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Methanol Blends Danish Methanol Association 24. August 2020

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Page 1: Methanol Blends

Methanol BlendsDanish Methanol Association24. August 2020

Page 2: Methanol Blends

Experiencewith M85

Danish Methanol Association

Page 3: Methanol Blends

M85

Koldstart Koldstart under 5 oC kræver mere benzin – min. 30% benzin

Danish Methanol Association

Page 4: Methanol Blends

M85

Check Engine

Too leanHigh oxygen

Errors: “P0171 System Too Lean Bank 1” and ”P0130 O2 Sensor Circuit Bank 1 Sensor1” turns on "Check Engine" light. May require more petrol or AFR adjustment.

Danish Methanol Association

Page 5: Methanol Blends

M85requires a Flex Fuel Kit

Port injection –here with no Fuel Sensor

Direct injection is different

Danish Methanol Association

Page 6: Methanol Blends

EcoFuelBox®

Air-Fuel Ratio KnobE10: 14,2:1E85: 9,9:1M85: 7,8:1

Danish Methanol Association

Page 7: Methanol Blends

Product portfolio for Biomotors Engine Indirect

InjdectionDirect

injection

Euro 3/4 , <= 7CV

Euro 3/4 , 8HP-14CV

Euro 5/6, <= 7CV

Euro 5/6, 8HP-14CV Danish Methanol Association

Page 8: Methanol Blends

M85

Kit challenges

Kits should be AFR-adjusted

Fuel sensor readings should be corrected for permittivityDanish Methanol Association

Calories LHV AFR Permittivity

Gasoline 32 MJ/l 14,7:1 e=2

Ethanol 21 MJ/l 9,0:1 e=25.3

Methanol 16 MJ/l 6,5:1 e=33

E10 31,5 MJ/l 14,2:1

E85 22,7 MJ/l 9,9:1

M85/A85 18,5 MJ/l 7,8:1

Page 9: Methanol Blends

With Flex Fuel Kit 95 Octane Petrol 105 Octane M85

Air-Fuel Ratio 14,0:1 7,6:1

Fuel energy MJ/l 32,2 18,2

Danish Methanol Association

Page 10: Methanol Blends

With Flex Fuel Kit 95 Octane Petrol 105 Octane M85

Performance

Max. power 68 hk 73 hk

Max. torque 97 Nm 102 Nm

MJ/km 1,63 1,62

MJ/km 1,63 1,62

Car efficiency 15% 15%

Engine efficiency 25% 25%

Danish Methanol Association

Page 11: Methanol Blends

With Flex Fuel Kit 95 Octane Petrol 105 Octane M85

Emissions

CO2, g/km 118 118

CO, g/km 1,4 0,4

NOx, g/km 0,4 0,6

Pn, G#/km 234 259

EURO 5 & 6 Norm

NOx, g/km 0,06 0,06

Danish Methanol Association

Page 12: Methanol Blends

M85M45Mpure

Blenderpumpe

Danish Methanol Association

Page 13: Methanol Blends

Max torque[Nm]

at RPM Max power[kW] at RPM

Gasoline E5 97.3 3450 50.3 5900M15 97.9 3650 52.3 5900M25 97.8 3600 51.5 6000M50 97.3 3550 50.8 5950M65 97.1 3700 51.3 6000M75 96.8 3650 51.8 5950M85 97.7 3500 51.8 5850M85C (Flex Fuel Kit) 102.3 3550 53.4 5800M100 97.7 3650 52.5 5950

Table 1 Engine power and torque of Peugeot 107 with gasoline and methanol blends.On M65, M75 and M100, the engine clearly didn’t perform right.

The Engine did run M50

Danish Methanol Association

Page 14: Methanol Blends

M45 RVP problem?

Source:Methanol Institute for M0-M15; ASTM D5797-17 for M51-M85.

0

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0 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95100

Reid

kPa

Methanol vol %

RVP 38 oC of Methanol Blends with Gasoline (62 kPa)

Methanol blends M0-M100 Summer LowSummer High Winther LowWinther High M85

Danish Methanol Association

Page 15: Methanol Blends

Phase Separation

Ethanol as a cosolvent

With E10 no needfor additionalcosolvent

Danish Methanol Association

0

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ETH

AN

OL

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L%

METHANOL VOL%

ETHANOL AS COSOLVENT

Petrol

E10

Page 16: Methanol Blends

M85M45

CorrosionInhibitor

Cyclohexyldimethylamine (DMCHA)

Methanol with DMCHA passed new NACE Corrosion test

Candidate corrosion inhibitor (acc. to National Standard of the People’s Republic of China; GB/T 23799-2009. Methanol gasoline (M85) for motor vehicles).

Danish Methanol Association

Page 17: Methanol Blends

M85M45

DetergentPolyetheramine (PEA).

Candidate detergent (acc. to National Standard of the People’s Republic of China; GB 19592-2019. Detergent Additive for Motor Gasoline).

Danish Methanol Association

Page 18: Methanol Blends

M85

Årstidsvariationunder forsøg

Table is for E10 only

Single tank !Blender pump

Danish Methanol Association

E10 Vapour pressure DVPE kPa Min Max1/5-31/5 OG 1/9-30/9 60,0 88,01/10-30/4 40,0 88,01/6-31/8 40,0 63,0

Page 19: Methanol Blends

MpureM85M45fra samme tank

Energiskat ?

Skatteministeriet Aarhus, 10. februar 2020

Vedr. beskatning af bio-methanol og e-methanol til transport.

Hvorledes skal methanolen beskattes og kan anvendelsen i M85 og Mpure ligestilles? Kan der opnås lempelse af energiskatten på methanolen?

NEW FUEL A/S Agro Food Park 13 DK 8200 Aarhus N

Denmark www.newfuel.dk

[email protected]

Danish Methanol Association

Page 20: Methanol Blends

Mette Frederiksen er stillet godt en million methanolbiler i udsigt 2030, hvis hun vil have det.

Link

2030; 17 PJ 950.000 m3

M85 800.000 FFV

2022; 54 PJ 2.550.000 petrol cars

2030; 17 PJ 750.000 petrol cars.

2030; 5 PJ 500.000 EV's

2030; 9 PJ 500.000 Fuel Cell EV's

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2021 2023 2025 2027 2029 2031

PJ p

er Y

ear

Light Vehicles Motor Fuel Sales Forecast Denmark. 105 Octane M85(conservative estimate)

Gasoline

Electricity (Danish Counsilon Climate Change)

Fuel Cell Vehicles

Danish Methanol Association