laboratory characterization of municipal solid waste incineration ash sita marie syal, mohammad...

1
Laboratory Characterization of Municipal Solid Waste Incineration Ash Sita Marie Syal, Mohammad Kabalan, Matt Hambright, and Dr. Dimitrios Zekkos, P.E. Department of Civil and Environmental Engineering, University of Michigan Objectives The objective of this study is to characterize the physical and mechanical properties of municipal solid waste incineration (MSWI) ash. MSWI ash consists of bottom and fly ash. The mixture of the two is known as combined ash. Careful characterization of the ash may lead to a more efficient design of monofills, and to possible reuse in major civil infrastructure such as levees, highways, and embankments. The study consists of: a) A literature review of the characteristics of the MSWI ash b) Testing of samples of ash from Carleton Farms Landfill in Michigan Surface Morphology using Scanning Electron Microscopy SEM uses an electron beam to form a detailed morphological image of the material particles Electron beams are focused and deflected when they come in contact with a specimen. The deflected electrons are detected to produce images such as those seen here. These images of an MSWI ash sample were taken on the FEI Quanta 200 3D at the Electron Microbeam Analysis Laboratory at the University of Michigan. The following observations can be made: Bottom ash is porous, sub-angular to angular. These physical characteristics suggest relatively high frictional characteristics Ash Sample 2: Retained in Sieve No. 20 Mag: 48x 300 30 3 0 .3 0.03 0 20 40 60 80 100 P I T e s tin g 2 0 1 0 -1 1 S a m p le 1 S a m p le 2 S a m p le 3 S a m p le 4 F ly A sh T ra v a r e t a l. (2 009) C h a n g a n d W e y (2 0 0 6 ) C h a n g a n d W e y (2 0 0 6 ) C h a n g a n d W e y (2 0 0 6 ) G o h a n d T a y (1 9 9 3 ) G o h a n d T a y (1 9 9 3 ) T a y a n d G o h (1 9 9 1 ) C o m b in e d A sh T ra v a r e t a l. (2 009) F o rre s te r a n d G o o d w in (1 9 9 0 ) F o rre s te r a n d G o o d w in (1 9 9 0 ) P I's T e stin g P e rc e n t P a ssin g (% ) P a rtic le S iz e (m m ) B o tto m A sh B e rg a n d N e a l (1 998) T ra v a r e t a l. (2 009) Z w a h r (2 004) Fo rre s te r a n d G o o d w in (1 9 9 0 ) Iz q u ie rd o e t a l. (2 001) Iz q u ie rd o e t a l. (2 001) Iz q u ie rd o e t a l. (2 001) T a y a n d G o h (1 9 9 1 ) Z h a n g e t a l. (1 999) D e m a rs e t a l. (1 993) FL IT (re p o rt 1 9 9 9 )-P in e lla s C o u n ty FL IT (re p o rt 1 9 9 9 )-K e y W est FL IT (re p o rt 1 9 9 9 )-W e s t P a lm Beach P a n d e lin e e t a l. (1 997) P a n d e lin e e t a l. (1 997) G re ss e t a l. (1 992) Sieve Analysis (ASTM C-136) This test method is used to evaluate the grain size distribution of particulate materials. The Grain Size Distribution curves for each type of ash (bottom, fly and combined) exhibit some, but not extreme, variability. Fly ash is finer than bottom ash. Data in the literature as well as experimental data from this study suggest the MSWI ash classifies as a “well graded sand” with some gravel or silt. As a consequence, it could be used as a fill material. Proctor Compaction (ASTM D-1557, ASTM D-698) This test method is used to determine the compaction characteristics (density and moisture) of particulate materials. Bottom ash (red) tends to have higher dry density values than the finer combined ash (blue). The Modified Proctor Compaction curves for each type of ash (bottom and combined) show variability in optimum dry densities that is comparable to natural soils. Specific Gravity Specific gravity values of the MSWI ash in the literature suggest values ranging between 1.5 and 2.5 Specific gravity values of the MSWI ash tested as part of this study suggest values ranging between 2.1 and 2.6. These relatively low values, suggest that the MSWI ash could be used as lightweight fill. Consolidated Drained Triaxial Test(ASTM D-4767) This test method is used to determine the shear strength of earth materials. The triaxial test data suggest a cohesion c=52.5 kPa (7.6 psi) and a friction angle φ=45 o . These results indicate a high strength material, making it attractive for reuse as a fill. Also, slopes of monofills may be stable at steeper slopes than those used in Subtitle D landfills. Conclusions MSWI ash has: Low specific gravity Moderate variability in properties Coarse surface morphology Grain size distribution of a well graded sand No plasticity of fines High shear strength. Thus, MSWI ash properties seem to have attractive physical and mechanical characteristics for reuse in civil infrastructure Monofill ash capacity may be higher than previously expected, as the ash seems to be a strong material. Environmental considerations related to the reuse of the MSWI ash in civil infrastructure need to be considered. Ash Sample 2: Retained in Sieve No. 20 Mag: 769x Organic Content (ASTM D-2974) This test method is used to evaluate the amount of organics present in the particulate material. Organic content is measured by heating a sample from 110 o C to 440 o C and measuring the amount of material loss. Organic content values were generally between 1.5% and 2.6% Acknowledgments The authors are grateful to Mr. Matt Neely from Republic Services for providing support to the field activities and sample collection at Carleton Farms Landfill. Procedures and Results 0 5 10 15 0 250 500 750 1000 1250 1500 N o m oistu re γ d = 13 .4 -13 .7 kN /m 3 D e via to r S tre ss (K Pa) A xia lS tra in (% ) σ 3 =50 kP a σ 3 =100 kP a σ 3 =200 kP a M o d ifie d P ro cto r B o tto m A sh Fo rreste r & G oodw in (1 9 9 0 ) Izq u ierd o et a l (2 0 0 1 ), M a tero Izq u ierd o et a l (2 0 0 1 ), S an t A d ria Pa n d elin e e t a l (1 9 9 7 ) Pa n d elin e e t a l (1 9 9 7 ) D em ars e t a l (1 9 9 3 ) D em ars e t a l (1 9 9 3 ) D em ars e t a l (1 9 9 3 ) C h e sn e r a n d E ig h m y (1989) C om b in e d A sh Fo rreste r & G oodw in (1 9 9 0 ) C h e sn e r a n d E ig h m y (1989) T h is stu d y (S am p le # 4) S ta n d a rd P ro cto r Pa n d elin e e t a l (1 9 9 7 ) B A G e o syn te c (2 0 0 4 ) Pa n d elin e e t a l (1 9 9 7 ) B A Izq u ierd o et a l (2 0 0 1 ) S an t A d ria Izq u ierd o et a l (2 0 0 1 ) M ate ro T h is stu d y (S am p le # 2) T h is stu d y (S am p le # 3) T h is stu d y (S am p le # 4) C om p actio n C urves D ry D en sity (p cf) M o istu re C o n ten t (% ) 0 10 20 30 40 80 100 120 140

Upload: amber-biglin

Post on 15-Dec-2015

217 views

Category:

Documents


0 download

TRANSCRIPT

Page 1: Laboratory Characterization of Municipal Solid Waste Incineration Ash Sita Marie Syal, Mohammad Kabalan, Matt Hambright, and Dr. Dimitrios Zekkos, P.E

Laboratory Characterization of Municipal Solid Waste Incineration Ash

Sita Marie Syal, Mohammad Kabalan, Matt Hambright, and Dr. Dimitrios Zekkos, P.E.

Department of Civil and Environmental Engineering, University of Michigan

Objectives

The objective of this study is to characterize the physical and mechanical properties of municipal solid waste incineration (MSWI) ash. MSWI ash consists of bottom and fly ash. The mixture of the two is known as combined ash.

Careful characterization of the ash may lead to a more efficient design of monofills, and to possible reuse in major civil infrastructure such as levees, highways, and embankments.

The study consists of:a) A literature review of the characteristics of the MSWI ashb) Testing of samples of ash from Carleton Farms Landfill in Michigan

Surface Morphology using Scanning Electron Microscopy

• SEM uses an electron beam to form a detailed morphological image of the material particles

• Electron beams are focused and deflected when they come in contact with a specimen. The deflected electrons are detected to produce images such as those seen here.

• These images of an MSWI ash sample were taken on the FEI Quanta 200 3D at the Electron Microbeam Analysis Laboratory at the University of Michigan. The following observations can be made:

• Bottom ash is porous, sub-angular to angular.

• These physical characteristics suggest relatively high frictional characteristics

Ash Sample 2: Retained in Sieve No. 20 Mag: 48x

300 30 3 0.3 0.03

0

20

40

60

80

100

PI Testing 2010-11 Sample 1 Sample 2 Sample 3 Sample 4

Fly Ash Travar et al. (2009) Chang and Wey (2006) Chang and Wey (2006) Chang and Wey (2006) Goh and Tay (1993) Goh and Tay (1993) Tay and Goh (1991)

Combined Ash Travar et al. (2009) Forrester and Goodwin (1990) Forrester and Goodwin (1990) PI 's Testing

Perc

ent

Passin

g (

%)

Particle Size (mm)

Bottom Ash Berg and Neal (1998) Travar et al. (2009) Zwahr (2004) Forrester and Goodwin (1990) Izquierdo et al. (2001) Izquierdo et al. (2001) Izquierdo et al. (2001) Tay and Goh (1991) Zhang et al. (1999) Demars et al. (1993) FL IT (report 1999)-Pinellas County FL IT (report 1999)-Key West FL IT (report 1999)-West Palm Beach Pandeline et al. (1997) Pandeline et al. (1997) Gress et al. (1992)

Sieve Analysis (ASTM C-136)This test method is used to evaluate the grain size distribution of particulate

materials.

• The Grain Size Distribution curves for each type of ash (bottom, fly and combined) exhibit some, but not extreme, variability.

• Fly ash is finer than bottom ash.• Data in the literature as well as experimental data from this study suggest

the MSWI ash classifies as a “well graded sand” with some gravel or silt. • As a consequence, it could be used as a fill material.

Proctor Compaction (ASTM D-1557, ASTM D-698)This test method is used to determine the compaction characteristics

(density and moisture) of particulate materials.

• Bottom ash (red) tends to have higher dry density values than the finer combined ash (blue).

• The Modified Proctor Compaction curves for each type of ash (bottom and combined) show variability in optimum dry densities that is comparable to natural soils.

Specific Gravity• Specific gravity values of the MSWI ash in the literature suggest values

ranging between 1.5 and 2.5• Specific gravity values of the MSWI ash tested as part of this study suggest

values ranging between 2.1 and 2.6. • These relatively low values, suggest that the MSWI ash could be used as

lightweight fill.

Consolidated Drained Triaxial Test(ASTM D-4767)This test method is used to determine the shear strength of earth

materials.

• The triaxial test data suggest a cohesion c=52.5 kPa (7.6 psi) and a friction angle φ=45o.

• These results indicate a high strength material, making it attractive for reuse as a fill. Also, slopes of monofills may be stable at steeper slopes than those used in Subtitle D landfills.

Conclusions• MSWI ash has:

• Low specific gravity • Moderate variability in properties• Coarse surface morphology• Grain size distribution of a well graded sand• No plasticity of fines• High shear strength.

• Thus, MSWI ash properties seem to have attractive physical and mechanical characteristics for reuse in civil infrastructure

• Monofill ash capacity may be higher than previously expected, as the ash seems to be a strong material.

• Environmental considerations related to the reuse of the MSWI ash in civil infrastructure need to be considered.

Ash Sample 2: Retained in Sieve No. 20 Mag: 769x

Organic Content (ASTM D-2974)This test method is used to evaluate the amount of organics present in the

particulate material.• Organic content is measured by heating a sample from 110oC to 440oC and

measuring the amount of material loss. • Organic content values were generally between 1.5% and 2.6%

Acknowledgments• The authors are grateful to Mr. Matt Neely from Republic Services for

providing support to the field activities and sample collection at Carleton Farms Landfill.

Procedures and Results

0 5 10 150

250

500

750

1000

1250

1500No moisture

γd=13.4-13.7 kN/m3

De

via

tor

Str

ess

(K

Pa

)

Axial Strain (%)

σ3=50 kPa

σ3=100 kPa

σ3=200 kPa

Modified ProctorBottom Ash

Forrester & Goodwin (1990) Izquierdo et al (2001), Matero Izquierdo et al (2001), Sant Adria Pandeline et al (1997) Pandeline et al (1997) Demars et al (1993) Demars et al (1993) Demars et al (1993) Chesner and Eighmy (1989)

Combined Ash Forrester & Goodwin (1990) Chesner and Eighmy (1989) This study (Sample #4)

Standard Proctor Pandeline et al (1997) BA Geosyntec (2004) Pandeline et al (1997) BA Izquierdo et al (2001) Sant Adria Izquierdo et al (2001) Matero This study (Sample #2) This study (Sample #3) This study (Sample #4)

Compaction Curves

Dry

Densi

ty (

pcf

)

Moisture Content (%)

0 10 20 30 40

80

100

120

140