form 27 state of colorado oil and gas conservation · pdf filesite investigation and...

SITE INVESTIGATION AND REMEDIATION WORKPLAN

State of Colorado Oil and Gas Conservation Commission

1120 Lincoln Street, Suite 801, Denver, Colorado 80203 (303)894-2100 Fax:(303)894-2109

This form shall be submitted to the Director for approval prior to the initiation of site investigation and remediation activities. Form 27 is intended to be used whenever possible. Additional documentation will be required when large volumes of soil and groundwater have been impacted or involve large facilities with multiple source areas. See Rule 910. Attach as many pages as needed to fully describe the proposed work.

OGCC Operator Number:____________________________________________________

Name of Operator:_________________________________________________________

Address:_________________________________________________________________

City:__________________________________________ State:_____ Zip:_____________

Contact Name and Telephone:

___________________________________________

No:_________________________________________

Fax:________________________________________

FORM

27 Rev 6/99

API Number: ___________________________________ County: _________________________________________________________

Facility Name: __________________________________ Facility Number: __________________________________________________

Well Name: ____________________________________ Well Number: ____________________________________________________

Location: (QtrQtr, Sec, Twp, Rng, Meridian): ___________________________________________ Latitude: ____________ Longitude: ___________

OGCC Employee:

Spill Complaint Inspection NOAV Tracking No:

FOR OGCC USE ONLY

CAUSE OF CONDITION BEING INVESTIGATED AND REMEDIATED Spill or Release Plug & Abandon Central Facility Closure Site/Facility Closure Other (describe):___________________________

TECHNICAL CONDITIONS Type of Waste Causing Impact (crude oil, condensate, produced water, etc): __________________________________________________________

Site Conditions: Is location within a sensitive area (according to Rule 901e)? Y N If yes, attach evaluation.

Adjacent land use (cultivated, irrigated, dry land farming, industrial, residential, etc.): ____________________________________________

Soil type, if not previously identified on Form 2A or Federal Surface Use Plan: _________________________________________________

Potential receptors (water wells within 1/4 mi, surface waters, etc.): _________________________________________________________

_______________________________________________________________________________________________________________

Description of Impact (if previously provided, refer to that form or document):

Impacted Media (check): Extent of Impact: How Determined:

Soils ___________________________________________ ________________________________________ Vegetation ___________________________________________ ________________________________________

Groundwater ___________________________________________ ________________________________________

Surface Water ___________________________________________ ________________________________________

REMEDIATION WORKPLAN Describe initial action taken (if previously provided, refer to that form or document):

Describe how source is to be removed:

Describe how remediation of existing impacts is to be accomplished, including removal and disposal at an injection well or licensed

facility, land treatment on site, removal of impacted groundwater, insitu bioremediation, burning of oily vegetation, etc.:

Submit Page 2 with

PetersoA

Typewritten Text

2145501

PetersoA

Text Box

RECEIVED 7/22/2013

PetersoA

Text Box

#7904

REMEDIATION WORKPLAN (Cont.)

State of ColoradoOil and Gas Conservation Commission

1120 Lincoln Street, Suite 801, Denver, Colorado 80203 (303)894-2100 Fax:(303)894-2109

FORM27

Rev 6/99

Tracking Number: ________________________________________Name of Operator: ________________________________________OGCC Operator No: ______________________________________Received Date: __________________________________________Well Name & No: _________________________________________Facility Name & No: _______________________________________

If groundwater has been impacted, describe pro posed monitoring plan (# of wells or sample points, sampling schedule, analytical methods, etc.):

Describe reclamation plan. Discuss existing and new grade recontouring; method and testing of compaction alleviation; and reseeding program, including location of new seed, seed mix and noxious weed prevention. Attach diagram or drawing. Use additional sheet for description if required.

Attach samples and analytical results taken to verify remediation of impacts. Show locations of samples on an onsite schematic or drawing.

Is further site investigation required? Y N If yes, describe:

Final disposition of E&P waste (landtreated and disposed onsite, name of licensed disposal facility, recycling, reuse, etc.):

IMPLEMENTATION SCHEDULEDate Site Investigation Began: _____________ Date Site Investigation Completed: ___________ Date Remediation Plan Submitted: ___________

Remediation Start Date: __________________ Anticipated Completion Date: ________________ Actual Completion Date: ___________________

I hereby certify that the statements made in this form are, to the best of my knowledge, true, correct, and complete.Print Name: _________________________________________ Signed: ________________________________________Title:__________________________________________ Date:_____________________

OGCC Approved: ________________________________ Title:________________________________ Date:_____________

_______________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________________

OGCC Employee:

Based on the topographical setting of the release area (high arid mesa) and Division of WaterResources data, it is not anticipated groundwater has been impacted.

No reclamation activities are necessary as no surface disturbance occurred.

Analytical data and a map depicting the sample locations (soil and water) from the impacted areas areattached.

The water utilized for the flushing activities will be contained and recovered with a vac truck. Therecovered water will be transported and transferred to one of the WPX production water storagefacilities. The excavated material, that slightly exceeds pH and SAR concentrations will be transportedto the KP 11-16 well pad (COGCC facility #335557) where it will be incorporated into the cut slope ofthe pad during reclamation activities.

✔

7/2/2013 7/3/2013 7/22/2013

7/2/2013 7/31/13 TBD

Karolina Blaney

Environmental Specialist 7/22/2013

BKGD1

BKGD 3 BKGD 2POND 2

POND 1DITCH 5 SOIL

DITCH 4 SOIL

DITCH 3 SOIL

DITCH 1 WATER

DITCH 2 WATER

POINT OF ORIGIN

KP 24-17

Sec. 17

Sec. 20

.0 75 150 Feet

LegendSample LocationPondImpacted Area

PLSSTownshipSectionWPX Access Roads

Hydrographic FeaturesPerennial StreamIntermittent Stream

6S 91W

Sec. 17

Sec. 20

Sec. 16Sec. 18

Sec. 21Sec. 19

Sec. 9 Attachment A--Sample Location MapLocation: KP 34-17

WPX Energy Rocky Mountain, LLC

T:\Client_Specific\2008\Williams_EP\Spills\2013\KP 34-17 Spill\KP 34-17 Attachment A.mxd HCSI_jharris Revision Date: 7/10/2013 4:34:15 PM

S i t e V i c i n i t y

0 2,000 FeetDISCLAIMER : This Geographic Information System (GIS) and itscomponents are designed as a source of reference for answeringinquiries, for planning and for modeling. GIS is not intended, nor does itreplace legal description information in the chain of title and otherinformation contained in official government records such as the CountyClerk and Recorders office or the courts. In addition, the representationsof locations in this GIS cannot be substituted for actual legal surveys.

Total Affected Area =~11,464 Ft2

05-Jul-2013

WPX Energy Rocky Mountain, LLCKarolina Blaney

Dear Karolina,

Re: Kokopelli Riser Water 7/2/13 Work Order: 1307091

1058 Country Rd 215Parachute, CO 81635

ALS Environmental received 3 samples on 03-Jul-2013 09:30 AM for the analyses presented in the following report.

Project ManagerAnn Preston

Ann PrestonElectronically approved by: Bill Carey

Certificate No: MN 532786

The analytical data provided relates directly to the samples received by ALS Environmental and for only the analyses requested.

Sample results are compliant with NELAP standard requirements and QC results achieved laboratory specifications. Any exceptions are noted in the Case Narrative, or noted with qualifiers in the report or QC batch information. Should this laboratory report need to be reproduced, it should be reproduced in fullunless written approval has been obtained from ALS Environmental. Samples will be disposed in 30 daysunless storage arrangements are made.

The total number of pages in this report is 15.

If you have any questions regarding this report, please feel free to contact me.

Sincerely,

ADDRESS 3352 128th Avenue Holland, Michigan 49424-9263 | PHONE (616) 399-6070 | FAX (616) 399-6185

Report of Laboratory Analysis

Date: 05-Jul-13ALS Group USA, Corp

Project: Kokopelli Riser Water 7/2/13Client: WPX Energy Rocky Mountain, LLC

Work Order: 1307091Work Order Sample Summary

Lab Samp ID Client Sample ID Collection DateTag Number Date ReceivedMatrix Hold1307091-01 Ditch 1 Water 7/2/2013 14:40 7/3/2013 09:301307091-02 Pond 1 Water 7/2/2013 14:50 7/3/2013 09:301307091-03 Pond 2 Water 7/2/2013 15:30 7/3/2013 09:30

Sample Summary Page 1 of 1

ALS Group USA, Corp Date: 05-Jul-13

QUALIFIERS, ACRONYMS, UNITSProject: Kokopelli Riser Water 7/2/13

Client: WPX Energy Rocky Mountain, LLC

WorkOrder: 1307091

Units Reported Description

Qualifier Description

Acronym Description

Micrograms per Literµg/LMilligrams per Litermg/L

Value exceeds Regulatory Limit*Not accreditedaAnalyte detected in the associated Method Blank above the Reporting LimitBValue above quantitation rangeEAnalyzed outside of Holding TimeHAnalyte is present at an estimated concentration between the MDL and Report LimitJNot offered for accreditationnNot Detected at the Reporting LimitNDSample amount is > 4 times amount spikedODual Column results percent difference > 40%PRPD above laboratory control limitRSpike Recovery outside laboratory control limitsSAnalyzed but not detected above the MDLU

Method DuplicateDUP

Laboratory Control SampleLCS

Laboratory Control Sample DuplicateLCSD

Method BlankMBLK

Method Detection LimitMDL

Matrix SpikeMS

Matrix Spike DuplicateMSD

Relative Percent DifferenceRPD

Target Detection LimitTDL

APHA Standard MethodsA

ASTMD

EPAE

SW-846 Update IIISW

Qualifiers Page 1 of 1


Project: Kokopelli Riser Water 7/2/13Client: WPX Energy Rocky Mountain, LLC

Work Order: 1307091Case Narrative

Batch 49488, Sample 13061112-31BMS and MSD: The MS and/or MSD recovery was outside of the control. The parent sample is unrelated to this Work Order.

Case Narrative Page 1 of 1

Project: Kokopelli Riser Water 7/2/13Sample ID: Ditch 1Collection Date: 7/2/2013 02:40 PM Matrix: WATER

Analyses Result Qual Units Date AnalyzedReport Limit

Client: WPX Energy Rocky Mountain, LLCWork Order: 1307091

Dilution Factor

Lab ID: 1307091-01


METALS BY ICP-MS SW6020A Analyst: MLPrep Date: 7/3/2013Magnesium 7/3/2013 06:57 PM20 mg/L 100380

VOLATILE ORGANIC COMPOUNDS SW8260 Analyst: AKBenzene 7/3/2013 09:47 AM1.0 µg/L 191Ethylbenzene 7/3/2013 09:47 AM1.0 µg/L 114m,p-Xylene 7/3/2013 09:47 AM2.0 µg/L 1170o-Xylene 7/3/2013 09:47 AM1.0 µg/L 140Toluene 7/3/2013 11:48 AM5.0 µg/L 5180Xylenes, Total 7/3/2013 09:47 AM3.0 µg/L 1210 Surr: 1,2-Dichloroethane-d4 7/3/2013 11:48 AM70-120 %REC 596.8 Surr: 1,2-Dichloroethane-d4 7/3/2013 09:47 AM70-120 %REC 1101 Surr: 4-Bromofluorobenzene 7/3/2013 09:47 AM75-120 %REC 1106 Surr: 4-Bromofluorobenzene 7/3/2013 11:48 AM75-120 %REC 596.8 Surr: Dibromofluoromethane 7/3/2013 09:47 AM85-115 %REC 197.2 Surr: Dibromofluoromethane 7/3/2013 11:48 AM85-115 %REC 593.0 Surr: Toluene-d8 7/3/2013 11:48 AM85-120 %REC 595.1 Surr: Toluene-d8 7/3/2013 09:47 AM85-120 %REC 1102

ANIONS BY ION CHROMATOGRAPHY SW9056 Analyst: EDChloride 7/3/2013 11:23 AM400 mg/L 4005,200Sulfate 7/3/2013 11:02 AM20 mg/L 2095

TOTAL DISSOLVED SOLIDS A2540 C Analyst: JJGTotal Dissolved Solids 7/3/2013 10:02 AM10 mg/L 112,000

Analytical Results Page 1 of 3

Note: See Qualifiers page for a list of qualifiers and their definitions.

Project: Kokopelli Riser Water 7/2/13Sample ID: Pond 1Collection Date: 7/2/2013 02:50 PM Matrix: WATER



Dilution Factor

Lab ID: 1307091-02


METALS BY ICP-MS SW6020A Analyst: MLPrep Date: 7/3/2013Magnesium 7/3/2013 06:27 PM0.20 mg/L 113

VOLATILE ORGANIC COMPOUNDS SW8260 Analyst: AKBenzene 7/3/2013 08:59 AM1.0 µg/L 12.7Ethylbenzene 7/3/2013 08:59 AM1.0 µg/L 1NDm,p-Xylene 7/3/2013 08:59 AM2.0 µg/L 15.9o-Xylene 7/3/2013 08:59 AM1.0 µg/L 11.2Toluene 7/3/2013 08:59 AM1.0 µg/L 16.7Xylenes, Total 7/3/2013 08:59 AM3.0 µg/L 17.1 Surr: 1,2-Dichloroethane-d4 7/3/2013 08:59 AM70-120 %REC 197.6 Surr: 4-Bromofluorobenzene 7/3/2013 08:59 AM75-120 %REC 199.8 Surr: Dibromofluoromethane 7/3/2013 08:59 AM85-115 %REC 195.0 Surr: Toluene-d8 7/3/2013 08:59 AM85-120 %REC 195.3

ANIONS BY ION CHROMATOGRAPHY SW9056 Analyst: EDChloride 7/3/2013 12:23 PM4.0 mg/L 462Sulfate 7/3/2013 10:42 AM1.0 mg/L 18.9

TOTAL DISSOLVED SOLIDS A2540 C Analyst: JJGTotal Dissolved Solids 7/3/2013 10:02 AM10 mg/L 1260



Project: Kokopelli Riser Water 7/2/13Sample ID: Pond 2Collection Date: 7/2/2013 03:30 PM Matrix: WATER



Dilution Factor

Lab ID: 1307091-03


METALS BY ICP-MS SW6020A Analyst: MLPrep Date: 7/3/2013Magnesium 7/3/2013 06:33 PM0.20 mg/L 19.2

VOLATILE ORGANIC COMPOUNDS SW8260 Analyst: AKBenzene 7/3/2013 09:23 AM1.0 µg/L 1NDEthylbenzene 7/3/2013 09:23 AM1.0 µg/L 1NDm,p-Xylene 7/3/2013 09:23 AM2.0 µg/L 1NDo-Xylene 7/3/2013 09:23 AM1.0 µg/L 1NDToluene 7/3/2013 09:23 AM1.0 µg/L 1NDXylenes, Total 7/3/2013 09:23 AM3.0 µg/L 1ND Surr: 1,2-Dichloroethane-d4 7/3/2013 09:23 AM70-120 %REC 1102 Surr: 4-Bromofluorobenzene 7/3/2013 09:23 AM75-120 %REC 1104 Surr: Dibromofluoromethane 7/3/2013 09:23 AM85-115 %REC 197.2 Surr: Toluene-d8 7/3/2013 09:23 AM85-120 %REC 199.2

ANIONS BY ION CHROMATOGRAPHY SW9056 Analyst: EDChloride 7/3/2013 10:22 AM1.0 mg/L 14.1Sulfate 7/3/2013 10:22 AM1.0 mg/L 18.6

TOTAL DISSOLVED SOLIDS A2540 C Analyst: JJGTotal Dissolved Solids 7/3/2013 10:02 AM10 mg/L 1150




Project: Kokopelli Riser Water 7/2/13


QC BATCH REPORT

Batch ID: 49488 Instrument ID ICPMS1 Method: SW6020A

QualRPD Limit

Analysis Date: 7/3/2013 05:57 PM

Prep Date: 7/3/2013

Analyte Result %REC %RPD

Units:mg/L

PQL

Client ID: SeqNo:2369533

MBLK

Run ID: ICPMS1_130703A

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1

Sample ID: MBLK-49488-49488

Magnesium 0.20ND

QualRPD Limit


Prep Date: 7/3/2013


Units:mg/L

PQL


LCS


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1

Sample ID: LCS-49488-49488

0010Magnesium 98.1 80-1200.209.809

QualRPD Limit


Prep Date: 7/3/2013


Units:mg/L

PQL


MS


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1

Sample ID: 13061112-31BMS

SO036.661Magnesium 9960 80-1201.0136.3

QualRPD Limit


Prep Date: 7/3/2013


Units:mg/L

PQL


MSD


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1

Sample ID: 13061112-31BMSD

SO136.736.661Magnesium 9950 80-120 201.0 0.366136.2

The following samples were analyzed in this batch: 1307091-01C 1307091-02C 1307091-03C

QC Page: 1 of 5Note: See Qualifiers Page for a list of Qualifiers and their explanation.



QC BATCH REPORT

Batch ID: R123111 Instrument ID VMS7 Method: SW8260

QualRPD Limit

Analysis Date: 7/3/2013 03:44 AM

Prep Date:


Units:µg/L

PQL


MBLK

Run ID: VMS7_130702B

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1

Sample ID: VBLKW2-130702-R123111

Benzene 1.0NDEthylbenzene 1.0NDm,p-Xylene 2.0NDo-Xylene 1.0NDToluene 1.0NDXylenes, Total 3.0ND

0020 Surr: 1,2-Dichloroethane-d4 98.7 70-120019.740020 Surr: 4-Bromofluorobenzene 100 75-120020.010020 Surr: Dibromofluoromethane 97 85-115019.40020 Surr: Toluene-d8 98.4 85-120019.69

QualRPD Limit


Prep Date:


Units:µg/L

PQL


LCS


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1

Sample ID: VLCSW2-130702-R123111

0020Benzene 94.4 80-1201.018.890020Ethylbenzene 97.3 75-1251.019.460040m,p-Xylene 98.4 75-1302.039.370020o-Xylene 103 80-1201.020.540020Toluene 89.5 75-1201.017.90060Xylenes, Total 99.8 75-1303.059.910020 Surr: 1,2-Dichloroethane-d4 98.9 70-120019.780020 Surr: 4-Bromofluorobenzene 103 75-120020.590020 Surr: Dibromofluoromethane 99.7 85-115019.940020 Surr: Toluene-d8 96.9 85-120019.38

QualRPD Limit


Prep Date:


Units:µg/L

PQL


MS


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1

Sample ID: 13061120-29A MS

01.1420Benzene 92.4 80-1201.019.6109.3820Ethylbenzene 100 75-1251.029.390040m,p-Xylene 97 75-1302.038.80020o-Xylene 98 80-1201.019.610020Toluene 92.4 75-1201.018.480060Xylenes, Total 97.4 75-1303.058.410020 Surr: 1,2-Dichloroethane-d4 99 70-120019.80020 Surr: 4-Bromofluorobenzene 104 75-120020.830020 Surr: Dibromofluoromethane 95.8 85-115019.170020 Surr: Toluene-d8 96 85-120019.21




QC BATCH REPORT


QualRPD Limit


Prep Date:


Units:µg/L

PQL


MSD


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1

Sample ID: 13061120-29A MSD

19.611.1420Benzene 91.8 80-120 301.0 0.61419.4929.399.3820Ethylbenzene 101 75-125 301.0 0.57729.56

38.8040m,p-Xylene 95.9 75-130 302.0 1.1438.3619.61020o-Xylene 96.4 80-120 301.0 1.7519.2718.48020Toluene 88.6 75-120 301.0 4.217.7258.41060Xylenes, Total 96 75-130 303.0 1.3457.63

19.8020 Surr: 1,2-Dichloroethane-d4 97.2 70-120 300 1.8319.4420.83020 Surr: 4-Bromofluorobenzene 102 75-120 300 1.6520.4919.17020 Surr: Dibromofluoromethane 96.7 85-115 300 0.88319.3419.21020 Surr: Toluene-d8 96.2 85-120 300 0.20819.25

The following samples were analyzed in this batch: 1307091-01A 1307091-02A 1307091-03A




QC BATCH REPORT

Batch ID: R123164 Instrument ID IC3 Method: SW9056

QualRPD Limit


Prep Date:


Units:mg/L

PQL


MBLK

Run ID: IC3_130703A

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1

Sample ID: CCB/MBLK-R123164

Chloride 1.0NDSulfate 1.0ND

QualRPD Limit


Prep Date:


Units:mg/L

PQL


LCS

Run ID: IC3_130703A

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1

Sample ID: LCS-R123164

0010Chloride 95.3 88-1071.09.5290010Sulfate 96.9 85-1101.09.687

QualRPD Limit


Prep Date:


Units:mg/L

PQL

Client ID: Pond 2 SeqNo:2369237

MS

Run ID: IC3_130703A

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1

Sample ID: 1307091-03B MS

04.11910Chloride 102 75-1251.014.2908.55410Sulfate 101 75-1251.018.63

QualRPD Limit


Prep Date:


Units:mg/L

PQL

Client ID: Pond 2 SeqNo:2369238

MSD

Run ID: IC3_130703A

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1

Sample ID: 1307091-03B MSD

14.294.11910Chloride 97.5 75-125 201.0 3.0313.8718.638.55410Sulfate 96 75-125 201.0 2.618.15

The following samples were analyzed in this batch: 1307091-01B 1307091-02B 1307091-03B




QC BATCH REPORT

Batch ID: R123166 Instrument ID TDS Method: A2540 C

QualRPD Limit


Prep Date:


Units:mg/L

PQL


MBLK

Run ID: TDS_130703A

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1

Sample ID: MBLK-R123166

Total Dissolved Solids 10ND

QualRPD Limit


Prep Date:


Units:mg/L

PQL


LCS

Run ID: TDS_130703A

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1


00495Total Dissolved Solids 86.5 80-12010428

QualRPD Limit


Prep Date:


Units:mg/L

PQL

Client ID: Ditch 1 SeqNo:2369266

DUP

Run ID: TDS_130703A

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1

Sample ID: 1307091-01B DUP

1245000Total Dissolved Solids 0 0-0 2010 5.2111820

The following samples were analyzed in this batch: 1307091-01B 1307091-02B 1307091-03B


ALS Group USA, Corp

Sample Receipt Checklist

Client Name: WPX

Work Order: 1307091

Date/Time Received: 03-Jul-13 09:30

Received by: DS

Checklist completed byeSignature Date

Reviewed by:DateeSignature

Matrices: WaterCarrier name: FedEx

Shipping container/cooler in good condition? Yes No Not Present

Custody seals intact on shipping container/cooler? Yes No Not Present

Custody seals intact on sample bottles? Yes No Not Present

Chain of custody present? Yes No

Chain of custody signed when relinquished and received? Yes No

Chain of custody agrees with sample labels? Yes No

Samples in proper container/bottle? Yes No

Sample containers intact? Yes No

Sufficient sample volume for indicated test? Yes No

All samples received within holding time? Yes No

Container/Temp Blank temperature in compliance? Yes No

Yes No No VOA vials submittedWater - VOA vials have zero headspace?

Water - pH acceptable upon receipt? Yes No N/A

Temperature(s)/Thermometer(s): 3.0 c

Login Notes:

Cooler(s)/Kit(s):

03-Jul-13 03-Jul-13 Diane Shaw Ann Preston

pH adjusted? Yes No N/ApH adjusted by:

Date/Time sample(s) sent to storage: 7/3/2013 9:45:23 AM

CorrectiveAction:

Comments:

Client Contacted: Date Contacted: Person Contacted:

Contacted By: Regarding:

SRC Page 1 of 1

12-Jul-2013

HRL Compliance SolutionsMark Mumby

Dear Mark,

Re: WPX KP 34-17 Produced Water Line Break Work Order: 1307193

2385 F 1/2 RoadGrand Junction, CO 81505



Ann PrestonElectronically approved by: Ann Preston






Sincerely,




Project: WPX KP 34-17 Produced Water Line BreakClient: HRL Compliance Solutions


Lab Samp ID Client Sample ID Collection DateTag Number Date ReceivedMatrix Hold1307193-01 Ditch 2 Water 7/2/2013 16:15 7/6/2013 09:451307193-02 Ditch 3 Soil 7/2/2013 16:20 7/6/2013 09:451307193-03 Ditch 4 Soil 7/2/2013 16:50 7/6/2013 09:451307193-04 Ditch 5 Soil 7/2/2013 17:05 7/6/2013 09:451307193-05 Point of Origin Soil 7/2/2013 16:55 7/6/2013 09:451307193-06 BKGD 1 Soil 7/2/2013 16:55 7/6/2013 09:451307193-07 BKGD 2 Soil 7/2/2013 17:05 7/6/2013 09:451307193-08 BKGD 3 Soil 7/2/2013 17:10 7/6/2013 09:45



Project: WPX KP 34-17 Produced Water Line BreakClient: HRL Compliance Solutions

Work Order: 1307193Case Narrative

Batch 49547 sample 1307193-05 DRO surrogate recovery was above the upper control limits. The sample results may be biased high due to matrix interference.

Batch 49553 MS/MSD data for Metals is not related to this project's samples. No data requires qualification.

Case Narrative Page 1 of 1




Acronym Description

Percent of Sample% of sampleMicrograms per Kilogram Dry Weightµg/Kg-dryMicrograms per Literµg/LMilligrams per Kilogram Dry Weightmg/Kg-dryMilligrams per Litermg/LMillimhos-Centimeter at 25 Degrees Celciusmmhos/cm @25°

noneStandard Unitss.u.


Method DuplicateDUP



Limit of Detection (see MDL)LOD

Limit of Quantitation (see PQL)LOQ

Method BlankMBLK


Matrix SpikeMS


Practical Quantitation LimitPQL




ASTMD

EPAE

SW-846 Update IIISW


Project: WPX KP 34-17 Produced Water Line BreakSample ID: Ditch 2Collection Date: 7/2/2013 04:15 PM Matrix: WATER


Client: HRL Compliance SolutionsWork Order: 1307193

Dilution Factor

Lab ID: 1307193-01


METALS BY ICP-MS SW6020A Analyst: MLPrep Date: 7/8/2013Magnesium 7/8/2013 09:24 PM0.20 mg/L 1120

VOLATILE ORGANIC COMPOUNDS SW8260 Analyst: BGBenzene 7/9/2013 02:10 PM5.0 µg/L 5220Ethylbenzene 7/9/2013 02:10 PM5.0 µg/L 56.6m,p-Xylene 7/9/2013 02:10 PM10 µg/L 562o-Xylene 7/9/2013 02:10 PM5.0 µg/L 520Toluene 7/9/2013 02:10 PM5.0 µg/L 5260Xylenes, Total 7/9/2013 02:10 PM15 µg/L 582 Surr: 1,2-Dichloroethane-d4 7/9/2013 02:10 PM70-120 %REC 5102 Surr: 4-Bromofluorobenzene 7/9/2013 02:10 PM75-120 %REC 5101 Surr: Dibromofluoromethane 7/9/2013 02:10 PM85-115 %REC 595.0 Surr: Toluene-d8 7/9/2013 02:10 PM85-120 %REC 599.8

ANIONS BY ION CHROMATOGRAPHY SW9056 Analyst: EDChloride 7/8/2013 01:03 PM400 mg/L 4004,500Sulfate 7/8/2013 11:22 AM10 mg/L 1021

TOTAL DISSOLVED SOLIDS A2540 C-97 Analyst: YMTotal Dissolved Solids 7/9/2013 11:26 AM10 mg/L 16,000



Project: WPX KP 34-17 Produced Water Line BreakSample ID: Ditch 3Collection Date: 7/2/2013 04:20 PM Matrix: SOIL



Dilution Factor

Lab ID: 1307193-02


DIESEL RANGE ORGANICS BY GC-FID SW8015M Analyst: CWPrep Date: 7/8/2013DRO (C10-C28) 7/9/2013 02:15 PM5.2 mg/Kg-dry 1110 Surr: 4-Terphenyl-d14 7/9/2013 02:15 PM39-115 %REC 198.7

GASOLINE RANGE ORGANICS BY GC-FID SW8015 Analyst: CWGRO (C6-C10) 7/9/2013 03:14 AM3.1 mg/Kg-dry 5027 Surr: Toluene-d8 7/9/2013 03:14 AM50-150 %REC 50128

MERCURY BY CVAA SW7471 Analyst: LRPrep Date: 7/10/2013Mercury 7/10/2013 03:58 PM0.019 mg/Kg-dry 1ND

METALS BY ICP-MS SW6020A Analyst: MLPrep Date: 7/8/2013Arsenic 7/9/2013 04:10 AM2.0 mg/Kg-dry 53.2Barium 7/9/2013 04:10 AM2.0 mg/Kg-dry 5270Cadmium 7/9/2013 04:10 AM0.81 mg/Kg-dry 5NDChromium 7/9/2013 04:10 AM2.0 mg/Kg-dry 511Copper 7/9/2013 04:10 AM2.0 mg/Kg-dry 59.1Lead 7/9/2013 04:10 AM2.0 mg/Kg-dry 59.0Nickel 7/9/2013 09:03 PM2.2 mg/Kg-dry 513Selenium 7/9/2013 04:10 AM2.0 mg/Kg-dry 5NDSilver 7/9/2013 04:10 AM2.0 mg/Kg-dry 5NDZinc 7/9/2013 04:10 AM4.1 mg/Kg-dry 539

SOLUBLE CATIONS FOR SAR SW6020A Analyst: RHPrep Date: 7/10/2013Calcium 7/10/2013 11:54 AM10 mg/L 2071Magnesium 7/10/2013 11:54 AM4.0 mg/L 2026Sodium 7/10/2013 11:54 AM4.0 mg/L 201,900

SODIUM ADSORPTION RATIO USDA H60 METHO Analyst: RHPrep Date: 7/10/2013Sodium Adsorption Ratio 7/10/20130.010 none 149

SEMI-VOLATILE ORGANIC COMPOUNDS SW8270 Analyst: RMPrep Date: 7/8/2013Acenaphthene 7/9/2013 03:29 PM19 µg/Kg-dry 1NDAcenaphthylene 7/9/2013 03:29 PM37 µg/Kg-dry 1NDAnthracene 7/9/2013 03:29 PM19 µg/Kg-dry 1NDBenzo(a)anthracene 7/9/2013 03:29 PM21 µg/Kg-dry 1NDBenzo(a)pyrene 7/9/2013 03:29 PM21 µg/Kg-dry 1NDBenzo(b)fluoranthene 7/9/2013 03:29 PM22 µg/Kg-dry 1NDBenzo(g,h,i)perylene 7/9/2013 03:29 PM35 µg/Kg-dry 1NDBenzo(k)fluoranthene 7/9/2013 03:29 PM22 µg/Kg-dry 1NDChrysene 7/9/2013 03:29 PM19 µg/Kg-dry 1NDDibenzo(a,h)anthracene 7/9/2013 03:29 PM22 µg/Kg-dry 1NDFluoranthene 7/9/2013 03:29 PM19 µg/Kg-dry 1ND






Dilution Factor

Lab ID: 1307193-02


Fluorene 7/9/2013 03:29 PM19 µg/Kg-dry 1NDIndeno(1,2,3-cd)pyrene 7/9/2013 03:29 PM25 µg/Kg-dry 1NDNaphthalene 7/9/2013 03:29 PM19 µg/Kg-dry 136Pyrene 7/9/2013 03:29 PM19 µg/Kg-dry 1ND Surr: 2-Fluorobiphenyl 7/9/2013 03:29 PM12-100 %REC 170.1 Surr: 4-Terphenyl-d14 7/9/2013 03:29 PM25-137 %REC 1118 Surr: Nitrobenzene-d5 7/9/2013 03:29 PM37-107 %REC 167.9

VOLATILE ORGANIC COMPOUNDS SW8260B Analyst: AKPrep Date: 7/8/2013Benzene 7/8/2013 05:12 PM38 µg/Kg-dry 1NDEthylbenzene 7/8/2013 05:12 PM38 µg/Kg-dry 1NDm,p-Xylene 7/8/2013 05:12 PM75 µg/Kg-dry 1300o-Xylene 7/8/2013 05:12 PM38 µg/Kg-dry 173Toluene 7/8/2013 05:12 PM38 µg/Kg-dry 190Xylenes, Total 7/8/2013 05:12 PM110 µg/Kg-dry 1370 Surr: 1,2-Dichloroethane-d4 7/8/2013 05:12 PM70-130 %REC 1100 Surr: 4-Bromofluorobenzene 7/8/2013 05:12 PM70-130 %REC 1108 Surr: Dibromofluoromethane 7/8/2013 05:12 PM70-130 %REC 195.0 Surr: Toluene-d8 7/8/2013 05:12 PM70-130 %REC 194.6

ELECTRICAL CONDUCTIVITY (SAR) USDA H60 METHO Analyst: JBPrep Date: 7/10/2013Electrical Conductivity @ Saturation 7/10/2013 02:45 PM0.025 mmhos/cm @25 511

CHROMIUM, TRIVALENT CALCULATION Analyst: MBChromium, Trivalent 7/11/2013 11:00 AM0.63 mg/Kg-dry 111

CHROMIUM, HEXAVALENT SW7196A Analyst: JBPrep Date: 7/8/2013Chromium, Hexavalent 7/9/2013 04:30 PM0.62 mg/Kg-dry 1ND

MOISTURE A2540 G Analyst: BDMoisture 7/8/2013 12:00 PM0.050 % of sample 120

PH SW9045D Analyst: CHpH 7/8/2013 09:05 AMs.u. 18.6






Dilution Factor

Lab ID: 1307193-03





METALS BY ICP-MS SW6020A Analyst: MLPrep Date: 7/8/2013Arsenic 7/9/2013 04:34 AM2.0 mg/Kg-dry 53.9Barium 7/9/2013 04:34 AM2.0 mg/Kg-dry 5360Cadmium 7/9/2013 04:34 AM0.81 mg/Kg-dry 5NDChromium 7/9/2013 04:34 AM2.0 mg/Kg-dry 515Copper 7/9/2013 04:34 AM2.0 mg/Kg-dry 511Lead 7/9/2013 04:34 AM2.0 mg/Kg-dry 511Nickel 7/9/2013 09:08 PM2.0 mg/Kg-dry 516Selenium 7/9/2013 04:34 AM2.0 mg/Kg-dry 5NDSilver 7/9/2013 04:34 AM2.0 mg/Kg-dry 5NDZinc 7/9/2013 04:34 AM4.0 mg/Kg-dry 558

SOLUBLE CATIONS FOR SAR SW6020A Analyst: RHPrep Date: 7/10/2013Calcium 7/10/2013 11:59 AM10 mg/L 2085Magnesium 7/10/2013 11:59 AM4.0 mg/L 2024Sodium 7/10/2013 11:59 AM4.0 mg/L 201,800








Dilution Factor

Lab ID: 1307193-03


Fluorene 7/9/2013 03:48 PM19 µg/Kg-dry 1NDIndeno(1,2,3-cd)pyrene 7/9/2013 03:48 PM25 µg/Kg-dry 1NDNaphthalene 7/9/2013 03:48 PM19 µg/Kg-dry 122Pyrene 7/9/2013 03:48 PM19 µg/Kg-dry 1ND Surr: 2-Fluorobiphenyl 7/9/2013 03:48 PM12-100 %REC 158.1 Surr: 4-Terphenyl-d14 7/9/2013 03:48 PM25-137 %REC 193.2 Surr: Nitrobenzene-d5 7/9/2013 03:48 PM37-107 %REC 156.5

VOLATILE ORGANIC COMPOUNDS SW8260B Analyst: AKPrep Date: 7/8/2013Benzene 7/8/2013 05:37 PM39 µg/Kg-dry 1270Ethylbenzene 7/8/2013 05:37 PM39 µg/Kg-dry 150m,p-Xylene 7/8/2013 05:37 PM77 µg/Kg-dry 1560o-Xylene 7/8/2013 05:37 PM39 µg/Kg-dry 1130Toluene 7/8/2013 05:37 PM39 µg/Kg-dry 1650Xylenes, Total 7/8/2013 05:37 PM120 µg/Kg-dry 1690 Surr: 1,2-Dichloroethane-d4 7/8/2013 05:37 PM70-130 %REC 195.8 Surr: 4-Bromofluorobenzene 7/8/2013 05:37 PM70-130 %REC 1110 Surr: Dibromofluoromethane 7/8/2013 05:37 PM70-130 %REC 192.4 Surr: Toluene-d8 7/8/2013 05:37 PM70-130 %REC 192.5











Dilution Factor

Lab ID: 1307193-04



GASOLINE RANGE ORGANICS BY GC-FID SW8015 Analyst: CWGRO (C6-C10) 7/9/2013 04:04 AM3.3 mg/Kg-dry 50ND Surr: Toluene-d8 7/9/2013 04:04 AM50-150 %REC 50118



SOLUBLE CATIONS FOR SAR SW6020A Analyst: RHPrep Date: 7/10/2013Calcium 7/10/2013 12:05 PM10 mg/L 2057Magnesium 7/10/2013 12:05 PM4.0 mg/L 2012Sodium 7/10/2013 12:05 PM4.0 mg/L 201,800








Dilution Factor

Lab ID: 1307193-04


Fluorene 7/9/2013 04:08 PM20 µg/Kg-dry 1NDIndeno(1,2,3-cd)pyrene 7/9/2013 04:08 PM26 µg/Kg-dry 1NDNaphthalene 7/9/2013 04:08 PM20 µg/Kg-dry 1NDPyrene 7/9/2013 04:08 PM20 µg/Kg-dry 1ND Surr: 2-Fluorobiphenyl 7/9/2013 04:08 PM12-100 %REC 162.1 Surr: 4-Terphenyl-d14 7/9/2013 04:08 PM25-137 %REC 196.0 Surr: Nitrobenzene-d5 7/9/2013 04:08 PM37-107 %REC 161.4

VOLATILE ORGANIC COMPOUNDS SW8260B Analyst: AKPrep Date: 7/8/2013Benzene 7/8/2013 06:03 PM39 µg/Kg-dry 1NDEthylbenzene 7/8/2013 06:03 PM39 µg/Kg-dry 1NDm,p-Xylene 7/8/2013 06:03 PM79 µg/Kg-dry 1NDo-Xylene 7/8/2013 06:03 PM39 µg/Kg-dry 1NDToluene 7/8/2013 06:03 PM39 µg/Kg-dry 1NDXylenes, Total 7/8/2013 06:03 PM120 µg/Kg-dry 1ND Surr: 1,2-Dichloroethane-d4 7/8/2013 06:03 PM70-130 %REC 194.8 Surr: 4-Bromofluorobenzene 7/8/2013 06:03 PM70-130 %REC 1109 Surr: Dibromofluoromethane 7/8/2013 06:03 PM70-130 %REC 192.8 Surr: Toluene-d8 7/8/2013 06:03 PM70-130 %REC 194.6

ELECTRICAL CONDUCTIVITY (SAR) USDA H60 METHO Analyst: JBPrep Date: 7/10/2013Electrical Conductivity @ Saturation 7/10/2013 02:45 PM0.025 mmhos/cm @25 59.4







Project: WPX KP 34-17 Produced Water Line BreakSample ID: Point of OriginCollection Date: 7/2/2013 04:55 PM Matrix: SOIL



Dilution Factor

Lab ID: 1307193-05


DIESEL RANGE ORGANICS BY GC-FID SW8015M Analyst: RDPrep Date: 7/8/2013DRO (C10-C28) 7/9/2013 04:28 AM5.3 mg/Kg-dry 1390 Surr: 4-Terphenyl-d14 S 7/9/2013 04:28 AM39-115 %REC 1393




SOLUBLE CATIONS FOR SAR SW6020A Analyst: RHPrep Date: 7/10/2013Calcium 7/10/2013 12:10 PM10 mg/L 2035Magnesium 7/10/2013 12:10 PM4.0 mg/L 206.4Sodium 7/10/2013 12:10 PM4.0 mg/L 201,800





Project: WPX KP 34-17 Produced Water Line BreakSample ID: Point of OriginCollection Date: 7/2/2013 04:55 PM Matrix: SOIL



Dilution Factor

Lab ID: 1307193-05


Fluorene 7/9/2013 02:28 PM19 µg/Kg-dry 188Indeno(1,2,3-cd)pyrene 7/9/2013 02:28 PM25 µg/Kg-dry 1NDNaphthalene 7/9/2013 02:28 PM19 µg/Kg-dry 1130Pyrene 7/9/2013 02:28 PM19 µg/Kg-dry 1ND Surr: 2-Fluorobiphenyl 7/9/2013 02:28 PM12-100 %REC 163.2 Surr: 4-Terphenyl-d14 7/9/2013 02:28 PM25-137 %REC 194.5 Surr: Nitrobenzene-d5 7/9/2013 02:28 PM37-107 %REC 161.3

VOLATILE ORGANIC COMPOUNDS SW8260B Analyst: AKPrep Date: 7/8/2013Benzene 7/8/2013 06:27 PM38 µg/Kg-dry 1NDEthylbenzene 7/8/2013 06:27 PM38 µg/Kg-dry 180m,p-Xylene 7/8/2013 06:27 PM76 µg/Kg-dry 11,700o-Xylene 7/8/2013 06:27 PM38 µg/Kg-dry 1390Toluene 7/8/2013 06:27 PM38 µg/Kg-dry 171Xylenes, Total 7/8/2013 06:27 PM110 µg/Kg-dry 12,100 Surr: 1,2-Dichloroethane-d4 7/8/2013 06:27 PM70-130 %REC 1102 Surr: 4-Bromofluorobenzene 7/8/2013 06:27 PM70-130 %REC 1114 Surr: Dibromofluoromethane 7/8/2013 06:27 PM70-130 %REC 195.6 Surr: Toluene-d8 7/8/2013 06:27 PM70-130 %REC 199.4








Project: WPX KP 34-17 Produced Water Line BreakSample ID: BKGD 1Collection Date: 7/2/2013 04:55 PM Matrix: SOIL



Dilution Factor

Lab ID: 1307193-06


METALS BY ICP-MS SW6020A Analyst: MLPrep Date: 7/9/2013Arsenic 7/9/2013 09:26 PM1.9 mg/Kg-dry 54.1

MOISTURE A2540 G Analyst: BDMoisture 7/8/2013 12:00 PM0.050 % of sample 10.69






Dilution Factor

Lab ID: 1307193-07









Dilution Factor

Lab ID: 1307193-08



SOLUBLE CATIONS FOR SAR SW6020A Analyst: RHPrep Date: 7/10/2013Calcium 7/10/2013 12:15 PM10 mg/L 20140Magnesium 7/10/2013 12:15 PM4.0 mg/L 20130Sodium 7/10/2013 12:15 PM4.0 mg/L 2060

SODIUM ADSORPTION RATIO USDA H60 METHO Analyst: RHPrep Date: 7/10/2013Sodium Adsorption Ratio 7/10/20130.010 none 10.88







Project: WPX KP 34-17 Produced Water Line Break


QC BATCH REPORT

Batch ID: 49547 Instrument ID GC8 Method: SW8015M

QualRPD Limit


Prep Date: 7/8/2013


Units: mg/Kg

PQL

Client ID: SeqNo: 2373471

MBLK

Run ID: GC8_130708B

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1

Sample ID: DBLKS1-49547-49547

DRO (C10-C28) 4.2ND001.667 Surr: 4-Terphenyl-d14 59.1 39-11500.9847

QualRPD Limit


Prep Date: 7/8/2013


Units: mg/Kg

PQL


LCS

Run ID: GC8_130708B

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1

Sample ID: DLCSS1-49547-49547

00166.7DRO (C10-C28) 89.1 49-1244.2148.6001.667 Surr: 4-Terphenyl-d14 41.3 39-11500.6883

QualRPD Limit


Prep Date: 7/8/2013


Units: mg/Kg

PQL


MS

Run ID: GC8_130708B

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1


054.56464.6DRO (C10-C28) 79.6 49-13012424.3004.646 Surr: 4-Terphenyl-d14 57 39-11502.65

QualRPD Limit


Prep Date: 7/8/2013


Units: mg/Kg

PQL


MSD

Run ID: GC8_130708B

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1


424.354.56481.5DRO (C10-C28) 76.5 49-130 3012 0.288423.12.6504.815 Surr: 4-Terphenyl-d14 44.1 39-115 300 22.22.122

The following samples were analyzed in this batch: 1307193-02B 1307193-03B 1307193-04B1307193-05B




QC BATCH REPORT

Batch ID: R123306 Instrument ID GC9 Method: SW8015

QualRPD Limit


Prep Date:


Units: µg/L

PQL


MBLK

Run ID: GC9_130708B

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1

Sample ID: GBLK2-130708-R123306

GRO (C6-C10) 200ND00100 Surr: Toluene-d8 119 70-1300118.8

QualRPD Limit


Prep Date:


Units: µg/L

PQL


LCS

Run ID: GC9_130708B

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1

Sample ID: GLCS2-130708-R123306

0010000GRO (C6-C10) 86.5 70-130200864900100 Surr: Toluene-d8 115 70-1300115.3

QualRPD Limit


Prep Date:


Units: µg/L

PQL


MS

Run ID: GC9_130708B

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1


0010000GRO (C6-C10) 80.5 70-130200804700100 Surr: Toluene-d8 112 70-1300112.3

QualRPD Limit


Prep Date:


Units: µg/L

PQL


MSD

Run ID: GC9_130708B

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1


8047010000GRO (C6-C10) 76.6 70-130 30200 4.917661112.30100 Surr: Toluene-d8 108 70-130 300 3.72108.2

The following samples were analyzed in this batch: 1307193-02A 1307193-03A 1307193-04A1307193-05A




QC BATCH REPORT

Batch ID: 49609 Instrument ID HG1 Method: SW7471

QualRPD Limit


Prep Date: 7/10/2013


Units: mg/Kg

PQL


MBLK

Run ID: HG1_130710A

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1


Mercury 0.020ND

QualRPD Limit




Units: mg/Kg

PQL


LCS

Run ID: HG1_130710A

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1


000.1665Mercury 98.7 80-1200.0200.1644

QualRPD Limit




Units: mg/Kg

PQL


MS

Run ID: HG1_130710A

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1


00.0098120.1246Mercury 101 75-1250.0150.1354

QualRPD Limit




Units: mg/Kg

PQL


MSD

Run ID: HG1_130710A

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1


0.13540.0098120.1214Mercury 101 75-125 350.015 2.310.1323





QC BATCH REPORT


QualRPD Limit


Prep Date: 7/8/2013


Units: mg/L

PQL


MBLK


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1


JMagnesium 0.200.01271

QualRPD Limit


Prep Date: 7/8/2013


Units: mg/L

PQL


LCS


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1


0010Magnesium 102 80-1200.2010.24

QualRPD Limit


Prep Date: 7/8/2013


Units: mg/L

PQL


MS


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1

Sample ID: 1307148-13AMS

02.33410Magnesium 102 75-1250.2012.56

QualRPD Limit


Prep Date: 7/8/2013


Units: mg/L

PQL


MSD


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1

Sample ID: 1307148-13AMSD

12.562.33410Magnesium 101 75-125 200.20 1.0412.43

The following samples were analyzed in this batch: 1307193-01C




QC BATCH REPORT


QualRPD Limit


Prep Date: 7/8/2013


Units: mg/Kg

PQL


MBLK


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1


Arsenic 0.25NDBarium 0.25ND

JCadmium 0.100.00202Chromium 0.25ND

JCopper 0.250.0777JLead 0.250.005195JNickel 0.250.02835JSelenium 0.250.0631JSilver 0.250.00104JZinc 0.500.07955

QualRPD Limit


Prep Date: 7/8/2013


Units: mg/Kg

PQL


LCS


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1


005Arsenic 96.5 80-1200.254.824005Barium 102 80-1200.255.08005Cadmium 98.4 80-1200.104.922005Chromium 98.6 80-1200.254.93005Lead 106 80-1200.255.305005Selenium 90.4 80-1200.254.52005Silver 99.9 80-1200.254.996005Zinc 115 80-1200.505.73

QualRPD Limit


Prep Date: 7/8/2013


Units: mg/Kg

PQL


MS


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 4


01.17.225Arsenic 106 75-1251.48.786S024.027.225Barium -42.8 75-1251.420.92

00.24077.225Cadmium 101 75-1250.587.54603.5177.225Chromium 107 75-1251.411.2201.5257.225Copper 95.5 75-1251.48.42202.3387.225Lead 105 75-1251.49.9100.32257.225Selenium 97.5 75-1251.47.36400.0085367.225Silver 98.9 75-1251.47.15308.7017.225Zinc 99.1 75-1252.915.86




QC BATCH REPORT


QualRPD Limit


Prep Date: 7/8/2013


Units: mg/Kg

PQL


MS


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 4


03.9387.022Arsenic 107 75-1251.411.47SO037.827.022Barium 157 75-1251.448.82

00.42587.022Cadmium 103 75-1250.567.69406.0887.022Chromium 120 75-1251.414.5304.7327.022Copper 106 75-1251.412.17

S017.637.022Lead 131 75-1251.426.8501.2877.022Selenium 99.3 75-1251.48.26100.048457.022Silver 99.6 75-1251.47.039

SO030.897.022Zinc 147 75-1252.841.24

QualRPD Limit


Prep Date: 7/8/2013


Units: mg/Kg

PQL


MSD


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 4


8.7861.17.278Arsenic 110 75-125 251.5 3.619.109R20.9224.027.278Barium 83.2 75-125 251.5 35.930.07

7.5460.24077.278Cadmium 109 75-125 250.58 7.578.1411.223.5177.278Chromium 107 75-125 251.5 0.95711.328.4221.5257.278Copper 99.4 75-125 251.5 3.978.763

9.912.3387.278Lead 120 75-125 251.5 11.211.097.3640.32257.278Selenium 103 75-125 251.5 5.897.8117.1530.0085367.278Silver 103 75-125 251.5 4.537.48515.868.7017.278Zinc 87.8 75-125 252.9 4.9915.09

QualRPD Limit


Prep Date: 7/8/2013


Units: mg/Kg

PQL


MSD


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 4


11.473.9387.153Arsenic 102 75-125 251.4 2.2111.22O48.8237.827.153Barium 119 75-125 251.4 5.3146.29

7.6940.42587.153Cadmium 101 75-125 250.57 0.4477.6614.536.0887.153Chromium 107 75-125 251.4 5.7213.7212.174.7327.153Copper 98.6 75-125 251.4 3.2211.7926.8517.637.153Lead 91.6 75-125 251.4 10.424.188.2611.2877.153Selenium 96.5 75-125 251.4 0.9158.1867.0390.048457.153Silver 96.3 75-125 251.4 1.486.936

O41.2430.897.153Zinc 93.3 75-125 252.9 9.3137.57





QC BATCH REPORT


QualRPD Limit


Prep Date: 7/9/2013


Units: mg/Kg

PQL


MBLK


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1


Arsenic 0.25ND

QualRPD Limit


Prep Date: 7/9/2013


Units: mg/Kg

PQL


LCS


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1


005Arsenic 95.2 80-1200.254.762

QualRPD Limit


Prep Date: 7/9/2013


Units: mg/Kg

PQL


MS


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 5


02.7817.8Arsenic 100 75-1252.010.59

QualRPD Limit


Prep Date: 7/9/2013


Units: mg/Kg

PQL


MSD


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 5


10.592.7817.874Arsenic 94.5 75-125 252.0 3.510.22

The following samples were analyzed in this batch: 1307193-06A 1307193-07A 1307193-08A




QC BATCH REPORT


QualRPD Limit


Prep Date: 7/9/2013


Units: mg/Kg

PQL


MBLK


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1


Nickel 0.25ND

QualRPD Limit


Prep Date: 7/9/2013


Units: mg/Kg

PQL


LCS


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1


005Nickel 101 80-1200.255.045

QualRPD Limit


Prep Date: 7/9/2013


Units: mg/Kg

PQL


MS


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 4


02.5357.764Nickel 94.9 75-1251.69.904

QualRPD Limit


Prep Date: 7/9/2013


Units: mg/Kg

PQL


MS


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 4


04.0777.289Nickel 109 75-1251.512.01

QualRPD Limit


Prep Date: 7/9/2013


Units: mg/Kg

PQL


MSD


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 4


9.9042.5357.68Nickel 92.4 75-125 251.5 2.769.634

QualRPD Limit


Prep Date: 7/9/2013


Units: mg/Kg

PQL


MSD


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 4


12.014.0777.463Nickel 100 75-125 251.5 3.711.57





QC BATCH REPORT

Batch ID: 49546 Instrument ID SVMS6 Method: SW8270

QualRPD Limit


Prep Date: 7/8/2013


Units: µg/Kg

PQL


MBLK

Run ID: SVMS6_130709A

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1

Sample ID: SBLKS1-49546-49546

Acenaphthene 30NDAcenaphthylene 30NDAnthracene 30NDBenzo(a)anthracene 30NDBenzo(a)pyrene 30NDBenzo(b)fluoranthene 30NDBenzo(g,h,i)perylene 30NDBenzo(k)fluoranthene 30NDChrysene 30NDDibenzo(a,h)anthracene 30NDFluoranthene 30NDFluorene 30NDIndeno(1,2,3-cd)pyrene 30NDPyrene 30ND

001667 Surr: 2-Fluorobiphenyl 77.6 12-10001294001667 Surr: 4-Terphenyl-d14 111 25-13701854001667 Surr: Nitrobenzene-d5 68.3 37-10701139

QualRPD Limit


Prep Date: 7/8/2013


Units: µg/Kg

PQL


LCS


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1

Sample ID: SLCSS1-49546-49546

00666.7Acenaphthene 78.8 45-11030525.700666.7Acenaphthylene 76.6 45-1053051100666.7Anthracene 80.3 55-10530535.300666.7Benzo(a)anthracene 85.6 50-1103057100666.7Benzo(a)pyrene 93.1 50-11030620.700666.7Benzo(b)fluoranthene 94.4 45-11530629.700666.7Benzo(g,h,i)perylene 98 40-12530653.700666.7Benzo(k)fluoranthene 90.6 45-1153060400666.7Chrysene 89.8 55-11030598.700666.7Dibenzo(a,h)anthracene 97.3 40-1253064900666.7Fluoranthene 87.2 55-11530581.300666.7Fluorene 78.3 50-11030522.300666.7Indeno(1,2,3-cd)pyrene 98.6 40-12030657.300666.7Pyrene 89.9 45-12530599.3001667 Surr: 2-Fluorobiphenyl 73.3 12-10001222001667 Surr: 4-Terphenyl-d14 99.7 25-13701661001667 Surr: Nitrobenzene-d5 70.9 37-10701182




QC BATCH REPORT

Batch ID: 49546 Instrument ID SVMS6 Method: SW8270

QualRPD Limit


Prep Date: 7/8/2013


Units: µg/Kg

PQL


MS


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1


001941Acenaphthene 73.1 45-110871419001941Acenaphthylene 70.7 45-105871373001941Anthracene 79.1 55-105871535001941Benzo(a)anthracene 82.6 50-110871604001941Benzo(a)pyrene 87.2 50-110871693001941Benzo(b)fluoranthene 89 45-115871727001941Benzo(g,h,i)perylene 91.4 40-125871774001941Benzo(k)fluoranthene 86.4 45-115871678001941Chrysene 85.6 55-110871662001941Dibenzo(a,h)anthracene 91.4 40-125871775001941Fluoranthene 82.3 55-115871598001941Fluorene 74.7 50-110871451001941Indeno(1,2,3-cd)pyrene 92.3 40-120871791001941Pyrene 89.9 45-125871746004852 Surr: 2-Fluorobiphenyl 69 12-10003349004852 Surr: 4-Terphenyl-d14 98.5 25-13704779004852 Surr: Nitrobenzene-d5 66.3 37-10703216

QualRPD Limit


Prep Date: 7/8/2013


Units: µg/Kg

PQL


MSD


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1


141901986Acenaphthene 74 45-110 3089 3.61471137301986Acenaphthylene 71.9 45-105 3089 3.921428153501986Anthracene 79.4 55-105 3089 2.751578160401986Benzo(a)anthracene 81.6 50-110 3089 1.031620169301986Benzo(a)pyrene 87.4 50-110 3089 2.541737172701986Benzo(b)fluoranthene 91 45-115 3089 4.531807177401986Benzo(g,h,i)perylene 85.5 40-125 3089 4.371698167801986Benzo(k)fluoranthene 86.8 45-115 3089 2.711724166201986Chrysene 83.5 55-110 3089 0.2361658177501986Dibenzo(a,h)anthracene 87.2 40-125 3089 2.391733159801986Fluoranthene 81.2 55-115 3089 0.91613145101986Fluorene 72.6 50-110 3089 0.6121442179101986Indeno(1,2,3-cd)pyrene 86.6 40-120 3089 4.011721174601986Pyrene 90.5 45-125 3089 2.971798334904965 Surr: 2-Fluorobiphenyl 71 12-100 400 5.133525477904965 Surr: 4-Terphenyl-d14 99.5 25-137 400 3.284938321604965 Surr: Nitrobenzene-d5 68.2 37-107 400 5.193387





QC BATCH REPORT

Batch ID: 49551 Instrument ID VMS8 Method: SW8260B

QualRPD Limit


Prep Date: 7/8/2013


Units: µg/Kg

PQL


MBLK

Run ID: VMS8_130708A

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1


Benzene 30NDEthylbenzene 30NDm,p-Xylene 60NDo-Xylene 30NDToluene 30NDXylenes, Total 90ND

001000 Surr: 1,2-Dichloroethane-d4 101 70-13001010001000 Surr: 4-Bromofluorobenzene 98.5 70-1300985001000 Surr: Dibromofluoromethane 98.5 70-1300985001000 Surr: Toluene-d8 95.2 70-1300952.5

QualRPD Limit


Prep Date: 7/8/2013


Units: µg/Kg

PQL


LCS


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1


001000Benzene 86.6 75-12530865.5001000Ethylbenzene 86.5 75-12530865002000m,p-Xylene 86.2 80-125601724001000o-Xylene 87.2 75-12530872.5001000Toluene 83.2 70-12530832.5003000Xylenes, Total 86.5 75-125902596001000 Surr: 1,2-Dichloroethane-d4 102 70-13001016001000 Surr: 4-Bromofluorobenzene 99 70-1300989.5001000 Surr: Dibromofluoromethane 103 70-13001029001000 Surr: Toluene-d8 98.6 70-1300986

QualRPD Limit


Prep Date: 7/8/2013


Units: µg/Kg

PQL


MS


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 50


01062050000Benzene 88.2 75-1251,5005472001245050000Ethylbenzene 89.5 75-1251,500572000159500100000m,p-Xylene 94.5 80-1253,00025400003098050000o-Xylene 93.8 75-1251,5007790008898050000Toluene 88.6 70-1251,5001333000190400150000Xylenes, Total 94.3 75-1254,5003318000050000 Surr: 1,2-Dichloroethane-d4 93 70-1300465200050000 Surr: 4-Bromofluorobenzene 100 70-1300502200050000 Surr: Dibromofluoromethane 95 70-1300475000050000 Surr: Toluene-d8 98.8 70-130049380




QC BATCH REPORT


QualRPD Limit


Prep Date: 7/8/2013


Units: µg/Kg

PQL


MSD


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 50


547201062050000Benzene 84.2 75-125 301,500 3.6852750572001245050000Ethylbenzene 88 75-125 301,500 1.2856480

254000159500100000m,p-Xylene 89.8 80-125 303,000 1.86249300779003098050000o-Xylene 92 75-125 301,500 1.1677000

1333008898050000Toluene 82.1 70-125 301,500 2.49130000331800190400150000Xylenes, Total 90.6 75-125 304,500 1.69326300

46520050000 Surr: 1,2-Dichloroethane-d4 92.6 70-130 300 0.4854630050220050000 Surr: 4-Bromofluorobenzene 102 70-130 300 1.785112047500050000 Surr: Dibromofluoromethane 98 70-130 300 3.064898049380050000 Surr: Toluene-d8 99 70-130 300 0.20249480

The following samples were analyzed in this batch: 1307193-02A 1307193-03A 1307193-04A1307193-05A




QC BATCH REPORT


QualRPD Limit


Prep Date:


Units: µg/L

PQL


MBLK


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1



0020 Surr: 1,2-Dichloroethane-d4 100 70-120020.030020 Surr: 4-Bromofluorobenzene 97.4 75-120019.490020 Surr: Dibromofluoromethane 97.6 85-115019.530020 Surr: Toluene-d8 101 85-120020.15

QualRPD Limit


Prep Date:


Units: µg/L

PQL


LCS


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1


0020Benzene 87.8 80-1201.017.550020Ethylbenzene 85.5 75-1251.017.10040m,p-Xylene 85.1 75-1302.034.030020o-Xylene 84.2 80-1201.016.830020Toluene 84.6 75-1201.016.920060Xylenes, Total 84.8 75-1303.050.860020 Surr: 1,2-Dichloroethane-d4 101 70-120020.250020 Surr: 4-Bromofluorobenzene 99 75-120019.790020 Surr: Dibromofluoromethane 102 85-115020.450020 Surr: Toluene-d8 98.6 85-120019.73

QualRPD Limit


Prep Date:


Units: µg/L

PQL


MS


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1


0020Benzene 93.9 80-1201.018.780020Ethylbenzene 90.9 75-1251.018.180040m,p-Xylene 92.4 75-1302.036.940020o-Xylene 90.7 80-1201.018.140020Toluene 87 75-1201.017.40060Xylenes, Total 91.8 75-1303.055.080020 Surr: 1,2-Dichloroethane-d4 99.4 70-120019.870020 Surr: 4-Bromofluorobenzene 102 75-120020.460020 Surr: Dibromofluoromethane 100 85-1150200020 Surr: Toluene-d8 95.8 85-120019.16




QC BATCH REPORT


QualRPD Limit


Prep Date:


Units: µg/L

PQL


MSD


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1


18.78020Benzene 90.3 80-120 301.0 3.9118.0618.18020Ethylbenzene 90.4 75-125 301.0 0.49618.0936.94040m,p-Xylene 91.1 75-130 302.0 1.3436.4518.14020o-Xylene 89.4 80-120 301.0 1.4417.88

17.4020Toluene 86.6 75-120 301.0 0.40317.3355.08060Xylenes, Total 90.6 75-130 303.0 1.3754.3319.87020 Surr: 1,2-Dichloroethane-d4 95.9 70-120 300 3.5319.1820.46020 Surr: 4-Bromofluorobenzene 104 75-120 300 1.9420.86

20020 Surr: Dibromofluoromethane 98.1 85-115 300 1.9219.6219.16020 Surr: Toluene-d8 96.2 85-120 300 0.46919.25

The following samples were analyzed in this batch: 1307193-01A




QC BATCH REPORT

Batch ID: 49577 Instrument ID WETCHEM Method: SW7196A

QualRPD Limit


Prep Date: 7/8/2013


Units: mg/Kg

PQL


MBLK

Run ID: WETCHEM_130709K

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1


Chromium, Hexavalent 0.49ND

QualRPD Limit


Prep Date: 7/8/2013


Units: mg/Kg

PQL


LCS


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1


001.969Chromium, Hexavalent 96.2 75-1100.491.894

QualRPD Limit


Prep Date: 7/8/2013


Units: mg/Kg

PQL

Client ID: Ditch 3 SeqNo: 2374080

MS


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1


00.035711.976Chromium, Hexavalent 67 60-1300.491.36

QualRPD Limit


Prep Date: 7/8/2013


Units: mg/Kg

PQL


MSD


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1


1.360.035711.969Chromium, Hexavalent 72 60-130 300.49 6.621.453





QC BATCH REPORT

Batch ID: R123278 Instrument ID WETCHEM Method: SW9045D

QualRPD Limit


Prep Date:


Units: s.u.

PQL


LCS

Run ID: WETCHEM_130708L

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1

Sample ID: WLCSS1-130708-R123278

004.4pH 98.4 90-11004.33

QualRPD Limit


Prep Date:


Units: s.u.

PQL

Client ID: Point of Origin SeqNo: 2371885

DUP

Run ID: WETCHEM_130708L

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1


8.7700pH 0 0-0 200 08.77

The following samples were analyzed in this batch: 1307193-02B 1307193-03B 1307193-04B1307193-05B 1307193-08A




QC BATCH REPORT


QualRPD Limit


Prep Date:


Units: mg/L

PQL


MBLK

Run ID: IC3_130708A

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1



QualRPD Limit


Prep Date:


Units: mg/L

PQL


LCS

Run ID: IC3_130708A

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1


0010Chloride 96.2 88-1071.09.6160010Sulfate 99.8 85-1101.09.982

QualRPD Limit


Prep Date:


Units: mg/L

PQL


MS

Run ID: IC3_130708A

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 2


010.3510Chloride 91.9 75-1252.019.54010.5410Sulfate 94.3 75-1252.019.97

QualRPD Limit


Prep Date:


Units: mg/L

PQL


MSD

Run ID: IC3_130708A

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 2


19.5410.3510Chloride 89.5 75-125 202.0 1.2419.319.9710.5410Sulfate 92 75-125 202.0 1.1519.74

The following samples were analyzed in this batch: 1307193-01B




QC BATCH REPORT

Batch ID: R123324 Instrument ID MOIST Method: A2540 G

QualRPD Limit


Prep Date:


Units: % of sample

PQL


MBLK

Run ID: MOIST_130708A

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1

Sample ID: WBLKS-R123324

Moisture 0.050ND

QualRPD Limit


Prep Date:


Units: % of sample

PQL


LCS


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1


00100Moisture 100 99.5-100.50.050100

QualRPD Limit


Prep Date:


Units: % of sample

PQL


DUP


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1


19.300Moisture 0 0-0 200.050 3.3119.95

QualRPD Limit


Prep Date:


Units: % of sample

PQL

Client ID: Point of Origin SeqNo: 2373012

DUP


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1


21.1700Moisture 0 0-0 200.050 3.821.99

The following samples were analyzed in this batch: 1307193-02B 1307193-03B 1307193-04B1307193-05B 1307193-06A 1307193-07A1307193-08A




QC BATCH REPORT

Batch ID: R123409 Instrument ID TDS Method: A2540 C-97

QualRPD Limit


Prep Date:


Units: mg/L

PQL


MBLK

Run ID: TDS_130709B

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1



QualRPD Limit


Prep Date:


Units: mg/L

PQL


LCS

Run ID: TDS_130709B

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1



QualRPD Limit


Prep Date:


Units: mg/L

PQL


DUP

Run ID: TDS_130709B

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1

Sample ID: 1307203-01A DUP




ALS Group USA, Corp


Client Name: HRL

Work Order: 1307193


Received by: DS



Matrices: Water, SoilCarrier name: FedEx















Login Notes:

Cooler(s)/Kit(s):

08-Jul-13 08-Jul-13 Diane Shaw Bill Carey



CorrectiveAction:

Comments:



SRC Page 1 of 1

18-Jul-2013

HRL Compliance SolutionsMark Mumby

Dear Mark,

Re: WPX KP 34-17 Produced Water Release 7/12/13 Work Order: 1307450

2385 F 1/2 RoadGrand Junction, CO 81505



Ann PrestonElectronically approved by: Ann Preston






Sincerely,




Project: WPX KP 34-17 Produced Water Release 7/12/13Client: HRL Compliance Solutions


Lab Samp ID Client Sample ID Collection DateTag Number Date ReceivedMatrix Hold1307450-01 Ditch 4 Soil 7/12/2013 11:10 7/13/2013 09:451307450-02 Pond 1 Water 7/12/2013 12:30 7/13/2013 09:451307450-03 Trip Blank Water 7/12/2013 7/13/2013 09:45



QUALIFIERS, ACRONYMS, UNITSProject: WPX KP 34-17 Produced Water Release 7/12/13

Client: HRL Compliance Solutions

WorkOrder: 1307450





Acronym Description

Percent of Sample% of sampleMicrograms per Kilogram Dry Weightµg/Kg-dryMicrograms per Literµg/LMilligrams per Litermg/LMillimhos-Centimeter at 25 Degrees Celciusmmhos/cm @25°

none


Method DuplicateDUP



Limit of Detection (see MDL)LOD

Limit of Quantitation (see PQL)LOQ

Method BlankMBLK


Matrix SpikeMS


Practical Quantitation LimitPQL




ASTMD

EPAE

SW-846 Update IIISW


Project: WPX KP 34-17 Produced Water Release 7/12/13Sample ID: Ditch 4Collection Date: 7/12/2013 11:10 AM Matrix: SOIL



Dilution Factor

Lab ID: 1307450-01


SOLUBLE CATIONS FOR SAR SW6020A Analyst: RHPrep Date: 7/18/2013Calcium 7/18/2013 02:36 PM10 mg/L 20120Magnesium 7/18/2013 02:36 PM4.0 mg/L 2080Sodium 7/18/2013 02:36 PM4.0 mg/L 20730


VOLATILE ORGANIC COMPOUNDS SW8260B Analyst: AKPrep Date: 7/15/2013Benzene 7/15/2013 03:52 PM32 µg/Kg-dry 1ND Surr: 1,2-Dichloroethane-d4 7/15/2013 03:52 PM70-130 %REC 199.0 Surr: 4-Bromofluorobenzene 7/15/2013 03:52 PM70-130 %REC 196.5 Surr: Dibromofluoromethane 7/15/2013 03:52 PM70-130 %REC 196.9 Surr: Toluene-d8 7/15/2013 03:52 PM70-130 %REC 192.8





Project: WPX KP 34-17 Produced Water Release 7/12/13Sample ID: Pond 1Collection Date: 7/12/2013 12:30 PM Matrix: WATER



Dilution Factor

Lab ID: 1307450-02


VOLATILE ORGANIC COMPOUNDS SW8260 Analyst: BGBenzene 7/15/2013 05:45 PM1.0 µg/L 1NDEthylbenzene 7/15/2013 05:45 PM1.0 µg/L 1NDm,p-Xylene 7/15/2013 05:45 PM2.0 µg/L 1NDo-Xylene 7/15/2013 05:45 PM1.0 µg/L 1NDToluene 7/15/2013 05:45 PM1.0 µg/L 1NDXylenes, Total 7/15/2013 05:45 PM3.0 µg/L 1ND Surr: 1,2-Dichloroethane-d4 7/15/2013 05:45 PM70-120 %REC 194.8 Surr: 4-Bromofluorobenzene 7/15/2013 05:45 PM75-120 %REC 193.6 Surr: Dibromofluoromethane 7/15/2013 05:45 PM85-115 %REC 192.5 Surr: Toluene-d8 7/15/2013 05:45 PM85-120 %REC 189.2

ANIONS BY ION CHROMATOGRAPHY SW9056 Analyst: EDChloride 7/15/2013 11:31 AM2.0 mg/L 220Sulfate 7/15/2013 11:31 AM2.0 mg/L 25.6

TOTAL DISSOLVED SOLIDS A2540 C-97 Analyst: KFTotal Dissolved Solids 7/15/2013 12:35 PM10 mg/L 1200



Project: WPX KP 34-17 Produced Water Release 7/12/13Sample ID: Trip BlankCollection Date: 7/12/2013 Matrix: WATER



Dilution Factor

Lab ID: 1307450-03


VOLATILE ORGANIC COMPOUNDS SW8260 Analyst: BGBenzene 7/15/2013 06:10 PM1.0 µg/L 1NDEthylbenzene 7/15/2013 06:10 PM1.0 µg/L 1NDm,p-Xylene 7/15/2013 06:10 PM2.0 µg/L 1NDo-Xylene 7/15/2013 06:10 PM1.0 µg/L 1NDToluene 7/15/2013 06:10 PM1.0 µg/L 1NDXylenes, Total 7/15/2013 06:10 PM3.0 µg/L 1ND Surr: 1,2-Dichloroethane-d4 7/15/2013 06:10 PM70-120 %REC 197.2 Surr: 4-Bromofluorobenzene 7/15/2013 06:10 PM75-120 %REC 194.8 Surr: Dibromofluoromethane 7/15/2013 06:10 PM85-115 %REC 194.2 Surr: Toluene-d8 7/15/2013 06:10 PM85-120 %REC 190.0




Project: WPX KP 34-17 Produced Water Release 7/12/13


QC BATCH REPORT

Batch ID: 49723 Instrument ID ICPMS2 Method: SW6020A (Dissolve)

QualRPD Limit




Units: mg/L

PQL


DUP


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 20

Sample ID: 1307450-01BDUP

121.900Calcium 0 0-010 15.4142.279.900Magnesium 0 0-04.0 18.395.96

731.600Sodium 0 0-04.0 7.07785.2

QualRPD Limit

Analysis Date: 7/18/2013



Units: none

PQL


DUP

Run ID: SAR_130718A

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1

Sample ID: 1307450-01BDUP

12.6500Sodium Adsorption Ratio 0 500.010 1.412.47





QC BATCH REPORT


QualRPD Limit




Units: µg/Kg

PQL


MBLK


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1


Benzene 30ND001000 Surr: 1,2-Dichloroethane-d4 102 70-13001015001000 Surr: 4-Bromofluorobenzene 98.4 70-1300983.5001000 Surr: Dibromofluoromethane 99.2 70-1300992001000 Surr: Toluene-d8 102 70-13001018

QualRPD Limit




Units: µg/Kg

PQL


LCS


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1


001000Benzene 103 75-125301030001000 Surr: 1,2-Dichloroethane-d4 96.3 70-1300963001000 Surr: 4-Bromofluorobenzene 101 70-13001010001000 Surr: Dibromofluoromethane 103 70-13001026001000 Surr: Toluene-d8 102 70-13001018

QualRPD Limit




Units: µg/Kg

PQL


MS


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1


001000Benzene 91.7 75-12530917001000 Surr: 1,2-Dichloroethane-d4 97.5 70-1300975001000 Surr: 4-Bromofluorobenzene 103 70-13001032001000 Surr: Dibromofluoromethane 97.2 70-1300972001000 Surr: Toluene-d8 103 70-13001032

QualRPD Limit




Units: µg/Kg

PQL


MSD


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1


91701000Benzene 93.6 75-125 3030 2935.597501000 Surr: 1,2-Dichloroethane-d4 101 70-130 300 3.581010

103201000 Surr: 4-Bromofluorobenzene 104 70-130 300 1.06104497201000 Surr: Dibromofluoromethane 100 70-130 300 2.991002

103201000 Surr: Toluene-d8 103 70-130 300 0.09691031





QC BATCH REPORT


QualRPD Limit


Prep Date:


Units: µg/L

PQL


MBLK


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1



0020 Surr: 1,2-Dichloroethane-d4 92.8 70-120018.560020 Surr: 4-Bromofluorobenzene 90.3 75-120018.060020 Surr: Dibromofluoromethane 90.6 85-115018.130020 Surr: Toluene-d8 88.4 85-120017.67

QualRPD Limit


Prep Date:


Units: µg/L

PQL


LCS


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1


0020Benzene 92.9 80-1201.018.580020Ethylbenzene 91.1 75-1251.018.220040m,p-Xylene 90.6 75-1302.036.240020o-Xylene 89.3 80-1201.017.860020Toluene 95.2 75-1201.019.030060Xylenes, Total 90.2 75-1303.054.10020 Surr: 1,2-Dichloroethane-d4 87 70-120017.390020 Surr: 4-Bromofluorobenzene 92 75-120018.410020 Surr: Dibromofluoromethane 90.2 85-115018.040020 Surr: Toluene-d8 90.2 85-120018.04

The following samples were analyzed in this batch: 1307450-02A 1307450-03A




QC BATCH REPORT

Batch ID: 49723 Instrument ID WETCHEM Method: USDA H60 Method

QualRPD Limit




Units: mmhos/cm @25°C

PQL


DUP

Run ID: WETCHEM_130718E

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 5


5.300Electrical Conductivity @ Saturation 0 500.025 125.975





QC BATCH REPORT


QualRPD Limit


Prep Date:


Units: mg/L

PQL


MBLK

Run ID: IC3_130715A

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1



QualRPD Limit


Prep Date:


Units: mg/L

PQL


LCS

Run ID: IC3_130715A

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1


0010Chloride 96.1 88-1071.09.6120010Sulfate 99 85-1101.09.904

QualRPD Limit


Prep Date:


Units: mg/L

PQL

Client ID: Pond 1 SeqNo: 2379485

MS

Run ID: IC3_130715A

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 2


019.7710Chloride 104 75-1252.030.1405.63310Sulfate 100 75-1252.015.68

QualRPD Limit


Prep Date:


Units: mg/L

PQL

Client ID: Pond 1 SeqNo: 2379486

MSD

Run ID: IC3_130715A

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 2


30.1419.7710Chloride 101 75-125 202.0 0.95229.8515.685.63310Sulfate 97.6 75-125 202.0 1.8315.39





QC BATCH REPORT

Batch ID: R123638 Instrument ID TDS Method: A2540 C-97

QualRPD Limit


Prep Date:


Units: mg/L

PQL


MBLK

Run ID: TDS_130715A

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1



QualRPD Limit


Prep Date:


Units: mg/L

PQL


LCS

Run ID: TDS_130715A

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1



QualRPD Limit


Prep Date:


Units: mg/L

PQL


DUP

Run ID: TDS_130715A

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1

Sample ID: 1307425-01ADUP






QC BATCH REPORT

Batch ID: R123643 Instrument ID MOIST Method: A2540 G

QualRPD Limit


Prep Date:


Units: % of sample

PQL


MBLK

Run ID: MOIST_130715C

SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1

Sample ID: WBLKS-R123643

Moisture 0.050ND

QualRPD Limit


Prep Date:


Units: % of sample

PQL


LCS


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1


00100Moisture 100 99.5-100.50.05099.99

QualRPD Limit


Prep Date:


Units: % of sample

PQL


DUP


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1

Sample ID: 1307466-01A DUP

9.7600Moisture 0 0-0 200.050 13.98.49

QualRPD Limit


Prep Date:


Units: % of sample

PQL


DUP


SPK ValSPK Ref

ValueRPD Ref

ValueControl

Limit

DF: 1


21.0600Moisture 0 0-0 200.050 1.4820.75



ALS Group USA, Corp


Client Name: HRL

Work Order: 1307450


Received by: DS



Matrices: Soil, WaterCarrier name: FedEx















Login Notes:

Cooler(s)/Kit(s):

13-Jul-13 15-Jul-13 Diane Shaw Ann Preston



CorrectiveAction:

Comments:



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