htw™ gasification of high volatile bituminous coal david

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Energy Systems and Technology Prof. Dr.-Ing. B. Epple Otto-Berndt-Straße 2 64287 Darmstadt / Germany Phone: +49 6151 16 23002 www.est.tu-darmstadt.de HTW™ Gasification of High Volatile Bituminous Coal David Krause M.Sc., TU Darmstadt 9 th International Freiberg Conference on IGCC & XtL Technologies 06 June 2018, Berlin, Germany

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Energy Systemsand Technology

Prof. Dr.-Ing. B. Epple

Otto-Berndt-Straße 2

64287 Darmstadt / Germany

Phone: +49 6151 16 23002

www.est.tu-darmstadt.de

HTW™ Gasification of High Volatile Bituminous Coal

David Krause M.Sc., TU Darmstadt

9th International Freiberg Conference on IGCC & XtL Technologies

06 June 2018, Berlin, Germany

Energy Systems

and TechnologyProf. Dr.-Ing. B. Epple

Structure of Presentation

Introduction of the HTW™ Process

Brief description of the test setup

Feedstock

Test results

Continuous operation

Compact results

Optimization

Summary and Outlook

1

Energy Systems

and TechnologyProf. Dr.-Ing. B. Epple

Introduction of the HTW™ Process

a) Continuous extraction of bed material

b) Injection of gasification agents (O2, Steam,

CO2)

c) T below ash softening point (850 – 950 °C)

d) High T conversion of heavy

hydrocarbons up to 1,200 °C

e) Recirculation of particles separated in

cyclone to the fluidized bed

2

Cyclone

Recycle

Line

Bubbling

Fluidized

Bed

Post

Gasification

Zone

Nozzles So

urc

e:

thys

se

nk

rup

pIn

du

str

ial S

olu

tio

ns

AG

c)

a)

d)

b)

e)

Energy Systems

and TechnologyProf. Dr.-Ing. B. Epple

Pilot Plant

2015 retrofitting of a fluidized bed reactor into a HTW™ gasifier

Investigation of

Feedstock suitability

Equipment for large-scale plant usage

Gasifier

Inner diameter of 400 mm

Height of 11 m

Temperatures up to 1,200 °C

Operating at atmospheric pressure level

3

So

urc

e:

ES

T T

U D

arm

sta

dt

Energy Systems

and TechnologyProf. Dr.-Ing. B. Epple

Pilot Plant

4

feedHTW™ gasifier

feeding

system

raw gas

cooler

combustion

chamber

bag filter

stackinduced

draft fan

bottom ash

filter

ash

gasification medium

combustion air

So

urc

e:

ES

T T

U D

arm

sta

dt

Energy Systems

and TechnologyProf. Dr.-Ing. B. Epple

Feedstock

High Volatile Bituminous Coal (HVBC) prepared by grinding

Continious operation for 5 days (7.4 tons)

5

HVBC

Lower Heating Value MJ/kg 29.1

Ash Softening Point °C 1,100

Water Content wt.-% 5.7

Ash Content wt.-% 7.0

C-fix wt.-% 52.6

Volatile Content wt.-% 34.7

D50 µm 402Source: Wuhan Erun technology co.,ltd

Energy Systems

and TechnologyProf. Dr.-Ing. B. Epple

Operation with high volatile bituminous

coal

Continuous operation

▪ TBed ≈ 915 °C ▪ Δptotal ≈ 110 mbar – 120 mbar ▪ TPGZ ≈ 945 °C

6

700

750

800

850

900

950

1000

0

50

100

150

200

250

300

0:00 2:00 4:00 6:00 8:00 10:00

Tem

pera

ture

in

°C

Dif

fere

nti

al

pre

ssu

re i

n m

bar

TPGZ

TBed

Δp

Energy Systems

and TechnologyProf. Dr.-Ing. B. Epple

Operation with high volatile bituminous

coal

Continuous operation

7

700

750

800

850

900

950

1000

0

15

30

45

60

75

90

0:00 2:00 4:00 6:00 8:00 10:00

Tem

pera

ture

in

°C

Mo

le f

racti

on

in

Vo

l.-%

, d

ry

TPGZ

TBed

CO

H2

CO2

CH4

Energy Systems

and TechnologyProf. Dr.-Ing. B. Epple

Summary of results

Comparison of test results with High Volatile Bituminous Coal and Lignite Energy Grained

8

HVBC LEG

Coal mass flow kg/h 61.0 70

Gasifier performance kWth 493 418

Raw gas quantity kg/h 221.4 225

Gas composition (dry)

CO2 Vol.-% 48.7 30

CO Vol.-% 23.1 31

CH4 Vol.-% 1.9 1

H2 Vol.-% 26.3 30

Lower heating value raw gas (dry) MJ/m³ 6.4 7.5

Carbon conversion rate % 75.7 96

Energy Systems

and TechnologyProf. Dr.-Ing. B. Epple

Optimization

Original Optimization

9

Cyclone

Loop Seal

Gasification

agents

So

urc

e:

ES

T T

U D

arm

sta

dt

New Design

Energy Systems

and TechnologyProf. Dr.-Ing. B. Epple

Optimization

Impact of the optimization

10

Campaign Optimization

Gas composition (dry)

CO2 Vol.-% 48.7 36.4

CO Vol.-% 23.1 28.8

CH4 Vol.-% 1.9 2.1

H2 Vol.-% 26.3 32.7

Lower heating value raw gas (dry) MJ/m³ 6.4 7.9

Carbon conversion rate % 75.7 94

Energy Systems

and TechnologyProf. Dr.-Ing. B. Epple

Summary and Outlook

Gasification test

Continuous operation for 5 days with high volatile bituminous coal (gasification of 7.4 tons)

Stable process, resilient to disruptions

Optimization for the pilot plant operation include:

New design of cyclone

Removal of loop seal

Increasing preheating temperature of the gasification agents

Prove that the HTW™ gasification is applicable to the High Volatile Bituminous Coal

11

Energy Systems

and TechnologyProf. Dr.-Ing. B. Epple

Summary and Outlook

FABIENE:

Flexible Supply of Electricity and Fuels from

Gasification of Lignite in a Fluidized Bed

Erection of a gas purification unit

Coupling with the existing HTW™ gasification

pilot plant and a catalysis test rig of RWE

4 two-week test campaigns

Techno-Economic assessment of

polygeneration based on fluidized bed

gasification

Christian Heinze, TU Darmstadt

11:50 – 12:10

Room: Pavillon

12

Energy Systems

and TechnologyProf. Dr.-Ing. B. Epple

13

Thank you for your kind attention!