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Lecture 12 Advanced Stages of Stellar Evolution – II Silicon Burning and NSE

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Page 1: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

Lecture 12

Advanced Stages of Stellar Evolution – IISilicon Burning and NSE

Page 2: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

Silicon BurningSilicon burning proceeds in a way different from any nuclear process

discussed so far. It is analogous, in ways, to neon burning in that itproceeds by photodisintegration and rearrangement*, but it involves manymore nuclei and is quite complex.

The reaction 28Si + 28Si à (56Ni)* does not occur owing to the large Coulomb inhibition. Rather a portion of the silicon (and sulfur, argon, etc.)�melt� by photodisintegration reactions into a sea of neutrons, protons, and alpha-particles. These lighter constituents add onto the remaining silicon and heavier elements, gradually increasing their mean atomic weight until species in the iron group are most abundant.

Carbon burning Heavy ion fusionNeon Burning Photodisintegration rearrangementOxygen burning Heavy ion fusionSilicon burning Photodisintegration rearrangement

*Basically the temperature threshold for removing an alpha from 24Mg is reached beforethat of 28Si+28Si

Page 3: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

Initial Composition

The initial composition is mostly Si and S, but which isotopes of Si and S dominate depends upon whether one is discussing the inner core or less dense locations farther out in the star. It is quite different for silicon core burning in a presupernova star and the explosive variety of silicon burning we shall discuss later.

In the center of the star, one typically has, after oxygen burning, anda phase of electron capture that goes on between oxygen depletion and silicon ignition:

30Si, 34S, 38Ar and a lot of other less abundant nuclei. High η

Farther outside of the core where silicon might burn explosively, onehas species more characteristically with Z = N

28Si, 32S, 36Ar, 40Ca, etc.

Historically, Si burning was discussed for a 28Si rich composition. Low η

Page 4: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

Neutron excess after oxygen core depletionin 15 and 25 solar massstars.

The inner core is becomingincreasingly �neutronized�,especially for the lower mass stars. The process accelerates during siliconburning

The nucleosynthesis of the inner core would be very strangewere it to be ejected (it is not).η ~ 0.002 – 0.004 is good. 0.01is not

15

25

η

η

Page 5: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

Quasi-equilibriumThis term is used to describe a situation where groups of

adjacent isotopes, but not all isotopes globally, have come into equilibrium with respect to the exchange of n, p, a, and g.

It began in neon burning with 20Ne + γ! 16O + α andcontinues to characterize an increasing number of nuclei duringoxygen burning. In silicon burning, it becomes the rulerather than the exception. A typical "quasiequilibrium cluster" might include the equilibrated reactions :

28Si! 29Si! 30Si! 31P! 32S! 28Si n n p p α

By which one means Y(28Si) Yn ρλnγ (28Si) ≈ Y(29Si) λγ n (29Si)

Y(30Si)Ynρλnγ (29Si) ≈Y(30Si)λγ n (30Si)

etc.

Page 6: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

24 45 46 60 (at least)A A≤ ≤ ≤ ≤

Late during oxygen burning, many isolated clusters grow and mergeuntil, at silicon ignition, there exist only two large QE groups

Reactions below 24Mg, e.g., 20Ne(a,g)24Mg and 12C(a,g)16O are, in general,not in equilibrium with their inverses at oxygen depletion (exception, 16O(a,g)20Ne which has been in equilibrium since neon burning).

Within the groups heavier than A = 24, except at the boundaries of the clusters,the abundance of any species is related to that of another by successive application of the Saha equation.

40 32 36 40

28 28 32 36

28 32 36

32 36 40

3 3

( ) ( ) ( ( ). .,

( ) ( ) ( ) ( )

( ) ( ) ( )

( ) ( ) ( )

( , ) .

Y Ca Y S Y Ar Y Cae g

Y Si Y Si Y S Y Ar

Y Si Y S Y Ar

S Ar Ca

f T Q Y etc

α αγ α αγ α αγ

γα γα γα

αγ α

ρ λ ρ λ ρ λλ λ λ

ρ

⎛ ⎞⎛ ⎞⎛ ⎞= ⎜ ⎟⎜ ⎟⎜ ⎟⎝ ⎠⎝ ⎠⎝ ⎠⎛ ⎞⎛ ⎞⎛ ⎞

= ⎜ ⎟⎜ ⎟⎜ ⎟⎜ ⎟⎜ ⎟⎜ ⎟⎝ ⎠⎝ ⎠⎝ ⎠

=

Page 7: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

The situation at the end of oxygen burning is that there are two large QE groups coupled by non-equilibratedlinks near A = 45.

Early during silicon burning these two groups merge and the only remaining non-equilibrated reactions are forA < 24 (Mg).

45A >

24 45A≤ ≤

The non-equilibrated linkhas to do with the doubleshell closure at Z = N = 20

Page 8: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

Y ( A Z ) = C( A Z ,ρ,T9 )Y (28 Si)YαδαYp

δ pYnδ n

where δα = largest integer ≤ Z-142

δ n = N −14− 2δα

δ p = Z −14− 2δα e.g.,35 Cl 17 protons; 20 neutrons

δα =1 δ p = 1 δ n = 240K 19 protons 21 neutrons

δα = 2 δ p = 1 δ n = 3

Within that one group,(A > 23), which contains 28Si and the vast majority of the mass, one can evaluate any abundance relative to e.g., 28Si

Need 6 parameters: Ya, Yp, Yn andY(28Si) plus T and r, but …

Page 9: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

C(A Z ) = ρNA( )δα +δ p +δn

C '(A Z )

C '(A Z ) = 5.942×1033T9

3/2( )− δα +δ p +δn( )

G(A Z )

G(28Si)

2− δ p +δn( ) A

28

⎛⎝⎜

⎞⎠⎟

3/21

4

⎛⎝⎜

⎞⎠⎟

3δα /2

exp(Q / kT )

where

Q = BE(A Z ) − BE(28Si) − δαBE(α )

i.e., the energy required to dissociate the nucleus AZ into28Si and d a alpha particles. The binding energy of a neutron orproton is zero.

Page 10: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

32S

31P

28Si 29Si 30Si

32 30 2

30 28 2

32 28

32 32 302 2

28 30 28

For constant and T

( ) ( )

( ) ' ( )

( ) '' ( )

( ) ( ) ( )

( ) ( ) ( )

p

n

p n

Y S const Y Si Y

Y Si const Y Si Y

Y S const Y Si Y

Y S Y S Y SiY Y Y

Y Si Y Si Y Si

α

α

ρ

=

=

=

⎛ ⎞ ⎛ ⎞⎛ ⎞∝ ∝ ∝⎜ ⎟ ⎜ ⎟⎜ ⎟⎝ ⎠ ⎝ ⎠⎝ ⎠

i

i

i

Yα= C

α(T

9,ρ) Y

n

2Y

p

2

Cα=

1

2(5.94 ×10

33)−3ρ

3T

9

9/2exp(328.36 / T

9)

where 328.36 = BE(α )/kT

This reduces the number of independent variables to 5, butwait …

Moreover there exist loops like:

p

p

n n

a

Page 11: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

60 24

60 24

1

( )

i i

A

i i i

A

AY

N Z Y η

≥ ≥

≥ ≥

− ≈

The large QE cluster that includes nuclei from A = 24 through at least A = 60 contains most of the matter (20Ne, 16O, 12C, and aare all small), so we have the additional two constraints

The first equation can be used to eliminate one more unknown, say Yp, and the second can be used to replaceYn with an easier to use variable, η. Thus 4 variables now specify the abundances of all nuclei heavier than magnesium . These are

r, T9, h, and Y(28Si)

mass conservation

charge conservation

Page 12: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

QE

24 A 60≤ ≤

28Si24Mg+α

20Ne+α

16O+α

12C+α

7α28

9, , , ( ) QET Y Siρ η ⇒

For low η, the cluster evolves at a rate given by 24Mg(g,a)20Ne

The photodisintegration of 24Mgprovides a�s (and n�s and p�s sinceYa =CaYn

2Yp2) which add onto

the QE group gradually increasingits mean atomic weight. As a result the intermediate mass group,Si-Ca gradually �melts� into the iron group.

Y ( A Z ) = C( A Z ,ρ,T9 )Y (28 Si)Yα

δαYpδ pYn

δ n

Page 13: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

Nature of the burning:Lighter species melt away while the iron group grows

Page 14: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

But this assumes 28Si burns to 56Ni ( small η approximation)

Energetics:

Suppose 28Si burns to 56Ni. To rough approximation2(28Si) -> 56Ni (n.b. not fusion of 2 silicons)

qnuc = 9.65 x 1017 [1/2 (483.982 -236.536)/28]= 1.9 x 1017 erg g-1 (not much)

Page 15: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

This is misleading because, except explosively(later), silicon burning does not produce 56Ni. There has been a lot of electron capture during oxygen burning andmore happens in silicon burning. The silicon that burns is not 28Si, but more typically 30Si.

E.g., Si ignition in a 15 M

star ηc≈0.07 Y

e≈ 0.46

Si depletion ηc ≈0.13 Ye≈ 0.44

Under these conditions silicon burning produces 54Fe, 56Fe, 58Fe and

other neutron rich species in the iron group.

Suppose 56

30

⎛⎝⎜

⎞⎠⎟

30Si → 56Fe

qnuc = 9.65 × 1017 492.26( ) / 56− 255.62( ) / 30⎡⎣ ⎤⎦ = 2.6 × 1017 erg g-1 which is closer to correct for Si

core burning than 1.9 × 1017 erg g−1

i.e., qnuc = 9.65×1017 Xi

AiBE(Ai )∑

Page 16: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

An approximation to energy generation is derived in Appendix 2. See also next page

It depends on T47

This approximation implies that Si buring will achieve balanced power at 3.5 billion degrees with a generation rate approximately 1013 erg g-1 s-1

The approximate lifetime is thus

q ΔX (28Si)εnuc

∼2.6 ×1017 (1)

1013 ~ 7 hours

Shell burning and convection can lengthen this todays to weeks

Page 17: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for
Page 18: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

Nucleosynthesis

Basically, silicon burning in the star�s core turns the products of oxygen burning (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for a given neutron excess, η.

The silicon-burning nucleosynthesis that is ejected by a super-nova is produced explosively, and has a different composition dominatedby 56Ni.

The products of silicon-core and shell burning in the core are both so neutron-rich (η so large) that they need to be left behind in a neutron star orblack hole. However, even in that case, the composition and its evolutionis critical to setting the stage for core collapse and the supernova explosion that follows.

Page 19: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

Following Si-burning at the middle of a 25 solar mass star:

54Fe 0.48758Ni 0.14756Fe 0.14155Fe 0.07157Co 0.044

Neutron-rich nuclei in the iron peak.

Ye = 0.4775

Following explosive Si-burning in a 25 solar mass supernova, interesting

species produced at Ye = 0.498 to 0.499.

44Ca 44Ti47,48,49Ti 48,49Cr51V 51Cr55Mn 55Co

50,52,53Cr 52,53Fe54,56,57Fe 56,57Ni59Co 59Cu58,60,61,62Ni 60,61,62Zn

product parent

Silicon burning nucleosynthesis

44Ti and 56.57Ni are important

targets of γ-ray astronomy

Page 20: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

25 Solar MassPop I

at Si-depletion(Woosley and Heger 2007)

This partwill collapseand make a shock

FeSi O He

H

η~0.002

Page 21: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

Nuclear Statistical Equilibrium

24 24 24 20

16 20 20 16

12 16 16 12

12 12

( , ) ( , )

( , ) ( , ) (for a long time already)

( , ) ( , )

3 ( , )2

Ne Mg Mg Ne

O Ne Ne O

C O O C

C C

α γ γ α

α γ γ α

α γ γ α

α γ α α

→ ↔

As the silicon abundance tends towards zero (though it never becomes microscopically small), the unequilibratedreactions below A = 24 finally come into equilibrium

The 3a reaction is the last to equilibrate. Once this occurs,every isotope is in equilibrium with every other isotope by strong and electromagnetic reactions(but not by weak interactions)

Page 22: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

In particular, Y(28Si) = f (T ,ρ)Yα7 with the result that now

only 3 variables, ρ, T9,and η specify the abundances

of everything

Y(AZ ) = C(AZ ,ρ,T9 ) YnNYp

Z

C(AZ ,ρ,T9 ) = ρNA( )A−1C '(AZ ,T9 )

C ' (AZ ,T9 )=G(AZ ,T9 )

2Aθ1−A exp BE(AZ ) / kT⎡⎣ ⎤⎦

θ =5.943 × 1033T93/2

G(AZ ,T9 ) is the temperature-dependent

partition function.At low T

G(AZ ,T9 ) = 2Ji +1( )∑ e−Ei /kT

At high T, though (see earlier discussion of nuclear level density)

G(AZ ,T9 )≈ π6akT

ea(kT )

a ≈ A9

MeV-1

Page 23: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

Until the temperature becomes very high (T ≥1010K )The most abundant nuclei are those with large binding energyper nucleon and "natural" values of η. For example,

η = 0 56Ni

0.037 54Fe

0.071 56Fe etc.

In general, the abundance of an isotope peaks at itsnatural value for η. E. g.,

η(54Fe) = N − ZA

= 28 - 2654

=0.0370

η(56Fe) = N − ZA

= 30 - 2656

=0.0714

Page 24: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

The resultant nucleosynthesis is most sensitive to η.

Page 25: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

True Equilibrium

If the weak interactions were also to be balanced, (e.g., neutrino capture occurring as frequently on the daughternucleus as electron capture on the parent), one would have a state of true equilibrium. Only two parameters, r and T, would specify the abundances of everything. The first time this occurredin the universe was for temperatures above 10 billion K in the Big Bang.

However, one can also have a dynamic weak equilibrium whereneutrino emission balances anti-neutrino emission, i.e., when

0e

dY

dt=

This could occur, and for some stars does, when electron-capture balances beta-decay globally, but not onindividual nuclei. The abundances would be set by ρ and T, butwould also depend on the weak interaction rate set employed.

Page 26: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

Weak Interactions

Electron capture, and at late times beta-decay, occur for a variety ofisotopes whose identity depends on the star, the weak reaction ratesemployed, and the stage of evolution examined. During the late stagesit is most sensitive to η, the neutron excess.

Aside from their nucleosynthetic implications, the weak interactionsdetermine Ye, which in turn affects the structure of the star. The most important isotopes changing Ye are not generally the most abundant, but those that have some combination of significant abundance and favorable nuclear structure (especially Q-value) for weak decay.

From silicon burning onwards these weak decays provide neutrinoemission that competes with and ultimately dominates that fromthermal processes (i.e., pair annihilation).

Page 27: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

He – depletionO – depletionPreSN

25 M

solar metallicity

He – depletionO – depletionPreSN

25 M

zero initial metalicity

The distribution of neutron excess, h,within two stars of 25 solar masses(8 solar mass helium cores) is remarkably different. In the Pop Istar, h is approximately 1.5 x 10-3

everywhere except in the inner core (destined to become a collapsedremnant)

In the Pop III (Z = 0) star the neutron excess is essentially zero at the end of heliumburning (some primordial nitrogen was created)Outside of the core h is a few x 10-4, chiefly from weak interactions during carbon burning.Note some primary nitrogen production at the outer edge where convection has mixed 12Cand protons.

log η

Interior mass

Interior mass

log η

Page 28: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

Si-depletion Si-shell burn Core contraction PreSN

T(109 K) 3.78 4.13 3.55 7.16ρ (g cm-3) 5.9 x 107 3.2 x 108 5.4 x 108 9.1 x 109

Ye 0.467 0.449 0.445 0.432

e-capture 54,55Fe 57Fe, 61Ni 57Fe, 55Mn 65Ni, 59Fe

b-decay 54Mn, 53Cr 56Mn,52V 62Co,58Mn 64Co, 58Mn

O-depletion O-shell Si-ignition Si-shell

T(109K) 2.26 1.90 2.86 3.39ρ(g cm-3) 1.2 x 107 2.8 x 107 1.1 x 108 4.5 x 107

Ye 0.498 0.495 0.489 0.480

e-capture 35Cl, 37Ar 35Cl, 33S 33S,35Cl 54,55Fe

b-decay 32P, 36Cl 32P,36Cl 32P, 28Al 54,55Mn

15 solar mass star (Heger et al 2001)

Page 29: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for
Page 30: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

Fe

Si, S, Ar, Ca

He, C

H, He He

1400 R

0.5 R

0.1 R

0.003 R

25 M

Presupernova Star (typical for 9 - 130 M

)

O,Mg,Ne

C,O

240,000 L

Page 31: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

(note scale breaks)

Page 32: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for
Page 33: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

As silicon shells, typically one or at most two, burn out, the iron coregrows in discontinuous spurts and approaches instability.

Pressure is predominantly due to relativistic electrons. As they become increasingly relativistic, the structural adiabatic indexof the iron core hovers precariously near 4/3. The presence of non-degenerate ions has a stabilizing influence, but the core is rapidly losing entropy to neutrinos and becoming degenerate making the concept of a Chandrasekhar Mass relevant.

In addition to neutrino losses there are also two other important instabilities:

• Photodisintegration – which takes energy that might have providedpressure and uses it instead to pay a debt of negative nuclearenergy generation.

• Electron capture – since pressure is dominantly from electrons,removing them reduces the pressure.

Page 34: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

Photodisintegration:

Yα = Cα (T9 ,ρ) Yn2Yp

2

Cα=

1

2(5.94 × 1033 )−3 ρ 3T

9

9/2 exp(328.36 / T9)

where 328.36 = BE(α )/kT ⇒ Cα increases rapidly as T ↓

from earlier in this lecture

Setting Yα = 1/8 (i.e., X = ½ divided by 4) and Yp=Yn=1/4gives the line for the helium-nucleon transition on the previous page.

The Ni-α transition is given by Clayton problem 7-11 and eqn 7-22. It comes from solving the Saha equation for NSE(see previous discussion these notes) for the case

X(56Ni)= Xα =0.5⇒Y (

56Ni)=1/112; Yα =1/ 8

Y (56Ni)=C56(T9 )ρ

12Yα13

Page 35: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

See also Clayton Fig 7-9 and discussion

Illiadis

Typical presupernovacentral conditions

The transition from the iron group to He andespecially from He to2n + 2p absorbs anenormous amount of energy.

Figure needs correctingfor high temperaturenuclear partitionfunctions.

Dominant constituent in NSE (η approximately 0)

Page 36: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

The photodisintegration of one gram of 56Ni to one gram ofα-particles absorbs:

qnuc

= 1.602×10−6N

A(δY

i)(BE

i) − qν erg/gm∑

= 9.64×1017 −1

56

⎛⎝⎜

⎞⎠⎟

483.993( )+1

4

⎛⎝⎜

⎞⎠⎟

28.296( )⎡

⎣⎢

⎦⎥

= −1.51×1018 erg g−1

Similarly, the photodisintegration of one gram of α’s to one gram ofnucleons absorbs:

qnuc

=9.64×1017 −1

4

⎛⎝⎜

⎞⎠⎟

28.296( ) + 0⎡

⎣⎢⎤

⎦⎥

=−6.82×1018 erg g−1

essentially undoing all the energy released by nuclear reactionssince the zero age main sequence.

Page 37: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

Electron captureThe pressure and entropy come mainly from electrons, but as the

density increases, so does the Fermi energy, eF. The rise in eFmeans more electrons have enough energy to capture on nuclei turning protons to neutrons inside them. This reduces Ye which inturn makes the pressure and entropy at a given density smaller.

( )1/3

71.11 MeV

F eYε ρ=

By 2 x 1010 g cm-3, eF= 10 MeV which is above the capture threshold for all but the most neutron-rich nuclei. There is also briefly a small abundance of free protons (up to 10-3 by mass) which captures electrons.

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Entr

opy

(S/N

Ak)

What about degeneracy? Can the core be supported byelectron degeneracy pressure and form a stable (Fe) dwarf?

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Entropy

Page 40: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

Because of increasing degeneracy the concept of a ChandrasekharMass for the iron core is relevant – but it must be generalized.

0 implies degeneracyη >

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The Chandrasekhar Mass

2

3 3 4 4 3 2

4/3

4 4

15 -2

4/3

Traditionally, for a fully relativistic, completely degenerate gas:

20.745

1.2435 10 dyne cm

1.457 M at 0.5

0

5

83

.

c c e

Ch

c c

e

eM Y

P K Y G M

K

Y

ρ

ρ ρ= =

= ×

= =

=

This is often referred to loosely as 1.4 or even 1.44 solar masses

see lecture 1

Page 42: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

BUT1) Ye here is not 0.50 (Ye is actually a function

of radius or interior mass)

2) The electrons are not fully relativistic in the outer layers (g is not 4/3 everywhere)

3) General relativity implies that gravity is stronger than classical and an infinite central density is not allowed (there exists a critical r for stability)

4) The gas is not ideal. Coulomb interactions reducethe pressure at high density

5) Finite temperature (entropy) corrections

6) Surface boundry pressure (if WD is inside a massive star)

7) Rotation

Effect on MCh

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Relativistic corrections, both special and general, are treated by Shapiro and Teukolsky in Black Holes, White Dwarfs, and Neutron Starspages 156ff. They find a critical density (entropy = 0).

2

10 -30.502.646 10 gm cm

c

eY

ρ⎛ ⎞

= × ⎜ ⎟⎝ ⎠

Above this density the white dwarf is (general relativistically)unstable to collapse. For Ye = 0.50 this corresponds to a mass

2/31

1.415 M

in general, the relativistic correction to the Newtonian value is

M 0.50 9 4 310

M

2.87% 0.50

2.67% 0.45

Ch

e

e

e

M

Y

Y

Y

=

⎡ ⎤⎛ ⎞Δ ⎢ ⎥= − + ⎜ ⎟⎢ ⎥⎝ ⎠⎣ ⎦=− =

=− =

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Coulomb Corrections

Three effects must be summed – electron-electron repulsion, ion-ionrepulsion and electron ion attraction. Clayton p. 139 – 153 gives a simplified treatment and finds, over all, a decrement to the pressure(eq. 2-275)

ΔPCoul

= −3

10

4π3

⎛⎝⎜

⎞⎠⎟

Z2/3

e2

ne

4/3

Fortunately, the dependence of this correction on ne is the sameas relativistic degeneracy pressure. One can then just proceed to use a corrected

1/32 5/3

0 2/3

4 /3 4 /3

0 3 2/3

4 /3

2 31

5

1 4.56 10

eK K Z

c

K Z

π−

⎡ ⎤⎛ ⎞= −⎢ ⎥⎜ ⎟

⎝ ⎠⎢ ⎥⎣ ⎦⎡ ⎤= − ×⎣ ⎦

Page 45: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

( )1/3

0 2 4/3

4 /3

3/ 2

Ch

0 0

Ch

2/3

0

Ch

where 34

Mand

M

hence

M 1 0.02266

A

Ch

cK N

K

K

ZM

π=

⎛ ⎞= ⎜ ⎟⎝ ⎠

⎡ ⎤⎛ ⎞= −⎢ ⎥⎜ ⎟

⎝ ⎠⎢ ⎥⎣ ⎦

2

e

12

Ch e

56

Putting the relativistic and Coulomb corrections together

with the dependence on Y one has

M 1.38 M for C (Y 0.50)

= 1.15 M for Fe (Y

= =

e

e

260.464)

56

= 1.08 M for Fe-core with <Y 0.45

= =

>≈

So why are iron cores so big at collapse (1.3 - 2.0 M

) and

why do neutron stars have masses ≈1.4 M

?

Page 46: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

( )

( )

2 2 24/30

4/3 2 2 4

1/31/3

For 3, 4 / 3, relativistic degeneracy

1 21 1 ...

30.01009

8

(Clayton 2-48)

c e

e

Fe e

e

n

k TP K Y

x m c

phx n Ymc m c

γ

πρ

ρπ

= =

⎡ ⎤⎛ ⎞= + − +⎢ ⎥⎜ ⎟

⎝ ⎠⎣ ⎦

⎛ ⎞= = =⎜ ⎟

⎝ ⎠

Finite Entropy Corrections

Chandrasekhar (1938)Fowler & Hoyle (1960) p 573, eq. (17)Baron & Cooperstein, ApJ, 353, 597, (1990)

Page 47: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

In particular, Baron & Cooperstein (1990) show that

2

1/33

1/3

7

3/ 2

4 /3

2

0

21 ...

3

3

8

1.11( ) MeV

and since a first order expansion gives

1

o

F

eF F

F e

Ch

Ch Ch

F

kTP P

h np c

Y

M K

kTM M

πε

επ

ε ρ

πε

⎛ ⎞⎛ ⎞⎜ ⎟= + +⎜ ⎟⎜ ⎟⎝ ⎠⎝ ⎠

⎛ ⎞= =⎜ ⎟

⎝ ⎠=

⎛ ⎞⎛ ⎞⎜ ⎟≈ + ⎜ ⎟⎜ ⎟⎝ ⎠⎝ ⎠

Page 48: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

And since, in the appendix to these notes we show

se =π 2kTYeε F

(relativistic degeneracy)

one also has

MCh ≈ MCh0 1+

seπYe

⎝⎜⎞

⎠⎟

2

+ ...⎛

⎝⎜⎜

⎠⎟⎟

Here MCh0 incluedes all other non-thermal corrections

The entropy of the radiation and ions also affects MCh, but much less.

This finite entropy correction is not important for isolated white dwarfs. They�re too cold. But it is very importantfor understanding the final evolution of massive stars.

Page 49: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

Because of its finite entropy (i.e., because it is hot)the iron core develops a mass that, if it were cold,could not be supported by degeneracy pressure.

Because the core has no choice but to decrease itselectronic entropy (by neutrino radiation, electroncapture, and photodisintegration), and because its(hot) mass exceeds the Chandrasekhar mass, it must eventually collapse.

Page 50: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

E.g., on the following pages are excerpts from the final day in the life of a 15 M⊙ star. During silicon shell burning, the electronic entropyranges from 0.5 to 0.9 in the Fe core and is about 1.3 in the convectiveshell.

MCh ≈1.08 M⊙ 1+ 0.7π (0.45)

⎛⎝⎜

⎞⎠⎟

2⎛

⎝⎜

⎠⎟ = 1.34 M⊙ > 0.95 M⊙

The Fe core plus Si shell is also stable because

MCh≈ 1.15 M⊙ 1+ 1.0π (0.47)

⎛⎝⎜

⎞⎠⎟

2⎛

⎝⎜

⎠⎟ = 1.67 M⊙ > 1.3M⊙

0.45 and 0.47 are average values of Ye in the region being discussed. For 0.45 we used the smaller value for MCh0 a few pages back. For 0.47 we used the value for 56Fe. These are allcrude averages to make a point.

Page 51: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for
Page 52: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

But when Si burning in this shell is complete:

Neutrino losses farther reduce se. So too do photodisintegration* and electron captureand the boundry pressure of the overlying silicon shell is not entirely negligible.

The core collapses

3) The Fe core is now ~1.35 M⊙.

se central = 0.4

se at edge of Fe core = 1.1

average ≈0.7 Ye ranges from 0.438 (center) to 0.47 (edge).

use an averge of 0.45MCh now about 1.34 M⊙ (uncertain to at least a

few times 0.01 M

• Photodisintegration raises the ionic entropy because one nucleus becomes 14. The collapse is approximately adiabatic so total entropy is constant.Thus se = stot - sion must decrease

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Electron

Page 54: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

Appendix 1: The solution ofreaction networks.

Page 55: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

Consider the reaction pair:

dY1

dt=−Y

1+ Y

2

dY2

dt= Y

1− Y

2

An explicit solution of the linearized equations would be

Ynew

=Yold+δY where

δY1= (−Y

1+ Y

2) Δt

δY2= (Y

1− Y

2) Δt

In the usual case that the two species were not in equlibrium

Y1λ

1≠ Y

2, a large time step, Δt →∞, would lead to a

divergent value for the change in Y, including negative values.

For large ∆t, the answer could oscillate.

Page 56: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

On the other hand, forward or "implicit" differencing would giveδY1

Δt= − Y1 +δY1( )λ1 +   Y2 +δY2( )λ2

δY2

Δt= − Y2 +δY2( )λ2 +   Y1 +δY1( )λ1

δY11Δt

+ λ1⎛⎝⎜

⎞⎠⎟ +δY2 −λ2( ) = −Y1λ1 + Y2λ2

δY1 −λ1( ) +δY21Δt

+ λ2⎛⎝⎜

⎞⎠⎟ = Y1λ1 − Y2λ2

Add equations ⇒ δY1= −δY2; substituting, one also has :

δY1=Y2λ2 −Y1λ1

1 / Δt + λ1+ λ2

⎛⎝⎜

⎞⎠⎟

(if 1/Δt >> λ, same as the explicit solution)

Even if Δt →∞ the change in Y is finite and tends tothe equilibrium value Y1λ1=Y2λ2

In general an n x n matrix

n = 2 here

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Appendix 2: Energy generation during silicon burning

Page 58: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

This is very like neon burning except that 7 alpha-particlesare involved instead of one.

Page 59: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

Reaction rates governing the rate at which silicon burns:

Generally speaking, the most critical reactions will be those connecting equilibratednuclei with A > 24 (magnesium) with alpha-particles. The answer depends ontemperature and neutron excess:

Most frequently, for η small, the critical slow link is 24Mg(γ,α)20Ne

The reaction 20Ne(γ,α)16O has been in equilibrium with 16O(α,γ)20Ne ever since neon burning. At high temperatures and low Si-mass fractions,20Ne(α,γ)24Mg equilibrates with 24Mg(γ,α)20Ne and 16O(γ,α)12C becomesthe critical link.

However for the values of η actually appropriate to silicon burning ina massive stellar core, the critical rate is 26Mg(p,α)23Na(p,α)20Ne

Page 60: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

To get 24Mg

To get a

Page 61: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for
Page 62: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for
Page 63: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for
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3. Appendix on Entropy

Page 65: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

T

S = k log W

ZentralfriedhofVienna, Austria

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41

3

AN kT

P aTρ

µ= +

3/ 2 3 3/ 2( / ) /( / )T T Tρ ρ =

for ideal gas plus radiation

dividing by k makes s dimensionless

As discussed previously

Page 67: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

34 4

2

34 4

2 3

3

3

rad

Eg., just the radiation part

1/

4 1 1

3

4 1

3

44

3

4

3

4So S

3

V

T dS d PdV

aTT dS dT aT d aT dV

aTdT aT dV aT dV

dS aT V dT aT dV

d aT V

aT

ρε

ρρ ρ

ρ

ρ

≡= +

⎛ ⎞= + − +⎜ ⎟

⎝ ⎠

= + +

= +

⎛ ⎞= ⎜ ⎟

⎝ ⎠

⎛ ⎞= ⎜ ⎟⎝ ⎠

Page 68: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

Cox and Guili(24.76b)

expressionCox and GuiliPrinciples of Stellar StructureSecond editionA. Weiss et alCambridge Scientific Publishers

ReifFundamentals of Statisticaland Thermal PhysicsMcGraw Hill

Page 69: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

η=µ

kT

where µ, the chemical potential is defined by

T S =E + PV −µ N (CG10.20)

hence

Se

/V = (εeρ +P

e− µ n

e) / T

Se= ε

e+

Pe

ρ−µn

e

ρ⎛

⎝⎜⎞

⎠⎟/ T

Ye=

ne

ρ NA

se=S

e/ N

Ak =

εeρ +P

e

ρNAkT

⎝⎜⎞

⎠⎟−ηY

e

=5

2−η

⎛⎝⎜

⎞⎠⎟

Ye

η0

For an ideal gas

ε ρ + P=3

2+1

⎛⎝⎜

⎞⎠⎟ρN

AkT

Page 70: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

For a non-relativistic, non-degenerate electron gas,

Clayton 2-63 and 2-57 imply (for η<< 0)

ne=

2 2πmekT( )

3/2

h3

eη −

e2η

23/2+...

⎛⎝⎜

⎞⎠⎟

which implies

-η ≈ ln2 2πm

ekT( )

3/2

neh

3

⎣⎢⎢

⎦⎥⎥

which gives the ideal gas limit for electron entropy

(similar to ions but has Ye and m

e)

Page 71: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

For η>>1 (great degeneracy)

ne≈

8πc

3h

3kT( )

3 1

3η3 1+

π 2

η2

⎣⎢

⎦⎥

Pe≈

8π3c

3h

3kT( )

4 1

4η4 1+

2π 2

η2+

7π 4

15η4

⎣⎢

⎦⎥ P

e∝ n

e

4/3( )

Pe

nekT

≈1

1+2π 2

η2

1+π 2

η2

⎢⎢⎢⎢

⎥⎥⎥⎥

>>1

η π and keeping only terms in η−2

Pe

nekT

≈η4

1+2π 2

η2

⎝⎜⎞

⎠⎟1−

π 2

η2

⎝⎜⎞

⎠⎟⎡

⎣⎢⎢

⎦⎥⎥

≈η4

1+2π 2

η2−π 2

η2

⎝⎜⎞

⎠⎟=η4+π 2

Page 72: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

ue=3P

eη =

µ

kTµ ≈ε

F

Se

V= (u

e+ P

e− µ n

e) / T ≈

4Pe−µn

e( )T

≈n

ekT η +

π 2

η⎛

⎝⎜⎞

⎠⎟−ηn

ekT

T=π 2

nek

η

=π 2ρN

AY

ek

η

se=

Se

ρNAk≈π 2

Ye

η

se≈π 2

kTYe

εF

Page 73: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for
Page 74: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for

and negligible radiationpressure (entropy)

Page 75: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for
Page 76: Lecture 12 - Lick Observatorywoosley/ay220-19/lectures/lecture12.pdfAY NZY η ≥≥ ≥≥ ≈ ... (Si, S, Ar, Ca, etc.) into the most tightly bound nuclei (in the iron group) for