ipc presentation
DESCRIPTION
Presentation by Jim Lunt at The 9th SPSJ International Polymer Conference (IPC 2012)-Held in Kobe Japan.TRANSCRIPT
![Page 1: IPC presentation](https://reader033.vdocuments.mx/reader033/viewer/2022052206/555123a2b4c905b1138b5533/html5/thumbnails/1.jpg)
Bioplastics Advances and Sustainability
December 14, 2012
The 9th SPSJ International Polymer Conference (IPC2012)
![Page 2: IPC presentation](https://reader033.vdocuments.mx/reader033/viewer/2022052206/555123a2b4c905b1138b5533/html5/thumbnails/2.jpg)
Basic Definitions for Bioplastics.
Growth Factors For Bioplastics.
Feedstocks and Sustainability.
First and Second Generation Bioplastics.
Bioplastics Growth Projections and Market Trends.
Applications in Use Today for Bioplastics.
Presentation Outline
![Page 3: IPC presentation](https://reader033.vdocuments.mx/reader033/viewer/2022052206/555123a2b4c905b1138b5533/html5/thumbnails/3.jpg)
Basic Definitions for Bioplastics
Biodegradable or Compostable Bioplastics Meet all scientifically recognized standards for biodegradability and compostability of plastics and plastic products.
Independent of carbon origin-(i.e. Ecoflex, PBS, PLA ). Focus is on end-of-life or disposability.
Biobased Bioplastics Must be organic and contain some percentage of recently fixed (new) carbon found in biological resources or crops.
Focus on renewable resource based origin. Uses C14 content measurement.
![Page 4: IPC presentation](https://reader033.vdocuments.mx/reader033/viewer/2022052206/555123a2b4c905b1138b5533/html5/thumbnails/4.jpg)
Renewable resource versus oil based.
Reduced environmental impact.
Concerns about human health.
End-of-Life disposal issues – Landfill.
Legislative initiatives.
Growth Factors for Bioplastics
![Page 5: IPC presentation](https://reader033.vdocuments.mx/reader033/viewer/2022052206/555123a2b4c905b1138b5533/html5/thumbnails/5.jpg)
Bioplastics
Opportunity
Growth Factors for Bioplastics
![Page 6: IPC presentation](https://reader033.vdocuments.mx/reader033/viewer/2022052206/555123a2b4c905b1138b5533/html5/thumbnails/6.jpg)
Today's Bioplastic Feedstocks
Corn
Cassava
Sugarcane
Sugar beet
Sorghum
All refined sugars - dextrose, glucose, sucrose.
Sorghum
![Page 7: IPC presentation](https://reader033.vdocuments.mx/reader033/viewer/2022052206/555123a2b4c905b1138b5533/html5/thumbnails/7.jpg)
Food versus Fuel Debate:
• Food Crops Diversion to Fuels/Plastics
• Land Use
• Fertilizer Use
• Pesticide Use
• The “Ripple Effect “
Use of GMO's
Bioplastics Feedstock Issues
![Page 8: IPC presentation](https://reader033.vdocuments.mx/reader033/viewer/2022052206/555123a2b4c905b1138b5533/html5/thumbnails/8.jpg)
More “Sustainable” Biomass Feedstocks
Lignocellulose (wood, corn stover, other agricultural residues)
Oil seeds (soy, rape/canola, palm, coconut, Jatropha)
Microalgae
Macroalgae (kelp)
Waste:
MSW, food processing (cellulosic) Used fats and oils Animal processing wastes (rendering, feathers, hair, manure)
![Page 9: IPC presentation](https://reader033.vdocuments.mx/reader033/viewer/2022052206/555123a2b4c905b1138b5533/html5/thumbnails/9.jpg)
Leading Biomass Source – Lignocellulosics
Corn stover
Sugar cane bagasse
Tall grasses
Rice straw
Wood chips Wheat straw
Source: Virent –”The Future For Bioplastics Feedstocks”
![Page 10: IPC presentation](https://reader033.vdocuments.mx/reader033/viewer/2022052206/555123a2b4c905b1138b5533/html5/thumbnails/10.jpg)
Extracting Sugars From Cellulosics
Dilute acid and enzyme hydrolysis
Wet oxidation and enzyme hydrolysis
Concentrated acid extraction
Catalytic biomass deconstruction
Most Common Industrial Approaches
![Page 11: IPC presentation](https://reader033.vdocuments.mx/reader033/viewer/2022052206/555123a2b4c905b1138b5533/html5/thumbnails/11.jpg)
Commercially Proven Technology
Virdia Process (c1938)
Loblolly Pine
Preparation Sizing
Tall Oil Removal
Tall Oil
Concentrated HCL Deconstruction
Lignin Deacidification
Lignin
Sugar Recovery HCL Recycle
Final Purification
Soluble C5/C6 Sugars
HCL
HCL
![Page 12: IPC presentation](https://reader033.vdocuments.mx/reader033/viewer/2022052206/555123a2b4c905b1138b5533/html5/thumbnails/12.jpg)
Compounded, Biobased
& Compostable
O O
OH OH HO HO
H H
CH3 CH3
L-Lactic Acid L-Lactic Acid
O
OH HO
H
CH3
L-Lactic Acid
O O
OH OH HO HO
H3C H3C H H
D-Lactic Acid
(0.5%)
O
OH HO
H3C H
D-Lactic Acid
(0.5%)
Polylactic Acid (PLA)
100% Renewable & Compostable
First Generation BioplasticsFirst Generation Bioplastics
Starch/PLA/ECOFLEX
……
……
……
……
.……
……
……
……
……
……
……
……
…
![Page 13: IPC presentation](https://reader033.vdocuments.mx/reader033/viewer/2022052206/555123a2b4c905b1138b5533/html5/thumbnails/13.jpg)
First Generation PHA’s
PHA picture courtesy of Telles
Compostable, biodegradable and renewable
![Page 14: IPC presentation](https://reader033.vdocuments.mx/reader033/viewer/2022052206/555123a2b4c905b1138b5533/html5/thumbnails/14.jpg)
Bioplastics are still less than 1% of the approximate 230 million tons
of plastics in use today.
Projected Biomaterials TrendsProjected Biomaterials Trends
Projected 20-30%AGR
![Page 15: IPC presentation](https://reader033.vdocuments.mx/reader033/viewer/2022052206/555123a2b4c905b1138b5533/html5/thumbnails/15.jpg)
Increasing demand for biobased, durable products in electronics and automotive applications.
By 2011 durables were expected to account for almost 40% of bioplastics –
compared with 12% in 2010. (European Bioplastics)
Projected Durables Growth Projected Durables Growth
![Page 16: IPC presentation](https://reader033.vdocuments.mx/reader033/viewer/2022052206/555123a2b4c905b1138b5533/html5/thumbnails/16.jpg)
Sales Trends in Bioplastics Sales Trends in Bioplastics
Jim Lunt & Associates LLC. Projections
205KT 500KT 1.2MT
![Page 17: IPC presentation](https://reader033.vdocuments.mx/reader033/viewer/2022052206/555123a2b4c905b1138b5533/html5/thumbnails/17.jpg)
Continuing lack of infrastructure for use and disposal of compostable plastics. “Compostables” performance v durables. Increasing demand for biobased, semi-durable and durable products for household goods, electronics and automotive applications. Increasing interest and developments in existing and new monomers from renewable resources.
Why The Change?Why The Change?
![Page 18: IPC presentation](https://reader033.vdocuments.mx/reader033/viewer/2022052206/555123a2b4c905b1138b5533/html5/thumbnails/18.jpg)
Braskem “Green Polyethylene” from Sugar Cane
ethanol
ethylene
sugar cane molasses
HDPE polyethylene
![Page 19: IPC presentation](https://reader033.vdocuments.mx/reader033/viewer/2022052206/555123a2b4c905b1138b5533/html5/thumbnails/19.jpg)
Bio Ethylene Glycol
ethanol
ethylene
sugar cane molasses
ethylene oxide Ethylene glycol
India Glycols, GTC, FENC, JBF
-H2O
fermentation
oxidation +H2O
![Page 20: IPC presentation](https://reader033.vdocuments.mx/reader033/viewer/2022052206/555123a2b4c905b1138b5533/html5/thumbnails/20.jpg)
Biobased TPA for PET from Sugars Gevo Global Bioenergies
Amyris Genomatica
Toray/UOP
SABIC
t,t muconic acid
d limonene p cymene BP
dimethyl furan
fdca
biobutanol isobutylene isooctene
p-xylene
TPA
![Page 21: IPC presentation](https://reader033.vdocuments.mx/reader033/viewer/2022052206/555123a2b4c905b1138b5533/html5/thumbnails/21.jpg)
Anellotech/Virent Processes for Biobased Aromatics
BTX=benzene, toluene, xylenes mixture.
Anellotech Process
Virent Process
![Page 22: IPC presentation](https://reader033.vdocuments.mx/reader033/viewer/2022052206/555123a2b4c905b1138b5533/html5/thumbnails/22.jpg)
Other Bio “Building BlocksOther Bio “Building Blocks””
Succinic acid
Adipic acid
Butane diol
PTT, DSM, BASF, Bioamber, Roquette, Mitsubishi Chem., Myriant, Purac
Rennovia, Verdezyne, Genomatica
Genomatica
FDCA
Avantium
Ketals Segetis, XLTerra/Reluceo
Caprolactam
Acrylic acid
Isosorbide
Propylene
Propane 1,3 diol
Amyris
Ceres, Dow/OPX
ADM, Roquette
Braskem
DuPont / Tate & Lyle
![Page 23: IPC presentation](https://reader033.vdocuments.mx/reader033/viewer/2022052206/555123a2b4c905b1138b5533/html5/thumbnails/23.jpg)
Biobased Succinic Acid and Derivatives
Biobased Succinic Acid
Courtesy Myriant
Succinic acid/PBS • BioAmber • PTT • MCC • DSM/Roquette • BASF/Purac
Butane diol • Genomatica
Adipic acid • Rennovia • Verdezyne
![Page 24: IPC presentation](https://reader033.vdocuments.mx/reader033/viewer/2022052206/555123a2b4c905b1138b5533/html5/thumbnails/24.jpg)
Examples of Emerging Technologies
bottles
films
fibers
Plant based carbohydrates
FDCA
PEF
EG
Avantium’s PEF is a 100% biobased polyester, with glass transition 10 C higher than PET ,oxygen barrier 6-10 times better than PET, CO2 barrier 2-4 times better than PET, and water 2 times better than PET.
Courtesy of Avantium
Avantium PEF ‘yxy’
![Page 25: IPC presentation](https://reader033.vdocuments.mx/reader033/viewer/2022052206/555123a2b4c905b1138b5533/html5/thumbnails/25.jpg)
L-Ketals HO
OH
O
O
succinic acid
HO OH
O
3-hydroxypropionic acid
OH
O
NH2
HO
O
glutamic acid
aspartic acid
OHHO
O
O NH2
HO OH
OH
glycerol
O
OHO
4-hydroxybutyrolactone
itaconic acid
HOOH
O
O
O
O
OH
levulinic acid
O
O
OH
O
HO
2,5-furandicacboxylic acid
OH OHOH
OH OH
xylitol
OH
OHOH
OH
OH
OH
sorbitol
HOOH
OH
OH
OH
OH
O
O
glucaric acid
OO
HO
O
OR
Ketal Plasticizers/Poly XLK
OO
O
O
O
O
n
XLTerra
PXLK
![Page 26: IPC presentation](https://reader033.vdocuments.mx/reader033/viewer/2022052206/555123a2b4c905b1138b5533/html5/thumbnails/26.jpg)
Bioplastic Products In The Marketplace
![Page 27: IPC presentation](https://reader033.vdocuments.mx/reader033/viewer/2022052206/555123a2b4c905b1138b5533/html5/thumbnails/27.jpg)
PLA
![Page 28: IPC presentation](https://reader033.vdocuments.mx/reader033/viewer/2022052206/555123a2b4c905b1138b5533/html5/thumbnails/28.jpg)
Cellulose Acetate
![Page 29: IPC presentation](https://reader033.vdocuments.mx/reader033/viewer/2022052206/555123a2b4c905b1138b5533/html5/thumbnails/29.jpg)
Compounded PLA/Starch Blends
![Page 30: IPC presentation](https://reader033.vdocuments.mx/reader033/viewer/2022052206/555123a2b4c905b1138b5533/html5/thumbnails/30.jpg)
Green Polyethylene
![Page 31: IPC presentation](https://reader033.vdocuments.mx/reader033/viewer/2022052206/555123a2b4c905b1138b5533/html5/thumbnails/31.jpg)
Bio PET
![Page 32: IPC presentation](https://reader033.vdocuments.mx/reader033/viewer/2022052206/555123a2b4c905b1138b5533/html5/thumbnails/32.jpg)
The Future For Bioplastics The Future For Bioplastics Will Depend OnWill Depend On
Oil pricing continuing to increase.
Improved performance.
Composting/recycling infrastructure developments.
Expanding from single-use compostable to durable applications.
Moving to non-food source feedstocks.
Competition from carbon dioxide based plastics.
![Page 33: IPC presentation](https://reader033.vdocuments.mx/reader033/viewer/2022052206/555123a2b4c905b1138b5533/html5/thumbnails/33.jpg)
Thank YouThank YouThank YouThank You