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Micro-Raman Spectroscopy Measurement of Stress in Silicon Sergej Shashkov, SOL instruments Ltd., Nezavisimosti ave.58-10, Minsk, Belarus www.solinstruments.com

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Page 1: Micro-Raman Spectroscopy Measurement of Stress in Silicon€¦ · Micro-Raman Spectroscopy Measurement of Stress in Silicon Sergej Shashkov, SOL instruments Ltd., Nezavisimosti ave.58-10,

Micro-Raman Spectroscopy Measurement

of Stress in Silicon

Sergej Shashkov, SOL instruments Ltd.,

Nezavisimosti ave.58-10, Minsk, Belarus

www.solinstruments.com

Page 2: Micro-Raman Spectroscopy Measurement of Stress in Silicon€¦ · Micro-Raman Spectroscopy Measurement of Stress in Silicon Sergej Shashkov, SOL instruments Ltd., Nezavisimosti ave.58-10,

Mechanical stress can have direct or indirect effects on the functioning

and reliability of a chip and can cause different failure modes, such as:

- changes in electron or hole mobility

- dislocations near isolation structures

- cracks in chips,

- creep in metals,

- stress migration, etc.

Stress can also be used in a positive way, for example to increase the

carrier mobility.

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Page 3: Micro-Raman Spectroscopy Measurement of Stress in Silicon€¦ · Micro-Raman Spectroscopy Measurement of Stress in Silicon Sergej Shashkov, SOL instruments Ltd., Nezavisimosti ave.58-10,

Local Strain Metrologies

T. Kanayama, 2007 Int Conf Frontiers of Characterization and Metrology for

Nanoelectronics, March 29, 2007

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Page 4: Micro-Raman Spectroscopy Measurement of Stress in Silicon€¦ · Micro-Raman Spectroscopy Measurement of Stress in Silicon Sergej Shashkov, SOL instruments Ltd., Nezavisimosti ave.58-10,
Page 5: Micro-Raman Spectroscopy Measurement of Stress in Silicon€¦ · Micro-Raman Spectroscopy Measurement of Stress in Silicon Sergej Shashkov, SOL instruments Ltd., Nezavisimosti ave.58-10,

E.D. Palik, “Handbook of Optical Constants of Solids”, Academic Press,Sant Diego, 1998.

Penetration Depth

Page 6: Micro-Raman Spectroscopy Measurement of Stress in Silicon€¦ · Micro-Raman Spectroscopy Measurement of Stress in Silicon Sergej Shashkov, SOL instruments Ltd., Nezavisimosti ave.58-10,

The sample consists 1, 1.5, 2 and

4 µm wide Si stripes separated by

4 µm shallow trenches.

The next equation can be applied

to the Si stress monitoring:

σ(MPa) = −435 ·(ω - ω0) (cm−1),

where σ is the stress value,

0 = 520.5 cm −1 is the peak

position of the stress-free state, ω

is the Si peak position at the

stressed state.

Compressive

stress Δω>0 Tensile stress

Δω<0

Page 7: Micro-Raman Spectroscopy Measurement of Stress in Silicon€¦ · Micro-Raman Spectroscopy Measurement of Stress in Silicon Sergej Shashkov, SOL instruments Ltd., Nezavisimosti ave.58-10,

1sec/point; 532nm laser; ~2 mW laser power, 20nm scanning step

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Page 8: Micro-Raman Spectroscopy Measurement of Stress in Silicon€¦ · Micro-Raman Spectroscopy Measurement of Stress in Silicon Sergej Shashkov, SOL instruments Ltd., Nezavisimosti ave.58-10,

A periodic STI (shallow trench isolation) structure

Page 9: Micro-Raman Spectroscopy Measurement of Stress in Silicon€¦ · Micro-Raman Spectroscopy Measurement of Stress in Silicon Sergej Shashkov, SOL instruments Ltd., Nezavisimosti ave.58-10,

Defect Area on the Silicon Wafer

Stress Distribution

Variation of stress lies in the range between +43 MPa and -175 MPa.

AFM

Page 10: Micro-Raman Spectroscopy Measurement of Stress in Silicon€¦ · Micro-Raman Spectroscopy Measurement of Stress in Silicon Sergej Shashkov, SOL instruments Ltd., Nezavisimosti ave.58-10,

EEPROM Investigation

514.50 520.01

521

519

517

515

513

511

cm-1

15 x 15 um

Page 11: Micro-Raman Spectroscopy Measurement of Stress in Silicon€¦ · Micro-Raman Spectroscopy Measurement of Stress in Silicon Sergej Shashkov, SOL instruments Ltd., Nezavisimosti ave.58-10,

Growing of Ge dots on Si Substrate

(schematic diagram)

Ge QD on a Silicon Substrate

AFM Topography

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Page 12: Micro-Raman Spectroscopy Measurement of Stress in Silicon€¦ · Micro-Raman Spectroscopy Measurement of Stress in Silicon Sergej Shashkov, SOL instruments Ltd., Nezavisimosti ave.58-10,

0

-0.1

-0.2

-0.3

0

+43.5

+86.4

+130.5

cm-1 MPa

Raman Microscopy of Ge dots on Si

Si-Si Ge-Ge

Si-Ge

Page 13: Micro-Raman Spectroscopy Measurement of Stress in Silicon€¦ · Micro-Raman Spectroscopy Measurement of Stress in Silicon Sergej Shashkov, SOL instruments Ltd., Nezavisimosti ave.58-10,

Si peak shift, cm-1

Strain Investigation in a SiGe Sample

Page 14: Micro-Raman Spectroscopy Measurement of Stress in Silicon€¦ · Micro-Raman Spectroscopy Measurement of Stress in Silicon Sergej Shashkov, SOL instruments Ltd., Nezavisimosti ave.58-10,

AFM Cantilever: Raman Imaging

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Page 15: Micro-Raman Spectroscopy Measurement of Stress in Silicon€¦ · Micro-Raman Spectroscopy Measurement of Stress in Silicon Sergej Shashkov, SOL instruments Ltd., Nezavisimosti ave.58-10,

Thank you very much for your attention!

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