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Published by: Indian Centre for Plastics in the Environment A Programme on “Environmental Management Capacity Building Technical Assistance Project”, Sponsored by Ministry of Environment and Forests, Government of India. Management of Plastics, Polymer Wastes and Bio-polymers and Impact of Plastics on the Eco-system Volume 6 • Issue 1 • Jan.-Mar. 2008 For Internal Circulation only Contents Editorial 2 Closing the Loop 3 Plastic Power 6 Plastics Recycling Technologies 8 China Drafts Plastics Bag Standards 11 California Ban on Plastics Bags 12 Less Plastic Going to Landfill 13 Banning of Plastic Bags – Notifications 13 Use of Plastics Waste in the Construction of Asphalt Road 14 Plastics Saves Energy 16 ICPE Participation in Exhibition and Awareness Programmes 18

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Page 1: Management of Plastics, Polymer Wastes and Bio-polymers ...icpe.in/envis_newsletter/Envis_Jan_Mar_08.pdf · European average with 15.7% mechanical recycling, according to the Plastics

Published by: Indian Centre for Plastics in the Environment

A Programme on“Environmental ManagementCapacity BuildingTechnical Assistance Project”,Sponsored by Ministry ofEnvironment and Forests,Government of India.

Management of Plastics, Polymer Wastes andBio-polymers and Impact of Plastics on the Eco-system

Volume 6 • Issue 1 • Jan.-Mar. 2008For Internal Circulation only

Contents

■ Editorial 2

■ Closing the Loop 3

■ Plastic Power 6

■ PlasticsRecycling Technologies 8

■ China DraftsPlastics Bag Standards 11

■ California Ban onPlastics Bags 12

■ Less Plastic Going to Landfill 13

■ Banning of Plastic Bags –Notifications 13

■ Use of Plastics Waste in theConstruction of Asphalt Road 14

■ Plastics Saves Energy 16

■ ICPE Participation inExhibition andAwareness Programmes 18

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Name of the ENVIS Centre

INDIAN CENTRE FOR PLASTICS IN THE ENVIRONMENTOlympus House, 2nd Floor,

25, Raghunath Dadaji Street, Fort, Mumbai – 400 001.Tel.: 022-22617137 / 22617165 / 22617168

E-mail: [email protected]; [email protected]: www.icpeenvis.nic.in; www.envis-icpe.com; www.icpenviro.org

★ ★ ★

1009, Vijaya Building, 10th Floor, 17 Barakhamba Road, New Delhi - 110 001.Tel.: 011-2332 6377 • Fax: 011-2332 6376 • E-mail: [email protected]

Area of ActivityCapacity Enhancement Programme on Management of Plastics,

Polymer Wastes and Bio-polymers, Impact of Plastics on Eco-System

Head of InstitutionMr. K. G. Ramanathan, President-Governing Council

Mr. Sujit Banerji, Executive Secretary/Member-Executive Committee

ICPE-ENVIS Co-ordinatorMr. T. K. Bandopadhyay, Sr. Technical Manager

Readers are welcome to send their suggestions, contributions, articles, case studies,and new developments for publication in the Newsletter to the ICPE-ENVIS address.

Reproduction of material from this Newsletter is welcome, with prior permission.

For more information on ENVIS and about the contents, please contact Editor

Editorial

ICPE-ENVIS Centre has been publishing the ENVIS Newsletter since 2003.The Newsletter has been bringing important information on various issueson Plastics - its positive impact on Environment, problems of PlasticsWaste Management and the possible scientific solutions; vital data onLifecycle Analysis of Plastics and Energy Savings by Plastics have beenprovided in various issues of the Newsletter. It will be our endeavour tocontinue our work in this direction to build up more data in the area ofactivity and to reproduce the same in more user-friendly way. The currentissue of ENVIS Newsletter has adopted a new approach as per thesuggestions of the ENVIS Headquarters in the Ministry. Readers mayplease send their comments and suggestions to improve the quality ofthe Newsletter.

Readers are also requested to visit ICPE-ENVIS website:www.icpeenvis.nic.in to view the updated information on issues relatedto Plastics in the Environment.

T. K. BandopadhyayEditor - ICPE-ENVIS Newsletter

ICPEhas moved toNew Premises

EditorMr. T. K. Bandopadhyay

Sr. Technical Manager,ICPE, Mumbai

Editorial BoardMr. P. P. Kharas

Member - Governing Council,Convenor - Communication

Mr. Vijay MerchantNGO - Projects Member,

Governing Council

Mr. P. V. NarayananAdvisor, ICPE

Mr. T. K. BandopadhyaySr. Technical Manager,

ICPE, Mumbai

Ms. Savita PradeepTechnical Manager,

ICPE, New Delhi

Subscription Information:ENVIS is sent free of cost to all those

interested in the informations onPlastics and Environment

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Plastics Iitter has been headline news in recentmonths. Reducing the amount of waste going to landfillis an important way of tackling this issue.

The good news is that in Europe the amount of wasteplastics going to landfill has fallen steadily since 1999.Overall recovery of plastics waste in the EU-25, plusNorway and Switzerland, reached 50% in 2006,according to a recent report by PlasticsEurope.1

Total recovery rates, which include recycling as wellas energy recovery, are up from 47% in 2005. Whatthis means is that we are now recovering the sameamount of plastics as we are putting into landfill (C&I2008, 3, 7).

An important element of the UK's strategy to evadelandfill is to promote recycling. Recycling of end-of-life plastics stood at 15.7% in the UK in 2006,compared with an average of 19.7% across the EU-25, plus Norway and Switzerland.

The plastics recycling industry is growing strongly inthe UK. This expansion of plastics recycling is not only

mandated by European waste managementlegislation, but also sparked by rising prices for virginmaterials and improved waste collection and sortingtechnologies.

To move away from exporting plastic packaging wastefor treatment overseas, more PET recycling capacitiesare springing up in the UK. The world’s largest bottlerecycling facility is currently being built not at CocaCola's headquarters in Atlanta, Georgia, but inHemswell, Lincolnshire (C&I 2007, 18, 10). It can dealwith PET (drinks) and HDPE (milk) bottles and isexpected to come on stream commercially later thisyear. It will be capable of handling up to 100,000t ofmixed plastic bottles annually.

PET bottle collection grew to see 40% of all PET bottlesin Europe collected for recycling in 2006. Therecovered PET (rPET) is partly made into polyesterfibres for the textile industry; for example, it takes 25two-litre PET bottles to make one ‘fleece’ garment.Another option is polyester sheet, but as recyclinggrows these markets become saturated. This makesit increasingly interesting to close the loop and turnPET into drinks bottles again.

A number of approaches have been developed forproducing food grade rPET. In a multi-layer system,for instance, recycled material is covered with orsandwiched between virgin materials. But the use ofrPET for direct food contact is expanding, not leastbecause drinks producers such as Coca Cola are facingpressure from consumers to use recycled materials.

Closing the LoopDespite the negative publicity overplastics waste, polymer recovery isincreasing across Europe, reportsJan-Erik Johansson*

* Jan-Erik Johansson is Advocacy Director ofPlasticsEurope and a Chemical Engineer

In brief• Overall recovery of plastics waste in the

EU-25, plus Norway and Switzerland, reached50% in 2006.

• More than 70% of the UK’s plastics waste islandfilled, compared with less than 10% inSwitzerland, Denmark, Sweden and Austria.

• The world’s largest bottle recycling facility isbeing built in Lincolnshire, UK.

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Mechanically, food-grade rPET canbe produced through a supercleaning process, for example,involving a hot wash using causticsoda and low foaming detergents.Typically, a decontaminationprocess follows either before orafter extrusion, involving heatingfor at least four hours at 200°Cunder a vacuum or in an inertatmosphere such as nitrogen.

Mechanical recycling accounted forthe bulk of all plastics recycling inEurope in 2006 as 19.1% of allwaste plastics went through thisprocess, up 1.7% on 2005. The UKperformed slightly below theEuropean average with 15.7%mechanical recycling, according tothe Plastics Europe report.

In addition, the recycling of PVCwindow frames and other profilesis increasing exponentially andgrew by 84% on 2005 levels in2006. Collection schemes forwindows and window relatedprofiles exist in many Europeancountries, including the UK. ThePVC granules from window framesand profiles are reused for producing new PVCconstruction products.

Feedstock recycling, which involves decomposing thepolymers into their constituent components, is aninteresting niche application. It has the advantage thatit is more flexible over the composition of the feedmaterial and more tolerant to impurities thanmechanical recycling, although it is capital-intensive

and requires large quantities of plastics to beeconomically viable.

One way to achieve this is a process of gasification.The long polymer chains are broken down into smallmolecules, for example, into synthesis gas. Syngas,consisting of carbon monoxide, carbon dioxide andhydrogen, can then be used as a basis for methanol,oxo-alcohols, ammonia and methyl formiate. These

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in turn serve to produce a wide range of organicchemicals – including plastics. Before repoly-merisation, the matter needs to be decolourised andcontaminants removed.

Chemical recycling of plastics is also possible throughpyrolysis, that is, heating the waste pellets in theabsence, or near absence, of oxygen. This technologycan produce a naphtha feedstock for petrochemicalprocessing. Treating the pyrolysis gases in a catalyticconverter and condenser system yields a hydrocarbondistillate comprising straight and branched chainaliphatics, cyclic aliphatic and aromatic hydrocarbons.Through careful condensation and fractionation, thesegases can be turned into petroleum distillate. A de-sulphur unit makes the process complete and turnsthe plastics waste into diesel.

End-of-life plastics can also be used as a reducingagent in the blast furnaces of steel and non-ferrousmills. Pellets made from mixed waste plastics partiallyreplace coke in the production of pig iron from ironore. The heat in the furnace breaks the plastics downinto synthesis gas, which then reduces the iron ore topig iron. This method has been practised on a largescale in Germany for many years.

Although promising, feedstock recycling is not verywidespread. Only five countries in Europe havecapacity for feedstock recycling: Germany, Norway,Sweden, Austria and Poland. In 2006, it accountedfor only 0.6% of all plastics waste treatment in theEU-25 plus Norway and Switzerland, down 1% from2005. This is mainly due to reduced conversion in agasification plant in Germany, but also due to thechallenging economics of such technologies.

But increasing recycling is only one way of reducinglandfill. Integrated waste management requires arational and all encompassing analysis of theenvironmental impact related to the differentpossibilities for treating waste. In 2001, a studyconducted by the Netherlands-based researchorganisation TNO for PlasticsEurope forecast thatmechanical recycling would be optimal at 15-20% ofthe plastics packaging waste volume. More recycling,

the study concluded, would notreduce the environmental impact,but would increase costs by a factorof three.

This is because the collection,shipment, cleaning and sorting ofplastics packaging waste, which isoften mixed and contaminated bydirt, generates an environmentalimpact itself and this can outweighthe benefits of recycling beyond acertain volume. Additionally, therequired quality of the recyclate

needed for a specific application may not be met,which might mean that the material cannot be putback on the market.

Today, most countries achieve around 20-30% inplastics recycling, even in the most environmentallyconscious countries in Europe. This increase,compared with the TNO forecast, is a result ofinnovation in cleaning and sorting technology that hasimproved the environmental impact of recycling.

If it is difficult to get beyond 20-30% recycling, whatis the most eco-efficient way to deal with theremainder? Plastics can be described as solid oil, solandfilling them would amount to putting oil into theground. The high energy content in plastics is toovaluable to throw away and well worth recovering.

Energy recovery from waste is relatively undevelopedin the UK where it accounted for just 7% of plasticswaste treatment in 2006, compared with 30.3% in theEU-25 (plus Norway and Switzerland), and more than65% in countries such as Austria, Denmark, Swedenand Switzerland.

An additional efficient recovery route involves the useof solid recovered fuel (SRF). When all eco-efficientlyrecyclable items are removed, SRF can be preparedfrom the residual organic fraction of, for example,household waste. This mixture of wood, paper andplastics can be separated and converted into asubstitute fuel. It can be used for co-combustion incement kilns, paper mills and power plants where itreplaces coal or other solid fuels.

A combination of these different techniques is neededfor eco-efficient waste management. Diverting wastefrom landfill is also a boon to the climate because itreduces emissions of methane, a greenhouse gas23 times more powerful than CO2.

Reference:1 The compelling facts about plastics 2006,PlasticsEurope, Brussels, January 2008.

(Source: Chemistry & Industry – 24 March 2008)

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New EU legislation, in the form of the WasteFramework Directive (WTD), is aiming to tighten uprules on waste management to ensure that there ismore prevention of waste. A major difference that hasemerged between the plastics industry and politiciansis that the MEP's want to give absolute priority torecycling. The plastics sector, on the other hand, islooking for a balance between recycling and energyrecovery. This would mean that as much as possibleof the waste that cannot be mechanically recycled isturned in to energy or even into polymer feedstocks.

The legislation is due to be finally approved later thisyear by the Council of Ministers, representing thegovernments of the EU's 27 member states, and theEuropean Parliament. The council has alreadyreached agreement on a common position on thecontent of the directive. Parliament is scheduled tovote on the legislation in a second reading.

The directive aims to clarify and define what is waste,recycling, recovery and disposal. It attempts to makea clear distinction between recovery and disposal. Asa result, the use of landfill, which is regarded asexcluding any attempt at recovery, will become a lastresort.

‘The objective of the directive is to create the highestvalue out of waste but how that highest value will be

achieved can be a difficult question to resolve,' saysHarald Kaeb, managing director of the EuropeanBioplastics Association, Berlin.

The plastics industry reckons that high levels ofrecovery of waste can be reached by exploiting theenergy content of plastics. In 2006, nearly 20% ofplastics was recycled into other products or materialswhile 30% or 7.4 mt was recovered as energy,according to PlasticsEurope, the industry bodyrepresenting polymer producers. This 30% of plasticsis theoretically capable of generating nine gigawattsof energy, PlasticsEurope says. This is the equivalentof nine large power stations working at 100%efficiency with cogenerated power and steam.

Energy recovery is seen by the plastics industry aswell as by much of the waste management sector, ascrucial to finding environmentally positive ways ofdealing with unrecycled mixed municipal solid waste.Currently less than 40% of EU municipal waste isrecycled, while nearly half is landfilled and less thana fifth is recovered for energy through incineration.

'Plastics have a high calorific value close to that ofgasoline or diesel and much higher than coal or wood,'explains Jan-Erik Johansson, PlasticsEurope'sregional director for North Europe. 'Plasticsaccounting for 10% by weight of a mixed waste streamcan make up 30% of its calorific value.'

Plastic PowerProducing energy from plastics could becrucial weapon in the EU’s quest toreduce levels of waste going to landfill,writes Sean Milmo

In brief• Due to be introduced later this year,

the EU's waste framework directiveaims to reduce the amount of wastegoing to landfill.

• In 2006, nearly 20% of plastics wasrecycled, and 30% was recovered asenergy.

• More energy recovered from plasticscould potentially further reduceamounts being landfilled.

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If amounts of waste going into landfill are to bedrastically reduced – which is one aim of the directive– energy recovery appears to be the obvious majoralternative. In the longer term, the plastics industrywould like the use of gasification and/or pyrolysisprocesses so that mixed waste with a plastics contentcan be turned into chemical feedstocks formanufacturing polymers and other products, or intoelectricity or fuels. Gasification transforms the wasteinto syngas, comprising carbon monoxide andhydrogen, from which methanol can be made as abase feedstock.

'Gasification will offer another route besidesincineration in energy recovery,' says AafkoSchanssema, a consumer and environmental affairsspecialist at PlasticsEurope. "This form of wastemanagement will fit into the new infrastructure ofbiorefineries and other facilities which will beestablished in Europe to provide new low-carbonsources of energy and raw materials from biomassand other waste.”

In this common position on the waste frameworkdirective, the council backed the use of gasificationand pyrolysis. It decided, however, that incinerationwould only be categorised as an approved energyrecovery method if the incinerator is used for boththe generation of electricity and heat with an energyefficiency of at least 60%.

‘This efficiency standard is not linked to the energycontent of the waste or the amount of plastic in it,'says Schanssema. ‘The determining factor is thecombination of heat and power. This suits countrieslike Denmark where there are a lot of district heatingsystem linked to incinerators producing both stem andpower. But it is not much benefit in countries like Italy,which does not have an infrastructure for heat andpower facilities.'

Some MEPs want even stricter controls on the use ofincineration in the belief that as much recycling aspossible should be encouraged. In particular, they wishto deter companies from avoiding recycling byresorting directly to energy recovery. 'There are someMEP colleagues who are opposed fundamentally tothe idea of energy from waste plants and who willnever vote for them in any shape or form,' saysCaroline Jackson, a UK Conservative MEP andrapporteur on the directive for the Parliament'senvironment committee.

In addition to the greater emphasis on recycling, MEPswant the legislation to include targets so that EUcountries are under pressure to raise levels of wasteprevention, re-use of products or components and ofrecycling. In its common position the council ignoredtargets, even though Parliament had given highpriority to their adoption in its first reading. 'It would

be wrong to miss the opportunity to ensure that thisdirective does more than supply a set of definitions,'says Jackson.

She is proposing that by 2012 member states shouldstabilise their output of waste at 2009 levels eventhough municipal waste has been growing by anaverage of 2% / year since the mid-1990s. By 2020the amount of household waste re-used or recycledin the EU should also be increased to a minimum 50%.

MEPs want close adherence to a five-stage wastemanagement hierarchy set out in the directive. Thisstarts with prevention of waste, then re-use, followedby recycling, after which comes recovery, includingenergy recovery, and finally disposal, such as landfill.

The council agreed that departure from the hierarchymay be 'necessary for specific waste streams whenjustified for reasons of, inter alia, technical feasibility,economic viability and environmental protection.'

This variable approach would appear to allowbioplastics waste, which because of its low quantities,is being excluded from mechanical recycling processesor even in some cases composting operations, tobypass the hierarchy. 'Until we have higher volumesof bioplastics in the marketplace, the best option isfor bioplastics waste to go straight to the energyrecovery stage', says Kaeb.

In response to the desire of some MEPs for amandatory hierarchy, Jackson is proposing that onlyafter 'consultation and involvement of citizens andstakeholders' can divergence from the five-stagesystem take place. 'The directive must make clear thatdepartures from the hierarchy cannot take placecasually and must be done as part of an orderedprocess.'

However, PlasticsEurope claims that such a‘bureaucratic' approach will hamper the developmentof new processes such as gasification, in which therewill be a need to switch between energy and feedstockrecovery. 'There are a lot of innovations taking placewith technologies which can make waste managementof plastics more efficient,' says Schanssema. "Thelegislation should be phrased in such a way as to allowthe development of the innovations of the future.”

Jackson's task is to find a compromise between whatParliament and the council wants. In return for thesupport of the council for its recycling target,Parliament may soften its stance on the hierarchy,which will give the plastics industry more of theflexibility it desires.

Sean Milmo is a freelance writer based in Essex UK.

Source: Reprinted with the permission of Neil EisbergEditor, Chemistry & Industry

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PlasticsRecycling TechnologiesA Note prepared by Indian Centre for Plastics in the Environment

Human consumption has far outstrippedavailable resources causing a seriouschallenge to our future generations.Recycling as a process has been given atop priority in the world body – UNO.

The selection of methodologies and processes for themanagement of plastic wastes available from pre-consumer sources and end of life products may beapproached using various strategies, all of whichshould include a preliminary analysis of the availablerecovery options.

While determining the methodologies of recoverysystem, it is required to make a distinction betweendifferent recovery options, as below:

Recycling of Plastics has been classifiedinto 4 main categories:A. Primary Recycling – Conversion of waste plastics

into products having performance levelcomparable to that of original products made fromvirgin plastics.

B. Secondary Recycling – Conversion of wasteplastics into products having less demandingperformance requirements than the originalmaterial.

C. Tertiary Recycling – The process of producingchemicals/fuels/similar products from wasteplastics.

D. Quaternary Recycling – The process of recoveringenergy from waste plastics by incineration.

International Standards like ISO refers PlasticsRecycling as a Recovery Process and the differentcategories of recovery processes are broadly as below:

Recovery has been divided into two categories –MATERIAL RECOVERY and ENERGY RECOVERY.

The processes considered under Material Recoveryare:

1) Mechanical Recycling,

2) Feedstock Recycling, and

3) Biological Recycling.

The category considered under Energy Recovery isdirect and controlled combustion to generate heat.

The schematic diagram of some plastic recoveryoptions.

MATERIAL RECOVERY1) Mechanical Recycling:This is the most preferred and widely used RecyclingProcess due to its cost effectiveness and ease ofconversion to useful products of daily use. Thelimitation of this process is that the process requireshomogeneous and clean input.

The process of Mechanical Recycling of waste plasticsinto products of varying usefulness mostly involvesthe following essential steps:

a. Collection / Segregationb. Cleaning & Dryingc. Sizing / Chippingd. Agglomerating / Colouringe. Extrusion / Pelletisationf. Fabrication into End Product

Each of the above steps involves a series of operations.

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a. Collection / Segregation:

The basic principle of plastic/polymer processing isthat the polymeric materials under processing arerequired to be compatible with each other.

Certain polymeric materials are compatible with eachother at all proportions. For example, LDPE andLLDPE are generally compatible to each other at allproportions.

However, it is to be remembered that even differingmolecular weight variety of the same polymer maynot be compatible for useful purpose. For example,phase separation may occur if a high molecular gradeof LDPE is processed with a very low molecular weightLDPE.

The advanced technology of separating/segregatingdifferent types of waste plastics involves ‘FloatationProcess’. In this process, the property of the varyingdensities of different plastics is made use of forsegregating different types of plastics.

However, in the Indian context, this separation orsegregation process, in many cases, is done by manualprocess utilizing the availability of cheap and expertlabour force.

In case the waste is contaminated with embeddedmetals, proper method of separating the metals/othercontaminants is required.

b. Cleaning & Drying:

The scale of cleaning depends on the type of waste.Generally, industrial waste does not require significantcleaning operation, whereas, post-consumer wasterequires proper cleaning. Whenever a cleaningoperation is involved, it is to be ensured that the wateror any other cleaning material used, should bedischarged after ascertaining that the discharge doesnot contain any objectionable substance. A properTreatment Device may have to be deployed – like awater treatment plant/effluent treatment plant. Fordrying, a suitably designed drier is used.

Many industries situated outside the metropolises, useopen space for natural drying of the cleaned waste.

c. Sizing/Chipping:

The cleaned plastics waste is then required to beproperly sized so that those may be fed into theextruders for processing and pelletizing. The sizingoperation depends on the type and shape of the wasteplastics.

During this process, attention is required to separateany powdery material from the sized / chipped plastics.

d. Agglomerating/Colouring:

In the next operation the sized plastics waste is mixedwith colour master batch in high-speed mixers/agglomerators and the output is ready for extrusioninto pellets.

e. Extrusion/Pelletisation:

This is the most important part of the process whereinthe sized/chipped plastics are plasticised andregranulated to make the plastics material ready forfabrication next. The type and size of the Extruderdepend on the type and volume of the plastics waste.

f. Fabrication into End Product:

Finally the reprocessed plastics granules are used asraw material for producing end products using similarfabrication machines like Injection Moulding/Extrusion, etc., depending upon specific requirement.

2) Feedstock Recycling:In this process the Plastic Wastes are converted into:

• Monomer – About 50% Recovery is possible.

Limitation – Large Scale Process generally setupby the basic raw material manufacturers.

• Fuel – Close to 100% Recovery ispossible divided into main fractionof liquid fuel (about 75%), solid fuel(about 15%) and gaseous fuel(about 10%).

The technology, however, isproprietary in nature and isavailable only to select technologyprovider in the developed and developing countries.

One Indian scientist (Nagpur-based) has developedthe technology a few years back which has beencommercialized in a small way. As per availableinformation, a small plant of 5 tonne per dayproduction capacity costs around Rs. 7 crores andcan offer the liquid fuel in the market at a price ofaround Rs. 25 per litre.

The fuel can be used in place of normal keroseneused for industrial purpose. It is also reported that6 units of electricity can be generated from 1 litreof fuel thus produced.

Advantage of this process includes use of all typesof plastics including laminated plastics withoutcreating any environmental pollution.

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• Reducing agent in blast furnacefor the production of iron.

The carbon and hydrogen molecules in plastics(wastes) take part in the conversion reaction insidethe blast furnace for the production of iron fromthe basic iron ore.

Use of plastics help providing two reducing agents– carbon monoxide and hydrogen for the conversionreaction whereas the traditional coke used in theblast furnace provide only one reducing agent –carbon monoxide. A 3.0 million tons per annumcapacity steel plant can use up to 0.6 million tonsof plastic wastes per annum. The process iscommercially used in some developed countries.

Advantage of this process includes use of all typesof plastics including laminated plastics withoutcreating any environmental pollution.

3) Biological Recycling:This deals with mainly composting of compostableplastics and recovery of methane.

ENERGY RECOVERYOne of the most effective methods of Recycling ofPlastic Wastes for recovery of energy is the use ofplastic wastes as an alternative to fossil fuel in cementkilns. The process takes advantage of the highercalorific value of plastics compared to coal. The listbelow gives a comparison of the calorific values ofdifferent plastic materials as compared to coal.

Polyethylene 46 MJ/kgPolypropylene 44 MJ/kgPolyamide (Nylons) 32 MJ/kg

PET 22 MJ/kgCellulose Acetate 16 MJ/kgCoal 29 MJ/kg

The use of waste plastics as co-processor in cementkilns is in use commercially in many developedcountries. Recently, the process has been successfullytried in the ACC Cement Plant at Kymore under a jointproject of ICPE and ACC.

All types of plastic wastes without adequate cleaningcan be used in the process and the process is safe asper environmental norms. About 15% of fossil fuel canbe replaced in the process without much affecting thenormal production capacity of the cement kiln.

USE OF PLASTICS WASTE INROAD CONSTRUCTION

A unique process of use of waste plastics in theconstruction of Asphalt road has been developed inIndia in recent times. In the process, certain types ofwaste plastics (mostly polyolefins) can be blended withbitumen or coated on aggregates to improve theproperties of road and at the same time to reduce thecost to a limit of about 10 to 15% cost of bitumenwithout sacrificing the life of the road. The processdoes not require any additional machinery and canbe used anywhere using the same machineries usedfor road construction. The plastic wastes mostly carrybags and similar wastes are required to be pulverized/shredded into small pieces which is possible byemploying inexpensive / conventional machines.

Whichever form of recycling is chosen, the wholeprocess can succeed only if an efficient solid wastecollection mechanism is put in place at the firstinstant. The Government has already come out withThe Waste Management (Handling) Rules, 2000 forthis purpose. All out efforts are required to be putto implement the Government Rules on wastemanagement.

There is a need for Government intervention/support for encouraging recycling.ACC Cement Plant at Kymore

Blast Furnace

Construction of Tar Road using Plastics Waste in Mumbai.

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China has taken the first stepstowards implementing the newPlastic Shopping Bag law bypublishing a set of draft standardsdetailing measurements foracceptable types of plastics bags,labeling instructions, andinspection methods.

The Chinese State Council(Cabinet) issued a ban on theproduction, sale and use of plasticsshopping bags under 0.025mmthick, dubbed ‘ultra thin plasticsshopping bags’ on 1 January. All other types of plasticsbags are to be restricted.

The Chinese Standardization Administration publishedits first draft of the ban’s standards on 4 February.The draft standards, drawn up following consultationwith the China National Light Industry Council andthe Standardization Technology Committee of NationalPlastic Products, comprise three separate documents,each specifying what will be acceptable for plasticsbags, labeling requirements, and inspection methods.

What is a plastics bag?The first document contains the definitions,terminology, requirements, test methods, inspectionregulations, and other elements relating to thepackaging, transportation and storage of plasticsshopping bags.

The draft document states clearly that all plastics bagsused by the retail industry and other service industries,or any plastics bag used to carry any sort of item,falls within the law.

All plastics shopping bags must be more than0.025mm thick and free of bubbles, perforation or anyother defects. They should primarily be either clearor white in colour, although other colours areacceptable.

Plastics shopping bags which are used to contain foodmust be clear. Any printing on the plastics shoppingbags must not take up more than 20 per cent surfacearea.

China DraftsPlastics Bag Standards

So-called biodegradable, starch-based bags must contain at least15 per cent starch to beacceptable.

Physical propertiesPhysical properties and testsrequired of plastics shopping bagsare listed, including the acceptedchemical properties of the bags.

According to the regulations,‘During transportation, bags must

be covered to prevent machinery hitting the bags andsuffering sun and rain effects’.

In addition, instructions are given on how the plasticsshopping bags should be stored in a clean and dryenvironment free from contamination. Bags will havean expiry date not more than a year from theproduction date.

The regulations also state that manufacturers shoulddetermine the bags’ maximum storage time accordingto the bag’s physical properties.

Identification and labelingA very detailed set of rules govern the informationwhich must be printed on the plastics shopping bags.

Symbols indicating whether the bag is degradable,reusable or otherwise have to be shown. Bags mustinclude the manufacturer’s name, its dimensions inmillimeters, strength in kilograms and chemistryincluding material resins, fillers, plasticizers,reinforcing agents and other additives have to beprinted on the bag.

Standardization code numbers specifying theapproved material types of the plastics shoppingbags is provided in the regulations and the bags mustalso be printed with English acronyms in the text (suchas PP).

Bags containing recycled material must list all therecycled resins used and their respective weight-basedpercentages. Bags for medical purposes or chemicalsand pesticides must not be reused.

International News

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Bags for food usage must also carry a sign ‘For fooduse’, indicating that the plastics may be used in directcontact with food; in the fresh food markets wheremost Chinese shop for meat and seafood, vendors useplastics shopping bags without inner wrapping beforehanding it to their customers.

At the same time, food-used bags must reflect the resincolour and should not have added color pigments.

The specifications include diagrams of the requiredpositioning of various markings which all plasticsshopping bags must carry.

Additionally, as part of the consumer educationcampaign, all bags must carry the Chinese slogan, ‘Toprotect the environment and conserve resources,please reuse this bag as many times as possible’.

Other safety warnings such as keep away from infantsand children to avoid suffocation must also be printed.

Inspection methodsThe third regulation specifies the sample testing types,and also lays down guidelines for the bags’appearance, signs, thickness, length and width, andload strength, and outlines the methods for quickinspection, testing and evaluation.

The regulation states that every batch of plasticsshopping bags must be inspected and that a batch of

same model, same material composition bags whichare produced continuously should not exceed 5 tonnes.

Since the minimal basic requirement for the plasticsbag is that they must be more than 0.025 mm thick,inspectors are supplied with diagrams to show howthey should check the plastics shopping bags’thickness.

Inspectors are also instructed to smell the bags for‘strange’ smells presumably looking for toluene inksused in the printing, a ban which will soon be imposedin the Method for Administration on RecyclingPackaging Materials.

The Chinese Standards Authority is ‘open to feedback’on its draft regulations. Industry was granted exactly30 days to submit their suggestions, or objections, tothe draft. In reality, because of the New Year holiday,all Chinese businesses were closed from 7-21 January,leaving industry one week to make any submissions.

Each of the three documents contains standardizationcodes scattered throughout: GB/T xxxxx2008, (withthe XXXX to be replaced by the actual codes).

The speed and details in which these regulations havebeen written suggests that they have actually been inthe planning stage for many months. It also suggeststhat once passed, the Method for Administration onRecycling Packaging Materials will be implementedwith similar speed.

California Ban on Plastics BagsStruck down by Court in OaklandICPE-ENVIS had carried a news item on the banningof plastic carryout bags in Oakland.

It is now learnt that the CaliforniaCourt has struck down the ban onplastic carryout bags. The Courthas maintained that the city had notconducted an adequate study on theenvironmental impact of the ban thatwent into effect on January 18, 2008.This ban was never enforced.

The decision was handed down April17, 2008.

The Court had found evidence in therecord that supports at least a fairargument that single-use paper bags aremore damaging than single-use plastic bags.

The decision means Oakland will not beable to implement its ban unless itchallenges the decision or conducts afurther environmental impact review at anestimated cost of $125,000.

The Alameda Country court decisionstem from a lawsuit filed on August 3by the Coalition to Support Plastic BagRecycling.

The Coalition argued that themanufacturing or paper bagsgenerates 50 times more waterpollutants than the manufacturingof plastic bags.

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Recovery of plastics has finallyreached the 50% mark acrossEurope: the point where we arerecycling as much plastic as weare putting into landfills. PlasticsEurope’s report – thecompelling facts about plasticreveals that in 2006 half of allpost-consumer plastics endingup as waste were being usedagain either through straight-forward recycling or energyrecovery. Recycling ratesincreased to 19.7% and energyrecovery rate to 30.3%. As thesame time, demand for plasticincreased 4% to a total of 49.5mtons across Europe (EU25 + Norway and Sweden).

‘Improved collection and sorting techniques managedunder better national schemes lead me to forecast thatin 2007, growth rates for recycling and energyrecovery will be similar to 2006,’ says Jan-ErikJohansson of PlasticsEurope.

Seven countries, including Switzerland, Denmark,Germany, Austria, the Netherlands, Sweden and

Less Plastic Going to Landfill

Belgium, now recycle more than80% of their plastics waste, theultimate goal being to divert allplastic from landfill. But half ofEurope recovers less than 30%of their waste. And countrieslike the UK, Ireland and Greeceare at the bottom end of thescale, recovering only about20%.

The recycling rate is determinedmainly by how efficiently bottlesand films are collected andseparated. Countries can fairlyquickly improve their recyclingrate by organizing their

collection and separation schemes, according toJohansson, but moving beyond that is difficult, he says.

Europe now produces about 25% of the total estimatedworldwide plastics production of 245m tons. Theoverall turnover for the whole of the industry is morethan Euro 280bn.

Source: Chemistry & Industry 2008, 2, 8

Department of Public Relations,Chandigarh

Whereas the Chandigarh Administration is of theopinion that the use of polythene/plastic carry bags iscausing grave injury and is detrimental to theenvironment and the health of human beings as wellas animals; the Administration, Union Territory,Chandigarh exercising the delegated powers underSection 5 of the Environmental (Protection) Act, 1986hereby directs that no person including a shopkeeper,vendor, wholesaler or retailer, trader, hawker orferiwala shall use polythene/plastic carry bags forsupply of goods in polythene/plastic carry bags inUnion Territory, Chandigarh.

Domestic News

Banning of Plastic Bags – Notifications

Coimbatore Municipal CorporationBearing the environmental safety in mind and in orderto preserve the beauty of the city and its suburbs thisCouncil has decided to ban one-time used plasticarticles from being manufacture, used, sold and storedby any cities within Coimbatore Corporation.Accordingly the Coimbatore Corporation Council inits resolution No.68 dt.20-6-2000 and resolution No.170 dt. 11-6-2001 banned that plastic carry bagsbelow 20 micron thickness, plastic tumblers,manufacture of plastic sheets and sale and alsodecided to impose penalty on those who violateprovisions therefor.

As per the standing health community in No.18. dt9-1-2008, the Resolution is passed and placed beforethe Council for its approval.

Industry has submitted representation to the respective authorities to amend the notification appropriatelyin line with MOEF Rules.

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Use of Plastics Waste in theConstruction of Asphalt Road– ICPE-MCGM Joint ProjectUse of bitumen for the construction of asphalt roadhas been known since long back. Major requirementsof an asphalt road are:

• Good Binding Property• High Marshal Stability• Better Resistance to Water• Ductility – Reduced Surface Cracking• Penetration Value• Reduced Plastic Flow at High Temperature

Use of certain synthetic polymers to improve theadhesion and other properties of asphalt road is alsoknown to the road engineers. Following syntheticpolymers have been used to modify the properties ofbitumen for improving the quality and life of asphaltroads:

• PE – Either Wax or Resin• PP – Homo & Copolymers• PS• EVA• SBR

High cost of virgin synthetic polymers restricts theiruse in specific & high value/critical applications. Lowcost waste plastics offer an alternative to the high costvirgin synthetic polymers. In fact, as the cost of low-end plastics waste is less than that of bitumen, thereis a saving in the cost of road construction. This alsoprovides a scientific and environmental-friendlymethod of disposal of low-end plastics waste.

India is considered pioneer in using plastics waste forthe construction of asphalt road. Central RoadResearch Institute, Delhi, Thiagarajar College of

MCGM engineers supervising the operation

Plastics waste being prepared for mixing with the bitumen andaggregate

Ingredients being mixed with aggregate

Engineering, Madurai and K. K. Poly Flex, Bangalorehave been working in this regard since about 2002and have already either constructed or helped in theconstruction of hundreds of kilometers of asphaltroads using waste plastics in the Southern IndianStates.

ICPE also encouraged development and popularizationof this technology for duel purpose:

• Scientific and Environmental-friendly method ofdisposal of low-end plastics waste.

• Construction of better quality asphalt roads atreduced cost.

ICPE has been working with the Road EngineeringDepartment of Municipal Corporation of GreaterMumbai (MCGM) since 2005, for popularizing use ofwaste plastics for the construction of asphalt roads.

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Aggregate mixture being put inside hot mixing chamber (rotor)

Rotor and mix discharge unit

Road laying work in process

Road laying work in process

MCGM Road Engineers supervising the construction. ICPE staffare also seen in the picture

MCGM Road Testing Engineer is testing the density of the roadusing automatic Nuclear Testing Device.

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Plastics waste being added through automatic dosing machine

During the beginning of 2008, MCGM and ICPE haveconstructed a stretch of road near Dadar RailwayStation, Mumbai (Prof. V. S. Aghase Road) using wasteplastics in blend with bitumen and aggregates. Astretch of normal asphalt road, without mixing anywaste plastics, also has been laid along the same roadfor evaluating the performance of both the roads overa period of time under similar conditions. Initial testsindicated improvement in important propertiesincluding Marshal Stability values of the asphalt road.ICPE and MCGM Engineers would monitor theperformance of the road properties over a period oftime.

ICPE along with Gujarat State Plastics Manufacturers’Association/Plastindia Foundation are also workingwith the Road & Building Department of Governmentof Gujarat, who has sanctioned construction of 10 kmsstretch of asphalt road using waste plastics.

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Plastics Saves EnergySynergy with Energy Conference – and “India Energy Show 2008”on March 14, 2008, at Ahmedabad

Extending his greetings to the Chief Guest,Mr. Saurabhbhai Patel, Hon’ble Minister of State forFinance, Energy & Petrochemicals; the VIP’s on thedais, the galaxy of delegates, technocrats, experts fromthe energy sector who were present at the Conference,President, Plastindia Foundation, Mr. Arvind Mehta,expressed his delight to be the Guest of Honour at thefunction.

Deviating from the general theme under discussion,Mr. Arvind Mehta, sought to dwell and focus on theaspects as to how plastics are proving to be worthyenergy saver in various sectors. “Plastics demand thelowest energy for raw material production amongother materials such as Aluminium, Copper, Zinc,Steel, etc.,” he said.

“Keeping in view the emerging trends of the use ofplastics in the Energy Sector, Plastindia 2009 hasdedicated a pavilion exclusively for ‘Plastics – EnergySaver’,” he informed the august gathering.

Elaborating on the areas where plastics havecontributed substantially in energy savings, Mr. Arvind

Mehta presented case studies on some importantareas:

a. Plastics in Packagingb. Plastics in Pipesc. Plastics in Housingd. Plastics in Automobilese. Plastics – Non conventional energy generationf. Plastics in Energy

The energy efficiency of Plastics in the PackagingIndustry is noteworthy he said. “Plastics”, he said,“costs 1/4th; consumes 2/5th the energy; volume ofwaste is half and the weight of plastic packaging is1/3rd that of other conventional materials used, andabove all its recyclable properties are becoming morevaluable”.

Speaking on Plastics in Pipes, he said, “For every MTSteel pipes replaced by plastic pipes the power savingis approx. 23 MW”.

“Use of plastic profile foam insulation alone in homesand buildings will ultimately save nearly 60 millionbarrels of oil over other kind of insulation. Plasticprofiles with insulation save energy and it is possibleto heat homes with 3 litres instead of 23 litres of fuel,”he said.

Mr. Mehta stated that “In the automobile sector, useof Plastics is growing and because they have reducedtare weight and fuel consumption”. “In Europe theannual fuel savings due to use of plastics in theautomobile has resulted in 2.3 M T of fuel savings” hesaid.

“Light weight and insulation properties of plastics haveenabled compact and efficient units in non-conventional energy generation,” he stated.

“The Compounded Annual Growth Rate of Plastics inEnergy sector is around 26%, with an annualconsumption of 107 KTA in India,” he said, speakingof Plastics in the Energy sector. “Total cabling lengthin India using plastics is around 1,12,530 kms andHDPE is being used extensively for Gas Distributionin Metros across the country,” he affirmed.

To conclude, he said “We are looking for an optimisticparticipation from the energy sector at PLASTINDIA2009, which will only propel the growth of the Industryand encourage more innovations and productdevelopments”.

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ICPE GC & EC Meetingheld on 13th February, 2008at ICPE Office, Mumbai

Nobel Peace Prize 2007

Dr. D. K. Biswas is the Advisor-Principal(Environmental Affairs), ICPE

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www.envis-icpe.com46,164 hits in January 2008

The Members of Governing Council and the ExecutiveCommittee of ICPE meet regularly for taking PolicyDecisions on various activities to be undertakenby the Centre and for reviewing the status of thesame. Seen in the picture are: Mr. K. G. Ramanathan,President – Governing Council, and Mr. J. B. Kamat,Member, (representing CPMA). Others in thepicture are: Mr. Arvind Mehta, Mr. Vijay Merchant,Mr. Rajiv Tolat, Mr. S. K. Sharma and Mr. J. V. Raval(Members representing Plastindia Foundation),Dr. T. K. Chakravarthy (DCPC), Mr. Rajiv Dhar (IIP),Mr. Prabuddha Dasgupta (HUL), Mr. P. K. Sahoo(CIPET) and Mr. P. V. Narayanan (Advisor, ICPE).

ICPE along with Maharashtra Plastic Manufacturers’Association (MPMA), has been engaged in the PlasticsWaste Management Activities in Mahabaleshwar areawith the co-operation of local civic authorities.

The continuous effort of ICPE and MPMA broughtresult in the Plastics Waste Management inMahabaleshwar area and the local authority hadacknowledged the services of ICPE and MPMA in thisregard.

Appreciation

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ICPE Participation inExhibition andAwareness Programmes

Pune Expo 2008 - Industrial Exhibition and SeminarPune, 28th Feb – 3rd March, 2008

Display panels on Plastics Recycling and relatedawareness on Waste Management along with samplesof recycled plastic products were exhibited. Duringthe technical seminar organized on 29th February,2008, Mr. T. K. Bandopadhyay, Sr. Technical Manager,

ICPE, made a presentation on Plastics – Benefits,Environmental Issues and Scientific Solutions.Mr. Rajiv Tolat, Treasurer / Member-ExecutiveCommittee, ICPE appraised the gathering on ICPE’srole in handling of environmental issues with respectto plastics.

National Conference onEnvironmental Engineering Management (NCEEM) 2008 andSilver Jubilee Celebration of the Educational Institute Tatyasaheb KoreInstitute of Engineering and TechnologyKolhapur – 15th February, 2008

One of the most prestigious Engineering Institutesin the country had organized the Conference wheredistinguished experts in the field of EnvironmentalManagement took part. Mr. Sujit Banerji, President,Polymers Business, Reliance Industries Ltd. andExecutive Secretary/Member-Executive Committee,

ICPE, delivered the keynote address on theenvironmental benefits of plastics as a whole.

Mr. T. K. Bandopadhyay, Sr. Technical Manager, ICPE,participated in the planery session of the Seminar anddeliberated on various Environmental issues ofPlastics and its solutions.

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Mr. T. K. Bandopadhyay, Sr. Technical Manager-ICPE,making a presentation

ICPE Awareness Pavilion in the exhibition

Section of audience On the dais (L to R): Dr. Rao, Principal of the Institute andMr. Sujit Banerji, Chief Guest on the occasion seen with otherdignitaries

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PLASTEC 2008 Exhibition and SeminarChennai, 21st-24th February, 2008

Chennai Plastics Manufacturers and MerchantsAssociation had organized a 4-day Exhibition –PLASTEC 2008 during 21st-24th February, 2008. ICPEparticipated in the exhibition displaying the awarenessmaterial and providing information on varioustechniques of Plastics Recycling. The visiting publictook keen interest in the information provided in ICPEStall through display of panels and samples of recycledplastic products.

During the technical seminar, Mr. T. K. Bandopadhyaymade presentation on Environmental Issues of Plasticsand Scientific Solutions. Mr. Bandopadhyay alsochaired the concluding session at the end of theSeminar for compiling the proceedings forrecommendation to the local government on variousissues relating to Plastics.

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Mr. Soloman Pappaiah, famous Tamil speaker, conducting a public debate on “Plastics: Boon or Bane to the Environment

ICPE Pavilion

Visitors at ICPE Pavilion

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Do Not Litter.Keep Your Environment Clean.

• Segregate and Throw Waste Only inWaste Bins.

• Use Two Bins – One for Wet Waste,One for Dry Waste.

Waste Food and otherBiodegradable Waste …Can be compostedinto manure.

Plastics, Metals, Paper …Can be recycled intouseful products.

Issued in Public Interest by

www.icpenviro.org • www.envis-icpe.com • www.icpeenvis.nic.in