l11-evaluating production performancecvd
TRANSCRIPT
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Termodinamica de
Hidrocarburos
Maria A. Barrufet
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Sketch of a
Production
Mechanism
for a Gas
Condensate
Constant Volume Depletion (CVD)
Pi = Initial Reservoir Pressure
T = Reservoir Temperature
Vi = Reservoir Pore Volumezi = Initial Reservoir Fluid Composition
(Gas Condensate)
(1)
1. Mass in place (either in moles or pounds)
Given
Pi =3,000
psia
P1 = 2,800 P1= 2,800 P2 = 2,500
np1np2
Vp1Vp2
( zi)o ( zi)1
( yi)2
( xi)2
( yi)
1
( x i) 1
Vi V1= Vi + Vp1 Vi V2= Vi + Vp2
V1= VL1+ VG1 V2= VL2+ VG2
ni = P iVi/zRT
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Sketch of a
Production
Mechanism
for a Gas
Condensate
V
( y i)n
( x i) n
( z i)n-1
pnnpn
Target for gascycling
End of Depletion
Constant Volume Depletion of a Conden sate Reservoir (cont.)
At any depletion stage need:
Moles and composition of liquid phase (n l , x i's)
Moles of gas phase formed (n v, y i's)
Comp ressibility factor of the liquid phase, zl
Comp ressibility factor of the gas phase, zv
n zi= yinv+ xinlFrom flash calculations
VG=nvzv RT
P
VL=nlzl RT
P
From EOS
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Simulation of a Constant
Volume Depletion (CVD) Test
for a Gas Condensate or aVolatile Oil Using an EOS
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CVD with EOS
Numerical Example of a CVD. The
data required for the EOS for this
calculation are,initial fluid compositions
reservoir temperature
initial pressure and pressure depletion
stage
The production data required are
Pressures and Gp.
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Flow chart
for asimulated
CVD test
Given Reservoir Fluid CompositionTemperature, Dew Point PressureControl parameters
Determine Moles ofGas to be produced
Recombine RemainingPhases
Calculate initialnumber of moles
Drop pressure below Pd
Select Hydrocarbon Pore
Volume
Flow Diagram for simulating a CVD
P = P - P
Calculate TotalVolume
Evaluate Flash
Calculate Volume ofCondensate
Calculate Volume of
Gas
Flash to SC
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z (liquid)z(vapor)
z(2 phase)
P/ z = 4055 -1.0578e-05 Gp (Correct two-phase z)
P/ z = 4055 -8.1097e-06 Gp (z = z liquid)
P/ z = 4055-1.6219e-05
What's the "two-phase" z-factor?
From the EOS (Equation of state ) will have three roots. The largest Vcorresponds to the vapor and the smallest to the liquid.
VL=nlzl RT
P
Vv =nvzv RT
P
PVvRT
= zv= f (P, T, yi's)
PVLRT
= zl = f (P, T, xi's)
z2= nvn zv + nln zl z2 = PVini-npRT
or
5e+84e+83e+82e+81e+80e+00
1000
2000
3000
4000
5000
Gp
P/z
2
Gp (z = z vapor)
Estimation of Reserves: Simpson's Condensate Field
z (liquid)z(vapor)
z(2 phase)
P/ z = 4055 -1.0578e-05 Gp (Correct two-phase z)
P/ z = 4055 -8.1097e-06 Gp (z = z liquid)
P/ z = 4055-1.6219e-05
What's the "two-phase" z-factor?
From the EOS (Equation of state ) will have three roots. The largest Vcorresponds to the vapor and the smallest to the liquid.
VL=nlzl RT
P
Vv =nvzv RT
P
PVvRT
= zv= f (P, T, yi's)
PVLRT
= zl = f (P, T, xi's)
z2= nvn zv + nln zl z2 = PVini-npRT
or
5e+84e+83e+82e+81e+80e+00
1000
2000
3000
4000
5000
z (liquid)z(vapor)
z(2 phase)
P/ z = 4055 -1.0578e-05 Gp (Correct two-phase z)
P/ z = 4055 -8.1097e-06 Gp (z = z liquid)
P/ z = 4055-1.6219e-05
What's the "two-phase" z-factor?
From the EOS (Equation of state ) will have three roots. The largest Vcorresponds to the vapor and the smallest to the liquid.
VL=nlzl RT
P
Vv =nvzv RT
P
PVvRT
= zv= f (P, T, yi's)
PVLRT
= zl = f (P, T, xi's)
z2= nvn zv + nln zl z2 = PVini-npRT
or
5e+84e+83e+82e+81e+80e+00
1000
2000
3000
4000
5000
Gp
P/z
2
Gp (z = z vapor)
Estimation of Reserves: Simpson's Condensate Field
Differences in the
estimation of
reserves using
three different
compressibility
factors
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CVD for Near Critical Fluids
For every pressure depletion stage PVT
simulators provide
Moles produced (gas or liquid, or both)
Z factors (gas, liquid, 2-phase)
Gas & liquid
Compositions
DensitiesViscosities
Interfacial tensions
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Examples from PVTi
Output file with PVT calculations has
extension *.mes . Only portions shown here
CVD for a volatile oil at 176 oFSome experimental data provided
CVD for a Gas condensate at 250 oF
No experimental data given
http://localhost/var/www/apps/conversion/tmp/scratch_2/L11-CVDoil176.txthttp://localhost/var/www/apps/conversion/tmp/scratch_2/L11-CVDoil176.txthttp://localhost/var/www/apps/conversion/tmp/scratch_2/L11-CVDoil176.txthttp://localhost/var/www/apps/conversion/tmp/scratch_2/L11-CVDgascon250.txthttp://localhost/var/www/apps/conversion/tmp/scratch_2/L11-CVDgascon250.txthttp://localhost/var/www/apps/conversion/tmp/scratch_2/L11-CVDgascon250.txthttp://localhost/var/www/apps/conversion/tmp/scratch_2/L11-CVDgascon250.txthttp://localhost/var/www/apps/conversion/tmp/scratch_2/L11-CVDgascon250.txthttp://localhost/var/www/apps/conversion/tmp/scratch_2/L11-CVDgascon250.txthttp://localhost/var/www/apps/conversion/tmp/scratch_2/L11-CVDoil176.txthttp://localhost/var/www/apps/conversion/tmp/scratch_2/L11-CVDoil176.txthttp://localhost/var/www/apps/conversion/tmp/scratch_2/L11-CVDoil176.txt -
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CVD for Near Critical Fluids
For every pressure depletion stage
MOST simulators DO NOT PROVIDE
How moles produced separate at surface
Gas produced in MSCF
Oil Produced in STB
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Need to Complete Evaluation
nt, Pav, T
Oil Volume (STB),
no, Psu rface,
Tsurface
Gas Volume (MSCF),
ng, Psurf ace, Tsu rface
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What do we get with this?
A good estimate of the potential of your
reservoir
Could design separator stages to
obtain more liquid
Estimates of recovery factors for oil &
gas as a function of average reservoir
pressure
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Learning Objectives
Understand the production mechanismsfor a gas condensate or a volatile oil(Constant Volume Depletion, CVD)
Interpret the results of a simulated CVDtest from a commercial simulator
Determine oil and gas recoveries
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Worked Out Example:
Simulation of a ConstantVolume Depletion (CVD) Test
for a Gas Condensate or a
Volatile Oil Using an EOS
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Numerical Example of a CVD
Data required for the EOS for this
calculation include
initial fluid compositions
reservoir temperature
initial pressure and pressure depletion stage
When calibrating the EOS, given a certain
reservoir size need to match productiondata (Gp and Np)
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Component Mole %
C1 75.2
C2 7.7
C3 4.4C4 3.1
C5 2.2
C6 2.3
C7 2.099C8 1.235
C9 0.727
C10+
1.039
Initial gascondensate
composition
CVD Example
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Summary Results Gas
Condensate CVD at T=195F
CVD Results Z - Factor Gas Viscosity
P(psi)100
d
l
V
V100
t
p
n
n100
t
p
n
nz
g
z2
)( cPg
m
2,960 0 0 0 0.779 0.030
2,500 14.02 14.4 14.4 0.799 0.769 0.023
2,000 14.42 16.6 31.0 0.825 0.763 0.019
1,500 12.96 16.7 47.7 0.855 0.755 0.0161,000 11.09 16.5 64.2 0.891 0.735 0.015
500 8.93 16.0 80.2 0.933 0.665 0.013
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Gas produced properties for each
depletion stage (T = 195o
F )P (psi) 2,960 2,500 2,000 1,500 1,000 500Mole% 100 85.197 83.176 82.484 81.745 80.627
~Vv(f t/mol) 1.848 2.246 2.897 4.005 6.259 13.103
V
V
v
t
% 100 88.1 88.6 90.5 92.9 95.8
rg(lb/f t) 14.881 10.924 7.949 5.574 3.557 1.783
Zg 0.7787 0.7994 0.8249 0.8553 0.891 0.9327
mg
(cP) 0.0303 0.0226 0.0186 0.0162 0.0146 0.0135
Mwg 27.50 24.54 23.03 22.33 22.26 23.36
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Produced Gas Compositions after each
depletion stage at 195F to flash at
standard conditions
P (psi) 2,960 2,500 2,000 1,500 1,000 500
C1 75.2 78.84 80.695 81.403 81.021 78.595
C2 7.7 7.65 7.697 7.834 8.071 8.406C3 4.4 4.153 4.062 4.105 4.322 4.857
C4 3.1 2.743 2.56 2.518 2.664 3.244
C5 2.2 1.806 1.576 1.471 1.516 1.943
C6 2.3 1.731 1.386 1.194 1.159 1.485
C7
2.099 1.45 1.057 0.832 0.745 0.914C8 1.235 0.782 0.521 0.376 0.313 0.364
C9 0.727 0.41 0.242 0.157 0.118 0.126
C10+
1.039 0.435 0.203 0.11 0.071 0.067MwC10
+153.8 147.7 144.7 142.9 141.6 140.7
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CVD ExampleOutput needed
From the EOS information we can
calculate the following terms:
Initial Gross Gas in Place (MSCF/ac-ft)Initial Residue Gas in Place (MSCF/ac-
ft)
Initial Oil in Place (STB/ac-ft)
Increments of Gross Gas Production
(MSCF/ac-ft)
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CVD ExampleOutput needed
Cumulative gross gas production(MSCF/ac-ft
Residue gas in each increment
(MSCF/ac-ftCumulative residue gas in eachpressure stage (MSCF/ac-ft
Liquid produced in each pressure stage
(STB/ac-ftCumulative liquid produced in eachpressure stage (STB/ac-ft)
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CVD ExampleOutput needed
Average Gross Gas-Oil-Ratio in Each
Pressure Stage (SCF/bbl)
Average Residue Gas-Oil-Ratio in
Pressure Stage(SCF/bbl)Cumulative Gross Gas Recovery
Percentage
Cumulative Residue Gas RecoveryPercentage
Cumulative Liquid Recovered Percentage
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CVD ExampleOutput needed
These terms will be described as we
move along
Quantities will be evaluated per acre
foot of net bulk reservoir rock.
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CVD ExampleSolution
The hydrocarbon pore volume per acre
foot is
f tac
f t
,..,V
S,V
HC
iwHC
3
534625012056043
156043
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CVD ExampleSolution
Step 1:
Calculate the initial number of moles
(nt) based upon the hydrocarbonpore space per acre foot. Then,
evaluate the number of moles and
cumulative number of moles
produced at each pressure stage.
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Using VHC as a base volume.
The number of moles contained in this
hydrocarbon pore volume is
CVD ExampleSolution
R
RRt
HCP
RTZnV
RR
RHC
tRTZ
PVn
ftac
molelb.,
..
,,
RTZ
PVn
RR
RHC
t 585323
65573107790
96025346
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CVD ExampleSolution
The number of moles produced at P
=2,500 psia (1stdepletion stage is)
f tac
molelb..,.nfn
tpp 6919508582953231440
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CVD ExampleSolution
Step 2:
Calculate the Initial Gross Gas in
Place per ac-ft, then evaluate theincrements of Gross Gas Production
(MSCF/ac-ft) and Cumulative Gross
Gas Production (MSCF/ac-ft)
produced after each pressure stage.
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CVD ExampleSolution
The Initial Gross Gas in Place
expressed in MMSCF/ac-ft is
714
520731058295323
.
..,
P
RTnG
SC
SCt
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CVD ExampleSolution
Note that the standard molar volume
of an ideal gas has been taken as
520 R (60 F) and 14.7 psia.
mollb/SCF..
.
P
RTV~
SC
SC
sc 5643379
714
5207310
f tac
MSCF,
feetac
SCF,,G 34118433401
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CVD ExampleSolution
The Gross Gas Production at each
pressure stage is evaluated as
where fpis the fraction of molesproduced (see summary table)
GfGpp
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CVD ExampleSolution
At P = 2,500 psia
Proceed with all the other pressures
and fill the corresponding columnsin the following table:
f tac
MSCF
.,.GfG pp 0819334111440
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CVD ExampleSolution
P(psi) np np Gp Gp GRP GRP NpNp GOR
2960 0 0 0
2500 508.69 508.69 193.08 193.08
20001500
1000
500
Here is the tricky part
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CVD ExampleSolution
Step 3:
Evaluate the Initial Residue Gas inplace (MSCF/ac-ft) and the Initial Oilin Place (STB/ac-ft).
Note that these terms are usually expressed indifferent units!
NGGR
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CVD ExampleSolution
To evaluate these quantities we need
to flash the initial number of moles
with initial gas composition tostandard conditions.
Fl h lt f d t
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Flash results of gas condensate
initial composition
to 14.7 psia and 60oFProperty Total Vapor Liquid
Mole% 100 94.983 5.017
V~ (ft/mol) 358.755 377.573 2.503
r (lb/ft) 0.077 0.061 43.706
Z 0.9458 0.9954 0.0066m(cP) 0.0103 0.5083Mw 27.5 23.18 109.4
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Gas and liquid Compositions from
flashing initial mixture to 14.7 psia and
60oF
Component Initial Vapor LiquidC1 75.2 79.147 0.47C2 7.7 8.09 0.31
C3 4.4 4.596 0.688C4 3.1 3.168 1.812C5 2.2 2.081 4.446C6 2.3 1.728 13.123
C7
2.099 0.86 25.56C8 1.235 0.258 19.741C9 0.727 0.056 13.428
C10+
1.039 0.015 20.423MwC10
+153.8 137.5 154
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CVD ExampleSolution
the Initial Residue Gas per acre-feet
is:
f tac
MSCF.,,.GfG
vR 7227313411949830
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CVD ExampleSolution
and the Initial Liquid in Place is
f tac
SCF.N
..,.V~nfNotl
6059443
503258295323050170
f tac
STB.
.
.N 0178796145
6059443
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CVD ExampleSolution
Step 4: Evaluate the following properties
Residue Gas produced (GRP) in each pressure
stage (MSCF/ac-ft)
Cumulative Residue Gas in each pressure
stage(MSCF/ac-ft)
Liquid produced (Np
)
in each pressure stage
(STB/ac-ft)
Cumulative Liquid Produced in each pressure
stage (STB/ac-ft)
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CVD ExampleSolution
This requires flashing the number of
moles of gas produced in each
depletion stage to standardconditions
Next see an example at 2,500 psi,
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Flash results to 14.7 psia and 60 oF from
the gas produced at P = 2,500 psia
Property Total Vapor Liquid
Mole% 100 97.534 2.466
V~ (ft/mol) 368.436 377.687 2.553
r (lb/ft) 0.067 0.059 44.209
Z 0.9714 0.9957 0.0067
m(cP) 0.0104 0.5396
Mw 24.68 22.45 112.88
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Compositions
of the gas and
the liquidobtained from
flashing the gas
produced at
2,500 psia
Component Total Vapor Liquid
C1 78.84 80.821 0.477
C2 7.65 7.836 0.3C3 4.153 4.242 0.634
C4 2.743 2.772 1.584
C5 1.806 1.757 3.753
C6 1.731 1.489 11.306
C7 1.266 0.741 22.039
C8 0.745 0.26 19.936
C9
0.439 0.064 15.27C10
+
0.627 0.018 24.701
MwC10+
153.8 137.5 154.3
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CVD ExampleSolution
The residue gas and the liquid produced
are evaluated as
Example at P = 2,500 psia
pvRP GfG oplp V~nfN
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CVD ExampleSolution
The residue gas
pvRP GfG
f tac
MSCFG
RP3196.188081.19397534.0
at P = 2,500 psia is
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CVD ExampleSolution
The liquid produced
oplp V~
nfN
f tac
SCFN
p0256.3255
3
.269.50802466.0
f tac
STBN
p -== 7046.5
614.5
0256.32
at P = 2,500 psia is
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CVD ExampleSolution
Cumulative values are obtained just
by adding the results obtained from
each stageYou will have an exercise of this
nature using an output from a
simulator
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CVD ExampleSolution
Step 5:
Evaluate the following
Average Gross Gas-Oil-Ratio in Each Pressure
Stage (SCF/STB)Average Residue Gas-Oil-Ratio in PressureStage(SCF/STB)
Gross Gas and Cumulative Gross Gas
Recovery PercentageResidue Gas and Cumulative Residue GasRecovery Percentage
Liquid Recovery and Cumulative LiquidRecovery Percentage
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CVD ExampleSolution
The Average Gross Gas-Oil-Ratio,
and the Average Residue Gas-Oil-
Ratio in Each Pressure Stage(SCF/STB) are evaluated as
p
p
N
G
GOR pRP
R N
GGOR
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CVD ExampleSolution
The Gross Gas and Residue Gas
Recovery Percentages are
The liquid recovery in each stage is
100G
GpGross
100
R
RP
GGGresid
100N
NNrec
p
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CVD ExampleSolution
for example at P = 2,500 psia
STB
SCF.,
.
.,GOR 5584633
70465
0081193
STB
SCF.,
.
.,GOR
R 901133
70465
6319188
7814100
722731
3196188.
.,
.Gresid
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CVD ExampleSolution
for example at P = 2,500 psia
STB
SCF.,
.
.,GOR
R 901133
70465
6319188
4141003411
081193.
,
.Gross
227100
017879
70465.
.
.Nrec
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CVD ExampleSolution
Steps 1 to 5 are repeated for all the
depletion pressures, and the
cumulative values are calculated
From a CVD simulated test
properties of the liquid remaining inthe reservoir are also reported.
These can be used for gas cycling
projects.
Properties of the liquid (oil) remaining in
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Properties of the liquid (oil) remaining in
the reservoir at 195oF after every
depletion stage (Condensate Good
Money).P (ps i) 2,960 2,500 2,000 1,500 1,000 500
Mole% 100 14.803 16.824 17.516 18.255 19.373
~
Vo(f t/mo l)1.848 1.75 1.852 1.982 2.149 2.381
V
Vl
t
% 100 11.9 11.4 9.5 7.1 4.2
ro(lb /f t) 14.881 25.476 28.402 31.069 33.657 36.364
Zo 0.7787 0.6229 0.5273 0.4232 0.3059 0.1695
mo (cP) 0.0303 0.0718 0.092 0.1158 0.1462 0.1891
Mwo 27.50 44.59 52.6 61.57 72.32 86.57
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Overall Composition changes
with pressure at 195oF
P (psi) 2,960 2,500 2,000 1,500 1,000 500
C1 75.2 75.2 74.586 73.118 70.465 65.611
C2 7.7 7.7 7.709 7.711 7.672 7.488
C3 4.4 4.4 4.442 4.533 4.67 4.83C4 3.1 3.1 3.16 3.304 3.556 3.967
C5 2.2 2.2 2.267 2.432 2.74 3.303
C6 2.3 2.3 2.396 2.639 3.101 3.994
C7 2.099 2.099 2.208 2.485 3.014 4.058
C8 1.235 1.235 1.312 1.501 1.862 2.574
C9 0.727 0.727 0.78 0.909 1.151 1.625
C10+
1.039 1.039 1.141 1.366 1.769 2.55
MwC10+
153.8 153.8 154.2 154.5 154.7 154.9
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CVD ExerciseUse PVTi
Use file provided VOLCON1.pvi
Evaluate two CVDs one at T = 220oF and at
T=260oF (volatile, condensate)
Use pressure stages of 500 psia and finalpressure of 1000 psia
Save gas compositions of every depletion
stage
Calculate the cumulative oil and gas
produced for each case and
http://localhost/var/www/apps/conversion/tmp/scratch_2/11.VOLCON1.PVIhttp://localhost/var/www/apps/conversion/tmp/scratch_2/11.VOLCON1.PVI -
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CVD ExerciseUse PVTi
Cumulative Gross Gas Production(MSCF/ac-ft)
Residue Gas in Each Increment(MSCF/ac-ft)
Cumulative Residue Gas in Each PressureStage (MSCF/ac-ft
Liquid Produced in Each Pressure Stage
(STB/ac-ftCumulative Liquid Produced in EachPressure Stage(STB/ac-ft)
Properties of the gas produced
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Properties of the gas produced
at 195 oF for each depletion
stageP (psi) 2,960 2,500 2,000 1,500 1,000 500Mole% 100 85.197 83.176 82.484 81.745 80.627
~Vv
(f t/mol) 1.848 2.246 2.897 4.005 6.259 13.103
V
V
v
t
% 100 88.1 88.6 90.5 92.9 95.8
rg
(lb/f t) 14.881 10.924 7.949 5.574 3.557 1.783
Zg 0.7787 0.7994 0.8249 0.8553 0.891 0.9327mg
(cP) 0.0303 0.0226 0.0186 0.0162 0.0146 0.0135
Mwg 27.50 24.54 23.03 22.33 22.26 23.36
Produced Gas Compositions after each
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p
depletion stage at 165F used to perform
the flash calculations at standard
conditionsP (psi) 2,960 2,500 2,000 1,500 1,000 500
C1 75.2 78.84 80.695 81.403 81.021 78.595
C2 7.7 7.65 7.697 7.834 8.071 8.406
C3 4.4 4.153 4.062 4.105 4.322 4.857C4 3.1 2.743 2.56 2.518 2.664 3.244
C5 2.2 1.806 1.576 1.471 1.516 1.943
C6 2.3 1.731 1.386 1.194 1.159 1.485
C7 2.099 1.45 1.057 0.832 0.745 0.914
C8 1.235 0.782 0.521 0.376 0.313 0.364C9 0.727 0.41 0.242 0.157 0.118 0.126
C10+
1.039 0.435 0.203 0.11 0.071 0.067MwC10
+153.8 147.7 144.7 142.9 141.6 140.7