list of semiconductor materials - wikipedia, the free encyclopedia
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semiconducting materialsTRANSCRIPT
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List of semiconductor materialsFrom Wikipedia, the free encyclopedia
Semiconductor materials are nominally small band gap insulators. The defining property of a semiconductormaterial is that it can be doped with impurities that alter its electronic properties in a controllable way.
Because of their application in the computer and photovoltaic industry—in devices such as transistors, lasersand solar cells—the search for new semiconductor materials and the improvement of existing materials is animportant field of study in materials science.
Most commonly used semiconductor materials are crystalline inorganic solids. These materials are classifiedaccording to the periodic table groups of their constituent atoms.
Different semiconductor materials differ in their properties. Thus, in comparison with silicon, compoundsemiconductors have both advantages and disadvantages. For example, gallium arsenide (GaAs) has six timeshigher electron mobility than silicon, which allows faster operation; wider band gap, which allows operation ofpower devices at higher temperatures, and gives lower thermal noise to low power devices at room temperature;its direct band gap gives it more favorable optoelectronic properties than the indirect band gap of silicon; it canbe alloyed to ternary and quaternary compositions, with adjustable band gap width, allowing light emission atchosen wavelengths, and allowing e.g. matching to wavelengths with lowest losses in optical fibers. GaAs canbe also grown in a semiinsulating form, which is suitable as a latticematching insulating substrate for GaAsdevices. Conversely, silicon is robust, cheap, and easy to process, whereas GaAs is brittle and expensive, andinsulation layers can not be created by just growing an oxide layer; GaAs is therefore used only where silicon isnot sufficient.[1]
By alloying multiple compounds, some semiconductor materials are tunable, e.g., in band gap or latticeconstant. The result is ternary, quaternary, or even quinary compositions. Ternary compositions allow adjustingthe band gap within the range of the involved binary compounds; however, in case of combination of direct andindirect band gap materials there is a ratio where indirect band gap prevails, limiting the range usable foroptoelectronics; e.g. AlGaAs LEDs are limited to 660 nm by this. Lattice constants of the compounds also tendto be different, and the lattice mismatch against the substrate, dependent on the mixing ratio, causes defects inamounts dependent on the mismatch magnitude; this influences the ratio of achievable radiative/nonradiativerecombinations and determines the luminous efficiency of the device. Quaternary and higher compositionsallow adjusting simultaneously the band gap and the lattice constant, allowing increasing radiant efficiency atwider range of wavelengths; for example AlGaInP is used for LEDs . Materials transparent to the generatedwavelength of light are advantageous, as this allows more efficient extraction of photons from the bulk of thematerial. That is, in such transparent materials, light production is not limited to just the surface. Index ofrefraction is also compositiondependent and influences the extraction efficiency of photons from thematerial.[2]
Contents
1 Types of semiconductor materials2 Table of semiconductor materials3 Table of semiconductor alloy systems4 See also5 References
Types of semiconductor materials
Group IV elemental semiconductors
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Group IV compound semiconductorsGroup VI elemental semiconductorsIIIV semiconductors (See also: Template:IIIV compounds): Crystallizing with high degree ofstoichiometry, most can be obtained as both ntype and ptype. Many have high carrier mobilities anddirect energy gaps, making them useful for optoelectronics.IIVI semiconductors: usually ptype, except ZnTe and ZnO which is ntypeIVII semiconductorsIVVI semiconductorsIVVI semiconductorsVVI semiconductorsIIV semiconductorsIIIIVI2 semiconductorsOxidesLayered semiconductorsMagnetic semiconductorsOrganic semiconductorsChargetransfer complexesOthers
Table of semiconductor materials
Group Elem. Material FormulaBandgap(eV)
Gap type Description
IV 1 Diamond C 5.47[3][4] indirect
Excellent thermalconductivity.Superior mechanicaland opticalproperties.Extremely highmechanical qualityfactor.[5]
IV 1 Silicon Si 1.12[3][4] indirect
Used in conventionalcrystalline silicon (cSi) solar cells, and inits amorphous formas amorphous silicon(aSi) in thin filmsolar cells. Mostcommonsemiconductormaterial inphotovoltaics;dominatesworldwide PVMARKET ; easyto fabricate; goodelectrical andmechanicalproperties. Formshigh quality thermaloxide for insulationpurposes.Used in early radardetection diodes and
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IV 1 Germanium Ge 0.67[3][4] indirect
first transistors;requires lower puritythan silicon. Asubstrate for highefficiencymultijunctionphotovoltaic cells.Very similar latticeconstant to galliumarsenide. Highpurity crystals usedfor gammaspectroscopy. Maygrow whiskers,which impairreliability of somedevices.
IV 1 Gray tin, αSn Sn 0.00,[6]
0.08[7]indirect
Low temperatureallotrope (diamondcubic lattice).
IV 2Siliconcarbide, 3CSiC
SiC 2.3[3] indirect used for early yellowLEDs
IV 2Siliconcarbide, 4HSiC
SiC 3.3[3] indirect
IV 2Siliconcarbide, 6HSiC
SiC 3.0[3] indirect used for early blueLEDs
VI 1 Sulfur, αS S8 2.6[8]
VI 1 Gray selenium Se 1.74 Used in seleniumrectifiers.
VI 1 Tellurium Te 0.33
IIIV 2 Boron nitride,cubic BN 6.36[9] indirect potentially useful for
ultraviolet LEDs
IIIV 2 Boron nitride,hexagonal BN 5.96[9] quasidirect potentially useful for
ultraviolet LEDs
IIIV 2 Boron nitridenanotube BN ~5.5
IIIV 2 Boronphosphide BP 2 indirect
IIIV 2 Boronarsenide BAs 1.5 indirect
Resistant to radiationdamage, possibleapplications inbetavoltaics.
IIIV 2 Boronarsenide
B12As2 3.47 indirect
Resistant to radiationdamage, possibleapplications inbetavoltaics.Piezoelectric. Notused on its own as asemiconductor; AlN
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IIIV 2 Aluminiumnitride AlN 6.28[3] direct
close GaAlNpossibly usable forultraviolet LEDs.Inefficient emissionat 210 nm wasachieved on AlN.
IIIV 2 Aluminiumphosphide AlP 2.45[4] indirect
IIIV 2 Aluminiumarsenide AlAs 2.16[4] indirect
IIIV 2 Aluminiumantimonide AlSb 1.6/2.2[4] indirect/direct
IIIV 2 Galliumnitride GaN 3.44[3][4] direct
problematic to bedoped to ptype, pdoping with Mg andannealing allowedfirst highefficiencyblue LEDs[2] andblue lasers. Verysensitive to ESD.Insensitive toionizing radiation,suitable forspacecraft solarpanels. GaNtransistors canoperate at highervoltages and highertemperatures thanGaAs, used inmicrowave poweramplifiers. Whendoped with e.g.manganese, becomesa magneticsemiconductor.
IIIV 2 Galliumphosphide GaP 2.26[3][4] indirect
Used in early low tomedium brightnesscheapred/orange/greenLEDs. Usedstandalone or withGaAsP. Transparentfor yellow and redlight, used assubstrate for GaAsPred/yellow LEDs.Doped with S or Tefor ntype, with Znfor ptype. Pure GaPemits green,nitrogendoped GaPemits yellowgreen,ZnOdoped GaPemits red.
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IIIV 2 Galliumarsenide GaAs 1.43[3][4] direct
second mostcommon in use aftersilicon, commonlyused as substrate forother IIIVsemiconductors, e.g.InGaAs andGaInNAs. Brittle.Lower hole mobilitythan Si, PtypeCMOS transistorsunfeasible. Highimpurity density,difficult to fabricatesmall structures.Used for nearIRLEDs, fastelectronics, andhighefficiency solarcells. Very similarlattice constant togermanium, can begrown ongermaniumsubstrates.
IIIV 2 Galliumantimonide GaSb 0.726[3][4] direct
Used for infrareddetectors and LEDsandthermophotovoltaics.Doped n with Te, pwith Zn.
IIIV 2 Indium nitride InN 0.7[3] direct
Possible use in solarcells, but ptypedoping difficult.Used frequently asalloys.
IIIV 2 Indiumphosphide InP 1.35[3] direct
Commonly used assubstrate forepitaxial InGaAs.Superior electronvelocity, used inhighpower andhighfrequencyapplications. Used inoptoelectronics.
IIIV 2 Indiumarsenide InAs 0.36[3] direct
Used for infrareddetectors for 1–3.8 µm, cooled oruncooled. Highelectron mobility.InAs dots in InGaAsmatrix can serve asquantum dots.Quantum dots maybe formed from amonolayer of InAs
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on InP or GaAs.Strong photoDember emitter,used as a terahertzradiation source.
IIIV 2 Indiumantimonide InSb 0.17[3] direct
Used in infrareddetectors andthermal imagingsensors, highquantum efficiency,low stability, requirecooling, used inmilitary longrangethermal imagersystems. AlInSbInSbAlInSbstructure used asquantum well. Veryhigh electronmobility, electronvelocity and ballisticlength. Transistorscan operate below0.5V and above200 GHz. Terahertzfrequencies maybeachievable.
IIVI 2 Cadmiumselenide CdSe 1.74[4] direct
Nanoparticles usedas quantum dots.Intrinsic ntype,difficult to dope ptype, but can be ptype doped withnitrogen. Possibleuse inoptoelectronics.Tested for highefficiency solarcells.
IIVI 2 Cadmiumsulfide CdS 2.42[4] direct
Used inphotoresistors andsolar cells;CdS/Cu2S was thefirst efficient solarcell. Used in solarcells with CdTe.Common asquantum dots.Crystals can act assolidstate lasers.Electroluminescent.When doped, can actas a phosphor.Used in solar cellswith CdS. Used inthin film solar cells
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IIVI 2 Cadmiumtelluride CdTe 1.49[4] direct
and other cadmiumtelluridephotovoltaics; lessefficient thancrystalline siliconbut cheaper. Highelectrooptic effect,used in electroopticmodulators.Fluorescent at790 nm.Nanoparticles usableas quantum dots.
IIVI,oxide 2 Zinc oxide ZnO 3.37[4] direct
Photocatalytic.Bandwidth tunablefrom 3 to 4 eV byalloying withmagnesium oxideand cadmium oxide.Intrinsic ntype, ptype doping isdifficult. Heavyaluminium, indium,or gallium dopingyields transparentconductive coatings;ZnO:Al is used aswindow coatingstransparent in visibleand reflective ininfrared region andas conductive filmsin LCD displays andsolar panels as areplacement ofindium tin oxide.Resistant to radiationdamage. Possibleuse in LEDs andlaser diodes.Possible use inrandom lasers.
IIVI 2 Zinc selenide ZnSe 2.7[4] direct
Used for blue lasersand LEDs. Easy tontype doping, ptype doping isdifficult but can bedone with e.g.nitrogen. Commonoptical material ininfrared optics.
IIVI 2 Zinc sulfide ZnS 3.54/3.91[4] direct
Band gap 3.54 eV(cubic), 3.91(hexagonal). Can bedoped both ntypeand ptype. Common
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scintillator/phosphorwhen suitablydoped.
IIVI 2 Zinc telluride ZnTe 2.25[4] direct
Can be grown onAlSb, GaSb, InAs,and PbSe. Used insolar cells,compoments ofmicrowavegenerators, blueLEDs and lasers.Used inelectrooptics.Together withlithium niobate usedto generate terahertzradiation.
IVII 2 Cuprouschloride CuCl 3.4[10] direct
IVI 2 Copper sulfide Cu2S 1.2 directptype, Cu2S/CdSwas the first efficientthin film solar cell
IVVI 2 Lead selenide PbSe 0.27 direct
Used in infrareddetectors for thermalimaging.Nanocrystals usableas quantum dots.Good hightemperaturethermoelectricmaterial.
IVVI 2 Lead(II)sulfide PbS 0.37
Mineral galena, firstsemiconductor inpractical use, used incat's whiskerdetectors; thedetectors are slowdue to high dielectricconstant of PbS.Oldest material usedin infrared detectors.At room temperaturecan detect SWIR,longer wavelengthsrequire cooling.
IVVI 2 Lead telluride PbTe 0.32
Low thermalconductivity, goodthermoelectricmaterial at elevatedtemperature forthermoelectricgenerators.Tin sulfide (SnS) is asemiconductor withdirect optical band
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IVVI 2 Tin sulfide SnS 1.3/1.0[11] direct/indirect
gap of 1.3 eV andabsorptioncoefficient above 104
cm−1 for photonenergies above 1.3eV. It is a ptypesemiconductorwhose electricalproperties can betailored by dopingand structuralmodification and hasemerged as one ofthe simple, nontoxicand affordablematerial for thinfilms solar cellssince a decade.
IVVI 2 Tin sulfide SnS2 2.2
IVVI 2 Tin telluride SnTe Complex bandstructure.
IVVI 3 Lead tintelluride PbSnTe
Used in infrareddetectors and forthermal imaging.
IVVI 3 Thallium tintelluride
Tl2SnTe5
IVVI 3Thalliumgermaniumtelluride
Tl2GeTe5
VVI,layered 2 Bismuth
tellurideBi2Te3
Efficientthermoelectricmaterial near roomtemperature whenalloyed withselenium orantimony. Narrowgap layeredsemiconductor. Highelectricalconductivity, lowthermalconductivity.Topologicalinsulator.
IIV 2 Cadmiumphosphide
Cd3P2
Ntype intrinsicsemiconductor. Veryhigh electronmobility. Used ininfrared detectors,photodetectors,dynamic thinfilm
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IIV 2 Cadmiumarsenide
Cd3As2 0.14pressure sensors, andmagnetoresistors.Recentmeasurementssuggest that 3DCd3As2 is actually azero bandgap Diracsemimetal in whichelectrons behaverelativistically as ingraphene.[12]
IIV 2 Cadmiumantimonide
Cd3Sb2
IIV 2 Zincphosphide
Zn3P2
IIV 2 Zinc arsenide Zn3As2
IIV 2 Zincantimonide
Zn3Sb2
Used in infrareddetectors andthermal imagers,transistors, andmagnetoresistors.
Oxide 2Titaniumdioxide,anatase
TiO2 3.2 indirect photocatalytic, ntype
Oxide 2 Titaniumdioxide, rutile
TiO2 3.02 direct photocatalytic, ntype
Oxide 2Titaniumdioxide,brookite
TiO2 2.96 [13]
Oxide 2 Copper(I)oxide
Cu2O 2.17 [14]
One of the moststudiedsemiconductors.Many applicationsand effects firstdemonstrated with it.Formerly used inrectifier diodes,before silicon.
Oxide 2 Copper(II)oxide CuO 1.2 Ptype
semiconductor.
Oxide 2 Uraniumdioxide
UO2 1.3
High Seebeckcoefficient, resistantto high temperatures,promisingthermoelectric andthermophotovoltaicapplications.Formerly used inURDOX resistors,conducting at hightemperature.Resistant to radiationdamage.
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Oxide 2 Uraniumtrioxide
UO3
Oxide 2 Bismuthtrioxide
Bi2O3Ionic conductor,applications in fuelcells.
Oxide 2 Tin dioxide SnO2 3.7Oxygendeficient ntype semiconductor.Used in gas sensors.
Oxide 3 Bariumtitanate
BaTiO3 3
Ferroelectric,piezoelectric. Usedin some uncooledthermal imagers.Used in nonlinearoptics.
Oxide 3 Strontiumtitanate
SrTiO3 3.3
Ferroelectric,piezoelectric. Usedin varistors.Conductive whenniobiumdoped.
Oxide 3 Lithiumniobate
LiNbO3 4
Ferroelectric,piezoelectric, showsPockels effect. Wideuses in electroopticsand photonics.
Oxide 3 Lanthanumcopper oxide
La2CuO4 2superconductivewhen doped withbarium or strontium
Layered 2 Lead(II)iodide
PbI2
Layered 2 Molybdenumdisulfide
MoS2
Layered 2 Galliumselenide GaSe 2.1 indirect
Photoconductor.Uses in nonlinearoptics.
Layered 2 Tin sulfide SnS
Layered 2 Bismuthsulfide
Bi2S3
Magnetic,diluted(DMS)[15]
3Galliummanganesearsenide
GaMnAs
Magnetic,diluted(DMS)
3Indiummanganesearsenide
InMnAs
Magnetic,diluted(DMS)
3Cadmiummanganesetelluride
CdMnTe
Magnetic,diluted(DMS)
3Leadmanganesetelluride
PbMnTe
Magnetic 4Lanthanumcalcium La0.7Ca0.3MnO3
colossalmagnetoresistance
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manganateMagnetic 2 Iron(II) oxide FeO antiferromagnetic
Magnetic 2 Nickel(II)oxide NiO 3.6 – 4.0
eV direct[16][17] antiferromagnetic
Magnetic 2 Europium(II)oxide EuO ferromagnetic
Magnetic 2 Europium(II)sulfide EuS ferromagnetic
Magnetic 2 Chromium(III)bromide
CrBr3
other 3Copperindiumselenide, CIS
CuInSe2 1 direct
other 3 Silver galliumsulfide
AgGaS2nonlinear opticalproperties
other 3 Zinc siliconphosphide
ZnSiP2
other 2ArsenicsulfideOrpiment
As2S3semiconductive inboth crystalline andglassy state
other 2ArsenicsulfideRealgar
As4S4semiconductive inboth crystalline andglassy state
other 2 Platinumsilicide PtSi
Used in infrareddetectors for 1–5 µm. Used ininfrared astronomy.High stability, lowdrift, used formeasurements. Lowquantum efficiency.
other 2 Bismuth(III)iodide
BiI3
other 2 Mercury(II)iodide
HgI2
Used in somegammaray and xray detectors andimaging systemsoperating at roomtemperature.
other 2 Thallium(I)bromide TlBr
Used in somegammaray and xray detectors andimaging systemsoperating at roomtemperature. Used asa realtime xrayimage sensor.
other 2 Silver sulfide Ag2S 0.9 [18]
other 2 Iron disulfide FeS2 0.95
Mineral pyrite. Usedin later cat's whiskerdetectors,
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investigated for solarcells.
other 4Copper zinctin sulfide,CZTS
Cu2ZnSnS4 1.49 direct
Cu2ZnSnS4 isderived from CIGS,replacing theIndium/Gallium withearth abundantZinc/Tin.
other 4Copper zincantimonysulfide, CZAS
Cu1.18Zn0.40Sb1.90S7.2 2.2[19] direct
Copper zincantimony sulfide isderived from copperantimony sulfide(CAS), a famatiniteclass of compound.
other 3 Copper tinsulfide, CTS
Cu2SnS3 0.91 direct
Cu2SnS3 is ptypesemiconductor and itcan be used in thinfilm solar cellapplication.
Table of semiconductor alloy systems
The following semiconducting systems can be tuned to some extent, and represent not a single material but aclass of materials.
Group Elem. Materialclass Formula
Bandgap(eV)lower
upper Gap type Description
IV 2 Silicongermanium
Si1xGex 0.67 1.11[3] indirect
adjustable band gap,allows construction ofheterojunction structures.Certain thicknesses ofsuperlattices have directband gap.[20]
IV 2 Silicontin Si1xSnx 1.0 1.11 indirect Adjustable band gap.[21]
IIIV 3Aluminiumgalliumarsenide
AlxGa1xAs 1.42 2.16[3] direct/indirect
direct band gap for x<0.4(corresponding to 1.42–1.95 eV); can be latticematched to GaAssubstrate over entirecomposition range; tendsto oxidize; ndoping withSi, Se, Te; pdoping withZn, C, Be, Mg.[2] Can beused for infrared laserdiodes. Used as a barrierlayer in GaAs devices toconfine electrons to GaAs(see e.g. QWIP). AlGaAswith composition close toAlAs is almosttransparent to sunlight.
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Used in GaAs/AlGaAssolar cells.
IIIV 3Indiumgalliumarsenide
InxGa1xAs 0.36 1.43 direct
Welldeveloped material.Can be lattice matched toInP substrates. Use ininfrared technology andthermophotovoltaics.Indium contentdetermines charge carrierdensity. For x=0.015,InGaAs perfectly latticematches germanium; canbe used in multijunctionphotovoltaic cells. Usedin infrared sensors,avalanche photodiodes,laser diodes, optical fibercommunication detectors,and shortwavelengthinfrared cameras.
IIIV 3Indiumgalliumphosphide
InxGa1xP 1.35 2.26 direct/indirect
used for HEMT and HBTstructures and highefficiency multijunctionsolar cells for e.g.satellites. Ga0.5In0.5P isalmost latticematched toGaAs, with AlGaIn usedfor quantum wells for redlasers.
IIIV 3Aluminiumindiumarsenide
AlxIn1xAs 0.36 2.16 direct/indirect
Buffer layer inmetamorphic HEMTtransistors, adjustinglattice constant betweenGaAs substrate andGaInAs channel. Canform layeredheterostructures acting asquantum wells, in e.g.quantum cascade lasers.
IIIV 3Aluminiumindiumantimonide
AlxIn1xSb
IIIV 3Galliumarsenidenitride
GaAsN
IIIV 3Galliumarsenidephosphide
GaAsP 1.43 2.26 direct/indirect
Used in red, orange andyellow LEDs. Oftengrown on GaP. Can bedoped with nitrogen.
IIIV 3Galliumarsenideantimonide
GaAsSb 0.7 1.42[3] direct
Used in blue laser diodes,ultraviolet LEDs (down
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IIIV 3Aluminiumgalliumnitride
AlGaN 3.44 6.28 directto 250 nm), andAlGaN/GaN HEMTs.Can be grown onsapphire. Used inheterojunctions with AlNand GaN.
IIIV 3Aluminiumgalliumphosphide
AlGaP 2.26 2.45 indirect Used in some greenLEDs.
IIIV 3Indiumgalliumnitride
InGaN 2 3.4 direct
InxGa1–xN, x usuallybetween 0.02–0.3 (0.02for nearUV, 0.1 for390 nm, 0.2 for 420 nm,0.3 for 440 nm). Can begrown epitaxially onsapphire, SiC wafers orsilicon. Used in modernblue and green LEDs,InGaN quantum wells areeffective emitters fromgreen to ultraviolet.Insensitive to radiationdamage, possible use insatellite solar cells.Insensitive to defects,tolerant to latticemismatch damage. Highheat capacity.
IIIV 3Indiumarsenideantimonide
InAsSb
IIIV 3Indiumgalliumantimonide
InGaSb
IIIV 4
Aluminiumgalliumindiumphosphide
AlGaInP direct/indirect
also InAlGaP, InGaAlP,AlInGaP; for latticematching to GaAssubstrates the In molefraction is fixed at about0.48, the Al/Ga ratio isadjusted to achieve bandgaps between about 1.9and 2.35 eV; direct orindirect band gapsdepending on theAl/Ga/In ratios; used forwaveengths between560–650 nm; tends toform ordered phasesduring deposition, whichhas to be prevented[2]
IIIV 4
Aluminiumgalliumarsenide AlGaAsP
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phosphide
IIIV 4
Indiumgalliumarsenidephosphide
InGaAsP
IIIV 4
Indiumgalliumarsenideantimonide
InGaAsSb Use inthermophotovoltaics.
IIIV 4
Indiumarsenideantimonidephosphide
InAsSbP Use inthermophotovoltaics.
IIIV 4
Aluminiumindiumarsenidephosphide
AlInAsP
IIIV 4
Aluminiumgalliumarsenidenitride
AlGaAsN
IIIV 4
Indiumgalliumarsenidenitride
InGaAsN
IIIV 4
Indiumaluminiumarsenidenitride
InAlAsN
IIIV 4
Galliumarsenideantimonidenitride
GaAsSbN
IIIV 5
Galliumindiumnitridearsenideantimonide
GaInNAsSb
IIIV 5
Galliumindiumarsenideantimonidephosphide
GaInAsSbP
Can be grown on InAs,GaSb, and othersubstrates. Can be latticematched by varyingcomposition. Possiblyusable for midinfraredLEDs.
IIVI 3
Cadmiumzinctelluride,CZT
CdZnTe 1.4 2.2 direct
Efficient solidstate xrayand gammaray detector,can operate at roomtemperature. Highelectrooptic coefficient.Used in solar cells. Canbe used to generate anddetect terahertz radiation.
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Can be used as a substratefor epitaxial growth ofHgCdTe.
IIVI 3Mercurycadmiumtelluride
HgCdTe 0 1.5
Known as "MerCad".Extensive use in sensitivecooled infrared imagingsensors, infraredastronomy, and infrareddetectors. Alloy ofmercury telluride (asemimetal, zero bandgap) and CdTe. Highelectron mobility. Theonly common materialcapable of operating inboth 3–5 µm and 12–15 µm atmosphericwindows. Can be grownon CdZnTe.
IIVI 3Mercuryzinctelluride
HgZnTe 0 2.25
Used in infrareddetectors, infraredimaging sensors, andinfrared astronomy.Better mechanical andthermal properties thanHgCdTe but moredifficult to control thecomposition. Moredifficult to form complexheterostructures.
IIVI 3Mercuryzincselenide
HgZnSe
other 4
Copperindiumgalliumselenide,CIGS
Cu(In,Ga)Se2 1 1.7 directCuInxGa1–xSe2.Polycrystalline. Used inthin film solar cells.
See alsoHeterojunctionOrganic semiconductorsSemiconductor characterization techniques
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9. Evans, D A; McGlynn, A G; Towlson, B M; Gunn, M; Jones, D; Jenkins, T E; Winter, R; Poolton, N R J (2008)."Determination of the optical bandgap energy of cubic and hexagonal boron nitride using luminescence excitationspectroscopy". Journal of Physics: Condensed Matter 20 (7): 075233. Bibcode:2008JPCM...20g5233E(http://adsabs.harvard.edu/abs/2008JPCM...20g5233E). doi:10.1088/09538984/20/7/075233(https://dx.doi.org/10.1088%2F09538984%2F20%2F7%2F075233).
10. Claus F. Klingshirn (1997). Semiconductor optics (http://books.google.com/?id=QRQU7S2CKCYC&pg=PA127).Springer. p. 127. ISBN 354061687X.
11. Patel, Malkeshkumar; Indrajit Mukhopadhyay; Abhijit Ray (26 May 2013). "Annealing influence over structural andoptical properties of sprayed SnS thin films". Optical Materials 35: 1693–1699. Bibcode:2013OptMa..35.1693P(http://adsabs.harvard.edu/abs/2013OptMa..35.1693P). doi:10.1016/j.optmat.2013.04.034(https://dx.doi.org/10.1016%2Fj.optmat.2013.04.034).
12. Borisenko, Sergey et al. "Experimental Realization of a ThreeDimensional Dirac Semimetal". Physical ReviewLetters (PRL) 113 (027603). arXiv:1309.7978 (https://arxiv.org/abs/1309.7978). Bibcode:2014PhRvL.113b7603B(http://adsabs.harvard.edu/abs/2014PhRvL.113b7603B). doi:10.1103/PhysRevLett.113.027603(https://dx.doi.org/10.1103%2FPhysRevLett.113.027603).
13. S. Banerjee et al. (2006). "Physics and chemistry of photocatalytic titanium dioxide: Visualization of bactericidalactivity using atomic force microscopy" (http://www.ias.ac.in/currsci/may252006/1378.pdf) (PDF). Current Science 90(10): 1378.
14. O. Madelung, U. Rössler, M. Schulz (ed.). "Cuprous oxide (Cu2O) band structure, band energies". LandoltBörnstein– Group III Condensed Matter. Numerical Data and Functional Relationships in Science and Technology. 41C: NonTetrahedrally Bonded Elements and Binary Compounds I. doi:10.1007/10681727_62(https://dx.doi.org/10.1007%2F10681727_62).
15. B. G. Yacobi Semiconductor materials: an introduction to basic principles (http://books.google.com/books?id=6FAbQCiaNPEC&pg=PA153&dq=%22MAGNETIC+SEMICONDUCTORS%22&lr=&as_drrb_is=q&as_minm_is=0&as_miny_is=&as_maxm_is=0&as_maxy_is=&num=50&as_brr=3&cd=3#v=onepage&q=%22MAGNETIC%20SEMICONDUCTORS%22&f=false) Springer, 2003, ISBN 0306473615
16. Synthesis and Characterization of NanoDimensional Nickelous Oxide (NiO) Semiconductor S. Chakrabarty and K.Chatterjee
17. Synthesis and Room Temperature Magnetic Behavior of Nickel Oxide Nanocrystallites Kwanruthai Wongsaprom*[a]and Santi Maensiri [b]
18. HODES; Ebooks Corporation (8 October 2002). Chemical Solution Deposition of Semiconductor Films(http://books.google.com/books?id=RLeR6v2Nq84C&pg=PA319). CRC Press. pp. 319–. ISBN 9780824743451.Retrieved 28 June 2011.
19. Prashant K Sarswat; Michael L Free. Enhanced Photoelectrochemical Response from Copper Antimony Zinc SulfideThin Films on Transparent Conducting Electrode,International Journal of Photoenergy, vol. 2013, Article ID154694, 7 pages, 2013. doi:10.1155/2013/154694 (http://www.hindawi.com/journals/ijp/2013/154694/cta/).
20. Rajakarunanayake, Yasantha Nirmal (1991) Optical properties of SiGe superlattices and wide band gap IIVIsuperlattices (http://thesis.library.caltech.edu/2857/) Dissertation (Ph.D.), California Institute of Technology
21. Hussain, Aftab M.; Fahad, Hossain M.; Singh, Nirpendra; Sevilla, Galo A. Torres; Schwingenschlögl, Udo; Hussain,Muhammad M. "Tin an unlikely ally for silicon field effect transistors?". physica status solidi (RRL) RapidResearch Letters 8 (4): 332–335. Bibcode:2014PSSRR...8..332H(http://adsabs.harvard.edu/abs/2014PSSRR...8..332H). doi:10.1002/pssr.201308300(https://dx.doi.org/10.1002%2Fpssr.201308300).
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