heat and energy transfer energy of phase changebrownk/es106/es106.2009.0409.heat.f.pdfheat •...
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Heat and Energy TransferEnergy of Phase Change
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Temperature• Measure of hotness• Celsius
0o freezing point of pure water at standard pressure100o boiling point at standard pressure
• Fahrenheit0o was lowest attained32 was his age when he performed experiments212 is boiling point in those increments
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Temperature
• Convert with equationsOrder of operations
Parentheses firstThen multiply or divideAdd or subtract last
• Or use adjacent scales such as p. 142 of Conceptual Physical Science textbook
32)-(F95C =
32 C59F +=
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Temperature• Kelvin same size as degree Celsius• ‘Absolute Zero’ is 0 K
(notice no degree symbol on K)• 0o C = 273 K• Molecular motion ceases at absolute zero
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Heat
• Calorie– Amount of heat required to raise the
temperature of 1 gram of pure water 1o C– Food ‘Calories’ are kilocalories
• Joule ~ ¼ of calorie– 1 cal. = 4.184 J
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Laws of Thermodynamics
1. Heat added = increase in thermal energy + external work done by the system
2. Heat never spontaneously flows from a cold substance to a hot substance
3. No system can reach absolute zero
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Specific Heat Capacity
• Quantity of heat needed to change the temperature of given amount of a substance 1o C
• Water—very high specific heat capacity– Maritime areas more mild temperature than
continental areas– Takes 1/8 calorie to raise temperature of iron
1o C
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Heat Expansion• Random motion causes substance to be
bigger• Liquids usually have greater heat
expansion than solids• Thermostats use different expansion of
different type of metals
http://www.alaskarails.org/terminology/questions.html http://demo.physics.uiuc.edu/LectDemo/scripts/demo_descript.idc?DemoID=40
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Water Expansion
• Unusual response to cooling
• Contracts until reaching 4o C
• Expands slightly upon further cooling to 0o C
• Expands 9% upon freezing
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Water Molecule
• Bent • Polar
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Water Expansion
• Molecule shape fit together closer in liquid• Open structured crystal due to hydrogen
bonding of polar molecules upon freezing
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Heat Transfer: conduction
• Tile is a better conductor of heat than the wood floor
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Heat Transfer: convection
• Currents from heater shown by shadows
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Heat Transfer: radiation
• Does not need material to transfer radiant energy
• Dark bodies absorb it better than light-colored ones
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Radiant Energy
• All objects emit thermal energy– Visible light above ~500oC– Re-emit absorbed radiation at
wavelength according to temperature
• Good absorbers are good emitters
• Poor absorbers are poor emitters
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Heat Transfer
• Conduction– Direct molecule interaction– Transferring energy to next molecule
• Convection– Movement of fluid: liquid or gas
• Radiation– Through open space– Electromagnetic radiation
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Energy of Water Phase Change
• Calorie: energy to change 1 g water 1 K or 1 oC
• Also need energy to change to different state of matter
• Energy of vaporization/condensation540 calories per gram of water = 2256 J/g
• Energy of melting/freezing80 calories per gram= 334 J/g
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Energy of phase change for water
http://hyperphysics.phy-astr.gsu.edu/hbase/thermo/phase.html
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Solid Ice
H2O(s) Ice
http://www.unit5.org/christjs/Matter%20and%20Energy/Unit%202%20PP_files/frame.htm
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Molecular Structure of Ice
Zumdahl, Zumdahl, DeCoste, World of Chemistry 2002, page 455
http://www.unit5.org/christjs/Matter%20and%20Energy/Unit%202%20PP files/frame.htm
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Three phases of
water
http://www.cdli.ca/CITE/glaciers.htm
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Atmosphere
• Evaporation – Energy goes into air– Cools remaining water
• Condensation– Energy goes from air to surface– Warms local environment
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Atmosphere
• Warm air has greater capacity for holding water in the vapor phase
• Saturation = at capacity• Relative Humidity—percent of water
contained compared to saturated amount at that temperature
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Water Vapor Capacity
http://www.wdtv.com/weather/images/Weather_Review/humidity.htm
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Condensation
As air rises, it expands and coolsCondensation of water vapor occurs
http://observe.arc.nasa.gov/nasa/earth/hydrocycle/graphics/condensation.jpg
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Condensation diagram
http://weatherstreet.com/weatherquestions/What_is_condensation.htm
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Sea Fog
http://www.anythingmarine.co.uk/anything/met.htm
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Coastal fog
http://www.victoriaweather.ca/clouds.php?image=fog
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Homework Assignment
• Handout available today• Also posted on web page for class
http://www.wou.edu/~brownk go to ES 106 page and look for today’s date (April 9)
• Due in one week, April 16– If you won’t be here that day,
get it in early or have someone else bring it– If you weren’t here April 9,
it is STILL DUE on April 16