geochemical characterisation of weld range waste and ...€¦ · from the sinosteel midwest...

SRK Consulting (Australasia) Pty Ltd

Reg’d No ABN 56 074 271 720

Trading as SRK Consulting

Geochemical Characterisation of Weld Range Waste and

Mineralised Rock: Static and Kinetic Testing

Report 2

Report Prepared for

Sinosteel Midwest Corporation Limited

Prepared by

SMM004

March 2011

SRK Consulting Geochemical Characterisation of Waste Rock and Low Grade Ore; Static and Kinetic Testing Page i

GARV/CHAP SMM004_ENV_RP_2_Rev1.docx March 2011

Geochemical Characterisation of Weld Range Waste and Mineralised Rock: Static and Kinetic Testing Report 2 Project Code: SMM004 Document Reference: SMM001_ENV_RP_2 Revision: Rev 1 Sinosteel Midwest Corporation Limited

SRK Consulting (Australasia) Pty Ltd Level 2, 44 Market Street

Sydney NSW 2000

Compiled by:

Peer Reviewed by:

Andrew Garvie Principal Consultant (Geo-environmental)

Claire Linklater Principal Consultant (Geo-environmental)

Email: Andrew Garvie, [email protected] Authors:

Andrew Garvie, Alex Watson

SRK Approval Signature: Client Approval Signature:

Name: Simon Hanrahan Title: Project Manager

Name: Beng Ko Title: Mining Manager

Date: 18 March 2011 Date:

SRK Consulting Geochemical Characterisation of Waste Rock and Low Grade Ore; Static and Kinetic Testing Page ii


SRK Report Distribution Record

Ref: SMM004_ENV_RP_2_Rev1

Geochemical Characterisation of Waste and Mineralised Rock; Static and Kinetic Testing

Date: 18 March 2011

Name/Title Company Copy #

Beng Ko Sinosteel Midwest Corporation Limited 0

Beng Ko Sinosteel Midwest Corporation Limited 1

This document is protected by copyright vested in SRK. It may not be reproduced or transmitted in

any form or by any means whatsoever to any person without the written permission of the

copyright holder, SRK.

Rev No. Date Revised By Revision Details

0 11 February 2011 Andrew Garvie

Draft report issued to client as SMM004_ENV_RP_2_Rev0 Geochemical Characterisation of Waste Rock and Low Grade Ore; Static and Kinetic Testing; Report 2

1 18 March 2011 Simon Hanrahan

Final report issued to client as: SMM004_ENV_RP_2_Rev0 Geochemical Characterisation of Waste Rock and Low Grade Ore; Static and Kinetic Testing; Report 2

SRK Consulting Geochemical Characterisation of Waste and Mineralised Rock; Static and Kinetic Testing Page iii


Executive Summary

This report presents results of the geochemical characterisation of waste and mineralised material

from the Sinosteel Midwest Corporation Weld Range Project.

Overall Objective

The overall objective was to determine the potential for waste rock, stockpile material and pit walls

to be sources of acid drainage and metalliferous leachate.

The findings were used to define a simple method of classifying mined rock as potentially acid

forming (PAF) or non acid forming (NAF) during operation of the mine.

Outline of work programme

Design and implementation of a sampling programme – Drill core and the block model were

reviewed to identify samples representative of the major domains and weathering states of waste

rock and mineralised material. Samples identified were within or immediately adjacent to the

Madoonga and Beebyn pit shells designed in the prefeasibility study.

Since collection of the samples, the project has progressed to the bankable prefeasibility value

improvement stage (BFS VI) which includes a larger pit design based on two products (MWB and

Spot Market Ore).

Two hundred and sixty five samples of waste material and 74 samples of mineralised material were

collected for geochemical characterisation. The block model was used to estimate the mass of each

material in each domain.

Design and management of a static test programme – A static test programme provided data for

the assessment of the potential of materials to produce acidic and metalliferous drainage (ADML).

Parameters measured included paste pH and paste electrical conductivity, total sulphur, sulphate

sulphur, total carbon/total inorganic carbon, acid neutralising capacity (NP), net acid generation

(NAG), whole rock chemical assay and the acid buffering characteristic curve (ABCC).

Data interpretation – Static test results were interpreted to identify sources of acid potential and

acid neutralising capacity and to classify samples as potentially acid forming (PAF), non-acid

forming (NAF) or uncertain (UC). Elemental abundances were compared with average global

abundances, and element leachability assessed.

Design and implementation of a kinetic test programme – A subset of 13 samples that included

samples classed as PAF, NAF and UC were tested in columns a) to obtain an indication of rates

oxidation, acid neutralisation and solute release and b) to assist in identifying criteria that separate

PAF materials from NAF materials. The kinetic test programme comprised modified AMIRA-type

column test procedures. Four columns operated for 16 weeks and nine columns had operated for 45

weeks at the time of preparing this report. An assessment of the need to continue column operation

was made.

Development of a simple classification system for use during mine operations – A simple

classification scheme was developed for a) constructing a block model that identified materials

with the potential to produce ADML and b) for classifying materials during mining. Materials

classed as PAF under the simple scheme would be segregated during mining and managed to

control the development and impact of acid and metalliferous drainage.

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Results

Some materials contain stored acidity and at the time of mining they could have potential to release

acid. These materials include a significant proportion of the detrital (DID) and smaller proportions

of the felsic (FEL), banded iron formation, hydrated and mafic wastes. Similarly, small

proportions of the three mineralised domains (ORE, O_AL, O_SI) could also be marginally net

acid generating.

Generally there are limited quantities of soluble salts present, which indicate that flushing of the

mined materials prior to oxidation will not affect the solute content of water significantly.

Ninety one percent of the samples had a total sulphur content of less than 0.1 wt%. Thus, the

majority of material is expected to have a low maximum potential acidity (less than 3 kg(H2SO4)/t).

Neutralising potential (NP) is generally limited, average NP is often less than 15 kg(H2SO4)/t.

Carbonate-based neutralisation potential (CarbNP) was also calculated, but may overestimate NP

due to the presence of non neutralising carbonates such as siderite. The minimum of the NP and

CarbNP was the most appropriate measure of neutralising capacity available. A small number of

ABCC tests indicated that the actual neutralising capacity for some material may be less than the

minimum of the NP and CarbNP.

Some domains have little neutralisation potential and therefore would not be expected to provide

significant acid buffering capacity. The units include the MAF, DID, FEL, HYD, and high alumina

mineralised (O_Al).

Static and kinetic leach testing indicates that solute release rates are generally low under neutral

conditions and can increase under acidic conditions.

The masses of wastes at the Madoonga and Beebyn deposits classed as NAF, PAF and UC are

presented in the tables immediately below. Two classification schemes were used: the AMIRA and

neutralising potential ratio classification schemes. These schemes require quantification of acid

generation and neutralisation capacity and other parameters.

Madoonga

NAF PAF UC PAF

Domains

Waste Mass % 83 to 90 10 0.5 to 5.5 BIF, HYD,

MAF, SHL, DID Mass (Mt) 108 to 117 13 0.7 to 8

Mineralised Mass % 76 to 100 0 to 24 0

ORE, O_SI Mass (Mt) 38 to 50 0 to 12 0

NAF – non-acid forming. PAF – potentially acid forming, UC – uncertain (screening tests do not clearly identify sample as PAF or NAF).

Beebyn

NAF PAF UC PAF

Domains

Waste Mass % 99 to 100 0 0 to 1

MAF Mass (Mt) 231 to 233 0 0 to 2.5

Mineralised Mass % 98 to 100 0 0 to 2

O_Al Mass (Mt) 47.5 to 48.4 0 0.9

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Based on the understanding gained from the static test results, a simplified classification scheme is

proposed for classifying samples as PAF or NAF. The classification of materials was based solely

on the total sulphur (total S) content of samples in relation to a total S cut-off grade (Sc).

The lower the value of Sc the larger the volume of material classed as PAF.

Data for Weld Range samples suggests that Sc may lie between 0.1 and 0.36 wt% S. The lower

bound value is based on NAG testing results, whilst the upper bound value is based on data from

kinetic tests.

Based on the lower bound Sc value of 0.1 wt% S and the PSF pit shell design the mass of material

that would be classed as PAF at:

a) Madoonga would be about 21 Mt

b) Beebyn would be about 3.3 Mt.

As the BFS (VI) pit shells contain about twice the mass of waste within the PFS pit shells it is

possible that mass of waste classed as PAF for the BFS (VI) pit shell would be about 49 Mt.

The mass of waste classed as PAF varies little for Sc values in the range 0.1 to 0.25 wt% S.

Examples for the PFS pit shell are given in the following table.

Sc (wt% S)

Mass of Waste Classed as PAF (Mt)

Madoonga Beebyn

0.0 130.7 233.2

0.1 20.6 3.3

0.25 13.1 3.3

It may be possible to obtain data that supports use of a larger value of Sc (and thereby reduce the

mass of waste classed as PAF). Such data could be obtained from the samples that were leach

tested for 45 weeks. A sample of material would be removed from the columns that produced

neutral pH at week 45 and tested to determine the quantity of oxidisable sulphur remaining in each

column sample. Laboratory costs are expected to be less than $2,500.

SRK Consulting Geochemical Characterisation of Waste and Mineralised Rock; Static and Kinetic Testing Page vi


Recommendations

SRK recommends that:

1. That a simple scheme based on a threshold value of total sulphur content (Sc) is used for

classifying materials during mining. In the absence of further information on the acid

producing and acid neutralising capacity of materials the scheme would be as shown in

recommendations 2 and 3.

2. The value of Sc is taken as 0.1 wt% S.

3. Materials with:

a) Total S ≥ 0.1 wt% are classed as PAF and those with

b) Total S < 0.1 wt% are classed NAF.

4. An assessment is undertaken to determine whether use of a larger value of Sc can be justified.

A larger value of Sc would result in a smaller volume of waste being classified PAF. An

approach is presented in recommendation 5.

5. Operation of the long-term (45 week) kinetic columns should cease. Samples should be

obtained from those columns giving neutral leachate. These samples should be sent to a

commercial laboratory to measure the quantity of remaining oxidisable sulphide. The data

obtained will help determine whether a larger Sc can be used.

6. The current review of the quantity and distribution of PAF and NAF materials within the BFS

(VI) pit shell being is completed. Details are given in Section 5.1.

7. An assessment is undertaken of the potential quality of water that comes into contact the waste

and mineralised material. Details are given in Section 5.2.

SRK Consulting Geochemical Characterisation of Waste and Mineralised Rock; Static and Kinetic Testing Page vii


Table of Contents

Executive Summary ................................................................................................. iii Disclaimer ................................................................................................................. x List of Abbreviations ................................................................................................ xi

Introduction ..................................................................................................... 1 1. Terms of reference ........................................................................................ 1 1.1 Background ................................................................................................... 2 1.2

1.2.1 Project location .............................................................................................. 2 1.2.2 Regional Setting and Climate ........................................................................ 3 1.2.3 Geological setting .......................................................................................... 3

Report scope ................................................................................................. 3 1.3

Geochemical Investigation Programme .......................................................... 4 2. Overview ........................................................................................................ 4 2.1 Identification of domains ................................................................................ 4 2.2 Sampling ........................................................................................................ 5 2.3

2.3.1 Sampling approach ....................................................................................... 5 2.3.2 Sample preparation ....................................................................................... 6

Static testing methods .................................................................................... 7 2.4 Kinetic testing sample selection and methods ................................................ 7 2.5

Results and discussion ................................................................................... 8 3. Static testing results ....................................................................................... 8 3.1

3.1.1 Paste pH and paste EC ................................................................................. 8 3.1.2 Sulphur distribution ......................................................................................10 3.1.3 Acid neutralising capacity ............................................................................13 3.1.4 Acid buffering characteristics ......................................................................14 3.1.5 Net acid generation .....................................................................................16 3.1.6 Elemental analysis ......................................................................................19 3.1.7 Distilled Water Leach Extractions................................................................20 3.1.8 Mineralogical assessment ...........................................................................21 3.1.9 Acid generation classification ......................................................................25 3.1.10 Distribution of Mass .....................................................................................27

Kinetic test results ........................................................................................ 30 3.23.2.1 Sample properties .......................................................................................30 3.2.2 Results and discussion ................................................................................32

Waste Rock Management ............................................................................. 40 4. Simple classification scheme ....................................................................... 40 4.1 Selection of Sc for Weld Range .................................................................... 41 4.2 Mass Dependence on Sulphur Threshold .................................................... 42 4.3 Management Strategies ............................................................................... 45 4.4

Current and Future Work .............................................................................. 48 5. PAF material - mass and distribution and schedule ..................................... 48 5.1 Water Quality Assessment ........................................................................... 48 5.2

Conclusions and recommendations .............................................................. 50 6. Conclusions ................................................................................................. 50 6.1 Recommendations ....................................................................................... 51 6.2

References.................................................................................................... 53 7.

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List of Tables

Table 2-1: Domains of the Weld Range block model ......................................................... 5 Table 2-2: Distribution of rock samples subjected to static tests ....................................... 6 Table 2-3: Distribution of samples over rock domain and weathering class for

samples collected in 2009 .................................................................................... 6 Table 2-4: Test measurements and analytical methods .................................................... 7 Table 3-1: Percentage of samples in each domain with paste pH values between 5

and 6 .................................................................................................................... 9 Table 3-2: Sulphur content by domain in Madoonga waste and mineralised rock ........... 12 Table 3-3: Sulphur content by domain in Beebyn waste and mineralised rock ................ 12 Table 3-4: Summary of NP and CarbNP results .............................................................. 13 Table 3-5: Comparison of estimated neutralising capacities ............................................ 15 Table 3-6: Summary of NAG test results ......................................................................... 17 Table 3-7: Percentage of each waste domain with NAGpH < 4.5 .................................... 17 Table 3-8: Geochemical abundance indices for selected elements ................................. 19 Table 3-9: Summary of leach extraction test results ......................................................... 20 Table 3-10: Mineralogical summary ................................................................................ 22 Table 3-11: NPR classification scheme ........................................................................... 25 Table 3-12: Acid-base accounting classification scheme ................................................ 26 Table 3-13: Classification of all samples according to the NPR using NP ....................... 26 Table 3-14: Classification of all samples according to NPR using minimum of NP

and CarbNP ....................................................................................................... 27 Table 3-15: Classification of waste samples according to the NPR using minimum

of NP and CarbNP ............................................................................................. 27 Table 3-16: Summary of sample classification according to the AMIRA classification

scheme .............................................................................................................. 27 Table 3-17: Estimates of masses of the various domains at Madoonga in each AMD

class ................................................................................................................... 28 Table 3-18: Estimates of masses of the various domains in each AMD class at

Beebyn ............................................................................................................... 29 Table 3-19: Properties of samples selected for kinetic testing ......................................... 31 Table 3-20: Summary of acid generation and neutralisation rates ................................... 36 Table 3-21: Release rates of selected elements ............................................................. 38 Table 4-1: Mass of materials classed as NAF and PAF under simple classification

scheme (Madoonga) .......................................................................................... 43 Table 4-2: Mass of materials classed as NAF and PAF under simple classification

scheme (Beebyn) ............................................................................................... 43

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List of Figures

Figure 1-1: General location of the Weld Range Project ................................................... 2 Figure 3-1: Frequency and cumulative distribution of paste pH values for all

samples ............................................................................................................... 9 Figure 3-2: Frequency and cumulative distribution of paste EC values for all

samples ............................................................................................................. 10 Figure 3-3: Total sulphur content distribution for all samples ........................................... 11 Figure 3-4: Acid buffering characteristic curves for selected samples ............................. 15 Figure 3-5: Measured NAGpH and sulphur contents ....................................................... 18 Figure 3-6: Kinetic test sample classification relative to all samples ................................ 32 Figure 3-7: Consecutive leachate pH profiles for kinetic tests ......................................... 33 Figure 3-8: Consecutive leachate pH profiles for kinetic tests ......................................... 33 Figure 3-9: Consecutive sulphate concentration profiles for kinetic tests ......................... 34 Figure 3-10: Consecutive sulphate concentration profiles for kinetic tests ....................... 34 Figure 3-11: Arsenic concentrations for kinetic tests ....................................................... 39 Figure 3-12: Arsenic concentrations for kinetic tests ....................................................... 39 Figure 4-1: Distribution of samples within a simple classification scheme ....................... 41 Figure 4-2: Mass PAF waste and indicative MPA as a function of Sc (Madoonga) ........... 44 Figure 4-3: Mass PAF waste and indicative MPA as a function of Sc (Beebyn) ............... 44 Figure 4-4: PAF waste rock surrounded by NAF waste rock ........................................... 46 Figure 4-5: PAF waste rock under water cover in pit with water table rebound................ 46 Figure 4-6: PAF waste rock under water cover in pit without water table rebound

above base of the pit .......................................................................................... 47

List of Appendices

Appendix 1: Nomenclature Appendix 2: Static Testing Methods and Guidelines Appendix 3: Paste pH and Electrical Conductivity Appendix 4: Acid Base Account Test Results Appendix 5: Net Acid Generation (NAG) Test Results Appendix 6: Solid Multi-Element Assay (Major Elements) Appendix 7: Solid Multi-Element Assay (Minor Elements) Appendix 8: Global Abundance Indices (Major Elements) Appendix 9: Global Abundance Indices (Minor Elements) Appendix 10: Multi element Leach Analysis Appendix 11: Acid Buffering Characteristic Curves Appendix 12: Net Acid Production Potential & Classification Appendix 13: Kinetic Test Results Appendix 14: Molar Ratio Plots

SRK Consulting Geochemical Characterisation of Waste and Mineralised Rock; Static and Kinetic Testing Page x


Disclaimer

The opinions expressed in this Report have been based on the information supplied to SRK

Consulting (Australasia) Pty Ltd (SRK) by Sinosteel Midwest Corporation (SMC). The opinions in

this Report are provided in response to a specific request from SMC to do so. SRK has exercised

all due care in reviewing the supplied information. Whilst SRK has compared key supplied data

with expected values, the accuracy of the results and conclusions from the review are entirely

reliant on the accuracy and completeness of the supplied data. SRK does not accept responsibility

for any errors or omissions in the supplied information and does not accept any consequential

liability arising from commercial decisions or actions resulting from them.

SRK Consulting Geochemical Characterisation of Waste and Mineralised Rock; Static and Kinetic Testing Page xi


List of Abbreviations

Term Definition

ABCC Acid buffering characteristic curve

ALS Australian Laboratory Services

AMD Acid and metalliferous drainage

ANC Acid neutralising capacity

AP Acid potential calculated based on all non sulphate sulphur present as pyrite (kgH2SO4/tonne)

ARD Acid rock drainage

BFS Bankable Feasibility Study

BIF banded iron formation

CarbNP Carbonate neutralisation potential estimated from the measured inorganic carbon concentration and assuming all carbon is present as carbonate (CO3) (kgH2SO4/tonne)

DD Diamond drilling

DID Detrital

DSO Direct shipping ore

EC Electrical conductivity

FEL Felsic

GAI Global abundance index

HYD Hydrated

ICP-MS Inductively coupled plasma mass spectrometry

ICP-OES Inductively coupled optical emission spectroscopy

kg kilogram

m metre

MAF Mafic

MAG Magnetite

MPA Maximum potential acidity calculated assuming that all sulphur is present as pyrite (kgH2SO4/tonne)

NAF Non acid forming - a classification in regard to potential for rock to be acid forming

NAG Net acid generation (kgH2SO4/tonne)

NAPP Net acid producing potential (kgH2SO4/tonne)

NP Acid neutralising capacity (kgH2SO4/tonne)

NPR Net Potential Ratio

PAF Potentially acid forming - a classification in regard to potential for rock to be acid forming

PAF-LC Potentially acid forming and of low capacity to produce acid

PFS Prefeasibility study

pH Negative logarithm of the concentration of hydrogen ions

RC Reverse circulation drilling

RL Relative levels

SHL Shale

SMC Sinosteel Midwest Corporation

SRK SRK Consulting (Australasia) Pty Ltd

TIC Total inorganic carbon

UC Uncertain – a classification in regard to potential for rock to be acid forming

WRP Weld Range Project

SRK Consulting Geochemical Characterisation of Waste and Mineralised Rock; Static and Kinetic Testing Page 1


Introduction 1.

Terms of reference 1.1

The Weld Range Project (WRP) is a Sinosteel Midwest direct shipping ore (DSO) project.

A prefeasibility was complete at the time of sample selection for geochemical characterisation.

Since the sample selection a bankable feasibility study (Value Improvement) based on a larger pit

shell was completed.

The proposed project includes the development of open-cut pits, stockpiling of ore, blending of ore

on site and construction of waste material landforms.

Sinosteel Midwest Corporation (SMC) engaged SRK Consulting (Australasia) Pty Ltd (SRK) to

carry out a geochemical characterisation programme to assess the potential for acid and

metalliferous drainage (AMD) from rock exposed during mining; including waste rock, mineralised

stockpiles and the pit walls. The assessment is to provide guidance for waste management during

operations and establish closure requirements.



Background 1.2

1.2.1 Project location

WRP is located 600 km NNE of Perth, 65 km southwest of Meekatharra and 50 km northwest of

Cue in the Mid West region of Western Australia. A location map is provided in Figure 1-1.

Figure 1-1: General location of the Weld Range Project



1.2.2 Regional Setting and Climate

The landscape has contrasting vegetation types, but arid shrub lands make up the vast majority of

vegetation types encountered. The arid shrub lands host a number of native plant species which do

not occur in many other bioregions. There are few or no trees or perennial grasses across much of

the landscape.

Summers are characterised by hot, dry days and mild to warm dewless nights. Maximum daily

temperatures during the summer range from 29 to 38 °C and the minimum daily temperatures range

from 14 to 22 °C. Whilst cyclones are not regarded as regular events in the Meekatharra district;

they do cause widespread heavy rainfall. Cyclones usually occur between November and April

when intense low pressure disturbances develop off the north-west coast of Western Australia.

Winter is characterised by mild days and cool to cold nights. Winter average daily temperatures

range between 6 and 19 °C in July and rise to 13 and 29 °C in October (Department of Agriculture,

WA).

At Cue the average daily temperature ranges from 7 to 18°C in July to 23 to 38°C in January.

Mean annual rainfall is 232 mm with the wettest months being January to July. Average annual

open pan evaporation is about 3 m per year.

1.2.3 Geological setting

The Weld Range Project includes the Madoonga and Beebyn iron ore deposits located in the Weld

Range. Both the Beebyn and Madoonga deposits consist of steeply dipping rock sequences dipping

SE at Beebyn and SSE at Madoonga. The rock sequences include banded iron formations (BIFs)

and dolerite.

At Madoonga sediments and sedimentary rocks lie above deeply weathered rocks. The local rock

sequence comprises, from north to south, a package of felsic (FEL) sedimentary rocks that are

overlain by BIF approximately 60 to 250 m thick. The lower part of the BIF contains a 5 to 10 m

thick shale unit. A 20 to 50 m thick zone of deeply weathered and altered rocks within which the

iron mineralisation is hosted, occurs in the hanging wall of the BIF. Mafic igneous rocks including

dolerite and basalt occur in the hanging-wall to the iron mineralisation.

The Beebyn deposit contains numerous BIFs interlayered with dolerite. The main BIF at the north

is approximately 40 m thick. Thinner BIFs to the south have thicknesses ranging from about 2 to

10 m. Least altered and unweathered BIFs contain millimetre to centimetre-thick iron-, silica-,

Fe-silicate- and locally carbonate-rich bands (Kenworthy and Hodkiewicz, 2008).

The mine plan includes development of open-cut pits, stockpiles and waste rock dumps.

Report scope 1.3

This report documents the findings of the geochemical characterisation tests carried out on samples

representative of waste material and mineralised material from the proposed WRP.

The geochemical investigation comprised both static and kinetic test procedures. The scope of the

geochemical testing programme is presented in Section 2 of this report. Section 3 presents and

discusses the outcomes of the geochemical investigation. Section 4 presents a discussion of

possible waste rock management strategies. Conclusions and recommendations are provided in

Section 6.



Geochemical Investigation Programme 2.

Overview 2.1

The geochemical characterisation of wastes and mineralised material began in April 2008 with the

selection of the first set of samples (Round A) for laboratory testing. A second set of samples

(round B) was selected in March 2009.

The samples were selected to represent materials within the pit shell of the prefeasibility study

(PFS) which was based on producing Mid West Blend (MWB) ore. Since collection of the samples,

the project has progressed to the bankable prefeasibility value improvement stage (BFS VI) which

includes a pit design based on two products (MWB and Spot Market Ore).

Based on the PFS study a total mass of waste produced at the Madoonga and Beebyn deposits was

approximately 364 Mt. The substantially larger pit of the BFS (VI) would result in a total

production of 712 Mt of waste. Currently a review of the block model is being conducted to assess

the similarities of materials from within the PFS pit and materials from between the PFS and BFS

pit shells.

The geochemical investigation of samples from within the PFS pit shell was carried out in two

phases.

Phase 1 comprised a scoping study to assess the overall magnitude of the potential for acid

generation based primarily on static test procedures. Sample selection was based on a site specific

block model, the available information on lithologies and degree of weathering and estimates of the

mass of each domain that would be mined. The programme was designed to i) identify domains

that may produce acid and those that may consume acid and, ii) determine the overall variability

within each domain.

Phase 2 was designed to establish the net potential for acid generation and determine metal leach

rates using kinetic tests procedures and supplemental static tests. Materials for testing were

selected based on the outcomes of Phase 1.

There are three main objectives of kinetic testing. They are to obtain:

1. Estimates of rates of sulfate release (oxidation).

2. Estimated rates of release of metals.

3. Estimates of times to the onset of acidification of the effluent.

A secondary objective was to identify a sulphur content below which materials can be considered

unlikely to produce acidic effluent. This sulphur content may serve as a criterion for classifying

materials as PAF or NAF during mining.

An initial report on the geochemical characterisation completed as of September 2009 was reported

in October 2009 (SRK, 2009). The current report documents geochemical characterisation work

conducted up to January 2011 including that completed as of September 2009.

Identification of domains 2.2

The Weld Range iron ore deposit is hosted in sedimentary rocks and comprises two mineralised

zones; the Madoonga zone to the west and the Beebyn zone to the east. Table 2-1 presents domain

codes used in the block model and a description of the corresponding rock types. The domain

codes represent a spatial grouping of rock codes and were developed by Sinosteel Midwest

Corporation.



Table 2-1: Domains of the Weld Range block model

Domain ID General rock type

BIF Bedded sediments (host to the iron ore mineralisation)

DID Detrital, indurated conglomerate/canga material

FEL Felsic volcanic

SHL Shale

HYD Hydrated goethitic clays, non-mineralised BIF 2 material on the south western side at Madoonga

MAF Mafic/basalt/dolerite/ultramafic

O_AL High alumina goethite-hematite, hematite/goethite/limonite Fe > 45% Fe, Al2O3>4%; potentially ore grade or low grade ore

O_SI high silica goethite-hematite, hematite/goethite/limonite Fe > 45% Fe, SiO2 > 5.5%, Al2O3<4%; potentially ore grade or low grade ore

ORE Hematite/goethite/limonite Fe > 45% Fe, SiO2 < 5.5%, Al2O3<4%; ore grade rock

MAG Magnetite > 45% Fe (Beebyn only)

Note: ORE in the context of this report refers to spatially grouped mineralised material meeting certain grade criteria. As used in this report ORE is not intended to imply economic viability according to the JORC definition.

Within this report the three domains ORE, O_AL, O_SI are referred to as mineralised material.

Sampling 2.3

2.3.1 Sampling approach

A primary aim was to select samples from the major domains and a range of spatial locations from

within the planned pit. As some domains were not well represented in the drill core or cuttings

obtained from within the PFS pit shell a small number of samples were gathered from outside the

PFS pit shell.

SRK visited the Weld Range site in April 2008 and identified a total of 59 samples from the

available diamond drill core from the Beebyn and Madoonga deposits (Round A). Another

280 samples were selected in the second quarter of 2009 by SMC staff (Round B). The samples,

selected using the geological database developed during the prefeasibility study (PFS), represented

both the Madoonga and Beebyn zones and were obtained from diamond drill core where available,

reverse circulation (RC) cuttings or surface samples. Core up to 6 m in length was collected.

Table 2-2 presents the estimated mass of each domain (PFS estimate) that would be mined, the

mass distribution and the number of samples from each domain submitted for geochemical testing.

Since sample selection the pit shell has been altered. In the current design the pit is approximately

50 m deeper than in the PFS study. An initial review of drill hole locations and lithologies

indicates that all major lithologies present in the pit of the current design are represented by the

samples selected by the samples selected and reported here. A more detailed investigation of the

representativeness of samples and their spatial distribution to determine location of sulphur bearing

domains is recommended in this report.



Table 2-2: Distribution of rock samples subjected to static tests

Domain ID

Madoonga Beebyn

Mass (t)

Mass (%)

Number of

samples

% of samples

Mass (t)

Mass (%)

Number of

samples

% of samples

BIF 42,846,416 24 41 21 22,044,812 8 27 18

DID 9,419,835 5 30 16 0 0 0 0

FEL 10,548,108 6 11 6 0 0 0 0

SHL 12,831,818 7 19 10 0 0 0 0

HYD 17,223,346 10 30 16 0 0 0 0

MAF 37,908,914 21 19 10 210,973,420 75 84 57

MAG 0 0 0 0 226,560 0 4 3

O_AL 1,369,288 1 12 6 8,776,403 3 10 7

O_SI 8,471,622 5 15 8 1,947,083 1 9 6

ORE 40,303,640 22 15 8 37,682,867 13 13 9

All 180,922,987 100 192 100 281,651,145 100 147 100

Note: ORE in the context of this report refers to spatially grouped mineralised material meeting certain grade criteria. As used in this report ORE is not intended to imply economic viability according to the JORC definition.

Appendix 1 provides a table showing equivalent nomenclature used elsewhere in this report.

The various weathering states of the domains were also represented in the sampling. Table 2-3

presents the weathering state of samples collected in the second quarter of 2009. The weathering

state of samples collected in April 2008 was not available.

Table 2-3: Distribution of samples over rock domain and weathering class for samples collected in 2009

Domain ID Weathering state

No. of

Samples

Totals EW MW FR

BIF 9 18 11 38

DID 17 10 0 27

FEL 4 6 1 11

SHL 8 6 0 14

HYD 8 11 7 26

MAF 38 31 17 86

O_AL 5 12 5 22

O_SI 9 8 7 24

ORE 9 10 9 28

MAG 0 1 3 4

Totals 107 113 60 280

Note: EW, MW and FR are abbreviations of extremely weathered, moderately weathered and fresh.

2.3.2 Sample preparation

Core samples were crushed to 5 to 10 mm. Samples for static testing were further crushed to less

than 2 mm for paste pH and EC measurements and pulverised to less than 75μm for other chemical

analysis. A total of thirteen samples of core crushed to 5 to 10 mm were subjected to kinetic

testing.



Static testing methods 2.4

The static test parameters and measurement procedures used in the testing programme are

summarised in Appendix 2. The samples were sent to the SGS Laboratory in Welshpool, Western

Australia and Australian Laboratory Services (ALS), Brisbane for the static tests shown in Table

2-4. All samples from the first and second sampling programme were submitted for static testing.

Table 2-4: Test measurements and analytical methods

Measurement Analytical method[1]

Paste pH and paste electrical conductivity (EC) 1:2 solid: liquid ratio using pH and EC meter

Total sulphur Leco Analyser

Sulphate sulphur ICP-OES

Total carbon/total inorganic carbon (TIC) Leco/IR on hot acid digest

Acid neutralising capacity (ANC) Modified Sobek method

Single addition net acid generation (NAG) Single stage NAG test

Whole rock chemical assay ICP-OES/ICP-MS on four acid digest

Kinetic NAG NAG with temperature and pH time series measurement

Leach Testing Water: solids ratio using deionised water over a period of 12 hours

Acid buffering characteristics curve AMIRA, 2002

Notes: [1] See Appendix 1 for detailed method descriptions and guidelines

Kinetic testing sample selection and methods 2.5

Samples for column leaching were selected to represent the majority of domains (waste and

mineralised), NAF, UC and PAF samples based on static testing and a wide range of total S

contents. The domains represented were BIF, MAF, DID, HYD, SHL, Ore, Ore Hi Al and Ore Hi

SiO2.

The material in the four columns of Round A kinetic testing had total S contents of less than

0.1 wt% and were column tested for 16 weeks. Nine Round B samples were column tested for a

total of 45 weeks and the total S content ranged from 0.1 to 23.8 wt%.

A modified AMIRA procedure (AMIRA, 2002) was used for kinetic testing. The principal

differences related to the particle size at which the tests were completed and the flushing regime.

Flushing was increased to a weekly (rather than monthly) schedule and the samples were crushed

to less than 10 mm (rather than -4 mm).



Results and discussion 3.

Static testing results 3.1

The complete static test results are presented in Appendices; paste parameters (Appendix 3), acid

base account results (Appendix 4) and net acid generation (NAG) test results (Appendix 5).

Elemental analyses are provided in Appendix 6 and Appendix 7. Multi-element analysis of leach

extracts are reported in Appendix 10. Appendix 11 presents acid buffering characteristic curve

results. The results are briefly discussed in the following sections.

3.1.1 Paste pH and paste EC

The paste pH and paste electrical conductivity (EC) test was designed originally to measure the

load of oxidation products associated with waste material that had weathered for extended periods.

In the case of drill core, test results have to be considered in the light of how the samples were

obtained (e.g. wet or dry drilling as the drilling fluids may interact to contribute to the test

outcome) and the state of weathering (i.e. how long the core had been in storage, how it had been

stored and handled etc.).

Paste pH generally provides an indication of the state of acid generation of the sample at the time

of testing; low pH values indicate the sample is net acid generating whereas near neutral to alkaline

pH indicates that acid generation has as yet not occurred. It however cannot be used to infer that

acid generation will not occur.

In general, a high electrical conductivity is used to infer soluble salts from oxidation, however, in

the current samples the results only indicate salinity already present in the sample (i.e. evaporites or

naturally saline pore water) and not necessarily generated from oxidation.

The samples were obtained from drill core and drill cuttings that were stored in core trays for up to

18 months before testing and may have undergone some oxidation.

The majority of paste pH values were in the neutral to alkaline pH range, as shown in the

cumulative distribution plot provided in Figure 3-1. About 1% of the samples had paste pH values

below 5; one sample from each of the shale (SHL), hydrated (HYD) and banded iron formation

(BIF).

The percentages of samples in each rock type with paste pH values between 5 and 6 are presented

in Table 3-1. These results suggest that a significant proportion of the detrital (DID) and smaller

proportions of the felsic (FEL), banded iron formation, hydrated and mafic wastes could be

marginally net acid generating. Similarly, small proportions of all three mineralised domains could

also be marginally net acid generating. Drainage from the mineralised materials stored at site

would need to be controlled to prevent potential impact on the environment.



Table 3-1: Percentage of samples in each domain with paste pH values between 5 and 6

Domain ID Percentage samples with

paste pH: 5 < pH < 6

BIF 6

DID 47

FEL 9

HYD 3

MAF 2

MAG 0

SHL 0

ORE 4

O_AL 14

O_SI 21

Figure 3-1: Frequency and cumulative distribution of paste pH values for all samples

A distribution plot of the paste EC results is provided in Figure 3-2. About 2% of the samples had

paste EC values in excess of 1000 μS/cm. Of those samples with paste EC values greater than

1000 μS/cm five samples were mafic, two hydrated and one was shale.

The generally limited quantities of soluble salts present in the samples suggest that initial flushing

will not affect water quality significantly.

0%

10%

20%

30%

40%

50%

60%

70%

80%

90%

100%

0

5

10

15

20

25

30

35

40

4

4.4

4.8

5.2 6

6.4 6.8

7.2

7.6 8

8.4 8.8

9.2

9.6

10

Fre

qu

en

cy

Paste pH

Frequency

Cumulative %



Figure 3-2: Frequency and cumulative distribution of paste EC values for all samples

3.1.2 Sulphur distribution

The distribution and cumulative distribution of total sulphur content for all are presented in

Figure 3-3. Table 3-2 and Table 3-3 provide a breakdown of the distribution of sulphur content by

deposit and domain.

Ninety one percent of the samples had a total sulphur content of less than 0.1 wt%.

Although about one third of all the waste would originate from the Madoonga deposit, the results

suggests that about 94% of the sulphur would be present in the Madoonga waste rock. This is in

part due to the shale and hydrated material occurring only at the Madoonga deposit. SHL and

HYD material are the domains with the highest average sulphur contents. At Madoonga, 70% of

the sulphur is in the shale and a further 16% is in the hydrated material.

The mass weighted average sulphur content in Madoonga waste is estimated to be about 0.36% and

that in the Beebyn waste rock is estimated to be about 0.012%.

The shale at Madoonga had the highest recorded, highest average and highest median sulphur

contents of 23.8%, 2.02% and 0.39% respectively and is considered to be the most variable

domain. In contrast, the total sulphur in Beebyn waste ranged up to only 0.36% for all samples

analysed.

The maximum total sulphur contents of the mineralised rock for Madoonga and Beebyn samples

were 0.18% and 0.19% respectively. The average mass weighted sulphur contents were 0.066%

and 0.012% for Madoonga and Beebyn samples respectively.

0%

10%

20%

30%

40%

50%

60%

70%

80%

90%

100%

0

20

40

60

80

100

120

5010

015

020

0

250

300

350

500

550

600

650

700

750

800

850

900

950

10

00

Mor

e

Fre

qu

en

cy

Paste EC (uS/cm)

Frequency

Cumulative %



Figure 3-3: Total sulphur content distribution for all samples

0%

20%

40%

60%

80%

100%

120%

0

50

100

150

200

250

0.0

1

0.0

4

0.0

7

0.1

0.1

3

0.1

6

0.1

9

0.2

2

0.2

5

0.2

8

0.3

1

0.3

4

0.3

7

0.4

0.4

3

0.4

6

0.4

9

Nu

mb

er

of s

amp

les

Total S (wt%)

Frequency

Cumulative %



Table 3-2: Sulphur content by domain in Madoonga waste and mineralised rock

All waste BIF Detrital Felsic Hydrated Mafic Shale Mineralised ORE O_AL O_Si

Minimum (wt %)

0.003 0.003 0.005 0.005 0.005 0.003 0.003 0.005 0.005 0.005 0.005

Maximum (wt %)

23.800 0.778 0.100 0.030 8.560 0.480 23.800 0.180 0.180 0.090 0.100

Mean (wt %)

0.360 0.075 0.037 0.017 0.333 0.041 2.026 0.050 0.072 0.033 0.043

Median (wt %)

0.020 0.010 0.040 0.010 0.020 0.005 0.390 0.050 0.070 0.020 0.030

Rock mass (t)

130,778,437 42,846,416 9,419,835 10,548,108 17,223,346 37,908,914 12,831,818 50,144,550 40,303,640 1,369,288 8,471,622

Mass S (t)

470,622 32,339 3,510 1,774 57,354 15,680 259,929 33,000 28,884 445 3,671

S Dist (%)

100 8.7 0.9 0.5 15.5 4.2 70.1 100.0 88 1 11

Table 3-3: Sulphur content by domain in Beebyn waste and mineralised rock

All waste BIF Mafic Magnetite Mineralised ORE O_Al O_Si

Minimum (wt %)

0.003 0.005 0.003 0.005 0.005 0.005 0.005 0.005

Maximum (wt %)

0.360 0.070 0.360 0.020 0.190 0.020 0.120 0.190

Mean (wt %)

0.012 0.010 0.012 0.009 0.018 0.007 0.027 0.026

Median (wt %)

0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005

Rock mass (t)

233,244,792 22,044,812 210,973,420 226,560 48,406,353 37,682,867 8,776,403 1,947,083

Mass S (t)

28,042 2,278 25,744 20 5,577 2,754 2,326 498

S Dist (%)

100 8.1 91.8 0.1 100.0 49 42 9



3.1.3 Acid neutralising capacity

The acid neutralisation capacity or potential (NP) is determined by reacting the sample with excess

acid (generally to a pH of less than 2) and then determining the acid consumed. Excess acid

addition depresses the pH to low values which results in both carbonate and silicate minerals

reacting. During high rates of acid generation only the carbonate minerals (predominantly calcium

and magnesium carbonates) react sufficiently rapidly to neutralise the acidity and maintain neutral

pH conditions. Therefore, the carbonate NP equivalent (CarbNP) was calculated from the

inorganic carbon content of each sample to provide an indication of the carbonate mineral content.

While recognising that not all carbonate minerals react to neutralise acidity (e.g. iron-bearing

carbonates such as siderite can be less effective neutralisers), using inorganic carbon content to

infer CarbNP is a reasonable first step to assess the readily available neutralisation capacity.

The average NP results for each domain are summarised in Table 3-4. The table also provides the

corresponding average CarbNP and the ratio of average CarbNP to average NP for each unit

(expressed as a percentage). For samples where the CarbNP exceeds the NP (CarbNP/NP > 100%)

it should be expected that CarbNP in excess of the NP would not be available to neutralise acidity.

Table 3-4: Summary of NP and CarbNP results

Domain ID Wt

Dist (%)

N

CarbNP (kg(H2SO4)/t) NP (kg(H2SO4)/t CarbNP/NP

(%) Average Min. Max. Average Min. Max.

BIF 14 68 35 0 511 11 0 118 318

DID 2 30 2 1 12 2 0 4 137

FEL 2 11 2 1 3 4 1 10 45

HYD 4 30 20 1 226 2 0 8 953

MAF 54 103 3 0 52 10 0 62 26

MAG 0.05 4 145 60 221 118 91 193 123

SHL 3 19 43 0 307 24 0 127 178

ORE 17 28 6 1 120 9 0 117 59

O_AL 2 22 3 1 20 3 0 11 82

O_Si 2 24 14 1 181 12 0 168 121

Note: N= number of samples.

The results indicate that some domains have little neutralisation potential and therefore would not

be expected to provide significant buffering capacity. The units include the DID, FEL, HYD, and

high alumina mineralised (O_Al).

Waste types with significant NP included the magnetite (MAG) and SHL. However, the magnetite

unit would represent less than 1% of the total rock mass and therefore does not provide significant

overall NP. Mafic material has little carbonate neutralising capacity; therefore the majority of the

NP may not be readily available to buffer pH within a neutral pH range.

The calculated CarbNP values for BIF, HYD, MAG and SHL are greater than the respective NP

values. Thus a significant fraction of the measured total inorganic carbon is not present as

neutralising carbonates.

Mineralised ORE and high silica mineralised (O_SI) samples had an average NP of 9 and 12 kg

(H2SO4)/t equivalent with similar average CarbNP values of 6 and 14 kg(H2SO4)/t respectively.



3.1.4 Acid buffering characteristics

Eighteen samples representing a range of NP and CarbNP values were selected for acid buffering

characteristic curve testing. The complete results are provided in Appendix 11. The results of

seven samples are presented graphically in Figure 3-4 and the numerical results for all samples are

summarised in Table 3-5.

As shown in the figure, the pH of one of the samples (A13059) commenced at a pH of less than 6.

This is consistent with either an inorganic carbon content below detection (i.e. no carbonate

minerals and therefore provide no pH buffering capacity) or carbonate minerals that do not

contribute to circum neutral buffering. The remainder of the samples all commenced at a pH

above 6, were buffered in the neutral pH range for different acid additions and then decreased to

acidic pH values. This is typical of carbonate mineral buffering. The variation amongst the

different samples reflects differences in initial carbonate mineral content and possibly mineral

composition (e.g. calcite, dolomite, siderite etc.).

The curves were used to estimate the NP equivalency (i.e. NP equivalent to acid that had been

consumed) to a pH endpoint of 6 (for carbonate phases) and 4.5 to infer the availability of the NP

and the CarbNP. These results are shown in Table 3-5.

Significantly, the ABCC results indicated that not all of the carbonate minerals are available for

acid neutralisation at a pH 6 endpoint. Since only calcite and dolomite will react to buffer the pH

to above a value of 6, the carbonates that have reacted to that point are indicative of the available

CarbNP that would neutralise acidity. The difference between the pH endpoint acid consumption

and the inferred CarbNP represents carbonate minerals that would not react (e.g. siderite as

identified in the mineralogical analysis) to buffer the pH to circum neutral conditions.

In summary, the acid buffering characteristics curves indicate that both the NP and the CarbNP

lead to overestimation of the neutralisation potential available to buffer the pH to above 6 (i.e. to

prevent the onset of acid generating conditions.).



Table 3-5: Comparison of estimated neutralising capacities

Sample No. Domain Deposit NP CarbNP

ABCC (at pH 6)

ABCC (at pH 4.5)

kgH2SO4/t

A13001 Mafic B 0.98 3 1.35 2.8

A13005a BIF B 0.25 1 0.11 0.45

A13026 Shale M 47.04 85 3.2 20.3

A13027 Shale M 117.6 307 15.5 69

A13028 BIF M 12.7 212 0.58 4.2

A13030 Detrital M 0.49 5 0.24 0.85

A13034 BIF M <0.5 2 0.17 0.44

A13057 BIF M <0.5 0 0.4 0.8

A13059 b BIF M <0.5 4 0 0.7

ADML_1B_003b

Ore Hi SiO2 B 168 181 NM NM

ADML_1B_027b Detrital M 0.8 1 0 0.3

ADML_1B_056 Mafic M 7.5 1 1.2 3.8

ADML_1B_064b Ore M 0.25 0.25 0.18 0.45

ADML_1B_110b Ore Hi Al B 5.5 4 0.55 1.2

ADML_1B_137b Mafic B 0.6 2 0 0

ADML_1B_243b Hydrated M 6.4 168 0.05 0.47

ADML_1B_249b Hydrated M <0.5 2 0 0

ADML_1B_280b Shale M <0.5 2 0 0

Notes: b - Sample tested in kinetic column M - Madoonga B - Beebyn NM - not measured

Figure 3-4: Acid buffering characteristic curves for selected samples

2

3

4

5

6

7

8

9

0 20 40 60 80 100 120 140

pH

kgH2SO4/tonne

A13001

A13005

A13026

A13027

A13030

A13057

A13059



3.1.5 Net acid generation

The NAG tests are intended to provide a direct measure of the acid that may be generated by a

sample by oxidizing the sulphide minerals with a strong oxidant. The acidity generated is then

neutralised directly by the sample and the net acid generated is measured by titration with a strong

alkali. The results are summarised in Table 3-6 for both the Madoonga and Beebyn deposits. The

NAG test was conducted on 196 samples.

Overall, 9% of the samples had a NAG pH of less than 4.5 and would be considered net acid

generating. The NAG pH of 58% of the samples was above pH 6.0 and would be considered

non-acid forming (NAF). The NAG pH of the balance of the samples (33%) fell between

4.5 and 6.

The table shows for each domain the number of samples tested, the percentage of samples that

returned a NAG pH below 4.5, the percentage of samples that returned a NAG pH between 4.5 and

6, and the average NAG at pH values of 4.5 and 7. The last column shows the ratio of the NAG at

pH 7 to that at pH 4.5.

Waste rock domains that had no NAG pH values below 4.5 included the FEL unit. The

mineralised domains that had no NAG pH values below 4.5 included the ORE and the O_Si.

Domains that had no NAG pH values below 4.5 would be considered non acid forming. Although

caution is required in drawing conclusions for O_Si as only two samples were characterised. For

this domain further characterisation is necessary before a conclusion can be drawn. The large

proportion of samples that were buffered to a pH in excess of 6 within the remainder of the units

suggests that sufficient excess reactive neutralisation potential is available to maintain net pH

conditions.

The SHL would be considered most reactive as approximately 32% of the samples returned a NAG

pH value of less than 4.5, and as such would have the highest potential to generate acid. For those

samples found to be net acid generating, the average net acid generation potential was about 36 kg

(H2SO4)/t (Note that the test does not indicate the excess neutralisation potential for samples that

are non-acid forming and therefore cannot be used to infer the average net acid generation

properties of the lithological unit as a whole.)

Table 3-7 presents the total mass of each domain that would be waste rock, the fraction of the

waste rock in each domain expressed as a percentage and the percentage contribution to the total

mass by each domain that may be acid generating.

The average NAG at pH 7 of the MAF, BIF and DID ranged between 0.7 and 1.0 kg (H2SO4)/t.

The average values for HYD and SHL were 7.9 and 36.1 kg (H2SO4)/t. This suggests that some

portion of the waste could be net acid generating. Further analysis is required to evaluate the

overall potential for acid generation.



Table 3-6: Summary of NAG test results

Domain ID N Percentage samples with NAG pH Avg. NAG (kg(H2SO4)/t) NAG ratio

< 4.5 4.5 to 6 > 6 pH 4.5 pH 7 pH7/pH4.5

BIF 54 9 39 52 0.4 1.0 2.4

DID 10 10 60 30 0.005 0.7 135

FEL 11 0 27 73 0.0 0.5

HYD 26 12 42 46 6.6 7.9 1.2

MAF 43 2 26 72 0.2 0.7 4.2

MAG 4 0 0 100 0.0 0.1

SHL 19 32 32 37 31.1 36.1 1.2

ORE 10 0 20 80 0.0 0.3

O_Al 14 7 21 71 0.0 0.1

O_Si 2 0 50 50 0.0 0.1

Overall 193 9 33 58

Table 3-7: Percentage of each waste domain with NAGpH < 4.5

Domain ID Mass

(t) % Total mass

% samples of domain

with NAGpH<4.5

% Total mass with

NAGpH<4.5

BIF 64,891,228 17.8 9 1.7

DID 9,419,835 2.6 10 0.3

FEL 10,548,108 2.9 0 0.0

HYD 17,223,346 4.7 12 0.5

MAF 248,882,333 68.4 2 1.6

MAG 226,560 0.1 0 0.0

SHL 12,831,818 3.5 32 1.1

Total 364,023,228

5.2

In the NAG measurement, titration to pH 4.5 generally accounts for free acid (H2SO4) and ferric

iron generated during the oxidation of sulphide minerals (that has not been neutralized by the

contained NP). Titration from pH 4.5 to pH 7 generally accounts for acidity associated with some

metals, such as copper, that are soluble at pH 4.5 but practically insoluble at pH 7. Acidity

attributed to un-oxidised ferrous iron will also be accounted for in the titration up to pH 7 (ferrous

iron remains soluble at pH 4.5; however oxidation to ferric by atmospheric oxygen accelerates as

the pH increases).

The ratio of acidity for the two titrations (i.e. pH4.5:pH7) may be used to infer whether or not the

acidity due to metal ions (other than ferric iron) is significant. Where the ratio is one, there is no

additional acidity, but the greater the ratio the larger the contribution from metals other than ferric

iron. Where available, the ratio ranged from 1.2 to 135, suggesting that other dissolved metals are

being released when acidic conditions develop. These metals will be identified as part of the

kinetic testing programme as described in a later section.



A plot of NAGpH as a function of total sulphur content is presented in Figure 3-5. (Note the scale

has been adjusted to exclude high S content samples so that a better resolution could be obtained

for the majority of the samples.) The results indicate a general trend of decreasing NAGpH with

increasing sulphur content. Only five samples with total sulphur content of less than 0.1% had a

NAG pH of less than 4.5; this represents about 3% of samples with a sulphur content of less than

0.1%. Therefore adopting a criterion of 0.1% as a cut-off grade for non acid forming materials

would lead to a potential misclassification of about 3% of the samples. Considering the low

sulphur content, (i.e. maximum potentials for acid generation are low, less than 3 kgH2SO4/t)

sufficient excess neutralisation capacity would be expected to be available to neutralise any local

acid generation that could result. This level of misclassification is considered acceptable. Thus, it

may be appropriate to assume that samples with sulphur contents less than 0.1% are not net acid

generating.

Figure 3-5: Measured NAGpH and sulphur contents

0

2

4

6

8

10

12

0 0.2 0.4 0.6 0.8 1

NA

Gp

H

S (wt%)



3.1.6 Elemental analysis

Global Abundance Indices (GAI) values were used to identify elements that exceed normal crustal

abundances (values used for comparison are mean sediment).

For each domain the mass fraction of each element was averaged over all samples. The GAI values

in Table 3-8 were determined from the averages according to the method described in Appendix 2.

Cells were left blank in Table 3-8 and Appendices 8 and 9 where all samples had GAI values of

0 or less. Elements with GAI values of 3 or greater are generally considered to be significantly

enriched.

Table 3-8: Geochemical abundance indices for selected elements

Domain ID Ag As Co Cr Cu Fe Ni

BIF

2

2

DID 1 3

1

2

FEL

HYD 1 2

1

1

MAF

1 1 1 1 1

MAG

2

SHL 2 3 1 2 1 1 2

ORE 1 3

1 2

O_Al 1 3 1 1 1 2

O_Si 1 3

2

Domain ID Re S Sb Sc Se Te W

BIF 1

1 2 1 3 2

DID

2 3 2 5

FEL 1

3

2

HYD 1

2 2

3 1

MAF 1

1 4 1 2

MAG 1

1

1 2

SHL 3 1 2 3 1 5

ORE 1

3 2 2 5 2

O_Al 1

2 3 2 5 2

O_Si 1

2 2 2 5 2

There was generally low enrichment of the major elements, with Fe enriched in 25 samples and Ca,

Mn and S only enriched in 1 sample (out of a total of 338). There was comparable trace element

mineralisation across the range of domains, with the exception of the FEL and magnetite domain,

which are the least mineralised.

Arsenic was enriched in the detrital, shale and ORE material. The BIF contained the largest

number of samples with higher iron contents.



3.1.7 Distilled Water Leach Extractions

Distilled water leach extraction tests were conducted on 51 samples to assess the readily soluble

elements in the samples. The results are summarised in Table 3-9 with the ANZECC guideline

values for watering of stock animals. All results are listed in Appendix 10.

While the leach extraction test results cannot be used to directly estimate the water quality that

would be released from the mine waste materials, the results can be used to identify solutes that

could potentially be released at significant concentrations. Therefore, the results are compared to

Australian and New Zealand Guidelines for Fresh and Marine Water Quality (ANZECC (2000))

only to identify solutes that potentially may be of significance. Elements that exceeded ANZECC

(2000) guideline values for human health or stock watering are shaded in Table 2-1.

For all elements the median concentration was less than the ANZECC guideline value and for all

but three elements (Fe, Ni, Se) the maximum concentration was less than the guideline value. For

Ni the maximum value exceeded the guideline value by 2% and for Se the exceedance was 50%.

The largest exceedance was for iron and for which the concentration was a factor of 10 greater than

the guideline value.

Table 3-9: Summary of leach extraction test results

Element Units Minimum Median Maximum ANZECC Guideline

value

Al mg/L 0.005 0.05 4.37 5

As mg/L 0.0005 0.0005 0.055 0.5

B mg/L 0.05 0.17 1.59 5

Ca mg/L 0.5 4 57 1000

Cd mg/L 0.00005 0.00005 0.0016 0.01

Co mg/L 0.0005 0.0005 0.077 1

Cr mg/L 0.0005 0.0005 0.044 1[1]

Cu mg/L 0.0005 0.001 0.011 0.5[2]

Fe mg/L 0.025 0.13 21 2

Hg mg/L 0.00005 0.00005 0.0002 0.002

Mo mg/L 0.0005 0.0005 0.01 0.15

Ni mg/L 0.0005 0.0005 1.02 1

Pb mg/L 0.0005 0.0005 0.004 0.1

Se mg/L 0.005 0.005 0.03 0.02

SO4 mg/L 1 15 320 1000

U mg/L <0.001 <0.001 <0.001 0.2

Zn mg/L 0.0025 0.019 0.105 20

pH pH units 5.58 7.58 9.05 -

Note:

ANZECC Guideline for stock water

[1] Total Cr

[2] Sheep



3.1.8 Mineralogical assessment

A mineralogical assessment was carried out by Pontifex and Associates (Pty) Ltd. A total of

45 drill core samples from seven drill holes were assessed by petrographic analysis of polished thin

sections, with 38 of the samples also assessed using integrating semi-quantitative XRD. There are

a number of limitations of the testing procedures, some of which are overcome by the use of both

XRD and petrographic analysis (for example the identification of non crystalline clays). Sulphides

were only detected in 12 samples by optical examination, due to the fine particle size and sparse

distribution.

Whole rock chemical assay of the samples were not available at the time of analysis and therefore

could not be used as part of the mineralogical assessment.

The mineralogical assessment was provided by Pontifex, 2008. The approximate abundance of

minerals is consolidated in Table 3-10. The table summarises the mineralogical phase only.



Table 3-10: Mineralogical summary

Sample ID

Hole ID (WRRD)

Interval (m)

Host Rock &

Weathering (from SMM)

Petrographic Rock Type (Mineralogy

Report)

Mineralogy (Most to Least)

% Gross Mineralogical Composition (where provided)

From To

Carbonate Sulphide Iron Oxides Clays and Silicates Other

Do

lom

ite

Sid

eri

te

An

keri

te

Carb

on

ate

[1]

Pyri

te

Ma

gn

eti

te

Hem

ati

te

Go

eth

ite

Cla

y,

kao

lin

ite

Ch

lori

te

Qu

art

z

Fe

silic

ate

s

Mo

nazit

e

Ti

Oxid

es

Po

rosit

y/V

oid

A13011 0488 56 58 BIF BIF lim>> clay-lim > mag

5 60

15

20

A13013 0488 121 123 BIF BIF hem > dolomite >> chlorite

30

45

5

20

A13014 0488 141 143 BIF BIF hem > mag > dolomite 5-7

7-10

65

15-20

A13015 0488 163 165 BIF BIF mag, dolomite > hem > chlorite

40

<1[2]

35 15

10

A13016 0488 171 173 BIF BIF mag > hem, chlorite

3-5 45 25

20

15

A13036 0491 184 186 BIF BIF qtz (jasper) > siderite > hem > mag

45

<<1 <1 5

50

A13037 0491 226 228 BIF BIF mag > chert > fibrous Fe-silicate > siderite

5

45 1-2

1 30 15

A13004 0493 64 66 BIF BIF goeth-lim > chert > mag > hem

20 10 40

30

A13005 0493 92 94 BIF BIF goeth >> chert > hem > mag > carbonate

A13043 0520 85 87 BIF BIF hem > mag, carbonate

7

7 80

7

A13044 0520 99 101 BIF BIF hem >> goeth

1

70 20

10

A13034 0491 125 127 BIF Goethite rock goeth >> qtz > hem

A13025 0524 161 163 BIF BIF chert > siderite > mag > hem

30

1-2 10 15

50

A13028 0524 203 205 BIF BIF chert (jasper) > siderite > mag > hem

35

5-7 10 5

40

A13029 0524 210 212 BIF Siderite-BIF siderite >> mag > ?talc > fibrous Fe-silicate ?apatite tr

65

7 10

17

A13020 0524 52 54 BIF Colloform goeth rock

goeth >> hem

A13054 0529 50 52 BIF BIF hem > goeth > qtz



Sample ID

Hole ID (WRRD)

Interval (m)

Host Rock &



Report)



From To


Do

lom

ite

Sid

eri

te

An

keri

te

Carb

on

ate

[1]

Pyri

te

Ma

gn

eti

te

Hem

ati

te

Go

eth

ite

Cla

y,

kao

lin

ite

Ch

lori

te

Qu

art

z

Fe

silic

ate

s

Mo

nazit

e

Ti

Oxid

es

Po

rosit

y/V

oid

A13055 0529 55 57 BIF BIF hem

A13056 0529 72 74 BIF BIF mag, jasper >> hem

50 5

50

A13049 0525 82 84 BIF Colloform, goeth

goeth >> hem

A13050a

0525 152 154 BIF Colloform, goeth

goeth >> hem, qtz

A13052 0529 11 13 BIF Colloform, goeth

goeth >> hem, qtz

A13030

0491 8 10 Detrital Fe-rich conglom goeth > hem > qtz, clays

25 35 10

10

10

A13019a

0524 9 11 Detrital Fe-rich conglom hem > goeth

ADML 1B 027a

0245 2.7 4.6 Detrital - -

5 40 50 3

1

A13047 0525 10 12 Detrital Fe-rich conglom goeth-lim > hem > qtz

Tr

A13035a

0491 163 165 Hydrated Goethite rock goeth >> qtz, apparent clays but not shown by XRF

A13021 0524 74 76 Hydrated Colloform goeth rock

goeth >> hem, qtz

A13053 0529 35 37 Hydrated Goeth rock goeth with coarse ex-magnetite altered to lx-lim

A13023 0524 91 93 Hydrated Goeth rock goeth only

ADML 1B 243a

WRRC0875 132 133 Hydrated - -

10

1 13 18

2 56

A13010 0488 39 41 Mafic qtz microdolerite

chloritic limonitic clays > qtz, hem > lx

A13012 0488 81 83 Mafic qtz microdolerite

chlorite >> qtz > lx

A13017a

0488 174 176 Mafic Dolerite chlorite >> qtz > lx

A13018 0488 194 196 Mafic Coarse dolerite actinolite, albite, biotite, chlorite, epidote, lx

Tr



Sample ID

Hole ID (WRRD)

Interval (m)

Host Rock &



Report)



From To


Do

lom

ite

Sid

eri

te

An

keri

te

Carb

on

ate

[1]

Pyri

te

Ma

gn

eti

te

Hem

ati

te

Go

eth

ite

Cla

y,

kao

lin

ite

Ch

lori

te

Qu

art

z

Fe

silic

ate

s

Mo

nazit

e

Ti

Oxid

es

Po

rosit

y/V

oid

A13032 0491 61 63 Mafic Basalt saprolitic-lim-clays

A13007 0493 127 129 Mafic Basalt qtz > chlorite > muscovite > lx

A13008 0493 137 139 Mafic Basalt (or dolerite)

qtz > chlorite > muscovite > lx

A13040 0520 14 16 Mafic Qtz-microdolerite

hem-lim and qtz > kaolinite > lx

35

20 5

40

A13041 0520 36 38 Mafic Qtz-microdolerite

chlorite >> qtz > lx

A13046 0520 119 121 Mafic Coarse dolerite chlorite > albite and qtz > lx

1

A13022 0524 81 83 Mafic Lim-goeth rock goeth, lim, apparent clays but not shown by XRD

A13048 0525 40 42 Mafic Dolerite kaolinite > goethite > qtz > lx

ADML_1B 056 0528 238.6 240.1 Mafic - -

<1 8

89

<1 2

ADML_1B 117 0497 15.3 18 Mafic - -

4 5

65 25

<1

A13059a

0529 127 129 Mafic BIF chert > minnesotaite > mag and ?stilpnomelane

2-3 5-7 10

50 35

ADML_1B_ 003a

0489 105 106.5 Ore Hi SiO2 - -

15

<1% 65 5

5 <1 10

A13039 0491 262 264 Shale Shale/mudstone qtz > chlorite > calcite > kaolinite > muscovite

A13026 0524 180 182 Shale Shale of slate qtz > chlorite > muscovite > carbonate, hematite > lx

7-10

A13058 0529 119 121 Shale Ferruginised shale

qtz, kaolinite > muscovite

?oxid py tr

a Kinetic column tested [1] Speciation and/or abundance not indicated [2] Contains pyrite and chalcocite

Mineral legend: mag = magnetite hem = hematite goeth = goethite

lim = limonite lx = leucoxene (TiO2) py = pyrite (FeS2) tr = trace (<1% in thin section)



The results indicate:

Sulphide mineralisation is primarily pyrite (FeS2).

Carbonate minerals including siderite (FeCO3), dolomite (CaMgCO3) and calcite (CaCO3) were

present. Whilst the dolomite and calcite would be expected to react to neutralise acidity, the

rate of dissolution of dolomite can be slower than that of calcite. The dissolution of siderite

(FeCO3) will neither consume nor generate acidity. The presence of siderite is consistent with

the outcomes of the ABCC test results, and the comparison of the NP and CarbNP results.

Alumino-silicate minerals (such as chlorite), which are known to contribute towards the ANC in

the Sobek static test method, were identified in a number of samples. These minerals are slow

reacting and are generally only expected to contribute to neutralising capacity at low pH values

encountered after the onset of AMD.

3.1.9 Acid generation classification

3.1.9.1 Classification criteria

The samples were categorised generally in three classes depending on their potential to generate

acid as follows:

Potentially acid generating (PAF) where the static testing provides evidence of net acid

generation.

Non acid forming (NAF) for which the static testing provides evidence that the samples are net

acid consuming.

Uncertain (UC) for samples where evidence is less conclusive with respect to net acid

generation.

While in many cases the criteria for classification are site specific, generally accepted criteria have

been developed that usually provide reasonable accuracy with respect to net acid generation. The

criteria that have been adopted herein are based on methods described in the ARD Test Handbook

(AMIRA, 2002) and the net potential ratio (NPR) method described by Price (1997).

The NPR provides a measure of the proportions of acid neutralising capacity to acid potential:

NPR = NP/AP

Where AP is the acid generation potential expressed in kg H2SO4/tonne calculated as follows:

AP = S(S2-

) * 30.6

The NPR classifications and the criteria defining the classifications are shown in Table 3-11.

Table 3-11: NPR classification scheme

Classification NPR range

NAF NPR > 3

UC 1 < NPR < 3

PAF NPR < 1

The AMIRA classification system relies on the NAGpH, the net acid production potential (NAPP

expressed as kg H2SO4 /tonne), the NAG (pH 4.5), as well as the total organic carbon (TOC)

because organic carbon because hydrogen peroxide reacts with organic matter to produce organic

acids. The NAPP is determined as follows:

NAPP = AP - NP



Table 3-12 lists the AMIRA (2002) classifications and the criteria defining the classification.

Table 3-12: Acid-base accounting classification scheme

Class Sub-class Description

NAF - Samples with a negative NAPP value and a NAG pH of ≥4.5

PAF

PAF Samples with a positive NAPP value and a NAG pH of <4.5

PAF-LC PAF materials associated with low NAG acidities (NAG pH4.5 <5kgH2SO4/t)

Uncertain

UC(PAF) Samples with negative NAPP but giving NAG pH values <4.5

UC(PAF, high TOC) PAF samples that are associated with high TOC content (>5 wt%). The high TOC content may have interfered with the NAG test results

UC(NAF) Samples with positive NAPP value but NAG pH values ≥4.5. Some of the sulphur is possibly present in these samples in non-pyritic forms

LC=low capacity; UC=uncertain; TOC=total organic carbon; NAG pH=pH measured during net acid generation test; TOC=total organic carbon.

The AP, NAPP, NPR values and sample classifications according to both systems are provided in

Appendix 12. The results are discussed below.

We have also adopted an overriding criterion based on the sulphur cut-off grade of 0.1% below

which net acid generation is not expected to occur.

3.1.9.2 Net potential ratio

A summary of the number of samples in each class is provided in Table 3-13. The results indicate

that about 59% of the samples are non acid forming (NAF) and about 18% of the samples could be

classified as potentially acid generating. The distribution of the NAF / PAF samples is not

dissimilar to that obtained for the NAG test results (Table 3-6).

As discussed before, a number of the samples contain very low sulphur content, and thus very low

overall potential for acid generation. However, if combined with a low NP value, an NPR of less

than three is calculated even though the overall potential for acid generation is negligible. The

sample distribution was reassessed by reclassifying samples that have a sulphur content of less than

0.2% as NAF. The results are included in Table 3-13 and suggest that the fraction of the waste

samples that may be potentially acid generating could be as low as 4%.

Table 3-13: Classification of all samples according to the NPR using NP

Class Conventional

Adjusted for sulphur content

N Distribution N Distribution

NAF 201 59% 307 90%

UC 77 23% 9 3%

PAF 61 18% 23 7%

Note: N=number of samples

As discussed previously, not all of the neutralisation potential may be available to buffer the pH

within the near neutral pH range. Sample classification was revisited after assigning neutralisation

potential to a value equal to the minimum of the NP and the CarbNP values.

The results are shown in Table 3-14 for all samples combined and Table 3-15 for only waste

samples. Overall, when using a minimum NP estimate, the percentage of samples classified as

PAF increases, whilst those classed as NAF decreases. However, when low sulphur contents are

taken into account, uncertainty in NP has little effect on sample classification.



Table 3-14: Classification of all samples according to NPR using minimum of NP and CarbNP

Class Conventional Low sulphur content


NAF 178 52% 307 90%

UC 74 22% 9 3%

PAF 87 26% 23 7%


Table 3-15: Classification of waste samples according to the NPR using minimum of NP and CarbNP

Class Conventional Low sulphide content


NAF 145 55% 239 91%

UC 59 23% 8 3%

PAF 60 22% 17 6%


3.1.9.3 AMIRA

The majority (84%) of samples are classified as non acid forming (Table 3-16). The remaining

samples classify into the potentially acid forming (5%) and uncertain (11%) classification.

Samples that classified potentially acid forming included BIF (2), MAF(1), HYD(1) and SHL(5).

Table 3-16: Summary of sample classification according to the AMIRA classification scheme

Class Sub-class N % of samples

NAF 180 92

PAF PAF 7 4

PAF-LC 5 2.5

UC

UC(PAF) 2 1

UC (PAF, high TOC) 0 0

UC(NAF) 1 0.5


3.1.10 Distribution of Mass

Table 3-17 and Table 3-18 provide estimates of the mass of each domain in each class for each

deposit.



Table 3-17: Estimates of masses of the various domains at Madoonga in each AMD class

Domain ID NPR Mass (t) AMIRA Mass (t)

Mass (t) NAF PAF UC NAF PAF PAF-LC UC(PAF) UC(NAF)

BIF 42,846,416 35,531,174 4,180,138 3,135,104 38,414,028 0 4,432,388 0 0

DID 9,419,835 8,791,846 627,989 0 9,419,835 0 0 0 0

FEL 10,548,108 10,548,108 0 0 10,548,108 0 0 0 0

HYD 17,223,346 14,926,900 1,722,335 574,112 15,236,037 662,436 662,436 0 662,436

MAF 37,908,914 31,923,296 1,995,206 1,995,206 34,749,838 3,159,076 0 0 0

MAG 0 0 0 0 0 0 0 0 0

SHL 12,831,818 6,753,588 4,052,153 2,026,077 8,779,665 3,376,794 675,359 0 0

Total waste 130,778,437 108,474,913 12,577,821 7,730,498 117,147,511 7,198,307 5,770,183 0 662,436

Distribution (%) 100 83 10 6 90 5.5 4 0 0.5

O_AL 1,369,288 1,369,288 0 0 1,369,288 0 0 0 0

O_SI 8,471,622 7,342,072 1,129,550 0 8,471,622 0 0 0 0

ORE 40,303,640 29,556,003 10,747,637 0 40,303,640 0 0 0 0

Total mineralised 50,144,550 38,267,363 11,877,187 0 50,144,550 0 0 0 0

Distribution (%) 100 76 24 0 100 0 0 0 0



Table 3-18: Estimates of masses of the various domains in each AMD class at Beebyn

Domain ID NPR Mass (t) AMIRA Mass (t)

Mass (t) NAF PAF UC NAF PAF PAF-LC UC(PAF) UC(NAF)

BIF 22,044,812 22,044,812 0 0 22,044,812 0 0 0 0

DID 0 0 0 0 0 0 0 0 0

FEL 0 0 0 0 0 0 0 0 0

HYD 0 0 0 0 0 0 0 0 0

MAF 210,973,420 208,491,380 2,482,040 0 210,973,420 0 0 0 0

MAG 226,560 226,560 0 0 226,560 0 0 0 0

SHL 0 0 0 0 0 0 0 0 0

Total waste 233,244,792 230,762,752 2,482,040 0 233,244,792 0 0 0 0

Distribution (%) 100 99 1 0 100 0 0 0 0

O_AL 8,776,403 7,898,763 0 877,640 8,776,403 0 0 0 0

O_SI 1,947,083 1,947,083 0 0 1,947,083 0 0 0 0

ORE 37,682,867 37,682,867 0 0 37,682,867 0 0 0 0

Total mineralised 48,406,353 47,528,713 0 877,640 48,406,353 0 0 0 0

Distribution (%) 100 98 0 2 100 0 0 0 0



For Madoonga results suggest that:

83 to 90% of the waste (108 to 117 Mt) is NAF

10% of the waste (13 Mt) is PAF

up to 6% of the waste (8 Mt) is UC

banded iron formation (BIF), hydrated (HYD), mafic (MAF) and shale (SHL) will produce

waste that is PAF

76 to 100%mineralised materials were classed NAF

0 to 24% were classed as PAF.

The PAF mineralised material was ORE and O_SI

Mineralised material classed as PAF it had a low capacity to produce acid (< 6.1 kg(H2SO4)/t

For Beebyn results suggest that:

99% of the waste (230 to 232 Mt) is NAF

about 1% of the waste (2.5 Mt) is PAF

none of the waste would be classed as UC

the PAF waste is from the mafic domain (MAF)

all of the mineralised materials were NAF and 2% were PAF.

The PAF mineralised material was O_AL

Kinetic test results 3.2

3.2.1 Sample properties

Kinetic tests provide an indication of rates of oxidation, acid neutralisation and solute release and

can assist in identifying criteria that separate PAF materials from NAF materials. Samples were

selected to cover a wide range of sulphur contents, along with samples classified as NAF, UC and

PAF.

Properties of samples selected for kinetic testing are shown in Table 3-19. The acid producing and

acid neutralising capacities of kinetically tested samples are also represented in Figure 3-6 together

with those of all other samples submitted for static test work. The kinetically tested samples are

highlighted in yellow squares.

Four samples selected from the Round A samples were tested in columns for 16 weeks in 2009.

These samples were classed as PAF based on static testing but had low total sulphur contents

ranging between 0.02 and 0.07 wt% S. The four samples were A13017, A13019, A13035 and

A13050. The testing of these samples was stopped after 16 weeks.

Another nine samples were selected from Round B samples. These samples were tested during

2010 over a period of 45 weeks. The columns were still operating at the time of preparation of this

report.

Two of the nine samples A13017 and ADML_1B_003 which are clearly non-acid forming due to

the low sulphur content and high NP and were selected to assess the potential of solute release from

net neutral samples.

Some sample names contain the prefix ADML_1B. For convenience the prefix will be omitted

when referring to the samples in the following text. For example ADML_1B_003 will be referred

to as 003.



Table 3-19: Properties of samples selected for kinetic testing

Sample ID

Units

ADML_1B_ ADML_1B_

249 137 280 A13059 O64 110 243 O27 _003 A13017 A13019 A13035 A13050

Lithology HYD MAF SHL BIF Ore Ore Hi Al HYD DID Ore Hi SiO2 MAF DID HYD BIF

Static Class PAF PAF PAF PAF PAF UC PAF PAF NAF NAF PAF PAF PAF

NP (ANC) kgH2SO4/t <0.5 0.6 <0.5 <0.5 <0.5 5.5 6.4 0.8 168 38.22 <0.1 <0.1 <0.1

CarbNP kgH2SO4/t 2.45 2.45 1.63 3.67 1.63 4.1 168.2 0.82 181 11 12 5 4

ABCC NP kgH2SO4/t 0 0 0 0 0.18 0.5 0.47 0.4 NM NM NM NM NM

S(T) % 8.56 0.36 23.8 0.778 0.18 0.12 0.47 0.1 0.19 0.02 0.07 0.09 0.05

SO4 % 0.48 0.06 0.22 0.26 NM NM 0.02 NM NM NM 0.02 0.01 0.01

ST-SO4 wt% 8.08 0.30 23.58 0.51 NC NC 0.45 NC NC 0.02 0.05 0.08 0.04

MPA kgH2SO4/t 261.9 11.0 728.3 23.8 5.5 3.7 14.4 3.1 5.8 0.5 2.0 2.8 1.5

AP kgH2SO4/t 247.2 9.2 721.7 NC NC NC 13.7 NC NC NC 1.5 2.4 1.2

NAGpH(ox) pH units 1.7 4 1.7 1.9 NM 8 5.8 NM NM 7.5 5.3 6.1 5.7

NAPP kgH2SO4/t 246.7 8.6 721.4 23.6 5.3 -1.8 7.3 2.3 -162.2 -37.8 1.5 2.3 1.0

NPR (NP/AP) 0.00 0.00 0.07 0.00 0.01 0.05 1.50 0.47 0.26 28.90 83.27 0.33 0.20 0.41

Grey cells indicate that the NP was below detection limit and NP has been taken as equal to half the detection limit (0.5 kg(H2SO4)/t)

Static class is based on the neutralisation potential ratio (NP/AP)



Figure 3-6: Kinetic test sample classification relative to all samples

3.2.2 Results and discussion

A summary of findings arising from kinetic testing is provided in the following sections. The

complete results together with plots of selected parameters are presented in Appendix 13.

3.2.2.1 Acid generation and neutralisation

The oxidation of sulphides produces reaction products that include sulphates and acidity. Where

the acid is not neutralised the pH of the column leachate decreases. Sulphate minerals may be

present in the sample material prior to starting column operation, possibly having formed as a result

of previous oxidation of sulphides.

The leachate pH values for consecutive leach cycles are illustrated in Figure 3-7 and Figure 3-8.

The time-series plots show that leachates from nine samples remained in the near neutral pH range,

indicative of carbonate mineral buffered pH conditions. In addition, the sulphate to (calcium

+ magnesium) molar ratio remained at or below a value of one (see plots provided in Appendix 14),

consistent with carbonate-based neutralisation of acid generated from sulphide oxidation.

Leachates from four samples were acidic at week 45 (Samples 249, 137, 280 and A13059). All

four samples were classed as PAF by static testing. Of the 13 samples kinetically tested these

samples had four of the five largest total S contents.

With respect to the four tests that have given acidic leachate, the following comments can be made:

Two of the samples produced long-term average leachate pH less than 3. In both cases, the

leachate was acidic immediately (by Week 2).

Two samples produced long-term average leachate pH around 4.3. In one of these samples, the

pH of early leachates was near-neutral, then plateaued at pH 5 before settling at the long-term

average value around Week 31.

The lowest total sulphur content of a material that had produced acidic effluent was 0.36 wt%

S.

0.1

1

10

100

0.001 0.01 0.1 1 10

AN

C (

kg

[H2S

O4)/

t[ro

ck

])

Total S(wt%)

NPR=1

NPR=3

Kinetic columns

BIF

Detrital

Felsic

Hydrated

Mafic

Magnetite

Ore

Ore Hi Al

Ore Hi SiO2

Shale

NAFUC

PAF

A13017

Acidic at week 45

Stopped at week 16



Figure 3-7: Consecutive leachate pH profiles for kinetic tests

Figure 3-8: Consecutive leachate pH profiles for kinetic tests

The change in sulphate concentrations over time in the kinetic test leachates are shown in Figure

3-9 and Figure 3-10 (note the logarithmic scale on the y-axis).

2.0

3.0

4.0

5.0

6.0

7.0

8.0

9.0

0 10 20 30 40 50

pH

Time (weeks)

ADML_1B_137

ADML_1B_249

ADML_1B_280

A13059

3.0

4.0

5.0

6.0

7.0

8.0

9.0

0 10 20 30 40 50

pH

Time (weeks)

ADML_1B_003

ADML_1B_027

ADML_1B_064

ADML_1B_110

ADML_1B_243

A13017

A13019

A13035

A13050



The higher sulphate concentrations in the early leachates probably reflect leaching of pre-existing

readily soluble sulphate from the sample. The longer term sulphate release is more likely to reflect

sulphate released by sulphide oxidation taking place during the test.

Figure 3-9: Consecutive sulphate concentration profiles for kinetic tests

Figure 3-10: Consecutive sulphate concentration profiles for kinetic tests

Solute concentrations in column leachates during the last few weeks of column operation were used

to calculate acid production and acid neutralisation rates. The rates are presented in Table 3-20.

For some samples the estimated rates of acid production may be overestimates as the sulphate

concentrations were decreasing in the last few weeks or were below the detection limit.

1

10

100

1000

0 2 4 6 8 10 12 14 16

Sulp

hat

e C

on

cen

trat

ion

(m

g/l)

Time (Weeks)

A13017

A13019

A13035

A13050

0.1

1

10

100

1000

10000

0 10 20 30 40 50

Sulp

hat

e c

on

cen

trat

ion

mg/

L)

Time (weeks)

ADML_1B_003

ADML_1B_027

ADML_1B_064

ADML_1B_110

ADML_1B_137

ADML_1B_243

ADML_1B_249

ADML_1B_280

A13059



Estimates of the time to deplete the remaining acid potential and neutralisation potentials are also

reported in Table 3-20. For the neutral columns 064, 110 and 243 the neutralising potential was

predicted to be depleted within 1 to 9 years. Assuming that acid continues to be produced the

leachates would then become acidic.

It was estimated that the leachate from column 003 would remain neutral for about 200 years.

For columns A13019, A13035 and A13050 the neutralising potential was predicted to be depleted

before the acid potential. However, for these columns the total S content was less than 0.1 wt% S.

As will be discussed in Section 4.2, for these low sulphur contents there is reason to expect that the

columns will not become acidic.

Kinetic columns provide measurements of rates of acid production and acid neutralisation of waste

material under laboratory conditions. The laboratory measured rates may differ from field rates

due to a number of factors. One of these factors is the difference between the particle size

distribution of samples placed in columns and the particle size distribution of waste in a waste rock

dump or stockpile. This and other factors will be taken into consideration when using column-

derived data to estimate acid production rates applicable to waste rock dumps.



Table 3-20: Summary of acid generation and neutralisation rates

Sample ID

Units

ADML_1B_ ADML_1B_

249 137 280 A13059 O64 110 243 O27 _003 A13017 A13019 A13035 A13050

pH at week 45/16 pH units 2.8 4.3 2.7 4.3 7 7.5 7.9 6.6 8.8 7 6.5 6.5 6.5

Con

sum

ptio

n

rate

s NP (ANC) kg(H2SO4)/t/wk 0.0018 0.0007 0.0421 0.0025 0.0023 0.0103 0.0317 0.0007 0.0158 0.0057 0.0031 0.0061 0.0053

AP kg(H2SO4)/t/wk 0.1914 0.2500 0.6375 0.0078 0.0004 0.0004 0.0046 0.0004 0.0004 0.0011 0.0033 0.0033 0.0008

Tim

e to

co

nsu

me

rem

ain

ing

NP (ANC) years 0.0 0.0 0.0 0.0 0.0 9 3 20 204 129 6 3 4

ABCC NP years 0.0 0.0 0.0 0.0 0.5 0.1 0.0 9 NM NM NM NM NM

AP years 26.0 79.0 22.0 36.0 256.0 199.0 56.0 145.0 294.0 8.0 10.0 13.7 32.3



3.2.2.2 Solute leachability

Table 3-21 summarises calculated average solute release rates calculated from data obtained during

the last few weeks of column operation.

In general, higher element release rates coincide with acidic effluents. For example, for sample

280 (a shale), which had a pH of 2.8, the Al and As release rates were 16.6 and 0.11 mg/kg/wk.

Whereas for sample 027, at pH 6.6, the release rates for the same metals were 0.005 and

0.00048 mg/kg/wk.

The evolution of As in column leachates is presented in Figure 3-11 and Figure 3-12. Results for all

columns and all metals are presented in Appendix 13.

As discussed in Section 3.2.2.1 rates measured for laboratory samples may differ from rates for

reactions under field conditions. This should be considered when using the laboratory measured

rates, for example, in water quality predictions.



Table 3-21: Release rates of selected elements

Sample ID

Release Rate (mg/kg/wk)

ADML_1B

_003 _027 _064 _110 _137 _243 _249 _280 A13059 A13017 A13019 A13035 A13050

Stability wk

38 22 22 30 38 31 30 30 28 13 13 13 13

pH 7.98 6.16 6.78 7.62 4.3 8.06 2.81 2.8 4.38 7.2 6.1 6.7 6.8

Sulphate 0.37 0.40 0.41 0.34 2.2 4.86 187 687 8.19 1.07 3.24 3.25 0.75

Al 0.013 0.0047 0.0099 0.0066 0.051 0.0056 2.47 16.61 0.057 0.011 0.0036 0.0030 0.0038

Sb 0.0001 1.06 x 10-5

1.86 x 10-5

7.06 x 10-6

2.73 x 10-5

7.17 x 10-5

0.0012 0.0009 1.28 x 10-5

0.0001 3.6 x 10-6

1.48 x 10-5

0.0007

As 0.0038 0.0005 0.0012 0.0001 6.86 x 10-5

6.41 x 10-5

0.039 0.11 0.0003 0.0013 0.0001 0.0003 0.0002

Cd 7.44 10-6

0.0014 0.0013 0.0040 1.07 x 10-5

0.0063 0.0049 0.002 0.0020 7.1 x 10-6

7.2 x 10-6

5.9 x 10-6

7.5 x 10-6

Ca 3.75 0.12 0.37 1.36 0.15 1.01 0.14 0.14 0.77 0.85 0.91 0.52 1.2

Co 3.72 x 10-5

0.0002 0.0002 3.41 x 10-5

0.0004 3.82 x 10-5

0.016 0.41 0.0021 3.55 x 10-5

0.0012 2.95 x 10-5

3.75 x 10-5

Cu 0.0037 0.0047 0.0041 0.0034 0.0031 0.0030 0.039 0.49 0.0057 0.0036 0.0036 0.0030 0.0038

Fe 0.0059 0.0080 0.0052 0.0034 0.005 0.0064 89.3 184.04 0.89 0.014 0.0036 0.0030 0.0075

Pb 0.0003 0.0004 0.0002 0.0002 0.0004 0.0003 0.0044 0.0008 0.0009 0.0002 0.0002 0.0004 0.0002

Mg 1.65 0.10 0.32 1.06 0.077 6.90 0.36 9.78 0.095 0.90 0.21 1.19 0.58

Mo 0.0004 2.78 x 10-5

0.0001 3.91 x 10-5

1.57 x 10-6

0.0002 0.0001 6.87 x 10-5

2.14 x 10-5

9.94 x 10-5

1.8 x 10-5

0.0002 0.0006

Ni 0.0037 0.0040 0.0041 0.0034 0.0031 0.0030 0.039 0.99 0.0043 0.0036 0.0036 0.0030 0.0038

Se 0 3.51 x 10-5

5.34 x 10-5

0 0 0 0 0 0 0.0002 0.0002 0.0027 0.0002

Zn 0.0037 0.016 0.010 0.0045 0.020 0.010 0.036 0.054 0.047 0.0071 0.0072 0.0089 0.0075



Figure 3-11: Arsenic concentrations for kinetic tests

Figure 3-12: Arsenic concentrations for kinetic tests

0

0.001

0.002

0.003

0.004

0.005

0.006

0.007

0.008

0 2 4 6 8 10 12 14 16

Ars

en

ic C

on

cen

trat

ion

(m

g/l)

Time (Weeks)

A13017

A13019

A13050

A13035

0.0001

0.001

0.01

0.1

1

0 10 20 30 40 50

Ars

en

ic c

on

cen

trat

ion

(m

g/L)

Time (weeks)

ADML_1B_003

ADML_1B_027

ADML_1B_064

ADML_1B_110

ADML_1B_137

ADML_1B_243

ADML_1B_249

ADML_1B_280

A13059



Waste Rock Management 4.

Simple classification scheme 4.1

A simple classification scheme is required for developing a block model of waste types and for classing

materials during mining. Materials classed as PAF under the simple scheme would be segregated during

mining and managed to control the development and impact of acid and metalliferous drainage.

Static test results conducted in 2009 were used to classify the waste and ore samples as potentially acid

forming (PAF), non-acid forming (NAF) or uncertain (UC). The NPR classification scheme was used.

This classification scheme is an internationally accepted method of screening the potential of materials to

be PAF. However, the classification scheme requires the measurement of the acid neutralising capacity

and the acid generating potential.

The acid generating potential can be estimated from the total S content, which can be readily and

routinely measured as part of the resource definition work. The ANC cannot be estimated reliably using

parameters routinely included in resource definition work. Measurement of ANC is potentially more time

consuming than determination of the total S content.

To provide a simple classification scheme, a scheme based on total sulphur content is proposed. A

fundamental assumption is that samples with total S contents less than a threshold value Sc are non-acid

forming and those with total S greater than Sc are potentially acid forming. Figure 4-1 shows the new

simple classification system projected onto the previous classification system. Some low S samples,

previously classed as PAF would now be classed as NAF (Region C) – however, as discussed earlier

(Section 3.1.5), the acid potential associated with these samples is extremely low.

Some samples previously classed as NAF will be classed as PAF (Region B) because their total S content

is greater than Sc. An outcome of this is that a mass of material previously classed as NAF is destined to

be managed as PAF material. However, as will be shown, relatively small masses of material are

involved.

As the value of Sc is increased the mass of material classed and managed as PAF decreases. However,

there is a risk that a portion of the material with a total S content less than Sc is potentially acid forming.

Thus, as Sc increases the risk of not managing potentially acid forming material appropriately increases.



Figure 4-1: Distribution of samples within a simple classification scheme

Selection of Sc for Weld Range 4.2

Static testing of Weld Range materials suggested that some samples with low total S content are

potentially acid forming. Kinetic testing included PAF-classed samples with total S contents ranging from

0.10 to 23.8 wt%. As of Week 45, only those samples with total S ≥ 0.36 wt% had produced acidic

effluent. Current data thus places an upper bound on the Sc value of 0.36 wt% S. In the case of the PAF

columns with lower total S, it remains possible that acid leachates could be produced. Thus it remains

possible that a Sc should be set to at a value less than 0.36 wt% S.

Only about 3% of samples with total S contents less than 0.1 wt% had NAGpH values less than 4.5 and

the majority of samples had circum neutral of alkaline NAGpH values (Section 3.1.5). This indicates that

0.1 wt% S may be a suitable to value for Sc.

SRK recommend that a lower Sc threshold is used, 0.1 wt% S. This threshold is known to be applied

elsewhere within the Pilbara to differentiate wastes with very low risk of generating ADML. Also, an

International Kinetic Database reported by Morin et al. (1995) showed that no incidences of acidic

leachate were documented for samples with initial sulphur content less than 0.1% (30 such samples were

included, and none generated leachate of pH less than 5).

While a lower value for Sc decreases the risk of not identifying and not managing PAF material it also

results in a larger volume of material being treated as PAF waste. However, Section 4.3 shows that the

increase in the mass of waste treated as NAF is relatively small as for a range of Sc values between 0.1

and 0.25.

0.1

1

10

100

0.001 0.01 0.1 1 10

AN

C (

kg

[H2S

O4)/

t[ro

ck

])

Total S(wt%)

NPR=1

NPR=3

Sc =0.1

NAF

UC

PAF

NAF

UC

PAF

Sc=0.1

A

B

C

D



It may be possible to obtain data that supports increasing the value of Sc (and decreasing the mass of

waste classed PAF) from the samples that were leach tested for 45 weeks. Sample material removed from

the columns would be submitted for static testing to determine the quantity of oxidisable sulphur

remaining in each column sample.

The test would be conducted by collecting a subsample from each column of material that has not

produced acidic leachate. Each subsample would then be split and one portion (A) analysed to determine

the total S and sulphate S content. The second portion (B) would be reacted with peroxide to oxidise

available sulphides to sulphates. The quantity of sulphates would be determined.

If the quantity of sulphates determined for the oxidised portion (portion B) does not exceed the quantity

of sulphates in the unreacted portion (portion A) then it can be concluded that there are no sulphides in

the materials that are readily oxidised and could contribute to acid production. Where this is the case it is

unlikely that the samples will produce acidic leachate in the future.

It is expected that results would be available from a commercial laboratory about two to three weeks after

the receipt of samples and that the tests would be relatively inexpensive (less than $2500).

SRK therefore recommends that the operation of columns is stopped and the samples are collected from

all neutral columns that were operating to week 45 and sent to a commercial laboratory to measure the

quantity of remaining oxidisable sulphide.

Mass Dependence on Sulphur Threshold 4.3

For six values of Sc, Table 4-1 presents, estimates for the Madoonga deposit of the:

1. Mass of waste rock that would be classed as PAF under the simple scheme (regions B+D; Figure 4-1)

2. Mass of waste rock that would be classed as PAF under the simple scheme and was classed as NAF

under the NPR scheme (region B; Figure 4-1).

3. Mass of waste rock classed as PAF under the simple scheme and as PAF or UC under the NPR

scheme (region C; Figure 4-1).

The mass of waste classed as PAF at Madoonga under the simple scheme is also shown in Figure 4-2 for

several values of Sc. The figure shows that the mass of waste that would be classed as PAF decreases as

Sc increases. Note that the mass of PAF waste decreases by only a small fraction for Sc values between

0.1 and 0.25 wt% S.

Table 4-2 and Figure 4-3 present similar data for Beebyn.

The masses of waste that would be classed as PAF using a total S cut-off grade of 0.1 wt% S are:

Madoonga - 21 Mt

Beebyn - 3.3 Mt

The above estimates of the masses of PAF material are based on the PFS pit design. The masses may

change as a result of the review of the distribution of PAF material within the BFS pit shell.

A water quality assessment will be conducted to assess the potential impact of the PAF wastes and

stockpiles on water contacting the dumps and stockpiles. It is possible that the assessment will find that

some PAF material will not significantly impact water quality and that the mass of material to be

managed to control acid drainage and metalliferous leaching is less than stated above



SRK recommends that Sinosteel plan to manage approximately 21 Mt of PAF waste at Madoonga and 3.3

Mt of PAF waste at Beebyn pending the findings of a) the review of the distribution of PAF material

within the BFS pit shell and b) a water quality assessment.

Table 4-1: Mass of materials classed as NAF and PAF under simple classification scheme (Madoonga)

Sc

wt%

Region

B+D B C

Mass treated

as PAF

(tons)

Mass treated

as PAF

when it is NAF (t)

Mass. of PAF or UC material

with S content < Sc

(tons)

0 130,778,437 66,282,407 0

0.05 34,939,845 3,810,462 31,065,634

0.1 20,577,378 1,720,393 43,966,021

0.15 16,381,258 675,359 48,790,130

0.2 14,188,000 675,359 50,409,276

0.25 13,142,966 675,359 52,028,422

Table 4-2: Mass of materials classed as NAF and PAF under simple classification scheme (Beebyn)

Sc

wt%

Region

B+D B C

Mass treated as

PAF

(tons)

Mass treated

as PAF

when it is NAF (t)

Mass. of PAF or UC material

with S content < Sc

(tons)

0 233,244,792 213,453,703 0

0.05 9,079,070 5,780,555 16,492,574

0.1 3,298,515 816,475 17,309,048

0.15 3,298,515 816,475 17,309,048

0.2 3,298,515 816,475 17,309,048

0.25 3,298,515 816,475 17,309,048



Figure 4-2: Mass PAF waste and indicative MPA as a function of Sc (Madoonga)

Figure 4-3: Mass PAF waste and indicative MPA as a function of Sc (Beebyn)

0.0E+00

2.0E+07

4.0E+07

6.0E+07

8.0E+07

1.0E+08

1.2E+08

1.4E+08

0 0.05 0.1 0.15 0.2 0.25 0.3

Mas

s P

AF

was

e r

ock

(t)

Sc (S wt% )

Madoonga

0.0E+00

5.0E+07

1.0E+08

1.5E+08

2.0E+08

2.5E+08

0 0.05 0.1 0.15 0.2 0.25 0.3

Mas

s P

AF

was

e ro

ck (

t)

Sc (S wt% )

Beebyn



Management Strategies 4.4

Current indications are that a small proportion of the waste rock and mineralised material could be PAF.

The impact of the PAF material on water quality has not yet been evaluated. An evaluation of this type is

proposed in the next section.

In the event that a water quality assessment determines that it is necessary to manage PAF material

several options are available including i) covering or isolating the PAF waste with NAF materials to

reduce the quantity of water contacting the PAF waste (Figure 4-4), ii) co-mingling or blending the PAF

waste with NAF waste that has excess neutralisation capacity and iii) segregating and placing the PAF

waste where acid generation can easily be controlled or prevented (e.g. backfilling to the open pit below

the long term water table).

For option i) NAF material would be placed at the base of the dump to reduce contact between PAF waste

and the water that flows at the interface of the waste (base of the dump) and the original ground surface.

PAF material would then be covered with NAF material, graded to enhance runoff and compacted to limit

infiltration, thus reducing the contact between incident rain and PAF waste. Depending on the properties

of the NAF material (e.g. thickness of layer, sulphide mineral content, particle size distribution,

weathering properties etc.), it may also serve to reduce the availability of oxygen to the PAF material thus

reducing the rate of oxidation. This management strategy may be used during mining when the pit is

being constructed and PAF material must be removed from the pit for efficient mining.

Blending PAF material with material containing excess neutralisation capacity generally requires tight

controls on blending ratios and is operationally complex to implement. Success has been limited in the

past due to the fact that it is not always possible to achieve well mixed conditions during placement and

maintain contact between the acid produce and neutralising materials in the longer term. Based on current

information this option would not be recommended.

In-pit disposal could limit to very low levels, or even preclude, oxidation of sulphides if the PAF waste is

placed below the long term steady water level in the pit. Because of the demonstrated performance on

controlling oxidation and acid generation, placement of PAF materials below the water table within the

open pit is believed to be the most effective option for managing PAF waste rock at the site.

The relative levels (RL) of the groundwater prior to digging of the pits at Madoonga and Beebyn were RL

481 and RL 495 m respectively. Preliminary hydrogeology investigations indicate that 25 years after

mining has finished the water level would have risen to RL 430 and RL 480 m at Madoonga and Beebyn

respectively. These levels are below the original groundwater level. Thus, there would be no net

groundwater recharge from the pits for at least 25 years.

Waste placed at the base of the pit would be flooded, reducing the diffusive supply of oxygen to the waste

by about four orders of magnitude and slowing the rate of oxidation greatly. A schematic arrangement of

the waste in the pit is shown in Figure 4-5. Benign or NAF material placed over the PAF material would

reduce the evaporative loss of rain and rising groundwater prior to flooding of the pit as a result of the

recovery of the groundwater levels. The importance of the NAF layer in reducing evaporation increases in

the event that the balance of recharge and evaporation is such that the water level in the pit does not rise

far above the pit floor (Figure 4-6).



Figure 4-4: PAF waste rock surrounded by NAF waste rock

Figure 4-5: PAF waste rock under water cover in pit with water table rebound

PAF WASTE ROCK SURROUNDED BY NAF WASTE ROCK

Base seep

LEGEND

PAF or metal leachingUC

NAF and non-metal leaching

Water flux direction

Natural Surface Level

Water Level

Low 's' concentrations = low oxygen consumption rates = widespread distribution of oxygen = PAF oxidation

X:\Projects\SMM001 - Weld Range Iron Ore Project BFS\06_Working_Files_\Drafting

\H_Data in Drafting\Acid Waste Rock Sketches - 24.09.09\A4 Figures 250909.dwg

N.S.L.

W.L.

To groundwater N.S.L.

PAF UNDER WATER COVER IN PIT

PAF / metal leaching

Benign material over PAF

N.S.L.

W.L.

PAF material is placed in bottom

of pit. Water level rebounds to

cover PAF material over time



Pit shellLEGEND





Water Level

N.S.L.

W.L.



Figure 4-6: PAF waste rock under water cover in pit without water table rebound above base of the pit



PAF UNDER EVAPORATIVE LOSS POND

N.S.L.

Pit shell

W.L.

Evaporative loss of water RainfallRainfall

Groundwater flow Groundwater flow

PAF / metal leaching

Benign material over PAF

LEGEND





Water Level

N.S.L.

W.L.



Current and Future Work 5.

Estimates of the quantities of PAF material in the Madoonga and Beebyn pits in this report are based on

the PFS pit shell. The current (BFS) pit is larger than the PFS pit shell and consequently more waste will

be produced. Thus there is a need to determine how well samples collected from within the PFS pit shell

represent the rock types within the BFS pit shell.

Materials outside the PFS pit shell and inside the BFS (VI) pit shell were not sampled to any significant

degree. Therefore these materials have not been classified as either PAF or NAF. Available information

should be reviewed to determine the distribution of sulphur within these materials

Quantities of PAF material, rates of acid production and neutralisation and rates of solute release have

been estimated from kinetic testing of waste and stockpile material. These quantities are determined in

part for use in assessing the impact of mined materials on the quality of water that they contact. One

possible outcome of a water quality assessment is the need to manage the PAF waste to reduce the

potential impact on waters.

Current and future recommended work includes:

a) The current review of the distribution of PAF material within the BFS pit shell

b) An assessment of the quality of water that contacts the waste and mineralised material.

PAF material - mass and distribution and schedule 5.1

Available drillhole logs, the geological model and the block model will be reviewed to estimate the mass

and spatial distribution of PAF material (based on distribution of sulphur within the materials).

The accuracy of the estimates will depend on the both the accuracy of the classification of the wastes as

PAF and the quantity and locations of relevant geological data obtained from drillhole sampling.

At Weld Range the drillholes collars are typically located to the south of the mineralised zone and

drillholes dip to the north and terminate near the mineralised zone. Thus, wastes in the northern side of

the pit are sparsely sampled. SRK understands there is no block modelling to the north. In the absence of

drillhole and block model data, the geological model will be used to infer masses of the various

lithologies and alteration types. Simulation of sulphur grades in the northern waste may be undertaken if

appropriate.

The objective will be to assign a classification (PAF or not PAF) to waste material at the same spatial

resolution as the block model units. Any assumptions made regarding the spatial distribution of the

geological and the geochemical characteristics will be reported.

The movement of pit waste will then be reported as per the current mining schedule. The time steps in the

scheduling will be one year. The spatial locations of the PAF waste blocks will be tracked and the likely

spatial locations within proposed waste dumps recorded.

Water Quality Assessment 5.2

The findings of the static and kinetic testing of the previous section show that there is potential for acid

drainage or metal leaching being produced from some materials in waste rock dumps, pit walls or

stockpiles at Weld Range. It is necessary therefore to assess how water quality might be affected.



A water quality assessment would include:

1. Development of a model to predict water quality from waste rock dumps. It will be necessary to make

assumptions at this stage. For example, the distribution of oxidation and neutralising rates in the

dump will be assumed.

2. Prediction of contaminant release rates from the dump for each lithological unit where possible.

3. Assessment of potential oxygen transport constraints because the contaminant release rate is

dependent on the oxidation rate.

4. Prediction of the potential quality of water seeping from the dump by assessing the rainfall and net

infiltration, seepage evolution through the different lithologies in the dump and by assuming flow

paths through the dump. The geochemical modelling programme PHREEQC will be used where

appropriate.

5. Review of water receptors. Whilst the seepage discharged from the dump may be of poor quality,

there may not be any receptors that will be affected by it both from a negative impact and legal

perspective. With the assistance of Sinosteel Midwest Management possible receptors will be

identified and the potential implications of the seepage on these will be assessed and conceptual

strategies to minimise the impacts will be identified (e.g. reducing seepage volume and impact by

limiting oxygen and water inflow).

6. Identification of strategies for management of waste rock and pit walls. An assessment of the

implications of implementing the various proposed strategies will be conducted taking into account

mine planning, groundwater and surface water conditions and requirements.



Conclusions and recommendations 6.

Conclusions 6.1

Some materials contain stored acidity and at the time of mining they could have potential to release

acid. These materials include a significant proportion of the detrital (DID) and smaller proportions

of the felsic (FEL), banded iron formation, hydrated and mafic wastes. Similarly, small proportions

of the three mineralised domains (ORE, O_AL, O_SI) could also be marginally net acid generating.

Generally there are limited quantities of soluble salts present, which indicate that flushing of the

mined materials prior to oxidation will not affect the solute content of water significantly.

The majority of waste rock and mineralised materials are expected to have low total sulphur

contents. Of the 339 samples subjected to static tests, 91% of the samples had a total sulphur

content of less than 0.1 wt%.

Non neutralising carbonates are present and therefore the minimum of the neutralising potential NP

and CarbNP was the most appropriate measure of the neutralising capacity available for the

majority of samples. A small number of acid buffering characteristic tests indicated that the actual

neutralising potential for some material may be less than the minimum of the NP and CarbNP.

Static and kinetic leach testing indicates that solute release rates are generally low under neutral

conditions and can increase under acidic conditions.

The masses of PAF, NAF and UC waste and mineralised material were estimated using

conventional static testing and classification methods and are presented in the tables below for the

Madoonga and Beebyn deposits.

Madoonga

NAF PAF UC PAF

Domains

Waste Mass % 83 to 90 10 0.5 to 5.5 BIF, HYD,

MAF, SHL, DID Mass (Mt) 108 to 117 13 0.7 to 8

Mineralised Mass % 76 to 100 0 to 24 0

ORE, O_SI Mass (Mt) 38 to 50 0 to 12 0

NAF – non-acid forming. PAF – potentially acid forming, UC – uncertain (screening tests do not clearly identify sample as PAF or NAF)

Beebyn

NAF PAF UC PAF Domains

Waste Mass % 99 to 100 0 0 to 1

MAF Mass (Mt) 231 to 233 0 0 to 2.5

Mineralised Mass % 98 to 100 0 0 to 2

O_Al Mass (Mt) 47.5 to 48.4 0 0.9

At least some of the materials classed as PAF by static tests did produce acidic effluent in column

tests, verifying their potential to produce acidic drainage in waste dumps. The acid leachates were

produced in column tests involving materials with relatively high total S contents (≥ 0.36 wt%).



It is not clear from investigations on samples from Weld Range whether PAF-classed materials

with lower total S contents will become acidic.

In principal a simple scheme can be established for classifying samples as PAF or NAF based

solely on the total S content of samples. However, for the scheme to be of practical value, it is

necessary to establish a threshold total S content (Sc) below which waste is unlikely to become

acidic in the long term. (In this simple classification scheme material classed as UC in the

conventional schemes is conservatively classed as PAF.)

The lower the value of Sc the larger the volume of material classed as PAF.

Data for Weld Range samples suggests that Sc may lie between 0.1 and 0.36 wt% S.

Based on the lower bound Sc value of 0.1 wt% S and the PSF pit shell design the mass of material

that would be classed as PAF at:

a) Madoonga would be about 21 Mt

b) Beebyn would be about 3.3 Mt.

The mass of waste classed as PAF varies little for Sc values in the range 0.1 to 0.25 wt% S.

Examples are given in the following table.

Sc (wt% S) Mass of Waste Classed as PAF (Mt)

Madoonga Beebyn

0.0 130.7 233.2

0.1 20.6 3.3

0.25 13.1 3.3

It may be possible to obtain data that supports using a larger value of Sc (and thereby reduce the

mass of waste classed PAF) from the samples that were leach tested for 45 weeks. To obtain

suitable data a sample of material would be removed from the columns and statically tested to

determine the quantity of oxidisable sulphur remaining in each column sample.

Recommendations 6.2

SRK recommends that:

1. That a simple scheme based on a threshold value of total sulphur content (Sc) is used for

classifying materials during mining. In the absence of further information on the acid

producing and acid neutralising capacity of materials the scheme would be as shown in

recommendations 2 and 3.

2. The value of Sc is taken as 0.1 wt% S.

3. Materials with:

a) Total S ≥ 0.1 wt% are classed as PAF and those with

b) Total S < 0.1 wt% are classed NAF.

4. An assessment is undertaken to determine whether use of a larger value of Sc can be justified.

A larger value of Sc would result in a smaller volume of waste being classified PAF. An

approach is presented in recommendation 5.



5. Operation of the long-term (45 week) kinetic columns should cease. Samples should be

obtained from those columns giving neutral leachate. These samples should be sent to a

commercial laboratory to measure the quantity of remaining oxidisable sulphide. The data

obtained will help determine whether a larger Sc can be used.

6. The current review of the quantity and distribution of PAF and NAF materials within the BFS

(VI) pit shell being is completed. Details are given in Section 5.1.

7. An assessment is undertaken of the potential quality of water that comes into contact the waste

and mineralised material. Details are given in Section 5.2.



References 7.

AMIRA International Limited, ARD Test Handbook: Project P387A Prediction and Kinetic

Control of Acid Mine Drainage, May 2002.

Bowen, H J M, 1979. Environmental Chemistry of the Elements, (Academic Press: London).

Förstner, U, Ahlf, W and Calmano, W, 1993. Sediment quality objectives and criteria development

in Germany, Water Science & Technology, 28: 307-316.

Li, M, 2000 Acid Rock Drainage Prediction for Low-Sulphide, Low-Neutralisation Potential Mine

Wastes. Proceedings from the Fifth International Conference on Acid Rock Drainage. Society

for Mining, Metallurgy and Exploration Inc.

Morin and Hutt, 2007 A Case Study of Important Aluminosilicate Neutralisation, MDAG.com

Internet Case Study 25.

Pontifex, I R, 2008. Mineralogical Report No. 9341.

Price, W A, 1997. Guidelines and Recommended Methods for the Prediction of Metal Leaching

and Acid Rock Drainage at Minesites in British Columbia, Reclamation Section, Energy and

Minerals Division Ministry of Employment and Investment.

SRK Consulting, 2008. Mineralisation Study at the Beebyn and Madoonga Orebodies, Weld

Range, unpublished report by SRK Consulting for Sinosteel Midwest Corporation Limited

(authors: S Kenworthy and P Hodkiewicz).

SRK Consulting, 2009. Geochemical Characterisation of Weld Range Waste and Mineralised Rock

- Static and Kinetic Testing. Report SMM001_ENV_RP_1 (Rev 1) prepared for Sinosteel

Midwest Management Pty Ltd.

SRK Consulting Geochemical Characterisation of Waste and Mineralised Rock; Static and Kinetic Testing Appendices


Appendices

SRK Consulting Geochemical Characterisation of Waste and Mineralised Rock; Static and Kinetic Testing Appendix 1


Appendix 1: Nomenclature

SRK Consulting Geochemical Characterisation of Waste and Mineralised Rock; Static and Kinetic Testing Appendix 1-1

GARV/CHAP/kami/dick SMM004_ENV_RP_2_Rev1.docx March 2011

Equivalent nomenclatures

BIF BIF

DID Detrital

FEL Felsic

SHL Shale

HYD Hydrated

MAF Mafic

MAG Magnetite

O_AL Ore Hi Al

O_SI Ore Hi SiO2

ORE Ore

Sample ID Column ID

ADML_1B_003 SRK1

ADML_1B_027 SRK5

ADML_1B_064 SRK7

ADML_1B_110 SRK10

ADML_1B_137 SRK15

ADML_1B_243 SRK24

ADML_1B_249 SRK25

ADML_1B_280 SRK330

A13059 SRK 13059



Appendix 2: Static Testing Methods and Guidelines



STATIC TESTING METHODS AND GUIDELINES

Paste pH and Paste EC

Paste parameters provide an indication of the degree of weathering the material has experienced as

well as the availability of reactive mineral species and readily soluble salts. Generally, paste pH

values less than pH 5 are indicative of stored acidity (i.e. stored oxidation products) and net acid

generating conditions, whereas high paste pH values suggest the presence of reactive neutralising

minerals.

These characteristics reflect the potential of a sample to impact the quality of water contacting the

sample without the sample undergoing further chemical change/weathering. Such potential exists

whether the sample is classified as NAF, UC or PAF. A method consistent with the AMIRA

(2002) method was used.

Net Acid Producing Potential

The net acid producing potential (NAPP) is the theoretical balance between the capacity of the

sample to generate acid via the oxidation of sulphides and its capacity to neutralise any acid

formed. The maximum potential acidity (MPA) of the sample is calculated from the total sulphur

content, assuming that all sulphur is present as pyrite.

The acid neutralisation capacity (ANC) or neutralisation potential (NP) is measured by reacting the

sample with a known amount of low pH hydrochloric acid. After the pH has stabilized the sample

is back titrated with a base to determine the amount of acid that had been consumed by the sample,

which is assumed to represent the NP.

The NAPP is calculated as follows:

NAPP = MPA – NP (kg H2SO4/t)

Where MPA = 30.6 x S% and the sulphur content is expressed as weight percent (wt %).

The assumption that all sulphur in the sample is present as sulphide (pyrite) generally overestimates

the amount of acid generated, since sulphur will exist in other forms that are not acid generating

(e.g. as sulphate, elemental sulphur and non acid generating sulphides).

Net Acid Generation

Net acid generation (NAG) measures how a sample could behave under highly oxidising

conditions. The sample is contacted with the strong oxidant hydrogen peroxide. The peroxide

oxidises the sulphides contained in the sample which generates acid. Concurrently, neutralising

minerals that may be present consume all or part of the acid generated. Following a predetermined

contact time, the solution pH is recorded and the NAG acidity of the sample is quantified by

titration with a base (sodium hydroxide).

Acid Neutralising Capacity (ANC) and Carbonate Neutralising Potential (CarbNP)

The acid neutralisation capacity (ANC) or neutralisation potential (NP) is a measure of the role that

gangue minerals could play in neutralising acid generated during sulphide oxidation. The ANC

measurement is described above (see Net Acid Producing Potential). The neutralisation potential

of a sample can be sourced from both carbonate and silicate minerals. Calcium and magnesium

carbonates are the most important contributors for domains that generate acid at a high rate since

they are very reactive and readily neutralise acidity at a high rate. Some carbonate minerals, such

as iron and manganese carbonates, do not contribute to neutralisation. Other neutralising minerals

such as silicates react at low pH values and will only contribute to the neutralising capacity after

the leaching solution has become strongly acidic.



The endpoint pH after the addition of HCl in the NP measurement is very low (typically between

pH values of 1 and 2) and leads to additional reactions that will occur only at a low pH

(i.e. neutralisation due to dissolution of the silicate minerals). The NP measurement may therefore

overestimate the neutralisation capacity that is available.

A more appropriate assessment of the NP that is available to maintain near neutral pH conditions is

to infer the proportion of NP that is sourced from the calcium and magnesium carbonate minerals

directly. The inorganic carbon content can be used to infer the carbonate mineral content and

estimate the carbonate neutralisation potential (CarbNP). Comparison of the CarbNP values with

the NP values can give an indication of the proportion of the neutralising capacity of the sample

that is due to the presence of carbonate minerals.

Acid Buffering Characteristic Curve

The ABCC test involves slow titration of a sample with acid while continuously monitoring pH.

This data provides an indication of what portion of the acid neutralising capacity (ANC) measured

in a sample is readily available for acid neutralisation (AMIRA, 2002).

Global Abundances

Bulk chemical assays were undertaken on all samples. The following elements were included in

the assays:

Major elements – Al, Ca, Fe, K, Mg, Mn, Na, P, S and Si; and

Minor elements – Ag, As, Au, B, Ba, Be, Bi, C, Cd, Co, Cr, Cu, F, Hg, Mo, Ni, Pb, Sb, Se, Sn,

Sr, Te, Th, Tl, U, V and Zn.

A direct comparison of the measured abundances of the elements was made with the average

abundance of elements in the Earth’s crust (Bowen, 1979). This provides the global abundance

index (GAI) of elements and indicates which elements are ‘enriched’ in the sample with respect to

the global average. The GAI is calculated using the following formula (Förstner, 1993):

GAI =

Abundance Average5.1

ionConcentrat Measuredlog 2Int

An example of GAI values is provided in the following table. In the table n is the ratio of the

measured abundance in the sample to the reference material abundance.

Ranges of the Ratio of the Measured Concentration to Average Abundance (n) and the Corresponding Global Abundance Index

n range GAI

1 < n < 3 0

3 ≤ n < 6 1

6 ≤ n < 12 2

12 ≤ n < 24 3

Zero or positive GAI values indicate enrichment of the element in the sample when compared to

average-crustal abundances. As a general rule, a GAI of 3 or higher signifies enrichment that

warrants further evaluation.



Leach Extraction Tests

A total of 250 g of sample and 750 mL of distilled water are placed in a 1000 mL container. The

mixture is gently agitated for 24 hours and allowed to stand for a minimum of three hours allowing

suspended material to settle. The supernatant is collected and submitted for multi-element analysis.

Kinetic Testing Procedure

A modified AMIRA procedure (AMIRA, 2002) was utilised with the principle differences relating

to the particle size at which the tests were completed and the flushing regime. The testing

procedure was as follows.

Each sample was coarse crushed (<10 mm) and placed in a large diameter Buchner filter lined with

filter paper to retain the solids. The rock sample was then subjected to a weekly rinsing and drying

cycle. Each week the sample was rinsed with about 1000 ml of deionised water. The water was

added to the top of the sample and allowed to drain under gravity and the leachate collected at the

base of Buchner filter and submitted for analysis as follows:

Weekly – pH, electrical conductivity (EC), sulphate, acidity and total alkalinity.

Every 3 to 4 weeks – Ag, Al, As, Ba, Be, Ca, Cd, Cl, Co, Cr, Cu, Fe, Hg, K, Mg, Mn, Mo, Na,

Ni, P, Pb, Sb, Se, Sn, Sr, Th, Tl, U, V and Zn.

Generally column leach tests that exhibit slow rates of reaction require a minimum operating time

of 40 to 50 weeks unless acidity conditions develop fully at an early stage of the test. The criteria

that may be considered to assess whether testing should be discontinued include:

pseudo steady state;

oxidation rates (i.e. acid generation rates) and neutralisation potential depletion rates together

with static test results indicate that net acid generating conditions are unlikely to develop, and

metal leachability is unlikely to change in the future; and

A good understanding of rates of oxidation and leaching has been developed based on the

available data.



Appendix 3: Paste pH and Electrical Conductivity

SRK ConsultingSMM001_Geochemical Characterisation of Weld Range Waste and Mineralised Rock

Paste pH and Paste EC Test Results

SMC Sample Zone Sample Type Domain Weathering HOLE_ID From To Paste pH Paste ECM-Madoonga m m pH Unit µS/cmB-Beebyn 0.1 1.00

A13020 M DD BIF WRRD0524 52 54 7.7 50A13024 M DD BIF WRRD0524 124 126 8 77A13025 M DD BIF WRRD0524 161 163 8.5 82A13028 M DD BIF WRRD0524 203 205 8.5 110A13029 M DD BIF WRRD0524 210 212 8.4 180A13033 M DD BIF WRRD0491 97 99 7.1 36A13034 M DD BIF WRRD0491 125 127 6.7 300A13036 M DD BIF WRRD0491 184 186 8.2 130A13037 M DD BIF WRRD0491 226 228 8 240A13049 M DD BIF WRRD0525 82 84 6.9 110A13050 M DD BIF WRRD0525 152 154 6.8 93A13051 M DD BIF WRRD0525 163 165 7.3 37A13052 M DD BIF WRRD0529 11 13 5.6 65A13054 M DD BIF WRRD0529 50 52 5.9 44A13055 M DD BIF WRRD0529 55 57 5.9 22A13056 M DD BIF WRRD0529 72 74 7.7 79A13057 M DD BIF WRRD0529 96 98 6.4 330A13059 M DD BIF WRRD0529 127 129 7.2 370ADML_1B_012 M DD BIF EW WRRD0262 79.7 83.5 7 201ADML_1B_014 M DD BIF MW WRRD0491 99.7 101.8 7.4 73ADML_1B_015 M DD BIF FR WRRD0524 124.3 126 7.7 103ADML_1B_016 M DD BIF FR WRRD0526 45 46.9 7.5 58ADML_1B_017 M DD BIF FR WRRD0527 90.4 92.35 7.5 55ADML_1B_018 M DD BIF MW WRRD0528 216.6 218.6 7.4 230ADML_1B_019 M DD BIF FR WRRD0529 60.2 63.6 6.8 63ADML_1B_021 M DD BIF MW WRRD0530 15 16.8 6.5 48ADML_1B_022 M DD BIF FR WRRD0530 48.7 50.45 6.1 144ADML_1B_023 M DD BIF EW WRRD0581A 9 12.4 6.1 168ADML_1B_047 M DD BIF FR WRRD0527 45.6 47.9 6.3 13ADML_1B_074 M DD BIF EW WRRD0597 55 57.4 7.5 114ADML_1B_077 M DD BIF MW WRRD0720 37.3 39.4 6.4 66ADML_1B_187 M DD BIF EW WRRD0261 44 46 7.6 93ADML_1B_193 M DD BIF EW WRRD0265 80 80.5 7.5 241ADML_1B_204 M DD BIF MW WRRD0531 23 24 7 62ADML_1B_205 M DD BIF FR WRRD0580 32.5 33.5 6.2 60ADML_1B_211 M DD BIF FR WRRD0580 157.3 158.8 6.8 268ADML_1B_213 M Surface sample BIF MW Field Sample 0 1 6.6 165ADML_1B_214 M Surface sample BIF MW Field Sample 0 1 6.7 127ADML_1B_225 M DD BIF MW WRRD0525 110.4 114.6 7.1 46ADML_1B_227 M DD BIF MW WRRD0581a 27.4 28.4 6.6 28ADML_1B_229 M DD BIF MW WRRD0594 169 170 6.9 21A13019 M DD Detrital WRRD0524 9 11 6.3 210A13030 M DD Detrital WRRD0491 8 10 6.9 50A13047 M DD Detrital WRRD0525 10 12 6 220ADML_1B_010 M DD Detrital MW WRRD0262 2.1 4.1 6 244ADML_1B_024 M DD Detrital MW WRRD0592 11 14 7.2 70ADML_1B_027 M DD Detrital MW WRRD0245 2.7 4.6 5.9 147ADML_1B_035 M DD Detrital MW WRRD0263 1.3 4 6.5 170ADML_1B_036 M DD Detrital MW WRRD0265 1.3 3.1 6.7 113ADML_1B_037 M DD Detrital MW WRRD0491 0 2 6.4 84ADML_1B_038 M DD Detrital EW WRRD0491 2 5.1 6.6 109ADML_1B_040 M DD Detrital EW WRRD0525 8.3 10.9 5.2 156ADML_1B_041 M DD Detrital MW WRRD0525 5.6 8.2 5.2 36ADML_1B_045 M DD Detrital MW WRRD0526 0 2.2 5.8 34ADML_1B_046 M DD Detrital EW WRRD0527 0 3.1 5.6 34ADML_1B_049 M DD Detrital EW WRRD0528 0 2.3 6.2 37ADML_1B_050 M DD Detrital MW WRRD0528 11.5 13.5 7.5 39ADML_1B_051 M DD Detrital EW WRRD0528 17.2 18.9 6.7 22ADML_1B_060 M DD Detrital EW WRRD0530 0 2.1 6.4 65ADML_1B_061 M DD Detrital EW WRRD0590 10.5 22.8 6.7 164ADML_1B_062 M DD Detrital EW WRRD0591 5.3 19.6 7.2 107ADML_1B_063 M DD Detrital EW WRRD0594 0 8 7 81ADML_1B_067 M DD Detrital EW WRRD0595 3 4.4 6.9 101ADML_1B_068 M DD Detrital MW WRRD0595 11 12.8 7 51ADML_1B_206 M DD Detrital EW WRRD0580 3 4.8 5.6 40ADML_1B_212 M Surface sample Detrital EW Field Sample 0 1 5.8 35ADML_1B_215 M Surface sample Detrital EW Field Sample 0 1 5.8 46




ADML_1B_216 M Surface sample Detrital EW Field Sample 0 4 5.5 69ADML_1B_217 M Surface sample Detrital EW Field Sample 0 2 5.7 34ADML_1B_218 M Surface sample Detrital EW Field Sample 0 1 5 56ADML_1B_219 M Surface sample Detrital EW Field Sample 0 1 5.4 81ADML_1B_032 M DD Felsic FR WRRD0594 60 61 8.8 103ADML_1B_033 M DD Felsic EW WRRD0594 65 66.2 8.3 86ADML_1B_034 M DD Felsic MW WRRD0594 66.6 67.5 8.5 84ADML_1B_257 M Surface sample Felsic EW 0 0 0 6.3 90ADML_1B_258 M Surface sample Felsic MW 0 0 0 7.1 203ADML_1B_259 M Surface sample Felsic EW 0 0 0 5.6 83ADML_1B_260 M Surface sample Felsic MW 0 0 0 7.5 176ADML_1B_261 M Surface sample Felsic MW 0 0 0 7 184ADML_1B_262 M Surface sample Felsic EW 0 0 0 6.7 186ADML_1B_265 M Surface sample Felsic MW 0 0 0 7.2 397ADML_1B_270 M Surface sample Felsic MW 0 0 0 7.6 100A13021 M DD Hydrated WRRD0524 74 76 7.4 83A13023 M DD Hydrated WRRD0524 91 93 7.2 72A13035 M DD Hydrated WRRD0491 163 165 6.6 4200A13053 M DD Hydrated WRRD0529 35 37 5.2 120ADML_1B_043 M DD Hydrated MW WRRD0526 15.4 19 6.8 33ADML_1B_044 M DD Hydrated FR WRRD0526 19 21.1 6.9 29ADML_1B_048 M DD Hydrated MW WRRD0527 104.1 105.6 6.8 79ADML_1B_075 M DD Hydrated MW WRRD0720 41.6 44.3 6.7 79ADML_1B_076 M DD Hydrated EW WRRD0720 20.1 22.4 6.7 97ADML_1B_078 M DD Hydrated FR WRRD0720 51.95 53.7 6.9 129ADML_1B_226 M DD Hydrated EW WRRD0526 6.5 8.3 7 61ADML_1B_228 M DD Hydrated MW WRRD0525 99.8 102.5 7 36ADML_1B_241 M RC Hydrated EW WRRC0850 1 2 7.4 224ADML_1B_242 M RC Hydrated EW WRRC0850 9 10 7.1 146ADML_1B_243 M RC Hydrated MW WRRC0875 132 133 6.7 861ADML_1B_244 M RC Hydrated MW WRRC0875 117 118 6.7 370ADML_1B_245 M RC Hydrated MW WRRC0876 130 131 7 324ADML_1B_246 M RC Hydrated MW WRRC0876 113 114 7 165ADML_1B_247 M DD Hydrated FR WRRC0962d 211.4 213 6.9 80ADML_1B_248 M DD Hydrated MW WRRC0883d 124.6 126 6.8 96ADML_1B_249 M DD Hydrated MW WRRC0880d 129.4 130.2 4.6 1000ADML_1B_250 M DD Hydrated FR WRRC0880d 130 132.3 7.5 242ADML_1B_251 M DD Hydrated MW WRRC0979d 134.8 136.4 7.3 90ADML_1B_252 M DD Hydrated EW WRRC0868d 111.4 114.9 7.2 221ADML_1B_254 M DD Hydrated FR WRRC0852ad 148.4 150 7.4 84ADML_1B_255 M DD Hydrated FR WRRC0852ad 158.5 160 7.6 134ADML_1B_256 M RC Hydrated FR WRRC0881 98 100 6.9 142ADML_1B_271 M RC Hydrated EW WRRC1006 79 81 6.4 310ADML_1B_272 M RC Hydrated EW WRRC1006 64 66 6.6 425ADML_1B_273 M RC Hydrated EW WRRC0888 69 70 6.5 74A13022 M DD Mafic WRRD0524 81 83 7.3 140A13031 M DD Mafic WRRD0491 44 46 7.3 250A13032 M DD Mafic WRRD0491 61 63 7.4 150A13048 M DD Mafic WRRD0525 40 42 6.1 73ADML_1B_009 M DD Mafic EW WRRD0491 19.35 20.4 7 178ADML_1B_011 M DD Mafic EW WRRD0262 23.4 27.3 6.1 461ADML_1B_025 M DD Mafic EW WRRD0592 19 23 7 170ADML_1B_026 M DD Mafic MW WRRD0592 77.5 79.1 6.9 1700ADML_1B_039 M DD Mafic EW WRRD0524 24.6 30.3 6.9 129ADML_1B_056 M DD Mafic FR WRRD0528 238.6 240.1 8.5 372ADML_1B_069 M DD Mafic EW WRRD0595 29.1 31.2 7.8 69ADML_1B_070 M DD Mafic FR WRRD0595 51.8 53.9 9.2 162ADML_1B_071 M DD Mafic FR WRRD0595 121.2 123.3 9.2 126ADML_1B_191 M DD Mafic MW WRRD0264 124.7 125.8 6.1 125ADML_1B_200 M DD Mafic EW WRRD0525 33.4 36 6 50ADML_1B_208 M DD Mafic EW WRRC0580 40.2 42.8 6.8 146ADML_1B_237 M DD Mafic FR WRRD0528 249.1 250.8 8 1200ADML_1B_238 M DD Mafic MW WRRD0595 81.7 83 8.4 55ADML_1B_008 M DD Ore FR WRRD0271 90.1 92.5 7.7 537ADML_1B_029 M DD Ore FR WRRD0245 34 36 6.3 620ADML_1B_031 M DD Ore FR WRRD0261 35.5 38.3 7 269ADML_1B_042 M DD Ore EW WRRD0525 69.6 72.8 6.9 52




ADML_1B_054 M DD Ore EW WRRD0528 101.5 106.2 6.9 66ADML_1B_055 M DD Ore EW WRRD0528 144.6 147.1 7 70ADML_1B_057 M DD Ore EW WRRD0529 28.6 29.8 5 103ADML_1B_064 M DD Ore MW WRRD0594 174 176.1 6.8 187ADML_1B_066 M DD Ore EW WRRD0594 213 216.5 7 638ADML_1B_072 M DD Ore MW WRRD0597 2.5 5 7.4 170ADML_1B_188 M DD Ore FR WRRD0262 51.3 52.3 7.4 283ADML_1B_189 M DD Ore MW WRRD0264 27.2 30.5 6.8 123ADML_1B_192 M DD Ore FR WRRD0265 50 51 6.8 222ADML_1B_209 M DD Ore MW WRRD0580 59.7 61.7 7.1 155ADML_1B_210 M DD Ore MW WRRD0580 108 109.3 7.1 110ADML_1B_030 M DD Ore Hi Al FR WRRD0245 71 73.5 6.5 264ADML_1B_053 M DD Ore Hi Al MW WRRD0528 61 64 7.2 20ADML_1B_058 M DD Ore Hi Al MW WRRD0529 49 53 6.4 46ADML_1B_190 M DD Ore Hi Al FR WRRD0264 40.5 42 5 126ADML_1B_194 M DD Ore Hi Al FR WRRD0491 121 122.2 7.3 162ADML_1B_195 M DD Ore Hi Al MW WRRD0491 12 13.5 7.2 34ADML_1B_198 M DD Ore Hi Al MW WRRD0524 121 122.2 7.2 71ADML_1B_202 M DD Ore Hi Al MW WRRC0527 14.6 17 6.4 33ADML_1B_231 M DD Ore Hi Al EW WRRD0524 84.6 87.3 7.4 55ADML_1B_234 M DD Ore Hi Al FR WRRD0271 40 42 7.1 246ADML_1B_235 M DD Ore Hi Al EW WRRD0261 3.1 5 5.7 66ADML_1B_236 M DD Ore Hi Al FR WRRD0246 59.3 61.3 7 82ADML_1B_013 M DD Ore Hi SiO2 EW WRRD0262 93 95 6.9 382ADML_1B_020 M DD Ore Hi SiO2 FR WRRD0529 107 109 6.9 42ADML_1B_028 M DD Ore Hi SiO2 MW WRRD0245 5.6 7.9 5.6 55ADML_1B_052 M DD Ore Hi SiO2 MW WRRD0528 47 49 7 27ADML_1B_059 M DD Ore Hi SiO2 FR WRRD0529 65 67 5.7 24ADML_1B_065 M DD Ore Hi SiO2 EW WRRD0594 193 195 6.9 166ADML_1B_073 M DD Ore Hi SiO2 MW WRRD0597 7 11.5 7 193ADML_1B_196 M DD Ore Hi SiO2 EW WRRD0491 109.3 111.6 7.2 74ADML_1B_199 M DD Ore Hi SiO2 EW WRRDo524 99-100 107.5 7.2 31ADML_1B_201 M DD Ore Hi SiO2 FR WRRD0527 10 11 6.4 54ADML_1B_203 M DD Ore Hi SiO2 EW WRRD0528 70.8-73.1 94.2 7.2 60ADML_1B_207 M DD Ore Hi SiO2 MW WRRD0580 17.3 18.5 5.8 36ADML_1B_230 M DD Ore Hi SiO2 FR WRRD0244 85.3 87 7.2 318ADML_1B_232 M DD Ore Hi SiO2 MW WRRD0524 46 47 7.3 46ADML_1B_233 M DD Ore Hi SiO2 FR WRRD0529 4 6 5.5 38A13026 M DD Shale WRRD0524 180 182 8.6 150A13027 M DD Shale WRRD0524 194 196 8.7 710A13038 M DD Shale WRRD0491 249 251 9 210A13039 M DD Shale WRRD0491 262 264 8.8 250A13058 M DD Shale WRRD0529 119 121 7.3 68ADML_1B_274 M DD Shale MW WRRC0719d 100 102 6.6 520ADML_1B_275 M DD Shale MW WRRC0719d 105.3 107.5 8.2 287ADML_1B_276 M DD Shale MW WRRC0719d 111.3 113.3 6.9 633ADML_1B_277 M DD Shale MW WRRC0719d 115.4 116.6 6.9 452ADML_1B_280 M DD Shale MW WRRC0963d 196.8 199 4.3 1490ADML_1B_281 M DD Shale MW WRRC0963d 194.2 196 8 166ADML_1B_282 M DD Shale EW WRRC0963d 190 192.2 6.6 291ADML_1B_283 M DD Shale EW WRRC0963d 178.4 180 7.7 145ADML_1B_284 M DD Shale EW WRRC0963d 171.7 173.9 7.2 210ADML_1B_285 M DD Shale EW WRRC0966d 138 140 7.2 162ADML_1B_286 M DD Shale EW WRRC0966d 143.2 144.9 6.8 357ADML_1B_287 M DD Shale EW WRRC0966d 146.7 142.8 7 240ADML_1B_288 M DD Shale EW WRRC0964d 145.9 147.4 7.1 122ADML_1B_289 M DD Shale EW WRRC0964d 150 151 7.2 118A13003 B DD BIF WRRD0493 41 43 6.5 30A13004 B DD BIF WRRD0493 64 66 6.7 21A13005 B DD BIF WRRD0493 92 94 7.1 48A13006 B DD BIF WRRD0493 110 112 7.2 30A13011 B DD BIF WRRD0488 56 58 8 100A13013 B DD BIF WRRD0488 121 123 9.1 260A13014 B DD BIF WRRD0488 141 143 9.2 220A13015 B DD BIF WRRD0488 163 165 9.2 320A13016 B DD BIF WRRD0488 171 173 8.8 250A13042 B DD BIF WRRD0520 65 67 9 160




A13043 B DD BIF WRRD0520 85 87 9.2 190A13044 B DD BIF WRRD0520 99 101 8.2 120ADML_1B_083 B DD BIF EW WRRD0610 183 186.3 7.2 56ADML_1B_084 B DD BIF MW WRRD0610 175.8 178.1 7.3 50ADML_1B_098 B DD BIF MW WRRD0493 30.3 32.2 8 97ADML_1B_100 B DD BIF MW WRRD0493 67.7 73.8 7.1 62ADML_1B_107 B DD BIF EW WRRD0494 40.5 44.3 7.4 83ADML_1B_130 B DD BIF EW WRRD0521 29.9 32.8 8.3 194ADML_1B_138 B DD BIF MW WRRD0587 27.7 28.5 5.8 104ADML_1B_138 B DD BIF MW WRRD0587 21.9 23.8 4.6 128ADML_1B_149 B DD BIF FR WRRD0640 49 50.3 9 104ADML_1B_156 B DD BIF EW WRRD0731 39.6 41.2 8.5 404ADML_1B_174 B DD BIF MW WRRD0489 119.3 120.8 9 381ADML_1B_185 B DD BIF MW WRRD0499 39 41 6.2 145ADML_1B_186 B DD BIF FR WRRD0499 51 52 7.4 77ADML_1B_197 B DD BIF FR WRRD0493 36 38 7.2 51ADML_1B_221 B DD BIF MW WRRD0640 34.7 36.3 6.1 23A13001 B DD Mafic WRRD0493 14 16 6.3 130A13002 B DD Mafic WRRD0493 25 27 6.6 70A13007 B DD Mafic WRRD0493 127 129 7.9 60A13008 B DD Mafic WRRD0493 137 139 8.3 70A13009 B DD Mafic WRRD0488 6 8 6.8 170A13010 B DD Mafic WRRD0488 39 41 8.5 80A13012 B DD Mafic WRRD0488 81 83 8.6 90A13017 B DD Mafic WRRD0488 174 176 8.4 150A13018 B DD Mafic WRRD0488 194 196 9.5 260A13040 B DD Mafic WRRD0520 14 16 7.7 280A13041 B DD Mafic WRRD0520 36 38 8.7 180A13045 B DD Mafic WRRD0520 108 110 8.5 150A13046 B DD Mafic WRRD0520 119 121 8.3 170ADML_1B_001 B DD Mafic EW WRRD0489 39.4 41 7 110ADML_1B_005 B DD Mafic EW WRRD0523 92.3 93.9 7.6 162ADML_1B_006 B DD Mafic MW WRRD0523 86.1 87.3 8.4 92ADML_1B_007 B DD Mafic EW WRRD0488 42.7 47.5 8.1 108ADML_1B_079 B DD Mafic EW WRRD0577 70 75 7.6 125ADML_1B_080 B DD Mafic MW WRRD0577 89.6 92.1 8.4 84ADML_1B_081 B DD Mafic MW WRRD0603 171 173.9 7.4 105ADML_1B_082 B DD Mafic EW WRRD0610 116 121.1 7.3 132ADML_1B_085 B DD Mafic FR WRRD0630 177 179.05 9.3 101ADML_1B_086 B DD Mafic MW WRRD0667 89.3 91.7 8.6 130ADML_1B_087 B DD Mafic EW WRRD0670 119.1 122.05 7.5 129ADML_1B_088 B DD Mafic FR WRRD0675 160.2 162.6 8.7 103ADML_1B_089 B DD Mafic MW WRRD0488 63 65.1 8.7 82ADML_1B_090 B DD Mafic FR WRRD0488 72.7 75.1 8.7 90ADML_1B_091 B DD Mafic FR WRRD0488 189.9 192.7 9.7 231ADML_1B_092 B DD Mafic EW WRRD0490 11.5 13.4 7.2 81ADML_1B_093 B DD Mafic MW WRRD0490 27.9 29 8.3 111ADML_1B_094 B DD Mafic FR WRRD0490 15.7 118 9.1 96ADML_1B_095 B DD Mafic EW WRRD0492 38 38.5 8 131ADML_1B_096 B DD Mafic MW WRRD0492 41.5 43.5 8.9 89ADML_1B_097 B DD Mafic EW WRRD0493 25 28.1 7 79ADML_1B_103 B DD Mafic MW WRRD0493 126.4 129.4 8.1 78ADML_1B_104 B DD Mafic FR WRRD0493 133 135 8.8 86ADML_1B_105 B DD Mafic EW WRRD0494 22.8 25.6 8.4 375ADML_1B_106 B DD Mafic MW WRRD0494 54.6 57.1 7.6 76ADML_1B_108 B DD Mafic EW WRRD0496 15.4 18.4 7.7 119ADML_1B_112 B DD Mafic EW WRRD0496 135 138.4 7.4 125ADML_1B_113 B DD Mafic MW WRRD0496 156.4 157.8 8.7 91ADML_1B_114 B DD Mafic FR WRRD0496 165.9 168.15 9.2 148ADML_1B_116 B DD Mafic EW WRRD0497 9.1 12.2 8.8 100ADML_1B_117 B DD Mafic MW WRRD0497 15.3 18 8.7 107ADML_1B_119 B DD Mafic EW WRRD0500 9.1 13.1 7.4 1280ADML_1B_120 B DD Mafic MW WRRD0500 15.4 17.95 9 170ADML_1B_121 B DD Mafic EW WRRD0500 38.9 41.6 8.1 96ADML_1B_122 B DD Mafic FR WRRD0500 80.4 83 9.3 153ADML_1B_123 B DD Mafic EW WRRD0520 9.8 12.8 7.9 463ADML_1B_124 B DD Mafic MW WRRD0520 21.8 24.1 8.6 119




ADML_1B_126 B DD Mafic FR WRRD0520 32.9 34.8 8.9 93ADML_1B_128 B DD Mafic MW WRRD0520 110.8 112.2 8.8 70ADML_1B_129 B DD Mafic EW WRRD0521 19 21.4 7.2 126ADML_1B_131 B DD Mafic EW WRRD0521 66.4 68.4 8.6 98ADML_1B_132 B DD Mafic MW WRRD0522 60.6 62.2 9.3 148ADML_1B_133 B DD Mafic FR WRRD0522 63.9 65.2 9 78ADML_1B_134 B DD Mafic EW WRRD0522 10.6 12.1 8.7 405ADML_1B_135 B DD Mafic EW WRRD0523 50.2 51.7 8.7 105ADML_1B_136 B DD Mafic MW WRRD0523 81.9 83.6 7.8 142ADML_1B_137 B DD Mafic EW WRRD0587 9 11.7 8.4 128ADML_1B_139 B DD Mafic EW WRRD0582 10 13 8.4 636ADML_1B_140 B DD Mafic EW WRRD0588 3.4 6.1 6.8 52ADML_1B_141 B DD Mafic EW WRRD0583 3.5 6 9 193ADML_1B_142 B DD Mafic MW WRRD0583 14 16.5 9.2 107ADML_1B_143 B DD Mafic FR WRRD0583 24 25 5.3 126ADML_1B_144 B DD Mafic EW WRRD0640 1 8 6.3 89ADML_1B_146 B DD Mafic MW WRRD0490 19 20 6.9 147ADML_1B_150 B DD Mafic FR WRRD0731 93.6 95 9 111ADML_1B_151 B DD Mafic MW WRRD0731 57.1 58.35 9.3 71ADML_1B_152 B DD Mafic FR WRRD0732 94.6 95.6 9.4 114ADML_1B_153 B DD Mafic MW WRRD0731 16 17 7.8 2800ADML_1B_154 B DD Mafic MW WRRD0731 24.5 25.5 7.8 72ADML_1B_155 B DD Mafic EW WRRD0731 32 33.5 7.9 1140ADML_1B_157 B DD Mafic EW WRRD0732 15.5 17.5 9.4 127ADML_1B_158 B DD Mafic MW WRRD0731 26 30 7.9 264ADML_1B_159 B DD Mafic MW WRRD0731 52 53 7.1 104ADML_1B_160 B DD Mafic EW WRRD0732 71.8 73.2 8.1 131ADML_1B_161 B DD Mafic EW WRRD0642 3.2 6 8.9 83ADML_1B_162 B DD Mafic EW WRRD0642 32.4 34 7.4 74ADML_1B_163 B DD Mafic MW WRRD0642 39.5 40.5 8 50ADML_1B_164 B DD Mafic EW WRRC0641 36 37.5 9.2 124ADML_1B_167 B DD Mafic MW WRRD0522 38.3 39.6 8.5 62ADML_1B_168 B DD Mafic MW WRRD0500 58 59.3 9.1 54ADML_1B_169 B DD Mafic MW WRRD0731 49.8 50.9 7.3 35ADML_1B_175 B DD Mafic MW WRRD0489 143 145 8.6 64ADML_1B_179 B DD Magnetite FR WRRD0488 169 170.5 9.1 268ADML_1B_180 B DD Magnetite MW WRRD0488 150.8 152 9.3 161ADML_1B_181 B DD Magnetite FR WRRD0488 161 162 9 195ADML_1B_222 B DD Magnetite FR WRRD0489 99.1 100.8 8.6 303ADML_1B_002 B DD Ore MW WRRD0489 78 79.4 7.2 59ADML_1B_102 B DD Ore MW WRRD0493 118.3 121.3 7.3 47ADML_1B_109 B DD Ore MW WRRD0496 37.4 42.3 7.6 96ADML_1B_111 B DD Ore EW WRRD0496 74.6 78.9 7.6 130ADML_1B_115 B DD Ore EW WRRD0497 1.2 5 7.4 84ADML_1B_118 B DD Ore FR WRRD0497 57.2 59.7 7.6 89ADML_1B_125 B DD Ore FR WRRD0520 68.1 70.5 9.2 247ADML_1B_147 B DD Ore MW WRRD0640 20.3 23 9.2 94ADML_1B_171 B DD Ore EW WRRD0496 67.9 70.1 7.6 41ADML_1B_173 B DD Ore FR WRRD0497 96 97.3 7.3 31ADML_1B_177 B DD Ore MW WRRD0290 146.7 147.7 8.1 86ADML_1B_178 B DD Ore FR WRRD0488 135 136.2 9.1 142ADML_1B_224 B DD Ore EW WRRD0520 49.5 51.9 7.9 73ADML_1B_110 B DD Ore Hi Al EW WRRD0496 45.3 48.3 8 260ADML_1B_127 B DD Ore Hi Al MW WRRD0520 97 99 8.1 151ADML_1B_145 B DD Ore Hi Al MW WRRD0640 12.4 14 6.3 140ADML_1B_145 B DD Ore Hi Al MW WRRD0640 8.6 10.7 6.2 88ADML_1B_172 B DD Ore Hi Al EW WRRD0496 109.5 110.8 7.5 81ADML_1B_182 B DD Ore Hi Al MW WRRD0497 46.1 48 7.7 107ADML_1B_183 B DD Ore Hi Al MW WRRD0520 5.9 7.7 8 88ADML_1B_184 B DD Ore Hi Al EW WRRD0520 5.9 7.7 8 140ADML_1B_278 B RC Ore Hi Al MW WRRC1097 6 7 5.4 99ADML_1B_279 B RC Ore Hi Al MW WRRC1097 17 18 6.7 186ADML_1B_003 B DD Ore Hi SiO2 FR WRRD0489 105 106.5 8.4 493ADML_1B_004 B DD Ore Hi SiO2 MW WRRD0489 131.9 134.5 8.1 227ADML_1B_099 B DD Ore Hi SiO2 EW WRRD0493 52.5 56.5 6.8 35ADML_1B_101 B DD Ore Hi SiO2 EW WRRD0493 82.3 84.3 7.4 70ADML_1B_148 B DD Ore Hi SiO2 EW WRRD0640 43.1 44.6 9.4 128




ADML_1B_170 B DD Ore Hi SiO2 MW WRRD0493 106 109 7.6 26ADML_1B_176 B DD Ore Hi SiO2 MW WRRD0489 94 95.5 8.3 342ADML_1B_220 B DD Ore Hi SiO2 FR WRRD0640 40 41.2 5.7 34ADML_1B_223 B DD Ore Hi SiO2 EW WRRD0489 123.4 126.4 8.1 62



Appendix 4: Acid Base Account Test Results


Acid Base Account Test Results

SMC Sample ID Zone Domain ID Total S SO4 Total C TIC CarbNP ANC MPA NPR

Unit % mg/kg % % kg(H2SO4)/t kg(H2SO4)/t kg(H2SO4)/t

LOR 0.01 100 0.02 0.02A13020 M BIF 0.007 0.08 0.055 4.49 <0.49 0.21 1.17A13024 M BIF 0.084 1.39 1.365 111.42 13.72 2.57 5.34A13025 M BIF 0.062 0.899 0.874 71.34 15.68 1.90 8.26A13028 M BIF 0.116 2.62 2.595 211.83 12.74 3.55 3.59A13029 M BIF 0.267 4.28 4.255 347.34 13.72 8.17 1.68A13033 M BIF 0.0025 0.04 0.015 1.22 <0.49 0.08 3.27A13034 M BIF 0.112 880 0.05 0.025 2.04 <0.49 3.43 0.07A13036 M BIF 0.02 3.81 3.785 308.97 14.7 0.61 24.02A13037 M BIF 0.619 0.287 0.262 21.39 8.82 18.94 0.47A13049 M BIF 0.055 340 0.064 0.039 3.18 <0.49 1.68 0.15A13050 M BIF 0.051 205 0.122 0.052 4.24 <0.49 1.56 0.16A13051 M BIF 0.0025 0.006 -0.019 0.00 <0.49 0.08 3.27A13052 M BIF 0.096 580 0.108 0.028 2.29 <0.49 2.94 0.09A13054 M BIF 0.008 0.043 0.018 1.47 <0.49 0.24 1.02A13055 M BIF 0.0025 0.016 -0.009 0.00 <0.49 0.08 3.27A13056 M BIF 0.089 0.016 -0.009 0.00 <0.49 2.72 0.09A13057 M BIF 0.228 0.006 -0.019 0.00 <0.49 6.98 0.04A13059 M BIF 0.778 0.07 0.045 3.67 <0.49 23.81 0.01ADML_1B_012 M BIF 0.02 0.04 <0.02 0.82 0.8 0.61 1.31ADML_1B_014 M BIF <0.01 0.03 <0.02 0.82 <0.5 0.15 1.63ADML_1B_015 M BIF 0.16 1.7 1.66 135.51 7.3 4.90 1.49ADML_1B_016 M BIF 0.05 0.04 0.04 3.27 1.4 1.53 0.92ADML_1B_017 M BIF 0.1 0.64 0.62 50.61 6.8 3.06 2.22ADML_1B_018 M BIF <0.01 0.04 <0.02 0.82 1.5 0.15 9.80ADML_1B_019 M BIF <0.01 0.02 0.02 1.63 <0.5 0.15 1.63ADML_1B_021 M BIF 0.03 <0.02 <0.02 0.82 1.6 0.92 1.74ADML_1B_022 M BIF 0.01 <0.02 <0.02 0.82 <0.5 0.31 0.82ADML_1B_023 M BIF 0.02 0.02 0.02 1.63 2.4 0.61 3.92ADML_1B_047 M BIF <0.01 0.04 <0.02 0.82 <0.5 0.15 1.63ADML_1B_074 M BIF <0.01 0.04 <0.02 0.82 1.7 0.15 11.11ADML_1B_077 M BIF 0.01 0.02 0.02 1.63 0.5 0.31 1.63ADML_1B_187 M BIF <0.01 0.12 <0.02 0.82 3.4 0.15 22.22ADML_1B_193 M BIF <0.01 0.07 <0.02 0.82 1.8 0.15 11.76ADML_1B_204 M BIF <0.01 0.05 <0.02 0.82 1 0.15 6.54ADML_1B_205 M BIF <0.01 <0.02 <0.02 0.82 1.4 0.15 9.15ADML_1B_211 M BIF 0.02 0.12 0.09 7.35 3.8 0.61 6.21ADML_1B_213 M BIF 0.01 <0.02 <0.02 0.82 1.2 0.31 3.92ADML_1B_214 M BIF <0.01 0.03 <0.02 0.82 1.7 0.15 11.11ADML_1B_225 M BIF <0.01 0.04 <0.02 0.82 2 0.15 13.07ADML_1B_227 M BIF <0.01 <0.02 <0.02 0.82 0.6 0.15 3.92ADML_1B_229 M BIF <0.01 0.05 <0.02 0.82 <0.5 0.15 1.63A13019 M Detrital 0.065 550 0.261 0.151 12.33 <0.49 1.99 0.13A13030 M Detrital 0.011 <100 0.156 0.066 5.39 <0.49 0.34 0.74A13047 M Detrital 0.057 0.266 0.086 7.02 2.94 1.74 1.69ADML_1B_010 M Detrital 0.05 0.11 <0.02 0.82 0.5 1.53 0.33ADML_1B_024 M Detrital <0.01 0.06 <0.02 0.82 2.4 0.15 15.69ADML_1B_027 M Detrital 0.1 0.1 <0.02 0.82 0.8 3.06 0.26ADML_1B_035 M Detrital 0.05 0.18 0.03 2.45 1.9 1.53 1.24ADML_1B_036 M Detrital 0.05 0.17 0.03 2.45 0.8 1.53 0.52ADML_1B_037 M Detrital 0.02 0.06 <0.02 0.82 1.1 0.61 1.80ADML_1B_038 M Detrital <0.01 0.05 <0.02 0.82 2.1 0.15 13.73ADML_1B_040 M Detrital 0.07 0.24 <0.02 0.82 0.5 2.14 0.23ADML_1B_041 M Detrital 0.04 0.13 0.03 2.45 <0.5 1.22 0.20ADML_1B_045 M Detrital 0.06 0.11 <0.02 0.82 <0.5 1.84 0.14ADML_1B_046 M Detrital 0.06 0.26 0.05 4.08 <0.5 1.84 0.14ADML_1B_049 M Detrital 0.04 0.1 <0.02 0.82 <0.5 1.22 0.20ADML_1B_050 M Detrital 0.02 0.11 0.03 2.45 <0.5 0.61 0.41ADML_1B_051 M Detrital 0.01 0.16 0.03 2.45 1.1 0.31 3.59ADML_1B_060 M Detrital 0.01 <0.02 <0.02 0.82 <0.5 0.31 0.82ADML_1B_061 M Detrital <0.01 0.04 <0.02 0.82 <0.5 0.15 1.63ADML_1B_062 M Detrital <0.01 0.03 <0.02 0.82 2.4 0.15 15.69ADML_1B_063 M Detrital <0.01 0.04 <0.02 0.82 1.1 0.15 7.19ADML_1B_067 M Detrital 0.01 0.06 <0.02 0.82 2.7 0.31 8.82

Where TIC, ANC or S contents were less than the laboratory limit of reporting the values used to calculate CarbNP and NPR were half the LOR.





LOR 0.01 100 0.02 0.02ADML_1B_068 M Detrital 0.01 0.1 0.02 1.63 1.1 0.31 3.59ADML_1B_206 M Detrital 0.01 0.04 <0.02 0.82 3.4 0.31 11.11ADML_1B_212 M Detrital 0.04 0.14 <0.02 0.82 1.9 1.22 1.55ADML_1B_215 M Detrital 0.07 0.19 0.02 1.63 1.4 2.14 0.65ADML_1B_216 M Detrital 0.01 0.22 0.02 1.63 3.6 0.31 11.76ADML_1B_217 M Detrital 0.05 0.17 0.03 2.45 3.8 1.53 2.48ADML_1B_218 M Detrital 0.1 0.27 <0.02 0.82 2.9 3.06 0.95ADML_1B_219 M Detrital 0.08 0.11 <0.02 0.82 4.3 2.45 1.76ADML_1B_032 M Felsic <0.01 <0.02 <0.02 0.82 9.4 0.15 61.44ADML_1B_033 M Felsic <0.01 <0.02 <0.02 0.82 8 0.15 52.29ADML_1B_034 M Felsic <0.01 <0.02 <0.02 0.82 9.9 0.15 64.71ADML_1B_257 M Felsic 0.01 0.03 0.03 2.45 4.7 0.31 15.36ADML_1B_258 M Felsic 0.03 0.02 0.02 1.63 2.5 0.92 2.72ADML_1B_259 M Felsic 0.03 0.06 0.03 2.45 2.2 0.92 2.40ADML_1B_260 M Felsic 0.02 0.03 0.03 2.45 1 0.61 1.63ADML_1B_261 M Felsic 0.01 0.07 0.04 3.27 1.5 0.31 4.90ADML_1B_262 M Felsic 0.01 <0.02 <0.02 0.82 2 0.31 6.54ADML_1B_265 M Felsic 0.03 0.04 0.04 3.27 1.3 0.92 1.42ADML_1B_270 M Felsic 0.03 <0.02 <0.02 0.82 0.8 0.92 0.87A13021 M Hydrated 0.053 190 0.045 0.02 1.63 <0.49 1.62 0.15A13023 M Hydrated 0.056 110 0.034 0.009 0.73 <0.49 1.71 0.15A13035 M Hydrated 0.09 370 0.137 0.057 4.65 <0.49 2.75 0.09A13053 M Hydrated 0.056 0.164 0.074 6.04 <0.49 1.71 0.15ADML_1B_043 M Hydrated <0.01 0.04 <0.02 0.82 <0.5 0.15 1.63ADML_1B_044 M Hydrated <0.01 0.03 <0.02 0.82 0.5 0.15 3.27ADML_1B_048 M Hydrated <0.01 0.05 <0.02 0.82 <0.5 0.15 1.63ADML_1B_075 M Hydrated 0.02 0.04 <0.02 0.82 1.6 0.61 2.61ADML_1B_076 M Hydrated 0.01 0.11 <0.02 0.82 0.5 0.31 1.63ADML_1B_078 M Hydrated <0.01 <0.02 <0.02 0.82 <0.5 0.15 1.63ADML_1B_226 M Hydrated 0.01 0.06 <0.02 0.82 2.2 0.31 7.19ADML_1B_228 M Hydrated <0.01 0.08 <0.02 0.82 <0.5 0.15 1.63ADML_1B_241 M Hydrated 0.01 0.05 0.02 1.63 6.7 0.31 21.90ADML_1B_242 M Hydrated <0.01 0.03 0.03 2.45 7.2 0.15 47.06ADML_1B_243 M Hydrated 0.47 2.09 2.06 168.16 6.4 14.38 0.45ADML_1B_244 M Hydrated 0.01 0.06 0.02 1.63 2.5 0.31 8.17ADML_1B_245 M Hydrated 0.03 1.84 1.84 150.20 7.7 0.92 8.39ADML_1B_246 M Hydrated 0.06 0.09 0.09 7.35 2.5 1.84 1.36ADML_1B_247 M Hydrated 0.16 <0.02 <0.02 0.82 1.2 4.90 0.25ADML_1B_248 M Hydrated <0.01 <0.02 <0.02 0.82 0.7 0.15 4.58ADML_1B_249 M Hydrated 8.56 0.15 0.03 2.45 <0.5 261.94 0.00ADML_1B_250 M Hydrated 0.2 2.82 2.77 226.12 6.9 6.12 1.13ADML_1B_251 M Hydrated 0.04 0.06 0.04 3.27 1.7 1.22 1.39ADML_1B_252 M Hydrated 0.03 0.07 0.03 2.45 2.7 0.92 2.94ADML_1B_254 M Hydrated 0.03 0.11 0.11 8.98 1.7 0.92 1.85ADML_1B_255 M Hydrated 0.02 0.05 0.05 4.08 2 0.61 3.27ADML_1B_256 M Hydrated <0.01 0.03 0.03 2.45 3.2 0.15 20.92ADML_1B_271 M Hydrated 0.02 <0.02 <0.02 0.82 1.3 0.61 2.12ADML_1B_272 M Hydrated 0.01 <0.02 <0.02 0.82 1 0.31 3.27ADML_1B_273 M Hydrated <0.01 0.03 0.03 2.45 <0.5 0.15 1.63A13022 M Mafic 0.022 <100 0.05 0.025 2.04 <0.49 0.67 0.37A13031 M Mafic 0.0025 0.043 0.018 1.47 <0.49 0.08 3.27A13032 M Mafic 0.0025 0.031 0.006 0.49 <0.49 0.08 3.27A13048 M Mafic 0.0025 0.042 0.017 1.39 <0.49 0.08 3.27ADML_1B_009 M Mafic <0.01 0.13 <0.02 0.82 <0.5 0.15 1.63ADML_1B_011 M Mafic <0.01 0.1 0.02 1.63 <0.5 0.15 1.63ADML_1B_025 M Mafic <0.01 0.03 0.03 2.45 0.8 0.15 5.23ADML_1B_026 M Mafic 0.01 <0.02 <0.02 0.82 1.1 0.31 3.59ADML_1B_039 M Mafic <0.01 0.04 <0.02 0.82 0.5 0.15 3.27ADML_1B_056 M Mafic 0.48 <0.02 <0.02 0.82 7.5 14.69 0.51ADML_1B_069 M Mafic <0.01 <0.02 <0.02 0.82 16.2 0.15 105.88ADML_1B_070 M Mafic 0.03 0.02 0.02 1.63 11.5 0.92 12.53ADML_1B_071 M Mafic 0.01 0.04 0.04 3.27 10.5 0.31 34.31ADML_1B_191 M Mafic <0.01 0.09 <0.02 0.82 8.2 0.15 53.59






LOR 0.01 100 0.02 0.02ADML_1B_200 M Mafic <0.01 0.12 <0.02 0.82 3.6 0.15 23.53ADML_1B_208 M Mafic <0.01 0.02 <0.02 0.82 3.8 0.15 24.84ADML_1B_237 M Mafic 0.14 0.08 0.06 4.90 8.9 4.28 2.08ADML_1B_238 M Mafic <0.01 <0.02 <0.02 0.82 4.2 0.15 27.45ADML_1B_008 M Ore 0.07 0.04 <0.02 0.82 <0.5 2.14 0.12ADML_1B_029 M Ore 0.07 0.04 <0.02 0.82 0.8 2.14 0.37ADML_1B_031 M Ore 0.05 0.09 <0.02 0.82 0.8 1.53 0.52ADML_1B_042 M Ore 0.01 0.09 <0.02 0.82 0.8 0.31 2.61ADML_1B_054 M Ore 0.11 0.06 <0.02 0.82 0.5 3.37 0.15ADML_1B_055 M Ore 0.1 0.03 <0.02 0.82 <0.5 3.06 0.08ADML_1B_057 M Ore 0.11 0.1 0.02 1.63 <0.5 3.37 0.07ADML_1B_064 M Ore 0.18 0.02 0.02 1.63 <0.5 5.51 0.05ADML_1B_066 M Ore 0.09 0.03 <0.02 0.82 <0.5 2.75 0.09ADML_1B_072 M Ore 0.07 0.12 0.03 2.45 0.9 2.14 0.42ADML_1B_188 M Ore <0.01 0.08 <0.02 0.82 2.2 0.15 14.38ADML_1B_189 M Ore 0.02 0.05 <0.02 0.82 1.4 0.61 2.29ADML_1B_192 M Ore 0.05 0.06 <0.02 0.82 2.4 1.53 1.57ADML_1B_209 M Ore 0.08 0.05 <0.02 0.82 3.1 2.45 1.27ADML_1B_210 M Ore 0.06 0.03 <0.02 0.82 3.6 1.84 1.96ADML_1B_030 M Ore Hi Al <0.01 0.09 <0.02 0.82 1.3 0.15 8.50ADML_1B_053 M Ore Hi Al 0.04 0.03 <0.02 0.82 <0.5 1.22 0.20ADML_1B_058 M Ore Hi Al 0.02 0.1 0.02 1.63 <0.5 0.61 0.41ADML_1B_190 M Ore Hi Al 0.05 0.03 <0.02 0.82 4.1 1.53 2.68ADML_1B_194 M Ore Hi Al 0.09 0.24 0.03 2.45 3.4 2.75 1.23ADML_1B_195 M Ore Hi Al <0.01 0.19 0.07 5.71 3.6 0.15 23.53ADML_1B_198 M Ore Hi Al 0.05 0.03 <0.02 0.82 2.4 1.53 1.57ADML_1B_202 M Ore Hi Al <0.01 0.19 <0.02 0.82 2.7 0.15 17.65ADML_1B_231 M Ore Hi Al 0.02 0.07 <0.02 0.82 1.7 0.61 2.78ADML_1B_234 M Ore Hi Al <0.01 0.08 <0.02 0.82 3 0.15 19.61ADML_1B_235 M Ore Hi Al 0.08 0.1 <0.02 0.82 1.8 2.45 0.74ADML_1B_236 M Ore Hi Al 0.02 0.14 <0.02 0.82 1.4 0.61 2.29ADML_1B_013 M Ore Hi SiO2 0.08 0.26 0.05 4.08 2.3 2.45 0.94ADML_1B_020 M Ore Hi SiO2 <0.01 0.04 <0.02 0.82 <0.5 0.15 1.63ADML_1B_028 M Ore Hi SiO2 0.1 0.05 <0.02 0.82 1.1 3.06 0.36ADML_1B_052 M Ore Hi SiO2 0.01 0.07 <0.02 0.82 <0.5 0.31 0.82ADML_1B_059 M Ore Hi SiO2 0.01 0.02 0.02 1.63 <0.5 0.31 0.82ADML_1B_065 M Ore Hi SiO2 0.08 0.03 <0.02 0.82 <0.5 2.45 0.10ADML_1B_073 M Ore Hi SiO2 0.08 0.05 <0.02 0.82 1.6 2.45 0.65ADML_1B_196 M Ore Hi SiO2 <0.01 0.07 <0.02 0.82 2.4 0.15 15.69ADML_1B_199 M Ore Hi SiO2 <0.01 0.04 <0.02 0.82 1.2 0.15 7.84ADML_1B_201 M Ore Hi SiO2 0.04 0.14 <0.02 0.82 1.9 1.22 1.55ADML_1B_203 M Ore Hi SiO2 0.03 0.03 <0.02 0.82 1.9 0.92 2.07ADML_1B_207 M Ore Hi SiO2 0.02 0.25 0.05 4.08 2.4 0.61 3.92ADML_1B_230 M Ore Hi SiO2 0.08 0.03 <0.02 0.82 1.4 2.45 0.57ADML_1B_232 M Ore Hi SiO2 <0.01 0.05 <0.02 0.82 0.6 0.15 3.92ADML_1B_233 M Ore Hi SiO2 0.1 0.13 <0.02 0.82 0.6 3.06 0.20A13026 M Shale 1.17 1.07 1.045 85.30 47.04 35.80 1.31A13027 M Shale 1.3 3.78 3.755 306.52 117.6 39.78 2.96A13038 M Shale 1.14 1.92 1.895 154.69 117.6 34.88 3.37A13039 M Shale 1.87 2.52 2.495 203.67 127.4 57.22 2.23A13058 M Shale 0.0025 0.009 -0.016 0.00 <0.49 0.08 3.27ADML_1B_274 M Shale 3.18 0.05 <0.02 0.82 5.3 97.31 0.05ADML_1B_275 M Shale 0.4 0.04 0.04 3.27 5.6 12.24 0.46ADML_1B_276 M Shale 2.97 0.06 <0.02 0.82 4.8 90.88 0.05ADML_1B_277 M Shale 2.04 0.05 <0.02 0.82 4.8 62.42 0.08ADML_1B_280 M Shale 23.8 0.1 0.02 1.63 <0.5 728.28 0.00ADML_1B_281 M Shale 0.09 <0.02 <0.02 0.82 6.9 2.75 2.51ADML_1B_282 M Shale 0.39 0.71 0.61 49.79 2.5 11.93 0.21ADML_1B_283 M Shale <0.01 <0.02 <0.02 0.82 2.3 0.15 15.03ADML_1B_284 M Shale 0.07 0.02 0.02 1.63 2.3 2.14 1.07ADML_1B_285 M Shale <0.01 <0.02 <0.02 0.82 3 0.15 19.61ADML_1B_286 M Shale 0.03 <0.02 <0.02 0.82 2.5 0.92 2.72ADML_1B_287 M Shale 0.01 <0.02 <0.02 0.82 2.8 0.31 9.15






LOR 0.01 100 0.02 0.02ADML_1B_288 M Shale <0.01 <0.02 <0.02 0.82 1.5 0.15 9.80ADML_1B_289 M Shale 0.01 <0.02 <0.02 0.82 2.3 0.31 7.52A13003 B BIF 0.009 0.014 -0.011 0.00 <0.49 0.28 0.91A13004 B BIF 0.01 0.018 -0.007 0.00 <0.49 0.31 0.82A13005 B BIF 0.006 <100 0.036 0.011 0.90 <0.49 0.18 1.36A13006 B BIF 0.0025 0.048 0.023 1.88 <0.49 0.08 3.27A13011 B BIF 0.0025 0.006 -0.019 0.00 4.9 0.08 64.05A13013 B BIF 0.0025 1.46 1.435 117.14 98 0.08 1281.05A13014 B BIF 0.007 1.13 1.105 90.20 91.14 0.21 425.49A13015 B BIF 0.008 1.86 1.835 149.79 117.6 0.24 480.39A13016 B BIF 0.474 0.647 0.622 50.77 47.04 14.50 3.24A13042 B BIF 0.0025 0.528 0.503 41.06 40.18 0.08 525.23A13043 B BIF 0.0025 1.1 1.075 87.75 88.2 0.08 1152.94A13044 B BIF 0.0025 0.044 0.019 1.55 <0.49 0.08 3.27ADML_1B_083 B BIF <0.01 <0.02 <0.02 0.82 <0.5 0.15 1.63ADML_1B_084 B BIF <0.01 <0.02 <0.02 0.82 1.1 0.15 7.19ADML_1B_098 B BIF <0.01 <0.02 <0.02 0.82 0.9 0.15 5.88ADML_1B_100 B BIF <0.01 0.02 0.02 1.63 0.7 0.15 4.58ADML_1B_107 B BIF <0.01 <0.02 <0.02 0.82 1.2 0.15 7.84ADML_1B_130 B BIF <0.01 0.31 0.27 22.04 28.6 0.15 186.93ADML_1B_138 B BIF <0.01 <0.02 <0.02 0.82 0.7 0.15 4.58ADML_1B_138 B BIF 0.07 0.03 <0.02 0.82 <0.5 2.14 0.12ADML_1B_149 B BIF <0.01 <0.02 <0.02 0.82 11.6 0.15 75.82ADML_1B_156 B BIF <0.01 <0.02 <0.02 0.82 13.6 0.15 88.89ADML_1B_174 B BIF <0.01 6.29 6.26 511.00 67.7 0.15 442.48ADML_1B_185 B BIF 0.02 0.03 <0.02 0.82 1.4 0.61 2.29ADML_1B_186 B BIF <0.01 0.03 <0.02 0.82 1.9 0.15 12.42ADML_1B_197 B BIF <0.01 0.1 <0.02 0.82 3.4 0.15 22.22ADML_1B_221 B BIF <0.01 0.02 <0.02 0.82 2.3 0.15 15.03A13001 B Mafic 0.023 <100 0.141 0.041 3.35 0.98 0.70 1.39A13002 B Mafic 0.008 0.093 0.013 1.06 <0.49 0.24 1.02A13007 B Mafic 0.0025 0.016 -0.009 0.00 4.9 0.08 64.05A13008 B Mafic 0.0025 0.006 -0.019 0.00 6.86 0.08 89.67A13009 B Mafic 0.0025 0.009 -0.016 0.00 <0.49 0.08 3.27A13010 B Mafic 0.0025 0.033 0.008 0.65 14.7 0.08 192.16A13012 B Mafic 0.0025 0.005 -0.02 0.00 22.54 0.08 294.64A13017 B Mafic 0.015 0.154 0.129 10.53 38.22 0.46 83.27A13018 B Mafic 0.064 0.128 0.103 8.41 32.34 1.96 16.51A13040 B Mafic 0.0025 0.047 0.022 1.80 3.92 0.08 51.24A13041 B Mafic 0.0025 0.034 0.009 0.73 12.74 0.08 166.54A13045 B Mafic 0.0025 0.089 0.064 5.22 20.58 0.08 269.02A13046 B Mafic 0.045 0.036 0.011 0.90 29.4 1.38 21.35ADML_1B_006 B Mafic <0.01 <0.02 <0.02 0.82 5.2 0.15 33.99ADML_1B_007 B Mafic <0.01 <0.02 <0.02 0.82 3.8 0.15 24.84ADML_1B_079 B Mafic <0.01 <0.02 <0.02 0.82 <0.5 0.15 1.63ADML_1B_080 B Mafic <0.01 <0.02 <0.02 0.82 7.8 0.15 50.98ADML_1B_081 B Mafic <0.01 <0.02 <0.02 0.82 2.8 0.15 18.30ADML_1B_082 B Mafic <0.01 <0.02 <0.02 0.82 4.3 0.15 28.10ADML_1B_085 B Mafic <0.01 <0.02 <0.02 0.82 12.5 0.15 81.70ADML_1B_086 B Mafic <0.01 <0.02 <0.02 0.82 19.7 0.15 128.76ADML_1B_087 B Mafic <0.01 <0.02 <0.02 0.82 3.2 0.15 20.92ADML_1B_088 B Mafic 0.02 <0.02 <0.02 0.82 22 0.61 35.95ADML_1B_089 B Mafic <0.01 <0.02 <0.02 0.82 14.6 0.15 95.42ADML_1B_090 B Mafic <0.01 <0.02 <0.02 0.82 20.2 0.15 132.03ADML_1B_091 B Mafic 0.02 0.04 0.04 3.27 18.2 0.61 29.74ADML_1B_092 B Mafic <0.01 0.03 <0.02 0.82 5.7 0.15 37.25ADML_1B_093 B Mafic <0.01 <0.02 <0.02 0.82 11.2 0.15 73.20ADML_1B_094 B Mafic <0.01 <0.02 <0.02 0.82 10.6 0.15 69.28ADML_1B_095 B Mafic <0.01 <0.02 <0.02 0.82 16.9 0.15 110.46ADML_1B_096 B Mafic <0.01 <0.02 <0.02 0.82 <0.5 0.15 1.63ADML_1B_097 B Mafic <0.01 0.1 0.1 8.16 1.9 0.15 12.42ADML_1B_103 B Mafic <0.01 <0.02 <0.02 0.82 5.7 0.15 37.25ADML_1B_104 B Mafic <0.01 0.03 <0.02 0.82 12.4 0.15 81.05






LOR 0.01 100 0.02 0.02ADML_1B_105 B Mafic <0.01 0.4 0.4 32.65 35.3 0.15 230.72ADML_1B_106 B Mafic <0.01 0.02 0.02 1.63 2.5 0.15 16.34ADML_1B_108 B Mafic <0.01 0.1 <0.02 0.82 1.8 0.15 11.76ADML_1B_112 B Mafic <0.01 0.04 <0.02 0.82 7.2 0.15 47.06ADML_1B_113 B Mafic <0.01 <0.02 <0.02 0.82 14.9 0.15 97.39ADML_1B_114 B Mafic <0.01 0.03 0.03 2.45 12.5 0.15 81.70ADML_1B_116 B Mafic <0.01 0.09 0.07 5.71 11.6 0.15 75.82ADML_1B_117 B Mafic <0.01 <0.02 <0.02 0.82 13.1 0.15 85.62ADML_1B_119 B Mafic 0.01 <0.02 <0.02 0.82 8.4 0.31 27.45ADML_1B_120 B Mafic <0.01 <0.02 <0.02 0.82 10.5 0.15 68.63ADML_1B_121 B Mafic <0.01 <0.02 <0.02 0.82 10.6 0.15 69.28ADML_1B_122 B Mafic 0.04 0.09 0.09 7.35 12.7 1.22 10.38ADML_1B_123 B Mafic <0.01 0.2 0.16 13.06 18.9 0.15 123.53ADML_1B_124 B Mafic <0.01 <0.02 <0.02 0.82 10.6 0.15 69.28ADML_1B_126 B Mafic <0.01 <0.02 <0.02 0.82 14 0.15 91.50ADML_1B_128 B Mafic <0.01 <0.02 <0.02 0.82 18.3 0.15 119.61ADML_1B_129 B Mafic <0.01 <0.02 <0.02 0.82 4.3 0.15 28.10ADML_1B_131 B Mafic <0.01 <0.02 <0.02 0.82 15.4 0.15 100.65ADML_1B_132 B Mafic <0.01 0.12 0.12 9.80 22.7 0.15 148.37ADML_1B_133 B Mafic <0.01 <0.02 <0.02 0.82 10.3 0.15 67.32ADML_1B_134 B Mafic <0.01 <0.02 <0.02 0.82 13.6 0.15 88.89ADML_1B_135 B Mafic <0.01 <0.02 <0.02 0.82 7.3 0.15 47.71ADML_1B_136 B Mafic <0.01 <0.02 <0.02 0.82 9.8 0.15 64.05ADML_1B_137 B Mafic 0.36 0.03 0.03 2.45 0.6 11.02 0.05ADML_1B_139 B Mafic 0.02 0.74 0.64 52.24 61.8 0.61 100.98ADML_1B_140 B Mafic <0.01 <0.02 <0.02 0.82 1.2 0.15 7.84ADML_1B_141 B Mafic <0.01 <0.02 <0.02 0.82 11.1 0.15 72.55ADML_1B_142 B Mafic <0.01 <0.02 <0.02 0.82 12.5 0.15 81.70ADML_1B_143 B Mafic <0.01 0.02 0.02 1.63 1 0.15 6.54ADML_1B_144 B Mafic <0.01 0.06 <0.02 0.82 1.4 0.15 9.15ADML_1B_146 B Mafic <0.01 0.02 <0.02 0.82 0.7 0.15 4.58ADML_1B_150 B Mafic 0.06 0.02 0.02 1.63 11.8 1.84 6.43ADML_1B_151 B Mafic <0.01 <0.02 <0.02 0.82 10.8 0.15 70.59ADML_1B_152 B Mafic <0.01 <0.02 <0.02 0.82 16 0.15 104.58ADML_1B_153 B Mafic <0.01 <0.02 <0.02 0.82 9.6 0.15 62.75ADML_1B_154 B Mafic <0.01 <0.02 <0.02 0.82 3.9 0.15 25.49ADML_1B_155 B Mafic <0.01 0.08 0.08 6.53 9.6 0.15 62.75ADML_1B_157 B Mafic <0.01 0.03 0.03 2.45 10.3 0.15 67.32ADML_1B_158 B Mafic <0.01 <0.02 <0.02 0.82 11 0.15 71.90ADML_1B_159 B Mafic <0.01 <0.02 <0.02 0.82 2.7 0.15 17.65ADML_1B_160 B Mafic <0.01 <0.02 <0.02 0.82 11.5 0.15 75.16ADML_1B_161 B Mafic <0.01 <0.02 <0.02 0.82 10.9 0.15 71.24ADML_1B_162 B Mafic <0.01 <0.02 <0.02 0.82 6.2 0.15 40.52ADML_1B_163 B Mafic <0.01 0.02 0.02 1.63 3.8 0.15 24.84ADML_1B_164 B Mafic <0.01 <0.02 <0.02 0.82 12.7 0.15 83.01ADML_1B_167 B Mafic <0.01 <0.02 <0.02 0.82 13.1 0.15 85.62ADML_1B_168 B Mafic <0.01 <0.02 <0.02 0.82 6.8 0.15 44.44ADML_1B_169 B Mafic <0.01 0.02 <0.02 0.82 4.4 0.15 28.76ADML_1B_175 B Mafic <0.01 <0.02 <0.02 0.82 8.2 0.15 53.59ADML_1B_005 B Mafic <0.01 0.03 0.03 2.45 1.9 0.15 12.42ADML_1B_179 B Magnetite 0.02 2.12 2.12 173.06 90.6 0.61 148.04ADML_1B_180 B Magnetite <0.01 0.73 0.73 59.59 91.8 0.15 600.00ADML_1B_181 B Magnetite <0.01 1.55 1.55 126.53 96.7 0.15 632.03ADML_1B_222 B Magnetite <0.01 2.71 2.71 221.22 193 0.15 1261.44ADML_1B_002 B Ore <0.01 0.04 <0.02 0.82 <0.5 0.15 1.63ADML_1B_102 B Ore <0.01 0.06 <0.02 0.82 <0.5 0.15 1.63ADML_1B_109 B Ore 0.02 0.03 <0.02 0.82 1.8 0.61 2.94ADML_1B_111 B Ore <0.01 0.02 0.02 1.63 1.9 0.15 12.42ADML_1B_115 B Ore 0.02 <0.02 <0.02 0.82 1.2 0.61 1.96ADML_1B_118 B Ore <0.01 <0.02 <0.02 0.82 1.7 0.15 11.11ADML_1B_125 B Ore <0.01 1.49 1.47 120.00 117 0.15 764.71ADML_1B_147 B Ore <0.01 <0.02 <0.02 0.82 12.3 0.15 80.39ADML_1B_171 B Ore <0.01 <0.02 <0.02 0.82 5.3 0.15 34.64






LOR 0.01 100 0.02 0.02ADML_1B_173 B Ore <0.01 0.02 <0.02 0.82 42.3 0.15 276.47ADML_1B_177 B Ore <0.01 0.03 <0.02 0.82 3.2 0.15 20.92ADML_1B_178 B Ore <0.01 0.13 0.13 10.61 55.6 0.15 363.40ADML_1B_224 B Ore <0.01 0.1 <0.02 0.82 3.1 0.15 20.26ADML_1B_110 B Ore Hi Al 0.12 0.09 0.05 4.08 5.5 3.67 1.50ADML_1B_127 B Ore Hi Al <0.01 0.04 0.02 1.63 5.6 0.15 36.60ADML_1B_145 B Ore Hi Al <0.01 0.09 <0.02 0.82 0.7 0.15 4.58ADML_1B_145 B Ore Hi Al <0.01 0.02 0.02 1.63 <0.5 0.15 1.63ADML_1B_172 B Ore Hi Al <0.01 0.04 0.04 3.27 4.4 0.15 28.76ADML_1B_182 B Ore Hi Al <0.01 0.05 <0.02 0.82 3.9 0.15 25.49ADML_1B_183 B Ore Hi Al <0.01 0.03 <0.02 0.82 4.4 0.15 28.76ADML_1B_184 B Ore Hi Al <0.01 0.34 0.24 19.59 10.7 0.15 69.93ADML_1B_278 B Ore Hi Al 0.05 0.12 0.03 2.45 2.3 1.53 1.50ADML_1B_279 B Ore Hi Al 0.06 0.16 0.04 3.27 4.1 1.84 2.23ADML_1B_003 B Ore Hi SiO2 0.19 2.22 2.22 181.22 168 5.81 28.90ADML_1B_004 B Ore Hi SiO2 <0.01 0.11 0.07 5.71 4.9 0.15 32.03ADML_1B_099 B Ore Hi SiO2 <0.01 0.03 0.03 2.45 1.5 0.15 9.80ADML_1B_101 B Ore Hi SiO2 <0.01 0.04 <0.02 0.82 0.6 0.15 3.92ADML_1B_148 B Ore Hi SiO2 <0.01 0.04 0.04 3.27 11.2 0.15 73.20ADML_1B_170 B Ore Hi SiO2 <0.01 0.24 0.03 2.45 4.7 0.15 30.72ADML_1B_176 B Ore Hi SiO2 <0.01 1.53 1.5 122.45 65.2 0.15 426.14ADML_1B_220 B Ore Hi SiO2 <0.01 0.03 <0.02 0.82 2.9 0.15 18.95ADML_1B_223 B Ore Hi SiO2 <0.01 0.03 <0.02 0.82 4.4 0.15 28.76ADML_1B_001 Mafic <0.01 <0.02 <0.02 0.82 <0.5 0.15 1.63




Appendix 5: Net Acid Generation (NAG) Test Results


Net Acid Generation (NAG) Test Results

SMC Sample ID Zone Domain ID Sample Type NAGpH NAG [pH 4.5] NAG [pH 7.0] MPA B - Beebyn pH Unit kg H2SO4/t kg H2SO4/t kg(H2SO4)/tM- Madoonga 0.1

A13020 M BIF DD 6.3 <0.5 <0.5 0.21A13024 M BIF DD 7.7 <0.5 <0.5 2.57A13025 M BIF DD 7.7 <0.5 <0.5 1.90A13028 M BIF DD 7.9 <0.5 <0.5 3.55A13029 M BIF DD 7 <0.5 <0.5 8.17A13033 M BIF DD 5.3 <0.5 <0.5 0.08A13034 M BIF DD 6.1 <0.5 <0.5 3.43A13036 M BIF DD 8.5 <0.5 <0.5 0.61A13037 M BIF DD 3 2 5 18.94A13049 M BIF DD 6 <0.5 <0.5 1.68A13050 M BIF DD 5.7 <0.5 <0.5 1.56A13051 M BIF DD 4.8 <0.5 <0.5 0.08A13052 M BIF DD 4.7 <0.5 <0.5 2.94A13054 M BIF DD 5 <0.5 <0.5 0.24A13055 M BIF DD 4.6 <0.5 <0.5 0.08A13056 M BIF DD 2.9 1 3 2.72A13057 M BIF DD 2.3 5 7 6.98A13059 M BIF DD 1.9 14 17 23.81

ADML_1B_012 M BIF DD --- --- --- 0.61ADML_1B_014 M BIF DD --- --- --- 0.15ADML_1B_015 M BIF DD 7.2 <0.1 <0.1 4.90ADML_1B_016 M BIF DD 4.1 <0.1 2.1 1.53ADML_1B_017 M BIF DD 6.9 <0.1 0.2 3.06ADML_1B_018 M BIF DD 5.8 <0.1 1.2 0.15ADML_1B_019 M BIF DD --- --- --- 0.15ADML_1B_021 M BIF DD --- --- --- 0.92ADML_1B_022 M BIF DD 5.6 <0.1 1.4 0.31ADML_1B_023 M BIF DD --- --- --- 0.61ADML_1B_047 M BIF DD 5.4 <0.1 1.1 0.15ADML_1B_074 M BIF DD 6.7 <0.1 0.2 0.15ADML_1B_077 M BIF DD 8.8 <0.1 <0.1 0.31ADML_1B_187 M BIF DD 5 <0.1 1 0.15ADML_1B_193 M BIF DD 5.8 <0.1 0.4 0.15ADML_1B_204 M BIF DD --- --- --- 0.15ADML_1B_205 M BIF DD 5 <0.1 1.8 0.15ADML_1B_211 M BIF DD --- --- --- 0.61ADML_1B_213 M BIF Surface sample --- --- --- 0.31ADML_1B_214 M BIF Surface sample --- --- --- 0.15ADML_1B_225 M BIF DD --- --- --- 0.15ADML_1B_227 M BIF DD --- --- --- 0.15ADML_1B_229 M BIF DD --- --- --- 0.15

A13019 M Detrital DD 5.3 <0.5 <0.5 1.99A13030 M Detrital DD 5.3 <0.5 <0.5 0.34A13047 M Detrital DD 5.7 <0.5 <0.5 1.74

ADML_1B_010 M Detrital DD 6.2 <0.1 1.4 1.53ADML_1B_024 M Detrital DD --- --- --- 0.15ADML_1B_027 M Detrital DD --- --- --- 3.06ADML_1B_035 M Detrital DD --- --- --- 1.53ADML_1B_036 M Detrital DD --- --- --- 1.53ADML_1B_037 M Detrital DD 5.8 <0.1 0.6 0.61ADML_1B_038 M Detrital DD --- --- --- 0.15ADML_1B_040 M Detrital DD --- --- --- 2.14ADML_1B_041 M Detrital DD --- --- --- 1.22ADML_1B_045 M Detrital DD 5.3 <0.1 1 1.84ADML_1B_046 M Detrital DD --- --- --- 1.84ADML_1B_049 M Detrital DD --- --- --- 1.22ADML_1B_050 M Detrital DD --- --- --- 0.61

DD = Diamond drill core sample RC = reverse circulation sample




ADML_1B_051 M Detrital DD 4.3 <0.1 1.6 0.31ADML_1B_060 M Detrital DD --- --- --- 0.31ADML_1B_061 M Detrital DD 6.4 <0.1 0.2 0.15ADML_1B_062 M Detrital DD --- --- --- 0.15ADML_1B_063 M Detrital DD 7.5 <0.1 <0.1 0.15ADML_1B_067 M Detrital DD --- --- --- 0.31ADML_1B_068 M Detrital DD 4.9 <0.1 1.2 0.31ADML_1B_206 M Detrital DD --- --- --- 0.31ADML_1B_212 M Detrital Surface sample --- --- --- 1.22ADML_1B_215 M Detrital Surface sample --- --- --- 2.14ADML_1B_216 M Detrital Surface sample --- --- --- 0.31ADML_1B_217 M Detrital Surface sample --- --- --- 1.53ADML_1B_218 M Detrital Surface sample --- --- --- 3.06ADML_1B_219 M Detrital Surface sample --- --- --- 2.45ADML_1B_032 M Felsic DD 7.2 <0.1 <0.1 0.15ADML_1B_033 M Felsic DD 7.6 <0.1 <0.1 0.15ADML_1B_034 M Felsic DD 7.3 <0.1 <0.1 0.15ADML_1B_257 M Felsic Surface sample 6.1 <0.1 0.4 0.31ADML_1B_258 M Felsic Surface sample 6.5 <0.1 0.2 0.92ADML_1B_259 M Felsic Surface sample 5.5 <0.1 0.7 0.92ADML_1B_260 M Felsic Surface sample 5.6 <0.1 0.9 0.61ADML_1B_261 M Felsic Surface sample 5.2 <0.1 1.7 0.31ADML_1B_262 M Felsic Surface sample 6.1 <0.1 0.3 0.31ADML_1B_265 M Felsic Surface sample 6.2 <0.1 0.2 0.92ADML_1B_270 M Felsic Surface sample 6.1 <0.1 0.9 0.92

A13021 M Hydrated DD 5.8 <0.5 <0.5 1.62A13023 M Hydrated DD 5.8 <0.5 <0.5 1.71A13035 M Hydrated DD 6.1 <0.5 <0.5 2.75A13053 M Hydrated DD 4.9 <0.5 <0.5 1.71

ADML_1B_043 M Hydrated DD 5.7 <0.1 0.8 0.15ADML_1B_044 M Hydrated DD 5.7 <0.1 0.8 0.15ADML_1B_048 M Hydrated DD --- --- --- 0.15ADML_1B_075 M Hydrated DD --- --- --- 0.61ADML_1B_076 M Hydrated DD 6.2 <0.1 0.2 0.31ADML_1B_078 M Hydrated DD 8.1 <0.1 <0.1 0.15ADML_1B_226 M Hydrated DD --- --- --- 0.31ADML_1B_228 M Hydrated DD --- --- --- 0.15ADML_1B_241 M Hydrated RC 7.3 <0.1 <0.1 0.31ADML_1B_242 M Hydrated RC 7.1 <0.1 <0.1 0.15ADML_1B_243 M Hydrated RC 5.8 <0.1 1.2 14.38ADML_1B_244 M Hydrated RC 5.5 <0.1 1.2 0.31ADML_1B_245 M Hydrated RC 7.9 <0.1 <0.1 0.92ADML_1B_246 M Hydrated RC 5.6 <0.1 0.6 1.84ADML_1B_247 M Hydrated DD 3.2 3.5 5.5 4.90ADML_1B_248 M Hydrated DD 4 0.2 1.9 0.15ADML_1B_249 M Hydrated DD 1.7 168 187 261.94ADML_1B_250 M Hydrated DD 7.8 <0.1 <0.1 6.12ADML_1B_251 M Hydrated DD 11 0.1 1.7 1.22ADML_1B_252 M Hydrated DD 5.6 <0.1 0.5 0.92ADML_1B_254 M Hydrated DD 6.2 <0.1 0.6 0.92ADML_1B_255 M Hydrated DD 6.1 <0.1 1.7 0.61ADML_1B_256 M Hydrated RC 5.5 <0.1 0.9 0.15ADML_1B_271 M Hydrated RC 6.7 <0.1 0.6 0.61ADML_1B_272 M Hydrated RC 7.8 <0.1 <0.1 0.31ADML_1B_273 M Hydrated RC 5.4 <0.1 1 0.15

A13022 M Mafic DD 6.2 <0.5 <0.5 0.67A13031 M Mafic DD 5.9 <0.5 <0.5 0.08A13032 M Mafic DD 5.9 <0.5 <0.5 0.08





A13048 M Mafic DD 5 <0.5 <0.5 0.08ADML_1B_009 M Mafic DD --- --- --- 0.15ADML_1B_011 M Mafic DD --- --- --- 0.15ADML_1B_025 M Mafic DD --- --- --- 0.15ADML_1B_026 M Mafic DD 6.4 <0.1 0.2 0.31ADML_1B_039 M Mafic DD --- --- --- 0.15ADML_1B_056 M Mafic DD 3.3 7 16.3 14.69ADML_1B_069 M Mafic DD --- --- --- 0.15ADML_1B_070 M Mafic DD 7.1 <0.1 <0.1 0.92ADML_1B_071 M Mafic DD 7.3 <0.1 <0.1 0.31ADML_1B_191 M Mafic DD 8 <0.1 <0.1 0.15ADML_1B_200 M Mafic DD 5.7 <0.1 0.8 0.15ADML_1B_208 M Mafic DD --- --- --- 0.15ADML_1B_237 M Mafic DD 5.5 <0.1 0.4 4.28ADML_1B_238 M Mafic DD 6.6 <0.1 0.4 0.15ADML_1B_008 M Ore DD 6.9 <0.1 0.4 2.14ADML_1B_029 M Ore DD --- --- --- 2.14ADML_1B_031 M Ore DD --- --- --- 1.53ADML_1B_042 M Ore DD 6.9 <0.1 0.4 0.31ADML_1B_054 M Ore DD --- --- --- 3.37ADML_1B_055 M Ore DD --- --- --- 3.06ADML_1B_057 M Ore DD --- --- --- 3.37ADML_1B_064 M Ore DD --- --- --- 5.51ADML_1B_066 M Ore DD 6.9 <0.1 0.1 2.75ADML_1B_072 M Ore DD --- --- --- 2.14ADML_1B_188 M Ore DD --- --- --- 0.15ADML_1B_189 M Ore DD --- --- --- 0.61ADML_1B_192 M Ore DD --- --- --- 1.53ADML_1B_209 M Ore DD --- --- --- 2.45ADML_1B_210 M Ore DD 7 <0.1 <0.1 1.84ADML_1B_030 M Ore Hi Al DD 3.7 0.2 1.6 0.15ADML_1B_053 M Ore Hi Al DD 6.4 <0.1 1.2 1.22ADML_1B_058 M Ore Hi Al DD --- --- --- 0.61ADML_1B_190 M Ore Hi Al DD --- --- --- 1.53ADML_1B_194 M Ore Hi Al DD --- --- --- 2.75ADML_1B_195 M Ore Hi Al DD --- --- --- 0.15ADML_1B_198 M Ore Hi Al DD 6.6 <0.1 0.4 1.53ADML_1B_202 M Ore Hi Al DD --- --- --- 0.15ADML_1B_231 M Ore Hi Al DD --- --- --- 0.61ADML_1B_234 M Ore Hi Al DD 6.8 <0.1 0.4 0.15ADML_1B_235 M Ore Hi Al DD 6.4 <0.1 1.8 2.45ADML_1B_236 M Ore Hi Al DD --- --- --- 0.61ADML_1B_013 M Ore Hi SiO2 DD --- --- --- 2.45ADML_1B_020 M Ore Hi SiO2 DD --- --- --- 0.15ADML_1B_028 M Ore Hi SiO2 DD --- --- --- 3.06ADML_1B_052 M Ore Hi SiO2 DD --- --- --- 0.31ADML_1B_059 M Ore Hi SiO2 DD --- --- --- 0.31ADML_1B_065 M Ore Hi SiO2 DD --- --- --- 2.45ADML_1B_073 M Ore Hi SiO2 DD --- --- --- 2.45ADML_1B_196 M Ore Hi SiO2 DD --- --- --- 0.15ADML_1B_199 M Ore Hi SiO2 DD --- --- --- 0.15ADML_1B_201 M Ore Hi SiO2 DD --- --- --- 1.22ADML_1B_203 M Ore Hi SiO2 DD 6.8 <0.1 0.2 0.92ADML_1B_207 M Ore Hi SiO2 DD --- --- --- 0.61ADML_1B_230 M Ore Hi SiO2 DD --- --- --- 2.45ADML_1B_232 M Ore Hi SiO2 DD --- --- --- 0.15ADML_1B_233 M Ore Hi SiO2 DD --- --- --- 3.06

A13026 M Shale DD 7.1 <0.5 <0.5 35.80





A13027 M Shale DD 7.8 <0.5 <0.5 39.78A13038 M Shale DD 9.3 <0.5 <0.5 34.88A13039 M Shale DD 8.6 <0.5 <0.5 57.22A13058 M Shale DD 5.8 <0.5 <0.5 0.08

ADML_1B_274 M Shale DD 2.1 69.5 83.8 97.31ADML_1B_275 M Shale DD 3 3.2 9.7 12.24ADML_1B_276 M Shale DD 2.1 63.6 74.4 90.88ADML_1B_277 M Shale DD 2.4 30.9 37.3 62.42ADML_1B_280 M Shale DD 1.7 419 466 728.28ADML_1B_281 M Shale DD 5.7 <0.1 0.7 2.75ADML_1B_282 M Shale DD 3 5.2 8.4 11.93ADML_1B_283 M Shale DD 6 <0.1 0.3 0.15ADML_1B_284 M Shale DD 4.6 <0.1 1.9 2.14ADML_1B_285 M Shale DD 5.9 <0.1 0.8 0.15ADML_1B_286 M Shale DD 5.6 <0.1 0.5 0.92ADML_1B_287 M Shale DD 5.8 <0.1 1 0.31ADML_1B_288 M Shale DD 6.2 <0.1 0.2 0.15ADML_1B_289 M Shale DD 6 <0.1 0.4 0.31

A13003 B BIF DD 5.5 <0.5 <0.5 0.28A13004 B BIF DD 5 <0.5 <0.5 0.31A13005 B BIF DD 5.4 <0.5 <0.5 0.18A13006 B BIF DD 5.6 <0.5 <0.5 0.08A13011 B BIF DD 6.6 <0.5 <0.5 0.08A13013 B BIF DD 8.3 <0.5 <0.5 0.08A13014 B BIF DD 8.4 <0.5 <0.5 0.21A13015 B BIF DD 8.1 <0.5 <0.5 0.24A13016 B BIF DD 7.7 <0.5 <0.5 14.50A13042 B BIF DD 8.6 <0.5 <0.5 0.08A13043 B BIF DD 9.6 <0.5 <0.5 0.08A13044 B BIF DD 7.8 <0.5 <0.5 0.08

ADML_1B_083 B BIF DD 4.6 <0.1 1.9 0.15ADML_1B_084 B BIF DD 7.2 <0.1 <0.1 0.15ADML_1B_098 B BIF DD 6.8 <0.1 0.3 0.15ADML_1B_100 B BIF DD 7.2 <0.1 <0.1 0.15ADML_1B_107 B BIF DD 6.8 <0.1 <0.1 0.15ADML_1B_130 B BIF DD --- --- --- 0.15ADML_1B_138 B BIF DD 5.2 <0.1 1.1 0.15ADML_1B_138 B BIF DD 0 0 0 2.14ADML_1B_149 B BIF DD 7.6 <0.1 <0.1 0.15ADML_1B_156 B BIF DD 7.6 <0.1 <0.1 0.15ADML_1B_174 B BIF DD 9.4 <0.1 <0.1 0.15ADML_1B_185 B BIF DD 4.6 <0.1 2.7 0.61ADML_1B_186 B BIF DD 5.8 <0.1 0.9 0.15ADML_1B_197 B BIF DD 7.8 <0.1 <0.1 0.15ADML_1B_221 B BIF DD 5.3 <0.1 1.4 0.15

A13001 B Mafic DD 4.8 <0.5 <0.5 0.70A13002 B Mafic DD 4.9 <0.5 <0.5 0.24A13007 B Mafic DD 6.7 <0.5 <0.5 0.08A13008 B Mafic DD 6.6 <0.5 <0.5 0.08A13009 B Mafic DD 5.5 <0.5 <0.5 0.08A13010 B Mafic DD 6.5 <0.5 <0.5 0.08A13012 B Mafic DD 7 <0.5 <0.5 0.08A13017 B Mafic DD 7.5 <0.5 <0.5 0.46A13018 B Mafic DD 7.8 <0.5 <0.5 1.96A13040 B Mafic DD 6.5 <0.5 <0.5 0.08A13041 B Mafic DD 7.1 <0.5 <0.5 0.08A13045 B Mafic DD 6.5 <0.5 <0.5 0.08A13046 B Mafic DD 6.3 <0.5 <0.5 1.38





ADML_1B_006 B Mafic DD 7.4 <0.1 <0.1 0.15ADML_1B_007 B Mafic DD --- --- --- 0.15ADML_1B_079 B Mafic DD --- --- --- 0.15ADML_1B_080 B Mafic DD 7 <0.1 <0.1 0.15ADML_1B_081 B Mafic DD --- --- --- 0.15ADML_1B_082 B Mafic DD --- --- --- 0.15ADML_1B_085 B Mafic DD 8 <0.1 <0.1 0.15ADML_1B_086 B Mafic DD --- --- --- 0.15ADML_1B_087 B Mafic DD --- --- --- 0.15ADML_1B_088 B Mafic DD 8.1 <0.1 <0.1 0.61ADML_1B_089 B Mafic DD --- --- --- 0.15ADML_1B_090 B Mafic DD --- --- --- 0.15ADML_1B_091 B Mafic DD 7.4 <0.1 <0.1 0.61ADML_1B_092 B Mafic DD --- --- --- 0.15ADML_1B_093 B Mafic DD 8.3 <0.1 <0.1 0.15ADML_1B_094 B Mafic DD --- --- --- 0.15ADML_1B_095 B Mafic DD --- --- --- 0.15ADML_1B_096 B Mafic DD --- --- --- 0.15ADML_1B_097 B Mafic DD --- --- --- 0.15ADML_1B_103 B Mafic DD --- --- --- 0.15ADML_1B_104 B Mafic DD --- --- --- 0.15ADML_1B_105 B Mafic DD --- --- --- 0.15ADML_1B_106 B Mafic DD --- --- --- 0.15ADML_1B_108 B Mafic DD --- --- --- 0.15ADML_1B_112 B Mafic DD --- --- --- 0.15ADML_1B_113 B Mafic DD 8.2 <0.1 <0.1 0.15ADML_1B_114 B Mafic DD 8.2 <0.1 <0.1 0.15ADML_1B_116 B Mafic DD --- --- --- 0.15ADML_1B_117 B Mafic DD 8.1 <0.1 <0.1 0.15ADML_1B_119 B Mafic DD --- --- --- 0.31ADML_1B_120 B Mafic DD --- --- --- 0.15ADML_1B_121 B Mafic DD --- --- --- 0.15ADML_1B_122 B Mafic DD --- --- --- 1.22ADML_1B_123 B Mafic DD --- --- --- 0.15ADML_1B_124 B Mafic DD --- --- --- 0.15ADML_1B_126 B Mafic DD 7.8 <0.1 <0.1 0.15ADML_1B_128 B Mafic DD --- --- --- 0.15ADML_1B_129 B Mafic DD --- --- --- 0.15ADML_1B_131 B Mafic DD --- --- --- 0.15ADML_1B_132 B Mafic DD 8.2 <0.1 <0.1 0.15ADML_1B_133 B Mafic DD 7.9 <0.1 <0.1 0.15ADML_1B_134 B Mafic DD --- --- --- 0.15ADML_1B_135 B Mafic DD --- --- --- 0.15ADML_1B_136 B Mafic DD --- --- --- 0.15ADML_1B_137 B Mafic DD --- --- --- 11.02ADML_1B_139 B Mafic DD 10 <0.1 <0.1 0.61ADML_1B_140 B Mafic DD --- --- --- 0.15ADML_1B_141 B Mafic DD --- --- --- 0.15ADML_1B_142 B Mafic DD --- --- --- 0.15ADML_1B_143 B Mafic DD 4.9 <0.1 1 0.15ADML_1B_144 B Mafic DD --- --- --- 0.15ADML_1B_146 B Mafic DD --- --- --- 0.15ADML_1B_150 B Mafic DD 7.3 <0.1 <0.1 1.84ADML_1B_151 B Mafic DD --- --- --- 0.15ADML_1B_152 B Mafic DD --- --- --- 0.15ADML_1B_153 B Mafic DD --- --- --- 0.15ADML_1B_154 B Mafic DD --- --- --- 0.15ADML_1B_155 B Mafic DD --- --- --- 0.15





ADML_1B_157 B Mafic DD --- --- --- 0.15ADML_1B_158 B Mafic DD --- --- --- 0.15ADML_1B_159 B Mafic DD 6.1 <0.1 0.6 0.15ADML_1B_160 B Mafic DD --- --- --- 0.15ADML_1B_161 B Mafic DD --- --- --- 0.15ADML_1B_162 B Mafic DD --- --- --- 0.15ADML_1B_163 B Mafic DD --- --- --- 0.15ADML_1B_164 B Mafic DD --- --- --- 0.15ADML_1B_167 B Mafic DD --- --- --- 0.15ADML_1B_168 B Mafic DD --- --- --- 0.15ADML_1B_169 B Mafic DD 5.6 <0.1 5.8 0.15ADML_1B_175 B Mafic DD --- --- --- 0.15ADML_1B_005 B Mafic DD --- --- --- 0.15ADML_1B_179 B Magnetite DD 9 <0.1 <0.1 0.61ADML_1B_180 B Magnetite DD 8.6 <0.1 <0.1 0.15ADML_1B_181 B Magnetite DD 8.6 <0.1 <0.1 0.15ADML_1B_222 B Magnetite DD 6.3 <0.1 0.4 0.15ADML_1B_002 B Ore DD --- --- --- 0.15ADML_1B_102 B Ore DD --- --- --- 0.15ADML_1B_109 B Ore DD --- --- --- 0.61ADML_1B_111 B Ore DD --- --- --- 0.15ADML_1B_115 B Ore DD 5.5 <0.1 0.8 0.61ADML_1B_118 B Ore DD 6.8 <0.1 0.3 0.15ADML_1B_125 B Ore DD 11.3 <0.1 <0.1 0.15ADML_1B_147 B Ore DD --- --- --- 0.15ADML_1B_171 B Ore DD 5.3 <0.1 0.7 0.15ADML_1B_173 B Ore DD 6.2 <0.1 <0.1 0.15ADML_1B_177 B Ore DD --- --- --- 0.15ADML_1B_178 B Ore DD 7.9 <0.1 <0.1 0.15ADML_1B_224 B Ore DD --- --- --- 0.15ADML_1B_110 B Ore Hi Al DD 8 <0.1 <0.1 3.67ADML_1B_127 B Ore Hi Al DD 8 <0.1 <0.1 0.15ADML_1B_145 B Ore Hi Al DD 0 0 0 0.15ADML_1B_145 B Ore Hi Al DD 6.5 <0.1 0.2 0.15ADML_1B_172 B Ore Hi Al DD 5.3 <0.1 1.7 0.15ADML_1B_182 B Ore Hi Al DD 6.6 <0.1 0.5 0.15ADML_1B_183 B Ore Hi Al DD 7.4 <0.1 <0.1 0.15ADML_1B_184 B Ore Hi Al DD 7.4 <0.1 <0.1 0.15ADML_1B_278 B Ore Hi Al RC 4.9 <0.1 1.9 1.53ADML_1B_279 B Ore Hi Al RC 5.9 <0.1 1 1.84ADML_1B_003 B Ore Hi SiO2 DD --- --- --- 5.81ADML_1B_004 B Ore Hi SiO2 DD --- --- --- 0.15ADML_1B_099 B Ore Hi SiO2 DD 5.3 <0.1 <0.1 0.15ADML_1B_101 B Ore Hi SiO2 DD --- --- --- 0.15ADML_1B_148 B Ore Hi SiO2 DD --- --- --- 0.15ADML_1B_170 B Ore Hi SiO2 DD --- --- --- 0.15ADML_1B_176 B Ore Hi SiO2 DD --- --- --- 0.15ADML_1B_220 B Ore Hi SiO2 DD --- --- --- 0.15ADML_1B_223 B Ore Hi SiO2 DD --- --- --- 0.15ADML_1B_001 Mafic DD 5 <0.1 0.8 0.15




Appendix 6: Solid Multi-Element Assay (Major Elements)


Major Element Concentrations

Zone Analyte Al Ca Fe K Mg Mn Na P S

B - Beebyn Units ppm ppm % ppm ppm ppm % ppm %

Mean Sediment M- Madoonga Comparative Abundance 72000 66000 4.1 20000 14000 770 0.57 0.067 0.22

SMC Sample ID Domain IDA13020 M BIF 4900 170 67.3 50 480 667 0.011 0.068 0.02

A13024 M BIF 1300 980 33.1 50 4770 1420 0.011 0.02 0.112

A13025 M BIF 3500 1290 35.9 50 6890 1280 0.011 0.039 0.085

A13028 M BIF 600 2080 17.7 50 7240 2740 0.012 0.029 0.153

A13029 M BIF 1300 3900 29.5 100 13500 8230 0.011 0.077 0.267

A13033 M BIF 1300 220 14.2 50 90 138 0.013 0.02 0.015

A13034 M BIF 9800 140 67.1 50 380 145 0.049 0.018 0.144

A13036 M BIF 800 2420 23.6 50 9830 4570 0.012 0.027 0.029

A13037 M BIF 1300 1770 31.9 200 7540 2710 0.017 0.064 0.739

A13049 M BIF 11400 260 64 50 370 182 0.009 0.22 0.09

A13050 M BIF 6900 130 42.9 50 270 85.5 0.011 0.046 0.085

A13051 M BIF 800 90 12.1 50 110 138 0.007 0.02 0.016

A13052 M BIF 6800 25 59 50 110 66.3 0.008 0.03 0.128

A13054 M BIF 34800 25 53.7 50 100 116 0.011 0.031 0.027

A13055 M BIF 7000 25 58.6 50 90 189 0.009 0.034 0.017

A13056 M BIF 1300 90 33.9 50 100 216 0.0025 0.012 0.109

A13057 M BIF 1700 100 29.3 50 220 245 0.006 0.036 0.267

A13059 M BIF 1400 6E+06 16.7 300 7900 3880 0.008 0.022 0.809

ADML_1B_012 M BIF 74800 300 29.7 300 300 1070 0.02 0.038 0.03

ADML_1B_014 M BIF 2400 100 31.2 100 100 364 0.01 0.059 0.01

ADML_1B_015 M BIF 600 900 25.6 100 5000 1700 0.0025 0.02 0.17

ADML_1B_016 M BIF 400 100 19.2 50 200 261 0.0025 0.005 0.05

ADML_1B_017 M BIF 200 100 24.4 50 2300 1620 0.0025 0.002 0.08

ADML_1B_018 M BIF 1300 100 44.1 50 200 604 0.01 0.091 0.01

ADML_1B_019 M BIF 800 100 19.4 50 100 208 0.0025 0.014 0.01

ADML_1B_021 M BIF 16000 100 20.1 50 100 155 0.0025 0.037 0.03

ADML_1B_022 M BIF 700 100 23.5 50 100 179 0.0025 0.049 0.01

ADML_1B_023 M BIF 3500 100 25 200 300 419 0.01 0.059 0.02

ADML_1B_047 M BIF 1000 100 21.2 50 50 93 0.0025 0.032 0.01

ADML_1B_074 M BIF 3700 200 11.1 100 100 76 0.01 0.015 0.01

ADML_1B_077 M BIF 500 100 14.35 50 200 582 0.0025 0.007 0.02

ADML_1B_187 M BIF 1300 100 2.68 100 100 202 0.01 0.008 0.005

ADML_1B_193 M BIF 13200 200 8.06 200 600 304 0.03 0.032 0.01

ADML_1B_204 M BIF 1600 200 3.31 100 100 151 0.01 0.01 0.01

ADML_1B_205 M BIF 1700 50 23 50 100 379 0.01 0.038 0.02

ADML_1B_211 M BIF 700 200 8.43 50 400 370 0.02 0.026 0.03

ADML_1B_213 M BIF 1700 300 28.6 100 200 230 0.0025 0.07 0.02

ADML_1B_214 M BIF 900 400 32.3 50 200 248 0.0025 0.064 0.01

ADML_1B_225 M BIF 600 100 9.22 50 50 78 0.0025 0.007 0.01

ADML_1B_227 M BIF 600 100 26.8 50 100 169 0.0025 0.06 0.005

ADML_1B_229 M BIF 700 200 6.96 50 100 127 0.0025 0.016 0.01

A13019 M Detrital 10300 1160 67.8 1300 810 124 0.142 0.047 0.091

A13030 M Detrital 48600 590 55.5 100 900 940 0.016 0.024 0.02

A13047 M Detrital 18100 100 56.4 50 720 2310 0.012 0.091 0.091

ADML_1B_010 M Detrital 21500 100 48.4 100 200 162 0.01 0.035 0.05

ADML_1B_024 M Detrital 99000 1400 20.7 300 1000 105 0.06 0.012 0.02

ADML_1B_027 M Detrital 10000 100 25 100 200 463 0.01 0.028 0.12

ADML_1B_035 M Detrital 24100 600 43.4 200 900 78 0.02 0.04 0.06

ADML_1B_036 M Detrital 27100 200 41.4 200 300 118 0.01 0.039 0.06

ADML_1B_037 M Detrital 47600 500 22.4 3300 600 366 0.03 0.03 0.02






SMC Sample ID Domain IDADML_1B_038 M Detrital 84100 5800 17 600 3800 250 0.07 0.011 0.01

ADML_1B_040 M Detrital 22500 100 25 200 300 1060 0.01 0.139 0.1

ADML_1B_041 M Detrital 6700 100 25 50 100 1140 0.01 0.077 0.05

ADML_1B_045 M Detrital 25400 100 25 300 100 182 0.01 0.105 0.08

ADML_1B_046 M Detrital 18300 200 48.7 400 100 61 0.01 0.062 0.08

ADML_1B_049 M Detrital 22200 200 45.8 800 200 636 0.01 0.071 0.05

ADML_1B_050 M Detrital 20500 300 25 100 400 1570 0.02 0.045 0.02

ADML_1B_051 M Detrital 56900 300 41.8 100 700 249 0.02 0.059 0.02

ADML_1B_060 M Detrital 92400 700 16 13900 1000 217 0.06 0.037 0.02

ADML_1B_061 M Detrital 68300 3200 22 500 3400 268 0.08 0.021 0.01

ADML_1B_062 M Detrital 63500 1300 23.1 700 1800 154 0.07 0.013 0.01

ADML_1B_063 M Detrital 73400 2200 15.35 1400 3200 832 0.23 0.025 0.01

ADML_1B_067 M Detrital 83700 4500 25.6 1200 2800 310 0.15 0.017 0.02

ADML_1B_068 M Detrital 61200 300 38.7 200 500 123 0.02 0.027 0.02

ADML_1B_206 M Detrital 52000 800 28.8 600 1600 220 0.03 0.017 0.02

ADML_1B_212 M Detrital 10400 100 25 50 100 715 0.0025 0.069 0.05

ADML_1B_215 M Detrital 25300 100 25 50 50 14 0.01 0.055 0.09

ADML_1B_216 M Detrital 28600 200 43 1000 200 25 0.01 0.047 0.12

ADML_1B_217 M Detrital 25700 100 48.6 100 100 97 0.01 0.05 0.07

ADML_1B_218 M Detrital 26100 100 48.8 300 100 67 0.01 0.072 0.14

ADML_1B_219 M Detrital 18600 300 43.6 200 200 1050 0.01 0.06 0.11

ADML_1B_032 M Felsic 71800 47300 8.68 1600 35000 1000 1.37 0.021 0.005

ADML_1B_033 M Felsic 66500 15900 9.1 1600 33200 1150 0.1 0.015 0.005

ADML_1B_034 M Felsic 68700 30200 8.85 1000 36300 1320 0.22 0.022 0.005

ADML_1B_257 M Felsic 64900 100 0.72 17500 1600 11 0.04 0.003 0.01

ADML_1B_258 M Felsic 53100 100 1.3 23900 1900 16 0.03 0.005 0.04

ADML_1B_259 M Felsic 77800 100 2.26 25300 2100 20 0.04 0.006 0.03

ADML_1B_260 M Felsic 52000 100 0.66 24600 2000 33 0.03 0.006 0.02

ADML_1B_261 M Felsic 71000 200 0.94 28300 2100 67 0.05 0.006 0.01

ADML_1B_262 M Felsic 55100 200 2.02 22700 1000 165 0.05 0.006 0.01

ADML_1B_265 M Felsic 36300 300 0.62 14400 1200 59 0.04 0.008 0.03

ADML_1B_270 M Felsic 57400 100 0.61 23900 2000 10 0.04 0.004 0.03

A13021 M Hydrated 9300 180 61.7 50 360 134 0.017 0.032 0.087

A13023 M Hydrated 4600 100 68.7 50 180 204 0.01 0.02 0.085

A13035 M Hydrated 8800 250 65 50 600 193 0.203 0.148 0.138

A13053 M Hydrated 14500 25 49 50 50 71.8 0.008 0.08 0.089

ADML_1B_043 M Hydrated 1400 100 3.65 50 100 114 0.01 0.008 0.005

ADML_1B_044 M Hydrated 1800 100 3.48 100 100 138 0.01 0.006 0.005

ADML_1B_048 M Hydrated 2300 100 26.2 50 200 248 0.01 0.08 0.01

ADML_1B_075 M Hydrated 3200 200 17.65 100 200 2120 0.01 0.017 0.02

ADML_1B_076 M Hydrated 11900 200 8.51 800 200 159 0.01 0.041 0.01

ADML_1B_078 M Hydrated 400 200 30.9 50 200 242 0.0025 0.076 0.01

ADML_1B_226 M Hydrated 6600 200 12.85 50 200 108 0.0025 0.037 0.02

ADML_1B_228 M Hydrated 500 100 4.97 50 100 200 0.0025 0.012 0.005

ADML_1B_241 M Hydrated 51200 2500 20.6 3700 2300 1090 0.12 0.027 0.02

ADML_1B_242 M Hydrated 83800 3000 9.89 1800 2900 597 0.18 0.009 0.01

ADML_1B_243 M Hydrated 2600 1000 24.6 300 5100 1980 0.02 0.017 0.48

ADML_1B_244 M Hydrated 4000 200 18.8 400 200 122 0.02 0.024 0.01

ADML_1B_245 M Hydrated 2800 700 9.35 50 4000 2390 0.01 0.006 0.02

ADML_1B_246 M Hydrated 800 100 8.44 100 200 979 0.01 0.008 0.06






SMC Sample ID Domain IDADML_1B_247 M Hydrated 5000 100 26.4 50 100 256 0.01 0.018 0.17

ADML_1B_248 M Hydrated 500 50 4.4 100 50 56 0.0025 0.005 0.01

ADML_1B_249 M Hydrated 6200 200 22.9 200 100 164 0.01 0.022 7.6

ADML_1B_250 M Hydrated 700 1300 12.2 100 5900 4300 0.01 0.007 0.19

ADML_1B_251 M Hydrated 300 100 12 50 100 140 0.01 0.009 0.04

ADML_1B_252 M Hydrated 114500 200 19.15 14600 1300 321 0.04 0.018 0.02

ADML_1B_254 M Hydrated 1200 200 28.4 200 300 323 0.01 0.052 0.03

ADML_1B_255 M Hydrated 4000 200 24.4 400 200 78 0.01 0.056 0.02

ADML_1B_256 M Hydrated 900 200 10.9 100 100 131 0.01 0.019 0.01

ADML_1B_271 M Hydrated 77200 100 8.17 16900 800 876 0.06 0.026 0.01

ADML_1B_272 M Hydrated 79200 400 14.3 5600 600 1700 0.05 0.027 0.01

ADML_1B_273 M Hydrated 1900 100 21.4 200 100 185 0.01 0.019 0.01

A13022 M Mafic 9700 140 63.2 50 360 153 0.014 0.037 0.064

A13031 M Mafic 120000 600 13.2 200 790 255 0.043 0.03 0.012

A13032 M Mafic 77700 630 18.8 1700 1010 422 0.04 0.061 0.012

A13048 M Mafic 123000 270 26.3 1400 1290 893 0.023 0.06 0.016

ADML_1B_009 M Mafic 97900 500 14.1 200 700 57 0.02 0.016 0.01

ADML_1B_011 M Mafic 120000 400 12.1 500 500 29 0.05 0.004 0.01

ADML_1B_025 M Mafic 79900 1000 17.75 400 2300 214 0.05 0.041 0.01

ADML_1B_026 M Mafic 75200 500 10.95 300 900 292 0.12 0.033 0.02

ADML_1B_039 M Mafic 96300 500 25.1 5700 1000 573 0.03 0.023 0.01

ADML_1B_056 M Mafic 58900 100 15.35 100 58500 1310 0.05 0.024 0.53

ADML_1B_069 M Mafic 74700 31700 8.53 3500 24300 762 1.83 0.018 0.005

ADML_1B_070 M Mafic 72000 64100 7.89 3000 46700 1480 2.04 0.023 0.04

ADML_1B_071 M Mafic 74500 55900 7.46 8500 55100 1480 1.71 0.022 0.02

ADML_1B_191 M Mafic 66500 100 13.15 100 78600 3830 0.01 0.03 0.01

ADML_1B_200 M Mafic 97900 200 27.1 100 500 673 0.01 0.075 0.01

ADML_1B_208 M Mafic 142500 300 6.67 5600 600 67 0.05 0.025 0.005

ADML_1B_237 M Mafic 32900 100 14.25 100 67700 930 0.08 0.007 0.17

ADML_1B_238 M Mafic 70900 1800 8.77 9400 18400 828 0.03 0.024 0.005

ADML_1B_008 M Ore 3300 100 25 100 500 291 0.02 0.027 0.08

ADML_1B_029 M Ore 7200 50 25 100 100 94 0.02 0.005 0.09

ADML_1B_031 M Ore 5300 100 25 100 200 284 0.01 0.074 0.07

ADML_1B_042 M Ore 5900 100 25 50 200 248 0.01 0.163 0.02

ADML_1B_054 M Ore 9400 200 25 50 300 206 0.01 0.046 0.13

ADML_1B_055 M Ore 5000 200 25 50 300 74 0.01 0.089 0.12

ADML_1B_057 M Ore 19200 50 25 50 300 27 0.01 0.056 0.15

ADML_1B_064 M Ore 8400 300 25 100 400 94 0.02 0.122 0.21

ADML_1B_066 M Ore 5000 100 25 100 300 82 0.03 0.045 0.11

ADML_1B_072 M Ore 9300 600 25 100 600 58 0.03 0.013 0.1

ADML_1B_188 M Ore 4000 200 25 300 100 493 0.02 0.054 0.01

ADML_1B_189 M Ore 2700 50 25 100 100 389 0.01 0.053 0.03

ADML_1B_192 M Ore 5900 100 25 100 300 29 0.02 0.006 0.05

ADML_1B_209 M Ore 15600 200 25 300 400 293 0.01 0.085 0.14

ADML_1B_210 M Ore 7000 100 25 100 200 110 0.01 0.037 0.09

ADML_1B_030 M Ore Hi Al 32800 100 40.8 400 100 556 0.03 0.062 0.01

ADML_1B_053 M Ore Hi Al 18700 300 25 100 200 516 0.01 0.109 0.06

ADML_1B_058 M Ore Hi Al 22400 100 25 50 500 127 0.01 0.044 0.03

ADML_1B_190 M Ore Hi Al 29800 50 25 100 50 858 0.01 0.209 0.06

ADML_1B_194 M Ore Hi Al 26100 100 25 3500 400 258 0.03 0.013 0.11






SMC Sample ID Domain IDADML_1B_195 M Ore Hi Al 38100 500 46.5 200 700 7490 0.02 0.097 0.02

ADML_1B_198 M Ore Hi Al 16800 100 25 200 300 341 0.01 0.098 0.07

ADML_1B_202 M Ore Hi Al 26700 400 47 400 800 87 0.03 0.057 0.03

ADML_1B_231 M Ore Hi Al 30800 100 45.3 2600 400 372 0.01 0.025 0.03

ADML_1B_234 M Ore Hi Al 24300 200 25 300 300 996 0.03 0.108 0.02

ADML_1B_235 M Ore Hi Al 18000 200 25 100 200 112 0.01 0.041 0.1

ADML_1B_236 M Ore Hi Al 6200 100 25 100 200 231 0.01 0.084 0.04

ADML_1B_013 M Ore Hi SiO2 11100 200 42.3 300 300 862 0.04 0.019 0.09

ADML_1B_020 M Ore Hi SiO2 8600 100 25 50 300 805 0.0025 0.089 0.005

ADML_1B_028 M Ore Hi SiO2 20600 100 25 100 300 51 0.02 0.018 0.12

ADML_1B_052 M Ore Hi SiO2 12000 200 25 100 100 373 0.01 0.099 0.02

ADML_1B_059 M Ore Hi SiO2 4400 100 25 50 200 348 0.0025 0.066 0.01

ADML_1B_065 M Ore Hi SiO2 8500 200 25 100 200 198 0.01 0.157 0.1

ADML_1B_073 M Ore Hi SiO2 7600 500 25 100 600 85 0.02 0.013 0.11

ADML_1B_196 M Ore Hi SiO2 5500 100 25 100 200 465 0.01 0.059 0.02

ADML_1B_199 M Ore Hi SiO2 700 100 18.6 50 100 195 0.0025 0.041 0.005

ADML_1B_201 M Ore Hi SiO2 15100 100 25 100 600 88 0.01 0.067 0.06

ADML_1B_203 M Ore Hi SiO2 11900 300 25 100 400 696 0.01 0.131 0.05

ADML_1B_207 M Ore Hi SiO2 9400 100 25 100 200 157 0.01 0.065 0.03

ADML_1B_230 M Ore Hi SiO2 6300 100 25 100 200 510 0.03 0.056 0.1

ADML_1B_232 M Ore Hi SiO2 17100 200 25 100 100 743 0.01 0.075 0.01

ADML_1B_233 M Ore Hi SiO2 9100 100 25 100 100 14 0.01 0.066 0.14

A13026 M Shale 74400 12900 7.9 24600 14300 1290 0.091 0.024 1.2

A13027 M Shale 46900 56600 12.3 9600 33200 3990 0.044 0.026 1.46

A13038 M Shale 68200 60900 6.44 20300 15400 1040 0.036 0.018 1.16

A13039 M Shale 62300 84900 8.07 13700 16900 1830 0.026 0.021 2.21

A13058 M Shale 75500 160 9 21000 870 478 0.056 0.031 0.013

ADML_1B_274 M Shale 66800 100 7.47 14700 29400 393 0.02 0.007 2.82

ADML_1B_275 M Shale 73900 200 6.31 18200 19800 364 0.03 0.008 0.38

ADML_1B_276 M Shale 72300 100 7.57 19600 17400 318 0.03 0.005 2.62

ADML_1B_277 M Shale 53100 100 12.45 700 26200 905 0.01 0.006 1.78

ADML_1B_280 M Shale 86700 200 23.5 100 700 159 0.07 0.013 0.005

ADML_1B_281 M Shale 66600 100 15.1 100 60600 1420 0.01 0.012 0.11

ADML_1B_282 M Shale 110000 500 18.8 200 600 570 0.04 0.103 0.39

ADML_1B_283 M Shale 79400 300 8.18 13300 2300 195 0.05 0.052 0.01

ADML_1B_284 M Shale 74200 300 8.19 14500 500 221 0.06 0.054 0.06

ADML_1B_285 M Shale 116500 300 19.35 15800 700 259 0.06 0.131 0.01

ADML_1B_286 M Shale 110500 400 23.3 15700 900 148 0.07 0.078 0.03

ADML_1B_287 M Shale 119500 400 16.6 3600 500 783 0.04 0.113 0.01

ADML_1B_288 M Shale 132500 300 15.05 22300 800 97 0.08 0.122 0.02

A13003 B BIF 5700 120 41.9 50 140 188 0.014 0.119 0.038

A13004 B BIF 2200 150 42.5 50 210 217 0.019 0.06 0.031

A13005 B BIF 7100 200 62.9 50 280 212 0.015 0.167 0.018

A13006 B BIF 11600 180 58.9 50 230 262 0.013 0.118 0.029

A13011 B BIF 30800 410 52.5 1400 10700 1010 0.019 0.091 0.01

A13013 B BIF 10500 26000 58.8 100 20500 132 0.014 0.015 0.01

A13014 B BIF 5300 23100 63 50 15000 772 0.014 0.077 0.014

A13015 B BIF 7400 31200 57.1 50 21600 1550 0.012 0.083 0.015

A13016 B BIF 4800 11900 67.6 50 9060 929 0.014 0.107 0.515

A13042 B BIF 9300 9090 72.9 50 6190 138 0.011 0.032 0.016






SMC Sample ID Domain IDA13043 B BIF 9600 17200 66.3 50 10800 85.5 0.014 0.023 0.01

A13044 B BIF 7400 690 69 50 810 293 0.009 0.044 0.008

ADML_1B_083 B BIF 2400 100 33.8 100 100 56 0.0025 0.015 0.005

ADML_1B_084 B BIF 1900 100 32.7 100 200 69 0.0025 0.022 0.005

ADML_1B_098 B BIF 2700 500 29.9 100 900 127 0.03 0.039 0.01

ADML_1B_100 B BIF 1200 100 37.6 50 200 109 0.01 0.051 0.01

ADML_1B_107 B BIF 8000 300 27.3 100 300 168 0.01 0.053 0.01

ADML_1B_130 B BIF 44700 8400 42.8 100 2000 218 0.02 0.074 0.01

ADML_1B_138 B BIF 15000 100 25 300 300 89 0.01 0.064 0.08

ADML_1B_138 B BIF 60800 300 5.19 6400 700 19 0.03 0.003 0.01

ADML_1B_149 B BIF 72900 47200 8.98 3700 38300 1230 1.16 0.028 0.005

ADML_1B_156 B BIF 79900 24200 9.23 3200 24400 786 2.21 0.019 0.01

ADML_1B_174 B BIF 6100 95200 25.7 200 52100 2170 0.01 0.065 0.005

ADML_1B_185 B BIF 3000 100 28.6 50 100 70 0.01 0.038 0.03

ADML_1B_186 B BIF 1800 100 30.6 50 100 54 0.01 0.016 0.01

ADML_1B_197 B BIF 23100 300 25 100 500 2180 0.01 0.067 0.02

ADML_1B_221 B BIF 3500 100 37.1 100 100 221 0.01 0.109 0.01

A13001 B Mafic 105000 1690 11.4 12500 11900 317 0.081 0.013 0.03

A13002 B Mafic 86500 520 12.4 13600 3430 677 0.046 0.024 0.022

A13007 B Mafic 89800 300 13.1 3500 33000 244 0.028 0.046 0.023

A13008 B Mafic 95600 180 8.14 20200 29700 314 0.048 0.018 0.157

A13009 B Mafic 135000 660 16.3 3600 1880 93.7 0.069 0.004 0.039

A13010 B Mafic 100000 850 13.8 300 105000 5790 0.038 0.028 0.011

A13012 B Mafic 111000 1350 13.3 200 140000 1570 0.014 0.048 0.041

A13017 B Mafic 87200 3000 17.7 50 111000 1460 0.013 0.031 0.034

A13018 B Mafic 72900 62000 11 10200 35200 1710 2.03 0.03 0.102

A13040 B Mafic 101000 1520 13.5 400 2780 5280 0.043 0.024 0.018

A13041 B Mafic 110000 1390 13.3 300 124000 1550 0.021 0.016 0.023

A13045 B Mafic 94200 2660 17.1 200 90200 959 0.03 0.039 0.007

A13046 B Mafic 79700 6390 12.5 1600 66000 898 0.563 0.025 0.082

ADML_1B_006 B Mafic 75400 900 11.45 200 72700 1060 0.02 0.02 0.005

ADML_1B_007 B Mafic 88600 1100 14.75 100 33500 544 0.03 0.033 0.005

ADML_1B_079 B Mafic 97700 500 13.25 7300 900 332 0.06 0.021 0.005

ADML_1B_080 B Mafic 80600 100 13.4 3600 48400 891 0.03 0.006 0.005

ADML_1B_081 B Mafic 85200 400 12.45 500 800 188 0.03 0.034 0.005

ADML_1B_082 B Mafic 96100 300 14.35 300 900 334 0.01 0.037 0.01

ADML_1B_085 B Mafic 66200 59400 7.73 1800 62600 1190 0.59 0.028 0.01

ADML_1B_086 B Mafic 85600 3300 11.15 1200 8400 241 0.08 0.007 0.01

ADML_1B_087 B Mafic 88900 24100 9.81 26500 26400 1540 1.27 0.032 0.005

ADML_1B_088 B Mafic 78000 600 9.44 12800 1300 98 0.05 0.056 0.005

ADML_1B_089 B Mafic 79900 1400 11.15 500 116500 1230 0.01 0.038 0.04

ADML_1B_090 B Mafic 88800 1600 13.9 200 121000 1230 0.02 0.051 0.005

ADML_1B_091 B Mafic 64400 1400 9.87 200 85100 1410 0.01 0.047 0.01

ADML_1B_092 B Mafic 92600 3500 11.95 1200 8900 234 0.09 0.008 0.01

ADML_1B_093 B Mafic 91300 16400 8.85 4100 30400 2780 2.48 0.013 0.005

ADML_1B_094 B Mafic 76600 58500 9.08 5800 57100 1440 1.03 0.023 0.01

ADML_1B_095 B Mafic 63900 10400 7.71 1100 41100 829 0.74 0.004 0.005

ADML_1B_096 B Mafic 65100 32500 5.73 3900 52800 687 2.33 0.009 0.005

ADML_1B_097 B Mafic 77800 500 12.35 15500 2600 716 0.05 0.028 0.005

ADML_1B_103 B Mafic 73800 300 12.6 2700 21800 183 0.02 0.044 0.005






SMC Sample ID Domain IDADML_1B_104 B Mafic 67500 200 8.68 5900 54300 376 0.02 0.01 0.005

ADML_1B_105 B Mafic 73600 10700 11.2 200 2700 231 0.03 0.019 0.005

ADML_1B_106 B Mafic 51800 300 12.5 100 2000 2910 0.01 0.008 0.005

ADML_1B_108 B Mafic 93700 300 12.95 700 800 108 0.03 0.024 0.01

ADML_1B_112 B Mafic 94200 500 25.9 100 1600 769 0.02 0.113 0.01

ADML_1B_113 B Mafic 61200 900 16.55 300 79300 919 0.02 0.024 0.005

ADML_1B_114 B Mafic 70000 36900 7.91 3900 39500 1620 2.66 0.032 0.005

ADML_1B_116 B Mafic 102000 2500 22.5 100 1800 493 0.08 0.053 0.005

ADML_1B_117 B Mafic 68800 500 13.6 100 71700 1310 0.02 0.017 0.01

ADML_1B_119 B Mafic 104000 1700 11.1 1500 7700 132 0.19 0.016 0.02

ADML_1B_120 B Mafic 72000 30800 9.37 2700 32500 1190 2.2 0.026 0.005

ADML_1B_121 B Mafic 87100 7000 10.3 3100 21000 729 0.99 0.017 0.005

ADML_1B_122 B Mafic 74600 55700 8.24 6500 46200 1450 1.29 0.022 0.05

ADML_1B_123 B Mafic 104000 3900 15.15 100 2400 1830 0.06 0.016 0.01

ADML_1B_124 B Mafic 75300 1500 11 1100 49500 963 0.05 0.019 0.005

ADML_1B_126 B Mafic 65400 800 11.5 100 85300 1190 0.02 0.014 0.005

ADML_1B_128 B Mafic 77100 1900 14.05 400 94500 1380 0.02 0.042 0.01

ADML_1B_129 B Mafic 109000 800 13.3 400 1000 193 0.02 0.018 0.01

ADML_1B_131 B Mafic 55700 2900 8.16 300 60500 823 0.04 0.006 0.005

ADML_1B_132 B Mafic 37100 7100 8.76 100 128500 766 0.02 0.015 0.005

ADML_1B_133 B Mafic 33900 12400 7.69 100 131500 850 0.02 0.014 0.005

ADML_1B_134 B Mafic 60600 3500 7.13 600 43000 557 1.14 0.006 0.01

ADML_1B_135 B Mafic 92300 1800 14.9 9700 8400 1490 0.04 0.039 0.01

ADML_1B_136 B Mafic 66600 1300 9.53 1000 39200 748 0.04 0.022 0.005

ADML_1B_137 B Mafic 105000 100 11.7 2800 500 35 0.02 0.006 0.4

ADML_1B_139 B Mafic 101500 20200 13.15 2200 1700 74 0.13 0.019 0.03

ADML_1B_140 B Mafic 116500 600 10.85 4100 1400 133 0.02 0.009 0.01

ADML_1B_141 B Mafic 66900 57300 6.71 6100 45800 979 1.23 0.013 0.005

ADML_1B_142 B Mafic 56000 53400 6.85 3100 57100 996 0.95 0.021 0.005

ADML_1B_143 B Mafic 112000 500 18 3700 700 267 0.06 0.04 0.03

ADML_1B_144 B Mafic 43200 500 46.4 200 1100 2940 0.02 0.073 0.03

ADML_1B_146 B Mafic 1000 100 31.2 200 100 75 0.0025 0.033 0.01

ADML_1B_150 B Mafic 73800 66300 7.87 2200 44100 1340 1.09 0.023 0.07

ADML_1B_151 B Mafic 69300 53900 8.56 5900 49300 1320 1.34 0.022 0.01

ADML_1B_152 B Mafic 62100 38600 9.88 7600 16700 1360 2.23 0.13 0.005

ADML_1B_153 B Mafic 110000 2400 6.3 800 15700 253 0.17 0.007 0.01

ADML_1B_154 B Mafic 37100 700 27.8 200 900 219 0.03 0.031 0.01

ADML_1B_155 B Mafic 110500 1700 18.1 400 1800 135 0.09 0.013 0.02

ADML_1B_157 B Mafic 75400 62900 7.96 1900 43300 1330 1.7 0.023 0.01

ADML_1B_158 B Mafic 95500 4600 7.69 1700 20700 472 0.34 0.007 0.01

ADML_1B_159 B Mafic 104000 800 7.16 100 600 65 0.04 0.005 0.01

ADML_1B_160 B Mafic 91700 12600 7.29 1300 25200 655 1.46 0.009 0.01

ADML_1B_161 B Mafic 71300 36500 9.66 1200 32200 1000 2.25 0.014 0.005

ADML_1B_162 B Mafic 101000 900 23.5 100 900 311 0.06 0.016 0.005

ADML_1B_163 B Mafic 18000 700 48.9 100 1200 256 0.03 0.041 0.005

ADML_1B_164 B Mafic 69500 41300 6.81 8800 41000 1450 2.54 0.023 0.005

ADML_1B_167 B Mafic 84400 4300 10.5 4600 54700 2140 0.81 0.009 0.005

ADML_1B_168 B Mafic 75000 51300 8.71 2100 40700 1480 1.79 0.027 0.005

ADML_1B_169 B Mafic 5600 200 37.3 100 700 156 0.01 0.059 0.01

ADML_1B_175 B Mafic 79400 900 20.2 100 64100 673 0.01 0.008 0.005






SMC Sample ID Domain IDADML_1B_005 B Mafic 98900 800 15.4 200 2100 386 0.02 0.082 0.01

ADML_1B_179 B Magnetite 2300 33800 25 50 18700 1790 0.01 0.108 0.03

ADML_1B_180 B Magnetite 4700 15300 49.8 50 9800 151 0.01 0.085 0.005



ADML_1B_002 B Ore 3100 200 25 100 500 2270 0.01 0.062 0.01

ADML_1B_102 B Ore 5000 300 25 100 400 379 0.01 0.167 0.005

ADML_1B_109 B Ore 10800 200 25 100 900 108 0.01 0.056 0.02

ADML_1B_111 B Ore 3800 200 25 50 700 789 0.01 0.045 0.01

ADML_1B_115 B Ore 16300 300 39.9 200 900 501 0.01 0.022 0.02

ADML_1B_118 B Ore 4800 200 37.7 50 400 95 0.01 0.062 0.005

ADML_1B_125 B Ore 3700 21600 39.3 50 12400 165 0.01 0.023 0.005

ADML_1B_147 B Ore 67500 55900 9.38 5400 55000 1390 0.94 0.024 0.01

ADML_1B_171 B Ore 2800 100 25 50 400 529 0.0025 0.051 0.005

ADML_1B_173 B Ore 7600 100 25 50 300 337 0.0025 0.075 0.01

ADML_1B_177 B Ore 2600 200 25 100 700 258 0.0025 0.074 0.005

ADML_1B_178 B Ore 2100 4000 25 100 2500 221 0.01 0.079 0.005

ADML_1B_224 B Ore 20500 400 34 100 500 312 0.01 0.058 0.005

ADML_1B_110 B Ore Hi Al 32100 1300 48 600 1000 567 0.02 0.076 0.12

ADML_1B_127 B Ore Hi Al 22000 700 25 100 1100 275 0.01 0.071 0.005

ADML_1B_145 B Ore Hi Al 7800 300 25 100 900 891 0.01 0.076 0.03

ADML_1B_145 B Ore Hi Al 2300 100 39.6 100 200 150 0.0025 0.108 0.01

ADML_1B_172 B Ore Hi Al 29000 300 25 100 1400 1540 0.01 0.132 0.01

ADML_1B_182 B Ore Hi Al 44200 500 37.2 50 600 448 0.01 0.146 0.01

ADML_1B_183 B Ore Hi Al 22100 500 39.5 200 1000 10350 0.02 0.028 0.01

ADML_1B_184 B Ore Hi Al 41200 4600 39.2 100 2900 319 0.02 0.092 0.005

ADML_1B_278 B Ore Hi Al 56000 200 43.6 400 300 75 0.01 0.026 0.04

ADML_1B_279 B Ore Hi Al 56800 200 47.5 100 700 110 0.03 0.026 0.07

ADML_1B_003 B Ore Hi SiO2 6900 31400 49.6 1100 19700 802 0.03 0.069 0.16

ADML_1B_004 B Ore Hi SiO2 6000 1600 25 400 2900 1170 0.01 0.084 0.01

ADML_1B_099 B Ore Hi SiO2 9500 100 25 100 200 152 0.01 0.115 0.01

ADML_1B_101 B Ore Hi SiO2 1800 100 25 100 100 78 0.01 0.093 0.01

ADML_1B_148 B Ore Hi SiO2 69500 49900 8.82 700 45200 1400 2.33 0.021 0.01

ADML_1B_170 B Ore Hi SiO2 3900 500 25 100 500 219 0.01 0.065 0.01

ADML_1B_176 B Ore Hi SiO2 5400 19500 25 300 12500 633 0.02 0.084 0.01

ADML_1B_220 B Ore Hi SiO2 2200 100 25 100 200 162 0.0025 0.113 0.02

ADML_1B_223 B Ore Hi SiO2 1600 800 44.7 100 800 315 0.01 0.056 0.005

ADML_1B_001 Mafic 111500 1100 16.85 300 900 98 0.06 0.008 0.01



Appendix 7: Solid Multi-Element Assay (Minor Elements)


Minor Element Concentrations

Zone Analyte Ag As Be Cd Co Cr Cs Cu Ga Ge Hf Hg In La Li Nb Ni Pb

B - Beebyn Units ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm

Mean Sediment M- MadoongaComparative Abundance 0.057 7.7 2 0.17 14 72 72 33 18 1.7 2.5 0.19 1.6 41 56 13 52 19

SMC Sample ID Domain IDA13020 M BIF 0.6 57 0.4 0.05 11.3 50 - 67 - - - 0.2 - - 0.8 1.5 21 22A13024 M BIF 0.05 11 0.2 0.05 1.6 5 - 2.5 - - - 0.05 - - 1 0.4 2.5 2A13025 M BIF 0.05 7 0.4 0.05 4 20 - 7 - - - 0.1 - - 3.8 0.5 12 3A13028 M BIF 0.1 4 0.4 0.6 21.2 5 - 45 - - - 0.05 - - 0.7 1.4 9 3A13029 M BIF 0.05 5 0.4 0.05 4 5 - 2.5 - - - 0.05 - - 0.3 0.1 24 3A13033 M BIF 0.2 25 0.5 0.05 2.9 10 - 18 - - - 0.05 - - 4.1 0.1 9 4A13034 M BIF 1.7 249 0.2 0.05 5.5 270 - 160 - - - 0.3 - - 0.4 2.4 2.5 18A13036 M BIF 0.05 4 0.3 0.05 1.2 20 - 2.5 - - - 0.05 - - 1.1 0.6 8 7A13037 M BIF 0.1 10 0.6 0.05 5 5 - 9 - - - 0.1 - - 0.2 1.3 9 4A13049 M BIF 0.3 555 0.6 0.05 12.3 450 - 168 - - - 0.2 - - 0.7 1.9 18 38A13050 M BIF 0.7 73 0.05 0.05 2.9 30 - 235 - - - 0.1 - - 1.3 0.6 2.5 12A13051 M BIF 0.05 10 0.5 0.05 1 20 - 13 - - - 0.05 - - 1.9 0.1 2.5 7A13052 M BIF 1.1 230 0.05 0.05 3.8 260 - 166 - - - 0.2 - - 0.2 2.1 2.5 19A13054 M BIF 0.05 20 0.4 0.05 5.9 150 - 59 - - - 0.05 - - 0.7 1.8 14 29A13055 M BIF 0.05 12 0.6 0.05 6.1 60 - 20 - - - 0.05 - - 0.3 3.7 9 35A13056 M BIF 0.2 6 0.4 0.1 1.9 5 - 2.5 - - - 0.05 - - 0.6 0.2 2.5 75A13057 M BIF 0.05 11 0.4 0.05 4.2 5 - 22 - - - 0.05 - - 0.5 0.1 6 4A13059 M BIF 0.05 3 0.4 0.05 4.6 10 - 29 - - - 0.05 - - 0.3 0.1 17 3ADML_1B_012 M BIF 0.07 368 0.35 0.01 7.8 180 0.24 139.5 20.3 1.12 3.4 0.05 0.10 2.6 34.9 5.7 70.2 24.7ADML_1B_014 M BIF 0.06 65.3 0.31 0.03 5 17 0.08 39.6 0.64 0.31 0.1 0.015 0.00 1.7 2.2 0.6 24.6 4.6ADML_1B_015 M BIF 0.03 3.5 0.27 0.02 1.8 4 0.12 2.2 0.37 0.23 0.05 0.016 0.00 2.4 0.7 0.5 5.3 1.5ADML_1B_016 M BIF 0.05 4.1 0.21 0.01 2.1 5 0.05 6.3 0.29 0.24 0.05 0.038 0.00 2.8 0.7 0.6 3.3 1.4ADML_1B_017 M BIF 0.02 4 0.3 0.01 0.7 3 0.06 0.8 0.26 0.25 0.05 0.009 0.01 0.7 0.5 0.5 2.8 0.5ADML_1B_018 M BIF 0.14 29.2 0.66 0.07 23.6 22 0.07 26.3 0.6 0.41 0.05 0.017 0.02 11.7 0.5 0.7 69.7 6.6ADML_1B_019 M BIF 0.08 3.1 0.27 0.01 2 10 0.06 10.5 0.51 0.26 0.05 0.011 0.01 1.1 0.4 0.5 7.8 32.7ADML_1B_021 M BIF 0.21 10.1 0.56 0.01 1.7 188 0.07 69.5 4.11 0.29 0.6 0.02 0.03 3.1 2.2 1.5 41 6.9ADML_1B_022 M BIF 0.04 2.4 0.77 0.02 1.8 4 0.07 4 0.5 0.34 0.05 0.011 0.00 2.6 0.2 0.8 6.4 1.4ADML_1B_023 M BIF 0.13 7.6 1.14 0.01 3.1 6 0.11 22.7 0.99 0.51 0.1 0.009 0.01 17.9 0.5 1 12.4 5.3ADML_1B_047 M BIF 0.03 4.3 0.16 0.01 1.7 7 0.05 5.2 0.35 0.23 0.05 0.026 0.00 1.4 0.9 0.6 5.2 0.9ADML_1B_074 M BIF 0.06 12.1 0.21 0.01 1 27 0.025 10.6 1.07 0.13 0.2 0.037 0.01 3.8 3.8 0.5 5.5 2.7ADML_1B_077 M BIF 0.1 12.1 0.24 0.01 1.2 8 0.025 3.8 0.28 0.15 0.05 0.0025 0.01 1.5 0.2 0.4 4.8 1.1ADML_1B_187 M BIF 0.03 6.1 0.2 0.01 1.9 14 0.06 8.8 0.64 0.05 0.05 0.028 0.00 3.9 1.8 0.3 3.7 6.6ADML_1B_193 M BIF 0.1 20.8 0.17 0.01 2.1 75 0.06 22.7 1.45 0.11 0.5 0.025 0.01 11 11.8 0.7 11.4 22.2ADML_1B_204 M BIF 0.05 31.3 0.28 0.01 1.8 61 0.025 39.5 0.7 0.05 0.1 0.013 0.02 3.1 0.7 0.2 7.6 9_ _ADML_1B_205 M BIF 0.07 29.8 0.56 0.01 1.9 11 0.025 15.1 0.45 0.22 0.1 0.023 0.01 2.7 0.5 0.4 10.7 2.2ADML_1B_211 M BIF 0.1 86 0.31 0.02 5.2 15 0.025 14.8 0.73 0.07 0.05 0.094 0.01 2.8 0.9 0.3 18.5 3.6ADML_1B_213 M BIF 0.18 2.3 0.63 0.01 1.8 9 0.05 5.9 0.5 0.37 0.1 0.01 0.01 2.6 0.6 0.5 3.8 3.2ADML_1B_214 M BIF 0.08 2.3 0.62 0.01 1 12 0.025 4.3 0.8 0.41 0.1 0.005 0.01 3.4 0.2 0.5 2.3 6.5ADML_1B_225 M BIF 0.09 24 0.06 0.01 1.3 47 0.05 22.7 0.3 0.05 0.3 0.037 0.01 0.7 3.2 0.9 4 4.5ADML_1B_227 M BIF 0.22 2.6 0.5 0.01 1.1 5 0.07 4.9 0.68 0.39 0.05 0.005 0.00 1.1 0.4 0.7 9.5 3.9ADML_1B_229 M BIF 0.21 73.1 0.2 0.02 2.4 13 0.06 34 0.52 0.025 0.05 0.019 0.01 2.7 3.2 0.4 11 5A13019 M Detrital 0.1 98 0.4 0.05 6.5 70 - 20 - - - 0.1 - - 0.8 5.6 2.5 9A13030 M Detrital 0.3 70 0.3 0.05 21.2 290 - 11 - - - 0.05 - - 4.3 7.8 60 11A13047 M Detrital 0.2 210 0.5 0.05 23.3 460 - 68 - - - 0.2 - - 0.7 3.8 16 18ADML_1B_010 M Detrital 0.14 55.7 0.35 0.02 5.9 212 0.11 12.9 14.3 0.93 0.9 0.017 0.04 1.9 1.2 4.6 12.6 8.5ADML_1B_024 M Detrital 1.82 15.9 0.46 0.01 34.2 778 0.26 106 25.2 0.9 1.8 0.016 0.11 1.5 22.5 2.9 125 3.7ADML_1B_027 M Detrital 1.79 318 0.22 0.01 5.7 159 0.07 140 5.41 2.46 1.4 1.095 0.05 1 1 2.7 7.8 38.7ADML_1B_035 M Detrital 0.15 61.7 0.57 0.01 8.2 363 0.2 15.3 18.05 1.57 1.5 0.034 0.06 4.1 2.3 5.6 15.1 7.7ADML_1B_036 M Detrital 0.12 170.5 0.71 0.01 5 226 0.14 56.2 10.85 1.26 1.2 0.067 0.09 2.4 1.7 3.8 9.9 9.5ADML_1B_037 M Detrital 0.17 37.2 1.39 0.03 8.9 273 1.29 45.8 13.15 0.39 3.2 0.076 0.06 12.7 15.9 7 34.7 20.4ADML_1B_038 M Detrital 0.1 17.6 0.46 0.05 27.9 373 0.33 47.5 15.7 0.39 1.3 0.043 0.06 9.6 21.7 4.9 117 5.4ADML_1B_040 M Detrital 0.26 174 0.53 0.02 23.3 393 0.13 89.8 4.29 1.45 0.3 0.163 0.03 1.9 0.3 1.3 27 33ADML_1B_041 M Detrital 0.23 175 0.16 0.02 9.3 258 0.06 40.9 7.36 1.05 0.5 0.045 0.05 0.7 0.1 3.4 12.3 16.5ADML_1B_045 M Detrital 0.11 51.8 0.43 0.01 4.8 205 0.19 48.5 4.48 1.11 1.2 0.048 0.04 4 3.2 1.9 19.6 13.7ADML_1B_046 M Detrital 0.24 49.7 0.4 0.01 3.2 286 0.23 35.8 11.75 1.47 1.7 0.125 0.07 3.3 1.4 3.7 9.1 6.6ADML_1B_049 M Detrital 0.23 120 0.84 0.06 8.2 363 0.38 90.1 7.68 1.21 1.6 0.115 0.06 7 5.9 3.1 19.7 26.4ADML_1B_050 M Detrital 0.13 161.5 0.2 0.01 28 285 0.12 41.5 11 1.05 1 0.03 0.05 1.9 1.3 4.3 34.8 15.3ADML_1B_051 M Detrital 0.07 102.5 0.41 0.01 18.5 664 0.18 111 14.15 1.72 1.3 0.072 0.07 2.4 5.5 3.9 69 12.8ADML_1B_060 M Detrital 0.08 27.4 1 0.05 8.8 1030 0.71 110 20.5 0.57 5.9 0.024 0.08 16.5 10.7 10.4 166 16.2ADML_1B_061 M Detrital 0.09 13.3 0.62 0.01 16.6 348 1.43 47.5 14.3 0.47 1.6 0.047 0.06 5.6 24.9 4.9 68.2 25.1ADML_1B_062 M Detrital 0.04 15.6 0.57 0.01 13.1 426 0.51 39.7 14.35 0.43 1.5 0.012 0.06 3.9 10.9 4 61.2 7.5ADML_1B_063 M Detrital 0.13 24.8 0.51 0.02 61.8 270 0.93 201 19.15 0.47 1.9 0.039 0.07 7.4 11.4 3.9 54.8 8.5ADML_1B_067 M Detrital 0.04 44.8 0.8 0.03 33.3 395 0.52 49.8 19.5 1.2 1.3 0.019 0.07 8.5 22.1 4.8 103 10.9ADML_1B_068 M Detrital 0.09 45 0.35 0.01 24 858 0.14 86.8 12.1 1.49 1.2 0.021 0.07 1.8 7.7 3.2 87.4 6ADML_1B_206 M Detrital 0.1 34.7 0.62 0.01 10.6 690 0.36 48.3 15.6 0.34 1.5 0.012 0.07 10.6 5.9 2.3 43.1 11ADML_1B_212 M Detrital 0.2 116.5 0.24 0.02 9.9 911 0.025 19.7 25.6 1.19 1.1 0.02 0.06 1.3 0.3 10.5 10.8 57.2ADML_1B_215 M Detrital 0.28 136.5 0.2 0.01 0.9 623 0.06 154 11.6 1.5 1.3 0.041 0.10 1.4 0.3 2.8 2.7 10.9ADML_1B_216 M Detrital 0.2 139.5 0.35 0.01 1.9 197 0.44 73.4 6.74 1.76 1.2 0.012 0.04 4.3 2.1 2.8 7.3 8.4ADML_1B_217 M Detrital 0.24 55.7 0.49 0.01 3.7 368 0.13 81.4 9.76 1.66 1.4 0.033 0.08 3.1 1.8 2.6 16.5 12.3ADML_1B_218 M Detrital 0.32 197 0.73 0.01 2.6 498 0.19 84.4 13.35 1.73 1.5 0.044 0.09 3.6 0.9 5.2 6.3 15.8ADML_1B_219 M Detrital 0.17 540 0.79 0.01 1.4 420 0.1 234 7.82 1.36 0.9 0.01 0.31 2.2 0.5 2 22.1 16.5ADML_1B_032 M Felsic 0.04 3.6 0.17 0.07 45.7 333 0.29 92.8 14.1 0.3 0.8 0.055 0.05 1.6 17.9 1 128.5 1






SMC Sample ID Domain IDADML_1B_033 M Felsic 0.02 2.6 0.21 0.15 140.5 409 0.63 101.5 13.5 0.24 0.7 0.017 0.04 0.9 17.3 1 227 0.6ADML_1B_034 M Felsic 0.03 1.3 0.17 0.09 103.5 305 0.92 89.8 17.1 0.25 0.8 0.027 0.06 1.8 23.3 1 202 0.8ADML_1B_257 M Felsic 0.04 0.9 0.62 0.01 0.7 80 0.8 4.3 13 0.025 4.4 0.0025 0.04 7.1 2 8.3 5.3 7.3ADML_1B_258 M Felsic 0.03 1.9 0.69 0.01 1.2 64 0.89 7 11.8 0.025 4.2 0.008 0.03 18.6 1.6 7.4 8.8 20.6ADML_1B_259 M Felsic 0.08 7.7 0.76 0.01 1.6 127 1.31 13.6 16.45 0.025 6 0.0025 0.04 11.3 3.7 7.5 24 19ADML_1B_260 M Felsic 0.02 1.9 0.74 0.01 0.8 45 0.95 5.8 14.45 0.025 3.7 0.009 0.03 12.2 1.2 6.5 10.1 11ADML_1B_261 M Felsic 0.04 1.5 0.73 0.01 0.9 54 1.14 15.2 16.8 0.025 5.2 0.008 0.05 8.2 2.2 7.5 10.2 11.3ADML_1B_262 M Felsic 0.04 2.9 0.81 0.01 1.6 45 0.79 10.8 12.95 0.025 4.5 0.0025 0.03 6.1 1.2 6.7 4.1 7.5ADML_1B_265 M Felsic 0.03 0.7 0.65 0.01 0.8 112 0.66 4.5 8.56 0.025 2.9 0.0025 0.02 23.2 1.4 5.2 3.8 16.1ADML_1B_270 M Felsic 0.05 1.4 0.72 0.01 1.2 62 0.97 4.8 13.45 0.05 4 0.006 0.03 22.2 2.3 7.6 11.7 37.4A13021 M Hydrated 0.5 449 0.2 0.05 3.9 240 - 124 - - - 0.3 - - 0.4 4.6 2.5 19A13023 M Hydrated 0.2 308 0.05 0.05 3.1 120 - 249 - - - 0.4 - - 0.2 2.5 2.5 10A13035 M Hydrated 0.6 122 0.5 0.05 3.5 280 - 71 - - - 0.6 - - 0.4 2.3 39 10A13053 M Hydrated 0.5 121 0.3 0.2 8.6 1080 - 276 - - - 0.05 - - 1.2 19.9 2.5 18ADML_1B_043 M Hydrated 0.02 5.3 0.32 0.01 2.1 27 0.025 13.3 0.46 0.05 0.05 0.032 0.00 1.1 1.2 0.4 4.7 1.3ADML_1B_044 M Hydrated 0.02 2.2 0.49 0.01 2.2 11 0.05 7 0.67 0.05 0.1 0.013 0.00 1.6 1.5 0.4 4.9 1ADML_1B_048 M Hydrated 0.03 26 0.81 0.02 5.1 16 0.06 17.4 1.12 0.26 0.1 0.01 0.02 3.6 1.1 0.5 39.1 0.8ADML_1B_075 M Hydrated 0.5 10.2 0.58 0.04 11.5 43 0.07 28.6 1.21 0.19 0.2 0.05 0.01 6.7 0.8 0.7 32.4 2.6ADML_1B_076 M Hydrated 0.38 7.4 0.84 0.01 5.1 73 0.12 51.1 2.53 0.1 0.5 0.012 0.02 11.8 3.4 0.8 30.1 11.2ADML_1B_078 M Hydrated 0.18 2.6 0.51 0.02 1.4 4 0.06 3.5 0.34 0.37 0.05 0.011 0.01 2.2 0.3 0.4 8 2.2ADML_1B_226 M Hydrated 0.06 14.6 0.3 0.01 2 36 0.06 19.2 1.3 0.11 0.3 0.053 0.02 1.8 1 0.5 6.3 3.9ADML_1B_228 M Hydrated 0.03 4.5 0.08 0.01 0.8 25 0.025 18.2 0.39 0.025 0.05 0.009 0.01 0.25 4.6 0.2 2.2 0.8ADML_1B_241 M Hydrated 0.07 22.8 1.16 0.16 23 356 1.5 62.9 15.35 0.13 2.2 0.021 0.07 26.6 11.2 4.7 74.3 18.9ADML_1B_242 M Hydrated 0.04 6.5 0.46 0.05 71.8 354 1.77 64.9 18.4 0.13 1.8 0.011 0.06 18.2 15.3 5.4 143 6.3ADML_1B_243 M Hydrated 0.04 18.1 0.16 0.01 3.2 85 0.12 10.1 0.92 0.11 0.1 0.029 0.01 2 1.1 0.3 14.7 1.9ADML_1B_244 M Hydrated 0.05 20.5 0.17 0.01 3.9 127 0.13 15 1.59 0.08 0.1 0.047 0.02 2.1 1.1 0.4 12.9 4ADML_1B_245 M Hydrated 0.02 0.3 0.13 0.01 1.3 60 0.05 5.9 0.42 0.025 0.1 0.02 0.01 2.7 0.8 0.2 8.8 0.5ADML_1B_246 M Hydrated 1 6.3 0.14 0.01 2.8 165 0.1 19.8 0.38 0.025 0.05 0.45 0.01 1 0.8 0.1 8.5 0.9ADML_1B_247 M Hydrated 0.18 0.8 0.36 0.02 1.7 113 0.06 283 0.27 0.13 0.05 0.079 0.00 1 1.4 0.3 10.5 1.3ADML_1B_248 M Hydrated 0.43 28 0.06 0.01 1.1 240 0.08 13.5 0.29 0.025 0.05 0.009 0.01 0.5 0.6 0.2 3.4 2.3ADML_1B_249 M Hydrated 0.76 62.3 0.33 0.1 8.4 80 0.15 33.6 1.65 0.1 0.2 0.075 0.05 3.4 0.5 0.4 32.5 38.6ADML_1B_250 M Hydrated 0.05 4.6 0.26 0.04 2 182 0.08 4.6 0.39 0.025 0.05 0.0025 0.00 2.7 0.3 0.2 4.5 2.3ADML_1B_251 M Hydrated 0.22 13 0.19 0.01 7.3 134 0.05 13.5 0.34 0.07 0.05 0.01 0.00 1.2 0.8 0.1 4 1.7ADML_1B_252 M Hydrated 0.15 261 0.48 0.04 18.6 2740 1.04 166 22.6 0.72 1.3 0.005 0.40 0.25 15.7 0.5 279 4.9_ _ yADML_1B_254 M Hydrated 0.16 4.3 0.33 0.01 1.3 118 0.12 6.3 0.37 0.14 0.05 0.0025 0.02 2 0.7 0.3 8.9 1.2ADML_1B_255 M Hydrated 0.08 9.2 0.29 0.01 1.7 189 0.12 7.3 1.07 0.12 0.1 0.005 0.02 5.2 1.3 0.5 12.8 1.7ADML_1B_256 M Hydrated 0.14 16.4 0.23 0.01 11.6 108 0.07 14.7 0.46 0.05 0.05 0.031 0.00 2.4 2.3 0.1 28.4 7.2ADML_1B_271 M Hydrated 0.52 12.7 1.91 0.05 42 711 0.9 130.5 21.4 0.09 4.5 0.0025 0.08 14.6 9.7 7.8 146.5 59.3ADML_1B_272 M Hydrated 0.05 5.7 0.91 0.11 37.1 461 0.39 64.3 13.35 0.16 1.5 0.0025 0.09 13.3 6.5 2.3 122 33.3ADML_1B_273 M Hydrated 0.09 6.8 0.28 0.01 1.5 85 0.05 5.5 0.56 0.13 0.1 0.007 0.01 6.8 1.7 0.2 5.7 2.1A13022 M Mafic 0.2 263 0.1 0.05 3.1 150 - 145 - - - 0.7 - - 0.2 3.1 11 14A13031 M Mafic 0.2 2 0.6 0.05 9.8 400 - 144 - - - 0.05 - - 40.7 4.9 181 8A13032 M Mafic 0.05 20 0.6 0.05 44.6 290 - 155 - - - 0.05 - - 18.8 3.1 147 7A13048 M Mafic 0.2 12 0.7 0.1 53.1 990 - 338 - - - 0.05 - - 12 18 446 8ADML_1B_009 M Mafic 0.04 29.7 0.33 0.02 9.5 470 0.17 187.5 18.45 0.23 1.3 0.026 0.07 1.3 11.7 2.3 83.2 3.3ADML_1B_011 M Mafic 0.07 6.1 0.17 0.01 4 359 0.18 63.9 23.3 0.49 1.5 0.018 0.06 0.25 7.5 3.1 50.7 3.3ADML_1B_025 M Mafic 0.05 13.2 0.64 0.02 37.5 461 0.42 271 16.6 0.69 1.2 0.016 0.07 2 13.5 2 130 2.7ADML_1B_026 M Mafic 0.05 4.7 0.37 0.08 27.7 382 0.2 112 13.35 0.32 1 0.012 0.05 1.4 32.3 1.8 95.1 1.6ADML_1B_039 M Mafic 0.05 47.9 0.42 0.02 17.3 425 0.71 118.5 18.75 2.11 1.3 0.024 0.08 6.9 13 2.2 78 11.4ADML_1B_056 M Mafic 0.64 284 1.16 0.6 89.2 918 0.16 158.5 24.2 0.86 5.2 0.026 0.09 24.2 60.4 6.9 802 7.7ADML_1B_069 M Mafic 0.03 3.1 0.17 0.08 68.4 422 0.68 95.5 15.9 0.33 0.9 0.017 0.05 5.4 10.7 1.1 289 1.1ADML_1B_070 M Mafic 0.05 2.4 0.14 0.09 43.2 319 0.15 93.4 14.5 0.37 0.8 0.015 0.05 1.5 14.6 1.1 109.5 1ADML_1B_071 M Mafic 0.04 1.2 0.1 0.15 45.7 283 0.43 106 13 0.25 0.8 0.018 0.04 1.5 21.9 1 112.5 1ADML_1B_191 M Mafic 2.18 11.7 0.9 1.39 31.5 186 0.1 149 21.1 0.32 6 0.095 0.07 32.1 56.8 7 89.2 427ADML_1B_200 M Mafic 0.17 19.4 0.81 0.09 20 1280 0.11 249 29.1 1.6 4.8 0.03 0.12 4.9 7.3 15.3 368 11.2ADML_1B_208 M Mafic 0.03 20.8 0.82 0.02 2.9 409 0.47 93 28.8 0.22 2.6 0.024 0.08 1.5 32.9 3.4 214 7.3ADML_1B_237 M Mafic 0.87 156 0.61 0.05 129 2290 0.12 1420 22.6 0.63 3 0.021 0.11 11.3 2.2 10 908 3.4ADML_1B_238 M Mafic 0.07 21.6 0.41 0.18 41.2 373 1.46 65.8 16.2 0.12 1.1 0.011 0.05 1.8 22.7 1.1 107 1.8ADML_1B_008 M Ore 0.42 187 0.13 0.01 5.5 136 0.09 64.7 0.46 1.55 0.1 0.149 0.01 1.1 0.5 0.6 11.3 6.1ADML_1B_029 M Ore 0.49 320 0.14 0.01 1.8 75 0.05 145 0.74 2.06 0.1 0.297 0.01 0.25 0.1 0.8 5.6 16.3ADML_1B_031 M Ore 0.39 86.9 0.29 0.02 4.2 55 0.07 79.7 1.79 1.56 0.2 0.298 0.04 1.8 1.1 0.8 14.9 13ADML_1B_042 M Ore 0.28 105.5 0.67 0.02 24 671 0.06 297 0.76 1.29 0.05 0.177 0.06 8.1 0.3 0.7 48.3 15.8ADML_1B_054 M Ore 0.3 466 0.17 0.01 8.8 246 0.025 159.5 4.46 2.35 0.8 0.163 0.06 0.9 1.2 1.5 18.3 46ADML_1B_055 M Ore 1.08 277 0.14 0.01 2.2 186 0.025 145.5 1.78 1.84 0.1 0.768 0.02 1 0.3 0.8 10.4 21.6ADML_1B_057 M Ore 1.09 178 0.19 0.02 6.4 472 0.06 254 4.29 1.09 0.5 0.318 0.04 2.6 2.1 1.2 13.2 8.6ADML_1B_064 M Ore 0.42 177 0.35 0.01 5.3 145 0.05 102.5 0.43 2 0.05 0.041 0.01 0.25 1 0.7 17 33.5ADML_1B_066 M Ore 0.55 281 0.1 0.04 2.3 110 0.06 150.5 1.84 2.2 0.7 0.251 0.03 0.25 0.2 1.3 19.3 23ADML_1B_072 M Ore 0.57 238 0.18 0.03 3.7 157 0.05 85.1 1.36 1.36 0.6 0.491 0.02 1 0.3 1.2 13.5 6.1ADML_1B_188 M Ore 0.2 39.5 0.44 0.01 4.8 48 0.025 27.5 1.01 1.76 0.05 0.051 0.02 1.7 0.3 0.7 14.4 6.3ADML_1B_189 M Ore 0.2 35.6 0.56 0.01 8.8 13 0.025 17.4 0.79 0.63 0.1 0.019 0.01 1.2 0.2 0.8 5.6 9.8ADML_1B_192 M Ore 0.39 197 0.05 0.01 1.9 67 0.025 56.6 0.49 1.56 0.1 0.166 0.00 0.25 0.3 0.8 7 10ADML_1B_209 M Ore 0.64 510 0.35 0.03 18.3 417 0.025 455 25.6 1.73 0.7 0.665 0.30 1.8 2.5 1 21 52.8






SMC Sample ID Domain IDADML_1B_210 M Ore 0.56 244 0.11 0.01 3.6 260 0.025 87.9 7.48 1.67 0.1 0.734 0.07 0.5 0.3 0.7 17.9 9.3ADML_1B_030 M Ore Hi Al 0.11 32.2 0.51 0.03 5.1 11 0.07 15 1.42 1.91 0.4 0.049 0.03 8.8 30.2 0.8 15.3 13.1ADML_1B_053 M Ore Hi Al 0.1 248 0.67 0.12 13.7 109 0.07 200 1.32 3.1 0.1 0.09 0.05 3.6 7.3 0.9 46.2 28.3ADML_1B_058 M Ore Hi Al 0.18 25.3 0.3 0.01 7.1 228 0.025 66.6 3.25 0.64 0.2 0.021 0.04 4.6 0.8 0.9 20 38.7ADML_1B_190 M Ore Hi Al 0.24 22.7 0.81 0.01 20.9 46 0.08 187 6.63 1.15 0.4 0.018 0.07 1.4 2.8 1.1 19.1 49.7ADML_1B_194 M Ore Hi Al 0.31 210 0.26 0.01 3.5 877 0.5 120 9.61 2.1 1.4 0.156 0.11 1.6 3.3 3 10.8 39.5ADML_1B_195 M Ore Hi Al 0.13 184 0.45 0.04 118.5 340 0.19 49.5 8.21 1.6 0.5 0.039 0.03 2.7 5 1.7 100.5 9.8ADML_1B_198 M Ore Hi Al 0.41 225 0.4 0.02 6.2 211 0.025 194.5 3.11 1.48 2.1 0.56 0.06 4.6 4.3 4 23.1 17.8ADML_1B_202 M Ore Hi Al 0.17 42.7 0.55 0.02 7.8 362 0.2 62.6 14.9 1.24 2.1 0.094 0.17 10.4 2.2 2.8 21.7 11.7ADML_1B_231 M Ore Hi Al 0.25 146.5 0.2 0.02 5.5 400 0.65 216 4.89 1.47 3 0.389 0.07 1.9 7.9 3.4 36 11ADML_1B_234 M Ore Hi Al 0.14 142 0.77 0.01 316 99 0.11 198 2.59 2.11 0.2 0.046 0.02 2.2 3.4 0.7 30 30.2ADML_1B_235 M Ore Hi Al 0.74 452 0.42 0.01 5 314 0.17 147.5 21.9 0.86 1.7 0.144 0.22 3.4 2.9 2.5 10.9 19.9ADML_1B_236 M Ore Hi Al 0.41 209 0.44 0.01 5.4 102 0.05 167 2.56 1.9 0.4 0.101 0.09 2.6 0.3 1.1 7.5 12.4ADML_1B_013 M Ore Hi SiO2 0.67 191 0.19 0.01 9.2 237 0.1 187 2.25 1.11 0.4 0.143 0.05 0.7 3 1 10.7 18.3ADML_1B_020 M Ore Hi SiO2 0.18 9.4 1.25 0.08 9 35 0.08 64.7 0.69 0.69 0.05 0.028 0.01 11.9 4.4 0.8 55.9 3.9ADML_1B_028 M Ore Hi SiO2 1.12 519 0.17 0.01 4.8 251 0.12 171.5 10.5 1.81 0.7 1.14 0.12 1.5 0.6 1.2 12 23ADML_1B_052 M Ore Hi SiO2 0.09 106 0.52 0.1 19.9 254 0.06 87.8 1.16 1.41 0.05 0.121 0.04 16.1 5.4 0.7 59.4 73.7ADML_1B_059 M Ore Hi SiO2 0.31 13.7 1.3 0.08 10 26 0.07 42.3 1.41 1.39 0.1 0.042 0.01 9.4 0.9 1 23.1 423ADML_1B_065 M Ore Hi SiO2 0.17 169.5 0.52 0.01 2.3 265 0.07 99.3 2.44 2.5 0.1 0.043 0.04 2.7 2.4 0.9 13.2 55.2ADML_1B_073 M Ore Hi SiO2 0.69 171.5 0.12 0.04 5.3 145 0.06 82.5 1.28 1.51 0.4 0.492 0.01 2.3 0.4 1.2 13.7 11.3ADML_1B_196 M Ore Hi SiO2 0.14 273 0.59 0.04 38 134 0.06 70.2 2.92 2.15 0.2 0.03 0.11 2.3 0.5 1.1 76.3 9.2ADML_1B_199 M Ore Hi SiO2 0.05 10 0.29 0.01 1.3 11 0.05 7.8 0.36 0.32 0.05 0.025 0.01 1.8 0.8 0.5 9.3 1.8ADML_1B_201 M Ore Hi SiO2 0.27 89.4 0.22 0.01 4.9 387 0.07 90.3 8.84 1.26 0.7 0.249 0.10 1.8 0.3 1.6 9.2 4.8ADML_1B_203 M Ore Hi SiO2 0.17 645 1.13 0.16 18.2 244 0.025 349 4.09 1.74 0.2 0.171 0.12 2 1.4 1 82 24.4ADML_1B_207 M Ore Hi SiO2 0.21 65.3 0.5 0.02 6.3 101 0.025 30.1 9.06 2.59 0.6 0.106 0.02 2.8 1.3 4.2 10.2 4.7ADML_1B_230 M Ore Hi SiO2 0.53 296 0.13 0.01 3 1080 0.025 176 18.2 1.83 2.2 0.265 0.10 0.25 0.2 3.2 7.9 38.1ADML_1B_232 M Ore Hi SiO2 0.15 40.4 0.54 0.02 63.1 64 0.07 50.4 1.7 2.21 0.2 0.032 0.03 3.6 13.9 0.8 27 33.6ADML_1B_233 M Ore Hi SiO2 0.89 326 0.26 0.02 3.7 772 0.07 160.5 12.3 1.6 0.3 0.135 0.11 1 0.3 0.9 4.3 15.4A13026 M Shale 0.2 23 1.8 0.7 42.3 480 - 92 - - - 0.05 - - 8.7 9.4 370 15A13027 M Shale 0.2 220 1.5 0.5 73.4 810 - 165 - - - 0.05 - - 10.2 7.2 555 16A13038 M Shale 0.2 12 1.6 0.3 37.9 570 - 88 - - - 0.05 - - 12.6 8.5 377 16A13039 M Shale 0.2 32 1.4 0.4 67.3 690 - 147 - - - 0.05 - - 14.2 7.6 670 15A13058 M Shale 0.3 34 2.4 0.2 23.3 630 - 129 - - - 0.05 - - 8.3 11.2 258 21ADML_1B_274 M Shale 0.57 59.4 0.92 0.53 50.1 489 1.12 69.9 16.75 0.23 3.7 0.103 0.07 14.2 15 5.7 335 48.2_ _ADML_1B_275 M Shale 0.23 50.6 1.15 0.22 36.1 565 1.38 124.5 18.8 0.14 4.2 0.024 0.07 36.1 13.7 6.5 337 17.3ADML_1B_276 M Shale 0.15 81.2 1.15 0.05 58.8 560 1.57 77.5 19.75 0.14 4 0.036 0.06 31.9 12.8 6.4 449 17.1ADML_1B_277 M Shale 0.19 58.8 0.54 0.15 106.5 563 0.14 108 15 0.19 2.8 0.016 0.07 24.7 12.7 4.8 772 10.4ADML_1B_280 M Shale 7.25 259 0.28 0.49 124.5 503 0.53 122 26.4 0.28 3.8 0.611 0.09 27.2 26.8 8.3 386 110ADML_1B_281 M Shale 0.46 171 0.5 2.98 71.6 872 0.06 292 21.6 0.71 5.2 0.074 0.13 31.5 33.1 6.3 601 8.1ADML_1B_282 M Shale 0.26 155.5 1.03 0.1 9.7 997 0.39 116.5 27.8 1.64 6.4 0.022 0.12 15.6 47.5 4 428 5.9ADML_1B_283 M Shale 0.15 57.9 1.16 0.15 18 519 0.9 94.3 21.1 0.19 4.7 0.0025 0.09 38.1 11.8 4 146.5 28ADML_1B_284 M Shale 0.42 53.3 1.26 0.05 12.8 522 0.97 83 20.3 0.11 4.3 0.0025 0.10 10 9.4 5.3 158 17.7ADML_1B_285 M Shale 0.08 172.5 1.26 0.01 27 900 0.74 54.7 28.2 1.45 7.8 0.025 0.08 6.7 28.6 5.3 189 9.9ADML_1B_286 M Shale 0.11 191 1.09 0.02 16.9 1270 0.68 82.1 32 0.95 7.2 0.027 0.11 22.7 35.6 5.1 275 33.4ADML_1B_287 M Shale 0.08 166 0.89 0.01 23.2 628 0.23 69.9 24.8 1 5.8 0.023 0.07 22.1 53.1 5.4 302 7.1ADML_1B_288 M Shale 0.07 105 1.58 0.01 16 853 1.2 56.2 35.4 0.77 8.6 0.011 0.10 81.3 34.3 7.2 335 26A13003 B BIF 0.1 12 0.5 0.05 13.4 30 - 31 - - - 0.2 - - 0.8 1.4 62 4A13004 B BIF 0.2 6 0.6 0.05 5.3 30 - 2.5 - - - 0.2 - - 0.5 0.9 31 7A13005 B BIF 0.5 73 1.1 0.1 50 20 - 79 - - - 0.5 - - 1.7 3.8 52 6A13006 B BIF 0.6 86 0.8 0.1 48.8 50 - 153 - - - 1.6 - - 4.5 3.6 91 3A13011 B BIF 0.3 23 1.5 0.05 25.7 170 - 85 - - - 0.05 - - 15.6 2.7 99 6A13013 B BIF 0.4 7 0.7 0.05 6.6 20 - 7 - - - 0.3 - - 4 1.4 19 3A13014 B BIF 0.2 8 0.5 0.05 7.3 30 - 2.5 - - - 1.2 - - 2.3 1.2 21 4A13015 B BIF 0.1 7 0.5 0.05 8.4 30 - 34 - - - 0.05 - - 3.9 1.8 17 4A13016 B BIF 0.1 8 0.9 0.05 18.3 5 - 279 - - - 0.1 - - 2.2 2.4 2.5 4A13042 B BIF 0.05 10 1.1 0.05 5.7 20 - 19 - - - 1.6 - - 3.6 0.9 43 3A13043 B BIF 0.05 6 0.8 0.05 4 90 - 12 - - - 1.4 - - 1.8 1 34 7A13044 B BIF 0.05 23 1.5 0.05 13.6 5 - 79 - - - 0.3 - - 1.5 1.8 31 3ADML_1B_083 B BIF 0.11 9.8 0.49 0.01 2.6 6 0.025 21.2 1.32 0.34 0.1 0.007 0.02 1.3 1.2 0.6 6.6 1.7ADML_1B_084 B BIF 0.09 11.2 0.46 0.01 1.7 7 0.025 14.3 1.42 0.33 0.05 0.006 0.02 1.1 0.9 0.5 4.6 1.3ADML_1B_098 B BIF 0.05 5.9 0.67 0.01 12.8 19 0.05 14.8 1.14 0.3 0.1 0.036 0.02 2.1 1.1 0.5 21.4 6.1ADML_1B_100 B BIF 0.15 8.3 0.62 0.01 4 11 0.025 12.3 1.41 0.36 0.1 0.011 0.03 2.3 1.5 0.6 16.5 1.5ADML_1B_107 B BIF 0.09 25.9 0.95 0.05 27 123 0.16 38.8 3.47 0.26 0.2 0.036 0.07 4.6 2.3 0.9 91.2 3.7ADML_1B_130 B BIF 0.12 172 0.69 0.01 23 950 0.32 157 8.78 2.99 0.8 0.021 0.26 3.1 8.8 2 171.5 16ADML_1B_138 B BIF 0.14 41.5 0.61 0.02 20.9 17 0.11 79.1 1.56 1.58 0.1 0.034 0.03 4.5 1.5 0.8 35 5.4ADML_1B_138 B BIF 0.01 7.8 0.34 0.01 5.2 243 0.63 57.1 12.25 0.05 1 0.0025 0.04 1.1 14.1 1.2 43.6 2.7ADML_1B_149 B BIF 0.04 1.1 0.27 0.11 47.1 122 0.47 96.7 16.35 0.13 1.2 0.005 0.06 3.7 23.1 1.8 123.5 6.2ADML_1B_156 B BIF 0.02 4.9 0.36 0.1 98.8 156 1.51 127 18.15 0.05 1.4 0.006 0.07 11.6 14.1 2.1 309 1.9ADML_1B_174 B BIF 0.07 7.3 1.54 0.01 3.4 9 6.51 14.1 4.05 0.32 0.1 0.026 0.05 2 0.9 0.8 29 0.8ADML_1B_185 B BIF 0.06 10.9 0.44 0.01 3.7 11 0.025 11.1 1.34 0.3 0.1 0.034 0.03 4.3 0.5 0.6 12.4 2.6ADML_1B_186 B BIF 0.06 8.9 0.39 0.01 3.4 7 0.025 3.7 1.08 0.31 0.1 0.028 0.02 1 0.7 0.5 14.2 0.7ADML_1B_197 B BIF 0.2 474 0.68 0.02 9.6 260 0.07 128 4.98 2.83 0.4 0.097 0.15 3 5.2 1.4 33 88.1






SMC Sample ID Domain IDADML_1B_221 B BIF 0.08 22.1 0.61 0.05 7.3 15 0.07 16.6 1.35 0.94 0.1 0.033 0.04 2.1 1.3 0.6 33 2.3A13001 B Mafic 0.2 3 1.1 0.1 56.2 240 - 186 - - - 0.05 - - 28.8 6.7 121 6A13002 B Mafic 0.1 12 1.7 0.05 45.2 180 - 92 - - - 0.05 - - 15.2 5.4 173 4A13007 B Mafic 0.3 28 0.6 0.05 33 150 - 135 - - - 0.2 - - 63 4.3 163 5A13008 B Mafic 0.1 13 0.6 0.05 28.1 190 - 115 - - - 0.05 - - 37.7 5 113 3A13009 B Mafic 0.4 2 0.7 0.05 4.1 690 - 12 - - - 0.05 - - 15.5 5.2 116 2A13010 B Mafic 0.1 0.5 1.3 0.05 93.3 990 - 8 - - - 0.05 - - 82.2 6.2 216 2A13012 B Mafic 0.05 0.5 1.8 0.05 73.3 200 - 79 - - - 0.05 - - 82.7 9.4 142 4A13017 B Mafic 0.05 0.5 1.8 0.05 68.1 190 - 148 - - - 0.05 - - 78.6 7.4 130 3A13018 B Mafic 0.05 0.5 0.4 0.05 47.8 140 - 126 - - - 0.05 - - 18.8 6.3 78 4A13040 B Mafic 0.1 0.5 5.4 0.05 368 40 - 282 - - - 0.05 - - 156 6.5 232 5A13041 B Mafic 0.05 0.5 2 0.05 65.7 170 - 101 - - - 0.05 - - 109 6.6 123 3A13045 B Mafic 0.05 3 1.4 0.05 99.5 200 - 70 - - - 0.05 - - 85.8 5.6 204 3A13046 B Mafic 0.05 3 1.4 0.05 54.2 160 - 23 - - - 0.05 - - 102 4.9 84 3ADML_1B_006 B Mafic 0.02 1.8 0.93 0.01 106.5 172 1.24 26.3 17.65 0.34 1.3 0.006 0.06 7.8 71.5 2.8 140 1.1ADML_1B_007 B Mafic 0.03 0.8 1.32 0.01 62.8 733 1.42 11.3 16.25 0.29 1.5 0.006 0.05 4.6 42.5 3 290 0.7ADML_1B_079 B Mafic 0.1 37.7 1.19 0.05 18.5 253 0.57 79.2 23.1 0.27 2.2 0.014 0.09 12.9 49 1.4 124 0.8ADML_1B_080 B Mafic 0.06 26.5 0.58 0.02 52.4 278 0.18 123.5 24.6 0.26 2.4 0.008 0.09 2.6 72.5 2.6 87.7 0.8ADML_1B_081 B Mafic 0.04 18.5 0.64 0.04 8.5 147 0.15 142 20 0.27 1.5 0.005 0.07 1.8 66.4 2.6 55.2 3.8ADML_1B_082 B Mafic 0.06 9.6 1.02 0.01 17.5 133 0.19 203 19.95 0.34 1.2 0.0025 0.07 3.1 8 3 62.6 2.4ADML_1B_085 B Mafic 0.06 1.8 0.26 0.08 55.2 512 0.17 64.1 13.1 0.14 1.1 0.008 0.04 4.2 27.4 2 127.5 2.6ADML_1B_086 B Mafic 0.03 4.4 0.41 0.11 107 182 0.75 102 18.5 0.2 1.3 0.0025 0.06 16.1 13.7 2.3 229 1.7ADML_1B_087 B Mafic 0.04 7 0.36 0.09 74.3 178 8.3 143 20.8 0.19 1.7 0.0025 0.08 4.4 27 2.7 111 2.7ADML_1B_088 B Mafic 0.03 67.9 0.44 0.02 5.6 86 0.43 103.5 19.6 0.19 2.3 0.006 0.07 12.7 30.2 2.4 103 1.3ADML_1B_089 B Mafic 0.04 1.2 2.18 0.01 54.6 80 0.82 67.1 17.3 0.25 1.5 0.0025 0.05 2.2 74.5 3.1 78.8 1ADML_1B_090 B Mafic 0.05 1.2 2.31 0.01 73 69 0.55 52.7 22.7 0.43 1.7 0.0025 0.07 7 86.4 3.4 104 0.6ADML_1B_091 B Mafic 0.04 0.8 1.69 0.01 46.5 8 0.27 93.9 13.6 0.22 1.7 0.006 0.04 5.5 66.7 3.4 35 0.6ADML_1B_092 B Mafic 0.02 4.7 0.48 0.12 105 192 0.77 110.5 19.8 0.26 1.4 0.024 0.06 15.2 15.4 2.3 245 1.7ADML_1B_093 B Mafic 0.04 2.5 0.41 0.03 106.5 173 0.78 131.5 20.2 0.21 1.6 0.007 0.07 10.6 22.8 2.6 226 2.1ADML_1B_094 B Mafic 0.03 4.7 0.26 0.05 66.1 118 0.68 87.2 15.6 0.23 1.1 0.0025 0.05 5.9 28.2 1.8 265 2.6ADML_1B_095 B Mafic 0.03 1.6 0.61 0.03 84.1 2240 0.41 117 13.5 0.2 1.4 0.0025 0.05 24.1 17.2 2.1 708 1.7ADML_1B_096 B Mafic 0.02 0.2 0.35 0.04 42.5 653 0.52 47.2 11.35 0.14 1.1 0.0025 0.03 5.2 12.6 1.7 260 2ADML_1B_097 B Mafic 0.04 12.2 1.74 0.05 46.8 191 0.67 82.1 18.3 0.2 1.7 0.0025 0.08 4.4 13.7 2.3 158 2ADML_1B_103 B Mafic 0.12 33 0.51 0.06 29.5 128 0.21 147.5 18.45 0.2 1.7 0.013 0.09 5.5 53.4 1.9 179 5.5_ _ADML_1B_104 B Mafic 0.1 12 0.53 0.04 39.3 150 0.3 112 16 0.19 1.4 0.005 0.05 3.5 63.6 2.4 86.1 1.4ADML_1B_105 B Mafic 0.03 59 0.28 0.03 10.1 465 0.29 60.9 15.8 0.13 1.6 0.005 0.05 2.6 4.8 1.8 66.7 7.5ADML_1B_106 B Mafic 0.02 3.2 0.78 0.14 119 1380 0.22 81 11.7 0.13 1 0.012 0.03 9.1 21.5 1.3 327 1.3ADML_1B_108 B Mafic 0.02 24.7 0.34 0.02 14.4 203 0.14 109.5 22.6 0.53 1.8 0.0025 0.10 0.8 6.2 2.9 84.5 1.9ADML_1B_112 B Mafic 0.11 86.8 3.18 0.01 34.6 178 0.23 334 23.5 1.73 2.2 0.006 0.22 5.3 16.4 4.3 258 1.6ADML_1B_113 B Mafic 0.04 18.7 4.62 0.01 117.5 162 0.65 90.5 15.85 0.99 1.2 0.01 0.06 5 51.3 2.8 263 1.1ADML_1B_114 B Mafic 0.05 4.2 0.31 0.07 52 73 0.24 76.9 15.25 0.22 1.1 0.0025 0.05 4 15.4 2.6 74.6 1.7ADML_1B_116 B Mafic 0.03 2.1 2.03 0.01 33 88 0.1 77.4 23.1 1.18 1.9 0.01 0.08 7.2 84.6 3.2 91.1 0.5ADML_1B_117 B Mafic 0.03 1.6 1.27 0.01 58.8 5 0.24 172.5 17.25 0.33 2.1 0.0025 0.03 11.1 52.1 4.2 38 0.7ADML_1B_119 B Mafic 0.02 23.8 0.6 0.03 36.7 199 1.05 149.5 23.7 0.17 1.5 0.0025 0.08 2.2 13.4 2.6 144.5 3.8ADML_1B_120 B Mafic 0.03 13.3 0.66 0.06 80 124 0.22 81.2 16.4 0.21 1.1 0.0025 0.06 34.7 16.7 1.8 243 2ADML_1B_121 B Mafic 0.05 20.1 0.32 0.2 64.5 173 0.45 126.5 20.3 0.16 1.5 0.0025 0.08 6.5 18.3 2.3 237 3.4ADML_1B_122 B Mafic 0.06 27 0.32 0.03 49.7 248 0.22 87 15.35 0.16 0.9 0.009 0.05 3.9 18.9 1.7 131 3.3ADML_1B_123 B Mafic 0.03 1.5 1.44 0.02 68.1 84 0.12 69.8 22.8 0.71 1.8 0.01 0.06 14.9 55.9 4 65.1 0.7ADML_1B_124 B Mafic 0.12 1.6 2.48 0.01 46.3 21 1.38 15.3 15.6 0.21 1.5 0.007 0.04 5.5 79.2 2.7 56.5 2.1ADML_1B_126 B Mafic 0.02 0.5 1.62 0.01 57.1 124 0.13 4.3 14.65 0.19 0.9 0.0025 0.02 3.1 78.5 2.1 94 0.5ADML_1B_128 B Mafic 0.03 1.9 1.92 0.01 82.8 173 1.21 104 19.85 0.41 1.6 0.006 0.08 5 73.7 2.6 127.5 2ADML_1B_129 B Mafic 0.02 17.7 0.7 0.03 7.5 1350 0.13 117.5 23.5 0.37 2.1 0.0025 0.06 1 5.5 2 272 3.3ADML_1B_131 B Mafic 0.12 1.8 0.21 0.02 83.7 1700 1.23 75.2 12.3 0.3 1.1 0.005 0.04 3.5 38.8 1.8 687 3.5ADML_1B_132 B Mafic 0.02 7 0.24 0.03 88.2 2040 0.17 65.1 7.6 0.26 0.7 0.005 0.02 2.3 13.8 1.1 863 0.5ADML_1B_133 B Mafic 0.01 3.2 0.17 0.02 79.1 1910 0.18 72.4 7.3 0.29 0.7 0.0025 0.03 1.2 12.3 1.2 820 0.5ADML_1B_134 B Mafic 0.03 1 0.28 0.01 104.5 494 0.25 46.2 12 0.17 1.4 0.0025 0.04 31.4 30.1 2.2 577 1.2ADML_1B_135 B Mafic 0.03 6.7 1.87 0.02 54.6 76 1.18 146.5 22.1 0.48 2.2 0.005 0.08 0.8 16.8 3.5 70.9 1.1ADML_1B_136 B Mafic 0.12 1.9 0.64 0.03 89.5 160 11.1 56.9 13.55 0.15 1.2 0.0025 0.06 6.7 50.6 2.4 114.5 23.1ADML_1B_137 B Mafic 0.04 2 0.46 0.01 13.4 21 0.29 113.5 25.5 0.78 2.5 0.0025 0.09 1.3 13.8 2.4 52.7 9.4ADML_1B_139 B Mafic 0.02 22.7 0.5 0.03 13.8 224 0.46 153.5 23.2 0.13 1.7 0.01 0.08 0.8 5.6 2.7 108 6.1ADML_1B_140 B Mafic 0.02 7.3 0.66 0.03 13.1 890 0.6 184.5 21.1 0.15 1.4 0.024 0.07 3.2 10.7 2.6 64 2.2ADML_1B_141 B Mafic 0.01 6.6 0.49 0.05 39.2 435 1.74 83 12.7 0.14 0.9 0.016 0.04 25.1 17 1.5 204 1.7ADML_1B_142 B Mafic 0.01 3.3 0.19 0.09 43.4 599 0.49 63.3 11.3 0.13 0.9 0.008 0.03 6.8 24 1.5 147.5 1.9ADML_1B_143 B Mafic 0.06 34.9 1.08 0.03 7.5 184 0.4 113.5 24.9 0.98 2.3 0.035 0.11 2.4 37.4 2.1 138.5 9.7ADML_1B_144 B Mafic 0.37 28.2 1.12 0.11 154 75 0.11 115 4.55 1.11 0.4 0.133 0.07 11 14.2 1.2 106 12.5ADML_1B_146 B Mafic 0.06 9.4 0.37 0.01 2.7 5 0.07 4 0.67 0.23 0.05 0.062 0.02 0.6 0.7 0.4 14.2 1.7ADML_1B_150 B Mafic 0.04 1.2 0.25 0.1 48.1 236 0.45 90 15.3 0.11 1.1 0.008 0.05 3.6 14.5 1.6 121 2.4ADML_1B_151 B Mafic 0.03 3 0.24 0.04 56 150 0.68 96.3 14.8 0.1 1.6 0.0025 0.05 4.4 22.8 2.2 216 1.8ADML_1B_152 B Mafic 0.06 1.5 0.8 0.21 77.9 2 5.31 176 22.2 0.08 4.1 0.005 0.12 13.8 4.7 6.1 65 4.7ADML_1B_153 B Mafic 0.03 13.8 0.38 0.03 48.8 270 0.23 170.5 28.7 0.06 2.1 0.006 0.10 2.3 20 3.6 200 2ADML_1B_154 B Mafic 0.09 9.4 0.96 0.09 19.4 82 0.32 156.5 10.1 1.13 0.7 0.007 0.06 1.7 8.7 1.4 82.7 1.2ADML_1B_155 B Mafic 0.03 3.3 0.32 0.04 36.5 213 0.56 141.5 25.6 1.16 1.9 0.008 0.09 3.9 5.1 3 135.5 3.6






SMC Sample ID Domain IDADML_1B_157 B Mafic 0.03 0.8 0.28 0.08 48.2 239 0.47 83.3 15.45 0.16 0.9 0.005 0.05 3.8 15.6 1.7 127 1.6ADML_1B_158 B Mafic 0.08 1.5 0.25 0.04 42.2 403 0.36 126 22.2 0.05 1.3 0.009 0.07 1.6 23.7 2.2 192.5 3.2ADML_1B_159 B Mafic 0.01 2.3 0.39 0.01 3.6 179 0.15 109.5 22.4 0.025 1.7 0.005 0.08 1 8 2.4 53 3.3ADML_1B_160 B Mafic 0.05 2.4 0.3 0.11 55.8 382 0.19 97.2 19.75 0.06 1 0.01 0.07 14 17.2 2 241 6.9ADML_1B_161 B Mafic 0.02 0.7 0.34 0.11 43.7 279 0.23 67.4 15.3 0.19 0.8 0.0025 0.06 3.2 15.2 1.8 146 4.6ADML_1B_162 B Mafic 0.02 7.9 1.79 0.01 13 255 0.15 161.5 24.5 0.86 1.8 0.007 0.10 2.6 28.9 3.3 214 0.9ADML_1B_163 B Mafic 0.07 20.2 0.58 0.01 9 9 0.07 69.1 2.26 0.44 0.1 0.045 0.05 11.2 7.1 0.8 94.4 0.6ADML_1B_164 B Mafic 0.03 3.5 0.48 0.04 38.7 127 0.36 58.6 13.3 0.07 1.2 0.006 0.04 4.8 13.9 2 100.5 2.3ADML_1B_167 B Mafic 0.07 32.1 0.49 0.15 167 348 0.13 96.8 17.85 0.26 1.2 0.011 0.06 2.8 38.8 1.9 198.5 1.9ADML_1B_168 B Mafic 0.04 2.2 0.21 0.07 65.7 135 0.33 100 15.1 0.25 1.1 0.0025 0.05 3.5 19 1.9 126 2.2ADML_1B_169 B Mafic 0.08 8.5 0.37 0.02 15.3 21 0.05 18 1.75 0.38 0.1 0.019 0.01 1.2 0.8 0.8 50.2 2.6ADML_1B_175 B Mafic 0.06 69.6 0.64 0.01 69.2 217 0.29 190 21.3 0.73 2.2 0.062 0.19 6.7 41.2 4.2 187 1.9ADML_1B_005 B Mafic 0.09 22.2 1.45 0.03 40 454 0.33 61.8 22.7 0.45 1.9 0.0025 0.10 31.4 29.2 1.4 102 1.4ADML_1B_179 B Magnetite 0.14 3 0.37 0.01 5.2 6 0.07 24.9 2.08 3.93 0.1 0.011 0.03 4 1.4 0.8 6.4 3ADML_1B_180 B Magnetite 0.12 4.6 0.47 0.01 5.2 10 0.08 8.8 2.43 0.69 0.2 0.037 0.03 4.9 1.8 0.9 11.1 2.3ADML_1B_181 B Magnetite 0.1 5.2 0.52 0.02 10.3 39 0.2 30.8 6.6 2.4 0.5 0.009 0.04 3.9 8.4 1.4 23.9 1.7ADML_1B_222 B Magnetite 0.07 2.6 1.08 0.01 2.2 8 0.56 1.3 4.12 4.41 0.1 0.014 0.04 6.4 0.8 0.8 13 0.9ADML_1B_002 B Ore 0.07 13.1 1.12 0.05 15.9 8 0.11 27.9 2.99 0.64 0.1 0.012 0.06 3 0.5 1 36 0.8ADML_1B_102 B Ore 0.3 137.5 0.5 0.18 85 39 0.06 142.5 1.79 0.96 0.1 0.029 0.05 5.8 1.4 0.9 117.5 2.3ADML_1B_109 B Ore 0.12 27.8 1.29 0.01 6.7 22 0.07 47.5 1.75 0.92 0.1 0.01 0.03 1 1.2 0.9 25 2.2ADML_1B_111 B Ore 0.21 499 1.66 0.35 6.5 8 0.07 68.1 3.04 5.35 0.1 0.014 0.08 3.7 0.4 1 25 1.6ADML_1B_115 B Ore 0.07 14.2 0.75 0.01 18.3 22 0.16 45.1 3.2 0.58 0.2 0.016 0.04 10.4 4.7 0.9 19.6 1.6ADML_1B_118 B Ore 0.11 9.3 1.02 0.01 5.2 17 0.07 60.1 3.13 0.41 0.1 0.096 0.04 6.5 1.4 0.7 22.9 1.1ADML_1B_125 B Ore 0.07 13.3 0.76 0.01 6.5 12 0.12 15.6 2.89 0.47 0.1 0.076 0.04 4.8 1.3 0.8 22.7 1.4ADML_1B_147 B Ore 0.04 3.4 0.29 0.05 59.1 115 0.48 86.8 14 0.22 1 0.01 0.05 4 21.8 1.8 275 3.7ADML_1B_171 B Ore 0.13 31.3 1.07 0.01 3.5 7 0.025 31 2.42 0.7 0.1 0.011 0.04 2.5 0.6 0.8 26 1.7ADML_1B_173 B Ore 0.24 57.1 0.82 0.01 9.2 65 0.025 52.1 3.83 0.68 0.2 0.016 0.08 1.6 0.4 1.1 35 0.9ADML_1B_177 B Ore 0.22 23.3 0.82 0.03 8 11 0.025 30.1 1.54 0.68 0.1 0.033 0.02 2.7 0.5 0.9 22.5 3.3ADML_1B_178 B Ore 0.14 10.3 0.62 0.01 4.9 14 0.05 14.1 2.08 0.69 0.1 0.048 0.04 2.9 0.8 0.7 15.5 1.9ADML_1B_224 B Ore 0.09 8.6 1.76 0.01 7.2 46 0.16 126 6.53 0.68 0.6 0.013 0.10 28.1 7.3 1.5 53.6 1.4ADML_1B_110 B Ore Hi Al 0.11 44.9 1.44 0.01 10.5 68 0.1 91.5 6.36 3.07 0.2 0.017 0.05 3.7 2.2 1.1 32 3ADML_1B_127 B Ore Hi Al 0.1 22.2 1.75 0.01 14 52 0.13 99.3 8.11 0.61 0.4 0.023 0.04 5.2 5.1 1.5 58 3.3ADML_1B_145 B Ore Hi Al 0.45 27.8 0.64 0.1 30 35 0.06 90.1 2.43 2.03 0.2 0.046 0.04 3.9 0.7 1 37 4.5ADML_1B_145 B Ore Hi Al 0.06 9.4 0.7 0.02 6.8 6 0.07 5 0.89 0.31 0.05 0.155 0.03 1.7 0.7 0.6 34.8 1.6_ _ADML_1B_172 B Ore Hi Al 0.13 144 2.07 0.03 25 162 0.06 153 11.25 1.65 1 0.009 0.09 5.6 2.3 2.4 239 2.4ADML_1B_182 B Ore Hi Al 0.12 20.1 1.42 0.01 20.6 1660 0.025 486 16.25 0.72 2 0.015 0.06 14.8 2 3.2 620 1.9ADML_1B_183 B Ore Hi Al 0.1 10.2 1.02 0.03 421 28 0.08 148.5 5.05 0.7 0.2 0.018 0.06 8.4 71.5 0.9 131 2.1ADML_1B_184 B Ore Hi Al 0.13 27.5 2.32 0.02 7.9 148 0.15 153.5 17.95 0.68 1.4 0.068 0.19 5.9 11.7 3.3 66.1 3ADML_1B_278 B Ore Hi Al 0.12 35.8 0.48 0.02 6.3 760 0.19 14.3 24.3 0.77 2.1 0.0025 0.14 3.5 6.4 2.6 34.1 13.4ADML_1B_279 B Ore Hi Al 0.11 81.5 0.34 0.03 16.3 1420 0.08 102.5 24.3 2.67 2.5 0.077 0.12 3.4 1.1 3.1 78.1 4.4ADML_1B_003 B Ore Hi SiO2 0.06 6.2 1.16 0.22 5 11 1.19 20.2 4.47 4.5 0.1 0.007 0.06 5.4 1.6 0.8 22.4 1ADML_1B_004 B Ore Hi SiO2 0.09 22.2 2.15 0.06 11.8 24 5.65 21.9 5.41 1.42 0.2 0.015 0.07 5.4 1 1 122 0.8ADML_1B_099 B Ore Hi SiO2 0.14 11.9 0.95 0.07 17.9 10 0.025 37.8 1.85 0.98 0.1 0.038 0.04 8.5 4 0.9 56.1 1.9ADML_1B_101 B Ore Hi SiO2 0.17 43.8 0.58 0.05 8.9 39 0.06 40.3 1.56 2.44 0.1 0.034 0.03 3.8 0.2 0.9 40 3ADML_1B_148 B Ore Hi SiO2 0.04 1.4 0.27 0.07 45.9 231 0.27 94.8 13.7 0.1 0.9 0.005 0.04 3.5 15.4 1.5 109 1.2ADML_1B_170 B Ore Hi SiO2 0.33 202 0.47 0.07 23.2 46 0.025 111.5 1.48 1.28 0.1 0.039 0.02 4.1 1 0.8 78.7 1.2ADML_1B_176 B Ore Hi SiO2 0.17 11.1 1.95 0.02 4.9 8 0.94 6.7 3.79 4.34 0.1 0.019 0.04 3.9 1.4 0.7 22.2 16.1ADML_1B_220 B Ore Hi SiO2 0.11 29.8 0.61 0.09 7.7 7 0.06 10.1 1.5 3.29 0.1 0.046 0.02 1.9 0.4 0.7 43 4.4ADML_1B_223 B Ore Hi SiO2 0.11 14.7 1.3 0.01 3.4 9 2.4 6.5 2.02 0.69 0.1 0.053 0.04 2.3 1 0.8 38 1.2ADML_1B_001 Mafic 0.02 22 0.97 0.01 8.4 285 0.1 64.7 26.2 1.01 2.8 0.006 0.08 1.8 37.8 3.8 22.2 1.2


Minor Element Concentrations (continued)

Zone Analyte Rb Re Sb Sc Se Sn Sr Ta Te Th Ti Tl U V W Y Zn Zr

B - Beebyn Units ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm % ppm ppm ppm ppm ppm ppm ppm

Mean SedimentM- Madoonga

Comparative Abundance 135 4E-04 1.20E+00 1.2 0.42 4.6 320 1.5 0.01 9.6 0.38 0.95 3.1 105 1.7 40 95 150

SMC Sample ID Domain IDA13020 M BIF 0.3 - 1.3 - 2.5 1.3 1.1 - 0.1 0.1 0.006 0.25 0.12 29 2.3 4.36 68 3.4

A13024 M BIF 0.52 - 3.6 - 2.5 0.25 1 - 0.1 0.13 0.003 0.25 0.025 1 2.6 2.33 28 2.6

A13025 M BIF 0.58 - 3.1 - 2.5 0.25 1.5 - 0.1 0.025 0.02 0.25 0.025 9 5.3 2.03 50 2.9

A13028 M BIF 0.57 - 1.1 - 2.5 4.9 2.3 - 0.1 0.025 0.003 0.25 0.025 1 3.5 2.68 71 1.4

A13029 M BIF 0.51 - 0.7 - 2.5 0.25 1.7 - 0.1 0.025 0.004 0.25 0.025 1 4.1 2.77 57 1.1

A13033 M BIF 0.34 - 1.1 - 2.5 0.25 1.4 - 0.1 0.025 0.004 0.25 0.025 7 1.9 1.63 36 0.6

A13034 M BIF 0.2 - 10.6 - 2.5 1.7 2 - 0.1 1.46 0.018 0.25 0.43 54 0.6 1.25 34 17.9

A13036 M BIF 0.45 - 0.8 - 2.5 0.25 1.8 - 0.1 0.025 0.003 0.25 0.05 1 1.3 2.76 33 1.6

A13037 M BIF 0.59 - 3.4 - 2.5 0.25 0.8 - 0.1 0.08 0.004 0.25 0.025 1 5.6 1.27 27 2.1

A13049 M BIF 0.09 - 15.2 - 2.5 1.9 3.6 - 0.4 0.31 0.031 0.25 0.47 171 2.5 3.38 48 7.1

A13050 M BIF 0.17 - 12.1 - 2.5 0.8 0.8 - 0.1 0.08 0.013 0.25 0.21 10 0.5 1.12 17 3

A13051 M BIF 0.11 - 3.8 - 2.5 0.25 0.3 - 0.1 0.025 0.002 0.25 0.05 6 0.9 1.15 51 0.25

A13052 M BIF 0.09 - 14.4 - 2.5 0.6 0.8 - 0.1 0.5 0.024 0.25 0.35 30 0.7 0.62 15 8.9

A13054 M BIF 0.08 - 5.9 - 2.5 1.8 1.7 - 0.1 0.33 0.016 0.25 0.25 72 5.8 1.33 17 8

A13055 M BIF 0.1 - 9.8 - 2.5 0.7 2.1 - 0.1 0.34 0.039 0.25 0.2 47 5.2 2.61 17 12.1

A13056 M BIF 0.15 - 5.2 - 2.5 0.25 0.7 - 0.1 0.025 0.004 0.25 0.025 1 2.7 2.16 16 0.7

A13057 M BIF 1.15 - 4.6 - 2.5 0.25 1.6 - 0.1 0.22 0.007 0.25 0.025 1 2 3.66 24 1.7

A13059 M BIF 1.57 - 2.8 - 2.5 0.5 1 - 0.1 0.08 0.006 0.25 0.07 3 2.3 1.37 31 2.4

ADML_1B_012 M BIF 1.3 0.001 1.72 22.6 1 1.5 10.2 0.34 0.29 1.3 1.025 0.09 0.5 381 7.8 9 28 118.5

ADML_1B_014 M BIF 0.3 0.001 1.18 1.3 0.5 0.2 1.7 0.03 0.16 0.1 0.007 0.03 0.1 26 2.9 3.1 76 1.9

ADML_1B_015 M BIF 0.4 0.001 3.6 0.4 0.5 0.1 0.9 0.03 0.08 0.1 0.0025 0.01 0.05 2 2.5 2.5 17 1.1

ADML_1B_016 M BIF 0.1 0.001 1.58 0.4 0.5 0.1 0.8 0.03 0.08 0.1 0.0025 0.02 0.05 3 4.7 3.3 3 0.5

ADML_1B_017 M BIF 0.1 0.001 2.26 0.2 0.5 0.1 0.3 0.03 0.1 0.1 0.0025 0.01 0.05 2 5 1.3 6 0.25

ADML_1B_018 M BIF 0.1 0.001 6.21 1.8 0.5 0.3 3.1 0.03 0.2 0.1 0.0025 0.01 0.2 19 5.9 4.1 71 1.2

ADML_1B_019 M BIF 0.05 0.001 4.04 1.8 0.5 0.2 0.4 0.03 0.08 0.1 0.0025 0.01 0.05 8 4.5 1.5 14 1.1

ADML_1B_021 M BIF 0.1 0.001 3.63 7.5 1 0.6 1.9 0.09 0.32 1.6 0.071 0.01 0.4 31 1.8 3.4 6 23.4

ADML_1B_022 M BIF 0.05 0.001 3.82 0.6 0.5 0.2 2.4 0.03 0.14 0.1 0.0025 0.01 0.05 2 6.2 3.2 10 1.8

ADML_1B_023 M BIF 1.2 0.001 1.24 2.9 0.5 1.3 6.6 0.03 0.36 0.4 0.009 0.02 0.3 5 3.3 6.1 43 4.6

ADML_1B_047 M BIF 0.1 0.001 1.17 0.6 0.5 0.1 0.4 0.03 0.11 0.2 0.0025 0.01 0.1 2 4.3 2 6 1_ _

ADML_1B_074 M BIF 0.1 0.001 3.18 1.1 1 0.2 1 0.03 0.08 0.6 0.014 0.01 0.1 9 1.2 3.1 3 8.2

ADML_1B_077 M BIF 0.1 0.001 0.94 0.4 0.5 0.3 0.3 0.03 0.025 0.1 0.0025 0.01 0.1 2 0.7 2 9 0.7

ADML_1B_187 M BIF 0.3 0.002 1.45 1.5 0.5 0.3 1.8 0.03 0.025 0.1 0.0025 0.02 0.1 3 0.9 3.2 6 1

ADML_1B_193 M BIF 0.8 0.002 2.19 3.1 1 0.3 4.4 0.03 0.025 0.9 0.022 0.03 0.4 11 2.9 6.7 10 19.5

ADML_1B_204 M BIF 0.3 0.002 2.01 3.5 1 0.2 1.6 0.03 0.025 0.7 0.006 0.01 0.8 35 0.6 2.7 5 4

ADML_1B_205 M BIF 0.2 0.002 2.43 3.8 0.5 0.3 0.3 0.03 0.025 0.2 0.0025 0.01 0.3 8 2.4 2.5 14 2.4

ADML_1B_211 M BIF 0.1 0.001 5.01 1.4 0.5 0.2 2.5 0.03 0.025 0.1 0.0025 0.02 0.1 7 1.5 2.1 15 2

ADML_1B_213 M BIF 0.1 0.002 1.22 1.1 0.5 0.2 10.8 0.03 0.025 0.8 0.0025 0.01 0.1 3 0.8 2 19 2.2

ADML_1B_214 M BIF 0.05 0.001 0.75 0.9 0.5 0.2 8.3 0.03 0.025 0.9 0.009 0.01 0.1 6 0.9 2.6 20 1.9

ADML_1B_225 M BIF 0.05 0.001 3.23 1.9 1 0.7 0.4 0.06 0.11 0.9 0.037 0.01 0.2 6 3.6 1.2 4 12.9

ADML_1B_227 M BIF 0.05 0.002 1.19 0.9 0.5 0.2 0.1 0.03 0.025 0.1 0.0025 0.01 0.05 2 4.5 2 17 0.7

ADML_1B_229 M BIF 0.05 0.002 2.66 1.2 0.5 0.2 1.1 0.03 0.025 0.1 0.0025 0.01 0.05 10 0.7 2.1 9 1.8

A13019 M Detrital 1.96 - 8.3 - 2.5 1.4 3.2 - 0.1 1.22 0.106 0.25 0.67 52 8.8 3.08 20 24.4

A13030 M Detrital 0.91 - 5.6 - 2.5 1.1 6.6 - 0.1 1.08 0.399 0.25 0.44 148 3.1 2.42 17 29.5

A13047 M Detrital 0.25 - 15.8 - 2.5 0.9 2.4 - 0.1 0.79 0.145 0.25 0.27 136 3.2 2.71 94 24.4

ADML_1B_010 M Detrital 0.4 0.001 10.1 11.7 2 1.2 1.7 0.29 0.28 2.7 0.253 0.02 1.1 117 7.7 2.7 2 30.5

ADML_1B_024 M Detrital 0.9 0.001 2.15 49.3 1 0.7 9.9 0.19 0.26 2 0.489 0.01 0.8 547 2.7 3.2 8 54.8

ADML_1B_027 M Detrital 0.2 0.001 29 10 16 1.3 2 0.17 0.73 3.9 0.096 0.04 0.7 72 2.4 2.5 14 44.1

ADML_1B_035 M Detrital 1.3 0.001 8.35 7 2 1.4 3.7 0.39 0.35 4.2 0.293 0.02 1 166 6.6 5.9 5 51.4

ADML_1B_036 M Detrital 1.3 0.001 8.4 8.9 4 1 3.2 0.25 0.35 3.6 0.3 0.03 0.8 146 5.3 4.1 7 45.3

ADML_1B_037 M Detrital 24.7 0.001 4.67 18 2 1.4 13.3 0.58 0.22 16.1 0.297 0.22 1.9 164 2.6 9.2 27 105

ADML_1B_038 M Detrital 9 0.001 3.05 21.6 1 1.1 21.2 0.34 0.11 3.5 0.615 0.06 0.7 314 1.3 9.9 12 45.1

ADML_1B_040 M Detrital 1.8 0.002 11.7 6.6 3 0.5 1.2 0.08 0.33 0.6 0.082 0.13 0.2 105 2 2.5 107 12.6

ADML_1B_041 M Detrital 0.4 0.001 22.5 3.5 3 1.2 0.9 0.19 0.39 1 0.224 0.03 0.2 104 5 3.8 14 17.2

ADML_1B_045 M Detrital 2.2 0.001 9.96 18.3 2 0.6 3.1 0.1 0.37 8.8 0.067 0.03 1.3 56 2.9 2.8 12 40.1

ADML_1B_046 M Detrital 2.9 0.001 10.9 10.8 8 1.1 4.4 0.25 0.42 4.9 0.168 0.02 1.2 94 7.7 3.5 6 61.5

ADML_1B_049 M Detrital 5.7 0.001 13.6 12.4 3 0.7 6.3 0.19 0.43 12.8 0.13 0.14 1.6 128 2.5 5.3 21 53.6

ADML_1B_050 M Detrital 0.6 0.001 20.1 6.3 2 1.3 5.8 0.3 0.61 1.9 0.308 0.03 0.4 160 5.2 3.7 18 33.3

ADML_1B_051 M Detrital 0.7 0.001 15.5 25.5 3 1.1 3.1 0.23 0.5 3 0.352 0.01 0.7 317 3.9 5.8 37 44.3

ADML_1B_060 M Detrital 49.6 0.001 4.74 36.7 1 2.7 27.3 0.82 0.29 13.2 0.517 0.51 2.8 187 2.4 19.2 24 228

ADML_1B_061 M Detrital 3.9 0.001 3.28 28.6 1 1.1 11.5 0.32 0.27 5.1 0.365 0.07 0.6 180 4.2 6.1 15 56.9

ADML_1B_062 M Detrital 3.8 0.001 3.67 27.8 1 0.9 13.3 0.26 0.22 4.7 0.342 0.03 0.7 230 2.4 4.6 9 49.5

ADML_1B_063 M Detrital 10.7 0.001 3.06 32 1 1.2 18.3 0.28 0.29 5.6 0.466 0.09 0.7 279 1.1 11.2 43 64.2

ADML_1B_067 M Detrital 19.2 0.001 7.15 27.5 2 1.1 24.3 0.3 0.35 3.4 0.554 0.06 1 277 1.8 10.1 13 41.4







SMC Sample ID Domain IDADML_1B_068 M Detrital 0.9 0.001 3.79 38.2 2 0.5 3.5 0.16 0.56 1.2 0.495 0.01 0.5 509 0.7 4.9 15 43.2

ADML_1B_206 M Detrital 4.9 0.002 6.79 43.2 2 0.7 15.1 0.13 0.1 5.3 0.271 0.13 0.7 418 3.5 10.2 28 47.4

ADML_1B_212 M Detrital 0.2 0.001 23.3 10.9 2 3.3 1.1 0.62 0.16 1.6 0.911 0.01 0.5 309 20.9 3.1 15 42.6

ADML_1B_215 M Detrital 0.2 0.001 31.8 15.5 5 1 2.2 0.19 0.45 5.3 0.182 0.01 1 98 4.7 2.5 2 51

ADML_1B_216 M Detrital 7.6 0.002 5.35 18.6 5 0.6 9.8 0.2 0.13 6 0.129 0.06 1.4 64 1.5 3 2 44.6

ADML_1B_217 M Detrital 1 0.001 11.9 19 5 0.9 3.7 0.15 0.11 7.3 0.127 0.03 1.2 84 4.7 3.3 6 51.2

ADML_1B_218 M Detrital 2.3 0.001 22.9 29.8 7 1.3 3.3 0.37 0.32 8 0.388 0.03 2 132 8.3 3.7 4 58.2

ADML_1B_219 M Detrital 1.2 0.001 13.5 27.6 6 2 9 0.14 0.25 3.2 0.085 0.05 0.8 138 4 3.6 40 35.2

ADML_1B_032 M Felsic 3.6 0.002 1.65 44.3 1 0.3 76.5 0.05 0.05 0.3 0.327 0.04 0.1 221 0.1 14.5 91 21.3

ADML_1B_033 M Felsic 4.6 0.001 1.65 45.8 0.5 0.3 63.4 0.05 0.06 0.3 0.344 0.04 0.05 170 0.1 19.2 158 21.4

ADML_1B_034 M Felsic 3.2 0.001 1.92 41.8 0.5 0.3 56.1 0.06 0.07 0.3 0.368 0.03 0.1 208 0.1 19.8 126 20.7

ADML_1B_257 M Felsic 62.3 0.001 1.26 5.4 0.5 2.6 3.2 0.74 0.025 11.4 0.099 0.23 1.9 10 1.2 12.4 9 159

ADML_1B_258 M Felsic 81.3 0.001 1.18 5.3 1 2.3 9.1 0.68 0.025 10.5 0.087 0.31 2 12 4.7 17.2 14 150.5

ADML_1B_259 M Felsic 87.2 0.001 3.44 8 2 3 10.7 0.66 0.025 14.9 0.114 0.35 2.4 34 1.5 18.2 9 225

ADML_1B_260 M Felsic 82.6 0.002 1.43 5 0.5 2.6 3.9 0.54 0.025 8.6 0.084 0.34 1.7 10 4.5 14.3 7 138.5

ADML_1B_261 M Felsic 99.9 0.001 1.28 7 1 3.3 4.5 0.7 0.025 13.1 0.104 0.36 2.4 22 1 17.8 5 195.5

ADML_1B_262 M Felsic 98.7 0.001 1.18 6.6 1 2.4 5.2 0.59 0.025 9.7 0.119 0.33 2.2 17 3.7 18.8 9 176.5

ADML_1B_265 M Felsic 64.2 0.002 0.66 3.9 0.5 2 11.3 0.49 0.025 7.9 0.069 0.2 1.2 9 1.2 12.8 3 110

ADML_1B_270 M Felsic 86.8 0.001 1.33 5.6 0.5 2.4 4.1 0.68 0.025 10.6 0.081 0.31 2 7 4.6 15.4 13 148

A13021 M Hydrated 0.16 - 68.6 - 2.5 1.7 1.9 - 0.1 4.9 0.118 0.25 0.95 104 2.1 6.78 28 87

A13023 M Hydrated 1.07 - 29.2 - 2.5 1 2.9 - 0.3 3.07 0.03 0.25 0.48 18 0.6 3.04 25 29.8

A13035 M Hydrated 0.08 - 16.3 - 2.5 0.7 5 - 0.1 1.12 0.008 0.25 0.8 56 0.8 1.47 48 5.5

A13053 M Hydrated 0.46 - 30.2 - 2.5 2.2 2.9 - 0.1 7.08 1 0.25 1.34 347 34.1 24.6 20 430

ADML_1B_043 M Hydrated 0.2 0.001 0.94 1.9 0.5 0.2 0.7 0.03 0.05 0.2 0.007 0.02 0.1 4 1.6 2.4 3 2

ADML_1B_044 M Hydrated 0.4 0.001 1.17 3.4 1 0.1 1.5 0.03 0.025 0.2 0.01 0.02 0.2 5 3.2 4.3 1 2.1

ADML_1B_048 M Hydrated 0.1 0.001 3.46 1.2 0.5 0.3 1.1 0.03 0.14 0.3 0.007 0.01 0.4 3 4 2.2 31 2.5

ADML_1B_075 M Hydrated 0.5 0.002 1.91 2.3 1 0.3 1.3 0.03 0.025 1.2 0.026 0.18 0.8 10 2 5.8 28 9.8

ADML_1B_076 M Hydrated 4.5 0.002 5.54 7 0.5 0.3 2.8 0.05 0.06 1.3 0.03 0.03 1.1 16 1.7 5.3 9 22.9

ADML_1B_078 M Hydrated 0.1 0.002 1.79 0.5 0.5 0.2 1.9 0.03 0.025 0.1 0.0025 0.01 0.1 2 3.9 2.9 10 0.7_ _ y

ADML_1B_226 M Hydrated 0.3 0.001 3.71 6.2 1 0.2 2.2 0.03 0.025 2.5 0.02 0.01 0.4 13 1.9 2.1 6 12.2

ADML_1B_228 M Hydrated 0.05 0.002 0.98 1.1 0.5 0.3 0.2 0.03 0.025 0.1 0.0025 0.02 0.05 7 0.6 0.5 2 1.5

ADML_1B_241 M Hydrated 32.7 0.001 4.73 22 2 1.2 34.3 0.37 0.09 8.2 0.315 0.24 1.2 281 3.1 17.2 33 87.5

ADML_1B_242 M Hydrated 11.7 0.001 1.95 35.3 0.5 1.2 30.8 0.43 0.025 5.3 0.452 0.1 0.9 202 1.2 15.2 12 71

ADML_1B_243 M Hydrated 1.9 0.001 3.38 1.8 0.5 0.9 1.4 0.03 0.025 0.2 0.01 0.02 0.1 15 16.6 1.9 25 3.5

ADML_1B_244 M Hydrated 2.2 0.002 3.94 2.2 0.5 0.6 1.6 0.03 0.025 0.4 0.019 0.01 0.1 17 20.6 2.3 15 5.8

ADML_1B_245 M Hydrated 0.2 0.001 0.41 0.7 0.5 0.6 2.1 0.03 0.025 0.2 0.0025 0.01 0.05 4 7.6 2.7 13 2.2

ADML_1B_246 M Hydrated 0.2 0.001 1.12 0.4 3 1.4 3.7 0.03 0.025 0.1 0.0025 0.01 0.05 4 10.4 1.2 13 1.7

ADML_1B_247 M Hydrated 0.1 0.002 1.81 0.4 0.5 0.8 0.7 0.03 0.025 0.1 0.0025 0.01 0.05 2 10.5 2.4 16 0.6

ADML_1B_248 M Hydrated 0.5 0.001 1.3 0.3 0.5 3.1 0.4 0.03 0.025 0.1 0.0025 0.01 0.05 3 1.8 0.7 2 1.2

ADML_1B_249 M Hydrated 0.8 0.003 31.7 3 0.5 2.5 20.5 0.03 0.09 0.7 0.015 0.04 0.3 13 5.1 5.6 19 11.4

ADML_1B_250 M Hydrated 0.4 0.001 3.47 0.5 0.5 2.7 2.6 0.03 0.025 0.1 0.0025 0.01 0.05 3 0.6 2.3 12 1.1

ADML_1B_251 M Hydrated 0.1 0.001 1.33 0.2 0.5 0.9 1.4 0.03 0.025 0.1 0.0025 0.01 0.05 4 9.5 1.4 3 1.1

ADML_1B_252 M Hydrated 92.9 0.001 37.8 53.3 1 0.5 2.5 0.03 0.19 0.1 0.135 0.36 0.4 461 0.5 4.3 112 53.6

ADML_1B_254 M Hydrated 0.7 0.002 2.11 0.5 0.5 1.1 2.4 0.03 0.05 0.1 0.0025 0.01 0.1 6 8.3 2.2 23 2

ADML_1B_255 M Hydrated 2.7 0.001 2.43 2.4 0.5 1.4 4.2 0.03 0.05 0.1 0.05 0.01 0.1 21 3.5 2.8 13 5.3

ADML_1B_256 M Hydrated 0.3 0.001 1.87 1.2 0.5 0.7 1.2 0.03 0.025 0.1 0.0025 0.02 0.05 11 22.9 1.6 11 0.7

ADML_1B_271 M Hydrated 74.7 0.001 3.8 24.4 2 2.3 6.6 0.63 0.41 8.9 0.439 0.58 3.7 171 1.6 15 24 186

ADML_1B_272 M Hydrated 19.9 0.001 0.82 45.9 0.5 0.6 6.5 0.16 0.11 1.7 0.376 0.38 1.5 240 1.2 21.7 75 62.2

ADML_1B_273 M Hydrated 0.7 0.001 1.07 1.1 0.5 0.4 0.8 0.03 0.05 0.1 0.009 0.01 0.1 8 4.9 3.6 13 3

A13022 M Mafic 0.12 - 28.7 - 2.5 2.4 1.6 - 0.1 1.92 0.041 0.25 0.57 43 1.5 2.78 43 34.3

A13031 M Mafic 0.97 - 5.9 - 2.5 0.7 4.3 - 0.1 0.88 0.604 0.25 0.3 235 0.3 16.2 141 58.3

A13032 M Mafic 8.35 - 2.5 - 2.5 0.25 6.2 - 0.1 0.56 0.378 0.25 0.29 232 0.8 10.9 90 29

A13048 M Mafic 3.91 - 1.8 - 2.5 1.4 3.9 - 0.1 1.32 1 0.25 0.44 566 11.3 8.28 62 122

ADML_1B_009 M Mafic 0.8 0.002 7.48 47.9 1 0.5 3.6 0.13 0.06 0.9 0.438 0.01 0.2 254 0.4 6.1 54 42.4

ADML_1B_011 M Mafic 1.3 0.001 2.3 42.6 1 0.7 3.6 0.2 0.025 1 0.563 0.01 0.3 186 0.6 1.1 27 47.8

ADML_1B_025 M Mafic 1.2 0.001 2.9 61 1 0.5 10 0.11 0.14 1 0.367 0.01 0.4 430 0.6 12.7 61 35.5

ADML_1B_026 M Mafic 0.7 0.001 1.99 46.3 0.5 0.4 5.1 0.1 0.08 0.6 0.353 0.01 0.2 189 0.4 9 69 33.3

ADML_1B_039 M Mafic 22.5 0.001 2.27 70.9 1 0.5 4.8 0.12 0.09 0.8 0.399 0.19 0.4 443 1 8.6 29 45

ADML_1B_056 M Mafic 0.05 0.006 3 9.9 1 1.7 1.9 0.56 0.5 5.8 0.371 0.01 4.4 220 2.8 14.8 274 192

ADML_1B_069 M Mafic 33.8 0.001 1.29 45.2 1 0.3 60 0.03 0.1 0.3 0.387 0.03 0.1 220 0.1 37.6 116 26.5

ADML_1B_070 M Mafic 6.2 0.001 1.98 38.8 1 0.3 51.3 0.05 0.06 0.3 0.351 0.06 0.1 234 0.1 14.6 91 24.1

ADML_1B_071 M Mafic 19.2 0.002 2.45 42.7 1 0.3 70.9 0.03 0.025 0.3 0.353 0.16 0.1 235 0.1 14.5 120 24.7

ADML_1B_191 M Mafic 0.1 0.002 1.82 8.3 3 2.8 17.4 0.67 0.025 8.4 0.13 0.04 3.2 59 2.1 26.1 846 226







SMC Sample ID Domain IDADML_1B_200 M Mafic 0.3 0.002 3.08 93 2 2.5 2.5 0.88 0.025 2.7 1.425 0.01 0.6 557 2.1 12.7 84 194

ADML_1B_208 M Mafic 18.5 0.002 2.61 90.1 3 0.6 3.4 0.2 0.025 1 0.737 0.18 0.4 596 7.1 7.6 54 86.9

ADML_1B_237 M Mafic 0.05 0.002 2.62 23.8 2 1.3 2.7 0.66 0.025 0.9 0.981 0.03 0.4 350 2 9.4 166 109

ADML_1B_238 M Mafic 41.7 0.001 4.77 51.2 1 0.3 12.3 0.07 0.025 0.4 0.382 0.48 0.1 228 4.5 23.9 171 37.5

ADML_1B_008 M Ore 0.1 0.002 3.78 2.3 2 0.2 1.9 0.03 0.19 0.2 0.005 0.04 0.3 12 0.4 0.7 13 1.4

ADML_1B_029 M Ore 0.05 0.001 22.9 9.9 6 0.4 0.5 0.03 0.59 0.4 0.009 0.01 0.3 9 0.4 0.6 11 3.9

ADML_1B_031 M Ore 0.05 0.001 17.6 2.7 3 0.4 1.1 0.03 0.56 1 0.01 0.01 0.4 19 0.7 3.5 17 6.2

ADML_1B_042 M Ore 0.2 0.001 7.14 22.3 1 1.3 2.8 0.03 0.35 0.1 0.007 0.01 0.4 65 2.9 5.2 61 1.6

ADML_1B_054 M Ore 0.1 0.001 51.9 7 2 0.6 1.7 0.06 0.6 2.3 0.025 0.02 0.5 109 0.7 2.2 42 25.1

ADML_1B_055 M Ore 0.2 0.001 39 5.4 8 0.3 1.5 0.03 0.56 0.4 0.008 0.01 0.4 43 0.6 0.7 25 2.7

ADML_1B_057 M Ore 0.2 0.001 13.3 22.9 4 0.7 0.6 0.03 0.68 1.3 0.057 0.01 0.5 60 2 2.8 21 18

ADML_1B_064 M Ore 0.1 0.001 1.03 9.2 0.5 0.7 2.4 0.03 0.63 0.1 0.006 0.01 0.3 119 0.2 3.6 29 0.9

ADML_1B_066 M Ore 0.1 0.001 23 3.8 14 0.7 1.8 0.03 0.86 2 0.029 0.01 0.4 32 0.5 1.8 37 24.8

ADML_1B_072 M Ore 0.2 0.001 22.6 18.1 13 0.5 1.2 0.03 0.48 3.7 0.037 0.01 0.5 20 1.2 1.3 12 21.4

ADML_1B_188 M Ore 0.2 0.001 2.36 18.9 1 0.3 1.9 0.03 0.025 0.1 0.0025 0.01 0.1 45 6.6 4.3 33 2.2

ADML_1B_189 M Ore 0.4 0.002 2.18 1.6 0.5 0.6 0.6 0.03 0.025 0.2 0.005 0.01 0.1 5 7.3 2.1 32 2.2

ADML_1B_192 M Ore 0.1 0.002 5.31 3.7 10 0.2 0.6 0.03 0.06 0.3 0.007 0.01 0.2 5 3 0.4 9 3.5

ADML_1B_209 M Ore 0.3 0.002 85.4 21.4 4 1.7 1.6 0.03 0.9 2.6 0.035 0.05 1.1 433 1.7 3.3 47 28.5

ADML_1B_210 M Ore 0.2 0.001 34.6 7.1 6 0.3 1.8 0.03 0.12 1 0.01 0.01 0.4 57 2.2 0.9 26 2.9

ADML_1B_030 M Ore Hi Al 0.4 0.002 2.75 5 0.5 0.3 3.5 0.03 0.46 1.1 0.011 0.02 0.2 19 5.5 7.9 26 12.5

ADML_1B_053 M Ore Hi Al 0.2 0.001 3.01 19.5 1 0.9 3 0.03 0.49 0.3 0.015 0.04 0.3 272 2.3 6.6 48 5.6

ADML_1B_058 M Ore Hi Al 0.1 0.001 6.82 10.2 1 1.7 1.6 0.03 0.48 0.7 0.019 0.01 0.3 64 5.1 1.7 13 8.9

ADML_1B_190 M Ore Hi Al 0.1 0.002 2.44 10.9 2 0.5 0.7 0.05 0.16 1.5 0.022 0.01 0.8 45 9.8 1.8 24 14.8

ADML_1B_194 M Ore Hi Al 21.5 0.002 2.99 16.6 2 0.8 3.5 0.14 0.17 2.9 0.181 0.41 0.6 145 0.5 4.6 38 58.4

ADML_1B_195 M Ore Hi Al 0.9 0.002 5.92 10.2 2 0.4 15.9 0.07 0.14 0.7 0.145 0.4 1.3 222 1.1 5.1 140 18

ADML_1B_198 M Ore Hi Al 0.8 0.002 46.3 7.5 12 2.1 3.1 0.31 0.48 5.6 0.141 0.04 1.5 61 4.2 15.8 21 78.2

ADML_1B_202 M Ore Hi Al 3 0.002 26 23.4 5 1.5 8.4 0.18 0.37 9.6 0.107 0.02 2.3 118 11.2 12.4 15 83

ADML_1B_231 M Ore Hi Al 20.4 0.002 21.3 12.3 13 2.8 3 0.27 0.56 6.8 0.162 0.4 1.5 53 1.9 8 24 111.5

ADML_1B_234 M Ore Hi Al 0.1 0.001 3.87 64.1 1 0.3 2.8 0.03 0.11 0.5 0.029 0.02 0.4 31 2.8 5.5 34 7.2_ _

ADML_1B_235 M Ore Hi Al 1 0.002 46.9 19.2 7 1.6 3 0.17 0.88 8.2 0.126 0.02 1.7 109 2.7 5.3 6 62

ADML_1B_236 M Ore Hi Al 0.05 0.001 42.1 8.8 2 0.7 0.8 0.03 0.19 2 0.04 0.01 0.6 19 1.2 4.1 26 16.4

ADML_1B_013 M Ore Hi SiO2 1.1 0.001 9.66 8.7 2 0.4 3.6 0.03 0.78 0.8 0.051 0.4 0.4 37 1 1.5 14 13

ADML_1B_020 M Ore Hi SiO2 0.1 0.001 12.45 1.7 0.5 0.2 9.2 0.03 0.33 0.1 0.0025 0.01 0.4 17 6 14 44 0.7

ADML_1B_028 M Ore Hi SiO2 0.6 0.001 59.5 9.4 20 1 3.7 0.05 0.75 3.2 0.031 0.02 0.6 118 0.9 2 18 22.5

ADML_1B_052 M Ore Hi SiO2 0.2 0.001 2.49 21.8 0.5 0.3 5.5 0.03 0.38 0.1 0.008 0.02 0.2 95 2.5 5.7 58 1.3

ADML_1B_059 M Ore Hi SiO2 0.1 0.001 12.2 3.5 0.5 0.4 1 0.03 0.48 0.4 0.009 0.01 0.2 21 11.1 6.8 36 3.9

ADML_1B_065 M Ore Hi SiO2 0.2 0.001 9.86 7.8 1 0.8 3.7 0.03 0.68 0.3 0.014 0.01 0.1 120 4 3.6 33 4.4

ADML_1B_073 M Ore Hi SiO2 0.5 0.001 8.05 15.3 9 0.7 1.9 0.03 0.42 1.8 0.036 0.01 0.5 28 1 3.5 16 14.6

ADML_1B_196 M Ore Hi SiO2 0.3 0.001 5.1 6.5 1 0.9 2.4 0.03 0.32 0.6 0.024 0.01 0.4 43 1.2 5.6 56 9.9

ADML_1B_199 M Ore Hi SiO2 0.2 0.002 2.81 0.5 0.5 0.2 1.4 0.03 0.025 0.1 0.0025 0.01 0.1 6 4.3 3.3 10 1.4

ADML_1B_201 M Ore Hi SiO2 1.1 0.002 27.1 19.2 3 0.6 3.4 0.06 0.17 3 0.054 0.01 0.8 121 4.3 2.9 7 26.1

ADML_1B_203 M Ore Hi SiO2 0.2 0.002 11.3 27.9 1 1.3 2.6 0.03 0.21 1 0.018 0.08 0.7 290 2.2 6.3 67 8.1

ADML_1B_207 M Ore Hi SiO2 0.3 0.002 5.15 5.4 4 1.1 1.2 0.23 0.26 1 0.235 0.01 1.1 127 10.7 3.8 10 27.4

ADML_1B_230 M Ore Hi SiO2 0.05 0.002 35.3 21.1 8 1.3 0.9 0.14 0.34 1.5 0.676 0.01 0.7 185 1.8 5.9 13 86

ADML_1B_232 M Ore Hi SiO2 0.4 0.001 2.23 11.9 1 0.5 2 0.03 0.07 0.6 0.016 0.02 0.2 68 2.2 5.3 75 8.7

ADML_1B_233 M Ore Hi SiO2 0.3 0.002 54.2 22.4 6 0.3 2.2 0.03 0.38 1.1 0.021 0.01 0.5 128 0.9 0.9 6 9.3

A13026 M Shale 131 - 3.7 - 2.5 1.3 9.5 - 0.1 9.95 0.286 0.5 3 118 1 14.7 118 161

A13027 M Shale 56.9 - 4.1 - 2.5 0.8 20.3 - 0.1 4.86 0.249 0.25 1.68 128 1 14 98 123

A13038 M Shale 105 - 3.3 - 2.5 1.1 19.5 - 0.1 8.46 0.273 0.25 2.66 111 1 14.2 109 148

A13039 M Shale 73.5 - 4.3 - 2.5 0.9 21.4 - 0.1 6.59 0.269 0.25 2.14 140 0.6 16.6 110 143

A13058 M Shale 104 - 2.6 - 2.5 1.2 7.5 - 0.1 9.72 0.381 0.6 3.07 130 3.9 20.5 111 184

ADML_1B_274 M Shale 47.8 0.01 17 16 2 1.4 5.9 0.46 0.27 5.2 0.329 0.35 2.8 125 2.5 10 93 158.5

ADML_1B_275 M Shale 95.9 0.003 5.85 19.9 3 1.4 6.5 0.54 0.31 9 0.358 0.43 3.1 133 5.2 20 134 170.5

ADML_1B_276 M Shale 116.5 0.01 9.85 21.9 2 2.4 5.4 0.51 0.37 8 0.369 0.51 2.9 148 2.2 15.9 93 170.5

ADML_1B_277 M Shale 3.9 0.007 4.45 17.3 3 0.9 1.6 0.37 0.31 5.3 0.29 0.31 2.7 130 2.1 15.5 105 118.5

ADML_1B_280 M Shale 0.7 0.015 60.4 14.2 12 0.7 2.8 0.6 0.86 8 0.475 0.08 2.3 84 3.2 11.7 6 164

ADML_1B_281 M Shale 0.2 0.013 6.95 14.2 1 1.6 2.5 0.52 0.38 6.2 0.395 0.01 4.5 231 2.9 17.3 265 211

ADML_1B_282 M Shale 0.6 0.003 7.73 31.9 1 1.4 7.6 0.32 0.56 11.8 0.248 0.01 5.1 230 1.3 24.1 50 270

ADML_1B_283 M Shale 55.7 0.002 5.62 21.3 0.5 1.3 7.7 0.34 0.4 9.5 0.228 0.54 3 151 1.2 15.8 44 192

ADML_1B_284 M Shale 66.5 0.001 8.32 19.3 0.5 1.3 7.4 0.41 0.32 8.6 0.282 0.76 2.7 134 1.4 14.6 34 177

ADML_1B_285 M Shale 55.2 0.001 5.47 22.4 1 1.7 13.8 0.45 0.31 11 0.289 0.69 4.3 222 2.1 9.7 36 334

ADML_1B_286 M Shale 63.1 0.001 21.3 28.3 2 1.6 13.9 0.44 0.67 10.8 0.341 0.6 4 348 2 12.6 75 301

ADML_1B_287 M Shale 10.5 0.001 2.84 19.8 0.5 1.5 19.8 0.45 0.46 8.3 0.315 0.19 3.4 216 2 10.1 39 249







SMC Sample ID Domain IDADML_1B_288 M Shale 97.8 0.001 9.57 30.7 2 2.1 29.6 0.63 0.7 15.2 0.379 0.8 4.7 250 1.9 19 53 356

A13003 B BIF 0.97 - 9.6 - 2.5 0.25 3.3 - 0.1 0.12 0.039 0.25 0.14 65 18.4 5.65 71 4.4

A13004 B BIF 0.39 - 9 - 2.5 0.25 2 - 0.1 0.36 0.008 0.25 0.06 4 12.7 2.98 50 2.6

A13005 B BIF 0.16 - 11.2 - 2.5 1.4 1.8 - 0.1 0.22 0.012 0.25 0.25 10 39.3 7.34 105 5.5

A13006 B BIF 0.19 - 7.5 - 2.5 1.3 2 - 0.1 0.84 0.026 0.25 0.27 34 162 9.87 186 11.5

A13011 B BIF 6.5 - 4.8 - 2.5 1.2 12.1 - 0.1 0.87 0.071 0.25 1.6 119 17 15.7 49 13.7

A13013 B BIF 1.02 - 6.8 - 2.5 0.6 84.9 - 0.1 0.27 0.057 0.25 0.93 22 23.2 10.6 30 10.6

A13014 B BIF 0.29 - 4.4 - 2.5 0.25 53.6 - 0.1 0.49 0.013 0.25 4.49 34 76.6 10.7 39 7.7

A13015 B BIF 0.21 - 3.1 - 2.5 0.25 16.4 - 0.1 0.16 0.035 0.25 0.65 23 5.3 9.54 40 6.6

A13016 B BIF 0.31 - 3.4 - 2.5 2 9.5 - 0.1 0.24 0.019 0.25 0.74 16 5.5 19 53 5.3

A13042 B BIF 0.2 - 6 - 2.5 0.7 24.2 - 0.1 0.14 0.016 0.25 1.31 28 95.5 11.5 23 5.2

A13043 B BIF 0.25 - 4.1 - 2.5 0.9 17.8 - 0.1 0.45 0.017 0.25 3.89 39 66.9 10.9 25 8

A13044 B BIF 0.23 - 10.3 - 2.5 0.25 3.5 - 0.1 0.18 0.03 0.25 0.49 107 19.5 7.56 36 5

ADML_1B_083 B BIF 0.1 0.002 4.57 2.4 0.5 0.2 1.4 0.03 0.025 0.2 0.011 0.01 0.1 12 1.5 3.6 15 4

ADML_1B_084 B BIF 0.2 0.001 5.35 1.4 0.5 0.2 1.5 0.03 0.025 0.1 0.009 0.01 0.05 8 1.3 2.7 12 2.7

ADML_1B_098 B BIF 0.5 0.002 9.73 4.1 0.5 0.3 2.2 0.03 0.025 0.2 0.012 0.01 0.1 18 22.5 3.5 31 2.3

ADML_1B_100 B BIF 0.1 0.002 8.24 2.2 0.5 0.4 3.4 0.03 0.025 0.3 0.008 0.01 0.1 8 6.6 4.6 30 3.1

ADML_1B_107 B BIF 0.5 0.003 11.75 7.9 1 0.6 2.4 0.03 0.09 0.5 0.044 0.02 0.2 54 4.2 7.6 34 8.4

ADML_1B_130 B BIF 0.4 0.001 4.87 81.1 2 1 9.4 0.11 0.35 1.2 0.191 0.05 2.1 143 1.9 7.9 54 27.9

ADML_1B_138 B BIF 0.3 0.002 8.22 24.2 1 0.4 4.2 0.03 0.1 0.3 0.015 0.01 0.2 21 31.5 4.1 58 3.7

ADML_1B_138 B BIF 27 0.002 2.79 33 1 0.4 6.5 0.09 0.025 1 0.285 0.13 0.2 195 1.2 5.5 13 34.6

ADML_1B_149 B BIF 11.3 0.002 0.45 40.7 1 0.5 70.5 0.12 0.025 1 0.466 0.04 0.2 245 0.8 19.4 113 36.4

ADML_1B_156 B BIF 14.3 0.002 0.64 49.6 1 0.6 105.5 0.15 0.025 1.2 0.546 0.14 0.3 302 0.3 50 193 44.1

ADML_1B_174 B BIF 6 0.002 2.73 2.2 1 0.5 19.6 0.03 0.025 0.6 0.021 0.01 0.3 17 10.7 5.1 10 6.3

ADML_1B_185 B BIF 0.2 0.007 6.4 1.2 0.5 0.3 9 0.03 0.025 0.4 0.01 0.01 0.3 7 23 2.6 27 4.2

ADML_1B_186 B BIF 0.2 0.002 6.98 0.6 0.5 0.2 1.1 0.03 0.025 0.2 0.008 0.01 0.1 7 24.9 2.2 13 3.1

ADML_1B_197 B BIF 0.2 0.002 5.81 16.5 1 0.9 3.9 0.03 0.94 0.9 0.076 0.07 0.9 277 1.4 5.7 39 17.8

ADML_1B_221 B BIF 0.3 0.002 9.23 3.2 0.5 0.4 1.8 0.03 0.025 0.2 0.012 0.02 0.1 9 42.1 4.3 61 3.7

A13001 B Mafic 167 - 2.8 - 2.5 0.7 20.7 - 0.1 1.73 0.791 0.25 0.52 349 0.4 54.8 140 80

A13002 B Mafic 62.9 - 3.9 - 2.5 0.7 13.1 - 0.1 2.13 0.659 0.25 0.66 289 2.7 28.1 112 75.7

A13007 B Mafic 14.1 - 39.5 - 2.5 0.7 5.1 - 0.1 0.77 0.335 0.25 0.25 268 22.2 11.3 170 66.4

A13008 B Mafic 67.5 - 7.5 - 2.5 0.25 22.7 - 0.1 0.79 0.36 0.25 0.19 222 5.4 10.8 83 63.8

A13009 B Mafic 31.1 - 1 - 2.5 0.7 14.2 - 0.1 1.13 0.362 0.25 0.32 258 1 3.71 30 43.7

A13010 B Mafic 2.7 - 0.7 - 2.5 0.6 34.1 - 0.1 1.19 0.55 0.25 0.51 175 0.8 14.3 118 47.5

A13012 B Mafic 1.99 - 0.5 - 2.5 0.6 4.7 - 0.1 1.25 0.783 0.25 0.55 252 1.2 7.21 113 58.8

A13017 B Mafic 0.72 - 0.4 - 2.5 0.25 4.6 - 0.1 1.45 0.688 0.25 1.24 284 5 9.04 126 62.5

A13018 B Mafic 57 - 0.7 - 2.5 0.6 114 - 0.1 1.45 0.635 0.25 0.43 285 0.8 25.3 116 53.9

A13040 B Mafic 3.08 - 0.5 - 2.5 0.6 30.2 - 0.1 1.47 0.762 0.25 0.72 226 0.3 33.5 109 79.1

A13041 B Mafic 1.42 - 0.3 - 2.5 0.5 9.2 - 0.1 1.02 0.62 0.25 0.27 230 0.5 8.56 104 58

A13045 B Mafic 0.59 - 0.5 - 2.5 0.25 14.2 - 0.1 1.65 0.541 0.25 0.81 336 8.9 19.9 158 71.1

A13046 B Mafic 7.25 - 1.3 - 2.5 0.25 24.7 - 0.1 1.32 0.579 0.25 0.34 286 1.5 14.2 76 56.8

ADML_1B_006 B Mafic 0.8 0.003 0.24 18.2 0.5 0.5 6.9 0.2 0.025 0.9 0.451 0.01 0.4 300 0.5 15.3 93 48

ADML_1B_007 B Mafic 5.3 0.001 0.45 53.7 0.5 0.7 12.2 0.2 0.025 1.2 0.499 0.01 0.4 174 0.7 14.1 226 49.4

ADML_1B_079 B Mafic 28.8 0.002 61.4 64.4 1 0.6 12.2 0.1 0.025 2 0.325 0.17 0.5 363 3.2 26.6 42 83.4

ADML_1B_080 B Mafic 7.8 0.002 4.01 44.4 0.5 0.6 4.4 0.17 0.025 0.8 0.582 0.17 0.3 400 10.5 8.3 120 91.9

ADML_1B_081 B Mafic 2.8 0.002 2.04 55.9 0.5 0.6 6.9 0.17 0.025 1.8 0.631 0.02 0.4 295 5.9 7.1 36 54.8

ADML_1B_082 B Mafic 1.6 0.002 0.45 59.5 1 0.6 3.3 0.18 0.025 1 0.553 0.01 0.3 267 0.3 11.9 65 40.5

ADML_1B_085 B Mafic 7.8 0.003 0.45 44.7 1 0.4 70.5 0.12 0.025 1.1 0.365 0.02 0.3 206 0.2 15.1 68 41.7

ADML_1B_086 B Mafic 9.1 0.002 1.05 37.3 1 0.5 35.9 0.15 0.025 1.4 0.54 0.07 0.2 231 0.3 29.2 62 46.3

ADML_1B_087 B Mafic 107 0.003 0.85 54.6 1 0.6 178 0.18 0.025 1.6 0.651 0.39 0.5 327 0.3 24.6 114 59.1

ADML_1B_088 B Mafic 52.1 0.002 6.45 44.6 1 0.5 12.7 0.15 0.025 1.4 0.386 0.12 0.5 237 3.2 19.4 37 89.1

ADML_1B_089 B Mafic 3.8 0.003 0.55 34.4 1 0.7 6.9 0.19 0.025 1.1 0.531 0.02 0.3 221 0.7 7.2 79 56.2

ADML_1B_090 B Mafic 1.1 0.002 0.42 43.3 1 0.5 7 0.21 0.025 1.2 0.607 0.01 0.6 275 0.7 15.2 133 65.1

ADML_1B_091 B Mafic 1.4 0.002 0.33 26 1 0.6 5.2 0.22 0.025 1.2 0.616 0.01 0.3 166 0.5 13 86 64.1

ADML_1B_092 B Mafic 7.5 0.002 1.09 39.8 1 0.5 37.9 0.15 0.025 1.4 0.549 0.07 0.2 243 0.3 27.5 67 48.4

ADML_1B_093 B Mafic 26.6 0.002 0.77 55.7 1 0.6 66.9 0.17 0.025 1.8 0.599 0.14 0.3 292 0.5 36.1 93 56.4

ADML_1B_094 B Mafic 33 0.003 0.75 40.5 1 0.3 94.8 0.11 0.025 1.1 0.427 0.16 0.3 209 0.2 26 91 36.3

ADML_1B_095 B Mafic 5.3 0.001 0.84 66.6 1 0.4 57.2 0.16 0.025 1.8 0.402 0.01 0.3 192 0.2 39.5 136 50.7

ADML_1B_096 B Mafic 16.6 0.002 0.46 50.5 1 0.4 129 0.12 0.025 1.4 0.317 0.03 0.2 160 0.1 19 60 40.2

ADML_1B_097 B Mafic 58.4 0.002 3.77 50.6 1 0.8 8.9 0.15 0.025 1.6 0.56 0.07 0.9 292 3.3 30.7 75 63.3

ADML_1B_103 B Mafic 9.2 0.002 34.4 41.2 1 0.9 4.8 0.19 0.05 1 0.309 0.06 0.3 245 3.7 9.6 124 61.3

ADML_1B_104 B Mafic 20.6 0.002 49.5 31.6 1 0.6 6.2 0.23 0.025 0.7 0.438 0.12 0.2 235 2.4 12.1 107 48.9

ADML_1B_105 B Mafic 1.5 0.003 1.9 34 1 0.6 20.8 0.17 0.025 2.2 0.319 0.05 0.4 213 0.3 7.2 20 56.7







SMC Sample ID Domain IDADML_1B_106 B Mafic 0.7 0.003 1.71 37.1 1 0.3 3.4 0.1 0.025 1.3 0.203 0.02 0.5 176 0.6 12.2 88 35

ADML_1B_108 B Mafic 3.7 0.002 1.01 55.8 1 0.6 5.2 0.22 0.025 1.8 0.629 0.01 0.6 252 2.9 5 41 60.6

ADML_1B_112 B Mafic 0.2 0.003 1.17 49.6 1 4.1 8.6 0.26 0.29 0.9 0.787 0.01 0.5 348 2.4 16.1 213 76.1

ADML_1B_113 B Mafic 0.9 0.001 0.72 26.9 1 0.9 9.9 0.19 0.025 0.6 0.47 0.01 0.2 229 0.8 8.4 268 43.6

ADML_1B_114 B Mafic 4.5 0.003 1.13 38.8 1 0.5 145.5 0.17 0.025 0.8 0.443 0.02 0.2 223 0.2 16.7 99 33.8

ADML_1B_116 B Mafic 0.7 0.002 0.48 86.4 1 0.6 26.7 0.21 0.025 1.3 0.545 0.01 0.7 322 1.4 14 95 67

ADML_1B_117 B Mafic 3.8 0.003 0.82 32.5 1 0.7 15 0.27 0.025 1.5 0.67 0.01 0.4 194 1 14.9 111 75.3

ADML_1B_119 B Mafic 20.1 0.002 1.76 62.9 1 0.5 22.1 0.17 0.025 1.5 0.659 0.03 0.7 378 0.6 16.3 120 48.5

ADML_1B_120 B Mafic 5.2 0.002 0.99 41.8 3 0.4 104 0.15 0.025 1 0.458 0.03 0.3 238 3.8 146.5 104 30.9

ADML_1B_121 B Mafic 10.8 0.003 1.21 55.9 1 0.9 46.8 0.16 0.025 1.4 0.6 0.03 0.3 302 0.3 54.9 160 48

ADML_1B_122 B Mafic 17.3 0.003 1.73 41.2 1 0.6 102 0.11 0.025 1 0.397 0.06 0.3 235 0.4 18.3 94 27.6

ADML_1B_123 B Mafic 0.5 0.001 0.56 78.5 1 0.7 34.3 0.26 0.025 1.5 0.68 0.03 0.8 273 0.8 21.9 49 58.8

ADML_1B_124 B Mafic 16.9 0.001 0.95 42.7 0.5 0.6 23 0.17 0.025 1.1 0.497 0.01 0.3 232 0.6 10 102 51.7

ADML_1B_126 B Mafic 0.6 0.002 0.29 14.9 0.5 0.4 10.7 0.15 0.025 0.6 0.357 0.01 0.2 193 0.7 4.9 85 32.1

ADML_1B_128 B Mafic 2.1 0.002 0.29 32.7 1 0.6 10.1 0.19 0.025 1.3 0.576 0.02 0.4 311 1.2 12.5 93 55.1

ADML_1B_129 B Mafic 1.5 0.002 2.81 55.3 1 0.7 5.8 0.15 0.06 2.3 0.3 0.02 0.7 355 1.2 6.6 41 76.8

ADML_1B_131 B Mafic 1.5 0.001 0.72 39.1 1 0.5 19.3 0.13 0.05 1.5 0.304 0.01 0.3 154 0.3 8.6 120 39

ADML_1B_132 B Mafic 0.5 0.001 0.5 25.8 0.5 0.3 10.7 0.08 0.025 0.9 0.185 0.01 0.1 118 0.2 11.4 70 22.7

ADML_1B_133 B Mafic 0.4 0.001 0.19 24.2 0.5 0.3 8.4 0.09 0.025 0.9 0.183 0.01 0.2 115 0.1 6.5 68 24.2

ADML_1B_134 B Mafic 4.7 0.002 0.25 36.6 1 0.5 50.1 0.16 0.025 1.8 0.345 0.01 0.9 177 0.4 50.3 66 46.2

ADML_1B_135 B Mafic 14.9 0.002 0.26 41.3 1 0.8 15.6 0.23 0.025 0.7 0.569 0.14 0.6 406 2.2 10.3 140 80

ADML_1B_136 B Mafic 17.8 0.002 0.28 38.3 1 0.4 10.4 0.18 0.025 1.1 0.403 0.04 0.3 204 0.2 14 86 43.7

ADML_1B_137 B Mafic 5.7 0.002 2.71 67.9 1 0.7 18.3 0.19 0.06 1.4 0.569 0.01 0.4 400 0.3 4.5 39 88.3

ADML_1B_139 B Mafic 8.5 0.002 6.76 51.4 1 0.7 86.9 0.19 0.05 1.4 0.586 0.06 0.5 332 0.9 3.2 61 55.3

ADML_1B_140 B Mafic 33.2 0.002 1.86 85.5 1 0.5 7.8 0.17 0.06 1.4 0.452 0.09 0.3 245 0.4 5.2 26 42.1

ADML_1B_141 B Mafic 44.9 0.002 0.74 40 2 0.5 135 0.11 0.025 0.7 0.277 0.08 0.2 178 0.3 80.4 96 26.5

ADML_1B_142 B Mafic 17 0.002 1.09 40.3 0.5 0.4 82.9 0.1 0.025 0.7 0.274 0.03 0.2 183 0.2 29.1 55 28.1

ADML_1B_143 B Mafic 13.4 0.001 99.4 38.8 1 0.9 7.1 0.14 0.08 0.9 0.337 0.11 0.7 379 21.9 6.4 87 80

ADML_1B_144 B Mafic 0.7 0.002 16.55 26.1 0.5 0.8 5.5 0.05 0.1 0.9 0.042 0.24 0.5 54 105.5 12.5 87 14_ _

ADML_1B_146 B Mafic 0.6 0.001 13.05 1.5 1 0.3 0.6 0.03 0.1 0.1 0.006 0.01 0.1 7 50 1.9 18 1.3

ADML_1B_150 B Mafic 11.7 0.001 0.4 40.2 1 0.5 74.1 0.1 0.025 1 0.387 0.04 0.3 227 0.2 17.3 81 34.5

ADML_1B_151 B Mafic 33.8 0.002 0.4 37.3 1 0.5 79.5 0.15 0.025 1.5 0.344 0.07 0.4 191 0.3 21.8 87 53.6

ADML_1B_152 B Mafic 75.9 0.002 0.86 36.3 3 0.8 68.3 0.42 0.025 4.1 0.876 0.25 0.9 195 0.8 60.3 81 139.5

ADML_1B_153 B Mafic 0.7 0.001 0.92 61.9 1 1.2 17.8 0.26 0.025 1 0.802 0.01 0.3 388 0.5 10 96 62.8

ADML_1B_154 B Mafic 1.9 0.001 0.9 26.3 1 0.7 5.1 0.07 0.025 0.8 0.247 0.01 0.5 181 0.5 7.4 62 20.4

ADML_1B_155 B Mafic 2.6 0.001 0.81 72.8 1 0.7 8.4 0.2 0.025 1.6 0.753 0.01 0.6 375 0.3 31.4 76 61.1

ADML_1B_157 B Mafic 7 0.002 0.31 40.5 1 0.5 97.3 0.11 0.025 1 0.395 0.03 0.3 229 0.3 17.5 83 28.3

ADML_1B_158 B Mafic 2.4 0.002 0.31 54.2 1 0.6 32.4 0.15 0.025 1 0.555 0.02 0.2 321 0.6 7.9 108 35.9

ADML_1B_159 B Mafic 0.7 0.001 1.35 58.7 1 0.9 5.3 0.16 0.025 1.3 0.65 0.01 0.3 319 0.8 4 60 53.7

ADML_1B_160 B Mafic 3.8 0.001 1.93 52.7 1 0.7 69.9 0.15 0.025 1.2 0.514 0.02 0.3 289 0.4 40.2 178 26

ADML_1B_161 B Mafic 1.7 0.002 0.98 37.9 0.5 0.7 60.3 0.12 0.025 0.8 0.399 0.03 0.2 232 0.5 15.6 147 19.5

ADML_1B_162 B Mafic 0.5 0.001 0.46 45.2 1 0.6 13.4 0.21 0.025 1 0.56 0.01 0.7 323 0.9 6.1 45 58.7

ADML_1B_163 B Mafic 0.1 0.002 2.29 6.9 0.5 0.8 8.2 0.03 0.09 0.1 0.013 0.02 0.9 39 58.8 7.6 3 2.3

ADML_1B_164 B Mafic 15.5 0.001 0.25 37.3 0.5 0.4 138.5 0.15 0.025 1.5 0.333 0.06 0.4 190 0.6 13.2 66 38.8

ADML_1B_167 B Mafic 9.6 0.002 1.64 49.6 1 1.1 38.9 0.13 0.025 1.2 0.488 0.1 0.3 284 0.7 31.7 178 41.3

ADML_1B_168 B Mafic 6.8 0.002 0.58 45.9 1 0.5 75.2 0.12 0.025 1 0.497 0.02 0.2 247 0.2 20.2 86 37.8

ADML_1B_169 B Mafic 0.2 0.002 5.57 7.3 0.5 0.2 1 0.03 0.025 0.4 0.035 0.01 0.1 30 19.5 3.3 43 4.9

ADML_1B_175 B Mafic 0.4 0.002 1.18 27.5 1 1.4 4 0.24 0.23 0.9 0.795 0.01 0.5 326 4.7 9 300 87.2

ADML_1B_005 B Mafic 1 0.002 0.54 57.7 1 0.4 6.4 0.14 0.06 1.6 0.27 0.01 0.7 324 0.9 34 109 65.8

ADML_1B_179 B Magnetite 0.2 0.003 3.68 1.1 0.5 0.2 5.4 0.03 0.025 0.4 0.012 0.01 0.4 11 2.4 10.5 19 5.1

ADML_1B_180 B Magnetite 0.2 0.002 4.4 1.7 1 0.7 34.5 0.03 0.025 0.6 0.02 0.01 4.2 17 37 11.8 17 7.9

ADML_1B_181 B Magnetite 0.5 0.002 2.58 9.7 1 0.4 13.5 0.03 0.025 0.3 0.178 0.01 1.1 73 3.6 13.2 43 19.1

ADML_1B_222 B Magnetite 1.4 0.002 7.2 1.6 0.5 0.4 10.9 0.03 0.025 0.3 0.012 0.01 0.1 12 7.2 4.8 14 4.2

ADML_1B_002 B Ore 0.1 0.001 6.48 2 0.5 0.6 4.9 0.03 0.09 0.2 0.015 0.01 0.1 16 8.7 9.6 47 3.7

ADML_1B_102 B Ore 0.2 0.003 10.05 10.9 1 0.6 3.1 0.15 0.06 0.4 0.011 0.01 0.3 42 13.3 8.5 152 5.2

ADML_1B_109 B Ore 0.1 0.002 3.09 12.9 0.5 1.3 7.9 0.03 0.08 0.2 0.01 0.01 0.3 11 0.6 4 42 3

ADML_1B_111 B Ore 0.1 0.003 14.8 3.5 0.5 0.5 3.1 0.03 0.09 0.4 0.016 0.01 0.2 12 4.7 14 22 5.9

ADML_1B_115 B Ore 1.1 0.003 5.22 16.3 1 0.5 19.1 0.03 0.05 0.7 0.037 0.01 0.6 34 11 11.3 11 8.2

ADML_1B_118 B Ore 0.1 0.002 5.32 2.8 0.5 0.5 11.4 0.03 0.07 0.3 0.016 0.01 0.6 21 89.9 12.5 17 4.7

ADML_1B_125 B Ore 0.1 0.002 7.54 2.4 0.5 0.5 52.7 0.03 0.05 0.3 0.013 0.01 0.4 16 63.4 15.6 6 4.9

ADML_1B_147 B Ore 27.5 0.002 0.76 30.4 1 0.4 80.9 0.12 0.025 1 0.391 0.15 0.3 209 1.4 17.8 96 31

ADML_1B_171 B Ore 0.1 0.002 19.45 2.9 0.5 0.3 2.2 0.03 0.025 0.3 0.009 0.01 0.2 9 3.4 7.6 38 3.9

ADML_1B_173 B Ore 0.05 0.003 10.2 2.5 1 0.6 1.4 0.03 0.025 0.6 0.024 0.01 0.2 22 0.5 6.2 40 9.8







SMC Sample ID Domain IDADML_1B_177 B Ore 0.3 0.003 11.85 1.6 0.5 0.3 1.1 0.03 0.025 0.3 0.014 0.01 0.3 38 51.8 9.1 34 3.8

ADML_1B_178 B Ore 0.2 0.003 5.67 1.2 0.5 0.6 10 0.03 0.025 0.1 0.007 0.01 2.8 18 68.7 7.5 17 2.4

ADML_1B_224 B Ore 0.6 0.002 9.41 16.7 1 1.3 11.4 0.1 0.09 1.7 0.074 0.01 1.8 94 22 18.1 42 23.3

ADML_1B_110 B Ore Hi Al 0.2 0.002 4.83 45.1 0.5 0.9 146.5 0.03 0.09 0.3 0.073 0.01 0.8 52 8 5.2 33 9.2

ADML_1B_127 B Ore Hi Al 0.4 0.001 8.66 10.1 0.5 0.6 4.6 0.05 0.09 0.3 0.147 0.01 0.9 196 16.6 12.6 47 17.2

ADML_1B_145 B Ore Hi Al 0.3 0.001 15.75 17.9 0.5 0.8 1.1 0.03 0.16 0.4 0.021 0.03 0.3 24 45.9 7.6 80 5.9

ADML_1B_145 B Ore Hi Al 0.1 0.001 9.91 3.2 0.5 0.3 0.8 0.03 0.08 0.1 0.005 0.01 0.1 6 122 3.7 39 2.1

ADML_1B_172 B Ore Hi Al 0.2 0.002 6.58 5.2 1 1.2 3.3 0.18 0.08 5.3 0.078 0.01 0.9 67 2.2 21.1 95 39.1

ADML_1B_182 B Ore Hi Al 0.2 0.002 4.88 26.8 1 0.5 7.7 0.16 0.025 1.3 0.315 0.01 0.6 159 9.7 14.8 64 83.2

ADML_1B_183 B Ore Hi Al 1 0.002 3.3 29.1 1 0.6 17.2 0.03 0.025 0.6 0.024 0.13 0.7 55 9.3 9.8 43 8.1

ADML_1B_184 B Ore Hi Al 0.6 0.003 13.25 12.4 1 2.9 12.2 0.19 0.13 3.5 0.215 0.01 7.3 84 74.7 25.6 43 55

ADML_1B_278 B Ore Hi Al 2.2 0.001 10.85 46.4 2 0.9 3.4 0.16 0.1 8.2 0.301 0.1 1.1 558 13.5 4.3 7 71.7

ADML_1B_279 B Ore Hi Al 0.6 0.002 15.7 37.7 2 1.2 4.3 0.19 0.21 3.9 0.484 0.03 0.9 456 9.2 6.3 22 95.4

ADML_1B_003 B Ore Hi SiO2 3 0.001 6.39 2.2 0.5 0.6 10.7 0.03 0.1 0.3 0.022 0.01 0.2 18 1.2 3.8 23 5.3

ADML_1B_004 B Ore Hi SiO2 13.5 0.001 5.07 2.1 2 0.8 5.9 0.03 0.12 0.5 0.021 0.02 0.5 21 14.2 7.2 21 7.1

ADML_1B_099 B Ore Hi SiO2 0.2 0.003 8.46 10.9 0.5 0.3 1.5 0.03 0.025 0.2 0.01 0.04 0.3 22 27.9 12.6 55 3.3

ADML_1B_101 B Ore Hi SiO2 0.4 0.003 6.84 7 0.5 0.5 3.8 0.08 0.06 0.2 0.006 0.01 0.1 13 17.9 3.9 62 2.7

ADML_1B_148 B Ore Hi SiO2 1.4 0.002 0.38 36.5 0.5 0.6 34.1 0.1 0.025 0.9 0.354 0.01 0.2 210 0.5 15.5 91 26.2

ADML_1B_170 B Ore Hi SiO2 0.2 0.003 4.58 6.5 0.5 0.3 1.7 0.03 0.025 0.3 0.014 0.01 0.2 26 26.7 6.2 148 5.5

ADML_1B_176 B Ore Hi SiO2 2.4 0.002 9.35 1 0.5 0.5 13.9 0.03 0.025 0.2 0.01 0.01 0.1 9 10.6 2.8 24 3

ADML_1B_220 B Ore Hi SiO2 0.3 0.002 7.13 3.3 1 0.4 0.6 0.03 0.025 0.2 0.008 0.02 0.2 7 86.8 4.9 83 2.8

ADML_1B_223 B Ore Hi SiO2 2.5 0.002 4.25 1 0.5 0.3 2.3 0.03 0.025 0.1 0.007 0.01 0.2 14 27.5 3.9 6 2.6

ADML_1B_001 Mafic 0.7 0.001 0.52 61.9 1 0.7 12.8 0.25 0.025 2.2 0.814 0.01 0.6 1 0.05 0.025 1 0.25



Appendix 8: Global Abundance Indices (Major Elements)


Major Element Global Abundance Indices



Mean Sediment M- MadoongaComparative Abundance 72000 66000 4.1 20000 14000 770 0.57 0.067 0.2

SMC Sample ID Domain IDA13020 M BIF 3A13024 M BIF 2A13025 M BIF 2A13028 M BIF 1 1A13029 M BIF 2 2A13033 M BIF 1A13034 M BIF 3A13036 M BIF 1 1A13037 M BIF 2 1 1A13049 M BIF 3 1A13050 M BIF 2A13051 M BIFA13052 M BIF 3A13054 M BIF 3A13055 M BIF 3A13056 M BIF 2A13057 M BIF 2A13059 M BIF 5 1 1 1ADML_1B_012 M BIF 2ADML_1B_014 M BIF 2ADML_1B_015 M BIF 2ADML_1B_016 M BIF 1ADML_1B_017 M BIF 1ADML_1B_018 M BIF 2ADML_1B_019 M BIF 1ADML_1B_021 M BIF 1ADML_1B_022 M BIF 1ADML_1B_023 M BIF 2ADML_1B_047 M BIF 1ADML_1B_074 M BIFADML_1B_077 M BIF 1ADML_1B_187 M BIFADML_1B_193 M BIFADML_1B_204 M BIFADML_1B_205 M BIF 1ADML_1B_211 M BIFADML_1B_213 M BIF 2ADML_1B_214 M BIF 2ADML_1B_225 M BIFADML_1B_227 M BIF 2ADML_1B_229 M BIFA13019 M Detrital 3A13030 M Detrital 3A13047 M Detrital 3 1ADML_1B_010 M Detrital 2ADML_1B_024 M Detrital 1ADML_1B_027 M Detrital 2ADML_1B_035 M Detrital 2ADML_1B_036 M Detrital 2ADML_1B_037 M Detrital 1






SMC Sample ID Domain IDADML_1B_038 M Detrital 1ADML_1B_040 M Detrital 2ADML_1B_041 M Detrital 2ADML_1B_045 M Detrital 2ADML_1B_046 M Detrital 2ADML_1B_049 M Detrital 2ADML_1B_050 M Detrital 2ADML_1B_051 M Detrital 2ADML_1B_060 M Detrital 1ADML_1B_061 M Detrital 1ADML_1B_062 M Detrital 1ADML_1B_063 M Detrital 1ADML_1B_067 M Detrital 2ADML_1B_068 M Detrital 2ADML_1B_206 M Detrital 2ADML_1B_212 M Detrital 2ADML_1B_215 M Detrital 2ADML_1B_216 M Detrital 2ADML_1B_217 M Detrital 2ADML_1B_218 M Detrital 2ADML_1B_219 M Detrital 2ADML_1B_032 M FelsicADML_1B_033 M FelsicADML_1B_034 M FelsicADML_1B_257 M FelsicADML_1B_258 M FelsicADML_1B_259 M FelsicADML_1B_260 M FelsicADML_1B_261 M FelsicADML_1B_262 M FelsicADML_1B_265 M FelsicADML_1B_270 M FelsicA13021 M Hydrated 3A13023 M Hydrated 3A13035 M Hydrated 3A13053 M Hydrated 2ADML_1B_043 M HydratedADML_1B_044 M HydratedADML_1B_048 M Hydrated 2ADML_1B_075 M Hydrated 1ADML_1B_076 M HydratedADML_1B_078 M Hydrated 2ADML_1B_226 M Hydrated 1ADML_1B_228 M HydratedADML_1B_241 M Hydrated 1ADML_1B_242 M HydratedADML_1B_243 M Hydrated 2ADML_1B_244 M Hydrated 1ADML_1B_245 M Hydrated 1ADML_1B_246 M Hydrated






SMC Sample ID Domain IDADML_1B_247 M Hydrated 2ADML_1B_248 M HydratedADML_1B_249 M Hydrated 1 4ADML_1B_250 M Hydrated 1ADML_1B_251 M HydratedADML_1B_252 M Hydrated 1ADML_1B_254 M Hydrated 2ADML_1B_255 M Hydrated 1ADML_1B_256 M HydratedADML_1B_271 M HydratedADML_1B_272 M Hydrated 1ADML_1B_273 M Hydrated 1A13022 M Mafic 3A13031 M Mafic 1A13032 M Mafic 1A13048 M Mafic 2ADML_1B_009 M Mafic 1ADML_1B_011 M MaficADML_1B_025 M Mafic 1ADML_1B_026 M MaficADML_1B_039 M Mafic 2ADML_1B_056 M Mafic 1 1ADML_1B_069 M Mafic 1ADML_1B_070 M Mafic 1 1ADML_1B_071 M Mafic 1 1ADML_1B_191 M Mafic 1 1 1ADML_1B_200 M Mafic 2ADML_1B_208 M MaficADML_1B_237 M Mafic 1 1ADML_1B_238 M MaficADML_1B_008 M Ore 2ADML_1B_029 M Ore 2ADML_1B_031 M Ore 2ADML_1B_042 M Ore 2ADML_1B_054 M Ore 2ADML_1B_055 M Ore 2ADML_1B_057 M Ore 2ADML_1B_064 M Ore 2ADML_1B_066 M Ore 2ADML_1B_072 M Ore 2ADML_1B_188 M Ore 2ADML_1B_189 M Ore 2ADML_1B_192 M Ore 2ADML_1B_209 M Ore 2ADML_1B_210 M Ore 2ADML_1B_030 M Ore Hi Al 2ADML_1B_053 M Ore Hi Al 2ADML_1B_058 M Ore Hi Al 2ADML_1B_190 M Ore Hi Al 2 1ADML_1B_194 M Ore Hi Al 2






SMC Sample ID Domain IDADML_1B_195 M Ore Hi Al 2 2ADML_1B_198 M Ore Hi Al 2ADML_1B_202 M Ore Hi Al 2ADML_1B_231 M Ore Hi Al 2ADML_1B_234 M Ore Hi Al 2ADML_1B_235 M Ore Hi Al 2ADML_1B_236 M Ore Hi Al 2ADML_1B_013 M Ore Hi SiO2 2ADML_1B_020 M Ore Hi SiO2 2ADML_1B_028 M Ore Hi SiO2 2ADML_1B_052 M Ore Hi SiO2 2ADML_1B_059 M Ore Hi SiO2 2ADML_1B_065 M Ore Hi SiO2 2ADML_1B_073 M Ore Hi SiO2 2ADML_1B_196 M Ore Hi SiO2 2ADML_1B_199 M Ore Hi SiO2 1ADML_1B_201 M Ore Hi SiO2 2ADML_1B_203 M Ore Hi SiO2 2ADML_1B_207 M Ore Hi SiO2 2ADML_1B_230 M Ore Hi SiO2 2ADML_1B_232 M Ore Hi SiO2 2ADML_1B_233 M Ore Hi SiO2 2A13026 M Shale 1A13027 M Shale 1 1 2A13038 M Shale 1A13039 M Shale 2A13058 M ShaleADML_1B_274 M Shale 3ADML_1B_275 M ShaleADML_1B_276 M Shale 2ADML_1B_277 M Shale 1 2ADML_1B_280 M Shale 1ADML_1B_281 M Shale 1 1ADML_1B_282 M Shale 1ADML_1B_283 M ShaleADML_1B_284 M ShaleADML_1B_285 M Shale 1ADML_1B_286 M Shale 1ADML_1B_287 M Shale 1ADML_1B_288 M Shale 1A13003 B BIF 2A13004 B BIF 2A13005 B BIF 3A13006 B BIF 3A13011 B BIF 3A13013 B BIF 3A13014 B BIF 3A13015 B BIF 3A13016 B BIF 3A13042 B BIF 3






SMC Sample ID Domain IDA13043 B BIF 3A13044 B BIF 3ADML_1B_083 B BIF 2ADML_1B_084 B BIF 2ADML_1B_098 B BIF 2ADML_1B_100 B BIF 2ADML_1B_107 B BIF 2ADML_1B_130 B BIF 2ADML_1B_138 B BIF 2ADML_1B_138 B BIFADML_1B_149 B BIFADML_1B_156 B BIF 1ADML_1B_174 B BIF 2 1ADML_1B_185 B BIF 2ADML_1B_186 B BIF 2ADML_1B_197 B BIF 2ADML_1B_221 B BIF 2A13001 B MaficA13002 B Mafic 1A13007 B Mafic 1A13008 B MaficA13009 B Mafic 1A13010 B Mafic 1 2 2A13012 B Mafic 1 2A13017 B Mafic 1 2A13018 B Mafic 1A13040 B Mafic 1 2A13041 B Mafic 1 2A13045 B Mafic 1 2A13046 B Mafic 1 1ADML_1B_006 B Mafic 1ADML_1B_007 B Mafic 1ADML_1B_079 B Mafic 1ADML_1B_080 B Mafic 1 1ADML_1B_081 B Mafic 1ADML_1B_082 B Mafic 1ADML_1B_085 B Mafic 1ADML_1B_086 B MaficADML_1B_087 B MaficADML_1B_088 B MaficADML_1B_089 B Mafic 2ADML_1B_090 B Mafic 1 2ADML_1B_091 B Mafic 2ADML_1B_092 B MaficADML_1B_093 B Mafic 1 1ADML_1B_094 B Mafic 1ADML_1B_095 B MaficADML_1B_096 B Mafic 1 1ADML_1B_097 B Mafic 1ADML_1B_103 B Mafic 1






SMC Sample ID Domain IDADML_1B_104 B Mafic 1ADML_1B_105 B MaficADML_1B_106 B Mafic 1 1ADML_1B_108 B Mafic 1ADML_1B_112 B Mafic 2ADML_1B_113 B Mafic 1 1ADML_1B_114 B Mafic 1ADML_1B_116 B Mafic 1ADML_1B_117 B Mafic 1 1ADML_1B_119 B MaficADML_1B_120 B Mafic 1ADML_1B_121 B MaficADML_1B_122 B Mafic 1ADML_1B_123 B Mafic 1ADML_1B_124 B Mafic 1ADML_1B_126 B Mafic 2ADML_1B_128 B Mafic 1 2ADML_1B_129 B Mafic 1ADML_1B_131 B Mafic 1ADML_1B_132 B Mafic 2ADML_1B_133 B Mafic 2ADML_1B_134 B Mafic 1ADML_1B_135 B Mafic 1ADML_1B_136 B MaficADML_1B_137 B MaficADML_1B_139 B Mafic 1ADML_1B_140 B MaficADML_1B_141 B Mafic 1ADML_1B_142 B Mafic 1ADML_1B_143 B Mafic 1ADML_1B_144 B Mafic 2 1ADML_1B_146 B Mafic 2ADML_1B_150 B Mafic 1ADML_1B_151 B Mafic 1ADML_1B_152 B Mafic 1ADML_1B_153 B MaficADML_1B_154 B Mafic 2ADML_1B_155 B Mafic 1ADML_1B_157 B Mafic 1ADML_1B_158 B MaficADML_1B_159 B MaficADML_1B_160 B MaficADML_1B_161 B Mafic 1ADML_1B_162 B Mafic 1ADML_1B_163 B Mafic 2ADML_1B_164 B Mafic 1ADML_1B_167 B Mafic 1ADML_1B_168 B Mafic 1ADML_1B_169 B Mafic 2ADML_1B_175 B Mafic 1 1






SMC Sample ID Domain IDADML_1B_005 B Mafic 1ADML_1B_179 B Magnetite 2ADML_1B_180 B Magnetite 3ADML_1B_181 B Magnetite 2ADML_1B_222 B Magnetite 2ADML_1B_002 B Ore 2ADML_1B_102 B Ore 2ADML_1B_109 B Ore 2ADML_1B_111 B Ore 2ADML_1B_115 B Ore 2ADML_1B_118 B Ore 2ADML_1B_125 B Ore 2ADML_1B_147 B Ore 1ADML_1B_171 B Ore 2ADML_1B_173 B Ore 2ADML_1B_177 B Ore 2ADML_1B_178 B Ore 2ADML_1B_224 B Ore 2ADML_1B_110 B Ore Hi Al 2ADML_1B_127 B Ore Hi Al 2ADML_1B_145 B Ore Hi Al 2ADML_1B_145 B Ore Hi Al 2ADML_1B_172 B Ore Hi Al 2ADML_1B_182 B Ore Hi Al 2ADML_1B_183 B Ore Hi Al 2 3ADML_1B_184 B Ore Hi Al 2ADML_1B_278 B Ore Hi Al 2ADML_1B_279 B Ore Hi Al 2ADML_1B_003 B Ore Hi SiO2 3ADML_1B_004 B Ore Hi SiO2 2ADML_1B_099 B Ore Hi SiO2 2ADML_1B_101 B Ore Hi SiO2 2ADML_1B_148 B Ore Hi SiO2 1 1ADML_1B_170 B Ore Hi SiO2 2ADML_1B_176 B Ore Hi SiO2 2ADML_1B_220 B Ore Hi SiO2 2ADML_1B_223 B Ore Hi SiO2 2ADML_1B_001 Mafic 1



Appendix 9: Global Abundance Indices (Minor Elements)


Minor Element GAI

Zone Analyte Ag As Be Cd Co Cr Cs Cu Ga Ge Hf Hg In La Li Nb Ni

B - Beebyn Units ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm

Mean Sediment M- MadoongaComparative Abundance 0.057 7.7 2 0.17 14 72 72 33 18 1.7 2.5 0.19 1.6 41 56 13 52

SMC Sample ID Domain IDA13020 M BIF 2 2

A13024 M BIF

A13025 M BIF

A13028 M BIF 1

A13029 M BIF

A13033 M BIF 1 1

A13034 M BIF 4 4 1 1

A13036 M BIF

A13037 M BIF

A13049 M BIF 1 5 2 1

A13050 M BIF 3 2 2

A13051 M BIF

A13052 M BIF 3 4 1 1

A13054 M BIF

A13055 M BIF

A13056 M BIF 1

A13057 M BIF

A13059 M BIF

ADML_1B_012 M BIF 4 1

ADML_1B_014 M BIF 2

ADML_1B_015 M BIF

ADML_1B_016 M BIF

ADML_1B_017 M BIF

ADML_1B_018 M BIF 1

ADML_1B_019 M BIF

ADML_1B_021 M BIF 1

ADML_1B_022 M BIF

ADML_1B_023 M BIF

ADML_1B_047 M BIF

ADML_1B_074 M BIF

ADML_1B_077 M BIF

ADML_1B_187 M BIF

ADML_1B_193 M BIF

ADML_1B_204 M BIF 1

ADML_1B_205 M BIF 1

ADML_1B_211 M BIF 2

ADML_1B_213 M BIF 1

ADML_1B_214 M BIF

ADML_1B_225 M BIF 1

ADML_1B_227 M BIF 1


A13019 M Detrital 3

A13030 M Detrital 1 2 1


ADML_1B_010 M Detrital 2

ADML_1B_024 M Detrital 4 2 1

ADML_1B_027 M Detrital 4 4 1 1

ADML_1B_035 M Detrital 2 1













Minor Element GAI




SMC Sample ID Domain IDADML_1B_061 M Detrital 1












ADML_1B_032 M Felsic 1 1

ADML_1B_033 M Felsic 2 1 1 1

ADML_1B_034 M Felsic 2 1 1

ADML_1B_257 M Felsic








A13021 M Hydrated 2 5 1 1

A13023 M Hydrated 1 4 2



ADML_1B_043 M Hydrated


ADML_1B_048 M Hydrated 1







ADML_1B_242 M Hydrated 1 1






ADML_1B_248 M Hydrated 2 1 1




ADML_1B_252 M Hydrated 4 4 1 1







A13022 M Mafic 1 4 1 1

A13031 M Mafic 1 1 1 1

A13032 M Mafic 1 1 1

A13048 M Mafic 1 1 3 2 2

ADML_1B_009 M Mafic 1 2 1

ADML_1B_011 M Mafic 1


Minor Element GAI




SMC Sample ID Domain IDADML_1B_025 M Mafic 2 2

ADML_1B_026 M Mafic 1 1


ADML_1B_056 M Mafic 2 4 1 2 3 1 3







ADML_1B_237 M Mafic 3 3 2 4 4 3

ADML_1B_238 M Mafic 1

ADML_1B_008 M Ore 2 4

ADML_1B_029 M Ore 2 4 1


ADML_1B_042 M Ore 1 3 2 2

ADML_1B_054 M Ore 1 5 1 1

ADML_1B_055 M Ore 3 4 1 1

ADML_1B_057 M Ore 3 3 2 2

ADML_1B_064 M Ore 2 3 1

ADML_1B_066 M Ore 2 4 1





ADML_1B_209 M Ore 2 5 1 3 1

ADML_1B_210 M Ore 2 4 1 1

ADML_1B_030 M Ore Hi Al 1

ADML_1B_053 M Ore Hi Al 4 2

ADML_1B_058 M Ore Hi Al 1 1 1


ADML_1B_194 M Ore Hi Al 1 4 3 1








ADML_1B_013 M Ore Hi SiO2 2 4 1 1

ADML_1B_020 M Ore Hi SiO2 1

ADML_1B_028 M Ore Hi SiO2 3 5 1 1 2

ADML_1B_052 M Ore Hi SiO2 3 1


ADML_1B_065 M Ore Hi SiO2 3 1 1



ADML_1B_199 M Ore Hi SiO2







A13026 M Shale 1 1 1 2 2

A13027 M Shale 1 4 1 2 1 2

A13038 M Shale 1 2 2

A13039 M Shale 1 1 1 2 1 3

A13058 M Shale 1 1 2 1 1


Minor Element GAI




SMC Sample ID Domain IDADML_1B_274 M Shale 2 2 1 1 2 2

ADML_1B_275 M Shale 1 2 2 1 2

ADML_1B_276 M Shale 2 1 2 2

ADML_1B_277 M Shale 1 2 2 2 1 3

ADML_1B_280 M Shale 6 4 2 2 1 1 2

ADML_1B_281 M Shale 2 3 3 1 3 2 2

ADML_1B_282 M Shale 1 3 3 1 2

ADML_1B_283 M Shale 2 2



ADML_1B_286 M Shale 4 3 1



A13003 B BIF

A13004 B BIF 1

A13005 B BIF 2 2 1

A13006 B BIF 2 2 1 1 2

A13011 B BIF 1

A13013 B BIF 2

A13014 B BIF 1 2

A13015 B BIF

A13016 B BIF 2

A13042 B BIF 2

A13043 B BIF 2

A13044 B BIF

ADML_1B_083 B BIF

ADML_1B_084 B BIF

ADML_1B_098 B BIF

ADML_1B_100 B BIF

ADML_1B_107 B BIF 1

ADML_1B_130 B BIF 3 3 1 1

ADML_1B_138 B BIF 1

ADML_1B_138 B BIF 1

ADML_1B_149 B BIF 1

ADML_1B_156 B BIF 2 1 1

ADML_1B_174 B BIF

ADML_1B_185 B BIF

ADML_1B_186 B BIF

ADML_1B_197 B BIF 1 5 1 1

ADML_1B_221 B BIF

A13001 B Mafic 1 1 1 1

A13002 B Mafic 1 1

A13007 B Mafic 1 1 1 1

A13008 B Mafic 1

A13009 B Mafic 2 2

A13010 B Mafic 2 3 1

A13012 B Mafic 1

A13017 B Mafic 1 1

A13018 B Mafic 1 1

A13040 B Mafic 4 2 1

A13041 B Mafic 1 1

A13045 B Mafic 2 1

A13046 B Mafic 1

ADML_1B_006 B Mafic 2

ADML_1B_007 B Mafic 1 2 1

ADML_1B_079 B Mafic 1 1

ADML_1B_080 B Mafic 1 1 1 1




Minor Element GAI




SMC Sample ID Domain IDADML_1B_085 B Mafic 1 2





















ADML_1B_116 B Mafic
























ADML_1B_146 B Mafic













ADML_1B_163 B Mafic


Minor Element GAI




SMC Sample ID Domain IDADML_1B_164 B Mafic



ADML_1B_169 B Mafic

ADML_1B_175 B Mafic 2 1 1 1 1


ADML_1B_179 B Magnetite




ADML_1B_002 B Ore

ADML_1B_102 B Ore 1 3 2 1

ADML_1B_109 B Ore 1

ADML_1B_111 B Ore 1 5 1

ADML_1B_115 B Ore

ADML_1B_118 B Ore

ADML_1B_125 B Ore

ADML_1B_147 B Ore 1 1

ADML_1B_171 B Ore 1



ADML_1B_178 B Ore

ADML_1B_224 B Ore 1

ADML_1B_110 B Ore Hi Al 1

ADML_1B_127 B Ore Hi Al 1

ADML_1B_145 B Ore Hi Al 2 1

ADML_1B_145 B Ore Hi Al

ADML_1B_172 B Ore Hi Al 3 1 1






ADML_1B_003 B Ore Hi SiO2



ADML_1B_101 B Ore Hi SiO2 1

ADML_1B_148 B Ore Hi SiO2 1 1

ADML_1B_170 B Ore Hi SiO2 1 4 1


ADML_1B_220 B Ore Hi SiO2 1


ADML_1B_001 Mafic 1


Minor Element GAI (continued)

Zone Analyte Pb Rb Re Sb Sc Se Sn Sr Ta Te Th Ti Tl U V W Y Zn Zr

B - Beebyn Units ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm % ppm ppm ppm ppm ppm ppm ppm

Mean Sediment M- MadoongaComparative Abundance 19 135 0.0004 1.2 1.2 0.42 4.6 320 1.5 0.005 9.6 0.38 0.95 3.1 105 1.7 40 95 150

SMC Sample ID Domain ID 0 0 0 0 0 0 0A13020 M BIF 1 3

A13024 M BIF 1 1 3

A13025 M BIF 1 3 1

A13028 M BIF 1 3

A13029 M BIF 1 3

A13033 M BIF 1 3

A13034 M BIF 2 1 3

A13036 M BIF 1 3

A13037 M BIF 1 3 1

A13049 M BIF 3 1 5

A13050 M BIF 2 1 3

A13051 M BIF 1 1 3

A13052 M BIF 3 1 3

A13054 M BIF 1 1 3 1

A13055 M BIF 2 1 3 1

A13056 M BIF 1 1 1 3

A13057 M BIF 1 1 3

A13059 M BIF 1 3

ADML_1B_012 M BIF 3 5 1 1

ADML_1B_014 M BIF 4


ADML_1B_016 M BIF 3

ADML_1B_017 M BIF 3

ADML_1B_018 M BIF 1 4 1


ADML_1B_021 M BIF 1 2 5

ADML_1B_022 M BIF 1 4 1

ADML_1B_023 M BIF 5

ADML_1B_047 M BIF 3_ _

ADML_1B_074 M BIF 3

ADML_1B_077 M BIF 1




ADML_1B_205 M BIF 1 1 1



ADML_1B_214 M BIF 1

ADML_1B_225 M BIF 3



A13019 M Detrital 2 1 3 1



ADML_1B_010 M Detrital 2 2 1 5 1
























SMC Sample ID Domain ID 0 0 0 0 0 0 0ADML_1B_068 M Detrital 1 4 1 6 1

ADML_1B_206 M Detrital 1 1 4 1 3 1

ADML_1B_212 M Detrital 1 3 2 1 4 3




















A13053 M Hydrated 4 1 3 1 3






ADML_1B_078 M Hydrated 1 1_ _ y


















ADML_1B_271 M Hydrated 1 1 3 1 5



A13022 M Mafic 3 1 3

A13031 M Mafic 1 1 3

A13032 M Mafic 1 3

A13048 M Mafic 1 3 1 2

ADML_1B_009 M Mafic 1 2 4 3









ADML_1B_191 M Mafic 3 1 2 2 1 2






SMC Sample ID Domain ID 0 0 0 0 0 0 0ADML_1B_200 M Mafic 1 5 1 1 1 1

ADML_1B_208 M Mafic 1 5 2 1 1 1

ADML_1B_237 M Mafic 1 3 1 1 1


ADML_1B_008 M Ore 1 1 1 4

ADML_1B_029 M Ore 3 2 3 6

ADML_1B_031 M Ore 3 2 6

ADML_1B_042 M Ore 1 3 5

ADML_1B_054 M Ore 4 1 1 6

ADML_1B_055 M Ore 4 1 3 6

ADML_1B_057 M Ore 2 3 2 6


ADML_1B_066 M Ore 3 1 4 6

ADML_1B_072 M Ore 3 3 4 6

ADML_1B_188 M Ore 3 1 1

ADML_1B_189 M Ore 1 1 1

ADML_1B_192 M Ore 1 1 1 3 3

ADML_1B_209 M Ore 1 5 3 2 6 1

ADML_1B_210 M Ore 4 1 3 4




ADML_1B_190 M Ore Hi Al 1 2 1 4 1


ADML_1B_195 M Ore Hi Al 1 1 2 1 4

ADML_1B_198 M Ore Hi Al 1 4 2 4 6

ADML_1B_202 M Ore Hi Al 1 3 3 2 5 2

ADML_1B_231 M Ore Hi Al 1 3 2 4 6

ADML_1B_234 M Ore Hi Al 1 5 3_ _

ADML_1B_235 M Ore Hi Al 1 4 3 3 6













ADML_1B_207 M Ore Hi SiO2 1 1 1 2 5 2




A13026 M Shale 1 1 3

A13027 M Shale 1 1 3

A13038 M Shale 1 3

A13039 M Shale 1 1 3

A13058 M Shale 1 3

ADML_1B_274 M Shale 4 3 3 1 5

ADML_1B_275 M Shale 2 1 3 2 5 1

ADML_1B_276 M Shale 4 2 3 1 5

ADML_1B_277 M Shale 3 1 3 2 5

ADML_1B_280 M Shale 1 4 5 2 4 6






ADML_1B_286 M Shale 3 3 1 6 1

ADML_1B_287 M Shale 3 5






SMC Sample ID Domain ID 0 0 0 0 0 0 0ADML_1B_288 M Shale 2 4 1 6

A13003 B BIF 2 1 3 2

A13004 B BIF 2 1 3 2

A13005 B BIF 2 1 3 3

A13006 B BIF 2 1 3 5

A13011 B BIF 1 1 3 2

A13013 B BIF 1 1 3 3

A13014 B BIF 1 1 3 4

A13015 B BIF 1 3 1

A13016 B BIF 1 3 1

A13042 B BIF 1 1 3 5

A13043 B BIF 1 1 3 4

A13044 B BIF 2 1 3 2

ADML_1B_083 B BIF 1 1 1

ADML_1B_084 B BIF 1 1

ADML_1B_098 B BIF 1 2 1 1 3

ADML_1B_100 B BIF 1 2 1 1

ADML_1B_107 B BIF 2 2 2 3

ADML_1B_130 B BIF 1 5 1 5

ADML_1B_138 B BIF 1 2 3 3 3

ADML_1B_138 B BIF 1 4 1

ADML_1B_149 B BIF 1 4 1

ADML_1B_156 B BIF 1 4 1

ADML_1B_174 B BIF 1 1 2

ADML_1B_185 B BIF 3 1 1 3

ADML_1B_186 B BIF 1 1 1 3

ADML_1B_197 B BIF 1 1 1 3 6

ADML_1B_221 B BIF 1 2 1 4

A13001 B Mafic 1 3 1

A13002 B Mafic 1 1 3

A13007 B Mafic 4 1 3 3

A13008 B Mafic 2 1 3 1

A13009 B Mafic 1 3

A13010 B Mafic 1 3

A13012 B Mafic 1 3

A13017 B Mafic 1 3

A13018 B Mafic 1 3

A13040 B Mafic 1 3

A13041 B Mafic 1 3

A13045 B Mafic 1 3 1 1

A13046 B Mafic 1 3



ADML_1B_079 B Mafic 1 5 5 1 1

ADML_1B_080 B Mafic 1 1 4 1 1 2
























SMC Sample ID Domain ID 0 0 0 0 0 0 0ADML_1B_106 B Mafic 2 4 1








ADML_1B_120 B Mafic 1 4 2 1 1















ADML_1B_139 B Mafic 1 1 4 2 1




ADML_1B_143 B Mafic 5 4 3 1 3

ADML_1B_144 B Mafic 1 3 3 3 5_ _


















ADML_1B_169 B Mafic 1 1 2 1 2

ADML_1B_175 B Mafic 1 3 4 1 1


ADML_1B_179 B Magnetite 2 1 1

ADML_1B_180 B Magnetite 1 1 1 3

ADML_1B_181 B Magnetite 1 2 1

ADML_1B_222 B Magnetite 1 2 1 1

ADML_1B_002 B Ore 1 3 1

ADML_1B_102 B Ore 2 2 2 3 2

ADML_1B_109 B Ore 1 2 3

ADML_1B_111 B Ore 2 3 3

ADML_1B_115 B Ore 2 1 3 2 2

ADML_1B_118 B Ore 1 1 3 5

ADML_1B_125 B Ore 1 2 2 4

ADML_1B_147 B Ore 1 4 1

ADML_1B_171 B Ore 1 3 1

ADML_1B_173 B Ore 2 2 1






SMC Sample ID Domain ID 0 0 0 0 0 0 0ADML_1B_177 B Ore 2 2 1 4

ADML_1B_178 B Ore 2 1 1 4

ADML_1B_224 B Ore 1 2 3 3 3

ADML_1B_110 B Ore Hi Al 1 1 4 3 1

ADML_1B_127 B Ore Hi Al 2 2 3 2




ADML_1B_182 B Ore Hi Al 1 1 3 1 1


ADML_1B_184 B Ore Hi Al 2 2 2 4 4

ADML_1B_278 B Ore Hi Al 2 4 1 3 1 2

ADML_1B_279 B Ore Hi Al 1 3 4 1 4 1 1

ADML_1B_003 B Ore Hi SiO2 1 3

ADML_1B_004 B Ore Hi SiO2 1 1 4 2

ADML_1B_099 B Ore Hi SiO2 2 2 2 1 3


ADML_1B_148 B Ore Hi SiO2 1 4 1





ADML_1B_001 Mafic 5 1



Appendix 10: Multi element Leach Analysis

EB0902908

False

CERTIFICATE OF ANALYSIS

Work Order : EB0902908 Page : 1 of 24

:: LaboratoryClient Environmental Division BrisbaneSRK CONSULTING (AUSTRALASIA) PTY LTD

: :ContactContact MR ANDREW GARVIE Tim Kilmister

:: AddressAddress LEVEL 6 44 MARKET STREET

SYDNEY NSW, AUSTRALIA 2000

32 Shand Street Stafford QLD Australia 4053

:: E-mailE-mail [email protected] [email protected]

:: TelephoneTelephone +61 02 8079 1200 +61-7-3243 7222

:: FacsimileFacsimile +61 02 9024 8888 +61-7-3243 7218

:Project ---- QC Level : NEPM 1999 Schedule B(3) and ALS QCS3 requirement

:Order number ----

:C-O-C number ---- Date Samples Received : 20-FEB-2009

Sampler : ---- Issue Date : 18-MAR-2009

Site : ----

30:No. of samples received

Quote number : BN/012/09 V2 28:No. of samples analysed

This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. All pages of this report have been checked and approved for

release.

This Certificate of Analysis contains the following information:

l General Comments

l Analytical Results

NATA Accredited Laboratory 825

This document is issued in

accordance with NATA

accreditation requirements.

Accredited for compliance with

ISO/IEC 17025.

SignatoriesThis document has been electronically signed by the authorized signatories indicated below. Electronic signing has been

carried out in compliance with procedures specified in 21 CFR Part 11.

Signatories Accreditation CategoryPosition

Inorganics

Cass Sealby Senior Chemist - Acid Sulphate Soils Inorganics

Stephen Hislop Senior Inorganic Chemist Inorganics

Environmental Division Brisbane


Tel. +61-7-3243 7222 Fax. +61-7-3243 7218 www.alsglobal.com

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SRK CONSULTING (AUSTRALASIA) PTY LTD

----:Project

General Comments

The analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the USEPA, APHA, AS and NEPM. In house

developed procedures are employed in the absence of documented standards or by client request.

Where moisture determination has been performed, results are reported on a dry weight basis.

Where a reported less than (<) result is higher than the LOR, this may be due to primary sample extract/digestate dilution and/or insuffient sample for analysis.

Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content, insufficient sample (reduced weight employed) or matrix interference.

When date(s) and/or time(s) are shown bracketed, these have been assumed by the laboratory for processing purposes. If the sampling time is displayed as 0:00 the information was not provided by client.

CAS Number = CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society.

LOR = Limit of reporting

^ = This result is computed from individual analyte detections at or above the level of reporting

Key :

All results reported in mg/L and the pH under EA005, have been determined on a 1:3 soil to DI water leachate, tumbled end over end for 24 hours.l

EA011S (Sequential Net Acid Generation): Both samples were stopped after stage 1 as the NAG at pH 7 was <2 kg H2SO4/t.l

LCS recovery for Sulphate as SO4- Total (ED040T) fall outside Dynamic Control Limits. They are however within ALS Static Control Limits and hence deemed acceptable.l

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Analytical Results

A13019

WRRD0524 9-11

A13050B

WRRD0525 152-154

A13050

WRRD0525 152-154

A13013B

WRRD0488 121-123

A13013

WRRD0488 121-123

Client sample IDSub-Matrix: DI WATER LEACHATE

11-MAR-2009 11:2311-MAR-2009 11:2311-MAR-2009 11:2311-MAR-2009 11:2311-MAR-2009 11:23Client sampling date / time

EB0902908-007EB0902908-004EB0902908-003EB0902908-002EB0902908-001UnitLORCAS NumberCompound

EA005: pH

9.058.58 8.06 8.02 7.57pH Unit0.01----pH Value

ED040F: Dissolved Major Anions

85 18 17 40mg/L114808-79-8Sulfate as SO4 2-

22 6 6 13mg/L1----^ Sulfur as S

4.253.98 4.13 4.76 10.7mg/L0.057440-21-3Silicon

ED045P: Chloride by PC Titrator

1114 9 7 6mg/L116887-00-6Chloride

ED093F: Dissolved Major Cations

1013 10 14 12mg/L17440-70-2Calcium

1512 3 3 2mg/L17439-95-4Magnesium

1413 11 12 8mg/L17440-23-5Sodium

22 <1 1 <1mg/L17440-09-7Potassium

EG020F: Dissolved Metals by ICP-MS<0.010.01 <0.01 <0.01 <0.01mg/L0.017429-90-5Aluminium

0.0020.003 0.002 0.001 <0.001mg/L0.0017440-36-0Antimony

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-38-2Arsenic

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-41-7Beryllium

0.2490.304 0.268 0.318 0.198mg/L0.0017440-39-3Barium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-69-9Bismuth

<0.0001<0.0001 <0.0001 <0.0001 <0.0001mg/L0.00017440-43-9Cadmium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-45-1Cerium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-46-2Caesium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-47-3Chromium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-48-4Cobalt

<0.0010.004 <0.001 <0.001 <0.001mg/L0.0017440-50-8Copper

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017429-91-6Dysprosium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-52-0Erbium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-53-1Europium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-54-2Gadolinium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-55-3Gallium

<0.01<0.01 <0.01 <0.01 <0.01mg/L0.017440-58-6Hafnium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-60-0Holmium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-74-6Indium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017439-91-0Lanthanum

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017439-92-1Lead

0.001<0.001 0.004 0.004 0.003mg/L0.0017439-93-2Lithium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017439-94-3Lutetium

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Analytical Results

A13019

WRRD0524 9-11

A13050B

WRRD0525 152-154

A13050

WRRD0525 152-154

A13013B

WRRD0488 121-123

A13013

WRRD0488 121-123




EG020F: Dissolved Metals by ICP-MS - Continued

<0.0010.003 0.004 0.002 0.003mg/L0.0017439-96-5Manganese

0.0030.004 <0.001 <0.001 <0.001mg/L0.0017439-98-7Molybdenum

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-00-8Neodymium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-02-0Nickel

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-10-0Praseodymium

0.0020.001 <0.001 <0.001 <0.001mg/L0.0017440-17-7Rubidium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-19-9Samarium

<0.01<0.01 <0.01 <0.01 <0.01mg/L0.017782-49-2Selenium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-22-4Silver

0.1200.120 0.034 0.043 0.038mg/L0.0017440-24-6Strontium

<0.005<0.005 <0.005 <0.005 <0.005mg/L0.00522541-49-7Tellurium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-27-9Terbium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-28-0Thallium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-29-1Thorium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.001----Thulium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-31-5Tin

<0.01<0.01 <0.01 <0.01 <0.01mg/L0.017440-32-6Titanium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-61-1Uranium

<0.01<0.01 <0.01 <0.01 <0.01mg/L0.017440-62-2Vanadium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-64-4Ytterbium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-65-5Yttrium

0.0140.020 0.019 0.016 0.032mg/L0.0057440-66-6Zinc

<0.005<0.005 <0.005 <0.005 <0.005mg/L0.0057440-67-7Zirconium

0.060.06 0.06 0.05 0.13mg/L0.057440-42-8Boron

<0.05<0.05 <0.05 <0.05 <0.05mg/L0.057439-89-6Iron

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-33-7Tungsten

EG035F: Dissolved Mercury by FIMS<0.0001<0.0001 <0.0001 <0.0001 <0.0001mg/L0.00017439-97-6Mercury

EG052F: Silica by ICPAES

9.18.5 8.8 10.2 22.8mg/L0.17631-86-9^ Silica

EK040P: Fluoride by PC Titrator

0.10.1 0.2 0.3 0.1mg/L0.116984-48-8Fluoride

EK067G: Total Phosphorus as P by Discrete Analyser<0.01<0.01 <0.01 <0.01 <0.01mg/L0.01----Total Phosphorus as P

EP006 Total Inorganic Carbon

129 4 6 1mg/L1----Total Inorganic Carbon

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Analytical Results

A13019

WRRD0524 9-11

A13050B

WRRD0525 152-154

A13050

WRRD0525 152-154

A13013B

WRRD0488 121-123

A13013

WRRD0488 121-123




EP007 Total Carbon

1411 6 8 4mg/L1----Total Carbon

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Analytical Results

A13040

WRRD0520 14-16

A13017B

WRRD0488 174-176

A13017

WRRD0488 174-176

A13010

WRRD0488 39-41

A13019B

WRRD0524 9-11




EA005: pH

7.837.39 7.89 7.91 6.77pH Unit0.01----pH Value


332 4 3 7mg/L114808-79-8Sulfate as SO4 2-

<110 1 1 2mg/L1----^ Sulfur as S

9.558.52 5.22 2.69 4.87mg/L0.057440-21-3Silicon


34 7 5 18mg/L116887-00-6Chloride

ED093F: Dissolved Major Cations<18 3 3 2mg/L17440-70-2Calcium

61 6 4 2mg/L17439-95-4Magnesium

78 14 10 23mg/L17440-23-5Sodium

<1<1 2 1 <1mg/L17440-09-7Potassium

EG020F: Dissolved Metals by ICP-MS

4.370.01 0.54 0.20 0.29mg/L0.017429-90-5Aluminium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-36-0Antimony

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-38-2Arsenic

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-41-7Beryllium

0.1610.221 0.814 0.540 0.289mg/L0.0017440-39-3Barium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-69-9Bismuth

<0.0001<0.0001 <0.0001 <0.0001 <0.0001mg/L0.00017440-43-9Cadmium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-45-1Cerium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-46-2Caesium

0.044<0.001 0.003 <0.001 0.006mg/L0.0017440-47-3Chromium

0.0030.003 <0.001 <0.001 <0.001mg/L0.0017440-48-4Cobalt

0.001<0.001 0.002 0.001 0.001mg/L0.0017440-50-8Copper

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017429-91-6Dysprosium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-52-0Erbium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-53-1Europium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-54-2Gadolinium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-55-3Gallium

<0.01<0.01 <0.01 <0.01 <0.01mg/L0.017440-58-6Hafnium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-60-0Holmium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-74-6Indium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017439-91-0Lanthanum

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017439-92-1Lead

0.0030.001 <0.001 <0.001 0.007mg/L0.0017439-93-2Lithium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017439-94-3Lutetium

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Analytical Results

A13040

WRRD0520 14-16

A13017B

WRRD0488 174-176

A13017

WRRD0488 174-176

A13010

WRRD0488 39-41

A13019B

WRRD0524 9-11





0.0740.757 0.014 0.004 0.008mg/L0.0017439-96-5Manganese

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017439-98-7Molybdenum

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-00-8Neodymium

0.0070.002 <0.001 <0.001 <0.001mg/L0.0017440-02-0Nickel


<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-17-7Rubidium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-19-9Samarium

<0.01<0.01 <0.01 <0.01 <0.01mg/L0.017782-49-2Selenium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-22-4Silver

0.0060.030 0.027 0.021 0.025mg/L0.0017440-24-6Strontium

<0.005<0.005 <0.005 <0.005 <0.005mg/L0.00522541-49-7Tellurium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-27-9Terbium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-28-0Thallium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-29-1Thorium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.001----Thulium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-31-5Tin

<0.01<0.01 <0.01 <0.01 <0.01mg/L0.017440-32-6Titanium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-61-1Uranium

<0.01<0.01 <0.01 <0.01 <0.01mg/L0.017440-62-2Vanadium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-64-4Ytterbium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-65-5Yttrium

0.0150.014 0.008 0.007 0.013mg/L0.0057440-66-6Zinc

<0.005<0.005 <0.005 <0.005 <0.005mg/L0.0057440-67-7Zirconium

0.140.13 0.10 0.10 1.59mg/L0.057440-42-8Boron

6.06<0.05 0.93 0.37 0.90mg/L0.057439-89-6Iron

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-33-7Tungsten

EG035F: Dissolved Mercury by FIMS<0.0001<0.0001 <0.0001 <0.0001 <0.0001mg/L0.00017439-97-6Mercury


20.418.3 11.2 5.8 10.4mg/L0.17631-86-9^ Silica


0.30.1 0.3 0.3 <0.1mg/L0.116984-48-8Fluoride

EK067G: Total Phosphorus as P by Discrete Analyser<0.01<0.01 <0.01 <0.01 <0.01mg/L0.01----Total Phosphorus as P


1<1 5 3 3mg/L1----Total Inorganic Carbon

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Analytical Results

A13040

WRRD0520 14-16

A13017B

WRRD0488 174-176

A13017

WRRD0488 174-176

A13010

WRRD0488 39-41

A13019B

WRRD0524 9-11




EP007 Total Carbon


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Analytical Results

A13011

WRRD0488 56-58

A13035B

WRRD0491 163-165

A13035

WRRD0491 163-165

A13023

WRRD0524 91-93

A13021

WRRD0524 74-76




EA005: pH

7.016.88 6.69 6.88 7.46pH Unit0.01----pH Value


1815 296 290 6mg/L114808-79-8Sulfate as SO4 2-

65 99 97 2mg/L1----^ Sulfur as S

1.725.18 1.72 1.58 3.74mg/L0.057440-21-3Silicon


1413 582 499 9mg/L116887-00-6Chloride


44 27 23 1mg/L17440-70-2Calcium

12 51 48 <1mg/L17439-95-4Magnesium

1616 418 373 14mg/L17440-23-5Sodium

<12 19 17 <1mg/L17440-09-7Potassium

EG020F: Dissolved Metals by ICP-MS<0.010.10 <0.01 <0.01 0.31mg/L0.017429-90-5Aluminium

<0.0010.002 <0.001 <0.001 0.001mg/L0.0017440-36-0Antimony

<0.0010.002 <0.001 <0.001 0.002mg/L0.0017440-38-2Arsenic

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-41-7Beryllium

0.2260.260 0.225 0.174 0.375mg/L0.0017440-39-3Barium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-69-9Bismuth

<0.0001<0.0001 <0.0001 <0.0001 <0.0001mg/L0.00017440-43-9Cadmium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-45-1Cerium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-46-2Caesium

<0.0010.004 <0.001 <0.001 0.002mg/L0.0017440-47-3Chromium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-48-4Cobalt

<0.0010.002 0.001 <0.001 0.004mg/L0.0017440-50-8Copper

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017429-91-6Dysprosium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-52-0Erbium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-53-1Europium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-54-2Gadolinium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-55-3Gallium

<0.01<0.01 <0.01 <0.01 <0.01mg/L0.017440-58-6Hafnium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-60-0Holmium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-74-6Indium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017439-91-0Lanthanum

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017439-92-1Lead

0.0010.002 0.002 0.003 0.007mg/L0.0017439-93-2Lithium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017439-94-3Lutetium

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Analytical Results

A13011

WRRD0488 56-58

A13035B

WRRD0491 163-165

A13035

WRRD0491 163-165

A13023

WRRD0524 91-93

A13021

WRRD0524 74-76





<0.0010.010 0.017 0.012 0.027mg/L0.0017439-96-5Manganese

<0.001<0.001 <0.001 <0.001 0.001mg/L0.0017439-98-7Molybdenum

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-00-8Neodymium

<0.001<0.001 <0.001 <0.001 0.002mg/L0.0017440-02-0Nickel


<0.0010.001 0.007 0.006 <0.001mg/L0.0017440-17-7Rubidium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-19-9Samarium

<0.01<0.01 0.03 0.03 <0.01mg/L0.017782-49-2Selenium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-22-4Silver

0.0250.024 0.466 0.391 0.018mg/L0.0017440-24-6Strontium

<0.005<0.005 <0.005 <0.005 <0.005mg/L0.00522541-49-7Tellurium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-27-9Terbium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-28-0Thallium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-29-1Thorium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.001----Thulium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-31-5Tin

<0.01<0.01 <0.01 <0.01 <0.01mg/L0.017440-32-6Titanium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-61-1Uranium

<0.01<0.01 <0.01 <0.01 <0.01mg/L0.017440-62-2Vanadium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-64-4Ytterbium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-65-5Yttrium

0.0080.011 0.028 0.028 0.017mg/L0.0057440-66-6Zinc

<0.0050.006 <0.005 <0.005 <0.005mg/L0.0057440-67-7Zirconium

0.090.17 0.36 0.35 0.24mg/L0.057440-42-8Boron

<0.051.56 <0.05 <0.05 7.03mg/L0.057439-89-6Iron

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-33-7Tungsten

EG035F: Dissolved Mercury by FIMS

0.0002<0.0001 <0.0001 <0.0001 <0.0001mg/L0.00017439-97-6Mercury


3.711.1 3.7 3.4 8.0mg/L0.17631-86-9^ Silica


0.20.3 0.2 0.2 0.4mg/L0.116984-48-8Fluoride

EK067G: Total Phosphorus as P by Discrete Analyser

0.02<0.01 <0.01 <0.01 <0.01mg/L0.01----Total Phosphorus as P



11 of 24:Page

Work Order :

:Client

EB0902908


----:Project

Analytical Results

A13011

WRRD0488 56-58

A13035B

WRRD0491 163-165

A13035

WRRD0491 163-165

A13023

WRRD0524 91-93

A13021

WRRD0524 74-76




EP007 Total Carbon


12 of 24:Page

Work Order :

:Client

EB0902908


----:Project

Analytical Results

A13049

WRRD0525 82-84

A13034

WRRD0491 125-127

A13006

WRRD0493 110-112

A13005

WRRD0493 92-94

A13042

WRRD0520 65-67




EA005: pH

8.028.59 7.77 7.58 7.97pH Unit0.01----pH Value


64 7 39 23mg/L114808-79-8Sulfate as SO4 2-

21 2 13 8mg/L1----^ Sulfur as S

3.733.17 3.29 1.20 2.14mg/L0.057440-21-3Silicon


510 7 36 9mg/L116887-00-6Chloride


29 3 7 28mg/L17440-70-2Calcium

<16 1 5 2mg/L17439-95-4Magnesium

1218 10 30 14mg/L17440-23-5Sodium

<11 <1 2 2mg/L17440-09-7Potassium


0.270.03 <0.01 <0.01 <0.01mg/L0.017429-90-5Aluminium

0.0020.005 <0.001 <0.001 <0.001mg/L0.0017440-36-0Antimony

0.002<0.001 <0.001 <0.001 <0.001mg/L0.0017440-38-2Arsenic

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-41-7Beryllium

0.3700.254 0.243 0.230 0.286mg/L0.0017440-39-3Barium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-69-9Bismuth

<0.0001<0.0001 <0.0001 <0.0001 <0.0001mg/L0.00017440-43-9Cadmium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-45-1Cerium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-46-2Caesium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-47-3Chromium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-48-4Cobalt

0.002<0.001 <0.001 <0.001 <0.001mg/L0.0017440-50-8Copper

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017429-91-6Dysprosium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-52-0Erbium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-53-1Europium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-54-2Gadolinium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-55-3Gallium

<0.01<0.01 <0.01 <0.01 <0.01mg/L0.017440-58-6Hafnium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-60-0Holmium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-74-6Indium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017439-91-0Lanthanum

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017439-92-1Lead

0.0060.002 0.011 0.003 0.002mg/L0.0017439-93-2Lithium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017439-94-3Lutetium

13 of 24:Page

Work Order :

:Client

EB0902908


----:Project

Analytical Results

A13049

WRRD0525 82-84

A13034

WRRD0491 125-127

A13006

WRRD0493 110-112

A13005

WRRD0493 92-94

A13042

WRRD0520 65-67





0.005<0.001 <0.001 <0.001 <0.001mg/L0.0017439-96-5Manganese

<0.0010.002 <0.001 <0.001 <0.001mg/L0.0017439-98-7Molybdenum

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-00-8Neodymium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-02-0Nickel


<0.0010.001 <0.001 <0.001 0.001mg/L0.0017440-17-7Rubidium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-19-9Samarium

<0.01<0.01 <0.01 <0.01 <0.01mg/L0.017782-49-2Selenium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-22-4Silver

0.0150.045 0.018 0.050 0.149mg/L0.0017440-24-6Strontium

<0.005<0.005 <0.005 <0.005 <0.005mg/L0.00522541-49-7Tellurium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-27-9Terbium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-28-0Thallium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-29-1Thorium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.001----Thulium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-31-5Tin

<0.01<0.01 <0.01 <0.01 <0.01mg/L0.017440-32-6Titanium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-61-1Uranium

<0.01<0.01 <0.01 <0.01 <0.01mg/L0.017440-62-2Vanadium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-64-4Ytterbium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-65-5Yttrium

0.013<0.005 0.009 0.007 0.012mg/L0.0057440-66-6Zinc

<0.005<0.005 <0.005 <0.005 <0.005mg/L0.0057440-67-7Zirconium

0.160.15 0.13 0.12 0.12mg/L0.057440-42-8Boron

6.94<0.05 0.06 <0.05 <0.05mg/L0.057439-89-6Iron

0.0040.003 <0.001 <0.001 <0.001mg/L0.0017440-33-7Tungsten

EG035F: Dissolved Mercury by FIMS<0.0001<0.0001 <0.0001 0.0001 <0.0001mg/L0.00017439-97-6Mercury


8.06.8 7.0 2.6 4.6mg/L0.17631-86-9^ Silica


0.30.2 0.2 0.2 0.4mg/L0.116984-48-8Fluoride

EK067G: Total Phosphorus as P by Discrete Analyser<0.010.07 <0.01 <0.01 <0.01mg/L0.01----Total Phosphorus as P



14 of 24:Page

Work Order :

:Client

EB0902908


----:Project

Analytical Results

A13049

WRRD0525 82-84

A13034

WRRD0491 125-127

A13006

WRRD0493 110-112

A13005

WRRD0493 92-94

A13042

WRRD0520 65-67




EP007 Total Carbon


15 of 24:Page

Work Order :

:Client

EB0902908


----:Project

Analytical Results

A13032

WRRD0491 61-63

A13001

WRRD0493 14-16

A13022

WRRD0524 81-83

A13055

WRRD0529 55-57

A13052

WRRD0529 11-13




EA005: pH

7.907.62 7.27 7.61 7.41pH Unit0.01----pH Value


922 13 3 6mg/L114808-79-8Sulfate as SO4 2-

37 4 <1 2mg/L1----^ Sulfur as S

5.453.61 3.75 7.93 2.76mg/L0.057440-21-3Silicon


28 15 3 13mg/L116887-00-6Chloride

ED093F: Dissolved Major Cations<14 10 <1 2mg/L17440-70-2Calcium

<12 2 <1 2mg/L17439-95-4Magnesium

159 15 8 19mg/L17440-23-5Sodium

<1<1 2 <1 2mg/L17440-09-7Potassium


0.89<0.01 <0.01 1.91 0.04mg/L0.017429-90-5Aluminium

0.002<0.001 0.001 <0.001 <0.001mg/L0.0017440-36-0Antimony

0.002<0.001 <0.001 <0.001 <0.001mg/L0.0017440-38-2Arsenic

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-41-7Beryllium

0.1550.212 0.358 0.145 0.310mg/L0.0017440-39-3Barium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-69-9Bismuth

<0.0001<0.0001 <0.0001 <0.0001 <0.0001mg/L0.00017440-43-9Cadmium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-45-1Cerium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-46-2Caesium

0.017<0.001 <0.001 0.003 <0.001mg/L0.0017440-47-3Chromium

<0.001<0.001 <0.001 0.001 <0.001mg/L0.0017440-48-4Cobalt

0.005<0.001 0.001 0.002 <0.001mg/L0.0017440-50-8Copper

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017429-91-6Dysprosium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-52-0Erbium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-53-1Europium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-54-2Gadolinium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-55-3Gallium

<0.01<0.01 <0.01 <0.01 <0.01mg/L0.017440-58-6Hafnium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-60-0Holmium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-74-6Indium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017439-91-0Lanthanum

0.004<0.001 <0.001 <0.001 <0.001mg/L0.0017439-92-1Lead

<0.0010.002 0.002 0.001 0.001mg/L0.0017439-93-2Lithium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017439-94-3Lutetium

16 of 24:Page

Work Order :

:Client

EB0902908


----:Project

Analytical Results

A13032

WRRD0491 61-63

A13001

WRRD0493 14-16

A13022

WRRD0524 81-83

A13055

WRRD0529 55-57

A13052

WRRD0529 11-13





0.0160.009 <0.001 0.002 <0.001mg/L0.0017439-96-5Manganese

0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017439-98-7Molybdenum

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-00-8Neodymium

0.001<0.001 <0.001 0.002 <0.001mg/L0.0017440-02-0Nickel


<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-17-7Rubidium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-19-9Samarium

<0.01<0.01 <0.01 <0.01 <0.01mg/L0.017782-49-2Selenium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-22-4Silver

0.0060.023 0.043 0.008 0.019mg/L0.0017440-24-6Strontium

<0.005<0.005 <0.005 <0.005 <0.005mg/L0.00522541-49-7Tellurium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-27-9Terbium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-28-0Thallium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-29-1Thorium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.001----Thulium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-31-5Tin

0.02<0.01 <0.01 0.04 <0.01mg/L0.017440-32-6Titanium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-61-1Uranium

<0.01<0.01 <0.01 <0.01 <0.01mg/L0.017440-62-2Vanadium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-64-4Ytterbium

<0.001<0.001 <0.001 0.008 <0.001mg/L0.0017440-65-5Yttrium

0.0130.012 0.013 0.024 0.031mg/L0.0057440-66-6Zinc

<0.005<0.005 <0.005 <0.005 <0.005mg/L0.0057440-67-7Zirconium

0.100.08 0.11 0.11 0.15mg/L0.057440-42-8Boron

21.0<0.05 <0.05 1.35 <0.05mg/L0.057439-89-6Iron

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-33-7Tungsten

EG035F: Dissolved Mercury by FIMS<0.0001<0.0001 <0.0001 0.0002 <0.0001mg/L0.00017439-97-6Mercury


11.77.7 8.0 17.0 5.9mg/L0.17631-86-9^ Silica

EK040P: Fluoride by PC Titrator<0.10.1 0.3 0.3 0.2mg/L0.116984-48-8Fluoride




2<1 4 1 4mg/L1----Total Inorganic Carbon

17 of 24:Page

Work Order :

:Client

EB0902908


----:Project

Analytical Results

A13032

WRRD0491 61-63

A13001

WRRD0493 14-16

A13022

WRRD0524 81-83

A13055

WRRD0529 55-57

A13052

WRRD0529 11-13




EP007 Total Carbon


18 of 24:Page

Work Order :

:Client

EB0902908


----:Project

Analytical Results

------------A13027

WRRD0524 194-196

A13026

WRRD0524 180-182


------------12-MAR-2009 10:5812-MAR-2009 10:58Client sampling date / time

------------EB0902908-030EB0902908-029UnitLORCAS NumberCompound

EA005: pH

8.348.31 ---- ---- ----pH Unit0.01----pH Value


123112 ---- ---- ----mg/L114808-79-8Sulfate as SO4 2-

4137 ---- ---- ----mg/L1----^ Sulfur as S

2.862.60 ---- ---- ----mg/L0.057440-21-3Silicon


972 ---- ---- ----mg/L116887-00-6Chloride


5433 ---- ---- ----mg/L17440-70-2Calcium

3819 ---- ---- ----mg/L17439-95-4Magnesium

5885 ---- ---- ----mg/L17440-23-5Sodium

1941 ---- ---- ----mg/L17440-09-7Potassium


0.030.04 ---- ---- ----mg/L0.017429-90-5Aluminium

0.0150.026 ---- ---- ----mg/L0.0017440-36-0Antimony

0.0190.001 ---- ---- ----mg/L0.0017440-38-2Arsenic

<0.001<0.001 ---- ---- ----mg/L0.0017440-41-7Beryllium

0.2100.260 ---- ---- ----mg/L0.0017440-39-3Barium

<0.001<0.001 ---- ---- ----mg/L0.0017440-69-9Bismuth

<0.0001<0.0001 ---- ---- ----mg/L0.00017440-43-9Cadmium

<0.001<0.001 ---- ---- ----mg/L0.0017440-45-1Cerium

<0.001<0.001 ---- ---- ----mg/L0.0017440-46-2Caesium

<0.001<0.001 ---- ---- ----mg/L0.0017440-47-3Chromium

<0.001<0.001 ---- ---- ----mg/L0.0017440-48-4Cobalt

<0.001<0.001 ---- ---- ----mg/L0.0017440-50-8Copper

<0.001<0.001 ---- ---- ----mg/L0.0017429-91-6Dysprosium

<0.001<0.001 ---- ---- ----mg/L0.0017440-52-0Erbium

<0.001<0.001 ---- ---- ----mg/L0.0017440-53-1Europium

<0.001<0.001 ---- ---- ----mg/L0.0017440-54-2Gadolinium

<0.001<0.001 ---- ---- ----mg/L0.0017440-55-3Gallium

<0.01<0.01 ---- ---- ----mg/L0.017440-58-6Hafnium

<0.001<0.001 ---- ---- ----mg/L0.0017440-60-0Holmium

<0.001<0.001 ---- ---- ----mg/L0.0017440-74-6Indium

<0.001<0.001 ---- ---- ----mg/L0.0017439-91-0Lanthanum

<0.001<0.001 ---- ---- ----mg/L0.0017439-92-1Lead

<0.0010.001 ---- ---- ----mg/L0.0017439-93-2Lithium

<0.001<0.001 ---- ---- ----mg/L0.0017439-94-3Lutetium

19 of 24:Page

Work Order :

:Client

EB0902908


----:Project

Analytical Results

------------A13027

WRRD0524 194-196

A13026

WRRD0524 180-182





0.0740.072 ---- ---- ----mg/L0.0017439-96-5Manganese

0.0020.004 ---- ---- ----mg/L0.0017439-98-7Molybdenum

<0.001<0.001 ---- ---- ----mg/L0.0017440-00-8Neodymium

0.0190.002 ---- ---- ----mg/L0.0017440-02-0Nickel

<0.001<0.001 ---- ---- ----mg/L0.0017440-10-0Praseodymium

0.0110.028 ---- ---- ----mg/L0.0017440-17-7Rubidium

<0.001<0.001 ---- ---- ----mg/L0.0017440-19-9Samarium

<0.01<0.01 ---- ---- ----mg/L0.017782-49-2Selenium

0.0010.002 ---- ---- ----mg/L0.0017440-22-4Silver

0.0420.036 ---- ---- ----mg/L0.0017440-24-6Strontium

<0.005<0.005 ---- ---- ----mg/L0.00522541-49-7Tellurium

<0.001<0.001 ---- ---- ----mg/L0.0017440-27-9Terbium

<0.001<0.001 ---- ---- ----mg/L0.0017440-28-0Thallium

<0.001<0.001 ---- ---- ----mg/L0.0017440-29-1Thorium

<0.001<0.001 ---- ---- ----mg/L0.001----Thulium

<0.001<0.001 ---- ---- ----mg/L0.0017440-31-5Tin

<0.01<0.01 ---- ---- ----mg/L0.017440-32-6Titanium

<0.001<0.001 ---- ---- ----mg/L0.0017440-61-1Uranium

<0.01<0.01 ---- ---- ----mg/L0.017440-62-2Vanadium

<0.001<0.001 ---- ---- ----mg/L0.0017440-64-4Ytterbium

<0.001<0.001 ---- ---- ----mg/L0.0017440-65-5Yttrium

0.0250.027 ---- ---- ----mg/L0.0057440-66-6Zinc

<0.005<0.005 ---- ---- ----mg/L0.0057440-67-7Zirconium

0.100.16 ---- ---- ----mg/L0.057440-42-8Boron

<0.05<0.05 ---- ---- ----mg/L0.057439-89-6Iron

<0.001<0.001 ---- ---- ----mg/L0.0017440-33-7Tungsten

EG035F: Dissolved Mercury by FIMS<0.0001<0.0001 ---- ---- ----mg/L0.00017439-97-6Mercury


6.15.6 ---- ---- ----mg/L0.17631-86-9^ Silica


0.30.5 ---- ---- ----mg/L0.116984-48-8Fluoride

EK067G: Total Phosphorus as P by Discrete Analyser<0.01<0.01 ---- ---- ----mg/L0.01----Total Phosphorus as P


3416 ---- ---- ----mg/L1----Total Inorganic Carbon

20 of 24:Page

Work Order :

:Client

EB0902908


----:Project

Analytical Results

------------A13027

WRRD0524 194-196

A13026

WRRD0524 180-182




EP007 Total Carbon

3418 ---- ---- ----mg/L1----Total Carbon

21 of 24:Page

Work Order :

:Client

EB0902908


----:Project

Analytical Results

A13030

WRRD0491 8-10

A13019B

WRRD0524 9-11

A13019

WRRD0524 9-11

A13050B

WRRD0525 152-154

A13050

WRRD0525 152-154

Client sample IDSub-Matrix: ROCK

20-FEB-2009 15:0020-FEB-2009 15:0020-FEB-2009 15:0020-FEB-2009 15:0020-FEB-2009 15:00Client sampling date / time


ED040T : Total Sulfate by ICPAES

130280 320 780 <100mg/kg10014808-79-8Sulfate as SO4 2-

22 of 24:Page

Work Order :

:Client

EB0902908


----:Project

Analytical Results

A13005

WRRD0493 92-94

A13035B

WRRD0491 163-165

A13035

WRRD0491 163-165

A13023

WRRD0524 91-93

A13021

WRRD0524 74-76





110190 380 360 <100mg/kg10014808-79-8Sulfate as SO4 2-

23 of 24:Page

Work Order :

:Client

EB0902908


----:Project

Analytical Results

A13001

WRRD0493 14-16

A13022

WRRD0524 81-83

A13052

WRRD0529 11-13

A13049

WRRD0525 82-84

A13034

WRRD0491 125-127





340880 580 <100 <100mg/kg10014808-79-8Sulfate as SO4 2-

24 of 24:Page

Work Order :

:Client

EB0902908


----:Project

Analytical Results

------------A13027

WRRD0524 194-196

A13026

WRRD0524 180-182


------------20-FEB-2009 15:0020-FEB-2009 15:00Client sampling date / time


EA011S: Net Acid Generation - Sequential (TOTAL)<0.1<0.1 ---- ---- ----kg H2SO4/t0.1----^ NAG at pH 4.5 (total)

<0.1<0.1 ---- ---- ----kg H2SO4/t0.1----^ NAG at pH 7.0 (total)

EA011S: pH OX (Stage 1)

8.37.8 ---- ---- ----pH Unit0.1----pH OX (Stage 1)

<0.1<0.1 ---- ---- ----kg H2SO4/t0.1----NAG at pH 4.5 (Stage 1)

<0.1<0.1 ---- ---- ----kg H2SO4/t0.1----NAG at pH 7.0 (Stage 1)

EB0918640

False

CERTIFICATE OF ANALYSIS

Work Order : EB0918640 Page : 1 of 15

:: LaboratoryClient Environmental Division BrisbaneSINOSTEEL MIDWEST MANAGEMENT PTY LTD

: :ContactContact MR ANDREW GARVIE Tim Kilmister

:: AddressAddress LEVEL 6

44 MARKET STREET

SYDNEY N.S.W., AUSTRALIA 2000


:: E-mailE-mail [email protected] [email protected]

:: TelephoneTelephone +61 2 90248800 +61-7-3243 7222

:: FacsimileFacsimile +61 2 90248888 +61-7-3243 7218

:Project ---- QC Level : NEPM 1999 Schedule B(3) and ALS QCS3 requirement

:Order number PO 3392

:C-O-C number ---- Date Samples Received : 20-NOV-2009

Sampler : ---- Issue Date : 18-DEC-2009

Site : ----

36:No. of samples received

Quote number : BN/180/09 34:No. of samples analysed

This report supersedes any previous report(s) with this reference. Results apply to the sample(s) as submitted. All pages of this report have been checked and approved for

release.

This Certificate of Analysis contains the following information:

l General Comments

l Analytical Results

NATA Accredited Laboratory 825

This document is issued in

accordance with NATA

accreditation requirements.

Accredited for compliance with

ISO/IEC 17025.

SignatoriesThis document has been electronically signed by the authorized signatories indicated below. Electronic signing has been

carried out in compliance with procedures specified in 21 CFR Part 11.

Signatories Accreditation CategoryPosition

Kim McCabe Senior Inorganic Chemist Inorganics

Stephen Hislop Senior Inorganic Chemist Inorganics

Environmental Division Brisbane


Tel. +61-7-3243 7222 Fax. +61-7-3243 7218 www.alsglobal.com

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General Comments

The analytical procedures used by the Environmental Division have been developed from established internationally recognized procedures such as those published by the USEPA, APHA, AS and NEPM. In house

developed procedures are employed in the absence of documented standards or by client request.

Where moisture determination has been performed, results are reported on a dry weight basis.

Where a reported less than (<) result is higher than the LOR, this may be due to primary sample extract/digestate dilution and/or insuffient sample for analysis.

Where the LOR of a reported result differs from standard LOR, this may be due to high moisture content, insufficient sample (reduced weight employed) or matrix interference.

When date(s) and/or time(s) are shown bracketed, these have been assumed by the laboratory for processing purposes. If the sampling time is displayed as 0:00 the information was not provided by client.

CAS Number = CAS registry number from database maintained by Chemical Abstracts Services. The Chemical Abstracts Service is a division of the American Chemical Society.

LOR = Limit of reporting

^ = This result is computed from individual analyte detections at or above the level of reporting

Key :

All leachate analytical results reported in mg/l have been determined on a 1:3 solid/water leach that has been tumbled end over end for 24 hours before analysis.l

ED045G (Chloride): LCS recovery falls outside Dynamic Control Limits. It is however within ALS Static Control Limits and hence deemed acceptable.l

LCS recovery for EG020A-W (Water Leachable Metals) fall outside Dynamic Control Limits for Antimony, Silver and Strontium. They are however within ALS Static Control Limits and

hence deemed acceptable. No further action is required.

l

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Analytical Results

ADML_1B_066ADML_1B_056ADML_1B_026ADML_1B_013ADML_1B_011Client sample IDSub-Matrix: LEACHATE

08-DEC-2009 14:0008-DEC-2009 12:0008-DEC-2009 14:0008-DEC-2009 14:0008-DEC-2009 12:00Client sampling date / time


EA005: pH

6.336.92 6.58 8.03 6.83pH Unit0.01----pH Value

ED040W: Water Leachable Sulphate by ICPAES

458 131 52 45mg/L114808-79-8Sulfate as SO4 2-

153 44 17 15mg/L1----^ Sulfur as S

ED045G: Chloride Discrete analyser

14850 393 148 95mg/L116887-00-6Chloride

ED093W: Water Leachable Major Cations

74 3 3 7mg/L17440-70-2Calcium

73 6 6 8mg/L17439-95-4Magnesium

8726 280 116 62mg/L17440-23-5Sodium

199 14 6 5mg/L17440-09-7Potassium

EG020W: Water Leachable Metals by ICP-MS

0.020.17 0.01 0.15 0.05mg/L0.017429-90-5Aluminium

<0.001<0.001 <0.001 0.002 <0.001mg/L0.0017440-36-0Antimony

<0.001<0.001 <0.001 0.055 <0.001mg/L0.0017440-38-2Arsenic

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-41-7Beryllium

0.3120.326 0.249 0.296 0.333mg/L0.0017440-39-3Barium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-69-9Bismuth

0.0002<0.0001 <0.0001 <0.0001 <0.0001mg/L0.00017440-43-9Cadmium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-45-1Cerium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-46-2Caesium

<0.001<0.001 <0.001 0.003 <0.001mg/L0.0017440-47-3Chromium

<0.001<0.001 <0.001 0.002 <0.001mg/L0.0017440-48-4Cobalt

0.001<0.001 <0.001 0.001 0.002mg/L0.0017440-50-8Copper

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017429-91-6Dysprosium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-52-0Erbium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-53-1Europium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-54-2Gadolinium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-55-3Gallium

<0.01<0.01 <0.01 <0.01 <0.01mg/L0.017440-58-6Hafnium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-60-0Holmium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-74-6Indium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017439-91-0Lanthanum

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017439-92-1Lead

0.026<0.001 0.013 <0.001 0.008mg/L0.0017439-93-2Lithium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017439-94-3Lutetium

0.0310.017 0.003 0.004 0.004mg/L0.0017439-96-5Manganese

<0.001<0.001 <0.001 0.010 <0.001mg/L0.0017439-98-7Molybdenum

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Analytical Results




EG020W: Water Leachable Metals by ICP-MS - Continued

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-00-8Neodymium

<0.001<0.001 <0.001 0.003 <0.001mg/L0.0017440-02-0Nickel


0.0110.002 0.002 0.002 0.004mg/L0.0017440-17-7Rubidium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-19-9Samarium

<0.01<0.01 <0.01 <0.01 <0.01mg/L0.017782-49-2Selenium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-22-4Silver

0.0620.031 0.050 0.020 0.049mg/L0.0017440-24-6Strontium

<0.005<0.005 <0.005 <0.005 <0.005mg/L0.00522541-49-7Tellurium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-27-9Terbium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-28-0Thallium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-29-1Thorium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.001----Thulium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-31-5Tin

<0.01<0.01 <0.01 <0.01 <0.01mg/L0.017440-32-6Titanium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-61-1Uranium

<0.01<0.01 <0.01 <0.01 <0.01mg/L0.017440-62-2Vanadium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-64-4Ytterbium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-65-5Yttrium

0.0320.018 0.053 0.016 0.022mg/L0.0057440-66-6Zinc

<0.005<0.005 <0.005 <0.005 <0.005mg/L0.0057440-67-7Zirconium

0.240.22 0.67 0.33 0.31mg/L0.057440-42-8Boron

<0.050.08 <0.05 0.41 0.07mg/L0.057439-89-6Iron

EG035W: Water Leachable Mercury by FIMS<0.0001<0.0001 <0.0001 <0.0001 <0.0001mg/L0.00017439-97-6Mercury


0.20.2 0.2 0.4 0.2mg/L0.116984-48-8Fluoride


0.020.06 <0.01 <0.01 0.08mg/L0.01----Total Phosphorus as P

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EA005: pH

7.017.58 7.91 7.98 7.82pH Unit0.01----pH Value


582 1 9 2mg/L114808-79-8Sulfate as SO4 2-

19<1 <1 3 <1mg/L1----^ Sulfur as S


653 2 11 6mg/L116887-00-6Chloride


2<1 1 <1 <1mg/L17440-70-2Calcium

2<1 2 2 1mg/L17439-95-4Magnesium

729 15 20 16mg/L17440-23-5Sodium

2<1 <1 <1 <1mg/L17440-09-7Potassium


0.200.85 0.48 1.90 0.41mg/L0.017429-90-5Aluminium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-36-0Antimony

<0.0010.003 0.001 <0.001 <0.001mg/L0.0017440-38-2Arsenic

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-41-7Beryllium

0.1590.187 0.356 0.298 0.472mg/L0.0017440-39-3Barium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-69-9Bismuth

<0.0001<0.0001 <0.0001 <0.0001 <0.0001mg/L0.00017440-43-9Cadmium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-45-1Cerium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-46-2Caesium

<0.0010.026 0.022 0.027 0.003mg/L0.0017440-47-3Chromium

<0.001<0.001 <0.001 0.004 <0.001mg/L0.0017440-48-4Cobalt

<0.0010.002 0.002 0.002 0.002mg/L0.0017440-50-8Copper

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017429-91-6Dysprosium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-52-0Erbium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-53-1Europium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-54-2Gadolinium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-55-3Gallium

<0.01<0.01 <0.01 <0.01 <0.01mg/L0.017440-58-6Hafnium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-60-0Holmium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-74-6Indium

<0.001<0.001 <0.001 0.002 <0.001mg/L0.0017439-91-0Lanthanum

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017439-92-1Lead

0.003<0.001 <0.001 0.001 0.002mg/L0.0017439-93-2Lithium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017439-94-3Lutetium

<0.0010.008 0.005 0.017 0.005mg/L0.0017439-96-5Manganese

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017439-98-7Molybdenum

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Analytical Results





<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-00-8Neodymium

<0.0010.012 0.007 0.031 0.005mg/L0.0017440-02-0Nickel


<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-17-7Rubidium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-19-9Samarium

<0.01<0.01 <0.01 <0.01 <0.01mg/L0.017782-49-2Selenium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-22-4Silver

0.0170.006 0.014 0.008 0.015mg/L0.0017440-24-6Strontium

<0.005<0.005 <0.005 <0.005 <0.005mg/L0.00522541-49-7Tellurium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-27-9Terbium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-28-0Thallium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-29-1Thorium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.001----Thulium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-31-5Tin

0.030.02 0.01 0.04 0.02mg/L0.017440-32-6Titanium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-61-1Uranium

<0.01<0.01 <0.01 0.04 <0.01mg/L0.017440-62-2Vanadium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-64-4Ytterbium

<0.001<0.001 <0.001 0.002 <0.001mg/L0.0017440-65-5Yttrium

0.0180.027 0.020 0.035 0.025mg/L0.0057440-66-6Zinc

<0.005<0.005 <0.005 <0.005 <0.005mg/L0.0057440-67-7Zirconium

0.520.22 0.16 0.29 0.35mg/L0.057440-42-8Boron

0.361.48 1.16 3.39 1.75mg/L0.057439-89-6Iron



0.20.2 0.2 0.2 0.3mg/L0.116984-48-8Fluoride


0.03<0.01 0.02 0.01 0.02mg/L0.01----Total Phosphorus as P

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EA005: pH

7.917.91 7.71 7.62 7.37pH Unit0.01----pH Value


11116 6 7 15mg/L114808-79-8Sulfate as SO4 2-

439 2 2 5mg/L1----^ Sulfur as S


6155 8 6 16mg/L116887-00-6Chloride

ED093W: Water Leachable Major Cations<110 2 1 <1mg/L17440-70-2Calcium

<112 2 <1 <1mg/L17439-95-4Magnesium

16156 16 13 28mg/L17440-23-5Sodium

<15 <1 <1 2mg/L17440-09-7Potassium


1.550.03 0.14 0.26 0.97mg/L0.017429-90-5Aluminium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-36-0Antimony

<0.001<0.001 0.002 0.009 0.005mg/L0.0017440-38-2Arsenic

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-41-7Beryllium

0.1320.191 0.368 0.307 0.247mg/L0.0017440-39-3Barium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-69-9Bismuth

<0.0001<0.0001 <0.0001 0.0011 <0.0001mg/L0.00017440-43-9Cadmium

<0.001<0.001 <0.001 0.001 <0.001mg/L0.0017440-45-1Cerium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-46-2Caesium

0.0070.010 0.008 0.006 0.006mg/L0.0017440-47-3Chromium

0.004<0.001 <0.001 <0.001 0.003mg/L0.0017440-48-4Cobalt

0.0060.003 0.001 0.005 0.007mg/L0.0017440-50-8Copper

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017429-91-6Dysprosium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-52-0Erbium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-53-1Europium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-54-2Gadolinium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-55-3Gallium

<0.01<0.01 <0.01 <0.01 <0.01mg/L0.017440-58-6Hafnium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-60-0Holmium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-74-6Indium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017439-91-0Lanthanum

<0.001<0.001 <0.001 <0.001 0.002mg/L0.0017439-92-1Lead

<0.0010.001 0.014 0.008 0.005mg/L0.0017439-93-2Lithium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017439-94-3Lutetium

0.016<0.001 0.008 0.012 0.028mg/L0.0017439-96-5Manganese

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017439-98-7Molybdenum

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<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-00-8Neodymium

0.012<0.001 <0.001 0.002 0.008mg/L0.0017440-02-0Nickel


<0.0010.002 <0.001 <0.001 <0.001mg/L0.0017440-17-7Rubidium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-19-9Samarium

<0.01<0.01 <0.01 <0.01 <0.01mg/L0.017782-49-2Selenium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-22-4Silver

0.0070.065 0.015 0.014 0.010mg/L0.0017440-24-6Strontium

<0.005<0.005 <0.005 <0.005 <0.005mg/L0.00522541-49-7Tellurium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-27-9Terbium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-28-0Thallium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-29-1Thorium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.001----Thulium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-31-5Tin

0.07<0.01 <0.01 <0.01 0.01mg/L0.017440-32-6Titanium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-61-1Uranium

0.02<0.01 <0.01 <0.01 <0.01mg/L0.017440-62-2Vanadium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-64-4Ytterbium

0.002<0.001 <0.001 <0.001 <0.001mg/L0.0017440-65-5Yttrium

0.0320.016 0.016 0.023 0.040mg/L0.0057440-66-6Zinc

<0.005<0.005 <0.005 <0.005 <0.005mg/L0.0057440-67-7Zirconium

0.321.59 0.22 0.19 0.29mg/L0.057440-42-8Boron

3.21<0.05 1.45 7.37 3.63mg/L0.057439-89-6Iron



0.20.6 0.2 0.2 0.2mg/L0.116984-48-8Fluoride


0.01<0.01 0.02 0.02 0.05mg/L0.01----Total Phosphorus as P

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Analytical Results




EA005: pH

6.765.58 7.25 7.35 7.48pH Unit0.01----pH Value


10018 14 190 9mg/L114808-79-8Sulfate as SO4 2-

336 5 63 3mg/L1----^ Sulfur as S


4426 28 6 63mg/L116887-00-6Chloride


83 2 57 3mg/L17440-70-2Calcium

302 2 4 2mg/L17439-95-4Magnesium

2628 32 8 45mg/L17440-23-5Sodium

91 4 34 5mg/L17440-09-7Potassium


0.02<0.01 0.19 0.03 0.20mg/L0.017429-90-5Aluminium

<0.001<0.001 <0.001 0.002 <0.001mg/L0.0017440-36-0Antimony

0.017<0.001 0.001 <0.001 <0.001mg/L0.0017440-38-2Arsenic

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-41-7Beryllium

0.2500.326 0.334 0.238 0.538mg/L0.0017440-39-3Barium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-69-9Bismuth

<0.0001<0.0001 <0.0001 <0.0001 <0.0001mg/L0.00017440-43-9Cadmium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-45-1Cerium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-46-2Caesium

<0.001<0.001 0.012 <0.001 0.004mg/L0.0017440-47-3Chromium

<0.0010.007 <0.001 <0.001 <0.001mg/L0.0017440-48-4Cobalt

0.0110.004 0.001 0.002 0.003mg/L0.0017440-50-8Copper

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017429-91-6Dysprosium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-52-0Erbium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-53-1Europium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-54-2Gadolinium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-55-3Gallium

<0.01<0.01 <0.01 <0.01 <0.01mg/L0.017440-58-6Hafnium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-60-0Holmium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-74-6Indium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017439-91-0Lanthanum

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017439-92-1Lead

<0.0010.006 0.002 <0.001 0.001mg/L0.0017439-93-2Lithium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017439-94-3Lutetium

0.0440.779 0.002 0.908 0.015mg/L0.0017439-96-5Manganese

0.002<0.001 <0.001 0.010 <0.001mg/L0.0017439-98-7Molybdenum

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Analytical Results





<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-00-8Neodymium

0.0020.009 0.002 0.002 0.004mg/L0.0017440-02-0Nickel


0.002<0.001 0.002 0.042 0.003mg/L0.0017440-17-7Rubidium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-19-9Samarium

<0.01<0.01 <0.01 <0.01 <0.01mg/L0.017782-49-2Selenium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-22-4Silver

0.0980.029 0.016 0.078 0.026mg/L0.0017440-24-6Strontium

<0.005<0.005 <0.005 <0.005 <0.005mg/L0.00522541-49-7Tellurium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-27-9Terbium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-28-0Thallium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-29-1Thorium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.001----Thulium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-31-5Tin

<0.01<0.01 <0.01 <0.01 0.01mg/L0.017440-32-6Titanium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-61-1Uranium

<0.01<0.01 <0.01 <0.01 <0.01mg/L0.017440-62-2Vanadium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-64-4Ytterbium

<0.001<0.001 <0.001 <0.001 <0.001mg/L0.0017440-65-5Yttrium

0.0180.105 0.020 0.028 0.024mg/L0.0057440-66-6Zinc

<0.005<0.005 <0.005 <0.005 <0.005mg/L0.0057440-67-7Zirconium

0.140.16 0.26 0.17 0.35mg/L0.057440-42-8Boron

0.081.41 0.64 0.09 1.12mg/L0.057439-89-6Iron



0.20.1 0.2 0.2 0.2mg/L0.116984-48-8Fluoride



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Analytical Results

----ADML_1B_287ADML_1B_286ADML_1B_276ADML_1B_274Client sample IDSub-Matrix: LEACHATE

----08-DEC-2009 12:0009-DEC-2009 14:0009-DEC-2009 14:0009-DEC-2009 14:00Client sampling date / time

----EB0918640-036EB0918640-035EB0918640-031EB0918640-029UnitLORCAS NumberCompound

EA005: pH

7.167.03 7.23 7.55 ----pH Unit0.01----pH Value


248320 17 24 ----mg/L114808-79-8Sulfate as SO4 2-

83107 6 8 ----mg/L1----^ Sulfur as S


913 61 43 ----mg/L116887-00-6Chloride


1020 4 4 ----mg/L17440-70-2Calcium

3756 4 4 ----mg/L17439-95-4Magnesium

1017 33 40 ----mg/L17440-23-5Sodium

4518 3 2 ----mg/L17440-09-7Potassium


0.080.06 0.04 0.08 ----mg/L0.017429-90-5Aluminium

0.0350.014 <0.001 <0.001 ----mg/L0.0017440-36-0Antimony

0.0020.001 <0.001 <0.001 ----mg/L0.0017440-38-2Arsenic

<0.001<0.001 <0.001 <0.001 ----mg/L0.0017440-41-7Beryllium

0.1950.152 0.335 0.411 ----mg/L0.0017440-39-3Barium

<0.001<0.001 <0.001 <0.001 ----mg/L0.0017440-69-9Bismuth

<0.00010.0016 <0.0001 <0.0001 ----mg/L0.00017440-43-9Cadmium

<0.001<0.001 <0.001 <0.001 ----mg/L0.0017440-45-1Cerium

<0.001<0.001 <0.001 <0.001 ----mg/L0.0017440-46-2Caesium

0.0020.002 0.025 0.012 ----mg/L0.0017440-47-3Chromium

0.0070.077 <0.001 <0.001 ----mg/L0.0017440-48-4Cobalt

0.0030.002 0.001 0.001 ----mg/L0.0017440-50-8Copper

<0.001<0.001 <0.001 <0.001 ----mg/L0.0017429-91-6Dysprosium

<0.001<0.001 <0.001 <0.001 ----mg/L0.0017440-52-0Erbium

<0.001<0.001 <0.001 <0.001 ----mg/L0.0017440-53-1Europium

<0.001<0.001 <0.001 <0.001 ----mg/L0.0017440-54-2Gadolinium

<0.001<0.001 <0.001 <0.001 ----mg/L0.0017440-55-3Gallium

<0.01<0.01 <0.01 <0.01 ----mg/L0.017440-58-6Hafnium

<0.001<0.001 <0.001 <0.001 ----mg/L0.0017440-60-0Holmium

<0.001<0.001 <0.001 <0.001 ----mg/L0.0017440-74-6Indium

<0.001<0.001 <0.001 <0.001 ----mg/L0.0017439-91-0Lanthanum

<0.001<0.001 <0.001 <0.001 ----mg/L0.0017439-92-1Lead

<0.0010.002 0.006 0.008 ----mg/L0.0017439-93-2Lithium

<0.001<0.001 <0.001 <0.001 ----mg/L0.0017439-94-3Lutetium

0.2300.652 0.006 0.003 ----mg/L0.0017439-96-5Manganese

0.001<0.001 <0.001 <0.001 ----mg/L0.0017439-98-7Molybdenum

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Analytical Results

----ADML_1B_287ADML_1B_286ADML_1B_276ADML_1B_274Client sample IDSub-Matrix: LEACHATE

----08-DEC-2009 12:0009-DEC-2009 14:0009-DEC-2009 14:0009-DEC-2009 14:00Client sampling date / time

----EB0918640-036EB0918640-035EB0918640-031EB0918640-029UnitLORCAS NumberCompound


<0.001<0.001 <0.001 <0.001 ----mg/L0.0017440-00-8Neodymium

0.0581.02 0.004 <0.001 ----mg/L0.0017440-02-0Nickel

<0.001<0.001 <0.001 <0.001 ----mg/L0.0017440-10-0Praseodymium

0.0800.021 0.001 <0.001 ----mg/L0.0017440-17-7Rubidium

<0.001<0.001 <0.001 <0.001 ----mg/L0.0017440-19-9Samarium

0.010.02 <0.01 <0.01 ----mg/L0.017782-49-2Selenium

<0.001<0.001 <0.001 <0.001 ----mg/L0.0017440-22-4Silver

0.0220.086 0.025 0.024 ----mg/L0.0017440-24-6Strontium

<0.005<0.005 <0.005 <0.005 ----mg/L0.00522541-49-7Tellurium

<0.001<0.001 <0.001 <0.001 ----mg/L0.0017440-27-9Terbium

<0.001<0.001 <0.001 <0.001 ----mg/L0.0017440-28-0Thallium

<0.001<0.001 <0.001 <0.001 ----mg/L0.0017440-29-1Thorium

<0.001<0.001 <0.001 <0.001 ----mg/L0.001----Thulium

<0.001<0.001 <0.001 <0.001 ----mg/L0.0017440-31-5Tin

0.01<0.01 <0.01 <0.01 ----mg/L0.017440-32-6Titanium

<0.001<0.001 <0.001 <0.001 ----mg/L0.0017440-61-1Uranium

<0.01<0.01 <0.01 <0.01 ----mg/L0.017440-62-2Vanadium

<0.001<0.001 <0.001 <0.001 ----mg/L0.0017440-64-4Ytterbium

<0.001<0.001 <0.001 <0.001 ----mg/L0.0017440-65-5Yttrium

0.0230.037 0.019 0.023 ----mg/L0.0057440-66-6Zinc

<0.005<0.005 <0.005 <0.005 ----mg/L0.0057440-67-7Zirconium

0.200.19 0.25 0.30 ----mg/L0.057440-42-8Boron

0.130.15 0.23 0.22 ----mg/L0.057439-89-6Iron

EG035W: Water Leachable Mercury by FIMS<0.0001<0.0001 <0.0001 <0.0001 ----mg/L0.00017439-97-6Mercury


0.20.2 0.2 0.3 ----mg/L0.116984-48-8Fluoride

EK067G: Total Phosphorus as P by Discrete Analyser<0.01<0.01 <0.01 <0.01 ----mg/L0.01----Total Phosphorus as P

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Analytical Results

ADML_1B_137ADML_1B_110ADML_1B_064ADML_1B_056ADML_1B_027Client sample IDSub-Matrix: ROCK

26-MAY-2009 15:0026-MAY-2009 15:0009-MAY-2009 15:0009-MAY-2009 15:0009-MAY-2009 15:00Client sampling date / time


EA011: Net Acid Generation-------- ---- ---- 4.0pH Unit0.1----pH (OX)

-------- ---- ---- 0.5kg H2SO4/t0.1----NAG (pH 4.5)

-------- ---- ---- 3.9kg H2SO4/t0.1----NAG (pH 7.0)

EA046 Acid Buffering Characterisation Curves-------- ---- ---- ----------Dummy Analyte

ED040: Sulphur as SO4 2-

320---- ---- ---- 1820mg/kg10014808-79-8Sulfate as SO4 2-

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Analytical Results

ADML_1B_276ADML_1B_275ADML_1B_274ADML_1B_249ADML_1B_243Client sample IDSub-Matrix: ROCK

04-JUL-2009 15:0004-JUL-2009 15:0004-JUL-2009 15:0004-JUL-2009 15:0004-JUL-2009 15:00Client sampling date / time


EA011A: Net Acid Generation - Sequential

205---- 56.8 ---- ----kg H2SO4/t0.1----^ NAG at pH 4.5 (total)

248---- 92.9 ---- ----kg H2SO4/t0.1----^ NAG at pH 7.0 (total)


1.5---- 1.9 ---- ----pH Unit0.1----pH OX (Stage 1)

160---- 49.4 ---- ----kg H2SO4/t0.1----NAG at pH 4.5 (Stage 1)

183---- 67.2 ---- ----kg H2SO4/t0.1----NAG at pH 7.0 (Stage 1)



37.2---- 5.9 ---- ----kg H2SO4/t0.1----NAG at pH 4.5 (Stage 2)








1.0---- <0.1 ---- ----kg H2SO4/t0.1----NAG at pH 4.5 (Stage 4)








14400640 2470 300 1550mg/kg10014808-79-8Sulfate as SO4 2-

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Analytical Results

--------ADML_1B_282ADML_1B_280ADML_1B_277Client sample IDSub-Matrix: ROCK

--------04-JUL-2009 15:0004-JUL-2009 15:0004-JUL-2009 15:00Client sampling date / time

--------EB0918640-034EB0918640-033EB0918640-032UnitLORCAS NumberCompound

EA011A: Net Acid Generation - Sequential

53934.2 ---- ---- ----kg H2SO4/t0.1----^ NAG at pH 4.5 (total)

61667.3 ---- ---- ----kg H2SO4/t0.1----^ NAG at pH 7.0 (total)



23324.3 ---- ---- ----kg H2SO4/t0.1----NAG at pH 4.5 (Stage 1)












6.90.5 ---- ---- ----kg H2SO4/t0.1----NAG at pH 4.5 (Stage 4)








64601130 420 ---- ----mg/kg10014808-79-8Sulfate as SO4 2-



Appendix 11: Acid Buffering Characteristic Curves

SRK ConsultingSMM001 Geochemical Charaterisation of Weld Range Waste and Mineralised Rock

ABCC Data

Sample ID A13057 Sample ID A13059EB0902908 Sample 5 (WRRD0529) EB0902908 Sample 6 (WRRD0529)HCl Molarity: 0.1 (96 - 98) HCl Molarity: 0.1 (127 - 129)mL Increments: 0.2 mL Increments: 0.2Weight (g) 2 Weight (g) 2

Addition

mLs added (total)

kg H2SO4 pH Addition

mLs added (total)

kg H2SO4 pH

0 0 0 6.84 0 0 0 5.81 0.2 0.49 5.76 1 0.2 0.49 5.212 0.4 0.98 4.1 2 0.4 0.98 3.763 0.6 1.47 3.9 3 0.6 1.47 3.694 0.8 1.96 3.47 4 0.8 1.96 3.455 1 2.45 4.42 5 1 2.45 3.46 1.2 2.94 3.97 6 1.2 2.94 2.527 1.4 3.43 3.71 7 1.4 3.43 2.328 1.6 3.92 3.54 8 1.6 3.92 3.199 1.8 4.41 3.39 9 1.8 4.41 3.1210 2 4.9 3.27 10 2 4.9 3.0411 2.2 5.39 3.2 11 2.2 5.39 2.9912 2.4 5.88 3.08 12 2.4 5.88 2.9113 2.6 6.37 3 13 2.6 6.37 2.8914 2.8 6.86 2.92 14 2.8 6.86 2.8115 3 7.35 2.88 15 3 7.35 2.7616 3.2 7.84 2.76 16 3.2 7.84 2.6517 3.4 8.33 2.73 17 3.4 8.33 2.6217 3.4 8.33 2.73 17 3.4 8.33 2.6218 3.6 8.82 2.7 18 3.6 8.82 2.5819 3.8 9.31 2.64 19 3.8 9.31 2.5420 4 9.8 2.62 20 4 9.8 2.5121 4.2 10.29 2.59 21 4.2 10.29 2.4822 4.4 10.78 2.61 22 4.4 10.78 2.4923 4.6 11.27 2.58 23 4.6 11.27 2.4724 4.8 11.76 2.54 24 4.8 11.76 2.4325 5 12.25 2.51 25 5 12.25 2.4126 5.2 12.74 2.49


ABCC Data


Addition

mLs added (total)


mLs added (total)

kg H2SO4 pH

0 0 0 6.63 0 0 0 6.531 0.2 0.49 5.38 1 0.2 0.49 4.372 0.4 0.98 4.3 2 0.4 0.98 3.733 0.6 1.47 4.28 3 0.6 1.47 3.564 0.8 1.96 3.56 4 0.8 1.96 3.315 1 2.45 3.74 5 1 2.45 3.186 1.2 2.94 3.62 6 1.2 2.94 3.127 1.4 3.43 3.47 7 1.4 3.43 38 1.6 3.92 3.38 8 1.6 3.92 2.969 1.8 4.41 3.27 9 1.8 4.41 2.8610 2 4.9 3.2 10 2 4.9 2.8311 2.2 5.39 3.13 11 2.2 5.39 2.7512 2.4 5.88 3.09 12 2.4 5.88 2.7513 2.6 6.37 3 13 2.6 6.37 2.6614 2.8 6.86 2.95 14 2.8 6.86 2.6415 3 7.35 2.9 15 3 7.35 2.6116 3.2 7.84 2.78 16 3.2 7.84 2.517 3.4 8.33 2.74 17 3.4 8.33 2.4717 3.4 8.33 2.74 17 3.4 8.33 2.4718 3.6 8.82 2.69 18 3.6 8.82 2.4319 3.8 9.31 2.65 19 3.8 9.31 2.420 4 9.8 2.62 20 4 9.8 2.3721 4.2 10.29 2.58 21 4.2 10.29 2.3522 4.4 10.78 2.623 4.6 11.27 2.5724 4.8 11.76 2.5325 5 12.25 2.5126 5.2 12.74 2.4927 5.4 13.23 2.4428 5.6 13.72 2.43


ABCC Data


Addition

mLs added (total)


mLs added (total)

kg H2SO4 pH

0 0 0 7.51 0 0 0 7.491 0.2 0.49 6.77 1 0.5 1.225 6.652 0.4 0.98 6.52 2 1 2.45 6.733 0.6 1.47 5.8 3 1.5 3.675 5.634 0.8 1.96 5.19 4 2 4.9 5.845 1 2.45 4.69 5 2.5 6.125 5.416 1.2 2.94 4.36 6 3 7.35 6.17 1.4 3.43 3.48 7 3.5 8.575 5.268 1.6 3.92 3.88 8 4 9.8 5.529 1.8 4.41 3.6 9 4.5 11.025 5.4310 2 4.9 3.54 10 5 12.25 5.8711 2.2 5.39 3.33 11 5.5 13.475 5.1612 2.4 5.88 3.23 12 6 14.7 5.0513 2.6 6.37 3.13 13 6.5 15.925 5.0214 2.8 6.86 3.05 14 7 17.15 4.8715 3 7.35 2.898 15 7.5 18.375 4.9416 3.2 7.84 2.8 16 8 19.6 4.5817 3.4 8.33 2.81 17 8.5 20.825 4.4617 3.4 8.33 2.81 17 8.5 20.825 4.4618 3.6 8.82 2.75 18 9 22.05 4.3619 3.8 9.31 2.72 19 9.5 23.275 4.0320 4 9.8 2.68 20 10 24.5 3.8821 4.2 10.29 2.65 21 10.5 25.725 3.6622 4.4 10.78 2.61 22 11 26.95 3.4323 4.6 11.27 2.59 23 11.5 28.175 3.2724 4.8 11.76 2.56 24 12 29.4 3.1325 5 12.25 2.53 25 12.5 30.625 3.0426 5.2 12.74 2.51 26 13 31.85 2.9427 5.4 13.23 2.49 27 13.5 33.075 2.8428 5.6 13.72 2.49 28 14 34.3 3.3529 5.8 14.21 2.46 29 14.5 35.525 3.0130 6 14.7 2.45 30 15 36.75 2.9231 6.2 15.19 2.44 31 15.5 37.975 2.832 6.4 15.68 2.44 32 16 39.2 2.7433 6.6 16.17 2.42 33 16.5 40.425 2.6934 6.8 16.66 2.42 34 17 41.65 2.6335 7 17.15 2.38 35 17.5 42.875 2.55

36 18 44.1 2.5437 18.5 45.325 2.5638 19 46.55 2.5239 19.5 47.775 2.5440 20 49 2.5241 20.5 50.225 2.4942 21 51.45 2.46


ABCC Data

Sample ID A13027EB0902908 Sample 30 (WRRD0524)HCl Molarity: 0.5 (194 - 196)mL Increments: 0.4Weight (g) 2

Addition

mLs added (total)

kg H2SO4 pH

0 0 0 8.381 0.4 4.9 6.342 0.8 9.8 6.023 1.2 14.7 6.064 1.6 19.6 5.525 2 24.5 5.326 2.4 29.4 5.787 2.8 34.3 5.358 3.2 39.2 5.039 3.6 44.1 5.8610 4 49 5.5511 4.4 53.9 5.2512 4.8 58.8 5.0213 5.2 63.7 5.0114 5.6 68.6 4.515 6 73.5 3.7216 6.4 78.4 4.9917 6.8 83.3 4.817 6.8 83.3 4.818 7.2 88.2 4.4919 7.6 93.1 3.7820 8 98 3.2121 8.4 102.9 2.8922 8.8 107.8 2.6623 9.2 112.7 2.5224 9.6 117.6 2.4125 10 122.5 2.3326 10.4 127.4 2.21



Appendix 12: Net Acid Production Potential & Classification


Net Acid Production Potential

SMC Sample ID Zone Domain Weather MPA AP ANC NAPP NAGpH NPRClass (NPR)

Class (AMIRA)

Units pH UnitLOR 0.06/0.3 0.2 0.1A13020 M BIF 0.21 <0.49 -0.04 6.3 1.2 NAF NAFA13024 M BIF 2.57 13.72 -11.1 7.7 5.3 NAF NAFA13025 M BIF 1.90 15.68 -13.8 7.7 8.3 NAF NAFA13028 M BIF 3.55 12.74 -9.2 7.9 3.6 NAF NAFA13029 M BIF 8.17 13.72 -5.5 7 1.7 UC NAFA13033 M BIF 0.08 <0.49 -0.2 5.3 3.3 NAF NAFA13034 M BIF 3.43 2.53 <0.49 3.2 6.1 0.1 PAF NAFA13036 M BIF 0.61 14.7 -14.1 8.5 24 NAF NAFA13037 M BIF 18.94 8.82 10.1 3 0.5 PAF PAF - LCA13049 M BIF 1.68 1.34 <0.49 1.4 6 0.1 NAF NAFA13050 M BIF 1.56 1.35 <0.49 1.3 5.7 0.2 NAF NAFA13051 M BIF 0.08 <0.49 -0.2 4.8 3.3 NAF NAFA13052 M BIF 2.94 2.35 <0.49 2.7 4.7 0.1 NAF NAFA13054 M BIF 0.24 <0.49 -0.01 5 1.0 NAF NAFA13055 M BIF 0.08 <0.49 -0.2 4.6 3.3 NAF NAFA13056 M BIF 2.72 <0.49 2.5 2.9 0.1 NAF NAFA13057 M BIF 6.98 <0.49 6.7 2.3 0.04 PAF PAF - LCA13059 M BIF 23.81 <0.49 23.6 1.9 0.01 PAF PAF - LCADML_1B_012 M BIF EW 0.61 0.8 -0.2 --- 1.3 NAF ADML_1B_014 M BIF MW 0.15 <0.5 -0.1 --- 1.6 NAF ADML_1B_015 M BIF FR 4.90 7.3 -2.4 7.2 1.5 UC NAFADML_1B_016 M BIF FR 1.53 1.4 0.1 4.1 0.9 NAF NAFADML_1B_017 M BIF FR 3.06 6.8 -3.7 6.9 2.2 UC NAFADML_1B_018 M BIF MW 0.15 1.5 -1.3 5.8 9.8 NAF NAFADML_1B_019 M BIF FR 0.15 <0.5 -0.1 --- 1.6 NAF ADML_1B_021 M BIF MW 0.92 1.6 -0.7 --- 1.7 NAF ADML_1B_022 M BIF FR 0.31 <0.5 0.1 5.6 0.8 NAF NAFADML_1B_023 M BIF EW 0.61 2.4 -1.8 --- 3.9 NAF ADML_1B_047 M BIF FR 0.15 <0.5 -0.1 5.4 1.6 NAF NAFADML_1B_074 M BIF EW 0.15 1.7 -1.5 6.7 11.1 NAF NAFADML_1B_077 M BIF MW 0.31 0.5 -0.2 8.8 1.6 NAF NAFADML_1B_187 M BIF EW 0.15 3.4 -3.2 5 22.2 NAF NAFADML_1B_193 M BIF EW 0.15 1.8 -1.6 5.8 11.8 NAF NAFADML_1B_204 M BIF MW 0.15 1 -0.8 --- 6.5 NAF ADML_1B_205 M BIF FR 0.15 1.4 -1.2 5 9.2 NAF NAFADML_1B_211 M BIF FR 0.61 3.8 -3.2 --- 6.2 NAF ADML_1B_213 M BIF MW 0.31 1.2 -0.9 --- 3.9 NAF ADML_1B_214 M BIF MW 0.15 1.7 -1.5 --- 11.1 NAF ADML_1B_225 M BIF MW 0.15 2 -1.8 --- 13.1 NAF ADML_1B_227 M BIF MW 0.15 0.6 -0.4 --- 3.9 NAF ADML_1B_229 M BIF MW 0.15 <0.5 -0.1 --- 1.6 NAF A13019 M Detrital 1.99 1.43 <0.49 1.7 5.3 0.1 NAF NAFA13030 M Detrital 0.34 0.23 <0.49 0.1 5.3 0.7 NAF NAFA13047 M Detrital 1.74 2.94 -1.2 5.7 1.7 NAF NAFADML_1B_010 M Detrital MW 1.53 0.5 1.0 6.2 0.3 NAF NAFADML_1B_024 M Detrital MW 0.15 2.4 -2.2 --- 15.7 NAF ADML_1B_027 M Detrital MW 3.06 0.8 2.3 --- 0.3 PAF ADML_1B_035 M Detrital MW 1.53 1.9 -0.4 --- 1.2 NAF ADML_1B_036 M Detrital MW 1.53 0.8 0.7 --- 0.5 NAF ADML_1B_037 M Detrital MW 0.61 1.1 -0.5 5.8 1.8 NAF NAFADML_1B_038 M Detrital EW 0.15 2.1 -1.9 --- 13.7 NAF ADML_1B_040 M Detrital EW 2.14 0.5 1.6 --- 0.2 NAF ADML_1B_041 M Detrital MW 1.22 <0.5 1.0 --- 0.2 NAF ADML_1B_045 M Detrital MW 1.84 <0.5 1.6 5.3 0.1 NAF NAFADML_1B_046 M Detrital EW 1.84 <0.5 1.6 --- 0.1 NAF ADML_1B_049 M Detrital EW 1.22 <0.5 1.0 --- 0.2 NAF

kg(H2SO4)/t

Note: Where measured values were below the limit of reporting (LOR) the value was set to 0.5 x LOR for use in calculation




Class (AMIRA)

Units pH UnitLOR 0.06/0.3 0.2 0.1

kg(H2SO4)/t

ADML_1B_050 M Detrital MW 0.61 <0.5 0.4 --- 0.4 NAF ADML_1B_051 M Detrital EW 0.31 1.1 -0.8 4.3 3.6 NAF NAFADML_1B_060 M Detrital EW 0.31 <0.5 0.1 --- 0.8 NAF ADML_1B_061 M Detrital EW 0.15 <0.5 -0.1 6.4 1.6 NAF NAFADML_1B_062 M Detrital EW 0.15 2.4 -2.2 --- 15.7 NAF ADML_1B_063 M Detrital EW 0.15 1.1 -0.9 7.5 7.2 NAF NAFADML_1B_067 M Detrital EW 0.31 2.7 -2.4 --- 8.8 NAF ADML_1B_068 M Detrital MW 0.31 1.1 -0.8 4.9 3.6 NAF NAFADML_1B_206 M Detrital EW 0.31 3.4 -3.1 --- 11.1 NAF ADML_1B_212 M Detrital EW 1.22 1.9 -0.7 --- 1.6 NAF ADML_1B_215 M Detrital EW 2.14 1.4 0.7 --- 0.7 NAF ADML_1B_216 M Detrital EW 0.31 3.6 -3.3 --- 11.8 NAF ADML_1B_217 M Detrital EW 1.53 3.8 -2.3 --- 2.5 NAF ADML_1B_218 M Detrital EW 3.06 2.9 0.2 --- 0.9 PAF ADML_1B_219 M Detrital EW 2.45 4.3 -1.9 --- 1.8 NAF ADML_1B_032 M Felsic FR 0.15 9.4 -9.2 7.2 61.4 NAF NAFADML_1B_033 M Felsic EW 0.15 8 -7.8 7.6 52.3 NAF NAFADML_1B_034 M Felsic MW 0.15 9.9 -9.7 7.3 64.7 NAF NAFADML_1B_257 M Felsic EW 0.31 4.7 -4.4 6.1 15.4 NAF NAFADML_1B_258 M Felsic MW 0.92 2.5 -1.6 6.5 2.7 NAF NAFADML_1B_259 M Felsic EW 0.92 2.2 -1.3 5.5 2.4 NAF NAFADML_1B_260 M Felsic MW 0.61 1 -0.4 5.6 1.6 NAF NAFADML_1B_261 M Felsic MW 0.31 1.5 -1.2 5.2 4.9 NAF NAFADML_1B_262 M Felsic EW 0.31 2 -1.7 6.1 6.5 NAF NAFADML_1B_265 M Felsic MW 0.92 1.3 -0.4 6.2 1.4 NAF NAFADML_1B_270 M Felsic MW 0.92 0.8 0.1 6.1 0.9 NAF NAFA13021 M Hydrated 1.62 1.43 <0.49 1.4 5.8 0.2 NAF NAFA13023 M Hydrated 1.71 1.60 <0.49 1.5 5.8 0.1 NAF NAFA13035 M Hydrated 2.75 2.38 <0.49 2.5 6.1 0.1 NAF NAFA13053 M Hydrated 1.71 <0.49 1.5 4.9 0.1 NAF NAFADML_1B_043 M Hydrated MW 0.15 <0.5 -0.1 5.7 1.6 NAF NAFADML_1B_044 M Hydrated FR 0.15 0.5 -0.3 5.7 3.3 NAF NAFADML_1B_048 M Hydrated MW 0.15 <0.5 -0.1 --- 1.6 NAF ADML_1B_075 M Hydrated MW 0.61 1.6 -1.0 --- 2.6 NAF ADML_1B_076 M Hydrated EW 0.31 0.5 -0.2 6.2 1.6 NAF NAFADML_1B_078 M Hydrated FR 0.15 <0.5 -0.1 8.1 1.6 NAF NAFADML_1B_226 M Hydrated EW 0.31 2.2 -1.9 --- 7.2 NAF ADML_1B_228 M Hydrated MW 0.15 <0.5 -0.1 --- 1.6 NAF ADML_1B_241 M Hydrated EW 0.31 6.7 -6.4 7.3 21.9 NAF NAFADML_1B_242 M Hydrated EW 0.15 7.2 -7.0 7.1 47.1 NAF NAFADML_1B_243 M Hydrated MW 14.38 14.3 6.4 8.0 5.8 0.4 PAF UC(NAF)ADML_1B_244 M Hydrated MW 0.31 2.5 -2.2 5.5 8.2 NAF NAFADML_1B_245 M Hydrated MW 0.92 7.7 -6.8 7.9 8.4 NAF NAFADML_1B_246 M Hydrated MW 1.84 2.5 -0.7 5.6 1.4 NAF NAFADML_1B_247 M Hydrated FR 4.90 1.2 3.7 3.2 0.2 PAF PAF - LCADML_1B_248 M Hydrated MW 0.15 0.7 -0.5 4 4.6 NAF NAFADML_1B_249 M Hydrated MW 261.94 262 <0.5 262 1.7 0.0 PAF PAFADML_1B_250 M Hydrated FR 6.12 6.9 -0.8 7.8 1.1 UC NAFADML_1B_251 M Hydrated MW 1.22 1.7 -0.5 11 1.4 NAF NAFADML_1B_252 M Hydrated EW 0.92 2.7 -1.8 5.6 2.9 NAF NAFADML_1B_254 M Hydrated FR 0.92 1.7 -0.8 6.2 1.9 NAF NAFADML_1B_255 M Hydrated FR 0.61 2 -1.4 6.1 3.3 NAF NAFADML_1B_256 M Hydrated FR 0.15 3.2 -3.0 5.5 20.9 NAF NAFADML_1B_271 M Hydrated EW 0.61 1.3 -0.7 6.7 2.1 NAF NAFADML_1B_272 M Hydrated EW 0.31 1 -0.7 7.8 3.3 NAF NAFADML_1B_273 M Hydrated EW 0.15 <0.5 -0.1 5.4 1.6 NAF NAF





Class (AMIRA)


kg(H2SO4)/t

A13022 M Mafic 0.67 0.57 <0.49 0.4 6.2 0.4 NAF NAFA13031 M Mafic 0.08 <0.49 -0.2 5.9 3.3 NAF NAFA13032 M Mafic 0.08 <0.49 -0.2 5.9 3.3 NAF NAFA13048 M Mafic 0.08 <0.49 -0.2 5 3.3 NAF NAFADML_1B_009 M Mafic EW 0.15 <0.5 -0.1 --- 1.6 NAF ADML_1B_011 M Mafic EW 0.15 <0.5 -0.1 --- 1.6 NAF ADML_1B_025 M Mafic EW 0.15 0.8 -0.6 --- 5.2 NAF ADML_1B_026 M Mafic MW 0.31 1.1 -0.8 6.4 3.6 NAF NAFADML_1B_039 M Mafic EW 0.15 0.5 -0.3 --- 3.3 NAF ADML_1B_056 M Mafic FR 14.69 14.6 7.5 7.2 3.3 0.5 PAF PAFADML_1B_069 M Mafic EW 0.15 16.2 -16 --- 106 NAF ADML_1B_070 M Mafic FR 0.92 11.5 -10.6 7.1 12.5 NAF NAFADML_1B_071 M Mafic FR 0.31 10.5 -10.2 7.3 34.3 NAF NAFADML_1B_191 M Mafic MW 0.15 8.2 -8.0 8 53.6 NAF NAFADML_1B_200 M Mafic EW 0.15 3.6 -3.4 5.7 23.5 NAF NAFADML_1B_208 M Mafic EW 0.15 3.8 -3.6 --- 24.8 NAF ADML_1B_237 M Mafic FR 4.28 8.9 -4.6 5.5 2.1 UC NAFADML_1B_238 M Mafic MW 0.15 4.2 -4.0 6.6 27.5 NAF NAFADML_1B_008 M Ore FR 2.14 <0.5 1.9 6.9 0.1 NAF NAFADML_1B_029 M Ore FR 2.14 0.8 1.3 --- 0.4 NAF ADML_1B_031 M Ore FR 1.53 0.8 0.7 --- 0.5 NAF ADML_1B_042 M Ore EW 0.31 0.8 -0.5 6.9 2.6 NAF NAFADML_1B_054 M Ore EW 3.37 0.5 2.9 --- 0.1 PAF ADML_1B_055 M Ore EW 3.06 <0.5 2.8 --- 0.1 PAF ADML_1B_057 M Ore EW 3.37 <0.5 3.1 --- 0.1 PAF ADML_1B_064 M Ore MW 5.51 <0.5 5.3 --- 0.0 PAF ADML_1B_066 M Ore EW 2.75 <0.5 2.5 6.9 0.1 NAF NAFADML_1B_072 M Ore MW 2.14 0.9 1.2 --- 0.4 NAF ADML_1B_188 M Ore FR 0.15 2.2 -2.0 --- 14.4 NAF ADML_1B_189 M Ore MW 0.61 1.4 -0.8 --- 2.3 NAF ADML_1B_192 M Ore FR 1.53 2.4 -0.9 --- 1.6 NAF ADML_1B_209 M Ore MW 2.45 3.1 -0.7 --- 1.3 NAF ADML_1B_210 M Ore MW 1.84 3.6 -1.8 7 2.0 NAF NAFADML_1B_030 M Ore Hi Al FR 0.15 1.3 -1.1 3.7 8.5 NAF NAFADML_1B_053 M Ore Hi Al MW 1.22 <0.5 1.0 6.4 0.2 NAF NAFADML_1B_058 M Ore Hi Al MW 0.61 <0.5 0.4 --- 0.4 NAF ADML_1B_190 M Ore Hi Al FR 1.53 4.1 -2.6 --- 2.7 NAF ADML_1B_194 M Ore Hi Al FR 2.75 3.4 -0.6 --- 1.2 NAF ADML_1B_195 M Ore Hi Al MW 0.15 3.6 -3.4 --- 23.5 NAF ADML_1B_198 M Ore Hi Al MW 1.53 2.4 -0.9 6.6 1.6 NAF NAFADML_1B_202 M Ore Hi Al MW 0.15 2.7 -2.5 --- 17.6 NAF ADML_1B_231 M Ore Hi Al EW 0.61 1.7 -1.1 --- 2.8 NAF ADML_1B_234 M Ore Hi Al FR 0.15 3 -2.8 6.8 19.6 NAF NAFADML_1B_235 M Ore Hi Al EW 2.45 1.8 0.6 6.4 0.7 NAF NAFADML_1B_236 M Ore Hi Al FR 0.61 1.4 -0.8 --- 2.3 NAF ADML_1B_013 M Ore Hi SiO2 EW 2.45 2.3 0.1 --- 0.9 NAF ADML_1B_020 M Ore Hi SiO2 FR 0.15 <0.5 -0.1 --- 1.6 NAF ADML_1B_028 M Ore Hi SiO2 MW 3.06 1.1 2.0 --- 0.4 PAF ADML_1B_052 M Ore Hi SiO2 MW 0.31 <0.5 0.1 --- 0.8 NAF ADML_1B_059 M Ore Hi SiO2 FR 0.31 <0.5 0.1 --- 0.8 NAF ADML_1B_065 M Ore Hi SiO2 EW 2.45 <0.5 2.2 --- 0.1 NAF ADML_1B_073 M Ore Hi SiO2 MW 2.45 1.6 0.8 --- 0.7 NAF ADML_1B_196 M Ore Hi SiO2 EW 0.15 2.4 -2.2 --- 15.7 NAF ADML_1B_199 M Ore Hi SiO2 EW 0.15 1.2 -1.0 --- 7.8 NAF ADML_1B_201 M Ore Hi SiO2 FR 1.22 1.9 -0.7 --- 1.6 NAF ADML_1B_203 M Ore Hi SiO2 EW 0.92 1.9 -1.0 6.8 2.1 NAF NAF





Class (AMIRA)


kg(H2SO4)/t

ADML_1B_207 M Ore Hi SiO2 MW 0.61 2.4 -1.8 --- 3.9 NAF ADML_1B_230 M Ore Hi SiO2 FR 2.45 1.4 1.0 --- 0.6 NAF ADML_1B_232 M Ore Hi SiO2 MW 0.15 0.6 -0.4 --- 3.9 NAF ADML_1B_233 M Ore Hi SiO2 FR 3.06 0.6 2.5 --- 0.2 PAF A13026 M Shale 35.80 47.04 -11.2 7.1 1.3 UC NAFA13027 M Shale 39.78 117.6 -77.8 7.8 3.0 UC NAFA13038 M Shale 34.88 117.6 -82.7 9.3 3.4 NAF NAFA13039 M Shale 57.22 127.4 -70.2 8.6 2.2 UC NAFA13058 M Shale 0.08 <0.49 -0.2 5.8 3.3 NAF NAFADML_1B_274 M Shale MW 97.31 97 5.3 92.0 2.1 0.1 PAF PAFADML_1B_275 M Shale MW 12.24 12 5.6 6.6 3 0.5 PAF PAF - LCADML_1B_276 M Shale MW 90.88 91 4.8 86.1 2.1 0.1 PAF PAFADML_1B_277 M Shale MW 62.42 62 4.8 57.6 2.4 0.1 PAF PAFADML_1B_280 M Shale MW 728.28 728 <0.5 728 1.7 0.0 PAF PAFADML_1B_281 M Shale MW 2.75 6.9 -4.1 5.7 2.5 NAF NAFADML_1B_282 M Shale EW 11.93 12 2.5 9.4 3 0.2 PAF PAFADML_1B_283 M Shale EW 0.15 2.3 -2.1 6 15.0 NAF NAFADML_1B_284 M Shale EW 2.14 2.3 -0.2 4.6 1.1 NAF NAFADML_1B_285 M Shale EW 0.15 3 -2.8 5.9 19.6 NAF NAFADML_1B_286 M Shale EW 0.92 2.5 -1.6 5.6 2.7 NAF NAFADML_1B_287 M Shale EW 0.31 2.8 -2.5 5.8 9.2 NAF NAFADML_1B_288 M Shale EW 0.15 1.5 -1.3 6.2 9.8 NAF NAFADML_1B_289 M Shale EW 0.31 2.3 -2.0 6 7.5 NAF NAFA13003 B BIF 0.28 <0.49 0.03 5.5 0.9 NAF NAFA13004 B BIF 0.31 <0.49 0.1 5 0.8 NAF NAFA13005 B BIF 0.18 0.08 <0.49 -0.1 5.4 1.4 NAF NAFA13006 B BIF 0.08 <0.49 -0.2 5.6 3.3 NAF NAFA13011 B BIF 0.08 4.9 -4.8 6.6 64.1 NAF NAFA13013 B BIF 0.08 98 -97.9 8.3 1281 NAF NAFA13014 B BIF 0.21 91.14 -90.9 8.4 425 NAF NAFA13015 B BIF 0.24 117.6 -117.4 8.1 480 NAF NAFA13016 B BIF 14.50 47.04 -32.5 7.7 3.2 NAF NAFA13042 B BIF 0.08 40.18 -40.1 8.6 525 NAF NAFA13043 B BIF 0.08 88.2 -88.1 9.6 1153 NAF NAFA13044 B BIF 0.08 <0.49 -0.2 7.8 3.3 NAF NAFADML_1B_083 B BIF EW 0.15 <0.5 -0.1 4.6 1.6 NAF NAFADML_1B_084 B BIF MW 0.15 1.1 -0.9 7.2 7.2 NAF NAFADML_1B_098 B BIF MW 0.15 0.9 -0.7 6.8 5.9 NAF NAFADML_1B_100 B BIF MW 0.15 0.7 -0.5 7.2 4.6 NAF NAFADML_1B_107 B BIF EW 0.15 1.2 -1.0 6.8 7.8 NAF NAFADML_1B_130 B BIF EW 0.15 28.6 -28.4 --- 187 NAF ADML_1B_138 B BIF MW 0.15 0.7 -0.5 5.2 4.6 NAF NAFADML_1B_138 B BIF MW 2.14 <0.5 1.9 --- 0.1 NAF ADML_1B_149 B BIF FR 0.15 11.6 -11.4 7.6 75.8 NAF NAFADML_1B_156 B BIF EW 0.15 13.6 -13.4 7.6 88.9 NAF NAFADML_1B_174 B BIF MW 0.15 67.7 -67.5 9.4 442 NAF NAFADML_1B_185 B BIF MW 0.61 1.4 -0.8 4.6 2.3 NAF NAFADML_1B_186 B BIF FR 0.15 1.9 -1.7 5.8 12.4 NAF NAFADML_1B_197 B BIF FR 0.15 3.4 -3.2 7.8 22.2 NAF NAFADML_1B_221 B BIF MW 0.15 2.3 -2.1 5.3 15.0 NAF NAFA13001 B Mafic 0.70 0.6 0.98 -0.3 4.8 1.4 NAF NAFA13002 B Mafic 0.24 <0.49 -0.01 4.9 1.0 NAF NAFA13007 B Mafic 0.08 4.9 -4.8 6.7 64.1 NAF NAFA13008 B Mafic 0.08 6.86 -6.8 6.6 89.7 NAF NAFA13009 B Mafic 0.08 <0.49 -0.2 5.5 3.3 NAF NAFA13010 B Mafic 0.08 14.7 -14.6 6.5 192 NAF NAF





Class (AMIRA)


kg(H2SO4)/t

A13012 B Mafic 0.08 22.54 -22.5 7 295 NAF NAFA13017 B Mafic 0.46 38.22 -37.8 7.5 83.3 NAF NAFA13018 B Mafic 1.96 32.34 -30.4 7.8 16.5 NAF NAFA13040 B Mafic 0.08 3.92 -3.8 6.5 51.2 NAF NAFA13041 B Mafic 0.08 12.74 -12.7 7.1 167 NAF NAFA13045 B Mafic 0.08 20.58 -20.5 6.5 269 NAF NAFA13046 B Mafic 1.38 29.4 -28.0 6.3 21.4 NAF NAFADML_1B_001 B Mafic EW 0.15 <0.5 -0.1 5 1.6 NAF NAFADML_1B_005 B Mafic EW 0.15 1.9 -1.7 --- 12.4 NAF ADML_1B_006 B Mafic MW 0.15 5.2 -5.0 7.4 34.0 NAF NAFADML_1B_007 B Mafic EW 0.15 3.8 -3.6 --- 24.8 NAF ADML_1B_079 B Mafic EW 0.15 <0.5 -0.1 --- 1.6 NAF ADML_1B_080 B Mafic MW 0.15 7.8 -7.6 7 51.0 NAF NAFADML_1B_081 B Mafic MW 0.15 2.8 -2.6 --- 18.3 NAF ADML_1B_082 B Mafic EW 0.15 4.3 -4.1 --- 28.1 NAF ADML_1B_085 B Mafic FR 0.15 12.5 -12.3 8 81.7 NAF NAFADML_1B_086 B Mafic MW 0.15 19.7 -19.5 --- 129 NAF ADML_1B_087 B Mafic EW 0.15 3.2 -3.0 --- 20.9 NAF ADML_1B_088 B Mafic FR 0.61 22 -21.4 8.1 35.9 NAF NAFADML_1B_089 B Mafic MW 0.15 14.6 -14.4 --- 95.4 NAF ADML_1B_090 B Mafic FR 0.15 20.2 -20.0 --- 132 NAF ADML_1B_091 B Mafic FR 0.61 18.2 -17.6 7.4 29.7 NAF NAFADML_1B_092 B Mafic EW 0.15 5.7 -5.5 --- 37.3 NAF ADML_1B_093 B Mafic MW 0.15 11.2 -11.0 8.3 73.2 NAF NAFADML_1B_094 B Mafic FR 0.15 10.6 -10.4 --- 69.3 NAF ADML_1B_095 B Mafic EW 0.15 16.9 -16.7 --- 110 NAF ADML_1B_096 B Mafic MW 0.15 <0.5 -0.1 --- 1.6 NAF ADML_1B_097 B Mafic EW 0.15 1.9 -1.7 --- 12.4 NAF ADML_1B_103 B Mafic MW 0.15 5.7 -5.5 --- 37.3 NAF ADML_1B_104 B Mafic FR 0.15 12.4 -12.2 --- 81.0 NAF ADML_1B_105 B Mafic EW 0.15 35.3 -35.1 --- 231 NAF ADML_1B_106 B Mafic MW 0.15 2.5 -2.3 --- 16.3 NAF ADML_1B_108 B Mafic EW 0.15 1.8 -1.6 --- 11.8 NAF ADML_1B_112 B Mafic EW 0.15 7.2 -7.0 --- 47.1 NAF ADML_1B_113 B Mafic MW 0.15 14.9 -14.7 8.2 97.4 NAF NAFADML_1B_114 B Mafic FR 0.15 12.5 -12.3 8.2 81.7 NAF NAFADML_1B_116 B Mafic EW 0.15 11.6 -11.4 --- 75.8 NAF ADML_1B_117 B Mafic MW 0.15 13.1 -12.9 8.1 85.6 NAF NAFADML_1B_119 B Mafic EW 0.31 8.4 -8.1 --- 27.5 NAF ADML_1B_120 B Mafic MW 0.15 10.5 -10.3 --- 68.6 NAF ADML_1B_121 B Mafic EW 0.15 10.6 -10.4 --- 69.3 NAF ADML_1B_122 B Mafic FR 1.22 12.7 -11.5 --- 10.4 NAF ADML_1B_123 B Mafic EW 0.15 18.9 -18.7 --- 124 NAF ADML_1B_124 B Mafic MW 0.15 10.6 -10.4 --- 69.3 NAF ADML_1B_126 B Mafic FR 0.15 14 -13.8 7.8 91.5 NAF NAFADML_1B_128 B Mafic MW 0.15 18.3 -18.1 --- 120 NAF ADML_1B_129 B Mafic EW 0.15 4.3 -4.1 --- 28.1 NAF ADML_1B_131 B Mafic EW 0.15 15.4 -15.2 --- 101 NAF ADML_1B_132 B Mafic MW 0.15 22.7 -22.5 8.2 148 NAF NAFADML_1B_133 B Mafic FR 0.15 10.3 -10.1 7.9 67.3 NAF NAFADML_1B_134 B Mafic EW 0.15 13.6 -13.4 --- 88.9 NAF ADML_1B_135 B Mafic EW 0.15 7.3 -7.1 --- 47.7 NAF ADML_1B_136 B Mafic MW 0.15 9.8 -9.6 --- 64.1 NAF ADML_1B_137 B Mafic EW 11.02 10.914 0.6 10.4 --- 0.1 PAF ADML_1B_139 B Mafic EW 0.61 61.8 -61.2 10 101 NAF NAFADML_1B_140 B Mafic EW 0.15 1.2 -1.0 --- 7.8 NAF





Class (AMIRA)


kg(H2SO4)/t

ADML_1B_141 B Mafic EW 0.15 11.1 -10.9 --- 72.5 NAF ADML_1B_142 B Mafic MW 0.15 12.5 -12.3 --- 81.7 NAF ADML_1B_143 B Mafic FR 0.15 1 -0.8 4.9 6.5 NAF NAFADML_1B_144 B Mafic EW 0.15 1.4 -1.2 --- 9.2 NAF ADML_1B_146 B Mafic MW 0.15 0.7 -0.5 --- 4.6 NAF ADML_1B_150 B Mafic FR 1.84 11.8 -10.0 7.3 6.4 NAF NAFADML_1B_151 B Mafic MW 0.15 10.8 -10.6 --- 70.6 NAF ADML_1B_152 B Mafic FR 0.15 16 -15.8 --- 105 NAF ADML_1B_153 B Mafic MW 0.15 9.6 -9.4 --- 62.7 NAF ADML_1B_154 B Mafic MW 0.15 3.9 -3.7 --- 25.5 NAF ADML_1B_155 B Mafic EW 0.15 9.6 -9.4 --- 62.7 NAF ADML_1B_157 B Mafic EW 0.15 10.3 -10.1 --- 67.3 NAF ADML_1B_158 B Mafic MW 0.15 11 -10.8 --- 71.9 NAF ADML_1B_159 B Mafic MW 0.15 2.7 -2.5 6.1 17.6 NAF NAFADML_1B_160 B Mafic EW 0.15 11.5 -11.3 --- 75.2 NAF ADML_1B_161 B Mafic EW 0.15 10.9 -10.7 --- 71.2 NAF ADML_1B_162 B Mafic EW 0.15 6.2 -6.0 --- 40.5 NAF ADML_1B_163 B Mafic MW 0.15 3.8 -3.6 --- 24.8 NAF ADML_1B_164 B Mafic EW 0.15 12.7 -12.5 --- 83.0 NAF ADML_1B_167 B Mafic MW 0.15 13.1 -12.9 --- 85.6 NAF ADML_1B_168 B Mafic MW 0.15 6.8 -6.6 --- 44.4 NAF ADML_1B_169 B Mafic MW 0.15 4.4 -4.2 5.6 28.8 NAF NAFADML_1B_175 B Mafic MW 0.15 8.2 -8.0 --- 53.6 NAF ADML_1B_179 B Magnetite FR 0.61 90.6 -90.0 9 148 NAF NAFADML_1B_180 B Magnetite MW 0.15 91.8 -91.6 8.6 600 NAF NAFADML_1B_181 B Magnetite FR 0.15 96.7 -96.5 8.6 632 NAF NAFADML_1B_222 B Magnetite FR 0.15 193 -192.8 6.3 1261 NAF NAFADML_1B_002 B Ore MW 0.15 <0.5 -0.1 --- 1.6 NAF ADML_1B_102 B Ore MW 0.15 <0.5 -0.1 --- 1.6 NAF ADML_1B_109 B Ore MW 0.61 1.8 -1.2 --- 2.9 NAF ADML_1B_111 B Ore EW 0.15 1.9 -1.7 --- 12.4 NAF ADML_1B_115 B Ore EW 0.61 1.2 -0.6 5.5 2.0 NAF NAFADML_1B_118 B Ore FR 0.15 1.7 -1.5 6.8 11.1 NAF NAFADML_1B_125 B Ore FR 0.15 117 -116.8 11.3 765 NAF NAFADML_1B_147 B Ore MW 0.15 12.3 -12.1 --- 80.4 NAF ADML_1B_171 B Ore EW 0.15 5.3 -5.1 5.3 34.6 NAF NAFADML_1B_173 B Ore FR 0.15 42.3 -42.1 6.2 276 NAF NAFADML_1B_177 B Ore MW 0.15 3.2 -3.0 --- 20.9 NAF ADML_1B_178 B Ore FR 0.15 55.6 -55.4 7.9 363 NAF NAFADML_1B_224 B Ore EW 0.15 3.1 -2.9 --- 20.3 NAF ADML_1B_110 B Ore Hi Al EW 3.67 5.5 -1.8 8 1.5 UC NAFADML_1B_127 B Ore Hi Al MW 0.15 5.6 -5.4 8 36.6 NAF NAFADML_1B_145 B Ore Hi Al MW 0.15 <0.5 -0.1 6.5 1.6 NAF NAFADML_1B_145 B Ore Hi Al MW 0.15 0.7 -0.5 --- 4.6 NAF ADML_1B_172 B Ore Hi Al EW 0.15 4.4 -4.2 5.3 28.8 NAF NAFADML_1B_182 B Ore Hi Al MW 0.15 3.9 -3.7 6.6 25.5 NAF NAFADML_1B_183 B Ore Hi Al MW 0.15 4.4 -4.2 7.4 28.8 NAF NAFADML_1B_184 B Ore Hi Al EW 0.15 10.7 -10.5 7.4 69.9 NAF NAFADML_1B_278 B Ore Hi Al MW 1.53 2.3 -0.8 4.9 1.5 NAF NAFADML_1B_279 B Ore Hi Al MW 1.84 4.1 -2.3 5.9 2.2 NAF NAFADML_1B_003 B Ore Hi SiO2 FR 5.81 168 -162.2 --- 28.9 NAF ADML_1B_004 B Ore Hi SiO2 MW 0.15 4.9 -4.7 --- 32.0 NAF ADML_1B_099 B Ore Hi SiO2 EW 0.15 1.5 -1.3 5.3 9.8 NAF NAFADML_1B_101 B Ore Hi SiO2 EW 0.15 0.6 -0.4 --- 3.9 NAF ADML_1B_148 B Ore Hi SiO2 EW 0.15 11.2 -11.0 --- 73.2 NAF ADML_1B_170 B Ore Hi SiO2 MW 0.15 4.7 -4.5 --- 30.7 NAF





Class (AMIRA)


kg(H2SO4)/t

ADML_1B_176 B Ore Hi SiO2 MW 0.15 65.2 -65.0 --- 426 NAF ADML_1B_220 B Ore Hi SiO2 FR 0.15 2.9 -2.7 --- 19.0 NAF ADML_1B_223 B Ore Hi SiO2 EW 0.15 4.4 -4.2 --- 28.8 NAF




Appendix 13: Kinetic Test Results

SRK ConsultingSMM004_Geochemical Characterisation of Weld Range

Kinetic Column DataSample ID A13017Date Cycle pH Cond. Acidity Alkalinity Sulphate Chloride Al Sb As Ba Be Cd Ca Cr Co Cu Fe Pb

Input Output umhos/cm (pH 8.3)mgCaCO3/L mgCaCO3/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L

LOD 0.10 2 5 5 1 1 0.01 0.00001 0.0001 0.00005 0.0001 0.00002 0.01 0.01 0.0001 0.01 0.01 0.0005

20-Apr-09 0 1000 770 6.8 100 <5 20 4 17 0.04 0.00031 0.0011 0.00124 <0.0001 <0.00002 1.85 <0.01 0.0001 0.01 <0.01 < 0.000502-May-09 1 1000 760 6.5 76 <5 11 13 10 0.03 0.00034 0.003 0.00044 <0.0001 <0.00002 1.2 <0.01 <0.0001 <0.01 0.02 < 0.000509-May-09 2 1000 760 7.5 7716-May-09 3 1000 770 7.3 9323-May-09 4 1000 790 7.2 53 <5 16 3 5 0.12 0.00036 0.0045 0.00028 <0.0001 <0.00002 1.08 <0.01 0.0001 <0.01 0.19 < 0.000530-May-09 5 1000 790 7 3806-Jun-09 6 1000 780 7.2 3913-Jun-09 7 1000 790 7.2 65 <5 18 7 3 0.09 0.00056 0.0054 0.00064 <0.0001 0.00004 1.34 <0.01 <0.0001 <0.01 0.09 < 0.000520-Jun-09 8 1000 790 7.6 5027-Jun-09 9 1000 790 7.1 5706-Jul-09 10 1000 790 7.3 56 <5 22 3 <1 0.03 0.00062 0.0059 0.00061 <0.0001 <0.00002 2.63 <0.01 <0.0001 <0.01 0.04 < 0.000513-Jul-09 11 1000 790 7.7 5318-Jul-09 12 1000 790 7.5 6025-Jul-09 13 1000 390 7.4 64 <5 33.0 12 20 0.02 0.00063 0.00420 0.00049 <0.0001 <0.00002 4 <0.01 <0.0001 <0.01 <0.01 < 0.000501-Aug-09 14 1000 760 7.5 6408-Aug-09 15 1000 810 7.3 2915-Aug-09 16 1000 710 7.2 40 <5 19.0 3 2.0 0.03 0.00033 0.0038 0.00133 <0.0001 <0.00002 2.4 <0.01 <0.0001 <0.01 0.04 < 0.0005

Volume mL

SRK ConsultingSMM004_Geochemical

Kinetic Column DataSample ID A13017Date Cycle

LOD

20-Apr-09 002-May-09 109-May-09 216-May-09 323-May-09 430-May-09 506-Jun-09 613-Jun-09 720-Jun-09 827-Jun-09 906-Jul-09 1013-Jul-09 1118-Jul-09 1225-Jul-09 1301-Aug-09 1408-Aug-09 1515-Aug-09 16

Characterisation of Weld Range

Mg Mn Hg Mo Ni P K Se Ag Na Sr Th Tl Sn U V Zn

mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/l mg/L mg/L mg/L mg/L mg/L0.01 0.01 0.0001 0.00005 0.01 0.1 0.1 0.0005 0.00001 0.1 0.00002 0.000005 0.00001 0.0001 0.000005 0.01 0.01

2.02 <0.01 0.0002 0.00155 <0.01 <0.1 2.5 0.0009 <0.00001 17.2 0.00898 0.000008 <0.00001 0.0004 0.000013 <0.01 0.011.33 <0.01 <0.0001 0.00226 <0.01 <0.1 1.5 0.0018 <0.00001 12.3 0.00522 < 0.000005 <0.00001 0.0003 0.00004 0.02 0.02

1.43 <0.01 <0.0001 0.00174 <0.01 <0.1 1.1 0.0014 0.00003 9.3 0.00381 0.000007 <0.00001 <0.0001 0.000062 0.06 <0.01

1.43 <0.01 <0.0001 0.00106 <0.01 <0.1 1 < 0.0005 <0.00001 6.3 0.00495 < 0.000005 <0.00001 <0.0001 0.000063 0.05 <0.01

2.78 <0.01 <0.0001 0.00069 <0.01 <0.1 1.6 < 0.0005 <0.00001 6.2 0.00914 0.000009 <0.00001 <0.0001 0.000123 0.07 0.04

4 <0.01 <0.0001 0.00071 <0.01 <0.1 2 < 0.0005 <0.00001 6.1 0.0112 < 0.000005 <0.00001 <0.0001 0.0002 0.05 0.02

2.53 <0.01 <0.0001 0.00028 <0.01 <0.1 1.3 < 0.0005 <0.00001 2.8 0.00828 < 0.000005 <0.00001 <0.0001 0.000281 0.04 0.02


Kinetic Column Elemental Concentration Plots

A13017

4

6

8

10

12

14

oncentration

(mg/L)

A13017

SO4

0

2

4

6

8

10

12

14

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13017

SO4

0

2

4

6

8

10

12

14

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13017

SO4

2.53

3.54

4.5

tion

(mg/L)

A13017

0

2

4

6

8

10

12

14

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13017

SO4

00.51

1.52

2.53

3.54

4.5

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13017

Ca

Mg

0

2

4

6

8

10

12

14

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13017

SO4

00.51

1.52

2.53

3.54

4.5

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13017

Ca

Mg

20

25

/L)

A13017

0

2

4

6

8

10

12

14

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13017

SO4

00.51

1.52

2.53

3.54

4.5

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13017

Ca

Mg

0

5

10

15

20

25

Concen

tration (m

g/L)

A13017

Cl

Na

0

2

4

6

8

10

12

14

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13017

SO4

00.51

1.52

2.53

3.54

4.5

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13017

Ca

Mg

0

5

10

15

20

25

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13017

Cl

Na



A13017

1.0E‐051.5E‐052.0E‐052.5E‐053.0E‐053.5E‐054.0E‐054.5E‐05

oncentration

(mg/L)

A13017

Cd

0.0E+005.0E‐061.0E‐051.5E‐052.0E‐052.5E‐053.0E‐053.5E‐054.0E‐054.5E‐05

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13017

Cd

0.0E+005.0E‐061.0E‐051.5E‐052.0E‐052.5E‐053.0E‐053.5E‐054.0E‐054.5E‐05

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13017

Cd

0 006

0.008

0.01

0.012

tion

(mg/L)

A13017

0.0E+005.0E‐061.0E‐051.5E‐052.0E‐052.5E‐053.0E‐053.5E‐054.0E‐054.5E‐05

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13017

Cd

0

0.002

0.004

0.006

0.008

0.01

0.012

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13017

As

Cu

0.0E+005.0E‐061.0E‐051.5E‐052.0E‐052.5E‐053.0E‐053.5E‐054.0E‐054.5E‐05

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13017

Cd

0

0.002

0.004

0.006

0.008

0.01

0.012

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13017

As

Cu

0.2

L)

A13017

0.0E+005.0E‐061.0E‐051.5E‐052.0E‐052.5E‐053.0E‐053.5E‐054.0E‐054.5E‐05

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13017

Cd

0

0.002

0.004

0.006

0.008

0.01

0.012

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13017

As

Cu

0

0.05

0.1

0.15

0.2

Concen

tration (m

g/L)

A13017

Al

Fe

0.0E+005.0E‐061.0E‐051.5E‐052.0E‐052.5E‐053.0E‐053.5E‐054.0E‐054.5E‐05

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13017

Cd

0

0.002

0.004

0.006

0.008

0.01

0.012

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13017

As

Cu

0

0.05

0.1

0.15

0.2

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13017

Al

Fe



A13017

0.0100.0150.0200.0250.0300.0350.0400.045

oncentration

(mg/L)

A13017

Ni

Zn

0.0000.0050.0100.0150.0200.0250.0300.0350.0400.045

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13017

Ni

Zn

0.0000.0050.0100.0150.0200.0250.0300.0350.0400.045

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13017

Ni

Zn

0 0010

0.0015

0.0020

tion

(mg/L)

A13017

0.0000.0050.0100.0150.0200.0250.0300.0350.0400.045

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13017

Ni

Zn

0.0000

0.0005

0.0010

0.0015

0.0020

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13017

Ba

Se

0.0000.0050.0100.0150.0200.0250.0300.0350.0400.045

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13017

Ni

Zn

0.0000

0.0005

0.0010

0.0015

0.0020

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13017

Ba

Se

0 010

0.012

L)

A13017

0.0000.0050.0100.0150.0200.0250.0300.0350.0400.045

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13017

Ni

Zn

0.0000

0.0005

0.0010

0.0015

0.0020

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13017

Ba

Se

0.000

0.002

0.004

0.006

0.008

0.010

0.012

Concen

tration (m

g/L)

A13017

Mn

Sr

0.0000.0050.0100.0150.0200.0250.0300.0350.0400.045

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13017

Ni

Zn

0.0000

0.0005

0.0010

0.0015

0.0020

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13017

Ba

Se

0.000

0.002

0.004

0.006

0.008

0.010

0.012

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13017

Mn

Sr




LOD 0.10 2 5 5 1 1 0.01 0.00001 0.0001 0.00005 0.0001 0.00002 0.01 0.01 0.0001 0.01 0.01 0.0005

20-Apr-09 0 1000 730 6.7 220 <5 18 52 18 <0.01 0.00007 0.0012 0.01286 <0.0001 0.00003 27.81 <0.01 0.0128 0.01 <0.01 < 0.000502-May-09 1 1000 710 5.9 170 <5 6 66 6 <0.01 0.00003 0.0008 0.00752 <0.0001 0.00002 26.67 <0.01 0.0049 <0.01 <0.01 < 0.000509-May-09 2 1000 710 6.6 13016-May-09 3 1000 720 6.5 11023-May-09 4 1000 720 6.4 80 <5 <5 26 3 0.04 0.00003 0.0006 0.00792 <0.0001 <0.00002 10.33 <0.01 0.0061 <0.01 0.04 < 0.000530-May-09 5 1000 720 6.7 7606-Jun-09 6 1000 720 6.8 6713-Jun-09 7 1000 720 6.6 57 <5 <5 20 3.0 <0.01 0.00002 0.0008 0.00824 <0.0001 <0.00002 6.45 <0.01 0.0039 <0.01 <0.01 < 0.000520-Jun-09 8 1000 720 7 5127-Jun-09 9 1000 720 6.9 4306-Jul-09 10 1000 720 6.5 41 <5 <5 13 2 <0.01 0.00002 0.0006 0.01032 <0.0001 0.00002 4.47 <0.01 0.0046 <0.01 <0.01 < 0.000513-Jul-09 11 1000 720 6.2 3618-Jul-09 12 1000 720 6.1 3525-Jul-09 13 1000 720 6.2 30 <5 <5 10 1 <0.01 0.00002 0.0003 0.00877 <0.0001 <0.00002 3.01 <0.01 0.0035 <0.01 <0.01 < 0.000501-Aug-09 14 1000 720 6.2 2708-Aug-09 15 1000 720 6.2 2515-Aug-09 16 1000 720 6.1 28 <5 <5 9 1 <0.01 0.00001 0.0003 0.00957 <0.0001 <0.00002 2.52 <0.01 0.0033 <0.01 <0.01 < 0.0005

Volume mL



LOD





5.02 0.09 <0.0001 0.00007 <0.01 <0.1 3.1 0.002 <0.00001 9.6 0.11245 0.000006 0.00002 0.0003 < 0.000005 <0.01 0.022.81 0.1 <0.0001 0.00006 <0.01 <0.1 1.1 0.0018 <0.00001 3.2 0.0677 0.000006 <0.00001 0.0002 < 0.000005 <0.01 0.03

1.95 0.1 <0.0001 < 0.00005 <0.01 <0.1 0.7 0.0017 0.00002 2.5 0.02687 0.000008 0.00001 <0.0001 0.000005 <0.01 <0.01

1.21 0.07 0.0003 < 0.00005 <0.01 <0.1 0.6 0.001 <0.00001 2.4 0.01903 < 0.000005 <0.00001 <0.0001 < 0.000005 <0.01 <0.01

0.95 0.08 <0.0001 < 0.00005 <0.01 <0.1 0.5 0.0006 <0.00001 1.4 0.01359 0.000008 <0.00001 <0.0001 < 0.000005 <0.01 0.03

0.63 0.07 <0.0001 < 0.00005 <0.01 <0.1 0.6 < 0.0005 <0.00001 1.2 0.00843 < 0.000005 <0.00001 <0.0001 < 0.000005 <0.01 0.02

0.57 0.07 <0.0001 < 0.00005 <0.01 <0.1 0.5 < 0.0005 <0.00001 1 0.00802 < 0.000005 <0.00001 <0.0001 0.000081 <0.01 0.02



A13019

20

30

40

50

60

70

oncentration

(mg/L)

A13019

SO4

0

10

20

30

40

50

60

70

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13019

SO4

0

10

20

30

40

50

60

70

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13019

SO4

15

20

25

30

tion

(mg/L)

A13019

0

10

20

30

40

50

60

70

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13019

SO4

0

5

10

15

20

25

30

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13019

Ca

Mg

0

10

20

30

40

50

60

70

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13019

SO4

0

5

10

15

20

25

30

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13019

Ca

Mg

20

/L)

A13019

0

10

20

30

40

50

60

70

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13019

SO4

0

5

10

15

20

25

30

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13019

Ca

Mg

0

5

10

15

20

Concen

tration (m

g/L)

A13019

Cl

Na

0

10

20

30

40

50

60

70

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13019

SO4

0

5

10

15

20

25

30

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13019

Ca

Mg

0

5

10

15

20

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13019

Cl

Na



A13019

0.00001

0.000015

0.00002

0.000025

0.00003

0.000035

oncentration

(mg/L)

A13019

Cd

0

0.000005

0.00001

0.000015

0.00002

0.000025

0.00003

0.000035

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13019

Cd

0

0.000005

0.00001

0.000015

0.00002

0.000025

0.00003

0.000035

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13019

Cd

0 006

0.008

0.01

0.012

tion

(mg/L)

A13019

0

0.000005

0.00001

0.000015

0.00002

0.000025

0.00003

0.000035

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13019

Cd

0

0.002

0.004

0.006

0.008

0.01

0.012

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13019

As

Cu

0

0.000005

0.00001

0.000015

0.00002

0.000025

0.00003

0.000035

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13019

Cd

0

0.002

0.004

0.006

0.008

0.01

0.012

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13019

As

Cu

0.0400.045

L)

A13019

0

0.000005

0.00001

0.000015

0.00002

0.000025

0.00003

0.000035

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13019

Cd

0

0.002

0.004

0.006

0.008

0.01

0.012

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13019

As

Cu

0.0000.0050.0100.0150.0200.0250.0300.0350.0400.045

Concen

tration (m

g/L)

A13019

Al

Fe

0

0.000005

0.00001

0.000015

0.00002

0.000025

0.00003

0.000035

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13019

Cd

0

0.002

0.004

0.006

0.008

0.01

0.012

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13019

As

Cu

0.0000.0050.0100.0150.0200.0250.0300.0350.0400.045

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13019

Al

Fe



A13019

0.010

0.015

0.020

0.025

0.030

0.035

oncentration

(mg/L)

A13019

Ni

Zn

0.000

0.005

0.010

0.015

0.020

0.025

0.030

0.035

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13019

Ni

Zn

0.000

0.005

0.010

0.015

0.020

0.025

0.030

0.035

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13019

Ni

Zn

0.008

0.010

0.012

0.014

tion

(mg/L)

A13019

0.000

0.005

0.010

0.015

0.020

0.025

0.030

0.035

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13019

Ni

Zn

0.000

0.002

0.004

0.006

0.008

0.010

0.012

0.014

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13019

Ba

Se

0.000

0.005

0.010

0.015

0.020

0.025

0.030

0.035

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13019

Ni

Zn

0.000

0.002

0.004

0.006

0.008

0.010

0.012

0.014

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13019

Ba

Se

0 10

0.12

L)

A13019

0.000

0.005

0.010

0.015

0.020

0.025

0.030

0.035

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13019

Ni

Zn

0.000

0.002

0.004

0.006

0.008

0.010

0.012

0.014

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13019

Ba

Se

0.00

0.02

0.04

0.06

0.08

0.10

0.12

Concen

tration (m

g/L)

A13019

Mn

Sr

0.000

0.005

0.010

0.015

0.020

0.025

0.030

0.035

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13019

Ni

Zn

0.000

0.002

0.004

0.006

0.008

0.010

0.012

0.014

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13019

Ba

Se

0.00

0.02

0.04

0.06

0.08

0.10

0.12

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13019

Mn

Sr


Kinetic Column DataSample ID A13035Date Cycle pH Cond. Acidity Acidity Alkalinity Sulphate Chloride Al Sb As Ba Be Cd Ca Cr Co Cu Fe

Input Output umhos/cm (pH 4.5) (pH 8.3)mgCaCO3/L mgCaCO3/L mgCaCO3/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L

LOD 0.10 2 5 5 5 1 1 0.01 0.00001 0.0001 0.00005 0.0001 0.00002 0.01 0.01 0.0001 0.01 0.01

20-Apr-09 0.1 1000 480 6.6 9300 0 <5 20 850 2800 <0.01 0.00014 0.0076 0.0285 <0.0001 0.00007 99.11 <0.01 0.0018 0.01 0.0221-Apr-09 0.2 1000 940 6.6 5500 0 <5 14 680 1600 <0.01 0.00011 0.0057 0.01503 <0.0001 0.00005 66.74 <0.01 0.0011 <0.01 <0.0122-Apr-09 0.3 1000 940 6.6 2800 0 <5 15.0 550 620 0.01 0.00008 0.0041 0.00847 <0.0001 <0.00002 43.55 <0.01 0.0006 <0.01 <0.0123-Apr-09 0.4 1000 950 6.7 650 0 <5 16.0 210 78.0 <0.01 0.00009 0.0019 0.00323 <0.0001 <0.00002 15.89 <0.01 0.0002 <0.01 <0.0124-Apr-09 0.5 1000 990 6.6 300 0 <5 14.0 98 23 <0.01 0.0001 0.0017 0.00215 <0.0001 <0.00002 8.65 <0.01 0.0001 <0.01 <0.0125-Apr-09 0.6 1000 990 6.6 200 0 <5 14.0 57 17.0 0.02 0.00011 0.0008 0.00207 <0.0001 0.00007 6.06 <0.01 0.0001 <0.01 <0.012-May-09 1 1000 590 6.10 260 0 <5 6.0 34 54 <0.01 0.00008 0.0015 0.00373 <0.0001 <0.00002 6.16 <0.01 0.0001 <0.01 <0.019-May-09 2 1000 580 6.50 250 016-May-09 3 1000 570 6.50 230 023-May-09 4 1000 590 6.60 180 0 <5 8.0 34 27.0 <0.01 0.00007 0.0027 0.00399 <0.0001 <0.00002 4.96 <0.01 <0.0001 <0.01 <0.0130-May-09 5 1000 590 6.8 170 06-Jun-09 6 1000 590 8.7 170 013-Jun-09 7 1000 580 7.3 130 0 <5 8.0 25 15 <0.01 0.00009 0.002 0.00396 <0.0001 <0.00002 3.56 <0.01 <0.0001 <0.01 <0.0120-Jun-09 8 1000 590 6.9 100 027-Jun-09 9 1000 590 6.7 88 06-Jul-09 10 1000 590 6.7 80 0 <5 <5 20 8 <0.01 0.00007 0.003 0.00313 <0.0001 <0.00002 2.33 <0.01 <0.0001 <0.01 <0.0113-Jul-09 11 1000 590 6.4 80 018-Jul-09 12 1000 590 6.4 77 025-Jul-09 13 1000 590 6.4 65 0 <5 6.0 16 5 <0.01 0.00006 0.00130 0.00256 <0.0001 <0.00002 2 <0.01 <0.0001 <0.01 <0.011-Aug-09 14 1000 590 6.6 63 08-Aug-09 15 1000 590 6.6 57 015-Aug-09 16 1000 590 6.7 56 0 <5 10.0 11 3 <0.01 0.00005 0.00110 0.00320 <0.0001 <0.00002 2 <0.01 <0.0001 <0.01 <0.01

Volume mL



LOD

20-Apr-09 0.121-Apr-09 0.222-Apr-09 0.323-Apr-09 0.424-Apr-09 0.525-Apr-09 0.62-May-09 19-May-09 216-May-09 323-May-09 430-May-09 56-Jun-09 613-Jun-09 720-Jun-09 827-Jun-09 96-Jul-09 1013-Jul-09 1118-Jul-09 1225-Jul-09 131-Aug-09 148-Aug-09 1515-Aug-09 16


Pb Mg Mn Hg Mo Ni P K Se Ag Na Sr Th Tl Sn U V Zn

mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/l mg/L mg/L mg/L mg/L mg/L0.0005 0.01 0.01 0.0001 0.00005 0.01 0.1 0.1 0.0005 0.00001 0.1 0.00002 0.000005 0.00001 0.0001 0.000005 0.01 0.01

0.0009 187.48 0.09 0.0097 0.00049 <0.01 <0.1 78.8 0.0932 0.00449 1661.2 1.84252 0.000088 0.00011 0.0008 0.000021 <0.01 0.040.0008 132.39 0.06 0.0026 0.00043 <0.01 <0.1 46.7 0.0764 0.00026 980 1.17193 0.000066 0.00005 0.0006 0.000009 <0.01 0.03

< 0.0005 96.94 0.04 0.001 0.00036 <0.01 <0.1 21.2 0.0637 0.00002 448.2 0.67778 0.00006 0.00002 0.0004 0.000006 <0.01 0.02< 0.0005 34.52 0.02 0.0007 0.00029 <0.01 <0.1 4.4 0.0246 0.00001 72.1 0.22707 < 0.000005 <0.00001 <0.0001 < 0.000005 <0.01 0.03< 0.0005 18.58 <0.01 0.0006 0.00028 <0.01 <0.1 1.8 0.0107 <0.00001 25.2 0.12293 < 0.000005 <0.00001 <0.0001 < 0.000005 <0.01 0.02< 0.0005 12.94 <0.01 <0.0001 0.0003 <0.01 <0.1 1.2 0.0063 <0.00001 15.4 0.08342 < 0.000005 <0.00001 <0.0001 0.000006 <0.01 0.02< 0.0005 11.4 <0.01 <0.0001 0.00034 <0.01 <0.1 2.2 0.0091 0.00071 26.3 0.08868 < 0.000005 <0.00001 <0.0001 < 0.000005 <0.01 0.01

< 0.0005 10.89 <0.01 <0.0001 0.00048 <0.01 <0.1 1.6 0.0213 0.00007 15.3 0.06657 < 0.000005 <0.00001 <0.0001 < 0.000005 <0.01 <0.01

< 0.0005 7.41 <0.01 0.0003 0.00052 <0.01 <0.1 1.3 0.016 0.00002 9.8 0.04718 < 0.000005 <0.00001 <0.0001 < 0.000005 <0.01 <0.01

< 0.0005 5.09 <0.01 <0.0001 0.00081 <0.01 <0.1 0.8 0.0129 0.00003 5.8 0.03218 0.00001 <0.00001 <0.0001 < 0.000005 <0.01 0.03

< 0.0005 4 <0.01 <0.0001 0 <0.01 <0.1 0.8 0.012 0.00001 4.1 0.023 < 0.000005 <0.00001 <0.0001 < 0.000005 <0.01 0.02

0.0012 4 <0.01 <0.0001 0 <0.01 <0.1 0.5 0.009 <0.00001 2.8 0.023 < 0.000005 <0.00001 <0.0001 0.00012 <0.01 0.03



A13035

200300400500600700800900

oncentration

(mg/L)

A13035

SO4

0100200300400500600700800900

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13035

SO4

0100200300400500600700800900

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13035

SO4

100

150

200

tion

(mg/L)

A13035

0100200300400500600700800900

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13035

SO4

0

50

100

150

200

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13035

Ca

Mg

0100200300400500600700800900

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13035

SO4

0

50

100

150

200

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13035

Ca

Mg

2500

3000

/L)

A13035

0100200300400500600700800900

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13035

SO4

0

50

100

150

200

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13035

Ca

Mg

0

500

1000

1500

2000

2500

3000

Concen

tration (m

g/L)

A13035

Cl

Na

0100200300400500600700800900

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13035

SO4

0

50

100

150

200

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13035

Ca

Mg

0

500

1000

1500

2000

2500

3000

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13035

Cl

Na



A13035

0.00002

0.00003

0.00004

0.00005

0.00006

0.00007

0.00008

oncentration

(mg/L)

A13035

Cd

0

0.00001

0.00002

0.00003

0.00004

0.00005

0.00006

0.00007

0.00008

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13035

Cd

0

0.00001

0.00002

0.00003

0.00004

0.00005

0.00006

0.00007

0.00008

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13035

Cd

0 006

0.008

0.01

0.012

tion

(mg/L)

A13035

0

0.00001

0.00002

0.00003

0.00004

0.00005

0.00006

0.00007

0.00008

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13035

Cd

0

0.002

0.004

0.006

0.008

0.01

0.012

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13035

As

Cu

0

0.00001

0.00002

0.00003

0.00004

0.00005

0.00006

0.00007

0.00008

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13035

Cd

0

0.002

0.004

0.006

0.008

0.01

0.012

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13035

As

Cu

0 020

0.025

/L)

A13035

0

0.00001

0.00002

0.00003

0.00004

0.00005

0.00006

0.00007

0.00008

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13035

Cd

0

0.002

0.004

0.006

0.008

0.01

0.012

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13035

As

Cu

0.000

0.005

0.010

0.015

0.020

0.025

Concen

tration (m

g/L)

A13035

Al

Fe

0

0.00001

0.00002

0.00003

0.00004

0.00005

0.00006

0.00007

0.00008

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13035

Cd

0

0.002

0.004

0.006

0.008

0.01

0.012

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13035

As

Cu

0.000

0.005

0.010

0.015

0.020

0.025

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13035

Al

Fe



A13035

0.0100.0150.0200.0250.0300.0350.0400.045

oncentration

(mg/L)

A13035

Ni

Zn

0.0000.0050.0100.0150.0200.0250.0300.0350.0400.045

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13035

Ni

Zn

0.0000.0050.0100.0150.0200.0250.0300.0350.0400.045

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13035

Ni

Zn

0.06

0.08

0.10

tion

(mg/L)

A13035

0.0000.0050.0100.0150.0200.0250.0300.0350.0400.045

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13035

Ni

Zn

0.00

0.02

0.04

0.06

0.08

0.10

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13035

Ba

Se

0.0000.0050.0100.0150.0200.0250.0300.0350.0400.045

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13035

Ni

Zn

0.00

0.02

0.04

0.06

0.08

0.10

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13035

Ba

Se

2.0

/L)

A13035

0.0000.0050.0100.0150.0200.0250.0300.0350.0400.045

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13035

Ni

Zn

0.00

0.02

0.04

0.06

0.08

0.10

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13035

Ba

Se

0.0

0.5

1.0

1.5

2.0

Concen

tration (m

g/L)

A13035

Mn

Sr

0.0000.0050.0100.0150.0200.0250.0300.0350.0400.045

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13035

Ni

Zn

0.00

0.02

0.04

0.06

0.08

0.10

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13035

Ba

Se

0.0

0.5

1.0

1.5

2.0

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13035

Mn

Sr




LOD 0.10 2 5 5 1 1 0.01 0.00001 0.0001 0.00005 0.0001 0.00002 0.01 0.01 0.0001 0.01 0.01 0.0005

20-Apr-09 0 1000 710 6.8 160 5 22 17 27 <0.01 0.0008 0.0004 0.00574 <0.0001 <0.00002 10.2 <0.01 0.0006 0.01 <0.01 < 0.000502-May-09 1 1000 720 6.4 97 <5 10 18 14 0.02 0.00669 0.0003 0.00274 <0.0001 <0.00002 6.87 <0.01 <0.0001 <0.01 <0.01 < 0.000509-May-09 2 1000 710 7.1 9816-May-09 3 1000 740 7.2 9323-May-09 4 1000 740 7 61 <5 14 8 7 0.01 0.01101 0.0006 0.00161 <0.0001 0.00003 4.78 <0.01 <0.0001 <0.01 0.02 < 0.000530-May-09 5 1000 740 7.2 4606-Jun-09 6 1000 750 7.20 3613-Jun-09 7 1000 740 7.00 36 <5 12.0 5 2.0 <0.01 0.00996 0.0012 0.00132 <0.0001 <0.00002 3.47 <0.01 <0.0001 <0.01 <0.01 0.000620-Jun-09 8 1000 740 7.40 4427-Jun-09 9 1000 740 7.00 4206-Jul-09 10 1000 740 6.9 33 <5 8.0 3 3 <0.01 0.00356 0.0008 0.00122 <0.0001 <0.00002 3.34 <0.01 <0.0001 <0.01 <0.01 < 0.000513-Jul-09 11 1000 740 6.7 2918-Jul-09 12 1000 740 6.8 3125-Jul-09 13 1000 750 6.7 31 <5 15.0 3 1 <0.01 0.0034 0.0007 0.0013 <0.0001 <0.00002 3 <0.01 <0.0001 <0.01 0.09 0.000601-Aug-09 14 1000 750 6.8 3208-Aug-09 15 1000 740 6.8 2715-Aug-09 16 1000 750 6.8 30 <5 13.0 2 1.0 0.01 0.00191 0.0006 0.00113 <0.0001 <0.00002 3.2 <0.01 <0.0001 <0.01 0.02 < 0.0005

Volume mL



LOD





4.78 <0.01 <0.0001 0.00025 <0.01 <0.1 3.5 0.0018 <0.00001 15.2 0.03986 < 0.000005 <0.00001 0.0003 0.000005 <0.01 0.012.48 <0.01 <0.0001 0.00416 <0.01 <0.1 1.7 0.0018 0.00016 7.9 0.02517 < 0.000005 <0.00001 0.0002 < 0.000005 <0.01 0.01

2.2 <0.01 <0.0001 0.00357 <0.01 <0.1 0.9 0.002 0.00002 5.1 0.01457 < 0.000005 <0.00001 <0.0001 < 0.000005 <0.01 <0.01

1.46 <0.01 0.0001 0.00276 <0.01 <0.1 0.6 0.0005 <0.00001 2.5 0.01002 < 0.000005 <0.00001 <0.0001 0.000007 <0.01 <0.01

1.56 <0.01 <0.0001 0.00245 <0.01 <0.1 0.3 < 0.0005 0.00001 1.4 0.00988 0.000009 <0.00001 <0.0001 < 0.000005 <0.01 0.03

1 <0.01 <0.0001 0.0017 <0.01 <0.1 0.4 < 0.0005 <0.00001 1 0.01 < 0.000005 <0.00001 <0.0001 0.00014 <0.01 0.05

1.54 <0.01 <0.0001 0.00164 <0.01 <0.1 0.3 < 0.0005 <0.00001 0.8 0.00845 < 0.000005 <0.00001 <0.0001 < 0.000005 <0.01 0.02



A13050

5

10

15

20

oncentration

(mg/L)

A13050

SO4

0

5

10

15

20

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13050

SO4

0

5

10

15

20

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13050

SO4

6

8

10

12

tion

(mg/L)

A13050

0

5

10

15

20

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13050

SO4

0

2

4

6

8

10

12

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13050

Ca

Mg

0

5

10

15

20

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13050

SO4

0

2

4

6

8

10

12

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13050

Ca

Mg

25

30

/L)

A13050

0

5

10

15

20

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13050

SO4

0

2

4

6

8

10

12

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13050

Ca

Mg

0

5

10

15

20

25

30

Concen

tration (m

g/L)

A13050

Cl

Na

0

5

10

15

20

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13050

SO4

0

2

4

6

8

10

12

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13050

Ca

Mg

0

5

10

15

20

25

30

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13050

Cl

Na



A13050

1.0E‐05

1.5E‐05

2.0E‐05

2.5E‐05

3.0E‐05

3.5E‐05

oncentration

(mg/L)

A13050

Cd

0.0E+00

5.0E‐06

1.0E‐05

1.5E‐05

2.0E‐05

2.5E‐05

3.0E‐05

3.5E‐05

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13050

Cd

0.0E+00

5.0E‐06

1.0E‐05

1.5E‐05

2.0E‐05

2.5E‐05

3.0E‐05

3.5E‐05

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13050

Cd

0 006

0.008

0.01

0.012

tion

(mg/L)

A13050

0.0E+00

5.0E‐06

1.0E‐05

1.5E‐05

2.0E‐05

2.5E‐05

3.0E‐05

3.5E‐05

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13050

Cd

0

0.002

0.004

0.006

0.008

0.01

0.012

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13050

As

Cu

0.0E+00

5.0E‐06

1.0E‐05

1.5E‐05

2.0E‐05

2.5E‐05

3.0E‐05

3.5E‐05

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13050

Cd

0

0.002

0.004

0.006

0.008

0.01

0.012

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13050

As

Cu

0 08

0.10

L)

A13050

0.0E+00

5.0E‐06

1.0E‐05

1.5E‐05

2.0E‐05

2.5E‐05

3.0E‐05

3.5E‐05

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13050

Cd

0

0.002

0.004

0.006

0.008

0.01

0.012

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13050

As

Cu

0.00

0.02

0.04

0.06

0.08

0.10

Concen

tration (m

g/L)

A13050

Al

Fe

0.0E+00

5.0E‐06

1.0E‐05

1.5E‐05

2.0E‐05

2.5E‐05

3.0E‐05

3.5E‐05

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13050

Cd

0

0.002

0.004

0.006

0.008

0.01

0.012

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13050

As

Cu

0.00

0.02

0.04

0.06

0.08

0.10

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13050

Al

Fe



A13050

0 01

0.02

0.03

0.04

0.05

0.06

oncentration

(mg/L)

A13050

Ni

Zn

0.00

0.01

0.02

0.03

0.04

0.05

0.06

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13050

Ni

Zn

0.00

0.01

0.02

0.03

0.04

0.05

0.06

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13050

Ni

Zn

0.004

0.005

0.006

0.007

tion

(mg/L)

A13050

0.00

0.01

0.02

0.03

0.04

0.05

0.06

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13050

Ni

Zn

0.000

0.001

0.002

0.003

0.004

0.005

0.006

0.007

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13050

Ba

Se

0.00

0.01

0.02

0.03

0.04

0.05

0.06

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13050

Ni

Zn

0.000

0.001

0.002

0.003

0.004

0.005

0.006

0.007

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13050

Ba

Se

0.0400.045

L)

A13050

0.00

0.01

0.02

0.03

0.04

0.05

0.06

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13050

Ni

Zn

0.000

0.001

0.002

0.003

0.004

0.005

0.006

0.007

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13050

Ba

Se

0.0000.0050.0100.0150.0200.0250.0300.0350.0400.045

Concen

tration (m

g/L)

A13050

Mn

Sr

0.00

0.01

0.02

0.03

0.04

0.05

0.06

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13050

Ni

Zn

0.000

0.001

0.002

0.003

0.004

0.005

0.006

0.007

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13050

Ba

Se

0.0000.0050.0100.0150.0200.0250.0300.0350.0400.045

0 2 4 6 8 10 12 14 16

Concen

tration (m

g/L)

Time (week)

A13050

Mn

Sr


Kinetic Column DataSample ID SRK1Date Cycle pH Cond. Acidity Alkalinity Sulphate Chloride Al Sb As Ba Be Cd Ca Cr Co Cu Fe Pb Mg

Input Output umhos/cm (pH 8.3)mgCaCO3/L mgCaCO3/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L

LOD 0.10 2 5 5 1 1 0.01 0.00001 0.0001 0.00005 0.0001 0.00002 0.01 0.01 0.0001 0.01 0.01 0.0005 0.0121-Dec-09 0 1000 730 7.7 250 5 67 16 38 <0.01 0.00059 0.0038 0.00208 <0.0001 0.00003 6.27 <0.01 0.0001 <0.01 <0.01 0.0137 303-Jan-10 1 1000 760 8 190 <5 50 18 21 <0.01 0.00073 0.0083 0.00068 <0.0001 <0.00002 2.14 <0.01 0.0005 <0.01 0.03 0.002 0.9209-Jan-10 2 1000 760 7.8 16016-Jan-10 3 1000 750 7.8 14023-Jan-10 4 1000 740 7.3 170 5 65 7 16 0.04 0.00132 0.0137 0.00082 <0.0001 0.00013 3.6 <0.01 0.0002 <0.01 0.05 0.0032 1.2530-Jan-10 5 1000 750 7.8 140 <5 74 4 506-Feb-10 6 1000 740 7.8 18013-Feb-10 7 1000 750 7.6 93 <5 48 3 2 0.06 0.00088 0.0182 0.00053 <0.0001 <0.00002 2.2 <0.01 0.0001 <0.01 0.3 0.0041 0.9920-Feb-10 8 1000 750 7.6 12027-Feb-10 9 1000 740 8.2 11006-Mar-10 10 1000 760 7.8 81 5 62 3 3 0.02 0.00093 0.014 0.00064 <0.0001 <0.00002 3.79 <0.01 <0.0001 <0.01 0.16 < 0.0005 1.6313-Mar-10 11 1000 740 8 13020-Mar-10 12 1000 740 7.8 12027-Mar-10 13 1000 700 7.4 130 <5 47 1 14 0.02 0.00074 0.0127 0.00071 <0.0001 0.00004 4.35 <0.01 <0.0001 <0.01 0.1 0.0009 2.0403-Apr-10 14 1000 740 7.6 10010-Apr-10 15 1000 690 8 13017-Apr-10 16 1000 750 7.9 100 6 47 < 1 6 <0.01 0.00047 0.0076 0.00059 <0.0001 0.00007 4.54 <0.01 <0.0001 <0.01 0.02 < 0.0005 2.1524-Apr-10 17 1000 780 7.70 9601-May-10 18 1000 700 7.8 9308-May-10 19 1000 760 7.80 93 <5 49 < 1 3 0.03 0.0004 0.0061 0.0006 <0.0001 0.00003 5.4 <0.01 <LOD <0.01 0.06 < 0.0005 2.615-May-10 20 1000 720 7.5 10022-May-10 21 1000 750 7.80 11029-May-10 22 1000 780 8.7 66 <5 39 < 1 < 1 <0.01 0.0003 0.0046 0.0004 <0.0001 <0.00002 6.1 <0.01 0.0 <0.01 0.02 < 0.0005 3.005-Jun-10 23 1000 770 7.90 9212-Jun-10 24 1000 770 7.9 9919-Jun-10 25 1000 710 7.90 98 6 52 < 1 2 <0.01 0.0003 0.0048 0.0007 <0.0001 <0.00002 7.5 <0.01 <0.0001 <0.01 0.02 < 0.0005 3.726-Jun-10 26 1000 690 8 1403-Jul-10 27 1000 680 8.00 140

10-Jul-10 28 1000 680 8 120 <5 67 < 1 1 0.01 0.00046 0.0224 0.00076 <0.0001 <0.00002 9.05 <0.01 <0.0001 <0.01 0.01 < 0.0005 4.0417-Jul-10 29 1000 710 7.9 12024-Jul-10 30 1000 710 7.9 12031-Jul-10 31 1000 750 7.9 110 <5 57 < 1 < 1 <0.01 0.00044 0.0376 0.00065 <0.0001 0.00002 7.67 <0.01 <0.0001 <0.01 <0.01 < 0.0005 3.467-Aug-10 32 1000 720 7.8 10014-Aug-10 33 1000 730 7.6 9321-Aug-10 34 1000 750 7.50 10028-Aug-10 35 1000 710 7.9 110 <5 57 < 1 < 1 0.02 0.00029 0.0089 0.00217 <0.0001 0.02907 9.12 <0.01 0.0006 <0.01 14.51 0.0005 4.154-Sep-10 36 1000 720 7.6 12011-Sep-10 37 1000 750 7.7 10018-Sep-10 38 1000 700 7.9 130 <5 60 < 1 3 <0.01 0.00035 0.0136 0.0007 <0.0001 0.00002 9.93 <0.01 <0.0001 <0.01 <0.01 < 0.0005 4.4725-Sep-10 39 1000 780 7.8 1002-Oct-10 40 1000 730 7.8 999-Oct-10 41 1000 740 7.8 110 <5 67 < 1 < 1 0.05 0.00036 0.0106 0.00206 <0.0001 <0.00002 10.48 <0.01 <0.0001 <0.01 0.02 0.0008 4.5916-Oct-10 42 1000 750 7.9 10023-Oct-10 43 1000 720 7.6 12030-Oct-10 44 1000 750 7.8 100 <5 56 < 1 < 1 <0.01 0.00036 0.0096 0.00111 <0.0001 <0.00002 9.46 <0.01 <0.0001 <0.01 <0.01 0.0006 4.196-Nov-10 45 1000 720 8.80 87

Note: Cadmium concentrations recorded for Week 35 are invalid due to contamination from the sample bottle lids.

Volume mL


Kinetic Column DataSample ID SRK1Date Cycle

LOD21-Dec-09 003-Jan-10 109-Jan-10 216-Jan-10 323-Jan-10 430-Jan-10 506-Feb-10 613-Feb-10 720-Feb-10 827-Feb-10 906-Mar-10 1013-Mar-10 1120-Mar-10 1227-Mar-10 1303-Apr-10 1410-Apr-10 1517-Apr-10 1624-Apr-10 1701-May-10 1808-May-10 1915-May-10 2022-May-10 2129-May-10 2205-Jun-10 2312-Jun-10 2419-Jun-10 2526-Jun-10 263-Jul-10 27

10-Jul-10 2817-Jul-10 2924-Jul-10 3031-Jul-10 317-Aug-10 3214-Aug-10 3321-Aug-10 3428-Aug-10 354-Sep-10 3611-Sep-10 3718-Sep-10 3825-Sep-10 392-Oct-10 409-Oct-10 4116-Oct-10 4223-Oct-10 4330-Oct-10 446-Nov-10 45


Mn Hg Mo Ni P K Se Ag Na Sr Th Tl Sn U V Zn

mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/l mg/L mg/L mg/L mg/L mg/L0.01 0.0001 0.00005 0.01 0.1 0.1 0.0005 0.00001 0.1 0.00002 0.000005 0.00001 0.0001 0.000005 0.01 0.01

<0.01 <0.0001 0.02706 <0.01 <0.1 7.1 0.0029 0.00002 50.4 0.01689 < 0.000005 <0.00001 <0.0001 0.00005 <0.01 0.06<0.01 0.0002 0.02667 <0.01 <0.1 5.1 0.0023 <0.00001 36.6 0.00576 < 0.000005 0.00002 <0.0001 0.00007 <0.01 0.07

<0.01 0.0001 0.02976 <0.01 <0.1 5.6 0.0018 <0.00001 40.7 0.00769 < 0.000005 <0.00001 <0.0001 0.000185 <0.01 0.07

<0.01 0.0001 0.0152 0.01 <0.1 2.9 0.0021 <0.00001 19 0.00522 < 0.000005 <0.00001 <0.0001 0.000132 <0.01 0.05

<0.01 <0.0001 0.0071 0.02 <0.1 5.8 0.0021 0.00011 21.7 0.00879 < 0.000005 0.00001 <0.0001 0.000262 <0.01 0.05

<0.01 0.0016 0.00307 <0.01 0.3 6.4 0.0011 0.00002 18.4 0.01024 < 0.000005 0.00001 <0.0001 0.000225 <0.01 0.04

<0.01 0.0002 0.00185 <0.01 <0.1 4.2 < 0.0005 <0.00001 14.4 0.01231 < 0.000005 <0.00001 <0.0001 0.000205 <0.01 0.05

<0.01 <0.0001 0.0013 <0.01 <0.1 4.8 0.0007 0.00002 12.0 0.013 < 0.000005 0.00001 <0.0001 0.00019 <0.01 0.05

<0.01 <0.0001 0.0009 <0.01 <0.1 1.8 < 0.0005 <0.00001 9.5 0.014 < 0.000005 <0.00001 <0.0001 0.00016 <0.01 0.05

<0.01 <0.0001 0.0008 <0.01 <0.1 3.8 0.0007 <0.00001 9.3 0.018 < 0.000005 0.00001 0.00010 0.00019 <0.01 0.04

<0.01 <0.0001 0.0013 <0.01 0.2 2.4 <0.00001 10.4 0.02028 < 0.000005 <0.00001 <0.0001 0.000231 <0.01 0.02

<0.01 <0.0001 0.00104 <0.01 1 1.8 <0.00001 8.6 0.01795 < 0.000005 <0.00001 <0.0001 0.000166 <0.01 <0.01

0.07 <0.0001 0.00024 <0.01 0.2 1.7 0.00005 6.9 0.01887 0.000037 <0.00001 <0.0001 0.000175 <0.01 <0.01

<0.01 <0.0001 0.00091 <0.01 0.1 4.3 0.00001 6.2 0.02099 < 0.000005 <0.00001 <0.0001 0.000169 <0.01 0.02

<0.01 <0.0001 0.00101 <0.01 <0.1 1.5 <0.00001 5.5 0.02078 < 0.000005 <0.00001 <0.0001 0.000162 <0.01 <0.01

<0.01 <0.0001 0.00086 <0.01 <0.1 1.5 <0.00001 4.6 0.01853 < 0.000005 <0.00001 <0.0001 0.000136 <0.01 <0.01



SRK 1

5

10

15

20

oncentration

(mg/L)

SRK 1

SO4

0

5

10

15

20

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 1

SO4

0

5

10

15

20

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 1

SO4

6

8

10

12

tion

(mg/L)

SRK 1

0

5

10

15

20

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 1

SO4

0

2

4

6

8

10

12

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 1

Ca

Mg

0

5

10

15

20

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 1

SO4

0

2

4

6

8

10

12

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 1

Ca

Mg

50

60

L)

SRK 1

0

5

10

15

20

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 1

SO4

0

2

4

6

8

10

12

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 1

Ca

Mg

0

10

20

30

40

50

60

Concen

tration (m

g/L)

SRK 1

Cl

Na

0

5

10

15

20

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 1

SO4

0

2

4

6

8

10

12

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 1

Ca

Mg

0

10

20

30

40

50

60

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 1

Cl

Na



SRK 1

0.0002

0.0004

0.0006

0.0008

0.001

oncentration

(mg/L)

SRK 1

Cd

0

0.0002

0.0004

0.0006

0.0008

0.001

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 1

Cd

0

0.0002

0.0004

0.0006

0.0008

0.001

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 1

Cd

0 02

0.025

0.03

0.035

0.04

tion

(mg/L)

SRK 1

0

0.0002

0.0004

0.0006

0.0008

0.001

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 1

Cd

0

0.005

0.01

0.015

0.02

0.025

0.03

0.035

0.04

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 1

As

Cu

0

0.0002

0.0004

0.0006

0.0008

0.001

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 1

Cd

0

0.005

0.01

0.015

0.02

0.025

0.03

0.035

0.04

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 1

As

Cu

14.000

16.000

L)

SRK 1

0

0.0002

0.0004

0.0006

0.0008

0.001

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 1

Cd

0

0.005

0.01

0.015

0.02

0.025

0.03

0.035

0.04

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 1

As

Cu

0.000

2.000

4.000

6.000

8.000

10.000

12.000

14.000

16.000

Concen

tration (m

g/L)

SRK 1

Al

Fe

0

0.0002

0.0004

0.0006

0.0008

0.001

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 1

Cd

0

0.005

0.01

0.015

0.02

0.025

0.03

0.035

0.04

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 1

As

Cu

0.000

2.000

4.000

6.000

8.000

10.000

12.000

14.000

16.000

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 1

Al

Fe



SRK 1

0.020

0.030

0.040

0.050

0.060

0.070

0.080

oncentration

(mg/L)

SRK 1

Ni

Zn

0.000

0.010

0.020

0.030

0.040

0.050

0.060

0.070

0.080

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 1

Ni

Zn

0.000

0.010

0.020

0.030

0.040

0.050

0.060

0.070

0.080

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 1

Ni

Zn

0.002

0.003

0.003

0.004

tion

(mg/L)

SRK 1

0.000

0.010

0.020

0.030

0.040

0.050

0.060

0.070

0.080

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 1

Ni

Zn

0.000

0.001

0.001

0.002

0.002

0.003

0.003

0.004

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 1

Ba

Se

0.000

0.010

0.020

0.030

0.040

0.050

0.060

0.070

0.080

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 1

Ni

Zn

0.000

0.001

0.001

0.002

0.002

0.003

0.003

0.004

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 1

Ba

Se

0.070

0.080

L)

SRK 1

0.000

0.010

0.020

0.030

0.040

0.050

0.060

0.070

0.080

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 1

Ni

Zn

0.000

0.001

0.001

0.002

0.002

0.003

0.003

0.004

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 1

Ba

Se

0.000

0.010

0.020

0.030

0.040

0.050

0.060

0.070

0.080

Concen

tration (m

g/L)

SRK 1

Mn

Sr

0.000

0.010

0.020

0.030

0.040

0.050

0.060

0.070

0.080

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 1

Ni

Zn

0.000

0.001

0.001

0.002

0.002

0.003

0.003

0.004

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 1

Ba

Se

0.000

0.010

0.020

0.030

0.040

0.050

0.060

0.070

0.080

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 1

Mn

Sr


Kinetic Column DataSample ID SRK5Date Cycle pH Cond. Acidity Alkalinity Sulphate Chloride Al Sb As Ba Be Cd Ca Cr Co Cu Fe Pb


LOD 0.10 2 5 5 1 1 0.01 0.00001 0.0001 0.00005 0.0001 0.00002 0.01 0.01 0.0001 0.01 0.01 0.000521-Dec-09 0 1000 680 6.8 140 6 10 22 28 <0.01 0.00007 0.0007 0.02179 <0.0001 0.00003 2.52 <0.01 0.0053 <0.01 <0.01 0.006703-Jan-10 1 1000 710 7.7 95 <5 6 17 15 <0.01 0.00003 0.0006 0.00952 <0.0001 <0.00002 2.25 <0.01 0.0025 0.01 0.02 0.001609-Jan-10 2 1000 710 6.7 6916-Jan-10 3 1000 720 6.5 5923-Jan-10 4 1000 710 6.1 47 5 6 9 8 0.02 0.00005 0.0009 0.01104 <0.0001 0.00006 1.12 <0.01 0.0008 <0.01 0.02 0.001530-Jan-10 5 1000 710 6.2 43 <5 8 9 606-Feb-10 6 1000 720 6.6 3613-Feb-10 7 1000 720 6.7 32 <5 <5 6 4 0.03 0.00004 0.0007 0.00687 <0.0001 <0.00002 0.54 <0.01 0.0005 <0.01 0.03 0.002320-Feb-10 8 1000 760 6.7 3527-Feb-10 9 1000 750 7.3 2606-Mar-10 10 1000 760 6.7 21 11 6 3 2 0.05 0.00002 0.0003 0.00535 <0.0001 <0.00002 0.34 <0.01 0.0003 <0.01 0.04 < 0.000513-Mar-10 11 1000 760 7 2520-Mar-10 12 1000 770 6.6 1727-Mar-10 13 1000 780 6.8 17 5 7 2 2 0.03 0.00002 0.0006 0.00408 <0.0001 0.00002 0.22 <0.01 0.0002 <0.01 0.03 0.00103-Apr-10 14 1000 780 6.9 4410-Apr-10 15 1000 790 6.7 1517-Apr-10 16 1000 800 7.3 18 5 7 1 3 0.03 0.00002 0.0004 0.00576 <0.0001 0.00003 0.28 <0.01 0.0002 <0.01 0.01 < 0.000524-Apr-10 17 1000 790 6.9 1501-May-10 18 1000 790 6.5 1208-May-10 19 1000 800 6 12 11 <5 < 1 1 0.02 <0.00001 0.0003 0.00326 <0.0001 <0.00002 0.17 <0.01 <0.0001 <0.01 0.02 < 0.000515-May-10 20 1000 800 6.3 1022-May-10 21 1000 810 6.5 1529-May-10 22 1000 800 6.5 12 <5 <5 < 1 1 <0.01 0.00001 0.0003 0.00499 <0.0001 <0.00002 0.25 <0.01 0.0002 <0.01 <0.01 0.001105-Jun-10 23 1000 810 6.4 1412-Jun-10 24 1000 810 3.4 18019-Jun-10 25 1000 820 6.4 13 15 9 < 1 1 0.01 <0.00001 0.0004 0.00498 <0.0001 <0.00002 0.27 <0.01 <0.0001 <0.01 0.02 < 0.000526-Jun-10 26 1000 770 6.7 1503-Jul-10 27 1000 760 4.60 3210-Jul-10 28 1000 780 6.8 17 6 10.0 < 1 1 <0.01 0.00002 0.0007 0.00503 <0.0001 <0.00002 0.25 <0.01 0.00 <0.01 0.02 < 0.000517-Jul-10 29 1000 780 6.5 924-Jul-10 30 1000 800 6.5 931-Jul-10 31 1000 790 4.4 37 17 <5 < 1 < 1 0.02 0.00006 0.0046 0.03389 <0.0001 <0.00002 0.81 <0.01 0.0015 0.02 <0.01 < 0.000507-Aug-10 32 1000 800 6.2 914-Aug-10 33 1000 790 6.1 821-Aug-10 34 1000 790 6.10 828-Aug-10 35 1000 800 5.8 11 5 <5 < 1 1 <0.01 0.00004 0.0008 0.00611 <0.0001 0.02491 0.18 <0.01 0.0002 <0.01 0.06 0.00304-Sep-10 36 1000 790 6.2 911-Sep-10 37 1000 790 6.3 918-Sep-10 38 1000 790 6.1 22 7 6.0 < 1 4 <0.01 0.00001 0.0003 0.0037 <0.0001 0.00003 0.13 <0.01 0.0001 <0.01 <0.01 < 0.000525-Sep-10 39 1000 780 6.3 902-Oct-10 40 1000 780 6.3 1009-Oct-10 41 1000 790 6.4 9 6 6.0 < 1 1 0.01 0.00002 0.0001 0.00465 <0.0001 0.00004 0.17 <0.01 0.0002 <0.01 0.01 0.001316-Oct-10 42 1000 800 6.3 923-Oct-10 43 1000 800 6.4 930-Oct-10 44 1000 790 6.3 8 6 6.0 < 1 < 1 <0.01 0.00001 0.0004 0.00568 <0.0001 <0.00002 0.14 <0.01 0.0002 <0.01 0.01 0.000506-Nov-10 45 1000 780 6.60 9


Volume mL



LOD21-Dec-09 003-Jan-10 109-Jan-10 216-Jan-10 323-Jan-10 430-Jan-10 506-Feb-10 613-Feb-10 720-Feb-10 827-Feb-10 906-Mar-10 1013-Mar-10 1120-Mar-10 1227-Mar-10 1303-Apr-10 1410-Apr-10 1517-Apr-10 1624-Apr-10 1701-May-10 1808-May-10 1915-May-10 2022-May-10 2129-May-10 2205-Jun-10 2312-Jun-10 2419-Jun-10 2526-Jun-10 2603-Jul-10 2710-Jul-10 2817-Jul-10 2924-Jul-10 3031-Jul-10 3107-Aug-10 3214-Aug-10 3321-Aug-10 3428-Aug-10 3504-Sep-10 3611-Sep-10 3718-Sep-10 3825-Sep-10 3902-Oct-10 4009-Oct-10 4116-Oct-10 4223-Oct-10 4330-Oct-10 4406-Nov-10 45



mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/l mg/L mg/L mg/L mg/L mg/L0.01 0.01 0.0001 0.00005 0.01 0.1 0.1 0.0005 0.00001 0.1 0.00002 0.000005 0.00001 0.0001 0.000005 0.01 0.013.4 0.04 0.0001 0.00015 <0.01 <0.1 3.4 < 0.0005 0.00001 21.9 0.02075 < 0.000005 0.00002 <0.0001 < 0.000005 <0.01 0.132.83 0.09 0.0002 0.00011 <0.01 <0.1 1.7 0.0007 <0.00001 10.1 0.01805 < 0.000005 0.00001 <0.0001 < 0.000005 <0.01 0.09

1.29 0.03 0.0001 0.00023 <0.01 <0.1 1.2 < 0.0005 0.00001 7 0.00721 < 0.000005 <0.00001 0.0001 < 0.000005 <0.01 0.07

0.68 0.02 <0.0001 0.00014 0.01 <0.1 0.5 < 0.0005 <0.00001 4.6 0.00428 < 0.000005 <0.00001 <0.0001 < 0.000005 <0.01 0.07

0.38 0.01 <0.0001 0.00006 0.02 <0.1 0.4 < 0.0005 0.00007 2.9 0.00242 < 0.000005 <0.00001 <0.0001 < 0.000005 <0.01 0.06

0.22 <0.01 <0.0001 < 0.00005 <0.01 <0.1 0.9 0.001 0.00002 2.1 0.00152 < 0.000005 <0.00001 <0.0001 < 0.000005 <0.01 0.04

0.27 <0.01 0.0001 0.00005 <0.01 <0.1 0.4 < 0.0005 <0.00001 2.4 0.0025 < 0.000005 <0.00001 <0.0001 < 0.000005 <0.01 0.04

0.14 <0.01 <0.0001 < 0.00005 <0.01 <0.1 0.6 < 0.0005 <0.00001 1.6 0.00113 < 0.000005 0.00001 <0.0001 < 0.000005 <0.01 0.03

0.22 <0.01 <0.0001 < 0.00005 <0.01 <0.1 0.3 < 0.0005 0.00001 1.8 0.00184 < 0.000005 <0.00001 <0.0001 < 0.000005 <0.01 0.07

0.21 <0.01 <0.0001 < 0.00005 <0.01 <0.1 0.3 0.0006 <0.00001 1.7 0.00187 < 0.000005 0.00001 0.0001 < 0.000005 <0.01 0.07

0.17 <0.01 <0.0001 0.00005 <0.01 <0.1 0.4 0 <0.00001 2.2 0.00162 < 0.000005 <0.00001 <0.0001 < 0.000005 <0.01 0.03

0.81 0.04 <0.0001 < 0.00005 <0.01 5.5 0.3 0 <0.00001 2 0.0066 < 0.000005 <0.00001 <0.0001 < 0.000005 <0.01 0.04

0.07 <0.01 <0.0001 0.00008 <0.01 <0.1 0.3 0 0.00001 1.1 0.0011 0.000014 <0.00001 0.0001 0.000007 <0.01 0.01

0.09 <0.01 <0.0001 0.00016 <0.01 <0.1 3.7 0 0.00002 1.1 0.00082 < 0.000005 <0.00001 <0.0001 < 0.000005 <0.01 0.08

0.12 <0.01 <0.0001 < 0.00005 <0.01 <0.1 0.2 0 <0.00001 1.2 0.00097 < 0.000005 <0.00001 <0.0001 < 0.000005 <0.01 0.01

0.12 <0.01 <0.0001 < 0.00005 <0.01 <0.1 0.2 0 <0.00001 1.1 0.00121 < 0.000005 <0.00001 <0.0001 < 0.000005 <0.01 0.04



SRK 5

5

10

15

20

25

oncentration

(mg/L)

SRK 5

SO4

0

5

10

15

20

25

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 5

SO4

0

5

10

15

20

25

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 5

SO4

2

2.5

3

3.5

4

tion

(mg/L)

SRK 5

0

5

10

15

20

25

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 5

SO4

0

0.5

1

1.5

2

2.5

3

3.5

4

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 5

Ca

Mg

0

5

10

15

20

25

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 5

SO4

0

0.5

1

1.5

2

2.5

3

3.5

4

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 5

Ca

Mg

25

30

L)

SRK 5

0

5

10

15

20

25

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 5

SO4

0

0.5

1

1.5

2

2.5

3

3.5

4

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 5

Ca

Mg

0

5

10

15

20

25

30

Concen

tration (m

g/L)

SRK 5

Cl

Na

0

5

10

15

20

25

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 5

SO4

0

0.5

1

1.5

2

2.5

3

3.5

4

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 5

Ca

Mg

0

5

10

15

20

25

30

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 5

Cl

Na



SRK 5

0.0001

0.0002

0.0003

0.0004

0.0005

oncentration

(mg/L)

SRK 5

Cd

0

0.0001

0.0002

0.0003

0.0004

0.0005

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 5

Cd

0

0.0001

0.0002

0.0003

0.0004

0.0005

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 5

Cd

0.015

0.02

0.025

tion

(mg/L)

SRK 5

0

0.0001

0.0002

0.0003

0.0004

0.0005

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 5

Cd

0

0.005

0.01

0.015

0.02

0.025

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 5

As

Cu

0

0.0001

0.0002

0.0003

0.0004

0.0005

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 5

Cd

0

0.005

0.01

0.015

0.02

0.025

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 5

As

Cu

0.060

0.070

L)

SRK 5

0

0.0001

0.0002

0.0003

0.0004

0.0005

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 5

Cd

0

0.005

0.01

0.015

0.02

0.025

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 5

As

Cu

0.000

0.010

0.020

0.030

0.040

0.050

0.060

0.070

Concen

tration (m

g/L)

SRK 5

Al

Fe

0

0.0001

0.0002

0.0003

0.0004

0.0005

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 5

Cd

0

0.005

0.01

0.015

0.02

0.025

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 5

As

Cu

0.000

0.010

0.020

0.030

0.040

0.050

0.060

0.070

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 5

Al

Fe



SRK 5

0.040

0.060

0.080

0.100

0.120

0.140

oncentration

(mg/L)

SRK 5

Ni

Zn

0.000

0.020

0.040

0.060

0.080

0.100

0.120

0.140

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 5

Ni

Zn

0.000

0.020

0.040

0.060

0.080

0.100

0.120

0.140

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 5

Ni

Zn

0 020

0.025

0.030

0.035

0.040

tion

(mg/L)

SRK 5

0.000

0.020

0.040

0.060

0.080

0.100

0.120

0.140

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 5

Ni

Zn

0.000

0.005

0.010

0.015

0.020

0.025

0.030

0.035

0.040

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 5

Ba

Se

0.000

0.020

0.040

0.060

0.080

0.100

0.120

0.140

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 5

Ni

Zn

0.000

0.005

0.010

0.015

0.020

0.025

0.030

0.035

0.040

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 5

Ba

Se

0 08

0.10

L)

SRK 5

0.000

0.020

0.040

0.060

0.080

0.100

0.120

0.140

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 5

Ni

Zn

0.000

0.005

0.010

0.015

0.020

0.025

0.030

0.035

0.040

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 5

Ba

Se

0.00

0.02

0.04

0.06

0.08

0.10

Concen

tration (m

g/L)

SRK 5

Mn

Sr

0.000

0.020

0.040

0.060

0.080

0.100

0.120

0.140

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 5

Ni

Zn

0.000

0.005

0.010

0.015

0.020

0.025

0.030

0.035

0.040

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 5

Ba

Se

0.00

0.02

0.04

0.06

0.08

0.10

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 5

Mn

Sr




LOD 0.10 2 5 5 1 1 0.01 0.00001 0.0001 0.00005 0.0001 0.00002 0.01 0.01 0.0001 0.01 0.01 0.0005 0.0121-Dec-09 0 1000 740 7.3 200 <5 20 16 43 0.06 0.00008 0.0031 0.00719 <0.0001 0.00004 7.07 <0.01 0.0031 0.01 <0.01 0.0048 4.9603-Jan-10 1 1000 790 7.9 76 <5 10 8 13 <0.01 0.00005 0.0014 0.00281 <0.0001 0.00002 2.58 <0.01 0.0016 <0.01 0.01 0.0012 1.509-Jan-10 2 1000 780 7.5 5716-Jan-10 3 1000 780 6.9 5023-Jan-10 4 1000 780 6.6 48 5 8 8 7 0.04 0.00008 0.0019 0.00182 <0.0001 0.00009 1.98 <0.01 0.0008 <0.01 0.02 0.0026 1.2530-Jan-10 5 1000 780 6.6 40 9 9.2 7 606-Feb-10 6 1000 790 6.7 4013-Feb-10 7 1000 780 6.7 40 <5 5 8 8 0.02 0.00009 0.0026 0.00126 <0.0001 0.00003 1.25 <0.01 0.0004 <0.01 0.03 0.0033 0.7920-Feb-10 8 1000 790 6.7 3927-Feb-10 9 1000 790 7 4106-Mar-10 10 1000 800 6.7 32 <5 7 6 3 0.02 0.00002 0.0009 0.00103 <0.0001 <0.00002 1.17 <0.01 0.0004 <0.01 0.04 < 0.0005 0.7913-Mar-10 11 1000 790 7 3620-Mar-10 12 1000 800 6.6 2627-Mar-10 13 1000 810 6.8 25 5 7 4 2 <0.01 0.00003 0.0013 0.0009 <0.0001 0.00002 0.83 <0.01 0.0004 <0.01 0.03 < 0.0005 0.5903-Apr-10 14 1000 820 6.8 2310-Apr-10 15 1000 830 7 2417-Apr-10 16 1000 830 6.4 27 7 7 2 2 0.02 0.00003 0.0006 0.00101 <0.0001 0.00004 1.01 <0.01 0.0004 <0.01 <0.01 < 0.0005 0.7624-Apr-10 17 1000 830 6.7 2201-May-10 18 1000 830 6.6 1808-May-10 19 1000 840 6.7 20 <5 8 2 1 <0.01 0.00002 0.001 0.00092 <0.0001 <0.00002 0.84 <0.01 0.0002 <0.01 <0.01 < 0.0005 0.7115-May-10 20 1000 840 6.7 1822-May-10 21 1000 840 6.9 2529-May-10 22 1000 830 6.9 20 6 9 < 1 < 1 <0.01 0.00002 0.001 0.0014 <0.0001 <0.00002 1.16 <0.01 0.0003 <0.01 <0.01 < 0.0005 1.0705-Jun-10 23 1000 840 6.9 2212-Jun-10 24 1000 840 7 2219-Jun-10 25 1000 830 6.9 19 <5 11 < 1 < 1 <0.01 0.00002 0.001 0.00139 <0.0001 <0.00002 1.04 <0.01 0.0002 <0.01 <0.01 < 0.0005 0.9326-Jun-10 26 1000 780 7 233-Jul-10 27 1000 790 6.70 2110-Jul-10 28 1000 790 6.9 21 5 10 < 1 < 1 <0.01 0.00003 0.0017 0.00135 <0.0001 <0.00002 0.94 <0.01 0.0004 <0.01 <0.01 < 0.0005 0.7817-Jul-10 29 1000 790 6.9 1724-Jul-10 30 1000 820 6.9 2031-Jul-10 31 1000 820 6.9 22 6 7 < 1 < 1 <0.01 0.00006 0.0082 0.00188 <0.0001 <0.00002 1.24 <0.01 0.0007 <0.01 0.01 < 0.0005 1.147-Aug-10 32 1000 800 6.9 1614-Aug-10 33 1000 820 6.8 1321-Aug-10 34 1000 810 6.70 1628-Aug-10 35 1000 790 6.8 16 5 7 < 1 < 1 <0.01 0.00005 0.0016 0.00257 <0.0001 0.02374 0.82 <0.01 0.0003 <0.01 0.02 < 0.0005 0.764-Sep-10 36 1000 790 6.7 1711-Sep-10 37 1000 820 6.7 1418-Sep-10 38 1000 810 6.6 13 5 7 < 1 1 <0.01 0.00003 0.0015 0.00077 <0.0001 <0.00002 0.55 <0.01 0.0002 <0.01 <0.01 < 0.0005 0.4825-Sep-10 39 1000 850 6.7 112-Oct-10 40 1000 800 6.6 129-Oct-10 41 1000 820 6.7 13 5 9 < 1 < 1 0.11 0.00009 0.0009 0.00163 <0.0001 0.00002 0.76 <0.01 0.0004 <0.01 0.02 0.0012 0.5816-Oct-10 42 1000 830 6.6 1123-Oct-10 43 1000 810 6.6 1430-Oct-10 44 1000 810 6.7 17 5 10 < 1 < 1 <0.01 0.00003 0.005 0.0011 <0.0001 <0.00002 0.83 <0.01 0.0004 <0.01 <0.01 < 0.0005 0.786-Nov-10 45 1000 810 7.00 10


Volume mL







<0.01 <0.0001 0.00019 0.01 <0.1 19.8 < 0.0005 0.00019 16.4 0.03177 < 0.000005 0.00001 <0.0001 < 0.000005 <0.01 0.05<0.01 0.0001 0.00032 <0.01 <0.1 6.3 < 0.0005 0.00001 5.7 0.01088 < 0.000005 <0.00001 <0.0001 < 0.000005 <0.01 0.03

<0.01 0.0001 0.00061 <0.01 <0.1 4.1 < 0.0005 0.00001 4.8 0.00791 < 0.000005 <0.00001 0.0002 0.000006 <0.01 0.06

<0.01 <0.0001 0.00082 0.01 <0.1 2.6 0.0014 0.00001 3.8 0.00636 < 0.000005 <0.00001 <0.0001 < 0.000005 <0.01 0.11

<0.01 <0.0001 0.00065 0.02 <0.1 1.8 < 0.0005 <0.00001 2.7 0.00494 < 0.000005 <0.00001 <0.0001 < 0.000005 <0.01 0.07

<0.01 <0.0001 0.0006 0.01 <0.1 1.4 0.001 0.00002 2.4 0.00378 < 0.000005 <0.00001 <0.0001 0.000006 <0.01 0.03

<0.01 <0.0001 0.00062 <0.01 <0.1 1.1 < 0.0005 <0.00001 2.4 0.00551 < 0.000005 <0.00001 <0.0001 < 0.000005 <0.01 0.07

<0.01 <0.0001 0.00069 <0.01 <0.1 1.1 < 0.0005 0.00001 1.7 0.00391 < 0.000005 0.00001 <0.0001 < 0.000005 <0.01 0.03

<0.01 0.0003 0.00086 <0.01 <0.1 0.8 0.0006 0.00002 1.8 0.00567 < 0.000005 0.0001 <0.0001 < 0.000005 <0.01 0.04

<0.01 <0.0001 0.00051 <0.01 <0.1 0.7 0.0009 0.00002 1.6 0.00481 < 0.000005 <0.00001 <0.0001 < 0.000005 <0.01 0.04

<0.01 <0.0001 0.00049 <0.01 <0.1 0.5 0 0.00001 1.8 0.00447 < 0.000005 <0.00001 <0.0001 < 0.000005 <0.01 0.03

<0.01 <0.0001 0.00048 <0.01 1.9 0.6 0 0.00001 1 0.00602 < 0.000005 <0.00001 <0.0001 < 0.000005 <0.01 0.02

<0.01 <0.0001 0.00038 <0.01 <0.1 0.4 0 0.00001 0.8 0.00404 < 0.000005 <0.00001 <0.0001 < 0.000005 <0.01 <0.01

<0.01 <0.0001 0.00022 <0.01 <0.1 0.8 0 0.00001 0.7 0.0026 < 0.000005 <0.00001 <0.0001 < 0.000005 <0.01 0.04

<0.01 <0.0001 0.00013 <0.01 <0.1 0.2 0 0.00002 0.6 0.00355 < 0.000005 <0.00001 <0.0001 < 0.000005 <0.01 0.02

<0.01 <0.0001 0.00025 <0.01 <0.1 0.2 0 0.00001 0.8 0.00421 < 0.000005 0.00002 0.0001 < 0.000005 <0.01 <0.01



SRK 7

468

1012141618

oncentration

(mg/L)

SRK 7

SO4

02468

1012141618

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 7

SO4

02468

1012141618

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 7

SO4

4

5

6

7

8

tion

(mg/L)

SRK 7

02468

1012141618

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 7

SO4

0

1

2

3

4

5

6

7

8

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 7

Ca

Mg

02468

1012141618

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 7

SO4

0

1

2

3

4

5

6

7

8

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 7

Ca

Mg

40

50

L)

SRK 7

02468

1012141618

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 7

SO4

0

1

2

3

4

5

6

7

8

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 7

Ca

Mg

0

10

20

30

40

50

Concen

tration (m

g/L)

SRK 7

Cl

Na

02468

1012141618

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 7

SO4

0

1

2

3

4

5

6

7

8

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 7

Ca

Mg

0

10

20

30

40

50

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 7

Cl

Na



SRK 7

0.0001

0.0002

0.0003

0.0004

0.0005

oncentration

(mg/L)

SRK 7

Cd

0

0.0001

0.0002

0.0003

0.0004

0.0005

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 7

Cd

0

0.0001

0.0002

0.0003

0.0004

0.0005

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 7

Cd

0 006

0.008

0.01

0.012

tion

(mg/L)

SRK 7

0

0.0001

0.0002

0.0003

0.0004

0.0005

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 7

Cd

0

0.002

0.004

0.006

0.008

0.01

0.012

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 7

As

Cu

0

0.0001

0.0002

0.0003

0.0004

0.0005

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 7

Cd

0

0.002

0.004

0.006

0.008

0.01

0.012

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 7

As

Cu

0 10

0.12

L)

SRK 7

0

0.0001

0.0002

0.0003

0.0004

0.0005

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 7

Cd

0

0.002

0.004

0.006

0.008

0.01

0.012

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 7

As

Cu

0.00

0.02

0.04

0.06

0.08

0.10

0.12

Concen

tration (m

g/L)

SRK 7

Al

Fe

0

0.0001

0.0002

0.0003

0.0004

0.0005

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 7

Cd

0

0.002

0.004

0.006

0.008

0.01

0.012

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 7

As

Cu

0.00

0.02

0.04

0.06

0.08

0.10

0.12

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 7

Al

Fe



SRK 7

0 02

0.04

0.06

0.08

0.10

0.12

oncentration

(mg/L)

SRK 7

Ni

Zn

0.00

0.02

0.04

0.06

0.08

0.10

0.12

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 7

Ni

Zn

0.00

0.02

0.04

0.06

0.08

0.10

0.12

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 7

Ni

Zn

0 004

0.005

0.006

0.007

0.008

tion

(mg/L)

SRK 7

0.00

0.02

0.04

0.06

0.08

0.10

0.12

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 7

Ni

Zn

0.000

0.001

0.002

0.003

0.004

0.005

0.006

0.007

0.008

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 7

Ba

Se

0.00

0.02

0.04

0.06

0.08

0.10

0.12

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 7

Ni

Zn

0.000

0.001

0.002

0.003

0.004

0.005

0.006

0.007

0.008

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 7

Ba

Se

0.030

0.035

L)

SRK 7

0.00

0.02

0.04

0.06

0.08

0.10

0.12

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 7

Ni

Zn

0.000

0.001

0.002

0.003

0.004

0.005

0.006

0.007

0.008

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 7

Ba

Se

0.000

0.005

0.010

0.015

0.020

0.025

0.030

0.035

Concen

tration (m

g/L)

SRK 7

Mn

Sr

0.00

0.02

0.04

0.06

0.08

0.10

0.12

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 7

Ni

Zn

0.000

0.001

0.002

0.003

0.004

0.005

0.006

0.007

0.008

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 7

Ba

Se

0.000

0.005

0.010

0.015

0.020

0.025

0.030

0.035

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 7

Mn

Sr




LOD 0.10 2 5 5 1 1 0.01 0.00001 0.0001 0.00005 0.0001 0.00002 0.01 0.01 0.0001 0.01 0.01 0.0005 0.0121-Dec-09 0 1000 560 7.5 150 <5 23 27 13 0.01 0.00005 0.0011 0.00171 <0.0001 0.00003 6.13 <0.01 0.0002 <0.01 <0.01 0.0023 5.5303-Jan-10 1 1000 600 7.5 150 <5 19 31 10 <0.01 0.00004 0.0011 0.00111 <0.0001 <0.00002 5.48 <0.01 0.0004 <0.01 <0.01 0.0008 4.6409-Jan-10 2 1000 600 7.6 14016-Jan-10 3 1000 650 7.4 12023-Jan-10 4 1000 600 7.3 120 <5 24 29 4 0.05 0.00006 0.0015 0.00178 <0.0001 0.00005 7.68 <0.01 0.0001 <0.01 <0.01 0.0013 5.8530-Jan-10 5 1000 600 7.5 120 <5 32 30 306-Feb-10 6 1000 600 7.5 12013-Feb-10 7 1000 600 7.5 87 5 24 19 2 0.01 0.00008 0.0016 0.00115 <0.0001 <0.00002 5.67 <0.01 <0.0001 <0.01 0.02 0.0152 4.7420-Feb-10 8 1000 650 7.4 8627-Feb-10 9 1000 640 7.6 8206-Mar-10 10 1000 660 7.5 87 <5 31 12 1 <0.01 0.00002 0.0009 0.00101 <0.0001 <0.00002 6.96 <0.01 <0.0001 <0.01 <0.01 < 0.0005 5.6213-Mar-10 11 1000 650 7.6 7320-Mar-10 12 1000 670 7.4 6727-Mar-10 13 1000 670 7.4 68 <5 26 6 < 1 <0.01 0.00002 0.0009 0.0009 <0.0001 <0.00002 4.88 <0.01 <0.0001 <0.01 <0.01 < 0.0005 4.0303-Apr-10 14 1000 680 7.3 5210-Apr-10 15 1000 700 7.6 7917-Apr-10 16 1000 710 7.7 66 <5 32 4 1 <0.01 0.00002 0.0006 0.00103 <0.0001 0.00005 5.36 <0.01 <0.0001 <0.01 <0.01 < 0.0005 4.4724-Apr-10 17 1000 710 7.6 6201-May-10 18 1000 710 7.5 5308-May-10 19 1000 710 7.5 52 <5 27 2 < 1 <0.01 <0.00001 0.0005 0.0007 <0.0001 <0.00002 4.64 <0.01 <0.0001 <0.01 <0.01 < 0.0005 4.0115-May-10 20 1000 730 7.6 5122-May-10 21 1000 720 7.5 4829-May-10 22 1000 740 7.7 51 <5 28 1 < 1 <0.01 <0.00001 0.0004 0.0007 <0.0001 <0.00002 4.62 <0.01 <0.0001 <0.01 <0.01 < 0.0005 4.0805-Jun-10 23 1000 750 7.5 4712-Jun-10 24 1000 750 7.6 5619-Jun-10 25 1000 760 7.6 52 <5 28 < 1 < 1 <0.01 0.00001 0.0005 0.00104 <0.0001 0.00003 4.66 <0.01 <0.0001 <0.01 <0.01 0.0007 4.0626-Jun-10 26 1000 640 7.5 543-Jul-10 27 1000 630 7.50 4710-Jul-10 28 1000 650 7.5 52 <5 24 < 1 < 1 <0.01 0.00002 0.0004 0.00087 <0.0001 <0.00002 3.77 <0.01 <0.0001 <0.01 <0.01 < 0.0005 3.1417-Jul-10 29 1000 650 7.6 5824-Jul-10 30 1000 1050 7.5 5431-Jul-10 31 1000 680 7.5 51 <5 25 < 1 < 1 <0.01 0.00002 0.0002 0.0009 <0.0001 <0.00002 4.04 <0.01 <0.0001 <0.01 <0.01 < 0.0005 3.217-Aug-10 32 1000 680 7.4 4314-Aug-10 33 1000 690 7.3 3921-Aug-10 34 1000 680 7.40 4828-Aug-10 35 1000 680 7.5 51 <5 25 < 1 < 1 <0.01 0.00002 0.0007 0.00362 <0.0001 0.0588 4.23 <0.01 <0.0001 <0.01 <0.01 < 0.0005 3.374-Sep-10 36 1000 680 7.4 4811-Sep-10 37 1000 680 7.5 4618-Sep-10 38 1000 680 7.5 52 <5 26 < 1 2 <0.01 0.00002 0.0004 0.00082 <0.0001 0.00031 3.87 <0.01 <0.0001 <0.01 <0.01 < 0.0005 325-Sep-10 39 1000 720 7.5 432-Oct-10 40 1000 670 7.4 429-Oct-10 41 1000 690 8.6 52 <5 27 < 1 < 1 0.05 0.00003 0.0003 0.00133 <0.0001 <0.00002 4.11 <0.01 <0.0001 <0.01 0.01 0.0005 3.1516-Oct-10 42 1000 700 7.5 4723-Oct-10 43 1000 690 7.5 4830-Oct-10 44 1000 680 7.4 44 <5 23 < 1 < 1 0.02 <0.00001 0.0004 0.0008 <0.0001 <0.00002 3.5 <0.01 <0.0001 <0.01 <0.01 < 0.0005 2.76-Nov-10 45 1000 670 8.90 41


Volume mL







<0.01 0.0001 0.00023 <0.01 <0.1 3.2 < 0.0005 0.00001 18.8 0.05257 < 0.000005 <0.00001 <0.0001 < 0.000005 <0.01 0.06<0.01 0.0002 0.00048 <0.01 0.9 2.3 < 0.0005 <0.00001 14.6 0.04705 < 0.000005 <0.00001 <0.0001 < 0.000005 <0.01 0.05

<0.01 0.0001 0.00061 <0.01 <0.1 2.8 < 0.0005 <0.00001 10.8 0.05583 0.000006 <0.00001 0.0001 0.000007 <0.01 0.06

<0.01 <0.0001 0.00067 0.01 <0.1 1.9 0.0014 0.00001 4 0.05249 0.000006 <0.00001 <0.0001 < 0.000005 <0.01 0.05

<0.01 <0.0001 0.00056 0.01 <0.1 1.6 0.0009 0.0002 2.5 0.05454 < 0.000005 <0.00001 <0.0001 0.000007 <0.01 0.05

<0.01 <0.0001 0.00044 <0.01 0.2 1.1 0.0009 <0.00001 1.5 0.03865 < 0.000005 <0.00001 <0.0001 < 0.000005 <0.01 0.03

<0.01 0.0001 0.00034 <0.01 <0.1 1 < 0.0005 <0.00001 1.6 0.05071 < 0.000005 <0.00001 <0.0001 0.000007 <0.01 0.04

<0.01 <0.0001 0.00023 <0.01 <0.1 0.8 < 0.0005 <0.00001 1.1 0.0381 < 0.000005 <0.00001 <0.0001 < 0.000005 <0.01 0.03

<0.01 0.0002 0.00019 <0.01 <0.1 0.6 < 0.0005 0.00002 1.3 0.03567 < 0.000005 0.00005 <0.0001 < 0.000005 <0.01 0.04

<0.01 <0.0001 0.00014 <0.01 <0.1 0.6 0.0008 0.00003 1.4 0.03776 < 0.000005 <0.00001 0.0001 0.000005 <0.01 0.04

<0.01 <0.0001 0.00016 <0.01 <0.1 0.5 0 0.00008 1.6 0.02903 < 0.000005 <0.00001 <0.0001 < 0.000005 <0.01 0.02

<0.01 <0.0001 0.00013 <0.01 <0.1 0.4 0 <0.00001 0.7 0.03097 < 0.000005 <0.00001 <0.0001 < 0.000005 <0.01 <0.01

<0.01 <0.0001 0.00012 <0.01 <0.1 0.4 0 0.00001 0.6 0.03159 < 0.000005 <0.00001 <0.0001 < 0.000005 <0.01 <0.01

<0.01 <0.0001 0.00012 <0.01 <0.1 1.7 0 0.00002 0.7 0.02963 < 0.000005 <0.00001 <0.0001 < 0.000005 <0.01 0.02

<0.01 <0.0001 0.0001 <0.01 <0.1 0.4 0 <0.00001 0.6 0.03116 < 0.000005 <0.00001 <0.0001 < 0.000005 <0.01 <0.01

<0.01 <0.0001 0.00009 <0.01 <0.1 0.3 0 <0.00001 0.5 0.02615 < 0.000005 <0.00001 <0.0001 0.000017 <0.01 0.02



SRK 10

10

15

20

25

30

35

oncentration

(mg/L)

SRK 10

SO4

0

5

10

15

20

25

30

35

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 10

SO4

0

5

10

15

20

25

30

35

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 10

SO4

56789

tion

(mg/L)

SRK 10

0

5

10

15

20

25

30

35

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 10

SO4

0123456789

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 10

Ca

Mg

0

5

10

15

20

25

30

35

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 10

SO4

0123456789

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 10

Ca

Mg

20

/L)

SRK 10

0

5

10

15

20

25

30

35

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 10

SO4

0123456789

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 10

Ca

Mg

0

5

10

15

20

Concen

tration (m

g/L)

SRK 10

Cl

Na

0

5

10

15

20

25

30

35

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 10

SO4

0123456789

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 10

Ca

Mg

0

5

10

15

20

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 10

Cl

Na



SRK 10

0.02

0.03

0.04

0.05

0.06

0.07

oncentration

(mg/L)

SRK 10

Cd

0

0.01

0.02

0.03

0.04

0.05

0.06

0.07

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 10

Cd

0

0.01

0.02

0.03

0.04

0.05

0.06

0.07

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 10

Cd

0 006

0.008

0.01

0.012

tion

(mg/L)

SRK 10

0

0.01

0.02

0.03

0.04

0.05

0.06

0.07

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 10

Cd

0

0.002

0.004

0.006

0.008

0.01

0.012

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 10

As

Cu

0

0.01

0.02

0.03

0.04

0.05

0.06

0.07

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 10

Cd

0

0.002

0.004

0.006

0.008

0.01

0.012

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 10

As

Cu

0 05

0.06

L)

SRK 10

0

0.01

0.02

0.03

0.04

0.05

0.06

0.07

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 10

Cd

0

0.002

0.004

0.006

0.008

0.01

0.012

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 10

As

Cu

0.00

0.01

0.02

0.03

0.04

0.05

0.06

Concen

tration (m

g/L)

SRK 10

Al

Fe

0

0.01

0.02

0.03

0.04

0.05

0.06

0.07

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 10

Cd

0

0.002

0.004

0.006

0.008

0.01

0.012

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 10

As

Cu

0.00

0.01

0.02

0.03

0.04

0.05

0.06

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 10

Al

Fe



SRK 10

0.02

0.03

0.04

0.05

0.06

0.07

oncentration

(mg/L)

SRK 10

Ni

Zn

0.00

0.01

0.02

0.03

0.04

0.05

0.06

0.07

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 10

Ni

Zn

0.00

0.01

0.02

0.03

0.04

0.05

0.06

0.07

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 10

Ni

Zn

0 0020

0.0025

0.0030

0.0035

0.0040

tion

(mg/L)

SRK 10

0.00

0.01

0.02

0.03

0.04

0.05

0.06

0.07

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 10

Ni

Zn

0.0000

0.0005

0.0010

0.0015

0.0020

0.0025

0.0030

0.0035

0.0040

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 10

Ba

Se

0.00

0.01

0.02

0.03

0.04

0.05

0.06

0.07

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 10

Ni

Zn

0.0000

0.0005

0.0010

0.0015

0.0020

0.0025

0.0030

0.0035

0.0040

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 10

Ba

Se

0 05

0.06

/L)

SRK 10

0.00

0.01

0.02

0.03

0.04

0.05

0.06

0.07

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 10

Ni

Zn

0.0000

0.0005

0.0010

0.0015

0.0020

0.0025

0.0030

0.0035

0.0040

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 10

Ba

Se

0.00

0.01

0.02

0.03

0.04

0.05

0.06

Concen

tration (m

g/L)

SRK 10

Mn

Sr

0.00

0.01

0.02

0.03

0.04

0.05

0.06

0.07

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 10

Ni

Zn

0.0000

0.0005

0.0010

0.0015

0.0020

0.0025

0.0030

0.0035

0.0040

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 10

Ba

Se

0.00

0.01

0.02

0.03

0.04

0.05

0.06

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 10

Mn

Sr




LOD 0.10 2 5 5 1 1 0.01 0.00001 0.0001 0.00005 0.0001 0.00002 0.01 0.01 0.0001 0.01 0.01 0.0005 0.0121-Dec-09 0 1000 240 4.1 83 15 <5 10 9 0.04 0.00002 0.0031 0.00615 <0.0001 0.00006 2.04 <0.01 0.0012 0.06 0.01 0.0304 0.5903-Jan-10 1 1000 380 4.1 170 12 <5 18 25 0.31 0.00003 0.0015 0.01439 0.0002 0.00006 2.44 <0.01 0.0052 0.06 0.02 0.0106 2.0809-Jan-10 2 1000 370 4.1 21016-Jan-10 3 1000 350 4 21023-Jan-10 4 1000 380 4 200 16 <5 38 22 0.95 0.00004 0.0023 0.03556 0.0005 0.00018 4.44 <0.01 0.0118 0.1 0.03 0.0061 4.5130-Jan-10 5 1000 390 4 200 23 <5 41 2206-Feb-10 6 1000 390 4 18013-Feb-10 7 1000 410 4 160 22 <5 34 12 0.7 0.00003 0.0014 0.03239 0.0003 0.00008 3.05 <0.01 0.0094 0.07 0.03 0.0441 3.5920-Feb-10 8 1000 520 4 15027-Feb-10 9 1000 510 4.1 12006-Mar-10 10 1000 520 4 120 20 <5 29 3 0.55 <0.00001 0.0005 0.03001 0.0003 0.00006 2.5 <0.01 0.0074 0.06 0.02 0.0048 2.813-Mar-10 11 1000 510 3.9 9820-Mar-10 12 1000 580 4 8527-Mar-10 13 1000 580 4 99 20 <5 21 < 1 0.36 <0.00001 0.0006 0.02777 0.0003 0.00006 1.54 <0.01 0.005 0.04 <0.01 0.0026 1.7403-Apr-10 14 1000 610 4.2 6910-Apr-10 15 1000 660 4.1 7817-Apr-10 16 1000 680 4.1 63 10 <5 17 1 0.57 <0.00001 0.0005 0.02631 0.0002 0.00019 1.15 0.01 0.0037 0.04 0.04 0.0021 1.2324-Apr-10 17 1000 640 4.2 5801-May-10 18 1000 690 4.2 5408-May-10 19 1000 670 4.1 55 31 <5 14 1 0.27 <0.00001 0.001 0.02523 0.0002 0.00004 0.92 <0.01 0.0027 0.04 <0.01 0.0006 0.8715-May-10 20 1000 700 4.1 6522-May-10 21 1000 690 4.1 5329-May-10 22 1000 780 4.1 47 17 <5 12 < 1 0.22 <0.00001 0.0005 0.02235 0.0002 0.00003 0.74 <0.01 0.0021 0.03 <0.01 < 0.0005 0.6905-Jun-10 23 1000 730 4.1 4612-Jun-10 24 1000 730 4.2 4019-Jun-10 25 1000 680 4.1 43 17 <5 10 < 1 0.17 <0.00001 0.0003 0.0203 0.0001 <0.00002 0.49 <0.01 0.0013 0.02 <0.01 < 0.0005 0.4126-Jun-10 26 1000 440 4.3 503-Jul-10 27 1000 470 4.30 4810-Jul-10 28 1000 480 4.2 51 10 <5 10 < 1 0.19 <0.00001 <0.0001 0.02582 0.0001 <0.00002 0.42 <0.01 0.001 0.020 <0.01 < 0.0005 0.3517-Jul-10 29 1000 510 4.3 4824-Jul-10 30 1000 220 4.4 4631-Jul-10 31 1000 580 4.3 46 10 <5 9 < 1 0.17 <0.00001 0.0002 0.02773 <0.0001 0.00002 0.41 <0.01 0.0012 0.02 <0.01 < 0.0005 0.317-Aug-10 32 1000 580 4.4 4114-Aug-10 33 1000 630 4.4 4021-Aug-10 34 1000 620 4.30 4228-Aug-10 35 1000 550 4.3 41 14 <5 8 < 1 0.19 0.00001 0.0001 0.03436 <0.0001 0.04183 0.44 <0.01 0.0011 0.02 0.01 < 0.0005 0.314-Sep-10 36 1000 610 4.3 4311-Sep-10 37 1000 590 4.3 4118-Sep-10 38 1000 550 4.3 44 14 <5 8 1 0.17 <0.00001 0.0002 0.03091 <0.0001 0.00006 0.43 <0.01 0.001 0.01 <0.01 < 0.0005 0.2925-Sep-10 39 1000 550 4.3 422-Oct-10 40 1000 560 4.3 439-Oct-10 41 1000 620 4.3 40 10 <5 7 < 1 0.17 0.00014 0.0003 0.02944 <0.0001 0.00003 0.51 <0.01 0.0012 0.01 0.02 0.0012 0.2416-Oct-10 42 1000 640 4.3 4123-Oct-10 43 1000 600 4.3 4230-Oct-10 44 1000 640 4.3 40 10 <5 7 < 1 0.15 <0.00001 <0.0001 0.03133 <0.0001 0.00004 0.43 <0.01 0.001 0.01 <0.01 0.0015 0.256-Nov-10 45 1000 580 4.30 40


Volume mL






mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/l mg/L mg/L mg/L mg/L mg/L0.01 0.0001 0.00005 0.01 0.1 0.1 0.0005 0.00001 0.1 0.00002 0.000005 0.00001 0.0001 0.000005 0.01 0.010.03 <0.0001 < 0.000005 <0.01 <0.1 1.4 < 0.0005 0.00002 4.7 0.00729 < 0.000005 0.00002 <0.0001 0.000048 <0.01 0.20.1 0.0002 < 0.000005 0.03 0.1 3 < 0.0005 0.00001 14.7 0.03025 < 0.000005 0.00002 <0.0001 0.00016 <0.01 0.47

0.24 0.0001 < 0.000005 0.04 <0.1 5.1 < 0.0005 0.00001 16.6 0.04842 0.000008 0.00004 0.0002 0.000295 <0.01 0.91

0.2 <0.0001 0.00009 0.04 <0.1 3.9 < 0.0005 0.00001 10 0.04183 < 0.000005 0.00004 <0.0001 0.000203 <0.01 0.68

0.15 <0.0001 < 0.000005 0.03 <0.1 3.3 0.0005 <0.00001 3.1 0.02942 < 0.000005 0.00003 <0.0001 0.000147 <0.01 0.55

0.09 <0.0001 0.00005 0.03 <0.1 1.9 0.0008 <0.00001 1.3 0.01946 < 0.000005 0.00001 <0.0001 0.000102 <0.01 0.35

0.07 <0.0001 < 0.000005 0.02 <0.1 1.3 < 0.0005 <0.00001 1.5 0.01681 < 0.000005 0.00001 <0.0001 0.000082 <0.01 0.26

0.04 <0.0001 < 0.000005 <0.01 <0.1 1.2 < 0.0005 <0.00001 1.5 0.01111 < 0.000005 0.00002 <0.0001 0.000061 <0.01 0.21

0.03 <0.0001 < 0.000005 <0.01 <0.1 0.7 0.0009 0.00001 1.6 0.00875 < 0.000005 0.00004 <0.0001 0.00005 <0.01 0.19

0.02 <0.0001 < 0.000005 <0.01 <0.1 0.5 < 0.0005 0.00001 1.3 0.0057 < 0.000005 0.00001 <0.0001 0.000049 <0.01 0.13

0.02 <0.0001 < 0.000005 <0.01 <0.1 0.5 0 <0.00001 1.9 0.00516 < 0.000005 <0.00001 <0.0001 0.000047 <0.01 0.09

0.02 <0.0001 < 0.000005 <0.01 <0.1 0.5 0 <0.00001 1.2 0.00495 < 0.000005 <0.00001 <0.0001 0.000049 <0.01 0.08

0.02 <0.0001 < 0.000005 <0.01 <0.1 0.5 0 <0.00001 0.5 0.00502 < 0.000005 <0.00001 <0.0001 0.000043 <0.01 0.08

0.01 <0.0001 < 0.000005 <0.01 <0.1 0.6 0 <0.00001 0.8 0.00476 < 0.000005 <0.00001 <0.0001 0.000042 <0.01 0.1

0.01 <0.0001 < 0.000005 <0.01 <0.1 0.4 0 0.00002 0.8 0.00488 0.000005 <0.00001 <0.0001 0.000041 <0.01 0.06

0.01 <0.0001 < 0.000005 <0.01 <0.1 0.4 0 0.00001 0.7 0.00477 < 0.000005 <0.00001 <0.0001 0.000038 <0.01 0.07



SRK 15

1015202530354045

oncentration

(mg/L)

SRK 15

SO4

05

1015202530354045

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 15

SO4

05

1015202530354045

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 15

SO4

3

4

5

tion

(mg/L)

SRK 15

05

1015202530354045

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 15

SO4

0

1

2

3

4

5

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 15

Ca

Mg

05

1015202530354045

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 15

SO4

0

1

2

3

4

5

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 15

Ca

Mg

25

30

/L)

SRK 15

05

1015202530354045

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 15

SO4

0

1

2

3

4

5

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 15

Ca

Mg

0

5

10

15

20

25

30

Concen

tration (m

g/L)

SRK 15

Cl

Na

05

1015202530354045

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 15

SO4

0

1

2

3

4

5

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 15

Ca

Mg

0

5

10

15

20

25

30

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 15

Cl

Na



SRK 15

0.0002

0.0004

0.0006

0.0008

0.001

oncentration

(mg/L)

SRK 15

Cd

0

0.0002

0.0004

0.0006

0.0008

0.001

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 15

Cd

0

0.0002

0.0004

0.0006

0.0008

0.001

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 15

Cd

0 06

0.08

0.1

0.12

tion

(mg/L)

SRK 15

0

0.0002

0.0004

0.0006

0.0008

0.001

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 15

Cd

0

0.02

0.04

0.06

0.08

0.1

0.12

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 15

As

Cu

0

0.0002

0.0004

0.0006

0.0008

0.001

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 15

Cd

0

0.02

0.04

0.06

0.08

0.1

0.12

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 15

As

Cu

0 8

1.0

L)

SRK 15

0

0.0002

0.0004

0.0006

0.0008

0.001

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 15

Cd

0

0.02

0.04

0.06

0.08

0.1

0.12

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 15

As

Cu

0.0

0.2

0.4

0.6

0.8

1.0

Concen

tration (m

g/L)

SRK 15

Al

Fe

0

0.0002

0.0004

0.0006

0.0008

0.001

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 15

Cd

0

0.02

0.04

0.06

0.08

0.1

0.12

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 15

As

Cu

0.0

0.2

0.4

0.6

0.8

1.0

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 15

Al

Fe



SRK 15

0.2

0.4

0.6

0.8

1.0

oncentration

(mg/L)

SRK 15

Ni

Zn

0.0

0.2

0.4

0.6

0.8

1.0

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 15

Ni

Zn

0.0

0.2

0.4

0.6

0.8

1.0

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 15

Ni

Zn

0 020

0.025

0.030

0.035

0.040

tion

(mg/L)

SRK 15

0.0

0.2

0.4

0.6

0.8

1.0

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 15

Ni

Zn

0.000

0.005

0.010

0.015

0.020

0.025

0.030

0.035

0.040

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 15

Ba

Se

0.0

0.2

0.4

0.6

0.8

1.0

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 15

Ni

Zn

0.000

0.005

0.010

0.015

0.020

0.025

0.030

0.035

0.040

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 15

Ba

Se

0 25

0.30

L)

SRK 15

0.0

0.2

0.4

0.6

0.8

1.0

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 15

Ni

Zn

0.000

0.005

0.010

0.015

0.020

0.025

0.030

0.035

0.040

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 15

Ba

Se

0.00

0.05

0.10

0.15

0.20

0.25

0.30

Concen

tration (m

g/L)

SRK 15

Mn

Sr

0.0

0.2

0.4

0.6

0.8

1.0

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 15

Ni

Zn

0.000

0.005

0.010

0.015

0.020

0.025

0.030

0.035

0.040

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 15

Ba

Se

0.00

0.05

0.10

0.15

0.20

0.25

0.30

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 15

Mn

Sr




LOD 0.10 2 5 5 1 1 0.01 0.00001 0.0001 0.00005 0.0001 0.00002 0.01 0.01 0.0001 0.01 0.01 0.0005 0.0121-Dec-09 0 1000 760 7.3 1700 <5 59 780 180 <0.01 0.00061 0.0075 0.00311 <0.0001 <0.00002 29.61 <0.01 0.0012 0.02 0.01 0.0022 187.2903-Jan-10 1 1000 310 7.2 350 <5 49 100 16 <0.01 0.00038 0.0007 0.0007 <0.0001 0.00002 5.29 <0.01 0.0004 0.01 <0.01 0.0008 39.1209-Jan-10 2 500 320 7.3 25016-Jan-10 3 500 320 7.6 25023-Jan-10 4 500 320 7.8 230 13 66 58 4 0.04 0.00034 0.001 0.0003 <0.0001 0.00003 3.41 <0.01 0.0002 <0.01 <0.01 < 0.0005 35.5830-Jan-10 5 500 310 7.8 210 <5 67 48 406-Feb-10 6 500 310 7.9 21013-Feb-10 7 500 310 7.8 190 <5 61 46 5 0.02 0.00023 0.0009 0.0004 <0.0001 0.00003 2.04 <0.01 <0.0001 <0.01 <0.01 0.0026 25.6720-Feb-10 8 500 290 7.7 20027-Feb-10 9 500 310 4.1 12006-Mar-10 10 500 310 8.1 240 <5 100 29 2 <0.01 0.00019 0.0006 0.00041 <0.0001 <0.00002 2.89 <0.01 0.0003 <0.01 <0.01 < 0.0005 34.1813-Mar-10 11 500 310 7.9 23020-Mar-10 12 500 320 7.8 17027-Mar-10 13 500 330 7.7 120 <5 72 23 2 <0.01 0.00036 0.0006 0.00052 <0.0001 0.00016 2.06 <0.01 0.0001 <0.01 <0.01 < 0.0005 23.4803-Apr-10 14 500 330 7.8 15010-Apr-10 15 500 330 8.1 22017-Apr-10 16 500 330 7.9 200 6 93 16 3 0.08 0.0002 <0.0001 0.00044 <0.0001 0.00004 2.56 <0.01 <0.0001 <0.01 0.01 < 0.0005 26.8724-Apr-10 17 500 320 8.1 21001-May-10 18 500 340 8.1 15008-May-10 19 500 320 8.3 190 <5 94 15 1 <0.01 0.0001 0.0004 0.00029 <0.0001 <0.00002 3 <0.01 <0.0001 <0.01 <0.01 < 0.0005 27.4815-May-10 20 500 330 8.3 21022-May-10 21 500 320 8.3 20029-May-10 22 500 360 8.2 160 <5 82 10 < 1 0.02 0.00014 0.0003 0.00046 <0.0001 0.00011 2.75 <0.01 0.0015 <0.01 <0.01 < 0.0005 21.2805-Jun-10 23 500 350 8.1 13012-Jun-10 24 500 350 8.2 18019-Jun-10 25 500 330 8.2 160 <5 85 11 1 <0.01 0.00036 0.0004 0.00027 <0.0001 0.00002 3.41 <0.01 0.0004 <0.01 <0.01 < 0.0005 21.9226-Jun-10 26 500 280 8 2103-Jul-10 27 500 310 7.90 17010-Jul-10 28 500 320 8.1 180 <5 78 16 1 <0.01 0.00018 0.0002 0.00063 <0.0001 <0.00002 2.86 <0.01 0.00 <0.01 <0.01 < 0.0005 19.6217-Jul-10 29 500 320 8 17024-Jul-10 30 500 300 8.1 19031-Jul-10 31 500 330 8.1 170 <5 46 15 < 1 <0.01 0.00013 <0.0001 0.00049 <0.0001 <0.00002 2.95 <0.01 0.0006 <0.01 <0.01 < 0.0005 19.077-Aug-10 32 500 320 7.9 15014-Aug-10 33 500 330 7.9 15021-Aug-10 34 500 330 7.90 16028-Aug-10 35 500 290 8.3 240 <5 110 16 1 <0.01 0.00011 0.0003 0.00535 <0.0001 0.08 3.93 <0.01 0.0002 <0.01 0.03 0.0007 27.124-Sep-10 36 500 330 7.9 16011-Sep-10 37 500 320 7.9 17018-Sep-10 38 500 280 8.2 230 <5 100 17 1 <0.01 0.00009 0.0001 0.00055 <0.0001 0.00007 3.62 <0.01 <0.0001 <0.01 <0.01 < 0.0005 25.7325-Sep-10 39 500 310 8.1 1902-Oct-10 40 500 320 8.1 1709-Oct-10 41 500 320 8.1 190 <5 80 16 1 0.04 0.00054 0.0001 0.00137 <0.0001 0.00003 2.99 <0.01 0.0001 <0.01 0.03 0.0018 19.5916-Oct-10 42 500 330 8 17023-Oct-10 43 500 330 8.1 18030-Oct-10 44 500 330 8.1 170 <5 72 15 1 <0.01 0.00015 0.0004 0.00066 <0.0001 0.00004 2.64 <0.01 0.0001 <0.01 <0.01 0.0009 17.996-Nov-10 45 500 320 7.90 180


Volume mL






mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/l mg/L mg/L mg/L mg/L mg/L0.01 0.0001 0.00005 0.01 0.1 0.1 0.0005 0.00001 0.1 0.00002 0.000005 0.00001 0.0001 0.000005 0.01 0.010.71 0.0002 0.00442 <0.01 <0.1 19.4 0.0176 0.00003 134.5 0.03413 0.000006 0.00003 0.0003 0.000105 <0.01 0.070.04 0.0002 0.01195 <0.01 <0.1 2.2 0.0022 0.00003 7.1 0.00395 < 0.000005 <0.00001 0.0002 0.000057 <0.01 0.19

0.01 <0.0001 0.03292 <0.01 <0.1 0.6 0.0009 0.00002 1.3 0.00154 0.000008 <0.00001 0.0001 0.000049 <0.01 0.14

<0.01 0.0003 0.04397 0.01 <0.1 0.5 0.0025 0.00002 0.8 0.00111 < 0.000005 <0.00001 <0.0001 0.000041 <0.01 0.11

0.01 0.0001 0.0278 0.02 <0.1 0.7 0.0014 0.00002 1.2 0.00124 < 0.000005 <0.00001 0.0003 0.000044 <0.01 0.06

<0.01 <0.0001 0.0131 <0.01 <0.1 0.4 0.001 0.00001 1.3 0.00083 < 0.000005 <0.00001 <0.0001 0.000035 <0.01 0.05

0.02 0.0001 0.00587 <0.01 <0.1 0.6 < 0.0005 <0.00001 1.9 0.00101 < 0.000005 <0.00001 <0.0001 0.000034 <0.01 0.06

0.01 <0.0001 0.00285 <0.01 <0.1 0.6 0.0009 0.00003 1.5 0.00088 < 0.000005 <0.00001 <0.0001 0.000016 <0.01 0.03

0.02 <0.0001 0.00137 <0.01 <0.1 0.2 0.0006 <0.00001 1.5 0.00084 < 0.000005 0.00003 <0.0001 0.000048 <0.01 0.03

0.02 <0.0001 0.00092 <0.01 <0.1 0.7 0.0007 0.00001 1.7 0.00135 0.000011 0.00002 0.0001 0.000024 <0.01 0.04

0.01 <0.0001 0.00093 <0.01 <0.1 0.3 0 <0.00001 1.5 0.00093 < 0.000005 <0.00001 <0.0001 0.000014 <0.01 0.03

<0.01 <0.0001 0.00082 <0.01 <0.1 0.2 0 0.00002 0.5 0.00094 < 0.000005 <0.00001 <0.0001 0.000013 <0.01 0.01

0.02 <0.0001 0.00058 <0.01 <0.1 0.1 0 <0.00001 0.6 0.00131 < 0.000005 <0.00001 0.0001 0.000012 <0.01 <0.01

0.01 <0.0001 0.00058 <0.01 <0.1 0.4 0 <0.00001 0.8 0.00098 < 0.000005 <0.00001 <0.0001 0.000007 <0.01 0.07

<0.01 <0.0001 0.00073 <0.01 <0.1 0.4 0 <0.00001 0.9 0.00121 0.000007 <0.00001 0.0001 0.000011 <0.01 0.02

0.01 <0.0001 0.00062 <0.01 <0.1 0.3 0 0.00001 0.5 0.00079 < 0.000005 <0.00001 0.0001 0.000008 <0.01 0.04



SRK 24

200300400500600700800900

oncentration

(mg/L)

SRK 24

SO4

0100200300400500600700800900

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 24

SO4

0100200300400500600700800900

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 24

SO4

100

150

200

tion

(mg/L)

SRK 24

0100200300400500600700800900

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 24

SO4

0

50

100

150

200

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 24

Ca

Mg

0100200300400500600700800900

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 24

SO4

0

50

100

150

200

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 24

Ca

Mg

200

L)

SRK 24

0100200300400500600700800900

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 24

SO4

0

50

100

150

200

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 24

Ca

Mg

0

50

100

150

200

Concen

tration (m

g/L)

SRK 24

Cl

Na

0100200300400500600700800900

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 24

SO4

0

50

100

150

200

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 24

Ca

Mg

0

50

100

150

200

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 24

Cl

Na



SRK 24

0.0001

0.0002

0.0003

0.0004

0.0005

oncentration

(mg/L)

SRK 24

Cd

0

0.0001

0.0002

0.0003

0.0004

0.0005

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 24

Cd

0

0.0001

0.0002

0.0003

0.0004

0.0005

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 24

Cd

0.015

0.02

0.025

tion

(mg/L)

SRK 24

0

0.0001

0.0002

0.0003

0.0004

0.0005

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 24

Cd

0

0.005

0.01

0.015

0.02

0.025

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 24

As

Cu

0

0.0001

0.0002

0.0003

0.0004

0.0005

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 24

Cd

0

0.005

0.01

0.015

0.02

0.025

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 24

As

Cu

0 8

1.0

L)

SRK 24

0

0.0001

0.0002

0.0003

0.0004

0.0005

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 24

Cd

0

0.005

0.01

0.015

0.02

0.025

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 24

As

Cu

0.0

0.2

0.4

0.6

0.8

1.0

Concen

tration (m

g/L)

SRK 24

Al

Fe

0

0.0001

0.0002

0.0003

0.0004

0.0005

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 24

Cd

0

0.005

0.01

0.015

0.02

0.025

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 24

As

Cu

0.0

0.2

0.4

0.6

0.8

1.0

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 24

Al

Fe



SRK 24

0.05

0.10

0.15

0.20

oncentration

(mg/L)

SRK 24

Ni

Zn

0.00

0.05

0.10

0.15

0.20

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 24

Ni

Zn

0.00

0.05

0.10

0.15

0.20

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 24

Ni

Zn

0 010

0.015

0.020

tion

(mg/L)

SRK 24

0.00

0.05

0.10

0.15

0.20

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 24

Ni

Zn

0.000

0.005

0.010

0.015

0.020

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 24

Ba

Se

0.00

0.05

0.10

0.15

0.20

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 24

Ni

Zn

0.000

0.005

0.010

0.015

0.020

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 24

Ba

Se

0.7

0.8

L)

SRK 24

0.00

0.05

0.10

0.15

0.20

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 24

Ni

Zn

0.000

0.005

0.010

0.015

0.020

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 24

Ba

Se

0.0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

Concen

tration (m

g/L)

SRK 24

Mn

Sr

0.00

0.05

0.10

0.15

0.20

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 24

Ni

Zn

0.000

0.005

0.010

0.015

0.020

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 24

Ba

Se

0.0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 24

Mn

Sr




LOD 0.10 2 5 5 1 1 0.01 0.00001 0.0001 0.00005 0.0001 0.00002 0.01 0.01 0.0001 0.01 0.01 0.0005 0.0121-Dec-09 0 5000 4490 2.8 1600 750 <5 710 9 31.58 0.00132 0.0208 0.00684 <0.0001 0.00444 12.85 0.3 0.1736 2.28 273.35 0.0667 4.8603-Jan-10 1 1000 800 3 980 320 <5 340 2 8.47 0.0005 0.0054 0.00082 0.0005 0.00556 1.82 0.12 0.1138 0.89 128.77 0.0155 2.409-Jan-10 2 1000 800 3 120016-Jan-10 3 1000 810 2.9 140023-Jan-10 4 1000 820 2.9 1600 690 <5 660 1 19.12 0.00029 0.0098 0.00138 0.0003 0.00588 2.12 0.17 0.1275 0.73 270.69 0.0215 5.430-Jan-10 5 1000 810 2.9 1600 830 <5 790 206-Feb-10 6 1000 810 2.8 190013-Feb-10 7 1000 830 2.8 1600 780 <5 790 1 15.98 0.00076 0.0167 0.00104 0.0003 0.00301 1.32 0.15 0.1035 0.37 324.68 0.0604 3.3820-Feb-10 8 1000 830 2.8 150027-Feb-10 9 1000 830 7.6 21006-Mar-10 10 1000 840 2.8 1600 760 <5 680 < 1 13.1 0.00084 0.0233 0.00088 0.0002 0.002 1.18 0.09 0.077 0.29 268.02 0.0165 2.613-Mar-10 11 1000 830 2.7 140020-Mar-10 12 1000 850 2.7 150027-Mar-10 13 1000 850 3 1300 660 <5 530 1 8.96 0.00114 0.0246 0.00086 0.0001 0.00131 0.72 0.06 0.0574 0.17 231.11 0.0171 2.0603-Apr-10 14 1000 850 3 130010-Apr-10 15 1000 860 2.8 140017-Apr-10 16 1000 860 3 1300 570 <5 490 1 7.8 0.00158 0.0227 0.00103 0.0002 0.00104 1 0.04 0.0484 0.16 209.7 0.0146 1.724-Apr-10 17 1000 850 2.8 1200

01-May-10 18 1000 850 2.8 120008-May-10 19 1000 860 2.8 1200 520 <5 470 < 1 7.31 0.00186 0.0348 0.00113 0.0003 0.00087 0.7 0.04 0.043 0.11 198.86 0.013 1.315-May-10 20 1000 860 2.8 110022-May-10 21 1000 850 2.9 110029-May-10 22 1000 860 3.2 450 160 <5 140 < 1 4.06 0.00174 0.0255 0.00094 0.0001 0.0006 0.62 0.03 0.0298 0.07 152.58 0.01 0.8305-Jun-10 23 1000 860 2.8 100012-Jun-10 24 1000 860 2.9 97019 Jun 10 25 1000 860 2 8 930 350 <5 290 < 1 2 89 0 00173 0 0161 0 00105 0 0001 0 0005 0 62 0 02 0 0238 0 06 118 1 0 0093 0 63

Volume mL

19-Jun-10 25 1000 860 2.8 930 350 <5 290 < 1 2.89 0.00173 0.0161 0.00105 0.0001 0.0005 0.62 0.02 0.0238 0.06 118.1 0.0093 0.6326-Jun-10 26 1000 820 2.9 12003-Jul-10 27 1000 820 2.70 160010-Jul-10 28 1000 820 2.9 1500 600 <5 420 < 1 6.98 0.00264 0.0693 0.00156 0.0001 0.00064 0.73 0.03 0.04 0 207.19 0.0142 1.1417-Jul-10 29 1000 820 2.8 150024-Jul-10 30 1000 850 2.9 140031-Jul-10 31 1000 850 2.8 1400 530 <5 350 2 4.71 0.00154 0.0471 0.0013 <0.0001 0.0005 0.33 0.02 0.0344 0.09 177.46 0.0087 0.887-Aug-10 32 1000 860 2.9 130014-Aug-10 33 1000 850 2.9 140021-Aug-10 34 1000 850 2.90 140028-Aug-10 35 1000 850 2.8 1400 570 <5 380 < 1 5.62 0.00235 0.0759 0.00431 0.0002 0.05497 0.32 0.02 0.0351 0.09 187.75 0.0102 0.784-Sep-10 36 1000 850 2.8 160011-Sep-10 37 1000 840 2.8 160018-Sep-10 38 1000 840 2.8 1600 660 <5 450 3 6.72 0.00324 0.1091 0.00137 0.0001 0.00057 0.28 0.02 0.0381 0.08 212.68 0.0105 0.7525-Sep-10 39 1000 870 2.7 18002-Oct-10 40 1000 840 2.7 19009-Oct-10 41 1000 850 2.7 1900 820 <5 580 < 1 7.51 0.00415 0.1266 0.00177 0.0002 0.00059 0.4 0.03 0.0462 0.11 267.08 0.0129 1.0316-Oct-10 42 1000 850 2.8 170023-Oct-10 43 1000 850 2.8 160030-Oct-10 44 1000 850 3 1900 720 <5 500 1 4.58 0.00368 0.1252 0.0018 <0.0001 0.00046 0.26 0.01 0.0377 0.09 222.98 0.0109 0.756-Nov-10 45 1000 840 2.80 1500




LOD21-Dec-09 003-Jan-10 109-Jan-10 216-Jan-10 323-Jan-10 430-Jan-10 506-Feb-10 613-Feb-10 720-Feb-10 827-Feb-10 906-Mar-10 1013-Mar-10 1120-Mar-10 1227-Mar-10 1303-Apr-10 1410-Apr-10 1517-Apr-10 1624-Apr-10 17

01-May-10 1808-May-10 1915-May-10 2022-May-10 2129-May-10 2205-Jun-10 2312-Jun-10 2419 Jun 10 25



mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/l mg/L mg/L mg/L mg/L mg/L0.01 0.0001 0.00005 0.01 0.1 0.1 0.0005 0.00001 0.1 0.00002 0.000005 0.00001 0.0001 0.000005 0.01 0.013.5 0.0002 0.00013 0.36 <0.1 0.9 0.0032 0.00001 12.1 0.02396 0.005763 0.00018 0.0003 0.007955 0.13 0.371.34 0.0002 0.00007 0.29 <0.1 0.2 0.0014 0.00003 2.3 0.00421 0.006065 0.00011 <0.0001 0.00819 0.06 0.19

0.97 <0.0001 0.00027 0.43 <0.1 0.3 0.0015 0.00005 2 0.00475 0.010325 0.00012 0.0002 0.007453 0.09 0.33

0.35 <0.0001 0.00028 0.3 0.1 0.5 0.0019 0.00004 1.3 0.00531 0.005941 0.00016 0.0001 0.003075 0.18 0.2

0.21 <0.0001 0.00115 0.22 0.2 0.4 0.0025 0.00003 1 0.00519 0.00311 0.00022 <0.0001 0.001749 0.13 0.18

0.15 <0.0001 0.00042 0.16 <0.1 0.7 0.0019 0.00005 1.2 0.00353 0.001923 0.00016 <0.0001 0.000904 0.07 0.09

0.11 <0.0001 0.00021 0.13 0.1 1.1 0.0014 0.00003 1.7 0.00489 0.001228 0.00014 <0.0001 0.000547 0.05 0.12

0.1 <0.0001 0.00024 0.11 <0.1 0.6 0.0011 0.00002 1 0.00378 0.001155 0.00017 <0.0001 0.000519 0.04 0.1

0.07 <0.0001 0.00018 0.09 <0.1 0.5 0.0008 0.00002 1.4 0.00363 0.000722 0.00015 <0.0001 0.000341 0.02 0.09

0 05 <0 0001 0 00015 0 06 <0 1 0 5 0 0017 0 00001 1 3 0 00359 0 000542 0 00012 0 0001 0 000272 0 02 0 0919-Jun-10 2526-Jun-10 263-Jul-10 2710-Jul-10 2817-Jul-10 2924-Jul-10 3031-Jul-10 317-Aug-10 3214-Aug-10 3321-Aug-10 3428-Aug-10 354-Sep-10 3611-Sep-10 3718-Sep-10 3825-Sep-10 392-Oct-10 409-Oct-10 4116-Oct-10 4223-Oct-10 4330-Oct-10 446-Nov-10 45

0.05 <0.0001 0.00015 0.06 <0.1 0.5 0.0017 0.00001 1.3 0.00359 0.000542 0.00012 0.0001 0.000272 0.02 0.09

0.08 <0.0001 0.00026 0.09 0.5 0.7 0 0.00006 1.9 0.00488 0.001256 0.00015 0.0001 0.000379 0.02 0.09

0.07 <0.0001 0.00016 0.08 0.2 2.7 0 0.00012 0.5 0.00217 0.000784 0.00011 <0.0001 0.000245 <0.01 0.08

0.07 <0.0001 0.00027 0.08 0.2 0.3 0 0.00007 0.9 0.00214 0.001067 0.00013 0.0002 0.000255 0.01 0.09

0.07 <0.0001 0.0004 0.09 0.3 3.1 0 0.0001 0.9 0.00217 0.001298 0.00012 0.0002 0.000297 0.02 0.09

0.09 <0.0001 0.00039 0.12 0.3 0.5 0 0.00006 0.8 0.00253 0.001539 0.00015 0.0002 0.000327 0.02 0.08

0.06 <0.0001 0.0004 0.09 0.2 0.4 0 0.00006 0.7 0.0018 0.001398 0.00011 0.0002 0.000271 0.01 0.09



SRK 25

200300400500600700800900

oncentration

(mg/L)

SRK 25

SO4

0100200300400500600700800900

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 25

SO4

0100200300400500600700800900

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 25

SO4

8

10

12

14

tion

(mg/L)

SRK 25

0100200300400500600700800900

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 25

SO4

0

2

4

6

8

10

12

14

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 25

Ca

Mg

0100200300400500600700800900

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 25

SO4

0

2

4

6

8

10

12

14

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 25

Ca

Mg

12

14

L)

SRK 25

0100200300400500600700800900

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 25

SO4

0

2

4

6

8

10

12

14

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 25

Ca

Mg

0

2

4

6

8

10

12

14

Concen

tration (m

g/L)

SRK 25

Cl

Na

0100200300400500600700800900

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 25

SO4

0

2

4

6

8

10

12

14

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 25

Ca

Mg

0

2

4

6

8

10

12

14

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 25

Cl

Na



SRK 25

0 01

0.02

0.03

0.04

0.05

0.06

oncentration

(mg/L)

SRK 25

Cd

0

0.01

0.02

0.03

0.04

0.05

0.06

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 25

Cd

0

0.01

0.02

0.03

0.04

0.05

0.06

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 25

Cd

1.5

2

2.5

tion

(mg/L)

SRK 25

0

0.01

0.02

0.03

0.04

0.05

0.06

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 25

Cd

0

0.5

1

1.5

2

2.5

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 25

As

Cu

0

0.01

0.02

0.03

0.04

0.05

0.06

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 25

Cd

0

0.5

1

1.5

2

2.5

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 25

As

Cu

300

350

L)

SRK 25

0

0.01

0.02

0.03

0.04

0.05

0.06

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 25

Cd

0

0.5

1

1.5

2

2.5

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 25

As

Cu

0

50

100

150

200

250

300

350

Concen

tration (m

g/L)

SRK 25

Al

Fe

0

0.01

0.02

0.03

0.04

0.05

0.06

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 25

Cd

0

0.5

1

1.5

2

2.5

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 25

As

Cu

0

50

100

150

200

250

300

350

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 25

Al

Fe



SRK 25

0.1

0.2

0.3

0.4

0.5

oncentration

(mg/L)

SRK 25

Ni

Zn

0.0

0.1

0.2

0.3

0.4

0.5

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 25

Ni

Zn

0.0

0.1

0.2

0.3

0.4

0.5

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 25

Ni

Zn

0 004

0.005

0.006

0.007

0.008

tion

(mg/L)

SRK 25

0.0

0.1

0.2

0.3

0.4

0.5

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 25

Ni

Zn

0.000

0.001

0.002

0.003

0.004

0.005

0.006

0.007

0.008

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 25

Ba

Se

0.0

0.1

0.2

0.3

0.4

0.5

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 25

Ni

Zn

0.000

0.001

0.002

0.003

0.004

0.005

0.006

0.007

0.008

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 25

Ba

Se

3.5

4.0

/L)

SRK 25

0.0

0.1

0.2

0.3

0.4

0.5

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 25

Ni

Zn

0.000

0.001

0.002

0.003

0.004

0.005

0.006

0.007

0.008

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 25

Ba

Se

0.0

0.5

1.0

1.5

2.0

2.5

3.0

3.5

4.0

Concen

tration (m

g/L)

SRK 25

Mn

Sr

0.0

0.1

0.2

0.3

0.4

0.5

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 25

Ni

Zn

0.000

0.001

0.002

0.003

0.004

0.005

0.006

0.007

0.008

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 25

Ba

Se

0.0

0.5

1.0

1.5

2.0

2.5

3.0

3.5

4.0

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 25

Mn

Sr




LOD 0.10 2 5 5 1 1 0.01 0.00001 0.0001 0.00005 0.0001 0.00002 0.01 0.01 0.0001 0.01 0.01 0.0005 0.0121-Dec-09 0 5000 4250 3.3 2300 350 <5 560 440 15.89 0.00453 0.0306 0.00191 0.0029 0.00721 24.03 0.34 3.4502 11.61 90.56 0.0471 58.9403-Jan-10 1 1000 650 2.9 1900 570 <5 940 96 28.81 0.00321 0.0584 0.00029 0.0044 0.00488 16.01 1.02 2.7087 14.1 138.55 0.0062 40.9109-Jan-10 2 1000 640 2.9 190016-Jan-10 3 1000 660 2.9 230023-Jan-10 4 1000 660 2.8 2700 1700 <5 1800 10 99.99 0.00349 0.2705 0.00019 0.0036 0.00406 4.22 2.37 2.7876 14.18 542.5 0.0044 66.2630-Jan-10 5 1000 660 2.9 2300 1500 <5 1500 506-Feb-10 6 1000 680 2.8 270013-Feb-10 7 1000 680 2.9 2300 800 <5 1500 3 57.42 0.00187 0.1634 0.00028 0.0008 0.00161 0.83 1.1 1.629 5.56 520.95 0.0177 36.2320-Feb-10 8 1000 740 2.9 170027-Feb-10 9 1000 740 2.8 190006-Mar-10 10 1000 750 2.8 1800 980 <5 1100 < 1 36.33 0.00028 0.0222 0.00022 0.0003 0.00088 0.38 0.58 1.1878 3.28 365.22 0.0024 24.7313-Mar-10 11 1000 750 2.8 170020-Mar-10 12 1000 770 2.9 160027-Mar-10 13 1000 780 3.1 1800 1000 <5 1200 < 1 40.47 0.00025 0.0206 0.0006 0.0003 0.00094 0.36 0.59 1.187 3.1 402.6 0.0042 29.6803-Apr-10 14 1000 790 3.1 170010-Apr-10 15 1000 800 2.8 240017-Apr-10 16 1000 800 3 2000 990 <5 1300 1 46.7 0.00038 0.0533 0.00032 0.0003 0.00117 0.56 0.65 1.3367 3.3 435.6 0.0042 32.3724-Apr-10 17 1000 800 2.8 210001-May-10 18 1000 800 2.9 180008-May-10 19 1000 800 2.9 1600 930 <5 970 < 1 35.29 0.0002 0.0288 0.00014 0.0002 0.00073 0.4 0.5 0.8716 2.14 346.36 0.0028 23.2515-May-10 20 1000 810 3 140022-May-10 21 1000 810 3 150029-May-10 22 1000 810 2.9 1600 930 <5 1100 < 1 36.67 0.00036 0.0909 0.00018 0.0002 0.00075 0.62 0.54 0.9081 2.01 381.02 0.002 24.6705-Jun-10 23 1000 820 3 140012-Jun-10 24 1000 830 3.1 120019-Jun-10 25 1000 820 2.9 1500 810 <5 810 < 1 27.36 0.00017 0.0165 0.00023 0.0002 0.00055 0.61 0.38 0.7032 1.53 291.8 0.0016 19.0326-Jun-10 26 1000 720 3 19003-Jul-10 27 1000 730 3.00 210010-Jul-10 28 1000 710 2.9 2900 29 <5 1700 1 78.82 0.00135 0.5429 0.00035 0.0004 0.00141 0.94 1.13 1.67 2 693 0.0019 43.7217-Jul-10 29 1000 730 3 210024-Jul-10 30 1000 780 3 200031-Jul-10 31 1000 770 2.8 3000 1700 <5 1700 1 72.6 0.00164 0.3205 0.00021 0.0002 0.00137 0.62 1.02 1.6089 2.25 693.54 0.0006 40.627-Aug-10 32 1000 770 3 190014-Aug-10 33 1000 770 2.8 260021-Aug-10 34 1000 760 2.80 270028-Aug-10 35 1000 770 2.9 1900 870 <5 810 1 28.76 0.00182 0.202 0.00131 <0.0001 0.023 0.24 0.38 0.7088 0.89 340.18 0.0024 16.574-Sep-10 36 1000 740 2.9 260011-Sep-10 37 1000 770 3 130018-Sep-10 38 1000 770 2.9 1700 850 <5 800 1 28.46 0.00166 0.2141 0.00024 <0.0001 0.00054 0.19 0.37 0.7516 0.77 349.61 0.003 17.7325-Sep-10 39 1000 770 2.7 26002-Oct-10 40 1000 740 2.7 23009-Oct-10 41 1000 770 2.7 2400 1300 <5 1200 2 41.53 0.00362 0.4054 0.00065 0.0001 0.00081 0.37 0.53 1.1256 1.1 510.47 0.0028 25.9316-Oct-10 42 1000 780 2.7 200023-Oct-10 43 1000 780 2.7 210030-Oct-10 44 1000 780 2.7 2000 1000 <5 950 2 29.91 0.00331 0.3302 0.00029 <0.0001 0.00064 0.24 0.39 0.8315 0.87 392.61 0.002 18.76-Nov-10 45 1000 740 2.70 2400


Volume mL






mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/l mg/L mg/L mg/L mg/L mg/L0.01 0.0001 0.00005 0.01 0.1 0.1 0.0005 0.00001 0.1 0.00002 0.000005 0.00001 0.0001 0.000005 0.01 0.011.42 0.0008 0.0001 3.95 <0.1 4.2 0.0791 0.00293 284.7 0.24105 0.000772 0.00106 0.0003 0.018279 0.17 0.561.31 0.0002 0.00015 3.43 <0.1 <0.1 0.0598 0.00043 90.5 0.06059 0.003427 0.00022 <0.0001 0.031793 0.7 0.41

1.94 <0.0001 0.00032 6.89 0.2 0.3 0.0426 0.00012 1.2 0.00253 0.019031 0.00003 0.0001 0.031966 1.21 0.56

1.06 0.0001 0.00021 4.19 <0.1 0.1 0.0289 0.00009 0.4 0.00167 0.014961 0.00002 <0.0001 0.008924 0.75 0.24

0.68 <0.0001 0.00039 2.95 0.1 <0.1 0.0181 0.00007 0.3 0.00089 0.00825 0.00002 <0.0001 0.003528 0.29 0.2

0.77 <0.0001 0.0001 3.26 <0.1 <0.1 0.0157 0.00009 0.8 0.0008 0.008767 0.00001 <0.0001 0.003129 0.23 0.14

0.84 <0.0001 < 0.00005 3.35 <0.1 0.2 0.0195 0.00006 1.2 0.00263 0.009545 0.00002 <0.0001 0.003206 0.28 0.16

0.6 <0.0001 < 0.00005 2.35 <0.1 0.2 0.0136 0.00004 0.6 0.00085 0.00648 0.00002 <0.0001 0.002033 0.16 0.14

0.63 <0.0001 < 0.00005 2.48 <0.1 0.2 0.0199 0.00004 1.1 0.00242 0.006954 0.00004 <0.0001 0.002033 0.21 0.14

0.48 <0.0001 < 0.00005 1.92 <0.1 0.1 0.0154 0.00005 1.1 0.00231 0.004775 0.00002 <0.0001 0.001381 0.1 0.12

1.21 <0.0001 0.00017 4.31 0.4 <0.1 0 0.00012 1.6 0.00292 0.013263 0.00002 <0.0001 0.003046 0.31 0.22

1.13 <0.0001 0.00016 4.05 0.2 <0.1 0 0.00012 0.5 0.00142 0.010417 0.00004 <0.0001 0.002573 0.33 0.2

0.46 <0.0001 0.00014 1.78 <0.1 0.2 0 0.00006 0.7 0.00099 0.003485 0.00002 <0.0001 0.000875 0.12 0.11

0.47 <0.0001 0.00014 1.8 <0.1 0.3 0 0.00008 0.6 0.00087 0.003594 0.00002 <0.0001 0.000692 0.11 0.12

0.7 <0.0001 0.00025 2.57 <0.1 <0.1 0 0.0001 0.6 0.00143 0.004448 0.00004 0.0001 0.000997 0.15 0.13

0.5 <0.0001 0.00022 2.01 <0.1 0.1 0 0.00009 0.6 0.00109 0.00313 0.00004 <0.0001 0.000668 0.11 0.12



SRK 330

500

1000

1500

2000

oncentration

(mg/L)

SRK 330

SO4

0

500

1000

1500

2000

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 330

SO4

0

500

1000

1500

2000

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 330

SO4

40

50

60

70

tion

(mg/L)

SRK 330

0

500

1000

1500

2000

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 330

SO4

0

10

20

30

40

50

60

70

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 330

Ca

Mg

0

500

1000

1500

2000

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 330

SO4

0

10

20

30

40

50

60

70

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 330

Ca

Mg

400

500

L)

SRK 330

0

500

1000

1500

2000

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 330

SO4

0

10

20

30

40

50

60

70

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 330

Ca

Mg

0

100

200

300

400

500

Concen

tration (m

g/L)

SRK 330

Cl

Na

0

500

1000

1500

2000

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 330

SO4

0

10

20

30

40

50

60

70

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 330

Ca

Mg

0

100

200

300

400

500

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 330

Cl

Na



SRK 330

0.005

0.01

0.015

0.02

0.025

oncentration

(mg/L)

SRK 330

Cd

0

0.005

0.01

0.015

0.02

0.025

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 330

Cd

0

0.005

0.01

0.015

0.02

0.025

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 330

Cd

8

10

12

14

16

tion

(mg/L)

SRK 330

0

0.005

0.01

0.015

0.02

0.025

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 330

Cd

0

2

4

6

8

10

12

14

16

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 330

As

Cu

0

0.005

0.01

0.015

0.02

0.025

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 330

Cd

0

2

4

6

8

10

12

14

16

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 330

As

Cu

700

800

L)

SRK 330

0

0.005

0.01

0.015

0.02

0.025

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 330

Cd

0

2

4

6

8

10

12

14

16

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 330

As

Cu

0

100

200

300

400

500

600

700

800

Concen

tration (m

g/L)

SRK 330

Al

Fe

0

0.005

0.01

0.015

0.02

0.025

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 330

Cd

0

2

4

6

8

10

12

14

16

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 330

As

Cu

0

100

200

300

400

500

600

700

800

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 330

Al

Fe



SRK 330

2

3

4

5

6

7

8

oncentration

(mg/L)

SRK 330

Ni

Zn

0

1

2

3

4

5

6

7

8

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 330

Ni

Zn

0

1

2

3

4

5

6

7

8

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 330

Ni

Zn

0.050.060.070.080.09

tion

(mg/L)

SRK 330

0

1

2

3

4

5

6

7

8

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 330

Ni

Zn

0.000.010.020.030.040.050.060.070.080.09

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 330

Ba

Se

0

1

2

3

4

5

6

7

8

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 330

Ni

Zn

0.000.010.020.030.040.050.060.070.080.09

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 330

Ba

Se

2 0

2.5

L)

SRK 330

0

1

2

3

4

5

6

7

8

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 330

Ni

Zn

0.000.010.020.030.040.050.060.070.080.09

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 330

Ba

Se

0.0

0.5

1.0

1.5

2.0

2.5

Concen

tration (m

g/L)

SRK 330

Mn

Sr

0

1

2

3

4

5

6

7

8

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 330

Ni

Zn

0.000.010.020.030.040.050.060.070.080.09

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 330

Ba

Se

0.0

0.5

1.0

1.5

2.0

2.5

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 330

Mn

Sr




LOD 0.10 2 5 5 1 1 0.01 0.00001 0.0001 0.00005 0.0001 0.00002 0.01 0.01 0.0001 0.01 0.01 0.0005 0.0121-Dec-09 0 1000 830 7.2 81 12 21 24 5 0.08 0.0004 0.0098 0.00169 <0.0001 0.00006 11.43 <0.01 0.002 0.02 0.05 0.0008 2.0203-Jan-10 1 1000 830 6.4 100 <5 9 40 2 0.07 0.00009 0.0007 0.00201 <0.0001 0.00011 10.81 <0.01 0.0071 0.02 0.21 0.0012 2.9409-Jan-10 2 1000 840 5.8 5616-Jan-10 3 1000 840 5.1 5523-Jan-10 4 1000 850 4.6 71 22 <5 23 1 0.1 0.00006 0.0009 0.00097 <0.0001 0.00008 6.17 <0.01 0.0045 0.02 0.33 < 0.0005 1.5730-Jan-10 5 1000 840 4.8 61 19 <5 24 106-Feb-10 6 1000 860 4.6 7113-Feb-10 7 1000 850 4.8 65 22 <5 27 1 0.05 0.00004 0.0003 0.00091 <0.0001 0.0001 4.91 <0.01 0.0036 <0.01 0.6 0.0011 0.9320-Feb-10 8 1000 840 4.9 5827-Feb-10 9 1000 850 7 6406-Mar-10 10 1000 850 4.5 38 23 <5 21 < 1 0.02 0.00002 <0.0001 0.00066 <0.0001 0.00014 4.4 <0.01 0.004 <0.01 0.62 0.0021 0.7713-Mar-10 11 1000 850 4.8 6020-Mar-10 12 1000 840 4.8 5327-Mar-10 13 1000 850 4.9 52 15 6 19 < 1 0.03 0.00002 0.0003 0.00046 <0.0001 0.00011 4.28 <0.01 0.0045 <0.01 0.66 0.0008 0.5303-Apr-10 14 1000 850 5.1 4810-Apr-10 15 1000 850 4.6 6517-Apr-10 16 1000 860 4.7 59 16 <5 19 < 1 0.12 0.00002 0.0001 0.00051 <0.0001 0.00022 3.88 <0.01 0.0059 0.01 1.14 < 0.0005 0.524-Apr-10 17 1000 850 5.1 44

01-May-10 18 1000 860 4.7 5708-May-10 19 1000 860 4.7 52 25 <5 19 < 1 0.1 0.00001 0.0003 0.00035 <0.0001 0.00012 3.35 <0.01 0.0045 0.01 1.06 < 0.0005 0.4315-May-10 20 1000 860 5.1 10022-May-10 21 1000 860 6.3 3829-May-10 22 1000 870 6 33 6 <5 12 1 0.05 0.00002 0.0004 0.0002 <0.0001 0.00006 3.03 <0.01 0.0022 <0.01 0.53 < 0.0005 0.3105-Jun-10 23 1000 870 5.1 4112-Jun-10 24 1000 860 6 3119 Jun 10 25 1000 870 6 1 31 <5 <5 11 < 1 0 02 0 00002 0 0003 0 00026 <0 0001 0 00006 2 95 <0 01 0 0019 <0 01 0 41 0 0011 0 28

Volume mL

19-Jun-10 25 1000 870 6.1 31 <5 <5 11 < 1 0.02 0.00002 0.0003 0.00026 <0.0001 0.00006 2.95 <0.01 0.0019 <0.01 0.41 0.0011 0.2826-Jun-10 26 1000 840 6.3 263-Jul-10 27 1000 850 3.90 9610-Jul-10 28 1000 840 5 37 10 <5 19 < 1 0.08 0.00003 0.0006 0.0003 <0.0001 0.0001 2.17 <0.01 0.00 <0.01 0.82 < 0.0005 0.2517-Jul-10 29 1000 850 4.4 6424-Jul-10 30 1000 860 4.4 5531-Jul-10 31 1000 860 4.4 58 29 <5 18 < 1 0.17 0.00002 0.0009 0.00059 <0.0001 0.00028 1.96 <0.01 0.0056 0.01 2.4 0.0018 0.257-Aug-10 32 1000 840 4.5 4614-Aug-10 33 1000 860 4.4 5621-Aug-10 34 1000 860 4.40 5528-Aug-10 35 1000 860 4.4 55 <5 <5 23 < 1 0.18 0.00004 0.0009 0.00152 <0.0001 0.02264 1.75 <0.01 0.0057 0.01 2.54 0.0021 0.244-Sep-10 36 1000 850 4.3 6911-Sep-10 37 1000 850 4.6 3918-Sep-10 38 1000 850 4.5 50 24 <5 17 < 1 0.08 0.00003 0.0004 0.00057 <0.0001 0.00021 1.73 <0.01 0.004 <0.01 1.54 0.0019 0.1925-Sep-10 39 1000 860 4.3 602-Oct-10 40 1000 850 4.4 569-Oct-10 41 1000 850 4.3 66 34 <5 21 < 1 0.13 0.00004 0.0006 0.00117 <0.0001 0.00021 1.87 <0.01 0.0051 0.02 2.36 0.003 0.2316-Oct-10 42 1000 850 4.3 6023-Oct-10 43 1000 850 4.3 6230-Oct-10 44 1000 860 4.3 55 29 <5 16 < 1 0.07 0.00002 0.0005 0.00069 <0.0001 0.00018 1.5 <0.01 0.0034 0.02 1.18 0.0023 0.186-Nov-10 45 1000 850 4.30 58




LOD21-Dec-09 003-Jan-10 109-Jan-10 216-Jan-10 323-Jan-10 430-Jan-10 506-Feb-10 613-Feb-10 720-Feb-10 827-Feb-10 906-Mar-10 1013-Mar-10 1120-Mar-10 1227-Mar-10 1303-Apr-10 1410-Apr-10 1517-Apr-10 1624-Apr-10 17

01-May-10 1808-May-10 1915-May-10 2022-May-10 2129-May-10 2205-Jun-10 2312-Jun-10 2419 Jun 10 25



mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/l mg/L mg/L mg/L mg/L mg/L0.01 0.0001 0.00005 0.01 0.1 0.1 0.0005 0.00001 0.1 0.00002 0.000005 0.00001 0.0001 0.000005 0.01 0.011.57 <0.0001 0.00013 <0.01 <0.1 1 < 0.0005 <0.00001 2.9 0.01565 < 0.000005 0.00001 <0.0001 0.00004 <0.01 0.083.3 <0.0001 0.00012 0.03 <0.1 0.6 0.0005 0.00001 1.4 0.01164 < 0.000005 <0.00001 <0.0001 0.000042 <0.01 0.07

2.02 <0.0001 0.00026 0.02 <0.1 0.4 0.0006 0.00001 0.9 0.00415 0.000018 <0.00001 <0.0001 0.000031 <0.01 0.09

2.23 <0.0001 < 0.00005 0.02 <0.1 0.3 < 0.0005 0.00003 0.5 0.00366 0.000014 <0.00001 <0.0001 0.000034 <0.01 0.11

2.26 <0.0001 < 0.00005 0.03 <0.1 0.2 < 0.0005 <0.00001 0.5 0.003 < 0.000005 <0.00001 <0.0001 0.00003 <0.01 0.13

1.53 <0.0001 < 0.00005 0.02 <0.1 0.3 0.0008 0.00001 0.9 0.0029 0.000009 <0.00001 <0.0001 0.000015 <0.01 0.09

1.41 0.0001 < 0.00005 0.02 <0.1 0.3 < 0.0005 0.00016 1.3 0.00457 0.00002 <0.00001 <0.0001 0.000016 <0.01 0.1

1.46 <0.0001 < 0.00005 0.02 <0.1 0.2 0.0006 <0.00001 0.7 0.00273 0.000014 <0.00001 <0.0001 0.000012 <0.01 0.11

0.76 <0.0001 < 0.00005 0.01 <0.1 0.5 0.0007 <0.00001 1.2 0.00333 0.000008 0.00002 <0.0001 0.000006 <0.01 0.07

0 56 <0 0001 < 0 00005 <0 01 <0 1 0 6 < 0 0005 <0 00001 1 3 0 00348 < 0 000005 <0 00001 <0 0001 0 000005 <0 01 0 0719-Jun-10 2526-Jun-10 263-Jul-10 2710-Jul-10 2817-Jul-10 2924-Jul-10 3031-Jul-10 317-Aug-10 3214-Aug-10 3321-Aug-10 3428-Aug-10 354-Sep-10 3611-Sep-10 3718-Sep-10 3825-Sep-10 392-Oct-10 409-Oct-10 4116-Oct-10 4223-Oct-10 4330-Oct-10 446-Nov-10 45

0.56 <0.0001 < 0.00005 <0.01 <0.1 0.6 < 0.0005 <0.00001 1.3 0.00348 < 0.000005 <0.00001 <0.0001 0.000005 <0.01 0.07

0.7 <0.0001 < 0.00005 <0.01 <0.1 0.3 0 <0.00001 1.5 0.00329 0.000009 <0.00001 <0.0001 < 0.000005 <0.01 0.07

1.24 <0.0001 < 0.00005 0.01 <0.1 0.2 0 <0.00001 0.3 0.00211 0.00002 <0.00001 <0.0001 0.000035 <0.01 0.1

1.32 <0.0001 < 0.00005 0.01 <0.1 0.2 0 <0.00001 0.7 0.00183 0.000015 <0.00001 <0.0001 0.000037 <0.01 0.1

1.4 <0.0001 < 0.00005 <0.01 <0.1 0.5 0 <0.00001 0.5 0.00177 0.000005 <0.00001 <0.0001 0.000041 <0.01 0.13

1.45 <0.0001 < 0.00005 0.01 <0.1 0.3 0 0.00001 0.4 0.00203 0.000008 <0.00001 <0.0001 0.000052 <0.01 0.11

1.24 <0.0001 < 0.00005 <0.01 <0.1 0.2 0 <0.00001 0.4 0.00155 < 0.000005 <0.00001 <0.0001 0.000052 <0.01 0.11



SRK 13059

1015202530354045

oncentration

(mg/L)

SRK 13059

SO4

05

1015202530354045

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 13059

SO4

05

1015202530354045

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 13059

SO4

8

10

12

14

tion

(mg/L)

SRK 13059

05

1015202530354045

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 13059

SO4

0

2

4

6

8

10

12

14

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 13059

Ca

Mg

05

1015202530354045

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 13059

SO4

0

2

4

6

8

10

12

14

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 13059

Ca

Mg

5

6

L)

SRK 13059

05

1015202530354045

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 13059

SO4

0

2

4

6

8

10

12

14

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 13059

Ca

Mg

0

1

2

3

4

5

6

Concen

tration (m

g/L)

SRK 13059

Cl

Na

05

1015202530354045

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 13059

SO4

0

2

4

6

8

10

12

14

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 13059

Ca

Mg

0

1

2

3

4

5

6

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 13059

Cl

Na



SRK 13059

0.0001

0.0002

0.0003

0.0004

0.0005

oncentration

(mg/L)

SRK 13059

Cd

0

0.0001

0.0002

0.0003

0.0004

0.0005

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 13059

Cd

0

0.0001

0.0002

0.0003

0.0004

0.0005

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 13059

Cd

0.015

0.02

0.025

tion

(mg/L)

SRK 13059

0

0.0001

0.0002

0.0003

0.0004

0.0005

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 13059

Cd

0

0.005

0.01

0.015

0.02

0.025

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 13059

As

Cu

0

0.0001

0.0002

0.0003

0.0004

0.0005

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 13059

Cd

0

0.005

0.01

0.015

0.02

0.025

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 13059

As

Cu

2 5

3.0

L)

SRK 13059

0

0.0001

0.0002

0.0003

0.0004

0.0005

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 13059

Cd

0

0.005

0.01

0.015

0.02

0.025

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 13059

As

Cu

0.0

0.5

1.0

1.5

2.0

2.5

3.0

Concen

tration (m

g/L)

SRK 13059

Al

Fe

0

0.0001

0.0002

0.0003

0.0004

0.0005

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 13059

Cd

0

0.005

0.01

0.015

0.02

0.025

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 13059

As

Cu

0.0

0.5

1.0

1.5

2.0

2.5

3.0

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 13059

Al

Fe



SRK 13059

0.04

0.06

0.08

0.10

0.12

0.14

oncentration

(mg/L)

SRK 13059

Ni

Zn

0.00

0.02

0.04

0.06

0.08

0.10

0.12

0.14

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 13059

Ni

Zn

0.00

0.02

0.04

0.06

0.08

0.10

0.12

0.14

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 13059

Ni

Zn

0.0015

0.0020

0.0025

tion

(mg/L)

SRK 13059

0.00

0.02

0.04

0.06

0.08

0.10

0.12

0.14

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 13059

Ni

Zn

0.0000

0.0005

0.0010

0.0015

0.0020

0.0025

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 13059

Ba

Se

0.00

0.02

0.04

0.06

0.08

0.10

0.12

0.14

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 13059

Ni

Zn

0.0000

0.0005

0.0010

0.0015

0.0020

0.0025

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 13059

Ba

Se

3.0

3.5

/L)

SRK 13059

0.00

0.02

0.04

0.06

0.08

0.10

0.12

0.14

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 13059

Ni

Zn

0.0000

0.0005

0.0010

0.0015

0.0020

0.0025

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 13059

Ba

Se

0.0

0.5

1.0

1.5

2.0

2.5

3.0

3.5

Concen

tration (m

g/L)

SRK 13059

Mn

Sr

0.00

0.02

0.04

0.06

0.08

0.10

0.12

0.14

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 13059

Ni

Zn

0.0000

0.0005

0.0010

0.0015

0.0020

0.0025

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 13059

Ba

Se

0.0

0.5

1.0

1.5

2.0

2.5

3.0

3.5

0 10 20 30 40 50

Concen

tration (m

g/L)

Time (week)

SRK 13059

Mn

Sr



Appendix 14: Molar Ratio Plots

SRK Consulting

SMM004 Geochemical Characterisation of Weld Range

Kinetic Column Data – Molar Ratio and Leachate pH Plots

2

3

4

5

6

7

8

9

10

00.20.40.60.81

1.21.41.61.8

0 2 4 6 8 10 12 14 16

pH

Molar ratio

Time (week)

A13017

SO4/(Ca+Mg)

pH

2

3

4

5

6

7

8

9

10

00.20.40.60.81

1.21.41.61.8

0 2 4 6 8 10 12 14 16

pH

Molar ratio

Time (week)

A13019

SO4/(Ca+Mg)

pH

2

3

4

5

6

7

8

9

10

00.20.40.60.81

1.21.41.61.8

0 2 4 6 8 10 12 14 16

pH

Molar ratio

Time (week)

A13035

SO4/(Ca+Mg)

pH

2

3

4

5

6

7

8

9

10

00.20.40.60.81

1.21.41.61.8

0 2 4 6 8 10 12 14 16

pH

Molar ratio

Time (week)

A13050

SO4/(Ca+Mg)

pH

2

3

4

5

6

7

8

9

10

00.20.40.60.81

1.21.41.61.8

0 10 20 30 40 50

pH

Molar ratio

Time (week)

SRK 1

SO4/(Ca+Mg)

pH

2

3

4

5

6

7

8

9

10

00.20.40.60.81

1.21.41.61.8

0 10 20 30 40 50

pH

Molar ratio

Time (week)

SRK 5

SO4/(Ca+Mg)

pH

2

3

4

5

6

7

8

9

10

00.20.40.60.81

1.21.41.61.8

0 10 20 30 40 50

pH

Molar ratio

Time (week)

SRK 7

SO4/(Ca+Mg)

pH

2

3

4

5

6

7

8

9

10

00.20.40.60.81

1.21.41.61.8

0 10 20 30 40 50

pH

Molar ratio

Time (week)

SRK 10

SO4/(Ca+Mg)

pH

2

3

4

5

6

7

8

9

10

00.51

1.52

2.53

3.54

4.5

0 10 20 30 40 50

pH

Molar ratio

Time (week)

SRK 15

SO4/(Ca+Mg)

pH

2

3

4

5

6

7

8

9

10

00.20.40.60.81

1.21.41.61.8

0 10 20 30 40 50

pH

Molar ratio

Time (week)

SRK 24

SO4/(Ca+Mg)

pH

2

3

4

5

6

7

8

9

10

0

10

20

30

40

50

60

70

0 10 20 30 40 50

pH

Molar ratio

Time (week)

SRK 25

SO4/(Ca+Mg)

pH

2

3

4

5

6

7

8

9

10

0

2

4

6

8

10

12

14

0 10 20 30 40 50

pH

Molar ratio

Time (week)

SRK 330

SO4/(Ca+Mg)

pH

2

3

4

5

6

7

8

9

10

00.51

1.52

2.53

3.54

4.55

0 10 20 30 40 50

pH

Molar ratio

Time (week)

SRK 13059

SO4/(Ca+Mg)

pH

geochemical characterisation of weld range waste and ...€¦ · from the sinosteel midwest...

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