hydrogen refueling cost shanghai

Upload: lte002

Post on 03-Apr-2018

219 views

Category:

Documents


0 download

TRANSCRIPT

  • 7/28/2019 Hydrogen Refueling Cost Shanghai

    1/12

    Chinas cup is defnitely hal ull. They are embarking on the greatest growth in

    the history o mankind. By 2025 China will build 221 cities with a million or more

    people and 15 mega cities with populations o over 10 million. In contrast, Europe

    has 35 cities with over a million people. To create these cities massive inrastructure

    will have to be developed. China will build over 50,000 skyscrapers which is the

    equivalent o 10 New York Cities.

    From 1990-2005 Chinas urban population more than doubled rom 254 million people

    to 572 million people. According to McKinsey Research, China will have 15 cities withpopulations over 10 million and 11 o which could have 25 to 35 million people by 2025.

    In total these 15 cities would have a combined population greater than the entire United

    States. (Exhibit 1)

    Shanghai would be almost as large as the country o Spain. Chinas energy demands wi

    more than double or 2025. Oil consumption will increase rom 6.9 million gallons a day

    to 12 million gallons a day.

    The ormula or Chinas success is a strong government commitment and a tremendous

    thirst or a growth that is ueled by water. Water is the lieblood o all existence. Withou

    water there would be no electricity, gasoline, nuclear power or a population that exceeds

    1.2 billion in China. Clearly China aims to tap into H20.

    China has approximately 300 million people with no access to water. Even though Chinahas 6% o the worlds total water resources, its large population means that the country

    only has 25% o the worlds average water resources per capita. The UN lists China as

    one o 13 countries that is experiencing serious water scarcity. O the 661 cities in China

    33% are scarce o water, while 17% o China is regarded as badly scarce o water.

    Chinas Thirst or Water

    1

    Source: Getty Images

    Source: McKinsey Global Institue China All City Model, McKinsey Global Institute analysis

    Mega (10+)

    Population by city size

    Millions o people, %

    100% =

    Compound annualgrowth rate, %

    Big (5-10)

    Midsized(1.5-5)

    Small(0.5-1.5)

    Big town(

  • 7/28/2019 Hydrogen Refueling Cost Shanghai

    2/12

    2

    Also, Chinas water resources are not evenly distributed across

    the country. The north and northeast Chinese region holds only~5% o the countrys water resources although it is home to

    40% o the population. North Chinas resh water resources are

    only 25% o the amount o water available in Southern China.

    This dierence in is the number o rivers and precipitation.

    Northern China is also home to the heavy industrial sector

    which requires greater water output than Southern China.

    Chinas water demand in 2030 is expected to reach 818 billion

    m3, o which just over 50% is rom agriculture (o which almost

    hal is or rice), 32% is industrial demand driven by thermal

    power generation, and the remaining is domestic. Current supply

    amounts to just over 618 billion m3. Signicant industrial and

    domestic wastewater pollution makes the supply-demand gapeven larger than the quantity. Twenty-one percent o available

    surace water resources nationally are unt even or agriculture.

    Thermal power generation is by ar the largest industrial water

    user, despite the high penetration o water-ecient technology,

    and is very water challenged.

    Industrial water demand in 2030 is projected at 265 billion m3

    which accounts or 40% o the additional industrial demand

    worldwide. Demand or water or domestic use will decrease

    rom 14% today to 12% in 2030. (Exhibit 2)

    The annual rate o eciency improvement in agricultural water

    use between 1990 and 2004 was approximately 1% across

    both rain-ed and irrigated areas. A similar rate o improvement

    Water Resource Volume(km3/yr)

    Renewable natural resources 2,700*

    Groundwater (renewable, actual) 109*

    Surace water (renewable, actual) 2,611*

    Higher quality nonconventional resources

    Desalination 0.102**

    Reuse tertiary or better 3.710***

    Total nonconventional resources 3.812

    Withdrawal

    Total annual groundwater withdrawal 107*

    Total annual surace water withdrawal 473*

    Source: * Ministry o Water Resources, 2008.

    ** Estimates based on quotations rom ofcial sources, 2009.

    By the end o 2008 the daily capacity was 280,000 m3/d. In the

    middle o 2007 the capacity was nearly 200,000 m 3/d, and at the

    beginning o 2007 the daily capacity was 160,000 m3/d.*** Ministry o Water Resources, 2008 (Around 45% o this

    treated waterwater is currently reused)

    Supply and Demand

    Water Supply

    From 2007 to 2008, Chinas total water resources increased by 7.7%,

    and its average precipitation increased by 6% to 646.4 mm. There is

    an 87% overlap between groundwater and surace water. At the end

    o 2008, the 496 large reservoirs in the country reserved 271 km o

    water, which is 29.5 km more than was reserved in 2007. Chinas total

    water withdrawal in 2008 was 583 km, which is 0.9 km more than the

    water withdrawal in 2007.

    Sector % Demand Volume

    (km3

    /yr)

    Agriculture 62.1 362

    Industrial 23.6 138

    Domestic 12.5 73

    Replenishment* 1.8 10

    Total annual use 100.0 583

    * Water or environmental use, such as the replenishment o surace water or groundwater.

    Source: Ministry o Water Resources, 2008

    Sectoral Water Use

    Chinas cities account or 58.9% o the countrys domestic water

    demand, while the counties account or the remaining 41.1% o domestic

    consumption. Compared with gures rom 2007, the water used or

    agricultural, industrial, domestic and environmental replenishment has

    increased by 2.1 km3 in 2008. The water consumption per capita was

    440 m3/c/yr, and 225 m3/yr o water was needed or each CNY 10,000

    GDP output. This gure is 8.1% less than in 2007.Municipal &Domestic

    Existingwithdrawals2

    2030withdrawals3

    Basins withdefcits

    Basins withsurplus

    Existingaccessible,

    reliable,

    sustainable

    supply1

    Relevant supply quantityis much lower than the

    absolute renewable wateravailablity in nature

    Ground-water

    Suracewater

    Billion m3, 154 basins/regions

    1 Existing supply which can be provided at 90% reliabili ty, based on historical hydrology and inrastructureinvestments scheduled through 2010; net o environmental requirements

    2 Based on 2010 agricultural production analyses rom IFPRI3 Based on GDP, population projections and agricultural production projections rom IFPRI; considers no water

    productivity gains between 2005-2030

    Source: Water 2030 Global Water Supply and Demand model; agricultural production based on IFPRI IMPACT-

    WATER base case

    Agriculture

    Industry

    2%

    40%

    4,500

    CAGR

    6,900

    900

    1,5002,800

    4,500

    4,200

    700

    3,500

    800

    3,100

    Exhibit 2: Aggregated global gap between existing accessible,

    reliable supply1 and 2030 water withdrawals, assuming no

    efciency gains

    100600

  • 7/28/2019 Hydrogen Refueling Cost Shanghai

    3/12

    Chinas Thirst or Water

    3

    occurred in industry. I agriculture and industry could sustain

    this rate to 2030, improvements in water eciency wouldaddress only 20% o the supply-demand gap, leaving a large

    decit to be lled.

    Chinese industry is extremely inecient in water use, recycling

    only 25% o their water compared with an average o 85% in

    developing countries. In 2002, Beijing opened its public-sector

    water industry to private and western investment. By 2008,

    private and oreign interests had stakes in 20% o Chinas public

    water utilities and 70% o the wastewater utilities.

    China Recognizes the Problem

    In the late 1990s China adopted the public-private partnership(PPP) contracts to build enough water and wastewater plants.

    In 2007, China raised its national standards or drinking water

    and established an inspection network to monitor water quality.

    The Health Ministry added 71 benchmarks to the 35 already

    required under previous standards.

    The eleventh ve-year plan and economic crisis stimulus

    package created the growth o Chinas wastewater treatment

    industry. However, there are still 167 cities without wastewater

    treatment plants (WWTPs). According to the Ministry oHousing and Urban-Rural Development, the existing plants are

    only 72% in operation because there is a lack o pipe works to

    deliver the wastewater to the plants.

    The Chinese economic stimulus package o 4 trillion yuan

    or $585 billion, ocused nearly 40% o its spending on

    environmental and energy-ecient projects. Over the next two

    decades the Chinese government will und 1 trillion RMB in

    urban water inrastructure rom (151 billion U.S. dollars).

    Pollution is actor taxing water in China. O the seven wate

    systems in China, 55% o the water had a water quality grade

    o I-III in 2008, 24.2% o Chinas water was graded IV-V, while

    20.8% o the water received a grade worse than V. Grade I reers

    to the natural water resources protected by the state. Grade I

    and III also reer to water resources that could be used to make

    drinking water and to sustain the aquatic eco-system, but these

    grades are not deemed as important as grade I. Grade IV wate

    is only or industrial use, and grade V water is only or agricultura

    use. Any grade considered worse than V is unsuitable or use.

    State Council

    State-owned AssetsSupervision and AdministrationCommission o the State Council

    Provincial State-owned AssetsSupervision and Administration

    Commission

    Urban State-owned AssetsSupervision and Administration

    Commission

    District or County State-ownedAssets Supervision and

    Administration Commission

    National Developmentand Reorm Commission

    Provincial Developmentand Reorm Commission

    Urban Developmentand Reorm Commission

    District or County Developmentand Reorm Commission

    Ministry o EnvironmentalProtection

    Provincial Department oEnvironmental Protection

    Urban Bureau oEnvironmental Protection

    District or County Bureau oEnvironmental Protection

    Ministry o Housing andUrban-Rural Development

    Provincial Department oHousing and

    Urban-Rural Development

    Urban Bureau o Housing andUrban-Rural Development

    District or County Bureau oHousing and

    Urban-Rural Development

    Ministry o Water Resources

    Provincial Departmento Water Resources

    Urban Bureau oWater Resources

    District or County Bureauo Water Resources

    Source: Adapted rom www.gov.cn

    Water Sector Organization and Structure

    Government ministries and agencies

  • 7/28/2019 Hydrogen Refueling Cost Shanghai

    4/12

    4

    Due to a lack o wastewater plants, pipe works and eective

    supervision, it is not unusual or residential and industriawastewater to be discharged directly into the environment

    About 70% o Chinas lakes and rivers are contaminated, and

    hal o Chinese cities rely on polluted groundwater. Citing the

    World Bank, the report notes that 54 billion tons o untreated

    waste were directly dumped into Chinas lakes and rivers in

    2006. About a quarter o Chinas population, 300 million, drink

    contaminated water every day. Almost two-thirds o these

    all ill, it said. Chinese authorities call the abled Yangtze Rive

    cancerous. Chemical and oil disasters are seemingly endless.

    The expected rapid urbanization during the 12th Five-Yea

    Plan (2011-2015) will threaten the security o Chinas wate

    resources, government authorities have said. Pollution controand prevention guidelines on eight major rivers and lakes across

    the country or the next ve years were jointly released by

    the ministries o Environmental Protection, Water Resources

    Agriculture, Housing and Urban-Rural Development, Industry

    and Inormation Technology, and the National Development and

    Reorm Commission.

    All the plans mentioned that rapid urbanization and ast economic

    development are posing great challenges to water protection in

    the eight rivers and lakes, including Haihe River near Beijing and

    Huaihe River, which marks the boundary between Chinas north

    and south.

    The volume o pollutants in these waterways during the nexve years will increase by 35 to 40% due to the industrialization

    and urbanization in the Haihe River area, according to the plan

    or that water system. The plan or the Yellow River said rapid

    economic development along the river area would create a

    water shortage o about 14 billion cubic meters by 2030.

    According to the plan or Liaohe River, which fows through

    Liaoning province, breakneck GDP growth will increase the

    pressure on the river system. Water pollution has long been a

    problem or authorities.

    At the end o 2007, about 9.5 million urban residents living along

    the Huaihe River aced the problem o unsae drinking water

    the plan said. The situation was worse in rural areas. A our-year

    study released by the China Geological Survey showed that

    only 24% o the underground water in the North China Plain is

    sae or direct drinking as excessive heavy metal and chemica

    ertilizers were ound in most water resources.

    Ammonia and nitrogen tested in the eight rivers were high

    lighted on a black list o water pollutants, the plans said. Abou

    30% o the monitored spots along the Yangtze River were ound

    to have excessive ammonia and nitrogen, mainly caused by

    domestic waste and excessive use o ertilizers.

    Water distributionnetworks (new buildand rehabilitation)

    16

    35,000

    30,000

    25,000

    20,000

    15,000

    10,000

    5,000

    007

    $millions

    Year

    08 09 10 11 12 13 14 15

    Water resources(including desalination)

    Water treatmentplants (new andrehabilitation)

    Drinking water capital expenditure

    Wastewater capital expenditure

    16

    20,000

    15,000

    10,000

    5,000

    007

    $millions

    Year

    08 09 10 11 12 13 14 15

    Wastewater networks(new and rehabilitation)

    Wastewater treatment plants(other)

    Source: GWI Global Water Market 2011

    Industrial and municipal capital expenditure

    60,000

    50,000

    40,000

    30,000

    20,000

    10,000

    007

    $millions

    Year

    08 09 10 11 12 13 14 15 15

    Municipal capital expenditure Industr ial capital expenditure

    Market Forecast or Capital Expenditures

  • 7/28/2019 Hydrogen Refueling Cost Shanghai

    5/12

    Chinas Thirst or Water

    5

    Beijing surpasses other Chinese cities in terms o its wate

    reuse development. In 2008 Beijing used 620 million m owater, which accounted or 18% o the countrys total wate

    withdrawal. Another 30 million m is expected to be added to

    this total by the end o 2009. According to Beijings municipa

    government, all o the wastewater treatment plants in the city

    will be upgraded to water reuse plants in the near uture. Then

    the total amount o available reclaimed water will be 2 km/yr

    Most o the big water reuse plants are in Beijing. Other cities

    like Tianjin, Qingdao and Dalian also advocate the water reuse

    industry, but the plants are either small or or industrial use only

    Water is an Essential Ingredient or Manuacturing

    & Chinas Growth

    Paper: China is now the biggest paper manuacturer in the

    world. At present there are 3,500 paper manuacturers all ove

    China. Thirteen provinces each produce at least 1 million tons

    o paper and paperboard, contributing to 91% o the nationa

    output. It is predicted that Chinas paper output will reach 100

    million tons in 2020. Currently, the paper industrys wate

    consumption is 10 times larger per unit o paper production

    than that o developed countries.

    Chemicals:There are 21,000 chemical manuacturers in China

    o which 80-90% are small companies with an annual revenue

    o less than CNY 50 million. The large chemical manuacturers

    are either state-owned or owned by oreign companies. Toreduce production costs, hal o these manuacturers are

    located along the Yangtze River and Yellow River. In the past

    the industry was celebrated due to its incredible contribution

    to GDP growth and tax collection. The government is now

    aware o the negative aspects o the industry, such as high

    water consumption and pollution.

    In some parts o Huaihe River, the amounts o ammonia and

    nitrogen were more than 10 times the national standard or

    surace water, posing dangers to water saety. Industrial pollution

    and domestic waste accounted or 75% o these pollutants.

    Li Shanzheng, proessor with the Beijing Hydraulic Research

    Institute, told China Daily that water shortages in China were

    severe. Saving water and nding ways to recycle it will help to

    alleviate the pressure the country is acing, Li said, adding that

    the nation needs more sewage treatment plants.

    According to the World Bank, water pollution directly causes

    66,000 deaths annually in China rom cancer and dysentery.

    Lack o clean water already idles as much as 15% o Chinas

    armland each year, and temporary and permanent industry

    shutdowns are common. The World Bank estimates, water

    pollution and shortalls currently cost the country $22 billion

    U.S. dollars, or 1.1% o total GDP, while crop and shery losses

    rom water shortages and pollution, including acid rain, cost

    another $6 billion USD each year.

    New to Water Management

    Seawater desalination is somewhat new to China. The rst

    seawater desalination plant was built in 1982 on Woody Island o

    the Xisha Islands, with a capacity o 200 m/d. Most o the plants

    are currently provided consulting services by two institutes: the

    southern Development Center o Water Treatment Technology,

    Hangzhou, and the northern Institute o Seawater Desalination

    and Multipurpose Utilization, SOA (Tianjin). The existing

    seawater desalination plants mostly provide water or industrial

    use. Only a ew small plants provide water or municipal use, to

    serve small counties.Source: Jupiter Images

    Worse than V

    100

    90

    80

    70

    60

    50

    40

    30

    20

    10

    0

    IV to V I to III

    Water Quality o the Seven Water Systems

    Source: Ministry o Water Resources, P.R.C.

    %

    Pearl Yangtze Songhua Yellow Huai Liao Hai

    River River River River River River River

  • 7/28/2019 Hydrogen Refueling Cost Shanghai

    6/12

    6

    Textile: The textile industry accounts or 8.5% o the total

    amount o water used by industry, and 10% o the total

    industrial discharge. China has 50,000 enterprises in the textile

    industry, and 99.5% o them are small businesses. Guangdong,

    Jiangsu, Zhejiang, Fujian, Shandong and Shanghai contribute to

    80% o the total output o the country. A recent trend in the

    textile industry is a move in location rom the south-east to the

    north-west o China.

    Power generation: This is the biggest consumer o water; 87%

    o power in China comes rom coal-red plants. There are our

    tiers in the power industry. The rst tier includes ve national

    power corporations: Huaneng, Datang, Guodian, Huadian

    and China Power Investment Corporation. These corporations

    account or 42.5% o the total output o the country. The

    second tier includes newly rising power groups such as Huarun,

    Shenhua, State Development & Investment Corporation and

    China Guangdong Nuclear Power Holding Co., Ltd. The second

    tier accounts or 10.2% o the total power output. The third tier

    is composed o nearly 50 regional power groups accounting or

    27% o the total power output, The ourth tier is comprised o

    private and oreign invested power enterprises.

    Food and beverage: The industry includes agricultural product

    process, ood stu manuacturing and beverage manuacturing.

    Serving 1.3 billion people with ood and beverages, it is a huge

    market. However, the manuacturers discharge non-treated

    wastewater into the very environment rom which they draw

    their water resources. To improve this, the central government

    has set the ood and beverage industry the target o reducing

    their water consumption by 30% or each CNY o industrial

    value added and 10% o pollutants discharged. This has created

    a market or water reuse acilities.

    Plans to reroute rivers compound the water shortage. The Grand

    Canal, a vital route o commerce rom Beijing to Shanghai or

    more than 1,500 years, has been slated as the eastern branch

    o the North-South Water Transer Project that will transer

    water rom the Yangtze River to the Beijing area. However, the

    severely polluted water is eectively unusable even i the project

    is nished. The overall project also includes a central componen

    to divert water rom a tributary o the Yangtze River to Beijing

    which will dislocate hundreds o thousands o Chinese and is

    scheduled or completion in 2014.

    China Plans Ahead

    Its not well known that China has set aside more money or

    the adoption o clean technologies than any other country on

    the planet, said Dallas Kachan, managing director o Cleantech

    Group in San Francisco, which tracks global investment in clean

    technologies.

    China would like to achieve an urban water supply coverage rate

    o at least 95%, and add 40 million m/d to the water supply

    capacity. Urban water supply pipes that are more than 50 years

    old should be rehabilitated, and the average urban leakage rates

    should be kept below 15%. The estimated budget or these

    water supply issues is CNY 200 billion.

    Water reuse: Reuse 10-15% o treated wastewater in wate

    scarce northern cities (China denes cities with less than 3,000

    m o water resources per capita as water scarce). Meanwhile

    the country aims to reuse 5-10% o treated wastewater in

    southern seaside cities experiencing water scarcity. In 2015

    China plans to increase these percentages to 20-25% in

    northern cities, and 10-15% in southern cities. China also aims

    to add 6.8 million m/d o reclaimed water to the 2005 capacity

    by building water reuse plants or upgrading existing waste

    water treatment plants.

    Wastewater treatment: Build wastewater treatment acilities

    in all cities and counties, and add 45 million m/d to the 2005

    capacity by expanding existing plants or building new ones. Othe

    aims include building 1,000 WWTPs, investing CNY 300 billion

    ($440 billion U.S. dollars) in wastewater treatment inrastructure

    Source: Getty Images, Photos.com

  • 7/28/2019 Hydrogen Refueling Cost Shanghai

    7/12

    Chinas Thirst or Water

    7

    and not pricing the wastewater treatment tari below CNY 0.80/

    m in all cities.

    Seawater desalination: Achieve a total capacity o 800,000-

    1,000,000 m/d, or both municipal and industrial uses. China

    also plans to use 55 km/yr o seawater (desalination is not

    necessary here, as seawater can be used as cooling water). In

    2020, China hopes to increase the total capacity o its seawater

    desalination to 2,500,000-3,000,000 m/d, and to increase its

    use o seawater to 100 km/yr. Any revenue rom seawater

    desalination projects will be ree o income tax.

    Industrial water: Keep the annual growth rate o industrial

    added value at 10%, while keeping the growth rate o industrial

    water withdrawal within 1.2%. China aims to recycle 70% o

    water used by industry (which is separate rom the water reuse

    targets mentioned previously).

    Pollution: Reduce the three million tons o pollutants in discharged

    wastewater and the one million tons o pollutants in discharged

    industrial wastewater. The pollutants include chemical oxygen

    demand (COD), suspended solids (SS), biological oxygen

    demand (BOD), lead, arsenic, cadmium, phosphorus, nitrogen,

    pH, coliorm, hydrargyrum and chrome.

    How to Achieve Chinas Water Requirements

    The production o energy requires large volumes o water.

    Thermoelectric cooling, hydropower, energy mineral extraction

    and mining, uel production and emission controls all rely

    on signicant amounts o water. According to the National

    Renewable Energy Lab, electricity production rom ossil uels

    and nuclear energy requires 190,000 million gallons o water

    per day; accounting or 39% o all reshwater withdraws in

    the nation. In many regions o the country, we use as much

    water turning on the lights and running electric appliances in ouhomes, as we use in taking showers and watering lawns.

    O this, 72% is or ossil uels related energy production and

    coal accounts or 52% o all US energy generation. Each kWh

    o energy generated by coal requires 25 gallons o water

    This is both a water quantity and a water quality issue. The

    amount o water usage is oten o great concern or electricity

    generating systems as populations increase and droughts

    become a concern. Still, according to the USGS, thermoelectric

    power generation accounts or only 3.3% o net reshwate

    consumption with over 80% going to irrigation.

    General numbers or resh water usage o dierent powe

    sources are shown below. All thermal cycle plants (nuclear, coal

    NG, solar thermal) require large amounts o water or cooling

    and condensing. However, the amount o water needed is

    reduced as boiler temperatures are increased. Thereore, coal

    which burns at very high temperatures, is more ecient and

    requires less water use.

    Natural drat wet cooling towers at many nuclear power plants

    and large ossil uel red power plants use large hyperbolic

    chimneys that release the waste heat to the ambien

    atmosphere by the evaporation o water. In areas with restricted

    water use a dry cooling tower or radiator, directly air cooled, may

    be necessary, since the cost or environmental consequences

    o obtaining make-up water or evaporative cooling would be

    prohibitive. These have lower eciency and higher energy

    consumption than a wet, evaporative cooling tower.

    Source: Corbis

    Power Average

    Source Gal/MW-h

    Nuclear 400-720

    Coal 390

    Natural Gas 140

    Hydroelectric 1430

    Solar Thermal 1060

    Geothermal 2900

    Biomass 390

    Photovoltaic 30

    Wind 1

    Source: U.S. Department o Energy

  • 7/28/2019 Hydrogen Refueling Cost Shanghai

    8/12

    8

    Where economically and environmentally easible, electric

    companies preer to use cooling water rom a lake or river or

    a cooling pond, instead o a cooling tower. This type o cooling

    can save the cost o a cooling tower and may have lower energy

    costs or pumping cooling water through the plants heat

    exchangers.

    However, the waste heat can cause the temperature o the

    water source to rise detectably upon discharge. Power plants

    using natural bodies o water or cooling must be designed to

    prevent intake o organisms into the cooling cycle. To urther

    complicate environmental matters, organisms that adapt to thewarmer plant water may be injured i the plant shuts down in

    cold weather.

    Thermal cycle plants require water or cooling, but it does not

    have to be resh water. A power generation site located on the

    coast has the option to use seawater. Such a site would not use

    cooling towers. (There is the added benet that discharge water

    temperatures would have less eect on the environment).

    Japanese nuclear power stations, or instance, do not use

    cooling towers at all because all o the plants are located on the

    coast. I dry cooling systems are used, signicant water rom

    the water table will not be used. Other, more novel, cooling

    solutions exist, such as sewage cooling at the Palo VerdeNuclear Generating Station.

    In recent years, recycled wastewater, or grey water, has been

    used in cooling towers. The Calpine Riverside and the Calpine

    Fox power stations in Wisconsin and the Calpine Mankato power

    station in Minnesota, as well as the Peterborough Power Station

    in the UK are among these acilities. The chemical industry

    continues to nd creative ways o recycling and reusing grey

    water waste streams. Dow recently began operating a novel

    system or reusing municipal wastewater at the Terneuzen site in

    the Netherlands. In collaboration with local authorities and a locawater producer, this site accepts more than 2.6 million gallons

    o municipal household wastewater every day. The local wate

    producer removes residual contaminants and Dow then uses

    more than 70% o this water to generate high pressure steam.

    In early 2010, Dow Water and Process Solutions introduced

    DOWEX 650C and DOWEX 550A or a nuclear power plan

    through CHEC. The technologies have proven a great success

    and have helped Dow Water and Process Solutions become

    the number one provider o CPP system products to the China

    Guangdong Nuclear Power Group (CGN).

    Lower Energy Membrane Technology

    The overall thermodynamic eciency o the process is abou

    20%. Large amounts o energy are needed to generate the high

    pressure that orces the water through the membrane. Curren

    methods require anywhere rom 8 to 20 kilowatt-hours o

    energy to produce 1,000 gallons o desalinated seawater. This

    depends on the quality o water to be treated. However, gains

    can be achieved through the separation unit. The loss here is the

    energy needed to push the water through the membrane. This

    can be reduced by designing a thinner membrane as part o a

    better lter system.

    The key ocus in desalination is around recovery o energy, reuse

    and minimizing the amount o mechanical energy required in

    the separation unit. As a process scales up, the cost is reduced

    This is true or water purication as well, but what you might no

    realize is just how massive that scale is. The Ashkelon Seawater

    reverse osmosis plant is the largest desalinization plant in the

    world and uses Dow ltration membranes.

    Pressure-driven Membrane Separation

    Source: Dow Water & Process Solutions

    Source: SXC

  • 7/28/2019 Hydrogen Refueling Cost Shanghai

    9/12

    Chinas Thirst or Water

    9

    This plant provides greater than 15% o the water needs o

    Israel rom the Mediterranean Sea. They produce more waterevery year than Dows entire output combined at a cost o

    60-70 US cts/m3 compared to desalination plants at 80-90 cts/

    m3. In a typical desalinization process, 50% o the water that is

    pumped into the system is discharged as brine waste. This ratio

    is crucial to avoid salt precipitation and membrane ouling.

    Obviously the pressure used to orce this wastewater through

    the system is a signicant loss. With these processes, the

    water is again used in cooling towers until it nally evaporates

    into the atmosphere. This is the rst time municipal wastewater

    has been reused on such a large scale in the industry. Three

    million tons o water per year was previously discharged into

    the North Sea ater a single use. Now this water is recycled ortwo more applications and has resulted in 65% less energy use

    at this aculty compared to the alternative option o desalinating

    seawater. The reduction in energy use is the equivalent o

    lowering carbon dioxide emissions by 5,000 tons per year.

    Utilizing Energy Reducing Technologies

    The water supply also requires energy use. A large amount o

    energy is needed to extract, treat, and deliver potable water.

    Additionally, energy is required to collect, treat, and dispose

    o wastewater. In the United States, our percent o all power

    generation is used or water supply and treatment and 75% o

    the cost o the municipal water processing and distribution iselectricity. There are two keys areas where advances in chemical

    engineering can acilitate decreased energy requirements or

    water processing. These are in water treatment, specically

    in the desalination o salt water, and in the treatment o

    contaminated water and wastewater or re-use.

    Three key technologies or water treatment are Reverse

    Osmosis, Ion Exchange and Ultraltration. Reverse osmosis

    one o the primary technologies behind seawater desalination

    is also used or wastewater treatment and recycling. Ion

    exchange technology involves the reversible exchange o ions

    between a solid (the ion exchange resin) and a liquid. This

    technology is ideally suited or removal o contaminants andprovides a wide variety o treatment solutions or healthcare,

    nutrition, ood and beverage, mining, chemical processing,

    industrial water and municipal water.

    Ultraltration is a pressure driven membrane separation process

    that separates particulate matter rom soluble components in

    the carrier fuid (such as water). UF membranes typically have

    pore sizes in the range o 0.01 - 0.10 m and have a high removal

    capability or bacteria and most viruses, colloids and silt (SDI).

    Dow Ion Exchange Resin Beads

    Source: Dow Water & Process Solutions

    Source: Dow Water & Process Solutions

    Dow Reverse Osmosis Membrane

    Dow Ultrafltration Fibers

    Source: Dow Water & Process Solutions

    Energy Reducing Technologies

  • 7/28/2019 Hydrogen Refueling Cost Shanghai

    10/12

    10

    Advances in Reverse Osmosis

    The single largest cost or seawater desalinization is the energy

    cost. And even though reverse osmosis is the lowest cost

    separation process, there is still room or improvement. It is

    interesting to take a step back and determine just where in the

    process the energy is used. A process has been designed to

    pressurize waste stream and is used to pressurize the seawater

    that is coming into the system. In this way we can recover

    between 95-99% o the 28.11 kw/m3 o energy that would

    be lost. This has been a huge breakthrough or desalination.

    Reverse osmosis membranes are being used in three major

    wastewater reclamation and resuse acilities in the city o

    Beijing. These novel membranes consist o three layers.

    The major structural support is provided by a non-woven polyesterweb. Because this web is too irregular and porous to provide a

    proper substrate or the salt barrier layer, a polysulone interlayer is

    cast onto the surace o the web. The interlayer is an engineering

    plastic with pore diameters controlled to approximately 150

    Angstroms. The nal layer is a polyamide that acts as the salt

    barrier; this layer is only 2,000 Angstroms thick but can withstand

    the high pressures because o the underlying support.

    The membrane materials have been continuously updated

    and rened to improve eciency through higher rejection,

    improved fux and low ouling perormance. They will be used to

    treated 45,000 m3 o water per day at three sites BeiXiaoHe

    Wastewater Treatment Plant, Beijing International Airport andthe Beijing Economic-Technological Development Area. This

    technology will help the city reach its goal o reusing hal o its

    water, signicantly extending this limited natural resource.

    New approaches to reduce the energy ootprint o water

    treatment systems involves capturing waste energy throughout

    the treatment process. Innovative desalination technologies

    that use low-grade or waste heat instead o electricity have

    the potential to substantially reduce energy inputs, yielding

    a more environmentally benign process and lower operation

    costs. Other important technologies include energy recovery

    devices in desalination plants, microbial uel cells that eed

    o wastewater and cogeneration plants co-located withwastewater treatment acilities.

    Technologies to Reduce Purifcation Costs

    Interestingly, one o the key applications o reverse osmosis

    and ultraltration technology is in the production o ultra pure

    water or ossil uel and nuclear power generation. These water

    treatment technologies help power plants utilize available water

    supplies eciently. Ultraltration, used in many municipal

    potable water plants, is even less costly puriying up to a trillion

    pounds o water per year at a cost o 1/1000 o a cent per poundIon exchange resins can be used to demineralize water or ossi

    and nuclear power plant boiler eedwater, cooling tower wate

    treatment and eedwater or industrial boilers and cogeneration

    plants. They are also used in condensate polishing, which allows

    the reuse o steam condensate rom power plant boilers to

    reduce the overall cost o producing puried boiler eedwater.

    These resins also help uranium mining operations use less

    water and generate less waste and enable the production

    o high purity uranium used in nuclear power applications

    helping meet the increasing global demand or energy. The bes

    resins have the best bed kinetics and thereore operate more

    eciently, giving longer runs and greater operating economy.

    Ultraltration eciency is based on a balance o pore diamete

    and porosity. In order to eectively remove pathogens, viruses

    and bacteria, the pore size must be at approximately the 0.03

    micron level. But the same membrane must have a high 50%

    porosity in order to allow high fux at a given transmembrane

    pressure. The material used or modular lters is key it mus

    have the high porosity and be breakage resistant, especially

    during cleaning to avoid ouling.

    Creating Sustainability

    Modern water treatment technology and distribution inrastructure

    have allowed us to conquer disease, to build advanced industria

    economies and to dramatically increase standards o living o

    many o the worlds people. Pushing the limits o water through

    science has also improved irrigation techniques making it possible

    to eed a rapidly growing population, turn deserts into inhabitable

    lands and to quench the thirst o large metropolitan areas. And

    the latest technologies have allowed us to minimize the wate

    needed or electricity generation while continuing to provide

    energy to a burgeoning population.

  • 7/28/2019 Hydrogen Refueling Cost Shanghai

    11/12

    Chinas Thirst or Water

    11

    Industrial water 4.6%

    Bottled water 3.5%

    Point o use equipment 2.5%

    Irrigation equipment 1.5%

    Utilities 88.0%

    Water opex 18.5%

    Wastewater opex 7.4%

    Drinking water capex 40.6%

    Wastewater capex 33.5%

    $47,831m

    $42,068m

    $32,346m

    $2,188m

    Total water market(2010)

    Utility market(2010)

    Combined capex(2010)

    Industrial market(2010)

    Services 6.1%

    Chemicals 39.5%

    IndustrialEquipment 54.5%

    Equipment 22.4%

    Site work 20.2%

    Pipes 20.9%

    Pumps & valves 12.4%

    Pipe rehab services 18.9%

    Proessional/other 5.3%

    WTPs 9.2%

    Water resources/other 10.7%

    Water network rehab 28.5%

    New water networks 6.5%

    WWTPs 21.1%

    New wastewater networks 11.3%

    Waterwater network rehab 10.1%

    Other waterwater 2.6%

    $31,154m

    $6,872m

    Utility capex(2010)

    Equipment market

    (2010)

    Other equipment 27.5%

    Standard process equipment 26.6%

    Headworks/screens 6.2%

    Filtration systems/media 6.1%

    Meters 7.4%

    Sludge management 16.6%

    Disinection 7.2%

    Membranes 2.4%

    Source: GWI Global Water Market 2011

    Appendix

    Market orecast breakdown, 2010

  • 7/28/2019 Hydrogen Refueling Cost Shanghai

    12/12

    Toll-ree telephone number or the ollowing countries: Austria, Belgium, Denmark, Finland, France, Germany, Hungary, Ireland, Italy, The Netherlands

    Norway, Portugal, Spain, Sweden, Switzerland, and the United Kingdom

    NOTICE: The use o this product in and o itsel does not necessarily guarantee the removal o cysts and pathogens rom water. Eective cyst and pathogen

    reduction is dependent on the complete system design and on the operation and maintenance o the system.

    NOTICE: No reedom rom any patent owned by Dow or others is to be inerred. Because use conditions and applicable laws may dier rom one

    location to another and may change with time, Customer is responsible or determining whether products and the inormation in this document are

    appropriate or Customers use and or ensuring that Customers workplace and disposal practices are in compliance with applicable laws and

    other government enactments. The product shown in this literature may not be available or sale and/or available in all geographies where Dow

    is represented. The claims made may not have been approved or use in all countries. Dow assumes no obligation or liability or the inormation

    in this document. Reerences to Dow or the Company mean the Dow legal entity selling the products to Customer unless otherwise

    expressly noted. NO WARRANTIES ARE GIVEN; ALL IMPLIED WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE

    ARE EXPRESSLY EXCLUDED.

    Published April 2011

    Form No. XXX-XXXXXXX-XXXX*Trademark o The Dow Chemical Company

    *

    Sources

    Dow Water & Process Solutions Water Energy Nexus, 2011

    Dow Water & Process Solutions Global Climate presentation

    Charting Our Water Future, McKinsey Research

    Report to Congress on the Interdependency o Energy & Water

    U.S. Department o Energy

    Taming the Water Dragons: Opportunities & Challenges in the

    Chinese Water Sector-Lux Research

    Global Market 2011-Global Water Intelligence

    New York Times

    China Daily

    Milwaukee Journal

    USA Today

    World Bank

    World Health Organization

    United Nations

    Cleantec Corporation