hydrogen refueling cost shanghai
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Chinas cup is defnitely hal ull. They are embarking on the greatest growth in
the history o mankind. By 2025 China will build 221 cities with a million or more
people and 15 mega cities with populations o over 10 million. In contrast, Europe
has 35 cities with over a million people. To create these cities massive inrastructure
will have to be developed. China will build over 50,000 skyscrapers which is the
equivalent o 10 New York Cities.
From 1990-2005 Chinas urban population more than doubled rom 254 million people
to 572 million people. According to McKinsey Research, China will have 15 cities withpopulations over 10 million and 11 o which could have 25 to 35 million people by 2025.
In total these 15 cities would have a combined population greater than the entire United
States. (Exhibit 1)
Shanghai would be almost as large as the country o Spain. Chinas energy demands wi
more than double or 2025. Oil consumption will increase rom 6.9 million gallons a day
to 12 million gallons a day.
The ormula or Chinas success is a strong government commitment and a tremendous
thirst or a growth that is ueled by water. Water is the lieblood o all existence. Withou
water there would be no electricity, gasoline, nuclear power or a population that exceeds
1.2 billion in China. Clearly China aims to tap into H20.
China has approximately 300 million people with no access to water. Even though Chinahas 6% o the worlds total water resources, its large population means that the country
only has 25% o the worlds average water resources per capita. The UN lists China as
one o 13 countries that is experiencing serious water scarcity. O the 661 cities in China
33% are scarce o water, while 17% o China is regarded as badly scarce o water.
Chinas Thirst or Water
1
Source: Getty Images
Source: McKinsey Global Institue China All City Model, McKinsey Global Institute analysis
Mega (10+)
Population by city size
Millions o people, %
100% =
Compound annualgrowth rate, %
Big (5-10)
Midsized(1.5-5)
Small(0.5-1.5)
Big town(
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2
Also, Chinas water resources are not evenly distributed across
the country. The north and northeast Chinese region holds only~5% o the countrys water resources although it is home to
40% o the population. North Chinas resh water resources are
only 25% o the amount o water available in Southern China.
This dierence in is the number o rivers and precipitation.
Northern China is also home to the heavy industrial sector
which requires greater water output than Southern China.
Chinas water demand in 2030 is expected to reach 818 billion
m3, o which just over 50% is rom agriculture (o which almost
hal is or rice), 32% is industrial demand driven by thermal
power generation, and the remaining is domestic. Current supply
amounts to just over 618 billion m3. Signicant industrial and
domestic wastewater pollution makes the supply-demand gapeven larger than the quantity. Twenty-one percent o available
surace water resources nationally are unt even or agriculture.
Thermal power generation is by ar the largest industrial water
user, despite the high penetration o water-ecient technology,
and is very water challenged.
Industrial water demand in 2030 is projected at 265 billion m3
which accounts or 40% o the additional industrial demand
worldwide. Demand or water or domestic use will decrease
rom 14% today to 12% in 2030. (Exhibit 2)
The annual rate o eciency improvement in agricultural water
use between 1990 and 2004 was approximately 1% across
both rain-ed and irrigated areas. A similar rate o improvement
Water Resource Volume(km3/yr)
Renewable natural resources 2,700*
Groundwater (renewable, actual) 109*
Surace water (renewable, actual) 2,611*
Higher quality nonconventional resources
Desalination 0.102**
Reuse tertiary or better 3.710***
Total nonconventional resources 3.812
Withdrawal
Total annual groundwater withdrawal 107*
Total annual surace water withdrawal 473*
Source: * Ministry o Water Resources, 2008.
** Estimates based on quotations rom ofcial sources, 2009.
By the end o 2008 the daily capacity was 280,000 m3/d. In the
middle o 2007 the capacity was nearly 200,000 m 3/d, and at the
beginning o 2007 the daily capacity was 160,000 m3/d.*** Ministry o Water Resources, 2008 (Around 45% o this
treated waterwater is currently reused)
Supply and Demand
Water Supply
From 2007 to 2008, Chinas total water resources increased by 7.7%,
and its average precipitation increased by 6% to 646.4 mm. There is
an 87% overlap between groundwater and surace water. At the end
o 2008, the 496 large reservoirs in the country reserved 271 km o
water, which is 29.5 km more than was reserved in 2007. Chinas total
water withdrawal in 2008 was 583 km, which is 0.9 km more than the
water withdrawal in 2007.
Sector % Demand Volume
(km3
/yr)
Agriculture 62.1 362
Industrial 23.6 138
Domestic 12.5 73
Replenishment* 1.8 10
Total annual use 100.0 583
* Water or environmental use, such as the replenishment o surace water or groundwater.
Source: Ministry o Water Resources, 2008
Sectoral Water Use
Chinas cities account or 58.9% o the countrys domestic water
demand, while the counties account or the remaining 41.1% o domestic
consumption. Compared with gures rom 2007, the water used or
agricultural, industrial, domestic and environmental replenishment has
increased by 2.1 km3 in 2008. The water consumption per capita was
440 m3/c/yr, and 225 m3/yr o water was needed or each CNY 10,000
GDP output. This gure is 8.1% less than in 2007.Municipal &Domestic
Existingwithdrawals2
2030withdrawals3
Basins withdefcits
Basins withsurplus
Existingaccessible,
reliable,
sustainable
supply1
Relevant supply quantityis much lower than the
absolute renewable wateravailablity in nature
Ground-water
Suracewater
Billion m3, 154 basins/regions
1 Existing supply which can be provided at 90% reliabili ty, based on historical hydrology and inrastructureinvestments scheduled through 2010; net o environmental requirements
2 Based on 2010 agricultural production analyses rom IFPRI3 Based on GDP, population projections and agricultural production projections rom IFPRI; considers no water
productivity gains between 2005-2030
Source: Water 2030 Global Water Supply and Demand model; agricultural production based on IFPRI IMPACT-
WATER base case
Agriculture
Industry
2%
40%
4,500
CAGR
6,900
900
1,5002,800
4,500
4,200
700
3,500
800
3,100
Exhibit 2: Aggregated global gap between existing accessible,
reliable supply1 and 2030 water withdrawals, assuming no
efciency gains
100600
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Chinas Thirst or Water
3
occurred in industry. I agriculture and industry could sustain
this rate to 2030, improvements in water eciency wouldaddress only 20% o the supply-demand gap, leaving a large
decit to be lled.
Chinese industry is extremely inecient in water use, recycling
only 25% o their water compared with an average o 85% in
developing countries. In 2002, Beijing opened its public-sector
water industry to private and western investment. By 2008,
private and oreign interests had stakes in 20% o Chinas public
water utilities and 70% o the wastewater utilities.
China Recognizes the Problem
In the late 1990s China adopted the public-private partnership(PPP) contracts to build enough water and wastewater plants.
In 2007, China raised its national standards or drinking water
and established an inspection network to monitor water quality.
The Health Ministry added 71 benchmarks to the 35 already
required under previous standards.
The eleventh ve-year plan and economic crisis stimulus
package created the growth o Chinas wastewater treatment
industry. However, there are still 167 cities without wastewater
treatment plants (WWTPs). According to the Ministry oHousing and Urban-Rural Development, the existing plants are
only 72% in operation because there is a lack o pipe works to
deliver the wastewater to the plants.
The Chinese economic stimulus package o 4 trillion yuan
or $585 billion, ocused nearly 40% o its spending on
environmental and energy-ecient projects. Over the next two
decades the Chinese government will und 1 trillion RMB in
urban water inrastructure rom (151 billion U.S. dollars).
Pollution is actor taxing water in China. O the seven wate
systems in China, 55% o the water had a water quality grade
o I-III in 2008, 24.2% o Chinas water was graded IV-V, while
20.8% o the water received a grade worse than V. Grade I reers
to the natural water resources protected by the state. Grade I
and III also reer to water resources that could be used to make
drinking water and to sustain the aquatic eco-system, but these
grades are not deemed as important as grade I. Grade IV wate
is only or industrial use, and grade V water is only or agricultura
use. Any grade considered worse than V is unsuitable or use.
State Council
State-owned AssetsSupervision and AdministrationCommission o the State Council
Provincial State-owned AssetsSupervision and Administration
Commission
Urban State-owned AssetsSupervision and Administration
Commission
District or County State-ownedAssets Supervision and
Administration Commission
National Developmentand Reorm Commission
Provincial Developmentand Reorm Commission
Urban Developmentand Reorm Commission
District or County Developmentand Reorm Commission
Ministry o EnvironmentalProtection
Provincial Department oEnvironmental Protection
Urban Bureau oEnvironmental Protection
District or County Bureau oEnvironmental Protection
Ministry o Housing andUrban-Rural Development
Provincial Department oHousing and
Urban-Rural Development
Urban Bureau o Housing andUrban-Rural Development
District or County Bureau oHousing and
Urban-Rural Development
Ministry o Water Resources
Provincial Departmento Water Resources
Urban Bureau oWater Resources
District or County Bureauo Water Resources
Source: Adapted rom www.gov.cn
Water Sector Organization and Structure
Government ministries and agencies
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Due to a lack o wastewater plants, pipe works and eective
supervision, it is not unusual or residential and industriawastewater to be discharged directly into the environment
About 70% o Chinas lakes and rivers are contaminated, and
hal o Chinese cities rely on polluted groundwater. Citing the
World Bank, the report notes that 54 billion tons o untreated
waste were directly dumped into Chinas lakes and rivers in
2006. About a quarter o Chinas population, 300 million, drink
contaminated water every day. Almost two-thirds o these
all ill, it said. Chinese authorities call the abled Yangtze Rive
cancerous. Chemical and oil disasters are seemingly endless.
The expected rapid urbanization during the 12th Five-Yea
Plan (2011-2015) will threaten the security o Chinas wate
resources, government authorities have said. Pollution controand prevention guidelines on eight major rivers and lakes across
the country or the next ve years were jointly released by
the ministries o Environmental Protection, Water Resources
Agriculture, Housing and Urban-Rural Development, Industry
and Inormation Technology, and the National Development and
Reorm Commission.
All the plans mentioned that rapid urbanization and ast economic
development are posing great challenges to water protection in
the eight rivers and lakes, including Haihe River near Beijing and
Huaihe River, which marks the boundary between Chinas north
and south.
The volume o pollutants in these waterways during the nexve years will increase by 35 to 40% due to the industrialization
and urbanization in the Haihe River area, according to the plan
or that water system. The plan or the Yellow River said rapid
economic development along the river area would create a
water shortage o about 14 billion cubic meters by 2030.
According to the plan or Liaohe River, which fows through
Liaoning province, breakneck GDP growth will increase the
pressure on the river system. Water pollution has long been a
problem or authorities.
At the end o 2007, about 9.5 million urban residents living along
the Huaihe River aced the problem o unsae drinking water
the plan said. The situation was worse in rural areas. A our-year
study released by the China Geological Survey showed that
only 24% o the underground water in the North China Plain is
sae or direct drinking as excessive heavy metal and chemica
ertilizers were ound in most water resources.
Ammonia and nitrogen tested in the eight rivers were high
lighted on a black list o water pollutants, the plans said. Abou
30% o the monitored spots along the Yangtze River were ound
to have excessive ammonia and nitrogen, mainly caused by
domestic waste and excessive use o ertilizers.
Water distributionnetworks (new buildand rehabilitation)
16
35,000
30,000
25,000
20,000
15,000
10,000
5,000
007
$millions
Year
08 09 10 11 12 13 14 15
Water resources(including desalination)
Water treatmentplants (new andrehabilitation)
Drinking water capital expenditure
Wastewater capital expenditure
16
20,000
15,000
10,000
5,000
007
$millions
Year
08 09 10 11 12 13 14 15
Wastewater networks(new and rehabilitation)
Wastewater treatment plants(other)
Source: GWI Global Water Market 2011
Industrial and municipal capital expenditure
60,000
50,000
40,000
30,000
20,000
10,000
007
$millions
Year
08 09 10 11 12 13 14 15 15
Municipal capital expenditure Industr ial capital expenditure
Market Forecast or Capital Expenditures
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Chinas Thirst or Water
5
Beijing surpasses other Chinese cities in terms o its wate
reuse development. In 2008 Beijing used 620 million m owater, which accounted or 18% o the countrys total wate
withdrawal. Another 30 million m is expected to be added to
this total by the end o 2009. According to Beijings municipa
government, all o the wastewater treatment plants in the city
will be upgraded to water reuse plants in the near uture. Then
the total amount o available reclaimed water will be 2 km/yr
Most o the big water reuse plants are in Beijing. Other cities
like Tianjin, Qingdao and Dalian also advocate the water reuse
industry, but the plants are either small or or industrial use only
Water is an Essential Ingredient or Manuacturing
& Chinas Growth
Paper: China is now the biggest paper manuacturer in the
world. At present there are 3,500 paper manuacturers all ove
China. Thirteen provinces each produce at least 1 million tons
o paper and paperboard, contributing to 91% o the nationa
output. It is predicted that Chinas paper output will reach 100
million tons in 2020. Currently, the paper industrys wate
consumption is 10 times larger per unit o paper production
than that o developed countries.
Chemicals:There are 21,000 chemical manuacturers in China
o which 80-90% are small companies with an annual revenue
o less than CNY 50 million. The large chemical manuacturers
are either state-owned or owned by oreign companies. Toreduce production costs, hal o these manuacturers are
located along the Yangtze River and Yellow River. In the past
the industry was celebrated due to its incredible contribution
to GDP growth and tax collection. The government is now
aware o the negative aspects o the industry, such as high
water consumption and pollution.
In some parts o Huaihe River, the amounts o ammonia and
nitrogen were more than 10 times the national standard or
surace water, posing dangers to water saety. Industrial pollution
and domestic waste accounted or 75% o these pollutants.
Li Shanzheng, proessor with the Beijing Hydraulic Research
Institute, told China Daily that water shortages in China were
severe. Saving water and nding ways to recycle it will help to
alleviate the pressure the country is acing, Li said, adding that
the nation needs more sewage treatment plants.
According to the World Bank, water pollution directly causes
66,000 deaths annually in China rom cancer and dysentery.
Lack o clean water already idles as much as 15% o Chinas
armland each year, and temporary and permanent industry
shutdowns are common. The World Bank estimates, water
pollution and shortalls currently cost the country $22 billion
U.S. dollars, or 1.1% o total GDP, while crop and shery losses
rom water shortages and pollution, including acid rain, cost
another $6 billion USD each year.
New to Water Management
Seawater desalination is somewhat new to China. The rst
seawater desalination plant was built in 1982 on Woody Island o
the Xisha Islands, with a capacity o 200 m/d. Most o the plants
are currently provided consulting services by two institutes: the
southern Development Center o Water Treatment Technology,
Hangzhou, and the northern Institute o Seawater Desalination
and Multipurpose Utilization, SOA (Tianjin). The existing
seawater desalination plants mostly provide water or industrial
use. Only a ew small plants provide water or municipal use, to
serve small counties.Source: Jupiter Images
Worse than V
100
90
80
70
60
50
40
30
20
10
0
IV to V I to III
Water Quality o the Seven Water Systems
Source: Ministry o Water Resources, P.R.C.
%
Pearl Yangtze Songhua Yellow Huai Liao Hai
River River River River River River River
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Textile: The textile industry accounts or 8.5% o the total
amount o water used by industry, and 10% o the total
industrial discharge. China has 50,000 enterprises in the textile
industry, and 99.5% o them are small businesses. Guangdong,
Jiangsu, Zhejiang, Fujian, Shandong and Shanghai contribute to
80% o the total output o the country. A recent trend in the
textile industry is a move in location rom the south-east to the
north-west o China.
Power generation: This is the biggest consumer o water; 87%
o power in China comes rom coal-red plants. There are our
tiers in the power industry. The rst tier includes ve national
power corporations: Huaneng, Datang, Guodian, Huadian
and China Power Investment Corporation. These corporations
account or 42.5% o the total output o the country. The
second tier includes newly rising power groups such as Huarun,
Shenhua, State Development & Investment Corporation and
China Guangdong Nuclear Power Holding Co., Ltd. The second
tier accounts or 10.2% o the total power output. The third tier
is composed o nearly 50 regional power groups accounting or
27% o the total power output, The ourth tier is comprised o
private and oreign invested power enterprises.
Food and beverage: The industry includes agricultural product
process, ood stu manuacturing and beverage manuacturing.
Serving 1.3 billion people with ood and beverages, it is a huge
market. However, the manuacturers discharge non-treated
wastewater into the very environment rom which they draw
their water resources. To improve this, the central government
has set the ood and beverage industry the target o reducing
their water consumption by 30% or each CNY o industrial
value added and 10% o pollutants discharged. This has created
a market or water reuse acilities.
Plans to reroute rivers compound the water shortage. The Grand
Canal, a vital route o commerce rom Beijing to Shanghai or
more than 1,500 years, has been slated as the eastern branch
o the North-South Water Transer Project that will transer
water rom the Yangtze River to the Beijing area. However, the
severely polluted water is eectively unusable even i the project
is nished. The overall project also includes a central componen
to divert water rom a tributary o the Yangtze River to Beijing
which will dislocate hundreds o thousands o Chinese and is
scheduled or completion in 2014.
China Plans Ahead
Its not well known that China has set aside more money or
the adoption o clean technologies than any other country on
the planet, said Dallas Kachan, managing director o Cleantech
Group in San Francisco, which tracks global investment in clean
technologies.
China would like to achieve an urban water supply coverage rate
o at least 95%, and add 40 million m/d to the water supply
capacity. Urban water supply pipes that are more than 50 years
old should be rehabilitated, and the average urban leakage rates
should be kept below 15%. The estimated budget or these
water supply issues is CNY 200 billion.
Water reuse: Reuse 10-15% o treated wastewater in wate
scarce northern cities (China denes cities with less than 3,000
m o water resources per capita as water scarce). Meanwhile
the country aims to reuse 5-10% o treated wastewater in
southern seaside cities experiencing water scarcity. In 2015
China plans to increase these percentages to 20-25% in
northern cities, and 10-15% in southern cities. China also aims
to add 6.8 million m/d o reclaimed water to the 2005 capacity
by building water reuse plants or upgrading existing waste
water treatment plants.
Wastewater treatment: Build wastewater treatment acilities
in all cities and counties, and add 45 million m/d to the 2005
capacity by expanding existing plants or building new ones. Othe
aims include building 1,000 WWTPs, investing CNY 300 billion
($440 billion U.S. dollars) in wastewater treatment inrastructure
Source: Getty Images, Photos.com
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Chinas Thirst or Water
7
and not pricing the wastewater treatment tari below CNY 0.80/
m in all cities.
Seawater desalination: Achieve a total capacity o 800,000-
1,000,000 m/d, or both municipal and industrial uses. China
also plans to use 55 km/yr o seawater (desalination is not
necessary here, as seawater can be used as cooling water). In
2020, China hopes to increase the total capacity o its seawater
desalination to 2,500,000-3,000,000 m/d, and to increase its
use o seawater to 100 km/yr. Any revenue rom seawater
desalination projects will be ree o income tax.
Industrial water: Keep the annual growth rate o industrial
added value at 10%, while keeping the growth rate o industrial
water withdrawal within 1.2%. China aims to recycle 70% o
water used by industry (which is separate rom the water reuse
targets mentioned previously).
Pollution: Reduce the three million tons o pollutants in discharged
wastewater and the one million tons o pollutants in discharged
industrial wastewater. The pollutants include chemical oxygen
demand (COD), suspended solids (SS), biological oxygen
demand (BOD), lead, arsenic, cadmium, phosphorus, nitrogen,
pH, coliorm, hydrargyrum and chrome.
How to Achieve Chinas Water Requirements
The production o energy requires large volumes o water.
Thermoelectric cooling, hydropower, energy mineral extraction
and mining, uel production and emission controls all rely
on signicant amounts o water. According to the National
Renewable Energy Lab, electricity production rom ossil uels
and nuclear energy requires 190,000 million gallons o water
per day; accounting or 39% o all reshwater withdraws in
the nation. In many regions o the country, we use as much
water turning on the lights and running electric appliances in ouhomes, as we use in taking showers and watering lawns.
O this, 72% is or ossil uels related energy production and
coal accounts or 52% o all US energy generation. Each kWh
o energy generated by coal requires 25 gallons o water
This is both a water quantity and a water quality issue. The
amount o water usage is oten o great concern or electricity
generating systems as populations increase and droughts
become a concern. Still, according to the USGS, thermoelectric
power generation accounts or only 3.3% o net reshwate
consumption with over 80% going to irrigation.
General numbers or resh water usage o dierent powe
sources are shown below. All thermal cycle plants (nuclear, coal
NG, solar thermal) require large amounts o water or cooling
and condensing. However, the amount o water needed is
reduced as boiler temperatures are increased. Thereore, coal
which burns at very high temperatures, is more ecient and
requires less water use.
Natural drat wet cooling towers at many nuclear power plants
and large ossil uel red power plants use large hyperbolic
chimneys that release the waste heat to the ambien
atmosphere by the evaporation o water. In areas with restricted
water use a dry cooling tower or radiator, directly air cooled, may
be necessary, since the cost or environmental consequences
o obtaining make-up water or evaporative cooling would be
prohibitive. These have lower eciency and higher energy
consumption than a wet, evaporative cooling tower.
Source: Corbis
Power Average
Source Gal/MW-h
Nuclear 400-720
Coal 390
Natural Gas 140
Hydroelectric 1430
Solar Thermal 1060
Geothermal 2900
Biomass 390
Photovoltaic 30
Wind 1
Source: U.S. Department o Energy
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Where economically and environmentally easible, electric
companies preer to use cooling water rom a lake or river or
a cooling pond, instead o a cooling tower. This type o cooling
can save the cost o a cooling tower and may have lower energy
costs or pumping cooling water through the plants heat
exchangers.
However, the waste heat can cause the temperature o the
water source to rise detectably upon discharge. Power plants
using natural bodies o water or cooling must be designed to
prevent intake o organisms into the cooling cycle. To urther
complicate environmental matters, organisms that adapt to thewarmer plant water may be injured i the plant shuts down in
cold weather.
Thermal cycle plants require water or cooling, but it does not
have to be resh water. A power generation site located on the
coast has the option to use seawater. Such a site would not use
cooling towers. (There is the added benet that discharge water
temperatures would have less eect on the environment).
Japanese nuclear power stations, or instance, do not use
cooling towers at all because all o the plants are located on the
coast. I dry cooling systems are used, signicant water rom
the water table will not be used. Other, more novel, cooling
solutions exist, such as sewage cooling at the Palo VerdeNuclear Generating Station.
In recent years, recycled wastewater, or grey water, has been
used in cooling towers. The Calpine Riverside and the Calpine
Fox power stations in Wisconsin and the Calpine Mankato power
station in Minnesota, as well as the Peterborough Power Station
in the UK are among these acilities. The chemical industry
continues to nd creative ways o recycling and reusing grey
water waste streams. Dow recently began operating a novel
system or reusing municipal wastewater at the Terneuzen site in
the Netherlands. In collaboration with local authorities and a locawater producer, this site accepts more than 2.6 million gallons
o municipal household wastewater every day. The local wate
producer removes residual contaminants and Dow then uses
more than 70% o this water to generate high pressure steam.
In early 2010, Dow Water and Process Solutions introduced
DOWEX 650C and DOWEX 550A or a nuclear power plan
through CHEC. The technologies have proven a great success
and have helped Dow Water and Process Solutions become
the number one provider o CPP system products to the China
Guangdong Nuclear Power Group (CGN).
Lower Energy Membrane Technology
The overall thermodynamic eciency o the process is abou
20%. Large amounts o energy are needed to generate the high
pressure that orces the water through the membrane. Curren
methods require anywhere rom 8 to 20 kilowatt-hours o
energy to produce 1,000 gallons o desalinated seawater. This
depends on the quality o water to be treated. However, gains
can be achieved through the separation unit. The loss here is the
energy needed to push the water through the membrane. This
can be reduced by designing a thinner membrane as part o a
better lter system.
The key ocus in desalination is around recovery o energy, reuse
and minimizing the amount o mechanical energy required in
the separation unit. As a process scales up, the cost is reduced
This is true or water purication as well, but what you might no
realize is just how massive that scale is. The Ashkelon Seawater
reverse osmosis plant is the largest desalinization plant in the
world and uses Dow ltration membranes.
Pressure-driven Membrane Separation
Source: Dow Water & Process Solutions
Source: SXC
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Chinas Thirst or Water
9
This plant provides greater than 15% o the water needs o
Israel rom the Mediterranean Sea. They produce more waterevery year than Dows entire output combined at a cost o
60-70 US cts/m3 compared to desalination plants at 80-90 cts/
m3. In a typical desalinization process, 50% o the water that is
pumped into the system is discharged as brine waste. This ratio
is crucial to avoid salt precipitation and membrane ouling.
Obviously the pressure used to orce this wastewater through
the system is a signicant loss. With these processes, the
water is again used in cooling towers until it nally evaporates
into the atmosphere. This is the rst time municipal wastewater
has been reused on such a large scale in the industry. Three
million tons o water per year was previously discharged into
the North Sea ater a single use. Now this water is recycled ortwo more applications and has resulted in 65% less energy use
at this aculty compared to the alternative option o desalinating
seawater. The reduction in energy use is the equivalent o
lowering carbon dioxide emissions by 5,000 tons per year.
Utilizing Energy Reducing Technologies
The water supply also requires energy use. A large amount o
energy is needed to extract, treat, and deliver potable water.
Additionally, energy is required to collect, treat, and dispose
o wastewater. In the United States, our percent o all power
generation is used or water supply and treatment and 75% o
the cost o the municipal water processing and distribution iselectricity. There are two keys areas where advances in chemical
engineering can acilitate decreased energy requirements or
water processing. These are in water treatment, specically
in the desalination o salt water, and in the treatment o
contaminated water and wastewater or re-use.
Three key technologies or water treatment are Reverse
Osmosis, Ion Exchange and Ultraltration. Reverse osmosis
one o the primary technologies behind seawater desalination
is also used or wastewater treatment and recycling. Ion
exchange technology involves the reversible exchange o ions
between a solid (the ion exchange resin) and a liquid. This
technology is ideally suited or removal o contaminants andprovides a wide variety o treatment solutions or healthcare,
nutrition, ood and beverage, mining, chemical processing,
industrial water and municipal water.
Ultraltration is a pressure driven membrane separation process
that separates particulate matter rom soluble components in
the carrier fuid (such as water). UF membranes typically have
pore sizes in the range o 0.01 - 0.10 m and have a high removal
capability or bacteria and most viruses, colloids and silt (SDI).
Dow Ion Exchange Resin Beads
Source: Dow Water & Process Solutions
Source: Dow Water & Process Solutions
Dow Reverse Osmosis Membrane
Dow Ultrafltration Fibers
Source: Dow Water & Process Solutions
Energy Reducing Technologies
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10
Advances in Reverse Osmosis
The single largest cost or seawater desalinization is the energy
cost. And even though reverse osmosis is the lowest cost
separation process, there is still room or improvement. It is
interesting to take a step back and determine just where in the
process the energy is used. A process has been designed to
pressurize waste stream and is used to pressurize the seawater
that is coming into the system. In this way we can recover
between 95-99% o the 28.11 kw/m3 o energy that would
be lost. This has been a huge breakthrough or desalination.
Reverse osmosis membranes are being used in three major
wastewater reclamation and resuse acilities in the city o
Beijing. These novel membranes consist o three layers.
The major structural support is provided by a non-woven polyesterweb. Because this web is too irregular and porous to provide a
proper substrate or the salt barrier layer, a polysulone interlayer is
cast onto the surace o the web. The interlayer is an engineering
plastic with pore diameters controlled to approximately 150
Angstroms. The nal layer is a polyamide that acts as the salt
barrier; this layer is only 2,000 Angstroms thick but can withstand
the high pressures because o the underlying support.
The membrane materials have been continuously updated
and rened to improve eciency through higher rejection,
improved fux and low ouling perormance. They will be used to
treated 45,000 m3 o water per day at three sites BeiXiaoHe
Wastewater Treatment Plant, Beijing International Airport andthe Beijing Economic-Technological Development Area. This
technology will help the city reach its goal o reusing hal o its
water, signicantly extending this limited natural resource.
New approaches to reduce the energy ootprint o water
treatment systems involves capturing waste energy throughout
the treatment process. Innovative desalination technologies
that use low-grade or waste heat instead o electricity have
the potential to substantially reduce energy inputs, yielding
a more environmentally benign process and lower operation
costs. Other important technologies include energy recovery
devices in desalination plants, microbial uel cells that eed
o wastewater and cogeneration plants co-located withwastewater treatment acilities.
Technologies to Reduce Purifcation Costs
Interestingly, one o the key applications o reverse osmosis
and ultraltration technology is in the production o ultra pure
water or ossil uel and nuclear power generation. These water
treatment technologies help power plants utilize available water
supplies eciently. Ultraltration, used in many municipal
potable water plants, is even less costly puriying up to a trillion
pounds o water per year at a cost o 1/1000 o a cent per poundIon exchange resins can be used to demineralize water or ossi
and nuclear power plant boiler eedwater, cooling tower wate
treatment and eedwater or industrial boilers and cogeneration
plants. They are also used in condensate polishing, which allows
the reuse o steam condensate rom power plant boilers to
reduce the overall cost o producing puried boiler eedwater.
These resins also help uranium mining operations use less
water and generate less waste and enable the production
o high purity uranium used in nuclear power applications
helping meet the increasing global demand or energy. The bes
resins have the best bed kinetics and thereore operate more
eciently, giving longer runs and greater operating economy.
Ultraltration eciency is based on a balance o pore diamete
and porosity. In order to eectively remove pathogens, viruses
and bacteria, the pore size must be at approximately the 0.03
micron level. But the same membrane must have a high 50%
porosity in order to allow high fux at a given transmembrane
pressure. The material used or modular lters is key it mus
have the high porosity and be breakage resistant, especially
during cleaning to avoid ouling.
Creating Sustainability
Modern water treatment technology and distribution inrastructure
have allowed us to conquer disease, to build advanced industria
economies and to dramatically increase standards o living o
many o the worlds people. Pushing the limits o water through
science has also improved irrigation techniques making it possible
to eed a rapidly growing population, turn deserts into inhabitable
lands and to quench the thirst o large metropolitan areas. And
the latest technologies have allowed us to minimize the wate
needed or electricity generation while continuing to provide
energy to a burgeoning population.
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Chinas Thirst or Water
11
Industrial water 4.6%
Bottled water 3.5%
Point o use equipment 2.5%
Irrigation equipment 1.5%
Utilities 88.0%
Water opex 18.5%
Wastewater opex 7.4%
Drinking water capex 40.6%
Wastewater capex 33.5%
$47,831m
$42,068m
$32,346m
$2,188m
Total water market(2010)
Utility market(2010)
Combined capex(2010)
Industrial market(2010)
Services 6.1%
Chemicals 39.5%
IndustrialEquipment 54.5%
Equipment 22.4%
Site work 20.2%
Pipes 20.9%
Pumps & valves 12.4%
Pipe rehab services 18.9%
Proessional/other 5.3%
WTPs 9.2%
Water resources/other 10.7%
Water network rehab 28.5%
New water networks 6.5%
WWTPs 21.1%
New wastewater networks 11.3%
Waterwater network rehab 10.1%
Other waterwater 2.6%
$31,154m
$6,872m
Utility capex(2010)
Equipment market
(2010)
Other equipment 27.5%
Standard process equipment 26.6%
Headworks/screens 6.2%
Filtration systems/media 6.1%
Meters 7.4%
Sludge management 16.6%
Disinection 7.2%
Membranes 2.4%
Source: GWI Global Water Market 2011
Appendix
Market orecast breakdown, 2010
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Toll-ree telephone number or the ollowing countries: Austria, Belgium, Denmark, Finland, France, Germany, Hungary, Ireland, Italy, The Netherlands
Norway, Portugal, Spain, Sweden, Switzerland, and the United Kingdom
NOTICE: The use o this product in and o itsel does not necessarily guarantee the removal o cysts and pathogens rom water. Eective cyst and pathogen
reduction is dependent on the complete system design and on the operation and maintenance o the system.
NOTICE: No reedom rom any patent owned by Dow or others is to be inerred. Because use conditions and applicable laws may dier rom one
location to another and may change with time, Customer is responsible or determining whether products and the inormation in this document are
appropriate or Customers use and or ensuring that Customers workplace and disposal practices are in compliance with applicable laws and
other government enactments. The product shown in this literature may not be available or sale and/or available in all geographies where Dow
is represented. The claims made may not have been approved or use in all countries. Dow assumes no obligation or liability or the inormation
in this document. Reerences to Dow or the Company mean the Dow legal entity selling the products to Customer unless otherwise
expressly noted. NO WARRANTIES ARE GIVEN; ALL IMPLIED WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE
ARE EXPRESSLY EXCLUDED.
Published April 2011
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*
Sources
Dow Water & Process Solutions Water Energy Nexus, 2011
Dow Water & Process Solutions Global Climate presentation
Charting Our Water Future, McKinsey Research
Report to Congress on the Interdependency o Energy & Water
U.S. Department o Energy
Taming the Water Dragons: Opportunities & Challenges in the
Chinese Water Sector-Lux Research
Global Market 2011-Global Water Intelligence
New York Times
China Daily
Milwaukee Journal
USA Today
World Bank
World Health Organization
United Nations
Cleantec Corporation