lys ark pettersen 2012
TRANSCRIPT
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TPG 4140 Natural Gas 2012
LNGFundamental Principles andHammerfest LNG Plant
Jostein Pettersen
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Outline
Why LNG?
What is LNG ?
Gas pre-treatment
Gas liquefaction
LNG storage and loading
LNG transport
LNG receiving terminals
OverviewSnhvit field development and Hammerfest LNG plant Land plant
Plant construction
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LNG Density
Natural gas
LNG
1 m3
LNG correspondsto ca 600 Sm3natural gas
S = Standard state, 15C, 1 atm
At temperatures above -110 CLNG vapour is lighter than air
LNG is lighter than waterLNG Density: 450 kg/m3
Water density: 1000 kg/m3
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Types of LNG plants
Base-load plants
Large plants which are directly based on a specific gas field development and are the mainplants for handling the gas. A base-load plant has typically a production capacity of above 3Mtpa (million tons per annum) of LNG. The main world-wide LNG production capacity comefrom this type of plants
Peak-shaving plants
Smaller plants that are connected to a gas network. During the period of the year when gasdemand is low, natural gas is liquefied and LNG is stored. LNG is vaporized during shortperiods when gas demand is high. These plants have a relatively small liquefaction capacity(as 200 tons/day) and large storage and vaporization capacity (as 6000 tons/day). Especiallyin the US many such plants exist
Small-scale plants
Small-scale plants are plants that are connected to a gas network for continuous LNGproduction in a smaller scale. The LNG is distributed by LNG trucks or small LNG carriers tovarious customers with a small to moderate need of energy or fuel. This type of LNG plantstypically has a production capacity below 500 000 tpa. In Norway and China several plants
within this category is in operation.
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Source: CERA
Source: IHS CERA.
00406-6_2808
Natural gas liquefaction plantsBase load capacity
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Gas processing
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Simplified LNG plant block diagram
Endflash
HHCExtraction
CH4/N2
Fuelgas
Power&
heat
(C5+) (C4 and C3)
(CO2 and H2S)
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Gas conditioning (pre-treatment) Acid Gas (CO2and H2S) removal
Acid gas causes corrosion, reduces heating value, and may freeze and create solids
in cryogenic process
Typical requirements for LNG: Max 50 ppmv CO2, Max 4 ppmv H2S
(ppmv - parts per million by volume)
Usual process: aMDEA (Amine)
Dehydration (water removal)
Water will freeze in cryogenic process
Typical requirement: Max 1 ppmw (weight) H2O
Usual process: Adsorption (Mol sieve)
Mercury removal
Mercury can cause corrosion problems, especially in aluminium heat exchangers
Requirement: Max 0.01 g/Nm3
Usual process: Adsorption
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Natural gas path through liquefaction
pressure-enthalpy diagram (C1:89.7% C2:5,5% C3:1.8% N2:2.8%)
1
10
100
-900 -800 -700 -600 -500 -400 -300 -200 -100 0 100 200
Enthalpy [kJ/kg]
Pressure
[bara]
-200oC -150oC -100o
C -50oC 0oC 50oC
PrecoolingLiquefactionSubcooling
Expansion
JT Throttling
End flash LNG
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Liquefaction process licensors
Base load LNG plants (3+ Mtpa)
Air Products and Chemicals Inc (APCI)
World leader since since the 1970sca 80 operating trains
C3MR process
AP-XTMHybrid (QatarGas II, III and IV, RasGas III: Six trains of 7.8 Mtpa each, Start up 2008)
ConocoPhillips (Optimised) Cascade
Trinidad: Atlantic LNG - 4 trains Egypt: Idku
Alaska: Kenai (Operating since 1969!)
Australia: Darwin LNG
Equatorial Guinea
Shell DMRDouble Mixed Refrigerant (Sakhalin, 2 x 4.8 Mtpastart-up 2007)
PMR (same as C3MRbut parallel MR circuits)no references
Linde/Statoil MFCMixed Fluid Cascade Process (Snhvit, 4.3 Mtpastart up 2007)
Axens Liquefin (No references)
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Simplified cascade process for natural gasliquefaction
MethaneEthylenePropane
NG12 C-32 C
1.4 bar 7 bar
-96 C
1.4 bar 19 bar
LNG -155 C
1.4 bar 45 bar
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Temperature stages in cascade process
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Example of single-mix refrigerant cycle for
natural gas liquefaction (Prico cycle)
LNG
NG
5 bar
30 bar
12 C
-155 C
12 C
-155 C -155,5 C
6,5 C
99,8 C
Composition:
NG Refrig
C1 0.897 0.360
C2 0.055 0.280C3 0.018 0.110
nC4 0.001 0.150
N2 0.028 0.100
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Temperatureenthalpy diagram of Prico example
-200
-150
-100
-50
0
50
100
150
-1500 -1000 -500 0 500 1000 1500
Enthalpy, x 10^6 kJ/hr
Temperature,
C
Mixed refrigerant dew point line
Mixed refrigerant bubble point line
NG bubble point
line
NG dew point line
Mixed refrigerant 30 bar
Mixed refrigerant 5 bar
NG 60 bar
LNG
NG
5 bar
30 bar
12 C
-155 C
12 C
-155 C -155,5 C
6,5 C
99,8 C
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Propane-precooled MR (C3MR) Process
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LNG storage and
loading
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Pre-stressed concrete outer walls
constructed by slipforming, sheathed
internally with a gas-tight layer of
nickel-alloyed steel.
Inner tank in nickel-alloyed steel,
separated from the outer walls by a
layer of perlite - a variety of volcanic
obsidian highly suitable for insulation
Extra layer of steel and insulation at
the transition between outer wall and
tank bottom to protect it against
strong local stresses should the
inner tank begin to leak.
Heating cables under the tanks will
ensure that the ground remains
above 0C in order to prevent frost
heaving.
Above-ground full-containment LNG tank design
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Typical storage and loading system
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LNG ships
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LNG transportationtechnical aspects
LNG is transported at163 deg. C and at atmospheric pressure This low temperature require that the LNG is transported and handled with special
consideration, i.e.
Completely separated from the ships hull
LNG temperature must be maintained during the voyagerequiring efficient insulation
of the cargo tanks and handling of boil off gas (BOG) All cargo handling equipment must be able to operate at the low temperature of -163
deg. C
Two basically different cargo containment systems are used:
Self supported independent tanks (Moss Rosenberg spherical tanks, IHI SPB,
cylindrical tanks) Membrane tanks (Gaz Transport and Technigaz (GTT))
Market share between the two concepts has been about. 50/50 - but the membrane concept
has been increasingly selected for recent newbuilding orders.
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Cargo containment systems
Spherical tanks
(Moss Rosenberg)Membrane containment
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Sabine Pass LNG Terminal (Planned)Artists Rendition
Source: Cheniere Energy, Inc.
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LNG receiving terminal - principles
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Hammerfest LNG Plant
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The first LNG liquefaction plant in Norway and Europe
The first offshore development in the Barents Sea
The largest industrial development in northern Norway ever
New technology on several areas
New markets
New organisation in a new area of Norway
- A Successful Frontier LNG Project
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Facts:
Discovered: 198184
Water depth: 250340 m
Distance to shore: 140 km
Gas in place (GIP): 317 GSm3
Recoverable reserves : 193 GSm3
Condensate: 34 MSm3
Statoil ASA (Operator) 36.79%
Petoro AS 30.00%
Total E&P Norge AS 18.40%
GDF Suez Norge AS 12.00%
RWE Dea Norge AS 2.81%
: \ \ \ \ K \ t \ \ r _ v r i t \ Li n r t \ \ t t i l _H y r _ l t _ li c _t t_ 1 v l . m
Snhvit, Albatrossand Askeladd
Owners:
Original 2002
figures
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2010-09-26
HammerfestMelkya (May 2006)
Slug catcher Inlet facilities
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SNHVITSimplified overview
CO2Injection
well
Production well
Seabed
Reservoir
Albatross
Production wells
CDU
Plem
Production wells
Production wells
Snhvit
CO2 Injection well
g
Pretreatment
Fractionation
Carbon dioxide
MEG
recovery
Condensate production
LPG production
LNG production
Liquefaction cycle Subcooling cycle
Storage and loading:
LNG, LPG, condensate
Precooling cycle
Prepared by Petrolink as
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Hammerfest LNG plant - block flow diagram
Slugcatcher
Inlet facilities/Metering
CO2removal
De-hydration
Mercuryremoval
Natural gasliquefaction
LPG
Storage
CondensateStorage
MEGRecovery
Condensatetreatment
CO2dryingand
recompressionNitrogenremoval
Fractionation(RefrigerantMake-up)
Fuel gassystem
C1/ C2/ C3 Refrig. Make-up
CO2reinjection(to pipeline)
Feed from
pipeline
Lean MEG(to pipeline)
LNGStorage
LNGStorage
N2to atm.
Utility
SystemsFlare
FacilitiesControl
room
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LAYOUT - HAMMERFEST LNG PLANT
Slug catcher
HP flare
LP flareCamp area
Condensate storagetank
LNG storage tanks
Product jetty
LPG storage tank
Storage & loading substation
N2cold box
NG Cold box
Process substation
Electrical power generation
Compression area, barge
Process area, barge
Construction jetty
Subsea road tunnel
Administration building / control room
Sea water outlet /sea water inlet
Holding basin / waste water treatment
Utility substation
MDEA storage / fuel gas
Compressed air and inert gas facilities
Landfall
Offshore utility substation
MEG process area
MEG substation
MEG storage tank area
Hot oil and chemicalstorage tanks
Pig receiver
Grid substation
Area 2 Area 3Area 1
HAMMERFEST LNG Process area
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Natural gas ColdBox
Nitrogen RemovalCold Box
Processsubstation
Electric powergeneration
Compressor area
Process area
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1
HAMMERFEST LNGProcess area
Mixed Fluid Cascade (MFC) Liquefaction process and
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Mixed Fluid Cascade (MFC ) Liquefaction process and
power/heat generation at Hammerfest
65 MW
65
MW
32 MW
NGL
M lk b f t ti t t
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Melkya before construction start-upJune 2001
M lk A t 2006
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Melkya August 2006
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Why this very large extent ofprefabrication?
Harsh weather conditions
Remotenesslack of necessary infrastructure
Reduce the necessity of steel work at site
Higher productivity at construction yard
Reduce work at site in general -of the total estimate of 15 million man-hours to
build the plant, 50 % is done at site.
Prefabrication and use of
large modules
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Cold box
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Process
plant
P f b i ti LNG l t b
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PrefabricationLNG plant on a barge
Process systems on the bargeWeight: 21.000 tonnes
Height over deck: 60 m
BargeWeight: 10.000 tonnesSize: 154 x 54 x 9m
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Blue Marlin and process barge in Cadiz.
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Hammerfesthere we are!
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In-docking of process-barge.
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21 August 2007: Production start
13.09.07 First LNG to tank26.09.07 First condensate cargo
20.10.07 First LNG cargo
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Arctic Shipping