment. European Commission, Joint Research Centre, European Chemicals

Bureau, Institute for Health and Consumer Protection. (EUR 20843 EN;

http://ecb.jrc.it/Documents/Existing-

Chemicals/RISK_ASSESSMENT/REPORT/bisphenolareport325.pdf).

General Electric (1976). Bisphenol-A: ninety day oral toxicity study in dogs. Unpublished report of

General Electric (IRDC Study 313-079) [cited in European Union, 2003].

Gold LS et al. (1984). A carcinogen potency database of the standardised results of animal bioassays.

Environmental Health Perspectives, 58:9–319 [cited in European Union, 2003].

Holson RR (2008). Statistical issues and techniques appropriate for developmental neurotoxicity

testing: a report from the ILSI Research Foundation/Risk Science Institute expert working group on

neurodevelopmental endpoints. Neurotoxicology and Teratology, 30(4):326–348.

Nitschke KD et al. (1988). Bisphenol A: 13-week aerosol toxicity study with Fischer 344 rats.

Unpublished report from The Dow Chemical Company.

NTP (1982) Carcinogenesis bioassay of bisphenol A (CAS No. 80-05-7) in F344 rats and B6C3F1 mice

(feed study). Research Triangle Park, NC, United States Department of Health and Human Services,

National Institutes of Health, National Toxicology Program, pp. 1–116 (Technical Report No. 215;

NTIS Order No. PB82-184060).

Stump DG et al. (2010). Developmental neurotoxicity study of dietary bisphenol A in Sprague-Dawley

rats. Toxicological Sciences, 115:167–182.

Takahashi O, Oishi S (2001). Testicular toxicity of dietary 2,2-bis(4-hydroxyphenyl)propane

(bisphenol A) in F344 rats. Archives of Toxicology, 75:42–51.

Til HP, Roverts WG, Beems RB (1978) Sub-chronic (90 day) oral toxicity study with

diphenylolpropane (DPP) in rats. Unpublished report No. R 6229 from TNO, the Netherlands.

Tyl RW et al. (2002). Three-generation reproductive toxicity study of dietary bisphenol A in CD

Sprague-Dawley rats. Toxicological Sciences, 68(1):121–146.

Tyl RW et al. (2008). Two-generation reproductive toxicity study of dietary bisphenol A in CD-1

(Swiss) mice. Toxicological Sciences, 104(2):362–384.

Yamasaki K et al. (2002a). Subacute oral toxicity study of ethynylestradiol and bisphenol A, based on

the draft protocol for the “Enhanced OECD Test Guideline no. 407”. Archives of Toxicology,

76:65–74.

Yamasaki K et al. (2002b). Changes of serum α2u-globulin in the subacute oral toxicity study of

ethynyl estradiol and bisphenol A based on the draft protocol for the “Enhanced OECD Test

Guideline No. 407”. Toxicology, 176:101–112.

Chemical Name : Diphenyl methane di-isocynate (MDI)

Synonyms: Methylene bisphenyl diisocyanate, 4,4-Diisocyanodiphenylmethane, Methylene bis(4-phenyl isocyanate),

Formula : C15H10N2O2

Toxic



CAS No: 101-68-8 UN No:Regulated Identification Shipping Name :Codes / Label : Hazardous Waste ID No :

Hazchem Code :Diphenylmethane-4,4'-diisocyanateToxic


2

3

4

Diphenyl methane di-isocynate (MDI)

101-68-8

2. PHYSICAL / CHEMICAL DATA196 deg C @ 5 mmHg

Solid White to pale yellow solid.

37 5.0X10-6 mm Hg @ 25 deg C

May have slightly musty odour

8.6 0.2 g/100ml (20 deg C)

1.197 @ 70 deg C

Hydrolyzed by water. Soluble in acetone, benzene, kerosene, and nitrobenzene.

Boiling Pt. °C:

Physical State:


Appearance:

Odour:



Others:


Melting Pt °C:

3. FIRE / EXPLOSION HAZARD DATAFlammability : 0.6 154TDG Flammability:

LEL:UEL:


Autoignition Temperature °C : 232Explosion sensitivity to impact:Explosion sensitivity to static Electricity:Hazardous Combustion Products : Toxic vapors are generated when heated.Hazardous Polymerization :Combustible Liquid:Flammable Material:Pyrophoric Material:



MATERIAL SAFETY DATA SHEETSDiphenyl methane di-isocynate (MDI)229

Stable under normal temperatures and pressures.Alcohols, alkalies, acids.

Combines vigorously or explosively with water.



:Page 1 of 3Diphenyl methane di-isocynate (MDI)

Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, cyanide fumes, nitrogen.



Inhalation : � Causes severe irritation of upper respiratory tract with coughing, burns, breathing difficulty, and possible coma. May cause asthmatic attacks due to allergic sensitization of the respiratory tract.�Ingestion : �Causes gastrointestinal tract irritation.�Skin : �Causes skin irritation.�Eye : �Causes eye irritation and possible burns.�

Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.



0.2 mg/m3 (0.02 ppm)

3 1 1



TLV (ACGIH) :



Inhalation:

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.

Skin:

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Eyes:


Ingestion:

LC50 (rat) mg/kg:

6. PREVENTIVE MEASURESEyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA s eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Do not allow water to get into the container because of violent reaction. Avoid contact with skin and eyes. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Keep from contact with moist air and steam.


Handling

:

:

Precautions :

Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a cool, dry place. Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substance

Storage :


Use dry sand or earth to smother fire.Do not use water. Most foams will react with the material and


FIRE:::

:

Page 2 of 3Diphenyl methane di-isocynate (MDI)

Clean up spills immediately with protective equipment. Sweep up or absorb material, then place in a dry closed container for disposal. Avoid generating dusty conditions. Remove all sources of ignition. Use a spark-proof tool. Do not expose spill to water.

First Aid Measures:


Steps To Be Taken


EXPOSURE:

SPILLS :

release corrosive/toxic gases. Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.May ignite or explode on contact with steam or moist air.Unusual Hazards :

Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.

Inhalation:


Skin:

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Eyes:


Ingestion:






10. DISCLAIMER


:

OTHERS :

Page 3 of 3Diphenyl methane di-isocynate (MDI)

Chemical Name : Isophorone diisocyanate

Synonyms: Isophoronc diamine diisocyanate, 3-Isocyanatomethyl-3,5,5-trimethylcyclohexyl isocyanate, IPDI

Formula : C12H18N2O2

Toxic




Hazchem Code :Isophorone diisocyanateClass 6.1, Toxic 17

2Z


34

Isophorone diisocyanate 4098-71-9

2. PHYSICAL / CHEMICAL DATA158 at 10 mm Hg

Liquid Clear, Colourless

-60 0.0003 mm Hg at 20Insoluble Miscible with aliphatic

and aromatic hydrocarbons, ether, ketones

Boiling Pt. °C:

Physical State:


Appearance:

Odour:



Others:


Melting Pt °C:

3. FIRE / EXPLOSION HAZARD DATAYesFlammability :

>110TDG Flammability:LEL:UEL:


Autoignition Temperature °C : 430Explosion sensitivity to impact:Explosion sensitivity to static Electricity:Hazardous Combustion Products : When decomposed, toxic gases (NOx) are released.Hazardous Polymerization : Will not occur.

YesYesNo

NoNoNo




MATERIAL SAFETY DATA SHEETSIsophorone diisocyanate333

Stable

Reacts with most substances containing active If atoms such as water, alcohols, phenols, amines, mercaptans, amides, methanes, ureas.



:

Page 1 of 3Isophorone diisocyanate

NoxHazardous Reaction Products5. HEALTH HAZARD DATA

Inhalation, Skin & Eyes, Ingestion

Inhalation: Respiratory tract irritation may occur. Pulmonary sensitization with bronchospasm on re-exposure is possible. Released oxides of nitrogen could produce severe irritation or pulmonary edema. Skin: Direct contact produces skin irritation. Dermal hypersensitivity reactions may be seen on re-exposure. Eyes: Irritation may result from direct eye contact. Exposure to vapors may produce irritation to the mucosa of the nose and throat. Ingestion: Gastrointestinal tract irritation could potentially occur.

Move patient to fresh air. Monitor for respiratory distress. Administer oxygen and assist ventilation as required. Treat bronchospasm with beta2 agonist and corticosteroid aerosols.



0.09 mg/m3 (0.01 ppm) (skin)

2 1 1 W



TLV (ACGIH) :



Inhalation:

Remove contaminated clothing and wash exposed area thoroughly with soap and water. A physician should examine the area if irritation or pain persists. Systemic antihistamine or corticosteroid therapy may be required for hypersensitivity reactions.

Skin:

Irrigate exposed eyes with copious amounts of tepid water for at least 15 minutes. If irritation, pain, swelling, lacrimation, or photophobia persist, the patient should be seen in a health care facility.

Eyes:

Do not induce vomiting. Activated charcoal: administer charcoal as a slurry (240 ml water/30 g charcoal). Usual dose: 25 to 100 g in adults/adolescents.

Ingestion:

0.26 mg/liter/4 hoursLC50 (rat) mg/kg:

6. PREVENTIVE MEASURESButyl rubber, latex or polyvinyl alcohol gloves, impervious clothing, face-shields, splash-proof goggles and respirators All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.


:

:

Precautions :Store in a cool, dry, well-ventilated location away from ignition sources.Storage :



Water spray or carbon dioxideThe fire-exposed containers should be kept cool by spraying water on them.When heated to decomposition, it emits toxic fumes of nitrogen oxides


Unusual Hazards

FIRE:::

:

Move patient to fresh air. Monitor for respiratory distress. Administer oxygen and Inhalation:

:


Shut off all ignition sources. Ventilate the area of spill. Absorb or scoop on a paper and transfer to a container for disposal.The chemical may be disposed of by dissolving in an appropriate solvent and atomizing in a combustion chamber.


Steps To Be Taken


SPILLS :

assist ventilation as required. Treat bronchospasm with beta2 agonist and corticosteroid aerosols.Remove contaminated clothing and wash exposed area thoroughly with soap and water. A physician should examine the area if irritation or pain persists. Systemic antihistamine or corticosteroid therapy may be required for hypersensitivity reactions.

Skin:

Irrigate exposed eyes with copious amounts of tepid water for at least 15 minutes. If irritation, pain, swelling, lacrimation, or photophobia persist, the patient should be seen in a health care facility.

Eyes:

Do not induce vomiting. Activated charcoal: administer charcoal as a slurry (240 ml water/30 g charcoal). Usual dose: 25 to 100 g in adults/adolescents.

Ingestion:

8. ADDITIONAL INFORMATION / REFERENCESThis chemical is used in paints and varnishes.9. MANUFACTURERS / SUPPLIERS DATA




10. DISCLAIMER


:

OTHERS :


Chemical Name : Toluene 2,4-diisocyanate

Synonyms: 2,4-Toluene diisocyanate, TDI, 2,4-Diisocyanatotoluene, 4-Methyl-m-phenylene diisocyanate

Formula : C9H6N2O2

Toxic, Flammable




Hazchem Code :Toluene diisocyanateClass 6.1, Toxic, Flammable 17

2Z


34

Toluene 2,4-diisocyanate 584-84-9

2. PHYSICAL / CHEMICAL DATA251 Liquid / solid Clear to light yellow

liquid or crystals19.5-21.5 8.0X10-3 mm Hg

@ 20 deg CSharp pungent odour.

6.0 Insoluble

1.2244 @ 20 deg C/4 deg C

Miscible with alcohol (decomp.) ether, acetone, benzene, CCl4.

Boiling Pt. °C:

Physical State:


Appearance:

Odour:



Others:


Melting Pt °C:




Autoignition Temperature °C : > 148.8Explosion sensitivity to impact: StableExplosion sensitivity to static Electricity: StableHazardous Combustion Products : Emits highly toxic fumes of NOx.Hazardous Polymerization : Will not occur.

YesNoNo

NoNoNo




MATERIAL SAFETY DATA SHEETSToluene 2,4-diisocyanate629

StableStrong oxidizers, water, acids, bases & amines (may cause foam & spatter); alcohols. Reacts slowly with water to form carbon dioxide and polyureas.Violent polymerisation reaction with bases or acyl chloride with water to


Reactivity


:Page 1 of 3Toluene 2,4-diisocyanate

release CO2Hazardous Reaction Products5. HEALTH HAZARD DATA

Inhalation, Ingestion, Stan &. Eyes.

Inhalation : Sensitiser and lung irritant. Causes asthma, pneumonitis, pulmonary edema, nocturnal cough and shortness of breath. Repeated low level exposure may produce lung disease. Eyes & Skin: Causes severe irritation. Oral toxicity is low.

Remove the victim to fresh air area, apply artificial respiration or oxygen if needed.



5800 mg/kg 0.02 ppm (0.15 mg/m3)0.4-2.14 ppm

0.005 ppm (0.04 mg/m3)

3 1 3



TLV (ACGIH) :



Inhalation:Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Get medical aid if symptoms occur.

Skin:

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Eyes:

Never give anything by mouth to an unconscious person. Get medical aid immediately. Do not induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.

Ingestion:

LC50 (rat) mg/kg:

6. PREVENTIVE MEASURESAvoid contact with liquid or vapour. Provide self-contained breathing apparatus, side covered safety goggles I face shield, rubber hand gloves, protective overclothing and shoes. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Avoid breathing dust, vapor, mist, or gas. Do not allow contact with water.


Handling

:

:

Precautions :

Keep in cool, dry, well ventilated area, away from heat, flame or Oxidisers. Storage in Polyethylene containers is hazardous due to absorption of water through the plastic.

Storage :



Dry chamical powder, Water, foam, CO2.Keep the containers cool by spraying water if exposed to heal or flame.Poisonous gases are produced in fire.


Unusual Hazards

FIRE:::

:

Remove the victim to fresh air area, apply artificial respiration or oxygen if needed.Inhalation:Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Get medical aid if symptoms occur.

Skin:

:

Page 2 of 3Toluene 2,4-diisocyanate

Shut off leaks if without risk. Contain the leakage on earth or sand.Seal all the waste in vapour light plastic bags for eventual disposal


Steps To Be TakenWaste Disposal Method:

SPILLS :

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Eyes:


Ingestion:

8. ADDITIONAL INFORMATION / REFERENCESAn experimental carcinogen. Combustible when exposed to heat or flame. Explosive in the form of vapours when exposed to heat or flame.9. MANUFACTURERS / SUPPLIERS DATA




10. DISCLAIMER


:

OTHERS :


Chemical Name : Toluene 2,6-diisocyanate

Synonyms: 2,6-Diisocyanate-1-methylbenzene, 2,6-Diisocya-natotoluene, 2,6-TDI, TolyIene-2,6-diisocyanate

Formula : C9H6N2O2

Toxic




Hazchem Code :Toluene diisocyanateClass 6.1, Toxic 17

2Z


34

Toluene 2,6-diisocyanate 91-08-7

2. PHYSICAL / CHEMICAL DATA129-133 °C at 18 mm Hg

Liquid Clear, colorless or pale yellow liquid

18.3 0.021 mm Hg @ 25 deg C

Pungent

6.0 Decomposes

1.22

Miscible with ether and benzene.

Boiling Pt. °C:

Physical State:


Appearance:

Odour:



Others:


Melting Pt °C:

3. FIRE / EXPLOSION HAZARD DATANoFlammability : > 112

TDG Flammability:LEL:UEL:


Autoignition Temperature °C : >620Explosion sensitivity to impact:Explosion sensitivity to static Electricity:Hazardous Combustion Products : When decomposed, toxic gases and vapours (such as

NOx) are released.Hazardous Polymerization : Non-hazardous polymerisation.

YesNoNo

NoNoNo




MATERIAL SAFETY DATA SHEETSToluene 2,6-diisocyanate630

StableWater, strong oxidiscrs, acids, bases

Polymerization reaction with bases



:



Inhalation, Skin & Eyes. Ingestion

It is a sensitizer and lung irritant. May cause asthma, pneumonitis, pulmonary edema, cough and shortness of breath. Causes severe irritation to eyes and skin.

Move the exposed person to fresh air at once. If breathing has stopped, perform artificial respiration. If there is breathing difficulty, give oxygen and keep the person warm and at rest.



0.091 mg/liter/4 hours (Mouse)

0.02 ppm (0.15 mg/m3)

2.10 ppm

0.005 ppm (0.04 mg/m3)

2 1 0



TLV (ACGIH) :

STEL:

Odour Threshold:


Inhalation:


Skin:

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Do not allow victim to rub or keep eyes closed.

Eyes:

Never give anything by mouth to an unconscious person. Get medical aid. Do not induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.

Ingestion:

LC50 (rat) mg/kg:

6. PREVENTIVE MEASURESImpervious clothing, gloves, face-shields, splash-proof goggles and supplied-air or self-contained breathing apparatus Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation. Do not allow contact with water. Wash clothing before reuse. Keep from contact with moist air and steam.


:

:

Precautions :

Store in a cool, dry, well ventilated location away from other areas where the fire hazard may be acute. Separate from other storage. Outside or detached storage is preferred. If stored in tanks, it should be blanketed with an inert gas, such as nitrogen.

Storage :



Water spray or carbon dioxideThe fire-exposed containers should be kept cool by spraying water on them.


Unusual Hazards

FIRE:::

:

Move the exposed person to fresh air at once. If breathing has stopped, perform artificial respiration. If there is breathing difficulty, give oxygen and keep the person warm and at rest.

Inhalation:

:


Ventilate the area of spill Absorb or scoop on a paper and transfer to a container for disposal.The chemical may be disposed of by dissolving in an appropriate solvent and atomizing in a combustion chamber.


Steps To Be Taken


SPILLS :


Skin:

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Do not allow victim to rub or keep eyes closed.

Eyes:

Never give anything by mouth to an unconscious person. Get medical aid. Do not induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.

Ingestion:






10. DISCLAIMER


:

OTHERS :


of 4

MATERIAL SAFETY DATA SHEET SECTION 1 - IDENTIFICATION OF THE MATERIAL AND SUPPLIER Material Name: Paraformaldehyde.

Catalogue Number: C007.

Other Names: Polyoxymethylene; Metaformaldehyde; Paraform.

Recommended Use: Used as a fixative in electron microscopy.

Supplier Name: ProSciTech

Street Address: 1/11 Carlton Street, Kirwan, Qld. 4817 Australia

Telephone Number: (07) 4773 9444 - 8:30am – 5:00pm, Monday to Friday (excluding Public Holidays)

Emergency Contact: (07) 4773 9444 - 8:30am – 5:00pm, Monday to Friday (excluding Public Holidays)

SECTION 2 - HAZARDS IDENTIFICATION Hazard Classification: Hazardous according to the criteria for Classifying Hazardous Substances [NOHSC:1008].

Hazardous and/or Dangerous Nature: HAZARDOUS SUBSTANCE. DANGEROUS GOODS.

Risk Phrases: R23/24/25 Toxic by inhalation, in contact with skin and if swallowed.

R34 Causes burns.

R40 Limited evidence of a carcinogenic effect.

R43 May cause sensitisation by skin contact.

Safety Phrases: S1/2 Keep locked up and out of reach of children.

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

S36/37 Wear suitable protective clothing and gloves.

S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

S51 Use only in well ventilated areas.

Refer to Section 15 for Poisons Schedule.

SECTION 3 - COMPOSITION /INFORMATION ON INGREDIENTS

Pure Substance (Proportion 100%): Chemical Identity: Paraformaldehyde.

Common Name(s): Polyoxymethylene; Metaformaldehyde; Paraform.

CAS Number: 50-00-0

Mixture Substance: Ingredients Cas Number(s) Proportion (%)

Paraformaldehyde 30525-89-4 90-100

Water 7732-18-5 0-10

SECTION 4 - FIRST AID MEASURES Ingestion: Seek medical attention. If individual is drowsy or unconscious, do not give anything by

mouth; place individual on the left side with the head down. Contact a physician,

medical facility, or poison control center for advice about whether to induce vomiting. If

possible do not leave person unattended.

Inhalation: If symptoms develop, immediately move individual away from exposure and into fresh

air. Seek immediate medical attention; keep person warm and quiet. If person is not

breathing, begin artificial respiration. If breathing is difficult, administer oxygen.

Eye Contact: If material gets into the eyes, immediately flush eyes gently with water for at least 15

minutes while holding eyelids apart. If symptoms develop as a result of vapour

exposure, immediately move individual away from exposure and into fresh air before

flushing as recommended above. Seek immediate medical attention.

Skin Contact: Immediately flush skin with water for at least 15 minutes while removing contaminated

clothing and shoes. Seek medical attention. Wash clothing before reuse and discard

contaminated shoes.

First Aid Facilities: Eyebath/eyewash, Safety shower & general washroom facilities.

Medical Attention & Special Treatment:

Not available.

of 4

Additional Information:

Danger may be fatal if swallowed, inhaled or absorbed through skin. Causes irritation to skin, eyes and

respiratory tract. Sensitizer. Suspect cancer hazard. Emits formaldehyde which may cause cancer. Risk of

cancer depends upon duration and level of exposure. Combustible solid.

SECTION 5 - FIRE FIGHTING MEASURES Suitable Extinguishing Media:

Water mist, carbon dioxide (co2), dry chemical.

Hazards from Combustion Products:

May form: carbon dioxide and carbon monoxide, various hydrocarbons.

Precautions for Fire Fighters:

Never use welding or cutting torch on or near drum (even empty) because product (even just residue) can ignite

explosively. Wear full fire fighting turn-out gear (full bunker gear) and respiratory protection (SCBA).

Hazchem Code: 4ZE

SECTION 6 - ACCIDENTAL RELEASE MEASURES Emergency Procedures:

Eliminate all ignition sources (flares, flames including pilot lights, electrical sparks). Persons not wearing

protective equipment should be excluded from area of spill until clean-up has been completed.

Containment & Clean up:

Large spill: Stop spill at source. Prevent from entering drains, sewers, streams or other bodies of water. Prevent

from spreading. If runoff occurs, notify authorities as required. Pump or vacuum transfer spilled product to clean

containers from recovery. Absorb unrecoverable product. Transfer contaminated absorbent, soil and other

materials to containers for disposal.

Small spill: absorb liquid on vermiculite, floor absorbent, or other absorbent material and transfer to hood.

SECTION 7 - HANDLING & STORAGE Precautions for Safe Handling:

Wear special protective equipment. Wash hands, face, forearms, and neck when exiting restricted areas. Change

to clean garments at the end of the day. Avoid dust formation and control ignition sources. Employ grounding,

venting, and explosion relief provisions in accord with accepted engineering practices in any process capable of

generating dust and or static electricity. Empty only into inert or non-flammable atmosphere. Emptying contents

into a non-inert atmosphere where flammable vapours may be present could cause a flash fire or explosion due

to static discharge. Containers of this material may be hazardous when empty since they retain product residues

(dust, solids), observe all warnings and precautions listed for the product.

Precautions for Safe Storage:

Store in a tightly closed container. Protect against physical damage. Outside or detached storage is preferred.

Inside storage should be in a standard flammable liquids storage room or cabinet. Separate from oxidizing

materials.

SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION National Exposure Standards: Formaldehyde CAS 50-00-0:

TWA 1ppm

TWA 1.2mg/m3

STEL 2ppm

STEL 2.5mg/m3

Biological Limit Values: No biological limit allocated.

Engineering Controls:

A system of local and or general exhaust is recommended to keep employee exposures below the airborne

exposure limits. Local exhaust ventilation is generally preferred because it can control the emissions of the

contaminant at its source, preventing dispersion of it into the general work area.

Personal Protective Equipment:

Respiratory protection: If overexposure has been determined or documented, a NIOSH approved air supplied

respirator is advised in absence of proper environmental control. OSHA regulations also permit other NIOSH

respirators under specified conditions. Engineering or administrative controls should be implemented to reduce

exposure.

Eye protection: Chemical splash goggles and face shield (8” min) in compliance with OSHA regulations are

advised; however, OSHA regulations also permit other type safety glasses. (Consult your industrial hygienist).

Skin protection: Wear impervious gloves (consult your safety equipment supplier) to prevent skin contact, wear

impervious clothing and boots.

of 4

Other protective clothing or equipment: Personal protective equipment should be selected for individual

applications and should consider factors which affect exposure potential, such as handling practices, chemical

concentrations and ventilation. It is ultimately the responsibility of the employer to follow regulatory guidelines

established by local authorities.

Work hygienic practices: See OSHA standard for more info on personal protective equipment, engineering and

work practice controls. (29 CFR 1910.1048)

SECTION 9 - PHYSICAL & CHEMICAL PROPERTIES Appearance: Clear to white solid.

Odour: Pungent odour.

pH: 4.3

Vapour pressure (mm of Hg at °C): 1.4mmhg at 25°C.

Vapour density: (Air = 1): 1.03

Boiling point/range (°C): Slowly sublimes to formaldehyde gas.

Freezing/melting point (°C): Melting point 120-170°C.

Solubility: Slightly soluble in cold water.

Specific gravity or density: Not available.

Flash Point: 70°C.

Flammable (explosive) limits: Lower limit: 7.0

Upper limit: 73

Ignition temperature: 300°c.

Additional Information: Not available.

SECTION 10 - STABILITY AND REACTIVITY Chemical stability: Stable under normal conditions of use.

Conditions to avoid: Heat, flame, ignition sources, dusting and incompatible materials.

Incompatible Materials: Alkali metals, alkalis, amines, isocyanates, nitrogen oxides, strong mineral

acids, strong oxidizing agents.

Hazardous Decomposition Products:

May form: dioxide and carbon monoxide, formaldehyde, hydrogen, various hydrocarbons.

Hazardous Reactions: Will not occur.

SECTION 11 - TOXICOLOGICAL INFORMATION Exposure and Health Effects:

Danger may be fatal if swallowed, inhaled or absorbed through skin. Causes irritation to skin, eyes and

respiratory tract. Sensitizer. Suspect cancer hazard. Emits formaldehyde which may cause cancer. Risk of cancer

depends upon duration and level of exposure. Combustible solid. Prolonged and repeated contact may cause

allergic dermatitis or asthma. May harm the kidneys. Pre-existing respiratory or allergic conditions may be

aggravated in some individuals by exposure to fumes and gases., pre-existing disorders of the following organs

(or organ systems) may be aggravated by exposure to this material; skin, lung (for example, asthma-like

conditions), eye.

Ingestion:

Swallowing this material may be harmful. Exposure causes severe irritation of the gastrointestinal tract. Severe

stomach pains will follow with possible loss of consciousness.

Inhalation:

This material is a dust or may produce dust. Breathing of dust, vapor and/or fume is possible. Breathing this

material may be harmful.

Eye Contact:

Can cause severe eye irritation. Symptoms include stinging, tearing, redness, and swelling of eyes. Can injure

eye tissue.

Skin Contact:

Can cause severe skin irritation. Prolonged or repeated contact may include redness, burning, and drying and

cracking of skin, skin burns, and other skin damage. Additional symptoms of skin contact may include:

abnormal colouring of the skin allergic skin reaction (delayed skin rash which may be followed by blistering,

scaling and other skin effects).

Human/Animal data: Acute oral toxicity- paraformaldehyde ld 50 rat: 800mg/kg

Acute dermal toxicity –paraformaldehyde ld 50 rabbit: 10,000 mg/kg

Carcinogenic Category: Group 1: Carcinogenic to humans.

Other Carcinogenic

Information:

Not available.

of 4

SECTION 12 – ECOLOGICAL INFORMATION Ecotoxicity: No data available.

Persistence and degradability: No data available.

Mobility: No data available.

Additional Information: No data available.

SECTION 13 - DISPOSAL CONSIDERATIONS Disposal Methods:

Destroy by liquid incineration with off-gas scrubber. Do not discharge effluent containing this product into

lakes, streams, ponds, or estuaries, oceans or other waters unless in accordance with the requirements of a

national pollutant discharge elimination system permit, and the permitting authority has been notified in writing

prior to discharge. Do not discharge effluent containing this product to sewer systems without previously

notifying the local sewage treatment plant authority.

Special Precautions/Additional Informational:

Dispose of in accordance with Local, State and Federal regulations.

SECTION 14 - TRANSPORT INFORMATION UN Number: UN2213

UN Proper Shipping Name: Paraformaldehyde

Class and Subsidiary risk: 4.1

Packing Group: PG III

Special Precautions for User: Not available.

Hazchem Code: 4ZE

SECTION 15 - REGULATORY INFORMATION Poison Schedule Number: None Allocated.

SECTION 16 - OTHER INFORMATION Date of preparation of MSDS:

April 11

Comments:

List of Publications referenced when creating this MSDS; - Hazardous Substances Information System Consolidated Lists: Safe Work Australia.

- APPROVED CRITERIA FOR CLASSIFYING HAZARDOUS SUBSTANCES [NOHSC:1008(2004)] 3rd

Edition: National Occupational Health and Safety Commission.

- Dangerous Goods - Initial Emergency Response Guide (SAA/SNZ HB76:1997).

- IATA Dangerous Goods Regulations.

- Adopted National Exposure Standards for Atmospheric Contaminants in the Occupational Environment

[NOHSC:1003(1995)].

- Australia Standard for the Uniform Scheduling of Drugs and Poisons [SUSPD] (Australian Government

Department of Health and Ageing). This Material Safety Data Sheet (MSDS) has been prepared in compliance with the National code of Practice for the Preparation of Material

Safety Data Sheets 2nd Edition [NOHSC:2011(2003)]. It is the user's responsibility to determine the suitability of this information for

adoption of necessary safety precautions. The information published in this MSDS has been compiled from the publications listed in Section 16: to the best of our ability and knowledge these publications are considered accurate. We reserve the right to revise Material Safety Data

Sheets as new information becomes available. Copies may be made for non-profit use.

… End of MSDS …

CYCLOHEXANONE CCH


Common Synonyms Watery liquid Colorless to light yellow Sweet,peppermint odor

Floats and mixes slowly with water.

AnoneCyclohexyl ketoneHytrol ONadonePimelic ketoneSextone

Keep people away. Avoid contact with liquid.Wear goggles, self-contained breathing apparatus, and rubber overclothing(including gloves).Call fire department.Notify local health and pollution control agencies.Protect water intakes.

Fire Combustible.Extinguish with water, dry chemical, foam, or carbon dioxide.


LIQUIDWill burn skin and eyes.Harmful if swallowed.Remove contaminated clothing and shoes.Flush affected areas with plenty of water.IF IN EYES, hold eyelids open and flush with plenty of water.IF SWALLOWED, and victim is CONSCIOUS, have victim drink wateror milk.

WaterPollution

Effect of low concentrations on aquatic life is unknown.May be dangerous if it enters water intakes.Notify local health and pollution control officials.Notify operators of nearby water intakes.

1. CORRECTIVE RESPONSE ACTIONSDilute and disperseStop dischargeContainCollection Systems: SkimSalvage waterfowl


2.1 CG Compatibility Group: 18; Ketone2.2 Formula: (CH2)5CO


51628

3. HEALTH HAZARDS

3.1 Personal Protective Equipment: Chemical goggles.

3.2 Symptoms Following Exposure: Inhalation of vapors from hot material can cause narcosis. Theliquid may cause dermatitis.

3.3 Treatment of Exposure: Immediately flush eyes with plenty of water; call a physician.

3.4 TLV-TWA: 25 ppm



3.7 Toxicity by Ingestion: Grade 2; LD50 = 0.5 to 5 g/kg




3.11 Liquid or Solid Characteristics: Causes smarting of the skin and first-degree burns on shortexposure and may cause secondary burns on long exposure.

3.12 Odor Threshold: 0.12 ppm

3.13 IDLH Value: 700 ppm

3.14 OSHA PEL-TWA: 50 ppm




4. FIRE HAZARDS



4.3 Fire Extinguishing Agents: Water, drychemical, foam, or carbon dioxide.



















6. WATER POLLUTION

6.1 Aquatic Toxicity:Currently not available




6.5 GESAMP Hazard Profile:Bioaccumulation: 0Damage to living resources: 1Human Oral hazard: 1



7.1 Grades of Purity: Technical: 99.87%

7.2 Storage Temperature: Currently not available

7.3 Inert Atmosphere: Currently not available

7.4 Venting: Currently not available


7.6 Ship Type: 3



8.1 49 CFR Category: Flammable liquid

8.2 49 CFR Class: 3









8.8 RCRA Waste Number: U057



PROPERTIES



9.3 Boiling Point at 1 atm: 312.4°F = 155.8°C =429.0°K

9.4 Freezing Point: –24.2°F = –31.2°C =242.0°K

9.5 Critical Temperature: 672.8°F = 356°C =629.2°K

9.6 Critical Pressure: 560 psia = 38 atm = 3.8MN/m2


9.8 Liquid Surface Tension: 34 dynes/cm =0.034 N/m at 20°C

9.9 Liquid Water Interfacial Tension: 90dynes/cm = 0.090 N/m at 22.7°C




9.13 Heat of Combustion: –15,430 Btu/lb =–8570 cal/g = –358.8 X 105 J/kg







NOTES

JUNE 1999

CYCLOHEXANONE CCH




35404550556065707580859095

100105110115120125130135140

60.02059.88059.73059.58059.44059.29059.14058.99058.85058.70058.55058.40058.26058.11057.96057.81057.67057.52057.37057.22057.08056.930




35404550556065707580859095

100

0.4190.4210.4240.4270.4300.4320.4350.4380.4410.4440.4460.4490.4520.455




35404550556065707580859095

1.0661.0541.0431.0321.0211.0100.9980.9870.9760.9650.9540.9420.931



Centipoise

556065707580859095

100105110115120125130135140145150155160165170175

2.5132.3772.2502.1332.0231.9211.8261.7371.6541.5771.5041.4361.3721.3121.2551.2021.1521.1051.0601.0180.9780.9410.9050.8720.840




68 5.000




60708090

100110120130140150160170180190200210220230240250260270280290300

0.3270.4070.5030.6160.7500.9071.0901.3011.5431.8212.1372.4962.9003.3553.8634.4305.0605.7576.5267.3728.2999.313

10.42011.62012.920




60708090

100110120130140150160170180190200210220230240250260270280290300

0.005750.007020.008520.010250.012260.014560.017190.020170.023530.027310.031540.036240.041460.047210.053550.060490.068070.076330.085290.094980.105400.116700.128800.141700.15550




0255075

100125150175200225250275300325350375400425450475500525550575600

0.2220.2370.2510.2650.2790.2930.3060.3200.3340.3470.3600.3730.3860.3990.4120.4250.4370.4500.4620.4740.4860.4980.5100.5220.534

JUNE 1999

Chemical Name : Cyclohexanone

Synonyms: Ketohexamethylene, Pimelic ketone, Cyclohexyl ketone, Anone, Hytrol-O, NadoneFormula : C6H10O

Toxic, Flammable




Hazchem Code :CyclohexanoneClass3, Toxic, Flammable 5

3Y


34

Cyclohexanone 108-94-1

2. PHYSICAL / CHEMICAL DATA155.6 Liquid Colorless to pale

yellow oily liquid.-31 5 mm Hg at 26.4

deg CSweet, sharp, mildly pleasant odor like acetone and peppermint.

3.4 50 g/L @ 30 deg C

0.9421 @ 25 deg C/4 deg C

Soluble in alcohol, ether, and other organic solvents.

Boiling Pt. °C:

Physical State:


Appearance:

Odour:



Others:


Melting Pt °C:

3. FIRE / EXPLOSION HAZARD DATAYesFlammability : 1.1 (at 100

deg C)9.4 44TDG Flammability:

LEL:

UEL:

Flash Point °C in OC:

Flash Point °C in CC:

Autoignition Temperature °C : 420Explosion sensitivity to impact: StableExplosion sensitivity to static Electricity:Hazardous Combustion Products : Fire may produce irritating, corrosive and/or toxic gases.Hazardous Polymerization : Will not occur.

YesYesNo

NoNoNo




MATERIAL SAFETY DATA SHEETSCyclohexanone162

Stable under normal temperatures and pressures. Forms explosive mixture with air.Oxidizing agents, strong acids, amines, nitric acid, plastics, rubber, sulfuric acid, alliphatic amines, lead, red metals , resins.

Chemical Stability

Incompatibility with other material

4. REACTIVITY DATA:

:

Page 1 of 3Cyclohexanone

Carbon monoxide, carbon dioxide, toxic gases.ReactivityHazardous Reaction Products5. HEALTH HAZARD DATA


Inhalation : � Inhalation of high concentrations may cause central nervous system effects characterized by headache, dizziness, unconsciousness and coma. May cause liver and kidney damage. May cause narcotic effects in high concentration. Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema. May cause irritation of the mucous membranes.�Ingestion : �Causes gastrointestinal irritation with nausea, vomiting and diarrhea. May cause liver and kidney damage. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure. May be harmful if swallowed.�Skin : �Causes skin irritation. Harmful if absorbed through the skin.�Eye : �May result in corneal injury. Vapors may cause eye irritation. Contact produces irritation, tearing, and burning pain.�

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Do not use mouth-to-mouth respiration.



50 ppm, skin.

50 ppm (200 mg/cu m)

0.88 ppm

20 ppm

1 2 0



TLV (ACGIH) :



Inhalation:


Skin:

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Eyes:


Ingestion:

LC50 (rat) mg/kg:

6. PREVENTIVE MEASURESEyes: Wear appropriate protective eyeglasses or chemical safety goggles. Skin: Wear appropriate protective gloves to prevent skin exposure.Wash thoroughly after handling. Use with adequate ventilation. Ground and bond containers when transferring material. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.


Handling

:

:

Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area.

Storage :

::


Precautions :

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up residual material by washing area with a 2-5% solution of soda ash.

First Aid Measures:


Steps To Be Taken


EXPOSURE:

SPILLS :


Alcohol foam, dry chemical or carbon dioxideIf material on fire or involved in fire: Do not extinguish fire unless flow can be stopped. Use water in flooding quantities as fog.Cool all affected containers with flooding quantities of water.


Unusual Hazards

FIRE:::

:

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Do not use mouth-to-mouth respiration.

Inhalation:


Skin:

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Eyes:


Ingestion:






10. DISCLAIMER


:

OTHERS :


Chemical Name : Diethylene glycol

Synonyms: 2,2'-Dihydroxyethyl ether, 3-Oxypentane-1,5-diol, Ethylene diglycol, 2,2'-Oxydiethanol

Formula : C4H10O3

Toxic




Hazchem Code :Toxic


34

Diethylene glycol 111-46-6

2. PHYSICAL / CHEMICAL DATA244-245 Liquid Colorless, syrupy

liquid-10.0 0.006 (25 deg C) Odourless

3.66 Miscible

1.18 @ 20 deg C/20 deg C

Miscible with water, alcohol, ether, acetone, ethylene glycol; insol in benzene, carbon tetrachloride.

Boiling Pt. °C:

Physical State:


Appearance:

Odour:



Others:


Melting Pt °C:

3. FIRE / EXPLOSION HAZARD DATAFlammability : 1.6 138-143



Autoignition Temperature °C : 229Explosion sensitivity to impact:Explosion sensitivity to static Electricity:Hazardous Combustion Products :Hazardous Polymerization :Combustible Liquid:Flammable Material:Pyrophoric Material:



MATERIAL SAFETY DATA SHEETSDiethylene glycol197

Stable under normal temperatures and pressures.Acids, methanoic acid, oxalic acid), azo, diazo, and hydrazines (e.g. dimethyl hydrazine, hydrazine, methyl hydrazine), isocyanates (e.g.



Page 1 of 3Diethylene glycol

methyl isocyanate), metals (alkali and alkaline, e.g. cesium, potassium, sodium), nitrides (e.g. potassium nitride)

Carbon monoxide, carbon dioxide, acrid smoke and fumes.ReactivityHazardous Reaction Products5. HEALTH HAZARD DATA


Inhalation : � May cause respiratory tract irritation. Inhalation of heated or misted form may cause pulmonary edema.�Ingestion : �May cause liver and kidney damage. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure. Human fatalities have been reported from acute poisoning.�Skin : �May cause mild skin irritation. May be absorbed through the skin.�Eye : �May cause mild eye irritation.

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.



15.6 g/kg

10 mg/m3

1 1 0



TLV (ACGIH) :



Inhalation:

Get medical aid. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.

Skin:

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Eyes:

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.

Ingestion:

LC50 (rat) mg/kg:

6. PREVENTIVE MEASURESEyes: Wear appropriate protective eyeglasses or chemical safety goggles. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Wash clothing before reuse.


Handling

:

:

Precautions :

Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep containers tightly closed. Store protected from moisture.

Storage :


To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.

Fire Extinguishing MediaFIRE:

:

::


Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Provide ventilation.

First Aid Measures:


Steps To Be Taken


EXPOSURE:

SPILLS :

Water or foam may cause frothing.Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.

Special Procedure

Unusual Hazards

:

:


Inhalation:

Get medical aid. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.

Skin:

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Eyes:

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.

Ingestion:






10. DISCLAIMER


:

OTHERS :


DIETHYLENE GLYCOL DEG


Common Synonyms Oily liquid Colorless Odorless


DEGDiglycolBis-(2-Hydroxyethyl)ether3-Oxa-1, 5-pentanediol2,2'-Oxybisethanol

Call fire department.Notify local health and pollution control agencies.

Fire Combustible.Extinguish with dry chemical, alcohol foam, or carbon dioxide.Water and foam may be ineffective on fire.Cool exposed containers with water.

Exposure Not harmful.

WaterPollution




2.1 CG Compatibility Group: 40; Glycol ether2.2 Formula: (HOCH2CH2)2O2.3 IMO/UN Designation: Not listed2.4 DOT ID No.: Not listed

2.5 CAS Registry No.: 111-46-62.6 NAERG Guide No.: Not listed2.7 Standard Industrial Trade Classification:

51616

3. HEALTH HAZARDS

3.1 Personal Protective Equipment: Full face mask with canister for short exposures to high vaporlevels; rubber gloves; goggles.

3.2 Symptoms Following Exposure: Ingestion of large amounts may cause degeneration of kidney andliver and cause death. Liquid may cause slight skin irritation.

3.3 Treatment of Exposure: INHALATION: no problem likely. If any ill effects do develop, get medicalattention. INGESTION: induce vomiting if ingested. No known antidote; treat symptomatically.EYE AND SKIN: flush with water. If any ill effects occur, get medical attention.




3.7 Toxicity by Ingestion: Grade 0; LD50 above 15 g/kg (rat)


3.9 Chronic Toxicity: Kidney and liver damage.

3.10 Vapor (Gas) Irritant Characteristics: None

3.11 Liquid or Solid Characteristics: None







4. FIRE HAZARDS

4.1 Flash Point: 255°F C.C.


4.3 Fire Extinguishing Agents: Alcohol foam,carbon dioxide, dry chemical

4.4 Fire Extinguishing Agents Not to BeUsed: Water or foam may causefrothing.













5.2 Reactivity with Common Materials: Notpertinent





6. WATER POLLUTION

6.1 Aquatic Toxicity:> 32,000 ppm/96 hr/mosquito fish/TLm/

fresh water


6.3 Biological Oxygen Demand (BOD): 6%,5 days



Damage to living resources: 0Human Oral hazard: 2Human Contact hazard: IReduction of amenities: XX


7.1 Grades of Purity: Regular grade; polyestergrade





7.6 Ship Type: Data not avaialable
















PROPERTIES




9.4 Freezing Point: 20°F = –8°C = 265°K

9.5 Critical Temperature: 766.4°F = 408°C =681.2°K

9.6 Critical Pressure: 680 psia = 46 atm = 4.7MN/m2














NOTES

JUNE 1999

DIETHYLENE GLYCOL DEG




405060708090

100110120130140150160170180190200210

70.80970.44070.08069.71969.34968.99068.62068.25967.90067.53067.16966.79966.44066.07065.70965.34964.98064.620




405060708090

100110120130140150160170180190200210

0.5340.5400.5450.5510.5570.5620.5680.5730.5790.5840.5900.5950.6010.6070.6120.6180.6230.629




65707580859095

100105110115120125130135140145150

1.4421.4421.4421.4421.4421.4421.4421.4421.4421.4421.4421.4421.4421.4421.4421.4421.4421.442



Centipoise

NOT

PERTINENT




MISCIBLE




80100120140160180200220240260280300320340360380

0.0000.0000.0010.0010.0030.0080.0160.0340.0670.1280.2370.4240.7361.2432.0463.288




80100120140160180200220240260280300320340360380

0.000000.000000.000010.000020.000050.000120.000240.000490.000950.001760.003170.005520.009330.015370.024670.03871




NOT

PERTINENT

JUNE 1999

DIPHENYLMETHANE DIISOCYANATE DPM


Common Synonyms Solid White to light yellow

Sinks in water.

Carwinate 125 MDiphenylmethane-4,4'-diisocyanateHylene M50MDIMultrathane MNacconate 300Vilrathane 4300

Keep people away. Avoid contact with solid and dust.Avoid inhalation.Call fire department.Notify local health and pollution control agencies.Protect water intakes.

Fire Combustible.Wear goggles and self-contained breathing apparatus.Extinguish with foam, dry chemical or carbon dioxide.


SOLIDIrritating to skin and eyes.Flush affected areas with plenty of water.IF IN EYES, hold eyelids open and flush with plenty of water.

WaterPollution


1. CORRECTIVE RESPONSE ACTIONSStop dischargeCollection Systems: DredgeDo not burn


2.1 CG Compatibility Group: 12; Isocyanate2.2 Formula: (p-OCNC6H4)2CH2

2.3 IMO/UN Designation: Not listed

2.4 DOT ID No.: 24892.5 CAS Registry No.: 101-68-82.6 NAERG Guide No.: 1562.7 Standard Industrial Trade Classification:

51489

3. HEALTH HAZARDS

3.1 Personal Protective Equipment: Approved mask or respirator; clean rubber gloves; chemicalgoggles; clean waterproof or freshly laundered protective clothing (coveralls, rubber boots, cap,etc.).

3.2 Symptoms Following Exposure: Breathlessness, chest discomfort, and reduced pulmonary function.

3.3 Treatment of Exposure: INHALATION: treat symptomatically; vaso-dilators; oxygen. Call aphysician. SKIN CONTACT: wash with soap and water. Rubbing alcohol helpful. EYE CONTACT:flush with water at least 15 min. Call a physician.

3.4 TLV-TWA: 0.005 ppm



3.7 Toxicity by Ingestion: Currently not available



3.10 Vapor (Gas) Irritant Characteristics: Severe irritation of eyes and throat; can cause eye and lunginjury. Cannot be tolerated even at low concentrations.

3.11 Liquid or Solid Characteristics: Minimum hazard. If spilled on clothing and allowed to remain, maycause reddening of the skin.





3.16 OSHA PEL-Ceiling: 0.02 ppm


4. FIRE HAZARDS

4.1 Flash Point: 425°F O.C.

4.2 Flammable Limits in Air: Not pertinent

4.3 Fire Extinguishing Agents: Carbondioxide, dry chemical or foam


4.5 Special Hazards of CombustionProducts: Toxic vapors are generatedwhen heated.

4.6 Behavior in Fire: Solid melts and burns


4.8 Electrical Hazards: Currently notavailable








5.1 Reactivity with Water: Slow, non-hazardous. Forms carbon dioxide gas.

5.2 Reactivity with Common Materials:Currently not available



5.5 Polymerization: May occur slowly. Is nothazardous.


6. WATER POLLUTION

6.1 Aquatic Toxicity:Currently not available





Human Contact hazard: IIReduction of amenities: XXX


7.1 Grades of Purity: Solid grades: 91-99%; liquidgrades may contain 50% o-dichlorobenzene

7.2 Storage Temperature: 0° -40°F

7.3 Inert Atmosphere: Not pertinent

7.4 Venting: Pressure-vacuum

7.5 IMO Pollution Category: B

7.6 Ship Type: 2



8.1 49 CFR Category: Keep Away From Food

8.2 49 CFR Class: 6.1












9.4 Freezing Point: 100°F = 37.7°C = 311°K









9.13 Heat of Combustion: Not pertinent







NOTES

JUNE 1999

DIPHENYLMETHANE DIISOCYANATE DPM




NOT

PERTINENT




NOT

PERTINENT




NOT

PERTINENT



Centipoise

100105110115120125130135140145150155160165170175180185190195200205210

6.6206.2055.8225.4695.1434.8414.5624.3034.0633.8403.6323.4393.2593.0912.9342.7872.6502.5222.4012.2892.1832.0831.989




INSOLUBLE




NOT

PERTINENT




NOT

PERTINENT




NOT

PERTINENT

JUNE 1999

Chemical Name : Ethyl acetate

Synonyms: Acetic acid ethyl ester, Acetic ether, Acetoxyethane, Vinegar naphthaFormula : C4H8O2

Flammable, Irritant




Hazchem Code :Ethyl acetateClass 3, Flammable, Irritant 5

3YE


34

Ethyl acetate 141-78-6

2. PHYSICAL / CHEMICAL DATA77.1 Liquid Colourless, watery.

-83 91 (25 deg C) Pleasant fruity odour.

3.04 50-100 mg/mL at 21°C

0.902 at 20°C

Misc. with alcohol, acetone chloroform, etherNeutral

Boiling Pt. °C:

Physical State:


Appearance:

Odour:



Others:


Melting Pt °C:

3. FIRE / EXPLOSION HAZARD DATAYesFlammability : 2.2 12.83 11.4 -4.4TDG Flammability:

LEL:UEL:


Autoignition Temperature °C : 426.6Explosion sensitivity to impact: StableExplosion sensitivity to static Electricity:Hazardous Combustion Products : Emits acrid smoke and irritating fumes.Hazardous Polymerization : Will not occur.

YesYesNo

NoNoNo




MATERIAL SAFETY DATA SHEETSEthyl acetate247

StableNitrates, strong oxidisers, alkalies & acids

Violent reaction with chloro sulfonic acid, (LiAlH2 + 2 - chloromethylfuran), oleum. Reacts vigorously with oxidising materials.



:

Page 1 of 3Ethyl acetate



Inhalation : Causes headache, dizziness, nausea, weakness, loss of consciousness, irritation of respiratory passage. Eyes : Causes irritation & dizziness. Skin : Causes irritation.




5620mg/kg

400 ppm (1400 mg/m3)

0.006 To 0.686 mg/L

400 ppm (1400 mg/m3)

1 3 0



TLV (ACGIH) :



Inhalation:

Wash the affected area with plenty of water & soap. Seek medical aid immediately.Skin:First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes

Eyes:


Ingestion:

LC50 (rat) mg/kg:

6. PREVENTIVE MEASURESAvoid contact with liquid or vapours. Provide organic vapour canister mask, face shield, and hand gloves. Wash thoroughly after handling. Use with adequate ventilation. Ground and bond containers when transferring material. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.


:

:

Precautions :

Store in a cool, dry, well ventilated area, away from heat, sparks, flame, and oxidising agents.

Storage :



Alcohol foam , CO2, dry chemical powder. Do not use water jet.Keep the containers cool by spraying water if exposed to heat or flame.Flashback along vapour trail may occur.


Unusual Hazards

FIRE:::

:


Inhalation:

Wash the affected area with plenty of water & soap. Seek medical aid immediately.Skin:First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes

Eyes:

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give Ingestion:

:


Shut off leaks if without risk. Contain leaking liquid on sand or earthSeal all waste in vapour tight plastic bags for eventual disposal.


Steps To Be TakenWaste Disposal Method:

SPILLS :

anything by mouth to an unconscious person. Get medical aid immediately.

8. ADDITIONAL INFORMATION / REFERENCESA very dangerous fire hazard when exposed to heat or flame. A synthetic flavouring substance & adjuvant.9. MANUFACTURERS / SUPPLIERS DATA




10. DISCLAIMER


:

OTHERS :


ISOPHORONE DIISOCYANATE IPD


Common Synonyms Liquid Colorless or yellowish

Sinks and reacts with water to produce carbon dioxide and the diamine.

IPDIIsophorone diaminediisocyanate

Keep people away. Avoid contact with liquid and vapor.Wear positive pressure breathing apparatus and special chemicalprotective suit.Call fire department. Shut off ignition sources.Notify local health and pollution control agencies.

Fire Combustible.POISONOUS GASES ARE PRODUCED IN FIRE.Wear positive pressure breathing apparatus andspecial chemical protective suit.Extinguish small fires with dry chemical, CO2, water spray or foam;large fires with water spray, fog or foam. (It reacts with water toproduce carbon dioxide and the corresponding diamine.)


VAPORPOISONOUS. MAY BE FATAL IF INHALED OR ABSORBED THROUGHSKIN.Contact may cause burns to skin and eyes.Move to fresh air.If not breathing, give artificial respiration.If breathing is difficult, give oxygen.

LIQUIDPOISONOUS. MAY BE FATAL IF SWALLOWED OR ABSORBED THROUGH SKIN.Contact may burn skin and eyes.Immediately flush skin or eyes with running water for at least 15minutes. Hold eyelids open periodically while flushing eyes.Speed in removing material from skin is of extreme importance.Remove and isolate contaminated clothing and shoes at the site.Keep victim quiet and maintain normal body temperature.Effects may be delayed; keep victim under observation.IF SWALLOWED and victim is UNCONSCIOUS OR HAVING CONVULSIONS,do nothing except keep victim warm.

WaterPollution


1. CORRECTIVE RESPONSE ACTIONSStop discharge


2.1 CG Compatibility Group: 12; Isocyanates2.2 Formula: C12H18N2O2

2.3 IMO/UN Designation: 6.1/22902.4 DOT ID No.: 2290

2.5 CAS Registry No.: 4098-71-92.6 NAERG Guide No.: 1562.7 Standard Industrial Trade Classification:

51489

3. HEALTH HAZARDS

3.1 Personal Protective Equipment: Wear positive pressure breathing apparatus and special protectiveclothing.

3.2 Symptoms Following Exposure: Poisonous. May be fatal if inhaled, swallowed or absorbed throughskin. Contact may cause burns to skin and eyes.

3.3 Treatment of Exposure: INHALATION: Move victim to fresh air; call emergency medical care. If notbreathing, give artificial respiration. If breathing is difficult, give oxygen. EYES: Immediately flusheyes with running water for at least 15 minutes; hold eyelids open periodically. SKIN: Immediatelyflush skin with running water for at least 15 minutes. Speed in removing material from skin is ofextreme importance. Remove and isolate contaminated clothing and shoes at the site. Keep victimquiet and maintain normal body temperature. Effects may be delayed; keep victim underobservation. INGESTION: If victim is unconscious or having convulsions, do nothing but keep himquiet and maintain normal body temperature.

3.4 TLV-TWA: 0.005 ppm.



3.7 Toxicity by Ingestion: Grade 2; LD50 > 2.6 g/kg (rat)



3.10 Vapor (Gas) Irritant Characteristics: Currently not available

3.11 Liquid or Solid Characteristics: Currently not available







4. FIRE HAZARDS

4.1 Flash Point: Currently not available

4.2 Flammable Limits in Air: Currently notavailable

4.3 Fire Extinguishing Agents: Small Fires:Dry chemical, CO2, water spray or foam.Large Fires: Water spray, fog or foam.(Reacts with water to produce gaseouscarbon dioxide and the correspondingdiamine.)

4.4 Fire Extinguishing Agents Not to BeUsed: Although water is suitable forextinguishing open air fires, it should notbe allowed to contaminate closed tankscontaining this material due to the risk ofhazardous gas generation.

4.5 Special Hazards of CombustionProducts: Contain toxic fumes of NOx.

4.6 Behavior in Fire: Undergoes oxidation toproduce toxic fumes containing NOx.










5.1 Reactivity with Water: Reacts with waterto produce water-soluble isophoronediamine (a toxic and corrosivecompound) and carbon dioxide.

5.2 Reactivity with Common Materials:Contact with aluminum, aluminum alloys,copper or copper alloys is prohibited.

5.3 Stability During Transport: Currently notavailable




6. WATER POLLUTION


Currently not available



6.4 Food Chain Concentration Potential:Currently not available

6.5 GESAMP Hazard Profile:Bioaccumulation: -

Damage to living resources: 3Human Oral hazard: 1Human Contact hazard: IIReduction of amenities: XXX


7.1 Grades of Purity: Currently not available

7.2 Storage Temperature: Not listed

7.3 Inert Atmosphere: Inerted

7.4 Venting: Pressure-Vacuum

7.5 IMO Pollution Category: B

7.6 Ship Type: 2



8.1 49 CFR Category: Keep Away From Food

8.2 49 CFR Class: 6.1











9.3 Boiling Point at 1 atm: Currently notavailable

9.4 Freezing Point: –76°F = –60°C = 213°K

9.5 Critical Temperature: Currently not available

9.6 Critical Pressure: Currently not available

9.7 Specific Gravity: 1.056 to 1.062 at 20°C

9.8 Liquid Surface Tension: Currently notavailable

9.9 Liquid Water Interfacial Tension: Currentlynot available

9.10 Vapor (Gas) Specific Gravity: 7.7(calculated)

9.11 Ratio of Specific Heats of Vapor (Gas):Currently not available

9.12 Latent Heat of Vaporization: Currently notavailable

9.13 Heat of Combustion: Currently not available







NOTES

JUNE 1999

ISOPHORONE DIISOCYANATE IPD




68 66.100




CURRENTLY

NOT

AVAILABLE




CURRENTLY

NOT

AVAILABLE



Centipoise

CURRENTLY

NOT

AVAILABLE




REACTS




NOT

PERTINENT




NOT

PERTINENT




CURRENTLY

NOT

AVAILABLE

JUNE 1999

Chemical Name : Maleic anhydride

Synonyms: Toxilic anhydride, 2 ,5-Furandione, Cis-butenedioic anhydrideFormula : C4H2O3

Toxic, Corrosive




Hazchem Code :Maleic anhydrideClass 8, Toxic, Corrosive 5

2X


34

Maleic anhydride 108-31-6

2. PHYSICAL / CHEMICAL DATA202 Molten solid Colourless crystals.

52.8 2.5X10-1 mm Hg at 25 deg C

Irritating, choking odour

3.4 40 g/100 mL

1.48

Soluble in dioxane, alcohol. Soluble in water, forming maleic acids.Acidic

Boiling Pt. °C:

Physical State:


Appearance:

Odour:



Others:


Melting Pt °C:


7.1 101.6TDG Flammability:LEL:UEL:


Autoignition Temperature °C : 476.6Explosion sensitivity to impact: StableExplosion sensitivity to static Electricity:Hazardous Combustion Products : Emits acrid smoke and irritating fumes.Hazardous Polymerization : Will not occur.

YesNoNo

NoNoNo




MATERIAL SAFETY DATA SHEETSMaleic anhydride352

StableStrong oxidizing agents, stong alkalies, amines, water, steam.

Violent reaction with bases (Na, K, Ca-hydroxides), alkali metals, amines, lithium , pyridine. Reacts vigorously with oxidising materials.



:

Page 1 of 3Maleic anhydride



Inhalation : Causes coughing, sneezing, throat irritation and produces pulmonary oedema. Skin : Contact causes irritation and redness. Vapours cause severe eye irritation, photophobia, and double vision may occur.

Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen.



481

1 mg/m3 (0.25 ppm)

1.84 mg/m

0.25 ppm (1 mg/m3)

3 1 1



TLV (ACGIH) :



Inhalation:

Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.

Skin:

Get medical aid immediately. Do not allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes).

Eyes:


Ingestion:

LC50 (rat) mg/kg:

6. PREVENTIVE MEASURESAvoid contact with liquid or solid. Provide approved organic vapour or gas canister , safety face shield , rubber gloves, boots, and aprons. Wash thoroughly after handling. Use only in a well ventilated area. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale.


:

:

Precautions :

Store in a dry, cool , well ventilated area, away from heat , flame , oxidising materials , cations , water and steam.

Storage :



Dry chemical powder, foam, CO2Keep the containers cool by spraying water if exposed to heat or flame.Dust could be ignited by spark or flame.


Unusual Hazards

FIRE:::

:

Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen.

Inhalation:

Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.

Skin:

Get medical aid immediately. Do not allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes).

Eyes:

:


Sweep up all spilled material to avoid dust and wash the surface with soap and water.Seal all the waste in vapour tight plastic bags for eventual disposal.


Steps To Be Taken


SPILLS :


Ingestion:

8. ADDITIONAL INFORMATION / REFERENCESCombustible when exposed to heat and flame. Reacts with water and steam to produce heat. Hot water may cause frothing. Reaction with cold water is slow and non - hazardous. This is a pesticide.9. MANUFACTURERS / SUPPLIERS DATA




10. DISCLAIMER


:

OTHERS :


MALEIC ANHYDRIDE MLA


Common Synonyms Molten; or solidcrystals or tablets

Colorless Choking odor

Sinks and mixes slowly with water.

cis-Butenedioic anhydride2,5-FuranedioneToxilic anhydride

Keep people away. Avoid contact with solid and liquid.Wear goggles, self-contained breathing apparatus, and rubber overclothing(including gloves).Call fire department.Notify local health and pollution control agencies.

Fire Combustible.Dust cloud may be ignited by spark or flame.Wear goggles, self-contained breathing apparatus, and rubber overclothing(including gloves).Extinguish with dry chemical, alcohol foam, or carbon dioxide.Water may be ineffective on fire.


LIQUID OR SOLIDWill burn skin and eyes.Harmful if swallowed.Remove contaminated clothing and shoes.Flush affected areas with plenty of water.IF IN EYES, hold eyelids open and flush with plenty of water.IF SWALLOWED and victim is CONSCIOUS, have victim drink wateror milk.

WaterPollution




2.1 CG Compatibility Group: Not listed.2.2 Formula: OCOCH=CHCO


51381

3. HEALTH HAZARDS

3.1 Personal Protective Equipment: Approved organic vapor-acid gas canister; chemical goggles andface shield; rubber gloves and boots; coveralls or rubber apron.

3.2 Symptoms Following Exposure: Inhalation causes coughing, sneezing, throat irritation. Skin contactcauses irritation and redness. Vapors cause severe eye irritation; photophobia and double visionmay occur.

3.3 Treatment of Exposure: INHALATION: give oxygen. EYE OR SKIN CONTACT: flush with lots ofwater for at least 15 min.; for eyes, call a physician. For molten maleic burns, remove crust andtreat as chemical and thermal burn.

3.4 TLV-TWA: 0.25 ppm



3.7 Toxicity by Ingestion: Grade 2; LD50 = 0.5 to 5 g/kg


3.9 Chronic Toxicity: None

3.10 Vapor (Gas) Irritant Characteristics: Vapors cause moderate irritation, such that personnel will findhigh concentrations unpleasant. The effect is temporary.

3.11 Liquid or Solid Characteristics: Causes smarting of the skin and first-degree burns on shortexposure; may cause secondary burns on long exposure.

3.12 Odor Threshold: 1.3 - 2.0 mg/m3


3.14 OSHA PEL-TWA: 0.25 mg/m3




4. FIRE HAZARDS

4.1 Flash Point: (Liquid) 215°F C.C.; 230°F O.C.


4.3 Fire Extinguishing Agents: Alcohol foam,dry chemical or carbon dioxide

4.4 Fire Extinguishing Agents Not to BeUsed: Water or foam may cause frothing


4.6 Behavior in Fire: When heated above300°F in the presence of variousmaterials may generate heat and carbondioxide. Will explode if confined.


4.8 Electrical Hazards: Class I, Group D








5.1 Reactivity with Water: Hot water maycause frothing. Reaction with cold wateris slow and non-hazardous.



5.4 Neutralizing Agents for Acids andCaustics: Solid spills can usually be re-covered before any significant reactionwith water occurs. Flush area of spillwith water.

5.5 Polymerization: Very unlikely at ordinarytemperatures, even in the molten state.

5.6 Inhibitor of Polymerization: None

6. WATER POLLUTION

6.1 Aquatic Toxicity:150 ppm/24 hr/sunfish/TLm/fresh water


6.3 Biological Oxygen Demand (BOD): 50%,5 days





7.1 Grades of Purity: Commercial: 99.5%



7.4 Venting: Open


7.6 Ship Type: 3



8.1 49 CFR Category: Corrosive material

8.2 49 CFR Class: 8









8.8 RCRA Waste Number: U147



PROPERTIES




9.4 Freezing Point: 127°F = 53°C = 326°K
















NOTES

JUNE 1999

MALEIC ANHYDRIDE MLA




NOT

PERTINENT




NOT

PERTINENT




NOT

PERTINENT



Centipoise

NOT

PERTINENT




INSOLUBLE




NOT

PERTINENT




NOT

PERTINENT




NOT

PERTINENT

JUNE 1999

MSDS for HI LAM GP – 50 / 100H

MATERIAL SAFETY DATA SHEET

Product reference : HI LAM GP – 50 / 100H Revision No. : 00 Date of issue : 23.10.2013

1. IDENTIFICATION OF PRODUCT AND COMPANY

Product name : POLYURATHANE Product Code : HI LAM GP – 50 / 100H Intended use : PRINTING INK / COATING INDUSTRY FOR VARIOUS APPLICATIONS

Company details : CYTECH COATINGS PVT.LTD.

SHED No. C1/3221/1 & 3223, G.I.D.C. SARIGAM – 396 155, TAL : UMERGAON, GUJARAT (INDIA) CONTACT PERSON : Mr. YOGESH PATIL TEL. No. +91-0260-6530325

2. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Characterization : Synthetic Resin Medium (CAS No. 1319-77-3)

3. HAZARDS IDENTIFICATION

Liquid. Adverse health effects are caused by inhaling, contact with skin and ingestion. 4. FIRST AID MEASURES

General information : Remove contaminated clothing and dispose of safety skin contact. In case of contact with skin, wash off immediately with soap and water.

5. Eye contact :

Rinse thoroughly with plenty of fresh water . Ingesting : Do not induce vomiting! Keep patient at rest. If accidentally swallowed, obtain medical attention.

6. FIRE-FIGHTING MEASURES Suitable extinguishing media : Water spray jet, Foam, Carbon dioxide, Dry powder, used : Water

7. ACCIDENTAL RELEASE MEASURES : Methods for cleaning up / taking up : Pick up with absorbent material (e.g., sand, kieselgur, acid binder, universal binder, sawdust). When picked up, treat material as prescribed under heading “Disposal”. Personal Precautions: - Do not breath vapors. Avoid ignition sources. Avoid contact with skin ,eyes and clothing.

8. HANDLING AND STORAGE

Handling : Avoid creation of exposable air/ solvent blends and do not exceed maximal working environment concentration (MAK/TLV) Storage : Store in a cool, well-aired place in tightly sealed Containers. Protection against fire and explosion Keep away from ignition sources. Ground to avoid static charging during mixing and pumping.

9. EXPOSURE CONTROLS / PERSONAL PROTECTION

Technical protective measures Ensure good airing to avoid solvent concentrations exceeding maximal working environment concentration values (MAK/TLV). Personal protective equipment : Hygiene measure : Keep away from foodstuffs and beverages.

Wash hands before breaks and after work. Clean skin thoroughly after work; apply skin cream.

Respiratory protection: n case of insufficient ventilation. Hand protection : Protective gloves Eye protection : Safety glasses

10. PHYSICAL AND CHEMICAL PROPERTIES

Data relevant to safety Specific Gravity : 1.20+/-0.05 Viscosity Gardener Tube (25ºC) : 55 To 60 CPS a t 30ºC Solid Percentage : 80% +/_ 2% w/w Solubility in water at 30°C : Insoluble Solubility in organic solvents : Soluble in selective organic solvents Ignition temperature : 150ºC Acid Value : <2.82

Odor In Solution Ethyl Acetate Dry Odorless

Typical Value Free Isocynates Zero NCO value (%max) 0.392 Solvent composition Resin 8 0% Ester 20%

Appearance : Form : Viscous liquid Color : Transparent Light Pale/ water white in Color Odor : Odorless after drying

11. STABILITY AND REACTIVITY

Stability: - Stable, if handled according to instructions in paragraph 7. Substance to avoid Keep away from strongly sour and alkaline materials as well as strong Oxidizing agents to avoid exothermic reactions.

Hazardous decomposition products At high temperatures, decomposition products such as Carbon Dioxide, Carbon Monoxide and smoke may be formed.

12. TOXICOLOGICAL INFORMATION

There is no data available for the product itself, inhalation of solvent components exceeding the MAK/TLV- values can cause adverse health effects such as irritation of the mucous membrane and the respiratory system and adverse effects on the renal and central nervous systems.

13. ECOLOGICAL INFORMATION

Further ecological information Remarks : No data can be given due to the product’s insolubility in water.

14. DISPOSAL CONSIDERATIONS

Product : In accordance with current regulations may be taken to waste disposal site or incineration plant, after consultation . with site operator and/or with the responsible authority.

Unclean packaging : Contaminated packaging should be emptied as far as possible and after appropriate cleansing may be taken for reuse.

15. TRANSPORT INFORMATION Road transport : ADR Non-hazardous goods RID Non-hazardous goods

Inland waterways transport : ADNR Non-hazardous goods.

Marine transport : IMDG/UN Non-hazardous goods

Air transport : ICAO/IATA-DGR Non-hazardous goods

Dispatch by post : Permitted.

16. REGULATORY INFORMATION

Non-hazardous, insoluble in water. 17. OTHER INFORMATION

This information is based on our present state of knowledge. It should not therefore, be construed as guaranteeing specific properties of the products described or their suitability for a particular application.