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    CONCEPT DIAGRAM ("Mind Map") OF TOPICSome students find that memorizing the OUTLINE of a topic helps them learn and remember the concepts and

    important facts. As you proceed th rough the topic, come back to this page regularly to see how each b it f its the

    whole. At the end of the notes you will find a blank version of this "Mind Map" to practise on.

    History of

    Metal Use

    Metal

    Extraction

    Needs Energy

    Metal Reaction with

    Oxygen

    Water

    Acids

    The Activity Seriesof the Metals

    MetalsWe Use

    Today

    Chemical Activity

    of the

    Metals

    Electron Transfer

    REDOX

    Our Use of

    Metals

    Activity & Usage

    of Metals

    METALS

    Patterns

    of the

    Periodic Table

    History of the

    Periodic Table

    Extracting

    Metals

    from

    Ores

    QuantityCalculations

    Definition

    of the Mole

    Conductivity

    Melting Points Chemical Bonding

    Valency

    Reactivity

    Atomic Radius1st Ionization

    Energy

    Electronegativity

    Minerals

    Ores

    &

    Resources

    Case Study:

    Extracting

    Copper

    from its Ore

    Molar Ratios

    in

    Reactions

    The Case for Recycling

    Metals

    Gay-Lussac's Law

    &

    Avogadro's Hypothesis

    Mole Quantity

    Calculations

    Masses

    Gas Volumes

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    The First Uses of MetalsFor most of human existence, people used tools of stone,

    wood and bone. Primitive tribes were familiar with gold

    which occurs uncombined in nature, but it i s too soft to be

    useful for anything but jewellery and decoration.

    About 5,000 years ago, in the Middle East, some people

    accidentally discovered that if certain rocks were roasted by

    fire, small amounts of copper would be found later i n t he

    ashes. Copper is too soft to be reallyuseful, but there was

    a brief "Copper Age" around the eastern end of the

    Mediterranean Sea. Copper was used for decoration,

    jewellery, small utensils, and occasionally for knives and

    spear points.

    The big breakthrough was the discovery by these copper-

    using people that if they roasted copper-bearing rocks

    (ores) with tin ores, the resulting "alloy" (mixture) of

    copper and tin produced a much harder metal, "bronze",

    which could be cast in moulds, and hammered to shape

    many useful tools and weapons ... this was the start of

    The Bronze Age (approx 4,500 to 2,500 years ago)

    It is no accident that the rise of the great ancient

    civilizations occurred about this time. The stone blocks of

    the pyramids and temples of ancient Egypt were cut and

    shaped with bronze chisels. Egyptians, and later Greeks,

    dominated their world because their soldiers were armed

    with bronze swords, spears and arrowheads.

    With bronze tools they built better ships and wagons for

    transport and trade, which brought wealth and power.

    Sad as it might be, t he f acts of human history are that

    progress has been marked by conflict, war and conquest,

    and metals have been a vital part of that development.

    Metal has many advantages over stone, wood, or b one:

    metal is harder, stronger, and flexible, not brittle.

    metal can be cast, hammered or drawn into shapes not

    possible in stone, such as saw blades, swords and armour.

    when tools become blunt, metal can be re-sharpened.

    Basically, a warrior with a bronze sword always beats a

    bloke with a stone axe ... we call that progress!

    The Iron Age (approx. 2,500 to 1,500 years ago)

    About 1,000 B.C. the extraction of iron from its ores was

    discovered. This requires much higher temperatures, and

    t he br eakthrough was probably t he invention of t he

    bellows, a device to pump air into afurnace so the wood or

    charcoal burns hotter.

    Iron is stronger and harder than bronze. A warrior armed

    with iron weapons will usually beat a bronze-armed man.

    Iron t ools and even the humble nail allowed new

    developments in buildings, ships, wagons. .. remember that

    towns, trade and commerce givewealth and power. An iron

    plough allows more land to be cultivated to grow more

    food, to feed a bigger army... and so on.

    It is no accident that the dominant world power of this

    time was ancient Rome, because their technology was

    based on iron.

    From the Medieval to the Modern

    After the collapse of the Roman Empire the variouscultures that dominated the "Dark Ages" still had iron-

    based technologies.

    The next great technological change was the "Industrial

    Revolution" which b egan about 1750 in England. This

    had many aspects, but the big change in technology was the

    use of coal (instead of wood) for fuel. As well as steam

    engines, coal allowed for large scale smelting of iron and

    the invention of steel (an alloy of iron with carbon).

    The engines, tools and machinery of the great factories

    were based on steel. Transport was revolutionized by steel

    locomotives running on steel rails. Steel ships replaced

    wooden ones, and steel weapons (machine guns, tanks and

    artillery) achieved new heights (depths?) in warfare and

    mass destruction.

    In the 20th century, new metals and alloys became available...

    aluminium, titanium, chromium, and many more.

    This was made possible by electricity, which is needed in

    large amounts to extract some metals from their ores, or to

    purify and process them once extracted.

    Human Progress has always been linked

    to our use of Metals.

    Progress in metal usage has always been linked

    to the availability of energy to extract the metals.

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    The Metals We Use TodayIn one sense, we are still in the "Iron Age". Iron is still the

    metal we use the most, but nearly always it is mixed with

    other elements in a variety of alloys, notably steel.

    Steel isused for bridges, tools and machinery, bolts, screws

    and nails, reinforcing inside concrete structures, engines,

    vehicle bodies, trains and their rails, ships, and "tin" cans.

    Iron ore occurs in huge deposits, so iron is common and

    economical to produce.

    Steel (in its various forms) is very hard and strong.

    It can be cast, milled, rolled, worked, bent, cut and

    machined into just about any shape or size imaginable.

    As always, our usage of the different steel alloys is linked to

    their particular properties:

    Steel Iron, Properties Uses

    Alloy with ...

    Mild steel 0.2% strong, but car bodies,

    carbon malleable pipes, roofing

    Tool steel 1-1.5% very hard drills, knives,

    carbon hammers

    Stainless 20% nickel resists food utensils,Steel & chromium corrOSIon, medical tools

    hygenic

    Brass

    is a common "non-ferrous" (no iron) alloy.

    Brass is very hard, but easilymachined for screw threads, etc.

    It is more expensive than steel, but is corrosion resistant, so

    it is ideal for taps and fittings forwater and gas pipes.

    Solder

    is an alloy of 30-50% tin with lead.

    Its most notable property IS a very low melting point,

    around 150-200C.

    Its major use is in plumbing for sealing the joints between

    pipes,. and in electronics for connecting small components

    on a"circuit board".

    Metals That Are Used in Their Pure State

    Although we use a wide range of alloys, there are some

    important metals we use in their pure, elemental state.

    Aluminium

    is very lightweight, yet strong and corrosion resistant

    Its lightweight strength is perfect

    for aircraft construction.

    Lightweight and a good conductor,

    it is used for electricity power lines.

    Malleable and corrosion resistant, it

    is ideal for window frames and drink cans.

    Copper

    is used for electrical wiring in building s and appliances,

    because of its great electrical conductivity and its ductility

    for ease of wire-making.

    Metal Extraction Needs EnergyAs mentioned previously, our use of diff erent metals

    through history can be linked to the availability of energy.

    In topic 1, you learned about the process of chemical

    decomposition; where a compound breaks down intosimpler substances.

    Decomposition is generally an endothermic process;

    energy is absorbed by the reactants during the reaction.

    Generally, you must supply energy to make the process

    happen.

    Metal ores are mineral compounds. To obtain the elemental

    metal involves decomposition, which is endothermic and

    requires energy. Some compounds require more energy

    than others for decomposition.

    Copper and tin ores require little energy. A decent wood

    fire can "smelt" the metal from its ore. TIllS why copper

    and bronze were used in ancient times.

    Iron ore requires more energy for decomposition. That's

    why the "Iron Age" came later.

    Aluminium and other "modern" metals require even more

    energy, and electricity works better than heat, so these only

    became available in quite recent times.

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    Before metals, people used tools mainly madefrom a)............................. or .

    The fIrst metal used was probably

    b) , because it occurs i n the

    elemental state in nature. However, it is too softto be used for tools, so was just used for

    c) .

    Metallurgy (the technology of metals) began withthe extraction of d) from ores

    that were simply e) .

    A big improvement was the mixing of ores of

    f) and .

    This produced the alloyg) ,

    which made tools and weapons with many

    advantages over stone: metal ish) and .

    and isnot i) like stonemetal can made into intricate shapes, such as

    j) : ,not possible in stone.

    Later, bronze was replaced by k) .

    which is1) and ,

    but requires more m) for

    its extraction.

    During the "Industrial Revolution", the use of

    n) for energy led to the production of

    0) which is iron with a small

    amount of p)................................ in it. This

    allowed the development of machinery, trains

    and the modern industrial world.

    In the 20th century new metals such as

    q) became availablebecause the

    r) needed to extract it from its

    s) was available.

    Today,the metal weuse most is still t) ,in the form of the alloyu) Its

    widespread useisbecause:

    it is common and v) to

    produce.

    it is very w) and .

    Steel comes in a variety of alloys, including

    x) steel (car bodies, pipes, roofIng)

    and y) steel used for foodutensils and medical tools.

    Other alloys used widely include:

    brass, amixture of z) and .

    aa) , with a verylowmelting

    point, is an alloy of ab) and

    .................................... and is used in

    ac) and .

    As well as many alloys, there are some metalscommonly used in their pure, elemental form:

    Aluminium, which has the advantages of beingad)................................. and resistant to

    ae) .Uses include af) .

    and .

    ag) is used for electrical

    wiring because of its good

    ah) and because it is

    ai) so it is easyto draw out into

    wues.

    Chemically, the extraction of metals from ores

    involves aj) .

    reactions, which are ak) -thermic. Some

    metals, such as al).................................... require

    very little energy, others such as

    am) require muchmore. In many cases an) .

    works better than heat in the extraction and

    purifIcation processes. The changes in

    ao) usage through history can be

    directly linked to society's changing sources and

    uses of ap) .

    WHEN COMPLETED, WORKSHEETS

    BECOME SECTION SUMMARIES

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    Metals React With OxygenOne of the most familiar laboratory reactions 1S the

    burning of magnesium:

    Magnesium + Oxygen ~ Magnesium oxide

    2 Mg + 0z ----.. 2 MgO

    In fact, many metals will burn, some alot more readily and

    violently than magnesium:

    Sodium + Oxygen --.-4 Na + 0z --..

    Sodium oxide

    2 NazO

    In these cases there is a violent exothermic reactio n, with

    light and heat energy produced. The product is often a

    powdery, crumbly solid.

    Other metals, such as alumin ium and zinc, react on the

    surface and the oxide compound formed is airtight and

    pr~vents further reaction. That's why these metals are often

    dull-looking ... the surface coat of oxide is dull.

    Aluminium + Oxygen2Al + 30z

    ~ Aluminium oxide

    ----.. 2 AlZ03

    Other metals, such as copper, react with oxygen very slowly

    and only if heated strongly. Some, like gold, will not react

    at all.

    T he point is, that

    metals have diff erent chemi cal activities.

    Metals React With Water

    Another favourite school reaction is when sodium reacts

    with water. This is often done outdoors, because it results

    in an exciting little explosion.

    What happens is:

    Sodium + Water ----.. Hydrogen(gas)

    2 Na + 2 HzO . Hz

    + Sodiumhydroxide

    + 2NaOH

    (In fact this is NOT the explosion reaction. The explosion

    is the reaction of the hydrogen with oxygen, to f orm water)

    Once again, some metals react easily and rapidly and form

    the metal h)7droxide, while others react slowly if heated insteam, and form oxides.

    Zinc + W ater ~ Hydrogen + Zinc oxide

    Zn + HzO ~ Hz + ZnO

    Metals W{ecopper and gold do not react at all.

    There is an "Activity Series" among the metals.

    Metals React With AcidsThe different activity levels of tl le metals is most clearly

    seen when metals are reacted with dilute acids.

    You may have done experimental work to observe howvigorously different metals react with a dilute acid.

    Metals like calcium and

    magnesium react vigorously.

    When there is a reaction, the

    gas produced ishydrogen.

    The metal is "eaten away" and

    dissolves into the liquid. This is

    because it forms a soluble ionic

    compound. Exactly what the

    compound is, depends on which acid is used.

    Zinc + H ydrochloric ~ Hydrogen + Zincacid chloride

    Zn + 2HCI ~ Hz + ZnClz

    Magnesium + Nitric ~ Hydrogen + Magnesiumacid nitrate

    Mg + 2 HN03 ~ Hz + Mg(N03h

    Iron + Sulfuricacid

    Fe + HZS0

    4

    + Iron(II)sulfate

    + FeS04

    The ionic compounds formed are collectively known as

    "salts", so the general pattern of the reactions is

    I Metal + Acid

    It will help you greatly to learn

    the common laboratory acids

    Common Name Chern Name

    H yd ro chlo ri c Hyd ro gen c hlo ri de

    SulfurIC Hydrogen Sulfate

    Nitric Hydrogen nitr ate

    Formula

    HCI

    HzS04HN03

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    The Activity Series of the Metals

    From these 3 patterns of reaction, i t seems there is a

    further, underlying pattern. Certain metals, like sodium,

    always seem to reac t readily and vigorously. Others, like

    copper, always react slowly or not at all.

    From this, aItd other reaction studies, the common

    laboratory metals can be arranged in an "Activity Series":

    Most

    Active

    Mg

    AI

    Ag

    Au

    Least

    Active

    The highly active metals all lie to the extreme left of the

    table, AND the h igher their activity, the lower down the

    table they are within each column.

    This is one of many patterns that allows you to use the

    Periodic Table instead of learning many small facts. For

    example, instead of memorizing the Activity Series fully,

    you can remember the pattern above and always be able to

    figure out the order of the most active metals.

    Northmead High School SL#603217

    Electron Transfer in Metal Reactions

    The chemical reactions that allow us to see the pattern of

    the Activity Series are just part of an even greater pattern

    in Chemistry ... the process of electron transfer.

    To understand this, look again atthe reaction between a

    metal and an acid:

    Zinc + Hydrochloric ~ Hydrogen + Zincacid (gas) chloride

    HCl and ZnClz are both ionic compounds. Here is the

    equation re-written to show the individual ion "species".

    IZn + 2B+ + 2Cr ------ B, + Zn +> + 2CrStudy this carefully and m ake sure you understand why

    there have to be 2 of some ions to agree with the original

    balanced equation.

    Notice that the chloride ions (Clj occur on both sides of

    the equation unchanged. Nothing has happened to them at

    all. We say they are "spectator ions". Like by-standers at a

    car crash they are not involved, while other atoms and ions

    undergo serious changes.

    Since they aren't actually i nvolved, we can leave the

    spectators out. This is called a "net equation".

    Now we can see what really happened;

    a zinc atom became a zinc ion

    and 2 hydrogen ions became a (covalent) hydrogen

    molecule.

    To do this, the zinc atom has to lose 2 electrons, and the

    hydrogen ions must gain a pair of electrons to share.

    Now it should be clear what reallyhappened: the zinc atom

    gave a pair of electrons to some hydrogen ions. Electrons

    were transferred from one "species" to another.

    The equations above are "Half-Equations" and are often

    used to describe what is reallyhappening in a reaction.

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    Oxidation and Reduction

    The transfer of e lectrons from one species to another is

    one of the most fundamental and important general

    reactions of Chemistry.

    The reaction between zinc and acid can be visualized like

    this:

    electrons transferred

    ~::;;::::~' G)

    Zinc atom 2 Hydrogen ions

    ~

    0;0I

    Covalent bond(2 electrons being shared)

    For historical reasons,

    the loss of electrons is called "Oxidation"

    The zinc oxidation allows the hydrogen to be reduced, and

    the hydrogen reduction allows the zinc to be oxidized.

    T he total reaction is an "Oxidation-Reduction" and is

    commonly abbreviated to "REDOX".

    Note that the syllabus does NOT r equire you to know

    these defInitions yet, but it is worth knowing about Redox

    for future topics. You ARE required to know about

    electron transfer and " its involvement in metal reactions.

    Northmead High School SL#60321 7

    First Ionization EnergyAlthough you're not yet required t o kn ow ab out

    Oxidation and Reduction, this bit you have to learn.

    Definition

    The Ionization Energy of an element is the energy

    required to remove an electron from an atom.

    For technical reasons, the measurement of this energyis carried out for atoms i n the gas state.

    +----.- Zn (g) + e -

    The energy required for this to happen is the

    "1st Ionization Energy"

    We know that zinc atoms normally lose 2 electrons to

    form the Zn +2 ion. However, the formal defInition for

    this process involves just the loss of 1 electron.

    Every element has it s o wn characteristic value, eventhose elements which would not normally lose

    electrons, such as non-metals like chlorine.

    Normally a chlorine atom forms a negative ion

    by gaining an electron.

    Technically though, it is possible for it to lose

    an electron if energy is added.

    This energy is the "1st Ionization Energy"

    Even the inert gases, which normally d o no t form ions

    at all, can be forced to lo se an electron if energy is

    added. They too have a 1st Ionization Energy value.

    Ionization Energy Determines the Activity Series

    Now back to the metals a n d the Activity Series.

    In order for a metal to begin reacting with an acid, (or

    with water or oxygen) it must lose an electron. Tlus will

    require the input of its 1st Ionization Energy.

    If the value for 1st Ionization energy is very low, the

    metal will gain this energy easily and quickly from its

    surroundings. It will readily enter the reaction, and the

    reaction will proceed vigorously.

    If its value for 1st IOluzation energy is higher, the atom

    cannot react so readily or vigorously ... its activity is

    lower.

    The ACTIVITY SERIES of t he Metals

    is determined by

    1st IONIZATION ENERGY

    K...Q)

    c NaL.Uc

    0

    Li.~.~c

    Ba.2

    AIc

    VI

    rUZnQ)...

    u

    E

    Fe

    Sn

    Ph

    Cu

    Ag

    Au

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    Choice of MetalsBased on ActivitySometimes which metal is chose n fo r a p arti cular

    application is based o n i ts position in the Activity Series.

    Example

    In critical electronic connections, su ch as computer

    network pl ugs, it is essential that the electric signals get

    through w itho ut loss or distortion.

    Normally we us e copper for electrical winng, but in a

    critical connection plug it is worth the extra expense of

    using gold.

    Copper is a low activity metal, but can slowly react with

    oxygen to form a non-conducting oxide layer in the

    connection. Go ld is l ower down the activity series and will

    not react at all, s o the plug connection cannot corrode.

    Gold's extremely low chemical activity (due to a relatively

    high 1st Ionization Energy) is part of the reason it h as

    always been used for jewellery.

    Gold's low activity means it will not tarnish or corrode, so

    it retains its beautiful colour and lustre.

    Steel is cheap, but since iron

    is about the middle of the

    Activity Series it will

    corrode (rust) by contact

    with water. Is it better to

    choose alower activity metal

    such as copper, which will

    not corrode as quickly, but is

    more expensive?

    The decision is usually to

    use cheap steel pipes for

    longer, outdoor uses like

    your garden taps.

    Indoors, where distances are

    shorter, and a rusted-out

    leaking pipe would b e a

    disaster inside awall or

    ceiling, copper is chosen,

    especially for hot water

    supply.

    Interestingly, sometimes the higher activity metals corrode

    less. Aluminiu m an d zinc are higher up the Activity Series

    than iron. They react rapidly when exposed to oxygen, but

    the surface layer of oxide is airtight and waterproof , and

    prevents oxygen or water getting to the m etal underneath.

    Therefore, these metals can be used in situations where

    corrosion needs to be prevented.

    "Galvanized" steel is coated with a thin layer of zinc to

    prevent (or slow down) corrosion of steel roofIng, fence

    wires, nails, bolts, etc.

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    When a metal reacts with oxygen it forms an a) .

    compound.

    I METAL + OXYGEN b) \

    Some metals will also react with water, forming

    c) gas and a d) .

    compound.

    I METAL + WATER --..c) + d) I

    Most metals will react with acids, forming e) .

    gas and an ionic compound called a ") "

    I METAL + ACID ~ e) + ) ,

    In all these reactions t he various metals react at

    g) rates, showing an order of chemical

    h) Fr om these reactions and others,

    the "Activity Series" has been determined.

    Metals such as i) and .

    are the most active. These are the elements located in the

    j) columns of the Periodic Table.

    Some metals such as k) and .

    have very low activity, and often do not react at all. Other

    common metals like 1) and

    .................................... are in t h e middle of the series. They

    will react, but generally do s o m) .

    All these reactions involve the transfer of n) .

    In the case of the Metal + Acid reaction, the metal atoms

    always 0)........................... electron(s) while a pair of

    p) ions gain 2 electrons (which they

    share in a q) bond) and form a

    r) molecule with formula s) .

    "Oxidation" is the technical term for t) .

    ................................. The opposite is "u) .

    In the Metal + Acid reaction, the metal is alwaysv) while w) ions

    are always x) .

    The "1st y) Energy" of an element is

    defined as the energy required to z) .

    ............................... from atoms in the aa) state.The very active metals are like that because they have very

    ab) (high/low) values for tllls. Metals

    further down the series do not react as vigorously because

    their values are ac) .

    Sometimes the choice of which metal to use is determined

    by the activity level. An example is ad) .

    1. Write a balanced, symbol equation for the reaction of

    each of the following metals with oxygen.

    a)Lead

    (assume lead(IV) ion forms)

    b) Iron

    (Assume iron(III) ion)

    2. a) Arrange the m etals in Q1 in or der of decreasing

    chemical activity.

    b) Which one(s), if any, might ignite easily and burn in

    air with a visible flame?

    3. Write a word equation AND a balanced, symbol

    equation to describe the reaction of:

    a) calcium metal with water (reacts spontaneously at room

    temperature)

    4. All the following equations are Metal + Acid reactions.Fill in all blank spaces, then re-write in symbols and

    balance.

    b) Calcium + Hydrochloric ~ + .acid

    c) + ~ Hydrogen + Bariumnitrate

    d) + ~ Hydrogen + iron(II)chloride

    5. For each of the reactions in Q4, wlllch chemical species

    a) lost electrons?b) gained electrons?

    c) was a "spectator"?

    WHEN COMPLETED, WORKSHEETS

    BECOME SECTION SUMMARIES

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    Atomic Structure, Number and Mass

    Here is a quick reminder of some basics about atoms you

    need to know:

    In the Nucleus are

    Protons &

    x'.," .Neutrons ..................... '"

    ;' :.' " ,- .. .

    , '\.::/\,n DebitaeDund..... t he nucleus a re

    the Electrons

    E ach element's atoms have a different, characteristic,

    number of protons and electrons. Therefore, each elementhas a different Atomic Number.

    In the Periodic Table t he elements are arranged i n order of

    Atomic Number.

    No.Protons + No.Neutrons = "Mass Number"(Electron mass is insignificant)

    The M ass N umber is always a whole number, but in the

    Periodic Table the "Atomic Weight" is shown instead.

    (How and why this i s different will be explained in a later

    topic)

    The Periodic Table

    is firstly a list of the elements, arranged i n o rd er, a nd

    showing all the basic details.

    Atomic Number

    18 Equal to the number of electronsand the number of protons in

    each atom

    ArArgon ..

    "Atomic Weight"

    NOT the "Mass Number"

    The shape and arrangement of t he Periodic Table is a very

    clever device to allow many patterns and grouping s to b e

    accommodated. You have already learnt one pattern in the

    position of the most active metals, and their 1st Ioniza tion

    Energies.

    History of the Periodic Table

    The modern concept of a chemical element as a substance

    containing identical atoms was first accepted almost exactly

    200 years ago.

    By 1830 there were about 40 known elements. Even with

    such a small sample, people began to notice patterns:

    Dobereiner (German) pointed out that there were several

    groups of 3 elements witl1.remarkably sinlliar properties:

    Lithium, sodium & potassiu m was one "triad".

    Chlorine, bromine and iodine formed another "triad".

    By 1860, with over 60 known elements, Newlands

    (English) proposed a "Law of Octaves".

    If the elements were arranged in order of r elative weights,

    Newlands found that every 8th element (an "octave" ) was

    sinlliar in properties. These similar elements included

    Dobereiner's triads.

    The s ystem worked well for the first 20 elements, but then

    became confused.

    The basis of the modern Periodic Table was developed by

    the Russian, Dmitri Mendeleev in 1869.

    Mendeleev used many physical and chemical properties:

    atomic weight density

    melting point formula of oxide compound

    density of oxide and many more,

    and arranged the elements in order of weight, but with

    elements with sinlliar properties under each other.

    Mendeleev's genius was to realiz t hat there were probably

    missing elements that hadn't een d iscovered yet. He

    cleverly lef t gaps in his table f or these undis covered

    elements.

    The most famous case was that of the "missing" element

    Mendeleev called "eka-silicon" . He us ed the patterns in his

    table to predict, very precisely, the properties for eka-

    silicon. Scientists went looking for such a substance and

    soon found a new element (which was named

    "Germanium") with properties almost exactly as predicted.

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    Patterns of the Periodic Table

    In Mendeleev's day no-one could explain why these patterns existed.

    However, when scientists see patterns in nature like this, they know there must be underlying "r ules" or

    "laws of nature" causing and controlling the patterns.

    Perhaps Mendeleev's great contribution was not just the Periodic Table itself,

    but the stimulus it gave other scientists to investigate the reasons behind the patterns.

    Within 40 years Science had unravelled the secrets of atomic structure, the electron energy levels, and more.

    At this s ta e our task is to lear n s ome of the atter ns.

    Electrical Conductivity

    As you go across any row ("period") of the table, you will

    move through anumber of metals, then one or two semi-

    metals, then into the non-metals.

    Therefore, the conductivity will start out high, but r apidly

    decrease as you encounter a semi-metal, and becomeextremely low at the non-metals.

    r!, I

    CLJ\ I i

    llj~H~~tJTEI1:1

    Boiling Points

    follow a similar pattern to

    Melting Points

    Valencies are the same

    down each group

    Melting Point

    You learned in topic 1 how melting point is determined by the

    bonding within a substance.

    At the left side of the table are the very active metals of d1e

    Activity Series. They are also usually soft, and have relatively low

    (for metals) melting points.

    Moving to the right across a period you enter d1e "Transition

    Block" containing typical hard, high melting point metals, held

    strongly together by "metallic bonding".

    Further right you hit d1e Semi-Metals. These often have very high

    melting points because of their covalent lattice structure.

    Then you enter d1e Non-Metals which have covalent molecular

    structures and quite low mp's. At the far right column, each period

    ends with an Inert Gas which are all s ingle-atom molecules, and

    have d1elowest mp of each period.

    This pattern repeats itself along each period.

    Melting Points of ElementsIII

    I

    Peaks are Transi ti on M etals

    or Semi-Metals

    Sketch Graph.oooN

    Go~ooo... -

    c-

    oc..

    010

    Nac

    Chemical Bonding, Valency & Reactivity

    What you've already learnt about the Activity Series, Ionic and Covalent Bonding and Valency

    will help you make sense of the following: ("" G 8 I Group nert ases

    No chemical reactions,

    no bonding

    Activity of Non-Metals

    Most active at top-right(FIuori ne)

    Activity (generally)decreases downwardsand to the left.