May 15, 2017May 17, 2017

Cairo, Egypt Alexandria, Egypt

Gas Processing OverviewPhil Hunt

Manu Van Leuvenhaege

UOP Limited, Guildford, UK 2017 Honeywell Oil & Gas Technologies Symposium

Agenda

• Gas Processing Portfolio

• Separex Membrane Technology

• Mercury Removal Adsorbent Technologies

• Honeywell UOP Modular Gas Plants

Unconventional Conventional

World total = 790CIS

Sources: IEA, BP, PFC Energy, EIA

AFRICA

W. EUROPE

OAP

NORTH AMERICA

(ex. Mexico)

LATIN AMERICA

INDIA

462328

MIDDLE EAST

CHINA

No circle within a region indicates minimal known Acid Gas or NGL Content |

Feed gas quality depends on location

High Med Low

Acid Gas

High Med Low

NGL Content

UOP 6004P_GP-3

Global Overview of Natural Gas Reserves

Technology #Units

Adsorbents 2,500+

PSA Units 1000+

Merox Process 1,700+

Benfield Process 650+

AGFS Process 400+

Selexol Process 100+

Membrane Systems 130+

Licensed NGL Recovery 90+

Licensed Sulfur Recovery 90+

Removal of Acid Gas and Other Components

Market Segments

AGFS

Process

Separex

Membranes

Regenerative

Adsorbents

Non

Regenerative

Adsorbents

Ortloff NGL

Recovery

Ortloff

Sulfur

Recovery

Selexol

Process

Merox

Process

On-shore Gas Plant

X X X X X X X X

LNG/NGL Complex

X X X X X X X X

Platforms & FPSO

X X X X

FLNG X X X X

© 2015 by Honeywell International Inc. All rights reserved.

% Typical Recovery**

Primary Hydrocarbon Recovery Goal

High

er Pre

ss

ure

Dro

pL

ow

er

Pre

ss

ure

Dro

p

99+% 98+%99+%99+%99+%Licensed Turbo-Expander

Technology

95+% 90+%99+%99+%99+%Open Art Turbo-Expander

Designs

95+% 90+% 50+%99+%Twister Supersonic Separator

85+% 70+% 35+%99+%Joule Thompson Expansion

95+% 90+% 30+%99+%Mechanical Refrigeration

99+% 98+% 20+%SeparSIV Adsorption

C2+ Gas Processing

Heavies C5+ Butanes Propane Ethane

**Actual recovery dependent on feed gas

composition, pressures, flow rates

Complete portfolio of hydrocarbon management options

Hydrocarbon Management

© 2015 by Honeywell International Inc. All rights reserved.

Agenda

• Gas Processing Portfolio

• Separex Membrane Technology

• Mercury Removal Adsorbent Technologies

• Honeywell UOP Modular Gas Plants

UOP Separex Membrane Elements

• Membranes are thin, semi-permeable barriers that selectively separate certain components

• Membranes are characterized by permeability or capacity (flux) and selectivity

FastSlow

Hig

h P

res

su

re

Lo

w P

res

su

re

CO2, H2S,

H2O

Hydrocarbons, N2

UOP Continues to Expand Membrane Product Portfolio

for Enhanced Capacity and Higher Selectivity

Membrane Process

Feed SpacerMembrane

Permeate Spacer

Membrane

Feed Spacer

Residual

Residual

• World-Scale Processing Plants Delivered as Modular Packaged Equipment

• Advanced Pre-Treatment Demonstrated to Improve Element Life

• Off-shore Experience

Separex Membranes: A Proven Technology

8

© 2015 by Honeywell International Inc. All rights reserved.

UOP Membrane Experience in Egypt

Location MMscfdCO2

InletCO2

Outlet

Nigeria

Pakistan

Pakistan

Mexico

Thailand

Egypt

Egypt

Egypt

Indonesia

Malaysia

Thailand

200

550+450

240

120

32

107

218

234

254

680

620

7%

6.5%

12%

70%

50%

6.7%

6.8%

9%

40%

44%

40%

2%

2%

3%

5%

20%

3%

3%

3%

20%

8%

21%

Western Desert, Egypt

Khalda (EGPC & Apache)

Five two-stage membrane systems

– 100 MMSCFD each

– 6-9% CO2 to < 3%

1-3: Commissioned 1999 (6% CO2)

4-5: Commissioned 2008 (9% CO2)

Total feed capacity = 559MMscfd

UOP 6004T_GP-9

To Boiler

Single StageMembrane

Amine System

xxxx

XXX

TreatedGas

to Acid Gas

Cooler

XXX

Hybrid schemes – Combining the Best of Two Worlds

GrassrootsBulk-cut with membranes

• Very attractive offshore to allow lower

weight and footprint and reduce

transport volume, or,

• Meeting pipeline spec at wellhead and

further reducing to LNG spec

downstream

RevampDebottleneck existing amine units

• Increasing feed gas flowrates, or,

• Increasing feed gas CO2 content

membrane will treat the gas to a

CO2 content that is acceptable to

the existing amine unit

SeparexMembranes

Each Application Has an Optimal Scheme:

Evaluate Simplicity & Robustness Versus Performance

© 2015 by Honeywell International Inc. All rights reserved.

Agenda

• Gas Processing Portfolio

• Separex Membrane Technology

• Mercury Removal Adsorbent Technologies

• Honeywell UOP Modular Gas Plants

Why remove Hg?

1. Health, Safety & Environment

2. Equipment Protection

3. Catalyst Protection

4. Product Quality

UOP Guard Bed Adsorbents

• Non-Regenerative System

• Removal to 0.01μg/Nm3 Hg

• Also combined with removal

of H2S, RSH and COS

• No dry stream required

• Used in more than 70 units

UOP HgSiv Adsorbents

• Regenerative System

• Removal to 0.01μg/Nm3 Hg

• Also combined with Molsiv

adsorbents for removal of

H2O, H2S, RSH and CO2

• Small layer in Molsiv Unit

• Used in more than 50 units

N. Africa

1-130μg/Nm3

Gulf

Asia-Pacific

200-2,000μg/Nm3

Off-Shore

Australia

50-200μg/Nm3

Europe

1-500μg/Nm3

The Americas

1-100μg/Nm3

Dehydration

Sulfur& CO2

Mercury

Dehydration

Mercury

UOP’s Experience in Mercury Removal

UOP 5989-12

© 2015 by Honeywell International Inc. All rights reserved.

Agenda

• Gas Processing Portfolio

• Separex Membrane Technology

• Mercury Removal Adsorbent Technologies

• Honeywell UOP Modular Gas Plants

© 2015 by Honeywell International Inc. All rights reserved.

Why Modularize?

More assembly work is done in the shop at a lower hourly rate and not subject to weather

Equipment and parts are more

readily available at the shop location,

closer to supplies

Much assembly work can be

completed prior to field move in,

while waiting on permits and

weather

Equipment, piping, and

instrumentation can be checked

out prior to shipment to

fieldCo

st

an

d S

ch

ed

ule

Qu

ality

an

d E

ffic

ien

cy

Train sizes up to 300 MMSCFD can be easily Modularized

Nat Gas Conditioning

Dehydration

• Mol Sieve Adsorption

• Glycol (TEG) Absorption

Acid Gas Treatment

• Amine Units (100-1000 gpm1)

• Membrane Units (1+ BCFD)

Sulfur Recovery

• Modular Claus (10-100+ LTPD)

• Sulfur Scavengers

Hg Removal Units

Rich Gas

Conditioner

FractionationDeethanizer / Depropanizer / Debutanizer

1gpm = gallons of amine per minute

SE

GM

EN

T

NGL Recovery NGL Upgrading

GA

S N

GL

CO

NT

EN

T (G

PM

2)

Mechanical

Refrigeration

Cryogenic

Turboexpander

Complete Modular Equipment Solutions: Pre-engineered or Custom

OF

FE

RIN

G

2GPM = gallons of NGL per

thousand SCF of natural gas

9

6

4

3

2

Deethanizer Depropanizer Debutanizer Butane Splitter

Natural

Gasoline

I-Butanes

N-Butanes

Mixed Butanes

PropanePurity

Ethane

Y-G

RA

DE

OR

RA

W M

IX

UOP Natural Gas Modular Products

UOP Scope Delineations

CONFIGURATION DIAGRAM

Typical Cryogenic Gas Plant Project

28-MAY-2014

A

Gas Processing Plant

CFG.01

HMO Unit(s)

Residue Gas to Sales Gas

Pipeline

Feed Gas

Municipal Water Supply or

Well Water Supply

Fuel Gas

Residue Gas

Compression

Battery

Lim

it

Battery

Lim

it

Stabilized Condensate

Product

Liquid Products to Storage

or Pipeline

Y-Grade

LPG

Nat. Gasoline

Instrument &

Plant Air

Package

Other Utilities if

required

N2

Cooling Water

Fire Water

BOP Flare

Header

FLARE

To OSBL Storm Water Treatment

4160 VTransformers

MCC & Elec

Equipment

LV Distribution

Storm Water

Collection &

Retention

1ph Distribution

Produced WaterTo OSBL Produced Water Treatment

15 kV from Utility

MV Distribution

INLET

SEPARATION

Slug Catcher

Separator

Inlet

Compression

Condensate

Stabilizer

Section

Truck

Loading

Station

Water

Treatment

(Potable

Water)

RO

Unit

Main Process

Units

MRU

RGC

AGRU

Dehydration

Cryogenic T/E

Refrigeration

Fractionation

Off-Spec

(Rerun)

Tank(s)

* Lease Automatic

Custody Transfer

Metering

(LACT)*NGL Product(s)

Residue Gas

Acid Gas

To Users

Metering

(LACT)*

Pipeline

Pumps

Control

Room

F&G Detection

Security Systems

BOP ControlsOffsite data/controls link

To Users

To Users

Storage

Tanks

LPG

Tanks

Thermal Oxidizer

or Sulfur Recovery

Core

PEU’s

Field

Install

Extended

BOP

Core

BOP

PEU Controls

How We Modularize

LPG Recovery Process Skids

Field Design Support Package

Pre-Engineered Cryo Plant

Pre-Engineered Cryo Plants

40 – 200+ MMSCFD

2 to 4 GPM C2+• Unsaturated Feed

• “Low” CO2 in Feed

MOLSIVTMInlet Gas Residue Gas

Y-grade

Cryo Plant

Inlet Gas Residue Gas

Y-grade

Cryo Plant

Refrig Loop

Pre-Engineered Cryo + Supplemental Refrigeration (SR)

6 GPM C2+• Unsaturated Feed

• “Low” CO2 in Feed

(saturated feed)

Supplemental

Refrigeration Units

1000 – 6000 HP

MOLSIVTM

Inlet Gas

Residue Gas

Y-grade

Cryo Plant

Refrig Loop

• Water Unsaturated Feed

• “High” CO2 in Feed

Amine

Treater

Cryo + SR + Pre-Engineered Amine

(saturated feed)

MOLSIVTM

Pre-Engineered Amine Units

100 – 1000+ gpm

Residue Gas

Gasoline

(saturated feed)

Cryo + SR + Amine + Fractionation

Cryo Plant

Refrig Loop

HMO System

Depropanizer Propane

ButaneDebutanizer

MOLSIVTM

Inlet Gas

Amine

Treater

Q u e s t i o n a n d A n s w e r