global e&c solutions jornada sobre gas de síntesis y sus...

Global E&C SolutionsJornada sobre Gas de Síntesis y sus Derivados

Buenos Aires October 2013 l Global E&C Solutions Udo Dengel

Presentation Outline

■ 1. Introduction� Air Liquide Global E&C Solutions

■ 2. Technologies� Syngas� Methanol� Methanol to Propylene

Air Liquide, world leader in gases for industry, he alth and the environment2 Sept 19 2012 General Presentation

■ 3. Wrap up

Confidential

Air Liquide Global E&C Solutions: Key figures 2012

■ 785 million € revenue■ 1.7 billion € order intakes■ 4 billion € orders-in-hands

■ Around 4,000 employees■ 15 Engineering centers worldwide■ 3 manufacturing workshops■ More than 1,600 patents

■ Total Orders-in-hands breakdown at December 31, 2012

Air Liquide, world leader in gases for industry, he alth and the environment3 April 2013 – E&C Presentation

at December 31, 2012

■ Traditional energy:Petrochemicals, Refining and Polymers

■ Alternative energy: Chemical conversion and natural gas conditioning

■ Renewable energy: biofuels

Hangzhou

Shanghai

Harima

BeijingDelhi

Houston

Montreal

Vitry/Seine

Bussy-Saint-Georges

Ennery MoscowKrakow

Champigny/Marne

Frankfurt

Hyderabad

Global E&C Solutions Main Centers and Business offices

Calgary

Donetsk


Sao PauloJohannesburg

Dubai

Riyadh

Chennai

Engineering centers Manufacturing workshops Business offices Cryogenic equipment centers

Ras Al Khaimah(under construction)

Singapore

Kuala Lumpur

The Air Liquide Group

50,000employees

Present in

80 countries


Revenue

€15,3 billion

Our Markets and Technologies

■ Global E&C Solutions gives its customers the best possible value with the world’s most advanced innovative technology bundled in a broad but focused portfolio:

Petroleum refining

Chemical conversion

Renewable resources

Carbon capture


Natural Gas conditioning

Petrochemicals

Polymers

Metals Processing

Food & Environment, Glass, Electronics

■ HyCO units for production of syngas and hydrogen� Partial Oxidation (MPGTM)� Steam Reforming� Combined Reforming� Autothermal Reforming� PSA technologies

■ Gasification� Multipurpose Gasification (MPGTM)� Coal Gasification (FBDBTM)

■

Chemical conversion


■ Methanol and MeOH Downstream� Mega MethanolTM

� Methanol LP � Methanol to Propylene (MTPTM)� Mega DMETM

■ Synthetic Natural Gas (SNG)

■ Synfuels (XtL)� Gas to Liquids (GtL)� Coal to Liquids (CtL)� Biomass to Syngas

■ Gas Cleaning� RectisolTM

� Purisol� MDEA/DEA� aMDEA� Sour Water Stripping (SWS)� Nitrogen wash� Membrane technologies

■ Sulfur Management (SRU)� Claus / OxyclausTM

SulfreenTM

Natural gas conditioning


� SulfreenTM

� Lurgi Tailgas Treatment (LTGTTM)� AquisulfTM

� SO2 Scrubber technology� MaxisulfTM

■ Production of carbon monoxyde� Cryogenic CO separation units

■ Air Gases production� Standard Cryogenic Air Separation Units� Custom Cryogenic Air Separation Units� Adsorption based Air Separation Units (EOX)

Syngas Technologies

Natural Gas Reforming

Air Liquide, world leader in gases for industry, he alth and the environment

Gasification SteamReforming

MPG

SteamReforming

MPG

Pre-reforming

CoalHeavy

ResidueNatural Gas

AL Synthesis Gas Production Technologies

Syngas Production Technologies from Lurgi/Air Liquide

Air Liquide, world leader in gases for industry, he alth and the environment10

H2S & CO2

Rectisol

CO ShiftConversion

H2SRectisol

CO2Removal

Autotherm.Reforming

Autotherm. Reforming

Synthesis Gas

CO ShiftConversion

Synthesis Gas

© Lurgi GmbH 2013

Typical Single Train Capacities

Autothermal

Steam Reforming


100 1,000 10,000 100,000 1,000,000

POX

Reforming

Nm³/h

© Lurgi GmbH 2013

H2/CO Ratios of Syngas, Natural Gas Feed

� Desired product, plant size and available feedstock and utilities defines most economical process

CMR

SMR

SMR = Steam Methane Reformer


1 2 3 4 5

POX

ATR

CMRCMR = Combined Methane Reforming

ATR = Autothermal Reforming

POX = Partial Oxidation

Synthesis Gas Production – Process Details

Air Liquide, world leader in gases for industry, he alth and the environment13 Sept 19 2012 General Presentation13

Confidential

Lurgi Reformer® – Efficient, Safe, and Competitive

Safe and Reliable

Top-fired design(Reduced number of burners)

CompetitiveEfficient

Counter-Weight catalyst tubes suspension system

On-line isolation of defective catalyst tubes

Feed preheating temperature up to

1202°C


(Reduced number of burners)

Large single-train capacities feasible (up to

1,000 catalyst tubes)

5/10/2012

Capability for 950°C and 35 bar at reformer outlet

1202°C

Process Gas Combustion Air

Fuel Gas Flue Gas

Features of Autothermal Reformer

■ Low S/C ratio ≈ 1.5 - 0.5 mol/mol� high CO selectivity� low CO2 emission

■ Outlet temperature 950 - 1050 °C� Low methane slip� Close approach to equilibrium


■ Max. pressure: 40 bar realised� Up to 80 bar possible

■ High gas throughput possible� Up to 1,000,000 Nm3 gas / hr

■ Highest reliability / availability

© Lurgi GmbH 2013

Highlights for Syngas Production

■ Lurgi offers all hydrocarbon based syngas technologies� More than 120 steam reforming plants� More than 30 autothermal reforming plants� More than 30 partial oxidation plants � Plant sizes ranging from 42,000 Nm³/day (HyCO)

up to 22,000,000 Nm³/day syngas

■ Feedstock range: Light/heavy natural gas


■ Feedstock range: Light/heavy natural gasLPG, associated gas, naphtha, fuel oil, heavy residues

■ Product range: CO, hydrogen, town gas,syngas for products likeoxo-alcohols, methanol, XtL …

■ Industry point of reference for oxygen blown ATR’s

© Lurgi GmbH 2013

Highlights for Syngas Production

■ World largest combined reforming syngas unit (ATLAS)

■ World largest multiple train – natural gas based – syngas unit (Mossel Bay, SA)

■ Vast experience in handling oxygen (since 1928) significantly enhanced by AL group expertise


■ 50+ years experience in ATR (since 1954)

■ Lurgi’s MegaSyn technology has been the entry ticket for large scale syngas products

■ Pilot plant to test more severe operating conditions

© Lurgi GmbH 2013

Methanol Technology Overview


Downstream technologies offered by Lurgi/Air Liquide


Confidential

Overview Methanol Licenses

■ Lurgi Methanol Licenses

� 55 Plants licensed


20

� 55 Plants licensed

� 38,200 ktpy Methanol

� 17,400 ktpy Methanol under use of ATR/CombinedReforming

� 21,900 ktpy Methanol with two-stage Synthesis

� 27,200 kpty licensed since 2001

Lurgi’s MegaMethanol® Process

■ Large Syngas Capacities Due to Oxygen Technology

■ High Reforming Pressure Reduces Plant Pipe Sizes

■ Small Syngas / Recycle Compressor


21

■ Two Stage Synthesis Reactor System

■ Low Natural Gas Consumption

■ Minimized Capital Investment for Large Scale Plants

Sept 19 2012 General Presentation21

Confidential

Combined Reforming – ATR and SMR - Together

SMR

ATR Desulphurization


Prereformer


Confidential

NG to MeOH Process selection : Influence of the plant capacity

■ Typical ranges for a Natural Gas based Methanol plant (low CO2 NG)

LP Synthesis

Combined Methanol Synthesis


0 10 000

Capacity (mtpd)

2 500 7 5005 000

SMR CombinedReforming

ATR

Natural Gas Methanol

Flue Gases

Sea Water

Intake

Distillation

Overview of Atlas Plant

PSAWater

Boiler

ASUDistillation

Atlas Methanol - 5000 t/d, 1.650.000 tpa, commissioned 2004


Sea WaterOutfall

ElectricityBackup only

Waste Water

Natural Gas Requirements

HHV 32 MMBTU/MT MeOH =4,250,000 Nm³/day = 155,000,000 scfd

Plot Requirements

300m x 400m

Production

5000 MTPD Methanol Grade AA

Gas cooled and

Water cooled Reactors

Note the compact

design

Water

Treatment

Steam Reformer

ATR

Steam Raising

Reactor

GigaMethanol® 2 x 10 000 MTPD

Air Liquide, world leader in gases for industry, he alth and the environment25 Sept 19 2012 General Presentation25

Confidential

Economy of Scale (Methanol Complex)

5,000 MTPDMegaMethanolToday´s benchmark

Air Liquide, world leader in gases for industry, he alth and the environment26 GPA Conference - London 2012

10,000 MTPDMegaMethanolToday´s potential


Selected operating Methanol References (Combined Reforming)

� Sabah, Malaysia 2000 MTPD since 1984 Turn Key by Lurgi

� KMI, Indonesia 2000 MTPD since 1998 Turn Key by Lurgi

� Titan, Trinidad 2500 MTPD since 2002 Turn Key by Lurgi

� Atlas, Trinidad 5000 MTPD since 2004 Turn Key by Lurgi

Zagros 1, - 5000 MTPD since 2007 LS EP by Lurgi


� Zagros 1, - 5000 MTPD since 2007 LS EP by Lurgi

� Zagros 2, - 5000 MTPD since 2008 LS EP by Lurgi

� Petronas, Malaysia 5000 MTPD since 2009 Turn Key by Lurgi


Most Recent Awards (2011-2013)

Client Location Capacity Feedstock Award

Undisclosed China 920,000 mtpy Natural Gas 2013

Sinopec China 1,800,000 mtpy Coal Gas 2013

Petrobras South America 800,000 mtpy Natural Gas 2012

SNCG CTL China 1,000,000 mtpy Coal Gas 2012


Sinopec ZTHC China 2 x 1,800,000 mtpy Coal Gas 2011

Qinghai Salt Lake China 1,000.000 tpy Coal Gas 2011

28 © Lurgi GmbH 2013

GTP/MTP Technology


Propylene1410 t/d 1)

Fuel Gas Internal use

DMEPre-Reactor

ProductConditioning LPG

109 t/d

MegaMethanol1.667 Mt/a = 5000 t/d

Ethylene60 t/d

Optional

MTP® Propylene – Process Diagram


Gasoline 540 t/d

Process Water 2800 t/dInternal Use (+)

Water Recycle

Olefin RecycleProduct

Fractionation

MTP Reactors(2 Operating + 1 Regenerating)

1) Propylene Purity 99.6 wt. %

30 © Lurgi GmbH 2013

MTP® Technical Highlights

■ Proprietary Zeolite Catalyst

■ Maximized Propylene Production� Selectivity > 65 % (Product Slate)� Yield > 28 % Wt. on Methanol Feed

■ Methanol Conversion > 99%


■ Low Coking Catalyst (< 0.5% Carbon Loss)

■ In-Situ Regeneration

■ Option for some Ethylene production

■ Valuable Co-Products (Gasoline and LPG)

© Lurgi GmbH 2013

Shenhua Ningxia Coal Industry Group Co. Ltd

China: Coal Based MTP® Commercialization

Air Liquide, world leader in gases for industry, he alth and the environment© Lurgi GmbH 2013

MTP® References

6 Licenses sold*�2 MTP Plants engineeried, projects stopped

�2 MTP Plants under commercial operation (490.000 tpy)

�1 MTP Plants under engineering (490.000 tpy)

�1 GTP Plant under engineering*) including repeat award in August 2011 and


*) including repeat award in August 2011 and latest award in 2013

Wrap up


Advantages of Lurgi Methanol Design


Confidential

Air Liquide / Lurgi Offer

Product

Lurgi Processes Methanol and MTP®

Syngas


Air SeparationDownstream Processes

Propylene

Syngas Preparation

■ Integration Between Processs ReducesCAPEX and OPEX

■ Utilities Minimized and Reliability Improved■ Singular Interface Reduces Risks■ Process Guarantees Bankable

(1) – For All Air Liquide Global E&C Solutions Technologies

Sept 19 2012 General Presentation

Confidential

Thank You !


Questions ?

37 Sept 19 2012 General Presentation

Confidential

HP ATR Pilot Plant

Basis for the Concept of GigaMethanol®


Demonstration Plant for Production of Syngas from Natural Gas, Liquid Hydrocarbons/Slurries at Pressures Up to 100 barg


Confidential

Lurgi’s Two Reactor Concept

■ Process- Quasi Isothermal- Quick Heat of

Reaction. 80 % of Heat Converted to MP Steam

■ Operation- Easy Start-up

■ Low Capital Investment to Production Capacity

■ Optimum Operating Process Conditions

■ High Conversion Rate

■ Low Natural Gas


- Easy Start-up- Safe Catalyst

Operation- Thermo-syphon

Effect. No Need for Pumps

■ Safe and Robust

■ Long Catalyst Life

■ Low Natural Gas Consumption

■ Lowest Syngas/Recycle Ration

■ High Methanol Outlet (11 to 13%)


Confidential

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