“inorganic and organometallic clusters and polymers: syntheses and applications” symposium
TRANSCRIPT
‘‘Inorganic and Organometallic Clusters and Polymers:Syntheses and Applications’’ Symposium
This 3-day symposium was organized by Pierre D. Harvey,
Universite de Sherbrooke, and Alaa S. Abd-El-Aziz,
University of Winnipeg, and was held in London, Ontario,
Canada, May 29th to June 1st, 2004 on the occasion of the
87th Canadian Institute of Chemistry Meeting. The sympo-
sium attracted 27 top scientists from all over the world as
invited speakers. Two special issues were also published in
Macromolecular Symposia (Volume 209, pages 1–251,
2004), and in the Journal of Cluster Science (JCS, Volume
15, Number 2, pages 61–261, 2004). These issues appeared
at the same time as the conference.
The symposium started with a brief introduction from
Pierre D. Harvey explaining the purposes of the conference.
He focused on the importance and opportunities of both
communities to interact and benefit from each other on
scientific grounds. This new strategy will help scientists
meet the challenges of modern problems and needs. Colla-
borations and exchange of ideas should issue from such an
original symposium, en route towards new materials and
unusual properties. The program consisted of a plenary
lecture, invited lectures and a poster session.
The first session focused on organometallic polymers
and dendrimers. The speakers were Alaa S. Abd-El-Aziz,
‘‘Synthesis of Iron-Containing Polymers with Azo Dyes in
the Backbones or Side Chains’’ (Canada), David R. Tyler,
‘‘Photochemically Degradable Polymers Containing Metal-
Metal Bonds along their Backbones; The Effect of Stress on
the Rates of Photochemical Degradation’’ (USA), Ikuyoshi
Tomita, ‘‘Synthesis and Applications of Polymers Contain-
ing Metallacyclopentadiene Moieties in the Main Chain’’
(Japan), Kimihisa Yamamoto, ‘‘Fine Control of Metal
Assembling in Novel Phenylazomethine Dendrimers’’
(Japan), Ashok K. Kakkar, ‘‘Metallodendritic Materials
for Heterogenized Homogeneous Catalysis’’ (Canada), and
Tara J. Burchell, student from Richard Puddephatt’s
group, ‘‘Self-Assembly of Coordination Polymers and the
Formation of Extended Networks through Secondary
Interactions’’ (Canada).
The second session focused on chalcogenide-containing
clusters. The speakers were Joachim Wachter, ‘‘Metal
Telluride Clusters – From Small Molecules to Polyhedral
Structures’’ (Germany), Minguey M. Shieh, ‘‘Chalcogen-
Containing Manganese Carbonyl Clusters: Synthesis and
Structural Transformations’’ (Taiwan), Pradeep Mathur,
‘‘Some Reactions of Acetylenic Systems with Mixed-Metal
Carbonyls’’ (India), and Andreas Eichhoefer, ‘‘Metal Chal-
cogenide Cluster Molecules’’ (Germany).
The third session exhibited a wide range of topics ranging
from bio-related polymers to materials and surface science.
The speakers were Ian Manners, ‘‘Synthesis and Properties
and Applications of Highly Metallized Cluster-Based
Polymers’’ (Canada), Hiroshi Nishihara, ‘‘Bottom-Up Fab-
rication of Bis(terpyridine)metal Polymer Chains at Gold
Surface and their Electron-Transfer Process’’ (Japan),
Heinz-Berhard Kraatz, ‘‘Hydrogen-Bonded Peptides on
Surfaces’’ (Canada), Mark G. Humphrey, ‘‘Towards Oligo-
clusters – Chemistry and Properties’’ (Australia), Mitsu-
hoko Shionoya, ‘‘Artificial Metallo-DNA towards Discrete
Metal Arrays’’ (Japan), and Boon K. Teo (given by his
student X. H. Sun), ‘‘Zero-Dimensional Nanodots on One-
Dimensional Nanowires: Reductive Deposition of Metal
Nanoparticles on Silicon Nanowires’’ (USA).
Conference Reports: This section contains reports ontopical conferences. Reports are usually written at the requestof the editorial office, but unsolicited contributions are also
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Macromol. Chem. Phys. 2004, 205, 1965–1966 DOI: 10.1002/macp.200400322 � 2004 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Conference Report 1965
Figure 1. A picture of some of the invited speakers.
The fourth session consisted of various topics, including
metal-containing polymers, supramolecular arrangements,
magnetism and electric conductivity. The speakers were
Robert C. Thompson, ‘‘Structure and Magnetism in Coor-
dination Polymers Incorporating Pyridinedicarboxylate
Bridging Ligands’’ (Canada), A. C. W. Leung (student
from Mark J. MacLachlan’s group), ‘‘Conjugated Metallo-
polymers’’ (Canada), Stuart L. James, ‘‘Metal-Containing
Rings, Cages and Nanoporous Polymers Based on Bridging
Phosphines’’ (Ireland), and Zhiping Zheng, ‘‘Supramole-
cular Arrays of Transition Metal Clusters by Design’’
(USA). The session ended with two award lectures. The first
one was presented by Martin Cowie, winner of the Alcan
Award (2003). His lecture was entitled ‘‘Roles of the Adja-
cent Metals in Carbon-Carbon Bond Formation in Hetero-
binuclear Rh/Os, Rh/Rh and Ir/Ru Complexes.’’ (Canada).
The second Alcan Award Lecture was presented by the
winner of the 2004 award, Laurence K. Thompson, ‘‘From
Dinuclear to Triakontahexanuclear Complexes – Adven-
tures in Supramolecular Coordination Chemistry’’
(Canada).
The fifth session was dedicated to cluster chemistry. The
speakers were Arthur J. Carty, ‘‘The Remarkable Coordi-
nating Properties and Reactivity of Electrophilic Amino-
phosphinidene Ligands PNR2’’ (Canada), J. M. Parnis,
‘‘Niobium Cluster Reactions with Ethene: Experimental
and Theoretical Study of Product Mass Distributions as a
Probe of Cluster Reactivity Mechanisms’’ (Canada), Brian
F. G. Johnson, ‘‘Clusters and Nanoparticles in Catalysis’’
(England), Richard D. Adams, ‘‘New Platinum-Ruthenium
and -Rhodium Cluster Complexes: Structures, Molecular
Dynamics and Catalytic Activity’’ (USA), and Michael I.
Bruce, ‘‘Cluster-Capped Carbon Chains’’ (Australia). This
session closed with the Award for Pure or Applied Inorganic
Chemistry Lecture presented by Michael Wolf, ‘‘Metal-
Containing Conjugated Materials: Oligomers, Polymers
and Nanomaterials’’ (Canada).
The sixth session focused on various aspects of cluster
chemistry. The speakers were Michael Veith, ‘‘Siloxanes
and Aminosiloxanes: Rotation and Oscillation of Lithium
Cations in Crystals within Molecular Boxes’’ (Germany),
Laurence F. Dahl, ‘‘New Frontiers in the Preparation/
Stereochemistry of Nanosized Metal Carbonyl Clusters:
Structure-to-Synthesis Approach’’ (USA), Dominique
Lucas, senior researcher in Yves Mugnier’s group,
‘‘Reactivity of the Pd3(dppm)3CO2þ Cluster towards Orga-
nic Halides. Applications to Organic Electrosynthesis’’
(France), David H. Farrar, ‘‘Synthesis and Initial Cluster
Coordination Studies of Indolylphosphines’’ (Canada), and
John F. Corrigan, ‘‘New Silylated-Chalcogen Reagents for
Metal-Chalcogen Nanocluster Assembly’’ (Canada).
Pierre D. Harvey closed the symposium by thanking
speakers, chairs, participants and sponsors. He stressed the
importance of finding new ideas from each other special-
ities and collaborations.
Pierre D. Harvey
Universite de Sherbrooke
Alaa S. Abd-El-Aziz
University of Winnipeg
Figure 2. A picture at the poster session of Patrick Shipman,University of Winnipeg and Pierre D. Harvey, Universite deSherbrooke.
1966 Conference Report
Macromol. Chem. Phys. 2004, 205, 1965–1966 www.mcp-journal.de � 2004 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim