MILLER INDICES• Miller indices were introduced in 1839 by the British mineralogist William

Hallowes Miller. The method was also historically known as the Millerian system, and the indices as Millerian.• The orientation of a surface or a crystal plane may be defined by

considering how the plane (or indeed any parallel plane) intersects the main crystallographic axes of the solid. • The application of a set of rules leads to the assignment of the Miller

Indices , (hkl) ; a set of numbers which quantify the intercepts and thus may be used to uniquely identify the plane or surface.• To determine the crystallography planes we take a unit cell with three axes

coordinate system.

• Rules for Miller Indicesi. Determine the intercepts (a,b,c) of the face along the crystallographic axes, in

terms of unit cell dimensions.ii. Take the reciprocalsiii. Clear fractionsiv. Reduce to lowest termsv. If a plane has negative intercept, the negative number is denoted by a bar (¯)

above the number. Never alter negative numbers. For example, do not divide -1, -1, -1 by -1 to get 1,1,1. vi. If plane is parallel to an axis, its intercept is zero and meets at infinity.vii. The three indices are enclosed in parenthesis, (hkl). A family of planes is

represented by {hkl}.

• General Principles

i. If a Miller index is zero, the plane is parallel to that axis.ii. The smaller a Miller index, the more nearly parallel the plane is to the axis.iii. The larger a Miller index, the more nearly perpendicular a plane is to that axis.iv. Multiplying or dividing a Miller index by a constant has no effect on the orientation of the

planev. When the integers used in the Miller indices contain more than one digit, the indices must

be separated by commas. E.g.: (3,10,13)vi. By changing the signs of all the indices a plane, we obtain a plane located at the same

distance on the other side of the origin.

Find the Miller indices for the vector shown in the unit cell shown in fig. where, a=b=c.

• Step 1: The given vector is passing through the origin of the coordinate system.• Step 2: Take the intercepts of the vector on the X, Y & Z axes.

• Step 3: Since a=b=c, the intercepts will be: ½, 1 & 0. Multiplying throughout by 2 and enclosing within square brackets we get, [120] to be the direction indices of the given vector.

Intercept on X Axis

Intercept on Y Axis

Intercept on Z Axis

a/2 b 0

Find the Miller Indices of plane shown in fig. where a=b=c.

Fig. a Fig. b

• Step 1: The given plane passes through the origin. Hence, the origin is shifted to the adjacent unit cell as shown in fig.(b).• Step 2: Find the intercepts of the plane with the X, Y & Z axes:

Intercept on X axis

Intercept on Y axis

Intercept on Z axis

-b c/2

-1 1/2

• Step 3: Take the reciprocals of the intercepts, we get 0,-1 & 2.• Step 4: Enclose the indices in round brackets (parenthesis) we get (0-12) to be the Miller Indices of given plane.

Some Examples to Solve

• Family of Equivalent PlanesDue to the symmetry of crystal structures the spacing and arrangement of atoms may be the same in several planes. These are known as equivalent planes, and a group of equivalent planes are known as a family of planes. Families of planes are written in curly brackets.

{001} = (001), (010), (100), (00-1), (0-10), (-100)

Relationship between crystallographic plane and directions.

• Conventionally, a plane in analytical geometry is expressed by a vector normal to the plane under consideration. It may be observed from fig, that the miller indices for a plane and a vector normal to it are same. if (uvw) is the miller indices of a plane, then the direction indices of a vector normal to it is [uvw].

REFERENCE• MATERIAL SCIENCE AND ENGINEERING: AN INTRODUCTION,WILLIAM

CALLISTER