metal contamination of surface sediments of the sfax–chebba coastal line, tunisia

9
ORIGINAL ARTICLE Metal contamination of surface sediments of the Sfax–Chebba coastal line, Tunisia Nedia Ghannem Dorra Gargouri Mohamed Moncef Sarbeji Chokri Yaich Chafai Azri Received: 24 October 2013 / Accepted: 29 March 2014 Ó Springer-Verlag Berlin Heidelberg 2014 Abstract Concentrations of several heavy metals (Pb, Cr, Cd, Cu, Zn and Fe) in surface sediment were determined to investigate the distributions and the metallic pollution status in Sfax–Chebba coastal area (southeast of Tunisia). Sediment samples were collected from 20 locations, rep- resenting three different site groups (i.e., site I: urban zone, site II: pre-urban zone and site III: rural zone). Heavy metal contents were analyzed by Atomic Absorption Spectrom- etry. The obtained results showed that generally, heavy metal concentrations in the coastal sediments near Sfax city (urban zone) were higher than those at other stations because of the anthropogenic activities. These concentra- tions exceeded the threshold effect levels. This was con- firmed by the chemometric approaches (enrichment factors, geoaccumulation index and principal component analysis) which showed a significant impact of multiple anthropo- genic sources. Moderate to extremely severe enrichment of sediments in terms of Pb, Cr, Cd, Cu and Zn were shown to exist in site I. Severe enrichment by Cd was also observed in other sites. Based on the geoaccumulation index, Pb, Cr, Cd, Cu and Zn can be considered as unpollutants to extreme pollutants. Keywords Heavy metals Sediment Contamination Chemometric methods Sfax–Chebba coast Introduction Coastal areas are sites of discharge and accumulation of a range of environmental contaminants, which ultimately affects the sustainability of living resources and public health (MacFarlane and Burchett 2000). Different urban, industrial, and agricultural activities, as well as atmo- spheric deposition (Yang et al. 2011) contribute to con- tamination of aquatic environments. Among environmental pollutants, heavy metals are of particular concern due to their toxicity, wide source, non- biodegradable properties, and their ability to accumulate for long period of time (Dong et al. 2011). They can cause harmful effects on both marine organisms and human pop- ulations (Muhammad et al. 2000; Vallejuelo et al. 2010; Wu and Zhang 2010). These metals are rapidly and efficiently associated with the sediment via adsorption onto surface particles, hydrolysis and co-precipitation. Adsorption is usually the predominant process because metals have strong affinities for iron and manganese hydroxides, particulate organic matter, and a lesser extent to clay minerals. Conse- quently, metals tend to accumulate in bottom sediments (Rezayi et al. 2011). Only small portion of free metal ions can be found dissolved in water (Sultan and Shazili 2009). Marine sediments are good indicators for the assessment of various contaminants in aquatic environments because they act as major repository of metals, leading to the contamination of coastal zone (Adams et al. 1992; Atgin et al. 2000; Caccia et al. 2003). Furthermore, they show less variation in time and area, allowing more consistent assessment of spatial and temporal contamination (Krishna et al. 2011). Therefore, the fate of heavy metals in sediment has recently been the subject of extensive discussion (Ding and Ji 2010; Kong et al. 2011; Sundaray et al. 2011; Tang et al. 2010). N. Ghannem (&) M. M. Sarbeji C. Yaich Department of Geology, National School of Engineers of Sfax, Road Soukra, km 4, PB 1173, 3038 Sfax, Tunisia e-mail: [email protected] D. Gargouri C. Azri Department of Earth Sciences, Faculty of Science of Sfax, Road Soukra, km 3,5, PB 1171, 3000 Sfax, Tunisia 123 Environ Earth Sci DOI 10.1007/s12665-014-3248-z

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Page 1: Metal contamination of surface sediments of the Sfax–Chebba coastal line, Tunisia

ORIGINAL ARTICLE

Metal contamination of surface sediments of the Sfax–Chebbacoastal line, Tunisia

Nedia Ghannem • Dorra Gargouri •

Mohamed Moncef Sarbeji • Chokri Yaich •

Chafai Azri

Received: 24 October 2013 / Accepted: 29 March 2014

� Springer-Verlag Berlin Heidelberg 2014

Abstract Concentrations of several heavy metals (Pb, Cr,

Cd, Cu, Zn and Fe) in surface sediment were determined to

investigate the distributions and the metallic pollution

status in Sfax–Chebba coastal area (southeast of Tunisia).

Sediment samples were collected from 20 locations, rep-

resenting three different site groups (i.e., site I: urban zone,

site II: pre-urban zone and site III: rural zone). Heavy metal

contents were analyzed by Atomic Absorption Spectrom-

etry. The obtained results showed that generally, heavy

metal concentrations in the coastal sediments near Sfax city

(urban zone) were higher than those at other stations

because of the anthropogenic activities. These concentra-

tions exceeded the threshold effect levels. This was con-

firmed by the chemometric approaches (enrichment factors,

geoaccumulation index and principal component analysis)

which showed a significant impact of multiple anthropo-

genic sources. Moderate to extremely severe enrichment of

sediments in terms of Pb, Cr, Cd, Cu and Zn were shown to

exist in site I. Severe enrichment by Cd was also observed

in other sites. Based on the geoaccumulation index, Pb, Cr,

Cd, Cu and Zn can be considered as unpollutants to

extreme pollutants.

Keywords Heavy metals � Sediment � Contamination �Chemometric methods � Sfax–Chebba coast

Introduction

Coastal areas are sites of discharge and accumulation of a

range of environmental contaminants, which ultimately

affects the sustainability of living resources and public

health (MacFarlane and Burchett 2000). Different urban,

industrial, and agricultural activities, as well as atmo-

spheric deposition (Yang et al. 2011) contribute to con-

tamination of aquatic environments.

Among environmental pollutants, heavy metals are of

particular concern due to their toxicity, wide source, non-

biodegradable properties, and their ability to accumulate for

long period of time (Dong et al. 2011). They can cause

harmful effects on both marine organisms and human pop-

ulations (Muhammad et al. 2000; Vallejuelo et al. 2010; Wu

and Zhang 2010). These metals are rapidly and efficiently

associated with the sediment via adsorption onto surface

particles, hydrolysis and co-precipitation. Adsorption is

usually the predominant process because metals have strong

affinities for iron and manganese hydroxides, particulate

organic matter, and a lesser extent to clay minerals. Conse-

quently, metals tend to accumulate in bottom sediments

(Rezayi et al. 2011). Only small portion of free metal ions can

be found dissolved in water (Sultan and Shazili 2009).

Marine sediments are good indicators for the assessment

of various contaminants in aquatic environments because

they act as major repository of metals, leading to the

contamination of coastal zone (Adams et al. 1992; Atgin

et al. 2000; Caccia et al. 2003). Furthermore, they show

less variation in time and area, allowing more consistent

assessment of spatial and temporal contamination (Krishna

et al. 2011). Therefore, the fate of heavy metals in sediment

has recently been the subject of extensive discussion (Ding

and Ji 2010; Kong et al. 2011; Sundaray et al. 2011; Tang

et al. 2010).

N. Ghannem (&) � M. M. Sarbeji � C. Yaich

Department of Geology, National School of Engineers of Sfax,

Road Soukra, km 4, PB 1173, 3038 Sfax, Tunisia

e-mail: [email protected]

D. Gargouri � C. Azri

Department of Earth Sciences, Faculty of Science of Sfax,

Road Soukra, km 3,5, PB 1171, 3000 Sfax, Tunisia

123

Environ Earth Sci

DOI 10.1007/s12665-014-3248-z

Page 2: Metal contamination of surface sediments of the Sfax–Chebba coastal line, Tunisia

The Sfax–Chebba coastal area (southeast of Tunisia)

represents an example of marine ecosystem whose biological

balances have been modified due to the particular marine

hydrodynamics of the gulf of Gabes and the anthropogenic

development, and in particular to the great industry settle-

ment of Sfax. Indeed, since the 1950s, the growing manu-

facturing industries, the population expansion and the rapid

urban development in Sfax city have resulted in industrial

and municipal wastewater, which can seriously affect sea-

water and marine sediments (Illou 1999; Mkawar et al. 2007

Choura et al. 2009; Gargouri et al. 2010; Ghannem et al.

2010; Chulli et al. 2012; Sahnoun et al. 2012).

In this context, the present study aims to (1) assess the

level of metal (Pb, Cr, Cd, Cu, Zn and Fe) concentrations in

surface sediments of Sfax–Chebba coast, (2) explore the

natural and anthropogenic input of heavy metals and (3)

discuss the pollution status on the area.

Materials and methods

Sampling and analysis surface sediment samples were

collected from 20 stations along the coastal area of Sfax–

Chebba (southeast of Tunisia) (Fig. 1). Such a coast is

characterized by semi-diurnal tide with amplitude about

1.4 m during spring tides and 0.3 m during neap tides

(Amari 1984). Tidal currents are generally very low;

however, they may be strong particularly at tidal channels.

The offshore swells are strongly dimmed during its prop-

agation by seagrass beds and shoals surrounding the Ker-

kennah archipelago. The swells are characterized by a high

variability of directions (W, NW, N to NE, E, S and SSE)

and velocities. E, NE and SE swell directions were dem-

onstrated dominant (Amari 1984).

In order to determine the distribution of metal contam-

ination in this coastal zone, the sampling stations were

divided into three site groups based on the possible

anthropogenic activities:

– Site I = Sfax-Sidi Mansour (Stations S1–S7: Urban zone,

densely populated area, commercial port, industrial park,

presence of the phosphogypsium deposit resulting from

old processing plants of NPK ‘‘phosphates’’).

– Site II = Haggouna-El Awabed (Stations S01–S03: Pre-

urban zone);

– Site III = El Louza-Chebba (Stations S001–S0010: rural

area and fishing activities).

Samples from each station were collected using an

Ekman grab. The top 5 cm of the sediment was removed

670000

670000

680000

680000

690000

690000

3850000 3850000

3860000 3860000

3870000 3870000

3880000 3880000

3890000 3890000

3900000 3900000N

Haggouna

el Louza port

port

el Awabed

S"10S"9S"8

S"7

S"6S"5

S"4

S"3

S"2

S"1

S'3

S'2

S'1

S7S6

S5S4

S3S2S1

Sidi Mansour

Sfax

Malloulech

Chebba

Port

Ouady EzzitPK4 canal

Site III

Site II

Site I

Tunisia

0 10Km

0 100Km

N

Fig. 1 Location of sampling sites in the coast from Sfax to Chebba

Environ Earth Sci

123

Page 3: Metal contamination of surface sediments of the Sfax–Chebba coastal line, Tunisia

with an acid-washed spatula to prevent contamination.

Immediately after collection, samples were placed in

polyethylene bags, refrigerated, and transported to the

laboratory. Sediment samples were dried to a constant dry

weight at 60 �C, and sieved through a 63-lm stainless steel

sieve. Finer sediments contain more heavy metals than the

coarser ones. This enrichment is mainly due to surface

adsorption and ionic attraction (Szefer et al. 1996).

For the analyses of total Pb, Cr, Cd, Cu, Zn and Fe

concentrations in sediment samples, about 0.5–1.0 g of the

dried sediment were digested in a mixture of concentrated

acids (nitric acid, fluorhydric acid, and perchloric acid)

according to the EPA 3052 guideline (EPA 1996). The

digested samples were then diluted to 25 ml with double

distilled water, and filtered through Whatman filter paper

into acid-washed polyethylene sample bottles. After fil-

tration, the samples were determined for Pb, Cr, Cd, Cu, Zn

and Fe using an air–acetylene flame Atomic Absorption

Spectrometry (SHIMADZU HIC- 6A model) using Zee-

man Effect.

The analytical data quality was guaranteed through the

implementation of laboratory quality assurance and quality

control methods, including the use of standard operating

procedures, calibration with standards, analysis of reagent

blanks, recovery of known additions and analysis of rep-

licates. All analyses were carried out in triplicate, and the

results were expressed as the mean.

The detection limits (mg/l) were 0.041 for Pb, 0.015 for

Cr, 0.004 for Cd, 0.010 for Cu, 0.003 for Zn and 0.013 for

Fe. Data reported in this study are calculated as dry weight.

Sediment quality assessment

Enrichment rate of sediment can be calculated by the

Eq. (1) as described by Yaboue (1991).

Tð%Þ ¼ CðXÞSitea � CðXÞSiteb

CðXÞSitea�100 ð1Þ

where T(%): enrichment rate of sediments for Site a (in our

case ‘‘urban area’’ or ‘‘pre-urban area’’) with respect to that

of Site b selected as rural area; CðXÞSitea: concentration of a

selected heavy metal ðX) in the sediment sampled in the

urban (pre-urban) area; CðXÞSiteb: concentration of the

selected heavy metal ðX) in the sediment sampled in the

rural area.

Due to the absence of Tunisian guidelines for coastal

sediments, Pb, Cr, Cd, Cu and Zn concentrations were

compared with the China sediment quality assessment

guidelines (i.e., the threshold effect levels or TEL) (Jun-

hong et al. 2011).

The TEL, as defined by MacDonald et al. (1996), is

the upper limit of the range of sediment contaminant

concentrations dominated by no effect data entries. Within

this range, concentrations of sediment-associated contami-

nants are not considered to represent significant hazards to

aquatic organisms. The TEL can be calculated by the fol-

lowing Eq. (2):

TEL ¼ffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi

EDS � Lð Þ � NEDS � Mð Þp

ð2Þ

where (EDS-L) is the 15th percentile concentration in the

effect data set, and (NEDS-M) is the 50th percentile con-

centration in the no effect data set. An elaborate description

of the numerical sediment quality assessment guidelines

and the TEL development can be found in MacDonald

(1994) and Macdonald et al. (1996).

In order to assess the impact of the anthropogenic

activities related to the abundance of trace metals in the

studied sediments, the computation of enrichment factor

(EF) is required.

A normalization procedure using Al or Fe is a powerful

tool to evaluate the anthropogenic input of trace metals in

the sediments (Nolting et al. 1999; Selvaraj et al. 2004).

In this study, the geochemical normalization was

obtained using Fe. This element is widely used as a crustal

reference (Feng et al. 1998; Schiff and Weisberg 1999;

Mucha et al. 2003; Zhou et al. 2007; Zhang et al. 2007).

According to Ergin et al. (1991), the metal EF can be

calculated as following Eq. (3):

EF ¼Cx=CFeð Þsample

Cx=CFeð Þcrust or background

ð3Þ

where (Cx/CFe) sample is the ratio of concentration of the

element being tested (Cx) to that of Fe (CFe) in the sedi-

ment sample, and (Cx/CFe)crust or background is the same ratio

in unpolluted baseline samples.

EF values were interpreted as suggested by Birch

(2003).

EF \ 1 indicates no enrichment, EF \ 3 is minor

enrichment, 3 \ EF \ 5 is moderate enrichment,

5 \ EF \ 10 is moderately severe enrichment,

10 \ EF \ 25 is severe enrichment, 25 \ EF \ 50 is very

severe enrichment, and EF [ 50 is extremely severe

enrichment.

The geoaccumulation index (Igeo) introduced by Muller

(1981) may contribute to the estimation of the degree of the

sediment contamination.

This index can be determined from the following

Eq. (4):

Igeo ¼ Log2

Cn

1:5Bn

� �

ð4Þ

where Cn is the measured concentration of element n, Bn is

the background concentration value (average crust) of the

element n, and 1.5 is the background matrix correction

Environ Earth Sci

123

Page 4: Metal contamination of surface sediments of the Sfax–Chebba coastal line, Tunisia

factor that is included to correct possible background value

variations due to lithogenic effects.

Statistical analysis

Correlation matrix and multivariate statistical analysis

including principal component analysis (PCA) were per-

formed using the ITCF statistical software package

(STATIT-CF 1987) to evaluate associations among the

investigated variables in the samples and to identify the

most common pollution sources.

Results and discussion

Heavy metal concentrations in studied superficial

sediments are presented in Table 1

Metal concentrations of Pb, Cr, Cd, Cu and Zn in sediments

were found to be higher in stations from S1 to S7, located

in the vicinity of Sfax city. Pb concentration (125.2 mg/kg)

and Cr (196.9 mg/kg) were, respectively, found highest

downstream PK4 and ‘‘Ouady Ezzit’’ canals (two principal

anthropogenic effluents). High concentrations of Cd, Cu

and Zn (36; 81.4 and 2,077.3 mg/kg, respectively) were

found around the phosphogypsum dump resulting from old

processing plants of NPK ‘‘phosphates’’. The minima of Cr

(1.5 mg/kg), Cd (0.1 mg/kg) and Zn (3.6 mg/kg) were

observed in station S’’1 (site III), and the minima of Pb

(0.2 mg/kg) and Cu (0.9 mg/kg) in stations S’1 and S’3

(site II). Port activities and industrial effluents of El Louza

as well as fishing boats activities along the coast contribute

to important levels in some stations of Cr (in site II and III),

Cd, Cu and Zn (in station S’’2, site III).

Heavy metals distribution among the three site groups

can be seen in Fig. 2. The mean concentrations (in mg/kg

dry weight) of Pb, Cr, Cd, Cu, Zn and Fe from the three

sites were, respectively, 28.3, 62.4, 10, 17, 398 and 8,822.5

from site I and 1.7, 57.6, 0.7, 4.5, 32.1 and 8,827 from site

II and 2.1, 41, 1.3, 5.7, 24.1 and 8,816.1 from site III.

Table 1 Heavy metals

concentrations (mg/kg dry

weight) in surface sediments

from the coast of Sfax–Chebba

nd not determineda Martin and Whitfield (1983)b Rais (1999)c Boudjellal et al. (1993)d Ahdy and Khaled (2009)

Site Station Metal

Pb Cr Cd Cu Zn Fe

I S1 20.2 1.6 36 2.6 2,077.3 8,825

S2 25.8 185.8 20.5 81.4 281.9 8,817

S3 125.2 21.3 6.8 8.1 270.1 8,826

S4 9.8 nd 1.8 6.5 47.7 8,820

S5 11 196.9 1.9 6.3 41.6 8,822

S6 4.9 9.9 2.1 4.8 40.4 8,830

S7 1.2 20.9 0.8 9.2 26.9 8,817.6

II S01 2.7 8.3 0.5 1 27.1 8,831.6

S02 2.3 14.5 0.8 2.7 59.9 8,824.8

S03 0.2 149.9 0.8 9.9 9.3 8,824.5

III S001 0.6 1.5 0.1 nd 3.6 8,816.3

S002 4.5 50.2 6.5 15.3 85.4 8,814.7

S003 2.4 57.2 0.9 11.3 11.6 8,815.9

S004 nd 97.5 0.8 7.9 23.4 8,816.3

S005 1.4 21.2 0.7 2 27.9 8,813.2

S006 1.6 105 0.3 4.5 14.0 8,812.5

S007 0.7 20.4 0.8 2.7 22.2 8,819.6

S008 2.5 20.8 0.6 2 20.8 8,821.2

S009 nd 25 0.9 1.5 5.1 8,816.9

S0010 7.1 11.4 0.9 10.4 26.5 8,814

Range 0.2–125.5 1.5–196.9 0.1–35.9 1–81.4 3.6–2,077.3 8,812.5–8,831.6

Crust averagea 16 71 0.2 32 127 35,900

Golf of Tunisb 112 nd 7 79 226 –

Bay of Algerc 93 63 1.10 79 256 –

Egyptian

Mediterranean Sea

(range)d

20.7–35.6 16.24–34.2 0.5–0.9 26.5–33.3 26.3–112.1 –

Environ Earth Sci

123

Page 5: Metal contamination of surface sediments of the Sfax–Chebba coastal line, Tunisia

Lower metals concentration in sites II and III were

observed, probably due to low anthropogenic activities in

the area. The coastal area was mostly dominated by man-

grove. Human population inhabited these sites was also

limited. The concentrations of heavy metal in the studied

sediment samples followed the order of sites I [ II [ III

for Cr and Zn. Concentrations of Pb, Cd and Cu showed the

following order: I [ III [ II, while Fe showed no clear

pattern as for other metals (Fig. 2). The mean metal

concentrations in sediment from stations closed to Sfax city

(site I) exceeded the crust average values (Martin and

Whitfield 1983). Mean concentrations of all metals (except

for Cd) were below crust average in sites II and III.

When compared to metal concentrations in sediments

from other inshore sectors of the Mediterranean Sea, con-

centrations of Pb, Cr, Cd, Cu and Zn in Sfax–Chebba coast

sediments were found higher (Table 1). This result indi-

cated heavy metal contamination of the studied sediments.

Pb

0

10

20

30

40

50

60

70

80

Cr

0

20

40

60

80

100

120

140

160

Cd

0

5

10

15

20

25

Cu

0

5

10

15

20

25

30

35

40

45

50

Zn

0

200

400

600

800

1000

1200

1400

Fe

0

2000

4000

6000

8000

10000

I II III I II III

I II III I II III

I II III I II III

Co

nce

ntr

atio

n (

mg

/kg

)

Co

nce

ntr

atio

n (

mg

/kg

)

Co

nce

ntr

atio

n (

mg

/kg

)

Co

nce

ntr

atio

n (

mg

/kg

)

Co

nce

ntr

atio

n (

mg

/kg

)

Co

nce

ntr

atio

n (

mg

/kg

)

Fig. 2 Mean metal concentrations

(mg/kg) in sediments of each site

group

Environ Earth Sci

123

Page 6: Metal contamination of surface sediments of the Sfax–Chebba coastal line, Tunisia

The computed enrichment rates of heavy metals [by

Eq. (1)] showed that the urban area is more enriched in

terms of Pb, Cr, Cd, Cu and Zn (Fig. 3). In such area, these

metals are characterized by higher rates varied between 4.5

and 94 %.

The values of TEL for each metal and also the number

of samples exceeding TEL are presented in Table 2. As

shown in Table 2, Metal concentrations of the aforemen-

tioned metals exceeded the TEL values for surface sedi-

ment samples. Moreover, it was revealed that

approximately 14, 29, 100, 14 and 43 % of the sediment

samples in site I for Pb, Cr, Cd, Cu and Zn, respectively,

had concentrations exceeding the TEL values for superfi-

cial sediments (Fig. 4). In site II, 34 and 67 % of the

sediment samples for Cr and Cd, respectively, had con-

centrations exceeding the TEL values. For Pb, Cu and Zn,

the concentrations do not exceed the TEL values. In site III,

only Cr and Cd had concentrations exceeding the TEL

values (30 and 70 %, respectively).

The computed metal enrichment factors in the studied

sediments with respect to average crust (Martin and

Whitfield 1983) showed that the EF of Pb ranges from 0.05

to 31.8, EF of Cr from 0.1 to 11.3, EF of Cd from 2.2 to

731.8, EF of Cu from 0.1 to 10.3 and EF of Zn from 0.1 to

66.5. The highest EF values were observed in stations near

the Sfax city with high anthropogenic activities, whereas

the lowest values were found in stations from site II and

site III. Some stations from site II and site III showed

important EF values of Cr and Cd. This significant

enrichment is related to the impact of dispersed anthropo-

genic sources along the coastline of the pre-urban and rural

areas. Among the site groups, EFs for all metals studied

were higher in site I when compared to other sites (Fig. 5).

The EF mean values for Pb, Cr, Cd, Cu and Zn were,

respectively, 7.2, 3.6, 202.9, 2.2 and 12.8 for site I; 0.4, 3.3,

13.9, 0.6 and 1 for site IIl; 0.5, 2.4, 25.6, 0.7 and 0.8 for site

III.

Based on the interpretation suggested by Birch (2003),

sediments in site I were categorized as moderately to

extremely severe enriched. Minor enrichment of Cu was

only observed in site I. No enrichments of Pb, Cu and Zn

were distinguished in sites II and III, while severe enrich-

ment by Cd was observed in site II and III. For the Cr, EF

values showed moderate enrichment in site II and minor

enrichment in site III.

Site I had the highest anthropogenic activities when

compared to the other stations, as mentioned earlier. Sites

II and III, where the anthropogenic activities is low,

showed the lowest EF values indicating less anthropogenic

inputs into the studied sites.

The results of computed geoaccumulation index (Igeo)

values are regrouped in Table 3. This index consists of

seven classes in relation to pollution extent. In site I, sed-

iments can be considered as unpolluted to strongly polluted

by Pb, whereas in the other sites, sediments are unpolluted

by this metal. For the Cr, the quality of sediments varies

from unpolluted to moderately polluted in sites I and II and

unpolluted in site III. According to Igeo values of Cd,

sediments can be considered as moderate to extreme pol-

luted for site I, from unpolluted to moderately polluted for

site II and from unpolluted to strongly polluted for site III.

Site I can be considered as unpolluted to moderately pol-

luted by Cu. The Igeo for Zn indicated strong contamination

in some stations from site I. However, no contamination by

this metal was detected in sites II and III.

Results of the descriptive study presented above were

refined by a PCA. Person’s correlation analysis was applied

to test the relationship among the heavy metals analyzed.

The correlation matrix showed that in overall stations Cd

and Zn, on one hand, and Cu and Cr on other hand, were

highly correlated with each other showing a strong positive

association (r = 0.92; p \ 0.05) and (r = 0.58; p \ 0.05),

respectively, while Pb, Cr, Cd, Cu and Zn were not

-100

-80

-60

-40

-20

0

20

40

60

80

100

Pb Cr Cd Cu Zn Fe

Enr

iche

men

t ra

te (

%)

Fig. 3 Enrichment rate for selected heavy metals

Table 2 Trace element concentrations (mg/kg dry weight) compared to marine sediment quality standards

Class Pb Cr Cd Cu Zn References

China sediment quality assessment guidelines TEL 30.2 52.3 0.68 18.7 124 Junhong et al. (2011)

Number of surface samples (site I) exceeding TEL/number of samples 1/7 2/7 7/7 1/7 3/7

Number of surface samples (site II) exceeding TEL/number of samples 0/3 1/3 2/3 0/3 0/3

Number of surface samples (site III) exceeding TEL/number of samples 0/10 3/10 7/10 0/10 0/10

Environ Earth Sci

123

Page 7: Metal contamination of surface sediments of the Sfax–Chebba coastal line, Tunisia

correlated with Fe as seen in Table 4. The high correlation

obtained between Cd and Zn and between Cu and Cr in

surface sediments of Sfax–Chebba coast suggests common

pollution sources of these metals. In contrast, lack of cor-

relations with Fe reflects an anthropogenic contribution of

these metals.

The PCA applied to all metal concentrations resulted

essentially in three principal components. The threshold of

significance considered for p \ 0.05 is equal to 0.423 after

the student test (n = 20). The significant correlations

between selected parameters (variables) and the compo-

nents represent approximately 65 % of the total variance.

The contribution of the first, second and third PCs of the

total variance are 36.29 and 17 %, respectively. Over the

1 9 2 factorial plane (presenting the maximum of inertia),

one can clearly show three distinct groups (Fig. 6):

– The first group (G1), which is negatively displayed

over axis 2, is representative of Fe. It is representative

of the natural component.

– The second group (G2), which is positively displayed

over axis 1, is representative of Cd, Zn and Pb. These

metals present among each other highly significant

positive correlation coefficients. This group did not

show any correlations with the first group, testifying the

impact of anthropogenic sources.

– The third group (G3), which is positively displayed over

axis 2, is articulated around Cr and Cu. Those metals (Cr

and Cu) showed significant positive correlation coeffi-

cients, but they did not show any correlations with

metals of the first and second groups. This clearly shows

the impact of other anthropogenic sources.

Conclusion

This study has been performed to assess the contamination

state of the Sfax–Chebba coastal line. From the geo-

chemical analysis viewpoint, the studied heavy metals (i.e.,

Pb, Cr, Cd, Cu, Zn and Fe) showed an important spatial

variation and significant inter-level enrichments, especially

for Cr, Cd, Cu, and Zn. It was also found that those metal

concentrations exceeded the TEL, especially in stations

near Sfax city (site I). The same behavior was observed for

metal enrichment factors (EF) and geoaccumulation index

(Igeo), further testifying the significant metallic pollution.

Those results allowed the classification of the site I sedi-

ments as moderately to extremely severe enriched by Pb,

Cr, Cd and Zn.

The statistical analysis of data by PCA showed that

anthropogenic inputs derived from industrial developments

and habitations are among the contamination sources that

directly impacted the coastal sediments of study area.

Study area appeared affected on one hand by anthropo-

genic sources emitting Cd, Zn and Pb, and on other hand it

seemed to be affected by other multiple anthropogenic

sources emitting Cr and Cu.

Although sediment contamination of ‘‘Sfax–Chebba’’

coastal line by heavy metals concerned especially the urban

area of the northern coast of Sfax city, it may possibly be

extended to rural area if significant and effective strategies

of management are not adopted.

0

1

10

100

1000

Pb Cr Cd Cu Zn

Enr

iche

men

t F

acto

r (E

F)

EF site I

EF site II

EF site III

Fig. 5 Mean enrichment factor (EF) for analyzed metals in different

sites

0

20

40

60

80

100

Pb Cr Cd Cu Zn

TE

L e

xcce

din

g r

ate

(%)

Site I

Site II

Site III

Fig. 4 TEL exceeding rate

Environ Earth Sci

123

Page 8: Metal contamination of surface sediments of the Sfax–Chebba coastal line, Tunisia

It is strongly recommended to perform an in-depth study

of the heavy metal impact on biological resources of the

Sfax coastal line.

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