genesis of the rosebery massive sulphide deposit, western

129
Genesis of the Rosebery massive sulphide deposit, western Tasmania, Australia. (Volume 2 - Appendices) by Neil K. Martin (BSc. Hons.) Submitted in fulfilment of the requirements for the degree of Doctor of Philosophy UNIVERSITY OF TASMANIA September, 2004

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Genesis of the Rosebery massive sulphide deposit, western Tasmania, Australia.

(Volume 2 - Appendices)

by

Neil K. Martin (BSc. Hons.)

Submitted in fulfilment of the requirements for the degree of Doctor of Philosophy

UNIVERSITY OF TASMANIA

September, 2004

Declaration

This thesis contains no material that has been accepted for a degree or diploma by the

University or any other institution, except by way of background information and duly

acknowledged in the thesis, and to the best of the candidate’s knowledge and belief, contains

no material previously published or written by another person, except where due

acknowledgement is made in the text of the thesis.

Neil K. Martin

Date:

Confidentiality

This thesis is not to be made available for loan or copying for two years following the date this

statement was signed. Following that time, the thesis may be made available for loan and

limited copying in accordance with the Copyright Act 1969.

Neil K. Martin

Date:

Contents

Appendix 1. Sample Catalogue 1 Appendix 2. Whole Rock Analyses 8 Appendix 3. Microprobe Analyses - Silicates 14 Appendix 4. Microprobe Analyses - Sulphides 18 Appendix 5. LA-ICP-MS Analyses - Sulphides 51 Appendix 6. Sulphur Isotope Analyses 87 Appendix 7. Geological Logs 92 Appendix 8. Specific New Data Collected & Presented 125

Appendix 1: Sample Catalogue

1

Appendix 1 Sample Catalogue

Appendix 1: Sample Catalogue

2

1535

53

B

V-0

020

R64

12

6

3.5

cor

e

ore

sem

i-mas

s. s

p-ga

ore

R

,1TS

15

3554

BV

-007

8

R

6460

69

c

ore

o

re

m

ass.

sp-

ga o

re

R,1

TS

1535

55

B

V-0

127

R65

29

9

1.2

cor

e

ore

dk ta

n sp

-py

R

,1TS

15

3556

BV

-016

6

R

7042

16.

7

c

ore

f

w

f

inel

y ba

nded

and

dis

s. p

y an

d sp

R

1535

57

B

V-0

167

R70

42

1

7.6

cor

e

ore

sem

i-mas

s. o

re, c

oars

e, b

lebb

y py

in c

l-sch

ist,

min

or g

a-cp

y

R

15

3558

BV

-016

8

R

7042

18.

3

c

ore

o

re

m

ass.

hon

ey-b

row

n sp

-ga

ore

R

1535

59

B

V-0

169

R70

42

1

9.1

cor

e

ba

mas

s. b

a w

ith s

p-ga

-py

R

15

3560

BV

-017

1

R

7042

19.

5

c

ore

t

sv

fg

sem

i-mas

s. p

y an

d al

tere

d se

dim

ent

R

15

3561

BV

-017

3

R

7042

20.

2

c

ore

o

re

m

ass.

sp-

ga w

ith b

a cl

ast

R

1535

62

B

V-0

175

R70

42

2

0.8

cor

e

sill

alte

red

sedi

men

t with

som

e ba

nds

sp, p

ossi

ble

porp

hyry

sill

R

15

3563

BV

-018

4

R

7044

21.

1

c

ore

o

re

m

ass.

hon

ey-b

row

n to

ora

nge

sp a

nd b

a

R

,1TS

15

3564

BV

-021

0

R

7046

25.

5

c

ore

o

re

m

ass.

fine

-gra

ined

lam

inat

ed p

y w

ith m

inor

sp

R,1

TS

1535

65

B

V-0

219

R69

53

1

3.5

cor

e

ore

mas

s. s

p-ga

-py

R

,1TS

15

3566

BV

-022

0

R

6953

14.

5

c

ore

o

re

m

ass.

sp-

ga

R,1

TS

1535

67

B

V-0

223

R69

53

1

8.3

cor

e

ore

mas

s. p

y-sp

R

1535

68

B

V-0

226

R69

53

2

2

cor

e

ore

mas

s. b

ande

d sp

-py

R

,1TS

15

3569

BV

-022

7

R

6953

24

c

ore

o

re

m

ass.

py,

min

or s

p

1535

70

C

00-0

079

1

23R

14

55.8

c

ore

o

re

m

ass.

hon

ey-b

row

n sp

-py-

cpy-

ga o

re w

ith "c

last

ic" t

extu

re

R

,PB

15

3571

C00

-008

2

123

R

1469

.5

cor

e

fw

si-s

e-cb

aug

en s

chis

t, di

ss. p

y

R

,PB

15

3572

C00

-008

7

123

R

1500

.9

cor

e

fw

se-

qz a

ugen

sch

ist w

ith c

l pse

udof

iam

me

R,1

TS

1535

73

C

00-0

091

1

32R

-D2

11

07

c

ore

h

w

dk

gre

y cl

alte

red,

fp c

ryst

al-r

ich

sand

ston

e

R,P

D,C

R,1

TS,X

RF

glas

s 15

3574

C00

-009

2

132

R-D

2

1131

.5

cor

e

hw

dk g

rey

cl a

ltere

d, fp

cry

stal

-ric

h sa

ndst

one,

late

cl v

einl

ets

R

,PD

,CR

,XR

F gl

ass

1535

75

C

00-0

098

1

32R

-D2

12

52.5

c

ore

s

ill

dk

gre

y se

-si a

ltere

d, q

z-fp

por

phyr

y si

ll, m

inor

cla

stic

xen

olith

s, m

inor

py

R,1

TS

1535

76

C

00-0

124

1

32R

-D2

13

89.4

c

ore

f

w

m

ass.

rhod

ochr

osite

+ c

l sch

ist w

ith re

lict f

p

R

1535

77

C

00-0

134

8

4R

82

8.4

c

ore

t

sv

fg

si-a

ltere

d sa

ndst

one/

schi

st +

ba-

min

or p

y

R,1

TS

1535

78

C

00-0

139

8

7R

61

9.8

c

ore

h

w

po

lym

ict b

recc

ia, m

ass

flow

uni

t, am

ygda

loid

al m

afic

cla

st

R

,1TS

15

3579

C00

-014

3

87R

770.

1

cor

e

tsv

pum

iceo

us fp

san

dsto

ne +

sha

le in

tracl

asts

, qua

rtz d

eriv

ed fr

om p

orph

yry

sill

R,P

D,C

R,X

RF

glas

s 15

3580

C00

-014

4

87R

772.

2

cor

e

tsv

pum

iceo

us fp

san

dsto

ne, q

uartz

der

ived

from

por

phyr

y si

ll

R,P

D,X

RF

glas

s 15

3581

C00

-015

6

R55

81-D

2 69

8.4

c

ore

t

sv

si

-se

alte

red,

fg fe

ldsp

athi

c sa

ndst

one,

min

or d

iss.

py

R,1

TS

1535

82

C

00-0

184

R

6760

135

.7

co

re

ts

v

st

ratif

ied

si-s

e al

tere

d se

dim

ent,

fp c

ryst

als

to 3

mm

R

,1TS

15

3583

C00

-020

8

127

R

1523

.2

cor

e

tsv

fg s

e-cl

-cb-

si s

chis

t, m

inor

dis

s. p

y-sp

R,P

D,C

R,X

RF

glas

s 15

3584

C00

-021

1

127

R

1505

.9

cor

e

tsv

mas

s. b

lack

cl-m

agne

tite-

cb +

sp-

py-g

a (D

ev. m

etas

.)

R

,1TS

,PB

1535

85

C

00-0

220

1

27R

14

55

c

ore

t

sv

se

-si a

ltere

d, fg

fp-c

ryst

al s

ands

tone

, nor

mal

ly g

rade

d

R

,1TS

15

3586

C00

-022

3

127

R

1394

.8

cor

e

tsv

si-s

e al

tere

d, d

iffus

ely

stra

tifie

d fg

feld

spat

hic

sand

ston

e

R

,1TS

15

3587

C00

-024

7

121

R

1327

.6

cor

e

fw

cl-s

e sc

hist

, pos

sibl

y fg

top

dact

itic

debr

is fl

ow u

nit

R

,1TS

15

3588

C00

-026

1

121

R-D

1

1282

.2

cor

e

tsv

fine

py re

plac

emen

t? o

f sed

imen

t bel

ow s

ill

R,1

TS,P

B 15

3589

C00

-027

8

R64

11

9

1.8

cor

e

tsv

grey

si-s

e sc

hist

, py

+ m

inor

sp

lens

es p

aral

lel t

o fo

liatio

n

R

,PD

,1TS

,PB

,XR

F gl

ass

Uni

v. T

as.

fie

ld id

.

hole

id.

de

pth

sa

mpl

e un

it

sam

ple

desc

riptio

n

c

atal

ogue

d m

ater

ials

ca

talo

gue

(m)

type

Appendix 1: Sample Catalogue

3

1535

90

C

00-0

280

R

6411

96.

3

c

ore

t

sv

si

-se

schi

st, f

g di

ss. p

y, m

inor

dk

tan

sp a

long

folia

tion

R

,PD

,1TS

,PB

,XR

F gl

ass

1535

91

C

00-0

283

R

6411

104

.2

co

re

or

e

dk

tan

sp-g

a-py

with

cg

text

ure,

min

or b

a cl

asts

R

15

3592

C00

-028

4

R64

11

1

06.4

core

ore

d

k re

d-br

own

sp-p

y, c

ore

very

bro

ken

R,P

D,P

B,X

RF

glas

s 15

3593

C00

-028

5

R65

29

8

7.6

cor

e

tsv

cl-s

e sc

hist

,cb

bleb

s, ta

n sp

as

wis

py le

nses

par

alle

l fol

iatio

n

R

,PD

,1TS

,PB

,XR

F gl

ass

1535

94

C

00-0

287

R

6529

90.

8

c

ore

o

re

dk

tan

sp-p

y-ga

, ser

iciti

c cl

asts

R,P

D,1

TS,P

B,X

RF

glas

s 15

3595

C00

-029

0

R65

29

9

9.5

cor

e

ore

mas

s. fg

pal

e ta

n sp

-ga

(+ b

a) +

late

r pat

chy

cpy-

py

R,P

D,1

TS,P

B,X

RF

glas

s 15

3596

C00

-029

2

R65

87

2

6

cor

e

fw

si-s

e sc

hist

, dk

red-

brow

n sp

in la

te s

yn- t

o po

st-d

efor

mat

ion

qz-c

b ve

in

R,P

D,1

TS,P

B,X

RF

glas

s 15

3597

C00

-029

7

R65

87

7

1.1

cor

e

ore

qz-s

e sc

hist

- pa

tchy

/blo

tchy

dis

s. to

mas

s. ta

n sp

-ga-

py, m

inor

cpy

R

,PD

,1TS

,PB

,XR

F gl

ass

1535

98

C

00-0

299

R

6587

77.

2

c

ore

o

re

m

ass.

fg p

ale

tan

sp-g

a +

ba v

einl

ets

R,P

D,1

TS,P

B,X

RF

glas

s 15

3599

C00

-030

1

R65

87

8

2.8

cor

e

ore

sem

i-mas

s. s

ulph

ide,

si-s

e sc

hist

, pat

chy/

blot

chy

tan

and

crea

m s

p-ga

R

,PD

,1TS

,PB

,XR

F gl

ass

1536

00

C

00-0

306

R

6592

78.

6

c

ore

o

re

se

mi-m

ass.

/dis

s. s

ulph

ide,

si-s

e sc

hist

, pat

chy/

blot

chy

pale

to ta

n sp

-ga

R,P

D,1

TS,P

B,X

RF

glas

s 15

3601

C00

-030

7

R65

92

8

2.7

cor

e

ore

sem

i-mas

s./d

iss.

sul

phid

e, s

i-se

schi

st, p

atch

y/bl

otch

y ta

n sp

-ga

R,P

D,1

TS,P

B,X

RF

glas

s 15

3602

C00

-031

7

R65

93

5

9.6

cor

e

ore

mas

s. s

ulph

ide,

si-s

e sc

hist

, tan

sp-

ga w

ith p

y ed

ges

R,P

D,1

TS,P

B,X

RF

glas

s 15

3603

C00

-032

0

R64

26

7

7.4

cor

e

fw

se-

si s

chis

t, di

ss. p

y

R,P

D,1

TS,P

B,X

RF

glas

s 15

3604

C00

-032

3

R64

26

9

3

cor

e

fw

si-s

e sc

hist

, tan

sp-

ga a

s w

ispy

dis

sem

inat

ions

par

alle

l fol

iatio

n

R,P

D,1

TS,P

B,X

RF

glas

s 15

3605

C00

-032

6

R64

26

1

05.9

core

ore

m

ass.

dk

tan

sp-g

a-py

R,P

D,1

TS,P

B,X

RF

glas

s 15

3606

C00

-032

9

R64

26

1

13.3

core

ore

m

ass.

fine

ly la

min

ated

sul

phid

e, s

i bre

ccia

with

mas

s. s

ulph

ide

mat

rix, d

k ta

n sp

-ga

R,P

D,2

TS,P

B,X

RF

glas

s 15

3607

C00

-033

2

R64

26

1

25

core

ore

m

ass.

ban

ded

red-

brow

n sp

-ga-

py +

ban

d m

ass.

py,

cla

sts

si-s

e-cl

sch

ist/b

recc

ia

R

15

3608

C00

-033

3

R64

64

8

9.8

cor

e

tsv

fg c

l-se-

si s

chis

t, di

ss. t

an s

p-ga

as

wis

py d

isse

min

atio

ns p

aral

lel f

olia

tion

R

,PD

,1TS

,PB

,XR

F gl

ass

1536

09

C

00-0

337

R

6464

104

.1

co

re

or

e

mas

s. s

ulph

ide,

tan

sp-g

a

R

,PD

,1TS

,PB

,XR

F gl

ass

1536

10

C

00-0

338

R

6464

109

co

re

or

e

mas

s. s

p-py

-ga

with

se-

si a

ltere

d se

dim

ent m

ass.

py

R,1

TS

1536

11

C

00-0

341

R

6464

111

.8

co

re

or

e

mas

s. s

ulph

ide,

fg ta

n sp

-ga-

py, w

ith la

te p

y ve

in/b

and

R

,PD

,1TS

,PB

,XR

F gl

ass

1536

12

C

00-0

343

R

6926

118

.7

co

re

or

e

cl-s

e-si

sch

ist,

diss

. to

sem

i-mas

s.dk

red-

brow

n sp

-py-

ga

R

,PD

,1TS

,PB

,XR

F gl

ass

1536

13

C

00-0

345

R

6926

123

.6

co

re

or

e

mas

s. s

ulph

ide,

late

qz

vein

, tan

sp-

ga-p

y

R

,PD

,1TS

,PB

,XR

F gl

ass

1536

14

C

00-0

346

R

6926

128

.2

co

re

ts

v

py

ritic

she

ar in

qz-

fp p

orph

yry

R,P

D,C

R,X

RF

glas

s 15

3615

C00

-035

0

R69

21

1

32

core

ore

b

ande

d se

mi-m

ass.

ligh

t tan

sp-

ga-p

y, fg

cl-s

e-si

sch

ist

R

,PD

,1TS

,PB

,XR

F gl

ass

1536

16

C

00-0

351

R

6921

135

.4

co

re

ba

mas

s. b

ande

d fg

ba,

min

or s

ulph

ides

R

15

3617

C00

-035

3

R70

13

1

64.6

core

ore

d

iss.

to s

emi-m

ass.

py,

min

or s

p-ga

, si-s

e sc

hist

, cb

bleb

s

R,P

D,1

TS,P

B,X

RF

glas

s 15

3618

C00

-035

5

R64

76

9

0.4

cor

e

fw

si-s

e au

gen

schi

st, 2

% d

iss.

py

R

,PD

,1TS

,PB

,XR

F gl

ass

1536

19

C

00-0

357

R

6476

98.

4

c

ore

f

w

s

i-se

auge

n sc

hist

, min

or ta

n sp

vei

nlet

s, c

l-qz-

cb+p

y-cp

y-ga

-sp

vein

lets

, min

or d

iss.

py

R,P

D,1

TS,P

B,XR

F gl

ass

1536

20

C

00-0

359

R

6476

107

co

re

or

e

mas

s. p

ale

hone

y sp

-ga

with

min

or s

ilice

ous

patc

hes

(qz

vein

or c

last

)

R,P

D,1

TS,P

B,X

RF

glas

s 15

3621

C00

-036

2

R64

76

1

15.3

core

ore

m

ass.

sul

phid

es c

ut b

y qz

-cb

vein

s, a

ll or

ange

sp-

ga-p

y

R,P

D,1

TS,P

B,X

RF

glas

s 15

3622

C00

-036

3

R64

76

1

18

core

ore

m

ass.

sp-

ga, p

y ba

nd re

plac

ing

sp-g

a or

e (c

onta

ins

sp-g

a in

clus

ion)

R

,2TS

15

3623

C00

-036

4

R64

76

1

20.8

core

ore

m

ass.

fg ta

n sp

-py-

ga, t

r cpy

R

,PD

,1TS

,PB

,XR

F gl

ass

1536

24

C

00-0

365

R

6476

123

.2

co

re

or

e

mas

s. "c

ooke

d" re

d br

own

sp-g

a an

d py

, min

or c

last

s si

-alte

red

sedi

men

t

R,P

D,1

TS,P

B,X

RF

glas

s 15

3625

C00

-036

6

R64

76

1

24.8

core

sill

blac

k si

licifi

ed p

orph

yry

sill,

late

dk

red-

brow

n sp

-py-

ga a

nd q

z-cb

vei

nlet

s,

R

1536

26

C

00-0

369

R

6476

135

.9

co

re

si

ll

si

-se

qz-fp

-por

phyr

y si

ll cu

t by

qz-c

b+(s

p-ga

-py

) vei

ns +

tan

sp-g

a-py

vei

ns

R,P

D,1

TS,P

B,X

RF

glas

s

Uni

v. T

as.

fie

ld id

.

hole

id.

de

pth

sa

mpl

e un

it

sam

ple

desc

riptio

n

c

atal

ogue

d m

ater

ials

ca

talo

gue

(m)

type

Appendix 1: Sample Catalogue

4

1536

27

C

00-0

371

R

5802

90

c

ore

f

w

s

e-si

aug

en s

chis

t

R

,1TS

,PB

1536

28

C

00-0

372

R

5802

108

.5

co

re

ts

v

cl

-se

alte

red

sand

ston

e/sh

ale

(with

in p

eper

itic

porp

hyry

?), f

g di

ss. p

y

R

,PD

,1TS

,PB

,XR

F gl

ass

1536

29

C

00-0

374

R

5802

175

.6

co

re

ts

v

ba

nded

bar

itic

sand

ston

e/m

ass.

ba,

fp c

ompo

nent

, ove

rlies

sill,

min

or p

y

R

,1TS

15

3630

C00

-037

5

R58

02

1

76.2

core

tsv

band

ed b

a cu

t by

red/

met

allic

pyr

agyr

ite v

ein

R,1

TS

1536

31

C

00-0

378

1

31R

12

59.1

c

ore

t

sv

fg

si-s

e sc

hist

, min

or d

iss.

tan

sp-g

a-py

R,P

D,1

TS,P

B,X

RF

glas

s 15

3632

C00

-037

9

R68

47

1

cor

e

tsv

dk g

reen

cl-s

e sc

hist

, ban

d of

red-

brow

n sp

-py,

10%

dis

s. p

y in

sch

ist

R

,PD

,1TS

,PB

,XR

F gl

ass

1536

33

C

00-0

381

R

6847

6.7

c

ore

t

sv

br

ecci

ated

se-

si s

chis

t, m

atrix

mas

s. ta

n/re

d br

own

sp-g

a-py

, ear

ly?

cg g

a-sp

-py-

cpy R

,PD

,1TS

,PB

,XR

F gl

ass

1536

34

C

00-0

383

R

6847

12.

3

c

ore

o

re

fg

ban

ded

mas

s. ta

n sp

-py-

ga

R

,PD

,1TS

,PB

,XR

F gl

ass

1536

35

C

00-0

385

R

6847

17.

6

c

ore

o

re

fg

diff

usel

y ba

nded

- m

ass.

tan

sp-g

a-py

R

,PD

,1TS

,PB

,XR

F gl

ass

1536

36

C

01-0

397

R

5192

-D1

631.

7

cor

e

ore

mas

s. b

ande

d ta

n sp

-min

or g

a-py

-cpy

, cla

stic

fp c

ompo

nent

R

,1TS

15

3637

C01

-040

0

R51

92-D

1 64

9

c

ore

b

a

m

ass.

ban

ded

ba, m

inor

py-

se

R

,1TS

15

3638

C01

-041

2

R59

75

2

01.9

core

tsv

ba v

ein/

band

with

sp-

ga s

elva

ges

in s

ilici

fied

shal

e/ch

ert

R,1

TS

1536

39

C

01-0

422

R

6298

74.

9

c

ore

o

re

m

ass.

fg p

y in

si-s

e sc

hist

R,1

TS

1536

40

C

01-0

423

R

6298

78.

8

c

ore

o

re

m

ass.

fg p

y w

ith w

hite

cb

fleck

s, re

lict p

orph

yriti

c te

xtur

e?

R

,1TS

15

3641

C01

-042

8

R62

97

7

3.3

cor

e

fw

fg

pale

blu

e-gr

een

se-c

l-si s

chis

t, m

g/cg

san

dsto

ne

R,P

D,C

R,1

TS,X

RF

glas

s 15

3642

C01

-044

3

R60

11

3

62

core

ore

d

k ta

n sp

-ga-

py w

ith s

i-se

and

ba c

last

s, lo

oks

high

ly fo

liate

d

R

,1TS

15

3643

C01

-046

5

R72

51

3

6

cor

e

ore

collo

form

py

vei

n in

of s

i-alte

red

sedi

men

ts w

ith o

rang

e sp

-py

ore

R

,1TS

15

3644

C01

-047

7

R62

17

1

13.2

core

tsv

se-s

i sch

ist,

mg/

cg c

last

ic s

ands

tone

with

qz,

inte

rest

ing

py te

xtur

es

R,1

TS

1536

45

C

01-0

495

R

5192

379

.3

co

re

fw

fg

se-s

i sch

ist w

ith c

b bl

ebs,

trac

e di

ss. p

y-ga

R,2

TS

1536

46

C

01-0

506

R

6335

247

.9

co

re

fw

blu

e-gr

ey, f

g se

-si s

chis

t

R,P

D,C

R,X

RF

glas

s 15

3647

C01

-050

8

R63

35

2

72.2

core

fw

s

e-si

sch

ist,

py v

ein

and

trace

sp

R

,PD

,XR

F gl

ass

1536

48

C

01-0

509

R

6335

303

.3

co

re

fw

se-

si s

chis

t/fp

xsta

l san

dsto

ne

R

,PD

,CR

,XR

F gl

ass

1536

49

C

01-0

532

R

6203

-D1

402

cor

e

fw

blu

e-gr

een

se-s

i-cl s

chis

t, m

inor

cpy

-py

in q

z-cl

vei

nlet

s

R,P

D,C

R,X

RF

glas

s 15

3650

C01

-054

7

R53

84

1

91.4

core

ore

m

ass.

ban

ded

py-s

p w

ith re

lict c

last

ic fp

R

,1TS

15

3651

C01

-054

8

R53

84

2

06.6

core

TSV

m

ass.

ba

vein

, int

ense

cb-

se-s

i alte

red

base

of t

urbi

dite

uni

t

R

,1TS

15

3652

C01

-054

9

R53

84

2

45.5

core

ba

m

ass.

ban

ded

ba, m

inor

pal

e sp

-ga,

R

15

3653

C01

-055

0

R53

84

2

54.6

core

ba

b

ande

d su

gary

ba,

min

or g

a-sp

R

1536

54

C

01-0

556

R

5827

227

.5

co

re

ba

mas

s. m

ottle

d ba

+ p

ale

sp-g

a w

ith s

e sc

hist

frag

men

ts (b

recc

ia)

R,2

TS

1536

55

C

01-0

557

R

5827

241

.7

co

re

ba

ban

ded

ba, m

inor

sp-

ga

R,1

TS

1536

56

C

01-0

558

R

5827

289

co

re

ba

mot

tled

ba o

re a

nd s

e sc

hist

(bre

ccia

), pa

le s

p-ga

R

1536

57

C

01-0

561

R

5827

657

.4

co

re

or

e

cl s

chis

t with

sul

phid

e st

ockw

ork,

cpy

-py-

po (D

ev. m

etas

.)

R

,1TS

15

3658

C01

-057

0

R68

03

5

0.5

cor

e

ore

mas

s. p

y-sp

-ga,

min

or b

a cl

asts

, lam

inat

ed +

fp g

rain

s

R

1536

59

C

01-0

574

R

6804

81.

3

c

ore

t

sv

lt

grey

si s

chis

t/che

rt, p

re-d

efor

mat

ion?

dk

grey

qz

vein

s

R

,PD

,1TS

,XR

F gl

ass

1536

60

C

01-0

575

R

6804

75.

5

c

ore

o

re

se

-si c

last

s? in

mas

s. p

ale

sp-g

a-py

+ fp

gra

ins

R

,1TS

15

3661

C01

-057

8

R68

04

6

7.7

cor

e

ore

fg la

min

ated

se

schi

st, p

ale

sp-g

a-py

with

si-s

e cl

asts

?

R

1536

62

C

01-0

579

R

6804

57.

7

c

ore

t

sv

se

-si s

chis

t afte

r mg

feld

spat

hic

sand

ston

e, tr

ace

fg d

iss.

py

R,P

D,C

R,X

RF

glas

s 15

3663

C01

-058

0

R68

04

4

7.5

cor

e

ore

mas

s. p

ale

sp-g

a-py

, min

or s

e-si

cla

sts,

gre

y fp

gra

ins

R

Uni

v. T

as.

fie

ld id

.

hole

id.

de

pth

sa

mpl

e un

it

sam

ple

desc

riptio

n

c

atal

ogue

d m

ater

ials

ca

talo

gue

(m)

type

Appendix 1: Sample Catalogue

5

1536

64

C

01-0

581

R

6804

40.

4

c

ore

t

sv

gr

ey s

e-si

-(cl

) sch

ist,

diss

. pal

e sp

-ga-

py

R,P

D,C

R,X

RF

glas

s 15

3665

C01

-058

2

R68

05

6

9.5

cor

e

ore

sem

i-mas

s. p

y-sp

-ga

in s

i-se

schi

st &

qz-

cb v

eins

R

1536

66

C

01-0

586

R

6805

31.

2

c

ore

o

re

se

mi-m

ass.

/dis

s. p

y-ta

n sp

-ga

in c

l-se

schi

st

R

1536

67

C

01-0

587

R

6805

5.4

c

ore

f

w

s

e-si

-(cl)

auge

n sc

hist

, lar

ge a

spy

crys

tal

R,P

D,C

R,X

RF

glas

s 15

3668

C01

-058

8

R68

04

2

6.9

cor

e

tsv

grey

si s

chis

t, dk

gre

y pr

e-de

form

atio

n? q

z ve

ins,

dis

s. p

y

R

,PD

,CR

,XR

F gl

ass

1536

69

C

01-0

589

R

6804

20.

2

c

ore

t

sv

lt

grey

si-s

e sc

hist

with

vei

ns/b

ands

ba

and

tan

sp-g

a-py

R

,PD

,CR

,XR

F gl

ass

1536

70

C

01-0

592

R

6806

56.

9

c

ore

o

re

m

ass.

tan

sp-g

a-py

ore

, diff

use

lam

inat

ions

R

15

3671

C01

-059

4

R68

06

4

3.8

cor

e

ore

mas

s. ta

n sp

-py-

ga w

ith fp

gra

ins

R,1

TS

1536

72

C

01-0

596

R

6806

34.

6

c

ore

o

re

m

ass.

tan

sp-p

y-ga

, diff

use

lam

inat

ions

R

15

3673

C01

-059

7

R68

06

2

9

cor

e

ore

sem

i-mas

s.-m

ass.

py

(+ta

n sp

-ga)

in c

l-se

schi

st

R

1536

74

C

01-0

600

R

6889

19.

4

c

ore

t

sv

si

-se

schi

st, d

iss.

sp-

ga-p

y

R

,PD

,XR

F gl

ass

1536

75

C

01-0

645

R

6902

104

co

re

ts

v

fg

ligh

t gre

en q

z-ph

yric

san

dsto

ne s

e-cl

alte

red

R

,PD

,CR

,XR

F gl

ass

1536

76

C

01-0

651

R

6901

64.

3

c

ore

f

w

d

k gr

ey-b

lack

cl-s

e-si

sch

ist &

~10

% p

y

R,1

TS

1536

77

C

01-0

656

R

6901

83.

7

c

ore

o

re

m

ass.

tan

sp-g

a-py

R

1536

78

C

01-0

658

R

6901

89.

2

c

ore

t

sv

m

ass.

fg p

y ve

in in

mas

s. c

b

R,1

TS

1536

79

C

01-0

662

R

6901

115

.1

co

re

ba

mas

s. b

ande

d ba

R

15

3680

C01

-066

3

R69

01

1

20.7

core

ore

m

ass.

py

vein

, min

or w

hite

ba

R

1536

81

C

01-0

665

R

6901

131

.6

co

re

ts

v

pa

le g

reen

fg q

z ph

yric

sed

imen

t

R

,PD

,CR

,1TS

,XR

F gl

ass

1536

82

C

01-0

698

R

5387

15.

9

c

ore

f

w

s

e-si

aug

en s

chis

t with

cl p

seud

ofia

mm

e

R

,PD

,CR

,XR

F gl

ass

1536

83

C

01-0

699

R

5387

77.

3

c

ore

f

w

b

lue-

grey

se-

si s

chis

t with

Fe-

Mn

cb fl

ecks

afte

r fp

R

,PD

,CR

,XR

F gl

ass

1536

84

C

01-0

700

R

5387

106

co

re

fw

fg

blue

-gre

y se

-si-(

cl) s

chis

t with

stro

ng fo

liatio

n

R,P

D,C

R,X

RF

glas

s 15

3685

C01

-070

2

R53

87

1

30.9

core

fw

d

k gr

ey s

e-cl

-si s

chis

t

R

,PD

,CR

,XR

F gl

ass

1536

86

C

01-0

705

R

5387

155

.7

co

re

fw

mot

tled

grey

se-

si s

chis

t with

bar

itic

vein

lets

/sto

ckw

ork

R

,1TS

15

3687

C01

-070

7

R53

87

1

57.9

core

ba

m

ass.

ban

ded

py-b

a

R

1536

88

C

01-0

713

R

5824

255

.9

co

re

fw

fg

grey

se-

si s

chis

t with

cb/

se fl

ecks

afte

r fp,

trac

e fg

dis

s. p

y

R

,PD

,CR

,XR

F gl

ass

1536

89

C

01-0

717

R

5824

317

.1

co

re

fw

mas

s. p

y, m

inor

sp-

ga w

ith d

k gr

ey fp

in s

i-alte

red

schi

st

R,1

TS

1536

90

C

01-0

718

R

5824

318

.3

co

re

fw

mas

s. p

y ve

ins

in s

i sch

ist (

collo

form

?)

R

,1TS

15

3691

C01

-072

0

R58

24

3

24.7

core

ore

m

ass.

py,

min

or s

p-ga

R

1536

92

C

01-0

724

R

5824

340

.7

co

re

ba

mas

s. b

ande

d ba

min

or s

p-ga

-py

+ la

ter p

y ve

in

R

1536

93

C

01-0

740

R

5824

494

.6

co

re

ts

v

fg

se-

si s

chis

t with

pre

-def

orm

atio

n qz

-py

vein

R,1

TS

1536

94

C

01-0

743

R

5824

523

.8

co

re

ts

v

fg

se-

si s

chis

t with

pre

-def

orm

atio

n qz

-py

vein

R,1

TS

1536

95

C

01-0

758

R

6052

272

.1

co

re

or

e

mas

s. ta

n sp

-ga-

py +

ba,

fp g

rain

s

R

15

3696

C01

-075

9

R60

52

2

77.9

core

ba

s

emi-m

ass.

ba

in s

e-si

sch

ist

R

1536

97

C

01-0

776

R

6055

319

.3

co

re

ts

v

dk

gre

en c

l-sch

ist +

cpy

-py

vein

lets

(Dev

. met

as.)

R,1

TS

1536

98

C

01-0

794

R

7467

35

c

ore

o

re

m

ass.

sp-

py-g

a-cp

y

R,P

B

1536

99

C

01-0

795

R

7467

41.

2

c

ore

o

re

m

ass.

py-

sp-g

a-cp

y

R,P

B

1537

00

C

01-0

797

R

7467

46.

4

c

ore

o

re

m

ass.

sp-

ga-p

y

R,P

B

Uni

v. T

as.

fie

ld id

.

hole

id.

de

pth

sa

mpl

e un

it

sam

ple

desc

riptio

n

c

atal

ogue

d m

ater

ials

ca

talo

gue

(m)

type

Appendix 1: Sample Catalogue

6

1537

01

C

01-0

799

R

7467

51.

4

c

ore

o

re

m

ass.

rem

obili

sed

sp-g

a-py

R

,PB

15

3702

C01

-080

1

R74

89

2

7.2

cor

e

fw

dis

s. p

y in

si-s

e-cl

sch

ist

R

,PB

15

3703

C01

-080

2

R74

89

2

9.5

cor

e

fw

dis

s. s

p-py

in s

i-se-

cl s

chis

t

R,P

B

1537

04

C

01-0

803

R

7489

34.

7

c

ore

o

re

m

ass.

ban

ded

py-s

p-ga

R,P

B

1537

05

C

01-0

804

R

7489

36.

7

c

ore

t

sv

m

ass.

py-

sp in

mas

s. c

b

R,P

B

1537

06

C

01-0

807

R

7489

41.

8

c

ore

o

re

m

ass.

sp-

ga-p

y

R,P

B

1537

07

C

01-0

808

R

7407

13.

4

c

ore

f

w

q

z-cb

-cl-s

ulph

ide

vein

(Dev

onia

n) in

si-s

e au

gen

schi

st

R,1

TS,P

B 15

3708

C01

-080

9

R74

07

4

6.2

cor

e

ore

mas

s. ta

n sp

-ga-

py

R

,PB

15

3709

C01

-081

0

R74

07

4

9

cor

e

ore

sem

i-mas

s. p

y-sp

-ga

in s

e-cl

sch

ist

R

,PB

15

3710

C01

-081

1

R74

07

5

3.5

cor

e

ore

mas

s. p

y-sp

-ga

R

,PB

15

3711

C01

-081

2

R74

07

5

5.8

cor

e

ore

mas

s. ta

n sp

-ga-

py in

si-c

l sch

ist

R,P

B

1537

12

C

01-0

813

R

7407

57.

7

c

ore

o

re

m

ass.

tan

sp-g

a-py

R,P

B

1537

13

C

01-0

814

R

7394

55.

8

c

ore

f

w

d

iss.

py

in s

e-si

sch

ist

R,P

B

1537

14

C

01-0

815

R

7394

60.

1

c

ore

o

re

m

ass.

red-

bn s

p-py

R,P

B

1537

15

C

01-0

817

R

7394

70.

8

c

ore

t

sv

di

ss. p

y-sp

in s

i-se

schi

st

R,P

B

1537

16

C

01-0

818

R

7394

74.

9

c

ore

o

re

m

ass.

red-

bn s

p-ga

-py

R,P

B

1537

17

C

01-0

820

R

7394

83.

1

c

ore

o

re

m

ass.

tan

sp-g

a-py

R,P

B

1537

18

C

01-0

822

R

7394

91.

1

c

ore

o

re

m

ass.

red-

bn s

p-ga

-py

R,P

B

1537

19

C

01-0

823

R

7455

51.

8

c

ore

f

w

g

rey

si-s

e sc

hist

+ d

iss.

py

R,P

B

1537

20

C

01-0

824

R

7455

70.

5

c

ore

t

sv

bl

ack

cl-s

e sc

hist

+ p

y-cp

y

R

,PB

15

3721

C01

-082

5

R74

55

8

3.7

cor

e

ore

mas

s. re

d-bn

sp-

ga-p

y

R

,PB

15

3722

C01

-082

6

R74

55

9

0.2

cor

e

ore

mas

s.dk

tan

sp-g

a-py

+ c

b bl

ebs

R,P

B

1537

23

C

01-0

828

R

7455

101

.1

co

re

or

e

m

ass.

dk ta

n sp

-py

band

ed o

re

R

,PB

15

3724

C01

-083

0

R74

55

1

11.5

core

ore

m

ass.

tan

sp-g

a-py

R,P

B

1537

25

C

01-0

832

R

7455

121

.9

co

re

or

e

mas

s. h

oney

-bn

sp-g

a-py

R

,PB

15

3726

C01

-083

3

R69

32

1

02.5

core

fw

v

eins

/dis

s. c

py-p

y-sp

in s

i-se

schi

st

R

,PB

15

3727

C01

-083

4

R69

32

1

11.4

core

ore

m

ass.

tan

sp-g

a-py

/si-s

e sc

hist

R,P

B

1537

28

C

01-0

835

R

6932

115

co

re

or

e

mas

s. ta

n sp

-ga-

py/s

i-se

schi

st -

mot

tled

R,P

B

1537

29

C

01-0

836

R

6932

120

.1

co

re

or

e

mas

s. ta

n sp

-ga-

py

R

,PB

15

3730

C01

-083

8

R69

32

1

27.3

core

ore

m

ass.

sp-

ga-p

y

R,P

B

1537

31

C

01-0

840

1

23R

14

52

c

ore

o

re

m

ass.

tan

sp-g

a-py

R,P

B

1537

32

C

01-0

841

R

6978

96.

7

c

ore

o

re

m

ass.

tan

sp-g

a-py

R,P

B

1537

33

C

01-0

842

R

6978

99.

5

c

ore

o

re

m

ass.

ba-

py (p

y ov

erpr

ints

?)

R,P

B

1537

34

C

01-0

844

R

6978

103

.3

co

re

or

e

mas

s. b

ande

d ta

n sp

-ga-

py

R

,PB

15

3735

C01

-084

6

R53

14

3

5.8

cor

e

ore

mas

s. p

y-sp

-ga-

po n

ear q

z-to

vei

n in

J-L

ens

(Dev

. met

as.)

R

,PB

15

3736

C01

-084

8

R53

14

4

1.8

cor

e

ore

mas

s. p

o-sp

-ga-

cpy-

py in

J-L

ens

(Dev

. met

as.)

R

,PB

15

3737

C01

-084

9

CP

-281

172

cor

e

-

to-s

ulph

ide

alte

red

rock

(Cha

mbe

rlain

pro

spec

t)

R,P

B

Uni

v. T

as.

fie

ld id

.

hole

id.

de

pth

sa

mpl

e un

it

sam

ple

desc

riptio

n

c

atal

ogue

d m

ater

ials

ca

talo

gue

(m)

type

Appendix 1: Sample Catalogue

7

1537

50

R

00-0

01

33K

x-c

ut -

north

face

1470

730

24

57

roc

k

or

e

ban

ded

mas

s. s

p-py

-ga,

late

py-

sp v

ein,

cl-s

e sc

hist

R

,1TS

,PB

1537

51

R

00-0

03

33K

x-c

ut -

north

face

1470

730

24

57

roc

k

or

e

ban

ded

mas

s. s

p-py

-ga,

late

py-

sp v

ein,

cl-s

e sc

hist

R

,1TS

,PB

1537

52

R

00-0

20

33K

- or

e dr

ive

14

90

7

33

2457

r

ock

ore

m

ass.

fg s

p-ga

ore

R

1537

53

R

01-0

49

31P

x-c

ut

9

72

780

25

10

roc

k

fa

ult

qz-

cb-c

py-p

y ve

ins

(faul

t) in

se-

si s

chis

t (P

6)

R

,PB

15

3754

R01

-064

39

P-P

10 o

re d

rive

1

080

1020

233

0

rock

sill

qz-p

hyric

por

phyr

y, s

hear

ed &

se-

si a

ltere

d

R,P

D,C

R,X

RF

glas

s 15

3755

R01

-065

38

P-P

10-o

re d

rive

north

109

0

10

20

2

345

ro

ck

o

re

m

ass.

py

with

fp g

rain

s &

mas

s. ta

n sp

-ga

R

,2TS

15

3756

R01

-070

M

urch

ison

Min

e

5

3765

40 3

8567

0

-

rock

ore

mas

sive

sp-

cb w

ith m

inor

cpy

(Dev

onia

n)

R

,PB

15

3757

R01

-075

S

alis

bury

pro

spec

t

5371

750

3777

40

-

rock

ore

goss

anou

s py

-si-t

o al

tere

d ro

ck

R,P

B

1537

58

R

01-0

78

Sou

th C

omet

min

e

5361

530

3710

60

-

rock

ore

mas

s. b

ande

d sp

-py

ore,

(Dev

onia

n) fi

ssur

e ho

sted

R

,PB

15

3759

R02

-081

37

P -

1020

N x

cut,

N fa

ce

10

25

1

025

2380

r

ock

ore

m

assi

ve b

ande

d sp

-ga-

py o

re P

13

R

15

3760

R02

-082

no

rther

n ex

plor

atio

n de

clin

e 1

860

900

23

60

roc

k

si

ll

qz-

fp p

orph

yry

dyke

/sill

- in

trusi

ve x

-cut

s fo

otw

all

R,P

D,C

R,X

RF

glas

s

Uni

v. T

as.

fiel

d id

. lo

catio

n

n

orth

east

R

L

sa

mpl

e u

nit

de

scrip

tion

cat

alog

ued

mat

eria

ls

cata

logu

e

typ

e

1537

38

C

02-0

852

1

12R

-D3

10

91

c

ore

f

w

s

e-si

-py

alte

red,

rhyo

litic

aph

yric

/fp-p

hyric

pep

eriti

c in

trusi

ve -

sth

end

of m

ine

R

,PD

,CR

,XR

F gl

ass

1537

39

C

02-0

854

R

7683

14

c

ore

f

w

q

z-fp

por

phyr

y un

it - x

-cut

s fo

otw

all a

nd jo

ins

K-le

ns p

orph

yry?

R

,PD

,CR

,XR

F gl

ass

1537

40

C

02-0

858

R

7128

4

c

ore

f

w

s

e-al

tere

d si

ltsto

ne -

diss

. sul

phid

e

R

1537

41

C

02-0

859

R

7128

7

c

ore

o

re

qz

-alte

red

sedi

men

t - s

emi-m

assi

ve s

ulph

ide

R

1537

42

C

02-0

860

R

7128

12

c

ore

o

re

m

ass.

pal

e sp

-ga

R

1537

43

C

02-0

861

R

7128

18

c

ore

o

re

se

-alte

red

sedi

men

t + d

iss.

sp-

ga-p

y

R

15

3744

C02

-086

2

R71

28

3

0

cor

e

tsv

qz-c

b al

tere

d qz

-fp p

orph

yry

R

15

3745

C02

-086

3

R71

28

3

5

cor

e

ore

mas

sive

ora

nge

brow

n sp

-ga

R

1537

46

C

02-0

864

R

7128

36.

5

c

ore

o

re

ba

ritic

qz-

se a

ltere

d se

dim

ent

R

1537

47

C

02-0

866

R

7128

60

c

ore

t

sv

cb

alte

red

sedi

men

t, di

ssem

inat

ed s

ulph

ide

R

15

3748

C02

-086

7

R71

28

6

7

cor

e

ore

mas

sive

pin

k cb

- sp

-ga-

py

R

15

3749

C02

-086

8

R71

28

6

8

cor

e

ore

sem

i-mas

sive

ora

nge-

brow

n sp

-ga

R

Uni

v. T

as.

fie

ld id

.

hole

id.

de

pth

sa

mpl

e un

it

sam

ple

desc

riptio

n

c

atal

ogue

d m

ater

ials

ca

talo

gue

(m)

type

Not

e: fi

eld

num

bers

util

ised

in th

e m

ain

text

hav

e be

en a

bbre

viat

ed (e

.g. C

00-2

93 =

C29

3 et

c.)

R =

rock

, PD

=pol

ishe

d re

sin

mou

nt, T

S=t

hin

sect

ion,

CR

=cru

shed

resi

due,

XR

F gl

ass=

XR

F gl

ass

disk

8

Appendix 2: Whole Rock Analyses

Appendix 2 Whole Rock Analysis

9

Appendix 2: Whole Rock Analyses

XR

F Si

O2

TiO

2 A

l2O

3 Fe

2O3

MnO

M

gO

CaO

N

a2O

K

2O

P2O

5 S

Ag

As

Ba

Bi

Cd

w

t(%)

wt(%

) w

t(%)

wt(%

) w

t(%)

wt(%

) w

t(%)

wt(%

) w

t(%)

wt(%

) w

t(%)

(ppm

) (p

pm)

(ppm

) (p

pm)

(ppm

) C

00-2

78

64.6

5 0.

33

15.0

0 6.

09

1.45

1.

52

0.13

<0

.1

4.79

0.

04

2.17

2

18

1205

4

8 C

00-2

80

84.9

5 0.

10

5.02

3.

84

0.03

0.

29

<0.0

2 <0

.1

1.77

<0

.01

3.37

3

42

516

9 21

C

00-2

84

15.5

1 0.

02

0.60

20

.21

0.18

0.

15

0.04

0.

2 0.

16

0.02

32

.83

56

131

50

74

703

C00

-285

50

.28

0.30

14

.21

8.19

4.

93

4.35

0.

39

<0.1

3.

54

0.06

2.

46

1 4

833

4 76

C

00-2

87

12.6

0 0.

16

3.56

17

.83

0.76

0.

24

0.26

<0

.1

1.24

0.

14

27.0

2 22

1 24

6 44

0 <4

54

1 C

00-2

90

5.86

0.

08

1.79

10

.39

0.16

0.

08

0.21

0.

2 0.

54

0.03

28

.86

265

1149

65

62

66

975

C00

-297

42

.54

0.44

12

.36

9.86

1.

14

0.86

0.

16

<0.1

4.

18

0.10

12

.58

17

430

2468

35

27

3 C

00-2

99

4.11

0.

04

0.09

5.

41

0.11

<0

.1

0.02

0.

5 0.

06

0.02

27

.07

473

562

2628

58

11

43

C00

-301

63

.54

0.48

14

.92

2.96

0.

06

0.96

0.

08

<0.1

5.

10

0.06

3.

98

65

43

4740

<3

93

C

00-3

06

63.4

8 0.

46

13.6

4 2.

90

0.06

0.

90

0.04

<0

.1

4.58

0.

04

4.58

10

5 13

9 59

12

<3

102

C00

-307

59

.64

0.28

6.

68

5.72

0.

08

0.50

0.

04

<0.1

2.

26

<0.0

1 10

.75

20

139

1583

<3

11

9 C

00-3

17

32.9

6 0.

44

10.3

8 7.

06

0.72

1.

10

1.14

0.

2 3.

66

0.08

14

.63

304

218

5336

<4

36

6 C

00-3

20

58.7

0 0.

18

8.18

17

.48

0.04

0.

42

0.06

<0

.1

2.88

0.

02

14.6

9 6

77

1680

22

1

C00

-323

65

.20

0.18

9.

06

6.72

0.

16

0.38

0.

06

<0.1

3.

06

<0.0

1 8.

22

22

15

984

67

155

C00

-326

7.

76

0.22

5.

14

15.1

0 2.

58

1.02

0.

28

0.2

1.50

0.

08

23.5

4 31

0 99

5 64

2 <4

65

6 C

00-3

29

43.6

0 0.

14

3.82

6.

84

0.10

0.

14

<0.0

2 <0

.1

1.32

<0

.01

14.6

9 52

7 59

8 44

0 <4

36

6 C

00-3

33

30.5

4 0.

46

21.7

2 14

.46

1.24

2.

92

0.14

<0

.1

5.82

0.

06

9.19

2

6 16

32

9 19

1 C

00-3

37

17.8

5 0.

04

0.68

12

.17

0.17

<0

.1

<0.0

2 0.

3 0.

25

0.02

27

.64

419

316

543

60

803

C00

-341

14

.89

0.04

0.

14

6.26

0.

22

<0.1

0.

84

0.3

0.04

0.

02

24.4

2 53

7 10

77

38

12

871

C00

-343

19

.76

0.52

14

.32

25.3

4 6.

06

0.60

0.

54

<0.1

4.

66

0.12

18

.85

21

220

2640

38

11

6 C

00-3

45

22.1

0 0.

10

2.56

16

.96

1.18

0.

64

0.10

0.

1 0.

90

<0.0

1 19

.72

952

2860

27

71

12

588

C00

-350

19

.26

0.50

13

.54

25.7

0 2.

52

1.06

0.

42

<0.1

4.

48

0.12

24

.42

71

168

5019

14

7 19

1 C

00-3

53

13.7

1 0.

26

5.87

31

.29

2.62

1.

62

4.01

0.

7 1.

58

0.02

29

.93

766

598

3965

42

15

3 C

00-3

55

76.3

1 0.

19

8.62

6.

22

0.05

0.

44

0.02

<0

.1

2.99

0.

01

4.82

4

21

1040

6

3 C

00-3

57

77.1

8 0.

11

5.95

6.

50

0.14

0.

41

0.08

<0

.1

2.11

<0

.01

5.57

29

59

12

27

60

29

C00

-359

9.

70

0.08

0.

65

11.5

2 0.

32

0.47

0.

79

0.4

0.22

0.

02

31.7

9 63

29

4 18

35

46

1183

C

00-3

62

49.3

4 0.

04

0.50

5.

80

0.22

0.

10

2.34

<0

.1

0.10

<0

.01

15.1

6 33

9 29

7 10

6 <4

23

9 C

00-3

64

1.22

0.

02

0.10

18

.81

0.22

0.

40

1.97

0.

1 0.

02

0.02

33

.44

257

1533

<4

12

9 10

18

C00

-365

24

.23

0.02

0.

21

34.4

1 0.

03

0.11

0.

16

<0.1

0.

05

0.01

32

.61

101

554

22

31

269

C00

-369

65

.52

0.28

9.

60

7.56

0.

04

0.36

0.

54

<0.1

5.

28

0.06

6.

85

37

113

2636

<3

70

C

00-3

72

42.2

4 0.

69

20.8

3 16

.11

0.07

1.

49

0.14

0.

04

7.63

0.

12

12.1

6 3

3500

29

58

<2

1 C

00-3

78

68.4

7 0.

44

14.2

3 3.

80

0.25

1.

21

0.09

<0

.1

4.60

0.

08

2.32

9

27

1811

<3

31

C

00-3

79

22.2

2 0.

50

14.7

8 26

.84

2.40

1.

60

0.28

<0

.1

4.62

0.

12

21.8

3 17

14

5 31

84

37

126

C00

-381

20

.12

0.26

8.

24

16.1

0 0.

10

0.52

<0

.02

<0.1

2.

84

0.02

23

.74

101

336

3754

<4

44

2 C

00-3

83

5.19

0.

04

0.72

8.

32

0.18

0.

13

0.24

0.

4 0.

25

0.03

28

.68

319

732

1212

23

95

9 C

00-3

85

8.67

0.

06

0.62

6.

36

0.31

0.

30

1.52

0.

2 0.

32

0.04

25

.45

703

778

1692

6 57

96

8

10

Appendix 2: Whole Rock Analyses

XR

F C

o C

u M

o N

b N

i Pb

R

b Sb

Se

Sn

Sr

Th

Tl

Y

Zn

Zr

(p

pm)

(ppm

) (p

pm)

(ppm

) (p

pm)

(ppm

) (p

pm)

(ppm

) (p

pm)

(ppm

) (p

pm)

(ppm

) (p

pm)

(ppm

) (p

pm)

(ppm

) C

00-2

78

21

521

2 15

5

66

232

3 <2

<2

12

22

9

48

4200

26

5 C

00-2

80

92

691

2 4

1 87

2 83

2

<2

<2

4 7

8 12

95

00

79

C00

-284

61

20

00

10

<2

11

1190

0 12

32

i/P

b n.

a.

<2

<3

i/Pb

<3

3485

00

8 C

00-2

85

25

40

<1

11

1 59

17

3 5

<2

2 9

22

6 40

34

600

242

C00

-287

27

18

00

24

<2

<3

1443

00

i/Pb

291

i/Pb

n.a.

5

i/Pb

i/Pb

i/Pb

2484

00

76

C00

-290

19

24

00

72

<2

17

1575

00

i/Pb

645

i/Pb

n.a.

52

i/P

b i/P

b i/P

b 38

0000

25

C

00-2

97

29

1600

11

4

<3

2200

0 20

5 27

i/P

b n.

a.

10

14

i/Pb

i/Pb

1252

00

196

C00

-299

18

27

00

27

<2

4 21

3200

i/P

b 22

10

i/Pb

n.a.

17

i/P

b i/P

b i/P

b 42

1700

C00

-301

33

50

8 3

6 3

2140

0 20

5 83

i/P

b <2

13

17

i/P

b i/P

b 41

200

240

C00

-306

37

66

0 6

5 <3

25

700

201

353

i/Pb

<2

10

20

i/Pb

i/Pb

4760

0 21

3 C

00-3

07

59

273

8 1

6 24

800

104

33

i/Pb

n.a.

4

10

i/Pb

i/Pb

1208

00

51

C00

-317

33

40

0 22

<2

58

10

7700

i/P

b 40

5 i/P

b n.

a.

46

i/Pb

i/Pb

i/Pb

1596

00

158

C00

-320

10

2 74

00

9 7

1 36

9 15

0 5

<2

3 6

12

5 12

20

3 14

8 C

00-3

23

56

2600

12

5

4 20

00

147

8 <2

n.

a.

6 11

12

23

67

000

154

C00

-326

16

44

00

18

<2

<3

1618

00

i/Pb

401

i/Pb

n.a.

8

i/Pb

i/Pb

i/Pb

2576

00

103

C00

-329

76

92

00

10

<2

<3

1269

00

i/Pb

863

i/Pb

n.a.

<2

i/P

b i/P

b i/P

b 15

8200

71

C

00-3

33

12

2400

12

11

<3

29

9 28

8 10

<2

n.

a.

14

34

14

43

9580

0 36

5 C

00-3

37

51

1000

11

<2

13

10

9800

i/P

b 77

5 i/P

b n.

a.

<2

i/Pb

i/Pb

i/Pb

3356

00

14

C00

-341

25

36

00

50

<2

15

1737

00

i/Pb

2004

i/P

b n.

a.

19

i/Pb

i/Pb

i/Pb

3626

00

4 C

00-3

43

34

6600

14

8

<3

1800

20

5 6

<2

n.a.

16

17

12

42

53

200

231

C00

-345

50

72

00

32

1 15

41

000

40

3230

i/P

b n.

a.

4 i/P

b i/P

b i/P

b 25

9400

47

C

00-3

50

27

4600

19

6

<3

9100

20

3 16

<2

n.

a.

12

i/Pb

i/Pb

i/Pb

8780

0 21

9 C

00-3

53

40

2400

39

5

<3

2270

0 80

22

51

i/Pb

n.a.

14

0 5

i/Pb

i/Pb

7320

0 15

5 C

00-3

55

79

1310

10

8

<3

527

137

3 <2

<2

6

12

7 17

97

0 14

7 C

00-3

57

76

204

8 5

<3

6300

10

6 4

3 <2

5

<3

i/Pb

15

8700

91

C

00-3

59

54

1400

24

<2

37

69

00

15

58

<2

n.a.

37

<3

i/P

b 6

4600

00

32

C00

-362

39

60

0 5

<2

<3

8870

0 i/P

b 62

9 i/P

b n.

a.

45

4 i/P

b i/P

b 18

1600

11

C

00-3

64

32

2000

29

<2

<3

10

3700

i/P

b 42

4 i/P

b n.

a.

14

i/Pb

i/Pb

i/Pb

3615

00

6 C

00-3

65

60

3800

8

<2

4 50

600

9 12

7 i/P

b n.

a.

3 i/P

b i/P

b i/P

b 10

5600

24

C

00-3

69

73

1200

56

5

5 42

00

122

59

<2

n.a.

57

13

10

24

29

400

125

C00

-372

18

16

36

16

5

178

308

34

<2

6 18

29

60

45

20

4 31

8 C

00-3

78

31

198

2 10

4

6300

18

9 15

<2

2

16

18

i/Pb

29

1520

0 20

9 C

00-3

79

28

5600

11

8

<3

1600

24

9 10

<2

n.

a.

12

17

33

37

5740

0 23

2 C

00-3

81

26

5800

8

<2

<3

1188

00

i/Pb

126

i/Pb

n.a.

9

i/Pb

i/Pb

i/Pb

1924

00

128

C00

-383

22

16

00

55

<2

13

1849

00

i/Pb

516

i/Pb

n.a.

7

i/Pb

i/Pb

i/Pb

3982

00

8 C

00-3

85

13

3600

30

<2

<3

17

4900

i/P

b 18

65

i/Pb

n.a.

13

3 i/P

b i/P

b i/P

b 36

9600

9

11

Appendix 2: Whole Rock Analyses

XRF

SiO

2 Ti

O2

Al2O

3 Fe

2O3

MnO

M

gO

CaO

N

a2O

K

2O

P2O

5 B

aO

S LO

I B

a C

u Pb

Sr

Zn

Zr

wt(%

) w

t(%)

wt(%

) w

t(%)

wt(%

) w

t(%)

wt(%

) w

t(%)

wt(%

) w

t(%)

wt(%

) w

t(%)

wt(%

) (p

pm)

(ppm

) (p

pm)

(ppm

) (p

pm)

(ppm

) C

00-1

43

58.5

0.

62

20.1

5 3.

86

0.15

2.

45

1.81

1.

33

4.93

0.

15

0.23

1.

23

5.35

21

00

<100

<2

00

147

200

258

C00

-144

54

.17

0.8

23.9

2 3.

55

0.21

1.

81

0.93

4.

05

4.83

0.

19

0.25

1.

86

4.66

22

00

<100

60

0 38

2 12

00

347

C00

-208

63

.98

0.47

13

.31

3.93

2.

6 1.

95

2.94

0.

21

3.35

0.

11

0.18

0.

15

6.67

16

00

<100

<2

00

63

300

215

C00

-346

66

.52

0.48

16

.79

1.42

0.

1 0.

65

2.06

3.

61

4.65

0.

12

0.29

0.

44

3.5

2600

<1

00

<200

13

4 40

0 21

2 C

01-4

28

67.0

3 0.

31

13.7

3 2.

47

0.6

5.21

2.

06

0.54

2.

82

0.05

0.

27

0.11

5.

5 24

00

<100

<2

00

73

200

245

C01

-506

71

.62

0.28

13

.05

1.83

0.

5 3.

15

1.1

0.08

3.

89

0.04

0.

1 0.

26

4.24

90

0 <1

00

<200

25

10

0 22

1 C

01-5

08

75.0

4 0.

21

6.62

0.

88

1.55

0.

67

5.38

0.

05

2.27

0.

06

0.13

0.

58

6.68

12

00

200

2200

10

9 52

00

96

C01

-509

63

.52

0.65

18

.11

2.99

0.

4 1.

25

0.55

0.

91

5.51

0.

15

1.07

2.

18

4.65

96

00

<100

<2

00

72

400

299

C01

-532

70

.64

0.29

13

.4

2.42

0.

13

3.66

1.

26

2.61

1.

82

0.04

0.

08

0.01

3.

59

700

<100

40

0 10

0 10

0 23

3 C

01-5

74

82.2

1 0.

32

8.16

1.

63

0.38

0.

71

0.45

0.

08

2.59

0.

04

0.58

1.

18

2.78

52

00

<100

1<

200

13

800

109

C01

-579

61

.73

0.69

18

.7

3.89

0.

54

1.27

0.

36

1.22

5.

56

0.15

0.

71

2.31

4.

6 64

00

<100

<2

00

28

300

302

C01

-581

72

.64

0.36

10

.22

4.12

0.

3 0.

56

0.35

0.

06

3.22

0.

1 0.

68

3.4

3.63

61

00

1400

13

00

9 26

600

119

C01

-587

73

.02

0.28

11

.85

1.55

0.

76

2.02

1.

7 0.

14

4.15

0.

04

0.22

0.

06

4.05

20

00

<100

20

0 56

20

0 21

4 C

01-5

88

35.4

9 0.

2 5.

6 2.

93

2.55

0.

66

9.01

0.

025

1.82

0.

03

17.7

9 6.

78

8.01

2E

+05

2700

48

00

3297

19

100

58

C01

-589

80

.21

0.21

9.

74

2.64

0.

04

0.52

0.

08

0.06

3.

22

0.03

0.

33

1.51

2.

53

3000

10

0 38

00

11

400

146

C01

-600

76

.26

0.21

11

.39

2.43

0.

04

0.62

0.

03

0.08

3.

85

0.03

0.

41

1.93

2.

83

3700

40

0 30

0 8

1590

0 12

7 C

01-6

98

71.9

6 0.

28

12.4

3 6.

7 0.

22

1.08

0.

1 0.

05

3.73

0.

05

0.21

0.

32

2.69

19

00

<100

<2

00

8 10

0 20

5 C

01-6

99

71.9

0.

3 12

.91

2.14

0.

36

2.23

1.

76

0.41

3.

75

0.05

0.

18

0.21

4.

05

1600

<1

00

<200

71

10

0 23

5 C

01-7

00

62.2

4 0.

38

16.2

2.

08

0.1

3.31

4.

65

1.43

3.

12

0.06

0.

21

0.01

6.

45

1900

<1

00

<200

23

6 <1

00

306

C01

-702

66

.77

0.36

16

.63

2.67

0.

15

4.83

0.

82

1.44

1.

79

0.05

0.

33

0.13

4.

32

3000

<1

00

<200

42

8 10

0 28

7 C

01-7

13

72.6

5 0.

28

12.4

1 1.

53

0.24

1.

89

2.51

0.

73

3.31

0.

04

0.17

0.

03

4.19

15

00

<100

<2

00

90

100

220

R01

-064

41

.68

0.5

18.0

3 7.

08

4.51

3.

09

4.43

1.

71

4.22

0.

11

1.89

2.

85

12.4

6 16

900

<100

10

0 10

0 30

0 24

8

12

Appendix 2: Whole Rock Analyses

XRF

SiO

2 Ti

O2

Al2

O3

Fe2O

3 M

nO

MgO

C

aO

Na2

O

K2O

P2

O5

BaO

LO

I to

tal

S B

a N

b Sc

V

Y Zr

w

t(%)

wt(%

) w

t(%)

wt(%

) w

t(%)

wt(%

) w

t(%)

wt(%

) w

t(%)

wt(%

) w

t(%)

wt(%

) w

t(%)

wt(%

) (p

pm)

(ppm

) (p

pm)

(ppm

) (p

pm)

(ppm

)

RO

2-08

2 68

.25

0.38

12

.9

2.85

0.

35

0.92

2.

81

1.37

5.

71

0.11

0.

21

3.92

99

.77

0.02

18

79

10.1

11

51

29

.1

170

CO

S-85

4 70

.37

0.43

14

.73

2 0.

09

0.49

1.

88

2.57

4.

41

0.12

0.

15

2.8

100.

03

0.07

13

47

11

10

58

22.3

19

6

CO

S-85

2 65

.03

0.4

16.4

4 3.

36

2.48

1.

49

0.42

0.

19

6.48

0.

06

0.33

3.

18

99.8

7 0.

36

3000

16

.8

9 18

46

.9

289

CO

O-0

91

74.6

1 0.

3 13

.71

2.01

0.

06

0.53

0.

45

4.3

2.28

0.

03

0.16

1.

09

99.5

3 <0

.01

1398

11

.6

6 13

27

.5

227

CO

O-0

92

70.8

5 0.

36

16.3

2.

26

0.08

0.

7 0.

54

4.09

3.

02

0.04

0.

2 1.

71

100.

13

0.01

17

62

14.9

6

14

29.6

27

6

CO

I-665

54

.37

0.98

26

.33

1.34

0.

04

1.49

0.

17

0.52

6.

69

0.13

4.

06

3.93

10

0.05

0.

52

3640

0 38

.3

15

123

33.8

45

4

CO

I-645

67

.91

0.58

15

.69

1.65

0.

19

2.43

1.

52

1.51

3.

34

0.07

1.

62

3.7

100.

2 0.

26

1450

0 19

.7

11

89

32.2

26

4

4 1

2 1.

5 1

1 de

tect

ion

limit(

ppm

)

Who

le ro

ck X

RF

anal

ysis

und

erta

ken

at D

epar

tmen

t of E

arth

Sci

ence

s - U

nive

rsity

of T

asm

ania

n.

a. -

not a

naly

sed

i/Pb

- int

erfe

renc

e fro

m h

igh

Pb c

onte

nt

13

Appendix 2: Whole Rock Analyses

ELEMENTS As Be Ga Ge In Rb Se Se Sn Te Tl U UNITS ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm DETECTION LIMIT 1 0.1 0.1 0.1 0.01 0.05 2 0.5 0.1 0.1 0.02 0.01 METHOD A/MS A/MS A/MS A/MS A/MS A/MS A/MS A/EMS A/MS A/MS A/MS A/MS C00-285 8 1.8 20.7 1.0 2.16 178.81 <2 0.8 3.3 0.1 5.92 4.09 C00-287 158 0.2 7.6 0.6 0.15 65.26 4 5.1 0.9 0.1 7.22 4.36 C00-290 728 0.1 15.9 2.2 0.74 24.02 6 7.1 0.8 0.1 24.19 5.29 C00-320 92 0.8 11.6 0.7 3.12 153.46 <2 1.0 1.9 0.1 4.51 3.25 C00-323 22 0.8 12.1 0.5 5.69 153.76 <2 1.6 4.2 0.1 10.61 3.34 C00-326 833 0.4 12.7 0.3 0.49 77.09 4 5.2 1.7 0.1 26.57 2.97 C00-329 430 0.3 8.7 13.7 0.16 47.42 2 3.7 4.6 0.1 11.07 5.48 C00-355 26 0.8 10.1 0.8 1.00 150.95 <2 <0.5 1.4 0.1 6.73 3.50 C00-357 69 0.7 8.3 1.0 2.93 112.55 <2 0.6 1.4 0.1 10.44 2.69 C00-359 311 0.4 20.6 3.5 158.53 13.87 8 10.9 18.7 0.1 11.90 11.36 C00-362 256 <0.1 2.5 18.4 0.10 3.75 4 4.5 0.8 0.1 7.67 0.86 C00-364 1224 <0.1 15.2 8.6 51.45 0.46 6 8.3 4.9 0.1 55.34 3.11 C00-365 473 <0.1 2.2 1.1 8.61 3.13 <2 2.5 1.0 0.1 15.64 1.32 C00-369 142 1.0 12.7 1.1 0.97 132.65 <2 0.6 1.8 0.1 10.19 4.00 C00-379 164 1.2 19.2 0.7 5.85 234.27 <2 1.6 2.6 0.1 31.96 5.53 C00-381 287 0.7 14.2 1.0 0.06 146.89 4 3.8 2.3 0.1 41.38 3.57 C00-383 500 <0.1 16.3 2.6 0.02 13.49 7 7.9 0.3 0.1 15.14 2.90 C00-385 555 <0.1 9.8 9.4 0.63 10.52 6 7.7 0.3 0.1 10.55 2.25 Laboratory : Genalysis Pty. Ltd. Job Code : 6.3/0306028 Client : Neil Martin Date : 17/10/2003

ELEMENTS Au Au-Rp1 Au-Rp2 UNITS ppm ppm ppm DETECTION LIMIT 0.01 0.01 0.01 METHOD FA/AAS FA/AAS FA/AAS C00-278 0.05 C00-280 0.13 C00-284 6.37 6.23 C00-285 0.06 C00-287 2.25 2.62 C00-290 2.57 C00-297 0.40 C00-299 3.42 C00-301 0.29 C00-306 0.77 C00-307 0.51 C00-317 0.67 C00-320 0.27 C00-323 0.17 C00-326 0.72 C00-329 2.50 C00-333 0.22 C00-337 4.31 3.53 C00-341 10.20 5.78 16.56 C00-343 0.29 C00-345 10.27 8.49 C00-350 0.56 C00-353 2.50 C00-355 0.10 C00-357 0.47 C00-359 2.16 1.93 C00-362 1.12 C00-364 5.94 0.87 4.10 C00-365 1.68 1.46 C00-369 1.93 2.38 C00-372 0.06 C00-378 0.04 C00-379 0.31 Laboratory : Genalysis Pty. Ltd. C00-381 0.90 Job Code : 6.3/0004693 C00-383 2.51 Client : Neil Martin C00-385 3.77 Date : 7/09/2000

Appendix 3: Microprobe Analysis—Silicates

14

Appendix 3 Microprobe Analysis

-Silicates

Appendix 3: Microprobe Analysis—Silicates

15 15

C08

7

chl1

cl

cl p

seud

ofia

mm

e - C

amb.

mat

rix 6

.17

0.01

4.

49

6.69

0

.48

1.

59

1.59

0.

04

0.09

0

.01

0.

00

0.0

0

0.05

2

8.00

19.

58 0

.81

C08

7

chl3

cl

cl p

seud

ofia

mm

e - C

amb.

mat

rix 5

.33

0.02

5.

46

6.40

0

.42

2.

23

2.23

0.

02

0.05

0

.00

0.

00

0.0

0

0.06

2

8.00

19.

92 0

.74

C08

7

chl4

cl

cl p

seud

ofia

mm

e - C

amb.

mat

rix 5

.31

0.02

5.

46

6.24

0

.44

2.

04

2.04

0.

02

0.39

0

.01

0.

00

0.0

0

0.07

2

8.00

19.

95 0

.75

C21

1

chl1

cl

mas

sive

cl-m

ag-s

p - D

ev. m

etas

.

m

etas

. 5.7

6 0.

02

4.52

8.

01

0.3

8

1.19

1.

19

0.00

0.

07

0.0

0

0.00

0

.00

0.

11

28.

00 1

9.96

0.8

7 C

211

ch

l2

cl

m

assi

ve c

l-mag

-sp

- Dev

. met

as.

met

as. 5

.81

0.00

4.

33

8.22

0

.32

1.

29

1.29

0.

01

0.01

0

.00

0.

00

0.0

0

0.02

2

8.00

20.

02 0

.86

C21

1

chl3

cl

mas

sive

cl-m

ag-s

p - D

ev. m

etas

.

m

etas

. 5.7

2 0.

03

4.57

7.

87

0.3

7

1.26

1.

26

0.00

0.

09

0.0

0

0.00

0

.01

0.

08

28.

00 1

9.95

0.8

6 C

211

ch

l4

cl

m

assi

ve c

l-mag

-sp

- Dev

. met

as.

met

as. 6

.05

0.04

3.

95

7.57

0

.21

1.

56

1.56

0.

01

0.49

0

.01

0.

00

0.0

1

0.3

2

8.00

19.

93 0

.83

C21

1

chl5

cl

mas

sive

cl-m

ag-s

p - D

ev. m

etas

.

m

etas

. 5.6

0 0.

01

4.80

7.

83

0.4

3

1.27

1.

27

0.00

0.

03

0.0

1

0.00

0

.00

0.

14

28.

00 1

9.99

0.8

6 C

247

cl

1

cl

c

l sch

ist -

in g

roun

dmas

s

m

atrix

5.7

2 0.

01

5.38

3.

58

0.2

5

4.61

4.

61

0.02

0.

00

0.0

0

0.01

0

.00

0.

28

28.

00 1

9.59

0.4

4 C

333

ch

l1

cl

cl

-se-

si s

chis

t in

grou

ndm

ass

mat

rix 5

.19

0.01

5.

60

5.60

0

.39

3.

18

3.18

0.

00

0.01

0

.01

0.

00

0.0

0

0.15

2

8.00

20.

00 0

.64

C33

3

chl3

cl

cl-s

e-si

sch

ist i

n gr

ound

mas

s

m

atrix

5.2

8 0.

02

5.47

5.

51

0.3

9

3.27

3.

27

0.00

0.

01

0.0

0

0.00

0

.00

0.

18

28.

00 1

9.96

0.6

3 C

333

ch

l4

cl

cl

-se-

si s

chis

t in

grou

ndm

ass

mat

rix 5

.19

0.01

5.

57

5.66

0

.38

3.

21

3.21

0.

01

0.00

0

.00

0.

00

0.0

0

0.17

2

8.00

20.

02 0

.64

C56

1

chl1

cl

cl-s

chis

t cpy

-py-

po -

C o

r D?

m

atrix

5.2

8 0.

01

5.34

4.

67

0.4

0

4.32

4.

32

0.00

0.

00

0.0

0

0.01

0

.00

0.

21

28.

00 2

0.04

0.5

2 C

561

ch

l2

cl

cl

-sch

ist c

py-p

y-po

- C

or D

?

mat

rix 5

.44

0.01

5.

02

4.39

0

.42

4.

72

4.72

0.

00

0.01

0

.01

0.

02

0.0

1

0.29

2

8.00

20.

04 0

.48

C56

1

chl3

cl

cl-s

chis

t cpy

-py-

po -

C o

r D?

m

atrix

5.3

0 0.

01

5.30

4.

54

0.4

1

4.45

4.

45

0.00

0.

00

0.0

0

0.00

0

.01

0.

18

28.

00 2

0.03

0.5

0 C

651

ch

l1

cl

cl

-sch

ist -

py -

Cam

b. -

belo

w P

-lens

m

atrix

5.2

8 0.

00

5.46

4.

59

0.3

5

4.27

4.

27

0.00

0.

00

0.0

1

0.01

0

.00

0.

21

28.

00 1

9.98

0.5

2 C

651

ch

l2

cl

cl

-sch

ist -

py -

Cam

b. -

belo

w P

-lens

m

atrix

5.2

9 0.

02

5.52

4.

55

0.3

5

4.18

4.

18

0.00

0.

01

0.0

0

0.00

0

.00

0.

23

28.

00 1

9.93

0.5

2 C

651

ch

l3

cl

cl

-sch

ist -

py -

Cam

b. -

belo

w P

-lens

m

atrix

5.2

8 0.

01

5.54

4.

67

0.4

1

4.01

4.

01

0.00

0.

00

0.0

1

0.00

0

.00

0.

19

28.

00 1

9.94

0.5

4 C

651

ch

l4

cl

cl

-sch

ist -

py -

Cam

b. -

belo

w P

-lens

m

atrix

5.3

5 0.

00

5.49

4.

55

0.3

4

4.17

4.

17

0.01

0.

00

0.0

0

0.00

0

.00

0.

16

28.

00 1

9.91

0.5

2 C

651

ch

l5

cl

cl

-sch

ist -

py -

Cam

b. -

belo

w P

-lens

m

atrix

5.3

2 0.

00

5.52

4.

56

0.3

3

4.16

4.

16

0.01

0.

00

0.0

0

0.00

0

.00

0.

19

28.

00 1

9.91

0.5

2 C

651

ch

l6

cl

cl

-sch

ist -

py -

Cam

b. -

belo

w P

-lens

m

atrix

5.3

3 0.

01

5.46

4.

42

0.3

6

4.32

4.

32

0.00

0.

01

0.0

0

0.00

0

.01

0.

27

28.

00 1

9.93

0.5

1 C

776

ch

l1

cl

cl

sch

ist -

cpy

,py

- pos

sibl

e D

ev. c

l?

mat

rix 5

.26

0.02

5.

45

5.66

0

.42

3.

15

3.15

0.

00

0.00

0

.00

0.

01

0.0

1

0.23

2

8.00

19.

99 0

.64

C77

6

chl2

cl

cl s

chis

t - c

py,p

y - p

ossi

ble

Dev

. cl?

m

atrix

5.2

5 0.

00

5.36

5.

72

0.4

5

3.29

3.

29

0.00

0.

00

0.0

0

0.00

0

.00

0.

24

28.

00 2

0.07

0.6

4 C

776

ch

l3

cl

cl

sch

ist -

cpy

,py

- pos

sibl

e D

ev. c

l?

mat

rix 5

.18

0.01

5.

51

5.60

0

.47

3.

27

3.27

0.

00

0.00

0

.00

0.

00

0.0

1

0.07

2

8.00

20.

05 0

.63

C77

6

chl4

cl

cl s

chis

t - c

py,p

y - p

ossi

ble

Dev

. cl?

m

atrix

5.1

5 0.

02

5.54

5.

59

0.4

6

3.28

3.

28

0.00

0.

01

0.0

0

0.00

0

.00

0.

16

28.

00 2

0.06

0.6

3 C

776

ch

l5

cl

cl

sch

ist -

cpy

,py

- pos

sibl

e D

ev. c

l?

mat

rix 5

.22

0.02

5.

46

5.70

0

.43

3.

16

3.16

0.

01

0.01

0

.01

0.

00

0.0

1

0.13

2

8.00

20.

03 0

.64

C80

8

chl1

cl

qz-c

b-cl

-sul

phid

e ve

in -

Dev

.

m

etas

. 5.3

6 0.

00

5.36

4.

98

0.3

2

3.89

3.

89

0.00

0.

00

0.0

0

0.00

0

.01

0.

19

28.

00 1

9.95

0.5

6 C

808

ch

l2

cl

qz

-cb-

cl-s

ulph

ide

vein

- D

ev.

met

as. 5

.35

0.00

5.

33

4.94

0

.35

3.

99

3.99

0.

00

0.00

0

.00

0.

00

0.0

0

0.2

2

8.00

19.

98 0

.55

C80

8

chl3

cl

qz-c

b-cl

-sul

phid

e ve

in -

Dev

.

m

etas

. 5.3

6 0.

01

5.36

5.

11

0.3

3

3.78

3.

78

0.00

0.

01

0.0

0

0.00

0

.00

0.

18

28.

00 1

9.95

0.5

7 C

808

ch

l4

cl

qz

-cb-

cl-s

ulph

ide

vein

- D

ev.

met

as. 5

.32

0.00

5.

39

4.95

0

.32

3.

97

3.97

0.

00

0.00

0

.01

0.

01

0.0

0

0.25

2

8.00

19.

98 0

.55

C80

8

chl5

cl

qz-c

b-cl

-sul

phid

e ve

in -

Dev

.

m

etas

. 5.3

9 0.

01

5.30

4.

89

0.3

3

4.01

4.

01

0.00

0.

00

0.0

0

0.00

0

.00

0.

17

28.

00 1

9.94

0.5

5 C

824

ch

l1

cl

bl

ack

cl-s

e sc

hist

+py-

cpy

- Cam

b. P

-lens

mat

rix 5

.29

0.01

5.

42

5.12

0

.26

3.

86

3.86

0.

00

0.00

0

.01

0.

01

0.0

1

0.28

2

8.00

19.

99 0

.57

C82

4

chl2

cl

blac

k cl

-se

schi

st+p

y-cp

y - C

amb.

P-le

ns m

atrix

5.3

0 0.

02

5.35

5.

10

0.2

7

3.93

3.

93

0.00

0.

01

0.0

1

0.02

0

.00

0.

21

28.

00 2

0.00

0.5

6 C

824

ch

l3

cl

bl

ack

cl-s

e sc

hist

+py-

cpy

- Cam

b. P

-lens

mat

rix 5

.34

0.02

5.

34

5.08

0

.28

3.

89

3.89

0.

00

0.00

0

.01

0.

00

0.0

1

0.19

2

8.00

19.

97 0

.57

C82

4

chl4

cl

blac

k cl

-se

schi

st+p

y-cp

y - C

amb.

P-le

ns m

atrix

5.3

3 0.

01

5.32

5.

11

0.2

3

3.96

3.

96

0.00

0.

00

0.0

1

0.00

0

.01

0.

29

28.

00 1

9.99

0.5

6 sa

mpl

e po

int

type

des

crip

tion

all

valu

es w

t% S

i

Ti

A

l

Fe

Mn

M

g

Ca

N

a

K

Sr

B

a

C

r

F

t_O

t

_cat

. Fe#

Appendix 3: Microprobe Analysis—Silicates

16

R01

-065

Tra

vA1_

1

feld

spar

/ab

48.9

676

8.3

761

0.

001

1

0.58

52 3

2.10

36 0

.000

2

0.02

6

0.0

778

0.

0315

0

.027

7

0.02

33

0.0

049

10

0.22

R

01-0

65 T

ravA

1_2

fe

ldsp

ar/a

b 49

.101

4 8

.460

9

0.00

02

10.

5811

32.

2268

0.0

002

0.

0317

0

.022

8

0.01

13

0.0

238

0.

0078

0

.000

1

100.

47

R01

-065

Tra

vA1_

3

feld

spar

/ab

48.9

738

8.3

449

0.

0002

1

0.67

1

32.0

639

0.0

002

0.

0226

0

.085

0.00

9

0.0

079

0.

0201

0

.005

8

100.

2 R

01-0

65 T

ravA

1_4

fe

ldsp

ar/a

b 48

.803

9 8

.396

6

0.00

02

10.

4715

32.

0581

0.0

013

0.

0215

0

.071

3

0.00

23

0.0

001

0.

0447

0

.015

99.8

9 R

01-0

65 T

ravA

1_5

fe

ldsp

ar/a

b 48

.969

1 8

.325

6

0.01

31

10.

569

32

.154

5 0

.000

6

0.02

65

0.0

414

0.

0045

0

.000

1

0.02

26

0.0

149

10

0.14

R

01-0

65 T

ravA

1_6

fe

ldsp

ar/a

b 48

.822

9 8

.449

4

0.00

22

10.

5853

31.

9244

0.0

007

0.

0209

0

.14

0.0

36

0.

0158

0

.088

1

0.00

84

100

.09

R01

-065

Tra

vA1_

7

feld

spar

/ab

48.9

517

8.3

217

0.

0002

1

0.50

27 3

2.18

76 0

.002

6

0.02

26

0.0

607

0.

0113

0

.000

1

0.03

17

0.0

211

10

0.11

R

01-0

65 T

ravA

1_8

fe

ldsp

ar/a

b 48

.669

6 8

.327

9

0.01

09

10.

5015

31.

9106

0.0

008

0.

0158

0

.112

7

0.02

25

0.0

001

0.

0648

0

.011

7

99.6

5 R

01-0

65 T

ravA

1_9

fe

ldsp

ar/a

b 47

.782

3 7

.002

5

0.22

65

11.

6989

30.

1059

0.0

002

1.

3746

0

.088

7

0.00

01

0.1

537

0.

0534

0

.853

8

99.3

4 R

01-0

65 T

ravA

1_10

fel

dspa

r/ab

48.8

315

8.2

884

0.

0002

1

0.57

13 3

2.01

67 0

.000

2

0.04

63

0.1

052

0.

0248

0

.000

1

0.05

44

0.0

001

99

.94

R01

-065

Tra

vA1_

11 f

elds

par/a

b 47

.664

1 7

.730

2

0.09

19

10.

8056

30.

8067

0.0

025

0.

4924

0

.062

2

0.00

68

0.0

811

0.

0175

0

.314

2

98.0

8 R

01-0

65 T

ravA

1_12

fel

dspa

r/ab

48.8

576

8.3

0

.004

2

10.5

636

32.

0592

0.0

002

0.

0192

0

.078

4

0.00

01

0.0

001

0.

0486

0

.019

9

99.9

5 R

01-0

65 T

ravA

1_13

fel

dspa

r/ab

48.9

39

8.3

59

0.

0022

1

0.57

13 3

2.08

43 0

.000

2

0.02

26

0.1

0

.024

8

0.01

58

0.0

524

0.

0428

1

00.2

1 R

01-0

65 T

ravA

1_14

fel

dspa

r/ab

48.5

78

8.0

598

0.

075

1

0.88

28 3

1.46

34 0

.000

2

0.40

18

0.1

267

0.

0607

0

.017

8

0.04

87

0.2

717

99

.99

R01

-065

Tra

vA1_

15 f

elds

par/a

b 47

.471

9 8

.073

5

0.03

9

9.8

468

30

.555

6 0

.000

2

0.01

4

1.4

267

1.

5313

0

.080

9

0.07

37

0.0

063

99

.12

R01

-065

Tra

vB1_

1

feld

spar

/ab

45.5

445

7.5

897

0.

0002

9

.761

8

29.9

43

0.0

002

0.

0107

0

.143

1

0.02

25

0.0

653

0.

044

0

.044

9

93.1

7 R

01-0

65 T

ravB

1_2

fe

ldsp

ar/a

b 48

.626

7 8

.345

3

0.00

02

10.

4872

31.

904

0.

0008

0

.028

2

0.08

34

0.0

023

0.

0001

0

.033

7

0.00

35

99.

52

R01

-065

Tra

vB1_

3

feld

spar

/ab

48.2

816

8.1

596

0.

0132

1

0.34

33 3

1.48

06 0

.000

2

0.02

2

0.5

553

0.

4005

0

.039

5

0.04

79

0.0

001

99

.34

R01

-065

Tra

vB1_

4

feld

spar

/ab

49.0

469

8.3

539

0.

0002

1

0.62

73 3

2.13

65 0

.000

2

0.02

82

0.0

738

0.

0811

0

.021

8

0.02

27

0.0

21

10

0.41

R

01-0

65 T

ravB

1_5

fe

ldsp

ar/a

b 49

.023

5 8

.448

1

0.00

39

10.

5338

32.

1377

0.0

002

0.

0226

0

.115

3

0.05

63

0.0

317

0.

0732

0

.034

6

100.

48

R01

-065

Tra

vB1_

6

feld

spar

/ab

48.9

783

8.3

945

0.

0016

1

0.57

05 3

2.10

91 0

.000

9

0.03

56

0.0

617

0.

0406

0

.047

5

0.04

28

0.0

002

10

0.28

R

01-0

65 T

ravB

1_7

fe

ldsp

ar/a

b 48

.919

8

.309

6

0.00

02

10.

4925

32.

1197

0.0

002

0.

022

0

.127

9

0.09

46

0.0

257

0.

033

0

.010

5

100.

15

R01

-065

Tra

vB1_

8

feld

spar

/ab

48.9

567

8.3

46

0.

0002

1

0.61

85 3

2.07

3

0.00

14

0.0

068

0.

133

0

.011

3

0.00

01

0.0

343

0.

0182

1

00.2

R

01-0

65 T

ravB

1_9

fe

ldsp

ar/a

b 48

.936

8 8

.304

2

0.00

02

10.

6275

32.

0578

0.0

021

0.

0232

0

.137

6

0.00

01

0.0

001

0.

0395

0

.018

100.

15

R01

-065

Tra

vB1_

10 f

elds

par/a

b 48

.866

8

.317

4

0.00

02

10.

5821

32.

0109

0.0

002

0.

0333

0

.167

0.02

03

0.0

001

0.

0467

0

.017

5

100.

06

R01

-065

Tra

vB1_

11 f

elds

par/a

b 48

.966

9 8

.325

9

0.01

54

10.

5797

32.

0966

0.0

002

0.

0169

0

.166

4

0.00

23

0.0

001

0.

0434

0

.033

4

100.

25

R01

-065

Tra

vB1_

12 f

elds

par/a

b 48

.849

3 8

.299

6

0.00

06

10.

5573

31.

9891

0.0

021

0.

022

0

.219

5

0.05

63

0.0

079

0.

0596

0

.007

5

100.

07

R01

-065

Tra

vB1_

13 f

elds

par/a

b 48

.860

4 8

.305

3

0.00

02

10.

4987

32.

0571

0.0

052

0.

0249

0

.158

8

0.10

81

0.0

04

0.

011

0

.000

1

100.

03

R01

-065

Tra

vB1_

14 f

elds

par/a

b 48

.84

8

.221

0.00

02

10.

6218

31.

957

0.

0069

0

.014

1

0.18

46

0.0

586

0.

0198

0

.059

0.01

78

100

R

01-0

65 T

ravB

1_15

fel

dspa

r/ab

45.8

877

5.9

625

0.

0002

7

.207

1

20.9

297

6.6

083

0.

0522

1

2.47

09 0

.083

1

0.00

59

0.0

485

0.

0002

9

9.26

R

01-0

65 T

ravB

1_16

fel

dspa

r/ab

48.8

651

8.3

15

0.

0061

1

0.50

37 3

2.10

55 0

.000

2

0.03

56

0.0

84

0.

009

0

.000

1

0.02

53

0.0

001

99

.95

R01

-065

Tra

vB1_

17 f

elds

par/a

b 49

.125

6 8

.36

0.0

128

10

.612

7 3

2.23

2

0.00

02

0.0

209

0.

0617

0

.011

3

0.00

79

0.0

641

0.

0001

1

00.5

1 R

01-0

65 T

ravB

2_1

fe

ldsp

ar/a

b 48

.784

3 8

.295

3

0.00

93

10.

5597

31.

9553

0.0

002

0.

0001

0

.116

8

0.06

08

0.0

455

0.

0389

0

.018

2

99.8

8 R

01-0

65 T

ravB

2_2

fe

ldsp

ar/a

b 41

.661

9 6

.880

9

0.30

17

8.2

885

24

.973

2 0

.000

1

0.03

52

4.6

705

4.

5049

0

.129

1

0.03

43

0.0

001

91

.48

R01

-065

Tra

vB2_

3

feld

spar

/ab

48.8

135

8.3

621

0.

0002

1

0.46

67 3

2.05

65 0

.000

8

0.03

33

0.0

455

0.

0676

0

.041

6

0.04

41

0.0

115

99

.94

R01

-065

Tra

vB2_

4

feld

spar

/ab

48.7

983

8.3

081

0.

0032

1

0.49

77 3

2.03

08 0

.007

1

0.01

53

0.0

926

0.

0315

0

.009

9

0.06

67

0.0

11

99

.87

R01

-065

Tra

vB2_

5

feld

spar

/ab

48.0

219

8.1

778

0.

0561

1

0.33

43 3

1.13

97 0

.000

2

0.00

84

0.7

175

0.

6143

0

.000

1

0.01

36

0.0

089

99

.09

R01

-065

Tra

vB2_

6

feld

spar

/ab

48.8

241

8.3

175

0.

0002

1

0.58

35 3

2.00

49 0

.000

2

0.01

98

0.0

794

0.

0316

0

.007

9

0.02

92

0.0

007

99

.9

sam

ple

tra

v/po

int

typ

e

W%

(O )

W%

(Na)

W%

(Mg)

W%

(Al)

W%

(Si)

W%

(P )

W%

(K )

W%

(Ca)

W%

(Mn)

W%

(Fe)

W%

(Sr)

W%

(Ba)

wt%

tota

l

Appendix 3: Microprobe Analysis—Silicates

17

R01

-065

Tra

vB2_

7

feld

spar

/ab

49.0

433

8.4

256

0.

0002

1

0.68

71 3

2.06

8

0.00

02

0.0

074

0.

1285

0

.040

6

0.00

01

0.0

292

0.

0105

1

00.4

4 R

01-0

65 T

ravB

2_8

fe

ldsp

ar/a

b 48

.935

3 8

.499

0.00

23

10.

4674

32.

1469

0.0

002

0.

017

0

.032

9

0.06

31

0.0

001

0.

0369

0

.000

1

100.

2 R

01-0

65 T

ravB

2_9

fe

ldsp

ar/a

b 49

.191

1 8

.382

2

0.00

48

10.

5684

32.

2663

0.0

002

0.

0356

0

.154

7

0.13

07

0.0

001

0.

0104

0

.015

2

100.

76

R01

-065

Tra

vC1_

1

feld

spar

/ab

49.2

078

8.3

642

0.

0002

1

0.63

15 3

2.26

51 0

.002

5

0.03

05

0.1

199

0.

0698

0

.000

1

0.02

46

0.0

001

10

0.72

R

01-0

65 T

ravC

1_2

fe

ldsp

ar/a

b 49

.049

5 8

.323

7

0.00

26

10.

6908

32.

0822

0.0

002

0.

0384

0

.157

3

0.00

01

0.0

297

0.

0396

0

.009

6

100.

42

R01

-065

Tra

vC1_

3

feld

spar

/ab

47.3

896

7.9

748

0.

0466

1

0.11

11 3

0.61

7

0.00

02

0.0

186

0.

958

1

.059

6

0.00

4

0.0

454

0.

0383

9

8.26

R

01-0

65 T

ravC

1_4

fe

ldsp

ar/a

b 48

.870

5 8

.361

4

0.00

02

10.

5828

32.

0392

0.0

002

0.

0345

0

.055

2

0.00

01

0.0

238

0.

035

0

.005

6

100.

01

R01

-065

Tra

vC1_

5

feld

spar

/ab

49.0

1

8.4

084

0.

0067

1

0.53

61 3

2.18

76 0

.000

2

0.02

09

0.0

278

0.

036

0

.000

1

0.05

05

0.0

208

10

0.31

R

01-0

65 T

ravC

1_6

fe

ldsp

ar/a

b 48

.935

6 8

.431

2

0.00

02

10.

5785

32.

0974

0.0

002

0.

0368

0

.013

7

0.02

25

0.0

001

0.

0208

0

.011

2

100.

15

R01

-065

Tra

vC1_

7

feld

spar

/ab

48.6

777

8.3

072

0.

0013

1

0.53

7

31.8

92

0.0

002

0.

0356

0

.121

0.03

61

0.0

001

0.

0636

0

.020

4

99.6

9 R

01-0

65 T

ravC

1_8

fe

ldsp

ar/a

b 48

.782

6 8

.310

5

0.00

1

10.

5181

32.

0221

0.0

002

0.

0481

0

.064

8

0.00

45

0.0

198

0.

0344

0

.007

3

99.8

1 R

01-0

65 T

ravC

1_9

fe

ldsp

ar/a

b 48

.940

4 8

.316

4

0.00

8

10.

6054

32.

0554

0.0

031

0.

0452

0

.093

1

0.00

01

0.0

455

0.

0843

0

.025

5

100.

22

R01

-065

Tra

vC1_

10 fe

ldsp

ar/a

b 48

.720

1 7

.955

5

0.06

44

10.

9288

31.

6279

0.0

002

0.

3675

0

.070

8

0.00

9

0.0

435

0.

0188

0

.236

8

100.

04

R01

-065

Tra

vC1_

11 fe

ldsp

ar/a

b 48

.781

8 8

.1

0.0

561

10

.780

6 3

1.76

62 0

.000

2

0.31

13

0.1

012

0.

0001

0

.035

6

0.04

41

0.1

663

10

0.14

R

01-0

65 T

ravC

1_12

feld

spar

/ab

48.7

891

8.2

275

0.

0002

1

0.57

78 3

2.01

67 0

.000

2

0.04

58

0.0

643

0.

0001

0

.000

1

0.03

5

0.0

001

99

.76

R01

-065

Tra

vC1_

13 fe

ldsp

ar/a

b 49

.053

8 8

.309

4

0.00

02

10.

6697

32.

1374

0.0

002

0.

0385

0

.081

5

0.00

01

0.0

178

0.

0538

0

.005

1

100.

37

R01

-065

Tra

vC1_

14 fe

ldsp

ar/a

b 47

.954

7

.259

7

0.18

24

11.

3147

30.

6117

0.0

002

0.

9836

0

.102

1

0.00

22

0.1

206

0.

0319

0

.586

7

99.1

5 R

01-0

65 T

ravC

1_15

feld

spar

/ab

48.8

43

8.2

772

0.

0141

1

0.60

41 3

1.99

08 0

.000

2

0.10

75

0.0

83

0.

0293

0

.000

1

0.03

31

0.0

499

10

0.03

R

01-0

65 T

ravC

1_16

feld

spar

/ab

48.8

07

8.3

411

0.

0039

1

0.51

72 3

2.04

21 0

.000

2

0.03

28

0.0

658

0.

0001

0

.007

9

0.02

79

0.0

091

99

.86

R01

-065

Tra

vC1_

17 fe

ldsp

ar/a

b 48

.899

8

.412

5

0.00

61

10.

5296

32.

101

0.

0087

0

.032

8

0.00

71

0.0

09

0.

0119

0

.009

1

0.00

01

100

.03

R01

-065

Tra

vC1_

18 fe

ldsp

ar/a

b 48

.813

3 8

.273

5

0.00

74

10.

531

32

.066

2 0

.000

2

0.03

51

0.0

177

0.

0248

0

.013

9

0.01

56

0.0

001

99

.8

R01

-065

Tra

vC1_

19 fe

ldsp

ar/a

b 48

.616

8

.311

0.00

64

10.

4889

31.

9097

0.0

002

0.

0322

0

.059

7

0.00

01

0.0

079

0.

0019

0

.018

99.4

5 R

01-0

65 T

ravC

1_20

feld

spar

/ab

48.5

968

8.2

914

0.

0002

1

0.53

88 3

1.85

91 0

.000

2

0.01

98

0.0

557

0.

0001

0

.011

9

0.04

28

0.0

173

99

.43

R01

-065

Tra

vC1_

21 fe

ldsp

ar/a

b 47

.704

6 6

.902

5

0.27

83

11.

6228

30.

1017

0.0

002

1.

2937

0

.079

3

0.00

9

0.1

599

0.

0346

0

.973

3

99.1

6

sam

ple

tra

v/po

int

typ

e

W%

(O )

W%

(Na)

W%

(Mg)

W%

(Al)

W%

(Si)

W%

(P )

W%

(K )

W%

(Ca)

W%

(Mn)

W%

(Fe)

W%

(Sr)

W%

(Ba)

wt%

tota

l

sam

ple

poin

t ty

pe

de

scrip

tion

a

ll va

lues

wt%

Si

Ti

A

l

Fe

Mn

M

g

Ca

N

a

K

S

r

Ba

Cr

F

C

l

O

C00

-087

se2

se

ricite

au

gen

schi

st -

FW, p

roxi

mal

18.2

8 0

.05

14

.79

9.3

4 0

.71

1.5

9

0.07

0

.12

5.6

8 0

.02

0.

10

0.0

0

0.37

0

.01

39.

19

C00

-171

se1

se

ricite

se

-si-c

l sch

ist -

FW

, pro

xim

al

23

.15

0.2

6

15.0

4 2

.17

0.0

8 1

.99

0.

00

0.0

5 7

.88

0.0

0

0.30

0

.00

0.

59

0.0

0 4

3.54

C

00-1

71 s

e2

seric

ite

se-s

i-cl s

chis

t - F

W, p

roxi

mal

23.3

9 0

.26

15

.36

2.7

9 0

.13

2.2

2

0.03

0

.06

7.5

1 0

.00

0.

21

0.0

0

0.49

0

.00

44.

37

C00

-333

se2

se

ricite

se

-si s

chis

t - F

W, p

roxi

mal

23

.73

0.0

6

16.9

2 1

.60

0.0

7 0

.99

0.

01

0.1

5 8

.29

0.0

3

0.11

0

.00

0.

72

0.0

0 4

5.02

C

01-5

04 s

e1

seric

ite

auge

n sc

hist

- or

e

22.6

0 0

.18

16

.13

3.4

2 0

.08

1.5

9

0.03

0

.08

7.6

6 0

.00

0.

41

0.0

0

0.40

0

.01

43.

92

C01

-650

se1

se

ricite

py

in c

l-se

schi

st -

FW, p

roxi

mal

23.2

8 0

.06

17

.55

1.1

7 0

.05

0.9

9

0.00

0

.12

8.5

6 0

.00

0.

30

0.0

2

0.46

0

.00

45.

01

C02

-824

se5

se

ricite

B

lack

cl-s

e sc

hist

- FW

, pro

xim

al

22

.71

0.1

8

16.8

5 2

.19

0.0

6 0

.91

0.

00

0.1

8 8

.23

0.0

4

0.15

0

.00

0.

52

0.0

1 4

4.00

Appendix 4: Microprobe Analysis—Sulphides

18

Appendix 4 Microprobe Analysis

-Sulphides

Appendix 4: Microprobe Analysis—Sulphides

19

S py/apy 151 S tet 131 high Cu/As Mn py/apy 102 Fe tet 128 high Sb/Ag Fe py/apy 187 Fe tet 142 Co py/apy 117 Cu tet 201 high Cu/As Ni py/apy 130 Zn tet 163 high Sb/Ag Cu py/apy 146 Zn tet 175 high Cu/As As py/apy 92 As tet 207 high Sb/Ag Se py/apy 61 As tet 184 high Cu/As Ag py/apy 84 Se tet 185 high Sb/Ag Au py/apy 323 Se tet 203 Bi py/apy 268 Ag tet 223 Cd tet 189 high Cu/As S ga 385 Sb tet 170 high Sb/Ag Zn ga 185 Sb tet 199 high Cu/As As ga 134 Te tet 125 high Sb/Ag Se ga 87 Te tet 137 high Cu/As Ag ga 199 Hg tet 175 high Sb/Ag Cd ga 198 Hg tet 199 high Cu/As Sb ga 202 Pb tet 365 high Sb/Ag Pb ga 799 Pb tet 381 high Cu/As Bi tet 230 high Sb/Ag S cpy 130 Bi tet 240 Mn cpy 109 Fe cpy 191 S py (with Tl) 225 Co cpy 128 Fe py (with Tl) 207 Ni cpy 143 Cu py (with Tl) 161 Cu cpy 181 Zn py (with Tl) 143 As cpy 89 As py (with Tl) 72 Se cpy 59 Se py (with Tl) 47 Ag cpy 90 Ag py (with Tl) 120 Au cpy 348 Cd py (with Tl) 132 Bi cpy 244 Sb py (with Tl) 95 Te py (with Tl) 97 S sp 135 Au py (with Tl) 611 Mn sp 91 Hg py (with Tl) 218 Fe sp 103 Tl py (with Tl) 238 Co sp 96 Pb py (with Tl) 288 Ni sp 121 Bi py (with Tl) 286 Cu sp 137 Zn sp 353 As sp 85 Beam set at 20kV and 60nA. Se sp 58 Ag sp 101 Cd sp 107

Calculated detection limits for microprobe analyses: element mineral d.l. comments element mineral d.l. comments (ppm) (ppm)

Appendix 4: Microprobe Analysis—Sulphides

20

C26

1

A_p

y_1

p

y

54.

7539

0.

0272

45.7

117

0

0.00

82

0.

0001

0.27

59

0

.007

1

0.

0112

0.0

067

0.00

01

10

0.80

C

261

A

_py_

2

py

5

4.51

59

0.03

13

45

.947

7

0

.003

2

0.

0086

0.01

45

0.

2501

0.0

156

0.01

07

0

.000

1

0.

0001

100.

80

C26

1

A_p

y_3

p

y

54.

3251

0.

0319

45.2

24

0

0.01

47

0.

0094

0.67

92

0

.023

1

0.

0069

0.0

001

0.00

01

10

0.31

C

261

B

_py_

7

py

5

4.68

59

0.01

91

46

.118

9

0

0.

002

0.0

001

0.21

48

0

.015

8

0.

0001

0.0

028

0.00

01

10

1.06

C

261

B

_py_

8

py

5

4.93

25

0.00

4

4

5.99

83

0

0.01

16

0.

0013

0.16

78

0

.017

1

0.

0001

0.0

001

0.00

01

10

1.13

C

261

B

_py_

9

py

5

4.55

5

0.00

63

45

.959

6

0

0.

0001

0.00

01

0.

1764

0.0

235

0.00

01

0

.000

1

0.

0001

100.

72

C27

8

A_p

y_1

p

y

52.

7368

0.

0011

46.2

506

0

0.00

01

0.

0024

0.07

14

0

.009

1

0.

0001

0.0

001

0.00

01

99

.07

C27

8

A_p

y_2

p

y

52.

7321

0.

0226

45.9

252

0

0.00

43

0.

0034

0.12

32

0

.019

2

0.

0058

0.0

001

0.00

01

98

.84

C27

8

A_p

y_3

p

y

52.

7502

0.

0094

45.9

748

0

0.00

01

0.

0016

0.06

88

0

.023

6

0.

0044

0.0

001

0.00

01

98

.83

C27

8

C_p

y_7

p

y

52.

7817

0.

0006

46.1

526

0

0.00

01

0.

0001

0.06

28

0

.013

3

0.

0065

0.0

001

0.00

01

99

.02

C27

8

C_p

y_8

p

y

52.

8407

0.

0001

45.9

292

0.0

189

0.00

01

0.

0085

0.13

04

0

.012

4

0.

0172

0.0

001

0.00

01

98

.96

C27

8

C_p

y_9

p

y

52.

9247

0.

0001

46.1

302

0

0.00

01

0.

0001

0.10

43

0

.013

6

0.

0141

0.0

001

0.00

01

99

.19

C28

0

A_p

y_1

p

y

53.

1281

0.

0001

46.1

506

0.0

004

0.00

01

0.

0001

0.06

8

0

.023

6

0.

0039

0.0

001

0.00

01

99

.38

C28

0

A_p

y_2

p

y

52.

9244

0.

0001

45.8

071

0.0

005

0.00

01

0.

0001

0.05

82

0

.022

0.

0001

0.0

001

0.00

01

98

.81

C28

0

A_p

y_3

p

y

52.

9082

0.

0001

46.0

846

0

0.00

01

0.

0001

0.06

92

0

.016

7

0.

0001

0.0

001

0.00

01

99

.08

C28

0

C_p

y_10

py

53.0

132

0.0

001

46.1

871

0.0

011

0.00

01

0.

0065

0.06

77

0

.014

1

0.

0009

0.0

001

0.00

01

99

.29

C28

0

C_p

y_11

py

52.6

556

0.0

001

46.1

68

0

0.00

79

0.

0001

0.07

48

0

.014

4

0.

0104

0.0

001

0.00

01

98

.93

C28

0

C_p

y_12

py

52.8

243

0.0

123

45.9

696

0

0.00

26

0.

0001

0.31

67

0

.016

4

0.

0213

0.0

001

0.00

01

99

.16

C28

4

A_p

y_1

p

y

52.

5448

0.

0098

44.7

633

0.0

077

0.02

46

0.

0089

0.09

04

0

.014

2

0.

0118

0.0

001

0.00

01

97

.48

C28

4

A_p

y_2

p

y

52.

9277

0.

004

44.

2976

0.

0304

0.0

144

0.00

01

0.

1931

0.0

136

0.00

68

0

.000

1

0.

0001

97.4

9 C

284

A

_py_

3

py

5

2.93

85

0.00

46

45

.578

6

0

.010

4

0.

0001

0.00

01

0.

1125

0.0

172

0.01

52

0

.000

1

0.

0001

98.6

8 C

284

C

_py_

13

py

52

.890

7

0

.000

1

45

.412

3

0

0.

0001

0.00

01

0.

1188

0.0

108

0.00

01

0

.015

2

0.

0001

98.4

5 C

284

C

_py_

14

py

52

.891

6

0

.000

1

45

.365

9

0

.020

2

0.

0107

0.00

42

0.

092

0.0

15

0.00

01

0

.000

1

0.

0001

98.4

0 C

284

C

_py_

15

py

53

.040

9

0

.006

7

45

.295

6

0

.014

1

0.

0001

0.00

13

0.

0907

0.0

14

0.00

01

0

.000

1

0.

0001

98.4

6 C

285

A

_py_

1

py

5

4.86

01

0.00

14

44

.773

0

0.

0001

0.00

59

0.

0724

0.0

095

0.00

67

0

.000

1

0.

0001

99.7

3 C

285

A

_py_

2

py

5

4.73

32

0.00

83

45

.067

9

0

.000

9

0.

0099

0.00

01

0.

0695

0.0

279

0.00

37

0

.000

1

0.

0001

99.9

2 C

285

A

_py_

3

py

5

4.88

06

0.00

01

45

.093

8

0

.153

5

0.

0001

0.01

29

0.

1401

0.0

116

0.00

04

0

.000

1

0.

0001

100.

29

C28

5

C_p

y_10

py

54.6

504

0.0

001

45.4

838

0.0

08

0.00

4

0

.009

3

0.

1967

0.0

167

0.00

7

0.00

01

0

.000

1

10

0.38

C

285

C

_py_

11

py

54

.888

3

0

.000

1

45

.383

7

0

.004

2

0.

0001

0.00

24

0.

1347

0.0

068

0.00

61

0

.029

3

0.

0001

100.

46

C28

5

C_p

y_12

py

54.8

679

0.0

001

45.5

957

0.1

071

0.01

27

0.

0017

0.13

62

0

.034

8

0.

0046

0.0

001

0.00

01

10

0.76

C

287

A

_py_

1

py

5

2.86

13

0.00

13

45

.318

6

0

0.

0001

0.00

24

0.

0682

0.0

076

0.00

89

0

.000

1

0.

0001

98.2

7 C

287

A

_py_

2

py

5

2.60

16

0.01

55

44

.477

1

0

0.

0001

0.01

31

0.

2093

0.0

141

0.01

33

0

.000

1

0.

0001

97.3

4 C

287

A

_py_

3

py

5

3.13

05

0.00

01

45

.483

0

.015

6

0.

0018

0.01

29

0.

0786

0.0

077

0.00

96

0

.000

1

0.

0001

98.7

4 C

290

A

_py_

1

py

5

2.69

78

0.00

01

46

.116

4

0

.01

0

.013

2

0.

0001

0.07

85

0

.016

9

0.

0001

0.0

001

0.00

01

98

.93

C29

0

A_p

y_2

p

y

52.

7928

0.

0001

45.9

229

0.0

062

0.00

02

0.

0042

0.08

06

0

.018

9

0.

0141

0.0

015

0.00

01

98

.84

C29

0

A_p

y_3

p

y

52.

7691

0.

0017

46.1

937

0.0

067

0.00

87

0.

0087

0.08

52

0

.010

2

0.

008

0.

0001

0.0

001

99.0

9 C

290

C

_py_

19

py

52

.547

4

0

.000

1

45

.549

4

0

0.

0001

0.01

51

0.

1975

0.0

165

0.01

34

0

.000

1

0.

0001

98.3

4 C

290

C

_py_

20

py

52

.915

1

0

.000

1

45

.926

0

.000

8

0.

0031

0.02

42

0.

1078

0.0

205

0.00

01

0

.000

1

0.

0001

99.0

0

sam

ple

poi

nt

typ

e W

%(S

)

W%

(Mn)

W

%(F

e)

W

%(C

o)

W%

(Ni)

W

%(C

u)

W%

(As)

W

%(S

e)

W%

(Ag)

W

%(A

u)

W%

(Bi)

W

%(s

um)

Appendix 4: Microprobe Analysis—Sulphides

21

C29

0

C_p

y_21

py

52.5

121

0.0

009

45.6

626

0

0.00

01

0.

0189

0.27

2

0

.011

4

0.

0105

0.0

001

0.00

01

98

.49

C29

2

A_p

y_4

p

y

52.

6689

0.

0001

46.5

969

0.0

042

0.00

01

0.

0001

0.08

0

.021

5

0.

0081

0.0

001

0.00

01

99

.38

C29

2

A_p

y_5

p

y

52.

7459

0.

0001

46.2

578

0

0.00

26

0.

0098

0.15

92

0

.017

9

0.

0027

0.0

001

0.00

01

99

.20

C29

2

A_p

y_6

p

y

52.

7231

0.

0004

46.1

774

0.0

014

0.00

08

0.

0001

0.07

62

0

.021

4

0.

0109

0.0

25

0.00

01

99

.04

C29

2

B_p

y_10

py

52.6

733

0.0

064

46.0

492

0

0.00

01

0.

0029

0.06

4

0

.013

8

0.

0113

0.0

157

0.00

01

98

.84

C29

2

B_p

y_11

py

52.8

625

0.0

001

46.0

903

0

0.00

01

0.

0001

0.06

05

0

.023

6

0.

0125

0.0

001

0.00

01

99

.05

C29

2

B_p

y_12

py

52.7

375

0.0

001

46.0

219

0.0

093

0.00

33

0.

0001

0.07

01

0

.014

8

0.

0092

0.0

001

0.00

01

98

.87

C29

2

B_p

y_7

p

y

52.

8056

0.

0001

46.1

454

0.0

011

0.00

56

0.

0009

0.06

61

0

.007

4

0.

0139

0.0

001

0.00

01

99

.05

C29

2

B_p

y_8

p

y

52.

8276

0.

0001

46.2

138

0

0.00

01

0.

0001

0.06

16

0

.023

4

0.

0001

0.0

001

0.00

01

99

.13

C29

2

B_p

y_9

p

y

52.

6641

0.

0001

46.1

172

0

0.00

01

0.

0113

0.14

9

0

.014

9

0.

0001

0.0

001

0.00

01

98

.96

C29

7

A_p

y_1

p

y

53.

0541

0.

0027

45.1

399

0.0

181

0.00

01

0.

0001

0.08

88

0

.010

9

0.

0141

0.0

105

0.00

01

98

.34

C29

7

A_p

y_2

p

y

53.

0324

0.

0061

45.3

837

0.0

1

0.0

001

0.00

01

0.

0977

0.0

143

0.00

01

0

.033

5

0.

0001

98.5

8 C

297

A

_py_

3

py

5

2.80

41

0.00

01

45

.396

7

0

0.

0001

0.00

01

0.

2803

0.0

215

0.00

01

0

.000

1

0.

0001

98.5

0 C

297

B

_py_

4

py

5

3.04

47

0.00

01

45

.078

8

0

0.

0072

0.00

01

0.

0746

0.0

192

0.00

75

0

.000

1

0.

0001

98.2

3 C

297

B

_py_

5

py

5

3.14

05

0.00

81

45

.325

1

0

.014

8

0.

0065

0.00

01

0.

0743

0.0

17

0.00

57

0

.000

1

0.

0001

98.5

9 C

297

B

_py_

6

py

5

2.84

41

0.00

01

44

.903

4

0

.006

7

0.

0001

0.01

7

0

.137

6

0.

0148

0.00

01

0

.000

1

0.

0001

97.9

2 C

297

D

_py_

16

py

52

.687

1

0

.000

6

45

.057

2

0

0.

0001

0.00

2

0

.281

9

0.

0208

0.00

01

0

.000

1

0.

0001

98.0

5 C

297

D

_py_

17

py

53

.147

7

0

.001

2

44

.837

2

0

0.

0168

0.00

01

0.

0631

0.0

14

0.00

01

0

.000

1

0.

0001

98.0

8 C

297

D

_py_

18

py

52

.921

4

0

.005

8

44

.913

4

0

.01

0

.014

7

0.

0001

0.07

02

0

.016

7

0.

0018

0.0

001

0.00

01

97

.95

C29

9

C_p

y_16

py

55.2

439

0.0

159

45.6

962

0.0

097

0.00

01

0.

0019

0.07

76

0

.012

5

0.

0086

0.0

001

0.00

01

10

1.07

C

299

C

_py_

17

py

55

.063

0

.004

3

45

.916

9

0

0.

0101

0.01

13

0.

0715

0.0

193

0.00

63

0

.000

1

0.

0001

101.

10

C29

9

C_p

y_18

py

55.1

001

0.0

001

45.1

442

0

0.00

01

0.

0058

0.07

08

0

.016

2

0.

0001

0.0

001

0.00

01

10

0.34

C

299

D

_py_

19

py

55

.180

5

0

.000

1

45

.400

9

0

.014

4

0.

0096

0.00

01

0.

0821

0.0

052

0.00

48

0

.000

1

0.

0001

100.

70

C29

9

D_p

y_20

py

54.9

828

0.0

001

45.7

139

0

0.00

67

0.

0001

0.05

64

0

.011

1

0.

0075

0.0

001

0.00

01

10

0.78

C

299

D

_py_

21

py

55

.123

5

0

.014

7

45

.418

7

0

0.

0001

0.00

97

0.

0598

0.0

095

0.00

01

0

.030

5

0.

0001

100.

67

C30

1

A_p

y_7

p

y

54.

5435

0.

0065

45.4

705

0.0

006

0.00

01

0.

0001

0.11

91

0

.020

1

0.

0003

0.0

001

0.00

01

10

0.16

C

301

A

_py_

8

py

5

4.73

54

0.00

05

45

.635

3

0

0.

004

0.0

001

0.10

8

0

.016

9

0.

0099

0.0

167

0.00

01

10

0.53

C

301

A

_py_

9

py

5

4.37

11

0.00

26

45

.695

5

0

.016

5

0.

0203

0.00

35

0.

2278

0.0

089

0.00

03

0

.035

3

0.

0006

100.

38

C30

1

B_p

y_10

py

54.7

786

0.0

051

45.9

85

0.0

023

0.00

01

0.

0339

0.07

16

0

.018

3

0.

0001

0.0

141

0.00

01

10

0.91

C

301

B

_py_

11

py

54

.474

0

.000

1

45

.294

6

0

0.

0108

0.00

01

0.

08

0.0

161

0.00

8

0.00

01

0

.020

8

99

.90

C30

1

B_p

y_12

py

53.7

734

0.0

001

45.0

45

0

0.00

39

0.

0001

1.73

63

0

.020

1

0.

0001

0.0

001

0.00

01

10

0.58

C

306

A

_py_

1

py

5

4.95

49

0.00

01

45

.508

3

0

.032

0.

0054

0.00

05

0.

074

0.0

132

0.00

01

0

.024

0.

0001

100.

61

C30

6

A_p

y_2

p

y

54.

885

0.

0001

45.1

077

0

0.00

56

0.

0001

0.16

31

0

.007

9

0.

0016

0.0

222

0.00

01

10

0.19

C

306

A

_py_

3

py

5

4.82

68

0.00

21

44

.419

3

0

.028

6

0.

0008

0.00

01

0.

393

0.0

147

0.00

01

0

.021

4

0.

0001

99.7

1 C

306

C

_py_

10

py

55

.290

9

0

.000

1

45

.067

0

0.

0001

0.00

63

0.

0707

0.0

113

0.00

01

0

.000

1

0.

0001

100.

45

C30

6

C_p

y_11

py

54.8

545

0.0

037

45.3

388

0.0

314

0.00

01

0.

01

0.0

882

0.00

79

0.

021

0.

0001

0.0

001

100.

36

C30

6

C_p

y_12

py

55.2

804

0.0

001

45.5

532

0

0.00

13

0.

0001

0.14

99

0

.013

7

0.

0121

0.0

001

0.00

01

10

1.01

C

307

A

_py_

1

py

5

2.80

48

0.00

01

46

.467

4

0

0.

0001

0.00

91

0.

1124

0.0

105

0.00

01

0

.000

1

0.

0001

99.4

0

sam

ple

poi

nt

typ

e W

%(S

)

W%

(Mn)

W

%(F

e)

W

%(C

o)

W%

(Ni)

W

%(C

u)

W%

(As)

W

%(S

e)

W%

(Ag)

W

%(A

u)

W%

(Bi)

W

%(s

um)

Appendix 4: Microprobe Analysis—Sulphides

22

C30

7

A_p

y_2

p

y

53.

0182

0.

0001

45.8

681

0

0.00

01

0.

006

0.0

828

0.00

98

0.

0085

0.0

001

0.00

01

98

.99

C30

7

A_p

y_3

p

y

52.

6584

0.

0001

46.2

356

0

0.00

01

0.

0001

0.11

52

0

.018

8

0.

0108

0.0

001

0.00

01

99

.04

C30

7

B_p

y_10

py

52.2

405

0.0

042

45.8

995

0

0.00

84

0.

0002

0.32

8

0

.009

0.

0001

0.0

001

0.00

01

98

.49

C30

7

B_p

y_11

py

52.6

334

0.0

001

45.9

824

0

0.00

01

0.

0001

0.27

25

0

.009

5

0.

0065

0.0

001

0.00

01

98

.90

C30

7

B_p

y_12

py

52.8

948

0.0

119

46.2

375

0

0.00

01

0.

0001

0.15

68

0

.011

0.

0004

0.0

001

0.00

01

99

.31

C30

7

B_p

y_7

p

y

52.

3158

0.

0001

45.9

248

0

0.00

01

0.

0001

0.37

27

0

.025

0.

0021

0.0

001

0.00

01

98

.64

C30

7

B_p

y_8

p

y

52.

5348

0.

0001

46.1

065

0

0.01

77

0.

0073

0.37

72

0

.021

3

0.

0001

0.0

001

0.00

01

99

.07

C30

7

B_p

y_9

p

y

52.

4007

0.

007

46.

1081

0

0.

0001

0.01

05

0.

388

0.0

223

0.00

77

0

.000

1

0.

0001

98.9

4 C

317

B

_py_

7

py

5

3.07

65

0.01

15

45

.755

6

0

.007

7

0.

0473

0.01

35

0.

103

0.0

187

0.00

23

0

.000

1

0.

0001

99.0

4 C

317

B

_py_

8

py

5

3.09

66

0.00

71

45

.766

1

0

0.

0457

0.00

01

0.

0984

0.0

213

0.00

01

0

.000

1

0.

0001

99.0

4 C

317

B

_py_

9

py

5

3.02

28

0.01

71

45

.446

9

0

.011

0.

0086

0.01

88

0.

148

0.0

145

0.01

1

0.00

01

0

.000

1

98

.70

C31

7

C_p

y_10

py

52.9

55

0.0

012

45.9

209

0.0

04

0.00

3

0

.000

1

0.

0635

0.0

11

0.00

51

0

.000

1

0.

0001

98.9

6 C

317

C

_py_

11

py

52

.831

9

0

.006

7

45

.685

0

.000

1

0.

0001

0.00

33

0.

0683

0.0

006

0.00

01

0

.000

1

0.

0001

98.6

0 C

317

C

_py_

12

py

52

.954

8

0

.019

4

45

.357

8

0

0.

0001

0.01

55

0.

0885

0.0

153

0.00

01

0

.000

1

0.

0001

98.4

5 C

320

A

_py_

1

py

5

2.82

28

0.00

78

45

.824

2

0

0.

0001

0.00

01

0.

0712

0.0

268

0.01

37

0

.004

0.

0001

98.7

7 C

320

A

_py_

2

py

5

2.88

95

0.00

08

45

.549

4

0

0.

0001

0.00

71

0.

0638

0.0

096

0.00

01

0

.000

1

0.

0001

98.5

2 C

320

A

_py_

3

py

5

2.96

9

0.00

01

45

.767

5

0

0.

0001

0.00

04

0.

0698

0.0

244

0.01

34

0

.000

1

0.

0001

98.8

4 C

320

A

_py_

4

py

5

2.79

74

0.00

01

45

.601

5

0

0.

0001

0.00

13

0.

078

0.0

155

0.00

87

0

.018

4

0.

0001

98.5

2 C

320

A

_py_

5

py

5

2.81

91

0.00

06

45

.801

5

0

0.

0001

0.00

01

0.

0882

0.0

134

0.00

01

0

.000

1

0.

0001

98.7

2 C

320

A

_py_

6

py

5

2.83

62

0.01

13

45

.656

1

0

0.

0034

0.00

01

0.

0961

0.0

169

0.00

01

0

.000

1

0.

0001

98.6

2 C

320

B

_py_

10

py

52

.682

7

0

.000

1

45

.915

7

0

0.

0003

0.00

41

0.

0698

0.0

212

0.01

23

0

.000

1

0.

0001

98.7

1 C

320

B

_py_

11

py

53

.002

9

0

.005

7

45

.653

6

0

0.

008

0.0

001

0.07

11

0

.015

7

0.

0071

0.0

001

0.00

01

98

.76

C32

0

B_p

y_12

py

53.0

167

0.0

074

45.8

078

0.0

125

0.00

01

0.

0161

0.06

73

0

.015

2

0.

0001

0.0

001

0.00

01

98

.94

C32

0

B_p

y_7

p

y

52.

8921

0.

0001

45.9

692

0.0

153

0.00

07

0.

0064

0.05

76

0

.018

9

0.

0001

0.0

001

0.00

01

98

.96

C32

0

B_p

y_8

p

y

52.

7957

0.

0001

45.7

805

0.0

397

0.00

14

0.

0001

0.06

7

0

.007

4

0.

0001

0.0

001

0.00

18

98

.69

C32

0

B_p

y_9

p

y

52.

9542

0.

0014

45.6

755

0.0

064

0.00

01

0.

0023

0.06

86

0

.018

6

0.

0034

0.0

115

0.00

01

98

.74

C32

3

B_p

y_7

p

y

53.

0448

0.

0001

45.7

66

0

0.00

01

0.

0059

0.05

93

0

.020

4

0.

0027

0.0

001

0.00

01

98

.90

C32

3

B_p

y_8

p

y

52.

7253

0.

0054

45.2

538

0.0

199

0.00

01

0.

0131

0.07

25

0

.016

9

0.

0017

0.0

001

0.00

01

98

.11

C32

3

B_p

y_9

p

y

52.

8438

0.

005

45.

378

0

0.

0001

0.02

49

0.

0645

0.0

166

0.00

01

0

.000

1

0.

0001

98.3

3 C

323

C

_py_

10

py

52

.880

9

0

.000

1

45

.517

4

0

0.

007

0.0

001

0.05

34

0

.021

7

0.

0001

0.0

001

0.00

01

98

.48

C32

3

C_p

y_11

py

52.9

591

0.0

001

45.6

058

0

0.00

03

0.

003

0.0

732

0.00

78

0.

0001

0.0

001

0.00

01

98

.65

C32

3

C_p

y_12

py

53.0

717

0.0

038

45.4

544

0

0.00

01

0.

0001

0.08

43

0

.010

5

0.

0001

0.0

001

0.00

01

98

.63

C32

6

A_p

y_1

p

y

51.

804

0.

0001

46.2

232

0

0.00

3

0

.000

1

0.

2532

0.0

187

0.00

27

0

.000

1

0.

0013

98.3

1 C

326

A

_py_

2

py

5

2.31

26

0.00

01

46

.472

1

0

0.

0128

0.00

01

0.

0754

0.0

121

0.01

38

0

.000

1

0.

0001

98.9

0 C

326

A

_py_

3

py

5

2.12

77

0.00

36

46

.239

7

0

0.

0022

0.00

89

0.

0828

0.0

157

0.00

46

0

.000

1

0.

0001

98.4

9 C

326

B

_py_

10

py

52

.347

4

0

.000

1

46

.435

6

0

.002

6

0.

0001

0.00

01

0.

0687

0.0

201

0.00

01

0

.000

1

0.

0001

98.8

8 C

326

B

_py_

11

py

52

.389

0

.000

1

46

.223

0

0.

0059

0.00

01

0.

11

0.0

182

0.00

07

0

.000

1

0.

0001

98.7

5 C

326

B

_py_

12

py

52

.362

8

0

.000

1

46

.282

5

0

0.

0022

0.00

01

0.

0681

0.0

209

0.00

11

0

.000

1

0.

0001

98.7

4

sam

ple

poi

nt

typ

e W

%(S

)

W%

(Mn)

W

%(F

e)

W

%(C

o)

W%

(Ni)

W

%(C

u)

W%

(As)

W

%(S

e)

W%

(Ag)

W

%(A

u)

W%

(Bi)

W

%(s

um)

Appendix 4: Microprobe Analysis—Sulphides

23

C32

6

B_p

y_T1

-01

py

52.1

944

0.0

171

46.2

105

0

0.00

99

0.

01

0.1

268

0.00

7

0

.009

0.

0001

0.0

001

98.5

8 C

326

B

_py_

T1-0

2

py

51

.494

9

0

.000

1

45

.946

2

0

0.

0001

0.01

86

1.

0822

0.0

167

0.00

88

0

.000

1

0.

0001

98.5

7 C

326

B

_py_

T1-0

3

py

51

.608

5

0

.000

1

45

.811

9

0

0.

0001

0.73

74

0.

1217

0.0

113

0.00

01

0

.000

1

0.

0001

98.2

9 C

326

B

_py_

T1-0

4

py

52

.16

0

.000

1

46

.058

3

0

0.

0201

0.04

21

0.

166

0.0

166

0.00

63

0

.000

1

0.

013

98.

48

C32

6

B_p

y_T1

-05

py

51.3

96

0.0

01

45.7

919

0.0

055

0.00

69

0.

9593

0.07

86

0

.015

5

0.

0057

0.0

001

0.00

01

98

.26

C32

6

B_p

y_T1

-06

py

52.3

296

0.0

001

46.2

341

0

0.00

01

0.

0043

0.06

1

0

.013

6

0.

0001

0.0

001

0.00

27

98

.65

C32

6

B_p

y_T1

-07

py

52.4

103

0.0

104

46.3

202

0.0

069

0.01

06

0.

0068

0.06

39

0

.023

7

0.

0058

0.0

001

0.00

01

98

.86

C32

6

B_p

y_T1

-08

py

52.3

854

0.0

033

46.4

218

0

0.00

01

0.

0028

0.06

7

0

.025

2

0.

0027

0.0

001

0.00

01

98

.91

C32

6

B_p

y_T1

-09

py

52.1

155

0.0

001

46.4

241

0

0.00

01

0.

0001

0.07

65

0

.023

8

0.

0088

0.0

001

0.00

01

98

.65

C32

6

B_p

y_T1

-10

py

52.3

414

0.0

001

46.5

704

0

0.00

01

0.

0001

0.06

57

0

.014

5

0.

0001

0.0

001

0.00

01

98

.99

C32

6

B_p

y_T1

-11

py

52.4

0.0

075

46.3

164

0

0.00

01

0.

0001

0.14

13

0

.022

0.

0109

0.0

001

0.00

01

98

.90

C32

6

B_p

y_T1

-12

py

52.0

716

0.0

063

46.2

08

0

0.00

6

0

.015

5

0.

097

0.0

139

0.00

54

0

.000

1

0.

0001

98.4

2 C

326

B

_py_

T1-1

3

py

52

.121

9

0

.012

7

45

.784

0

0.

0077

0.00

01

0.

0891

0.0

167

0.00

71

0

.000

1

0.

0001

98.0

4 C

326

C

_py_

T2-0

1

py

52

.238

1

0

.042

4

46

.196

9

0

.008

1

0.

0089

0.00

01

0.

0883

0.0

187

0.01

02

0

.015

7

0.

0001

98.6

3 C

326

C

_py_

T2-0

2

py

52

.329

6

0

.008

6

46

.364

4

0

.000

2

0.

0001

0.01

16

0.

105

0.0

139

0.00

88

0

.000

1

0.

0001

98.8

4 C

326

C

_py_

T2-0

3

py

52

.065

8

0

.000

1

46

.276

1

0

0.

025

0.0

001

0.08

96

0

.010

2

0.

0106

0.0

001

0.00

01

98

.48

C32

6

C_p

y_T2

-04

py

52.3

504

0.0

001

46.5

542

0

0.00

79

0.

0015

0.05

54

0

.005

9

0.

0001

0.0

045

0.00

01

98

.98

C32

6

C_p

y_T2

-05

py

51.9

487

0.0

294

46.0

259

0

0.00

01

0.

0129

0.05

2

0

.026

0.

0019

0.0

228

0.00

01

98

.12

C32

6

C_p

y_T2

-06

py

52.2

157

0.0

001

46.3

05

0

0.00

01

0.

0102

0.08

98

0

.015

8

0.

0031

0.0

001

0.00

01

98

.64

C32

6

C_p

y_T2

-07

py

51.7

961

0.0

001

46.1

42

0.0

091

0.00

01

0.

0104

0.08

91

0

.017

4

0.

0449

0.0

121

0.01

1

9

8.13

C

326

C

_py_

T2-0

8

py

52

.386

0

.000

1

46

.511

0

.003

7

0.

0001

0.00

01

0.

1031

0.0

154

0.00

01

0

.000

1

0.

0001

99.0

2 C

326

C

_py_

T2-0

9

py

52

.121

7

0

.004

46

.245

7

0

.000

3

0.

0001

0.00

22

0.

0659

0.0

216

0.00

01

0

.028

9

0.

0001

98.4

9 C

326

C

_py_

T2-1

0

py

52

.387

6

0

.013

1

46

.344

0

0.

0007

0.01

37

0.

0617

0.0

139

0.01

7

0.00

01

0

.000

1

98

.85

C32

6

C_p

y_T2

-11

py

52.4

937

0.0

001

46.3

559

0

0.00

91

0.

0048

0.08

09

0

.021

0.

0103

0.0

001

0.00

72

98

.98

C32

6

C_p

y_T2

-12

py

52.2

138

0.0

001

46.2

812

0.0

071

0.00

01

0.

0164

0.21

13

0

.017

5

0.

0229

0.0

001

0.00

01

98

.77

C32

6

C_p

y_T2

-13

py

52.0

631

0.0

127

46.1

996

0

0.01

24

0.

0137

0.25

04

0

.014

6

0.

0079

0.0

001

0.00

01

98

.57

C32

6

C_p

y_T2

-14

py

52.1

505

0.0

1

46.3

876

0

0.00

4

0

.000

1

0.

1554

0.0

137

0.00

01

0

.000

1

0.

0001

98.7

2 C

326

C

_py_

T2-1

5

py

52

.338

5

0

.000

1

46

.076

4

0

0.

0001

0.01

68

0.

1691

0.0

169

0.00

81

0

.002

9

0.

0049

98.6

3 C

326

C

_py_

T2-1

6

py

52

.470

4

0

.000

2

46

.450

1

0

0.

0001

0.00

01

0.

0871

0.0

149

0.00

92

0

.000

1

0.

0001

99.0

3 C

326

C

_py_

T2-1

7

py

52

.358

5

0

.000

1

46

.074

2

0

0.

0001

0.00

01

0.

0951

0.0

158

0.00

01

0

.019

7

0.

0001

98.5

6 C

329

aA

_py_

4

py

52

.154

2

0

.000

1

45

.390

6

0

.002

3

0.

0138

0.07

13

0.

6967

0.0

082

0.00

91

0

.000

1

0.

0001

98.3

5 C

329

aA

_py_

5

py

52

.895

7

0

.005

1

45

.477

4

0

0.

0036

0.02

53

0.

1416

0.0

11

0.00

67

0

.000

1

0.

0001

98.5

7 C

329

aA

_py_

6

py

52

.575

3

0

.003

9

45

.674

6

0

.000

1

0.

007

0.1

102

0.11

89

0

.015

2

0.

0044

0.0

001

0.00

01

98

.51

C32

9

aB_p

y_16

py

5

2.66

25

0.00

6

4

5.66

26

0.01

35

0

.000

1

0.

0001

0.10

69

0

.016

5

0.

0093

0.0

001

0.00

01

98

.48

C32

9

aB_p

y_17

py

5

2.86

6

0.00

01

45

.603

9

0

0.

0152

0.00

45

0.

0791

0.0

212

0.00

01

0

.000

1

0.

0001

98.5

9 C

329

aB

_py_

18

p

y

52.

863

0.

0037

45.7

18

0

0.00

55

0.

0017

0.09

54

0

.013

4

0.

0001

0.0

001

0.00

01

98

.70

C32

9

bA_p

y_1

py

55.0

144

0.0

067

46.0

495

0

0.03

47

0.

0011

0.27

29

0

.017

6

0.

021

0.

0001

0.0

001

101.

42

C32

9

bA_p

y_2

py

54.7

081

0.0

054

46.1

876

0

0.03

3

0

.000

1

0.

2216

0.0

232

0.01

25

0

.000

1

0.

0001

101.

19

sam

ple

poi

nt

typ

e W

%(S

)

W%

(Mn)

W

%(F

e)

W

%(C

o)

W%

(Ni)

W

%(C

u)

W%

(As)

W

%(S

e)

W%

(Ag)

W

%(A

u)

W%

(Bi)

W

%(s

um)

Appendix 4: Microprobe Analysis—Sulphides

24

C32

9

bA_p

y_3

py

54.8

774

0.0

125

46.0

683

0

0.00

2

0

.014

8

0.

094

0.0

177

0.01

45

0

.022

0.

0001

101.

12

C32

9

bC_p

y_16

py

5

4.58

41

0.01

63

46

.394

6

0

0.

0045

0.01

79

0.

0706

0.0

171

0.01

14

0

.000

1

0.

0001

101.

12

C32

9

bC_p

y_17

py

5

5.08

71

0.00

04

46

.202

8

0

0.

0059

0.00

44

0.

0984

0.0

123

0.00

01

0

.000

1

0.

0001

101.

41

C32

9

bC_p

y_18

py

5

5.07

23

0.00

25

46

.282

8

0

0.

0084

0.00

91

0.

12

0.0

204

0.00

01

0

.000

1

0.

0018

101.

52

C33

3

A_p

y_1

p

y

52.

7923

0.

0117

46.3

707

0

0.00

7

0

.005

5

0.

0763

0.0

169

0.02

5

0.00

01

0

.000

1

99

.31

C33

3

A_p

y_2

p

y

52.

9631

0.

0042

46.1

316

0.0

005

0.00

01

0.

008

0.0

728

0.00

71

0.

0001

0.0

001

0.00

01

99

.19

C33

3

A_p

y_3

p

y

52.

8413

0.

0001

46.2

668

0.0

001

0.00

01

0.

0001

0.07

37

0

.027

7

0.

0028

0.0

001

0.00

2

9

9.21

C

333

A

_py_

4

py

5

2.67

54

0.00

01

46

.174

8

0

.008

7

0.

0001

0.01

78

0.

063

0.0

104

0.00

01

0

.000

1

0.

0001

98.9

5 C

333

A

_py_

5

py

5

2.56

05

0.00

32

46

.105

3

0

.008

8

0.

0001

0.01

04

0.

0766

0.0

239

0.01

97

0

.031

3

0.

0001

98.8

4 C

333

A

_py_

6

py

5

2.64

11

0.00

66

45

.961

1

0

.007

4

0.

0055

0.00

01

0.

0871

0.0

242

0.00

08

0

.022

5

0.

0001

98.7

6 C

333

B

_py_

10

py

52

.883

4

0

.002

8

46

.102

1

0

.010

5

0.

0001

0.00

36

0.

0772

0.0

128

0.00

26

0

.000

1

0.

0001

99.1

0 C

333

B

_py_

11

py

52

.800

6

0

.000

1

46

.062

2

0

.002

7

0.

0017

0.00

01

0.

0845

0.0

152

0.01

06

0

.006

7

0.

0001

98.9

8 C

333

B

_py_

12

py

52

.895

0

.000

6

46

.210

5

0

.011

5

0.

0001

0.00

76

0.

0965

0.0

104

0.00

01

0

.000

1

0.

0001

99.2

3 C

333

B

_py_

13

py

52

.859

8

0

.005

1

46

.183

3

0

.003

8

0.

0146

0.00

01

0.

0755

0.0

107

0.00

02

0

.000

1

0.

0042

99.1

6 C

333

B

_py_

14

py

52

.887

6

0

.000

1

45

.817

4

0

.007

5

0.

0055

0.00

01

0.

0737

0.0

173

0.01

23

0

.000

1

0.

0001

98.8

2 C

333

B

_py_

15

py

52

.777

4

0

.000

1

46

.037

8

0

0.

0001

0.01

18

0.

0728

0.0

15

0.01

51

0

.000

1

0.

0001

98.9

3 C

337

A

_py_

1

py

5

1.69

52

0.00

01

46

.438

9

0

0.

0001

0.00

01

0.

1046

0.0

155

0.00

83

0

.000

1

0.

0001

98.2

6 C

337

A

_py_

2

py

5

1.92

13

0.00

01

45

.999

0

.005

1

0.

005

0.0

001

0.08

28

0

.007

0.

0237

0.0

001

0.00

01

98

.04

C33

7

A_p

y_3

p

y

51.

9155

0.

0056

46.2

592

0.0

172

0.00

44

0.

0001

0.13

19

0

.011

8

0.

0058

0.0

001

0.00

01

98

.35

C33

7

B_p

y_10

py

52.1

084

0.0

001

46.5

085

0

0.00

96

0.

0177

0.07

52

0

.014

2

0.

0001

0.0

001

0.00

01

98

.73

C33

7

B_p

y_11

py

52.3

115

0.0

084

46.3

478

0

0.00

86

0.

0042

0.06

89

0

.019

4

0.

007

0.

0013

0.0

001

98.7

8 C

337

B

_py_

12

py

52

.045

4

0

.000

1

46

.325

2

0

0.

0049

0.00

01

0.

0687

0.0

142

0.02

53

0

.000

1

0.

0001

98.4

8 C

341

A

_py_

1

py

5

5.17

57

0.00

21

46

.115

1

0

.003

6

0.

0034

0.00

01

0.

0622

0.0

178

0.01

51

0

.068

8

0.

0095

101.

47

C34

1

A_p

y_2

p

y

55.

1763

0.

0001

46.2

115

0.0

005

0.00

46

0.

0001

0.07

47

0

.016

4

0.

0011

0.0

001

0.00

01

10

1.49

C

341

A

_py_

3

py

5

5.20

45

0.00

19

46

.178

8

0

.001

7

0.

0052

0.01

97

0.

0816

0.0

094

0.00

93

0

.000

1

0.

0001

101.

51

C34

1

D_p

y_19

py

54.2

001

0.0

255

45.7

184

0

0.00

74

0.

0183

0.94

09

0

.024

9

0.

0001

0.0

001

0.00

01

10

0.94

C

341

D

_py_

20

py

54

.938

9

0

.024

9

45

.628

8

0

0.

0093

0.03

25

0.

3861

0.0

181

0.00

01

0

.000

1

0.

0001

101.

04

C34

1

D_p

y_21

py

55.0

363

0.0

388

45.9

927

0

0.00

51

0.

0001

0.49

54

0

.015

9

0.

0001

0.0

001

0.00

01

10

1.58

C

343

A

_py_

1

py

5

3.01

74

0.01

58

45

.631

3

0

.001

0.

0001

0.01

82

0.

074

0.0

112

0.00

05

0

.000

1

0.

0001

98.7

7 C

343

A

_py_

2

py

5

3.08

61

0.00

23

45

.756

9

0

0.

0001

0.00

01

0.

0606

0.0

068

0.00

8

0.00

01

0

.000

1

98

.92

C34

3

A_p

y_3

p

y

53.

072

0.

0001

46.0

441

0

0.00

01

0.

015

0.0

698

0.00

68

0.

0088

0.0

001

0.00

01

99

.22

C34

3

B_p

y_7

p

y

52.

8642

0.

0001

45.5

696

0

0.00

19

0.

0191

0.12

29

0

.011

4

0.

0001

0.0

001

0.00

01

98

.59

C34

3

B_p

y_8

p

y

52.

9527

0.

0047

45.4

387

0.0

116

0.00

39

0.

0001

0.07

69

0

.011

2

0.

0093

0.0

001

0.00

01

98

.51

C34

3

B_p

y_9

p

y

52.

8414

0.

0001

45.9

487

0

0.00

03

0.

0113

0.11

58

0

.016

9

0.

0043

0.0

152

0.00

01

98

.95

C34

5

A_p

y_1

p

y

55.

0126

0.

0164

45.7

245

0.0

145

0.00

01

0.

0237

0.07

33

0

.015

4

0.

0111

0.0

001

0.00

01

10

0.89

C

345

A

_py_

2

py

5

5.03

68

0.00

01

45

.988

0

0.

0001

0.00

01

0.

0727

0.0

233

0.00

93

0

.000

1

0.

0001

101.

13

C34

5

A_p

y_3

p

y

55.

025

0.

0066

46.0

33

0

0.01

33

0.

0126

0.07

46

0

.017

4

0.

0001

0.0

001

0.00

01

10

1.18

C

345

B

_py_

7

py

5

4.95

8

0.00

01

46

.124

0

0.

0081

0.00

59

0.

0775

0.0

198

0.00

12

0

.000

1

0.

0001

101.

19

sam

ple

poi

nt

typ

e W

%(S

)

W%

(Mn)

W

%(F

e)

W

%(C

o)

W%

(Ni)

W

%(C

u)

W%

(As)

W

%(S

e)

W%

(Ag)

W

%(A

u)

W%

(Bi)

W

%(s

um)

Appendix 4: Microprobe Analysis—Sulphides

25

C34

5

B_p

y_8

p

y

55.

0166

0.

0001

46.1

426

0

0.00

01

0.

0202

0.07

88

0

.016

6

0.

005

0.

0001

0.0

001

101.

28

C34

5

B_p

y_9

p

y

54.

9628

0.

0001

46.1

567

0

0.00

15

0.

0001

0.10

07

0

.023

0.

0039

0.0

461

0.00

01

10

1.30

C

350

A

_py_

1

py

5

2.90

41

0.00

08

46

.421

9

0

.002

4

0.

0001

0.00

47

0.

0717

0.0

115

0.00

45

0

.017

8

0.

0001

99.4

4 C

350

A

_py_

2

py

5

2.22

7

0.00

01

45

.874

0

0.

0001

0.00

01

0.

6888

0.0

115

0.01

49

0

.000

1

0.

0001

98.8

2 C

350

A

_py_

3

py

5

2.72

16

0.00

13

46

.059

1

0

.006

9

0.

0001

0.03

43

0.

2267

0.0

257

0.00

16

0

.000

1

0.

0001

99.0

8 C

350

B

_py_

4

py

5

2.69

51

0.00

19

46

.080

2

0

0.

0001

0.00

6

0

.080

7

0.

0172

0.00

93

0

.000

1

0.

0001

98.8

9 C

350

B

_py_

5

py

5

2.96

89

0.01

66

46

.220

7

0

0.

0188

0.01

6

0

.090

8

0.

0168

0.00

24

0

.000

1

0.

0001

99.3

5 C

350

B

_py_

6

py

5

2.85

45

0.00

81

46

.175

6

0

0.

0099

0.00

01

0.

0718

0.0

144

0.00

01

0

.000

1

0.

0001

99.1

3 C

350

C

_py_

10

py

52

.587

5

0

.003

46

.292

8

0

0.

0001

0.00

01

0.

0787

0.0

176

0.00

91

0

.000

1

0.

0001

98.9

9 C

350

C

_py_

11

py

52

.692

3

0

.000

1

46

.159

0

.003

5

0.

0001

0.00

01

0.

0904

0.0

205

0.00

4

0.00

01

0

.000

1

98

.97

C35

0

C_p

y_12

py

52.8

348

0.0

081

45.8

735

0.0

012

0.00

73

0.

0027

0.09

65

0

.009

6

0.

0024

0.0

001

0.00

01

98

.84

C35

3

A_p

y_1

p

y

52.

9587

0.

0001

45.8

401

0

0.00

01

0.

0075

0.05

73

0

.011

9

0.

0001

0.0

123

0.00

01

98

.89

C35

3

A_p

y_2

p

y

53.

0093

0.

0113

45.5

061

0

0.00

01

0.

0001

0.08

01

0

.014

9

0.

0023

0.0

001

0.00

01

98

.62

C35

3

A_p

y_3

p

y

53.

0879

0.

0129

45.7

141

0

0.00

01

0.

0144

0.06

49

0

.013

9

0.

0001

0.0

001

0.00

01

98

.91

C35

3

C_p

y_10

py

53.1

325

0.0

055

45.9

373

0

0.00

01

0.

0001

0.06

22

0

.018

4

0.

0001

0.0

001

0.00

01

99

.16

C35

3

C_p

y_11

py

52.9

778

0.0

333

45.7

997

0

0.00

01

0.

0001

0.07

41

0

.028

2

0.

0001

0.0

001

0.00

01

98

.91

C35

3

C_p

y_12

py

53.0

018

0.0

17

45.6

353

0

0.00

48

0.

0101

0.12

08

0

.009

5

0.

0043

0.0

001

0.00

01

98

.80

C35

5

A_p

y_T1

-01

py

52.7

313

0.0

063

46.2

436

0

0.00

29

0.

0305

0.13

53

0

.017

5

0.

0093

0.0

001

0.00

01

99

.18

C35

5

A_p

y_T1

-02

py

52.5

991

0.0

18

46.0

669

0

0.00

01

0.

0276

0.07

95

0

.022

3

0.

0074

0.0

374

0.00

01

98

.86

C35

5

A_p

y_T1

-03

py

52.4

094

0.0

048

46.2

659

0

0.00

01

0.

0001

0.06

97

0

.012

4

0.

0001

0.0

1

0.0

001

98.7

7 C

355

A

_py_

T1-0

4

py

52

.406

1

0

.002

7

46

.220

1

0

0.

006

0.0

17

0.12

99

0

.010

8

0.

0044

0.0

001

0.00

01

98

.80

C35

5

A_p

y_T1

-05

py

51.8

709

0.0

295

45.6

367

0

0.00

03

0.

8619

0.10

82

0

.012

6

0.

0235

0.0

001

0.00

01

98

.54

C35

5

A_p

y_T1

-06

py

52.1

289

0.0

149

46.0

573

0

0.00

87

0.

0173

0.53

17

0

.018

9

0.

0005

0.0

001

0.00

01

98

.78

C35

5

A_p

y_T1

-07

py

52.3

837

0.0

001

46.4

62

0

0.00

72

0.

0081

0.06

45

0

.018

3

0.

0005

0.0

218

0.00

01

98

.97

C35

5

A_p

y_T1

-08

py

52.2

036

0.0

001

46.4

409

0

0.00

01

0.

0001

0.06

41

0

.016

4

0.

0014

0.0

031

0.00

01

98

.73

C35

5

A_p

y_T1

-09

py

52.0

774

0.0

056

46.4

381

0

0.00

01

0.

015

0.1

169

0.01

45

0.

0028

0.0

001

0.00

01

98

.67

C35

5

A_p

y_T1

-10

py

52.4

275

0.0

001

46.4

179

0

0.00

45

0.

0001

0.06

49

0

.012

4

0.

0018

0.0

001

0.00

01

98

.93

C35

5

A_p

y_T2

-01

py

52.1

37

0.0

046

46.0

955

0.0

028

0.00

01

0.

0249

0.07

67

0

.025

1

0.

0236

0.0

001

0.00

01

98

.39

C35

5

A_p

y_T2

-02

py

52.3

2

0.0

001

46.3

278

0.0

039

0.00

01

0.

0001

0.08

35

0

.015

6

0.

0001

0.0

186

0.00

01

98

.77

C35

5

A_p

y_T2

-03

py

52.3

338

0.0

109

46.4

644

0.0

05

0.00

01

0.

0001

0.07

12

0

.019

7

0.

0084

0.0

001

0.00

01

98

.91

C35

5

A_p

y_T2

-04

py

52.4

974

0.0

001

46.4

5

0.

0266

0.0

024

0.00

01

0.

0684

0.0

136

0.01

39

0

.000

1

0.

0001

99.0

7 C

355

A

_py_

T2-0

5

py

52

.331

8

0

.012

1

46

.209

1

0

0.

0001

0.00

07

0.

153

0.0

175

0.00

01

0

.000

1

0.

0001

98.7

2 C

355

A

_py_

T2-0

7

py

52

.247

0

.000

1

46

.244

5

0

.003

6

0.

0001

0.00

01

0.

0664

0.0

206

0.00

01

0

.000

1

0.

0001

98.5

8 C

355

A

_py_

T2-0

8

py

52

.486

2

0

.004

8

46

.398

6

0

.002

0.

0001

0.00

52

0.

0893

0.0

139

0.00

01

0

.000

1

0.

0001

99.0

0 C

355

A

_py_

T2-0

9

py

52

.154

7

0

.000

1

46

.313

3

0

0.

0054

0.00

01

0.

075

0.0

105

0.01

72

0

.000

1

0.

0078

98.5

8 C

355

A

_py_

T3-0

1

py

52

.079

7

0

.000

1

46

.097

3

0

0.

0077

0.02

01

0.

0731

0.0

196

0.01

24

0

.000

1

0.

0001

98.3

1 C

355

A

_py_

T3-0

2

py

52

.065

3

0

.007

1

46

.138

5

0

0.

0116

0.00

94

0.

0789

0.0

108

0.00

01

0

.000

1

0.

0001

98.3

2 C

355

A

_py_

T3-0

3

py

52

.236

4

0

.000

1

46

.250

6

0

.034

5

0.

0001

0.00

01

0.

0672

0.0

132

0.00

62

0

.000

1

0.

0001

98.6

1

sam

ple

poi

nt

typ

e W

%(S

)

W%

(Mn)

W

%(F

e)

W

%(C

o)

W%

(Ni)

W

%(C

u)

W%

(As)

W

%(S

e)

W%

(Ag)

W

%(A

u)

W%

(Bi)

W

%(s

um)

Appendix 4: Microprobe Analysis—Sulphides

26

C35

5

A_p

y_T3

-04

py

52.4

6

0.

0036

46.

2622

0

0.

0001

0.03

49

0

.088

0.

0201

0.00

92

0

.000

1

0.

0001

98.

88

C35

5

A_p

y_T3

-05

py

52.0

502

0.0

001

46.3

596

0

0.0

001

0.00

01

0

.065

2

0.

0125

0.00

01

0

.017

0.

0001

98.

51

C35

5

A_p

y_T3

-06

py

52.1

008

0.0

013

46.3

331

0

0.0

087

0.00

37

0

.066

5

0.

0273

0.00

01

0

.016

5

0.

0001

98.

56

C35

5

A_p

y_T3

-07

py

52.0

723

0.0

001

46.4

896

0.0

024

0.00

77

0.

0037

0.0

876

0.01

17

0.

0005

0.0

001

0.00

01

9

8.68

C

355

A

_py_

T3-0

8

py

52

.163

7

0

.002

7

46

.511

2

0

.000

7

0.

0003

0.00

15

0

.079

5

0.

0164

0.00

28

0

.000

1

0.

0001

98.

78

C35

5

A_p

y_T3

-09

py

52.0

819

0.0

001

46.6

248

0

0.0

04

0.00

01

0

.077

5

0.

0147

0.00

44

0

.000

1

0.

0001

98.

81

C35

7

B_p

y_4

p

y

53

.076

8

0

.000

1

45

.204

6

0

0

.012

9

0.

0102

0.0

748

0.02

35

0.

0146

0.0

001

0.00

01

9

8.42

C

357

B

_py_

5

py

52.7

06

0.0

001

45.4

586

0.0

018

0.00

01

0.

0001

0.0

591

0.01

55

0.

0044

0.0

001

0.00

01

9

8.25

C

357

B

_py_

6

py

53.0

114

0.0

038

45.2

799

0

0.0

001

0.01

13

0

.077

0.

0236

0.01

81

0

.000

1

0.

0001

98.

43

C35

7

C_p

y_7

p

y

52

.821

4

0

.000

1

45

.179

1

0

0

.003

2

0.

0197

0.2

838

0.01

23

0.

0053

0.0

001

0.00

01

9

8.33

C

357

C

_py_

8

py

52.8

323

0.0

001

45.5

889

0

0.0

037

0.00

01

0

.139

4

0.

0226

0.00

33

0

.020

7

0.

0001

98.

61

C35

7

C_p

y_9

p

y

52

.981

6

0

.015

45

.810

3

0

0

.003

7

0.

0022

0.0

916

0.02

49

0.

0001

0.0

001

0.00

01

9

8.93

C

357

D

_py_

10

py

53

.027

0

.000

1

45

.676

3

0

.086

0.

0001

0.00

01

0

.073

6

0.

0143

0.01

27

0

.005

0.

0001

98.

90

C35

7

D_p

y_11

py

53.0

694

0.0

035

45.6

75

0

0.0

05

0.00

5

0.09

32

0

.007

4

0.

0044

0.0

001

0.00

01

9

8.86

C

357

D

_py_

12

py

52

.906

6

0

.002

7

45

.514

5

0

0

.008

4

0.

0126

0.0

73

0.01

11

0.

0074

0.0

001

0.00

14

9

8.54

C

359

A

_py_

1

py

52.9

171

0.0

121

45.6

074

0.0

081

0.00

43

0.

0137

0.0

677

0.00

74

0.

0065

0.0

083

0.00

07

9

8.65

C

359

A

_py_

2

py

52.8

529

0.0

001

45.5

705

0

0.0

056

0.01

11

0

.063

5

0.

0059

0.00

01

0

.000

1

0.

0001

98.

51

C35

9

A_p

y_3

p

y

52

.986

3

0

.003

1

45

.207

2

0

0

.001

0.

0024

0.0

563

0.01

96

0.

0001

0.0

001

0.00

01

9

8.28

C

359

B_

py_1

0

py

53

.070

4

0

.004

9

45

.668

5

0

0

.000

1

0.

0143

0.0

702

0.01

88

0.

0122

0.0

001

0.00

01

9

8.86

C

359

B_

py_1

1

py

53

.021

7

0

.025

45

.906

1

0

.001

7

0.

0001

0.00

01

0

.071

1

0.

0146

0.02

59

0

.000

1

0.

0001

99.

07

C35

9

B_py

_12

py

53.0

166

0.0

025

45.3

974

0.0

091

0.01

53

0.

0173

0.0

697

0.00

6

0

.000

1

0.

0192

0.00

01

9

8.55

C

362

B

_py_

7

py

52.5

715

0.0

021

45.9

71

0.0

004

0.00

01

0.

0001

0.1

316

0.02

71

0.

0001

0.0

001

0.00

01

9

8.70

C

362

B

_py_

8

py

52.5

217

0.0

025

45.7

217

0

0.0

001

0.01

13

0

.086

0.

0175

0.00

52

0

.000

1

0.

0001

98.

37

C36

2

B_p

y_9

p

y

52

.699

7

0

.000

1

45

.777

3

0

0

.000

1

0.

0001

0.1

095

0.01

65

0.

0079

0.0

001

0.01

27

9

8.62

C

362

C

_py_

16

py

52

.696

0

.002

3

46

.167

5

0

0

.005

6

0.

1059

0.0

818

0.01

72

0.

0175

0.0

001

0.00

91

9

9.10

C

362

C

_py_

17

py

52

.676

6

0

.000

1

45

.947

6

0

0

.007

3

0.

0363

0.0

987

0.01

3

0

.000

1

0.

0001

0.00

01

9

8.78

C

362

C

_py_

18

py

52

.556

6

0

.000

1

46

.251

3

0

0

.000

1

0.

0487

0.0

817

0.00

62

0.

0064

0.0

363

0.00

01

9

8.99

C

362

C

_py_

19

py

52

.631

4

0

.003

2

45

.451

0

0

.02

0.

0001

0.1

051

0.01

14

0.

0141

0.0

001

0.00

01

9

8.24

C

362

C

_py_

20

py

52

.541

2

0

.011

7

46

.016

3

0

0

.000

1

0.

0001

0.2

368

0.01

31

0.

0001

0.0

001

0.00

01

9

8.82

C

362

C

_py_

21

py

52

.580

4

0

.005

7

45

.773

9

0

.001

9

0.

001

0.0

001

0.09

81

0

.022

1

0.

0033

0.0

001

0.00

01

9

8.49

C

364

A

_py_

1

py

53.0

415

0.0

001

46.1

902

0

0.0

101

0.00

01

0

.083

2

0.

0176

0.01

25

0

.000

1

0.

0001

99.

36

C36

4

A_p

y_2

p

y

53

.130

2

0

.013

2

45

.787

4

0

0

.000

1

0.

0001

0.0

84

0.01

77

0.

0145

0.0

001

0.00

01

9

9.05

C

364

A

_py_

3

py

52.8

586

0.0

236

45.8

152

0

0.0

001

0.00

05

0

.088

6

0.

0196

0.00

61

0

.017

5

0.

0001

98.

83

C36

4

B_py

_19

py

53.0

223

0.0

162

45.8

59

0

0.0

001

0.01

53

0

.060

5

0.

0054

0.00

72

0

.000

1

0.

0091

99.

00

C36

4

B_py

_20

py

53.0

111

0.0

001

45.9

91

0

0.0

001

0.00

62

0

.071

4

0.

0093

0.02

51

0

.000

1

0.

0001

99.

11

C36

4

B_py

_21

py

52.7

583

0.0

001

46.0

419

0.0

014

0.00

01

0.

0053

0.0

771

0.01

18

0.

0031

0.0

001

0.00

01

9

8.90

C

365

A

_py_

1

py

53.1

189

0.0

001

45.3

418

0.0

067

0.00

01

0.

0041

0.0

702

0.01

54

0.

008

0.0

1

0.00

01

9

8.58

C

365

A

_py_

2

py

53.0

778

0.0

001

45.2

76

0

0.0

04

0.00

7

0.06

54

0

.007

2

0.

0001

0.0

001

0.00

01

9

8.44

sam

ple

poi

nt

typ

e W

%(S

)

W

%(M

n)

W%

(Fe)

W%

(Co)

W

%(N

i)

W%

(Cu)

W

%(A

s)

W%

(Se)

W

%(A

g)

W%

(Au)

W

%(B

i)

W%

(sum

)

Appendix 4: Microprobe Analysis—Sulphides

27

C36

5

A_p

y_3

p

y

52.

9496

0.

0001

45.7

021

0

0.00

91

0.

0092

0.08

53

0

.016

6

0.

0001

0.0

001

0.00

01

98

.77

C36

5

B_p

y_10

py

53.0

034

0.0

019

45.1

847

0

0.00

01

0.

0001

0.06

26

0

.011

0.

0076

0.0

001

0.00

01

98

.27

C36

5

B_p

y_11

py

52.8

757

0.0

088

45.5

28

0.0

04

0.01

06

0.

0144

0.06

96

0

.022

7

0.

0001

0.0

001

0.00

79

98

.54

C36

5

B_p

y_12

py

52.8

738

0.0

001

45.0

825

0.0

136

0.00

01

0.

0001

0.07

36

0

.021

4

0.

0172

0.0

001

0.00

01

98

.08

C36

5

B_p

y_7

p

y

51.

4385

0.

0001

44.9

181

0

0.00

35

0.

0007

2.52

15

0

.032

0.

015

0.

0003

0.0

001

98.9

3 C

365

B

_py_

8

py

5

2.62

4

0.00

29

45

.469

4

0

0.

0096

0.18

0

.090

8

0.

0161

0.00

78

0

.000

1

0.

0001

98.4

0 C

365

B

_py_

9

py

5

3.14

25

0.00

29

45

.678

0

0.

0001

0.01

55

0.

0738

0.0

123

0.00

36

0

.000

1

0.

0001

98.9

3 C

365

C

_py_

16

py

53

.191

0

.010

7

45

.825

4

0

.005

3

0.

0001

0.00

01

0.

0685

0.0

142

0.01

03

0

.000

1

0.

0001

99.1

3 C

365

C

_py_

17

py

52

.853

0

.000

1

45

.537

9

0

0.

0001

0.00

01

0.

0707

0.0

134

0.00

08

0

.000

1

0.

0001

98.4

8 C

365

C

_py_

18

py

53

.355

4

0

.000

1

45

.331

1

0

.009

1

0.

0067

0.00

06

0.

0754

0.0

154

0.00

78

0

.000

1

0.

0001

98.8

0 C

369

A

_py_

1

py

5

5.14

32

0.00

01

46

.162

2

0

0.

0047

0.01

02

0.

0675

0.0

112

0.00

48

0

.000

1

0.

0001

101.

40

C36

9

A_p

y_2

p

y

55.

0099

0.

0039

46.2

563

0

0.00

69

0.

0001

0.08

81

0

.010

2

0.

0048

0.0

001

0.00

01

10

1.38

C

369

A

_py_

3

py

5

5.12

81

0.00

48

45

.951

3

0

.064

6

0.

0143

0.00

2

0

.123

4

0.

0149

0.00

17

0

.000

1

0.

0001

101.

31

C36

9

B_p

y_7

p

y

54.

8624

0.

0067

46.0

292

0.0

049

0.00

35

0.

0113

0.13

5

0

.018

9

0.

0001

0.0

001

0.00

01

10

1.07

C

369

B

_py_

8

py

5

4.86

0.00

12

46

.249

7

0

.001

5

0.

0001

0.00

81

0.

0833

0.0

094

0.00

01

0

.000

1

0.

0001

101.

21

C36

9

B_p

y_9

p

y

55.

0788

0.

004

46.

2116

0.

0178

0.0

001

0.00

19

0.

0816

0.0

059

0.01

45

0

.000

1

0.

0001

101.

42

C37

2

A_p

y_4

p

y

54.

8668

0.

0001

45.5

332

0.0

105

0.00

01

0.

0001

0.13

75

0

.016

9

0.

0107

0.0

001

0.00

01

10

0.58

C

372

A

_py_

5

py

5

4.49

79

0.00

94

45

.639

1

0

0.

0001

0.00

01

0.

2132

0.0

226

0.01

61

0

.000

1

0.

0001

100.

40

C37

2

A_p

y_6

p

y

54.

5679

0.

0009

45.7

272

0

0.00

01

0.

0101

0.25

72

0

.016

6

0.

0022

0.0

229

0.00

01

10

0.61

C

372

B

_py_

10

py

54

.664

1

0

.000

1

44

.536

3

0

.015

2

0.

0001

0.00

88

0.

486

0.0

192

0.00

57

0

.000

1

0.

0001

99.7

4 C

372

B

_py_

11

py

54

.691

7

0

.000

1

45

.069

2

0

0.

0001

0.00

01

0.

2817

0.0

189

0.01

56

0

.000

1

0.

0001

100.

08

C37

2

B_p

y_12

py

54.9

591

0.0

001

45.8

252

0

0.00

27

0.

0001

0.15

26

0

.023

1

0.

0049

0.0

001

0.00

01

10

0.97

C

378

A

_py_

1

py

5

2.67

9

0.00

91

46

.029

7

0

0.

0147

0.01

18

0.

083

0.0

17

0.00

47

0

.000

1

0.

0001

98.8

5 C

378

A

_py_

2

py

5

2.61

79

0.00

01

45

.882

1

0

0.

0071

0.00

01

0.

1173

0.0

157

0.01

62

0

.027

3

0.

0001

98.6

8 C

378

A

_py_

3

py

5

3.01

59

0.00

01

45

.952

7

0

0.

0001

0.00

01

0.

064

0.0

151

0.00

29

0

.000

1

0.

0001

99.0

5 C

378

B

_py_

4

py

5

2.59

24

0.00

23

45

.873

8

0

0.

0038

0.00

01

0.

1945

0.0

243

0.00

01

0

.000

1

0.

0001

98.6

9 C

378

B

_py_

5

py

5

2.73

92

0.00

92

45

.948

0

0.

0001

0.00

01

0.

1583

0.0

061

0.00

21

0

.000

1

0.

0001

98.8

6 C

378

B

_py_

6

py

5

2.75

83

0.00

01

46

.168

0

0.

0111

0.00

42

0.

2149

0.0

237

0.00

62

0

.000

1

0.

0001

99.1

9 C

379

A

_py_

1

py

5

4.82

55

0.00

01

45

.376

6

0

.007

2

0.

005

0.0

001

0.06

28

0

.009

3

0.

0108

0.0

001

0.00

01

10

0.30

C

379

A

_py_

1

py

5

2.88

25

0.01

04

45

.567

9

0

0.

0001

0.00

01

0.

072

0.0

112

0.01

07

0

.000

1

0.

0001

98.5

6 C

379

A

_py_

2

py

5

3.10

06

0.00

79

45

.109

4

0

0.

0055

0.00

01

0.

0698

0.0

131

0.00

13

0

.000

1

0.

0001

98.3

1 C

379

A

_py_

2

py

5

5.12

42

0.00

01

45

.662

4

0

.006

3

0.

0001

0.00

82

0.

0588

0.0

211

0.00

41

0

.000

1

0.

0001

100.

89

C37

9

A_p

y_3

p

y

53.

2897

0.

0036

45.1

862

0.0

126

0.00

44

0.

0102

0.07

05

0

.018

6

0.

0008

0.0

001

0.00

01

98

.60

C37

9

A_p

y_3

p

y

55.

1155

0.

0001

45.5

96

0

0.00

83

0.

0001

0.06

33

0

.019

5

0.

0067

0.0

001

0.00

01

10

0.81

C

379

B

_py_

7

py

5

2.84

41

0.00

4

4

5.46

68

0

0.00

03

0.

0001

0.06

47

0

.009

8

0.

0001

0.0

001

0.00

01

98

.39

C37

9

B_p

y_7

p

y

55.

2126

0.

0087

46.2

27

0.0

015

0.00

01

0.

0217

0.06

7

0

.019

7

0.

0001

0.0

001

0.00

01

10

1.56

C

379

B

_py_

8

py

5

2.86

05

0.00

01

45

.403

1

0

.000

7

0.

0001

0.00

01

0.

0626

0.0

189

0.02

5

0.00

01

0

.000

1

98

.37

C37

9

B_p

y_8

p

y

55.

0461

0.

0106

46.0

566

0

0.00

53

0.

0001

0.07

07

0

.020

9

0.

012

0.

0001

0.0

001

101.

22

sam

ple

poi

nt

typ

e W

%(S

)

W%

(Mn)

W

%(F

e)

W

%(C

o)

W%

(Ni)

W

%(C

u)

W%

(As)

W

%(S

e)

W%

(Ag)

W

%(A

u)

W%

(Bi)

W

%(s

um)

Appendix 4: Microprobe Analysis—Sulphides

28

C37

9

B_p

y_9

p

y

53.

0066

0.

0094

45.3

579

0

0.01

06

0.

0001

0.05

87

0

.020

1

0.

0064

0.0

001

0.00

01

98

.47

C37

9

B_p

y_9

p

y

55.

2355

0.

0001

45.9

342

0

0.00

01

0.

0062

0.07

26

0

.011

4

0.

0001

0.0

001

0.00

01

10

1.26

C

379

C

_py_

16

py

55

.018

5

0

.011

9

45

.223

8

0

0.

0001

0.00

6

0

.087

7

0.

0104

0.00

57

0

.037

2

0.

0001

100.

40

C37

9

C_p

y_16

py

53.0

427

0.0

008

45.2

451

0

0.00

01

0.

0001

0.07

43

0

.019

7

0.

0019

0.0

001

0.00

01

98

.38

C37

9

C_p

y_17

py

53.0

054

0.0

001

44.8

529

0

0.00

02

0.

0044

0.06

67

0

.024

7

0.

0121

0.0

001

0.00

01

97

.97

C37

9

C_p

y_17

py

55.0

28

0.0

001

44.9

944

0

0.01

23

0.

0049

0.06

28

0

.018

8

0.

0046

0.0

001

0.00

01

10

0.13

C

379

C

_py_

18

py

54

.819

1

0

.000

1

45

.438

8

0

0.

0022

0.00

01

0.

0734

0.0

117

0.00

14

0

.000

1

0.

0001

100.

35

C37

9

C_p

y_18

py

52.9

741

0.0

001

45.5

259

0

0.00

01

0.

0001

0.06

24

0

.014

4

0.

0043

0.0

089

0.00

01

98

.59

C38

1

B_p

y_10

py

52.5

958

0.0

834

45.6

269

0

0.01

35

0.

0001

0.59

16

0

.017

8

0.

0131

0.0

001

0.00

01

98

.94

C38

1

B_p

y_11

py

52.8

488

0.0

694

45.7

286

0

0.00

01

0.

0152

0.24

67

0

.024

6

0.

0046

0.0

001

0.00

01

98

.94

C38

1

B_p

y_12

py

52.5

356

0.0

489

45.7

238

0

0.00

39

0.

0001

0.62

47

0

.018

4

0.

0001

0.0

001

0.00

01

98

.96

C38

3

A_p

y_1

p

y

52.

9155

0.

0001

45.8

983

0

0.00

61

0.

0047

0.06

65

0

.014

7

0.

0001

0.0

001

0.00

01

98

.91

C38

3

A_p

y_2

p

y

52.

9632

0.

0223

46.0

083

0

0.00

01

0.

0001

0.06

45

0

.013

6

0.

0098

0.0

001

0.00

01

99

.08

C38

3

A_p

y_3

p

y

52.

8728

0.

0001

45.8

524

0

0.02

94

0.

0001

0.06

01

0

.017

1

0.

0064

0.0

001

0.00

01

98

.84

C38

3

B_p

y_10

py

52.6

514

0.0

025

46.5

23

0

0.00

01

0.

0001

0.06

59

0

.022

3

0.

0078

0.0

292

0.00

13

99

.30

C38

3

B_p

y_11

py

52.5

514

0.0

04

46.2

192

0

0.00

07

0.

0053

0.07

05

0

.019

9

0.

0017

0.0

001

0.00

01

98

.87

C38

3

B_p

y_12

py

52.9

942

0.0

001

46.3

006

0.0

003

0.00

01

0.

0001

0.07

74

0

.020

2

0.

003

0.

0001

0.0

001

99.4

0 C

385

A

_py_

4

py

5

5.01

52

0.00

39

44

.676

2

0

.008

3

0.

0001

0.00

51

0.

0996

0.0

044

0.00

01

0

.000

1

0.

0001

99.8

1 C

385

A

_py_

5

py

5

5.14

17

0.00

01

44

.584

3

0

.021

8

0.

0107

0.00

48

0.

0879

0.0

123

0.00

57

0

.000

1

0.

0001

99.8

7 C

385

A

_py_

6

py

5

5.03

56

0.00

01

44

.458

1

0

0.

0001

0.00

54

0.

0717

0.0

207

0.00

01

0

.000

1

0.

0001

99.5

9 C

385

C

_py_

16

py

54

.916

5

0

.001

2

44

.524

1

0

0.

0001

0.00

01

0.

0737

0.0

087

0.00

83

0

.000

1

0.

0001

99.5

3 C

385

C

_py_

17

py

54

.914

2

0

.000

1

45

.458

9

0

0.

0071

0.00

01

0.

061

0.0

153

0.00

08

0

.000

1

0.

0001

100.

46

C38

5

C_p

y_18

py

55.0

651

0.0

001

44.5

534

0

0.01

19

0.

0001

0.06

38

0

.007

9

0.

0114

0.0

001

0.00

01

99

.71

C79

4

A_p

y_1

p

y

54.

0338

0.

0001

46.7

442

0

0.00

01

0.

0001

0.07

24

0

.022

2

0.

0001

0.0

001

0.00

01

10

0.87

C

794

A

_py_

2

py

5

4.12

76

0.01

27

46

.898

4

0

0.

0001

0.01

15

0.

0765

0.0

15

0.01

26

0

.018

5

0.

0001

101.

17

C79

4

A_p

y_3

p

y

53.

8586

0.

004

46.

5009

0.

0005

0.0

129

0.00

01

0.

0706

0.0

252

0.00

01

0

.000

1

0.

0001

100.

47

C79

5

A_p

y_1

p

y

53.

1931

0.

0117

47.6

583

0

0.00

01

0.

0001

0.27

08

0

.012

0.

0135

0.0

001

0.00

01

10

1.16

C

795

A

_py_

2

py

5

3.25

66

0.00

01

47

.467

8

0

0.

0055

0.01

43

0.

0973

0.0

239

0.01

3

0.00

81

0

.000

1

10

0.89

C

795

A

_py_

3

py

5

3.28

74

0.00

01

47

.696

4

0

.001

1

0.

0001

0.00

39

0.

059

0.0

08

0.00

39

0

.000

1

0.

0001

101.

06

C79

7

A_p

y_1

p

y

53.

326

0.

0094

47.7

66

0

0.02

11

0.

0001

0.07

28

0

.028

0.

0047

0.0

001

0.00

01

10

1.23

C

797

A

_py_

2

py

5

3.56

45

0.00

75

47

.808

5

0

.005

5

0.

0066

0.00

01

0.

0598

0.0

077

0.00

3

0.00

01

0

.000

1

10

1.46

C

797

A

_py_

3

py

5

3.30

63

0.00

66

47

.882

9

0

0.

0084

0.00

01

0.

0985

0.0

207

0.00

01

0

.000

1

0.

0001

101.

32

C80

1

A_p

y_1

p

y

53.

0281

0.

0081

47.4

517

0

0.00

01

0.

0001

0.06

44

0

.012

3

0.

0002

0.0

001

0.00

01

10

0.57

C

801

A

_py_

2

py

5

3.01

06

0.00

01

47

.415

3

0

0.

0001

0.00

01

0.

0667

0.0

167

0.00

36

0

.000

1

0.

0001

100.

51

C80

1

A_p

y_3

p

y

53.

4149

0.

0089

47.4

662

0

0.00

01

0.

0001

0.07

85

0

.015

8

0.

0001

0.0

001

0.00

13

10

0.99

C

802

B

_py_

4

py

5

3.62

26

0.00

23

47

.416

6

0

.025

9

0.

0001

0.02

33

0.

1281

0.0

153

0.01

93

0

.000

1

0.

0004

101.

25

C80

2

B_p

y_5

p

y

53.

803

0.

003

47.

2164

0.

0288

0.0

001

0.00

01

0.

1157

0.0

116

0.00

01

0

.000

1

0.

0001

101.

18

C80

2

B_p

y_6

p

y

53.

179

0.

0001

47.0

592

0.0

294

0.00

15

0.

003

0.2

003

0.01

49

0.

0041

0.0

13

0.00

01

10

0.50

sam

ple

poi

nt

typ

e W

%(S

)

W%

(Mn)

W

%(F

e)

W

%(C

o)

W%

(Ni)

W

%(C

u)

W%

(As)

W

%(S

e)

W%

(Ag)

W

%(A

u)

W%

(Bi)

W

%(s

um)

Appendix 4: Microprobe Analysis—Sulphides

29

C80

3

A_p

y_1

p

y

53.

7238

0.

0057

46.4

979

0.0

03

0.00

47

0.

0001

0.09

12

0

.009

6

0.

0163

0.0

001

0.00

01

10

0.35

C

803

A

_py_

2

py

5

3.83

12

0.00

32

46

.940

8

0

0.

0089

0.00

96

0.

1018

0.0

195

0.01

31

0

.000

1

0.

0002

100.

93

C80

3

A_p

y_3

p

y

53.

6781

0.

0001

46.5

968

0

0.00

01

0.

0441

0.22

36

0

.021

9

0.

0001

0.0

001

0.00

09

10

0.57

C

804

B

_py_

4

py

5

3.75

46

0.14

77

46

.753

3

0

0.

0023

0.00

26

0.

0876

0.0

118

0.00

01

0

.044

2

0.

0308

100.

84

C80

4

B_p

y_5

p

y

52.

2461

0.

013

45.

2033

0

0.

0062

0.21

51

2.

9675

0.0

417

0.01

4

0.00

01

0

.000

1

10

0.71

C

804

B

_py_

6

py

5

3.93

41

0.00

59

46

.622

5

0

0.

0001

0.03

39

0.

282

0.0

206

0.00

01

0

.002

1

0.

0001

100.

90

C81

2

A_p

y_1

p

y

53.

0321

0.

0038

47.1

349

0

0.09

39

0.

0001

0.37

08

0

.019

7

0.

0061

0.0

073

0.00

01

10

0.67

C

812

A

_py_

2

py

5

3.12

27

0.00

77

47

.190

1

0

0.

0428

0.00

01

0.

1938

0.0

113

0.00

91

0

.000

1

0.

0001

100.

58

C81

2

A_p

y_3

p

y

53.

2209

0.

0017

47.2

698

0

0.04

01

0.

0115

0.18

35

0

.015

2

0.

0098

0.0

057

0.00

01

10

0.76

C

813

B

_py_

4

py

5

3.20

5

0.00

04

47

.842

3

0

.003

8

0.

0055

0.00

01

0.

078

0.0

095

0.00

81

0

.013

8

0.

0001

101.

17

C81

3

B_p

y_5

p

y

53.

1588

0.

0062

47.6

706

0.0

075

0.00

34

0.

0001

0.08

12

0

.009

5

0.

0164

0.0

001

0.00

01

10

0.95

C

813

B

_py_

6

py

5

3.58

95

0.01

44

47

.567

7

0

0.

0084

0.00

01

0.

0767

0.0

165

0.00

01

0

.000

1

0.

0001

101.

27

C81

5

A_p

y_1

p

y

53.

3421

0.

0074

47.9

216

0

0.03

6

0

.015

6

0.

0839

0.0

184

0.00

82

0

.000

1

0.

0001

101.

43

C81

5

A_p

y_2

p

y

53.

1156

0.

0001

47.9

754

0

0.01

53

0.

0001

0.09

55

0

.014

0.

0095

0.0

001

0.00

01

10

1.23

C

815

A

_py_

3

py

5

3.19

39

0.00

01

47

.733

5

0

0.

0037

0.01

61

0.

1012

0.0

13

0.00

49

0

.000

1

0.

0001

101.

07

C81

7

B_p

y_4

p

y

54.

0448

0.

0034

46.5

017

0.0

086

0.00

74

0.

0001

0.12

36

0

.017

9

0.

0053

0.0

001

0.00

01

10

0.71

C

817

B

_py_

5

py

5

4.25

05

0.00

01

46

.919

0

0.

0001

0.00

01

0.

1184

0.0

214

0.00

17

0

.005

7

0.

0001

101.

32

C81

7

B_p

y_6

p

y

54.

2582

0.

0001

46.7

372

0

0.00

65

0.

0089

0.10

31

0

.016

5

0.

0162

0.0

001

0.00

01

10

1.15

C

820

A

_py_

1

py

5

2.93

17

0.01

39

47

.778

4

0

0.

0001

0.00

01

0.

1495

0.0

245

0.01

08

0

.000

1

0.

0001

100.

91

C82

0

A_p

y_2

p

y

52.

5005

0.

0028

47.7

357

0

0.00

01

0.

0001

0.50

76

0

.009

3

0.

0129

0.0

568

0.00

01

10

0.83

C

820

A

_py_

3

py

5

2.96

86

0.04

29

47

.689

3

0

0.

0008

0.00

59

0.

2202

0.0

188

0.01

11

0

.000

1

0.

0001

100.

96

C82

3

A_p

y_1

p

y

52.

7651

0.

0013

47.7

787

0

0.01

85

0.

0154

0.06

43

0

.021

9

0.

0001

0.0

001

0.00

01

10

0.67

C

823

A

_py_

2

py

5

3.32

02

0.00

17

48

.026

3

0

0.

0001

0.00

78

0.

0605

0.0

259

0.00

57

0

.038

7

0.

0001

101.

49

C82

3

A_p

y_3

p

y

53.

0077

0.

0036

48.0

401

0

0.01

01

0.

0001

0.07

86

0

.009

9

0.

0062

0.0

057

0.00

01

10

1.16

C

824

B

_py_

4

py

5

2.98

73

0.00

01

47

.472

7

0

0.

0042

0.01

57

0.

1721

0.0

136

0.01

41

0

.000

1

0.

0001

100.

68

C82

4

B_p

y_5

p

y

53.

1274

0.

0045

47.5

9

0

0.

0017

0.00

01

0.

1089

0.0

119

0.00

36

0

.000

1

0.

0001

100.

85

C82

4

B_p

y_6

p

y

53.

1649

0.

007

47.

4779

0

0.

0001

0.00

3

0

.184

9

0.

0176

0.00

3

0.02

56

0

.000

1

10

0.88

C

825

A

_py_

1

py

5

3.36

97

0.01

08

47

.716

5

0

.027

2

0.

0195

0.00

57

0.

0869

0.0

156

0.00

22

0

.001

8

0.

0001

101.

26

C82

5

A_p

y_2

p

y

53.

0177

0.

0001

47.3

181

0.0

304

0.00

01

0.

0094

0.09

13

0

.019

7

0.

0036

0.0

029

0.00

01

10

0.49

C

825

A

_py_

3

py

5

3.03

56

0.00

01

47

.268

5

0

0.

0313

0.00

01

0.

0902

0.0

049

0.00

01

0

.000

1

0.

0001

100.

43

C82

8

A_p

y_1

p

y

52.

9792

0.

0001

47.5

161

0

0.00

01

0.

0265

0.08

05

0

.015

6

0.

0001

0.0

001

0.00

01

10

0.62

C

828

A

_py_

2

py

5

2.78

24

0.00

17

47

.472

3

0

0.

0055

0.00

83

0.

1072

0.0

093

0.01

19

0

.000

1

0.

0001

100.

40

C82

8

A_p

y_3

p

y

53.

3193

0.

0023

47.6

55

0

0.00

25

0.

0239

0.14

36

0

.015

6

0.

0029

0.0

001

0.00

01

10

1.17

C

832

A

_py_

1

py

5

3.86

33

0.00

01

46

.924

2

0

0.

0001

0.00

94

0.

0645

0.0

139

0.00

07

0

.000

1

0.

0001

100.

88

C83

2

A_p

y_2

p

y

53.

9892

0.

0115

46.4

19

0

0.00

01

0.

0001

0.06

45

0

.026

1

0.

0054

0.0

001

0.00

01

10

0.52

C

832

A

_py_

3

py

5

3.81

15

0.00

77

46

.843

5

0

0.

0032

0.00

22

0.

0692

0.0

189

0.00

01

0

.000

1

0.

01

100

.77

C83

4

A_p

y_1

p

y

52.

8983

0.

0141

47.3

896

0

0.00

01

0.

0813

0.07

58

0

.009

0.

0001

0.0

001

0.00

01

10

0.47

C

834

A

_py_

2

py

5

2.59

02

0.00

85

47

.336

4

0

0.

0001

0.00

01

1.

0681

0.0

247

0.00

01

0

.000

1

0.

0001

101.

03

sam

ple

poi

nt

typ

e W

%(S

)

W%

(Mn)

W

%(F

e)

W

%(C

o)

W%

(Ni)

W

%(C

u)

W%

(As)

W

%(S

e)

W%

(Ag)

W

%(A

u)

W%

(Bi)

W

%(s

um)

Appendix 4: Microprobe Analysis—Sulphides

30

C83

4

A_p

y_3

p

y

53.

3778

0.

0001

47.5

303

0

0.00

05

0.

0087

0.15

41

0

.02

0.

0002

0.0

001

0.00

01

10

1.09

C

835

A

_py_

1

py

5

3.11

9

0.00

01

47

.424

4

0

0.

0234

0.00

82

0.

0674

0.0

089

0.00

01

0

.000

1

0.

0001

100.

65

C83

5

A_p

y_2

p

y

53.

3086

0.

0001

47.3

213

0

0.00

01

0.

0135

0.07

45

0

.020

8

0.

0001

0.0

001

0.00

01

10

0.74

C

835

A

_py_

3

py

5

3.15

93

0.00

01

47

.225

7

0

0.

015

0.0

082

0.07

84

0

.008

0.

0163

0.0

001

0.00

01

10

0.51

C

836

A

_py_

1

py

5

3.15

34

0.00

28

47

.500

4

0

0.

0001

0.00

65

0.

1193

0.0

19

0.00

45

0

.024

6

0.

0001

100.

83

C83

6

A_p

y_2

p

y

52.

9614

0.

0049

47.3

74

0.0

013

0.01

29

0.

0001

0.11

42

0

.020

6

0.

0001

0.0

001

0.00

01

10

0.49

C

836

A

_py_

3

py

5

3.39

99

0.00

01

47

.647

7

0

0.

0001

0.00

01

0.

0926

0.0

177

0.00

18

0

.000

1

0.

0001

101.

16

C84

0

A_p

y_1

p

y

52.

8277

0.

0247

46.0

981

0.0

054

0.01

2

0

.000

1

1.

2553

0.0

149

0.00

65

0

.000

1

0.

0001

100.

24

C84

0

A_p

y_2

p

y

54.

2932

0.

0134

46.7

439

0

0.00

55

0.

0148

0.08

75

0

.014

7

0.

0144

0.0

001

0.00

01

10

1.19

C

840

A

_py_

3

py

5

4.12

68

0.00

64

46

.606

5

0

0.

0001

0.00

01

0.

0669

0.0

127

0.00

01

0

.000

1

0.

0001

100.

82

C84

8

A_p

y_1

p

y

52.

7985

0.

0001

47.6

733

0

0.01

09

0.

0117

0.08

8

0

.017

3

0.

0069

0.0

239

0.00

01

10

0.63

C

848

A

_py_

2

py

5

2.81

78

0.00

45

47

.806

7

0

.000

4

0.

0002

0.00

11

0.

0702

0.0

159

0.00

42

0

.000

1

0.

0001

100.

72

C84

8

A_p

y_3

p

y

52.

8729

0.

0113

47.7

857

0

0.01

28

0.

0001

0.06

64

0

.013

6

0.

0107

0.0

001

0.00

01

10

0.77

C

849

A

_py_

7-7-

1

py

5

2.70

55

0.00

78

46

.212

7

0

.002

9

0.

1267

0.00

01

0.

0853

0.0

257

0.00

03

0

.000

1

0.

0001

99.1

7 C

849

A

_py_

8-8-

1

py

5

2.49

86

0.00

01

46

.723

2

0

0.

1054

0.01

28

0.

0669

0.0

199

0.00

01

0

.000

1

0.

0001

99.4

3 C

849

A

_py_

9-9-

1

py

5

2.58

62

0.00

01

46

.286

2

0

0.

2118

0.00

01

0.

0902

0.0

265

0.00

16

0

.004

5

0.

0001

99.2

1 R

001

A

_py_

1

py

5

1.95

97

0.00

42

46

.212

6

0

0.

0001

0.00

01

0.

0728

0.0

127

0.00

01

0

.000

1

0.

0001

98.2

6 R

001

A

_py_

2

py

5

2.47

2

0.00

01

46

.078

8

0

.101

0.

0001

0.01

33

0.

0918

0.0

191

0.00

35

0

.000

1

0.

0001

98.7

8 R

001

A

_py_

3

py

5

2.47

15

0.00

52

46

.187

0

0.

0001

0.00

01

0.

1038

0.0

046

0.01

55

0

.000

1

0.

0001

98.7

9 R

001

B

_py_

7

py

5

2.44

74

0.00

55

46

.235

0

0.

0059

0.02

26

0.

1024

0.0

118

0.00

68

0

.000

1

0.

0001

98.8

4 R

001

B

_py_

8

py

5

2.81

34

0.00

36

46

.141

3

0

.036

5

0.

0001

0.00

01

0.

0879

0.0

124

0.00

01

0

.034

3

0.

0001

99.1

3 R

001

B

_py_

9

py

5

2.51

54

0.01

24

46

.145

1

0

.036

1

0.

0039

0.00

29

0.

0898

0.0

229

0.00

38

0

.000

1

0.

0001

98.8

3 R

003

A

_py_

1

py

5

3.06

09

0.00

8

4

6.05

45

0

0.00

01

0.

016

0.0

66

0.01

29

0.

0001

0.0

001

0.00

01

99

.22

R00

3

A_p

y_2

p

y

52.

9818

0.

0001

46.2

21

0

0.01

31

0.

0105

0.06

19

0

.016

5

0.

0112

0.0

001

0.00

28

99

.32

R00

3

A_p

y_3

p

y

52.

8696

0.

0001

45.8

796

0

0.00

27

0.

0203

0.06

22

0

.018

6

0.

0016

0.0

001

0.00

01

98

.85

R00

3

B_p

y_7

p

y

53.

0521

0.

0148

46.0

533

0.0

009

0.00

48

0.

0001

0.06

98

0

.023

3

0.

011

0.

0001

0.0

001

99.2

3 R

003

B

_py_

8

py

5

3.13

21

0.00

78

46

.231

6

0

0.

0026

0.00

92

0.

0554

0.0

211

0.01

65

0

.000

1

0.

0001

99.4

8 R

003

B

_py_

9

py

5

3.09

85

0.00

72

45

.941

1

0

0.

0001

0.00

53

0.

0838

0.0

153

0.00

3

0.00

43

0

.000

1

99

.16

R07

5

A_p

y_4-

4-1

p

y

53.

0087

0.

0093

46.4

499

0

0.00

01

0.

0084

0.07

37

0

.018

4

0.

0001

0.0

001

0.00

01

99

.57

R07

5

A_p

y_5-

5-1

p

y

53.

3661

0.

0001

46.4

544

0

0.00

01

0.

0074

0.08

28

0

.007

9

0.

0004

0.0

001

0.00

01

99

.92

R07

5

A_p

y_6-

6-1

p

y

52.

6817

0.

0001

46.3

684

0.0

079

0.00

01

0.

0001

0.06

89

0

.019

0.

0085

0.0

001

0.00

13

99

.16

R07

8

A_p

y_10

-10-

1 py

52.6

033

0.0

153

46.0

955

0

0.01

08

0.

0001

0.12

19

0

.019

4

0.

0001

0.0

001

0.00

01

98

.87

R07

8

A_p

y_11

-11-

1 py

52.8

584

0.0

035

46.2

648

0

0.00

15

0.

0001

0.17

1

0

.018

5

0.

0001

0.0

045

0.00

01

99

.32

R07

8

A_p

y_12

-12-

1 py

52.8

658

0.0

073

45.6

917

0

0.00

01

0.

0047

0.07

34

0

.012

0.

0001

0.0

453

0.00

01

98

.70

R07

8

A_p

y_7-

7-1

p

y

52.

6807

0.

0031

46.4

874

0

0.00

36

0.

0011

0.11

87

0

.010

6

0.

0014

0.0

001

0.00

01

99

.31

R07

8

A_p

y_8-

8-1

p

y

53.

1797

0.

0046

46.4

411

0

0.00

21

0.

0001

0.08

56

0

.013

9

0.

0117

0.0

001

0.00

01

99

.74

R07

8

A_p

y_9-

9-1

p

y

53.

0229

0.

0138

46.3

237

0

0.00

01

0.

0075

0.07

14

0

.02

0.

0001

0.0

001

0.00

01

99

.46

sam

ple

poi

nt

typ

e W

%(S

)

W%

(Mn)

W

%(F

e)

W

%(C

o)

W%

(Ni)

W

%(C

u)

W%

(As)

W

%(S

e)

W%

(Ag)

W

%(A

u)

W%

(Bi)

W

%(s

um)

Appendix 4: Microprobe Analysis—Sulphides

31

C07

9

_sp_

7

s

p

32.5

845

0.

0445

1.81

95

0

.005

0

0.

0001

0.0

100

67.3

113

0.

0185

0.0

236

0.00

80

0

.177

6

10

2.00

C

079

_s

p_8

sp

32

.619

8

0.04

12

1.

8939

0.0

000

0.00

01

0

.018

3

67

.496

9

0.02

99

0

.028

8

0.

0067

0.1

783

102.

31

C07

9

_sp_

9

s

p

32.6

287

0.

0287

1.85

05

0

.005

6

0.

0016

0.0

246

67.2

151

0.

0259

0.0

067

0.00

01

0

.203

0

10

1.99

C

082

_s

p_7

sp

32

.926

7

0.08

46

6.

8858

0.0

000

0.00

01

2

.446

6

58

.459

5

0.03

48

0

.026

8

0.

0226

0.1

574

101.

04

C08

2

_sp_

8

s

p

33.0

848

0.

0578

7.36

48

0

.002

1

0.

0032

3.1

292

57.1

413

0.

0427

0.0

233

0.00

01

0

.177

9

10

1.03

C

082

_s

p_9

sp

32

.913

0

0.05

31

7.

3504

0.0

000

0.01

00

2

.839

3

57

.939

1

0.03

39

0

.020

9

0.

0268

0.1

820

101.

37

C21

1

A_s

p_1

s

p

34.3

962

0.

6604

10.8

046

0

.000

0

0.

0042

0.0

807

54.2

529

0.

0452

0.0

164

0.00

01

0

.206

5

10

0.47

C

211

A

_sp_

2

sp

34

.136

9

0.64

49

10

.865

5

0.0

000

0.00

01

0

.104

2

53

.940

4

0.04

83

0

.022

5

0.

0001

0.2

213

99.9

8 C

211

A

_sp_

3

sp

34

.322

9

0.68

11

11

.004

3

0.0

000

0.00

77

0

.100

0

53

.600

1

0.03

89

0

.031

1

0.

0140

0.1

908

99.9

9 C

211

A

_sp_

4

sp

34

.353

0

0.67

67

10

.925

5

0.0

000

0.00

01

0

.132

3

54

.134

1

0.03

80

0

.025

9

0.

0001

0.2

003

100.

49

C21

1

A_s

p_5

s

p

34.2

805

0.

6459

10.8

008

0

.000

0

0.

0001

0.1

219

53.9

071

0.

0434

0.0

021

0.00

01

0

.196

6

10

0.00

C

211

A

_sp_

6

sp

34

.399

1

0.66

44

10

.847

7

0.0

000

0.00

01

0

.117

2

54

.202

0

0.04

57

0

.019

7

0.

0001

0.1

935

100.

49

C21

1

A_s

p_7

s

p

34.8

296

0.

6233

10.5

371

0

.000

0

0.

0001

0.1

047

54.3

628

0.

0483

0.0

091

0.00

20

0

.204

3

10

0.72

C

211

A

_sp_

8

sp

34

.622

3

0.62

82

10

.516

6

0.0

000

0.00

93

0

.090

3

54

.322

4

0.03

85

0

.026

3

0.

0001

0.2

146

100.

47

C21

1

A_s

p_9

s

p

34.8

620

0.

6704

10.6

076

0

.000

0

0.

0001

0.1

195

54.1

467

0.

0480

0.0

164

0.00

01

0

.229

5

10

0.70

C

211

B_

sp_1

0

sp

34.7

286

0.

6202

10.5

786

0

.000

0

0.

0001

0.1

648

54.3

616

0.

0378

0.0

156

0.00

01

0

.189

0

10

0.70

C

211

B_

sp_1

1

sp

34.6

891

0.

6525

10.5

900

0

.000

0

0.

0076

0.1

811

54.1

922

0.

0406

0.0

239

0.00

01

0

.182

3

10

0.56

C

211

B_

sp_1

2

sp

34.7

797

0.

6061

10.4

284

0

.000

0

0.

0132

0.1

315

54.4

772

0.

0331

0.0

106

0.01

30

0

.207

2

10

0.70

C

278

B

_sp_

4

sp

33

.090

6

0.29

07

6.

6635

0.0

000

0.00

06

0

.027

6

59

.807

2

0.01

80

0

.021

2

0.

0015

0.1

811

100.

10

C27

8

B_s

p_5

s

p

33.0

321

0.

3122

6.44

65

0

.001

1

0.

0029

0.0

281

59.7

456

0.

0400

0.0

250

0.00

49

0

.150

1

99

.79

C27

8

B_s

p_6

s

p

32.9

148

0.

2978

6.34

46

0

.000

0

0.

0001

0.0

198

60.0

288

0.

0383

0.0

142

0.00

01

0

.153

1

99

.81

C28

0

B_s

p_4

s

p

33.3

455

0.

2782

5.65

74

0

.000

0

0.

0001

0.0

106

60.7

033

0.

0390

0.0

154

0.00

24

0

.194

3

10

0.25

C

280

B

_sp_

5

sp

33

.085

0

0.27

55

5.

3569

0.0

000

0.00

01

0

.020

5

60

.958

3

0.04

31

0

.019

2

0.

0001

0.1

847

99.9

4 C

280

B

_sp_

6

sp

32

.786

0

0.27

52

5.

4471

0.0

000

0.00

01

0

.018

4

61

.042

4

0.03

30

0

.017

2

0.

0001

0.1

760

99.8

0 C

284

A

_sp_

4

sp

33

.435

4

0.13

74

5.

0201

0.0

037

0.00

67

0

.000

1

60

.222

4

0.03

53

0

.013

8

0.

0193

0.1

865

99.0

8 C

284

A

_sp_

5

sp

33

.211

5

0.12

72

4.

9859

0.0

000

0.00

81

0

.018

5

58

.763

8

0.02

91

0

.016

2

0.

0001

0.1

646

97.3

3 C

284

A

_sp_

6

sp

33

.235

0

0.12

83

4.

8344

0.0

147

0.00

45

0

.002

6

59

.437

0

0.04

70

0

.024

1

0.

0001

0.1

624

97.8

9 C

284

C

_sp_

16

sp

33.1

272

0.

1753

5.00

44

0

.000

3

0.

0063

0.0

058

59.8

557

0.

0295

0.0

101

0.00

01

0

.190

2

98

.40

C28

4

C_s

p_17

sp

33

.086

3

0.15

31

4.

9742

0.0

000

0.01

06

0

.013

3

60

.488

5

0.02

71

0

.007

2

0.

0001

0.1

592

98.9

2 C

284

C

_sp_

18

sp

32.9

728

0.

1258

5.39

97

0

.005

5

0.

0036

0.0

027

58.7

929

0.

0349

0.0

298

0.00

81

0

.158

4

97

.53

C28

5

B_s

p_4

s

p

33.1

934

0.

2356

5.17

25

0

.000

0

0.

0023

0.0

462

59.2

138

0.

0367

0.0

284

0.00

08

0

.176

2

98

.11

C28

5

B_s

p_5

s

p

33.2

546

0.

2584

5.22

43

0

.000

0

0.

0052

0.0

074

59.0

678

0.

0186

0.0

319

0.00

01

0

.165

0

98

.03

C28

5

B_s

p_6

s

p

33.2

595

0.

2419

5.25

75

0

.000

0

0.

0019

0.0

001

61.0

893

0.

0311

0.0

094

0.00

01

0

.152

1

10

0.04

C

285

B

_sp_

7

sp

33

.143

9

0.27

00

5.

1554

0.0

080

0.00

07

0

.000

4

58

.589

0

0.02

38

0

.015

9

0.

0022

0.1

722

97.3

8 C

285

B

_sp_

8

sp

33

.129

4

0.28

52

5.

2310

0.0

044

0.00

08

0

.000

1

60

.200

5

0.03

89

0

.011

0

0.

0001

0.1

912

99.0

9 C

285

B

_sp_

9

sp

33

.118

5

0.29

94

5.

1746

0.0

086

0.00

50

0

.004

5

59

.612

2

0.03

31

0

.014

7

0.

0001

0.1

677

98.4

4 C

287

B

_sp_

4

sp

32

.986

5

0.19

87

4.

1884

0.0

004

0.01

62

0

.008

2

60

.687

1

0.03

74

0

.024

0

0.

0085

0.1

663

98.3

2 C

287

B

_sp_

5

sp

33

.001

5

0.20

45

4.

1071

0.0

000

0.00

79

0

.007

8

60

.347

7

0.02

51

0

.011

0

0.

0001

0.1

867

97.9

0

sam

ple

po

int

ty

pe

W%

(S )

W

%(M

n)

W%

(Fe)

W

%(C

o)

W%

(Ni)

W

%(C

u)

W%

(Zn)

W

%(A

s)

W%

(Se)

W

%(A

g)

W%

(Cd)

W

%(s

um)

Appendix 4: Microprobe Analysis—Sulphides

32

C28

7

B_s

p_6

s

p

32.8

573

0.

2030

4.05

03

0

.000

6

0.

0001

0.0

001

60.2

757

0.

0364

0.0

197

0.00

01

0

.179

7

97

.62

C28

7

C_s

p_10

sp

33

.082

9

0.20

36

4.

0367

0.0

000

0.01

36

0

.004

1

59

.841

7

0.02

61

0

.012

8

0.

0030

0.1

506

97.3

8 C

287

C

_sp_

11

sp

33.0

323

0.

2102

4.14

89

0

.000

0

0.

0001

0.0

001

60.2

861

0.

0456

0.0

111

0.00

01

0

.165

3

97

.90

C28

7

C_s

p_12

sp

33

.237

1

0.20

12

4.

0819

0.0

000

0.00

20

0

.007

9

60

.174

4

0.03

25

0

.007

1

0.

0001

0.1

571

97.9

0 C

290

A

_sp_

4

sp

32

.621

1

0.15

58

1.

7731

0.0

009

0.00

59

0

.003

1

64

.940

5

0.01

87

0

.017

2

0.

0001

0.1

881

99.7

2 C

290

A

_sp_

5

sp

32

.575

1

0.15

11

1.

6617

0.0

058

0.00

01

0

.000

1

64

.789

4

0.02

87

0

.027

6

0.

0001

0.1

963

99.4

4 C

290

A

_sp_

6

sp

32

.484

9

0.15

64

1.

7806

0.0

054

0.00

82

0

.001

5

64

.783

9

0.03

27

0

.028

2

0.

0001

0.2

075

99.4

9 C

290

A

_sp_

7

sp

32

.648

4

0.11

43

1.

5443

0.0

055

0.00

67

0

.014

3

64

.388

0

0.02

25

0

.017

4

0.

0069

0.2

093

98.9

8 C

290

A

_sp_

8

sp

32

.763

6

0.11

06

1.

5055

0.0

000

0.00

17

0

.007

4

64

.276

1

0.01

60

0

.023

4

0.

0069

0.2

055

98.9

2 C

290

A

_sp_

9

sp

32

.542

8

0.11

81

1.

4521

0.0

041

0.00

29

0

.007

3

64

.284

2

0.02

29

0

.015

3

0.

0039

0.1

874

98.6

4 C

290

B

_sp_

13

sp

32

.485

7

0.11

97

3.

4301

0.0

000

0.00

01

0

.022

0

62

.754

3

0.03

26

0

.017

5

0.

0001

0.2

193

99.0

8 C

290

B

_sp_

14

sp

32

.452

8

0.12

99

3.

5902

0.0

000

0.00

18

0

.004

4

62

.927

4

0.02

03

0

.023

0

0.

0001

0.2

111

99.3

6 C

290

B

_sp_

15

sp

32

.649

8

0.12

23

3.

6295

0.0

077

0.00

01

0

.014

4

62

.503

4

0.03

25

0

.008

8

0.

0080

0.1

967

99.1

7 C

297

_s

p_1-

1-1

sp

32

.376

7

0.22

83

5.

0708

0.0

010

0.00

71

0

.000

1

61

.257

1

0.05

03

0

.019

0

0.

0001

0.1

810

99.1

9 C

297

_s

p_2-

2-1

sp

32

.416

9

0.18

54

5.

0235

0.0

010

0.00

01

0

.013

2

61

.870

5

0.04

63

0

.023

6

0.

0001

0.1

414

99.7

2 C

297

_s

p_3-

3-1

sp

32

.508

0

0.24

18

5.

1272

0.0

000

0.00

77

0

.009

2

60

.986

3

0.02

07

0

.016

4

0.

0001

0.1

658

99.0

8 C

299

A

_sp_

4

sp

34

.196

9

0.09

92

1.

9414

0.0

124

0.00

22

0

.004

6

63

.194

7

0.03

31

0

.016

9

0.

0123

0.1

765

99.6

9 C

299

A

_sp_

4

sp

33

.163

1

0.10

74

1.

9290

0.0

049

0.00

57

0

.014

5

63

.530

7

0.02

28

0

.021

2

0.

0085

0.1

837

98.9

9 C

299

A

_sp_

5

sp

34

.124

5

0.10

58

1.

9792

0.0

038

0.00

33

0

.000

1

63

.262

3

0.03

02

0

.019

6

0.

0001

0.1

818

99.7

1 C

299

A

_sp_

5

sp

32

.983

1

0.09

80

1.

9477

0.0

003

0.00

01

0

.000

1

62

.665

5

0.01

50

0

.024

5

0.

0001

0.1

877

97.9

2 C

299

A

_sp_

6

sp

34

.189

1

0.10

00

1.

9301

0.0

041

0.00

83

0

.000

1

63

.218

3

0.02

36

0

.033

1

0.

0001

0.1

808

99.6

9 C

299

A

_sp_

6

sp

32

.982

2

0.09

66

1.

9114

0.0

007

0.00

01

0

.002

5

62

.974

3

0.01

57

0

.005

4

0.

0001

0.1

497

98.1

4 C

299

B

_sp_

10

sp

34

.353

7

0.10

21

1.

9946

0.0

043

0.00

38

0

.000

1

62

.948

9

0.02

34

0

.013

4

0.

0001

0.1

982

99.6

4 C

299

B

_sp_

10

sp

33

.221

5

0.11

40

1.

9527

0.0

065

0.00

24

0

.012

7

63

.569

1

0.02

76

0

.016

1

0.

0001

0.1

966

99.1

2 C

299

B

_sp_

11

sp

33

.187

0

0.09

26

1.

9494

0.0

000

0.00

01

0

.000

1

64

.383

1

0.03

37

0

.011

6

0.

0073

0.1

674

99.8

3 C

299

B

_sp_

12

sp

33

.248

2

0.09

43

1.

9375

0.0

069

0.00

67

0

.011

5

64

.121

2

0.03

62

0

.014

4

0.

0001

0.1

784

99.6

6 C

301

A

_sp_

1

sp

32

.963

2

0.24

56

3.

4947

0.0

000

0.00

95

0

.015

7

61

.257

0

0.02

13

0

.021

9

0.

0062

0.1

993

98.2

3 C

301

A

_sp_

2

sp

33

.012

9

0.24

89

3.

4301

0.0

082

0.00

02

0

.004

6

60

.968

1

0.03

86

0

.015

6

0.

0001

0.1

879

97.9

2 C

301

A

_sp_

3

sp

33

.031

8

0.20

86

3.

3612

0.0

000

0.00

01

0

.013

5

60

.836

6

0.02

79

0

.017

4

0.

0003

0.1

846

97.6

8 C

306

A

_sp_

4

sp

34

.163

1

0.15

81

2.

5560

0.0

062

0.00

08

0

.003

2

63

.003

3

0.02

21

0

.013

7

0.

0001

0.1

893

100.

12

C30

6

A_s

p_5

s

p

34.1

254

0.

1340

2.47

78

0

.005

7

0.

0130

0.0

001

63.1

670

0.

0178

0.0

040

0.00

01

0

.198

4

10

0.14

C

306

A

_sp_

6

sp

34

.173

8

0.13

54

2.

4771

0.0

000

0.00

01

0

.000

1

62

.941

4

0.03

35

0

.019

0

0.

0001

0.1

752

99.9

6 C

306

B

_sp_

7

sp

34

.053

9

0.20

74

2.

5361

0.0

062

0.00

01

0

.000

1

62

.855

1

0.02

65

0

.015

7

0.

0010

0.1

679

99.8

7 C

306

B

_sp_

8

sp

33

.902

2

0.18

33

2.

5222

0.0

040

0.00

10

0

.000

1

62

.873

1

0.03

12

0

.029

8

0.

0001

0.1

592

99.7

1 C

306

B

_sp_

9

sp

34

.058

1

0.17

35

2.

5366

0.0

000

0.00

01

0

.020

2

63

.083

0

0.02

18

0

.006

1

0.

0001

0.1

919

100.

09

C30

7

A_s

p_4

s

p

32.9

679

0.

0374

4.46

93

0

.000

0

0.

0089

0.1

928

60.9

106

0.

0324

0.0

129

0.00

35

0

.197

3

98

.83

C30

7

A_s

p_5

s

p

32.9

920

0.

0507

4.97

90

0

.004

1

0.

0001

0.3

578

60.7

622

0.

0193

0.0

301

0.01

89

0

.251

2

99

.47

C30

7

A_s

p_6

s

p

32.4

775

0.

0477

4.47

40

0

.000

0

0.

0117

0.0

730

60.9

843

0.

0360

0.0

130

0.00

01

0

.209

5

98

.33

sam

ple

po

int

ty

pe

W%

(S )

W

%(M

n)

W%

(Fe)

W

%(C

o)

W%

(Ni)

W

%(C

u)

W%

(Zn)

W

%(A

s)

W%

(Se)

W

%(A

g)

W%

(Cd)

W

%(s

um)

Appendix 4: Microprobe Analysis—Sulphides

33

C30

7

C_s

p_16

sp

32

.969

7

0.05

02

4.

3183

0.0

000

0.00

17

0

.011

5

60

.094

8

0.01

26

0

.020

3

0.

0001

0.2

299

97.7

1 C

307

C

_sp_

17

sp

33.0

737

0.

0970

5.16

57

0

.000

0

0.

0001

0.0

028

59.2

544

0.

0359

0.0

162

0.00

01

0

.248

0

97

.89

C30

7

C_s

p_18

sp

32

.932

1

0.05

41

4.

6558

0.0

000

0.00

04

0

.000

1

59

.907

8

0.04

72

0

.027

7

0.

0001

0.2

297

97.8

6 C

317

A

_sp_

4

sp

32

.769

6

0.09

86

2.

2850

0.0

000

0.00

01

0

.083

8

64

.600

5

0.01

85

0

.012

8

0.

0001

0.1

829

100.

05

C31

7

A_s

p_5

s

p

32.8

703

0.

1118

2.39

22

0

.001

5

0.

0001

0.0

661

64.5

439

0.

0215

0.0

233

0.00

01

0

.170

7

10

0.20

C

317

A

_sp_

6

sp

32

.741

9

0.11

81

3.

0833

0.0

000

0.00

01

0

.966

6

63

.311

2

0.03

22

0

.015

4

0.

0144

0.1

826

100.

47

C31

7

D_s

p_16

sp

32

.726

6

0.13

43

3.

0457

0.0

033

0.00

01

0

.000

1

63

.512

8

0.03

59

0

.017

5

0.

0059

0.1

928

99.6

8 C

317

D

_sp_

17

sp

32.8

555

0.

1257

3.01

52

0

.000

0

0.

0001

0.0

001

63.8

205

0.

0279

0.0

277

0.00

01

0

.186

0

10

0.06

C

317

D

_sp_

18

sp

32.7

486

0.

1242

2.98

70

0

.005

1

0.

0001

0.0

064

63.5

984

0.

0003

0.0

246

0.00

01

0

.186

9

99

.68

C32

3

A_s

p_4

s

p

32.8

335

0.

0983

5.87

74

0

.000

0

0.

0090

0.2

111

60.8

286

0.

0344

0.0

133

0.00

01

0

.202

3

10

0.11

C

323

A

_sp_

5

sp

32

.988

7

0.10

54

6.

0264

0.0

025

0.00

01

0

.079

0

60

.402

8

0.04

07

0

.009

4

0.

0084

0.1

709

99.8

3 C

323

A

_sp_

6

sp

33

.070

1

0.08

88

5.

7682

0.0

000

0.00

16

0

.278

2

60

.880

4

0.04

37

0

.026

8

0.

0001

0.2

125

100.

37

C32

3

D_s

p_13

sp

33

.221

3

0.14

62

6.

2425

0.0

000

0.00

72

0

.000

1

60

.347

9

0.05

28

0

.014

5

0.

0001

0.1

711

100.

20

C32

3

D_s

p_14

sp

33

.278

1

0.14

62

6.

2799

0.0

000

0.00

25

0

.007

4

60

.468

2

0.02

63

0

.005

8

0.

0001

0.1

829

100.

40

C32

3

D_s

p_15

sp

33

.146

4

0.14

72

6.

2833

0.0

000

0.00

71

0

.005

0

60

.507

9

0.04

88

0

.011

3

0.

0001

0.1

862

100.

34

C32

6

A_s

p_4

s

p

32.2

846

0.

1916

5.30

90

0

.000

0

0.

0001

0.0

035

61.0

852

0.

0152

0.0

265

0.00

01

0

.168

7

99

.08

C32

6

A_s

p_5

s

p

32.5

641

0.

1902

5.29

55

0

.000

0

0.

0001

0.0

001

61.0

175

0.

0314

0.0

170

0.00

01

0

.161

6

99

.28

C32

6

A_s

p_6

s

p

32.7

190

0.

1751

5.25

97

0

.000

0

0.

0006

0.0

001

61.3

432

0.

0210

0.0

331

0.00

01

0

.174

5

99

.73

C32

6

B_s

p_13

s

p

32.6

341

0.

1805

5.43

39

0

.000

0

0.

0008

0.0

001

61.4

951

0.

0415

0.0

153

0.00

01

0

.160

5

99

.96

C32

6

B_s

p_14

s

p

32.6

482

0.

1683

5.39

77

0

.000

0

0.

0001

0.0

085

61.4

320

0.

0498

0.0

185

0.01

37

0

.166

3

99

.90

C32

6

B_s

p_15

s

p

32.2

961

0.

1720

5.47

02

0

.000

0

0.

0094

0.0

001

61.0

339

0.

0291

0.0

236

0.00

01

0

.175

9

99

.21

C32

9

aA_s

p_7

sp

32

.959

7

0.22

08

4.

1325

0.0

000

0.00

71

0

.034

6

60

.705

6

0.04

17

0

.018

4

0.

0095

0.1

860

98.3

2 C

329

aA

_sp_

8

sp

33.1

913

0.

1338

3.96

09

0

.002

7

0.

0010

0.0

419

60.4

450

0.

0190

0.0

286

0.00

01

0

.165

6

97

.99

C32

9

aA_s

p_9

sp

33

.295

6

0.18

63

4.

0660

0.0

000

0.00

01

0

.016

3

61

.202

9

0.02

30

0

.015

1

0.

0001

0.1

705

98.9

8 C

329

aB

_sp_

19 s

p

32.8

689

0.

2144

4.09

68

0

.002

4

0.

0014

0.0

251

60.9

063

0.

0350

0.0

134

0.00

42

0

.172

1

98

.34

C32

9

aB_s

p_20

sp

33

.114

3

0.22

27

4.

1033

0.0

122

0.01

05

0

.027

3

61

.302

0

0.02

98

0

.017

9

0.

0001

0.1

956

99.0

4 C

329

aB

_sp_

21 s

p

33.3

941

0.

2360

4.01

47

0

.003

0

0.

0128

0.0

004

60.6

230

0.

0394

0.0

238

0.00

01

0

.189

9

98

.54

C32

9

bA_s

p_7

sp

33

.880

0

0.21

24

3.

8868

0.0

103

0.00

01

0

.074

4

62

.034

4

0.03

31

0

.031

9

0.

0001

0.1

681

100.

33

C32

9

bA_s

p_8

sp

33

.965

3

0.23

84

3.

9327

0.0

000

0.00

61

0

.021

6

61

.844

4

0.04

13

0

.005

0

0.

0069

0.1

585

100.

22

C32

9

bA_s

p_9

sp

33

.852

3

0.25

48

3.

9647

0.0

004

0.00

66

0

.027

2

62

.403

0

0.03

61

0

.018

6

0.

0001

0.1

636

100.

73

C33

3

A_s

p_7

s

p

32.9

491

0.

2069

6.40

51

0

.000

0

0.

0134

0.0

078

58.3

861

0.

0491

0.0

194

0.00

01

0

.179

5

98

.22

C33

3

A_s

p_8

s

p

33.3

791

0.

2055

6.48

77

0

.000

0

0.

0001

0.0

083

58.9

383

0.

0271

0.0

166

0.00

01

0

.152

4

99

.22

C33

3

A_s

p_9

s

p

33.0

923

0.

2079

6.52

94

0

.000

0

0.

0085

0.0

005

58.2

256

0.

0537

0.0

144

0.00

01

0

.165

3

98

.30

C33

3

B_s

p_16

s

p

33.2

658

0.

2011

6.28

03

0

.000

0

0.

0009

0.0

184

57.8

648

0.

0293

0.0

212

0.00

01

0

.163

6

97

.85

C33

3

B_s

p_17

s

p

33.1

314

0.

1793

6.34

04

0

.000

0

0.

0001

0.0

143

58.6

210

0.

0381

0.0

168

0.00

01

0

.159

1

98

.50

C33

3

B_s

p_18

s

p

33.1

885

0.

1834

6.31

49

0

.000

0

0.

0157

0.0

001

58.5

412

0.

0380

0.0

216

0.00

34

0

.166

1

98

.47

C33

7

A_s

p_4

s

p

32.3

813

0.

2505

2.90

79

0

.009

2

0.

0119

0.0

063

63.9

279

0.

0319

0.0

211

0.00

01

0

.175

7

99

.72

C33

7

A_s

p_5

s

p

32.4

390

0.

2213

2.91

30

0

.014

1

0.

0043

0.0

001

63.9

817

0.

0312

0.0

237

0.00

07

0

.157

3

99

.79

sam

ple

po

int

ty

pe

W%

(S )

W

%(M

n)

W%

(Fe)

W

%(C

o)

W%

(Ni)

W

%(C

u)

W%

(Zn)

W

%(A

s)

W%

(Se)

W

%(A

g)

W%

(Cd)

W

%(s

um)

Appendix 4: Microprobe Analysis—Sulphides

34

C33

7

A_s

p_6

s

p

32.4

258

0.

2105

2.93

27

0

.000

0

0.

0001

0.0

120

64.0

477

0.

0358

0.0

193

0.00

01

0

.154

2

99

.84

C33

7

B_s

p_13

s

p

32.0

588

0.

2233

2.93

72

0

.007

8

0.

0001

0.0

021

63.4

104

0.

0255

0.0

211

0.00

63

0

.165

0

98

.86

C33

7

B_s

p_14

s

p

32.6

784

0.

2197

2.87

52

0

.003

8

0.

0001

0.0

173

64.1

261

0.

0367

0.0

135

0.00

01

0

.182

9

10

0.15

C

337

B

_sp_

15

sp

32

.318

8

0.22

21

2.

9329

0.0

061

0.00

01

0

.002

2

64

.068

5

0.02

45

0

.033

2

0.

0071

0.1

955

99.8

1 C

341

A

_sp_

4

sp

33

.980

8

0.15

20

2.

4353

0.0

089

0.01

14

0

.000

1

63

.326

4

0.03

98

0

.041

0

0.

0001

0.1

846

100.

18

C34

1

A_s

p_5

s

p

34.0

180

0.

1444

2.42

47

0

.005

7

0.

0001

0.0

001

63.1

055

0.

0298

0.0

156

0.00

01

0

.187

6

99

.93

C34

1

A_s

p_6

s

p

33.9

931

0.

1518

2.45

46

0

.002

6

0.

0158

0.0

001

63.2

009

0.

0107

0.0

196

0.00

01

0

.199

0

10

0.05

C

341

B

_sp_

13

sp

34

.151

3

0.17

02

2.

0298

0.0

033

0.00

01

0

.006

3

63

.444

6

0.03

52

0

.003

9

0.

0001

0.1

992

100.

04

C34

1

B_s

p_14

s

p

34.2

650

0.

1601

2.02

53

0

.000

0

0.

0001

0.0

001

63.4

293

0.

0289

0.0

091

0.00

01

0

.192

0

10

0.11

C

341

B

_sp_

15

sp

34

.266

7

0.14

44

2.

0681

0.0

000

0.00

69

0

.100

7

63

.740

7

0.03

19

0

.010

0

0.

0001

0.1

987

100.

57

C34

3

A_s

p_4

s

p

33.4

697

0.

1328

5.99

54

0

.000

0

0.

0010

0.0

217

60.6

686

0.

0314

0.0

163

0.00

01

0

.172

0

10

0.51

C

343

A

_sp_

5

sp

33

.355

2

0.20

56

5.

7949

0.0

021

0.00

13

0

.042

0

59

.906

4

0.01

52

0

.012

3

0.

0001

0.1

818

99.5

2 C

343

A

_sp_

6

sp

33

.721

2

0.14

71

7.

4316

0.0

000

0.00

01

2

.221

5

54

.984

1

0.03

20

0

.010

2

0.

0187

0.1

797

98.7

5 C

343

B

_sp_

10

sp

33

.203

2

0.08

50

5.

9756

0.0

000

0.00

01

0

.612

7

58

.775

9

0.03

93

0

.008

4

0.

0110

0.1

603

98.8

7 C

343

B

_sp_

11

sp

33

.187

2

0.06

20

5.

9985

0.0

012

0.00

01

0

.742

9

59

.652

2

0.02

78

0

.012

4

0.

0001

0.1

700

99.8

5 C

343

B

_sp_

12

sp

33

.135

5

0.07

37

5.

7245

0.0

000

0.00

01

0

.186

0

58

.801

6

0.03

21

0

.020

3

0.

0024

0.1

866

98.1

6 C

345

A

_sp_

4

sp

34

.198

2

0.05

51

2.

4407

0.0

057

0.00

03

0

.000

1

63

.364

8

0.01

66

0

.004

1

0.

0067

0.1

712

100.

26

C34

5

A_s

p_5

s

p

34.2

759

0.

0571

2.49

12

0

.012

8

0.

0037

0.0

001

63.0

558

0.

0356

0.0

253

0.00

01

0

.182

6

10

0.14

C

345

A

_sp_

6

sp

34

.199

8

0.04

78

2.

5037

0.0

047

0.01

33

0

.035

6

63

.574

1

0.04

08

0

.009

4

0.

0082

0.1

852

100.

62

C35

3

A_s

p_4

s

p

33.2

232

0.

1835

3.65

72

0

.000

0

0.

0092

0.0

120

61.7

896

0.

0418

0.0

294

0.00

90

0

.154

7

99

.11

C35

3

A_s

p_5

s

p

33.2

190

0.

1798

3.92

32

0

.000

0

0.

0001

0.0

015

61.4

975

0.

0510

0.0

112

0.00

01

0

.154

8

99

.04

C35

3

A_s

p_6

s

p

33.1

389

0.

1561

3.40

46

0

.000

0

0.

0001

0.0

041

62.0

520

0.

0195

0.0

189

0.00

14

0

.147

9

98

.94

C35

3

C_s

p_13

sp

33

.130

6

0.12

47

2.

6780

0.0

000

0.00

70

0

.004

7

62

.822

3

0.02

55

0

.023

9

0.

0001

0.1

572

98.9

7 C

353

C

_sp_

14

sp

33.1

042

0.

1190

2.99

69

0

.000

0

0.

0044

0.0

195

62.8

197

0.

0189

0.0

152

0.00

01

0

.182

7

99

.28

C35

3

C_s

p_15

sp

32

.960

0

0.08

47

2.

9062

0.0

000

0.00

01

0

.020

4

62

.412

4

0.01

17

0

.015

8

0.

0126

0.1

575

98.5

8 C

355

_s

p_1-

1-1

sp

32

.755

0

0.19

81

8.

3577

0.0

000

0.00

61

0

.024

1

57

.433

2

0.04

42

0

.017

4

0.

0001

0.1

577

98.9

9 C

355

_s

p_2-

2-1

sp

32

.777

7

0.17

29

8.

2118

0.0

000

0.00

01

0

.021

2

58

.087

9

0.04

91

0

.005

7

0.

0001

0.1

669

99.4

9 C

355

_s

p_3-

3-1

sp

32

.891

3

0.21

10

8.

0343

0.0

000

0.00

02

0

.018

7

58

.354

4

0.05

09

0

.022

4

0.

0157

0.1

630

99.7

6 C

357

A

_sp_

1

sp

32

.839

9

0.04

05

3.

6592

0.0

078

0.00

77

0

.023

8

63

.262

6

0.02

19

0

.024

4

0.

0141

0.2

142

100.

12

C35

7

A_s

p_2

s

p

33.0

792

0.

0343

3.44

02

0

.000

0

0.

0124

0.0

171

63.5

270

0.

0338

0.0

167

0.00

91

0

.205

8

10

0.38

C

357

A

_sp_

3

sp

33

.212

1

0.03

76

3.

4389

0.0

000

0.00

01

0

.023

5

63

.466

7

0.03

98

0

.028

8

0.

0007

0.2

053

100.

45

C35

9

A_s

p_4

s

p

33.2

274

0.

0285

1.00

99

0

.003

6

0.

0031

0.0

127

64.4

081

0.

0273

0.0

159

0.00

01

0

.232

0

98

.97

C35

9

A_s

p_5

s

p

32.9

121

0.

0251

1.02

08

0

.000

0

0.

0001

0.0

153

63.5

305

0.

0312

0.0

093

0.00

77

0

.225

5

97

.78

C35

9

A_s

p_6

s

p

32.9

009

0.

0277

1.03

56

0

.003

0

0.

0040

0.0

290

63.7

711

0.

0149

0.0

144

0.00

64

0

.218

5

98

.03

C35

9

B_s

p_16

s

p

33.0

222

0.

0359

1.07

31

0

.002

0

0.

0001

0.1

234

63.7

751

0.

0321

0.0

168

0.01

16

0

.199

4

98

.29

C35

9

B_s

p_17

s

p

33.0

758

0.

0219

1.31

01

0

.002

5

0.

0048

0.2

957

64.8

582

0.

0198

0.0

153

0.00

42

0

.208

1

99

.82

C35

9

B_s

p_18

s

p

32.7

467

0.

0374

1.16

67

0

.006

6

0.

0001

0.1

701

63.5

026

0.

0227

0.0

170

0.00

01

0

.231

1

97

.90

C36

2

A_s

p_1

s

p

32.7

842

0.

0682

2.20

28

0

.006

4

0.

0019

0.0

010

64.5

765

0.

0345

0.0

161

0.00

51

0

.100

2

99

.80

sam

ple

po

int

ty

pe

W%

(S )

W

%(M

n)

W%

(Fe)

W

%(C

o)

W%

(Ni)

W

%(C

u)

W%

(Zn)

W

%(A

s)

W%

(Se)

W

%(A

g)

W%

(Cd)

W

%(s

um)

Appendix 4: Microprobe Analysis—Sulphides

35

C36

2

A_s

p_2

s

p

32.6

115

0.

0517

2.13

58

0

.000

0

0.

0001

0.0

001

64.5

595

0.

0265

0.0

189

0.00

74

0

.108

2

99

.52

C36

2

A_s

p_3

s

p

32.5

453

0.

0715

2.17

36

0

.000

0

0.

0001

0.0

002

64.6

273

0.

0261

0.0

156

0.00

01

0

.127

7

99

.59

C36

2

B_s

p_10

s

p

32.5

686

0.

0730

2.18

88

0

.000

0

0.

0001

0.0

001

64.4

746

0.

0415

0.0

138

0.00

72

0

.102

2

99

.47

C36

2

B_s

p_11

s

p

32.5

455

0.

0586

2.11

06

0

.000

0

0.

0001

0.0

001

64.1

407

0.

0259

0.0

215

0.00

01

0

.113

5

99

.02

C36

2

B_s

p_12

s

p

32.5

100

0.

0715

2.17

80

0

.006

1

0.

0001

0.0

023

64.3

079

0.

0221

0.0

174

0.01

23

0

.115

6

99

.24

C36

4

A_s

p_4

s

p

32.7

729

0.

0446

2.53

43

0

.003

1

0.

0001

0.0

365

63.9

857

0.

0238

0.0

032

0.00

01

0

.250

4

99

.65

C36

4

A_s

p_5

s

p

32.5

332

0.

0402

2.47

48

0

.000

0

0.

0108

0.0

399

63.9

013

0.

0289

0.0

037

0.01

30

0

.221

0

99

.27

C36

4

A_s

p_6

s

p

32.5

910

0.

0389

2.50

48

0

.000

0

0.

0001

0.0

194

64.0

320

0.

0383

0.0

257

0.01

77

0

.229

2

99

.50

C36

4

B_s

p_22

s

p

32.5

202

0.

0495

2.27

88

0

.007

8

0.

0044

0.0

263

64.1

582

0.

0355

0.0

137

0.02

01

0

.229

5

99

.34

C36

4

B_s

p_23

s

p

32.5

870

0.

0485

2.24

53

0

.006

3

0.

0001

0.0

342

64.1

080

0.

0380

0.0

119

0.01

30

0

.248

1

99

.34

C36

4

B_s

p_24

s

p

32.5

691

0.

0482

2.31

35

0

.000

0

0.

0001

0.0

157

64.1

311

0.

0313

0.0

148

0.00

35

0

.220

5

99

.35

C36

5

A_s

p_4

s

p

32.8

507

0.

0481

4.73

19

0

.000

0

0.

0001

0.0

001

61.9

883

0.

0281

0.0

116

0.00

01

0

.187

5

99

.85

C36

5

A_s

p_5

s

p

32.8

215

0.

0509

4.79

75

0

.000

5

0.

0001

0.0

001

61.9

959

0.

0261

0.0

000

0.00

45

0

.202

5

99

.90

C36

5

A_s

p_6

s

p

32.9

072

0.

0503

4.77

53

0

.001

0

0.

0001

0.0

192

62.1

639

0.

0264

0.0

307

0.00

01

0

.207

1

10

0.18

C

365

B

_sp_

13

sp

33

.081

3

0.02

65

4.

7103

0.0

000

0.00

46

0

.017

2

62

.088

0

0.00

51

0

.031

0

0.

0001

0.2

159

100.

18

C36

5

B_s

p_14

s

p

32.9

583

0.

0432

4.73

94

0

.000

0

0.

0001

0.0

102

61.9

243

0.

0224

0.0

342

0.01

10

0

.200

9

99

.94

C36

5

B_s

p_15

s

p

33.3

693

0.

0222

4.49

61

0

.000

0

0.

0001

0.0

001

62.0

696

0.

0286

0.0

194

0.00

30

0

.214

5

10

0.22

C

369

A

_sp_

4

sp

34

.495

9

0.04

13

4.

7031

0.0

000

0.00

14

0

.000

1

62

.226

6

0.03

12

0

.017

9

0.

0001

0.1

912

101.

71

C36

9

A_s

p_5

s

p

34.1

205

0.

0281

4.65

61

0

.002

9

0.

0001

0.0

050

61.3

988

0.

0394

0.0

182

0.02

33

0

.162

5

10

0.45

C

369

A

_sp_

6

sp

34

.186

6

0.02

51

4.

6906

0.0

000

0.00

01

0

.000

1

61

.459

1

0.03

03

0

.009

5

0.

0071

0.1

825

100.

59

C36

9

B_s

p_10

s

p

34.0

403

0.

0267

4.69

35

0

.000

0

0.

0001

0.0

030

61.2

902

0.

0397

0.0

123

0.01

48

0

.180

2

10

0.30

C

369

B

_sp_

11

sp

34

.481

4

0.02

33

4.

6123

0.0

000

0.00

01

0

.000

1

61

.572

2

0.04

47

0

.020

9

0.

0001

0.1

833

100.

94

C36

9

B_s

p_12

s

p

34.1

726

0.

0264

4.62

23

0

.002

1

0.

0001

0.0

001

61.6

214

0.

0311

0.0

255

0.00

01

0

.176

4

10

0.68

C

378

B

_sp_

16

sp

32

.863

0

0.03

05

2.

5686

0.0

000

0.00

01

0

.546

3

63

.346

5

0.03

20

0

.013

4

0.

0001

0.1

943

99.5

9 C

378

B

_sp_

17

sp

32

.832

2

0.03

64

2.

8813

0.0

000

0.00

01

0

.961

3

61

.860

2

0.02

93

0

.017

7

0.

0001

0.1

881

98.8

1 C

378

B

_sp_

18

sp

32

.822

1

0.06

39

2.

3514

0.0

039

0.00

40

0

.122

3

63

.546

2

0.03

27

0

.022

2

0.

0001

0.1

528

99.1

2 C

379

A

_sp_

4

sp

34

.353

8

0.15

09

5.

0490

0.0

062

0.00

18

0

.004

5

60

.702

6

0.04

23

0

.028

2

0.

0001

0.1

616

100.

50

C37

9

A_s

p_4

s

p

33.1

811

0.

1531

5.04

67

0

.000

0

0.

0046

0.0

098

60.6

713

0.

0366

0.0

323

0.00

01

0

.185

9

99

.32

C37

9

A_s

p_5

s

p

34.2

673

0.

1594

5.07

46

0

.000

0

0.

0054

0.0

176

60.8

552

0.

0252

0.0

284

0.00

01

0

.177

0

10

0.61

C

379

A

_sp_

5

sp

33

.149

8

0.15

32

5.

1421

0.0

000

0.00

83

0

.000

1

59

.125

3

0.03

29

0

.018

0

0.

0142

0.1

857

97.8

3 C

379

A

_sp_

6

sp

34

.518

3

0.16

94

5.

1287

0.0

000

0.00

31

0

.003

8

60

.392

3

0.04

33

0

.013

3

0.

0001

0.1

779

100.

45

C37

9

A_s

p_6

s

p

33.1

467

0.

1871

5.19

02

0

.000

0

0.

0001

0.0

001

59.3

730

0.

0321

0.0

179

0.00

15

0

.198

5

98

.15

C37

9

B_s

p_10

s

p

34.2

657

0.

1731

5.17

01

0

.000

0

0.

0001

0.0

237

60.8

852

0.

0347

0.0

271

0.00

01

0

.182

0

10

0.76

C

379

B

_sp_

10

sp

33

.300

1

0.17

04

5.

1681

0.0

084

0.00

01

0

.014

4

59

.059

1

0.02

26

0

.026

8

0.

0001

0.1

835

97.9

5 C

379

B

_sp_

11

sp

34

.346

5

0.15

78

5.

0252

0.0

000

0.00

01

0

.000

1

60

.629

8

0.03

20

0

.028

3

0.

0001

0.1

920

100.

41

C37

9

B_s

p_11

s

p

33.4

074

0.

1445

5.11

21

0

.000

0

0.

0066

0.0

122

60.0

717

0.

0185

0.0

218

0.00

01

0

.176

4

98

.97

C37

9

B_s

p_12

s

p

34.1

878

0.

1599

5.00

32

0

.000

0

0.

0001

0.0

047

60.4

428

0.

0227

0.0

241

0.00

72

0

.172

2

10

0.02

C

379

B

_sp_

12

sp

33

.473

8

0.15

36

5.

1712

0.0

022

0.00

01

0

.000

4

60

.007

5

0.03

78

0

.021

6

0.

0001

0.1

776

99.0

5

sam

ple

po

int

ty

pe

W%

(S )

W

%(M

n)

W%

(Fe)

W

%(C

o)

W%

(Ni)

W

%(C

u)

W%

(Zn)

W

%(A

s)

W%

(Se)

W

%(A

g)

W%

(Cd)

W

%(s

um)

Appendix 4: Microprobe Analysis—Sulphides

36

C38

1

A_s

p_7

s

p

33.3

565

0.

1403

4.46

61

0

.000

0

0.

0053

0.0

001

60.6

406

0.

0283

0.0

279

0.00

01

0

.180

9

98

.85

C38

1

A_s

p_8

s

p

33.1

584

0.

1588

4.47

75

0

.000

0

0.

0001

0.0

174

59.9

562

0.

0381

0.0

211

0.00

01

0

.175

2

98

.00

C38

1

A_s

p_9

s

p

33.1

397

0.

1435

4.46

39

0

.007

0

0.

0044

0.0

030

60.6

813

0.

0330

0.0

157

0.01

34

0

.163

9

98

.67

C38

1

B_s

p_13

s

p

33.1

939

0.

1099

4.30

17

0

.003

7

0.

0026

0.0

082

61.0

250

0.

0370

0.0

107

0.00

07

0

.202

7

98

.90

C38

1

B_s

p_14

s

p

33.0

697

0.

0864

4.23

96

0

.008

1

0.

0001

0.0

001

60.9

703

0.

0312

0.0

291

0.00

01

0

.174

9

98

.61

C38

1

B_s

p_15

s

p

32.9

767

0.

1508

4.32

66

0

.000

0

0.

0001

0.0

001

60.7

027

0.

0373

0.0

195

0.00

01

0

.154

5

98

.37

C38

3

A_s

p_4

s

p

32.8

961

0.

1232

1.39

55

0

.002

9

0.

0028

0.0

001

65.1

458

0.

0123

0.0

303

0.00

01

0

.179

9

99

.79

C38

3

A_s

p_5

s

p

32.4

989

0.

1166

1.36

67

0

.005

7

0.

0001

0.0

073

65.4

347

0.

0282

0.0

184

0.00

01

0

.151

9

99

.63

C38

3

A_s

p_6

s

p

32.7

119

0.

1176

1.24

33

0

.012

1

0.

0083

0.0

001

65.4

653

0.

0170

0.0

163

0.00

01

0

.178

2

99

.77

C38

3

B_s

p_13

s

p

33.0

112

0.

1078

1.44

82

0

.009

1

0.

0001

0.0

001

64.9

547

0.

0397

0.0

335

0.00

18

0

.179

6

99

.79

C38

3

B_s

p_14

s

p

32.7

227

0.

1088

1.46

48

0

.000

0

0.

0020

0.0

001

64.2

759

0.

0231

0.0

158

0.00

01

0

.152

9

98

.77

C38

3

B_s

p_15

s

p

33.2

505

0.

1095

1.45

63

0

.007

9

0.

0010

0.0

001

64.8

749

0.

0273

0.0

276

0.00

01

0

.172

7

99

.93

C38

5

B_s

p_10

s

p

32.9

567

0.

0639

2.45

77

0

.000

0

0.

0001

0.0

098

63.1

579

0.

0391

0.0

217

0.00

32

0

.207

2

98

.92

C38

5

B_s

p_11

s

p

32.9

737

0.

0730

2.42

64

0

.001

0

0.

0001

0.0

008

62.7

541

0.

0252

0.0

175

0.00

21

0

.183

8

98

.46

C38

5

B_s

p_12

s

p

33.1

992

0.

0586

2.46

08

0

.000

0

0.

0001

0.0

434

62.6

529

0.

0210

0.0

038

0.00

80

0

.202

6

98

.65

C38

5

C_s

p_19

sp

32

.983

4

0.05

53

2.

3483

0.0

000

0.00

28

0

.000

1

61

.996

5

0.01

92

0

.018

7

0.

0109

0.1

855

97.6

2 C

385

C

_sp_

20

sp

33.0

951

0.

0710

2.33

67

0

.005

0

0.

0001

0.0

135

62.5

711

0.

0328

0.0

256

0.00

01

0

.194

8

98

.35

C38

5

C_s

p_21

sp

33

.103

8

0.06

74

2.

3580

0.0

000

0.00

01

0

.004

9

62

.347

0

0.03

69

0

.024

6

0.

0001

0.1

919

98.1

3 C

794

_s

p_4

sp

32

.907

9

0.05

70

7.

1888

0.0

000

0.00

64

1

.702

3

58

.558

9

0.04

69

0

.017

5

0.

0013

0.1

437

100.

63

C79

4

_sp_

4

s

p

32.9

214

0.

0576

7.21

15

0

.000

0

0.

0050

1.7

013

59.3

365

0.

0382

0.0

296

0.01

20

0

.133

2

10

1.45

C

795

_s

p_4

sp

32

.726

6

0.16

36

0.

9529

0.0

019

0.00

77

0

.026

4

67

.377

6

0.02

55

0

.010

5

0.

0001

0.0

819

101.

37

C79

5

_sp_

5

s

p

32.7

627

0.

1159

1.18

48

0

.000

0

0.

0006

0.1

139

67.4

031

0.

0264

0.0

175

0.01

67

0

.058

7

10

1.70

C

795

_s

p_6

sp

32

.798

3

0.14

65

1.

0055

0.0

090

0.00

15

0

.022

2

67

.724

2

0.04

69

0

.021

5

0.

0072

0.0

567

101.

84

C79

7

_sp_

4

s

p

32.8

298

0.

1742

2.54

78

0

.000

0

0.

0001

0.0

010

65.9

356

0.

0191

0.0

230

0.00

01

0

.170

3

10

1.70

C

797

_s

p_5

sp

32

.859

5

0.17

95

2.

5611

0.0

071

0.00

01

0

.000

1

65

.653

9

0.02

26

0

.016

3

0.

0088

0.1

798

101.

49

C79

7

_sp_

6

s

p

32.7

275

0.

1794

2.53

97

0

.000

0

0.

0069

0.0

059

65.8

374

0.

0280

0.0

103

0.00

91

0

.177

5

10

1.52

C

799

_s

p_4

sp

33

.022

6

0.04

44

3.

5255

0.0

000

0.00

01

0

.016

1

65

.304

3

0.01

50

0

.004

6

0.

0102

0.3

077

102.

25

C79

9

_sp_

5

s

p

32.9

469

0.

0571

3.56

93

0

.000

0

0.

0020

0.0

107

65.2

709

0.

0162

0.0

114

0.00

01

0

.336

8

10

2.22

C

799

_s

p_6

sp

33

.161

0

0.04

88

3.

5220

0.0

000

0.00

21

0

.000

1

64

.957

6

0.03

14

0

.016

3

0.

0076

0.3

553

102.

10

C80

1

_sp_

4

s

p

32.5

142

0.

0578

1.46

56

0

.003

0

0.

0061

0.0

151

66.2

732

0.

0229

0.0

220

0.00

01

0

.173

8

10

0.55

C

801

_s

p_5

sp

30

.422

6

0.08

04

1.

3660

0.0

078

0.00

01

0

.165

7

65

.462

0

0.02

45

0

.020

5

0.

0599

0.1

736

97.7

8 C

801

_s

p_6

sp

32

.591

8

0.05

73

1.

4273

0.0

092

0.00

23

0

.004

4

66

.802

9

0.03

09

0

.026

1

0.

0007

0.1

903

101.

14

C80

2

_sp_

1

s

p

32.7

727

0.

1450

3.84

05

0

.008

9

0.

0001

0.0

055

63.9

124

0.

0373

0.0

189

0.00

01

0

.152

4

10

0.89

C

802

_s

p_2

sp

32

.873

7

0.14

21

3.

7675

0.0

000

0.00

60

0

.000

1

63

.997

3

0.04

49

0

.025

6

0.

0004

0.1

504

101.

01

C80

2

_sp_

3

s

p

32.8

939

0.

1409

3.78

84

0

.000

0

0.

0001

0.0

015

64.0

251

0.

0318

0.0

166

0.00

31

0

.158

3

10

1.06

C

803

_s

p_4

sp

32

.753

7

0.11

82

3.

2253

0.0

069

0.00

55

0

.006

0

65

.351

4

0.03

04

0

.021

4

0.

0034

0.1

689

101.

69

C80

3

_sp_

5

s

p

32.7

063

0.

0979

3.39

47

0

.000

0

0.

0035

0.1

615

64.9

324

0.

0333

0.0

155

0.00

31

0

.180

9

10

1.53

C

803

_s

p_6

sp

32

.793

2

0.09

22

3.

0353

0.0

053

0.00

01

0

.022

7

65

.629

6

0.01

87

0

.022

6

0.

0001

0.1

501

101.

77

sam

ple

po

int

ty

pe

W%

(S )

W

%(M

n)

W%

(Fe)

W

%(C

o)

W%

(Ni)

W

%(C

u)

W%

(Zn)

W

%(A

s)

W%

(Se)

W

%(A

g)

W%

(Cd)

W

%(s

um)

Appendix 4: Microprobe Analysis—Sulphides

37

C80

4

_sp_

1

s

p

32.5

496

0.

0423

2.00

77

0

.000

0

0.

0001

0.1

253

66.1

043

0.

0062

0.0

146

0.00

11

0

.185

4

10

1.04

C

804

_s

p_2

sp

32

.753

5

0.04

86

2.

4032

0.0

068

0.00

01

0

.124

4

66

.302

2

0.01

74

0

.023

1

0.

0001

0.1

856

101.

87

C80

4

_sp_

3

s

p

32.7

398

0.

0593

2.29

67

0

.006

0

0.

0046

0.3

632

66.2

525

0.

0344

0.0

232

0.00

01

0

.164

8

10

1.94

C

807

_s

p_7

sp

32

.967

0

0.14

64

4.

5482

0.0

000

0.00

14

0

.008

0

63

.293

2

0.03

32

0

.030

3

0.

0167

0.1

396

101.

18

C80

7

_sp_

8

s

p

33.2

220

0.

1625

4.54

90

0

.000

0

0.

0001

0.0

056

63.7

151

0.

0273

0.0

156

0.00

01

0

.134

1

10

1.83

C

807

_s

p_9

sp

33

.210

3

0.15

99

4.

5127

0.0

068

0.00

21

0

.005

2

63

.396

9

0.03

81

0

.005

3

0.

0039

0.1

506

101.

49

C80

8

_sp_

1

s

p

32.5

813

0.

1343

4.98

08

0

.000

0

0.

0032

0.0

001

63.2

817

0.

0352

0.0

284

0.00

01

0

.165

4

10

1.21

C

808

_s

p_2

sp

32

.718

4

0.09

02

4.

3398

0.0

068

0.00

84

0

.002

9

64

.153

4

0.04

67

0

.031

2

0.

0001

0.1

873

101.

59

C80

8

_sp_

3

s

p

32.7

027

0.

1238

4.83

06

0

.011

0

0.

0001

0.0

001

63.7

426

0.

0244

0.0

073

0.00

01

0

.190

3

10

1.63

C

809

_s

p_7

sp

33

.118

1

0.11

95

4.

7377

0.0

156

0.00

01

0

.014

3

63

.608

4

0.03

47

0

.010

4

0.

0040

0.1

597

101.

82

C80

9

_sp_

8

s

p

33.0

060

0.

1618

4.81

13

0

.000

0

0.

0029

0.0

094

62.9

830

0.

0273

0.0

217

0.00

01

0

.168

1

10

1.19

C

809

_s

p_9

sp

32

.229

2

0.08

27

4.

9945

0.0

000

0.00

01

0

.514

3

60

.826

4

0.02

17

0

.013

0

0.

0001

0.1

538

98.8

4 C

810

_s

p_4

sp

32

.412

7

0.34

01

3.

6786

0.0

000

0.00

49

0

.000

1

64

.056

6

0.02

76

0

.021

4

0.

0001

0.1

447

100.

69

C81

0

_sp_

5

s

p

32.5

335

0.

3336

3.65

26

0

.000

0

0.

0001

0.0

041

64.3

053

0.

0306

0.0

117

0.00

07

0

.147

6

10

1.02

C

810

_s

p_6

sp

32

.408

3

0.30

79

3.

4367

0.0

000

0.00

01

0

.008

0

64

.658

0

0.01

37

0

.018

2

0.

0001

0.1

427

100.

99

C81

1

_sp_

4

s

p

32.7

496

0.

2650

3.42

06

0

.001

2

0.

0017

0.0

282

65.1

638

0.

0271

0.0

204

0.00

01

0

.153

0

10

1.83

C

811

_s

p_5

sp

32

.769

8

0.27

18

3.

5823

0.0

003

0.00

92

0

.032

6

64

.507

1

0.02

33

0

.015

6

0.

0001

0.1

715

101.

38

C81

1

_sp_

6

s

p

32.4

603

0.

2789

4.55

85

0

.010

3

0.

0006

1.6

631

62.8

535

0.

0405

0.0

299

0.00

01

0

.152

0

10

2.05

C

812

_s

p_4

sp

33

.113

3

0.13

15

4.

1323

0.0

023

0.00

28

0

.000

1

64

.015

9

0.02

71

0

.021

8

0.

0105

0.1

783

101.

64

C81

2

_sp_

5

s

p

33.0

266

0.

1437

4.32

11

0

.000

0

0.

0016

0.0

120

63.8

527

0.

0191

0.0

188

0.00

89

0

.182

0

10

1.59

C

812

_s

p_6

sp

33

.191

8

0.14

48

4.

2782

0.0

000

0.00

01

0

.015

4

63

.997

6

0.03

64

0

.021

6

0.

0142

0.1

526

101.

85

C81

3

_sp_

1

s

p

33.2

000

0.

1193

3.29

91

0

.004

5

0.

0001

0.0

134

65.2

276

0.

0196

0.0

167

0.00

31

0

.204

2

10

2.11

C

813

_s

p_2

sp

32

.915

9

0.11

53

3.

2347

0.0

020

0.00

80

0

.009

4

65

.479

2

0.03

32

0

.009

2

0.

0080

0.1

708

101.

99

C81

3

_sp_

3

s

p

33.0

870

0.

1095

3.28

68

0

.005

9

0.

0041

0.0

001

65.3

046

0.

0210

0.0

138

0.01

03

0

.203

6

10

2.05

C

815

_s

p_4

sp

32

.881

5

0.17

69

5.

2995

0.0

000

0.00

77

0

.013

6

62

.836

4

0.03

35

0

.027

8

0.

0158

0.1

439

101.

44

C81

5

_sp_

5

s

p

32.8

237

0.

1905

5.24

98

0

.000

6

0.

0001

0.0

008

62.7

427

0.

0230

0.0

140

0.00

01

0

.164

4

10

1.21

C

815

_s

p_6

sp

33

.229

2

0.17

78

5.

3611

0.0

000

0.00

01

0

.004

7

62

.827

0

0.04

52

0

.023

7

0.

0001

0.1

411

101.

81

C81

7

_sp_

7

s

p

33.2

139

0.

0866

3.46

45

0

.001

1

0.

0087

0.0

609

64.9

800

0.

0222

0.0

309

0.00

44

0

.183

0

10

2.06

C

817

_s

p_8

sp

33

.141

0

0.12

35

4.

0342

0.0

013

0.00

01

0

.255

8

64

.213

2

0.03

78

0

.021

7

0.

0044

0.1

725

102.

01

C81

7

_sp_

9

s

p

33.1

922

0.

0924

4.43

07

0

.000

0

0.

0078

1.5

681

62.0

604

0.

0385

0.0

130

0.00

63

0

.165

3

10

1.57

C

818

_s

p_1

sp

33

.334

9

0.19

21

5.

8967

0.0

000

0.00

54

0

.003

6

61

.807

5

0.03

63

0

.025

2

0.

0001

0.1

823

101.

48

C81

8

_sp_

2

s

p

32.9

531

0.

1795

5.88

86

0

.000

0

0.

0114

0.0

121

62.2

118

0.

0412

0.0

178

0.00

09

0

.185

4

10

1.50

C

818

_s

p_3

sp

33

.068

9

0.17

94

5.

8792

0.0

000

0.00

01

0

.000

1

61

.848

4

0.02

70

0

.013

2

0.

0013

0.1

929

101.

21

C82

0

_sp_

4

s

p

32.3

720

0.

0970

3.46

09

0

.000

0

0.

0001

0.0

001

64.4

768

0.

0380

0.0

263

0.01

61

0

.132

8

10

0.62

C

820

_s

p_5

sp

32

.675

0

0.07

49

3.

4041

0.0

000

0.00

01

0

.006

0

65

.026

8

0.02

78

0

.035

3

0.

0027

0.1

470

101.

40

C82

0

_sp_

6

s

p

32.3

836

0.

0993

3.46

08

0

.001

6

0.

0001

0.0

041

64.6

534

0.

0340

0.0

126

0.00

01

0

.129

1

10

0.78

C

822

_s

p_1

sp

33

.040

7

0.21

01

4.

3986

0.0

123

0.00

73

0

.006

0

63

.734

2

0.02

26

0

.017

9

0.

0001

0.1

993

101.

65

C82

2

_sp_

2

s

p

32.8

751

0.

1924

4.39

26

0

.006

6

0.

0023

0.0

001

63.4

508

0.

0228

0.0

186

0.00

01

0

.194

4

10

1.16

sam

ple

po

int

ty

pe

W%

(S )

W

%(M

n)

W%

(Fe)

W

%(C

o)

W%

(Ni)

W

%(C

u)

W%

(Zn)

W

%(A

s)

W%

(Se)

W

%(A

g)

W%

(Cd)

W

%(s

um)

Appendix 4: Microprobe Analysis—Sulphides

38

C82

2

_sp_

3

s

p

33.0

318

0.

2005

4.41

28

0

.000

0

0.

0001

0.0

021

63.5

638

0.

0374

0.0

122

0.00

01

0

.190

2

10

1.45

C

825

_s

p_4

sp

32

.985

3

0.17

22

4.

7018

0.0

042

0.00

50

0

.006

5

62

.758

1

0.05

55

0

.015

9

0.

0035

0.1

833

100.

89

C82

5

_sp_

5

s

p

32.9

821

0.

1688

4.80

18

0

.000

0

0.

0042

0.0

204

63.0

913

0.

0306

0.0

185

0.00

01

0

.162

1

10

1.28

C

825

_s

p_6

sp

33

.115

8

0.15

44

4.

7048

0.0

043

0.00

08

0

.000

1

63

.222

5

0.01

58

0

.021

6

0.

0097

0.1

813

101.

43

C82

6

_sp_

7

s

p

32.9

638

0.

0358

2.18

25

0

.000

3

0.

0001

0.0

001

66.8

359

0.

0262

0.0

000

0.00

53

0

.216

3

10

2.27

C

826

_s

p_8

sp

33

.108

0

0.02

99

2.

3686

0.0

082

0.00

60

0

.054

7

66

.391

4

0.02

42

0

.011

3

0.

0097

0.2

101

102.

22

C82

6

_sp_

9

s

p

32.9

619

0.

0292

2.21

73

0

.000

4

0.

0040

0.0

209

66.8

578

0.

0071

0.0

249

0.00

01

0

.225

4

10

2.35

C

828

_s

p_4

sp

32

.735

2

0.11

58

2.

2390

0.0

076

0.00

80

0

.010

0

65

.563

6

0.01

94

0

.030

4

0.

0001

0.2

034

100.

93

C82

8

_sp_

5

s

p

33.0

581

0.

1094

3.00

11

0

.000

0

0.

0041

0.9

956

64.0

200

0.

0270

0.0

097

0.02

46

0

.201

7

10

1.45

C

828

_s

p_6

sp

33

.015

3

0.12

80

2.

3316

0.0

021

0.00

43

0

.012

1

65

.717

9

0.02

56

0

.004

4

0.

0001

0.2

179

101.

46

C83

0

_sp_

4

s

p

32.8

815

0.

0866

2.19

45

0

.000

0

0.

0001

0.0

244

66.4

336

0.

0214

0.0

319

0.01

85

0

.205

0

10

1.90

C

830

_s

p_5

sp

32

.643

3

0.10

22

2.

1797

0.0

000

0.00

34

0

.000

1

65

.888

8

0.03

01

0

.006

4

0.

0093

0.1

917

101.

06

C83

0

_sp_

6

s

p

32.6

745

0.

0817

2.32

15

0

.005

5

0.

0001

0.0

001

65.9

393

0.

0171

0.0

290

0.00

01

0

.172

4

10

1.24

C

832

_s

p_4

sp

32

.829

4

0.07

97

1.

5824

0.0

129

0.00

01

0

.000

1

67

.890

9

0.01

67

0

.023

1

0.

0001

0.2

057

102.

64

C83

2

_sp_

5

s

p

32.9

502

0.

0677

1.55

53

0

.000

0

0.

0002

0.0

053

67.5

590

0.

0237

0.0

160

0.00

01

0

.183

4

10

2.36

C

832

_s

p_6

sp

32

.809

3

0.08

58

1.

5989

0.0

043

0.00

01

0

.000

1

67

.566

2

0.04

11

0

.006

0

0.

0001

0.1

899

102.

30

C83

3

_sp_

7

s

p

33.1

636

0.

0597

4.05

69

0

.000

0

0.

0001

1.0

693

63.7

787

0.

0473

0.0

131

0.00

36

0

.173

5

10

2.37

C

833

_s

p_8

sp

33

.173

8

0.06

39

4.

5800

0.0

000

0.00

01

1

.890

2

61

.826

5

0.03

37

0

.024

0

0.

0058

0.1

541

101.

75

C83

3

_sp_

9

s

p

33.0

964

0.

0714

4.33

27

0

.000

0

0.

0060

1.4

492

62.5

710

0.

0250

0.0

178

0.00

01

0

.134

3

10

1.70

C

834

_s

p_4

sp

32

.950

1

0.12

10

3.

6443

0.0

206

0.00

80

0

.016

8

64

.728

6

0.03

46

0

.016

0

0.

0001

0.1

776

101.

72

C83

4

_sp_

5

s

p

33.0

050

0.

1806

3.74

90

0

.000

0

0.

0035

0.0

072

64.5

842

0.

0306

0.0

301

0.00

59

0

.145

6

10

1.74

C

834

_s

p_6

sp

32

.880

7

0.12

89

3.

6523

0.0

000

0.00

12

0

.013

7

64

.290

0

0.03

35

0

.021

4

0.

0001

0.1

759

101.

20

C83

5

_sp_

4

s

p

32.6

831

0.

1670

2.61

62

0

.003

9

0.

0001

0.0

165

65.3

671

0.

0284

0.0

181

0.01

36

0

.176

4

10

1.09

C

835

_s

p_5

sp

32

.546

9

0.16

30

2.

6051

0.0

037

0.00

02

0

.000

1

65

.128

3

0.02

12

0

.023

3

0.

0113

0.1

693

100.

67

C83

5

_sp_

6

s

p

32.8

794

0.

1597

2.68

47

0

.009

6

0.

0023

0.0

123

65.7

481

0.

0346

0.0

231

0.00

01

0

.161

7

10

1.72

C

836

_s

p_4

sp

32

.979

9

0.05

61

3.

6208

0.0

000

0.00

38

0

.013

2

64

.026

5

0.02

97

0

.036

6

0.

0001

0.1

395

100.

91

C83

6

_sp_

5

s

p

32.7

974

0.

0647

3.64

18

0

.000

0

0.

0001

0.0

001

64.3

710

0.

0327

0.0

218

0.00

01

0

.164

2

10

1.09

C

836

_s

p_6

sp

32

.981

2

0.06

31

3.

6616

0.0

000

0.00

01

0

.003

4

63

.924

3

0.02

10

0

.015

3

0.

0001

0.1

722

100.

84

C83

8

_sp_

4

s

p

32.6

730

0.

1026

3.26

07

0

.000

0

0.

0035

0.0

001

65.2

218

0.

0291

0.0

015

0.00

01

0

.129

1

10

1.42

C

838

_s

p_5

sp

32

.780

6

0.10

43

3.

2474

0.0

000

0.00

11

0

.009

4

64

.830

2

0.04

91

0

.012

1

0.

0120

0.1

083

101.

15

C83

8

_sp_

6

s

p

32.4

375

0.

1016

2.97

65

0

.005

0

0.

0001

0.0

001

64.8

194

0.

0215

0.0

200

0.00

44

0

.134

1

10

0.52

C

840

_s

p_7

sp

33

.010

5

0.13

41

3.

6755

0.0

101

0.00

53

0

.000

1

64

.959

7

0.03

45

0

.028

2

0.

0023

0.1

628

102.

02

C84

0

_sp_

8

s

p

33.0

391

0.

1353

3.79

24

0

.000

0

0.

0001

0.0

072

64.9

472

0.

0335

0.0

285

0.01

42

0

.170

2

10

2.17

C

840

_s

p_9

sp

33

.128

1

0.11

61

3.

8214

0.0

000

0.00

34

0

.002

4

64

.812

0

0.04

32

0

.019

5

0.

0001

0.1

730

102.

12

C84

1

_sp_

7

s

p

32.8

808

0.

2048

3.31

40

0

.000

0

0.

0040

0.0

144

65.0

387

0.

0335

0.0

019

0.00

38

0

.174

4

10

1.67

C

841

_s

p_8

sp

32

.715

4

0.21

65

3.

3602

0.0

047

0.00

39

0

.070

3

64

.985

5

0.03

27

0

.022

3

0.

0050

0.1

772

101.

59

C84

1

_sp_

9

s

p

32.8

519

0.

2054

3.46

03

0

.006

3

0.

0035

0.0

299

64.8

973

0.

0165

0.0

206

0.00

19

0

.150

4

10

1.64

C

842

_s

p_1

sp

33

.115

9

0.27

20

1.

1329

0.0

047

0.00

01

0

.017

4

67

.939

3

0.04

45

0

.008

5

0.

0001

0.1

697

102.

71

sam

ple

po

int

ty

pe

W%

(S )

W

%(M

n)

W%

(Fe)

W

%(C

o)

W%

(Ni)

W

%(C

u)

W%

(Zn)

W

%(A

s)

W%

(Se)

W

%(A

g)

W%

(Cd)

W

%(s

um)

Appendix 4: Microprobe Analysis—Sulphides

39

C84

2

_sp_

2

s

p

33.2

273

0.

2751

1.12

62

0

.001

8

0.

0035

0.0

001

67.5

577

0.

0189

0.0

290

0.00

01

0

.144

8

10

2.38

C

842

_s

p_3

sp

32

.896

8

0.30

79

1.

0672

0.0

043

0.00

96

0

.000

1

67

.510

3

0.01

44

0

.024

6

0.

0001

0.1

707

102.

01

C84

4

_sp_

1

s

p

32.8

538

0.

1088

2.05

70

0

.000

0

0.

0101

0.0

001

66.6

548

0.

0318

0.0

199

0.00

01

0

.180

9

10

1.92

C

844

_s

p_2

sp

32

.669

1

0.11

65

2.

1113

0.0

049

0.00

01

0

.010

2

66

.696

3

0.02

69

0

.010

6

0.

0077

0.1

917

101.

85

C84

4

_sp_

3

s

p

32.8

040

0.

1155

2.00

53

0

.003

3

0.

0087

0.0

075

66.4

779

0.

0377

0.0

122

0.00

49

0

.188

1

10

1.67

C

849

_s

p_3-

3-1

sp

32

.612

9

0.30

47

4.

0725

0.0

000

0.01

37

1

.100

9

62

.380

3

0.02

59

0

.025

5

0.

0001

0.2

008

100.

74

C84

9

_sp_

4-4-

1 s

p

32.5

681

0.

2303

3.60

25

0

.004

0

0.

0001

0.9

112

62.4

593

0.

0350

0.0

285

0.00

96

0

.205

3

10

0.05

R

001

A

_sp_

4

sp

32

.322

0

0.18

56

5.

4002

0.0

002

0.00

57

0

.027

2

61

.186

1

0.04

57

0

.015

7

0.

0075

0.1

738

99.3

7 R

001

A

_sp_

5

sp

32

.429

9

0.16

57

5.

3854

0.0

000

0.00

84

0

.029

2

61

.543

3

0.02

95

0

.014

6

0.

0025

0.1

696

99.7

8 R

001

A

_sp_

6

sp

32

.330

8

0.18

77

5.

5418

0.0

000

0.00

01

0

.032

8

61

.206

0

0.02

85

0

.009

6

0.

0001

0.1

519

99.4

9 R

001

B

_sp_

10

sp

32

.675

0

0.21

70

5.

5328

0.0

010

0.00

08

0

.040

4

61

.334

1

0.02

95

0

.015

6

0.

0001

0.1

798

100.

03

R00

1

B_s

p_11

s

p

32.6

396

0.

1845

5.51

57

0

.000

0

0.

0073

0.0

276

61.2

662

0.

0204

0.0

220

0.00

68

0

.164

8

99

.85

R00

1

B_s

p_12

s

p

32.8

374

0.

1905

5.53

64

0

.000

0

0.

0030

0.0

351

61.1

518

0.

0455

0.0

200

0.00

01

0

.175

9

10

0.00

R

003

A

_sp_

4

sp

33

.330

0

0.10

16

4.

9095

0.0

000

0.00

16

0

.007

8

60

.871

6

0.02

37

0

.022

0

0.

0143

0.1

804

99.4

6 R

003

A

_sp_

5

sp

33

.232

1

0.10

81

4.

7708

0.0

000

0.00

01

0

.002

0

61

.795

1

0.03

10

0

.026

0

0.

0184

0.1

815

100.

17

R00

3

A_s

p_6

s

p

33.3

748

0.

0988

4.61

71

0

.000

0

0.

0001

0.0

053

60.6

380

0.

0360

0.0

257

0.00

01

0

.191

4

98

.99

R00

3

B_s

p_10

s

p

33.1

801

0.

3516

5.44

63

0

.007

3

0.

0001

0.0

030

59.3

865

0.

0272

0.0

146

0.00

61

0

.192

4

98

.62

R00

3

B_s

p_11

s

p

33.0

274

0.

2624

5.44

83

0

.000

0

0.

0001

0.0

001

60.2

806

0.

0272

0.0

133

0.00

01

0

.186

9

99

.25

R00

3

B_s

p_12

s

p

33.1

175

0.

3664

5.46

64

0

.000

6

0.

0061

0.0

180

59.4

811

0.

0325

0.0

271

0.00

01

0

.185

4

98

.70

R04

9

_sp_

1

s

p

32.7

049

0.

0683

1.28

86

0

.000

0

0.

0055

0.0

055

66.9

792

0.

0201

0.0

000

0.01

06

0

.202

4

10

1.29

R

049

_s

p_2

sp

32

.741

2

0.04

87

1.

2944

0.0

049

0.01

27

0

.004

8

67

.685

9

0.03

16

0

.034

7

0.

0001

0.1

952

102.

05

R04

9

_sp_

3

s

p

32.8

487

0.

0582

1.89

83

0

.000

0

0.

0019

0.7

113

66.6

712

0.

0310

0.0

202

0.00

01

0

.152

6

10

2.39

R

070

_s

p_10

sp

32.8

360

0.

0539

7.82

38

0

.000

0

0.

0001

1.8

517

58.3

264

0.

0241

0.0

249

0.01

27

0

.448

6

10

1.40

R

070

_s

p_11

sp

32.7

876

0.

0562

7.71

88

0

.000

0

0.

0001

1.0

595

59.2

637

0.

0301

0.0

393

0.00

01

0

.483

1

10

1.44

R

070

_s

p_12

sp

32.7

117

0.

0387

6.31

70

0

.000

0

0.

0001

3.0

996

58.8

126

0.

0300

0.0

226

0.00

01

0

.452

1

10

1.48

R

078

_s

p_1-

1-1

sp

32

.830

8

0.02

80

6.

4012

0.0

000

0.00

01

0

.000

1

60

.461

9

0.04

99

0

.021

8

0.

0079

0.2

467

100.

05

R07

8

_sp_

2-2-

1 s

p

32.7

824

0.

0260

6.50

03

0

.000

0

0.

0001

0.0

001

59.6

627

0.

0347

0.0

182

0.00

95

0

.201

0

99

.24

R07

8

_sp_

3-3-

1 s

p

32.7

464

0.

0210

6.26

50

0

.000

0

0.

0013

0.0

011

59.8

620

0.

0539

0.0

198

0.00

98

0

.268

1

99

.25

R07

8

_sp_

4-4-

1 s

p

32.7

736

0.

0371

6.72

98

0

.000

0

0.

0001

0.0

131

59.6

766

0.

0406

0.0

195

0.00

01

0

.512

6

99

.80

R07

8

_sp_

5-5-

1 s

p

32.6

326

0.

0257

6.75

79

0

.000

0

0.

0001

0.0

001

59.5

371

0.

0425

0.0

066

0.01

02

0

.475

1

99

.49

R07

8

_sp_

6-6-

1 s

p

32.3

886

0.

0246

7.06

80

0

.000

0

0.

0033

0.0

091

59.2

507

0.

0507

0.0

270

0.00

81

0

.500

1

99

.33

sam

ple

po

int

ty

pe

W%

(S )

W

%(M

n)

W%

(Fe)

W

%(C

o)

W%

(Ni)

W

%(C

u)

W%

(Zn)

W

%(A

s)

W%

(Se)

W

%(A

g)

W%

(Cd)

W

%(s

um)

Appendix 4: Microprobe Analysis—Sulphides

40

C28

7

B_g

a7

g

a

1

2.88

74

0.

0254

0.

0178

0

0

.132

6

0.00

56

0.13

85

86.7

349

99.9

4 C

287

B

_ga8

ga

12.

7192

0.00

01

0.00

49

0.00

85

0.08

66

0

0.

095

8

6.50

46

9

9.42

C

287

B

_ga9

ga

12.

6889

0.00

01

0.02

48

0.01

98

0.11

3

0

0.

1112

86

.268

9

99

.23

C29

0

B_g

a10

g

a

1

2.76

58

0.

0001

0.

0097

0

0

.106

6

0.02

76

0.03

42

86.3

366

99.2

8 C

290

B

_ga1

1

ga

12.

6371

0.00

29

0.01

2

0.0

044

0.0

916

0

0.02

31

86.5

788

99.3

5 C

290

B

_ga1

2

ga

12.

5896

0.01

2

0.0

075

0.0

113

0.1

063

0

0.06

07

85.9

987

98.7

9 C

301

A

_ga4

ga

13.

2545

0.00

01

0.01

46

0.01

83

0.07

59

0.02

8

0.1

441

86.

4605

100

.00

C30

1

A_g

a5

g

a

1

3.16

33

0.

0361

0.

0133

0.

0024

0.

0931

0.

031

0

.096

4

8

6.55

4

9

9.99

C

301

A

_ga6

ga

13.

1385

0.01

55

0.01

09

0.00

01

0.11

97

0.02

81

0.16

86.

4049

99.

88

C31

7

C_g

a13

g

a

1

2.66

76

0.

006

0

.020

3

0

.021

2

0

.069

8

0

0.

0891

87

.287

7

10

0.16

C

317

C

_ga1

4

ga

12.

756

0.00

61

0.01

44

0.01

82

0.07

96

0

0.

0951

86

.992

3

99

.96

C31

7

C_g

a15

g

a

1

2.77

23

0.

0001

0.

013

0

.023

9

0

.110

2

0

0.

1581

87

.285

6

10

0.36

C

317

D

_ga1

9

ga

12.

6602

0.05

87

0.01

86

0.00

78

0.14

22

0

0.

1726

86

.428

3

99

.49

C31

7

D_g

a20

g

a

1

2.78

13

0.

049

0

.015

0

.016

6

0

.164

7

0.01

24

0.11

8

86.

7583

99.

92

C31

7

D_g

a21

g

a

1

2.63

08

0.

3445

0.

0233

0.

0108

0.

1705

0

0.17

14

85.4

396

98.7

9 C

326

A

_ga7

ga

12.

3666

0.03

27

0.01

05

0.00

74

0.12

42

0

0.

1371

84

.679

3

97

.36

C32

6

A_g

a8

g

a

1

2.15

09

0.

0555

0.

0183

0.

0025

0.

1317

0

0.09

66

85.4

298

97.8

9 C

326

A

_ga9

ga

12.

405

0.43

12

0

0.0

207

0.1

289

0.

0122

0.

1222

85

.193

6

98

.31

C32

9

aA

_ga1

0

ga

1

3.09

74

0.

0142

0.

0106

0.

0001

0.

0696

0.

0316

0.

1062

87

.568

5

10

0.90

C

329

a

A_g

a11

ga

13.

0304

0.00

01

0.00

92

0.00

61

0.11

14

0.00

91

0.08

28

86.6

664

99.9

2 C

329

a

A_g

a12

ga

12.

8047

0.00

01

0.01

89

0.01

09

0.08

45

0

0.

109

8

6.65

31

9

9.68

C

329

a

B_g

a22

ga

12.

6622

0.00

3

0.0

025

0.0

041

0.0

682

0

0.11

65

87.4

211

100.

28

C32

9

aB

_ga2

3

ga

1

2.75

78

0.

0135

0.

005

0

.012

1

0

.077

3

0.00

72

0.06

35

86.8

134

99.7

5 C

329

a

B_g

a24

ga

12.

7151

0.00

01

0.02

88

0.01

48

0.07

85

0.00

8

0.0

676

86.

6941

99.

61

C34

1

B_g

a10

g

a

1

3.23

26

0.

0096

0.

0239

0.

0076

0.

0632

0.

0373

0.

0669

86

.007

4

99

.45

C34

1

B_g

a11

g

a

1

3.14

22

0.

03

0

.022

7

0

.025

6

0

.077

4

0.02

76

0.02

72

86.9

121

100.

26

C34

1

B_g

a12

g

a

1

3.12

76

0.

0213

0.

0182

0.

0053

0.

1049

0

0.06

89

86.6

657

100.

01

C34

1

D_g

a22

g

a

1

3.20

04

0.

0001

0

0

.012

4

0

.075

4

0

0.

1167

86

.185

8

99

.59

C34

1

D_g

a23

g

a

1

3.13

34

0.

0233

0.

0093

0

0

.053

4

0

0.

0696

86

.517

1

99

.81

C34

1

D_g

a24

g

a

1

3.20

52

0.

0259

0.

014

0

.010

6

0

.099

1

0.02

21

0.04

89

86.8

464

100.

27

C35

9

B_g

a13

g

a

1

2.85

78

0.

0411

0.

0008

0.

013

0.

2387

0.

0426

0.

0255

87

.076

10

0.30

C

359

B

_ga1

4

ga

12.

9805

0.02

62

0.01

74

0.02

12

0.20

55

0.01

88

0.00

01

87.1

207

100.

39

C35

9

B_g

a15

g

a

1

2.93

53

0.

0218

0.

0168

0.

007

0.

2233

0.

0124

0.

0001

86

.507

1

99

.72

C36

2

A_g

a4

g

a

1

2.56

34

0.

021

0

.018

6

0

.008

0

.128

7

0.03

48

0.12

93

86.0

127

98.9

2 C

362

A

_ga5

ga

12.

6081

0.02

67

0.01

15

0.00

91

0.04

69

0

0.

0567

86

.323

99

.08

C36

2

A_g

a6

g

a

1

2.47

79

0.

0385

0.

0092

0.

0202

0.

0806

0

0.09

26

86.3

103

99.0

3 C

362

C

_ga2

2

ga

12.

7457

0.01

78

0.01

75

0.01

08

0.05

9

0

0.

0994

85

.812

8

98

.76

C36

2

C_g

a23

g

a

1

2.62

55

0.

0371

0.

0061

0.

0135

0.

1306

0

0.11

64

86.3

635

99.2

9

sam

ple

poin

t

t

ype

W

%(S

)

W

%(Z

n)

W

%(A

s)

W

%(S

e)

W

%(A

g)

W

%(C

d)

W

%(S

b)

W

%(P

b)

W

%(s

um)

Appendix 4: Microprobe Analysis—Sulphides

41

C36

2

C_g

a24

g

a

1

2.61

94

0.

004

0

.015

8

0

.001

1

0

.086

6

0.00

45

0.09

01

86.3

349

99.1

6 C

364

A

_ga7

ga

12.

8603

0.05

58

0.00

21

0.00

34

1.03

22

0

0.

0001

83

.501

3

97

.46

C36

4

A_g

a8

g

a

1

2.74

45

0.

0437

0

0

.007

9

1

.064

4

0.00

61

0.00

01

83.9

966

97.8

6 C

364

A

_ga9

ga

12.

8497

0.19

29

0.00

05

0.01

35

0.98

66

0

0.

0123

84

.251

8

98

.31

C36

5

C_g

a19

g

a

1

2.67

57

0.

015

0

.006

6

0

0.11

89

0

0.

1091

86

.276

4

99

.20

C36

5

C_g

a20

g

a

1

2.73

32

0.

0115

0.

0172

0.

0137

0.

1403

0.

0237

0.

122

8

6.25

38

9

9.32

C

365

C

_ga2

1

ga

12.

7325

0.00

27

0.01

38

0.00

02

0.12

73

0

0.

1168

87

.101

7

10

0.10

C

284

B

_ga1

0

ga

12.

8376

0.04

34

0.00

62

0.01

18

0.28

19

0.01

1

0.0

26

86.

8855

100

.10

C28

4

B_g

a11

g

a

1

2.71

55

0.

0391

0.

0021

0.

009

0.

3095

0.

0254

0.

04

8

6.71

27

9

9.85

C

284

B

_ga1

2

ga

12.

8879

0.36

68

0.00

15

0.01

91

0.30

01

0

0.

0001

86

.094

2

99

.67

C29

7

C_g

a13

g

a

1

2.80

13

0.

0001

0.

013

0

.002

7

0

.046

5

0.00

02

0.07

4

87.

3864

100

.32

C29

7

C_g

a14

g

a

1

2.64

91

0.

0001

0.

0194

0.

0117

0.

0636

0.

0121

0.

025

8

7.39

46

1

00.1

8 C

297

C

_ga1

5

ga

12.

7479

0.01

94

0.00

44

0.01

04

0.11

19

0

0.

0329

86

.992

2

99

.92

C29

9

B_g

a7

g

a

1

3.40

99

0.

2686

0.

0179

0.

0089

0.

1032

0

0.01

61

86.2

867

100.

11

C29

9

B_g

a8

g

a

1

3.33

33

0.

5612

0.

0111

0.

0118

0.

088

0

.022

7

0.02

09

86.5

593

100.

61

C29

9

B_g

a9

g

a

1

3.35

92

1.

1785

0.

0218

0.

015

0.

1115

0.

0272

0.

0001

86

.341

5

10

1.05

C

337

A

_ga7

ga

12.

0694

0.15

37

0.01

28

0.01

43

0.12

64

0

0.

0978

85

.081

9

97

.56

C33

7

A_g

a8

g

a

1

2.33

65

0.

2057

0.

0212

0.

0217

0.

0489

0.

0337

0.

0695

84

.380

8

97

.12

C33

7

A_g

a9

g

a

1

2.31

4

0.

0655

0.

0128

0.

0024

0.

1095

0

0.11

13

85.0

413

97.6

6 C

337

B

_ga1

6

ga

12.

4865

0.36

25

0.01

58

0

0.0

543

0.

003

0

.067

1

8

5.49

92

9

8.49

C

337

B

_ga1

7

ga

12.

4602

1.32

16

0.01

83

0.02

36

0.11

92

0

0.

0757

84

.943

2

98

.96

C33

7

B_g

a18

g

a

1

2.36

2

0.

2995

0.

0021

0.

0151

0.

0692

0

0.09

03

85.3

027

98.1

4 C

345

B

_ga1

0

ga

13.

3238

0.01

56

0.01

76

0.01

88

0.04

63

0

0.

0968

86

.635

4

10

0.15

C

345

B

_ga1

1

ga

13.

2677

0.03

4

0.0

181

0.0

149

0.1

091

0

0.11

81

86.5

895

100.

15

C34

5

B_g

a12

g

a

1

3.24

45

0.

0273

0.

0233

0.

022

0.

0494

0

0.05

36

86.4

64

99.8

8 C

345

C

_ga1

6

ga

13.

1737

0.01

63

0.01

56

0.01

75

0.08

9

0

0.

1353

86

.200

5

99

.65

C34

5

C_g

a17

g

a

1

3.26

67

0.

0186

0.

0188

0.

0022

0.

0928

0

0.09

56

86.5

833

100.

08

C34

5

C_g

a18

g

a

1

3.08

94

0.

0387

0.

0128

0.

0227

0.

1061

0

0.11

14

85.6

06

98.9

9 C

353

C

_ga1

6

ga

13.

0515

0.31

12

0.01

3

0.0

099

0.1

02

0

0.03

85

87.4

668

100.

99

C35

3

C_g

a17

g

a

1

2.92

94

0.

0492

0.

0145

0.

0062

0.

0761

0.

0001

0.

0459

87

.076

6

10

0.20

C

353

C

_ga1

8

ga

12.

8594

0.13

2

0.0

251

0.0

225

0.1

397

0.

0161

0.

0124

86

.761

2

99

.97

C37

9

C_g

a13

g

a

1

3.20

05

0.

0019

0.

0044

0.

0172

0.

7334

0

0.00

01

83.9

594

97.9

2 C

379

C

_ga1

3

ga

12.

7233

0.00

1

0.0

002

0.0

202

0.7

678

0.

0177

0.

0001

84

.769

3

98

.30

C37

9

C_g

a14

g

a

1

3.35

52

0.

0187

0.

0021

0.

0146

0.

7485

0.

0155

0.

0237

84

.840

6

99

.02

C37

9

C_g

a14

g

a

1

2.78

95

0.

0001

0.

0029

0.

0079

0.

8121

0

0.00

23

84.5

23

98.1

4 C

379

C

_ga1

5

ga

13.

2699

0.01

35

0.00

2

0.0

106

0.8

065

0

0.00

36

83.8

33

97.9

4 C

379

C

_ga1

5

ga

12.

7988

0.03

54

0.00

94

0.01

93

0.81

69

0

0.

0001

84

.894

8

98

.57

C38

5

B_g

a13

g

a

1

3.34

95

0.

1797

0.

0053

0.

0198

0.

076

0

.016

7

0.05

34

87.3

425

101.

04

sam

ple

poin

t

t

ype

W

%(S

)

W

%(Z

n)

W

%(A

s)

W

%(S

e)

W

%(A

g)

W

%(C

d)

W

%(S

b)

W

%(P

b)

W

%(s

um)

Appendix 4: Microprobe Analysis—Sulphides

42

C38

5

B_g

a14

ga

13.

2023

0.12

88

0.01

68

0.01

55

0.08

05

0.02

42

0.04

77

87.0

878

100.

60

C38

5

B_g

a15

ga

13.

2461

0.36

01

0.02

61

0.02

22

0.05

47

0

0.

0835

85

.652

9

99

.45

C38

5

C_g

a22

ga

13.

2357

0.03

41

0.00

36

0.00

85

0.07

3

0.0

023

0.

0561

85

.793

4

99

.21

C38

5

C_g

a23

ga

13.

3775

0.07

31

0.01

71

0.00

28

0.05

39

0

0.

0749

87

.666

6

10

1.27

C

385

C

_ga2

4

ga

1

3.16

85

0.

1016

0.

0158

0.

0195

0.

0824

0.

0011

0.

0922

85

.923

4

99

.40

C37

8

B_g

a10

ga

12.

587

0.00

01

0.01

79

0.01

66

0.06

18

0

0.

0813

86

.121

3

98

.89

C37

8

B_g

a11

ga

12.

7076

0.00

1

0.0

05

0

0.

0441

0.

0079

0.

0913

87

.132

2

99

.99

C37

8

B_g

a12

ga

12.

6313

0.00

62

0.02

05

0.01

81

0.08

78

0

0.

0659

86

.550

4

99

.38

C37

8

B_g

a7

g

a

12

.633

9

0.0

194

0.0

017

0.0

065

0.0

886

0.

0065

0.

0969

87

.080

6

99

.93

C37

8

B_g

a8

g

a

12

.656

0.0

125

0.0

008

0.0

099

0.1

017

0

0.1

86.

2547

99.

14

C37

8

B_g

a9

g

a

13

.996

2

0.0

415

0.0

219

0.0

041

0.0

997

0

0.05

35

83.3

915

97.6

1 sa

mpl

e po

int

typ

e

W%

(S )

W%

(Zn)

W%

(As)

W%

(Se)

W%

(Ag)

W%

(Cd)

W%

(Sb)

W%

(Pb)

W%

(sum

)

C07

9

_C

py_1

0

cp

y

34

.573

5

0.00

57

29

.787

7

0

0.00

01

33.8

967

0

.074

2

0.

0197

0.00

78

0

.000

1

0.

0001

98

.37

C07

9

_C

py_1

1

cp

y

34

.927

1

0.00

01

30

.089

0

0.00

32

33.9

158

0

.066

0.

0148

0.00

01

0

.018

4

0.

0001

99

.03

C07

9

_C

py_1

2

cp

y

34

.649

5

0.00

01

30

.034

0

0.00

45

33.9

894

0

.072

5

0.

017

0.0

028

0.00

01

0.

0001

98

.77

C08

2

_C

py_4

cp

y

34

.159

6

0.00

96

30

.318

3

0

0.00

01

33.8

851

0

.053

5

0.

0284

0.01

04

0

.046

2

0.

0001

98

.51

C08

2

_C

py_5

cp

y

34

.292

5

0.01

23

30

.412

0

0.00

01

34.0

305

0

.083

3

0.

0219

0.00

45

0

.000

1

0.

0093

98

.87

C08

2

_C

py_6

cp

y

33

.997

6

0.00

72

30

.201

5

0

0.00

52

33.8

913

0

.057

0.

0104

0.01

26

0

.000

1

0.

0001

98

.18

C28

0

B_C

py_7

cpy

34.4

282

0.

0032

29.3

276

0

0.

0009

32

.615

2

0.0

577

0.01

42

0.

0083

0.0

001

0.00

01

96.4

6 C

280

B

_Cpy

_8

c

py

34

.490

3

0.00

01

29

.562

5

0

0.00

01

32.9

57

0

.068

2

0.

0118

0.00

35

0

.018

4

0.

0001

97

.11

C28

0

B_C

py_9

cpy

34.2

462

0.

0073

29.2

814

0

0.

0001

32

.625

1

0.0

718

0.01

97

0.

0155

0.0

001

0.00

01

96.2

7 C

284

B

_Cpy

_7

c

py

34

.748

1

0.00

01

29

.643

7

0

0.00

01

31.7

972

0

.067

8

0.

0142

0.00

59

0

.000

1

0.

001

9

6.28

C

284

B

_Cpy

_8

c

py

34

.957

4

0.00

74

29

.606

6

0

0.00

06

32.2

721

0

.064

7

0.

0242

0.00

86

0

.006

4

0.

0095

96

.96

C28

4

B_C

py_9

cpy

34.5

931

0.

002

29.

5471

0

0.

0008

32

.346

5

0.0

651

0.02

08

0.

0209

0.0

001

0.00

01

96.6

0 C

290

C

_Cpy

_16

c

py

34

.386

9

0.00

53

29

.785

8

0

0.00

01

33.0

072

0

.060

9

0.

0151

0.01

18

0

.000

1

0.

0001

97

.27

C29

0

C_C

py_1

7

cpy

34.3

392

0.

0062

29.8

398

0

0.

0001

32

.904

1

0.0

634

0.01

4

0

.011

1

0.

0123

0.00

01

97.1

9 C

290

C

_Cpy

_18

c

py

34

.224

5

0.00

23

29

.741

5

0

0.00

6

33.

1172

0.04

79

0

.014

1

0.

0142

0.0

001

0.00

01

97.1

7 C

292

A

_Cpy

_1

c

py

34

.685

0.00

32

29

.867

8

0

0.00

79

32.5

974

0

.059

4

0.

0283

0.01

71

0

.003

0.

0001

97

.27

C29

2

A_C

py_2

cpy

34.6

582

0.

0072

30.0

583

0

0.

0001

33

.035

4

0.0

682

0.02

27

0.

0004

0.0

375

0.00

01

97.8

9 C

292

A

_Cpy

_3

c

py

34

.528

8

0.00

01

29

.640

4

0

0.00

01

32.4

534

0

.072

5

0.

0224

0.00

6

0

.034

5

0.

0001

96

.76

C29

7

C_C

py_1

0

cpy

34.8

089

0.

0011

29.4

72

0

0.

0001

31

.366

5

0.0

717

0.03

32

0.

0144

0.0

084

0.00

01

95.7

8 C

297

C

_Cpy

_11

c

py

34

.881

5

0.00

01

29

.769

9

0

0.00

01

31.8

953

0

.065

1

0.

0114

0.00

65

0

.024

0.

0001

96

.65

C29

7

C_C

py_1

2

cpy

34.9

128

0.

0061

29.5

942

0

0.

0124

31

.443

8

0.0

621

0.02

11

0.

017

0.0

018

0.00

01

96.0

7

sam

ple

poin

t

ty

pe

W%

(S )

W

%(M

n)

W%

(Fe)

W

%(C

o)

W%

(Ni)

W%

(Cu)

W

%(A

s)

W%

(Se)

W

%(A

g)

W%

(Au)

W

%(B

i) W

%(s

um)

Appendix 4: Microprobe Analysis—Sulphides

43

C31

7

A_C

py_1

cp

y

34.

8137

0

.000

1

29

.772

9

0

0.00

01

32.6

096

0

.048

7

0.

0164

0.0

06

0.00

01

0.

0001

97

.27

C31

7

A_C

py_2

cp

y

34.

772

0.00

01

2

9.50

45

0

0.00

01

32.5

853

0

.078

7

0.

0339

0.0

026

0.00

01

0.

0001

96

.98

C31

7

A_C

py_3

cp

y

34.

7319

0

.000

4

29

.609

1

0

0.00

01

32.3

709

0

.063

6

0.

0186

0.0

001

0.00

01

0.

0001

96

.79

C32

3

A_C

py_1

cp

y

34.

6009

0

.004

5

29

.469

3

0

0.00

01

31.5

106

0

.074

3

0.

0125

0.0

279

0.00

01

0.

0001

95

.70

C32

3

A_C

py_2

cp

y

34.

628

0.00

01

2

9.73

3

0

0.

0036

32

.065

3

0.0

723

0.00

58

0

.048

1

0.

0307

0.00

01

96.5

9 C

323

A

_Cpy

_3

cpy

3

4.64

64

0.0

07

29.5

517

0

0.

0001

31

.729

1

0.0

802

0.02

11

0

.044

9

0.

0001

0.00

01

96.0

8 C

329

a

A_C

py_1

cpy

3

4.59

83

0.0

075

29.8

782

0

0.

0001

32

.463

2

0.0

673

0.00

87

0

.025

2

0.

0001

0.00

01

97.0

5 C

329

a

A_C

py_2

cpy

3

4.58

02

0.0

049

29.7

585

0

0.

0001

32

.443

0.0

571

0.01

06

0

.023

1

0.

0213

0.00

01

96.9

0 C

329

a

A_C

py_3

cpy

3

4.67

67

0.0

001

29.9

271

0

0.

0182

32

.413

7

0.0

698

0.01

99

0

.029

2

0.

0001

0.00

01

97.1

5 C

329

a

B_C

py_1

3

cpy

3

4.49

01

0.0

029

29.6

813

0

0.

0001

31

.898

1

0.0

695

0.01

97

0

.02

0.

0057

0.00

01

96.1

9 C

329

a

B_C

py_1

4

cpy

3

4.81

19

0.0

015

29.7

983

0

0.

0088

32

.264

0.0

746

0.00

84

0

.025

5

0.

0036

0.00

01

97.0

0 C

329

a

B_C

py_1

5

cpy

3

4.74

5

0.

0001

29.

6755

0

0.

0002

32

.319

0.0

719

0.02

35

0

.033

6

0.

0001

0.00

01

96.8

7 C

329

b

A_C

py_4

cpy

3

5.93

27

0.0

119

30.0

628

0

0.

0053

33

.072

6

0.0

573

0.02

02

0

.000

3

0.

0001

0.00

01

99.1

6 C

329

b

A_C

py_5

cpy

3

6.17

6

0.

007

30.

0851

0

0.

0115

32

.946

1

0.0

632

0.02

5

0

.000

1

0.

0001

0.00

19

99.3

2 C

329

b

A_C

py_6

cpy

3

5.90

24

0.0

001

30.2

312

0

0.

0001

32

.963

9

0.0

637

0.02

46

0

.000

1

0.

0215

0.00

01

99.2

1 C

329

b

B_C

py_1

3

cpy

3

5.88

08

0.0

034

29.7

702

0

0.

0011

33

.259

0.0

695

0.01

03

0

.000

3

0.

0001

0.00

01

98.9

9 C

329

b

B_C

py_1

4

cpy

3

6.06

21

0.0

001

29.5

645

0

0.

0071

33

.085

9

0.0

639

0.00

64

0

.000

1

0.

0001

0.00

01

98.7

9 C

329

b

B_C

py_1

5

cpy

3

5.85

58

0.0

001

29.8

539

0

0.

005

3

2.84

72

0.0

704

0.01

06

0

.003

1

0.

0001

0.00

01

98.6

5 C

343

C

_Cpy

_13

c

py

34

.955

2

0.00

24

2

9.41

29

0

0.01

15

31.8

774

0

.069

9

0.

0156

0.0

658

0.00

62

0.

0001

96

.42

C34

3

C_C

py_1

4

cpy

34.7

455

0.

0001

29.

7748

0

0.

0001

32

.076

6

0.0

662

0.01

85

0

.057

4

0.

0001

0.00

01

96.7

4 C

343

C

_Cpy

_15

c

py

34

.795

7

0.00

01

2

9.67

22

0

0.00

27

32.1

64

0

.058

2

0.

0187

0.0

585

0.06

6

0

.000

1

96.8

4 C

350

B

_Cpy

_7

cpy

3

4.51

96

0.0

141

29.8

461

0

0.

0182

32

.689

2

0.0

705

0.01

73

0

.021

0.

0001

0.01

22

97.2

1 C

350

B

_Cpy

_8

cpy

3

4.65

45

0.0

009

30.0

412

0

0.

004

3

2.61

91

0.0

846

0.01

39

0

.005

8

0.

0001

0.00

01

97.4

2 C

350

B

_Cpy

_9

cpy

3

4.50

74

0.0

018

29.9

898

0

0.

0001

32

.637

0.0

725

0.02

46

0

.004

3

0.

0001

0.00

01

97.2

4 C

359

B

_Cpy

_7

cpy

3

4.85

01

0.0

001

29.7

146

0

0.

0077

32

.489

5

0.0

661

0.02

33

0

.015

3

0.

0421

0.00

01

97.2

1 C

359

B

_Cpy

_8

cpy

3

4.94

88

0.0

015

29.6

27

0

0.

0001

32

.794

9

0.0

787

0.02

92

0

.039

8

0.

0001

0.00

01

97.5

2 C

359

B

_Cpy

_9

cpy

3

4.88

13

0.0

042

29.5

716

0

0.

0001

32

.506

0.0

704

0.01

0

.022

3

0.

0416

0.00

01

97.1

1 C

364

C

_Cpy

_31

c

py

34

.352

9

0.00

48

2

9.98

33

0

0.00

01

33.0

346

0

.064

6

0.

0223

0.0

061

0.01

74

0.

0036

97

.49

C36

4

C_C

py_3

2

cpy

34.5

076

0.

0001

29.

7768

0

0.

009

3

2.99

64

0.0

691

0.01

51

0

.026

5

0.

0001

0.00

01

97.4

0 C

364

C

_Cpy

_33

c

py

34

.327

0.00

01

2

9.69

45

0

0.00

11

32.3

585

0

.055

2

0.

015

0.0

479

0.00

4

0

.005

8

96.5

1 C

369

C

_Cpy

_13

c

py

36

.063

0.00

01

2

9.99

63

0

0.00

01

33.3

975

0

.072

8

0.

0184

0.0

123

0.00

01

0.

0001

99

.56

C36

9

C_C

py_1

4

cpy

36.3

896

0.

0001

29.

6639

0

0.

0001

33

.237

3

0.0

633

0.02

61

0

.022

3

0.

0583

0.00

01

99.4

6 C

369

C

_Cpy

_15

c

py

35

.712

8

0.00

01

2

9.62

35

0

0.00

14

33.1

607

0

.064

9

0.

0184

0.0

226

0.04

19

0.

0001

98

.65

C37

8

B_C

py_1

3

cp

y

34.

526

0.00

01

2

9.75

4

0

0.

0008

32

.798

5

0.0

694

0.02

09

0

.011

7

0.

004

0.0

001

97

.19

C37

8

B_C

py_1

4

cp

y

34.

5979

0

.000

1

29

.212

1

0

0.00

01

32.4

533

0

.055

5

0.

0172

0.0

044

0.00

01

0.

0001

96

.34

C37

8

B_C

py_1

5

cp

y

34.

4275

0

.001

9

29

.346

8

0

0.00

19

32.3

053

0

.066

7

0.

0096

0.0

001

0.00

01

0.

0201

96

.18

C38

1

A_C

py_1

cp

y

34.

5971

0

.000

1

29

.870

7

0

0.00

61

32.3

532

0

.076

8

0.

0168

0.0

434

0.00

7

0

.000

1

96.9

7 C

381

A

_Cpy

_2

cpy

3

4.64

14

0.0

108

29.7

498

0

0.

0169

32

.689

4

0.0

778

0.02

02

0

.036

3

0.

0138

0.00

01

97.2

6

sam

ple

poin

t

ty

pe

W%

(S )

W

%(M

n)

W%

(Fe)

W

%(C

o)

W%

(Ni)

W%

(Cu)

W

%(A

s)

W%

(Se)

W

%(A

g)

W%

(Au)

W

%(B

i) W

%(s

um)

Appendix 4: Microprobe Analysis—Sulphides

44

C38

1

A_C

py_3

cp

y

34.

9643

0

.000

1

29

.9

0

0.00

01

32.4

031

0

.063

8

0.

0245

0.0

413

0.00

01

0.

0001

97

.40

C38

5

D_C

py_2

5

cpy

36.0

024

0.

0045

29.

3764

0

0.

0001

31

.310

8

0.0

765

0.02

61

0

.003

9

0.

0001

0.00

01

96.8

0 C

385

D

_Cpy

_26

c

py

36

.105

1

0.00

56

2

9.31

96

0

0.01

7

31.

6476

0

.064

9

0.

0164

0.0

001

0.00

01

0.

0001

97

.18

C38

5

D_C

py_2

7

cpy

35.7

797

0.

0007

29.

1304

0

0.

0001

31

.037

9

0.0

666

0.01

72

0

.004

0.

0127

0.00

01

96.0

5 C

794

_

Cpy

_7

cpy

35.1

764

0.

0004

30.

0681

0

0.

0003

32

.688

1

0.0

689

0.01

93

0

.000

1

0.

0001

0.00

41

98.0

3 C

794

_

Cpy

_8

cpy

35.0

633

0.

0007

30.

2681

0

0.

0039

32

.285

7

0.0

527

0.00

83

0

.013

7

0.

0001

0.00

01

97.7

0 C

794

_

Cpy

_9

cpy

35.0

185

0.

0001

30.

0075

0

0.

0071

32

.421

3

0.0

59

0.01

35

0

.004

7

0.

0001

0.00

41

97.5

4 C

801

_

Cpy

_11

cpy

33.6

62

0.

0001

30.

5901

0

0.

0001

31

.345

1

0.6

064

0.02

45

0

.015

7

0.

0001

0.00

77

96.2

5 C

803

_

Cpy

_7

cpy

34.7

955

0.

0001

30.

1988

0

0.

0014

32

.605

7

0.0

647

0.02

35

0

.015

3

0.

0001

0.00

01

97.7

1 C

803

_

Cpy

_8

cpy

35.0

575

0.

0016

30.

0195

0

0.

0001

32

.800

6

0.0

621

0.01

58

0

.029

7

0.

0178

0.00

01

98.0

0 C

803

_

Cpy

_9

cpy

34.8

997

0.

0001

30.

0836

0

0.

0001

32

.787

3

0.0

566

0.01

97

0

.002

4

0.

0061

0.00

68

97.8

6 C

809

_

Cpy

_4

cpy

35.2

576

0.

0001

30.

0658

0

0.

0001

33

.345

1

0.0

699

0.01

86

0

.000

1

0.

0001

0.02

74

98.7

8 C

809

_

Cpy

_5

cpy

35.1

102

0.

0066

30.

1312

0

0.

0076

33

.387

7

0.0

659

0.02

39

0

.010

8

0.

0024

0.00

01

98.7

5 C

809

_

Cpy

_6

cpy

35.2

419

0.

0085

30.

2487

0

0.

0001

33

.703

2

0.0

699

0.01

35

0

.006

4

0.

0001

0.00

72

99.3

0 C

814

_

Cpy

_1

cpy

34.2

9

0

.000

1

30

.100

5

0

0.00

01

33.9

254

0

.064

9

0.

0189

0.0

444

0.02

52

0.

0001

98

.47

C81

4

_C

py_2

c

py

34

.399

0.00

19

3

0.00

89

0

0.00

01

34.1

57

0

.078

9

0.

0065

0.0

185

0.00

01

0.

0001

98

.67

C81

4

_C

py_3

c

py

34

.540

3

0.00

01

3

0.02

1

0

0.

0001

34

.006

5

0.0

589

0.02

34

0

.022

4

0.

0001

0.00

01

98.6

7 C

822

_

Cpy

_4

cpy

34.4

232

0.

0055

30.

9275

0

0.

0001

32

.618

6

0.0

62

0.00

86

0

.043

9

0.

0001

0.00

01

98.0

9 C

822

_

Cpy

_5

cpy

34.6

667

0.

0001

30.

833

0

0.00

01

32.8

575

0

.052

8

0.

0098

0.0

333

0.00

01

0.

0001

98

.45

C82

2

_C

py_6

c

py

34

.662

5

0.00

46

3

0.89

05

0

0.01

05

32.9

633

0

.069

0.

0165

0.0

301

0.03

65

0.

0001

98

.68

C82

4

_C

py_1

c

py

34

.390

4

0.20

98

3

0.70

66

0

0.00

01

33.1

532

0

.058

6

0.

0045

0.0

205

0.00

01

0.

0001

98

.54

C82

4

_C

py_2

c

py

34

.499

5

0.01

55

3

0.87

08

0

0.00

01

33.3

494

0

.077

9

0.

0176

0.0

409

0.04

21

0.

0001

98

.91

C82

4

_C

py_3

c

py

34

.293

6

0.01

46

3

0.80

5

0

0.

0001

33

.492

2

0.0

745

0.01

62

0

.022

6

0.

0432

0.00

01

98.7

6 C

825

_

Cpy

_7

cpy

34.3

396

0.

0051

30.

7701

0

0.

0009

32

.304

4

0.0

782

0.02

9

0

.038

5

0.

0001

0.00

01

97.5

7 C

825

_

Cpy

_8

cpy

34.2

754

0.

0049

30.

4228

0

0.

0001

32

.678

7

0.0

748

0.01

33

0

.055

2

0.

0025

0.00

01

97.5

3 C

825

_

Cpy

_9

cpy

34.3

38

0.

0023

30.

6143

0

0.

0001

33

.000

7

0.0

698

0.02

22

0

.042

9

0.

0001

0.00

01

98.0

9 C

826

_

Cpy

_1

cpy

34.6

791

0.

0006

29.

8762

0

0.

0001

33

.993

2

0.0

781

0.01

43

0

.010

3

0.

0001

0.00

01

98.6

5 C

826

_

Cpy

_2

cpy

34.6

636

0.

0001

29.

9686

0

0.

0001

33

.640

1

0.0

558

0.01

74

0

.023

2

0.

0095

0.00

01

98.3

8 C

826

_

Cpy

_3

cpy

34.6

549

0.

0043

30.

019

0

0.00

01

33.8

09

0

.070

9

0.

0148

0.0

088

0.00

01

0.

0001

98

.58

C82

8

_C

py_7

c

py

34

.524

7

0.00

16

3

0.75

22

0

0.00

01

33.2

876

0

.054

5

0.

0196

0.0

122

0.00

01

0.

0001

98

.65

C82

8

_C

py_8

c

py

34

.297

4

0.01

15

3

0.69

55

0

0.00

05

33.1

405

0

.061

4

0.

0271

0.0

005

0.01

34

0.

0001

98

.25

C82

8

_C

py_9

c

py

34

.446

6

0.00

99

3

0.64

42

0

0.00

01

32.9

123

0

.062

8

0.

0145

0.0

013

0.00

01

0.

0001

98

.09

C83

3

_C

py_4

c

py

34

.891

4

0.02

57

2

9.93

39

0

0.00

01

33.7

704

0

.081

1

0.

0137

0.0

058

0.00

01

0.

0001

98

.72

C83

3

_C

py_5

c

py

34

.752

8

0.01

11

2

9.89

24

0

0.00

2

33.

5366

0

.072

8

0.

0187

0.0

108

0.01

19

0.

0001

98

.31

C83

3

_C

py_6

c

py

34

.982

7

0.00

04

2

9.72

43

0

0.01

24

33.6

196

0

.069

0.

0146

0.0

153

0.00

01

0.

0001

98

.44

C83

5

_C

py_7

c

py

34

.388

4

0.00

01

3

0.56

97

0

0.01

46

32.8

07

0

.075

8

0.

0269

0.0

001

0.00

01

0.

0001

97

.88

C83

5

_C

py_8

c

py

34

.311

3

0.00

01

3

0.88

83

0

0.00

01

32.6

705

0

.077

4

0.

0217

0.0

291

0.03

77

0.

0001

98

.04

C83

5

_C

py_9

c

py

34

.639

7

0.00

01

3

0.50

74

0

0.00

01

32.8

075

0

.063

9

0.

0103

0.0

087

0.00

01

0.

0001

98

.04

sam

ple

poin

t

ty

pe

W%

(S )

W

%(M

n)

W%

(Fe)

W

%(C

o)

W%

(Ni)

W%

(Cu)

W

%(A

s)

W%

(Se)

W

%(A

g)

W%

(Au)

W

%(B

i) W

%(s

um)

Appendix 4: Microprobe Analysis—Sulphides

45

C84

0

_C

py_4

c

py

35

.454

1

0.00

5

3

0.63

88

0

0.00

01

32.9

504

0

.059

0.

0253

0.0

545

0.02

03

0.

0001

99

.21

C84

0

_C

py_5

c

py

35

.445

2

0.00

01

3

0.83

09

0

0.00

14

33.1

199

0

.074

1

0.

0136

0.0

467

0.00

01

0.

0001

99

.53

C84

1

_C

py_4

c

py

34

.664

1

0.00

01

2

9.85

62

0

0.00

44

34.2

495

0

.056

3

0.

0063

0.0

228

0.00

01

0.

0001

98

.86

C84

1

_C

py_5

c

py

34

.640

2

0.00

23

3

0.28

72

0

0.01

21

34.0

111

0

.069

9

0.

0087

0.0

369

0.01

0

.003

6

99.0

8 C

841

_

Cpy

_6

cpy

34.9

441

0.

0001

30.

1559

0

0.

0001

34

.061

4

0.0

775

0.00

1

0.02

66

0

.039

7

0.

0001

99

.31

C84

8

_C

py_1

3

cp

y

34.

4948

0

.021

3

31

.636

8

0

0.00

01

33.6

053

0

.051

9

0.

0341

0.0

234

0.00

41

0.

0001

99

.87

C84

8

_C

py_1

4

cp

y

34.

1082

0

.064

8

31

.703

8

0

0.01

04

33.0

579

0

.048

0.

013

0.

0193

0.0

18

0.00

01

99.0

4 C

848

_

Cpy

_15

cpy

3

4.29

55

0.0

573

31.2

964

0

0.

0011

33

.599

1

0.0

7

0.01

34

0

.028

3

0.

0001

0.00

19

99.3

6 R

049

_

Cpy

_4

cpy

34.5

265

0.

0001

30.

1975

0

0.

0065

34

.360

4

0.0

749

0.01

23

0

.031

7

0.

0176

0.01

32

99.2

4 R

049

_

Cpy

_5

cpy

34.3

152

0.

0001

30.

2553

0

0.

0091

34

.251

6

0.0

625

0.01

49

0

.036

3

0.

0472

0.00

01

98.9

9 R

049

_

Cpy

_6

cpy

34.3

924

0.

0001

30.

4128

0

0.

0001

34

.265

7

0.0

517

0.01

39

0

.006

4

0.

0372

0.00

01

99.1

8 R

070

_

Cpy

_7

cpy

34.1

842

0.

0057

30.

2157

0

0.

0001

34

.313

1

0.0

752

0.02

53

0

.008

2

0.

0001

0.00

01

98.8

3 R

070

_

Cpy

_8

cpy

34.3

271

0.

0042

29.

9601

0

0.

0005

34

.242

1

0.0

672

0.02

58

0

.003

5

0.

0076

0.01

56

98.6

5 R

070

_

Cpy

_9

cpy

34.0

974

0.

0036

29.

9138

0

0.

0001

33

.924

3

0.0

847

0.01

79

0

.067

0.

0326

0.00

01

98.1

4 R

075

_

Cpy

_7-7

-1

cpy

34.5

951

0.

0001

29.

6783

0

0.

0001

33

.650

1

0.0

75

0.02

23

0

.013

2

0.

0259

0.01

49

98.0

8 R

075

_

Cpy

_8-8

-1

cpy

34.5

006

0.

0082

29.

9978

0

0.

0001

33

.804

4

0.0

774

0.01

36

0

.005

5

0.

0001

0.00

98

98.4

2 R

075

_

Cpy

_9-9

-1

cpy

34.3

736

0.

0001

29.

7824

0

0.

0039

33

.724

9

0.0

856

0.01

88

0

.000

1

0.

0001

0.00

01

97.9

9 sa

mpl

e po

int

type

W

%(S

)

W%

(Mn)

W

%(F

e)

W%

(Co)

W

%(N

i) W

%(C

u)

W%

(As)

W

%(S

e)

W%

(Ag)

W

%(A

u)

W%

(Bi)

W%

(sum

)

sam

ple

p

oint

t

ype

W

%(S

)

W%

(Mn)

W%

(Fe)

W

%(C

o)

W%

(Ni)

W

%(C

u)

W%

(As)

W

%(S

e)

W%

(Ag)

W

%(A

u)

W%

(Bi)

W

%(s

um)

C84

6

po_4

po

3

8.42

49

0.0

086

59

.900

5

0

0.

0001

0.0

001

0.08

69

0

.028

5

0.

0081

0.00

01

0

.000

1

98

.46

C84

6

po_5

po

3

8.73

85

0.0

001

59

.432

9

0

0.

0122

0.0

008

0.09

3

0.02

31

0.

0001

0.00

69

0

.004

9

98

.31

C84

6

po_6

po

3

8.51

65

0.0

001

59

.947

4

0

.009

4

0.

0001

0.0

012

0.10

43

0

.035

5

0.

0054

0.00

01

0

.000

1

98

.62

C84

8

po_4

po

3

8.19

61

0.0

196

60

.741

5

0

0.

0097

0.0

001

0.08

57

0

.039

3

0.

0071

0.01

87

0

.008

6

99

.13

C84

8

po_5

po

3

9.31

9

0.

0001

6

0.00

2

0.00

06

0.

0065

0.0

248

0.08

82

0

.022

2

0.

0016

0.00

01

0

.000

1

99

.47

C84

8

po_6

po

3

8.25

28

0.0

062

60

.983

4

0

0.

0043

0.0

134

0.10

55

0

.018

5

0.

0016

0.00

01

0

.000

1

99

.39

C84

8

po_7

po

3

8.28

01

0.0

115

61

.218

3

0

0.

0018

0.0

061

0.11

07

0

.022

1

0.

0001

0.00

01

0

.000

1

99

.65

C84

8

po_8

po

3

8.23

61

0.0

117

60

.835

6

0

0.

0001

0.0

097

0.09

74

0

.019

7

0.

0001

0.00

01

0

.001

1

99

.21

C84

8

po_9

po

3

8.22

2

0.

0001

6

0.89

5

0

0.01

1

0

.013

2

0.

0938

0.0

241

0.01

91

0.

0001

0.0

001

99.2

8

Appendix 4: Microprobe Analysis—Sulphides

46

C26

1

AA

spy_

4

as

py

22

.453

4

0.0

087

34.7

639

0

0.0

171

0.00

01

42

.066

1

0.1

656

0.00

01

0

.000

1

0.

0001

99.4

8 C

261

A

Asp

y_5

aspy

22.6

592

0

.004

34

.965

8

0

0

.000

1

0.

0078

42.1

275

0

.154

3

0.

0001

0.0

001

0.00

01

99

.92

C26

1

AA

spy_

6

as

py

23

.162

2

0.0

07

35.1

146

0

0.0

113

0.01

05

41

.533

8

0.1

532

0.00

01

0

.000

9

0.

0001

99.9

9 C

297

B

Asp

y_7

aspy

21.5

618

0

.000

1

34

.088

3

0

0

.000

1

0.

0001

42.2

475

0

.175

6

0.

0001

0.0

001

0.00

01

98

.07

C29

7

BA

spy_

8

as

py

20

.956

9

0.0

001

33.9

207

0

0.0

001

0.02

55

43

.124

9

0.1

639

0.00

01

0

.000

1

0.

0001

98.1

9 C

297

B

Asp

y_9

aspy

21.0

79

0

.002

3

33

.968

9

0

0

.007

3

0.

0074

42.8

918

0

.158

0.

0001

0.0

001

0.00

01

98

.12

C36

4

AA

spy_

10

asp

y

21

.591

1

0.0

085

34.4

832

0

0.0

001

0.00

01

42

.601

1

0.1

626

0.00

01

0

.000

1

0.

0069

98.8

5 C

364

A

Asp

y_11

a

spy

21.2

729

0

.017

7

34

.434

8

0

0

.000

1

0.

012

42.

8155

0

.162

1

0.

0113

0.0

001

0.00

4

9

8.73

C

364

A

Asp

y_12

a

spy

21.0

784

0

.003

6

34

.273

3

0

0

.003

6

0.

0001

43.1

498

0

.175

6

0.

0006

0.0

001

0.00

01

98

.69

C36

4

BA

spy_

16

asp

y

21

.662

8

0.0

085

34.9

084

0

0.0

001

0.02

16

42

.126

4

0.1

653

0.00

01

0

.000

1

0.

0001

98.8

9 C

364

B

Asp

y_17

a

spy

21.6

587

0

.005

2

34

.789

8

0

0

.005

9

0.

0411

42.1

384

0

.159

5

0.

0086

0.0

001

0.00

85

98

.82

C36

4

BA

spy_

18

asp

y

21

.283

7

0.0

001

35.0

426

0

0.0

001

0.00

01

42

.666

0.1

735

0.00

01

0

.000

1

0.

0001

99.1

7 C

364

B

Asp

y_28

a

spy

21.4

578

0

.000

1

34

.694

9

0

0

.000

1

0.

0168

42.7

424

0

.157

5

0.

0001

0.0

163

0.01

47

99

.10

C36

4

BA

spy_

29

asp

y

21

.391

7

0.0

001

34.5

565

0

0.0

069

0.00

89

42

.712

3

0.1

717

0.00

1

0.00

01

0.

0001

98.8

5 C

364

B

Asp

y_30

a

spy

21.1

603

0

.003

5

34

.616

2

0

0

.000

1

0.

0001

42.8

035

0

.149

3

0.

0024

0.0

001

0.00

01

98

.74

C37

2

AA

spy_

1

as

py

22

.873

2

0.0

001

34.8

281

0

0.0

001

0.00

08

41

.476

4

0.1

664

0.00

8

0.00

01

0.

0001

99.3

5 C

372

A

Asp

y_2

aspy

22.8

789

0

.000

1

34

.350

2

0

0

.000

1

0.

0001

41.6

712

0

.173

0.

0027

0.0

001

0.00

01

99

.08

C37

2

AA

spy_

3

as

py

22

.058

6

0.0

01

34.7

369

0

0.0

001

0.00

84

42

.752

0.1

477

0.00

4

0.00

01

0.

0001

99.7

1 C

372

B

Asp

y_7

aspy

23.0

547

0

.008

7

34

.538

5

0

0

.000

1

0.

0101

41.2

572

0

.155

2

0.

0023

0.0

001

0.00

01

99

.03

C37

2

BA

spy_

8

as

py

22

.382

5

0.0

001

34.1

437

0

0.0

001

0.00

01

42

.182

1

0.1

661

0.00

01

0

.018

6

0.

0003

98.8

9 C

372

B

Asp

y_9

aspy

22.4

663

0

.000

1

34

.975

1

0

0

.013

2

0.

002

42.

4215

0

.168

7

0.

01

0.

0001

0.00

01

10

0.06

C

801

A

spy_

10

a

spy

27.0

975

0

.000

1

35

.481

9

0

0

.005

3

0.

917

38.

6501

0

.156

1

0.

0201

0.0

001

0.00

01

10

2.33

C

817

A

spy_

1

a

spy

21.6

546

0

.000

1

34

.863

8

0

0

.009

8

0.

0019

42.3

685

0

.161

6

0.

0103

0.0

001

0.01

93

99

.09

C81

7

Asp

y_2

asp

y

21

.654

8

0.0

001

35.2

573

0

0.0

001

0.00

01

42

.637

4

0.1

585

0.00

01

0

.000

1

0.

0005

99.7

1 C

817

A

spy_

3

a

spy

21.6

771

0

.000

1

34

.812

7

0

0

.002

1

0.

0001

42.3

355

0

.184

8

0.

0056

0.0

1

0.00

01

99

.03

sam

ple

poi

nt

ty

pe

W

%(S

)

W%

(Mn)

W

%(F

e)

W%

(Co)

W

%(N

i)

W%

(Cu)

W

%(A

s)

W%

(Se)

W

%(A

g)

W%

(Au)

W

%(B

i)

W%

(sum

)

sam

ple

poin

t

typ

e

W%

(S )

W%

(Fe)

W%

(Cu)

W%

(Zn)

W%

(As)

W%

(Se)

W%

(Ag)

W%

(Cd)

W%

(Sb)

W

%(T

e) W

%(H

g)

W%

(Pb)

W

%(B

i) W

%(s

um)

C84

9

bo_

1-1-

1 bo

urno

nite

18.

8053

0.4

032

12

.545

9 0

.009

4

0.01

98

0.0

299

0

0.02

45

23.

7037

0

.060

9

0.00

01

42

.232

4

0.0

001

97.

84

C84

9

bo_

2-2-

1 bo

urno

nite

18.

7809

0.4

553

12

.621

9 0

.000

1

0.05

02

0.0

316

0.

0114

0

23.

5692

0

.085

8

0.00

01

41

.935

8

0.0

001

97.

54

C84

9

bo_

5-5-

1 bo

urno

nite

18.

8871

0.1

278

12

.649

5 0

.013

8

0

0.

0282

0

0

24

.019

3

0.06

59

0.00

01

42

.408

0.0

001

98.

20

C84

9

bo_

6-6-

1 bo

urno

nite

18.

8372

0.6

074

12

.407

5 0

.011

7

0.40

21

0.0

321

0

0

23

.568

0.05

12

0.00

01

41

.205

6

0.0

001

97.

12

Appendix 4: Microprobe Analysis—Sulphides

47

C29

9

A

_tet

1

tet

2

6.53

28

3.68

4

3

6.17

71

3.6

093

4

.717

6

0.

0493

2.68

73

0.

0605

22.0

653

0.

0361

0.00

01

0.

0001

0.01

08

99.

63

C29

9

A

_tet

2

tet

2

6.41

84

3.74

77

35

.758

8

3.61

68

4.

814

0.0

68

2

.642

0

21.8

975

0.

0092

0.00

01

0.

0001

0.00

81

98.

98

C29

9

A

_tet

3

tet

2

6.56

79

3.72

71

35

.597

5

3.63

74

4.

7969

0.05

22

2.

5605

0.00

77

21

.994

1

0.02

47

0.

0001

0.00

01

0.

0193

9

8.99

C

299

C_t

et13

te

t

26.

4011

3.

5623

36.0

566

3.

9086

4.71

97

0.

0547

2.81

02

0.

0096

22.2

357

0.

0181

0.00

01

0.

0001

0.01

77

99.

79

C29

9

C

_tet

14

tet

2

6.62

82

3.57

66

35

.577

5

3.96

22

4.

6907

0.05

66

2.

9331

0.02

31

21

.858

6

0.01

54

0.

0001

0.00

01

0.

0001

9

9.32

C

299

C_t

et15

te

t

26.

4449

3.

5843

35.4

82

4.

315

4.71

52

0.

0376

2.90

93

0.

043

22.

2114

0.

0276

0.00

01

0.

0001

0.00

01

99.

77

C31

7

D

_tet

22

tet

2

1.81

31

4.92

95

22

.377

2

1.85

29

0

0.0

175

1

9.45

95

0

26.8

948

0.

0342

0.00

01

0.

079

0.0

001

9

7.46

C

317

D_t

et23

te

t

22.

6164

5.

3675

22.6

37

2.

6772

0

0

.023

4

19.

1316

0

.004

5

27.

0666

0.

0424

0.00

01

0.

0791

0.00

74

99.

65

C31

7

D

_tet

24

tet

2

2.44

4.90

87

22

.216

9

1.40

79

0

0.0

184

1

9.99

96

0.0

193

2

7.72

46

0.05

93

0.

0001

0.00

79

0.

018

98.8

2 C

317

D_t

et25

te

t

23.

0155

4.

8036

22.3

322

1.

44

0

0

.017

19.

0529

0

27

.628

8

0.03

17

0.

0001

0.00

01

0.

0001

9

8.32

C

329

_B_t

et10

tet

2

6.05

52

5.68

25

33

.072

2

1.31

31

6.

7171

0.06

76

8.

5619

0.01

81

18

.679

1

0.01

73

0.

0001

0.00

01

0.

0001

1

00.1

8 C

329

_B_t

et11

tet

2

6.43

53

5.66

89

33

.377

5

1.27

62

6.

582

0.0

647

8

.505

6

0.0

199

1

8.77

51

0.04

72

0.

0001

0.00

01

0.

0001

1

00.7

5 C

329

_B_t

et12

tet

2

6.16

75

5.62

53

32

.987

1.25

92

6.

6

0.0

543

8

.830

4

0.0

283

1

8.87

88

0.04

7

0.

0001

0.00

42

0.

0001

1

00.4

8 C

337

C_t

et19

te

t

22.

6613

5.

5305

26.4

893

2.

3188

0

0

.028

7

14.

7701

0

.012

6

26.

624

0

.025

1

0.

0001

0.00

01

0.

0129

9

8.47

C

337

C_t

et20

te

t

22.

8677

5.

0387

25.4

038

3.

3587

0

0

.020

5

15.

1215

0

.034

5

27.

0367

0.

0491

0.00

01

0.

0001

0.00

01

98.

93

C33

7

C

_tet

21

tet

2

2.98

35

4.91

58

27

.292

3.33

78

0

0.0

179

1

3.90

78

0.0

196

2

6.71

37

0.02

6

0.

0001

0.00

01

0.

0001

9

9.21

C

341

B_t

et7

te

t

27.

5341

5.

0392

38.1

143

2.

3117

10.6

524

0.

0827

3.12

7

0

.018

9

13.

122

0

.016

0.

0001

0.00

43

0.

0001

1

00.0

2 C

341

B_t

et8

te

t

27.

2288

4.

8775

37.5

973

2.

6946

9.29

34

0.

0759

3.31

11

0.

0188

15.3

39

0.

0273

0.00

01

0.

0001

0.00

84

100

.47

C34

1

B

_tet

9

tet

2

7.31

88

5.04

88

38

.028

3

2.35

54

10

.39

0.0

784

3

.192

0.0

66

1

3.90

14

0.00

86

0.

0001

0.00

01

0.

0019

1

00.3

9 C

341

C_t

et16

te

t

27.

3145

4.

8456

37.5

007

2.

4665

9.52

28

0.

0814

3.61

32

0.

0503

14.8

059

0.

0181

0.00

01

0.

0001

0.00

01

100

.22

C34

1

C

_tet

17

tet

2

7.22

68

4.91

41

37

.319

2

2.57

43

9.

6425

0.08

15

3.

6988

0.01

07

14

.797

5

0.02

65

0.

0001

0.00

01

0.

0001

1

00.2

9 C

341

C_t

et18

te

t

27.

2963

4.

9436

37.4

829

2.

4544

9.58

25

0.

0617

3.70

12

0.

0017

14.8

575

0.

0257

0.00

01

0.

0001

0.01

78

100

.43

C34

5

C

_tet

13

tet

2

7.61

26

5.07

63

37

.109

2.26

82

11

.118

0.08

82

4.

6222

0.01

51

12

.379

0.04

89

0.

0001

0.00

01

0.

0001

1

00.3

4 C

345

C_t

et14

te

t

27.

5187

5.

0326

37.0

7

2

.324

4

11.

0833

0

.088

7

4.6

181

0

.023

8

12.

4344

0.

0391

0.00

01

0.

0001

0.00

01

100

.23

C34

5

C

_tet

15

tet

2

7.33

87

5.06

65

37

.101

3

2.26

65

11

.102

6

0.08

9

4

.800

3

0.0

281

1

2.25

69

0.03

92

0.

0001

0.00

01

0.

0001

1

00.0

9 C

353

B_t

et7

te

t

24.

2975

4.

6308

30.2

172

2.

3032

2.65

14

0.

0203

10.6

921

0

24.

2362

0.

0295

0.00

01

0.

0001

0.01

4

99

.09

C35

3

B

_tet

8

tet

2

3.66

89

4.56

43

28

.277

9

2.41

46

1.

1905

0.03

76

12

.742

1

0

2

5.93

05

0.01

7

0.

0001

0.00

01

0.

0001

9

8.84

C

353

B_t

et9

te

t

23.

8958

4.

6796

27.6

419

2.

4657

1.13

87

0.

0309

13.1

889

0.

0151

26.1

047

0.

0503

0.00

01

0.

0001

0.00

01

99.

21

C36

2

B

_tet

13

tet

2

3.25

65

4.40

6

2

6.13

76

2.6

43

0

0.

0198

15.4

469

0.

0103

26.9

756

0.

0444

0.00

01

0.

0001

0.01

15

98.

95

C36

2

B

_tet

14

tet

2

3.16

87

4.42

34

25

.692

8

3.03

88

0

0.0

262

1

5.70

49

0

27.1

126

0.

0174

0.00

01

0.

0001

0.00

01

99.

19

C36

2

B

_tet

15

tet

2

3.28

53

4.45

2

2

5.67

7

4.5

495

0

0.

027

15.

6583

0

.019

26.

6396

0.

0243

0.00

01

0.

0001

0.00

27

100

.33

C36

2

D

_tet

25

tet

2

3.22

93

4.64

12

25

.392

7

2.18

83

0

0.0

28

1

6.05

57

0.0

369

2

6.95

21

0.04

31

0.

0001

0.00

01

0.

0244

9

8.59

C

362

D_t

et26

te

t

22.

8746

4.

7306

26.0

451

2.

0661

0

0

.018

2

15.

8699

0

.011

27.

3461

0.

0541

0.00

01

0.

0001

0.00

26

99.

02

C36

2

D

_tet

27

tet

2

3.42

05

4.61

06

26

.687

3

2.07

06

1.

1457

0.02

49

15

.035

6

0

2

5.40

44

0.04

39

0.

0001

0.00

01

0.

0448

9

8.49

C

364

A_t

et13

te

t

23.

0439

4.

349

24.

2582

2

.194

2

0

0.01

34

18

.288

6

0.03

56

26

.791

1

0.04

2

0.

0001

0.00

01

0.

1854

9

9.20

C

364

A_t

et14

te

t

22.

8182

4.

347

24.

4129

2

.266

7

0.1

432

0.02

17

18

.272

2

0.00

78

26

.49

0.03

05

0.

0001

0.00

01

0.

1504

9

8.96

C

364

A_t

et15

te

t

22.

9079

4.

3716

24.3

638

2.

241

0.05

83

0.

0153

18.1

738

0.

016

26.

6474

0.

0242

0.00

01

0.

0001

0.17

95

99.

00

C36

4

B

_tet

25

tet

2

3.04

7

4.87

64

24

.540

6

2.34

85

0.

1831

0.01

92

17

.549

6

0.03

55

26

.208

4

0.04

53

0.

0001

0.00

01

0.

5527

9

9.41

sam

ple

poin

t

typ

e W

%(S

)

W%

(Fe)

W

%(C

u)

W%

(Zn)

W

%(A

s)

W%

(Se)

W

%(A

g)

W%

(Cd)

W

%(S

b)

W%

(Te)

W

%(H

g)

W%

(Pb)

W

%(B

i)

W%

(sum

)

Appendix 4: Microprobe Analysis—Sulphides

48

C36

4

B

_tet

26

tet

2

2.96

45

4.64

67

24

.038

8

1.95

27

0.

616

0.0

16

1

7.88

46

0.0

426

2

5.22

18

0.01

73

0.

0001

0.00

01

0.

3814

9

7.78

C

364

B_t

et27

te

t

22.

9433

4.

9255

24.2

42

1.

7239

0

0

.019

1

18.

0379

0

.017

2

26.

7426

0.

0184

0.00

01

0.

0001

0.23

22

98.

90

C36

5

D

_tet

22

tet

2

2.81

47

5.20

94

22

.481

1

1.24

51

0

0.0

242

1

9.68

88

0.0

109

2

7.85

63

0.04

11

0.

0001

0.00

01

0.

0001

9

9.37

C

365

D_t

et23

te

t

22.

8006

5.

2389

22.3

614

1.

1744

0

0

.021

8

19.

4505

0

27

.605

8

0.04

39

0.

0001

0.00

01

0.

0001

9

8.70

C

365

D_t

et24

te

t

22.

3709

5.

3488

20.9

337

1.

0768

0

0

.029

2

21.

7647

0

27

.177

2

0.05

33

0.

0001

0.00

01

0.

0038

9

8.76

C

383

C_t

et19

te

t

27.

3359

5.

7265

38.0

966

2.

984

15.9

209

0.

0922

3.83

81

0.

0313

5.44

69

0.

0319

0.00

01

0.

0001

0.00

01

99.

50

C38

3

C

_tet

20

tet

2

4.38

64

4.56

85

29

.513

2

3.49

81

5.

0215

0.05

15

11

.336

4

0.02

42

20

.371

9

0.03

7

0.

0001

0.01

87

0.

0001

9

8.83

C

383

C_t

et21

te

t

23.

4959

4.

2103

26.4

11

4.

2199

2.01

31

0.

0362

14.1

159

0.

0312

23.8

216

0.

046

0.00

01

0.

0001

0.00

01

98.

40

C38

5

A

_tet

1

tet

2

6.30

84

4.93

11

33

.872

7

2.08

01

6.

2102

0.06

63

5.

762

0.0

294

1

9.18

45

0.04

74

0.

0001

0.00

01

0.

0001

9

8.49

C

385

A_t

et2

te

t

26.

1976

4.

9967

33.7

842

2.

0237

6.12

87

0.

0519

5.99

61

0

19.

3919

0.

02

0.00

01

0.

0001

0.00

24

98.

59

C38

5

A

_tet

3

tet

2

6.39

82

5.04

34

33

.964

7

2.15

92

6.

384

0.0

518

5

.801

8

0

19.3

913

0.

0253

0.00

01

0.

0001

0.00

01

99.

22

C38

5

B

_tet

7

tet

2

6.57

34

4.85

47

34

.198

7

2.44

45

6.

2028

0.05

86

5.

9508

0.04

67

19

.683

0.04

45

0.

0001

0.00

01

0.

0001

1

00.0

6 C

385

B_t

et8

te

t

26.

3906

4.

7179

33.5

046

2.

2628

6.31

04

0.

0616

5.89

56

0.

0393

19.3

555

0.

055

0.00

01

0.

0001

0.00

01

98.

59

C38

5

B

_tet

9

tet

2

6.45

23

4.84

88

33

.972

2.41

62

6.

24

0.0

783

5

.896

4

0.0

67

1

9.53

53

0.03

6

0.

0001

0.00

01

0.

0001

9

9.54

C

844

tet_

4

te

t

25.

7895

4.

6235

37.4

198

2.

9463

6.68

33

0.

0677

3.12

7

0

.015

5

18.

2763

0.

0219

0.00

01

0.

0001

0.00

01

98.

97

C84

4

te

t_5

tet

2

5.67

15

4.55

01

37

.605

8

3.12

75

6.

7766

0.06

35

3.

0677

0.01

39

18

.332

5

0.00

27

0.

0001

0.00

01

0.

0001

9

9.21

C

844

tet_

6

te

t

25.

7355

4.

6745

37.4

614

2.

9316

6.64

49

0.

0593

3.15

1

0

.016

7

18.

4516

0.

0381

0.00

01

0.

0001

0.00

01

99.

16

C81

3

te

t_7

tet

2

2.77

89

5.46

8

2

2.06

23

7.0

105

0

0.

0277

19.0

983

0.

0238

24.8

741

0.

05

0.00

01

0.

0079

0.00

01

101

.40

C81

3

te

t_8

tet

2

3.32

8

7.05

07

22

.667

1

2.21

64

0

0.0

326

1

9.76

8

0

25.7

865

0.

0614

0.00

01

0.

0001

0.00

53

100

.92

C81

2

te

t_7

tet

2

3.53

29

7.65

19

22

.328

1

1.53

59

0

0.0

205

1

9.95

87

0

25.5

415

0.

0359

0.00

01

0.

0001

0.00

01

100

.61

C81

2

te

t_8

tet

2

2.73

27

5.27

59

22

.967

5

2.86

08

0

0.0

25

2

0.95

98

0

26.1

261

0.

0674

0.00

01

0.

0001

0.00

01

101

.02

C81

2

te

t_9

tet

2

2.27

48

6.45

58

21

.308

1

3.08

39

0

0.0

272

2

0.23

65

0

25.0

099

0.

0547

0.00

01

0.

0001

0.00

01

98.

45

C83

6

te

t7

tet

2

5.23

06

5.53

71

35

.301

9

1.87

55

5.

488

0.0

614

5

.725

2

0.0

213

2

0.05

63

0.02

62

0.

0001

0.00

01

0.

0001

9

9.32

C

836

tet8

te

t

23.

7982

4.

6743

30.0

068

2.

6727

0

0

.025

4

10.

7675

0

.047

1

27.

5384

0.

0497

0.00

01

0.

0001

0.00

01

99.

58

C83

6

te

t9

tet

2

5.32

29

5.36

84

34

.346

9

3.20

09

4.

9362

0.06

48

6.

1286

0.00

31

20

.449

6

0.03

54

0.

0001

0.00

01

0.

0001

9

9.86

C

836

tet1

0

te

t

25.

1804

5.

1862

33.9

521

2.

2794

5.18

31

0.

0511

6.17

97

0.

0072

20.6

524

0.

0467

0.00

01

0.

0001

0.02

31

98.

74

C83

6

te

t11

tet

2

5.72

8

5.45

34

35

.234

6

2.28

33

6.

5509

0.05

49

5.

2464

0.02

36

18

.595

7

0.00

91

0.

0001

0.00

01

0.

0025

9

9.18

C

836

tet1

2

te

t

24.

492

6.

6626

29.9

366

2.

4471

5.86

81

0.

0511

6.31

85

0.

0457

19.7

146

0.

037

0.00

01

4.

8489

0.00

01

100

.42

C80

1

te

t7

tet

2

7.56

9

5.32

72

39

.800

7

2.61

08

15

.955

5

0.11

64

2.

748

0.0

17

5

.277

7

0.0

302

0.00

01

0.

0228

0.00

01

99.

48

C80

1

te

t8

tet

2

5.55

7

4.32

68

35

.222

9

4.60

46

7.

5466

0.07

77

5.

7276

0.05

42

16

.484

8

0.04

0.

0001

0.02

27

0.

0138

9

9.68

C

801

tet9

te

t

27.

3347

5.

3171

39.6

489

2.

6288

16.0

448

0.

1151

2.66

38

0.

027

5.2

316

0

.025

6

0.

0001

0.00

01

0.

0001

9

9.04

C

832

tet7

te

t

24.

7692

3.

1666

32.0

273

4.

3855

3.98

75

0.

0531

9.42

06

0.

0775

21.6

016

0.

0164

0.00

01

0.

0096

0.02

94

99.

54

C83

2

te

t8

tet

2

4.80

97

3.12

88

32

.651

2

4.68

31

4.

0281

0.05

58

8.

9817

0.05

67

21

.522

0.05

4

0.

0001

0.03

69

0.

0001

1

00.0

1 C

832

tet9

te

t

24.

6138

3.

1518

31.9

653

4.

237

4.00

72

0.

042

9.3

506

0

.053

9

21.

8251

0.

0251

0.00

01

0.

0201

0.00

01

99.

29

C07

9

te

t_2

tet

2

4.63

89

5.35

23

33

.470

2

2.56

02

3.

5725

0.04

65

8.

2519

0.03

23

22

.501

3

0.03

44

0.

0001

0.00

01

0.

0001

1

00.4

6 C

842

tet7

te

t

27.

7801

3.

859

41.

7134

4

.289

17.

0899

0

.124

1.6

047

0

.044

8

4.0

944

0

.025

7

0.

0001

0.00

01

0.

0001

1

00.6

3 C

842

tet_

8

te

t

27.

7937

3.

824

41.

8737

4

.272

7

17.

118

0.11

85

1.

579

0.0

295

4

.247

5

0.0

496

0.00

01

0.

0001

0.00

01

100

.91

C84

2

te

t_9

tet

2

7.68

14

4.02

72

41

.645

3

4.03

07

17

.101

0.12

11

1.

673

0

4.21

75

0.

0187

0.00

01

0.

0001

0.00

01

100

.52

sam

ple

poin

t

typ

e W

%(S

)

W%

(Fe)

W

%(C

u)

W%

(Zn)

W

%(A

s)

W%

(Se)

W

%(A

g)

W%

(Cd)

W

%(S

b)

W%

(Te)

W

%(H

g)

W%

(Pb)

W

%(B

i)

W%

(sum

)

Appendix 4: Microprobe Analysis—Sulphides

49

C29

0

te

t_1-

1-1

tet

2

1.65

71

4.00

29

25

.285

2

2.67

09

0.

8746

0.00

76

11

.935

8

0.03

58

22

.505

1

0.05

82

0.

0001

10.3

096

0.

0001

9

9.34

C

290

tet_

3-3-

1 ?

27.

6906

4.

9198

40.8

834

3.

0811

17.2

919

0.

1037

1.92

46

0.

0189

3.68

29

0.

0297

0.00

01

0.

0001

0.00

01

99.

63

C29

0

te

t_4-

4-1

?

2

5.99

38

3.80

97

37

.845

5

3.94

73

10

.393

8

0.07

8

3

.782

7

0.0

218

1

2.86

42

0.02

67

0.

0001

0.00

01

0.

0001

9

8.76

sa

mpl

e po

int

t

ype

W%

(S )

W

%(F

e)

W%

(Cu)

W

%(Z

n)

W%

(As)

W

%(S

e)

W%

(Ag)

W

%(C

d)

W%

(Sb)

W

%(T

e)

W%

(Hg)

W

%(P

b)

W%

(Bi)

W

%(s

um)

Appendix 4: Microprobe Analysis—Sulphides

50

C01

-828

py1

a

djac

ent t

o ab

latio

n pi

t 1

em

baye

d su

bhed

ral p

yrite

- "c

lean

"

52.

4826

45.

5437

0.0

2

0.

0001

0

.516

7

0.02

25

0.04

2

0.0

341

C01

-828

py1

a

djac

ent t

o ab

latio

n pi

t 2

em

baye

d su

bhed

ral p

yrite

- "c

lean

"

53.

1482

45.

7576

0.0

337

0.

0064

0

.176

7

0.02

04

0.01

07

0 C

01-8

28 p

y1

dis

tal t

o ab

latio

n pi

t

3

em

baye

d su

bhed

ral p

yrite

- "c

lean

"

53.

3335

46.

029

0.0

081

0.

0237

0

.115

8

0.01

93

0.00

97

0.00

05

C01

-828

py2

a

djac

ent t

o ab

latio

n pi

t 4

anh

edra

l fg

crys

talli

ne m

ass

- rel

ict s

pong

iform

53.

0915

44.

9848

0.0

466

0.

0035

0

.407

8

0.02

32

0.02

04

0 C

01-8

28 p

y2

adj

acen

t to

abla

tion

pit 5

a

nhed

ral f

g cr

ysta

lline

mas

s - r

elic

t spo

ngifo

rm 5

2.86

69 4

5.03

15 0

.051

2

0.01

89

0.3

441

0.

0224

0.

017

0

C

01-8

28 p

y2

dis

tal t

o ab

latio

n pi

t

6

anh

edra

l fg

crys

talli

ne m

ass

- rel

ict s

pong

iform

53.

0902

44.

783

0.1

354

0.

0001

0

.369

3

0.01

87

0.00

91

0.00

34

C01

-828

py3

a

djac

ent t

o ab

latio

n pi

t 7

anh

edra

l fg

crys

talli

ne m

ass

- rel

ict s

pong

iform

52.

963

44.

8151

0.0

032

0.

0001

0

.343

2

0.02

66

0.00

78

0 C

01-8

28 p

y3

adj

acen

t to

abla

tion

pit 8

a

nhed

ral f

g cr

ysta

lline

mas

s - r

elic

t spo

ngifo

rm 5

3.21

69 4

4.78

6 0

.101

1

0.00

01

0.3

866

0.

019

0

.024

3

0 C

01-8

28 p

y3

adj

acen

t to

abla

tion

pit 9

a

nhed

ral f

g cr

ysta

lline

mas

s - r

elic

t spo

ngifo

rm 5

3.12

68 4

4.44

61 0

.063

4

0.00

96

0.4

377

0.

0163

0.

0298

0.

0247

C

01-8

28 p

y4

adj

acen

t to

abla

tion

pit 1

0 a

nhed

ral f

g cr

ysta

lline

mas

s - r

elic

t spo

ngifo

rm 5

3.02

31 4

4.62

54 0

.212

4

0.00

87

0.2

972

0.

019

0

.015

7

0.00

95

C01

-828

py4

a

djac

ent t

o ab

latio

n pi

t 11

anh

edra

l fg

crys

talli

ne m

ass

- rel

ict s

pong

iform

53.

1736

45.

2945

0.0

189

0.

0351

0

.269

6

0.01

71

0

0.

0297

C

01-8

28 p

y4

adj

acen

t to

abla

tion

pit 1

2 a

nhed

ral f

g cr

ysta

lline

mas

s - r

elic

t spo

ngifo

rm 5

3.00

04 4

4.56

48 0

.096

1

0.03

78

0.5

73

0.

0239

0.

0335

0.

0183

C

01-8

28 p

y5

not

lase

r sam

pled

13

anh

edra

l fg

crys

talli

ne m

ass

- rel

ict s

pong

iform

53.

0294

45.

939

0.0

104

0.

0433

0

.102

5

0.00

95

0.02

43

0.02

2 C

01-8

28 p

y6

not

lase

r sam

pled

14

anh

edra

l fg

crys

talli

ne m

ass

- rel

ict s

pong

iform

53.

2224

45.

637

0.0

111

0.

0741

0

.108

8

0.01

1

0.0

086

0.

0181

C

01-8

28 p

y7

not

lase

r sam

pled

15

em

baye

d su

bhed

ral p

yrite

- "c

lean

"

53.

0991

45.

693

0.0

146

0.

0729

0

.101

7

0.01

0.0

154

0.

0189

Sam

ple

grai

n co

mm

ent

No

pyrit

e m

orph

olog

y

W

%(S

) W

%(F

e) W

%(C

u) W

%(Z

n) W

%(A

s) W

%(S

e) W

%(A

g) W

%(C

d)

C01

-828

py1

a

djac

ent t

o ab

latio

n pi

t 1

0.0

341

0.

0117

0.

0001

0

0.00

01

0.0

002

0.0

001

0.

0297

98

.7

C01

-828

py1

a

djac

ent t

o ab

latio

n pi

t 2

0

0

.000

1

0.00

01

0

0.

0134

0

.004

2 0

.000

1

0.00

01

99.1

7 C

01-8

28 p

y1

dis

tal t

o ab

latio

n pi

t

3

0.0

005

0.

0001

0.

0001

0

0.01

06

0.0

172

0.0

001

0.

0001

99

.57

C01

-828

py2

a

djac

ent t

o ab

latio

n pi

t 4

0

0

.000

1

0.00

01

0

0.

0032

0

.089

1 0

.000

1

0.00

01

98.6

7 C

01-8

28 p

y2

adj

acen

t to

abla

tion

pit 5

0

0.0

256

0.

0001

0

0.02

89

0.1

555

0.0

001

0.

0001

98

.56

C01

-828

py2

d

ista

l to

abla

tion

pit

6

0

.003

4

0.03

81

0.00

01

0.01

59

0.0

305

0.

1626

0.0

001

0.

0001

98

.66

C01

-828

py3

a

djac

ent t

o ab

latio

n pi

t 7

0

0

.033

2

0.00

01

0

0.

0001

0

.170

3 0

.000

1

0.00

01

98.3

6 C

01-8

28 p

y3

adj

acen

t to

abla

tion

pit 8

0

0.0

636

0.

0001

0.

0168

0

.045

9

0.18

84 0

.000

1

0.00

01

98.8

5 C

01-8

28 p

y3

adj

acen

t to

abla

tion

pit 9

0

.024

7

0.07

98

0.00

01

0

0.

0065

0

.242

1 0

.000

1

0.01

1

98.

49

C01

-828

py4

a

djac

ent t

o ab

latio

n pi

t 10

0.0

095

0.

0673

0.

0001

0.

0876

0

.035

7

0.20

27 0

.000

1

0.00

01

98.6

C

01-8

28 p

y4

adj

acen

t to

abla

tion

pit 1

1 0

.029

7

0.00

48

0.00

01

0

0.

0199

0

.031

9 0

.000

1

0.00

01

98.9

C

01-8

28 p

y4

adj

acen

t to

abla

tion

pit 1

2 0

.018

3

0.05

59

0.00

01

0

0.

0001

0

.260

7 0

.000

1

0.00

97

98.6

7 C

01-8

28 p

y5

not

lase

r sam

pled

13

0.0

22

0.

0001

0.

0001

0.

1156

0

.002

0.01

7

0.00

01

0.00

01

99.3

2 C

01-8

28 p

y6

not

lase

r sam

pled

14

0.0

181

0.

0001

0.

0001

0

0.00

01

0.0

006

0.0

001

0.

0001

99

.09

C01

-828

py7

n

ot la

ser s

ampl

ed

15 0

.018

9

0.00

01

0.00

01

0

0.

0175

0

.000

2 0

.000

1

0.00

01

99.0

4 Sa

mpl

e g

rain

com

men

t

N

o W

%(C

d) W

%(S

b) W

%(T

e) W

%(A

u) W

%(H

g) W

%(T

l) W

%(P

b) W

%(B

i) w

t% to

tal

51

Appendix 5: LA-ICP-MS Analysis—Sulphides

Appendix 5 LA-ICP-MS Analysis

-Sulphides

52

Appendix 5: LA-ICP-MS Analysis—Sulphides

C07

9

ap19

a03

py

435

.729

2.9

17

7.8

20

4655

00

27.

238

9

.260

23.4

69

150

40.7

59

377

.461

C

079

ap

19a0

4

p

y

2

.145

<0.0

38

2.54

8

4

6550

0

24.2

66

13

.652

26

3.26

6

2

427.

855

241.

016

C07

9

ap19

a05

py

2.0

45

0.

211

12

3.12

1

4655

00

6.3

53

3

.078

33.0

72

14.

602

24

16.1

15

C07

9

ap19

a08

py

27.

580

0.

234

6.

052

465

500

79

.329

16.8

61

26.5

26

368

6.84

7

66

2.04

1 C

079

jl0

4a55

py

<0.8

41

<0.

087

<0.

674

4655

00

59.

387

7

.211

<4.1

07

<2.

117

16

.774

C

079

jl0

4a58

py

1546

.678

6.57

6

2.49

9

4

6550

0

32.4

45

10

.056

<3

.946

4

801.

433

94.6

21

C07

9

jl04a

59

py

2.

056

<

0.12

3

1

.591

46

5500

1

9.40

9

14.

544

59

7.57

7

2

437.

480

201.

733

C07

9

ap19

a06

sp

98.

530

0.

476

43

5.45

7

1850

0

<0

.019

<0.1

45

582.

477

n.a

.

1

.164

C

079

ap

19a0

7

s

p

1

.034

<0.0

52

420.

893

18

500

<0.0

30

<0

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98

.583

n

.a.

<1.

039

C

079

jl0

4a60

sp

<2.2

39

<0.

275

389

.468

1

5700

<0.6

41

<1

.800

73

.814

n

.a.

<7.

168

C

079

jl0

4a61

sp

1.60

6

<0.

098

360

.182

1

5700

<0.2

40

<0

.713

72

9.80

6

n

.a.

2.7

09

C08

2

ap18

a28

cpy

2.68

6

<0.

073

2.2

85

3043

00

0.2

74

<

0.44

0

n.a.

7

99.3

48

7.11

9 C

082

ap

18a2

9

p

y

2

.800

<0.0

60

<1.2

58

46

5500

0

.994

0.2

02

45

.025

4

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297.

522

C08

2

ap18

a30

py

3.5

53

<0

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<1

.320

4655

00

6.2

33

0

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351.

228

30.

958

43

.895

C

082

jl1

1a41

py

1091

.486

<0.1

71

664.

493

46

5500

1

8.05

6

6.5

49

14

.011

1

0.57

1

55.6

95

C08

2

jl11a

42

py

38

.358

<

0.17

7

3

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46

5500

4

.324

1.7

96

16

.665

<

2.01

0

98.4

20

C08

2

jl11a

43

py

<0

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<

0.06

2

0

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46

5500

3

1.09

5

<0.

557

5.

383

1.90

3

70

.123

C

082

jl1

1a44

py

<0.8

17

<0.

081

<0.

575

4655

00

25.

642

0

.716

<3.0

25

<1.

193

66

.759

C

211

ap

03c0

3

s

p

<

0.86

5

<0.1

85

5552

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10

7100

2

4.19

7

<0.

568

87

6.12

0

n

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<0.

883

C

211

ap

03c0

4

s

p

<

1.28

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02

5635

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10

7100

3

1.84

8

<0.

548

13

44.0

87

n

.a.

<0.

987

C

211

ap

03c0

5

s

p

<

2.27

1

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26

6685

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10

7100

2

9.73

8

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11

72.0

87

n

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<1.

176

C

211

ap

03c0

6

s

p

<

2.28

2

<0.3

30

6479

.861

10

7100

3

0.90

7

<0.

584

20

29.0

20

n

.a.

<1.

471

C

261

ap

10d0

5

a

py

14

6.30

4

1

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1

64.3

10

343

000

1.

826

80.

006

15

.483

<

14.3

48

n.a.

C

261

ap

10d0

4

p

y

<

1.91

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671.

946

46

5500

4

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99.

964

11

6.78

4

9

85.9

22

3828

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C

261

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10d0

6

p

y

2

8.71

6

1.94

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70.1

32

46

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1

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31

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5

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748.

481

C26

1

ap10

d07

py

24.

784

1.

288

60

.295

4655

00

2.0

09

4

5.82

8

320.

270

56.

080

80

2.00

6 C

261

ap

10d0

8

p

y

2

.685

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74.2

23

46

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1

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58.

358

29

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3.52

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690.

675

C26

1

jl11a

18

py

1.

314

0

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6

4.69

5

46

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0

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074

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813.

196

C26

1

jl11a

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py

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6

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C26

1

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748.

002

C27

8

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00

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386

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50

C27

8

ap03

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py

<1.

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4655

00

140

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1

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7

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8

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15

C27

8

ap03

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py

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141

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97

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4655

00

62.

079

1

1.11

4

7.78

5

67

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6

46.8

96

C27

8

ap03

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py

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335

<0

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76

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4655

00

35.

633

6

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39.2

91

<5.

803

72

9.59

3 C

278

ap

03e1

2

s

p

<

5.47

1

<0.8

06

2927

.640

64

800

<0.5

90

<2

.396

20

3.61

2

n

.a.

<2.

833

C

278

ap

03e1

4

s

p

<

7.40

3

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11

1858

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64

800

<0.7

20

<2

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10

633.

232

n

.a.

<5.

129

C

278

ap

03e1

8

s

p

<

7.56

5

<0.9

41

1766

.946

64

800

<0.8

10

<2

.652

12

125.

403

n

.a.

<3.

790

C

280

ap

03e0

3

p

y

<

3.74

6

<0.7

51

<7.7

53

46

5500

<

0.35

0

<1.

533

<2

.497

<

5.76

1

4.73

5

sam

ple

ru

n/po

int

t

ype

Ti

(ppm

)

V (p

pm)

Mn

(ppm

)

Fe

(ppm

)

Co

(ppm

)

Ni (

ppm

)

C

u (p

pm)

Z

n (p

pm)

A

s (p

pm)

53

Appendix 5: LA-ICP-MS Analysis—Sulphides

C28

0

ap03

e05

py

<4.

707

<0

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<6

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4655

00

<0.

519

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<9.

888

4.

185

C28

0

ap03

e06

py

29.

283

<0

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3

4655

00

4.7

78

<

1.92

0

844.

163

14.

376

26

49.6

33

C28

0

ap03

e07

py

10.

339

<0

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<6

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4655

00

0.8

21

<

1.56

4

8.07

7

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5

25.7

80

C28

0

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556

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00

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344

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8

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674

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10

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0

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280

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284

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5

c

py

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a.

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7.

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C28

4

ap06

b03

py

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9 C

284

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034

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4

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py

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564

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00

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141

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797

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284

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9

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139

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4

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py

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38

1.

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00

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2

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9

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72

10.

945

48

7.65

2 C

284

ap

06b0

4

s

p

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1358

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977

C

284

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06b0

7

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p

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50

400

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55

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284

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285

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7

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5

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46

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1

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3

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C

285

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03c1

0

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741

C28

5

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c13

py

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00

69.

343

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124.

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9.4

48

16

5.94

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285

ap

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4

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433

C28

5

ap03

c17

py

<4.

872

<0

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00

710

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1

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285

ap

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8

p

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1

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6

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285

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5

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C

285

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C28

5

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0

2.

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60

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6

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285

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6

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4

C28

7

ap17

b03

py

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268

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00

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111

<

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9

3555

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5.4

28

11

3.93

9 C

287

ap

17b0

5

p

y

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8

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27

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C

287

ap

17b0

7

p

y

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9

49.0

21

<6.

152

14

3.44

0 C

287

ap

17b0

9

p

y

6

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11.7

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46

5500

0

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62

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0

1691

6.32

3 C

287

ap

17b0

4

s

p

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n

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287

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8

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290

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8

cpy

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00

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13

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0

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f03

py

<4

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6

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0

46

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0

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46.

115

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6

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171

C29

0

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f07

py

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0.46

0

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4

46

5500

<

0.34

3

4.7

88

<2

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<

4.72

2

74.6

68

C29

0

ap10

f09

py

<2

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<

0.28

3

7

1.86

2

46

5500

<

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1

1.7

12

10

19.7

01

1

2.85

2

1709

.241

sam

ple

ru

n/po

int

t

ype

Ti

(ppm

)

V (p

pm)

Mn

(ppm

)

Fe

(ppm

)

Co

(ppm

)

Ni (

ppm

)

C

u (p

pm)

Z

n (p

pm)

A

s (p

pm)

54

Appendix 5: LA-ICP-MS Analysis—Sulphides

C29

0

ap10

f11

py

58

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<

0.42

2

<

7.00

5

46

5500

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5

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152

21

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3

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7

51.5

22

C29

0

ap10

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0.47

4

9

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46

5500

0

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3.5

31

41

0.17

0

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6.58

3

1170

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C

290

ap

10f1

3

py

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065

4655

00

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338

6

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<6.

404

11

9.79

9 C

290

ap

10f0

4

sp

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821

189

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1

2

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n

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290

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5

sp

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2

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16

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2

n

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C

290

ap

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0

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2

ap06

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cpy

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6.16

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292

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2

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2

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00

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2

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3

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7

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7

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7

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7

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45

C29

7

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1

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297

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7

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C29

7

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297

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7

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297

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7

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9

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9

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9

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1

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746

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1

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4

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67

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1

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4655

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1

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38

58.6

70

sam

ple

ru

n/po

int

t

ype

Ti

(ppm

)

V (p

pm)

Mn

(ppm

)

Fe

(ppm

)

Co

(ppm

)

Ni (

ppm

)

C

u (p

pm)

Z

n (p

pm)

A

s (p

pm)

55

Appendix 5: LA-ICP-MS Analysis—Sulphides

C30

1

ap03

d18

py

<1.

337

<0

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12

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4655

00

176

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1

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2

104.

044

335

0.77

5

33

56.3

15

C30

1

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482

<0

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22

03.8

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3430

0

2.

243

<0.

475

30

17.2

23

n

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<0.

944

C

301

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6

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p

<

7.91

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785.

133

34

300

2.37

5

<

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6

4946

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n.a

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6

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C

306

ap

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1

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<

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81

465

500

14

7.77

4

7.47

8

5.5

90

2

5521

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6

56.8

61

C30

6

ap06

e16

py

8.3

38

<0

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20

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4655

00

82.

733

1

7.58

3

4.93

7

76

38.3

69

14

9.94

0 C

306

ap

06e1

2

s

p

<

5.74

1

<0.4

93

1569

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25

200

1.15

3

<

1.40

4

6.70

9

n.

a.

<2.5

84

C30

6

ap06

e13

sp

<4.

283

<0

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15

76.7

97

2520

0

1.

183

<1.

021

5.

906

n.a.

<3

.083

C

306

ap

06e1

5

s

p

<

4.17

5

<0.4

37

1845

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25

200

0.98

2

<

1.32

0

6.19

3

n.

a.

<4.5

31

C30

6

ap06

e18

sp

<4.

858

<0

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95

2.64

9

2520

0

0.

819

<1.

328

7.

601

n.a.

<3

.149

C

307

ap

02a0

4

p

y

1

.898

0.21

7

7.04

0

4

6550

0

<0.1

06

<0

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35

2.63

7

1

943.

229

1640

.139

C

307

ap

02a0

5

p

y

4

47.3

75

0

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3

2.59

4

46

5500

1

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9

2.0

92

5.

774

2655

2.72

1

309.

523

C30

7

ap02

a06

py

<3.

151

<0

.519

3.

525

465

500

0.

373

<1.

325

<3

.700

<

4.43

1

3929

.102

C

307

ap

02a0

7

p

y

1

0.01

2

<0.1

57

7.44

2

4

6550

0

<0.0

87

<0

.350

<1

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2

.448

4023

.697

C

307

ap

02a0

8

p

y

<

0.99

9

<0.1

77

3.07

4

4

6550

0

<0.0

95

<0

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<0

.888

2

.402

3429

.646

C

307

ap

02a0

9

p

y

3

7.82

5

<0.2

48

39.5

51

46

5500

<

0.11

7

<0.

524

2.

046

2.53

1

75

52.2

24

C30

7

ap02

a14

py

<3.

341

<0

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<4

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4655

00

0.5

97

4

.966

<2.7

91

<8.

572

45

41.2

80

C30

7

ap02

a15

py

<2.

812

<0

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7.

308

465

500

1.

322

2.0

18

<3

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<

5.07

1

2682

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C

307

ap

02a1

8

p

y

<

3.13

9

<0.6

39

<4.9

06

46

5500

<

0.36

9

1.1

74

<3

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<

5.15

1

3202

.549

C

307

ap

02a1

0

s

p

<

4.66

6

<0.7

92

423.

535

46

800

<0.4

62

<1

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18

97.5

63

n

.a.

<3.

024

C

307

ap

02a1

1

s

p

1

910.

034

2

.013

5

42.8

57

468

00

<0

.127

<0.4

83

2996

.426

n.a

.

1

.193

C

307

ap

02a1

3

s

p

6

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<0.1

43

664.

293

46

800

0.36

7

<

0.34

2

7488

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n.a

.

<

0.45

9

C31

7

ap17

f03

cp

y

<2

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<

0.62

3

<

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6

30

4300

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0.26

1

<1.

061

n.

a.

385

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9.

369

C31

7

ap17

f11

cp

y

<1

0.01

8

<

0.85

6

<

13.7

57

304

300

<0

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<2.6

70

n.a.

2

50.3

19

7.63

9 C

317

ap

17f1

6

cpy

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06

<0.

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601

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3

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00

<0

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n.

a.

274

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6.

265

C31

7

ap17

f05

py

<0

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<

0.15

1

4

1.33

7

46

5500

1

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7

176

.508

0.9

19

<

1.58

2

105.

997

C31

7

ap17

f06

py

<1

.036

<

0.16

6

<

1.61

2

46

5500

2

.173

25.

946

1.

303

19.5

50

98.

072

C31

7

ap17

f09

py

18

8.30

0

0

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1

4.46

3

46

5500

1

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70.

719

3.

688

2327

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48.8

89

C31

7

ap17

f10

py

<0

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<

0.13

7

<

1.57

6

46

5500

0

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520

.963

0.7

76

<

2.13

5

475.

704

C31

7

ap17

f13

py

31

1.86

6

2

.095

2

39.7

42

465

500

68

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1108

.998

4.31

5

<6

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1

524.

555

C31

7

ap17

f14

py

<2

.494

<

0.44

8

3

80.2

46

465

500

13

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175.

004

<1.7

45

<5.

398

28

6.32

3 C

317

ap

17f1

5

py

<4.4

78

<0.

390

<6.

534

4655

00

<0.

399

2

30.4

55

<

2.04

5

42.

033

43

2.39

7 C

317

ap

17f0

4

sp

<4.4

12

<0.

724

113

0.85

7

2

8000

<0.4

15

<0

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57

32.4

63

n

.a.

<3.

839

C

317

ap

17f0

7

sp

<3.8

60

<0.

518

168

4.55

0

2

8000

<0.3

91

<0

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15

.899

n

.a.

<3.

319

C

320

ap

17a0

3

p

y

6

6.47

8

<0.1

69

67.9

01

46

5500

1

69.4

93

<0.

335

22

7.78

4

1

5.49

1

20.4

43

C32

0

ap17

a05

py

1.5

67

<0

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<2

.006

4655

00

22.

086

0

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1.51

7

<2

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4

14.4

40

C32

0

ap17

a06

py

3.9

47

<0

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<3

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4655

00

48.

892

0

.805

35.9

22

<4.

396

31

8.56

0 C

320

ap

17a0

7

p

y

<

1.89

7

<0.1

65

<2.0

20

46

5500

1

54.1

81

<0.

427

16

.106

1

56.8

29

3.66

9 C

320

ap

17a0

8

p

y

<

1.77

9

<0.1

55

<2.2

13

46

5500

1

0.25

4

<0.

414

4.

855

<2.2

77

155

.240

sam

ple

ru

n/po

int

t

ype

Ti

(ppm

)

V (p

pm)

Mn

(ppm

)

Fe

(ppm

)

Co

(ppm

)

Ni (

ppm

)

C

u (p

pm)

Z

n (p

pm)

A

s (p

pm)

56

Appendix 5: LA-ICP-MS Analysis—Sulphides

C32

0

ap17

a09

py

6.5

99

<0

.483

14

.210

4655

00

34.

804

8

.902

16.9

52

<8.

001

60

9.00

8 C

320

ap

17a1

0

p

y

2

9.39

0

<0.3

75

5.34

3

4

6550

0

19.2

06

<0

.938

1.

911

<6.9

39

216

.770

C

320

ap

17a1

1

p

y

7

8.07

9

<0.3

08

43.0

32

46

5500

1

65.8

16

0.7

25

19

.182

<

5.57

8

194.

428

C32

3

ap17

d03

cpy

<2.8

31

<0.

344

<3.

335

3043

00

<0.

144

<

0.79

0

n.a.

5

63.0

51

8.56

5 C

323

ap

17d0

5

p

y

1

89.1

04

<

0.13

3

1

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53

465

500

12

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0.90

5

104

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<1

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1

8.08

5 C

323

ap

17d0

6

p

y

1

5.21

3

<0.1

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14.5

89

46

5500

2

7.67

9

0.2

96

9.

255

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90

161

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C

323

ap

17d0

8

p

y

3

1.72

7

<0.1

04

41.7

12

46

5500

8

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1.0

05

14

5.57

0

<

1.62

2

28.4

46

C32

3

ap17

d09

py

38.

735

<0

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35

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4655

00

20.

097

0

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6.25

4

2.

619

122.

309

C32

3

ap17

d10

py

6.5

34

<0

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13

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4655

00

11.

677

1

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6.61

6

<2

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1

60.1

85

C32

3

ap17

d04

sp

<4.

014

<0

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12

53.8

61

6080

0

<0

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<1.2

65

419.

851

n.a

.

<

3.00

5

C32

3

ap17

d07

sp

<3.

655

<0

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13

89.0

11

6080

0

<0

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40

336.

667

n.a

.

<

2.30

4

C32

6

ap17

e03

py

2.4

81

<0

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10

0.74

3

4655

00

<0.

089

<

0.18

2

95.8

52

5.4

16

92

76.7

61

C32

6

ap17

e06

py

<0.

949

<0

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4655

00

0.3

96

<

0.39

0

806.

254

401

.712

31

4.71

4 C

326

ap

17e0

8

p

y

<

1.10

8

<0.1

30

19.8

87

46

5500

<

0.08

2

<0.

273

11

46.2

67

2

.211

608.

400

C32

6

ap17

e10

py

<3.

416

<0

.322

<4

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4655

00

1.6

81

<

0.68

4

226.

432

387

.941

71

46.3

97

C32

6

ap17

e11

py

<3.

111

<0

.245

28

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4655

00

8.4

62

<

0.90

3

4.31

9

61

57.7

55

40

4.24

9 C

326

ap

17e0

5

s

p

<

4.85

8

<0.6

44

2204

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53

600

<0.3

69

<1

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16

.782

n

.a.

<3.

202

C

326

ap

17e0

7

s

p

<

4.32

3

<0.3

88

1694

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53

600

<0.4

42

<0

.985

59

.050

n

.a.

<4.

812

C

329a

ap1

0e03

cp

y

<5

.107

<

0.55

1

<

4.92

9

30

4300

<

0.36

7

<0.

865

n.

a.

557

.856

99

.430

C

329a

ap1

0e05

cp

y

<5

.286

<

0.75

4

<

7.64

2

30

4300

<

0.53

1

<1.

276

n.

a.

325

.189

82

.522

C

329a

fb1

3a13

cp

y

<3

.608

<

0.55

3

<

8.97

7

30

4300

<

0.29

5

<1.

720

n.

a.

489

.547

<2

.321

C

329a

fb1

3a14

cp

y

<1

3.60

1

<

2.79

1

<

42.5

00

304

300

<1

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<5.9

67

n.a.

4

32.3

06

<9.0

13

C32

9a

a

p10e

06

py

<1.7

56

<0.

153

18.

665

4655

00

123

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4

9.52

7

2.73

2

50

07.4

05

54

3.48

2 C

329a

ap1

0e08

py

<1

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0.20

0

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1.99

9

46

5500

<

0.14

4

0.5

16

55

0.16

9

1

11.6

25

1060

.199

C

329a

ap1

0e09

py

<4

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<

0.51

3

4

6.28

7

46

5500

2

4.52

4

98.

231

33

.093

1

1473

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1

022.

865

C32

9a

a

p10e

12

py

<3.9

78

<0.

568

25.

170

4655

00

1.3

56

7

.793

1950

.489

946

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43

74.2

39

C32

9a

f

b13a

12

py

<4.4

71

<0.

692

<7.

249

4655

00

22.

708

1

39.1

29

<

1.82

7

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424

20

42.4

11

C32

9a

a

p10e

04

sp

<5.3

94

<0.

749

174

8.08

9

4

0600

<0.4

88

<1

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28

7.89

8

n

.a.

<5.

812

C

329a

ap1

0e07

sp

<5

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<

0.52

9

2

249.

195

406

00

<0

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<1.6

94

14.2

08

n.a

.

<

5.63

9

C32

9b

a

p06c

15

py

<3.3

48

<0.

298

<6.

135

4655

00

0.3

56

1

.155

144.

701

<5.

268

71

59.7

48

C32

9b

a

p06c

17

py

<3.6

32

<0.

352

<5.

823

4655

00

12.

895

6

1.26

4

<3.9

88

10.

356

68

9.83

9 C

329b

fb1

3a10

py

<3

.162

<

0.59

3

<

9.73

2

46

5500

3

.251

22.

648

36

.943

<

6.23

1

2077

.194

C

329b

fb1

3a11

py

<4

.451

<

0.48

5

2

5.02

6

46

5500

<

0.29

4

1.8

75

19

1.02

5

<

4.46

4

5920

.760

C

329b

ap0

6c13

sp

<5

.484

<

0.43

8

2

490.

770

393

00

<0

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12

100.

842

n.a

.

<

3.66

3

C32

9b

a

p06c

18

sp

<7.0

44

<0.

775

253

7.85

2

3

9300

<0.7

27

2.

331

1

31.6

21

n.a.

<5

.738

C

329b

ap0

6c14

te

t

<7

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<

0.67

6

6

6.42

3

56

600

<0.6

79

<2

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n.

a.

n.a

.

n

.a.

C33

3

ap10

b11

py

0.8

28

<0

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13

87.7

63

4655

00

51.

347

0

.764

2.52

9

2.

247

158.

951

C33

3

ap10

b12

py

<1.

188

<0

.141

<1

.900

4655

00

15.

653

1

.007

1.50

0

<2

.146

2

49.9

82

sam

ple

ru

n/po

int

t

ype

Ti

(ppm

)

V (p

pm)

Mn

(ppm

)

Fe

(ppm

)

Co

(ppm

)

Ni (

ppm

)

C

u (p

pm)

Z

n (p

pm)

A

s (p

pm)

57

Appendix 5: LA-ICP-MS Analysis—Sulphides

C33

3

ap10

b14

py

<1.

799

<0

.217

<2

.701

4655

00

104

.363

1

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<1.2

40

546

.606

47

2.03

1 C

333

ap

10b1

5

p

y

<

2.92

2

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37

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42

46

5500

2

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<0.

837

6.

104

<4.8

94

28.

626

C33

3

ap10

b17

py

<3.

070

<0

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93

.922

4655

00

34.

716

3

.206

196.

351

<9.

400

33

.180

C

333

ap

10b1

8

p

y

1

.653

<0.1

72

<2.0

91

46

5500

1

0.62

3

1.4

15

<1

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2

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458.

372

C33

3

ap10

b13

sp

<4.

851

<0

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22

18.5

79

6390

0

<0

.432

<1.8

02

68.3

35

n.a

.

<

3.59

2

C33

3

ap10

b16

sp

<3.

784

<0

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20

35.0

64

6390

0

<0

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<1.6

56

62.3

46

n.a

.

<

4.38

6

C33

7

ap17

b11

py

<3.

007

<0

.425

<5

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4655

00

168

.814

1

8.86

6

<1.4

71

73.

226

20

7.33

8 C

337

ap

17b1

3

p

y

8

.842

<0.1

16

<1.6

73

46

5500

1

.890

23.

040

0.

544

<2.0

47

328

.102

C

337

ap

17b1

5

p

y

<

1.45

6

<0.1

79

48.9

35

46

5500

<

0.13

6

<0.

339

35

.223

1

600.

414

323.

533

C33

7

ap17

b17

py

<4.

067

<0

.452

<5

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4655

00

33.

117

7

.079

<2.4

51

<7.

321

31

5.64

7 C

337

ap

17b1

8

p

y

<

4.20

2

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<6.8

43

46

5500

9

7.93

7

17.

053

<2

.393

<

6.81

2

220.

775

C33

7

ap17

b12

sp

<3.

841

<0

.563

24

80.7

74

2920

0

<0

.374

<0.8

14

54.3

38

n.a

.

<

2.45

8

C33

7

ap17

b14

sp

<4.

344

<0

.557

20

63.2

76

2920

0

<0

.421

<1.0

93

77.7

24

n.a

.

<

2.74

6

C34

1

ap10

f15

py

<1

.143

<

0.14

7

3

61.1

77

465

500

<0

.121

0.37

8

74.

835

1

4.10

7

8441

.251

C

341

ap

10f1

6

py

<1.6

56

<0.

171

150

.764

4

6550

0

<0.1

48

<0

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28

7.44

4

3

.734

1749

5.94

4 C

341

ap

10f1

7

py

<4.0

33

<0.

398

<4.

776

4655

00

<0.

369

1

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2758

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251

.814

35

45.6

06

C34

1

fb13

a06

py

<2

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<

0.28

0

1

65.6

58

465

500

1.

333

12.

254

60

8.08

2

3

.206

216.

008

C34

1

fb13

a07

py

<4

.321

<

0.63

5

4

60.4

87

465

500

<0

.308

<1.3

09

95.7

01

13.

547

98

44.7

78

C34

1

ap10

e13

sp

<5.

130

<0

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14

81.2

27

2240

0

<0

.510

<1.3

04

30.7

98

n.a

.

<

3.88

8

C34

1

ap10

e16

sp

<3.

871

<0

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17

25.8

40

2240

0

<0

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<2.1

44

455.

570

n.a

.

2

4.25

1 C

341

ap

10e1

8

s

p

<

5.63

2

<0.4

83

1391

.008

22

400

<0.4

99

<1

.665

27

.221

n

.a.

12.

857

C34

1

ap10

e14

tet

<5

.933

<

0.94

9

9

6.79

0

49

400

<0.8

54

<2

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n.

a.

n.a

.

n

.a.

C34

1

ap10

e15

tet

<6

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<

0.86

3

1

30.2

23

494

00

<0

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52

n.a.

n

.a.

n.a

. C

341

ap

10e1

7

t

et

<8.2

45

<0.

825

141

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4

9400

<0.6

89

<2

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n.

a.

n.a

.

n

.a.

C34

3

ap06

c03

py

8.9

33

<0

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72

.201

4655

00

1.5

83

<

0.27

6

47.8

34

3.2

33

69

4.98

1 C

343

ap

06c0

5

p

y

<

4.70

0

<0.5

34

<4.8

32

46

5500

1

1.61

2

<1.

172

41

.672

1

1.58

1

1451

.123

C

343

ap

06c0

9

p

y

3

2.83

1

0.20

5

223.

000

46

5500

2

.797

<0.

342

19

.949

6

.751

95.0

94

C34

3

ap06

c10

py

157

.357

<0.

151

92.

723

4655

00

427

.754

2

.686

10.0

07

29.

160

17

2.22

8 C

343

ap

06c1

1

p

y

9

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<0.1

49

18.1

51

46

5500

8

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<0.

317

10

.089

1

45.4

10

61.7

06

C34

3

ap06

c04

sp

18.

984

<0

.550

95

5.70

6

6150

0

<0

.513

<1.2

10

3064

.107

n.a

.

<

3.17

6

C34

3

ap06

c06

sp

<4.

575

<0

.706

10

74.0

09

6150

0

<0

.535

<1.4

89

5893

.862

n.a

.

<

2.93

2

C34

3

ap06

c12

sp

<8.

475

<0

.672

85

5.16

8

6150

0

<0

.558

<1.8

57

9054

.526

n.a

.

<

3.16

0

C34

5

ap06

d14

py

<1.

908

<0

.217

<3

.055

4655

00

<0.

166

2

0.04

8

<1.6

56

<2.

625

18

5.80

5 C

345

ap

06d1

5

p

y

5

3.04

6

1.23

5

<7.9

42

46

5500

1

.521

21.

383

18

.959

6

057.

007

89.7

18

C34

5

ap06

d16

py

68.

540

0.

749

<5

.713

4655

00

5.0

20

1

07.2

30

7

.069

<4.

279

35

5.06

4 C

345

ap

06d1

8

p

y

3

.897

<0.3

26

<6.4

20

46

5500

4

.107

25.

316

11

.873

<

6.52

8

116.

920

C34

5

ap06

f15

py

<4

.356

<

0.43

1

<

6.08

0

46

5500

1

.888

38.

601

25

.557

<

5.59

1

68.1

82

C34

5

fb13

a08

py

19

.206

<

0.40

1

<

7.24

0

46

5500

6

.985

53.

246

3.

899

23.4

30

211

.009

sam

ple

ru

n/po

int

t

ype

Ti

(ppm

)

V (p

pm)

Mn

(ppm

)

Fe

(ppm

)

Co

(ppm

)

Ni (

ppm

)

C

u (p

pm)

Z

n (p

pm)

A

s (p

pm)

58

Appendix 5: LA-ICP-MS Analysis—Sulphides

C34

5

fb13

a09

py

12

.641

<

0.37

4

<

4.78

4

46

5500

0

.290

1.0

66

1.

762

<2.7

24

52.

480

C34

5

ap06

f14

sp

<4

.365

<

0.43

6

5

82.5

71

248

00

<0

.510

<1.1

45

22.5

05

n.a

.

<

3.54

6

C34

5

ap06

f16

sp

<5

.109

<

0.35

6

7

49.8

09

248

00

<0

.393

<1.2

47

27.2

57

n.a

.

<

2.82

7

C34

5

ap06

f17

sp

<4

.635

<

0.49

3

7

22.9

19

248

00

<0

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<0.7

64

179.

047

n.a

.

<

3.08

1

C34

5

ap06

f18

te

t

<9

.785

<

1.21

9

5

2.64

7

50

600

<1.2

57

<2

.773

n.

a.

n.a

.

n

.a.

C35

0

ap03

d03

py

<1.

797

<0

.253

<2

.337

4655

00

3.5

47

<

0.40

2

748.

037

62.

439

10

45.8

06

C35

0

ap03

d04

py

<1.

394

<0

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<2

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4655

00

6.4

97

1

.617

<1.1

68

2.7

15

25

4.80

5 C

350

ap

03d0

6

p

y

4

.372

0.50

2

41.7

77

46

5500

6

.090

0.9

66

26

.730

4

.402

1459

.275

C

350

ap

03d0

7

p

y

8

.420

<0.5

01

17.0

90

46

5500

<

0.54

2

<1.

327

56

0.73

7

2

73.8

32

1648

.891

C

350

ap

03d0

8

p

y

<

1.14

1

<0.2

39

<2.1

56

46

5500

1

.689

<0.

566

54

5.66

1

1

70.5

65

3242

.635

C

350

ap

03d0

9

p

y

<

1.13

8

0.20

4

42.4

63

46

5500

2

.658

<0.

649

25

.986

3

25.3

91

978.

351

C35

3

ap06

f03

py

10

4.88

1

0

.771

1

2.05

9

46

5500

0

.677

1.9

56

3.

550

2.83

0

85

.857

C

353

ap

06f0

5

py

33.6

05

<0.

443

62.

995

4655

00

1.1

72

1

.702

<4.7

07

8.6

65

15

4.35

2 C

353

ap

06f0

7

py

8.87

1

<0.

852

<9.

345

4655

00

<0.

560

<

1.25

6

<6.4

42

611

.013

15

6.55

1 C

353

ap

06f0

8

py

<5.7

27

<0.

649

<7.

907

4655

00

1.5

56

1

.957

<6.0

66

60.

253

12

0.91

0 C

353

ap

06f1

0

py

33.4

17

<0.

526

20.

095

4655

00

0.9

32

3

.423

95.4

66

10.

786

40

7.37

6 C

353

ap

06f1

2

py

76.3

84

<0.

736

<10

.098

4

6550

0

0.72

9

<

1.62

9

18.8

95

43.

745

16

5.65

2 C

353

ap

06f1

3

py

8.52

2

<0.

565

<8.

026

4655

00

0.9

30

1

.927

5.40

1

<6

.041

9

6.22

2 C

353

ap

06f0

4

sp

<4.6

11

<0.

552

156

0.83

1

3

2600

<0.3

94

<1

.291

23

2.77

6

n

.a.

<2.

469

C

353

ap

06f0

6

sp

19.0

89

<0.

773

123

5.05

0

3

2600

<0.8

02

<1

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70

0.89

6

n

.a.

<4.

174

C

353

ap

06f1

1

sp

7.40

9

<0.

530

200

5.01

3

3

2600

<0.4

52

<0

.994

98

.966

n

.a.

<2.

846

C

355

ap

17a1

7

c

py

<1

2.36

0

<

1.30

8

<

15.4

63

304

300

<0

.871

<1.8

17

n.a.

3

74.4

63

<8.2

89

C35

5

ap17

d12

cpy

<9.6

93

<1.

093

<13

.871

3

0430

0

<0.8

54

<2

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n.

a.

105

2.16

7

9.

380

C35

5

ap17

a12

py

136

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0.2

02

134

.488

4

6550

0

14.1

32

1.

206

3

147.

858

121.

515

193

1.30

1 C

355

ap

17a1

5

p

y

4

3.41

1

<0.1

01

8.66

9

4

6550

0

20.9

56

0.

432

4

.629

2.7

74

15

1.44

4 C

355

ap

17a1

6

p

y

<

4.47

5

<0.4

29

<4.4

04

46

5500

6

6.70

0

<0.

802

1.

846

<6.1

56

65.

795

C35

5

ap17

d11

py

3.1

70

<0

.406

<4

.131

4655

00

25.

532

<

0.87

5

12.7

03

<3.

766

15

0.70

0 C

355

ap

17d1

3

p

y

<

2.73

7

<0.3

93

<6.9

92

46

5500

<

0.31

1

<1.

172

30

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<

7.58

5

19.3

91

C35

5

ap17

d15

py

218

.725

0.5

57

91.

331

4655

00

19.

211

0

.920

41.9

63

<3.

925

37

6.75

3 C

355

ap

17a1

8

s

p

<

5.19

8

<0.5

22

2164

.762

82

000

<0.3

73

<1

.191

11

9.55

2

n

.a.

<3.

503

C

355

ap

17d1

4

s

p

<

4.50

2

<0.4

47

1935

.759

82

000

<0.3

91

<1

.337

94

07.2

81

n

.a.

<3.

489

C

357

ap

06e0

4

p

y

2

.073

<0.1

44

<1.9

88

46

5500

2

1.45

8

<0.

308

4.

480

<1.3

44

21.

802

C35

7

ap06

e06

py

<2.

861

<0

.415

<5

.393

4655

00

1.5

86

<

0.80

0

<3.5

21

<4.

628

93

6.08

1 C

357

ap

06e0

7

p

y

4

.141

<0.5

13

<6.5

15

46

5500

4

7.80

3

<1.

193

<3

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<

6.68

3

5.78

4 C

357

ap

06e0

8

p

y

7

7.02

3

<0.3

68

13.1

09

46

5500

1

7.48

2

3.3

08

20

.351

<

3.98

4

373.

790

C35

7

ap06

e10

py

16.

383

<0

.494

10

.078

4655

00

29.

780

<

0.89

8

<3.5

03

<4.

784

66

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C

357

ap

06e0

3

s

p

<

6.10

9

<0.9

46

490.

402

35

100

<0.5

39

<1

.330

70

3.16

1

n

.a.

<4.

354

C

357

ap

06e0

9

s

p

<

4.79

9

<0.5

65

532.

572

35

100

<0.4

33

<1

.218

40

7.97

8

n

.a.

<5.

126

sam

ple

ru

n/po

int

t

ype

Ti

(ppm

)

V (p

pm)

Mn

(ppm

)

Fe

(ppm

)

Co

(ppm

)

Ni (

ppm

)

C

u (p

pm)

Z

n (p

pm)

A

s (p

pm)

59

Appendix 5: LA-ICP-MS Analysis—Sulphides

C35

9

ap10

d12

cpy

<4.4

36

<0.

498

<6.

545

3043

00

<0.

400

<

1.19

1

n.a.

1

74.4

78

140.

966

C35

9

ap10

d10

py

<3.

163

<0

.371

12

.174

4655

00

34.

853

2

1.23

5

<2.9

79

<6.

268

54

.486

C

359

ap

10d1

3

p

y

<

4.59

2

<0.5

53

<6.5

80

46

5500

3

2.69

3

37.

429

<4

.041

<

6.23

5

189.

394

C35

9

ap10

d16

py

14.

548

<0

.464

<5

.634

4655

00

55.

583

4

9.33

0

<3.7

35

<6.

953

48

.629

C

359

ap

10d1

7

p

y

<

3.74

1

<0.4

29

<5.7

90

46

5500

2

2.33

4

27.

117

<3

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<

5.81

6

111.

006

C35

9

ap10

d18

py

<2.

256

<0

.220

<3

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4655

00

1.5

42

2

2.79

0

6.84

5

<3

.574

4

7.71

4 C

359

ap

10d1

1

s

p

<

4.04

1

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81

375.

047

11

000

<0.3

86

<1

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77

4.41

8

n

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4.7

21

C35

9

ap10

d14

sp

23.

179

<0

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28

8.85

9

1100

0

<0

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<2.8

89

860.

547

n.a

.

<

6.35

8

C35

9

ap10

d15

sp

<4.

002

<0

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61

2.22

7

1100

0

<0

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<1.2

75

225.

815

n.a

.

5

.394

C

362

ap

06a0

4

p

y

<

3.17

7

<0.4

20

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32

46

5500

2

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10.

021

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3

9.82

8

480.

495

C36

2

ap06

a06

py

<3.

717

<0

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7.

852

465

500

<0

.295

<0.8

29

276.

216

974

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69

5.77

1 C

362

ap

06a0

9

p

y

<

3.37

7

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83

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17

46

5500

1

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34.

930

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<

5.50

6

366.

535

C36

2

ap06

a10

py

<4.

209

<0

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4655

00

2.0

62

7

.222

<4.0

36

<7.

013

38

6.46

4 C

362

ap

06a1

4

p

y

6

.635

<0.3

49

<5.3

56

46

5500

0

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7.5

67

12

9.60

7

1

00.2

79

794.

070

C36

2

ap06

a15

py

<4.

348

<0

.538

<7

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4655

00

2.6

28

6

.951

<3.9

89

<7.

238

17

3.38

0 C

362

ap

06a1

7

p

y

4

4.72

4

<0.4

11

63.8

37

46

5500

1

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7.9

40

<2

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<

5.65

3

468.

069

C36

2

ap06

a03

sp

<4.

720

<0

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60

0.62

6

2160

0

<0

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<1.2

92

4.78

6

n.

a.

<3.0

85

C36

2

ap06

a05

sp

<4.

665

<0

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71

8.98

9

2160

0

<0

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<1.1

63

10.2

99

n.a

.

<

2.11

0

C36

2

ap06

a11

sp

<5.

154

<0

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65

4.55

9

2160

0

<0

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<0.9

13

11.6

72

n.a

.

<

3.03

2

C36

2

ap06

a12

sp

<5.

213

<0

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79

0.92

6

2160

0

<0

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<1.1

30

9.73

3

n.

a.

<3.1

65

C36

2

ap06

a13

sp

<5.

208

<0

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73

0.56

3

2160

0

<0

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66

25.8

23

n.a

.

<

3.06

3

C36

2

ap06

a16

sp

<4.

521

<0

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76

2.39

4

2160

0

<0

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02

24.9

44

n.a

.

<

3.24

1

C36

4

ap10

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apy

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11

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064

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10

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<

12.4

69

n.a.

C

364

ap

10c1

1

c

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7

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0.41

0

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269

n.

a.

428

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25

0.81

7 C

364

ap

10c1

3

c

py

<3

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0.50

5

<

7.34

6

30

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<

0.52

7

<0.

905

n.

a.

131

0.26

5

20

6.48

3 C

364

ap

10c0

3

p

y

<

3.61

8

<0.4

73

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46

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5.1

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7

259.

828

C36

4

ap10

c05

py

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955

<0

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00

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1

8.26

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90

138

4.56

1

87

0.82

1 C

364

ap

10c0

8

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y

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3.28

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301

C36

4

ap10

c12

py

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<0

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4655

00

46.

147

2

.576

7.20

0

10

7.08

3

2

03.4

68

C36

4

ap10

c14

py

<3.

637

<0

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7.

599

465

500

49

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7.67

8

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082

7

613.

732

839.

536

C36

4

ap10

c15

py

<2.

495

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4655

00

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641

3

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7.34

2

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1

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210

C36

4

ap10

c17

py

<4.

551

<0

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5.68

2

4655

00

41.

397

8

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77.5

53

291

3.29

6

58

54.0

35

C36

4

ap10

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py

4.3

15

<0

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4655

00

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545

2

1.58

9

2.10

1

2.

726

715.

539

C36

4

ap10

c04

sp

<3.

130

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8

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0

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366.

682

n.a

.

<

3.43

1

C36

4

ap10

c09

sp

<4.

056

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0.12

3

2390

0

<0

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234.

003

n.a

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1.75

4 C

364

ap

10c1

0

s

p

<

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0

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69

524.

969

23

900

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22

<1

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26

1.24

0

n

.a.

24.

238

C36

5

ap03

b03

py

<1.

141

<0

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47

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4655

00

0.8

33

1

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2682

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937

9.29

0

48

4.66

6 C

365

ap

03b0

9

p

y

3

3.94

4

<0.8

11

22.1

63

46

5500

1

3.37

5

6.2

32

<3

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1

2.85

4

289.

026

sam

ple

ru

n/po

int

t

ype

Ti

(ppm

)

V (p

pm)

Mn

(ppm

)

Fe

(ppm

)

Co

(ppm

)

Ni (

ppm

)

C

u (p

pm)

Z

n (p

pm)

A

s (p

pm)

60

Appendix 5: LA-ICP-MS Analysis—Sulphides

C36

5

ap03

b11

py

9.5

55

<0

.559

30

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4655

00

0.9

59

4

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534.

409

177

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11

36.4

79

C36

5

ap03

b12

py

<3.

887

<0

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4655

00

<0.

312

<

1.60

3

3.76

4

<4

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5

8.28

0 C

365

ap

03b1

3

p

y

1

1.31

2

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47

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96

46

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6

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2

11.

731

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7

474.

534

C36

5

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py

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989

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12

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4655

00

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466

<

1.75

4

4.88

8

<7

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5

74.8

17

C36

5

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py

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526

<0

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45

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4655

00

<0.

427

<

1.21

5

12.6

51

12.

795

42

2.83

5 C

365

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s

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n

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365

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7

s

p

<

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7

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00

495.

561

47

100

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n

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C

365

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0

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531.

936

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n

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739

C

365

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p

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402

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100

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n

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994

C

365

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972

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n

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C

369

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5

cpy

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0

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n.

a.

207

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2

C36

9

ap06

b14

py

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290

<0

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4655

00

27.

047

2

0.00

9

9613

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151

3.55

4

88

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C

369

ap

06b1

5

p

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69

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7

4

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0

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121

45

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4.87

0

623.

778

C36

9

ap06

b16

py

<2.

589

<0

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4655

00

195

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1

41.5

83

2

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<3.

042

77

8.82

6 C

369

ap

06b1

7

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3

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68

67.

239

5.

389

26.3

24

995

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C

369

fb

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731

4655

00

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6

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7

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61

171

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4 C

369

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8

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1

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434

C36

9

ap06

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sp

<4.

592

<0

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27

8.81

4

4660

0

<0

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81

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90

n.a

.

<

2.23

5

C36

9

ap06

b13

sp

<4.

516

<0

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23

7.32

5

4660

0

<0

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80

2703

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n.a

.

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8

C37

2

ap02

b03

apy

65.8

97

3.3

97

52.

824

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00

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312

1

1.56

6

5.99

5

66

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n

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C37

2

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apy

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70

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150

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00

1.0

69

3

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948

n.

a.

C37

2

ap02

b12

apy

109.

611

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211

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3430

00

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1

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7

31

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30

n.

a.

C37

2

ap02

b04

py

1.9

10

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3.

292

465

500

18

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3

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3

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434

C37

2

ap02

b06

py

26.

169

<0

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6.

186

465

500

0.

914

0.8

78

2.

111

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4

18

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73

C37

2

ap02

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py

16.

610

1.

844

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8

4655

00

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601

2

3.85

8

172.

707

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285

69

33.7

99

C37

2

ap02

b08

py

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139

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15

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0

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00

50.

366

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2.64

2

123.

630

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02

39

36.7

75

C37

2

ap02

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py

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809

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4655

00

15.

374

1

1.69

7

5.02

5

6.

427

4396

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C

372

ap

02b1

0

p

y

2

2.80

5

1.28

9

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19

46

5500

4

0.70

0

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269

6.

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9

34

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28

C37

2

ap02

b11

py

50.

270

0.

820

31

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4655

00

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2

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8

10.6

87

5.3

57

17

575.

666

C37

2

ap02

b13

py

818

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1.1

10

5.2

01

4655

00

38.

973

1

8.98

7

3.77

7

3.

884

2220

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C

372

ap

02b1

4

p

y

3

1.94

6

0.76

9

14.2

45

46

5500

2

7.32

3

12.

783

2.

661

176.

890

143

67.1

19

C37

2

ap02

b15

py

<3.

967

2.

467

68

8.19

4

4655

00

69.

856

2

4.37

9

61.4

20

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012

25

77.8

36

C37

2

ap02

b16

py

67.

930

<0

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4655

00

1.9

32

8

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576

33

74.2

48

C37

2

ap02

b17

py

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351

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4655

00

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1

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6

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1

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763

C37

2

ap02

b18

py

620

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0.7

90

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16

4655

00

1.6

15

0

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9

3.

053

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C

378

ap

10b0

6

c

py

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3

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6

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304

300

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65

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64

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62

C37

8

ap10

b03

py

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064

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4655

00

33.

972

2

1.48

4

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54

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143

12

5.80

7 C

378

ap

10b0

5

p

y

<

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4

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41

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27

46

5500

1

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21.

583

<2

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<

5.19

1

2247

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sam

ple

ru

n/po

int

t

ype

Ti

(ppm

)

V (p

pm)

Mn

(ppm

)

Fe

(ppm

)

Co

(ppm

)

Ni (

ppm

)

C

u (p

pm)

Z

n (p

pm)

A

s (p

pm)

61

Appendix 5: LA-ICP-MS Analysis—Sulphides

C37

8

ap10

b08

py

16.

055

<0

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10

8.09

9

4655

00

169

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5

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0

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3.4

90

58

4.78

5 C

378

ap

10b0

9

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8

138

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5.95

3

1489

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C

378

ap

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0

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6

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0

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4

841.

925

C37

8

ap10

b07

sp

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777

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23

5.42

5

2600

0

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68

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0.17

8

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.

<

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6

C37

9

ap03

a03

py

19.

132

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268

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500

16

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<0.3

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9

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487.

829

C37

9

ap03

a06

py

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084

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735

465

500

1.

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8 C

379

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1

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6

356.

788

C37

9

ap03

a08

py

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909

2.74

4

15

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C

379

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03a0

9

p

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8

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0

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7

3.

219

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88

C37

9

ap03

a11

py

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4655

00

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66

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7

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4

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56

C37

9

ap03

a12

py

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00

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454

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9.64

7 C

379

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7

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C37

9

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py

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500

11

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3

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40

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9

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9

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C37

9

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9

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9

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9

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9

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C38

1

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343

000

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93

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n.

a.

C38

1

ap03

f03

cp

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339

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a.

555

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7.

602

C38

1

ap03

f08

cp

y

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300

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4

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1

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1

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1

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1

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f12

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1

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381

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1

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f18

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168

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00

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383

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82

C38

3

ap17

e14

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00

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2

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0.73

8

4.

910

48.1

89

sam

ple

ru

n/po

int

t

ype

Ti

(ppm

)

V (p

pm)

Mn

(ppm

)

Fe

(ppm

)

Co

(ppm

)

Ni (

ppm

)

C

u (p

pm)

Z

n (p

pm)

A

s (p

pm)

62

Appendix 5: LA-ICP-MS Analysis—Sulphides

C38

3

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e16

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118

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00

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y

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088

C38

3

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e18

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00

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C38

3

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110

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0.6

57

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383

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385

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5

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385

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5

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385

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5

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00

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9

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385

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C

385

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794

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18a3

4

c

py

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9.

521

C79

4

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a33

py

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691

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5

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00

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794

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6

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323

C79

4

ap18

a39

py

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492

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00

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C79

4

jl11a

74

py

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C79

4

jl11a

75

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0

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289.

796

C79

4

ap18

a37

sp

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896

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143

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0

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66

n

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C

794

ap

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1

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1

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795

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5

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py

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C79

5

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59

py

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C79

5

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7

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797

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2

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6

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79

C79

7

jl11z

09

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88

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797

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797

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C79

7

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799

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799

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32.2

93

C79

9

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37

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4.

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2

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10.

061

47

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1

509.

867

3369

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sam

ple

ru

n/po

int

t

ype

Ti

(ppm

)

V (p

pm)

Mn

(ppm

)

Fe

(ppm

)

Co

(ppm

)

Ni (

ppm

)

C

u (p

pm)

Z

n (p

pm)

A

s (p

pm)

63

Appendix 5: LA-ICP-MS Analysis—Sulphides

C79

9

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38

py

4.

647

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9

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9

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801

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1

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801

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801

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801

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00

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801

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801

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803

ap

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4

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C80

3

ap18

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3

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3

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3

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C80

4

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4

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804

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C80

4

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807

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807

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p

0

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71

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.

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8

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a47

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391

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10

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n

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0.8

87

C80

9

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64

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46

5500

3

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1.9

26

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59

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C80

9

jl04a

65

py

3.

600

0

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384

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9

jl04a

66

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852

C80

9

jl04a

67

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22

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0.09

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9

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00

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9

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00

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788

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728

sam

ple

ru

n/po

int

t

ype

Ti

(ppm

)

V (p

pm)

Mn

(ppm

)

Fe

(ppm

)

Co

(ppm

)

Ni (

ppm

)

C

u (p

pm)

Z

n (p

pm)

A

s (p

pm)

64

Appendix 5: LA-ICP-MS Analysis—Sulphides

C81

0

ap19

a71

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3.2

43

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522

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746

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a72

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8 C

810

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1

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00

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742

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812

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2

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0.8

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3

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531

C81

3

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175

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C

813

jl0

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813

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813

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813

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3

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4

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4

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5

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5

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817

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C81

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817

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7

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3

015.

601

sam

ple

ru

n/po

int

t

ype

Ti

(ppm

)

V (p

pm)

Mn

(ppm

)

Fe

(ppm

)

Co

(ppm

)

Ni (

ppm

)

C

u (p

pm)

Z

n (p

pm)

A

s (p

pm)

65

Appendix 5: LA-ICP-MS Analysis—Sulphides

C81

8

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int

t

ype

Ti

(ppm

)

V (p

pm)

Mn

(ppm

)

Fe

(ppm

)

Co

(ppm

)

Ni (

ppm

)

C

u (p

pm)

Z

n (p

pm)

A

s (p

pm)

66

Appendix 5: LA-ICP-MS Analysis—Sulphides

C82

6

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a73

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2.2

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6

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25

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30

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3

sam

ple

ru

n/po

int

t

ype

Ti

(ppm

)

V (p

pm)

Mn

(ppm

)

Fe

(ppm

)

Co

(ppm

)

Ni (

ppm

)

C

u (p

pm)

Z

n (p

pm)

A

s (p

pm)

67

Appendix 5: LA-ICP-MS Analysis—Sulphides

C83

6

ap19

a15

py

3.7

92

0.

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500

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276

sam

ple

ru

n/po

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t

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Ti

(ppm

)

V (p

pm)

Mn

(ppm

)

Fe

(ppm

)

Co

(ppm

)

Ni (

ppm

)

C

u (p

pm)

Z

n (p

pm)

A

s (p

pm)

68

Appendix 5: LA-ICP-MS Analysis—Sulphides

C84

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7

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2

sam

ple

ru

n/po

int

t

ype

Ti

(ppm

)

V (p

pm)

Mn

(ppm

)

Fe

(ppm

)

Co

(ppm

)

Ni (

ppm

)

C

u (p

pm)

Z

n (p

pm)

A

s (p

pm)

69

Appendix 5: LA-ICP-MS Analysis—Sulphides

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9

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4

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run/

poin

t

typ

e

Ti (p

pm)

V

(ppm

)

M

n (p

pm)

F

e (p

pm)

C

o (p

pm)

N

i (pp

m)

Cu

(ppm

)

Zn

(ppm

)

As

(ppm

)

70

Appendix 5: LA-ICP-MS Analysis—Sulphides

sam

ple

r

un/p

oint

typ

e

Mo

(ppm

)

A

g (p

pm)

C

d (p

pm)

S

n (p

pm)

S

b (p

pm)

A

u (p

pm)

T

l (pp

m)

P

b (p

pm)

B

i (pp

m)

P

eak

(s)

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0

.305

124

4.10

5

3.

222

1087

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1687

4.19

6

0.3

28

42

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C26

1

ap10

d06

py

68.

133

21.0

68

n.a

.

0

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85.

338

1.

178

45.1

31

4237

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0.0

68

39

.5

C26

1

ap10

d07

py

27.

763

201.

472

n.a

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0

.336

523

.050

1.

005

38.1

17

9428

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0.1

02

37

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C26

1

ap10

d08

py

73.

255

25.6

93

n.a

.

<

0.30

1

98.

041

0.

966

37.8

72

9133

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0.0

88

36

.6

C26

1

jl11a

18

py

74

.150

20.8

84

<12

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1.

293

107.

202

1.0

67

5

1.81

1

7249

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<0.

095

48

.9

C26

1

jl11a

19

py

13

0.16

1

23.9

44

<19

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1.

246

99.9

02

0.7

68

3

2.52

3

1268

8.92

7

0.1

17

49

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C26

1

jl11a

20

py

38

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413.

781

15.

118

1

.373

137

5.28

5

0.

523

14.2

90

1075

5.66

9

0.1

11

51

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C27

8

ap03

e11

py

<2.

496

14.5

09

n.a

.

<

0.59

7

23.

715

10

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0.53

9

118

4.70

8

12

4.85

5

4

1.5

C27

8

ap03

e13

py

<1.

578

0.22

0

n.

a.

<0.

436

0

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27

<0.

115

9.

166

2.02

3

25.

7 C

278

ap

03e1

5

p

y

<

3.91

8

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.a.

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764

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9.

964

4.70

3

42.

5 C

278

ap

03e1

6

p

y

<

4.63

9

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222

n.a.

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0.74

8

2.7

68

<0

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<

0.29

3

26.1

28

15

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4

4.5

C27

8

ap03

e12

sp

<4.

940

4.74

8

n.

a.

1.9

10

<

0.63

1

<0.4

28

<0.

390

1.

047

0.31

9

23.

7 C

278

ap

03e1

4

s

p

<

5.59

7

19

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n

.a.

2.0

28

1

5.36

2

<0.5

13

<0.

544

13

.225

7.58

6

38.

6 C

278

ap

03e1

8

s

p

<

6.81

6

15

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n

.a.

1.9

02

8

.276

<0.3

99

<0.

441

22

.417

12.8

88

42.

5

sam

ple

r

un/p

oint

typ

e

Mo

(ppm

)

A

g (p

pm)

C

d (p

pm)

S

n (p

pm)

S

b (p

pm)

A

u (p

pm)

T

l (pp

m)

P

b (p

pm)

B

i (pp

m)

P

eak

(s)

71

Appendix 5: LA-ICP-MS Analysis—Sulphides

C28

0

ap03

e03

py

<3.

579

<0.3

35

n.a

.

<

0.71

8

<0.

590

<0

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0.32

3

<0.3

82

<0

.086

33

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C28

0

ap03

e05

py

<4.

895

<0.4

78

n.a

.

<

0.81

6

<0.

517

<0

.328

<

0.28

7

0.51

9

0.

192

4

2.5

C28

0

ap03

e06

py

<3.

992

24.6

52

n.a

.

<

0.58

4

108

.306

6.

705

0.50

3

173

4.63

9

71

.477

3

9.5

C28

0

ap03

e07

py

<4.

448

2.73

3

n.

a.

<1.

707

3

.615

<0.3

17

<0.

262

19

2.82

3

18.3

12

32.

6 C

280

ap

03e1

0

p

y

7

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9.

383

n.a.

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0.88

3

36.

006

27

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0.78

0

910

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21

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3

9.5

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0

ap03

e04

sp

<6.

558

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4

n.

a.

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521

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0.98

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97

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<0

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81

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280

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03e0

8

s

p

<

8.64

1

1.

316

n.a.

2

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9

1.83

3

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35

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0

ap03

e09

sp

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417

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9

n.

a.

1.1

08

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0.91

6

<0.5

07

<0.

423

4.

502

0.44

5

30.

6 C

284

ap

06b0

5

c

py

<3

.764

111.

605

n.a

.

1

4.87

2

17.

648

<0

.267

0

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8.75

2

0.

618

3

3.6

C28

4

ap06

b03

py

<3.

834

<0.4

60

n.a

.

<

0.59

7

<0.

811

<0

.326

<

0.24

0

<0.3

12

<0

.057

45

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C28

4

ap06

b06

py

2.3

53

2.13

8

n.

a.

0.2

82

3

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0.15

1

<0

.064

10

9.33

5

3.33

1

43.

5 C

284

ap

06b0

8

p

y

<

4.38

2

1.

691

n.a.

<

0.57

6

4.1

28

0.

372

<0.2

00

46.8

30

2.

115

4

0.5

C28

4

ap06

b09

py

<4.

096

1.70

7

n.

a.

<0.

724

5

.617

<0.3

33

<0.

260

7.

862

0.58

8

24.

7 C

284

ap

06b1

0

p

y

5

.431

<0

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n

.a.

<0.

834

1

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<0.3

63

1.4

84

2.

321

0.38

7

20.

8 C

284

ap

06b0

4

s

p

<

5.16

6

21

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n

.a.

1.9

99

1

0.69

4

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01

<0.

484

13

.250

0.43

0

34.

6 C

284

ap

06b0

7

s

p

<

5.96

6

16

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n

.a.

1.2

60

4

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05

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340

8.

100

0.22

2

41.

5 C

284

ap

06b1

1

s

p

<

6.73

0

36

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n

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1.8

14

2

4.05

5

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28

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383

70

0.32

4

4.87

1

43.

5 C

285

ap

03c0

7

p

y

<

1.39

4

0.

254

n.a.

0

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13.

845

1.

498

<0.0

62

62.2

55

1.

200

4

3.5

C28

5

ap03

c10

py

<4.

958

<0.4

76

n.a

.

<

0.86

4

3.3

46

<0

.428

<

0.29

4

28.0

53

4.

221

4

4.5

C28

5

ap03

c13

py

<1.

634

0.35

2

n.

a.

0.4

11

3

.055

<0.1

31

<0.

084

10

5.75

2

31.1

12

42.

5 C

285

ap

03c1

4

p

y

<

1.38

7

0.

563

n.a.

0

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1.3

37

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7

10.4

67

0.

068

2

4.7

C28

5

ap03

c17

py

<4.

070

<0.4

80

n.a

.

<

1.89

2

<0.

507

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0.31

2

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85

0.

190

3

1.6

C28

5

ap03

c18

py

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150

<0.1

11

n.a

.

<

0.29

5

<0.

255

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0.10

7

4.39

7

0.

919

3

9.5

C28

5

ap03

c08

sp

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194

3.53

9

n.

a.

1.1

82

2

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94

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329

3.

978

2.72

9

41.

5 C

285

ap

03c0

9

s

p

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1

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0.41

1

4.15

4

3.

999

4

2.5

C28

5

ap03

c11

sp

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368

5.54

5

n.

a.

1.4

86

6

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36

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327

23

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13.2

17

38.

6 C

285

ap

03c1

2

s

p

<

5.40

9

2.

309

n.a.

1

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0.8

87

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4

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47

1.

938

3

9.5

C28

5

ap03

c15

sp

<5.

032

3.13

7

n.

a.

1.3

66

2

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13

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268

5.

927

4.12

0

45.

5 C

285

ap

03c1

6

s

p

<

4.92

6

1.

509

n.a.

1

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081

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0.37

8

1.50

3

0.

170

4

3.5

C28

7

ap17

b03

py

31.

202

25.9

52

n.a

.

<

0.32

3

100

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1.

340

0.82

6

150

6.87

6

0.

120

1

0.9

C28

7

ap17

b05

py

<3.

755

0.19

4

n.

a.

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297

0

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91

<0.

054

91

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28

33.6

C

287

ap

17b0

7

p

y

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6.41

9

0.

878

n.a.

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7

5.1

71

0.

446

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187.

253

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42

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C28

7

ap17

b09

py

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681

47.5

65

n.a

.

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2

777

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1.

117

1.14

9

79.

193

<

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2

12.9

C

287

ap

17b0

4

s

p

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13

4.5

23

n

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0.9

48

1

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79

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154

4.

261

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84

34.6

C

287

ap

17b0

8

s

p

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26.

992

n

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1.1

67

3

0.19

3

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0.1

83

19

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21

12.9

C

290

ap

10f0

8

cpy

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88

31

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n

.a.

24.

574

1

1.13

7

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76

0.2

58

6.

426

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74

45.5

C

290

ap

10f0

3

py

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62

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n

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0.64

7

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12

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156

0.

742

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33.6

C

290

ap

10f0

7

py

<4.9

86

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n

.a.

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394

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0.82

5

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73

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139

3.

060

<0.0

75

35.6

sam

ple

r

un/p

oint

typ

e

Mo

(ppm

)

A

g (p

pm)

C

d (p

pm)

S

n (p

pm)

S

b (p

pm)

A

u (p

pm)

T

l (pp

m)

P

b (p

pm)

B

i (pp

m)

P

eak

(s)

72

Appendix 5: LA-ICP-MS Analysis—Sulphides

C29

0

ap10

f09

py

<2

.012

27.7

21

n.a

.

0

.391

21.

446

5.

249

328.

884

2032

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2.3

96

31

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C29

0

ap10

f11

py

<2

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0.62

6

n.

a.

<0.

461

0

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0.37

9

<0

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26

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2.43

1

23.

7 C

290

ap

10f1

2

py

<3.6

60

11

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n

.a.

<0.

570

1

7.22

7

3.35

2

0.

372

8

87.0

56

0.95

1

22.

7 C

290

ap

10f1

3

py

<3.5

09

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n

.a.

<0.

579

<

0.60

2

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96

<0.

135

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<0.1

00

42.5

C

290

ap

10f0

4

sp

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73

3.

965

n.a.

1

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7

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7

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40

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C29

0

ap10

f05

sp

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6

n.

a.

1.4

25

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8

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27

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290

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10f1

0

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43

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0

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0.

859

38.8

95

21.

7 C

292

ap

06g0

3

c

py

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9

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4.5

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4

4.5

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2

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py

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.

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4

3.5

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2

ap06

g05

py

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445

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0

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4

5.5

C29

2

ap06

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py

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0

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7

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895

4

4.5

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2

ap06

g07

py

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0.21

6

n.

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0.3

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0

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71

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6.

162

4.33

7

42.

5 C

292

ap

06g0

8

p

y

<

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n

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0

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1.

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0.66

8

36.

6 C

292

ap

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0

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29.

7 C

297

ap

10a0

5

a

py

32

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0.

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4

3.5

C29

7

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a06

cpy

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14

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n

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4

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297

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10a1

7

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py

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080

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8

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39

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C29

7

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58.1

64

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56.

536

48

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0.13

6

404

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0.

151

4

4.5

C29

7

ap10

a04

py

<1.

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2.29

2

n.

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9

9.34

5

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6

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71

6.44

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40.5

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297

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1.

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0.48

7

561

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2.

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3

5.6

C29

7

ap10

a09

py

<4.

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7

n.

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6

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6

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39.5

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297

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0.

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1.5

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7

ap10

a13

py

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4

n.

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00.5

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4

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73

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0

37.

6 C

297

ap

10a1

5

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1.

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9.5

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7

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a16

py

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0.2

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8

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1

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0

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40.5

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297

ap

10a1

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a12

sp

<9.

061

9.28

8

n.

a.

0.9

03

1

2.97

6

<0.4

83

<0.

217

6.

949

<0.0

94

39.5

C

297

ap

10a1

4

s

p

<

10.1

64

2.0

44

n

.a.

1.0

23

<

0.85

0

<0.4

11

<0.

226

1.

314

<0.0

95

33.6

C

299

ap

17c0

8

p

y

<

7.56

2

<0

.520

n

.a.

<0.

785

<

0.73

1

<0.1

69

<0.

157

1.

166

<0.0

62

44.5

C

299

ap

17c1

0

p

y

<

9.52

8

2.

574

n.a.

5

.278

17.

462

2.

353

1.62

3

132

.493

9.

088

4

4.5

C29

9

ap17

c11

py

27.

472

4.01

9

n.

a.

<0.

810

2

0.15

5

1.61

5

<0

.133

26

7.41

8

18.6

56

26.

7 C

299

ap

17c0

4

s

p

<

8.41

8

3.

455

n.a.

1

.443

3.9

18

<0

.276

<

0.12

8

3.54

3

<0

.075

41

.5

C29

9

ap17

c06

sp

<10

.286

9

.434

n.a

.

1

.971

45.

085

<0

.305

<

0.16

5

11.8

92

0.

123

2

2.7

C29

9

ap17

c03

tet

<2

.958

n.a.

n

.a.

0.6

16

n

.a.

<0.

085

<

0.06

1

0.20

6

11

3.31

8

4

2.5

C29

9

ap17

c05

tet

<3

.388

n.a.

n

.a.

0.6

34

n

.a.

<0.

077

<

0.06

3

0.24

8

11

4.22

1

4

0.5

C29

9

ap17

c07

tet

<1

3.56

5

n.a.

n

.a.

<1.

406

n

.a.

<0.

365

<

0.19

0

3.40

3

91

.238

1

9.8

C30

1

ap03

d14

py

<0.

994

6.85

8

n.

a.

<0.

249

3

8.23

8

31.9

68

<0

.072

44

5.39

3

0.02

4

30.

6 C

301

ap

03d1

5

p

y

1

.985

33

.111

n

.a.

0.6

97

1

01.0

82

5.70

4

<0

.079

25

46.2

80

0

.379

39.5

sam

ple

r

un/p

oint

typ

e

Mo

(ppm

)

A

g (p

pm)

C

d (p

pm)

S

n (p

pm)

S

b (p

pm)

A

u (p

pm)

T

l (pp

m)

P

b (p

pm)

B

i (pp

m)

P

eak

(s)

73

Appendix 5: LA-ICP-MS Analysis—Sulphides

C30

1

ap03

d17

py

<5.

151

1.35

0

n.

a.

<0.

942

11

.263

25.9

40

<0

.325

78

.467

<0.0

72

35.

6 C

301

ap

03d1

8

p

y

<

1.06

3

17

.161

n.a.

0

.312

92.6

09

17

.157

0.08

5

175

7.84

6

0.

031

39.5

C

301

ap

03d1

0

s

p

<

1.29

3

65

.163

n.a.

0

.680

3.37

7

43

.983

<0.0

71

2.96

2

<0

.024

4

0.5

C30

1

ap03

d16

sp

<7.

453

19.3

87

n.

a.

1.5

56

6.

294

<0.7

41

<0

.637

13

.493

<0.1

92

39.

5 C

306

ap

06e1

1

p

y

<

4.31

9

3.

610

n.a.

<

0.52

2

8.05

6

<0

.235

<0.1

46

80.9

34

<0

.052

1

8.8

C30

6

ap06

e16

py

<6.

128

0.68

5

n.

a.

<0.

665

5.

293

<0.2

16

<0

.226

12

.287

<0.0

55

28.

7 C

306

ap

06e1

2

s

p

<

6.75

4

13

.214

n.a.

1

.597

7.80

2

<0

.296

<0.2

65

99.9

28

<0

.098

4

5.5

C30

6

ap06

e13

sp

<8.

552

10.2

62

n.

a.

1.5

17

5.

494

<0.3

94

<0

.224

7.

672

<0.0

57

27.

7 C

306

ap

06e1

5

s

p

<

9.22

6

10

.917

n.a.

1

.642

4.67

8

<0

.339

<0.2

82

9.85

9

<0

.081

1

6.8

C30

6

ap06

e18

sp

<5.

308

21.3

95

n.

a.

1.3

49

18

.024

<0.3

62

0.

243

2

290.

869

<0.0

64

41.

5 C

307

ap

02a0

4

p

y

<

1.15

9

58

1.39

1

n.a.

0

.355

1165

.976

0.2

39

0

.207

1947

.808

3.4

73

21

.7

C30

7

ap02

a05

py

<1.

595

9.39

7

n.

a.

0.4

99

19

.515

0.10

5

0.

402

5

87.4

65

0.35

0

21

.7

C30

7

ap02

a06

py

<4.

515

1.09

3

n.

a.

<0.

729

4.

398

<0.2

30

<0

.232

12

5.57

1

0.49

2

15

.8

C30

7

ap02

a07

py

<1.

265

<0.1

35

n.

a.

0.2

66

0.

221

<0.1

00

<0

.053

0.

468

<0.0

25

41.

5 C

307

ap

02a0

8

p

y

<

1.36

1

<0

.110

n.a.

0

.218

<0.1

55

<0.

111

<

0.04

9

<0.1

18

<0

.019

4

1.5

C30

7

ap02

a09

py

4.4

03

6.43

2

n.

a.

0.3

02

19

.466

1.05

9

0.

218

1

493.

951

3.20

9

41

.5

C30

7

ap02

a14

py

<3.

758

<0.4

13

n.

a.

<0.

670

<0

.435

0

.328

<0.

234

<0

.640

<0.0

85

44.

5 C

307

ap

02a1

5

p

y

<

4.05

5

1.

189

n.a.

<

0.73

0

1.36

9

<0

.276

<0.1

87

133.

842

1.

375

24.7

C

307

ap

02a1

8

p

y

<

4.06

9

<0

.396

n.a.

<

0.68

2

<0.5

50

<0.

234

<

0.31

7

<0.5

51

<0

.066

1

8.8

C30

7

ap02

a10

sp

<4.

528

53.4

05

n.

a.

1.5

13

37

.995

<0.3

61

0.

977

8

55.0

26

0.85

7

44

.5

C30

7

ap02

a11

sp

19.

010

65.3

23

n.

a.

3.1

06

59

.912

<0.1

17

1.

104

4

054.

317

6.58

9

42

.5

C30

7

ap02

a13

sp

<0.

864

40.0

22

n.

a.

1.0

91

33

.600

0.09

1

0.

250

4

32.3

07

<0.0

18

41.

5 C

317

ap

17f0

3

c

py

<6

.282

33.5

00

n.

a.

2.8

32

10

.510

<0.2

91

0.

728

5

.259

<0.

060

42

.5

C31

7

ap17

f11

cpy

<15.

397

16

.679

n.a.

2

.703

2.96

4

<0

.643

<0.3

97

2.77

8

<0

.211

4

4.5

C31

7

ap17

f16

cpy

<3.1

08

15

.291

n.a.

2

.729

6.53

3

<0

.115

<0.1

06

1.66

8

<0

.041

4

3.5

C31

7

ap17

f05

py

<1.

529

<0.1

65

n.

a.

0.2

25

0.

292

<0.0

86

<0

.047

0.

608

<0.0

15

44.

5 C

317

ap

17f0

6

p

y

<

1.51

9

1.

856

n.a.

<

0.29

8

2.88

9

<0

.054

<0.0

47

360.

755

<0

.015

1

9.8

C31

7

ap17

f09

py

14.

362

0.64

9

n.

a.

<0.

307

3.

823

<0.1

46

<0

.058

40

.445

<0.0

26

10.

9 C

317

ap

17f1

0

p

y

<

1.72

6

<0

.168

n.a.

0

.251

<0.2

17

<0.

058

<

0.03

4

<0.5

37

<0

.018

2

2.7

C31

7

ap17

f13

py

10.

279

0.74

2

n.

a.

<0.

760

11

.923

<0.2

37

0.

254

5

9.14

0

0.1

79

11

.9

C31

7

ap17

f14

py

<4.

834

<0.4

72

n.

a.

<0.

657

<1

.009

<

0.33

7

<0.

093

1.

885

<0.0

47

43.

5 C

317

ap

17f1

5

p

y

<

3.93

9

<0

.719

n.a.

<

0.73

3

<1.1

06

<0.

442

<

0.14

6

<0.3

82

<0

.069

1

9.8

C31

7

ap17

f04

sp

<7.

747

9.29

0

n.

a.

1.3

88

2.

027

<0.2

85

<0

.147

4.

230

<0.0

40

38.

6 C

317

ap

17f0

7

s

p

8

.103

11

.726

n.a.

1

.427

12.9

70

0.

329

<0.1

50

6.39

6

<0

.079

4

0.5

C32

0

ap17

a03

py

<3.

092

39.6

69

n.

a.

0.2

14

<0

.314

<

0.08

7

<0.

056

12

20.0

00

8

49.6

85

44.5

C

320

ap

17a0

5

p

y

<

3.35

2

2.

620

n.a.

<

0.27

1

<0.3

84

<0.

095

<

0.04

5

196.

021

12

.302

3

7.6

C32

0

ap17

a06

py

<4.

600

4.07

9

n.

a.

<0.

445

7.

710

0.68

6

<0

.074

13

5.69

7

32.9

77

11.

9 C

320

ap

17a0

7

p

y

<

3.16

7

<0

.247

n.a.

<

0.36

0

<0.3

93

<0.

073

<

0.05

1

6.93

7

4.

264

29.7

sam

ple

r

un/p

oint

type

M

o (p

pm)

Ag

(ppm

)

Cd

(ppm

)

Sn

(ppm

)

Sb

(ppm

)

Au

(ppm

)

Tl (

ppm

)

Pb

(ppm

)

B

i (pp

m)

P

eak

(s)

74

Appendix 5: LA-ICP-MS Analysis—Sulphides

C32

0

ap17

a08

py

5.0

30

0.34

9

n.

a.

<0.

278

1

.043

0.08

0

<0

.056

39

.801

8.48

8

41.

5 C

320

ap

17a0

9

p

y

<

9.06

9

0.

733

n.a.

<

0.55

5

4.5

06

0.

836

<0.0

95

34.4

74

12

.721

4

3.5

C32

0

ap17

a10

py

32.

338

<0.5

61

n.a

.

<

0.63

2

<0.

854

<0

.197

<

0.10

8

18.6

73

5.

513

4

3.5

C32

0

ap17

a11

py

<6.

086

<0.4

62

n.a

.

<

0.47

1

1.8

46

0.

257

<0.0

93

15.8

15

4.

734

4

4.5

C32

3

ap17

d03

cpy

<4.0

61

37

2.63

4

n

.a.

21.

028

3

.256

<0.1

35

<0.

078

2.

308

2.40

8

44.

5 C

323

ap

17d0

5

p

y

<

1.63

8

0.

275

n.a.

0

.233

0.4

90

<0

.076

<

0.03

5

20.2

57

10

.418

4

2.5

C32

3

ap17

d06

py

1.8

01

0.69

4

n.

a.

<0.

200

1

.082

0.07

9

<0

.035

56

.728

11.9

46

44.

5 C

323

ap

17d0

8

p

y

<

1.45

1

0.

266

n.a.

0

.197

1.8

17

<0

.069

<

0.04

1

29.9

69

3.

612

4

4.5

C32

3

ap17

d09

py

<1.

627

0.22

5

n.

a.

<0.

171

<

0.26

2

<0.0

61

<0.

041

41

.750

7.38

7

43.

5 C

323

ap

17d1

0

p

y

<

2.40

3

<0

.228

n

.a.

<0.

292

<

0.30

1

<0.1

07

<0.

063

19

.224

3.23

6

11.

9 C

323

ap

17d0

4

s

p

<

6.82

4

2.

113

n.a.

1

.391

<1.

215

<0

.258

<

0.15

2

1.79

5

0.

575

4

0.5

C32

3

ap17

d07

sp

<6.

571

9.50

6

n.

a.

0.9

57

4

.167

<0.2

69

<0.

141

96

.370

9.61

9

44.

5 C

326

ap

17e0

3

p

y

<

1.37

2

26

.642

n

.a.

0.2

10

3

81.0

86

6.25

5

1.

228

4

74.9

58

<0.0

14

42.5

C

326

ap

17e0

6

p

y

<

2.63

1

6.

672

n.a.

0

.451

50.

229

0.

747

1.26

3

95.

731

<

0.02

4

32.6

C

326

ap

17e0

8

p

y

<

2.09

3

10

32.3

47

n

.a.

0.2

37

1

4.74

6

<0.0

61

0.0

46

17

9.97

6

<0.0

23

46.5

C

326

ap

17e1

0

p

y

1

8.65

1

48

.017

n

.a.

<0.

666

3

2.98

3

1.47

0

0.

170

1

347.

748

<0.0

48

40.5

C

326

ap

17e1

1

p

y

<

5.33

0

0.

615

n.a.

<

0.68

5

2.4

67

0.

341

0.37

7

15.

820

<

0.04

8

37.6

C

326

ap

17e0

5

s

p

5

5.90

4

18

.686

n

.a.

1.2

24

1

9.03

7

0.37

0

<0

.146

15

.771

<0.0

55

41.5

C

326

ap

17e0

7

s

p

<

7.00

9

11

.049

n

.a.

1.2

32

1

1.23

5

<0.2

90

<0.

191

6.

443

<0.0

84

41.5

C

329a

ap1

0e03

cp

y

<5

.731

288.

945

n.a

.

8

3.26

3

16.

230

<0

.322

<

0.17

4

4.31

5

<0

.084

44

.5

C32

9a

a

p10e

05

cpy

<7.5

70

16

9.45

9

n

.a.

63.

669

3

.091

<0.3

69

<0.

202

6.

945

<0.0

86

10.9

C

329a

fb1

3a13

cp

y

<5

.032

31.9

66

<6.

788

1

49.6

37

14.3

11

n.a

.

<

0.33

3

62.2

66

<0

.113

38

.9

C32

9a

f

b13a

14

cpy

<17.

375

23

.531

<

25.6

17

50.5

91

43.

369

n.

a.

<1.

430

11

35.7

50

<

0.28

0

10.6

C

329a

ap1

0e06

py

<2

.289

0.79

1

n.

a.

0.3

15

5

.385

0.17

9

<0

.060

15

9.41

1

<0.0

20

39.5

C

329a

ap1

0e08

py

<2

.001

3.98

2

n.

a.

0.6

37

3

5.70

9

0.76

3

<0

.051

18

8.42

8

<0.0

28

40.5

C

329a

ap1

0e09

py

<6

.979

3.31

1

n.

a.

<0.

551

8

.461

0.61

2

0.

500

7

32.1

69

<0.0

82

42.5

C

329a

ap1

0e12

py

<6

.498

59.7

54

n.a

.

3

.686

135

.547

17

.943

<0.1

74

1564

.159

<0.

070

21

.7

C32

9a

f

b13a

12

py

<4.5

75

<0

.663

<

6.51

8

<0.

446

<

1.29

4

n.a.

<

0.34

3

1.01

1

<0

.080

38

.9

C32

9a

a

p10e

04

sp

<6.7

34

12

.088

n

.a.

2.2

31

1

6.30

6

<0.2

91

<0.

209

62

.020

<0.0

84

33.6

C

329a

ap1

0e07

sp

<5

.976

4.88

5

n.

a.

1.7

96

4

.471

<0.3

08

<0.

181

4.

658

<0.1

02

31.6

C

329b

ap0

6c15

py

<3

.942

7.45

2

n.

a.

<0.

587

1

33.9

95

24.9

85

<0

.238

79

0.27

9

<0.0

59

18.8

C

329b

ap0

6c17

py

<5

.076

<0.5

21

n.a

.

<

0.75

1

<0.

763

<0

.329

<

0.22

3

<0.4

64

<0

.056

26

.7

C32

9b

f

b13a

10

py

<4.4

00

4.

426

<7.8

64

<0.

493

2

2.04

1

n.a.

<

0.35

6

199.

442

<0

.085

28

.3

C32

9b

f

b13a

11

py

<5.0

27

8.

465

<7.9

20

<0.

586

5

5.37

4

n.a.

<

0.42

7

515.

427

<0

.073

29

.2

C32

9b

a

p06c

13

sp

<5.3

11

3.

686

n.a.

1

.805

1.6

86

<0

.413

<

0.28

7

2.33

6

<0

.084

34

.6

C32

9b

a

p06c

18

sp

<10.

063

7.

302

n.a.

1

.767

9.2

61

<0

.736

<

0.30

7

17.6

26

<0

.097

12

.9

C32

9b

a

p06c

14

tet

<8.7

75

n.

a.

n.a

.

2

.133

n.a

.

<

0.42

1

<0.

377

14

.220

0.86

5

19.

8 C

333

ap

10b1

1

p

y

<

1.49

5

<0

.148

n

.a.

<0.

171

0

.563

<0.0

62

<0.

057

4.

947

0.86

4

43.

5

sam

ple

r

un/p

oint

typ

e

Mo

(ppm

)

A

g (p

pm)

C

d (p

pm)

S

n (p

pm)

S

b (p

pm)

A

u (p

pm)

T

l (pp

m)

P

b (p

pm)

B

i (pp

m)

P

eak

(s)

75

Appendix 5: LA-ICP-MS Analysis—Sulphides

C33

3

ap10

b12

py

<1.

514

5.43

3

n.

a.

0.2

60

0

.511

<0.1

07

0.0

65

48

4.63

2

11.7

68

35.

6 C

333

ap

10b1

4

p

y

<

2.08

6

<0

.270

n

.a.

0.4

98

<

0.31

9

<0.1

34

<0.

058

5.

653

0.35

2

42.

5 C

333

ap

10b1

5

p

y

<

3.49

0

<0

.385

n

.a.

<0.

458

<

0.63

2

<0.2

23

<0.

158

8.

645

11.6

34

10.

9 C

333

ap

10b1

7

p

y

<

3.56

6

0.

487

n.a.

<

0.55

2

6.8

14

<0

.370

<

0.15

7

139.

210

0.

264

3

8.6

C33

3

ap10

b18

py

<1.

551

<0.2

29

n.a

.

0

.201

0.6

39

<0

.094

0

.118

2.64

0

1.

506

2

1.7

C33

3

ap10

b13

sp

<6.

001

2.31

4

n.

a.

0.8

27

<

0.83

0

<0.3

86

<0.

151

0.

689

0.30

6

41.

5 C

333

ap

10b1

6

s

p

<

4.98

9

7.

863

n.a.

1

.154

4.4

96

<0

.421

<

0.20

2

14.2

90

4.

030

3

8.6

C33

7

ap17

b11

py

<8.

123

<0.4

22

n.a

.

<

0.48

0

<0.

677

<0

.191

<

0.11

2

<0.5

64

<0

.035

42

.5

C33

7

ap17

b13

py

64.

033

<0.1

84

n.a

.

<

0.28

1

<0.

174

<0

.078

<

0.03

4

0.45

4

<0

.012

43

.5

C33

7

ap17

b15

py

<4.

815

308.

137

n.a

.

4

3.99

8

2.5

29

0.

400

<0.0

64

23.1

66

<0

.017

39

.5

C33

7

ap17

b17

py

<12

.371

<

0.56

9

n.a

.

<

0.84

0

<1.

404

<0

.265

<

0.13

1

0.95

3

<0

.071

21

.7

C33

7

ap17

b18

py

35.

395

<0.7

28

n.a

.

<

0.71

2

<1.

141

<0

.198

<

0.13

4

<0.5

46

<0

.070

18

.8

C33

7

ap17

b12

sp

<10

.567

1

2.20

1

n.a

.

1

.799

12.

233

<0

.183

<

0.08

6

7.14

5

<0

.053

33

.6

C33

7

ap17

b14

sp

<11

.441

4

0.11

3

n.a

.

4

.005

87.

323

<0

.341

0

.596

1002

.152

0.3

61

25

.7

C34

1

ap10

f15

py

<1

.426

24.0

54

n.a

.

0

.176

165

.932

24

1.54

4

3.33

6

316

.451

0.

060

4

0.5

C34

1

ap10

f16

py

<2

.066

13.9

27

n.a

.

0

.262

73.

914

30

1.02

0

4.87

1

335

9.13

9

1.

076

3

6.6

C34

1

ap10

f17

py

<3

.668

27.2

31

n.a

.

0

.508

143

.762

45

.425

0.32

5

129

2.66

7

0.

441

4

0.5

C34

1

fb13

a06

py

26

4.63

2

102.

250

<2.

822

<

0.27

6

26.

706

n.

a.

7.8

71

72

4.50

0

0.14

9

39.

8 C

341

fb

13a0

7

py

<3.7

97

23

.723

<

6.84

7

<0.

429

1

24.9

30

n.a.

0

.784

107.

113

<0

.082

40

.7

C34

1

ap10

e13

sp

9.5

94

6.62

2

n.

a.

1.5

10

1

.864

<0.2

79

<0.

161

9.

664

<0.0

85

35.6

C

341

ap

10e1

6

s

p

1

1.20

1

17

.406

n

.a.

1.9

18

1

5.92

3

<0.6

41

<0.

254

68

.600

<0.0

97

14.8

C

341

ap

10e1

8

s

p

<

7.39

8

5.

681

n.a.

1

.378

2.8

71

<0

.312

<

0.22

1

6.47

7

<0

.132

38

.6

C34

1

ap10

e14

tet

<1

1.34

7

n.a.

n

.a.

1.4

28

n

.a.

<0.

495

<

0.31

3

1.20

8

17

.470

2

3.7

C34

1

ap10

e15

tet

<1

0.49

9

n.a.

n

.a.

1.4

10

n

.a.

<0.

305

<

0.37

1

1.07

5

17

.706

3

8.6

C34

1

ap10

e17

tet

<1

0.02

9

n.a.

n

.a.

1.6

57

n

.a.

<0.

359

<

0.21

9

1.25

5

22

.697

3

4.6

C34

3

ap06

c03

py

23.

613

1.04

6

n.

a.

0.2

12

2

.148

0.20

8

0.

176

9

6.24

0

53.

516

45

.5

C34

3

ap06

c05

py

<4.

611

2.17

4

n.

a.

<0.

784

2

8.29

4

3.90

0

<0

.202

22

8.79

1

1.35

6

21.

7 C

343

ap

06c0

9

p

y

<

1.39

7

1.

615

n.a.

0

.237

0.8

18

<0

.088

<

0.08

5

249.

785

80

.486

3

9.5

C34

3

ap06

c10

py

<1.

382

6.65

8

n.

a.

0.2

40

2

.786

0.15

6

<0

.073

12

30.2

01

6

3.71

7

35.6

C

343

ap

06c1

1

p

y

<

1.62

4

0.

160

n.a.

0

.295

0.3

19

<0

.097

<

0.07

7

87.7

39

17

.965

3

5.6

C34

3

ap06

c04

sp

<6.

099

13.6

72

n.a

.

1

.722

1.7

11

2.

698

<0.2

62

5.52

8

1.

231

4

2.5

C34

3

ap06

c06

sp

<6.

432

26.5

25

n.a

.

1

.162

5.3

34

2.

309

<0.3

38

14.5

95

8.

669

1

6.8

C34

3

ap06

c12

sp

<7.

930

30.7

88

n.a

.

1

.427

10.

497

<0

.440

<

0.38

6

40.1

34

12

.885

1

3.8

C34

5

ap06

d14

py

<2.

586

<0.2

14

n.a

.

<

0.36

0

<0.

346

<0

.162

<

0.09

5

0.96

4

<0

.031

12

.9

C34

5

ap06

d15

py

8.2

28

1.50

5

n.

a.

1.0

15

4

5.09

2

<0.4

46

1.1

34

5.

264

<0.0

86

22.7

C

345

ap

06d1

6

p

y

<

5.10

0

1.

450

n.a.

<

0.56

4

3.3

88

<0

.312

0

.301

62.4

98

<0

.064

38

.6

C34

5

ap06

d18

py

<5.

140

4.11

8

n.

a.

<0.

646

3

2.43

4

0.74

0

1.

754

2

8.20

4

<0.

058

34

.6

C34

5

ap06

f15

py

<7

.641

1.23

6

n.

a.

<0.

680

5

.494

<0.3

16

<0.

192

58

7.13

0

<0.0

87

46.5

sam

ple

r

un/p

oint

typ

e

Mo

(ppm

)

A

g (p

pm)

C

d (p

pm)

S

n (p

pm)

S

b (p

pm)

A

u (p

pm)

T

l (pp

m)

P

b (p

pm)

B

i (pp

m)

P

eak

(s)

76

Appendix 5: LA-ICP-MS Analysis—Sulphides

C34

5

fb13

a08

py

56

.128

<0.5

55

<3.

161

<

0.36

7

<1.

057

n.

a.

<0.

266

35

.289

<0.0

53

36.3

C

345

fb

13a0

9

py

<2.0

70

<0

.394

<

2.90

5

0.2

78

2

.620

n.a.

<

0.23

8

4.19

3

<0

.041

39

.8

C34

5

ap06

f14

sp

<6

.877

23.3

22

n.a

.

3

.025

53.

537

<0

.379

0

.682

1358

4.18

6

0.1

11

42

.5

C34

5

ap06

f16

sp

<6

.546

19.3

00

n.a

.

3

.339

37.

430

<0

.298

0

.214

161.

454

<0

.080

35

.6

C34

5

ap06

f17

sp

<7

.068

25.3

09

n.a

.

3

.481

53.

766

0.

309

<0.2

97

131.

551

<0

.046

34

.6

C34

5

ap06

f18

te

t

<2

2.13

8

n.a.

n

.a.

213

.676

n.

a.

14.5

03

6.

318

4

05.2

59

<0.2

76

11.9

C

350

ap

03d0

3

p

y

<

1.25

7

2.

391

n.a.

2

.477

2.6

32

0.

178

<0.1

00

28.5

24

31

.979

4

4.5

C35

0

ap03

d04

py

<1.

190

0.25

7

n.

a.

<0.

269

<

0.20

7

<0.1

76

<0.

095

11

.167

1.17

3

41.

5 C

350

ap

03d0

6

p

y

<

1.80

6

33

.966

n

.a.

0.4

31

1

0.57

6

0.17

7

0.

613

1

830.

742

68.1

09

44.

5 C

350

ap

03d0

7

p

y

<

3.86

8

15

.637

n

.a.

1.4

62

9

.100

0.98

1

<0

.211

12

04.6

02

1

80.0

56

37.6

C

350

ap

03d0

8

p

y

<

1.32

4

29

.014

n

.a.

0.9

21

9

.960

1.07

5

<0

.084

23

29.3

43

2

20.7

61

46.5

C

350

ap

03d0

9

p

y

<

1.14

3

0.

465

n.a.

<

0.36

0

0.3

30

<0

.117

<

0.09

3

25.9

82

59

.548

4

4.5

C35

3

ap06

f03

py

28

.638

4.92

0

n.

a.

0.5

77

1

0.01

3

0.17

4

0.

082

1

140.

293

8.59

9

28.

7 C

353

ap

06f0

5

py

<5.5

40

0.

678

n.a.

<

0.71

0

5.2

31

<0

.288

<

0.19

6

159.

093

0.

274

4

4.5

C35

3

ap06

f07

py

<7

.861

1.90

9

n.

a.

<0.

941

6

.439

<0.4

44

<0.

285

39

1.93

6

2.33

0

10.

9 C

353

ap

06f0

8

py

<8.0

60

<0

.685

n

.a.

<0.

849

<

0.88

1

<0.3

52

<0.

264

50

.052

<0.1

06

10.9

C

353

ap

06f1

0

py

25.4

40

24

.593

n

.a.

<0.

944

1

22.7

50

1.93

6

20

.707

17

63.0

85

5

.548

32.6

C

353

ap

06f1

2

py

<9.0

53

3.

061

n.a.

<

0.84

8

8.4

43

<0

.353

<

0.20

2

863.

954

1.

271

1

2.9

C35

3

ap06

f13

py

<9

.277

2.79

8

n.

a.

<0.

723

1

3.12

2

0.65

2

<0

.247

67

.714

0.87

5

19.

8 C

353

ap

06f0

4

sp

<4.9

01

7.

012

n.a.

1

.831

4.3

73

<0

.267

<

0.24

8

2.08

5

<0

.054

22

.7

C35

3

ap06

f06

sp

<8

.681

17.9

93

n.a

.

1

.894

27.

440

<0

.376

<

0.26

3

819.

322

1.

264

4

2.5

C35

3

ap06

f11

sp

<6

.213

6.67

7

n.

a.

1.3

66

1

.473

<0.2

37

<0.

198

2.

609

<0.0

58

43.5

C

355

ap

17a1

7

c

py

<2

1.18

5

237.

632

n.a

.

1

4.62

5

3.4

16

<1

.064

<

0.29

3

2.67

6

0.

365

4

5.5

C35

5

ap17

d12

cpy

<15.

706

31

9.92

9

n

.a.

16.

468

1

5.07

7

<0.8

60

0.6

32

7.

942

0.73

5

41.

5 C

355

ap

17a1

2

p

y

1

0.62

4

38

.600

n

.a.

3.5

88

5

1.80

5

3.91

7

0.

749

7

70.1

35

8.61

7

20.

8 C

355

ap

17a1

5

p

y

<

2.26

4

0.

615

n.a.

<

0.23

9

0.9

41

<0

.074

0

.102

34.1

78

5.

890

3

7.6

C35

5

ap17

a16

py

<10

.285

<

0.48

8

n.a

.

<

0.53

1

<0.

801

<0

.190

<

0.11

0

0.57

1

0.

300

4

2.5

C35

5

ap17

d11

py

9.7

62

0.57

6

n.

a.

<0.

447

2

.340

<0.2

14

<0.

088

37

.559

12.0

34

38.

6 C

355

ap

17d1

3

p

y

<

9.09

2

25

.837

n

.a.

<0.

500

1

8.16

8

0.31

5

0.

625

3

969.

216

69.6

89

12.

9 C

355

ap

17d1

5

p

y

1

1.78

6

0.

998

n.a.

0

.391

8.6

16

0.

257

0.12

5

95.

790

6

.958

38.6

C

355

ap

17a1

8

s

p

<

8.18

4

2.

052

n.a.

1

.102

<0.

961

<0

.476

<

0.16

4

0.93

8

0.

064

4

1.5

C35

5

ap17

d14

sp

<7.

173

14.0

99

n.a

.

1

.582

6.0

82

<0

.321

<

0.23

0

54.6

85

1.

096

3

9.5

C35

7

ap06

e04

py

<1.

438

0.29

9

n.

a.

0.2

23

<

0.28

8

<0.0

92

<0.

066

13

.062

8.88

8

40.

5 C

357

ap

06e0

6

p

y

<

4.48

4

<0

.499

n

.a.

<0.

507

<

0.46

7

<0.3

38

<0.

159

0.

336

0.12

4

43.

5 C

357

ap

06e0

7

p

y

<

7.33

3

<0

.460

n

.a.

<0.

635

<

0.85

2

<0.2

36

<0.

227

7.

959

12.8

62

13.

8 C

357

ap

06e0

8

p

y

2

2.85

8

1.

461

n.a.

<

0.43

6

5.7

38

0.

663

1.01

3

67.

793

6

.870

41.5

C

357

ap

06e1

0

p

y

<

6.07

5

<0

.508

n

.a.

<0.

545

0

.708

<0.3

36

<0.

168

10

.422

7.44

8

37.

6 C

357

ap

06e0

3

s

p

<

7.89

6

11

.995

n

.a.

1.6

13

6

.386

<0.3

55

<0.

366

12

3.10

0

4.02

3

22.

7

sam

ple

r

un/p

oint

typ

e

Mo

(ppm

)

A

g (p

pm)

C

d (p

pm)

S

n (p

pm)

S

b (p

pm)

A

u (p

pm)

T

l (pp

m)

P

b (p

pm)

B

i (pp

m)

P

eak

(s)

77

Appendix 5: LA-ICP-MS Analysis—Sulphides

C35

7

ap06

e09

sp

<7.

562

8.79

5

n.

a.

1.7

24

5

.322

<0.3

13

0.7

73

36

7.12

9

5.60

2

32.

6 C

359

ap

10d1

2

c

py

<4

.745

199.

430

n.a

.

8

8.24

3

22.

845

<0

.160

0

.280

20.6

88

0.

972

2

8.7

C35

9

ap10

d10

py

<5.

048

0.90

1

n.

a.

<0.

610

2

.505

0.36

0

0.

242

3

.872

0.1

50

34

.6

C35

9

ap10

d13

py

<5.

084

<0.5

84

n.a

.

<

0.64

0

<1.

079

<0

.411

<

0.20

8

0.87

8

<0

.096

14

.8

C35

9

ap10

d16

py

<5.

877

<0.6

62

n.a

.

0

.599

<0.

849

<0

.253

<

0.17

1

0.53

6

<0

.083

35

.6

C35

9

ap10

d17

py

<4.

874

<0.5

80

n.a

.

<

0.78

4

1.9

97

<0

.254

0

.296

5.14

8

0.

155

1

8.8

C35

9

ap10

d18

py

<2.

442

8.16

6

n.

a.

0.4

61

1

4.11

3

0.19

9

0.

911

3

119.

791

19.0

73

18.

8 C

359

ap

10d1

1

s

p

<

5.36

9

60

.079

n

.a.

2.5

27

2

5.14

7

<0.3

11

0.6

17

56

.657

0.33

6

40.

5 C

359

ap

10d1

4

s

p

<

6.02

2

52

.207

n

.a.

5.2

76

2

7.35

4

<0.4

62

0.9

53

39

89.5

60

1

8.65

4

36.6

C

359

ap

10d1

5

s

p

<

7.19

7

35

.203

n

.a.

2.5

45

1

3.52

1

<0.4

35

0.2

58

32

.312

0.16

2

29.

7 C

362

ap

06a0

4

p

y

<

6.56

5

<0

.602

n

.a.

<0.

672

<

0.92

6

<0.3

71

<0.

314

<0

.213

<0.0

65

40.5

C

362

ap

06a0

6

p

y

<

5.52

0

54

.268

n

.a.

<0.

899

5

2.25

5

1.21

2

3.

960

4

45.4

69

<0.1

06

12.9

C

362

ap

06a0

9

p

y

<

5.24

1

<0

.621

n

.a.

<0.

694

<

0.85

0

<0.3

56

<0.

251

<0

.287

<0.0

72

43.5

C

362

ap

06a1

0

p

y

<

4.66

2

<0

.549

n

.a.

<0.

740

<

0.96

6

<0.3

34

<0.

323

<0

.269

<0.0

70

40.5

C

362

ap

06a1

4

p

y

<

4.65

9

22

.063

n

.a.

<0.

563

1

5.37

5

0.92

4

0.

511

2

16.6

83

<0.0

64

37.6

C

362

ap

06a1

5

p

y

<

6.39

6

<0

.585

n

.a.

<0.

715

<

0.91

9

<0.4

19

<0.

353

13

.523

<0.1

06

45.5

C

362

ap

06a1

7

p

y

<

5.38

2

<0

.515

n

.a.

<0.

679

1

.284

<0.3

31

<0.

265

7.

611

<0.0

73

44.5

C

362

ap

06a0

3

s

p

<

4.47

4

1.

610

n.a.

1

.400

<0.

908

<0

.366

<

0.34

8

1.22

4

<0

.094

37

.6

C36

2

ap06

a05

sp

<5.

296

4.89

8

n.

a.

1.3

36

5

.673

<0.3

90

<0.

363

3.

415

<0.0

98

37.6

C

362

ap

06a1

1

s

p

<

6.74

2

6.

686

n.a.

1

.564

5.2

38

<0

.219

<

0.35

8

4.28

5

<0

.108

38

.6

C36

2

ap06

a12

sp

<6.

008

4.84

7

n.

a.

1.2

46

1

.574

<0.3

91

<0.

312

3.

788

<0.0

94

41.5

C

362

ap

06a1

3

s

p

<

6.42

4

5.

968

n.a.

1

.140

16.

455

<0

.487

<

0.42

4

52.0

74

<0

.065

21

.7

C36

2

ap06

a16

sp

<6.

356

10.8

20

n.a

.

1

.421

11.

401

<0

.438

<

0.38

7

9.09

8

<0

.137

41

.5

C36

4

ap10

c06

apy

<8.8

66

4.

225

n.a.

<

1.74

6

32.

605

1.

659

2.05

6

59.

490

2

8.33

1

44.5

C

364

ap

10c1

1

c

py

<4

.332

248.

282

n.a

.

1

039.

945

21.8

73

<0.

351

1

.316

9.78

3

3.

879

4

0.5

C36

4

ap10

c13

cpy

<4.2

11

30

7.69

7

n

.a.

117

4.56

8

39

.997

<

0.22

3

19.

949

51

51.1

81

1

49.9

08

40.5

C

364

ap

10c0

3

p

y

5

.854

<0

.531

n

.a.

<0.

560

<

0.65

1

<0.3

07

<0.

167

1.

717

0.08

6

30.

6 C

364

ap

10c0

5

p

y

8

4.65

7

<0

.779

n

.a.

<0.

886

1

.154

<0.4

26

0.3

99

13

.403

0.60

3

10.

9 C

364

ap

10c0

8

p

y

<

4.86

9

10

.672

n

.a.

<0.

649

1

0.97

9

<0.5

16

3.8

16

83

6.12

6

28.6

88

17.

8 C

364

ap

10c1

2

p

y

<

4.05

0

<0

.668

n

.a.

<0.

632

<

0.95

4

0.44

7

0.

450

3

2.35

2

0.9

96

42

.5

C36

4

ap10

c14

py

<4.

421

3.27

7

n.

a.

<0.

754

5

.877

5.10

8

0.

906

3

22.1

33

12.9

87

38.

6 C

364

ap

10c1

5

p

y

<

3.35

8

2.

514

n.a.

<

0.41

2

4.1

72

0.

870

2.21

9

21.

945

1

.980

26.7

C

364

ap

10c1

7

p

y

<

5.66

4

16

.466

n

.a.

<0.

641

5

1.42

7

18.1

95

27

.037

44

7.95

5

19.9

61

16.

8 C

364

ap

10c1

8

p

y

2

.951

<0

.247

n

.a.

0.3

09

<

0.29

3

<0.1

71

<0.

088

0.

955

0.04

9

39.

5 C

364

ap

10c0

4

s

p

<

4.01

4

14

.443

n

.a.

1.6

51

<

0.75

6

<0.3

26

<0.

149

2.

957

0.36

5

43.

5 C

364

ap

10c0

9

s

p

<

4.13

1

16

.748

n

.a.

2.2

43

1

.204

<0.3

63

<0.

169

4.

116

0.69

1

42.

5 C

364

ap

10c1

0

s

p

<

4.91

0

22

.172

n

.a.

2.4

87

1

.763

<0.3

42

0.4

03

15

.109

1.68

7

44.

5 C

365

ap

03b0

3

p

y

<

1.10

9

19

.639

n

.a.

5.8

83

2

88.9

56

1.71

5

0.

290

2

763.

382

0.76

5

41.

5

sam

ple

r

un/p

oint

typ

e

Mo

(ppm

)

A

g (p

pm)

C

d (p

pm)

S

n (p

pm)

S

b (p

pm)

A

u (p

pm)

T

l (pp

m)

P

b (p

pm)

B

i (pp

m)

P

eak

(s)

78

Appendix 5: LA-ICP-MS Analysis—Sulphides

C36

5

ap03

b09

py

8.7

84

<0.4

48

n.a

.

<

0.91

3

2.6

88

<0

.478

<

0.37

2

3.31

7

<0

.092

12

.9

C36

5

ap03

b11

py

13.

949

10.1

83

n.a

.

<

0.65

5

56.

911

2.

385

105.

544

995.

290

0.

232

3

5.6

C36

5

ap03

b12

py

<4.

553

<0.4

31

n.a

.

<

0.77

5

2.5

34

0.

334

<0.3

00

16.5

56

<0

.099

42

.5

C36

5

ap03

b13

py

7.2

49

0.84

6

n.

a.

<1.

062

1

.740

<0.5

01

<0.

291

25

7.97

9

<0.1

08

30.6

C

365

ap

03b1

6

p

y

<

4.91

3

0.

872

n.a.

<

0.80

5

28.

878

0.

775

43.1

64

46.8

80

<0

.096

28

.7

C36

5

ap03

b17

py

<4.

116

<0.5

97

n.a

.

<

1.03

2

29.

466

0.

350

50.8

74

167.

084

<0

.094

37

.6

C36

5

ap03

b04

sp

<4.

264

13.6

46

n.a

.

1

.342

7.4

67

<0

.305

<

0.35

2

6.71

4

<0

.084

41

.5

C36

5

ap03

b07

sp

<5.

583

4.55

7

n.

a.

<0.

984

1

.920

<0.3

49

<0.

255

2.

465

<0.1

04

37.6

C

365

ap

03b1

0

s

p

<

6.25

8

5.

741

n.a.

1

.400

<0.

968

<0

.357

<

0.33

5

0.83

9

<0

.110

33

.6

C36

5

ap03

b14

sp

<5.

863

11.2

87

n.a

.

1

.326

13.

038

<0

.454

<

0.39

6

5.65

7

<0

.153

39

.5

C36

5

ap03

b15

sp

<5.

410

20.3

33

n.a

.

<

1.19

4

22.

012

<0

.587

<

0.34

7

7.71

4

<0

.096

36

.6

C36

9

fb13

a05

cp

y

<1

8.54

9

176.

022

<21

.021

2.

854

<5.8

54

n.a

.

<

1.31

7

2.44

5

<0

.256

35

.4

C36

9

ap06

b14

py

<3.

939

32.8

01

n.a

.

<

0.61

2

29.

652

2.

074

0.32

5

60.

516

<

0.05

0

44.5

C

369

ap

06b1

5

p

y

3

5.22

9

<0

.474

n

.a.

<0.

800

2

.250

<0.3

20

<0.

217

10

.992

<0.0

44

34.6

C

369

ap

06b1

6

p

y

3

.240

<0

.393

n

.a.

<0.

406

0

.905

<0.1

68

<0.

209

5.

157

<0.0

56

12.9

C

369

ap

06b1

7

p

y

1

5.64

3

3.

988

n.a.

<

0.72

0

17.

417

<0

.532

<

0.33

1

1307

.505

0.2

46

12

.9

C36

9

fb13

a03

py

2.

994

<0.

389

3

.120

0.2

15

<

1.00

7

n.a.

<

0.16

0

0.88

4

<0

.033

33

.6

C36

9

fb13

a04

py

<7

.224

<1.2

82

<10

.723

<0

.832

<

3.32

4

n.a.

<

0.53

2

<0.5

81

<0

.151

37

.1

C36

9

ap06

b12

sp

<4.

843

3.47

1

n.

a.

1.1

68

0

.971

<0.3

76

<0.

317

1.

276

<0.0

81

43.5

C

369

ap

06b1

3

s

p

<

6.51

3

9.

622

n.a.

1

.320

9.5

03

<0

.334

<

0.30

7

4.37

6

<0

.086

43

.5

C37

2

ap02

b03

apy

11.8

16

8.

172

n.a.

2

.098

811

.276

1.

106

12.6

58

1161

.450

1.0

22

19

.8

C37

2

ap02

b05

apy

<8.9

40

1.

684

n.a.

<

1.36

9

337

6.43

5

<0

.733

0

.517

145.

837

0.

278

4

5.5

C37

2

ap02

b12

apy

180.

715

11

.421

n

.a.

<1.

244

1

981.

297

1.73

3

1.

747

4

77.2

59

0.80

8

47.

4 C

372

ap

02b0

4

p

y

<

1.06

1

0.

482

n.a.

0

.232

3.9

21

<0

.073

0

.343

17.1

22

0.

046

4

2.5

C37

2

ap02

b06

py

<1.

516

0.62

1

n.

a.

0.2

58

7

.041

<0.1

19

0.1

03

31

.084

0.06

6

45.

5 C

372

ap

02b0

7

p

y

5

48.1

85

23.

861

n

.a.

0.9

94

5

89.1

45

0.97

8

10

24.3

60

64

0.24

7

1.19

9

43.

5 C

372

ap

02b0

8

p

y

3

0.10

2

14

.184

n

.a.

0.4

78

3

49.1

96

0.36

7

83

1.34

4

39

2.23

5

0.50

4

43.

5 C

372

ap

02b0

9

p

y

<

1.53

4

4.

326

n.a.

0

.283

17.

875

<0

.103

0

.266

738.

664

0.

512

4

2.5

C37

2

ap02

b10

py

<1.

803

4.06

3

n.

a.

0.4

76

2

6.85

6

0.11

9

1.

510

1

33.7

14

0.17

7

25.

7 C

372

ap

02b1

1

p

y

5

2.68

3

5.

387

n.a.

0

.434

113

.610

0.

151

97.7

09

62.1

22

0.

157

4

2.5

C37

2

ap02

b13

py

27.

675

2.89

0

n.

a.

0.4

14

2

1.00

5

<0.0

83

0.4

66

19

5.52

6

0.43

8

39.

5 C

372

ap

02b1

4

p

y

6

8.38

6

1.

540

n.a.

0

.628

91.

175

<0

.087

0

.566

50.9

11

0.

073

4

3.5

C37

2

ap02

b15

py

895

.092

2

3.74

7

n.a

.

0

.760

615

.068

0.

649

310.

871

1905

.187

2.2

46

47

.4

C37

2

ap02

b16

py

5.3

55

<0.4

41

n.a

.

<

0.60

8

2.0

92

<0

.264

<

0.21

9

2.28

6

<0

.076

44

.5

C37

2

ap02

b17

py

<4.

878

5.97

6

n.

a.

<0.

734

1

9.45

9

<0.2

60

<0.

350

25

08.1

72

1

.193

27.7

C

372

ap

02b1

8

p

y

1

2.39

1

0.

642

n.a.

0

.363

10.

696

<0

.083

0

.185

24.3

01

0.

025

4

0.5

C37

8

ap10

b06

cpy

<13.

628

68

.337

n

.a.

6.0

91

8

.832

<0.8

69

<0.

514

42

59.0

21

<

0.23

7

46.5

C

378

ap

10b0

3

p

y

<

3.50

9

<0

.355

n

.a.

<0.

520

<

0.69

2

<0.3

15

<0.

124

5.

937

<0.0

62

44.5

sam

ple

r

un/p

oint

typ

e

Mo

(ppm

)

A

g (p

pm)

C

d (p

pm)

S

n (p

pm)

S

b (p

pm)

A

u (p

pm)

T

l (pp

m)

P

b (p

pm)

B

i (pp

m)

P

eak

(s)

79

Appendix 5: LA-ICP-MS Analysis—Sulphides

C37

8

ap10

b05

py

<3.

792

<0.4

16

n.a

.

<

0.47

9

<0.

581

<0

.312

<

0.20

0

0.68

3

<0

.072

41

.5

C37

8

ap10

b08

py

<2.

188

<0.2

47

n.a

.

<

0.31

4

<0.

425

<0

.157

<

0.09

1

1.99

5

<0

.036

13

.8

C37

8

ap10

b09

py

<3.

605

<0.4

28

n.a

.

<

0.56

9

<0.

778

<0

.210

<

0.14

0

<0.3

27

<0

.055

37

.6

C37

8

ap10

b10

py

<5.

226

<0.7

01

n.a

.

<

0.52

5

<0.

734

<0

.362

<

0.21

1

1.48

5

<0

.067

25

.7

C37

8

ap10

b07

sp

<4.

959

52.1

15

n.a

.

0

.853

20.

828

1.

789

<0.1

96

10.8

29

<0

.077

26

.7

C37

9

ap03

a03

py

<1.

096

0.14

2

n.

a.

<0.

283

0

.657

0.12

8

<0

.082

9.

290

1.95

0

16.

8 C

379

ap

03a0

6

p

y

<

1.05

3

<0

.093

n

.a.

2.5

80

<

0.11

4

<0.0

82

<0.

068

<0

.120

<0.0

22

43.5

C

379

ap

03a0

7

p

y

<

1.45

7

7.

456

n.a.

<

0.19

0

46.

216

0.

612

0.32

8

504

.605

11

.185

4

1.5

C37

9

ap03

a08

py

<1.

223

<0.1

12

n.a

.

<

0.24

4

0.3

75

<0

.093

<

0.08

8

8.79

4

0.

249

4

2.5

C37

9

ap03

a09

py

<0.

873

<0.1

10

n.a

.

0

.240

<0.

134

<0

.069

<

0.09

1

3.89

5

0.

038

4

2.5

C37

9

ap03

a11

py

<1.

290

<0.1

81

n.a

.

<

0.20

7

<0.

113

0.

167

<0.0

90

0.81

2

0.

171

4

4.5

C37

9

ap03

a12

py

<1.

485

3.88

7

n.

a.

<0.

286

6

.345

0.24

3

<0

.072

16

1.56

0

3.12

8

46.

5 C

379

ap

03a1

7

p

y

<

1.21

9

5.

384

n.a.

<

0.24

6

0.4

76

<0

.132

0

.085

878.

198

21

.087

2

7.7

C37

9

ap03

a18

py

<0.

973

0.13

9

n.

a.

0.2

64

2

.881

<0.0

91

<0.

102

52

.182

<0.0

33

42.5

C

379

ap

03a0

4

s

p

<

2.99

2

2.

498

n.a.

1

.054

0.4

03

<0

.189

<

0.21

6

1.20

9

0.

334

4

2.5

C37

9

ap03

a05

sp

<5.

281

21.1

79

n.a

.

1

.824

18.

521

<0

.313

1

0.81

6

197.

612

18

.030

4

1.5

C37

9

ap03

a10

sp

<7.

987

8.39

4

n.

a.

1.5

33

3

.657

<0.4

82

<0.

473

56

.435

6.75

6

29.

7 C

379

ap

03a1

3

s

p

<

10.4

66

4.8

18

n

.a.

<1.

457

<

1.61

1

<0.6

83

<0.

719

4.

749

3.18

5

38.

6 C

379

ap

03a1

4

s

p

<

9.47

6

1.

939

n.a.

<

1.16

6

<0.

854

<0

.788

<

0.57

3

<0.7

73

<0

.172

36

.6

C37

9

ap03

a15

sp

<12

.655

2

3.68

6

n.a

.

<

1.82

3

32.

526

<0

.821

3

.436

866.

356

31

.502

2

7.7

C37

9

ap03

a16

sp

<4.

623

4.07

0

n.

a.

1.3

45

1

.076

<0.3

09

<0.

417

3.

168

1.86

7

37.

6 C

381

ap

03f1

6

apy

9.51

5

<

0.95

4

n.a

.

<

1.41

4

35.

028

<0

.721

<

0.56

1

0.89

5

<0

.201

46

.5

C38

1

ap03

f03

cp

y

<4

.326

464.

542

n.a

.

8

.546

1.7

04

<0

.253

<

0.24

1

1.04

0

<0

.123

42

.5

C38

1

ap03

f08

cp

y

<1

4.74

9

563.

596

n.a

.

7

.387

8.5

88

<0

.973

<

0.94

5

3.71

3

<0

.227

37

.6

C38

1

ap03

f05

py

31

.058

0.51

3

n.

a.

1.6

47

3

19.2

07

<0.2

84

195

.287

26.

510

0

.073

41.5

C

381

ap

03f0

7

py

10.8

29

2.

301

n.a.

0

.289

44.

117

4.

252

388.

394

33.0

39

<0

.015

41

.5

C38

1

ap03

f09

py

3.

561

1.3

37

n

.a.

<0.

282

2

4.82

1

0.19

0

14

.131

42

.665

0.04

0

43.

5 C

381

ap

03f1

1

py

20.6

98

0.

451

n.a.

0

.553

404

.587

0.

194

211.

898

2.87

9

<0

.022

44

.5

C38

1

ap03

f12

py

18

.993

1.08

7

n.

a.

1.1

94

4

07.0

89

0.21

5

22

0.03

5

0.

660

<0.0

27

40.5

C

381

ap

03f1

3

py

<1.3

80

<0

.094

n

.a.

0.2

69

0

.299

<0.0

88

0.0

92

3.

672

<0.0

30

43.5

C

381

ap

03f1

4

py

25.7

35

2.

929

n.a.

0

.427

187

.026

0.

552

220.

422

1806

.651

<0.

016

41

.5

C38

1

ap03

f18

py

<4

.213

<0.4

44

n.a

.

<

0.52

7

29.

309

<0

.308

1

83.2

40

1

.580

<0.

089

18

.8

C38

1

ap03

f04

sp

<1

.420

4.21

4

n.

a.

0.7

53

1

.814

0.08

2

<0

.082

1.

559

<0.0

23

34.6

C

381

ap

03f0

6

sp

<7.6

52

5.

639

n.a.

1

.595

2.6

58

<0

.443

<

0.46

2

2.82

2

<0

.140

39

.5

C38

1

ap03

f10

sp

<4

.284

8.03

6

n.

a.

1.3

69

2

.374

<0.3

59

<0.

272

3.

416

<0.0

89

43.5

C

381

ap

03f1

5

sp

<5.1

63

4.

713

n.a.

1

.557

0.8

52

<0

.357

0

.464

1.82

0

<0

.096

39

.5

C38

1

ap03

f17

sp

<8

.276

8.15

6

n.

a.

<1.

842

4

.459

<0.6

22

<0.

549

5.

139

<0.1

63

35.6

C

383

ap

17e1

2

p

y

<

6.15

2

<0

.553

n

.a.

<0.

727

<

0.96

7

<0.2

70

<0.

138

0.

513

<0.0

83

19.8

sam

ple

r

un/p

oint

typ

e

Mo

(ppm

)

A

g (p

pm)

C

d (p

pm)

S

n (p

pm)

S

b (p

pm)

A

u (p

pm)

T

l (pp

m)

P

b (p

pm)

B

i (pp

m)

P

eak

(s)

80

Appendix 5: LA-ICP-MS Analysis—Sulphides

C38

3

ap17

e14

py

21.

963

<0.1

96

n.a

.

0

.246

<0.

307

<0

.060

<

0.03

8

2.33

6

<0

.016

36

.6

C38

3

ap17

e16

py

18.

650

<0.4

74

n.a

.

<

0.66

8

<1.

190

<0

.193

0

.341

2.36

6

<0

.074

43

.5

C38

3

ap17

e17

py

199

.375

1

.371

n.a

.

<

0.79

5

11.

441

0.

363

0.23

5

45.

580

<

0.07

5

37.6

C

383

ap

17e1

8

p

y

<

4.66

2

12

.467

n

.a.

<0.

803

1

04.3

04

10.4

75

<0

.142

31

5.37

8

<0.0

55

42.5

C

383

ap

17e1

3

s

p

2

06.5

46

8.0

43

n

.a.

1.4

77

3

.594

<0.2

99

0.6

95

6.

872

<0.0

61

36.6

C

383

ap

17e1

5

s

p

4

9.04

3

26

.805

n

.a.

1.2

60

3

3.42

1

<0.2

74

0.3

26

20

4.66

7

<0.0

81

42.5

C

385

ap

06d0

5

c

py

74

.733

13.2

61

n.a

.

3

.238

44.

709

<0

.647

<

0.57

6

676.

316

<0

.254

10

.9

C38

5

ap06

d04

py

22.

765

<0.7

04

n.a

.

<

0.68

4

1.7

86

<0

.383

<

0.20

7

277.

745

<0

.085

23

.7

C38

5

ap06

d06

py

20.

882

<0.5

36

n.a

.

<

0.66

2

0.9

24

<0

.250

<

0.16

3

119.

470

<0

.053

45

.5

C38

5

ap06

d09

py

16.

382

8.32

5

n.

a.

0.2

68

9

.356

0.27

9

0.

300

1

871.

691

<0.0

28

24.7

C

385

ap

06d1

0

p

y

1

26.7

73

1.7

22

n

.a.

<0.

583

7

.328

<0.2

56

1.0

25

63

.039

<0.0

90

13.8

C

385

ap

06d1

1

p

y

4

3.97

3

2.

127

n.a.

<

0.52

0

8.6

78

<0

.328

1

.954

128.

834

<0

.063

24

.7

C38

5

ap06

d07

sp

<5.

163

11.2

77

n.a

.

1

.335

23.

692

<0

.236

<

0.22

0

1226

.570

<0.

103

42

.5

C38

5

ap06

d08

sp

42.

100

11.9

54

n.a

.

2

.017

22.

347

<0

.308

<

0.20

9

1594

.000

<0.

099

44

.5

C38

5

ap06

d12

sp

24.

271

18.4

63

n.a

.

1

.907

47.

351

<0

.330

0

.379

21.6

56

<0

.073

30

.6

C79

4

ap18

a34

cpy

2.09

5

8

5.79

5

n.a

.

2

8.83

7

22.

940

<0

.237

0

.238

22.6

96

19

.575

4

8.6

C79

4

ap18

a33

py

1.1

35

29.0

26

n.a

.

0

.368

24.

901

0.

817

2.27

1

226

6.50

4

51

3.42

0

4

5.1

C79

4

ap18

a36

py

<0.

216

0.16

4

n.

a.

0.2

54

3

.408

0.21

1

0.

139

6

0.82

6

19.

530

19

.1

C79

4

ap18

a39

py

<0.

177

0.31

0

n.

a.

0.1

97

9

.497

0.28

7

1.

314

8

.766

7.6

91

48

.6

C79

4

jl11a

74

py

<3

.977

0.77

1

<1

7.85

2

1

.004

0.9

43

<0

.257

<

0.21

3

39.6

89

17

.068

4

4.5

C79

4

jl11a

75

py

<3

.097

<0.2

93

<13

.673

1.

109

8.37

4

0.

468

0.28

0

14.

728

8

.299

49.8

C

794

ap

18a3

7

s

p

1

8.01

2

12

.814

n

.a.

0.8

94

1

0.75

6

0.37

1

1.

411

6

6.40

3

14.

702

50

.3

C79

4

ap18

a38

sp

7.9

34

20.2

55

n.a

.

0

.786

25.

566

0.

401

0.65

0

690

.490

28

.965

5

0.3

C79

5

ap19

a49

py

50.

254

79.1

64

n.a

.

0

.236

592

.099

4.

276

134.

344

3354

.223

<0.

017

38

.2

C79

5

ap19

a50

py

0.9

39

4.76

6

n.

a.

0.1

26

1

1.20

1

0.65

3

0.

290

1

45.4

83

<0.0

25

50.3

C

795

ap

19a5

1

p

y

0

.553

19

.276

n

.a.

0.2

28

7

1.97

4

1.97

6

11

.186

26

66.5

10

<

0.02

3

31.2

C

795

jl1

1a59

py

<2.6

63

10

.252

<

9.53

3

1.2

00

3

7.98

1

0.69

7

0.

704

3

302.

097

<0.0

51

67.0

C

795

jl1

1a60

py

<2.2

46

2.

670

<8.8

08

1.1

54

1

2.75

2

0.54

5

0.

670

1

22.6

92

<0.0

36

65.6

C

797

ap

19a9

1

p

y

<

0.26

4

1.

651

n.a.

<

0.13

8

16.

293

1.

547

<0.1

08

181.

278

0.

021

2

7.8

C79

7

ap19

a92

py

<0.

357

0.57

9

n.

a.

<0.

210

6

.173

0.76

6

<0

.107

71

.130

<0.0

14

52.0

C

797

ap

19a9

5

p

y

<

0.34

5

1.

359

n.a.

<

0.18

5

21.

216

0.

372

0.09

9

443

.020

<0

.010

48

.6

C79

7

jl11z

09

py

<2

.301

16.3

29

<12

.830

1.

249

141.

015

14.

517

<

0.12

6

1194

.150

0.0

90

45

.4

C79

7

jl11z

10

py

<5

.926

0.83

7

<2

2.06

8

1

.266

34.

897

0.

991

<0.3

09

329.

234

<0

.087

59

.5

C79

7

ap19

a93

sp

<0.

346

17.4

77

n.a

.

0

.496

12.

651

0.

245

0.07

7

11.

408

<

0.02

5

24.3

C

797

ap

19a9

4

s

p

0

.578

35

.735

n

.a.

0.5

60

3

9.02

6

0.25

5

0.

377

4

94.9

68

<0.0

19

50.3

C

799

ap

19a7

6

p

y

2

.994

34

.547

n

.a.

0.6

47

1

371.

605

1.75

8

13

69.2

74

24

14.0

49

<

0.00

9

20.8

C

799

jl1

1a35

py

10.4

88

26

.761

<

12.6

45

1.50

6

24

8.52

2

1

.146

43.

179

21

53.0

90

0

.109

44.5

C

799

jl1

1a36

py

<2.7

50

4.

715

<9.6

16

0.8

76

3

9.88

6

0.40

2

3.

354

7

20.3

85

<0.0

41

26.4

sam

ple

r

un/p

oint

typ

e

Mo

(ppm

)

A

g (p

pm)

C

d (p

pm)

S

n (p

pm)

S

b (p

pm)

A

u (p

pm)

T

l (pp

m)

P

b (p

pm)

B

i (pp

m)

P

eak

(s)

81

Appendix 5: LA-ICP-MS Analysis—Sulphides

C79

9

jl11a

37

py

<1

0.70

1

7.33

4

<3

2.84

4

0

.904

47.

280

0.

838

3.87

7

916

.421

<0

.153

20

.7

C79

9

jl11a

38

py

<5

.612

9.18

1

68

.231

1

.167

49.

691

0.

609

8.58

7

441

.739

<0

.075

31

.3

C79

9

ap19

a80

sp

<0.

381

8.93

2

n.

a.

0.8

50

4

.399

<0.2

60

<0.

098

2.

254

<0.0

14

52.0

C

799

ap

19a8

1

s

p

<

0.18

7

8.

942

n.a.

0

.936

4.4

36

<0

.114

<

0.06

4

1.81

4

<0

.010

52

.0

C80

1

ap10

a17

py

150

.822

0

.211

n.a

.

<

0.23

9

1.1

93

0.

101

0.19

1

20.

541

<

0.02

3

41.6

C

801

ap

10a1

8

p

y

2

83.1

49

0.7

58

n

.a.

<0.

217

2

.178

0.17

5

0.

197

2

00.8

82

<0.0

36

24.3

C

801

ap

10a2

2

p

y

1

06.9

57

0.1

21

n

.a.

<0.

240

0

.354

<0.0

82

1.8

61

13

.954

<0.0

19

13.9

C

801

jl1

1z06

py

116.

236

<0

.234

<

9.73

7

0.6

87

<

0.27

0

0.07

3

<0

.141

13

.099

<0.0

29

63.9

C

801

jl1

1z07

py

23.8

55

<0

.254

<

10.9

76

0.52

3

0.

380

<0.1

61

<0.

176

4.

474

<0.0

43

13.2

C

801

jl1

1z08

py

258.

962

<0

.221

<

9.36

4

0.5

93

<

0.21

8

<0.1

38

<0.

111

8.

031

<0.0

42

34.4

C

801

ap

10a2

3

s

p

1

32.4

83

12.

770

n

.a.

0.7

90

1

.601

0.09

7

0.

126

1

4.87

0

<0.

016

48

.6

C80

3

ap18

a64

cpy

<0.4

04

17

5.49

6

n

.a.

42.

221

9

.282

<0.2

41

<0.

217

5.

506

<0.0

23

46.8

C

803

ap

18a6

5

p

y

0

.205

<0

.084

n

.a.

<0.

171

0

.251

<0.0

83

0.9

44

4.

018

<0.0

09

26.0

C

803

jl1

1a45

py

<2.4

74

1.

179

<9.1

17

1.0

83

4

.472

0.32

7

<0

.124

16

5.87

6

0.10

5

67.

0 C

803

jl1

1a46

py

<2.2

32

6.

849

<8.0

91

0.7

88

2

8.61

5

4.57

0

7.

345

1

92.8

91

0.09

0

38.

8 C

803

jl1

1a47

py

14.7

86

18

.154

<

7.49

8

0.6

66

8

0.90

4

6.19

4

29

5.18

9

21

12.9

14

0

.924

20.7

C

803

jl1

1a48

py

<2.8

31

33

.000

<

8.50

9

1.2

46

7

0.77

7

3.45

0

0.

669

2

437.

871

0.42

7

68.

7 C

803

ap

18a6

2

s

p

1

.060

5.

772

n.a.

0

.160

13.

987

0.

128

5.67

2

247

.796

0.

044

3

8.2

C80

3

ap18

a63

sp

<0.

238

6.48

5

n.

a.

0.4

49

2

.874

0.10

4

<0

.086

2.

947

<0.0

17

22.5

C

804

ap

18a1

7

p

y

1

7.54

7

24

.876

n

.a.

0.2

02

1

79.5

27

10.4

44

62

8.95

9

10

78.4

26

0

.125

22.5

C

804

ap

18a1

8

p

y

<

0.20

7

<0

.060

n

.a.

<0.

197

<

0.29

2

<0.1

12

<0.

137

0.

788

<0.0

26

29.5

C

804

jl1

1a31

py

41.7

53

18

.147

<

8.17

3

1.0

13

1

66.5

18

6.50

6

27

3.81

8

79

6.85

2

0.06

8

59.

0 C

804

jl1

1a32

py

20.5

78

10

.559

<

10.2

18

1.24

7

92

.267

2

.600

135

.633

104

5.92

9

0.

065

6

3.0

C80

4

jl11a

34

py

15

.437

12.1

56

<12

.766

1.

705

90.8

20

3.6

72

1

64.6

65

1

142.

313

0.07

3

67.

0 C

807

jl0

4a21

py

<3.1

23

<0

.206

1

5.42

9

0.7

08

0

.833

<0.1

76

<0.

138

3.

576

<0.0

43

17.6

C

807

jl0

4a22

py

<3.2

14

<0

.231

<

7.05

0

0.6

55

<

0.33

2

<0.1

41

<0.

132

7.

037

<0.0

35

21.6

C

807

jl0

4a23

py

<2.6

86

0.

309

13.1

71

0.7

53

6

.630

<0.1

36

0.2

50

13

7.35

5

<0.0

44

73.1

C

807

jl0

4a24

py

<3.0

26

<0

.156

<

8.28

5

0.7

26

0

.264

<0.1

49

0.1

80

1.

721

<0.0

41

37.4

C

807

jl0

4a25

py

11.9

56

0.

383

32.7

51

0.8

92

2

.446

<0.1

45

0.3

49

53

.710

<0.0

39

39.2

C

807

jl0

4a26

sp

<6.4

98

30

.504

1

619.

274

1.86

5

46

.064

<

0.35

2

<0.

241

25

48.5

52

<

0.07

9

69.1

C

807

jl0

4a27

sp

<6.3

71

13

.780

1

591.

143

1.79

8

13

.362

<

0.35

8

<0.

267

17

.242

<0.0

65

69.1

C

808

ap

18a4

6

s

p

<

0.21

2

7.

407

n.a.

0

.468

5.5

61

<0

.139

<

0.13

6

13.8

02

3.

650

4

3.4

C80

8

ap18

a47

sp

<0.

195

2.96

1

n.

a.

0.3

48

0

.525

<0.1

90

<0.

091

4.

074

0.60

5

52.

0 C

809

jl0

4a64

py

<2.9

43

0.

523

<10.

430

0.8

74

1

3.01

2

0.38

2

<0

.122

71

.106

<0.0

47

49.3

C

809

jl0

4a65

py

<2.4

85

0.

269

<9.6

07

0.6

54

4

.150

<0.1

80

0.1

33

45

.324

<0.0

42

23.3

C

809

jl0

4a66

py

<2.3

62

<0

.169

<

8.94

1

0.7

96

<

0.28

6

<0.1

41

<0.

125

1.

071

<0.0

43

42.7

C

809

jl0

4a67

py

<2.7

02

<0

.246

<

11.8

42

0.64

6

0.

451

0.29

9

<0

.188

2.

504

<0.0

44

12.8

C

809

jl0

4a68

sp

<6.4

93

6.

897

2349

.928

2.2

96

1

2.50

9

<0.4

69

<0.

394

6.

906

<0.1

19

69.1

sam

ple

r

un/p

oint

typ

e

Mo

(ppm

)

A

g (p

pm)

C

d (p

pm)

S

n (p

pm)

S

b (p

pm)

A

u (p

pm)

T

l (pp

m)

P

b (p

pm)

B

i (pp

m)

P

eak

(s)

82

Appendix 5: LA-ICP-MS Analysis—Sulphides

C80

9

jl04a

69

sp

<2

.367

9.52

6

20

75.2

83

1

.752

24.

737

<0

.188

<

0.14

5

20.2

12

<0

.057

67

.8

C81

0

ap19

a71

py

0.9

55

13.7

69

n.a

.

0

.349

199

.980

1.

987

1.45

1

456

8.97

8

0.

080

2

6.0

C81

0

ap19

a72

py

<0.

384

1.44

0

n.

a.

0.1

66

2

2.67

5

<0.2

39

0.1

39

30

6.08

0

0.04

5

50.

3 C

810

ap

19a7

3

p

y

<

0.24

0

<0

.068

n

.a.

<0.

181

<

0.24

9

<0.0

71

<0.

117

0.

876

0.00

0

13.

9 C

810

ap

19a7

4

p

y

<

0.19

2

0.

562

n.a.

<

0.16

2

16.

527

<0

.205

<

0.10

2

137.

746

0.

090

4

6.8

C81

0

ap19

a67

sp

<0.

290

4.85

7

n.

a.

0.4

47

4

.819

<0.1

01

<0.

073

3.

712

<0.0

14

52.0

C

810

ap

19a6

8

s

p

1

.291

6.

878

n.a.

0

.546

10.

604

<0

.125

0

.170

19.4

88

0.

001

4

8.6

C81

1

jl04a

05

py

19

8.79

9

55.2

39

<13

.363

2.

193

1335

.529

2.00

6

49

6.57

5

24

06.7

62

1

.552

49.8

C

811

jl0

4a08

py

<3.9

75

3.

638

<16.

050

0.8

37

4

4.55

9

1.11

7

<0

.188

24

7.67

5

0.16

4

49.

3 C

812

ap

19a8

5

c

py

<0

.573

325.

777

n.a

.

2

4.02

9

15.

518

<0

.182

0

.523

10.1

25

<0

.027

48

.6

C81

2

ap19

a82

py

<0.

372

14.6

39

n.a

.

0

.470

28.

463

0.

129

3.09

4

144

3.89

6

0.

715

4

5.1

C81

2

ap19

a84

py

<0.

321

2.61

1

n.

a.

0.3

33

3

0.59

5

1.54

5

3.

670

2

76.2

84

0.03

0

13.

9 C

812

jl1

1a55

py

<2.4

87

<0

.233

<

10.8

52

0.67

4

<0

.226

<

0.16

1

<0.

094

0.

690

<0.0

47

31.3

C

812

jl1

1a57

py

<3.3

04

13

.801

<

10.7

08

1.33

6

41

.406

0

.565

2.1

18

42

84.3

82

0

.103

67.0

C

812

ap

19a8

6

s

p

<

0.32

9

12

.556

n

.a.

0.4

56

5

.316

0.10

8

<0

.104

2.

752

<0.0

10

48.6

C

812

ap

19a8

7

s

p

<

0.39

4

19

.676

n

.a.

0.5

22

1

7.19

5

<0.1

68

<0.

132

26

1.57

3

0.06

8

53.

8 C

813

jl0

4a37

py

45.0

04

1.

529

23.9

26

1.1

77

1

0.80

6

<0.2

19

2.0

95

88

.855

0.50

8

39.

2 C

813

jl0

4a38

py

5.44

5

0

.263

<9.

268

3

.264

2.8

90

<0

.130

<

0.10

6

31.2

32

0.

105

6

6.1

C81

3

jl04a

39

py

21

.303

<0.5

65

<30

.554

<0

.650

<

0.77

7

<0.4

57

<0.

324

8.

093

<0.1

24

39.2

C

813

jl0

4a41

py

<3.4

62

<0

.414

<

16.8

93

0.65

5

<0

.512

<

0.26

7

<0.

215

2.

673

<0.0

98

22.5

C

813

jl0

4a42

sp

28.5

02

8.

814

2434

.470

1.8

34

3

.320

<0.3

57

<0.

193

5.

153

<0.0

79

35.9

C

813

jl0

4a43

sp

20.5

65

53

.734

2

294.

818

1.94

5

10

6.30

1

<

0.19

8

0.3

92

13

18.3

54

2

.967

28.4

C

814

ap

19a4

5

p

y

<

0.25

6

3.

356

n.a.

0

.101

14.

902

2.

828

<0.0

54

144.

204

0.

036

5

2.0

C81

4

ap19

a46

py

<0.

149

4.01

7

n.

a.

<0.

190

6

3.01

6

4.91

9

<0

.121

36

8.04

3

1.01

3

52.

0 C

814

ap

19a4

7

p

y

1

.449

5.

164

n.a.

0

.126

53.

647

5.

257

0.07

8

278

.082

1.

417

4

1.6

C81

4

ap19

a48

py

<0.

281

8.63

9

n.

a.

<0.

126

5

6.59

6

13.4

40

<0

.060

34

3.63

3

0.22

6

39.

9 C

815

ap

18a9

3

p

y

<

0.34

4

48

.873

n

.a.

0.8

63

1

09.9

62

5.85

3

<0

.133

64

9.85

3

<0.0

27

39.9

C

815

ap

18a9

4

p

y

<

0.27

6

3.

404

n.a.

0

.708

31.

159

0.

344

0.17

8

96.

160

<

0.01

0

45.1

C

815

ap

18a9

5

p

y

<

0.30

6

<0

.065

n

.a.

0.2

10

1

.343

<0.0

73

<0.

112

10

.161

<0.0

11

48.6

C

815

ap

18a9

6

p

y

1

.482

8.

576

n.a.

0

.157

24.

192

0.

418

<0.1

07

260.

539

0.

033

5

0.3

C81

5

ap18

a97

sp

2.9

25

19.9

88

n.a

.

0

.604

42.

124

0.

096

0.35

2

293

2.44

7

0.

118

4

8.6

C81

5

ap18

a98

sp

0.1

84

30.3

78

n.a

.

0

.635

58.

279

<0

.077

0

.333

39.2

86

<0

.016

52

.0

C81

7

ap10

a05

apy

<0.7

98

12

.446

n

.a.

<0.

352

1

21.7

79

<0.3

34

<0.

211

87

0.13

5

27.8

78

41.

6 C

817

ap

10a0

3

p

y

3

6.90

8

14

0.44

2

n

.a.

2.8

99

1

223.

006

3.76

7

68

1.66

8

38

7.76

8

33.4

32

15.

6 C

817

ap

10a0

4

p

y

2

.662

9.

855

n.a.

0

.651

205

.544

0.

346

67.9

03

15.1

42

1.

330

3

9.9

C81

7

jl11a

70

py

<2

.292

7.13

6

<1

0.60

3

1

.094

14.

688

4.

212

<0.1

22

452.

641

20

.960

3

7.0

C81

7

jl11a

71

py

<2

.766

<0.2

90

<13

.389

0.

921

2.56

9

<0

.136

<

0.15

1

16.2

06

1.

114

1

5.4

C81

7

jl11a

72

py

21

.270

51.5

81

<49

.411

1.

066

189.

127

3.5

67

1

046.

858

2

20.6

70

25.5

49

22.

0

sam

ple

r

un/p

oint

typ

e

Mo

(ppm

)

A

g (p

pm)

C

d (p

pm)

S

n (p

pm)

S

b (p

pm)

A

u (p

pm)

T

l (pp

m)

P

b (p

pm)

B

i (pp

m)

P

eak

(s)

83

Appendix 5: LA-ICP-MS Analysis—Sulphides

C81

7

jl11a

73

py

23

.854

48.4

54

<21

.116

1.

203

330.

000

3.8

10

9

64.5

55

1

936.

778

52.2

70

56.

4 C

818

jl0

4a12

py

<2.4

07

3.

214

<7.6

83

0.8

66

4

1.86

8

0.64

1

0.

496

1

82.1

96

2.88

9

63.

0 C

818

jl0

4a13

py

<2.4

45

1.

144

<9.1

41

0.8

97

1

2.23

4

0.24

7

<0

.122

23

6.04

2

1.18

3

44.

5 C

818

jl0

4a14

py

<4.1

12

1.

635

<13.

095

0.8

47

2

1.28

5

0.28

7

0.

222

3

99.6

57

3.27

4

29.

1 C

818

jl0

4a15

py

<5.3

50

<0

.445

<

17.8

47

0.57

4

4.

391

<0.2

52

<0.

260

65

.751

<0.0

80

21.1

C

818

jl0

4a16

py

<2.9

78

<0

.211

<

9.63

1

0.7

39

2

.607

<0.1

28

<0.

132

25

.981

0.83

9

26.

0 C

818

jl0

4a17

sp

<3.5

66

6.

338

2075

.809

1.6

47

1

.753

<0.1

87

<0.

178

1.

504

0.06

6

67.

8 C

818

jl0

4a18

sp

<6.3

23

10

.051

2

247.

973

2.10

4

6.

599

<0.3

46

<0.

265

40

.301

0.60

3

68.

3 C

820

jl0

4a46

py

<2.1

27

0.

641

<12.

635

1.2

57

4

.133

0.28

7

0.

886

7

9.68

3

<0.

053

16

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C82

0

jl04a

47

py

3.

946

0.7

44

<

11.7

83

0.75

6

2.

411

<0.1

31

<0.

144

10

.843

<0.0

43

36.6

C

820

jl0

4a50

py

<1.8

38

5.

506

27.3

41

0.8

86

2

0.56

9

0.55

3

0.

183

1

467.

632

<0.0

54

32.2

C

820

jl1

1z14

py

18.4

92

9.

946

28.5

93

0.8

92

4

3.30

3

0.63

3

0.

611

2

128.

899

0.21

8

12.

8 C

820

jl1

1z15

py

<2.4

98

<0

.228

<

11.2

39

0.51

0

0.

716

<0.1

32

<0.

122

4.

477

<0.0

30

21.6

C

820

jl1

1z16

py

<2.9

08

4.

264

14.3

14

1.4

86

1

0.41

9

0.55

3

0.

223

9

67.3

79

<0.0

45

31.7

C

820

jl0

4a51

sp

<2.2

31

6.

572

1830

.455

1.6

68

0

.949

<0.1

96

<0.

139

6.

175

<0.0

58

68.3

C

820

jl0

4a52

sp

<2.4

26

15

.599

1

827.

815

1.81

5

11

.745

0

.231

<0.

153

9.

918

<0.0

58

69.1

C

822

jl0

4a31

cpy

<10.

794

28

7.28

8

<

41.3

42

4.28

0

6.

446

<0.3

41

<0.

466

5.

358

<0.1

66

13.2

C

822

jl0

4a32

cpy

61.4

34

38

2.86

0

<

22.5

23

8.01

9

14

.097

<

0.44

4

<0.

308

17

.301

<0.1

17

17.6

C

822

ap

10a1

6

s

p

2

84.6

21

13.

691

n

.a.

0.4

90

1

1.56

0

<0.1

04

0.1

31

11

.224

<0.0

24

31.2

C

822

jl0

4a34

sp

98.5

55

7.

475

2530

.045

1.9

61

4

.193

<0.4

80

<0.

340

6.

653

<0.1

31

49.9

C

823

ap

18a4

3

p

y

<

0.24

6

3.

654

n.a.

0

.430

0.4

14

<0

.199

<

0.14

0

237.

903

30

.525

4

6.8

C82

3

ap18

a44

py

1.8

76

0.89

4

n.

a.

<0.

184

1

.608

<0.0

99

<0.

120

19

2.34

2

11.7

88

50.

3 C

823

ap

18a4

5

p

y

0

.358

1.

482

n.a.

<

0.23

1

0.6

19

<0

.148

<

0.07

1

70.0

66

21

.910

5

2.0

C82

3

jl11a

82

py

<2

.174

4.53

5

<9

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0

.899

1.8

78

0.

147

<0.0

76

194.

176

29

.968

5

3.7

C82

3

jl11a

83

py

<3

.907

1.17

9

<1

2.30

7

1

.483

0.4

25

<0

.143

<

0.15

8

81.1

83

16

.982

3

7.0

C82

3

jl11a

84

py

5.

786

4.6

34

<

9.07

6

0.9

52

1

.222

<0.1

30

0.1

68

50

7.83

4

30.4

49

70.

9 C

824

ap

18a0

3

p

y

<

0.37

2

7.

390

n.a.

0

.189

0.8

37

0.

255

<0.1

23

49.6

96

15

.620

5

5.5

C82

4

ap18

a05

py

<0.

333

<0.0

58

n.a

.

<

0.15

6

<0.

410

<0

.144

<

0.10

5

0.33

6

0.

226

4

3.4

C82

4

ap18

a06

py

<0.

248

<0.0

49

n.a

.

0

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<0.

276

<0

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<

0.12

7

0.61

8

0.

101

4

5.1

C82

4

jl11a

49

py

<5

.318

<0.4

17

<20

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0.

970

1.25

4

<0

.235

<

0.22

3

4.77

1

2.

105

4

9.8

C82

4

jl11a

50

py

<7

.839

<0.6

65

<30

.560

1.

154

1.70

6

<0

.621

2

.165

5.32

5

13

.672

6

9.6

C82

4

jl11a

51

py

<6

.169

0.61

7

<1

9.89

7

0

.906

<0.

628

<0

.205

<

0.26

3

16.4

39

6.

959

6

8.3

C82

4

jl11a

52

py

<3

.563

<0.3

06

<15

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1.

178

<0.4

57

<0.

180

<

0.14

5

6.67

2

4.

990

6

7.0

C82

5

ap18

a53

cpy

114.

054

43

3.45

0

n

.a.

10.

646

2

6.26

9

<0.4

90

0.4

50

27

0.26

4

0.09

4

39.

9 C

825

ap

18a5

0

s

p

2

5.71

6

35

.090

n

.a.

0.6

32

4

4.47

0

0.41

6

0.

131

2

50.8

94

0.08

0

45.

1 C

825

ap

18a5

6

s

p

1

6.05

6

41

.953

n

.a.

0.9

76

6

5.92

9

0.21

0

0.

994

9

438.

187

2.98

7

52.

0 C

826

ap

18a7

0

c

py

6.

411

22.

867

n

.a.

161

.741

32

9.13

9

0

.752

61.

852

17

0.19

7

0.59

3

24.

3 C

826

ap

18a6

9

p

y

1

.588

14

4.50

7

0.

300

19.5

41

0.7

74

1

8.85

4

446.

818

1.

140

4

8.6

sam

ple

r

un/p

oint

typ

e

Mo

(ppm

)

A

g (p

pm)

C

d (p

pm)

S

n (p

pm)

S

b (p

pm)

A

u (p

pm)

T

l (pp

m)

P

b (p

pm)

B

i (pp

m)

P

eak

(s)

84

Appendix 5: LA-ICP-MS Analysis—Sulphides

C82

6

ap18

a71

py

6.3

60

0.26

2

n.

a.

<0.

267

2

.166

<0.2

15

0.3

31

67

.279

0.14

8

10.

4 C

826

ap

18a7

3

p

y

0

.250

3.

849

n.a.

0

.527

22.

466

8.

868

0.31

5

131

.520

10

.658

4

1.6

C82

6

jl11a

67

py

<2

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5.64

3

<9

.853

0

.670

45.

378

<0

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1

14.0

47

1

33.3

71

0.36

1

71.

8 C

826

jl1

1a68

py

165.

419

0.

565

47.9

90

1.3

61

1

.534

0.24

8

0.

223

1

19.7

92

0.34

1

67.

0 C

826

jl1

1a69

py

<2.1

66

6.

170

14.5

93

0.9

52

4

8.69

7

2.24

4

0.

898

2

51.9

76

28.8

81

29.

1 C

826

ap

18a6

8

s

p

0

.249

12

.904

n

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0.7

23

9

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95

0.3

99

8.

850

0.07

0

50.

3 C

826

ap

18a7

4

s

p

<

0.30

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14

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n

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0.9

90

1

3.96

2

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89

0.4

92

11

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0.08

1

36.

4 C

828

ap

18a7

7

p

y

3

4.81

8

33

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n

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0.7

71

9

15.0

67

5.14

4

18

68.4

88

10

02.6

59

1

1.84

5

46.8

C

828

ap

18a7

8

p

y

3

8.31

4

38

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n

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0.3

12

9

08.9

63

6.62

6

17

94.3

11

80

3.19

7

12.3

88

13.

9 C

828

ap

18a7

9

p

y

<

0.24

3

6.

337

n.a.

0

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50.

533

1.

233

1.80

9

859

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13

.885

5

2.0

C82

8

ap18

a82

py

46.

587

50.5

54

n.a

.

0

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110

1.02

1

7.

084

2121

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790.

751

9.

351

1

5.6

C82

8

ap18

a80

sp

385

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2

2.80

2

n.a

.

1

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34.

458

<0

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2

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49.1

88

1.

005

5

0.3

C82

8

ap18

a81

sp

11.

658

36.7

46

n.a

.

0

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61.

877

<0

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2

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197.

850

2.

117

1

7.3

C83

0

jl04a

80

py

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7.99

2

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34

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2.31

7

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74

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913

6.

218

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79

18.9

C

830

jl0

4a81

py

<2.8

62

0.

262

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54

0.9

02

2

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0.44

6

<0

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13

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73.6

C

830

jl0

4a82

py

<2.6

65

<0

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<

8.86

8

0.8

85

1

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0.34

2

0.

268

1

6.18

0

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30

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C83

0

jl04a

83

py

30

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54

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0.

556

0.60

9

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0

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3.76

6

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11

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C83

0

jl04a

84

sp

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5.66

9

21

83.0

94

2

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3.8

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0

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5.31

2

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60

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C83

0

jl04a

85

sp

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9.67

1

22

71.7

21

2

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14.

515

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0.26

5

10.3

63

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54

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C83

2

ap18

a85

py

<0.

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n.a

.

<

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0.13

7

1.86

2

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43

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C83

2

ap18

a86

py

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184

0.55

5

n.

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0

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21

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116

5.

232

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26.0

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832

ap

18a8

9

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y

1

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1.

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n.a.

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8

2.7

82

0.

238

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24

333.

800

0.

096

4

5.1

C83

2

jl11z

03

py

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1.

128

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96

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180

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0.11

4

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56

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69

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C83

2

jl11z

04

py

4.

980

1.1

74

1

7.91

4

1.1

82

0

.482

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89

<0.

102

58

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47

41.4

C

832

jl1

1z05

py

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87

0.

586

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1.0

54

1

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73

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167

9.

675

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71

50.7

C

832

ap

18a8

7

s

p

2

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12

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n

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0.9

77

1

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91

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4.

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15.6

C

832

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18a8

8

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1

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0.

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1

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926

0.47

5

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833

ap

18a1

4

c

py

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501

n.a

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738

21

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4

1.6

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3

ap18

a10

py

2.2

58

1.04

2

n.

a.

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1

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25

0.1

83

38

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21.3

55

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833

ap

18a1

3

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0

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13.

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0

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396.

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30

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3

4.7

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4

ap10

a26

py

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4.29

4

n.

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401

4

0.10

8

1.34

1

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1

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31.2

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835

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py

4.70

1

1

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6

48.

237

1

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46.

285

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1

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94.3

04

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48

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C83

5

jl04a

92

py

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7.55

6

15.8

73

<50

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1

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22

21.4

98

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22

56.5

20

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0.16

8

23.8

C

835

jl0

4a93

py

27.6

16

0.

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50

1.0

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0

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11

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52

74.0

C

835

jl0

4a94

sp

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62

14

.064

1

871.

307

2.75

1

17

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0.20

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170

11

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53.8

C

835

jl0

4a95

sp

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11

6.

133

1882

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2.2

87

7

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85

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296

7.

388

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55.1

C

836

ap

19a1

2

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y

6

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0.

538

n.a.

0

.407

3.6

39

0.

137

0.09

9

17.

347

<

0.01

3

20.8

C

836

ap

19a1

3

p

y

1

.872

0.

388

n.a.

1

.011

3.0

88

<0

.085

0

.120

6.00

4

<0

.011

12

.1

sam

ple

r

un/p

oint

typ

e

Mo

(ppm

)

A

g (p

pm)

C

d (p

pm)

S

n (p

pm)

S

b (p

pm)

A

u (p

pm)

T

l (pp

m)

P

b (p

pm)

B

i (pp

m)

P

eak

(s)

85

Appendix 5: LA-ICP-MS Analysis—Sulphides

C83

6

ap19

a14

py

2.9

96

0.87

2

n.

a.

1.1

13

3

.640

<0.0

88

0.0

94

5.

554

<0.0

07

15.6

C

836

ap

19a1

5

p

y

9

.497

<0

.093

n

.a.

0.1

27

0

.412

<0.0

87

0.1

19

3.

014

<0.0

09

17.3

C

836

jl1

1z17

py

<2.5

82

<0

.210

<

10.1

74

0.92

7

0.

672

<0.1

36

<0.

103

4.

352

<0.0

45

38.3

C

836

jl1

1z18

py

<2.3

38

7.

191

15.6

94

0.5

90

1

2.24

4

0.26

5

1.

141

2

47.1

46

<0.0

34

19.8

C

836

jl1

1z19

py

23.1

59

3.

412

<16.

262

73.

908

6

.869

<0.2

14

191

.959

609

.478

<0

.063

68

.7

C83

6

ap19

a16

sp

0.7

63

12.5

81

n.a

.

2

.055

28.

092

<0

.145

0

.868

3184

.281

0.1

56

12

.1

C83

6

ap19

a17

sp

0.6

81

8.78

9

n.

a.

1.2

37

1

3.24

9

<0.0

90

0.2

05

57

5.83

2

0.06

0

50.

3 C

838

ap

19a5

5

p

y

4

.545

58

2.32

4

n

.a.

<0.

186

4

10.8

47

8.30

0

86

.295

13

99.6

45

<

0.02

6

39.9

C

838

ap

19a5

6

p

y

0

.224

66

3.72

5

n

.a.

0.1

15

4

13.6

92

6.81

5

4.

745

2

815.

073

<0.0

08

29.5

C

838

ap

19a5

7

p

y

<

0.10

0

75

.833

n

.a.

0.0

87

1

00.9

43

0.60

9

1.

398

2

168.

455

<0.0

10

27.8

C

838

jl1

1a85

py

3.67

2

7

4.62

0

10.

920

1

.063

489

.901

1.

754

8.33

9

492

0.80

9

<0

.036

33

.9

C83

8

jl11a

86

py

<2

.323

63.7

86

<7.

183

0

.716

89.

546

17

0.44

9

1384

.542

2534

.419

<0.

045

26

.0

C83

8

jl11a

87

py

<2

.345

0.36

0

<9

.065

0

.902

1.0

98

0.

115

<0.1

63

6.67

6

<0

.048

70

.9

C83

8

ap19

a58

sp

2.7

04

6.85

4

n.

a.

0.4

91

1

3.22

1

0.10

2

<0

.057

30

.239

<0.0

13

52.0

C

838

ap

19a5

9

s

p

<

0.19

2

4.

628

n.a.

0

.336

1.5

71

0.

063

<0.0

69

2.32

6

<0

.014

19

.1

C84

0

ap19

a20

cpy

<0.3

92

73

0.33

8

n

.a.

45.

006

1

8.21

8

<0.4

10

0.6

29

7.

949

0.06

6

50.

3 C

840

ap

19a2

1

c

py

<0

.444

610.

662

n.a

.

5

7.90

4

8.7

85

<0

.679

<

0.18

6

4.63

3

<0

.080

34

.7

C84

0

ap19

a22

cpy

<0.6

36

53

9.09

6

n

.a.

44.

634

9

.700

<0.1

32

0.1

80

5.

303

0.03

2

29.

5 C

840

ap

19a2

3

s

p

0

.487

10

.254

n

.a.

0.5

00

5

.468

<0.1

28

<0.

092

2.

389

<0.0

33

43.4

C

840

ap

19a2

4

s

p

1

.235

24

.339

n

.a.

1.1

97

3

2.83

2

0.16

1

0.

230

1

25.4

28

0.37

5

52.

0 C

841

ap

19a1

02

cp

y

<0

.427

213.

245

n.a

.

8

7.85

9

17.

784

<0

.159

<

0.25

8

4.59

0

0.

382

2

2.5

C84

1

ap19

a103

cpy

<0.5

91

17

9.76

6

n

.a.

108

.910

6.

429

<0.2

58

<0.

139

2.

066

0.09

9

50.

3 C

841

ap

19a1

00

py

0.

514

5.1

29

n

.a.

<0.

141

2

15.5

92

11.3

25

0.

416

2

418.

217

0.04

6

41.

6 C

841

ap

19a1

01

py

31

.285

5.72

9

n.

a.

<0.

119

6

.089

0.29

6

<0

.070

26

4.37

3

0.70

5

34.

7 C

841

ap

19a9

8

p

y

<

0.45

6

5.

536

n.a.

<

0.23

2

14.

588

0.

228

<0.1

44

196.

949

1.

896

2

4.3

C84

1

ap19

a99

py

12.

218

30.1

63

n.a

.

0

.177

4.4

33

0.

175

0.17

8

342

6.15

7

81

.583

2

6.0

C84

1

ap19

a106

sp

0.23

5

5

.211

n.a

.

0

.558

0.6

02

<0

.074

<

0.09

9

0.90

4

0.

046

2

9.5

C84

1

ap19

a107

sp

<0.4

24

7.

058

n.a.

2

.210

1.0

37

<0

.150

<

0.07

4

1.75

3

0.

093

1

5.6

C84

1

ap19

a112

sp

<0.3

48

8.

560

n.a.

0

.586

5.2

71

<0

.126

<

0.12

1

39.0

51

0.

336

5

2.0

C84

1

ap19

a113

sp

0.30

1

1

1.38

4

n.a

.

0

.607

9.5

64

<0

.123

<

0.08

8

29.7

67

0.

523

5

2.0

C84

2

ap19

a62

py

0.3

96

41.3

12

n.a

.

<

0.14

6

416

.734

30

.668

0.91

1

369

1.65

2

0.

050

3

3.0

C84

2

ap19

a63

py

<0.

220

7.38

7

n.

a.

<0.

180

2

9.60

4

0.70

3

0.

181

1

61.2

74

<0.0

20

33.0

C

842

ap

19a6

4

p

y

<

0.31

8

12

.947

n

.a.

<0.

176

4

2.75

8

2.79

9

2.

035

3

76.5

35

<0.0

20

12.1

C

842

jl1

1a79

py

<2.4

25

1.

233

<9.8

19

0.6

79

1

4.65

4

0.34

1

<0

.112

49

.748

<0.0

43

38.3

C

842

jl1

1a80

py

<2.5

97

4.

547

<8.0

86

0.6

64

3

9.90

9

0.85

6

5.

278

1

671.

247

<0.0

46

31.7

C

842

jl1

1a81

py

<2.6

92

40

.825

<

8.85

5

0.5

93

9

0.29

1

4.32

2

0.

407

1

276.

895

<0.0

47

22.5

C

842

ap

19a6

5

s

p

0

.722

16

.038

n

.a.

0.4

10

1

5.93

2

0.28

3

0.

161

1

5.78

7

0.0

03

52

.0

C84

2

ap19

a66

sp

0.2

20

10.8

76

n.a

.

0

.463

11.

681

0.

285

0.11

3

10.

026

0

.003

52.0

sam

ple

r

un/p

oint

typ

e

Mo

(ppm

)

A

g (p

pm)

C

d (p

pm)

S

n (p

pm)

S

b (p

pm)

A

u (p

pm)

T

l (pp

m)

P

b (p

pm)

B

i (pp

m)

P

eak

(s)

86

Appendix 5: LA-ICP-MS Analysis—Sulphides

C84

4

ap10

a09

sp

<0.

973

6.87

1

n.

a.

0.8

07

1

3.63

4

<0.2

52

<0.

162

6.

318

<0.0

37

20.8

C

844

ap

10a1

0

s

p

0

.412

9.

298

n.a.

0

.821

22.

545

<0

.133

<

0.11

6

18.2

83

0.

012

3

4.7

C84

4

ap10

a11

sp

<0.

918

5.56

1

n.

a.

1.7

97

1

0.47

4

<0.4

05

<0.

324

22

7.60

1

0.09

3

39.

9 C

846

ap

19a4

0

p

o

<

0.71

6

2.

840

n.a.

0

.555

<0.

511

<0

.255

<

0.25

9

4.18

8

4.

994

4

8.6

C84

6

ap19

a41

po

45.

587

2.31

2

n.

a.

0.7

56

<

0.67

8

<0.2

62

<0.

200

3.

284

5.01

9

48.

6 C

846

ap

19a4

2

p

o

<

1.06

2

1.

357

n.a.

0

.772

<0.

700

0.

027

<0.2

20

3.81

8

3.

367

5

0.3

C84

6

ap19

a37

py

1.2

17

0.86

4

n.

a.

0.2

76

3

.383

<0.1

11

0.0

95

52

.250

16.4

82

50.

3 C

846

ap

19a3

8

p

y

1

04.9

90

1.4

86

n

.a.

0.1

79

3

.317

<0.1

18

0.2

52

38

.275

9.07

0

41.

6 C

846

ap

19a3

9

p

y

4

6.54

9

0.

346

n.a.

<

0.18

6

0.4

94

<0

.086

0

.058

19.7

80

8.

191

2

0.8

C84

6

jl11a

62

py

<3

.021

1.57

8

<9

.415

0

.901

3.3

52

0.

102

0.47

8

110

.971

8.

889

6

2.1

C84

6

jl11a

63

py

18

.184

3.38

0

<9

.895

0

.700

6.1

20

0.

105

0.80

6

673

.155

1.

749

3

4.4

C84

6

jl11a

64

py

47

.825

1.66

4

9.

682

0.95

3

3.

629

0.19

7

<0

.097

67

.140

28.4

26

72.

2 C

848

jl1

1a10

po

<15.

698

<1

.126

<

41.7

10

2.19

2

<1

.309

<

0.97

1

<0.

684

3.

170

<0.3

32

69.6

C

848

jl1

1a11

po

<11.

993

<0

.991

<

37.4

86

2.14

4

<1

.224

<

0.83

0

<0.

503

<1

.326

0.42

9

69.

6 C

848

jl1

1a03

py

15.8

73

<0

.672

<

21.8

82

0.98

4

<0

.998

<

0.53

8

<0.

445

2.

791

<0.1

40

10.6

C

848

jl1

1a04

py

<3.9

42

<0

.282

<

9.13

4

1.0

83

0

.298

<0.1

80

<0.

167

3.

104

<0.0

55

35.7

C

848

jl1

1a05

py

10.8

11

82

.733

<

9.47

1

1.4

28

8

59.0

17

26.1

19

17

73.9

25

30

54.9

15

5

93.4

74

58.1

C

848

jl1

1a06

py

14.9

51

<0

.365

<

12.4

43

1.14

3

<0

.379

<

0.24

2

<0.

210

1.

196

<0.0

56

49.3

C

848

jl1

1a07

py

28.1

73

1.

181

<13.

963

1.2

71

0

.777

<0.1

94

<0.

210

25

6.20

6

4.44

6

37.

4 C

849

jl1

1a14

py

<6.5

58

9.

809

<24.

005

1.1

76

3

9.62

6

<0.2

33

<0.

299

14

1.63

9

3.60

8

68.

7 C

849

jl1

1a15

py

<8.4

95

<1

.003

<

38.0

47

1.03

7

2.

570

<0.5

88

<0.

508

10

8.81

1

1.87

9

24.

2 C

849

jl1

1a16

py

<5.1

01

27

.633

<

19.5

32

0.98

2

73

.060

<

0.28

9

<0.

263

26

56.6

10

9

.998

59.0

C

849

jl1

1a17

py

<4.5

59

0.

422

<14.

314

1.0

40

2

2.12

3

<0.2

00

<0.

205

32

.413

5.31

7

24.

7 R

001

ap

17c1

3

p

y

<

5.21

3

5.

718

n.a.

<

0.64

8

13.

863

1.

147

0.21

7

119

7.26

9

10

5.04

0

4

3.5

R00

1

ap17

c15

py

<2.

437

3.74

5

n.

a.

0.2

97

1

2.38

9

0.81

5

0.

162

7

83.5

72

152.

836

45.

5 R

001

ap

17c1

6

p

y

<

2.83

3

0.

988

n.a.

<

0.28

4

10.

591

0.

654

0.13

5

102

.657

14

.834

2

7.7

R00

1

ap17

d16

py

<3.

611

3.25

8

n.

a.

<0.

379

5

.298

0.28

3

0.

093

4

71.6

26

107.

700

17.

8 R

001

ap

17d1

7

p

y

<

1.24

3

1.

225

n.a.

0

.199

2.1

59

<0

.052

0

.040

161.

906

13

.725

4

4.5

R00

1

ap17

c17

sp

<10

.541

3

.988

n.a

.

1

.211

<1.

644

<0

.346

<

0.19

0

2.48

6

4.

985

4

2.5

R00

1

ap17

c18

sp

<8.

059

7.81

3

n.

a.

1.0

05

1

.882

<0.3

46

<0.

145

7.

813

7.14

0

45.

5 R

003

ap

06g1

1

p

y

<

3.22

4

<0

.363

n

.a.

0.4

23

<

0.44

0

<0.1

86

<0.

102

21

.716

13.3

17

40.

5 R

003

ap

06g1

3

p

y

<

1.22

4

9.

816

n.a.

0

.301

4.1

93

0.

521

0.09

7

733

.973

14

3.39

2

3

1.6

R00

3

ap06

g16

py

<4.

051

0.80

6

n.

a.

0.4

97

<

0.61

1

<0.1

74

<0.

140

13

.571

17.9

16

43.

5 R

003

ap

06g1

7

p

y

<

3.07

0

<0

.360

n

.a.

<0.

418

<

0.63

5

<0.2

05

<0.

126

60

.187

36.4

59

44.

5 R

003

ap

06g1

8

p

y

<

3.99

5

0.

408

n.a.

0

.526

<0.

345

<0

.238

<

0.16

6

48.6

13

42

.837

3

7.6

R00

3

ap06

g12

sp

<5.

678

7.33

1

n.

a.

1.7

24

2

.863

<0.3

92

<0.

333

67

.096

9.47

9

40.

5 R

003

ap

06g1

4

s

p

<

6.74

9

7.

831

n.a.

1

.432

1.6

15

<0

.377

<

0.24

9

30.9

63

7.

797

2

7.7

R00

3

ap06

g15

sp

<6.

766

3.18

6

n.

a.

1.8

56

<

0.91

1

<0.3

39

<0.

267

1.

069

0.79

2

43.

5

sam

ple

r

un/p

oint

typ

e

Mo

(ppm

)

A

g (p

pm)

C

d (p

pm)

S

n (p

pm)

S

b (p

pm)

A

u (p

pm)

T

l (pp

m)

P

b (p

pm)

B

i (pp

m)

P

eak

(s)

87

Appendix 5: LA-ICP-MS Analysis—Sulphides

R04

9

ap18

a20

cpy

<0.5

12

33

8.56

2

n

.a.

6.5

31

5

.654

<0.2

02

<0.

219

3.

120

<0.0

38

48.6

R

049

ap

18a2

5

c

py

<0

.694

281.

621

n.a

.

5

.497

10.

923

<0

.179

<

0.31

9

14.3

18

<0

.054

46

.8

R04

9

ap18

a19

py

46.

751

27.2

25

n.a

.

0

.400

168

.807

11

.461

310.

871

3205

.501

0.1

88

48

.6

R04

9

ap18

a26

py

0.2

73

5.80

8

n.

a.

0.1

99

1

0.90

2

2.71

7

<0

.128

32

3.96

6

0.20

1

36.

4 R

049

ap

18a2

7

s

p

0

.391

32

.994

n

.a.

0.4

70

2

3.17

9

0.22

2

0.

181

6

7.46

7

0.0

79

50

.3

R07

0

ap19

a30

apy

6.18

9

2

.077

n.a

.

1

43.7

56

3861

.022

0.78

3

<0

.131

13

.065

2.64

3

22.

5 R

070

jl1

1z20

apy

<1.7

82

10

.852

<

7.73

6

1.9

21

9

626.

732

<0.1

49

<0.

089

46

.046

1.28

9

63.

9 R

070

ap

19a2

9

c

py

<0

.494

20.0

08

n.a

.

1

699.

357

14.0

88

<0.

183

<

0.15

5

7.26

8

<0

.036

45

.1

R07

0

ap19

a34

cpy

<0.5

63

15

6.30

1

n

.a.

152

0.85

1

7.

424

<0.2

19

0.1

05

5.

016

0.08

9

50.

3 R

070

ap

19a3

1

p

y

<

0.14

2

40

.987

n

.a.

403

.193

22

.823

<

0.09

9

<0.

032

51

9.19

8

2.73

6

48.

6 R

070

ap

19a3

2

p

y

<

0.20

4

84

.100

n

.a.

231

0.55

1

86

.739

0

.148

<0.

063

26

7.90

0

0.90

2

36.

4 R

070

ap

19a3

3

p

y

<

0.24

2

54

.862

n

.a.

123

0.98

1

20

.108

<

0.05

7

0.2

92

15

7.20

5

0.70

2

29.

5 R

070

jl1

1z21

py

<2.9

70

42

.777

5

5.96

0

389

.321

46

.506

<

0.21

0

<0.

143

17

10.4

60

6

.847

24.2

R

070

jl1

1z22

py

<3.2

23

25

9.32

6

2

8.95

4

125

.395

22

.060

<

0.20

0

<0.

173

93

.439

0.23

8

20.

7 R

070

ap

19a2

5

s

p

<

0.17

7

30

.973

n

.a.

159

.000

2.

283

0.01

8

<0

.047

2.

822

0.01

1

50.

3 R

070

ap

19a2

6

s

p

<

0.27

9

79

.913

n

.a.

47.

248

4

.800

<0.0

50

<0.

079

5.

867

0.04

3

52.

0 R

075

jl1

1a25

cpy

<6.0

87

4.

570

<20.

631

751

.098

31

.139

<

0.25

8

<0.

297

18

.149

3.56

6

63.

9 R

075

jl1

1a23

py

5.04

1

5

6.66

2

<8.

263

2

043.

686

512.

701

15.

165

1

8.53

1

1166

.816

159

.913

59

.0

R07

5

jl11a

24

py

<3

.643

5.75

9

<1

2.22

5

3

.362

105

.532

5.

373

0.56

9

360

.055

64

.711

6

9.6

R07

5

jl11a

26

py

<3

.747

5.00

2

<1

0.42

7

3

75.2

15

45.8

76

1.4

84

1

.093

100.

656

13

.348

6

7.4

R07

5

jl11a

27

py

<2

.817

2.37

3

<1

1.74

9

7

6.06

8

28.

138

0.

498

0.62

6

21.

932

4

.721

66.5

R

075

jl1

1a28

py

<3.3

12

25

.246

<

12.6

04

68.1

19

49.

990

3.

685

2.13

6

366

.209

12

6.78

2

6

7.8

R07

8

jl04a

72

py

<2

.825

12.3

08

<9.

698

0

.926

191

1.87

9

<0

.152

0

.334

4548

.005

<0.

049

74

.4

R07

8

jl04a

73

py

<2

.865

12.6

44

<8.

905

1

.014

196

7.33

1

<0

.156

0

.598

4002

.584

0.0

68

69

.2

R07

8

jl04a

76

sp

<1

5.66

2

2.60

1

32

43.4

12

2

.492

39.

125

<0

.787

<

0.66

7

28.1

45

<0

.243

60

.0

R07

8

jl04a

77

sp

<5

.599

23.2

38

544

7.16

3

1.

775

1912

.576

<0.3

63

2.7

05

81

8.61

1

<0.0

78

64.3

sa

mpl

e

run

/poi

nt

t

ype

M

o (p

pm)

Ag

(ppm

)

Cd

(ppm

)

Sn

(ppm

)

Sb

(ppm

)

Au

(ppm

)

Tl (

ppm

)

Pb

(ppm

)

Bi (

ppm

)

Pea

k (s

)

Appendix 6: Sulphur Isotope Analysis

88

Appendix 6 Sulphur Isotope Analysis

Appendix 6: Sulphur Isotope Analysis

89

BV

-169

ba

C

SL-

SO

4

3

8.26

K

lens

ore

- K

m

assi

ve b

ande

d ba

in s

ulph

ide

ore

A

u-A

g-P

b-ba

zon

e B

V-1

84

ba

CS

L-S

O4

46.

87

K le

ns

or

e - K

ba c

lot i

n m

assi

ve s

p-ga

ore

A

u-A

g-P

b-ba

zon

e C

00-1

34

b

a

CS

L-S

O4

39.

39

AB

-lens

b

a lo

de -

AB

fg

se-

schi

st/s

ands

tone

with

py-

ba le

nses

ba

lode

s C

00-2

83

b

a

CS

L-S

O4

33.

84

K le

ns

or

e - K

clot

s of

ba

in m

assi

ve s

p-py

-ga

ore

- fw

to s

ill

ba

in s

ulph

ide

lode

C

00-3

51

b

a

CS

L-S

O4

37.

86

K le

ns

or

e - K

mas

sive

ban

ded

ba -

fw to

pep

eriti

c si

ll

b

a in

sul

phid

e lo

de

C00

-374

ba

C

SL-

SO

4

4

1.77

K

lens

ba lo

de -

K

ba

nded

ba

+ fp

- hw

to p

eper

ite s

ill

ba

lode

s C

00-3

75

b

a

CS

L-S

O4

47.

33

K le

ns

ba

lode

- K

mas

sive

ba

- hw

to p

eper

itic

sill

ba

lode

s C

00-4

12

b

a

CS

L-S

O4

41.

36

K le

ns

fo

otw

all

pa

le g

rey

si-s

e sc

hist

/ cg

feld

spat

hic

sand

ston

e

b

a in

sul

phid

e lo

de

C00

-557

ba

C

SL-

SO

4

4

2.72

P

lens

ba lo

de -

P

m

assi

ve b

ande

d ba

, min

or s

p-ga

ba

lode

s C

01-5

48

b

a

CS

L-S

O4

44.

13

P le

ns

ba

lode

- P

mas

sive

ba

ba

lode

s C

01-5

50

b

a

CS

L-S

O4

42.

28

P le

ns

ba

lode

- P

mas

sive

ban

ded

ba

ba

lode

s C

01-5

56

b

a

CS

L-S

O4

35.

62

P le

ns

ba

lode

- P

mas

sive

ba

+ se

-sch

ist

ba

lode

s C

01-5

58

b

a

CS

L-S

O4

39.

01

P le

ns

ba

lode

- P

mas

sive

ba

+ se

-sch

ist

ba

lode

s C

01-6

62

b

a

CS

L-S

O4

43.

45

P le

ns

ba

lode

- P

mas

sive

ban

ded

ba

ba

lode

s C

01-6

63

b

a

CS

L-S

O4

44.

17

P le

ns

fo

otw

all

ba

clo

t in

py o

re

ba in

sul

phid

e lo

de

C01

-705

ba

C

SL-

SO

4

3

5.59

P

lens

foot

wal

l

ba s

tock

wor

k in

se-

schi

st

b

a st

ockw

ork

C01

-724

ba

C

SL-

SO

4

4

4.13

P

lens

ba lo

de -

P

m

assi

ve b

ande

d ba

cut

by

late

py

vein

b

a lo

des

C01

-759

ba

C

SL-

SO

4

4

2.50

P

lens

ba lo

de -

P

se

mi-m

assi

ve b

a

b

a lo

des

R00

-020

ba

C

SL-

SO

4

4

5.30

K

lens

ore

- K

ba

clo

t in

mas

sive

fg s

p-ga

ore

- fw

to p

eper

itic

sill

ba

in s

ulph

ide

lode

B

V-1

66

py

LA

-sul

phid

e

17.

01

K le

ns

fo

otw

all

di

ssem

inat

ed p

y in

cl s

chis

t

A

u-Ag

-Pb-

ba z

one

BV

-166

sp

C

SL-

SO

2

1

4.30

K

lens

foot

wal

l

diss

emin

ated

py

in c

l sch

ist

Au-

Ag-P

b-ba

zon

e B

V-1

67

py

LA

-sul

phid

e

12.

85

K le

ns

fo

otw

all

se

mi-m

assi

ve p

y-cp

y in

cl-s

chis

t

A

u-A

g-P

b-ba

zon

e B

V-1

67

py

LA

-sul

phid

e

12.

46

K le

ns

fo

otw

all

se

mi-m

assi

ve p

y-cp

y in

cl-s

chis

t

A

u-A

g-P

b-ba

zon

e B

V-1

68

py

LA

-sul

phid

e

14.

15

K le

ns

or

e - K

mas

sive

hon

ey-b

row

n m

assi

ve s

p-ga

ore

Au-

Ag-

Pb-

ba z

one

BV

-169

sp

C

SL-

SO

2

1

3.73

K

lens

ore

- K

m

assi

ve h

oney

-bro

wn

mas

sive

sp-

ba-g

a or

e

A

u-A

g-P

b-ba

zon

e B

V-1

71

py

LA

-sul

phid

e

16.

14

K le

ns

or

e - K

sem

i-mas

sive

py

Au-

Ag-

Pb-

ba z

one

BV

-173

sp

C

SL-

SO

2

1

7.62

K

lens

ore

- K

m

assi

ve ta

n sp

-ga-

ba o

re

A

u-A

g-P

b-ba

zon

e B

V-1

75

py

LA

-sul

phid

e

14.

85

K le

ns

TS

V

fg

host

bet

wee

n or

e an

d si

ll, s

tring

er p

y-sp

vei

ns

A

u-A

g-P

b-ba

zon

e B

V-1

75

sp

CS

L-S

O2

12.

10

K le

ns

TS

V

fg

host

bet

wee

n or

e an

d si

ll, s

tring

er p

y-sp

vei

ns

A

u-A

g-P

b-ba

zon

e C

00-1

56

p

y

CS

L-S

O2

-4.9

4

hos

t

T

SV

f

ram

boid

al p

y in

fg fe

ldsp

athi

c sa

ndst

one

T

SV

bac

kgro

und

C00

-220

py

C

SL-

SO

2

-3

.47

h

ost

TS

V

fra

mbo

idal

py

in fg

feld

spat

hic

sand

ston

e

TS

V b

ackg

roun

d C

00-2

23

p

y

CS

L-S

O2

-1.8

0

hos

t

T

SV

f

ram

boid

al p

y in

fg fe

ldsp

athi

c sa

ndst

one

T

SV

bac

kgro

und

C00

-320

py

LA

-sul

phid

e

13.

24

K le

ns

fo

otw

all

se

-si s

chis

t - d

isse

min

ated

py

F

e-Zn

-Cu

zone

C

00-3

23

p

y

LA-s

ulph

ide

1

3.58

K

lens

foot

wal

l

si-s

e sc

hist

- di

ss. t

an s

p-ga

Fe

-Zn-

Cu

zone

C

00-3

23

s

p

CS

L-S

O2

11.

69

K le

ns

fo

otw

all

si

-se

schi

st -

diss

. tan

sp-

ga

Fe-Z

n-C

u zo

ne

C00

-326

py

LA

-sul

phid

e

15.

02

K le

ns

or

e - K

mas

sive

sul

phid

e,"c

last

ic" t

extu

res

- dar

k ta

n sp

-ga-

py

Fe-

Zn-C

u zo

ne

C00

-329

py

LA

-sul

phid

e

10.

49

K le

ns

or

e - K

mas

sive

, fin

ely

lam

inat

ed d

ark

tan

sp-g

a

Fe

-Zn-

Cu

zone

C

00-3

29

s

p

CS

L-S

O2

9.7

2

K

lens

ore

- K

m

assi

ve, f

inel

y la

min

ated

dar

k ta

n sp

-ga

Fe-Z

n-C

u zo

ne

sam

ple

id

min

eral

ana

lysi

s

δ

S34

o

re le

ns

unit

c

omm

ents

p

urpo

se

Appendix 6: Sulphur Isotope Analysis

90

C00

-332

py

LA

-sul

phid

e

14.

90

K le

ns

or

e - K

mas

sive

red-

brow

n sp

-ga-

py, b

and

mas

sive

py

Fe-

Zn-C

u zo

ne

C00

-363

py

C

SL-

SO

2

1

2.78

K

lens

late

vei

ns -

K

m

assi

ve p

y re

plac

ing

dark

tan

sp-g

a or

e

la

te p

y ve

in s

et -

pre-

defo

rmat

ion

C00

-364

py

C

SL-

SO

2

1

3.31

K

lens

late

vei

ns -

K

m

assi

ve fg

tan

sp-p

y-ga

ore

, tr c

py

late

py

vein

set

- pr

e-de

form

atio

n C

00-3

66

p

y

LA-s

ulph

ide

1

3.27

K

lens

porp

hyry

- K

da

rk re

d-br

own

sp-p

y-ga

in b

lack

por

phyr

y

late

py

vein

set

- pr

e-de

form

atio

n C

01-4

43

s

p

CS

L-S

O2

10.

21

P le

ns

or

e - P

9

dark

tan

sp-g

a-py

with

si-s

e cl

asts

P

lens

stra

tigra

phic

cha

nges

C

01-5

49

p

y

LA-s

ulph

ide

2

3.54

P

lens

ba lo

de -

P

ba

nded

ba,

min

or s

p-ga

ba

lode

s C

01-5

70

p

y

LA-s

ulph

ide

1

4.55

P

lens

ore

- P6

m

assi

ve p

y-sp

-ga

+ m

inor

ba

clas

ts +

fp

P

lens

stra

tigra

phic

cha

nges

C

01-5

70

s

p

CS

L-S

O2

12.

14

P le

ns

or

e - P

6

mas

sive

py-

sp-g

a +

min

or b

a cl

asts

+ fp

P le

ns s

tratig

raph

ic c

hang

es

C01

-575

py

LA

-sul

phid

e

12.

88

P le

ns

or

e - P

7

mas

sive

pal

e sp

-ga-

py +

fp

P le

ns s

tratig

raph

ic c

hang

es

C01

-575

sp

C

SL-

SO

2

1

2.38

P

lens

ore

- P7

m

assi

ve p

ale

sp-g

a-py

+ fp

P

lens

stra

tigra

phic

cha

nges

C

01-5

78

p

y

LA-s

ulph

ide

1

2.09

P

lens

ore

- P7

pa

le s

p-ga

-py

P le

ns s

tratig

raph

ic c

hang

es

C01

-580

py

LA

-sul

phid

e

14.

40

P le

ns

or

e - P

6

mas

sive

pal

e sp

-ga-

py +

gre

y fp

gra

ins

P

lens

stra

tigra

phic

cha

nges

C

01-5

82

p

y

LA-s

ulph

ide

1

1.70

P

lens

ore

- P7

se

mi-m

assi

ve p

y-sp

-ga

in s

i-se

schi

st

P

lens

stra

tigra

phic

cha

nges

C

01-5

86

p

y

LA-s

ulph

ide

1

0.76

P

lens

ore

- P6

se

mi-m

assi

ve/d

iss.

py-

tan

sp-g

a in

cl-s

e sc

hist

P

lens

stra

tigra

phic

cha

nges

C

01-5

92

s

p

CS

L-S

O2

11.

00

P le

ns

or

e - P

6

mas

sive

tan

sp-g

a-py

ore

, diff

use

lam

inat

ions

P le

ns s

tratig

raph

ic c

hang

es

C01

-594

py

LA

-sul

phid

e

11.

23

P le

ns

or

e - P

6

mas

sive

tan

sp-p

y-ga

+ fp

P le

ns s

tratig

raph

ic c

hang

es

C01

-594

sp

C

SL-

SO

2

1

5.29

P

lens

ore

- P6

m

assi

ve ta

n sp

-py-

ga +

fp

P

lens

stra

tigra

phic

cha

nges

C

01-5

96

p

y

LA-s

ulph

ide

1

1.55

P

lens

ore

- P6

m

assi

ve ta

n sp

-py-

ga, d

iffus

e la

min

atio

ns

P

lens

stra

tigra

phic

cha

nges

C

01-5

96

s

p

CS

L-S

O2

11.

65

P le

ns

or

e - P

6

mas

sive

tan

sp-p

y-ga

, diff

use

lam

inat

ions

P le

ns s

tratig

raph

ic c

hang

es

C01

-597

py

LA

-sul

phid

e

11.

15

P le

ns

or

e - P

6

sem

i-mas

sive

/mas

sive

py

(+ta

n sp

-ga)

in c

l-se

schi

st

P

lens

stra

tigra

phic

cha

nges

C

01-5

97

p

y

CS

L-S

O2

11.

62

P le

ns

or

e - P

6

sem

i-mas

sive

/mas

sive

py

(+ta

n sp

-ga)

in c

l-se

schi

st

P

lens

stra

tigra

phic

cha

nges

C

01-6

56

p

y

LA-s

ulph

ide

1

7.43

P

lens

late

vei

ns -

P

m

assi

ve ta

n sp

-ga-

py

la

te p

y ve

in s

et -

pre-

defo

rmat

ion

C01

-656

sp

C

SL-

SO

2

1

6.00

P

lens

late

vei

ns -

P

m

assi

ve ta

n sp

-ga-

py

la

te p

y ve

in s

et -

pre-

defo

rmat

ion

C01

-658

py

LA

-sul

phid

e

16.

36

P le

ns

la

te v

eins

- P

mas

sive

fg p

y ve

in in

mas

sive

cb

late

py

vein

set

- pr

e-de

form

atio

n C

01-7

07

p

y

LA-s

ulph

ide

1

0.78

P

lens

ba lo

de -

P

m

assi

ve b

ande

d py

-ba

b

a lo

des

C01

-718

py

LA

-sul

phid

e

13.

37

P le

ns

la

te v

eins

- P

mas

sive

py

vein

s in

si s

chis

t

la

te p

y ve

in s

et -

pre-

defo

rmat

ion

C01

-718

py

C

SL-

SO

2

1

3.97

P

lens

late

vei

ns -

P

m

assi

ve p

y ve

ins

in s

i sch

ist

late

py

vein

set

- pr

e-de

form

atio

n C

01-7

20

p

y

LA-s

ulph

ide

1

1.72

P

lens

late

vei

ns -

P

m

assi

ve p

y, m

inor

sp-

ga

l

ate

py v

ein

set -

pre

-def

orm

atio

n C

01-7

20

s

p

CS

L-S

O2

11.

69

P le

ns

la

te v

eins

- P

mas

sive

py,

min

or s

p-ga

lat

e py

vei

n se

t - p

re-d

efor

mat

ion

C01

-740

py

LA

-sul

phid

e

17.

65

P le

ns

la

te v

eins

- P

fg

se-s

i sch

ist w

ith e

arly

qz-

py v

ein

la

te p

y ve

in s

et -

pre-

defo

rmat

ion

C01

-743

py

LA

-sul

phid

e

16.

60

P le

ns

la

te v

eins

- P

fg

se-s

i sch

ist w

ith e

arly

qz-

py v

ein

la

te p

y ve

in s

et -

pre-

defo

rmat

ion

C01

-758

sp

C

SL-

SO

2

1

4.00

P

lens

ore

- P13

m

assi

ve ta

n sp

-ga-

py

P

lens

stra

tigra

phic

cha

nges

C

01-7

59

p

y

LA-s

ulph

ide

2

1.25

P

lens

ba lo

de -

P

se

mi-m

assi

ve b

a in

se-

si s

chis

t

b

a lo

des

C01

-823

py

LA

-sul

phid

e

15.

82

K le

ns

fo

otw

all

gr

ey s

i-se

schi

st +

dis

sem

inat

ed p

y

F

e-Zn

-Cu

zone

C

01-8

24

p

y

LA-s

ulph

ide

1

2.03

K

lens

foot

wal

l

blac

k cl

-se

schi

st +

py-

cpy

F

e-Zn

-Cu

zone

C

01-8

26

p

y

LA-s

ulph

ide

1

0.57

K

lens

ore

- K

dk

tan

sp-g

a-py

+ c

b bl

ebs

F

e-Zn

-Cu

zone

C

01-8

26

s

p

CS

L-S

O2

11.

45

K le

ns

or

e - K

dk ta

n sp

-ga-

py +

cb

bleb

s

Fe-

Zn-C

u zo

ne

C01

-828

py

LA

-sul

phid

e

15.

24

K le

ns

or

e - K

dk ta

n sp

-py

band

ed o

re

F

e-Zn

-Cu

zone

sam

ple

id

min

eral

ana

lysi

s

δ

S34

o

re le

ns

unit

c

omm

ents

p

urpo

se

Appendix 6: Sulphur Isotope Analysis

91

C01

-828

sp

C

SL-

SO

2

1

3.60

K

lens

ore

- K

dk

tan

sp-p

y ba

nded

ore

Fe-

Zn-C

u zo

ne

C01

-830

py

LA

-sul

phid

e

16.

03

K le

ns

or

e - K

tan

sp-g

a-py

Fe

-Zn-

Cu

zone

C

01-8

32

p

y

LA-s

ulph

ide

1

5.13

K

lens

ore

- K

ho

ney-

bn s

p-ga

-py

F

e-Zn

-Cu

zone

C

01-8

32

s

p

CS

L-S

O2

13.

15

K le

ns

or

e - K

hone

y-bn

sp-

ga-p

y

Fe-

Zn-C

u zo

ne

C02

-858

py

C

SL-

SO

2

1

5.32

P

lens

TSV

s

e-al

tere

d si

ltsto

ne -

diss

emin

ated

sul

phid

e

P

lens

stra

tigra

phic

cha

nges

C

02-8

58

s

p

CS

L-S

O2

12.

90

P le

ns

TS

V

se-

alte

red

silts

tone

- di

ssem

inat

ed s

ulph

ide

P le

ns s

tratig

raph

ic c

hang

es

C02

-859

py

C

SL-

SO

2

1

1.85

P

lens

ore

- P9

qz

-alte

red

sedi

men

t - s

emi-m

assi

ve s

ulph

ide

P le

ns s

tratig

raph

ic c

hang

es

C02

-859

sp

C

SL-

SO

2

9

.51

P le

ns

or

e - P

9

qz-a

ltere

d se

dim

ent -

sem

i-mas

sive

sul

phid

e

P

lens

stra

tigra

phic

cha

nges

C

02-8

60

s

p

CS

L-S

O2

13.

47

P le

ns

or

e - P

9

mas

sive

pal

e sp

-ga

P

lens

stra

tigra

phic

cha

nges

C

02-8

61

s

p

CS

L-S

O2

8.7

0

P

lens

ore

- P9

se

ricite

-alte

red

sedi

men

t + d

isse

min

ated

sul

phid

e

P le

ns s

tratig

raph

ic c

hang

es

C02

-862

py

C

SL-

SO

2

9

.14

P le

ns

po

rphy

ry -

P

qz-c

b al

tere

d qz

-fp p

orph

yry

P le

ns s

tratig

raph

ic c

hang

es

C02

-863

sp

C

SL-

SO

2

1

0.89

P

lens

ore

- P10

m

assi

ve o

rang

e br

own

sp-g

a

P le

ns s

tratig

raph

ic c

hang

es

C02

-864

py

C

SL-

SO

2

1

3.87

P

lens

ore

- P10

ba

ritic

qua

rtz-s

eric

ite a

ltere

d se

dim

ent

P

lens

stra

tigra

phic

cha

nges

C

02-8

66

p

y

CS

L-S

O2

14.

38

P le

ns

TS

V

cb

alte

red

sedi

men

t, di

ssem

inat

ed s

ulph

ide

P le

ns s

tratig

raph

ic c

hang

es

C02

-867

sp

C

SL-

SO

2

1

6.71

P

lens

ore

- P13

m

assi

ve p

ink

carb

onat

e

P

lens

stra

tigra

phic

cha

nges

C

02-8

68

s

p

CS

L-S

O2

13.

64

P le

ns

or

e - P

13

sem

i-mas

sive

ora

nge-

brow

n sp

-ga

P

lens

stra

tigra

phic

cha

nges

R

02-0

81

s

p

CS

L-S

O2

12.

82

P le

ns

or

e - P

13

band

ed s

p-ga

-py

ore

P le

ns s

tratig

raph

ic c

hang

es

R02

-081

sp

C

SL-

SO

2

1

2.42

P

lens

ore

- P13

ba

nded

sp-

ga-p

y or

e

P

lens

stra

tigra

phic

cha

nges

sam

ple

id

min

eral

ana

lysi

s

δ

S34

o

re le

ns

unit

c

omm

ents

p

urpo

se

92

Appendix 7: Diamond Drill Logs

Appendix 7 Diamond Drill Logs

Tabulated below are the drill holes and intervals logged as part of this study. Several representative logs only are enclosed due to volume of material, with the remainder held at the University of Tasmania. Mine development and grade control holes collared below surface are prefixed by “R”, whereas surface exploration holes are suffixed by “R”. Assay, survey and other relevant data is contained within mine site drill datasets. BHID interval logged BHID interval logged From To (m) From To (m) 060R 738 1054 316 R6593 0 72 72 086R 540 864.8 324.8 R6760 0 165.9 165.9 087R 514 889.7 375.7 R6803 0 103.4 103.4 121R 1082 1511.9 429.9 R6804 0 92.5 92.5 121R-D1 1050 1425.3 375.3 R6805 0 29.6 29.6 122R 1170 1700 530 R6806 0 71.2 71.2 123R 1130 1509.1 379.1 R6827 0 83.4 83.4 127R 1200 1721.1 521.1 R6828 0 62.8 62.8 132R-D2 1030 1402 372 R6829 0 41.7 41.7 R5192 367 554 187 R6847 0 23.8 23.8 R5192-D1 300 830.7 530.7 R6889 0 101.4 101.4 R5382-D1 500 840.4 340.4 R6890 0 101.4 101.4 R5384 0 290 290 R6901 0 139.2 139.2 R5387 0 190.2 190.2 R6902 0 123.7 123.7 R5581-D2 570 716.8 146.8 R6910 0 201.4 201.4 R5802 0 200 200 R6921 0 172.8 172.8 R5824 0 649 649 R6926 0 152 152 R5827 0 399 399 R6932 0 162.3 162.3 R5964 0 104 104 R6978 0 116 116 R5975 0 338.6 338.6 R7013 0 192 192 R6011 0 570 570 R7251 0 68 68 R6051 0 258 258 R7252 0 71 71 R6052 0 347.2 347.2 R7254 0 55 55 R6053 0 398.7 398.7 R7255 0 73.7 73.7 R6055 0 497.3 497.3 R7394 0 105.6 105.6 R6075 0 124.5 124.5 R7407 0 66.6 66.6 R6203-D1 300 762 462 R7455 0 131.6 131.6 R6217 0 218.2 218.2 R7467 0 70.1 70.1 R6219 0 199 199 R7489 0 46.4 46.4 R6223 0 247 247 R6297 0 159 159 70 holes for a total of 15086.8m R6298 0 131 131 R6334 0 299.8 299.8 R6335 130 504 374 R6411 0 124.3 124.3 R6426 0 136.3 136.3 R6464 0 148 148 R6476 0 194 194 R6529 0 113.5 113.5 R6587 0 98.6 98.6 R6592 0 90.3 90.3

Appendix 7: Diamond Drill Logs

93

94

Appendix 7: Diamond Drill Logs

Appendix 7: Diamond Drill Logs

95

96

Appendix 7: Diamond Drill Logs

Appendix 7: Diamond Drill Logs

97

98

Appendix 7: Diamond Drill Logs

Appendix 7: Diamond Drill Logs

99

100

Appendix 7: Diamond Drill Logs

Appendix 7: Diamond Drill Logs

101

102

Appendix 7: Diamond Drill Logs

Appendix 7: Diamond Drill Logs

103

104

Appendix 7: Diamond Drill Logs

Appendix 7: Diamond Drill Logs

105

106

Appendix 7: Diamond Drill Logs

Appendix 7: Diamond Drill Logs

107

108

Appendix 7: Diamond Drill Logs

Appendix 7: Diamond Drill Logs

109

110

Appendix 7: Diamond Drill Logs

Appendix 7: Diamond Drill Logs

111

112

Appendix 7: Diamond Drill Logs

Appendix 7: Diamond Drill Logs

113

114

Appendix 7: Diamond Drill Logs

Appendix 7: Diamond Drill Logs

115

116

Appendix 7: Diamond Drill Logs

Appendix 7: Diamond Drill Logs

117

118

Appendix 7: Diamond Drill Logs

Appendix 7: Diamond Drill Logs

119

120

Appendix 7: Diamond Drill Logs

Appendix 7: Diamond Drill Logs

121

122

Appendix 7: Diamond Drill Logs

Appendix 7: Diamond Drill Logs

123

124

Appendix 7: Diamond Drill Logs

Appendix 8: Specific New Data Collected & Presented

125

Appendix 8 Specific New Data

Collected & Presented

Appendix 8: Specific New Data Collected & Presented

126

This study – new data collected raw data location

This study - new data presented

Chapter 3 70 drillholes logged (15,086.8m ) appendix 7 in text; figs. 3.4, 3.7 - 3.15, 3.22 28 thin sections appendix 1 in text; figs. 3.5, 3.16, 58 whole rock analyses appendix 2 in text; fig. 3.6 compilation of TSV thickness data

and intrusive location/extent Rosebery mine

dataset in text; figs.3.19, 5.1

Chapter 4 70 drillholes logged (15,086.8m ) appendix 7 in text; table 4.1; figs. 4.2 - 4.9, 4.11

28 thin sections appendix 1 in text; fig. 4.1 electron microprobe analyses –

chlorite, n=35 appendix 3 in text; figs. 4.13 - 4.14

electron microprobe analyses – sericite, n=7

appendix 3 in text; fig. 4.15

electron microprobe analyses – feldspar, n=53

appendix 3 in text

Chapter 5 70 drillholes logged (15,086.8m ) appendix 7 in text; figs. 5.5, 5.7-5.10, 5.19 58 whole rock analyses appendix 2 in text; fig. 5.2 85 thin sections & polished thin

sections; 82 polished resin mounts appendix 1 in text; tables 5.1 - 5.2; figs. 5.2,

5.11 - 5.19 Chapter 6 compilation of major element data K

lens & P lens ore Rosebery mine

dataset in text; table 6.1; figs. 6.1 - 6.3, 6.5 - 6.6

Chapter 7 85 thin sections & polished thin sections; 82 polished resin mounts

appendix 1 in text; fig. 7.2

electron microprobe analyses – pyrite, n=432

appendix 4 in text; tables 7.1 - 7.3

electron microprobe analyses – sphalerite, n=335

appendix 4 in text; tables 7.4 - 7.5, 7.11; figs. 7.6, 7.15 - 7.17, 7.19

electron microprobe analyses – galena, n=87

appendix 4 in text; table 7.7

electron microprobe analyses – chalcopyrite, n=114

appendix 4 in text; table 7.8

electron microprobe analyses – pyrrhotite, n=9

appendix 4 in text

electron microprobe analyses – arsenopyrite, n=25

appendix 4 in text

electron microprobe analyses – bournonite, n=4

appendix 4 in text

electron microprobe analyses – tennantite/tetrahedrite, n=79

appendix 4 in text; table 7.6; figs. 7.8, 7.17-7.19

LA-ICP-MS analyses – pyrite, n=431

appendix 5 in text; tables 7.1 - 7.2, 7.10; figs. 7.3 - 7.5, 7.9 - 7.10, 7.12 - 7.14, 7.16 - 7.17,

LA-ICP-MS analyses – sphalerite, n=174

appendix 5 in text; tables 7.4 - 7.5, 7.10; fig.7.7

LA-ICP-MS analyses – chalcopyrite, n=42

appendix 5 in text; table 7.9

LA-ICP-MS analyses – pyrrhotite, n=5

appendix 5 in text

LA-ICP-MS analyses – arsenopyrite, n=10

appendix 5 in text; table 7.9

LA-ICP-MS analyses – tennantite-tetrahedrite, n=9

appendix 5 in text

Chapter 8 SO4 analyses – barite, n=19 appendix 6 in text; tables 8.1 - 8.3; figs. 8.1 - 8.5

SO2 analyses – pyrite, n=12 appendix 6 in text; tables 8.1 - 8.3; figs. 8.1 - 8.5

SO2 analyses – sphalerite, n=27 appendix 6 in text; tables 8.1 - 8.3; figs. 8.1 - 8.5

laser SO2 analyses – pyrite, n=36 appendix 6 in text; tables 8.1 - 8.3; figs. 8.1 - 8.5