laminar premixed - detailed flame model
DESCRIPTION
flames types in combustion , laminar flameTRANSCRIPT
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Detailed Flame ModelIIT Kanpur
• Detailed chemical kinetic mechanism(elementary reactions)
• Not assuming temperature profile
• Solve using computer
∆∆
• Mass conservation: = 0 =
• 1-D
• Steady state
• Neglect KE and PE terms
• Pressure is constant
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Detailed Flame Model (Formulation)IIT Kanpur
• Species conservation ∆∆( ) ( ) ∆ =
, = constant (mass conservation) = + ,
bulk flow diffusion
+ , = For: 1, 2, …, N species
, = , bulkvelocity
speciesvelocity
∑diffusionalvelocity −velocity of individual species
relative to bulk velocity
for constant diffusivity−
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Detailed Flame Model (Formulation)IIT Kanpur
• Energy conservation ∆ 0, no heat loss
Tx Tx+x
[ ] [ ] ∆
0, no shaft work
ℎ + + ℎ + + ∆0, KE & PEneglected
0, KE & PEneglected
constant
heatflux
( ∆ − ) + (ℎ ∆ − ℎ ) = 0 + = 0 both conduction and additional enthalpy flux from diffusing species = − + ∑ , ℎheatflux
conductioncontribution
species diffusioncontribution , = − = − + ∑ − ℎ = − + ∑ ℎ − ∑ ℎ constant
ℎ
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Detailed Flame Model (Formulation)IIT Kanpur = − + ∑ ℎ − ℎ
+ = 0substitute in energy equation:
− + ∑ ℎ − + = 0− + ∑ + ∑ℎ = 0 (species conservation)− + ∑ = −∑ℎ ℎ = ℎ , + ∫ ,= ∫ , = ,− + ∑ , = −∑ℎ
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Detailed Flame Model (Formulation)IIT Kanpur − + ∑ , = −∑ℎ + ,− + ∑ + , , = −∑ℎ
constant (mass conservation)
+ − + ∑ , , = −∑ℎ − + ∑ , + ∑ , , = −∑ℎ
• Momentum conservation not required aspressure is assumed constant:
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DiffusionIIT Kanpur
, = , , + , ,ordinary diffusion due toconcentration gradient
thermal diffusion due totemperature gradient , = ,
, , = ∑mol fractionof species i
multicomponentdiffusion coefficient
not same as binarydiffusion coefficient
gradient ofspecies j
, = , , + , ,thermal diffusionvelocity
ordinary diffusionvelocity
• Multicomponent diffusion
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DiffusionIIT Kanpur = −
=matrix
= ∑ 1 − − 1 −number of species
binary diffusioncoefficient
, , = −thermal diffusioncoefficient
mass fractionof species i
• Thermal diffusion
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Boundary ConditionsIIT Kanpur
• Upstream: T(x -) = Tu and Yi(x -) = Yi,u
• Downstream: dT/dx (x +) = 0 and dYi/dx (x +) = 0
• is not known a priori and is part of the solution ( uVu = uSL)
• The domain: - < x < + is actually only ~cms
• Explicitly fix the coordinate system to move with the flame: T(x1) = T1
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Detailed Flame ModelIIT Kanpur
• Ideal-gas equation of state
• Relations for diffusion velocities (vi,diff)
• Temperature dependent species properties: hi(T), cp,i(T), ki(T) & DBij(T)
• Detailed chemical kinetic mechanism to obtain the • Interconversion relations for Xis, Yis and [Ci]s
• Assumption: no radiation, no KE and PE terms, constant pressure
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ResultsIIT Kanpur
Methane-Air ( = 1)
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ResultsIIT Kanpur Methane-Air ( = 1)