letters. atmospheric mixing

4
problems; and, third, it is important to coordinate federal-state actions to avoid or alleviate groundwater prob- lems. This is particularly true as EPA and the states are about to launch the Resources Conservation and Recovery Act (RCRA) and Underground In- jection Control (UIC) programs, and are looking hopefully to the passage of the Superfund legislation. With the new initiative and con- centrated effort in attempting to pre- vent a problem with enormous health implications from becoming a reality. the EPA will be living up to its man- date. ES&T is to be congratulated for running the groundwater article and keeping this issue before the public. blarion-bllay US. EPA, Office of Water and Waste Management Washington,b.C. 20460 Atmospheric mixing Dear Sir: The article “Atmospheric mixing” (ES& T, January 1980, p 15) gives a somewhat incomplete descrip- tion of research efforts that have con- tributed to current understanding of the transport processes by w h ic h ozone-rich air from the stratosphere can rapidly intrude into the tropo- sphere. This correspondence is in- tended to provide an expanded over- view of that research. The concept of tropopause folding appears in the literature as early as 1937. However, it was not until 1955 that Reed (I) presented rather con- vincing evidence that tropopause folding involved transport of strato- spheric air into the troposphere. Dur- ing the 1960s. tropopause folding was extensively researched by Danielsen (2) and Reiter (3) in connection with airborne measurements of the trans- port of radioactive debris from the stratosphere into the troposphere. In 1970, Danielsen (4) published aircraft data that showed the transport of high concentrations of stratospheric ozone through the tropopause fold. These researchers found tropopause folding to be associated with low- pressure systems and jet streams in the upper troposphere. Over the conti- nental United States, such weather systems occur frequently during winter and spring, and generally move from west to east under the influence of the prevailing westerly winds. In 1973, Mahlman (5) computed the air cir- culation associated with a jet stream. It showed strong downward motion from the stratosphere to the lower troposphere on the north side of the jet core. This downward branch trans- ports the natural ozone as observed by Danielsen. In addition to Shapiro’s spring 1978 flight program, another experimental program was carried out in the spring and fall of 1978 by SRI International and results published (6, 7). This pro- gram, sponsored bq the Air Pollution Research Advisory Committee of the Coordinating Research Council, Inc., investigated by instrumented aircraft several cases of tropopause folding and stratospheric/tropospheric ozone transport in areas east of the Rocky Mountains, \I here the occurrence and organization of such events had never been documented. In one case observed during October 1978, the stratospheric ozone intrusion penetrated down to 2 km above ground level. At this time, the fate of intrusions below 2 km re- mains unexplored. SRI, however, is continuing its research on the impact of stratospheric ozone on ground level measurements, as are several other researchers. (1) Reed, R. J., “A Study of a Characteristic Type of Upper Level Frontogenesis,” J Meteorol 1955,12, 226-37. continued on page 631 . . . with the proven effective R E-TH ER M@ Thermal OxidationSystem. AND you get energy recovery and recycling as a bonus’ Through extremely efficient thermal oxidation, your REECO RE-THERM unit effectively destroys hydrocarbon process fumes or anticipated air pollution control requirement Your RE-THERM unit also captures and recycles the energy in those previously unburned hydrocarbons gives you energy back to use again and again and again Result? Substantial overall plant fuel savings a healthy Simple in concept, ruggedly built your RE-THERM is carefully custom-engineered for your specific requirements And your RE-THERM unit allows continued use of your existing process and lets you meet any known RE-THERM ROI costly or quality threatening process changes required you can profit by owning this proven system for air pollution control with energy recycling, write or call us today REECO responds with theRE-THERM System And REECO responds when you do For more mformatlonon how VISIT BOOTH 816-818 EQUIPMENT CO., INC. - 7500 SCFM RE-THERM System Box 600%’ 520 Speedwell Avenue hrlorrls Pims NJ 07950 Phone (2011 538-8585 ___-~ _--- J CIRCLE 21 ON READER SERVICE CARD 628 Environmental Science & Technology

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Page 1: Letters. Atmospheric Mixing

problems; and, third, it is important to coordinate federal-state actions to avoid o r alleviate groundwater prob- lems. This is particularly true a s EPA and the states a re about to launch the Resources Conservation and Recovery Act ( R C R A ) and Underground In- jection Control ( U I C ) programs, and a re looking hopefully to the passage of the Superfund legislation.

With the new initiative and con- centrated effort in attempting to pre- vent a problem with enormous health implications from becoming a reality. the EPA will be living up to its man- date.

ES&T is to be congratulated for running the groundwater article and keeping this issue before the public. blarion-bllay U S . EPA, Office of Water and Waste Management Washington,b.C. 20460

Atmospheric mixing Dear Sir: The article “Atmospheric

mixing” (ES& T, January 1980, p 15) gives a somewhat incomplete descrip- tion of research efforts tha t have con- tributed to current understanding of the transport processes by w h ic h ozone-rich air from the stratosphere

can rapidly intrude into the tropo- sphere. This correspondence is in- tended to provide an expanded over- view of tha t research.

The concept of tropopause folding appears in the literature as early as 1937. However, it was not until 1955 that Reed ( I ) presented rather con- vincing evidence tha t tropopause folding involved transport of strato- spheric air into the troposphere. Dur- ing the 1960s. tropopause folding was extensively researched by Danielsen (2) and Reiter (3) in connection with airborne measurements of the trans- port of radioactive debris from the stratosphere into the troposphere. I n 1970, Danielsen ( 4 ) published aircraft da ta that showed the transport of high concentrations of stratospheric ozone through the tropopause fold.

These researchers found tropopause folding to be associated with low- pressure systems and jet streams in the upper troposphere. Over the conti- nental United States, such weather systems occur frequently during winter and spring, and generally move from west t o east under the influence of the prevailing westerly winds. In 1973, Mahlman ( 5 ) computed the a i r cir- culation associated with a jet stream. It showed strong downward motion

from the stratosphere to the lower troposphere on the north side of the jet core. This downward branch trans- ports the natural ozone as observed by Danielsen.

I n addition to Shapiro’s spring 1978 flight program, another experimental program was carried out in the spring and fall of 1978 by S R I International and results published (6, 7 ) . This pro- gram, sponsored bq the Air Pollution Research Advisory Committee of the Coordinating Research Council, Inc., investigated by instrumented aircraft several cases of tropopause folding and stratospheric/tropospheric ozone transport in areas east of the Rocky Mountains, \I here the occurrence and organization of such events had never been documented. In one case observed during October 1978, the stratospheric ozone intrusion penetrated down to 2 km above ground level. A t this time, the fa te of intrusions below 2 km re- mains unexplored. S R I , however, is continuing its research on the impact of stratospheric ozone on ground level measurements, as a re several other researchers. (1) Reed, R. J., “A Study of a Characteristic Type of Upper Level Frontogenesis,” J Meteorol 1955,12, 226-37.

continued on page 631

. . . with the proven effective R E-TH ER M@ Thermal Oxidation System. AND you get energy recovery and recycling as a bonus’

Through extremely efficient thermal oxidation, your REECO RE-THERM unit effectively destroys hydrocarbon process fumes or anticipated air pollution control requirement Your RE-THERM unit also captures and recycles the energy in those previously unburned hydrocarbons gives you energy back to use again and again and again Result? Substantial overall plant fuel savings a healthy

Simple in concept, ruggedly built your RE-THERM is carefully custom-engineered for your specific requirements And your RE-THERM unit allows continued use of your existing process and

lets you meet any known

RE-THERM ROI

costly or quality threatening process changes required

you can profit by owning this proven system for air pollution control with energy recycling, write or call us today REECO responds with theRE-THERM System And REECO responds when you do

For more mformatlonon how

VISIT BOOTH 816-818

EQUIPMENT CO., INC. -

7500 SCFM RE-THERM System Box 600%’ 520 Speedwell Avenue hrlorrls P i m s NJ 0 7 9 5 0 Phone ( 2 0 1 1 538-8585

_ _ _ - ~ _--- J

CIRCLE 21 ON READER SERVICE CARD

628 Environmental Science & Technology

Page 2: Letters. Atmospheric Mixing

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CIRCLE 9 ON READER SERVICE CARD

Volume 14, Number 6, June 1980 629

Page 3: Letters. Atmospheric Mixing
Page 4: Letters. Atmospheric Mixing

( 2 ) Danielsen, E. F., “Stratospheric-Tro- pospheric Exchange Based on Radioactivity, Ozone, and Potential Vorticity,” J . Atmos. Sci. 1968,25, 502-18. (3) Reiter, E. R., “A Case Study of Radio- active Fallout,” J . Appi . Meteorol. 1963, 2 (6), 691-705. (4) Danielsen, E. F.; Bleck, R.; Shedlovsky, J.; Wartburg, A,; Haagenson, P.; Pollock, W., “Observed Distribution of Radioactivity, Ozone, and Potential Vorticity Associated with Tro-Dooause Foldine.” J . Geoahvs. Res. ‘ . 1970, 75 I l i ) , 2353-61. ( 5 ) Mahlman, J. D.. “On the Maintenance of the Polar Front Jet S t ream,”J . Atmos Sti 1973,30, 544-56. (6) Johnson. W. B.: Viezee. W.: Cavanaeh. L.: Ludwig, F. L.; Singh, H. n.; Danielsen,-E. F., “Measurements of Stratospheric Ozone Penetrations Into the Lower Troposphere,” Proceedings of the 4th Symposium on Tur- bulence and Diffusion, p. 355-62, Boston, Mass. January 1979; American Meteorolog- ical Societv. ( 7 ) Viezee, W.; Johnson, W. B.; Singh, H. B.. “Airborne Measurements of Stratospheric Ozone Intrusions Into the Troposphere Over the United States,” Final Report, Volume I. Contract CRC-APRAC Project No. CAPA- 15-76 (1-77), 219 Perimeter Center Parkway, Atlanta, Ga., September 1979; Coordinating Research Council, Inc. William Viezee Warren B. Johnson Hanwant B. Singh SRI International Menlo Park. Calif. 94025

Alcohol fuel Dear Sir: Your discussion of gasohol

(ES& T, February 1980, p 140) omits three items which promise to be im- portant to the energy input required to produce fuel and which I would like to see discussed.

( I ) W h a t is the comparison with octane boosters? Alcohols increase octane without lead and without en- ergy-intensive refining. Hut what are the numbers?

(2) Alcohols can be separated from the mash catalytically; again, what are the numbers and who is developing the technology?

(3) Solar energy can very conve- niently be used on a small scale by farmers both for distillation and for drying. Paul Butkerert Freeport, N.Y. 11520

Marine pollution Dear Sir: This is an expression of

our appreciation for the fine job you and your colleagues did on our article on marine pollution ( E S & T, January 1980, p 32). The organization you in- troduced in the representation of fig- ures and tables was particularly grat- ifying. Donald C. Malins Director Northwest and Alaska Fisheries Center Seattle, Wash. 98 1 12

Volume 14, Number 6, June 1980 631