inorganic chemistry chapter 04

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PRE-U TEXT STPM INORGANIC CHEMISTRY ISBN: 978 983 3879 83 0 Chapter 4 – Group 14 elements: C, Si, Ge, Sn, Pb Practice 4.1 Physical and chemical properties of Group 14 elements Reinforce your understanding and knowledge of the variation of physical and chemical properties of Group 14 elements by elaborating the key words given below: STPM : 1998, P1/Q29, 1999, P1/Q22, Q23;, 2000, P1/Q22, Q23, P2/Q2(a); 2001, P1/Q21, Q23; 2002, P/Q22, P2/Q8(b)(ii), 2003, P2/Q3(a); 2004, P1/Q47; 2005, P1/Q21, Q43 Reference : Pages 57 to 60 Guide The Group 14 elements The electronic configuration of the valence electrons for all elements Physical properties of the Group 14 elements The variation of atomic radius when going down Group 14 o Nuclear charge o Screening effect o Effective nuclear charge The variation of first ionisation energy when going down Group 14 © Pearson Malaysia Sdn. Bhd. 2007 1 PRE-U TEXT INORGANIC CHEMISTRY

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Inorganic Chemistry

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PAGE PRE-U TEXT STPM INORGANIC CHEMISTRY

ISBN: 978 983 3879 83 0

Chapter 4 Group 14 elements: C, Si, Ge, Sn, Pb Practice 4.1 Physical and chemical properties of Group 14 elements

Reinforce your understanding and knowledge of the variation of physical and chemical properties of Group 14 elements by elaborating the key words given below:

STPM

: 1998, P1/Q29, 1999, P1/Q22, Q23;, 2000, P1/Q22, Q23, P2/Q2(a);

2001, P1/Q21, Q23; 2002, P/Q22, P2/Q8(b)(ii), 2003, P2/Q3(a);

2004, P1/Q47; 2005, P1/Q21, Q43Reference: Pages 57 to 60Guide

The Group 14 elementsThe electronic configuration of the valence electrons for all elementsPhysical properties of the Group 14 elements

The variation of atomic radius when going down Group 14 Nuclear charge

Screening effect

Effective nuclear charge The variation of first ionisation energy when going down Group 14 Atomic size

Effective nuclear charge

The variation of electrical conductivity when going down Group 14 From giant covalent structure to giant metallic structure The variation of melting point when going down Group 2 Strength of forces holding particles in the solid state

The arrangement of particles in the solid state Lattice structure

General chemical properties of Group 14 elements

Oxidation states of +2 and +4 Relative stability of the +2 and +4 oxidation state

Formation of complex ions

Tetrachlorides of Group 14

General properties

Physical properties of the tetrachlorides

Thermal stability of the tetrachlorides

Hydrolysis of tetrachlorides

Oxides of Group 14: Monoxides

The thermal stability of the monoxides

The acid/base nature of monoxides

Oxides of Group 14: Dioxides

The thermal stability of the dioxides

The acid/base nature of dioxides

Catenation

The allotropes of carbon

The uses of tin, silicon and carbon

Silicon(IV) oxide or silica Structure of silica

Chemical properties of silicon(IV) oxide

Uses of silica, silicon(IV) oxide

Glass

Soda-lime glass Potash glass

Flint/ lead glass

Borosilicate glass (pyrex)

Aluminosilicate glass

Silicates

Silicates with discrete SiO42- ions

Silicates with one shared oxygen atom

Silicates with two shared oxygen atoms

Silicates with three shared oxygen

AluminosilicatesPRE-U TEXT

INORGANIC CHEMISTRY

PAGE 1 Pearson Malaysia Sdn. Bhd. 2007