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International Testing of Formaldehyde Steve Zylkowski Lisa Bailey Kurt Bigbee FPS Seminar Eugene, OR July 10, 2007

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Page 1: International Testing of Formaldehydeowic.oregonstate.edu/sites/default/files/pubs/Zylkowski.pdf · adhesives PF, PRF, MDI All are very low emitters of formaldehyde. APA Perspective

International Testing of

Formaldehyde

Steve Zylkowski

Lisa Bailey

Kurt Bigbee

FPS Seminar Eugene, OR July 10, 2007

Page 2: International Testing of Formaldehydeowic.oregonstate.edu/sites/default/files/pubs/Zylkowski.pdf · adhesives PF, PRF, MDI All are very low emitters of formaldehyde. APA Perspective

APA Perspective

Certifies products made with water resistant adhesives

PF, PRF, MDI

All are very low emitters of formaldehyde

Page 3: International Testing of Formaldehydeowic.oregonstate.edu/sites/default/files/pubs/Zylkowski.pdf · adhesives PF, PRF, MDI All are very low emitters of formaldehyde. APA Perspective

APA Perspective

Structural wood products are certified for strength and bond performance

There are no U.S. formaldehyde regs for Structural Wood Products

Page 4: International Testing of Formaldehydeowic.oregonstate.edu/sites/default/files/pubs/Zylkowski.pdf · adhesives PF, PRF, MDI All are very low emitters of formaldehyde. APA Perspective

Overview

Japanese requirements for structural

panels

Global flow of wood panels

APA test results on imported plywood

Page 5: International Testing of Formaldehydeowic.oregonstate.edu/sites/default/files/pubs/Zylkowski.pdf · adhesives PF, PRF, MDI All are very low emitters of formaldehyde. APA Perspective

U.S. Structural Wood

Products Made for

Japanese Market

2002 Japanese Healthy House Law

JAS standards

F Star Rating (eg, F ****)

rating determines if/where/how

panels can be used in a home

Applies to glulam, plywood, OSB

Page 6: International Testing of Formaldehydeowic.oregonstate.edu/sites/default/files/pubs/Zylkowski.pdf · adhesives PF, PRF, MDI All are very low emitters of formaldehyde. APA Perspective

JAS Formaldehyde Rating

F **** ( or F 4 star) is the best rating and permits unlimited use of wood material in the house

F **** has become the dominant material of choice

Page 7: International Testing of Formaldehydeowic.oregonstate.edu/sites/default/files/pubs/Zylkowski.pdf · adhesives PF, PRF, MDI All are very low emitters of formaldehyde. APA Perspective

JAS Formaldehyde Method

9 – 11 liter desiccator

Prescribed number/size of specimens

Distilled water

Page 8: International Testing of Formaldehydeowic.oregonstate.edu/sites/default/files/pubs/Zylkowski.pdf · adhesives PF, PRF, MDI All are very low emitters of formaldehyde. APA Perspective

JAS Formaldehyde Test

The test is a passive test

Unlike ASTM E1333 or dynamic chamber methods

Desiccator maintained at 20 C for 24 hours

Page 9: International Testing of Formaldehydeowic.oregonstate.edu/sites/default/files/pubs/Zylkowski.pdf · adhesives PF, PRF, MDI All are very low emitters of formaldehyde. APA Perspective

JAS Formaldehyde Test

Water absorbs released formaldehyde

Water is reacted with acetylacetone

Resultant color is related to formaldehyde concentration

Page 10: International Testing of Formaldehydeowic.oregonstate.edu/sites/default/files/pubs/Zylkowski.pdf · adhesives PF, PRF, MDI All are very low emitters of formaldehyde. APA Perspective

JAS Formaldehyde Results - OSB

Distribution of Formaldehyde Results on OSB (n=457)

0

20

40

60

80

100

120

140

0 0.03 0.06 0.09 0.12 0.15 0.18 0.21 0.24 0.27 0.3 0.33

Formaldehyde Emission (mg/L)

No

. o

f O

bservati

on

s

Limit for Avg = 0.30 mg/L

Limit for single test = 0.40 mg/L

Page 11: International Testing of Formaldehydeowic.oregonstate.edu/sites/default/files/pubs/Zylkowski.pdf · adhesives PF, PRF, MDI All are very low emitters of formaldehyde. APA Perspective

JAS Formaldehyde Results

OSB (n=457)

Average: 0.070 mg/L

Range: 0 to 0.268 mg/L

F **** permits up to 0.40 mg/L with

average up to 0.30 mg/L

Page 12: International Testing of Formaldehydeowic.oregonstate.edu/sites/default/files/pubs/Zylkowski.pdf · adhesives PF, PRF, MDI All are very low emitters of formaldehyde. APA Perspective

JAS Formaldehyde Results

Plywood (n=11)

Average: 0.084 mg/L

Range: 0 to 0.281 mg/L

F **** permits up to 0.40 mg/L with

average up to 0.30 mg/L

Page 13: International Testing of Formaldehydeowic.oregonstate.edu/sites/default/files/pubs/Zylkowski.pdf · adhesives PF, PRF, MDI All are very low emitters of formaldehyde. APA Perspective

JAS Formaldehyde Results

Glulam (n=29)

Average: 0.217 mg/L

Range: 0.114 to 0.301 mg/L

F **** permits up to 0.40 mg/L with

average up to 0.30 mg/L

Page 14: International Testing of Formaldehydeowic.oregonstate.edu/sites/default/files/pubs/Zylkowski.pdf · adhesives PF, PRF, MDI All are very low emitters of formaldehyde. APA Perspective

JAS Certification

Japanese building law requires structural

wood products to be certified.

Certification is administered through the

Ministry of Agriculture, Forestry and

Fisheries (MAFF).

They accredit “Registered Offshore

Certification Bodies” (ROCB) using

process of ISO Guide 65.

Page 15: International Testing of Formaldehydeowic.oregonstate.edu/sites/default/files/pubs/Zylkowski.pdf · adhesives PF, PRF, MDI All are very low emitters of formaldehyde. APA Perspective

Japanese Regulations for

Wood Products

System is well established:

• Recognized Test Method

• Established Limits

• Certification required with

accreditation of CBs through MAFF

Page 16: International Testing of Formaldehydeowic.oregonstate.edu/sites/default/files/pubs/Zylkowski.pdf · adhesives PF, PRF, MDI All are very low emitters of formaldehyde. APA Perspective

Global Flow of Wood Panels

Page 17: International Testing of Formaldehydeowic.oregonstate.edu/sites/default/files/pubs/Zylkowski.pdf · adhesives PF, PRF, MDI All are very low emitters of formaldehyde. APA Perspective

The Structural Panel

Markets

U.S. & Canada

(BSF)2006

Residential 24.2Remodeling 8.8Nonresidential 3.9Industrial 7.5International .5

Total 44.9

Page 18: International Testing of Formaldehydeowic.oregonstate.edu/sites/default/files/pubs/Zylkowski.pdf · adhesives PF, PRF, MDI All are very low emitters of formaldehyde. APA Perspective

PANEL IMPORT TRENDS – USA

(EXCLUDING CANADA)

0

1500000

3000000

4500000

6000000

1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006

Vo

lum

e (

1000s s

q f

t 3/8

")

Softwood Plywood OSB Hardwood Plywood

SOURCE: Global Trade Atlas 2006

Page 19: International Testing of Formaldehydeowic.oregonstate.edu/sites/default/files/pubs/Zylkowski.pdf · adhesives PF, PRF, MDI All are very low emitters of formaldehyde. APA Perspective

CHINESE PLYWOOD PRODUCTION TRENDS

0

2000

4000

6000

8000

10000

12000

14000

1991

1993

1995

1997

1999

2001

2003

Softwood Hardwood

‘000 cubic meters

SOURCE: FAO, 2004

Million sf-3/8”

Page 20: International Testing of Formaldehydeowic.oregonstate.edu/sites/default/files/pubs/Zylkowski.pdf · adhesives PF, PRF, MDI All are very low emitters of formaldehyde. APA Perspective

US HARDWOOD PLYWOOD IMPORTS

SOURCE: Global Trade Atlas 2006

U.S. Imports of Hardwood Plywood

0

500

1000

1500

2000

2500

3000

3500

4000

4500

5000

2000  2001  2002  2003  2004  2005 

Vo

lum

e (

mil

lio

n s

q.

ft.)

Other

Ecuador

Brazil

Canada

Indonesia

Russia

Malaysia

China

Page 21: International Testing of Formaldehydeowic.oregonstate.edu/sites/default/files/pubs/Zylkowski.pdf · adhesives PF, PRF, MDI All are very low emitters of formaldehyde. APA Perspective

CHINESE LOG IMPORT TRENDS

0

2000

4000

6000

8000

10000

12000

14000

16000

18000

20000

1997

1999

2001

2003

2005

Volum

e ('000 cubic m

eters)

Other

New

Zealand

Russia

SOURCE: Global Trade Atlas 2005

Page 22: International Testing of Formaldehydeowic.oregonstate.edu/sites/default/files/pubs/Zylkowski.pdf · adhesives PF, PRF, MDI All are very low emitters of formaldehyde. APA Perspective
Page 23: International Testing of Formaldehydeowic.oregonstate.edu/sites/default/files/pubs/Zylkowski.pdf · adhesives PF, PRF, MDI All are very low emitters of formaldehyde. APA Perspective

Performance of Imported

Plywood

APA recently completed two studies of

imported plywood

Page 24: International Testing of Formaldehydeowic.oregonstate.edu/sites/default/files/pubs/Zylkowski.pdf · adhesives PF, PRF, MDI All are very low emitters of formaldehyde. APA Perspective

Performance of Imported

Plywood

APA recently completed two studies of

imported plywood

Study arose from marketplace questions

Page 25: International Testing of Formaldehydeowic.oregonstate.edu/sites/default/files/pubs/Zylkowski.pdf · adhesives PF, PRF, MDI All are very low emitters of formaldehyde. APA Perspective

Performance of Imported

Plywood

APA recently completed two studies of

imported plywood

Study arose from marketplace questions

First study: Concrete form (6 sources)

Page 26: International Testing of Formaldehydeowic.oregonstate.edu/sites/default/files/pubs/Zylkowski.pdf · adhesives PF, PRF, MDI All are very low emitters of formaldehyde. APA Perspective

Performance of Imported

Plywood

APA recently completed two studies of imported

plywood

Study arose from marketplace questions

First study: Concrete form (6 sources)

Second study: Industrial plywood (12 sources)

Page 27: International Testing of Formaldehydeowic.oregonstate.edu/sites/default/files/pubs/Zylkowski.pdf · adhesives PF, PRF, MDI All are very low emitters of formaldehyde. APA Perspective

Performance of Imported

Plywood

The plywood:

1) All of it was uncertified. No grademarks; No referenced standards

2) All of the plywood was obtained from distributors

3) Sample size was small – typically 2 panels per batch

Page 28: International Testing of Formaldehydeowic.oregonstate.edu/sites/default/files/pubs/Zylkowski.pdf · adhesives PF, PRF, MDI All are very low emitters of formaldehyde. APA Perspective

Concrete Form Test Program

Background

• Demanding Application

• Field failures have been reported with Chinese Hardwood Plywood

• Dry and wet bending and shear properties were tested

• PS 1 bond tests and JAS formaldehyde tests were conducted

Page 29: International Testing of Formaldehydeowic.oregonstate.edu/sites/default/files/pubs/Zylkowski.pdf · adhesives PF, PRF, MDI All are very low emitters of formaldehyde. APA Perspective

Industrial Plywood Test Program

Background

• Diverse Applications

• Imported Hardwood plywood has displaced domestic plywood

• Dry bending properties were tested

• Dry screw holding properties were tested

• PS 1 bond tests and JAS formaldehyde tests were conducted

Page 30: International Testing of Formaldehydeowic.oregonstate.edu/sites/default/files/pubs/Zylkowski.pdf · adhesives PF, PRF, MDI All are very low emitters of formaldehyde. APA Perspective

APA IMPORTED PLYWOOD TESTS

Flexure Tests

•Dry

•Wet – Following a

Vacuum Pressure

Soak Cycle

Page 31: International Testing of Formaldehydeowic.oregonstate.edu/sites/default/files/pubs/Zylkowski.pdf · adhesives PF, PRF, MDI All are very low emitters of formaldehyde. APA Perspective

APA IMPORTED PLYWOOD TESTS

Adhesive shear tests

• Wet – following a

vacuum pressure

soak cycle

• Wet – following a

boil cycle

Page 32: International Testing of Formaldehydeowic.oregonstate.edu/sites/default/files/pubs/Zylkowski.pdf · adhesives PF, PRF, MDI All are very low emitters of formaldehyde. APA Perspective

Conclusions: Concrete Form

4 of 6 batches failed

to meet the PS 1 bond

requirements

Page 33: International Testing of Formaldehydeowic.oregonstate.edu/sites/default/files/pubs/Zylkowski.pdf · adhesives PF, PRF, MDI All are very low emitters of formaldehyde. APA Perspective

Conclusions: Concrete Form

3 of 6 batches met

F****

The other three

batches varied widely

(0.80 to 9.97 mg/L)

Page 34: International Testing of Formaldehydeowic.oregonstate.edu/sites/default/files/pubs/Zylkowski.pdf · adhesives PF, PRF, MDI All are very low emitters of formaldehyde. APA Perspective

Conclusions: Industrial Plywood

Bending properties were 12 to 45% lower for the imported plywood

Screw holding properties were 19 to 22% lower

Page 35: International Testing of Formaldehydeowic.oregonstate.edu/sites/default/files/pubs/Zylkowski.pdf · adhesives PF, PRF, MDI All are very low emitters of formaldehyde. APA Perspective

Conclusions: Industrial Plywood

All imported

hardwood plywood

failed PS 1 boil test

All but two batches

failed the PS 1

vacuum soak test

Page 36: International Testing of Formaldehydeowic.oregonstate.edu/sites/default/files/pubs/Zylkowski.pdf · adhesives PF, PRF, MDI All are very low emitters of formaldehyde. APA Perspective

Conclusions: Industrial Plywood

All imported hardwood

plywood rated at either F* or

failed to meet this most

lenient level

Three batches had emission

levels greater than 10 mg/L

Page 37: International Testing of Formaldehydeowic.oregonstate.edu/sites/default/files/pubs/Zylkowski.pdf · adhesives PF, PRF, MDI All are very low emitters of formaldehyde. APA Perspective

In Conclusion……….

Certification of wood panels conveys

that the panels will perform at a

specified level.

Uncertified panels may result in

unexpected performance.

Page 38: International Testing of Formaldehydeowic.oregonstate.edu/sites/default/files/pubs/Zylkowski.pdf · adhesives PF, PRF, MDI All are very low emitters of formaldehyde. APA Perspective

OTHER ISSUES……

Be aware of the illegal use of

trademarks and trade names.

Be aware of the potential

illegal reference to US Product

Standard PS 1 or PS 2

notations.

Page 39: International Testing of Formaldehydeowic.oregonstate.edu/sites/default/files/pubs/Zylkowski.pdf · adhesives PF, PRF, MDI All are very low emitters of formaldehyde. APA Perspective

www.apawood.org