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    TPG 4140 Natural Gas 2012

    LNGFundamental Principles andHammerfest LNG Plant

    Jostein Pettersen

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    2 -

    Outline

    Why LNG?

    What is LNG ?

    Gas pre-treatment

    Gas liquefaction

    LNG storage and loading

    LNG transport

    LNG receiving terminals

    OverviewSnhvit field development and Hammerfest LNG plant Land plant

    Plant construction

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    LNG Density

    Natural gas

    LNG

    1 m3

    LNG correspondsto ca 600 Sm3natural gas

    S = Standard state, 15C, 1 atm

    At temperatures above -110 CLNG vapour is lighter than air

    LNG is lighter than waterLNG Density: 450 kg/m3

    Water density: 1000 kg/m3

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    Types of LNG plants

    Base-load plants

    Large plants which are directly based on a specific gas field development and are the mainplants for handling the gas. A base-load plant has typically a production capacity of above 3Mtpa (million tons per annum) of LNG. The main world-wide LNG production capacity comefrom this type of plants

    Peak-shaving plants

    Smaller plants that are connected to a gas network. During the period of the year when gasdemand is low, natural gas is liquefied and LNG is stored. LNG is vaporized during shortperiods when gas demand is high. These plants have a relatively small liquefaction capacity(as 200 tons/day) and large storage and vaporization capacity (as 6000 tons/day). Especiallyin the US many such plants exist

    Small-scale plants

    Small-scale plants are plants that are connected to a gas network for continuous LNGproduction in a smaller scale. The LNG is distributed by LNG trucks or small LNG carriers tovarious customers with a small to moderate need of energy or fuel. This type of LNG plantstypically has a production capacity below 500 000 tpa. In Norway and China several plants

    within this category is in operation.

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    Source: CERA

    Source: IHS CERA.

    00406-6_2808

    Natural gas liquefaction plantsBase load capacity

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    Gas processing

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    Simplified LNG plant block diagram

    Endflash

    HHCExtraction

    CH4/N2

    Fuelgas

    Power&

    heat

    (C5+) (C4 and C3)

    (CO2 and H2S)

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    10 - 2010-09-26

    Gas conditioning (pre-treatment) Acid Gas (CO2and H2S) removal

    Acid gas causes corrosion, reduces heating value, and may freeze and create solids

    in cryogenic process

    Typical requirements for LNG: Max 50 ppmv CO2, Max 4 ppmv H2S

    (ppmv - parts per million by volume)

    Usual process: aMDEA (Amine)

    Dehydration (water removal)

    Water will freeze in cryogenic process

    Typical requirement: Max 1 ppmw (weight) H2O

    Usual process: Adsorption (Mol sieve)

    Mercury removal

    Mercury can cause corrosion problems, especially in aluminium heat exchangers

    Requirement: Max 0.01 g/Nm3

    Usual process: Adsorption

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    12 - 2010-09-26

    Natural gas path through liquefaction

    pressure-enthalpy diagram (C1:89.7% C2:5,5% C3:1.8% N2:2.8%)

    1

    10

    100

    -900 -800 -700 -600 -500 -400 -300 -200 -100 0 100 200

    Enthalpy [kJ/kg]

    Pressure

    [bara]

    -200oC -150oC -100o

    C -50oC 0oC 50oC

    PrecoolingLiquefactionSubcooling

    Expansion

    JT Throttling

    End flash LNG

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    Liquefaction process licensors

    Base load LNG plants (3+ Mtpa)

    Air Products and Chemicals Inc (APCI)

    World leader since since the 1970sca 80 operating trains

    C3MR process

    AP-XTMHybrid (QatarGas II, III and IV, RasGas III: Six trains of 7.8 Mtpa each, Start up 2008)

    ConocoPhillips (Optimised) Cascade

    Trinidad: Atlantic LNG - 4 trains Egypt: Idku

    Alaska: Kenai (Operating since 1969!)

    Australia: Darwin LNG

    Equatorial Guinea

    Shell DMRDouble Mixed Refrigerant (Sakhalin, 2 x 4.8 Mtpastart-up 2007)

    PMR (same as C3MRbut parallel MR circuits)no references

    Linde/Statoil MFCMixed Fluid Cascade Process (Snhvit, 4.3 Mtpastart up 2007)

    Axens Liquefin (No references)

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    Simplified cascade process for natural gasliquefaction

    MethaneEthylenePropane

    NG12 C-32 C

    1.4 bar 7 bar

    -96 C

    1.4 bar 19 bar

    LNG -155 C

    1.4 bar 45 bar

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    Temperature stages in cascade process

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    17 - 2010-09-26

    Example of single-mix refrigerant cycle for

    natural gas liquefaction (Prico cycle)

    LNG

    NG

    5 bar

    30 bar

    12 C

    -155 C

    12 C

    -155 C -155,5 C

    6,5 C

    99,8 C

    Composition:

    NG Refrig

    C1 0.897 0.360

    C2 0.055 0.280C3 0.018 0.110

    nC4 0.001 0.150

    N2 0.028 0.100

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    18 - 2010-09-26

    Temperatureenthalpy diagram of Prico example

    -200

    -150

    -100

    -50

    0

    50

    100

    150

    -1500 -1000 -500 0 500 1000 1500

    Enthalpy, x 10^6 kJ/hr

    Temperature,

    C

    Mixed refrigerant dew point line

    Mixed refrigerant bubble point line

    NG bubble point

    line

    NG dew point line

    Mixed refrigerant 30 bar

    Mixed refrigerant 5 bar

    NG 60 bar

    LNG

    NG

    5 bar

    30 bar

    12 C

    -155 C

    12 C

    -155 C -155,5 C

    6,5 C

    99,8 C

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    19 - 2010-09-26

    Propane-precooled MR (C3MR) Process

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    20 - 2010-09-26

    LNG storage and

    loading

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    22 - 2010-09-26

    Pre-stressed concrete outer walls

    constructed by slipforming, sheathed

    internally with a gas-tight layer of

    nickel-alloyed steel.

    Inner tank in nickel-alloyed steel,

    separated from the outer walls by a

    layer of perlite - a variety of volcanic

    obsidian highly suitable for insulation

    Extra layer of steel and insulation at

    the transition between outer wall and

    tank bottom to protect it against

    strong local stresses should the

    inner tank begin to leak.

    Heating cables under the tanks will

    ensure that the ground remains

    above 0C in order to prevent frost

    heaving.

    Above-ground full-containment LNG tank design

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    23 - 2010-09-26

    Typical storage and loading system

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    24 - 2010-09-26

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    LNG ships

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    LNG transportationtechnical aspects

    LNG is transported at163 deg. C and at atmospheric pressure This low temperature require that the LNG is transported and handled with special

    consideration, i.e.

    Completely separated from the ships hull

    LNG temperature must be maintained during the voyagerequiring efficient insulation

    of the cargo tanks and handling of boil off gas (BOG) All cargo handling equipment must be able to operate at the low temperature of -163

    deg. C

    Two basically different cargo containment systems are used:

    Self supported independent tanks (Moss Rosenberg spherical tanks, IHI SPB,

    cylindrical tanks) Membrane tanks (Gaz Transport and Technigaz (GTT))

    Market share between the two concepts has been about. 50/50 - but the membrane concept

    has been increasingly selected for recent newbuilding orders.

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    Cargo containment systems

    Spherical tanks

    (Moss Rosenberg)Membrane containment

    27 -

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    Sabine Pass LNG Terminal (Planned)Artists Rendition

    Source: Cheniere Energy, Inc.

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    30 - 2010-09-26

    LNG receiving terminal - principles

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    31 - 2010-09-26

    Hammerfest LNG Plant

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    The first LNG liquefaction plant in Norway and Europe

    The first offshore development in the Barents Sea

    The largest industrial development in northern Norway ever

    New technology on several areas

    New markets

    New organisation in a new area of Norway

    - A Successful Frontier LNG Project

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    Facts:

    Discovered: 198184

    Water depth: 250340 m

    Distance to shore: 140 km

    Gas in place (GIP): 317 GSm3

    Recoverable reserves : 193 GSm3

    Condensate: 34 MSm3

    Statoil ASA (Operator) 36.79%

    Petoro AS 30.00%

    Total E&P Norge AS 18.40%

    GDF Suez Norge AS 12.00%

    RWE Dea Norge AS 2.81%

    : \ \ \ \ K \ t \ \ r _ v r i t \ Li n r t \ \ t t i l _H y r _ l t _ li c _t t_ 1 v l . m

    Snhvit, Albatrossand Askeladd

    Owners:

    Original 2002

    figures

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    2010-09-26

    HammerfestMelkya (May 2006)

    Slug catcher Inlet facilities

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    2010-09-26

    SNHVITSimplified overview

    CO2Injection

    well

    Production well

    Seabed

    Reservoir

    Albatross

    Production wells

    CDU

    Plem

    Production wells

    Production wells

    Snhvit

    CO2 Injection well

    g

    Pretreatment

    Fractionation

    Carbon dioxide

    MEG

    recovery

    Condensate production

    LPG production

    LNG production

    Liquefaction cycle Subcooling cycle

    Storage and loading:

    LNG, LPG, condensate

    Precooling cycle

    Prepared by Petrolink as

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    2010-09-26

    Hammerfest LNG plant - block flow diagram

    Slugcatcher

    Inlet facilities/Metering

    CO2removal

    De-hydration

    Mercuryremoval

    Natural gasliquefaction

    LPG

    Storage

    CondensateStorage

    MEGRecovery

    Condensatetreatment

    CO2dryingand

    recompressionNitrogenremoval

    Fractionation(RefrigerantMake-up)

    Fuel gassystem

    C1/ C2/ C3 Refrig. Make-up

    CO2reinjection(to pipeline)

    Feed from

    pipeline

    Lean MEG(to pipeline)

    LNGStorage

    LNGStorage

    N2to atm.

    Utility

    SystemsFlare

    FacilitiesControl

    room

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    2010-09-26

    LAYOUT - HAMMERFEST LNG PLANT

    Slug catcher

    HP flare

    LP flareCamp area

    Condensate storagetank

    LNG storage tanks

    Product jetty

    LPG storage tank

    Storage & loading substation

    N2cold box

    NG Cold box

    Process substation

    Electrical power generation

    Compression area, barge

    Process area, barge

    Construction jetty

    Subsea road tunnel

    Administration building / control room

    Sea water outlet /sea water inlet

    Holding basin / waste water treatment

    Utility substation

    MDEA storage / fuel gas

    Compressed air and inert gas facilities

    Landfall

    Offshore utility substation

    MEG process area

    MEG substation

    MEG storage tank area

    Hot oil and chemicalstorage tanks

    Pig receiver

    Grid substation

    Area 2 Area 3Area 1

    HAMMERFEST LNG Process area

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    Natural gas ColdBox

    Nitrogen RemovalCold Box

    Processsubstation

    Electric powergeneration

    Compressor area

    Process area

    23

    1

    HAMMERFEST LNGProcess area

    Mixed Fluid Cascade (MFC) Liquefaction process and

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    Mixed Fluid Cascade (MFC ) Liquefaction process and

    power/heat generation at Hammerfest

    65 MW

    65

    MW

    32 MW

    NGL

    M lk b f t ti t t

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    2010-09-26

    Melkya before construction start-upJune 2001

    M lk A t 2006

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    Melkya August 2006

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    2010-09-26

    Why this very large extent ofprefabrication?

    Harsh weather conditions

    Remotenesslack of necessary infrastructure

    Reduce the necessity of steel work at site

    Higher productivity at construction yard

    Reduce work at site in general -of the total estimate of 15 million man-hours to

    build the plant, 50 % is done at site.

    Prefabrication and use of

    large modules

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    Cold box

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    Process

    plant

    P f b i ti LNG l t b

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    PrefabricationLNG plant on a barge

    Process systems on the bargeWeight: 21.000 tonnes

    Height over deck: 60 m

    BargeWeight: 10.000 tonnesSize: 154 x 54 x 9m

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    Blue Marlin and process barge in Cadiz.

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    Hammerfesthere we are!

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    In-docking of process-barge.

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    21 August 2007: Production start

    13.09.07 First LNG to tank26.09.07 First condensate cargo

    20.10.07 First LNG cargo

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    Arctic Shipping